Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp:...

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Ion implantation John Paul Adrian Glaubitz Contents Introduction Terminology Motivation Equipment Principal setup Ion source Mass separator Beam deflection Implantation process Distribution and dose Activation Issues Defects Channeling Conclusion & summary Ion implantation John Paul Adrian Glaubitz University of Oslo 26.05.2011 1 / 19

Transcript of Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp:...

Page 1: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Ion implantation

John Paul Adrian Glaubitz

University of Oslo

26.05.2011

1 / 19

Page 2: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

1 IntroductionTerminologyMotivation

2 EquipmentPrincipal setupIon sourceMass separatorBeam deflection

3 Implantation processDistribution and doseActivation

4 IssuesDefectsChanneling

5 Conclusion & summary

2 / 19

Page 3: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Ion implantation is a technique for direct deposition of dopants into a crystalwhere a doping gas (eg. BF3) is ionized, extracted and impacted into the targetcrystal.

3 / 19

Page 4: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Predeposition diffusion has a number of deficiencies. For example, it is verydifficult to accurately control the doping profile and region, doping by diffusionhas to be performed at high temperatures meaning that other, unintentionaldiffusion in the crystal occurs as well, the crystal can easily be contaminated withother gases in the furnace while perfoming diffusion and it can be verychallenging to create lightly doped regions which are important for MOSFETs forexample (channels).

Ion implantation tackles these problems. It allows to precisely measure andcontrol the doping concentration and profile, avoids contamination by filtering thedopand gas through mass separation, and can be performed at room temperaturethus avoiding unintentional diffusion.

4 / 19

Page 5: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Predeposition diffusion has a number of deficiencies. For example, it is verydifficult to accurately control the doping profile and region, doping by diffusionhas to be performed at high temperatures meaning that other, unintentionaldiffusion in the crystal occurs as well, the crystal can easily be contaminated withother gases in the furnace while perfoming diffusion and it can be verychallenging to create lightly doped regions which are important for MOSFETs forexample (channels).

Ion implantation tackles these problems. It allows to precisely measure andcontrol the doping concentration and profile, avoids contamination by filtering thedopand gas through mass separation, and can be performed at room temperaturethus avoiding unintentional diffusion.

4 / 19

Page 6: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Predeposition diffusion has a number of deficiencies. For example, it is verydifficult to accurately control the doping profile and region, doping by diffusionhas to be performed at high temperatures meaning that other, unintentionaldiffusion in the crystal occurs as well, the crystal can easily be contaminated withother gases in the furnace while perfoming diffusion and it can be verychallenging to create lightly doped regions which are important for MOSFETs forexample (channels).

Ion implantation tackles these problems. It allows to precisely measure andcontrol the doping concentration and profile, avoids contamination by filtering thedopand gas through mass separation, and can be performed at room temperaturethus avoiding unintentional diffusion.

4 / 19

Page 7: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Predeposition diffusion has a number of deficiencies. For example, it is verydifficult to accurately control the doping profile and region, doping by diffusionhas to be performed at high temperatures meaning that other, unintentionaldiffusion in the crystal occurs as well, the crystal can easily be contaminated withother gases in the furnace while perfoming diffusion and it can be verychallenging to create lightly doped regions which are important for MOSFETs forexample (channels).

Ion implantation tackles these problems. It allows to precisely measure andcontrol the doping concentration and profile, avoids contamination by filtering thedopand gas through mass separation, and can be performed at room temperaturethus avoiding unintentional diffusion.

4 / 19

Page 8: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Predeposition diffusion has a number of deficiencies. For example, it is verydifficult to accurately control the doping profile and region, doping by diffusionhas to be performed at high temperatures meaning that other, unintentionaldiffusion in the crystal occurs as well, the crystal can easily be contaminated withother gases in the furnace while perfoming diffusion and it can be verychallenging to create lightly doped regions which are important for MOSFETs forexample (channels).

Ion implantation tackles these problems. It allows to precisely measure andcontrol the doping concentration and profile, avoids contamination by filtering thedopand gas through mass separation, and can be performed at room temperaturethus avoiding unintentional diffusion.

4 / 19

Page 9: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Predeposition diffusion has a number of deficiencies. For example, it is verydifficult to accurately control the doping profile and region, doping by diffusionhas to be performed at high temperatures meaning that other, unintentionaldiffusion in the crystal occurs as well, the crystal can easily be contaminated withother gases in the furnace while perfoming diffusion and it can be verychallenging to create lightly doped regions which are important for MOSFETs forexample (channels).

