UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III

STH AND WALNUT STREETSPHILADELPHIA. PENNSYLVANIA 19,106

In Reply Refer To: (3EN33)/ ' '

JUN 11198)Carl Everett, EsquireE.I. Du Pont de Nemours

and CompanyLegal Department1007 Market StreetWilmington, Delaware 19898

Re: Landfill on the Newport Pigment Plant Site

Dear Mr. Everett:

I am writing to confirm our telephone conversation of Thursday,June 5, 1980, during which you indicated that Du Font's NewportPigment Plant should be able to provide the Environmental Pro-tection Agency with any specific information which is availableabout the contents of the landfill on the Newport Pigment Plant site,as well as information about the construction of the landfill itself.

During our conversation you indicated that you believed that thelandfill was .used during the period from 1902 to 1975, and that theproperty had been bought by Du Pont in 1929. (I would appreciate havingthis information confirmed by letter as well.) In addition, you sta-ted that you -believed it would be impossible for plant personnelto determine exactly what went into the landfill, because you believedthat the material was deposited prior to the time when governmentalregulations required that such records be kept. Therefore, I recog-nize that it may be difficult for Newport Pigment Plant to providespecific data concerning some of the information which I am reques-ting, which is as follows:

What substances were disposed at the landfill on whatdates, (or general time periods; e.g., 1929-1940, etc.)the source and amount of each substance, as wellas the location and form (e.g., drums, liquid) of thed isposal ;

Was the waste treated in any way prior todisposal?

AR2003H

What is known about the construction of thelandfill r-(i.e., is any portion of it lined; are there "'construction plans which could be provided)?

How long was the landfill active?

Even if there is no precise data concerning the above questions, Iwould appreciate the most specific information which can be obtained.

For example, if plant personnel are not certain as to exactly whatwas deposited from 1970 to 1975, if an estimate could be provided interms of volume of waste disposed by type, that information would bepreferable to a breakdown in percentages without any volume specified.

As you requested, I am enclosing copies of the summaries of EPA'ssampling results from those samples taken from the Newport PigmentPlant site on February 21, 1980. I would also like to confirm my re-quest for copies of the analyses done by Du Pont on' the "split samples"which were obtained by plant officials on February 21, 1980.

I appreciate your cooperation in this matter, and I hope that it—w-rtt~Jbe possible for you to provide this information within the nextcouple of weeks.

Sincerely,

Ruthanne GordonAttorney, Legal Branch (3EN33)

Enclosures

AR2003I45

;f" *'• . * ' • • " ANNAPOLIS "FIELD OFFICE, E-siOfi inra "~ : ' 'gL. DATE: Hay 2, 1980

JUJJJECTJ Newport Pigments'^^ - <

..._.«: P. G. Johnson*jf Physical Scientist

(Red)TO: Daniel K. Donnelly

Chief, Lab Section

The samples identi d~tJeltwn«fer«--*i<ibjected to quantitative analysis byflame and furnace(atomic absorption.) Precision and accuracy data ispresented following the analytical results.

+-.—————————————————yg/l ——————————————————».Sample No. As_ Se_ Cj[ Cr Pb Ag Ba

800225-01 <2 8 3900** 31** 37 0.7 1170**02 ' <2 <2 <50 <1 20 <.2 13003 :<2 3 <50 <1 23 .3 12604 <2* <2* <50* <1* 17* <,2* 28*05 <2 <2 <50 <1 8.8 <.2 3606 <2 <2 <50 <1 8.4 <.2 3£

Avg. Coefficientof Variation,* 1.9' - 0.7 2.9 3.1

I Replicates n=2 n=O n*2 n=2 n=2% R, Ref. 100.0Sample 111.5 87.5 98.5 100.0 110.4

X R, CheckStd. 110.0 100.0 101.0 104 116

*dup!1cate preparation • . •**Spiked$R 97.5 110 • 92.0

*• •*

Sample No, location

800225-01 Newport Pigments Well, #DH-3 C000602 Newport Pigments Hell, sDM-6 C000703 Newport Pigments Hell, fDM-5 C000804. City of Newport - water supply C000905 Christina River (upstream) C001006 Christina River (downstream) C0011 .

' • • ' • - . - 'TWohnsontad . ^ A R 20.031 6

- ... _ .... - .- . . . . . . , . - - . . ,;-. .. ,

W6ST COAST TECHNICAL SGRVJCG INC. INDUSTRIAL CATEGORY.

