Ion Exchange Resins Product List
Transcript of Ion Exchange Resins Product List
Ion Exchange Resins Product List
Leading manufacturer of
UPS lon Exchange Resins
www.samyangtrilite.com
3Ion Exchange Resins Product List
No.1 Total Solution Provider
Samyang presents the full line-up of TRILITE Ion Exchange Resins from water treatment up to specialty
applications. Samyang develops Tailored resins optimized for customer needs and provides differentiated
technical services such as on-site visit for troubleshooting, technical seminars, process diagnosis, and design
consulting, etc. Also, Samyang IER Tech-center offers various analysis services for IERs and develops advanced
application technologies.
Locations (HQ, Plant, Tech-center of TRILITE)
Seoul (Head Office)
■ Technical sales force in 3 fields
- Demineralization/Ultrapure water /
Condensate polishing/Catalyst
- Food/Amino acids/Pharmaceuticals
- Wastewater/Chelating resins/
Purification
■ One Stop Service
- Analysis of IER
- Equipment diagnosis and design
support
- Technical seminars and trouble
shooting guides
Daejeon (Tech-center)
■ Analysis of IER
■ Recipe improvement of IER
■ New product development
- Tailored/Specialty resins
■ Application process development
- Pilot test
- Engineering data gathering
- Process proposal
Gunsan (UPS Resin Plant)
■ Samyang Fine Technology
(Joint venture with Mitsubishi
Chemicals)
■ Asia's largest manufacturing
capacity for UPS resins
■ Annual production capacity
- Cation 13,000㎘, Anion 7,000㎘
■ Product lines
- Uniform particle sized resins
- Chromatography resins
- Ultrapure water grade resins
(LCD, OLED)
Ulsan (UPW/Tailored/ Specialty Resin Plant)
■ Technology licensed by Mitsubishi
Chemicals & Self-development
■ Specialized production
of Tailored resins
■ Annual production capacity
- Cation 4,000㎘, Anion 3,000㎘
■ Product line
- Ultrapure water grade resins
(Semiconductor)
- Tailored resins : food, catalyst,
pharmaceuticals
- Specialty resins: chelating resins,
synthetic adsorbents, refining of
chemicals
Samyang Corporation Ion Exchange Resin Team
TEL : +82 2 740 7732~7
E-mail : [email protected]
http://www.samyangtrilite.com
Samyang Corporation is the history of Ion Exchange Resins in Korea
In 1976, Samyang Corporation successfully
initiated localized production of IER in South
Korea by technical cooperation with Mitsubishi
Chemical Corporation, Japan. In 2011, with
successful development of UPW (Ultrapure
water) grade resins, we are contributing to
enhancing national competitiveness in the
semiconductor and the display industries.
In 2016, Asia's largest UPS (Uniform Particle
Sized) specialized IER (Ion exchange resin)
plant; Samyang Fine Technology Corporation
was founded. TRILITE is being supplied to the
global market and is receiving rave reviews
from the users.
4 5Ion Exchange Resins Product List Ion Exchange Resins Product List
Uniformity of IER enlarges its Performance
TRILITE UPS resins are renowned in the industry for the consistent uniformity coefficient, which is directly
related to high performance. TRILITE UPS resins are manufactured under the strict quality control to ensure
optimized size of the resins, enabling extremely even reactions. UPS resins give an extremely even exhaustion
front of resins in the vessel, hence the operating capacity is enhanced. Also, it has outstanding mechanical and
chemical stability, leading to remarkably low crush rate even after long-term use.
Samyang TRILITE represents Next Generation Ion Exchange Resin
TRILITE UPS resin has adopted state-of-the-art Droplet generating technology for polymerization, differentiated
from the prevailing mechanical sieving of polymers and conventional polymerization technology. Premium grade
TRILITE Ion Exchange Resins are manufactured from the newest UPS IER plant in the world. TRILITE satisfies high
quality standards; Uniformity coefficient of TRILITE is under 1.1 with high mechanical and chemical stability.
Higher Operating Capacity, Reduction of Rinse Volume,
Longer Life Time of IER
Improved Kinetics, Fast Reaction Speed Excellent Physical & Chemical Strength+
(Raw Material Adjustment)
(Polymerization - Droplet Generator)
(Post-treatment – Functional group)
STM(Styrene Monomer)
DVB(Divinyl Benzene)
CH = CH₂ CH = CH₂
CH = CH₂
+
UPS(Uniform Particle Sized)Technology
(Raw Material Adjustment)
(Polymerization - Agitation)
(Post-treatment – Functional group)
STM(Styrene Monomer)
DVB(Divinyl Benzene)
CH = CH₂ CH = CH₂
CH = CH₂
+
Conventional Technology
Gaussian resin gives diffused
exhaustion front
UPS resin gives an extremely
even exhaustion front
Gaussian Resin
Next Generation IER, High Performance Low CostCutting-edge Technology Droplet Generator
(Packing)
60
50
40
30
20
10
0
UniformityCoefficient
1.1↓
200 400 600 800 1000
(Packing)
60
50
40
30
20
10
0200 400 600 800 1000
(%) (%)
(㎛) (㎛)
Lower Running Cost and Capital Expenditure
UPS Resin
UniformityCoefficient
1.6↓
Service Volume (Bed Volume)
UPS Resin (Mixed)
Gaussian Resin (Mixed)
30
25
20
15
10
5
0
0 10 20 30 40 50 60 70 80 90 100 110 120
Co
nd
uc
tivi
ty
(㎲/㎝
)
25 50 75 100 125 150
1.5
1.3
1.1
0.9
0.7
Op
era
tin
g C
ap
ac
ity
(eq
/ℓ-R
esi
n)
Specific Flow Rate (SV)
UPS Resin (SAC)
Gaussian Resin (SAC)
6 Ion Exchange Resins Product List
Classification of Ion Exchange Resin
SpecialtyAnion InertCation
SAC WAC SBA WBAChelating
resinsSynthetic adsorbents
For packed bed system,
mixed bed polisher
Functional Group
Mixing,
DryCatalyst
Nucleic Acid,
LysineUPW
Tailored Resin
UPS
(0.5 ~ 0.6mm)
Gaussian L-type(L)
(0.425 ~ 1.2mm)
Chromatography
(0.2 ~ 0.3mm)
Particle Distribution, Size
Gaussian
(0.3 ~ 1.2mm)
High
Crosslinkage
Crosslinkage
Low
Crosslinkage
* Crosslinkage : Divinylbenzeze versus total monomers in weight/weight (%)
Strongly acidic cation
Stronglybasic anion
Weakly acidic cation
Weaklybasic anion
Porous type
(Macropore)
Porosity
Gel type
(Micropore)
Micropore <100Å
Gel
Macropore 10Å<, <1000Å
Porous
Water treatment· Softening / Demineralization
· Condensate polishing
· Nuclear power
Ultrapure water
Catalyst
Chromatography separation
· Fructose / Glucose separation
· Amino acid separation / purification
· Acid purification
Food· Starch sugar refining
· Sugar refining
· Nucleic acid, Lysine separation / purification
Chelating resins· Secondary brine purification
· Wastewater treatment
Synthetic adsorbents
Ready to use mixed resins
Inert resins
Layered bed anion resins
EO/EG cycle water treatment
Contents
8 9Ion Exchange Resins Product List Ion Exchange Resins Product List
Various types of water treatment systems (softening, demineralization) are adaptable according to the types
of IERs, service/regeneration direction of solution and combination of IER towers. An appropriate system is
recommended under the conditions of raw water and required water quality.
TRILITE IER consists of the most efficient line-ups for various types of softening and demineralization of water.
It results in cost-effective, high performance of water treatment with remarkably high operating capacity and
high mechanical and chemical stability.
The Performance line-up realizes the high quality of performance, being manufactured from the
specialized UPS resin plant with state-of-the-art technology, Samyang Fine Technology Corporation.
The Basic line-up realizes the high-quality performance, being manufactured from the Samyang
Corporation Ulsan Plant.
The economy line-up proves the cost-effectiveness and the high quality, being manufactured
under the strict quality assurance system.
Water Treatment
Particle Size, Distribution, Uniformity Coefficient
Gaussian - Particle Size : 0.3 ~ 1.2mm
- Uniformity Coefficient : 1.6 ↓
Gaussian L-type(L) - Particle Size : 0.425 ~ 1.2mm
- Uniformity Coefficient : 1.4 ↓
UPS - Particle Size : 0.5 ~ 0.6mm
- Uniformity Coefficient : 1.1 ↓
Classification by regeneration system
Co-current regeneration
system
Counter-current regeneration system
Water blocking system
Packed bed
Upflow system Downflow system
Gaussian Gaussian or L-type UPS
Service Regeneration
IER
FreeboardMiddle Distributor
IER
Freeboard
IER
FreeboardIER
Freeboard
Classification by IER layer
Single
bed
Layered
bed
Mixed
bed
SAC WAC SBA WBA
SAC
WAC
SBA
WBA
SAC
SBA
TRILITE Water Treatment IER Line-up
UPS
Performance
Product Line
UPS(Samyang
Fine Technology)
1.1 ↓
Basic
Product Line
Gaussian(Samyang
Ulsan Plant)
1.3~1.6 ↓
Gaussian(OEM)
1.3~1.6 ↓
Economy
Product Line
UPS(OEM)
1.1~1.2 ↓
Type Weakly acidic cation resins (WAC) Weakly basic anion resins (WBA)
Gaussian, UPS Porous
WCA10L 4.2↑ 0.425~1.2
WBA
AW90 1.6↑ 0.50~0.60
UPSPorous
AW80 1.6↑ 0.40~0.60
GaussianPorous
AW30L 1.5↑ 0.425~1.2
Functionalgroup
(Polyacrylate+DVB) + Carboxylate (Polystyrene+DVB) + Tertiary Amine
Economy
Performance
Basic
Type
Strongly acidic cation resins (SAC) Strongly basic anion resins (SBA)
Gradename
TEC(eq/ℓ)
Particledistribution(㎜)
TypeGradename
TEC(eq/ℓ)
Particledistribution(㎜)
UPS Gel
MC-08 2.0↑ 0.55~0.65
Type1
MA-12 1.3↑ 0.53~0.63
MC-08H 1.8↑ 0.57~0.67 MA-12OH 1.0↑ 0.57~0.67
MC-10 2.2↑ 0.60~0.70 MA-10 1.35↑ 0.50~0.60
MC-10H 2.0↑ 0.61~0.71 MA-10OH 1.1↑ 0.54~0.64
MC-14 2.5↑0.60~0.70
MA-15 1.4↑ 0.55~0.65
MC-14H 2.4↑ MA-15OH 1.2↑ 0.58~0.68
Type2 MA-20 1.3↑ 0.53~0.63
Gaussian Gel
SCR-B 2.0↑
(General type)0.3~1.2(L-type)
0.425~1.2
Type1SAR10(MB) 1.3↑
(General type)0.3~1.2(L-type)
0.425~1.2
SAR12 1.3↑
Type2 SAR20(MB) 1.3↑
UPS Gel UKC-08 2.0↑ 0.55~0.65 Type1 UKA-12 1.3↑ 0.55~0.65
UKC-10 2.2↑ 0.60~0.70
UKC-12 2.3↑ 0.60~0.70
Gaussian Gel
KC-07 1.9↑
(General type)0.3~1.2(L-type)
0.425~1.2
Type1KA-10(MB) 1.3↑
(General type)0.3~1.2(L-type)
0.425~1.2
KH-70 1.9↑ KA-12 1.3↑
KC-08 2.0↑ Type2 KA-20(MB) 1.3↑
KH-80 2.0↑
Functionalgroup
(Polystyrene+DVB) + Sulfonate(Polystyrene+DVB) +
Type1 : TMA, trimethylamineType2 : DMEA, dimethylethanolamine
Economy
Economy
Performance
Performance
Basic
Basic
※ Uniformity Coefficient : An unit measuring uniformity of IERs. A coefficient closer to 1.0, the particle size more uniform.