Ion implantation tackles these problems. It allows to precisely measure andcontrol the doping concentration and profile, avoids contamination by filtering thedopand gas through mass separation, and can be performed at room temperaturethus avoiding unintentional diffusion.

4 / 19

Page 10: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Predeposition diffusion has a number of deficiencies. For example, it is verydifficult to accurately control the doping profile and region, doping by diffusionhas to be performed at high temperatures meaning that other, unintentionaldiffusion in the crystal occurs as well, the crystal can easily be contaminated withother gases in the furnace while perfoming diffusion and it can be verychallenging to create lightly doped regions which are important for MOSFETs forexample (channels).

Ion implantation tackles these problems. It allows to precisely measure andcontrol the doping concentration and profile, avoids contamination by filtering thedopand gas through mass separation, and can be performed at room temperaturethus avoiding unintentional diffusion.

4 / 19

Page 11: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Predeposition diffusion has a number of deficiencies. For example, it is verydifficult to accurately control the doping profile and region, doping by diffusionhas to be performed at high temperatures meaning that other, unintentionaldiffusion in the crystal occurs as well, the crystal can easily be contaminated withother gases in the furnace while perfoming diffusion and it can be verychallenging to create lightly doped regions which are important for MOSFETs forexample (channels).

Ion implantation tackles these problems. It allows to precisely measure andcontrol the doping concentration and profile, avoids contamination by filtering thedopand gas through mass separation, and can be performed at room temperaturethus avoiding unintentional diffusion.

4 / 19

Page 12: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Predeposition diffusion has a number of deficiencies. For example, it is verydifficult to accurately control the doping profile and region, doping by diffusionhas to be performed at high temperatures meaning that other, unintentionaldiffusion in the crystal occurs as well, the crystal can easily be contaminated withother gases in the furnace while perfoming diffusion and it can be verychallenging to create lightly doped regions which are important for MOSFETs forexample (channels).

Ion implantation tackles these problems. It allows to precisely measure andcontrol the doping concentration and profile, avoids contamination by filtering thedopand gas through mass separation, and can be performed at room temperaturethus avoiding unintentional diffusion.

4 / 19

Page 13: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Source: Streetman, Ben G.; Banerjee, Sanjay - Solid State Electronic Devices

5 / 19

Page 14: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Source: http://www.hull.ac.uk/chemistry/masspec3/principles%20of%20ms.html

6 / 19

Page 15: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Campbell, Stephen A - The Science and Engineering of Microelectronic Fabrication

Mv2

r= qvB and v =

√2EM

=√

2qVextM

thus

r = 1B

√2MVext

q

7 / 19

Page 16: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Campbell, Stephen A - The Science and Engineering of Microelectronic Fabrication

Deflection determines position of ion beam on target surface. Allows very preciseand controlled scanning over the surface which guarantees highly customizable

and reproducible doping patterns eligible for mass production.

8 / 19

Page 17: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Doping profile is approximately given by a Gaussian

N(x) = Φ√2π∆Rp

exp− 1

2(x−Rp∆Rp

)

• Rp: projected range

• ∆Rp: straggle

• Φ: dose (in cm−2

Both Rp and ∆Rp increase with increasing beam energy. The dose is obtained byintegrating the ion current over time.

9 / 19

Page 18: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Doping profile is approximately given by a Gaussian

N(x) = Φ√2π∆Rp

exp− 1

2(x−Rp∆Rp

)

• Rp: projected range

• ∆Rp: straggle

• Φ: dose (in cm−2

Both Rp and ∆Rp increase with increasing beam energy. The dose is obtained byintegrating the ion current over time.

9 / 19

Page 19: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Doping profile is approximately given by a Gaussian

N(x) = Φ√2π∆Rp

exp− 1

2(x−Rp∆Rp

)

• Rp: projected range

• ∆Rp: straggle

• Φ: dose (in cm−2

Both Rp and ∆Rp increase with increasing beam energy. The dose is obtained byintegrating the ion current over time.

9 / 19

Page 20: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Typical Gaussian with the characteristic parameters RP and ∆RP

Source: Streetman, Ben G.; Banerjee, Sanjay - Solid State Electronic Devices

10 / 19

Page 21: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Custom doping profiles are obtained through subsequent implantations

Source: Streetman, Ben G.; Banerjee, Sanjay - Solid State Electronic Devices

11 / 19

Page 22: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Right after implantation, only about 5 % of the dopants have been bonded to thecrystal and are electrically active. It is therefore necessary to activate theimplanted dopants through heat treatment. Due to the activation, diffusion willoccur and the doping profile changes accordingly.