MPLE ID C0006 Well Water \U' / SAMPLE ID C0006 Well WaterLAB ID ___ 19006A1_______ LAB ID______19006B1DATE EXTRACTED 2/28/80_________ DATE EXTRACTED 2/28/80DATE INJECTED 3/22/80_________ DATE INJECTED 3/17/80 0";STD ID DFTPP987 SENS69 Phenol202 STD ID DFTPP982 BENZ240 BN5TD1 75CONC FACTOR 1000___________ CONC FACTOR_____IQQQ_________

Acid Compounds ug/1 . Base/Neutral Compounds ug/121A 2.4,6-trichlorophenol____ND- 41B 4-bromophenyl phenyl ether Nn22A24A31A34A57A58A59A60A64A65A

p-chloro-m-cresol2-chlorophenol2, 4-dichlorophenol2,4-dimethylphenol2-nitrophenol4-nitrophenol2 , 4-dinitrophenol4 , 6-dinitro-o-cresolpentachlorophenolphenol

NDNDNDNDNDNDNDNDND

ND

Base/Neutral Compounds

IB5B8B9B12B18B20B25B26B27B28B35B36B37B

39B

acenaphthenebenzidine1,2, 4-trichlorobenzenehexachlorobenzenehexachloroethanebis ( 2-chloroethyl ) ether2-chloronapthalene1 , 2-dichlorobenzene1 , 3-dichlorobenzene1 , 4-dichlorobenzene3,3' -dichlorobenzidine2,4-dinitrotoluene2,6-dinitrotoluene1,2-diphenylhydrazine(as azobenzene)fluoranthene

ND

ND

ND

ND

ND

ND

KpfZ~\

'/( i * Jf m */\*rS

pJTj

PJTf ~

PJ^J

wn

ND

42B43B52B53B54B55B56B61B62B63B66B67 B68B69B70B71B72B73B74B75B76B77B78B79B80 B81B82B :83B84B

bis(2-chloroisopropyl) etherbis (2-chloroethoxy) methanehexachlorobutadienehexachlorocyclopentadieneisophoronenaphthalenenitrobenzeneN-nitrosodimethylamineN-nitrosodiphenylamineN-nitrosodi-n-propylaminebis (2-ethylhexyl) phthalatebutyl benzyl phthalatedi-n-butyl phthalatedi-n-octyl phthalatediethyl phthalatedimethyl phthalatebenzo(a) anthracenebenzo(a)pyrene3, 4-benzofluoranthenebenzo(k)fluoranthenechryseneacenaphthyleneanthracenebenzo(ghi)perylenefluorenephenanthrene flR?flflf~i 1 1 \jdibenzof a, h) anthraceneindeno(l,2,3-cd)pyrenepyrene

ND

ND

ND

ND

ND

ND

ND

ND

WD -

Krn

*

*

*

ND

ND

ND

ND

ND

ND

ND

-WD —

ND

ND

NDNDaa. 7v*l 1-NB —-NB —-NB —

40B 4-chlorophenyl phenyl eth^g, 129B 2,3,7,8-tetrachlorodibenzo-""' - ^<—<- Ml\

WeST COAST TECHNICAL SEVICE INC. INDUSTRIAL CATEGORY; 4jf f~ flfo.j&MPLE ID C0006 Well Water \ 0' /M:.AB ID 19006V3K>ATE INJECTED 3/11/80"TO ID DFTPP975 19005V12CONC. FACTOR

Volatiles2V acrolein3V acrylonitrile '4V benzene '6V carbon tetrachloride

7V chlorobenzene /10V 1,2-dichloroethane11V 1,1,1-trichloroethane13V 1,1-dichloroethane14V 1,1,2-trichloroethane15V 1,1,2,2-tetrachloroethane^6V chloroethane|?7V bis(chloromethyl) ether19V 2-chloroethylvinyl ether23V chloroform

29V 1, 1-dichloroethylene30V 1,2-trans-dichloroethylene32V 1,2-dichloropropane33V 1,3-dichloropropylene38V ethylbenzene44V methylene chloride45V methyl chloride46V methyl bromide47V bromoform48V dichlorobromomethane

49V trichlorofluoromethane50V dichlorodifluoromethane51V chlorodibromornethane•5V tetrachloroethylenef — ——— —— —— — — I ————————— 186V toluene87V trichloroethylene88V vinyl -chloride

V^

ug/1' ND

ND*

ND

ND( 11 /NDNDNDNDNDNDNDNDNDNDNDNDND*

ND

NDND

ND

ND

J$£*1 ND, fl

_• f<f)v r s. « '« ** ** *• * •ND

' SAMPLE ID C0006LAB ID Traces #29 & 28DATE EXTRACTED 2/28/80DATE INJECTED 3/20/80STD ID Trace #26CONC. FACTOR 1 & 1/100 OIL

Pesticides89P aldrin90P dieldrin91P chlordane92P 4,4'-DDT93P 4, 4 '-DDE94P 4, 4 '-ODD95P alpha-endosulfan96P beta-endosulfan ,97P endosulfan sulfate f\

i/98P endrin V_99P endrin aldehyde -

i/iOOP heptachlor/CD /vXiOlP heptachlor epoxide102P alpha-BHC103P beta-BHC104P gamma-BHC105P delta-BHC106P PCB-1242107P PCB-1254108P PCB-1221109P PCB-1232HOP PCB-1248HIP PCB-1260112P PCB-1016113P toxaphene