10 11Ion Exchange Resins Product List Ion Exchange Resins Product List
Demineralization system
Demineralization system LINE SAC SBA WAC WBA
2B2T (2Bed 2Tower) Cation Exchanger+ Anion Exchanger
2B3TCation Exchanger+ Degasifier+ Anion Exchanger
PerformanceMC-08MC-10
MA-12MA-20
Basic SCR-BSAR10SAR20
EconomyUKC-08UKC-10KC-08
UKA-12KA-12KA-20
Working MB (Mixed Bed)
Performance MC-08 MA-20P
Basic SCR-B SAR20MB
2B2T or 2B3T +MBP(Mixed Bed Polisher)
Performance MC-08MC-10
MA-10P
Basic SCR-B SAR10MB
3B3T + MBP
PerformanceMC-08MC-10
KA18LB AW90
Basic SCR-B KA18LB AW80
EconomyUKC-08UKC-10
KA18LB AW30L
4B3T + MBP
PerformanceMC-08MC-10
KA18LB WCA10L AW90
Basic SCR-B KA18LB WCA10L AW80
EconomyUKC-08
UKC-10KA18LB WCA10L AW30L
4B3T + MBP + CPP(Condensate Polishing)
Performance MC-10H
MC-14H
MA-10OH
MA-15OH
※ D : Degasifier ※ Anion grade name + (P), (MB) means the anti-clumping treatment. Anion resin used for MB or MBP requires anti-clumping
treatment that helps separation of cation and anion.
SAC SBA
SAC
SBA
SAC SBASAC
SBA
SAC SBAD※
SAC SBASAC
SBAD
SAC
WAC
SBA
WBA
SAC
SBAD
SACSBA
WBA
SAC
SBAD
SAC
WAC
SBA
WBA
SAC
SBA
SAC
SBAD Conden-
ser
Softening
NSF Test method
50 ㎖ of ion exchange resin is put into 100 ㎖ of water at 70℃ for 2 hours, and APHA(unit of chromaticity) is
measured with a visible spectrophotometer.
IER Grade Spec. Day 1 Day 2 Day 3 Day 4 Day 7
KH-80 Food < 25 12 13 13 13 14
SCR-B Tech - 145 149 153 160 183
SCR-BL Tech - 53 55 191 257 347
Food grade softening
When food grade softening is required, it is needed to select a suitable food grade ion exchange resin. Examples
are as follows.
Sodium hypochlorite(NaClO), Free chlorine(Cl2), Ozone(03)
When softeners are used with
oxidizing agents such as sodium
hypochlorite or free chlorine, it
is recommended to use highly
crossl inked strongly acidic
cation ion exchange resin with
high resistance to oxidation.
IER SelectionClO2
Concentration
Cl2 or O3
Concentration
MC-08
0.1ppm↓ 0.2ppm↓SCR-B
UKC-08, KC-07, KC-08
MC-100.15ppm↓ 0.3ppm↓
UKC-10
UKC-12 0.2ppm↓ 0.4ppm↓
Economy
Economy
Economy
Performance
Performance
Basic
Softening system Line SAC SBA WAC WBA
Softening(Industrial grade)
MC-08
MC-10
SCR-B
UKC-08
UKC-10, UKC-12
KC-07, KC-08
Softening
(Food grade)
KH-70
KH-80
Performance
Economy
Economy
BasicSAC
SAC
NSF certifiedTRILITE KH-80
KH-80 SCR-B SCR-BL
12 13Ion Exchange Resins Product List Ion Exchange Resins Product List
Typical power plant steam turbine loop and IER selection
Ion exchange resins for thermal power plant are classified by applications: Make-up system, condensate
polishing, etc. Various combinations of demineralization are adaptable for Make-up system for the power plant.
For condensate polishing plant (CPP), premium grade IERs are required with high operating capacity, high
operating temperature, and mechanical and chemical stability.
TRILITE IERs own various supply references to domestic and foreign thermal power plants hence contributing
to the competitive power supply for customers, with stable quality control and on-time delivery of resins.
Ion exchange resins for nuclear power plant are classified by applications: Make-up system, condensate
polishing and primary circuit for the nuclear power plant. For the primary circuit in the nuclear power plant,
IERs are exposed to radiation. Use of high crosslinkage IERs with low impurities, high mechanical and chemical
stability is highly recommended.
TRILITE IERs own various supply references to domestic and foreign nuclear power plants hence contributing
to the competitive power supply for customers, with stable quality control and on-time delivery of resins.
Pressurized water reactor type nuclear power plant steam turbine loop and IER selection
Power Plants - Thermal Power Plants - Nuclear
Classification
Nuclear grade resins for primary circuit
Strongly acidic cation resins (SAC) Strongly basic anion resins (SBA)
TypeGradename
TEC (eq/ℓ)Particle
distribution (㎜)Type
Gradename
TEC (eq/ℓ)Particle
distribution (㎜)
UPS
Gel MCN116K 2.4↑ 0.60~0.70 Gel type1 MAN210K 1.2↑ 0.58~0.65
MMN316K / Mixed Resin ratio = 1 : 1 as same equivalent (MCN116K : MAN210K)
Classification
Condensate polishing resins
Strongly acidic cation resins (SAC) Strongly basic anion resins (SBA)
TypeGradename
TEC (eq/ℓ)Particle
distribution (㎜)Type
Gradename
TEC (eq/ℓ)Particle
distribution (㎜)
GaussianPorous CMP28L 2.05↑
0.425~1.2Poroustype1
AMP18L 1.3↑0.425~1.2
CMP28LH 1.8↑ AMP18LOH 1.1↑
UPS Gel
MC-10 2.2↑ 0.60~0.70
Geltype1
MA-10 1.35↑ 0.50~0.60
MC-10H 2.0↑ 0.61~0.71 MA-10OH 1.1↑ 0.54~0.64
MC-14 2.5↑0.60~0.70
MA-15 1.4↑ 0.55~0.65
MC-14H 2.4↑ MA-15OH 1.2↑ 0.58~0.68
Storagetank
Condensate polisher
Conden-sate
storage
SAC(H form)
SAC
SBA
Containment structure
Condenser
LP Heater
DeaeratorHP
Heater
GeneratorLPTurbine
HPTurbine
Raw water
Make-up demineralization system
SAC
WAC
SBA
WBA
SAC
SBA
Conden-sate
storageSAC(Li form)
SBA(OH form)
Degasifier
Steam generator
Nuclear reactor
Primary circuit
Secondary circuit
Nuclear Grade
Containmentstructure
Conden-sate
storage
SAC
SBA
Condensate polisher
Boiler
Reheater2nd
Superheater
1st Superheater
Evaporator Tube
Condenser
LP HeaterDeaeratorHP Heater
GeneratorLPTurbine
IPTurbine
HPTurbine
Raw water
Make-up demineralization system
SAC
WAC
SBA
WBA
SAC
SBADegasifier
TRILITE condensate polishing resins enable stable operating of power plants with the superior hydralitic
properties and outstanding mechanical and chemical stability. TRILITE high crosslinkage nulear grade resins ensure optimal oulet water qulity with high ion exchange capacity
and low TOC leakage, also enable stable operating of power plants with the superior H+/OH- conversion rate
and low level of heavy metal ion impurities.
14 15Ion Exchange Resins Product List Ion Exchange Resins Product List
Performance
UPS Strongly Acidic Cation(SAC) Resins
Grade MC-04 MC-04H MC-08 MC-08H MC-10 MC-10H MC-14 MC-14H
Matrix Polystyrene + DVB (Gel type)
Functional group -SO₃-(Sulfonate)
Ionic form Na+ H+ Na+ H+ Na+ H+ Na+ H+
Specific gravity 1.16 1.13 1.28 1.20 1.32 1.22 1.36 1.32
Shipping weight (g/ℓ) 790 750 845 800 850 805 865 815
Moisture retention (%) 57~67 65~70 43~49 50~56 38~44 45~51 31~37 37~43
Total capacity (eq/ℓ) 1.3↑ 1.2↑ 2.0↑ 1.8↑ 2.2↑ 2.0↑ 2.5↑ 2.4↑
Uniformity coefficient 1.1↓
Average diameter (㎛) 500±50 500±30 600±50 620±50 650±50 660±50 650±50 650±50
Operating temp. (℃) 120↓
Operating pH range 0∼14
Swelling rate(Na+ → H+)
9% 9% 8% 7%
Remarks
Low Crosslinkage
Standard Crosslinkage
High Crosslinkage
Very High Crosslinkage
High crosslinkage resin features the high resistance against oxidizing agents, high exchange rate per apparent volume and less swelling rate. However, it adversely has less exchange rate for large molecules, less regeneration efficiency and vulnerable to organic fouling. Low crosslinkage resin features higher regeneration efficiency, high resistance against organic fouling and fast reaction rate. However, it adversely has low exchange capacity and vulnerable to oxidizing agents.
※ The data for Specific gravity/ Shipping weight/ Swelling rate is for reference.
Applications
TRILITE MC-04(H) TRILITE MC-04(H) is a low crosslinkage UPS SAC resin which features fast exchange reaction. It
is widely applied to various chemical reactions such as catalytic application (Bisphenol-A, etc),
separation and refining of nucleic acid and amino acid, etc.
TRILITE MC-08(H) TRILITE MC-08(H) is a standard crosslinkage UPS SAC resin. With its excellent regeneration
efficiency and less rinse volume consumption, high purity water can be produced economically.
It has outstanding mechanical and chemical stability, leading to low crush rate even after long-
term use. It is widely used for softening, demineralization and other applications such as lysine,
sugar and catalyst reaction.
TRILITE MC-10(H) TRILITE MC-10(H) is a high crosslinkage UPS SAC resin which features outstanding mechanical
and chemical stability. It is widely used for premium water treatments such as condensate
polishing and pretreatment for ultrapure water.
TRILITE MC-14(H) TRILITE MC-14(H) is a very high crosslinkage UPS SAC resin. It has outstanding mechanical and
chemical stability. It is widely used for premium application where extremely high exchange
capacity is required such as Primary circuit in nuclear power plants and etc.
Applications
TRILITE MA-12(OH) TRILITE MA-12(OH) is an UPS SBA resin (Gel Type 1) with TMA as functional group. It is
supplied either in Cl or OH forms. It features higher SiO2 removal and less ion leakage. With
the fast reaction rate, it is widely used for various applications such as MBP(Mixed bed
polisher) in demineralization, UPW and noble metal recovery.