N(x) = Φ√2π

√(∆R2

p+2Dt)exp− 1

2(

x−Rp

∆R2p+2Dt

)

• D: diffusivity

• t: time

Thus, to avoid strong unintentional diffusion, activation time must be kept asshort as possible. One may use rapid thermal annealing (RTA) for activation.

12 / 19

Page 23: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Right after implantation, only about 5 % of the dopants have been bonded to thecrystal and are electrically active. It is therefore necessary to activate theimplanted dopants through heat treatment. Due to the activation, diffusion willoccur and the doping profile changes accordingly.

N(x) = Φ√2π

√(∆R2

p+2Dt)exp− 1

2(

x−Rp

∆R2p+2Dt

)

• D: diffusivity

• t: time

Thus, to avoid strong unintentional diffusion, activation time must be kept asshort as possible. One may use rapid thermal annealing (RTA) for activation.

12 / 19

Page 24: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Right after implantation, only about 5 % of the dopants have been bonded to thecrystal and are electrically active. It is therefore necessary to activate theimplanted dopants through heat treatment. Due to the activation, diffusion willoccur and the doping profile changes accordingly.

N(x) = Φ√2π

√(∆R2

p+2Dt)exp− 1

2(

x−Rp

∆R2p+2Dt

)

• D: diffusivity

• t: time

Thus, to avoid strong unintentional diffusion, activation time must be kept asshort as possible. One may use rapid thermal annealing (RTA) for activation.

12 / 19

Page 25: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Right after implantation, only about 5 % of the dopants have been bonded to thecrystal and are electrically active. It is therefore necessary to activate theimplanted dopants through heat treatment. Due to the activation, diffusion willoccur and the doping profile changes accordingly.

N(x) = Φ√2π

√(∆R2

p+2Dt)exp− 1

2(

x−Rp

∆R2p+2Dt

)

• D: diffusivity

• t: time

Thus, to avoid strong unintentional diffusion, activation time must be kept asshort as possible. One may use rapid thermal annealing (RTA) for activation.

12 / 19

Page 26: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Right after implantation, only about 5 % of the dopants have been bonded to thecrystal and are electrically active. It is therefore necessary to activate theimplanted dopants through heat treatment. Due to the activation, diffusion willoccur and the doping profile changes accordingly.

N(x) = Φ√2π

√(∆R2

p+2Dt)exp− 1

2(

x−Rp

∆R2p+2Dt

)

• D: diffusivity

• t: time

Thus, to avoid strong unintentional diffusion, activation time must be kept asshort as possible. One may use rapid thermal annealing (RTA) for activation.

12 / 19

Page 27: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Source: L. Vines, E. V. Monakhov, J. Jensen, A. Yu. Kuznetsov, and B. G. Svensson. Effect of spatial defect

distribution on the electrical behavior of prominent vacancy point defects in swift-ion implanted Si. Phys.

Rev. B, 79(7):075206, February 2009

13 / 19

Page 28: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Topography scan (A) of the Si sample implanted with 3 MeV Au2+ ions with dose 5× 109cm−2 from

compared with a reference sample (B); there are no visible changes in the topography of the scan in (A)

after ion bombardment. The electronic changes are only visible in the SCM images

Source: [2] Lasse Vines, Edouard Monakhov, Bengt G. Svensson, Jens Jensen, Anders Hallen, and Andrej Yu.

Kuznetsov. Visualization of MeV ion impacts in Si using scanning capacitance microscopy. Phys. Rev. B,

73(8):085312, February 2006.

14 / 19

Page 29: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

SCM images of Si samples implanted with 3 MeV Au2+ ions with dose 5× 109cm−2 (A), 8× 108cm−2

(B) and 2× 108cm−2 (C), as well as an unimplanted sample (D). These images show dose-dependent

changes in the electronic structure of the Si bulk which are not visible in topography scans using AFM.

Source: [2] Lasse Vines, Edouard Monakhov, Bengt G. Svensson, Jens Jensen, Anders Hallen, and Andrej Yu.

Kuznetsov. Visualization of MeV ion impacts in Si using scanning capacitance microscopy. Phys. Rev. B,

73(8):085312, February 2006.

15 / 19

Page 30: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

If ions move parallel to a major crystal direction, they can travel very longdistance without any considerable energy loss due to scattering. This is calledchanneling and will disturb the doping profile.

Campbell, Stephen A - The Science and Engineering of Microelectronic Fabrication

Critical angle: Ψ = 9.73◦√

ZiZtEincd

16 / 19

Page 31: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

If ions move parallel to a major crystal direction, they can travel very longdistance without any considerable energy loss due to scattering. This is calledchanneling and will disturb the doping profile.