**| (pesticides less than 5 ug/1)/ ND = Not detected

** = Not confirmed by GCMS(1)= Unresolved

ORSGIf^U.(Red)

ug/1ND

NDND

ND

28.7 /- JtfD- •y-~~**45.0

V ND- -

**28.180._ JD--:

ND" v

**610.2"" —— ND"""

**.2

-_ND" "

ND

ND

ND

ND

ND

ND

ND

•NTDND

>jn

r TECHNICAL S6jRyj£6 INC. .INDUSTRIAL( M'to)C0007 Well Water \Pn / SAMPLE ID C00n7

19006A2 LAB IDDATE EXTRACTED 2/28/80 ___________ DATE EXTRACTED ?/7a/fin _____DATE INJECTED 3/22/80 __________ DATE INJECTED yi7/RQ ______STD ID DFTPP987 SENS69 Phenol202 STD ID DFTPPQ87 RFN7.9An 'RTJSTm 7?CONC FACTOR 1000 ________ CONC FACTOR 1nnn

Acid Compounds ug/1 Base/Neutral Compounds ug/121A 2,4,6-trichlorophenol_______ND 41B 4-bromophenyl phenyl ether

40B 4-chlorophenyl phenyl" ether ym -129B 2,3,7,8-tetrachlorodibenzo-p-dioxin_________________.

22A24A31A34A57A58A59A60A64A65A

p-chloro-m-cresol '.2-chlorophenol2,4-dichlorophenol2,4-dimethylphenol2-nitrophenol4-nitrophenol2 , 4-dinitrophenol4 , 6-dinitro-o-cresolpentachlorophenolphenol

ND

ND

ND

ND

ND

ND

Np

NDMnNn

Base/Neutral Compounds

IB5B8B9B12B18B20B25B26B27B28B35B36B37B

39B

acenaphthenebenzidine1 , 2,4-trichlorobenzenehexachlorobenzenehexachloroethanebi s ( 2-chloroethyl ) ether2-chloronapthalene1 , 2-dichlorobenzene1 , 3-dichlorobenzene1 , 4-dichlorobenzene3,3'-dichlorobenzidine2 , 4-dinitrotoluene2 , 6-dinitrotoluene1 , 2-diphenylhydrazine(as azobenzene)fluoranthene

ND

ND

ND

ND

ND

ND

NnNnwnranwn

ND" ND

ND

ND-v *

42B43B52B53B54B55B56B61B62B63B66B67B68B69B70B71B72B73B74B75B76B77B78B79B80B81B82B83B84B

bis(2-chloroisopropyl) etherbis (2-chloroethoxy) methane'hexachlorobutadienehexachlorocyclopentadieneisophoronenaphthalenenitrobenzeneN-nitrosodimethylamineN-nitrosodiphenylamineN-nitrosodi-n-propylaminebis (2-ethylhexyl) phthalatebutyl benzyl phthalatedi-n-butyl phthalatedi-n-octyl phthalatediethyl phthalatedimethyl phthalatebenzo(a) anthracenebenzo(a)pyrene3, 4-benzofluoranthenebenzo ( k ) fluoranthenechryseneacenaphthyleneanthracenebenzo (ghi)perylenefluorenepfeenanthrenedibenzo ( a , h ) $flh£fl:ar» r nindeno( 1 , 2,3-cd)pyrenepyrene

NDND

ND

-ND-

-44B-

-NB-ND

ND

ND*-

wn*

ND

ND

ND

ND

NDND

-NB-ND

-4JB-

-WB--NB-ND

ND

NnNnNn,

W6S1 Lo ia r TECHNICAL SERVi-C£.INC. INDUSTRIAL L

SAMPLE ID mnm M«n M-^/Dfl x SAMPLE ID 00007LAB ID 19006V5 ^^ LAB ID____ Trace #31f iij —————————————————————————• ______________________DATE INJECTED_____3/11/80_________ DATE EXTRACTED_____?/?9/anSTD ID pp^ppQ7^ iQn0gvl2_______ DATE INJECTED_______3/20/80CONC. FACTOR STD ID

CONC. FACTOR________in

Volatiles ug/1 Pesticides • ' . - . - ' ug/12V acrolein _Mn_ 89P aldrin rm3V4V6V7V10V11V13V14V15V16V

fel7VP 19V

23V29V30V32V33V38V44V45V46V47V48V49V50V51V85V

•P6V^^_ ——87V

acrylonitrilebenzenecarbon tetrachloridechlorobenzene1 , 2-dichloroethane1,1, 1-trichloroethane1 , 1-dichloroethane '1,1, 2-trichloroethane1 , 1 , 2, 2-tetrachloroethanechloroethanebis(chloromethyl) ether2-chloroethylvinyl ether .chloroform1 , 1-dichloroethylene1 , 2-trans-dichloroethylene1 , 2-dichloropropane1 ,3-dichlorbpropyleneethylbenzenemethylene chloridemethyl chloridemethyl bromidebromoformdichlorobromomethanetrichlorofluoromethanedichlorodifluoromethanechlorodibromomethanetetrachloroethylenetoluenetrichloroethylene