TRILITE MA-10(OH) TRILITE MA-10(OH) is a high crosslinkage UPS SBA resin (Gel Type 1) with TMA as functional
group. It features outstanding mechanical and chemical stability, SiO2 removal and less ion
leakage. It is widely applied to Condensate polishing.
TRILITE MA-15(OH) TRILITE MA-15(OH) is a very high crosslinkage UPS SBA exchange resin (Gel Type 1) with TMA
as functional group. It features outstanding mechanical and chemical stability. It is widely
applied to premium water treatment applications such as Anion exchanger for UPW and
Condensate polishing.
TRILITE MA-20 TRILITE MA-20 is an UPS SBA resin (Gel Type 2) with DMEA as functional group. It features
very high regeneration efficiency and operating capacity. It shows outstanding performance
when used in packed bed system and pre-treatment single bed for demineralization.
UPS Strongly Basic Anion(SBA) Resins
Type Type 1 Type 2
Grade MA-12 MA-12OH MA-10 MA-10OH MA-15 MA-15OH MA-20
Matrix Polystyrene + DVB (Gel type)
Functional group -N+(CH₃)₃ (TMA, Trimethylammonium)
-N+(CH₃)₂C₂H₄OH (DMEA,
Dimethylethanol-ammonium)
Ionic form Cl- OH- Cl- OH- Cl- OH- Cl-
Specific gravity 1.08 1.07 1.08 1.07 1.08 1.08 1.11
Shipping weight (g/ℓ) 670 660 675 665 705 670 700
Moisture retention (%) 49~55 62~70 43~49 59~65 39~45 54~62 45~51
Total capacity (eq/ℓ) 1.3↑ 1.0↑ 1.35↑ 1.1↑ 1.4↑ 1.2↑ 1.3↑
Uniformity coefficient 1.1↓
Average diameter (㎛) 580±50 620±50 550±50 590±50 600±50 630±50 590±50
Operating temp. (℃) 80↓ 60↓ 80↓ 60↓ 90↓ 70↓40↓ (OH- type)60↓ (Cl- type)
Operating pH range 0∼14
Swelling rate(Cl- → OH-)
24% 23% 22% 14%
Remarks Low Crosslinkage
Standard Crosslinkage
High Crosslinkage
Standard Crosslinkage
※ The data for Specific gravity/ Shipping weight/ Swelling rate is for reference.
Performance
16 17Ion Exchange Resins Product List Ion Exchange Resins Product List
EconomyBasic
Applications
TRILITE SAR10(MB), TRILITE SAR10(MB), KA-10(MB) are the high crosslinkage Gaussian SBA resin
TRILITE KA-10(MB) (Gel type 1) with higher SiO2 removal and less ion leakage. It is widely used for Anion
exchanger and MBP for demineralization, and also catalyst application and recovery of
noble metals such as gold.
TRILITE SAR12, TRILITE SAR12, KA-12 features higher SiO2 removal and less ion leakage. These are
TRILITE KA-12 widely used for surface water treatment required for a large amount of organic contents
and water treatment for high pressure boilers.
TRILITE UKA-12 TRILITE UKA-12 is a UPS SBA resin which is widely used for surface water treatment required
for a large amount of organic contents and water treatment for high pressure boilers.
TRILITE SAR20(MB), TRILITE SAR20(MB), KA-20(MB) are the Gaussian SBA resin (Gel type 2), and features
TRILITE KA-20(MB) high regeneration efficiency and operating capacity. It is most widely used for water
treatment, noble metal recovery and other refining applications.
EconomyBasic
Applications
TRILITE KC-07 TRILITE KC-07 is widely used for industiral softening with the cost advantage.
TRILITE KC-08 TRILITE KC-08 ia a standard crosslinkage Gaussian SAC resin with the cost advantage which
is widely used for industrial softening.
TRILITE KH-70, TRILITE KH-70, KH-80 are the premium grade resins for domestic appliances and food
TRILITE KH-80 processing softening applications. Special post treatments reduce the colorants leakage
and the bad ordor at the initial stage of usage.
TRILITE SCR-B TRILITE SCR-B is a standard crosslinkage Gaussian SAC resin. It is widely applied to water
treatments like softening and demineralization and other applications such as refining of
sugar/starch sugar, amino acids separation, dehydration of organic solvents and catalyst for
various chemical reactions.
TRILITE UKC-08 TRILITE UKC-08 is a standard crosslinkage UPS SAC resin and it is widely used for industrial
softening and demineralization.
TRILITE UKC-10, TRILITE UKC-10, UKC-12 is the high crosslinkage UPS SAC resins which are widely used for
TRILITE UKC-12 industrial softening and demineralization.
Gaussian/UPS Strongly Acidic Cation(SAC) Resins
Grade KC-07 KH-70 KC-08 KH-80 SCR-B UKC-08 UKC-10 UKC-12
Matrix Polystyrene + DVB (Gel type)
Functional group -SO3-(Sulfonate)
Ionic form Na+
Specific gravity 1.25 1.27 1.25 1.29 1.29 1.28 1.31 1.34
Shipping weight (g/ℓ) 800 820 800 830 830 840 850 860
Moisture retention (%) 45~50 45~50 43~50 43~50 43∼50 42~47 41~45 39~44
Total capacity (eq/ℓ) 1.9↑ 1.9↑ 2.0↑ 2.0↑ 2.0↑ 2.0↑ 2.2↑ 2.3↑
Effective size (㎛) 400↑ UPS
Uniformity coefficient 1.6↓ 1.1↓
Particle size (㎛) 300~1,200 600±50 650±50
Operating temp. (℃) 120↓
Operating pH range 0∼14
Swelling rate(Na+ → H+)
8~9% 9% 8% 7%
Remarks StandardCrosslinkage
High Crosslinkage
※ The data for Specific gravity/ Shipping weight/ Swelling rate is for reference.
Gaussian/UPS Strongly Basic Anion(SBA) Resins
Type Type 1 Type 2
Grade KA-10(MB) SAR10(MB) KA-12 SAR12 UKA-12 KA-20(MB) SAR20(MB)
Matrix Polystyrene + DVB (Gel type)
Functional group -N+(CH3)3 (TMA, Trimethylammonium)-N+(CH3)2C2H4OH
(DMEA, Dimethylethanolammonium)
Ionic form Cl-
Specific gravity 1.11 1.11 1.08 1.07 1.08 1.13 1.13
Shipping weight (g/ℓ) 670 685 685 680 670 720 700
Moisture retention (%) 43~47 43∼48 50~60 48∼55 49~55 40~50 39~45
Total capacity (eq/ℓ) 1.35↑ 1.3↑ 1.2↑ 1.3↑ 1.3↑ 1.3↑ 1.3↑
Effective size (㎛) 400↑ 400↑ 400↑ 400↑ UPS 400↑ 400↑
Uniformity coefficient 1.6↓ 1.6↓ 1.6↓ 1.6↓ 1.1↓ 1.6↓ 1.6↓
Particle size (㎛) 300∼1,200 580±50 300∼1,200
Operating temp. (℃)60↓(OH- type)80↓(Cl- type)
40↓(OH- type)60↓(Cl- type)
Operating pH range 0∼14
Swelling rate(Cl- → OH-)
24% 15% 12%
※ The data for Specific gravity/ Shipping weight/ Swelling rate is for reference.
18 19Ion Exchange Resins Product List Ion Exchange Resins Product List
Condensate polishing & Nuclear grade Resins
Type Condensate polishing Nuclear grade
Grade MC-10H CMP28LH MA-10OH AMP18LOH MCN116K MAN210K MMN316K
Matrix Polystyrene + DVB
Functional group-SO3
-
(Sulfonate)-N+(CH3)3
(TMA, Trimethylammonium)-SO3
-
(Sulfonate)
-N+(CH3)3 (TMA,
Trimethyl-ammonium)
MCN116K+
MAN210K
Ionic form H+ OH- H+ OH-
Total capacity (eq/ℓ) 2.0↑ 1.9↑ 1.1↑ 1.1↑ 2.4↑ 1.2↑
Moisture retention (%) 45∼51 42~48 59~65 50~56 36~43 54~60
Shipping weight (g/ℓ) 805 780 665 680 810 660
Uniformity coefficient 1.1↓ 1.4↓ 1.1↓ 1.4↓ 1.1↓
Particle size (㎛) 660±50 400~1,200 590±50 400~1,200 650±50 600±50
Effective size (㎛) UPS 400↑ UPS 450↑ UPS UPS
△TOC (ppb) - - - - 10↓ 10↓ 10↓
Operating temp. (℃) 120↓ 120↓ 60↓ 50↓ 120↓ 60↓ 60↓
Operating pH range 0∼14
※ The data for Shipping weight is for reference.
Applications
TRILITE MC-10H TRILITE MC-10H is a high crosslinkage UPS SAC resin which features outstanding
mechanical and chemical stability. It is widely used for premium water treatments such
as condensate polishing and pretreatment for ultrapure water.
TRILITE MA-10OH TRILITE MA-10OH is a high crosslinkage UPS SBA resin (Gel Type 1) with TMA as
functional group. It features outstanding mechanical and chemical stability, SiO2 removal
and less ion leakage. It is widely applied to Condensate polishing.
TRILITE CMP28LH TRILITE CMP28LH is a very high crosslinkage Gaussian SAC resin, which features higher
stability against oxidizing agents. It is widely used for water treatment, metal removals
and condensate polishing.
TRILITE AMP18LOH TRILITE AMP18LOH is a high crosslinkage resin, which features outstanding SiO2 removal
capaicty and less ion leakage. It is widely used for water treatment containing large
amount of organic contents MBP application and the condenstate polishing.
TRILITE MCN116K TRILITE MCN116K is a high crosslinkage UPS SAC resin and has polystyrene-DVB matrix
withsulfonic acid as functional group. It features excellent mechanical and chemical
stability, and low crush rate after long term use. It is widely used for premium water
treatment such as primary circuit for nuclear power plant.
TRILITE MAN210K TRILITE MAN210K is a high crosslinkage UPS SBA resin (Gel type 1) and has polystyrene-
DVB matrix with TMA as functional group. It features excellent mechanical/ chemical
stability and low crush rate after long term use. It is widely used for anion tower for
nuclear power plant, and under the standard operating conditions, it maintains less than
△TOC 10ppb of outlet water quality.
TRILITE MMN316K TRILITE MMN316K is a mixed resin of MCN116K and MAN210K by 1:1 exchange capacity ratio.
Performance
Applications
TRILITE WCA10L TRILITE WCA10L is a Gaussian WAC resin. Due to excellent ion exchange capacity, high
purity water can be produced economically. It features high mechanical and chemical
stability leading to low crush rate after long term use. It has high exchange capacity and
regeneration efficiency. It is widely applied in layered bed of water treatment systems
combined with SAC resins, and also used for Electrodeposition of paints, etc.
TRILITE AW20 TRILITE AW20 doesn’t have natural salt splitting capacity but high exchange capacity and
regeneration efficiency. It is widely used for refining of organic solvents with excellent
chemical stability, heat resisting capacity and mechanical strength against attrition loss.
