Isomerization and...Isomerization and Decomposition of Isoprene’s d-(Z)-Hydroxyperoxyl Radicals...
Transcript of Isomerization and...Isomerization and Decomposition of Isoprene’s d-(Z)-Hydroxyperoxyl Radicals...
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Isomerization and
Decomposition of Isoprene’s
d-(Z)-Hydroxyperoxyl Radicals
Gabriel da Silva
Melbourne Centre for Theoretical and Computational Chemistry
The University of Melbourne, Australia
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• Rivals methane emissions
• Completely removed in planetary boundary layer (where we live!)
• Produces many generations of products
• Important interplay with aerosols and CCN
• Interacts with NOx
Isoprene is perhaps the most important VOC governing the chemistry of our atmosphere
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Isoprene’s atmospheric chemistry is complex…
Paulot et al., Atmos. Chem. Phys. 2009.
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• Above forests, isoprene RO2 can live for a long time.
• Atmospheric chemical models still struggle to reproduce this chemistry.
• Lab studies of isoprene RO2 also disagree.
IsopreneIsoprene Peroxyl Radicals
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• Peroxyl radicals can scramble, isomerize, and decompose:
IsopreneRO2 Isomerization
Peeters, Vereecken, and Nguyen, Phys. Chem. Chem. Phys. 2009.
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This work reports on a newly discovered decomposition channel of the isoprene d-(Z)-hydroxyperoxyl radicals
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1 and 4 substituted ISOP-OH adducts can:
– Add O2 to form 1,4- and 4,1-RO2,
– Then isomerize to QOOH,
– THEN eliminate OH to make an isoprene enol epoxide (ISENEPOX):
IsopreneA New Mechanism…
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A New Mechanism…
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A New Mechanism…
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Isoprene4,1-(Z)-RO2 Mechanism
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IsopreneReaction Schematic
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IsopreneMaster Equation Simulations
Collisions
0 50 100 150 200 250 300
Yie
ld
0.0
0.2
0.4
0.6
0.8
1.0QOOH
E epoxide
Z epoxide
R + O2
RO2
0 50 100 150 200 250 300
Evib
(cm
-1)
0
2000
4000
6000
8000
10000
• EGME model developed in Multiwell
• 298 K and 1 atm N2
• DEd = 100±50 cm-1
• Used to simulate R + O2 on full surface
• Time (i.e., collision) dependant product yields
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IsopreneMaster Equation Simulations: Product Yields
Collisions
0 50 100 150 200 250 300
Yie
ld
0.0
0.2
0.4
0.6
0.8
1.0QOOH
E epoxide
Z epoxide
R + O2
RO2
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IsopreneMaster Equation Simulations: DEd
Collisions
0 100 200 300 400 500 600
Ep
ox
ide
Yie
ld
0.0
0.1
0.2
0.3
0.4100 cm
-1
50 cm-1
150 cm-1
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• Enols react rapidly with OH.
• Can tautomerize to aldehydes:
• Same mass as isoprene hydroxy carbonyls:
IsopreneIsEnEpox
So et al., Environ. Sci. Technol. 2014; J. Phys. Chem A 2015.
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• At short lifetimes, d-(Z)-ISOPO2 may give a pulse of chemically activated products.
• At longer lifetimes:
– Repeated “pulses” from O2 addition/loss cycles.
– Well skipping thermal decomposition possible.
IsopreneKinetic vs Thermodynamic RO2 Regimes
da Silva et al., Environ. Sci. Technol. 2010.
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IsopreneTHANK YOU!
FUNDING:Australian Research Council Discovery Project and Future Fellowship Schemes