Kebreab Ghebremichael, PhD Prof. Gary Amy, PhD 2007 · Factors affecting DBPs formation Water...
Transcript of Kebreab Ghebremichael, PhD Prof. Gary Amy, PhD 2007 · Factors affecting DBPs formation Water...
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Disinfection
Kebreab Ghebremichael, PhDProf. Gary Amy, PhD
2007
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Objectives and means of disinfection
• Destruction or inactivation of pathogenic organisms
• Disinfection can be done by:– chemical means- chlorine,
ozone, – non-chemical means- heat,
UV irradiation
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Mechanisms of pathogen inactivation
• Destruction of cellular structure• Interference with metabolic activities and
protein synthesis– In water treatment combinations of these
mechanisms play role
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Microorganisms• Microorganisms of concern include:
Type Size, μmViruses 0.01 to 0.1
Bacteria 0.1 to 5
Cryptosporidium oocysts 3 to 5
Giardia cysts 6 to 10
Protozoan 10 to 25
Algae 5 to 100
• Indicator organisms are often used to assess the presence or absence of pathogens
• Common indicator organisms are coliforms- E-coli
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Disinfection kinetics
• Chick’s law• Best described by first order reaction
• N/N0 = e -k.t reduction factor (R)
• Where – N = concentration of organisms (N/m3)– No = initial concentration of organisms (N/m3)– t = time– k = rate constant- this depends on disinfectant concentration,
organism and temperature
tkNNNk
dtdN *ln*
0−=⎟⎟
⎠
⎞⎜⎜⎝
⎛→−=
number of micro-organisms destroyed per unit of time is proportional to the number of organisms
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• Chick-Watson model– Relates the rate
constant of inactivation, k, to the disinfectant concentration, C.
– k = k’Cb b is coefficient of dilution
ln (N/N0) = k’Cb t
Disinfection kinetics
Source: Faust and Aly, 1998
(Lee and Nam, 2002)
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Removal of microorganisms during water treatment
Significant removal of microorganisms is achievable by processes other than disinfection.USEPA- Surface Water Treatment Rule (SWTR) –gives log removal credits to other processes
Log removalTreatment
Giardia Viruses
SWTR 3.0 (99.9%)
4.0 (99.99%)
Slow sand filtration 2.0 2.0
Conventional treatment 2.5 2.0
Direct filtration 2.0 1.5
Membrane processes 3-4 3-4*
* using Ultrafiltration
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Factors affecting disinfection
• Turbidity (particulates can shield micro organisms); turbidity should not exceed 0.5 NTU;
• Organic matter and ammonia (they react with disinfectants);
• pH (may change chemical form of disinfectant e.g. HOC / OCl-);
• Temperature (diffusion and reaction rate);• Disinfectant dose and contact time
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Primary and secondary disinfection
Primary disinfection: Commonly achieved by combination of filtration and chemical oxidation
Secondary or post disinfection: Maintaining residual disinfectant in the distribution system in order to control re-growth
Residual chlorine requirements at consumers points
WHO USEPA NL
Residual concentration, mg/L 0.2 0.25 0.0
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Re-growth
Main cause
• Availability of AOC and nutrient in the distribution system
Main effects
• Formation of taste and odour under anaerobic conditions
• Growth of macro-organisms e.g. worms;
• Corrosion
Control mechanisms
• Effective treatment to produce biostable water;
• Ensuring sufficient residual disinfectant in the network
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Common disinfection chemicals
Chlorine compounds-Cl2,
Can be found in liquefied gas, solution or solid forms
Ozone (O3)
Chlorine dioxide (ClO2)
Chloramine (eg. NH2Cl)
Potassium permanganate (KMnO4)-
produced on site
produced on site
formed by addition of ammonium and chlorine to the water
a violet solid
Silver (Ag+) in ceramic filters
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Strength and stability of disinfectants
Disinfectant Power Stability
OCl – (hypochlorite) Weak Decomposes slowly
Decomposes slowly
Very stable
(Very) stable
O3 Very strong Very unstable
KMnO3 Weak Unstable
HOCl (Hypochlorousacid) Strong
NH2Cl (Monochloramine) Very weak
ClO2 Strong
Which disinfectants are suitable for post disinfection?
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Effectiveness of disinfectants• Disinfectants can be compared in terms of CT value
– C is disinfectant dosage, mg/L– T contact time, min
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Chlorine
Compound Form % Chlorine
Chlorine(Cl2)Liquefied
gas 100
10 to 15
25 to 35
70
Sodium hypochlorite solution (NaOCl) Solution
Bleaching powder (CaOCl2) Solid
High test hypochlorite Ca(OCl)2 Solid
Chlorine is the most commonly used and low cost disinfectant. It is available in four different forms:
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Dissociation of chlorine
Chlorine dissolves in water & at normal pH it yields HOCl and OCl-
Cl2 + H2O → HOCl + H+ + Cl-
HOCl ↔ OCl- + H+
Sodium hypochlorite, Bleaching
powder, High Test Hypochlorite also
form HOCl and OCl-
Note that above pH 4, Cl2 does not exist
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Break point chlorination
Break point chlorination is the addition of sufficient chlorine to produce free available chlorine
HOCl and OCl- react with ammonium to form:monochloramine;dichloramine; trichloramine or oxidize it to N2
sum of HOCl and OCl- = Free available chlorineSum of mono-, di- and tri- chloramines = Combined available chlorineSum of free and combined chlorine = Total available chlorine
All forms are expressed as mg Cl2/l.