- KinND

NDND*

ND

NDNDNDNDND

NDND

ND

NDND

NDND*

NDNDNDNDNDND

' -ND.NDND

..»D.«-

90P dieldrin91P chlordane92P 4,4'-DDT93P 4, 4 '-DDE94P 4, 4 '-ODD95P alpha-endosulfan96P beta-endosulfan97P endosulfan sulfate98P endrin99P endrin aldehyde100P heptachlor101P heptachlor epoxide102P alpha-BHC103P beta-BHC104P gamma-BHC105P delta-BHC106P PCB-1242107P PCB-1254108P PCB-1221109P PCB-1232HOP PCB-1248HIP PCB-1260

- 112P PCB-1016113P tbxaphene

J D

—————— j^— — ND-

V __ NJ>ND

NDND

ND^— ND**5i?

ND-ND

'' ND**3vl

V ND

ND

ND

ND

ND

ND

ND

Nn

Nnwn

* = Less than 10 ug/1(pesticides less than 5 ug/1)

ND = Not detected ^ AR200350** = Not confirmed by GCMS

88V vinyl chloride "'_____ND

COAST TECHNICAL SGRXUCE INC. INDUSTRIAL L^I i_uORY.

C0008 Well WateA^X SAMPLE ID____COOQ8 Well Wa+ipr_______19006B3_________ LAB ID___________IQnnfifn

DATE EXTRACTED_____2/28/80______ DATE EXTRACTED_____?/?R/Rn C"\DATE IN1-:-"TED______3/22/80_____ DATE INJECTED______yi7/RnSTD ID DFTPP987 SENS69 Phenol202 STD IDCONC FACTOR______IQQQ__________ CONC FACTOR_______i nnn

Acid Compounds ug/1 Base/Neutral Compounds ug/121A 2,4,6-trichlorophenol______K?D 41B 4-bromophenyl phenyl ether Mn22A24A31A34A57A58A59A60A64A65A

p-chloro-m-cresol •2-chlorophenol2 , 4-dichlorophenol2, 4-dirnethylphenol2-nitrophenol4-nitrophenol2 , 4-dinitrophenol4 , 6-dinitro-o-cresolpentachlorophenolphenol

ND

ND

ND

ND

ND

ND

ND

ND

NDNn

Base/Neutral Compounds

IB5B8B9B12B18B20B25B26B27B28B35B36B37B

39B40B

.acenaphthenebenzidine1,2, 4-trichlorobenzenehexachlorobenzenehexachloroethaneb i s ( 2-chloroethy 1 ) ether2-chloronapthalene1 , 2-dichlorobenzene1 , 3-dichlorobenzene1 , 4-dichlorobenzene3 , 3 ' -dichlorobenzidine2 , 4-dinitrotoluene2 , 6-dinitrotoluene1 , 2-diphenylhydrazine(as azobenzene)fluoranthene x'«*'4-chlorophenyl phenyl ether

NDKin

ND

ND

NDND

ND

ND

ND

ND

ND

ND

ND

'.•VV "' Vnxin

42B43B52B53B54B

. 55B56B61B62B63B66B67B68B69B70B71B72B73B74B75B76B77B78B79B80881B82B83B84B129B

bis(2-chloroisopropyl) etherbis (2-chloroethoxy ) methanehexachlorobutadienehexachlorocyclopentadieneisophoronenaphthalenenitrobenzeneN-nitrosodimethylamineN-nitrosodiphenylamineN-nitrosodi-n-propylaminebis (2-ethylhexyl) phthalatebutyl benzyl phthalatedi-n-butyl phthalatedi-n-octyl phthalatediethyl phthalatedimethyl phthalatebenzo(a) anthracenebenzo(a)pyrene3,4-benzofluoranthenebenzo ( k ) fluoranthenechryseneacenaphthyleneanthracenebenzo(ghi)perylenefluorenephenanthrene... / .» . M 1 1 C, U U «J w 1dibenzo ( a , h ) anthraceneindeno (1,2, 3-cd ) py renepyrene2 , 3 , 7 1 8-tetrachlorodibenzo-

NDND

ND-

*JD

-NO-ND

ND •'•4JD--NO--yrQf

* ,

-NB-

-NB-

-NB--NB-ND

NDNDNDNDNDND

ND

NlP

ND

p-dioxin

i:«W6ST CUA5T TECHNICAL SERVICE INC. INDUSTRIAL LAJ LoORY.

/t' 1

i,:li

' ' if /*•' P \A P T K 7 M {

§-AB ID TPnnfivK'ATE INJECTED q/n /RnTT^ 7 T"\i u lu DFTPPQ7 s 1 Q n n vi ?