TRILITE AW30L TRILITE AW30L features outstanding chemical stability, high resistance against organic
fouling and superior decolonization capacity. It is widely applied in layered bed of water
treatment systems combined with SBA resins, and also used for starch sugar refining.
TRILITE AW80 TRILITE AW80 features an excellent chemical stability, high resistance against organic
fouling. It is widely used for Layered bed water treatment system combined with SBA resins.
TRILITE AW90 TRILITE AW90 is an UPS resin with high chemical stability, high resistance against organic
fouling and superior depolarization capacity. It is widely used for starch refining and Layered
bed water treatment system combined with SBA resins.
Performance Economy
Weakly Acidic Cation(WAC) / Weakly Basic Anion(WBA) Exchange Resins
TypeWeakly Acidic Cation
Exchange ResinsWeakly Basic Anion Exchange Resins
Grade WCA10L AW20 AW30L AW80 AW90
Matrix Polyacrylate + DVB Polystyrene + DVB
Functional groupCOOH
(Carboxylic acid)
Secondary
AmineTertiary Amine
Ionic form H+ Free Base
Specific gravity 1.19 1.07 1.05 1.04 1.04
Shipping weight (g/ℓ) 720 650 700 670 640
Moisture retention (%) 45~50 39~45 48~58 55~60 40~50
Total capacity (eq/ℓ) 4.2↑ 2.5↑ 1.5↑ 1.6↑ 1.6↑
Effective size (㎛) 500↑ 400↑ 400↑ UPS UPS
Uniformity coefficient 1.4↓ 1.6↓ 1.4↓ 1.2↓ 1.1↓
Particle size (㎛) 425~1,200 300~1,200 425~1,200 400~600 550±50
Operating temp. (℃) 120↓ 100↓ 60↓ 60↓ 60↓
Operating pH range 4~14 0~9 0~9 0~9 0~9
Swelling rate(H+ → Na+, FB → Cl-)
60% 30% 20% 23% 20%
※ The data for Specific gravity/ Shipping weight/ Swelling rate is for reference.
20 21Ion Exchange Resins Product List Ion Exchange Resins Product List
※ Feed water : Industrial water, Electrical Conductivity : 200 μS/cm↓
Outlet condition of TRILITE UPW Resins
Mixed-bed(UPRM100U)
UV-OX,etc
Final Polisher(UPRM300U)
AnionPolisher
(UPRA200U)
RO,etc
FeedWater
Outletcondition
① Resistivity (MΩ·cm) ② TOC (ppb)
18.25
18.20
18.15
18.10
18.05
18.00
20
15
10
5
00.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0
(Mettler Toledo M300) hrs (Anatel A1000S20P) hrs
⑥ Particle (0.05㎛/㎖): None
(RION XP-L4W)
⑤ Metals (ppt)
Li Be Na Mg Al K Ca Ti Cr Mn Fe Co Ni Cu
< 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
Zn Ga As Sr Mo Ag Cd Sn Sb Ba Au Pb Bi
< 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
③ Total Silica (ppt) ④ Boron (ppt)
100
80
60
40
20
0
500
400
300
200
100
0
(HACH Series 5000 Silica Analyzer) hrs (Sievers UPW Boron Analyzer) hrs
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0
Ultrapure Water
The role of Ultrapure water(UPW) is increasing in electronic industries such as semiconductors and display
(LCD, OLED), etc. With the development of the relevant sectors, the quality control over the UPW has more
tightened up.
The following conditions are to be met necessarily to produce ultrapure water consistently.
- Low uniformity coefficient of resins (1.1↓)
- High conversion rate of resins (H+, OH-)
- Strict control over TOC (Total Organic Carbon) and trace metal-ion through post-treatment on resins.
TRILITE UPW resins own reliable supply reference to various ultrapure water systems from LCD(Samsung
Display, LG Display, etc.) to semiconductor(Samsung Electronics, SK Hynix, etc.) thus contributing to
competitiveness with customers with stable quality control and on time delivery.
TRILITE UPW resins are classified as: Primary application - UPR100 Series, Secondary application - UPR200
Series, and Final Polishing application – UPR300 Series.
Gradeseries
Representative products
Cationconversion rate
Anion conversion rateOutlet condition
H+(%) OH-(%) Cl-(%)
UPR100Series
UPRM100U 99.0↑ 95.0↑ 1.0↓
Guarantee) Resistivity > 17.0 MΩ·cm (in 10min.)
Actual) Resistivity > 18.0 MΩ·cm (in 10min.)
UPR200Series
UPRM200U 99.0↑ 95.0↑ 1.0↓Resistivity > 18.1 MΩ·cm (in 30min)
△TOC < 5ppb (in 120min)
UPR300Series
UPRM300U 99.9↑ 97.0↑ 0.1↓
Resistivity > 18.2MΩ·cm (in 30min)△TOC < 1ppb (in 180min)
Metal Impurity (ppm, as Dry Base)Na<1, Fe<1, Ca<1, Zn<0.5, Al<0.5, Cu<0.5
※ Feed water(100 Series) : Conductivity 10㎲/㎝ RO outlet, SV36Feed water(200, 300 Series) : Resistivity > 17.5㏁.㎝, TOC < 2ppb, SV30
RawWater
Point of Use
Typical UPW process and IER selection
Tank
Tank
TankHeat
Exchanger
Heat Exchanger
MF
UF
UV-ST
UV-OX
① CationExchanger
④ AnionPolisher
⑤ Final Polisher
① CationExchanger
Degasifier
RO
② AnionExchanger
③ Mixed Bed
MDGor
VDGPre-Treatment
System
① Cation Exchanger : MC-08, MC-10
② Anion Exchanger : MA-12, MA-10, MA-15, MA-20, AW80/AW90
③ Mixed Bed Tower : UPRC100U, UPRC120U, UPRA100U, UPRA120U
④ Anion Polisher : UPRA200U, UPRA220U, UPRA240U, UPRA300U, UPRA320U, UPRA340U
⑤ Final Polisher : UPRM200U, UPRM220U, UPRM240U, UPRM300U, UPRM320U, UPRM340U
22 23Ion Exchange Resins Product List Ion Exchange Resins Product List
Ultrapure water for final polishing UPR300 Series
Grade UPRC300U UPRA300U UPRC320U UPRA320U
Matrix
UPS SAC Gel type UPS SBA Gel type1 UPS SAC Gel type UPS SBA Gel type1
Standard Crosslinkage
High Crosslinkage
Ionic form H+ OH- H+ OH-
Total capacity (eq/ℓ) 1.9↑ 1.0↑ 2.0↑ 1.1↑
Moisture retention (%) 50∼56 62∼70 45~51 59∼65
Average diameter (㎛) 620±50 620±50 660±50 590±50
Uniformity coefficient 1.1↓ 1.1↓ 1.1↓ 1.1↓
Ionic conversion rate
H+(%) 99.9↑ - 99.9↑ -
OH-(%) - 97.0↑ - 97.0↑
Cl-(%) - 0.1 ↓ - 0.1 ↓
Metal impurity(ppm, as Dry Base)
Na<1, Fe<1, Ca<1, Zn<0.5, Al<0.5, Cu<0.5
↓ ↓ ↓ ↓
Mixed ratio : 1:1 (Capacity ratio) Mixed ratio : 1:1 (Capacity ratio)
↓ ↓
Grade UPRM300U UPRM320U
Type Mixed resin
Outlet condition
Resitivity > 18.2 MΩ·cm (in 30min.)△TOC < 1ppb (in 180min.)
Resitivity > 18.2 MΩ·cm (in 30min.)△TOC < 1ppb (in 180min.)
Feed water : Resistivity > 17.5 MΩ·cm, TOC < 2ppb, SV30
Ultrapure water system
Ultrapure water for primary circuit UPR100 Series
Grade UPRC100U UPRA100U UPRC120U UPRA120U
Matrix
UPS SAC Gel type UPS SBA Gel type1 UPS SAC Gel type UPS SBA Gel type1
Standard Crosslinkage
High Crosslinkage
Ionic form H+ OH- H+ OH-
Total capacity (eq/ℓ) 1.8↑ 1.0↑ 2.0↑ 1.1↑
Moisture retention (%) 50∼56 62∼70 45~51 59∼65
Average diameter (㎛) 620±50 620±50 660±50 590±50
Uniformity coefficient 1.1↓ 1.1↓ 1.1↓ 1.1↓
Ionic conversion rate
H+(%) 99.0↑ - 99.0↑ -
OH-(%) - 95.0↑ - 95.0↑
Cl-(%) - 1.0 ↓ - 1.0 ↓
↓ ↓ ↓ ↓
Mixed ratio : 1:1 (Capacity ratio) Mixed ratio : 1:1 (Capacity ratio)
↓ ↓
Grade UPRM100U UPRM120U
Type Mixed resin
Outlet condition1)
Guarantee) Resistivity > 17.0 MΩ·cm (in 10min.)Actual) Resistivity > 18.0 MΩ·cm (in 10min.)
Feed water : Conductivity 10㎲/㎝ RO outlet, SV36
Outlet condition2)Guarantee) Resistivity > 18.0 MΩ·cm (in 30min.)
Feed water : Resistivity > 17.5 MΩ·cm, SV30
Ultrapure water for secondary circuit UPR200 Series
Grade UPRC200U UPRA200U UPRC220U UPRA220U
Matrix
UPS SAC Gel type UPS SBA Gel type1 UPS SAC Gel type UPS SBA Gel type1
Standard Crosslinkage
High Crosslinkage
Ionic form H+ OH- H+ OH-
Total capacity (eq/ℓ) 1.9↑ 1.0↑ 2.0↑ 1.1↑
Moisture retention (%) 50∼56 62∼70 45~51 59∼65
Average diameter (㎛) 620±50 620±50 660±50 590±50
Uniformity coefficient 1.1↓ 1.1↓ 1.1↓ 1.1↓
Ionic conversion rate
H+(%) 99.0↑ - 99.0↑ -
OH-(%) - 95.0↑ - 95.0↑
Cl-(%) - 1.0 ↓ - 1.0 ↓
↓ ↓ ↓ ↓
Mixed ratio : 1:1 (Capacity ratio) Mixed ratio : 1:1 (Capacity ratio)
↓ ↓
Grade UPRM200U UPRM220U
Type Mixed resin
Outlet condition
Resistivity > 18.1MΩ·cm (in 30min.)△TOC < 5ppb (in 120min.)
Resistivity > 18.1 MΩ·cm (in 30min.)△TOC < 5ppb (in 120min.)
Feed water : Resistivity > 17.5 MΩ·cm, TOC < 2ppb, SV30
24 25Ion Exchange Resins Product List Ion Exchange Resins Product List
Ion exchange resins are used as a catalyst for various chemical reactions and convert the Batch operation
into the Continuous operation. Based on the high conversion rate of IERs, the yield of the final product can be
maximized. The followings are the advantages of IERs used in the catalyst applications :
- Easily separable from the reaction system and cost-effective with the continuous reaction in the column reactor.
- Unnecessary for regeneration or re-concentration, high reaction selectivity and fewer byproducts produced.
- Easy to be selected with low corrosive to the system.
Also, the following disadvantage is taken care of disadvantages of catalyst IER for cation:
- Less heat stability compared to inorganic catalyst and slow reaction rate for macromolecules reactions.