Campbell, Stephen A - The Science and Engineering of Microelectronic Fabrication

Critical angle: Ψ = 9.73◦√

ZiZtEincd

16 / 19

Page 32: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

If ions move parallel to a major crystal direction, they can travel very longdistance without any considerable energy loss due to scattering. This is calledchanneling and will disturb the doping profile.

Campbell, Stephen A - The Science and Engineering of Microelectronic Fabrication

Critical angle: Ψ = 9.73◦√

ZiZtEincd

16 / 19

Page 33: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Ion implantation is a technique for depositing dopants into a target crystal usingan ion gun. The dopant is brought into gaseous form, ionized, mass-separatedand accelerated onto the target. Unlike predeposition diffusion, it will work atroom temperature (no unintended diffusion) and the doping profile can be veryaccurately measured and controlled, thus yielding highly reproducibleresults. Most problems from ion implantation result from crystal damage whichwill additionally alter the electronic configuration by introducing electrically activedefects. These defects have to be taken into consideration when determining theparameters for a profile. The defects introduced by ion implantation (prevention,effects, way of “healing”) are subject to research at many groups.

17 / 19

Page 34: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Ion implantation is a technique for depositing dopants into a target crystal usingan ion gun. The dopant is brought into gaseous form, ionized, mass-separatedand accelerated onto the target. Unlike predeposition diffusion, it will work atroom temperature (no unintended diffusion) and the doping profile can be veryaccurately measured and controlled, thus yielding highly reproducibleresults. Most problems from ion implantation result from crystal damage whichwill additionally alter the electronic configuration by introducing electrically activedefects. These defects have to be taken into consideration when determining theparameters for a profile. The defects introduced by ion implantation (prevention,effects, way of “healing”) are subject to research at many groups.

17 / 19

Page 35: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Ion implantation is a technique for depositing dopants into a target crystal usingan ion gun. The dopant is brought into gaseous form, ionized, mass-separatedand accelerated onto the target. Unlike predeposition diffusion, it will work atroom temperature (no unintended diffusion) and the doping profile can be veryaccurately measured and controlled, thus yielding highly reproducibleresults. Most problems from ion implantation result from crystal damage whichwill additionally alter the electronic configuration by introducing electrically activedefects. These defects have to be taken into consideration when determining theparameters for a profile. The defects introduced by ion implantation (prevention,effects, way of “healing”) are subject to research at many groups.

17 / 19

Page 36: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Ion implantation is a technique for depositing dopants into a target crystal usingan ion gun. The dopant is brought into gaseous form, ionized, mass-separatedand accelerated onto the target. Unlike predeposition diffusion, it will work atroom temperature (no unintended diffusion) and the doping profile can be veryaccurately measured and controlled, thus yielding highly reproducibleresults. Most problems from ion implantation result from crystal damage whichwill additionally alter the electronic configuration by introducing electrically activedefects. These defects have to be taken into consideration when determining theparameters for a profile. The defects introduced by ion implantation (prevention,effects, way of “healing”) are subject to research at many groups.

17 / 19

Page 37: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

Ion implantation is a technique for depositing dopants into a target crystal usingan ion gun. The dopant is brought into gaseous form, ionized, mass-separatedand accelerated onto the target. Unlike predeposition diffusion, it will work atroom temperature (no unintended diffusion) and the doping profile can be veryaccurately measured and controlled, thus yielding highly reproducibleresults. Most problems from ion implantation result from crystal damage whichwill additionally alter the electronic configuration by introducing electrically activedefects. These defects have to be taken into consideration when determining theparameters for a profile. The defects introduced by ion implantation (prevention,effects, way of “healing”) are subject to research at many groups.

17 / 19

Page 38: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

• Campbell, Stephen A - The Science and Engineering of MicroelectronicFabrication

• Streetman, Ben G.; Banerjee, Sanjay - Solid State Electronic Devices

• Halbleitertechnologie von A bis Z - http://www.halbleiter.org

• L. Vines, E. V. Monakhov, J. Jensen, A. Yu. Kuznetsov, and B. G.Svensson. Effect of spatial defect distribution on the electrical behavior ofprominent vacancy point defects in swift-ion implanted Si.

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Page 39: Ion implantationusers.physik.fu-berlin.de/~glaubitz/fys9310_talk.pdfRp) Rp: projected range Rp: straggle 2: dose (in cm Both Rpand pincrease with increasing beam energy. The dose is

Ionimplantation

John PaulAdrian

Glaubitz

Contents

Introduction

Terminology

Motivation

Equipment

Principal setup

Ion source

Mass separator

Beam deflection

Implantationprocess

Distribution anddose

Activation

Issues

Defects

Channeling

Conclusion &summary

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