• CONC. FACTOR

Volatiles2V acrolein3V acrylonitrile4V benzene6V carbon tetrachloride7V chlorobenzene10V 1 , 2-dichloroethane11V 1,1,1-trichloroethane13V 1,1-dichloroethane14V 1,1,2-trichloroethane15V 1,1,2,2-tetrachloroethane

k.l6V chloroethaneB^ 17V bis(chloromethyl) ether

19V 2-chloroethylvinyl ether23V chloroform.29V 1,1-dichloroethylene30V 1,2-trans-dichloroethylene32V 1 ,2-dichloropropane

- 33V 1,3-dichloropropylene38V ethylbenzene44V methylene chloride45V methyl chloride

. 46V methyl bromide47V bromoform48V dichlorobromomethane49V trichlorofluoromethane50V dichlorodifluoromethane51V chlorodibromomethane85V tetrachloroethylene '(86V toluene ' V87V trichloroethylene s '*

ws>• — -

UH/LND

ND

ND

ND

ND

-* J—wnNDNDNDNDNDND*

NDNDNDNDND*

ND

NDNDND

NDND _-- x.

j NPp)(»4" 86^^KD^/*-*•''

SAMPLE ID ^0008LAB ID iqnnfi Tr^pft^DATE EXTRACTED ?/9R/pnDATE INJECTED ,/7n/nnSTD ID T>- r,o #•>«

CONC. FACTOR 1n

Pesticides89P ' aldrin90P dieldrin91P chlordane92P 4,4'-DDT93P 4, 4 '-DDE94P 4,4'-DDD95P alpha-endosulfan96P beta-endosulfan97P endosulfan sulfate98P endrin99P endrin aldehyde100P heptachlor101P - heptachlor epoxide102P alpha-BHC103P beta-BHC104P gamraa-BHC105P delta-BHC106P PCB-1242107P PCB-1254108P PCB-1221109P PCB-1232HOP PCB-1248111P PCB-1260112P PCB-1016113P toxaphene

\*)« Less than 10 ug/1- (pesticides less than § *b&AND = Not detected** = Not confirmed by GCMS

I

*-. >- .,/ ; - ' :; Jt ;

ug/1rJ^j

** Ti

-Tin '""( **.3

——————— ND-

——————— ND-

——————— NB-s '-"ND

( ***:$ s D( **.4- ^

NDNDNDNDND

ND

ND

ND

ND

NDNDND

NDND

W352

88V . vinyl chloride_________________________ND

. i/ ii, • r,; '• - J:Uy£c;T iiG T TECHNICAL SGRVJCG INC. INDUSTRIAL LAI t^oRY.;; :; ..;.1ij-;I' ' /<fl<)

•!y?E ID C0009 Water SupplV P /\.As ID 19006A4•• DATE EXTRACTED 2/28/80•': DATE INJECTED 3/22/80

'X-i '

STD ID DFTPP987 SENS69 Phenol202• CONC FACTOR 1000

Acid Compounds21A 2, 4,6-trichlorophenol ;22A p-chloro-m-cresol i24A 2-chlorophenol31A 2,4-dichlorophenol34A 2,4-dimethylphenol57A 2-nitrophenol58A 4-nitrophenol59A 2,4-dinitrophenol60A 4,6-dinitro-o-cresol64A pentachlorophenol65A phenol

Base/Neutral Compounds

IB acenaphthene5B benzidine8B 1,2,4-trichlorobenzene9B hexachlorobenzene12B hexachloroethane18B bis(2-chloroethyl)ether20B 2-chloronapthalene25B 1,2-dichlorobenzene26B 1,3-dichlorobenzene27B 1,4-dichlorobenzene28B 3,3'-dichlorobenzidine35B 2,4-dinitrotoluene36B- 2,6-dinitrotoluene37B 1,2-diphenylhydrazine

(as azobenzene)39B fluoranthene

ug/1NDNDND

ND

ND

ND

ND

NDNDND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

wn

"wn""""40B '4-chlorophenyl phenyl ether Mn

1SAMPLE ID C0009 Water SupplyLAB ID 19006R4 r^.mDATE EXTRACTED 2/?8/Rn /,,,-j)DATE INJECTED T/IR/RO

H

STD ID DFTPP983 BEN7241 'RNSTnl 7fiCONC FACTOR 10nn

Base/Neutral Compounds ug41B 4-bromophenyl phenyl ether42B bis(2-chloroisopropyl) ether43B bis (2-chloroethoxy ) methane52B hexachlorobutadiene53B hexachlorocyclopentadiene54B isophorone55B naphthalene56B nitrobenzene61B N-nitrosodimethylamine62B N-nitrosodiphenylamine63B N-nitrosodi-n-propylamine66B bis (2-ethylhexyl) phthalate67B butyl benzyl phthalate68B di-n-butyl phthalate69B di-n-octyl phthalate70B diethyl phthalate71B dimethyl phthalate72B benzo(a) anthracene73B benzo(a)pyrene74B 3,4-benzofluoranthene75B benzo(k)fluoranthene76B chrysene77B acenaphthylene78B anthracene79B -benzo(ghi)peryleneSOB fluorene81B phenanthrene 3R2Q035'-?82B dibenzo(a,h)anthracene.83B indeno(l,2,3-cd)pyrene84B pyrene129B 2,3,7,8-tetrachlorodibenzo-