TRILITE catalyst resin optimizes the catalytic reactions with the improved porosity and excellent ionic conversion
rate of resins. It shows a fast reaction rate with maximized surface area and remarkable internal diffusion speed,
resulting in efficient reactions even in the non-polar solvent. Also, it has outstanding mechanical and chemical
stability and excellent elasticity of polymers. Hence, the superior durability of resins can be achieved even under
the rapid volume changes and results in longer lifetime ultimately.
Catalyst
Application Reaction Catalytic resins Equivalent
Hydrolysis of
methyl acetateCH₃COOCH₃ + H₂O → CH₃COOH + CH₃OH
PCC40H,
MC-08H,
CMP08LH
Esterification
reactionRCOOH + ROH → RCOOR + H₂O
PCC40H, MC-08H,
CMP08LH,
SPC160H, SPC180H,
SPC400LH
Synthesis of
methyl
methacrylate
SPC180H
Alkylation of
phenol
SPC260H,
SPC320HAmberlyst15Wet
Synthesis of
bisphenol-A
PCC30H,
PCC40H
Methyl tertiary
butyl ether
(MTBE)
SPC280H Amberlyst35Wet
t-amyl methyl
ether(TAME)
SPC160H,
SPC180H
CH₂ = C CH₃OH → CH₂ = C H₂O
CH₃
COOH
CH₃
COOCH₃
+ +
H₂CCH₃
CH₃CH₃OH H₃C OMe
CH₃
CH₃
+
H₂CCH₂CH₃
CH₃CH₃OH H₃C OMe
CH₂CH₃
CH₃
+
OH OHHO+
O
H₃C CH₃H₃C CH₃
OH OH
+ H₂CR
H CH₃
R
H
Applications
TRILITE PCC30H, TRILITE PCC30H, PCC40H is a low crosslinkage SAC resin with high reaction rate and
TRILITE PCC40H mechanical and chemical stability, and widely used as a catalyst for Bisphenol-A.
TRILITE SPC260H TRILITE SPC260H is a porous type SAC resin with high exchange capacity and good
resistance against attrition loss. It is widely used for etherification catalyst. It features
strong selectivity even for a low-temperature with the excellent reaction rate.
TRILITE SPC280H TRILITE SPC280H features an enhanced exchange capacity (approximately 10%)
compared to TRILITE SPC260H.
Strongly Acidic Cation Resins for Catalyst
Grade PCC30H PCC40H SPC260H SPC280H
MatrixPolystyrene+DVB
(Gel type)Polystyrene+DVB
(Porous type)
Functional group -SO3-(Sulfonate)
Ionic form H+(H Conversion rate 99.9%↑)
Shipping weight (g/ℓ) 750 780 800 800
Moisture retention (%) 60~70 57∼67 50~58 50~58
Total capacity (eq/kg) 4.5↑ 4.5↑ 4.7↑ 5.2↑
Total capacity (eq/ℓ) 1.2↑ 1.2↑ 1.75↑ 1.9↑
Effective size (㎛) 500↑ 400↑ 400↑
Uniformity coefficient 1.3↓ 1.6↓ 1.6↓ 1.6↓
Particle size (㎛) 600∼1,250 General type : 300∼1,200, L-type : 425~1,200, XL-type : 700~1200
Operating temp. (℃) 120↓ 120↓ 120↓ 120↓
Operating pH range 0∼14 0∼14 0∼14 0∼14
Specific surface area (㎡/g) - - 40~70 40~50
Pore Volume (㎡/g) - - 0.30~0.50 0.35~0.40
Pore radius (Å) - - 200~500 380~450
Shrinkage Water → Phenol : 53% Water → Phenol : 51%
Water → Methanol : 5%Water → MTBE : 9%Water → Hexane : 20%Water → Dry : 36%
Water → Methanol : 5%Water → MTBE : 10%Water → Hexane : 20%Water → Dry : 40%
26 27Ion Exchange Resins Product List Ion Exchange Resins Product List
Chromatography
Ion Exchange Resins for chromatography separation efficiently separate useful materials in various applications
such as high-purity separation of sugar solutions, e.g. Fructose/Glucose separation and sucrose recovery from
molasses, and acid purification, etc.
The following characteristics are required to be IERs for chromatography separation.
- Outstanding uniformity and excellent separation capacity.
- Relatively small particle size for maximum separation efficiency with a larger surface area per volume unit of resins.
- A longer life time with mechanical and chemical stability.
TRILITE chromatography resins completely satisfy the above conditions, and enable the most efficient
separation capacity by the various degree of crosslinkages (%), ionic forms and particle sizes. The Following
tables show major applications of UPS gel type cation exchange resins and UPS gel type 1 & 2 anion exchange
resins, and the full line-up of TRILITE chromatography resins.
TypeIonic forms
Representativeproducts
Major application
UPS SAC Gel type
Na MCK-30Glucose/Oligosaccharide separation,
Maltose/Oligosaccharide separation
K MCK-22M Sucrose collection from Molasses
Ca MCK-55Fructose/Glucose separation, Fructose/Allulose separation,
Fructose/Galactose separation
UPS SBA
Gel
type 1 Cl MA-13J Bio diesel purification process
type 2 Cl MA-23F Acid purification
Lower Uniformity coefficient (1.05~1.10) than
other resins for chromatographic separation
→ Excellent separation efficiency
Higher physical & chemical strength
→ Longer life time+
Crosslinkage Ionic form
Average particle size
210~220㎛ 283~295㎛ 305~328㎛ 340~350㎛
5% KMCK-22M
(305㎛)
MCK-22K
(346㎛)
6%
NaMCK-30
(220㎛)
MCK-30J
(295㎛)
MCK-30L
(328㎛)
MCK-30K
(350㎛)
KMCK-32
(213㎛)
MCK-32J
(288㎛)
MCK-32L
(320㎛)
MCK-32K
(345㎛)
CaMCK-35
(210㎛)
MCK-35J
(283㎛)
MCK-35L
(315㎛)
MCK-35M
(305㎛)
MCK-35K
(340㎛)
8%
NaMCK-50
(215㎛)
KMCK-52
(215㎛)
CaMCK-55
(210㎛)
※ The data for average particle size and the crosslinkage is for reference.
Applications
TRILITE MC-04H TRILITE MC-04H is a low crosslinkage UPS SAC resin which features fast exchange
reaction. It is widely applied to various chemical reactions such as catalysitc application
(Bisphenol-A, etc), separation and refining of nucleic acid and amino acid, etc.
TRILITE CMP08H TRILITE CMP08H is a low crosslinkage Gaussian SAC resin and is widely used in water
treatments such as softening and demineralization and special refining such as acid
catalyst, organic chemical reactions.
TRILITE CMP28H TRILITE CMP28H is a very high crosslinkage Gaussian SAC resin, which features higher
stability against oxidizing agents. It is widely used for water treatment, metal removals and
condensate polishing.
TRILITE SPC160H TRILITE SPC160H has very high whole bead count, high uniformity, excellent mechanical
and chemical stability. It is widely used for etherification, e.g. Tetrahydrofuran(THF).
TRILITE SPC180H TRILITE SPC180H features stronger mechanical strength, higher surface area and higher
porosity than other resins. Its high diffusion rate into the inside of resins leads high reaction
performance. It is used for water treatment and catalyst applications such as alkylation
and etherification, e.g. 1,4-BDO, MMA.
TRILITE SPC320H TRILITE SPC320H has high exchange capacity, large specific surface area and high
porosity. It shows excellent adsorption and recovery capacity to metal ions such as Cu,
V2O5, etc.
Strongly Acidic Cation Resins for Catalyst
Grade MC-04H CMP08H CMP28H SPC400H SPC160H SPC180H SPC320H
MatrixPolystyrene
+DVB(Gel type)
Polystyrene+DVB(Porous type)
Functional group -SO₃-(Sulfonate)
Ionic form H+(H Conversion rate 99.9%↑)
Shipping weight (g/ℓ) 750 720 780 690 740 750 780
Moisture retention 65∼70 65~71 42~48 65∼75 54∼60 53∼60 42~48
Total capacity (eq/kg) 5.1↑ 4.9↑ 4.0↑ 4.9↑ 4.5↑ 4.5↑ 4.5↑
Total capacity (eq/ℓ) 1.2↑ 1.1↑ 1.9↑ 1.0↑ 1.5↑ 1.5↑ 1.9↑
Effective size (㎛) UPS 400↑
Uniformity coefficient 1.1↓ 1.6↓
Particle size (㎛) 500±30 General type : 300∼1,200, L-type : 425~1,200, XL-type : 700~1200
Operating temp. (℃) 120↓
Operating pH range 0∼14
※ The data for Shipping weight is for reference.
28 29Ion Exchange Resins Product List Ion Exchange Resins Product List
크로마토그래피 분리
MCK-22 Series (Chromatography cation resins)
Grade MCK-22M MCK-22K
Matrix, Functional group Polystyrene + DVB, -SO₃-(Sulfonate)
Ionic form K+ (K Conversion rate 98%↑)
Shipping weight (g/ℓ) 815
Moisture retention (%) 47~52 (K type), 59~64 (H type)
Total capacity (eq/ℓ) 1.6↑
Average diameter (㎛) 305±15 346±15
Uniformity coefficient 1.1↓
MCK-30 Series (Chromatography cation resins)
Grade MCK-30 MCK-30J MCK-30L MCK-30K
Matrix, Functional group Polystyrene + DVB, -SO₃-(Sulfonate)
Ionic form Na+
Shipping weight (g/ℓ) 830
Moisture retention (%) 52~56
Total capacity (eq/ℓ) 1.6↑
Average diameter (㎛) 220±10 295±15 328±15 350±15
Uniformity coefficient 1.1↓
MCK-32 Series (Chromatography cation resins)
Grade MCK-32 MCK-32J MCK-32L MCK-32K
Matrix, Functional group Polystyrene + DVB, -SO₃-(Sulfonate)
Ionic form K+ (K Conversion rate 98%↑)
Shipping weight (g/ℓ) 840
Moisture retention (%) 46~51
Total capacity (eq/ℓ) 1.6↑
Average diameter (㎛) 213±10 288±15 320±15 345±15
Uniformity coefficient 1.1↓
※ The data for Shipping weight is for reference.
Fructose/Glucose separation by MCK-55
Isomerization of fructose by the use of enzyme produces glucose which features a higher sweetness (1.7 times
of sugar). The starch sugar is proved to be economically efficient and is substitutable to the use of sugar.
However, the enzyme reaction is a reversible reaction. The isomerization is limited up to 42% (equal to 90% of
sugar sweetness) due to reaction equilibrium. Hence, it is required to increase the glucose percentage up to
55%, with the IER technology.
A typical process to treat the fructose/glucose mixture with the Ca type ion exchange resin tower is described
as below. As the mixture passes through the IER layers, glucose moves faster than fructose which has a higher
affinity with Ca ion. In this principal, glucose elutes in before the fructose. The collection of glucose is sold as a
finished product, and the fructose is put to the previous process to react with the isomerization enzyme.