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Break point chlorinationSummary of the reactions:
I. 2NH4+ + 2Cl2 → 2NH2Cl + 4H+ + 2Cl-
II. 2NH2Cl + 2Cl2 → 2NHCl2 + 2H+ + 2 Cl-
III. 2NHCl2 → N2 + Cl2 + 2H+ + 2Cl- formed Cl2 reacts with remaining NH4
IV. 2NH4+ + 3 Cl2 → N2 + 8H+ + 6Cl-
The overall reaction is known as:
" Breakpoint Chlorination "
In general 6 mg Cl2 is required per mg NH4+
In practice more chlorine is required due to presence of organic matter
1 mg NH4+ requires 4 mg Cl2
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Break point chlorination
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Disinfection by products (DBPs)
• DBPs are produced by the reaction of disinfectants and– mainly organic compounds (NOM)– bromide ion
• Most common DBPs include:– Trihalomethanes (THMs)– Haloaceticacids (HAAs)– Bromate– Chlorite
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Guidelines for DBPs
* Maximum contaminant levels goals** HAA5: Sum of five HAAs,
DBPs Maximum contaminant level (μg/L)
WHO (1993) USEPA (2006)
100 0*
60*
0*
70*
80
60
10 (Average value)
1mg/L
100
60
200
50
HAA5**
Bromate 10
EU
Bromoform
Dibromochloromethane
Bromodichloromethane
Chloroform
TTHM 100
Chlorite
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Factors affecting DBPs formation
Water quality: Operational parameters
Type and concentration of precursors NOM, bromide
Disinfectant type and dose
pH Contact time (water age)
Temperature
Ammonia concentration
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0
10
20
30
40
50
0 5 10 15 20
Water age (hours)
TTH
M /
THA
As (
ug/L
)
TTHM THAAs ( six species )
0
20
40
60
80
4 5 6 7 8 9 10
pH
TTH
M /
THA
As (
ug/L
)
T THM T HAAs ( six species )
Factors affecting DBPs formation
Time
pH
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Isopleths of DBPs and chlorine residual in distribution networks
TTHM
Chlorine residual
THAA
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Chemical risks
DBPsChemical risk factors (per µg/L)
CHCl3 1.7x10-7
CHBrCl2 1.7x10-6
CHBr2Cl 2.4 x10-6
CHBr3 2.5 x10-7
DCAA 3.0 x10-6
TCAA 2.4 x10-6
Total chemical risks for DBPs formations
Risk from BrO3- is much higher - a
shift to H2O2-UV is envisaged
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Advanced disinfection
• Ozonation– More effective than chlorine, but expensive– Not much DBPs compared to chlorine– Ozone reacts with organic matter to form
biodegradable DOC• DOC + O3 → BDOC + O2
• BDOC include: Aldehydes, Carboxylic Acids, etc.
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Ozonation process
InfluentEffluent
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Ozone disinfection by products
• Ozone can directly or indirectly react with bromide to form ozone DBPs including bromate ion (BrO3
-)
• In the presence of NOM, non-halogenated DBPs are formedThese compounds are more easily assimilable (AOC) by bacteria than NOM,
• If both NOM and bromide are present, ozonation forms hypobromous acid, resulting in the formation of brominatedorganohalogen compounds (e.g. bromoform).
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A Potential Consequence of using ozone
• Creation of Biodegradable Organic Matter (BOM) from Natural Organic Matter (NOM)
• This results in– Transformation of Rapid Sand Filter (RSF) into Biological Sand
Filter (BSF) with Biofilm– Transformation of Granular Activated Carbon (GAC) into
Biological Activated carbon (BAC) with Biofilm
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UV disinfection
• Very effective with up to 99 % removal- Viruses requires higher UV dosage
• Penetrates the cell wall and destroys DNA
• No residual disinfectant
• Requires good water quality
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• High tech using UV lamps
UV disinfection
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UV disinfection
www.sodis.ch
• Low tech using solar energy (SODIS)
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Disinfection experience in the Netherlands and elsewhere
• Philosophical approach– North America:
• Remove NOM before Cl2
• DOC as a contaminant
– Central Europe:• Biostability• Limit biodegradable NOM (BOM) and eliminate Cl2• BDOC (or AOC) as a contaminant
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Practice in USA
• Chemical Disinfectants Employed– Chlorine – Chloramines– Ozone – Chlorine Dioxide
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Practice in Europe• Southern Europe and UK
– Chlorine with Distribution System Residual
• Central Europe (e.g., Berlin, Amsterdam, Zurich, Vienna)– No Distribution System Residual!
• Some parts of Europe (e.g., Paris)– Low Cl2 levels in distribution system- use booster
chlorination
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Thank you
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Conventional water treatment
FlocculationCoagulation
Sludge Backwash
Lime
Filtration Storage
ChlorineAlum Lime
Sedimentation