ZL

wnwnND

ND-ND-ND

~ND-ND

-ND- |

w-w-

*

-ND-4JD-ND

ND

JJD

ND

ND

NnNP

-W*ND

-NB->(-T. } *ND,

ND

MTL

•_.-,. i VECHiviJcAL SEftyJCfc INC. INDUSTRIAL V.AI CAp-ft

C0009 Water Supply\T J SAMPLE ID C0009______________19006V8_______ LAB ID 19006 Trace #33

)ATE INJECTED______3/11/80______ DATE EXTRACTED 2/28/80D ID DFTPP975 19005V12 .-. -^ DATE INJECTED 3/20/80

:ONC. FACTOR___________"_______ STD ID________Trace #26CONC. FACTOR 10

Volatiles . " . . ug/1 Pesticides • ug/12V acrolein ' " ' NP 89P aldrin '3V4V6V7V10V11V13V14V15V16V

f-23V29V30V '32V33V38V44V45V46V47V48V49V50V51V

K'-

87V88V

acrylonitrile 'benzene '>'carbon tetrachloridechlorobenzene1 , 2-dichloroethane1,1, 1-trichloroethane1 , 1-dichloroethanel,l;2-trichlbroethane1 , 1 ,2, 2-tetrachloroethanechloroethanebis(chloromethyl) ether2-chloroethylvinyl etherchloroform1 , 1-dichloroethylene1 , 2-trans-dichloroethylene1 , 2-dichloroprop ane1 ,3-dichloropropyleneethylbenzenemethylene chloridemethyl chloridemethyl bromidebromoformdichlorobromomethanetrichlorofluoromethanedichlorodifluoro.methanechlorodibro'momethanetetrachloroethylenetoluenetrichloroethylenevinyl chloride

NDNDND

ND*

NDNDNDNDND

NDNDND

ND

ND

NDND

ND•*-.

ND

NPNPND

ND

ND

Np.

NP -wnNn...wn

90P dieldrin91P chlordane92P 4,4'-DDT93P 4, 4 '-DDE94P 4,4'-DDD95P alpha-endosulfan96P beta-endosulfan97P endosulfan sulfate98P endrin99P endrin aldehyde100P heptachlor101P heptachlor epoxide102P alpha-BHC

- 103P beta-BHC104P gamma-BHC105P delta-BHC106P PCB-1242107P PCB-1254108P PCB-1221109P PCB-1232HOP PCB-1248HIP PCB-1260112P PCB-1016113P toxaphene

ND

' ND

•**.!.ND

ND

ND

ND

ND

ND

**.2

ND

NnND

**'. 4

wnwnwnwnwnwnwnwnwn •wn

* = Less than 10 ug/1(pesticides less than 5 ug/fl)R 2 0 0 3 5 k

ND = Not detected..... • ** = Not confirmed by GCMS

(l)=Not Resolved

W€ST COAST TECHNICAL 5GRVICG INC. INDUSTRIAL CAftLiORY.

/LE ID C0010 Recieving Wa£er^XB ID 19006A5

/>ATE EXTRACTED 2/28/80-••-/ DATE INJECTED 3/22/80

(M\0v

••' / STD ID DFTPP9S7 SENS69 Phenol202/ CONC FACTOR 1000

Acid Compounds21 A 2,4,6-trichlorophenol22A p-chloro-m-cresol24A 2-chlorophenol31 A 2,4-dichlorophenol34A 2,4-dimethylphenol57A 2-nitrophenol58A 4-nitrophenol59A 2,4-dinitrophenol60A 4,6-dinitro-o-cresol64A pentachlorophenol65A • phenol

Base/Neutral Compounds

IB acenaphthene5B benzidine8B 1,2,4-trichlorobenzene9B hexachlorobenzene12B hexachloroethane18B bis (2-chloroethyl) ether20B 2-chloronapthalene25B 1 , 2-dichlorobenzene26B 1 ,3-dichlorobenzene27B 1,4-dichlorobenzene28B 3,3' -dichlorobenzidine '35B 2,4-dinitrotoluene36B 2,6-dinitrotoluene37B 1,2-diphenylhydrazine

(as azobenzene)39B fluoranthene

ug/1

ND -wnwn

NDwp

NPND

NPND

——— ND-ND

NDND

NDND

NDND

ND

NP

ND

ND .ND

ND •

ND

NDND

40B 4-chlorophenyl phenyl ether ND

SAMPLE ID CQ010 Receiving Water\ LAB-^tT" •' 19006B5' DATE EXTRACTED 2/28/80 "'"DATE INJECTED 3/18/80 <•;<;„;STD ID DFTPP983 BENZ241 BNSTD176CONC FACTOR 1000