Fructose 90% ↑
Fructose/Glucose separation tower
Filtration, Concentration
Isomerization by enzyme
42% HFS
Activated carbon
Mixing
Ion exchanger
(for fructose)
55% HFS
Glucose (40~45%)
Fructose
Glucose
Fructose
Glucose Fructose
Glucose
MCK-55(Ca form)
High fructose syrup
30 31Ion Exchange Resins Product List Ion Exchange Resins Product List
Typical process of Starch sugar refining and Fructose/Glucose separation
CMP18
AMP24SCR-Bor
CMP18
AW30Lor
AW30C
Counter-current
pH 5~6
5㎲/㎝↓
CocurrentpH 8~9
20㎲/㎝↓
pH 4~6
2㎲/㎝↓
Bx 45
CV Max 0.05
2nd Ion exchanger(for fructose)
Concentration
Mixing
High fructose syrup
Activatedcarbon
Filtration
90~97% HFS
42% HFS
55% HFS
Isomerizationby enzyme
Concentration3rd Ion exchanger(for high fructose)
Fructose/Glucose Separation
CMP18
AMP24SCR-Bor
CMP18
AW30Lor
AW30C
Counter-current
pH 5~6
5㎲/㎝↓
CocurrentpH 8~9
20㎲/㎝↓
pH 4~6
2㎲/㎝↓
Bx 35~40
CV Max 0.05
Enzyme liquefaction, saccharification
Activated carbon1st Ion exchanger
(for glucose)
Corn syrup
Glucose
Emulsion of starch Filtration
ConcentrationConcentration
Starch(Corn)
The starch sugar refining is one of the primary food application for IERs. Unlike water treatment applications,
there are other variables affecting operation yields such as total organic contents or viscosity and adsorption
capacity to specific materials, hence customized Tailored resins optimized for specific operating conditions are
recommended.
Ion Exchange Resins used as food applications need for strict control and management of impurities and
foreign substances in the manufacturing process, and are registered as food grade between countries with
necessary permits as a Food additive. Also, Halal certificates are required for Islamic countries.
TRILITE food application IERs are optimized for various domestic and overseas food processes and contribute
to enhancing competitiveness to customers by continuous technical consultation and product improvements.
Porous type reins are recommended for starch sugar production with higher viscosity and less reactivity
of liquid rather than Gel type resins. TRILITE AW30C (WBA 99%↑) is recommended when the treated liquid
temperature is high (60℃↑) or there is worry about isomerization reaction.
TRILITE MCK-50 Series is receiving rave reviews from users with outstanding uniformity of resins and superior
mechanical and chemical stability to any other resins in the industry.
Food - Starch Sugar
Fructose(90~97%)
Glucose(80~90%)
Fructose (42%)
Glucose (52%)
Other sugars(6%)
pH 4~6
2㎲/㎝↓
Bx 40
CV Max 0.05
AW30C
AMP24
CMP18
(Mixture) (Separation)
MCK-55
MCK-35 Series (Chromatography cation resins)
Grade MCK-35 MCK-35J MCK-35M MCK-35L MCK-35K
Matrix, Functional group Polystyrene + DVB, -SO₃-(Sulfonate)
Ionic form Ca2+ (Ca Conversion rate 98%↑)
Shipping weight (g/ℓ) 840
Moisture retention (%) 47~51
Total capacity (eq/ℓ) 1.6↑ 1.7↑
Average diameter (㎛) 210±10 283±15 305±15 315±15 340±15
Uniformity coefficient 1.1↓
MCK-50 Series (Chromatography cation resins)
Grade MCK-50 MCK-52 MCK-55
Matrix, Functional group Polystyrene + DVB, -SO₃-(Sulfonate)
Ionic form Na+ K+ (K Conversion rate 98%↑)
Ca²+ (Ca Conversion rate 98%↑)
Shipping weight (g/ℓ) 855 865 865
Moisture retention (%) 46~50 39~43 42~46
Total capacity (eq/ℓ) 1.9↑ 2.0↑ 2.0↑
Average diameter (㎛) 215±10 215±10 210±10
Uniformity coefficient 1.1↓
Strongly Basic Anion Resins for Chromatography
Type Type 1 Type 2
Grade MA-13J MA-13F MA-23F
Matrix, Functional group Polystyrene + DVB, TMAPolystyrene + DVB,
DMEA
Ionic form Cl-
Shipping weight (g/ℓ) 720 720 715
Moisture retention (%) 43~53 47~51 42~46
Total capacity (eq/ℓ) 1.35↑ 1.4↑ 1.4↑
Average diameter (㎛) 300±15 230±10 230±10
Uniformity coefficient 1.1↓
※ The data for Shipping weight is for reference.
크로마토그래피 분리
32 33Ion Exchange Resins Product List Ion Exchange Resins Product List
Food - Sugar / Nucleic Acid / Lysine
Refined Sugar
White Sugar
Brown Sugar
Cane raw sugar refining process Sugar refining process with A/C Sugar refining process without A/C
Cane B Sugar (Raw sugar) C Sugar (Raw sugar)
Extraction Carbonation, Filtration Carbonation, Filtration
FiltrationDecolorization by IER(KA-11/SAR11 or AMP14)
Decolorizationby IER (2 steps)
(ASP10 + AMP14)
Crushing Affination, Melting Affination, Melting
Carbonation Activated carbon
Concentration,Crystallization
Concentration, Crystallization
Concentration, Crystallization
A Sugar B Sugar C SugarRefined Sugar
White Sugar
Brown Sugar
Typical process of nucleic acid
adsorption / elution processTypical process of lysine adsorption /
elution process
AMP26N MC-08LSNAC-4
orMC-04NH
AMP26N
Cultivation of microorganism
Cultivationof yeast
CrystallizationCrystallization
Broth withlysine
Extraction of nucleic acids
EvaporationEvaporation
Adsorption & separation
with IER
Decompositionof nucleic acids
Neutralization, Filtration
Adsorption & separation
with IER
Adsorptionof nucleic acids
Separationof GMP, IMP
Concentration Adsorption of lysine
2,000~3,000 I.U.
3,000~4,000 I.U.
800~1,000 I.U.
800~1,000 I.U.
300~400 I.U. 200~
300 I.U.100~150 I.U.
500~600 I.U. < 45 I.U. < 45 I.U.2,000~3,000 I.U.
< 100 I.U. < 100 I.U.3,000~4,000 I.U.
400~1,000 I.U. 400~1,000 I.U.
General sugar processes are classified into the production of raw sugar and refined sugar. The raw sugar
manufacturing process doesn’t need IERs, but refined sugar requires IERs necessarily. For refined sugar process,
it is also distinguished between the combination use of IERs & activation carbon and the use of two different
types of IERs. Without using activated carbon, there are a large number of colorants to be removed by IER. In
such a case, it is recommended to use the combination with TRILITE ASP10, which has the outstanding feature
of enhanced decolorization capacity and long lifetime with excellent resistance to organic fouling of resins.
Nucleic acids, one of the popular food additives, are
flavor enhancers and used as seasonings. IERs are
used for adsorption, separation, and concentration of
nucleic acids. TRILITE AMP26N and NAC-4 are Tailored
resins with high performance and long life cycle.
Ion Exchange Resins are used for separation and
purification of amino acids, constituents of protein.
Lysine as a feed nutrition additive is the most
commercialized amino acids. TRILITE MC-08LS is
a Tailored UPS resin with outstanding adsorption
capacity, mechanical and chemical stability.
※ GMP : Guanosine MonoPhosphate※ IMP : Inosine MonoPhosphate
※ Lysine : An essential amino acid
Starch sugar refining Resins
TypeSACGel
SAC Gel
SAC Porous
SBAPorous type 2
WBAPorous
WBAPorous
WBAPorous
Grade SCR-B MC-08 CMP18 AMP24 AW30L AW30C AW90
Matrix Polystyrene+DVB
Functional group -SO3-(Sulfonate)
-N+(CH3)2C2H4OH (DMEA)
Tertiary Amine
Ionic form Na+ Cl- Free Base
Specific gravity 1.29 1.28 1.3 1.09 1.05 1.05 1.04
Shipping weight (g/ℓ)
830 845 795 655 700 700 640
Moisture retention (%)
43∼50 43∼49 43∼50 54∼64 48~58 55~65 40~50
Total capacity (eq/ℓ) 2.0↑ 2.0↑ 1.8↑ 1.0↑ 1.5↑ 1.6↑ 1.6↑
Effective size (㎛) 400↑ UPS 400↑ 400↑ 400↑ 400↑ UPS
Uniformity Coefficient
1.6↓ 1.1↓ 1.6↓ 1.6↓ 1.4↓ 1.6↓ 1.1↓
Particle size (㎛) 300~1,200 600±50 300~1,200 300~1,200 400~1,200 300~1,200 550±50
Operating ptemp. (℃)
120↓ 120↓ 120↓50↓ (OH- type) 70↓ (Cl- type)
60↓ 100↓ 60↓
Operating pH range
0∼14 0∼14 0∼14 0∼14 0~9 0~9 0~9
Swelling rate(Na+ → H+, FB → Cl-,
Cl- → OH-)
8% 9% 8% 14% 20% 20% 20%
※ The data for Specific gravity/ Shipping weight/ Swelling rate is for reference.
34 35Ion Exchange Resins Product List Ion Exchange Resins Product List
Chelating Resins
CLR-08
Ca²+ 0.01ppm↓
Mg²+ 0.01ppm↓
Sr²+ 0.02ppm↓
Ba²+ 0.01ppm↓
In contrast to typical Ion exchange resins, the chelating resin selectively separates and removes a metal ion with
a functional group that can form a chelate (complex) with the metal ion. Chelating resins with various functional
groups are used in the following applications.
Grade Functional group Features Application
CLR-08 Iminodiacetate
- Much greater selectively for
multivalent ions (Ca²+, Mg²+, Sr²+, etc.)
from very highly concentrated
monovalent ions(Na+, etc.)
- Less leakage of multivalent ions
- Secondary brine purification
- Selective removal of bivalent ions
- Removal and recovery of heavy metals
/ rare metals from wastewater
CLR-09Aminomethyl
phosphonate
- slightly higher operating capacity than
CLR-08
- slightly more leakage of multivalent
ion than CLR-08
- Secondary brine purification
- Selective removal of bivalent ions
CLR-10 Thiouronium- Much greater selectivity for
mercury(Hg)- Mercury removal in wastewater
CLR-20 Polyamine
- Much greater selectivity for heavy
metals except alkali metal ions(Na+, K+,
etc) and alkaline earth metal ions(Ca2+,
Mg2+, etc)
- Separation of heavy metals from
alkali metal ions and alkaline earth
metal ions
CLR-B3 Glucamine- Much greater selectivity for boron(B)
from highly concentrated anions- Boron removal from wastewater
CLR-B3UP Glucamine- Much greater selectivity for boron(B)
and less TOC leakage(ΔTOC 5ppb↓)- Boron polisher for UPW
CLR-F Aminophosphonate- Much greater selectivity for fluoride(F)
even from low concentration- Fluoride removal in wastewater
CLR-N Triethylamine- Much greater selectivity for nitrate
than anion resins- Nitrate removal
TRILITE chelating resins are used for various applications and processes. Total solution service can be
provided by an optimized proposal for process retrofit and resin analysis. The professional consultation
can be provided; Preliminary technical review → Pilot plant test → Gathering engineering data → Optimized
design proposal → further Scale-up of the facility.
