JMAK avrami model metallurgy

12
Nucleation and Growth JMAK Model Johnson – Mehl – Avrami - Kolmogorov Prof. Ing. Carlo Mapelli

Transcript of JMAK avrami model metallurgy

Page 1: JMAK avrami model metallurgy

Nucleation and Growth JMAK Model Johnson – Mehl – Avrami - Kolmogorov Prof. Ing. Carlo Mapelli

Page 2: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli

Hypothesis of the model

2

Y volume fraction of the transformed phase nucleation rate (number of nuclei per second) growth rate (m3/s)

t time (s)

Page 3: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli

Graphical representation

3

Page 4: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli

Graphical representation

4

Page 5: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli

Physical pmeaning of the parameters (meaning of n-value)

There is no clear physical interpretation of the Avrami constants k and n. Originally, n was held to have an integer value between 1 and 4 which reflected the nature of the transformation in question. In the derivation above, for example, the value of 4 can be said to have contributions from three dimensions of growth and one representing a constant nucleation rate. Alternative derivations exist where n has a different value. If the nuclei are preformed, and so all present from the beginning, the transformation is only due to the 3-dimensional growth of the nuclei and n has a value of 3. An interesting condition occurs when nucleation occurs on specific sites (such as grain boundaries or impurities) which rapidly saturate soon after the transformation begins. Initially, nucleation may be random and growth unhindered leading to high values for n (3,4). Once the nucleation sites are consumed the formation of new particles will cease. Furthermore, if the distribution of nucleation sites is non-random then the growth may be restricted to 1 or 2-dimensions. Site saturation may lead to n values of 1, 2 or 3 for surface, edge and point sites, respectively.

5

Page 6: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli

Physical pmeaning of the parameters (meaning of n-value) – morphological meaning

6

Page 7: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli

Nucleation and Growth Phenomena Isothermal transformation (TTT curve)

7

Page 8: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli

Martensite formation is not based on nucleation and growth mechanism

8

Page 9: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli

Continuous cooling curve (CCT diagram)

9

Page 10: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli

Derivation of the model

10

Page 11: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli

Derivation of the model

11

Page 12: JMAK avrami model metallurgy

Prof. Ing. Carlo Mapelli 12

Y volume fraction of the transformed phase nucleation rate (number of nuclei per second) growth rate (m3/s)

t time (s)