Base/Neutral Compounds ui41B 4-bromophenyl phenyl ether42B bis(2-chloroisopropyl) ether43B bis (2-chloroethoxy ) methane52B hexachlorobutadiene53B hexachlorocyclopentadiene54B isophorone55B naphthalene56B nitrobenzene6lB N-nitrosodimethylamine62B N-nitrosodiphenylamine63B N-nitrosodi-n-propylamine66B bis (2-ethylhexyl) phthalate67B butyl benzyl phthalate68B di-n-butyl phthalate69B di-n-octyl phthalate70B diethyl phthalate71B dimethyl phthalate72B benzo(a) anthracene73B benzo(a)pyrene74B 3,4-benzofluoranthene75B benzo(k)fluoranthene76B chrysene77B acenaphthylene78B anthracene79B benzo(ghi)peryleneSOB fluorene81B phenanthrene H D O n A o r- ,

*"* «• e. U U O b82B dibenzo(a,h)anthracene83B indeno(l,2,3-cd)pyrene84B pyrene129B 2,3,7,8-tetrachlorodibenzo-

S/INDwnND

ND

ND

— ND-Nnwp

— NS-

NHIN* -ND*NP

*NDNDNPNPNDNDNPXDNP

NP

5~d(NPND

•n-dioxin

_^ WGST COAST T£GllxJlCAl SERVICE INd.' INDUSTRIAL CAT6GORY.

r . _\MPLE ID C0010 Receiving Water SAMPLE ID COOIO* - LAB ID___________19006V9 /7 /\ \ LAB ID. 19005

DATE INJECTED_____3/11/80 tv D I DATE EXTRACTED 2/2R/ROID DFTPP975 19005V12 \ \PJ DATE INJECTED yan/Rn

CONC. FACTOR STD IDCONC.' FACTOR_____TQ

Volatiles ug/1 Pesticides2V acrolein . NP 89P aldrin3V4V6V7V10V11V13V14V15V16V|17V19V23V29V30V32V33V38V44V45V46V47V48V49V50V51V185V86V87V

acrylonitrilebenzenecarbon tetrachloridechlorobenzene1 , 2-dichloroethane1,1, 1-trichloroethane1 , 1-dichloroethane1,1, 2-trichloroethane1,1,2, 2-tetrachloroethanechloroethanebis(chloromethyl) ether2-chloroethylvinyl etherchloroform1 , 1-dichloroethylene1 , 2-trans-dichloroethylene1 , 2-dichloropropane1 , 3-dichloropropyleneethylbenzenemethylene chloridemethyl chloridemethyl bromidebromoformdichlorobromomethanetrichlorofluoromethanedichlorodifluoromethanechlorodibromomethanetetrachloroethylenetoluenetrichloroethylene

NDNDNDND*

ND

NDND

ND

ND

NDND

ND

ND

NDND

ND

ND*

NDNPNDNDNDNDND

ND

ND

ND

90P91P92P

93P94P95P96P97P98P99P100P101P102P103P104P105P106P107P108P109PHOPHIP112P113P

dieldrinchlordane4,4'-DDT4, 4 '-DDE4,4'-DDDalpha-endosulfanbeta-endosulfanendosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxidealpha-BHCbeta-BHCgamma-BHCdelta-BHC 'PCB-1242PCB-1254PCB-1221PCB-1232PCB-1248PCB-1260PCB-1016toxaphene

ND_

-NILND_A/P

NDND

ND

ND

•NCu

ND

ND-

NDW5-

-N8-NDND

NP

NPND

NP

NDND

NPND

* = Less than 10 ug/1(pesticides less than 1 P? Q 3 5 g

ND = Not detected** = Not confirmed by GCMS

88V vinyl chloride___________wp

"7' WEST COAST TGCHNICAL SGRVICG INC INDUSTRIAL CAT GGORY.

ID____C0011 Receiving W teg v SAMPLE ID cnnil pA^A^rjngID__________19006B6 /f.A \ )LAB ID__________ignnKBE

DATE EXTRACTED_____2/28/80 \\sy/DATE EXTRACTED V?s/QQDATE INJECTED 3/22/80 ^-^ DATE INJECTED______-3/10/on "']'STD ID DFTPP987 SENS69 Phenol202 STD ID HFTPPOP^ PENZ24J BHSTD176CONC FACTOR_______1QQQ__________ CONC FACTOR_______innn__________

Acid Compounds ug/1 Base/Neutral Compounds ug/121A 2.4,6-trichlorophenol_____ wp 41B 4-bromophenyl phenyl ether22A24A31A34A57A58A59A60A64A65A

p-chloro-m-cresol2-chlorophenol2,4-dichlorophenol2,4-dimethylphenol2-nitrophenol4-nitrophenol2 , 4-dinitrophenol4 , 6-dinitro-o-cresolpentachlorophenolphenol