TRILITE chelating resins are being supplied to domestic and foreign customers especially for secondary brine
purification applicaton and proved the competitiveness to other equivalent resins.
Typical chloro-alkali process
Salt saturation
Dechlorination
Primary brine purification
Gas liquid separation
Secondary brine
purification
Ion exchange membrane
electrolysis cell
Vaporization
Salt
Chlorine
Hydrogen
Water
Secondary brine purification
50% NaOH
Sugar refining, Nucleic acid/Lysine adsorption Resins
TypeSugar refining resins
SBA Gel type 1 SBA Gel type 1 SBA Porous type 1 SBA Porous type
Grade SAR11 KA-11 AMP14 ASP10
Matrix Polystyrene+DVB Polyacrylate + DVB
Functional group -N+(CH3)3 (TMA, Trimethylammonium)Quaternary Ammonium
Ionic form Cl- Cl-
Shipping weight (g/ℓ) 690 700 670 700
Moisture retention (%) 55~65 55~65 57~67 65~75
Total capacity (eq/ℓ) 0.9↑ 0.9↑ 1.0↑ 0.9↑
Effective size (㎛) 400
Uniformity Coefficient 1.6↓
Particle size (㎛) 300~1,200 400~1,250
Operating temp. (℃) 60↓ (OH- Type)80↓ (Cl- Type)
70↓ (OH- Type)90↓ (Cl- Type)
40↓ (OH- Type)80↓ (Cl- Type)
Operating pH range 0~14
Swelling rate(Cl- → OH-)
35% 25% 25%
TypeNucleic acid adsorpion resins
Lysine adsorption resins
Gel SAC Porous type 2 UPS Gel SAC UPS Gel SAC
Grade NAC-4 AMP26N MC-04NH MC-08LS
Matrix Polystyrene+DVB
Functional group -SO₃- (Sulfonate)-N+ (CH₃)₂C₂H₄OH
(DMEA)-SO₃- (Sulfonate) -SO₃- (Sulfonate)
Ionic form Na+ Cl- H+ Na+
Shipping weight (g/ℓ) 780 680 750 845
Moisture retention (%) 57∼67 46∼52 65~70 43~49
Total capacity (eq/ℓ) 1.2↑ 1.1↑ 1.2↑ 2.0↑
Effective size (㎛) 450↑ 400↑ UPS UPS
Uniformity Coefficient 1.6↓ 1.1↓ 1.1↓
Particle size (㎛) 300∼1,200 500±50 600±50
Operating temp. (℃) 120↓ 50↓ (OH- Type)70↓ (Cl- Type)
120↓ 120↓
Operating pH range 0~14 0~14
Swelling rate(Na+ → H+, Cl- → OH-)
8% 13% 9% 9%
※ The data for Shipping weight/Swelling rate is for reference.
36 37Ion Exchange Resins Product List Ion Exchange Resins Product List
Synthetic Adsorbents
The reaction mechanism of synthetic adsorbents and experimental apparatuses
Synthetic adsorbents are non-functionalized resins with controlled pore size distribution and large surface area.
While the primary application of synthetic adsorbents is to adsorb various organics by Van der Waals forces,
it can be used in various applications such as decolorization of liquid chemical, separation, and purification of
proteins and antibiotics, purification of medical supplies and refining semiconductor chemicals.
The above diagram depicts the necessary test for the choice of Synthetic adsorbents. In general, the test is
preceded with TRILITE GSH-20 for adsorption and elution of target material first. To find out proper synthetic
adsorbent, re-test it with other types of synthetic adsorbents according to selectivity to M.W and elution rate of
the target material.
The following table shows the features of major TRILITE Synthetic adsorbents.
Type Product Feature
Aromatic standard type GSH-20
Relatively large pore radius, hence appropriate for
adsorption of large molecules (> 1,000mw). Easily elutes
and separates the target material.
Aromatic special type
GSP-25 Very large surface area and small pore radius, hence
appropriate for adsorption of small molecules (< 1,000mw)
and exclusion of large molecules.GSP-50
Aromatic chemically modified GSP-07
Substituted bromine turns out very high hydrophobicity
resulting very high selectivity to non-polar molecules.
Large amount of eluent may be required due to very high
adsorption force.
It can be can be used for solution with high density due to
high specific gravity.
The following table shows general tendency and guideline for choosing Synthetic Adsorbents.
Type Case and General Tendency Guideline
Selectivity
(molecular
weights)
Adsorption of all materials from solution containing
large amount of organics (mw > tens of thousands)GSH-20 > GSP-07 > GSP-25 > GSP-50
Adsorption of material from solution with large amount
of organic content (mw < 1,000)GSP-50 > GSP-25 > GSH-20 > GSP-07
Adsorption of materials (mw < several thousands) GSP-07 > GSP-50 > GSP-25 > GSH-20
ElutionElution tends to decrease with small pore radius and
large adsorption force.GSH-20 > GSP-25 > GSP-50 > GSP-07
Feeding solution
Eluent
Detector
Purewater
Regenerant
Fraction collector
Synthetic adsorbents
Pure water
ColumnTarget
moleculesPore radius
(Å)
Specific surface
area(m2/g)
Typical process of removing heavy metal from waste water
The above diagram depicts a waste water treatment system with TRILITE chelating resins which selectively
removes metal ions. As the environmental regulations are more strictly controlled, there is tendency for the
increasing wastewater treatment cost. TRILITE chelating resins can be an alternative solution to the high cost of
wastewater treatment.
Waste water containing
various heavy metal
(If mercury is not present)
Waste water containing
various heavy metal
(If mercury is present)
CLR-10(Mercury removal)
Neutralization coagulationsettlement treatment
CLR-20(Heavy metal removal)
Type Chelating resins
Grade CLR-08 CLR-09 CLR-10 CLR-20 CLR-B3 CLR-B3UP CLR-F CLR-N
Matrix Polystyrene+DVB
Functional group
Iminodia-cetate
Aminomethyl-phosphonate
Thiouronium Polyamine Glucamine GlucamineAmino-
phosphonateTriethylamine
Ionic form Na+ Na+ H+ OH- Free base Free base Al³+ Cl-
Total capacity (eq/ℓ)
Cu2+ 0.5↑
Ca2+ 0.4↑Ca2+ 0.6↑ 1.1↑
4mol↑as copper
0.6eq/ℓ↑as boron
0.6eq/ℓ↑as boron
11g↑ as fluorine
1.0↑
Particle size (㎛) 400~1,000 400~1,000 300~1,250 400~1,250 300~1,250 300~1,250 300~1,000 300~1,250
Equivalent
· Lewatit TP208
· Amberlite IRC748
· Diaion CR11· Purolite
S930
· Lewatit TP260
· Amberlite IRC747
· Purolite S940
· Eporous-Z7· Purolite
S924
· Diaion CR20
· Eporous MX-8C
· Diaion CRB03
· Amberlite IRA743
· Purolite S108
· Diaion CRBT03
· Eporous-K1· READ-F
· Amberlite IRA996
· Purolite A520E
CLR-10 (Optional)
CLR-20
Sandfilter
Activated carbon
filter
P
P
P
M M
Waste water
containing
heavy metal
Waste waterstorage pit
Neutralizingreaction pit
Clarifier
Dischargingor
recycling
pH adjusting pitChelating resin towerpH adjusting pit
Neutralizingagent
Neutralizingagent
Neutralizingagent
Coagulant
M
38 39Ion Exchange Resins Product List Ion Exchange Resins Product List
Ready to use Mixed Resins
Ready to use mixed resins produce high purity water in a more convenient way. Up to the usage of water
volume, they are widely used for cartridges or pressure vessels which do not require a complicated
regeneration process. The primary application for TRILITE SM200, SM210 is in Wire EDM applications. It features
an outstanding amount of treated water compared to other ready to use mixed resins in the market. TRILITE
SM300 used after RO(Reverse osmosis) in Make-up systems, results in treated water quality close to that of
Ultrapure water (Resistivity > 15.0MΩ·cm).
Type Ready to use mixed resins
Grade SM200 SM210 SM300
Matrix Polystyrene+DVB
Functional group Mixed resin
Shipping weight (g/ℓ) 700
Particle size (㎛) 300~1,200 (Uniformity Coefficient 1.6↓)
Operating temp. (℃) 50↓
Ionic formH+ (H% 99%↑)
OH- (OH% 90%↑)H+ (H% 99%↑)
OH- (OH% 95%↑)H+ (H% 99%↑)
OH- (OH% 95%↑)
Mixed Ratio, Volume 45:55 45:55 40:60
Operating capacity (eq/ℓ)0.4↑ (Feed water :
Conductivity 150㎲/㎝Potable water, SV36)
0.5↑ (Feed water :Conductivity 150㎲/㎝Potable water, SV36)
0.5↑ (Feed water :Conductivity 10㎲/㎝
RO outlet, SV36)
Outlet conditionResistivity > 10.0MΩ·cm(Feed water : Tap water)
Resistivity > 10.0MΩ·cm(Feed water : Tap water)
Resistivity > 15.0MΩ·cm(Feed water : Post-RO)
※ The data for Specific gravity and Operating capacity is for reference.
Gradename
Feature & Application
Components Treated water quality
SM200
Simple production of pure water from tab water For Laboratories,Wire-cutting(EDM)
KC-08H(H+ 99.0%↑)KA-12OH(OH- 90.0%↑)
Mixed ratio(Volume) : 45:55
OutGuarantee) Resistivity > 10.0 MΩ·cm (in 10min.)
Actual) Resistivity > 15.0 MΩ·cm (in 10min.)
Feed Conductivity 150㎲/㎝ Potable water, SV36
SM210
Simple production of pure water from tab water For Laboratories,Wire-cutting(EDM)
SCR-BH(H+ 99.0%↑)SAR12OH(OH- 95.0%↑)
Mixed ratio(Volume) : 45:55
OutGuarantee) Resistivity > 10.0 MΩ·cm (in 10min.)
Actual) Resistivity > 15.0 MΩ·cm (in 10min.)
Feed Conductivity 150㎲/㎝ Potable water, SV36
SM300
High Resistivity andsuperb SiO2 removal ability MB for Post-RO and EDI
SCR-BH(H+ 99.0%↑)SAR12OH(OH- 95.0%↑)
Mixed ratio(Volume) : 40:60
OutGuarantee) Resistivity > 15.0 MΩ·cm (in 10min.)
Actual) Resistivity > 17.0 MΩ·cm (in 10min.)
Feed Conductivity 10㎲/㎝ RO outlet, SV36
UPRM100U(UPS)
Very high resistivity,Electronics GradeUltrapure water
UPRC100U(H+ 99.0%↑)UPRA100U(OH- 95.0%↑)
Mixed ratio(Capacity) : 50:50
OutGuarantee) Resistivity > 17.0 MΩ·cm (in 10min.)
Actual) Resistivity > 18.0 MΩ·cm (in 10min.)