ND

NDND

ND

ND

ND

ND

ND

ND

ND

Base/Neutral Compounds

IB5B8B9B12B18B20B25B26B27B28B35B36B37B

39B40B

acenaphthenebenzidine1,2, 4-trichlorobenzenehexachlorobenzenehexachloroethanebis ( 2-chloroethyl ) ether2-chloronapthalene1 , 2-dichlorobenzene1 , 3-dichlorobenzene1 , 4-dichlorobenzene3,3' -dichlorobenzidine2 , 4-dinitrotoluene2 , 6-dinitrotoluene1 , 2-diphenylhydrazine(as azobenzene)fluoranthene4-chlorophenyl phenyl

wnwnwnwnwnwnND

... ———— MO.

NP

—————— ND-ND

————— -ND.

————— -SB-

\ . 'i>«' •'"•

ether wn

42B43B52B53B54B55B56B61 B62B63B66B67B68B69B70B71B72B73B74B75B76B77B78B79BSOB81B82B83B84B129B

bis(2-chloroisopropyl) etherbis (2-chloroethoxy ) methanehexachlorobutadienehexachlorocyclopentadieneisophoronenaphthalene 9nitrobenzeneN-nitrosodimethylamine

• N-nitrosodiphenylamineN-nitrosodi-n-propylaminebis (2-ethylhexyl) phthalatebutyl benzyl phthalatedi-n-butyl phthalatedi-n-octyl phthalatediethyl phthalatedimethyl phthalatebenzo(a) anthracenebenzo( a) pyrene3 , 4-benzofluoranthenebenzo ( k ) fluoranthenechryseneacenaphthyleneanthracenebenzo (ghi)perylenefluorenefhenanthrene ——— flR?nnqcdibenzo(a,h)anthricen<5U U ° windeno(l,2,3-cd)pyrenepyrene2,3,7, 8-tetrachlorodibenzo-

ND

ND

-NB-

ND

NnND

NnND|* *

xrn*

wnwn•Kin

ND

NDwnpJil

T\TTi

pJTi

ND

* ~HD>7 iWTl4kM.-

— NB-

p-dioxin

•' ''&'• fK"ir"' ?!£» WGS'i LUAST TECHNICAL SERVICE INC. INDUSTRIAL CAlcuORY.

/ 1/MPLE ID C0011 Receiving Wa£erj AB ID 19006V10|DATE INJECTED 3/n/so'sTD ID DFTPP975 19005V12

CONC. FACTOR

Volatiles2V acrolein3V acrylonitrile4V benzene6V carbon tetrachloride7V chlorobenzene10V 1,2-dichloroethane11V 1,1,1-trichloroetha-ne13V 1,1-dichloroethane14V 1,1,2-trichloroethane15V 1,1,2,2-tetrachloroethane|16V chloroethanePi 7V bis(chloromethyl) ether19V 2-chloroethylvinyl ether23V chloroform29V 1,1-dichloroethylene30V 1,2-trans-dichloroethylene32V 1 , 2-dichloropropane33V 1,3-dichloropropylene38V ethylbenzene44V methylene chloride45V methyl chloride46V methyl bromide47V bromoform48V dichlorobromomethane49V trichlorofluoromethane50V dichlorodifluoromethane51V chlorodibromomethaneP5V tetrachloroethylene86V toluene87V trichloroethylene

(fa ( / ;\ys

ND .*

ND

ND

NDNDND

NDNDNDNDNDNDNDNDND

ND

ND

ND*

NDNDNDNDND

. NDND

ND

.ND.

ND

SAMPLE ID C0011LAB ID 19006 Trace

' DATE EXTRACTED 2/28/8DATE INJECTED 3/20/8STD ID Trace #34CONC. FACTOR 10

f . '

Pesticides89P aldrin90P .dieldrin91P chlordane92P 4,4'-DDT93P 4,4'-DDE94P 4,4'-DDD95P alpha-endosulfan96P beta-endosulfan97P endosulfan sulfate98P endrin99P endrin aldehyde100P heptachlor101P heptachlor epoxide102P alpha-BHC103P beta-BHC104P gamma-BHC105P delta-BHC106P PCB-1242107P PCB-1254108P PCB-1221109P PCB-1232HOP PCB-1248HIP PCB-1260112P PCB-1016113P toxaphene

#35

o C-..-V-..0 (rt ,

ug/1ND

NDND

NDNDNDND

NDNDND

NDNDND

ND**1.2ND

ND

ND

ND

ND

NDND

ND

ND

ND

* = Less than 10 ug/1 flDOnn^o(pesticides less than 5ug/HUOa°

ND = Not detected** = Not confirmed by GCMS

88V vinyl' chloride___________ND