Feed Conductivity 10㎲/㎝ RO outlet, SV36
UPRM200U(UPS)
Very high resistivity, Low ΔTOC level LCD, OLED Ultrapure water final polisher
UPRC200U(H+ 99.0%↑)UPRA200U(OH- 95.0%↑)
Mixed ratio(Capacity) : 50:50
OutResistivity >18.1㏁·㎝ (in 30min.)
△TOC < 5ppb (in 120min.)
Feed Resistivity > 17.5㏁·㎝, TOC < 2ppb, SV30
UPRM300U(UPS)
Extremely high resistivity Extremely, low ΔTOC level Metal ion < 0.1pptSemiconductor Ultrapure water final polisher
UPRC300U(H+ 99.9%↑)UPRA300U(OH- 97.0%↑)
Mixed ratio(Capacity) : 50:50
OutResistivity > 18.2㏁·㎝ (in 30min.)
△TOC < 1ppb (in 180min.)Metal ion < 0.1ppt
Feed Resistivity > 17.5㏁·㎝, TOC < 2ppb, SV30
Synthetic adsorbents
Type Styrene TypeChemically Modified
Styrene Type
Grade GSH-20 GSP-25 GSP-50 GSP-07
Chemical structure
CH2-CH-
-CH₂-CH-CH₂-CH-
CH₂-CH- Br
-CH₂-CH-CH₂-CH-
Specific surface area (㎡/g) 750↑ 1,100↑ 1,000↑ 600↑
Pore Volume (㎡/g) 1.0~1.5 1.2~1.6 0.9~1.1 0.8~1.0
Pore radius (Å) 50~80 45~55 30~50 50~70
Particle size (㎛) 315~1,250 250~700 250~700 250~700
Equivalent Diaion HP20 Diaion SP825 Diaion SP850 Diaion SP207
Applications
TRILITE GSH-20 Widely used in refining of pharmaceuticals and natural extracts, since these are suitable
for adsorbing large molecules because of their relatively large pore sizes and superior
adsorption/ desorption. GSH20 is widely used in various industrial applications, especially
adsorption, desalting and Decolorization of natural products and small proteins.
TRILITE GSP-25, These have much larger surface area and a narrower, more uniform pore-size distribution
TRILITE GSP-50 than GSH-20. They offer nearly one and half times the surface area of GSH-20. With large
surface area and narrower pore radius, it selectively adsorbs small molecules and excludes
larger molecules. This grade is recommended for adsorption, desalting and decolorization.
TRILITE GSP-07 With high hydrophobicity, TRILITE GSP-07 has higher selectivity for non-polar molecules
than standard aromatic adsorbents, due to its chemically bonded bromine to the aromatic
rings. It is suitable for upward flow and batch processes due to its high specific gravity but
also for treatment of heavy liquid such as purification of hydrogen peroxide in electric and
electronic industry.
40 41Ion Exchange Resins Product List Ion Exchange Resins Product List
EO/EG Cycle Water TreatmentInert resins
Anion resins for Layered Bed
Inert resins are non-fuctionalized polymers developed for use as an upper layer in packed bed system, and also
used to enhance separation of catoin and anion exchange resins prior to regeneration in Triobed system.
Type Inert resins
Grade TR70 TR30
Matrix Polyethylene Polystyrene+DVB
Functional group None
Shipping weight (g/ℓ) 500 725
Particle size (㎛) 1,200~1,800 700~900
Operating temp. (℃) 90↓ 100↓
Remarks
The specific gravity islower than that of
water, it locates as top layer with in an IER tower, keeping the
layers compact, preventing any loss of active finer resins and improving the
regenerant distributionefficiency.
The specific gravity lies in the middle of that of cation resins
and anion resin. It forms a borderbetween them.
It eases separation of cation and anion resins, preventing
any counter regeneration hence improving the purity
of treated water.
NaOH
TRILITE TR70
IER
Freeboard
Regenerant
Service
Middle distributor
SAC
SBA
HCl
Packed bed Triobed
Freeboard
TRILITETR30
A layered bed water treatment system allows economical production of pure water through simultaneous
employment of Strongly Basic Anion(SBA) and Weakly Basic Anion(WBA) resins for an anion exchanger. Successive
regeneration of WBA resin with regeneration waste water of SBA resin enables high regeneration efficiency and ability
to cope with the change of raw water with a good resistance to organic fouling of resins.
TypeLayered bed anion resins
WBA SBA
Grade AW90LB KA18LB
MatrixPolystyrene+DVB
(Porous type)Polystyrene+DVB
(Gel type 1)
Functional group Tertiary Amine-N+(CH3)3
(TMA, Trimethyl-ammonium)
Ionic form Free Base Cl-
Specific gravity 1.04 1.11
Shipping weight (g/ℓ) 640 675
Moisture retention (%) 40~50 43∼47
Total capacity (eq/ℓ) 1.6↑ 1.3↑
Uniformity coefficient 1.1↓ 1.4↓
Particle size (㎛) 550±50 600~1,200
Operating temp. (℃) 60↓60↓ (OH- type)80↓ (Cl- type)
Operating pH range 0~9 0∼14
Swelling rate(FB → Cl-, Cl- → OH-)
20% 24%
Layered bed
Service
TRILITE KA18LB
TRILITE AW90LB
Freeboard
Regenerant
TRILITE KA18LB
TRILITE AW90LB
Freeboard
AW90LB
KA18LB
※ The data for Specific gravity/ Shipping weight/ Swelling rate is for reference.
※ The data for Shipping weight is for reference.
EO/EG
cycle water
EO(Ethylene oxide)/EG(Ethylene glycol) cycle water treatment is essential for MEG(Mono-ethylene glycol)
prodution. There occurs various types of impurities during the process, so the combination of several special
resins are being applied to remove them.
- Metal ion removal : Catalyst resin - SPC260EGH
- Aldehyde removal : Aldehyde removal resin(ARR) - AMP16EG
- Other organic acid removal : Weak base anion(WBA) resin - AW90EG
TypeEO/EG Cycle Water Treatment
SAC SBA WBA
Grade SPC260EGH AMP16EG AW90EG
MatrixPolystyrene+DVB
(Porous type)Polystyrene+DVB
(Porous type)Polystyrene+DVB
(Porous type)
Functional group -SO3-(Sulfonate)
-N+(CH3)3 (TMA, Trimethylammonium)
Tertiary Amine
Ionic form H+ Cl- Free Base
Shipping weight (g/ℓ) 800 685 640
Moisture retention (%) 50~58 49∼55 40~50
Total capacity (eq/ℓ) 1.75↑ 1.2↑ 1.6↑
Effective size (㎛) 400↑ 400↑ UPS
Uniformity coefficient 1.6↓ 1.6↓ 1.1↓
Particle size (㎛) 300~1,200 550±50
Operating temp. (℃) 120↓ 70↓ (OH- type)90↓ (Cl- type)
60↓
Operating pH range 0∼14 0∼14 0~9
※ The data for Shipping weight is for reference.
Ethylene+
O2
EO(Ethylene Oxide)
Stripping column
ScrubberGlycol
adsorption column
Evaporator
Dry column
MEG(Mono-ethylene
glycol)SAC WBASBAVacuum
degasifier
Sodium acetate
CO2
HCOOH
CH3COOH
Impurities in cycle water
ARRAldehyde
Removal Resin
Cationexchanger
Anionexchanger
With Silver Oxideas catalyst
NaOH(pH adjustme)
MEG process
42 43Ion Exchange Resins Product List Ion Exchange Resins Product List
COA (from DB)
Quality Assurance System (Self-manufacturing/OEM)
TRILITE Ion Exchange Resins assure strict quality management under ISO9001 Quality Assurance System.
TRILITE OEM products are being produced under the same quality assurance system, and through the pre-
shipment & on-arrival sample test, Samyang assures the trustworthy quality of the products.
Sampling
Customer
ISO9001
Shipping COA (from DB) Packing
Process Analysis
Keeping samples(for 4years)
Producthopper
DB
Y N
Periodical analysis
Osmotic shock stability Friability
Optional analysis
H/OH Conversion rate ResistivityΔTOC
Basic analysis
Bulk density Moisture retention Particle distributionExchange capacity Whole bead count
충전 역세 정치
눈금을 읽음
Qualitytest
Customer
Packing
① Production order
⑤ Product inspection
③ Product analysis
OEM Plant A OEM Plant B
1 2
Purchasing TRILITE means more than just a stable supply of high quality products . Our technical sales team
is subdivided into three specialized groups, and provides professional Total solutions as per the various
applications requested by customers. And, also Samyang IER Tech-center located in Daejeon provides analysis
service of resins with state-of-the-art facilities and other Pilot tests upon requests.
.exe
Kor/Chn/EngVersion Download
Samyang IER Tech-center located in Daejoen
provides resin analysis service for used resins and
resins for replacement . Multiperspective analysis
examines various fouling and performance of resins
for the most efficienct operation of facilities.
Ion exchange resin analysis
Samyang TriAngleTM is calculation software designing
water treatment system with ion exchange resins . User
friendly interface of the program supports economic
design of required resin quantity for the towers , as per
the various applications.
QR code scan or www.samyangtrilite.com
Ion exchange resin design program TriAngleTM
Samyang's professional engineers provide facility
diagnosis and optimised retofit proposals along with
trouble shooting guidelines for the problematic facility.
Facility diagnosisand retrofit proposalt
Samyang provides process development service for
various applications of IERs, including Lab. Test and
Pilot test.
Customised process developmentservices using various IERs
Analysis report
Applying for sample analysis
IER Analysis
ProcessConduct of analysis
Receiving of request
with sample
Inquiry to | Samyang Corporation | Ion Exchange Resin Team
· TEL : 02 740 7732~7 · E-mail : [email protected] · http://www.samyangtrilite.com
3 4
Technical Services
Performance
Economy
Basic
Shipback
Shipment
DB
Ulsan plant (UPW/Tailored/Specialty)
Seoul (HQ)
• Recipe supply
• Specification control
• Technical data analysis
• Product analysis
• Final product inspection
• Repacking & Shipping
• OEM contract• Production scheduling• Import processing
Process analysis
N
Y
Qualitytest
Qualitytest
N
Y
② Productio completion & sending samples by batch
④ Packing & shipping order
• Basic analysis
• Optional analysis
• Periodical analysis
Trucking, Shipping
Daejeon (Tech-center)
44 45Ion Exchange Resins Product List Ion Exchange Resins Product List 45Ion Exchange Resins Product List
1. Handling
Protective equipment must be used to protect eyes and skin, and resins must be handled in a place with good
ventilation. Eye-wash facilities are recommended at the work spot. When resins are spilled on the floor, they
are very slippery and may cause a person to fall. Avoid exposure to high temperature, sparks, flames, etc. Also,
avoid contact or mixing with oxidizing agents such as nitric acid because ion exchange resins can explode on
contact with nitric acid.
2. Storage
Resins should be stored in dry, cool and dark places where proper ventilation system is installed. The storage
container and bag of fiber drum should be tightly closed to prevent intrusion of impurities and drying of resins.
Do not store resins near oxidizing agents. At high temperature, rapid degradation of resins may occur, and
below 0℃, freezing of resins may occur which may cause physical breakage.
Factors affecting quality of resins in storage
Humidity
The ion exchange resin consists of about 50% water. When the dried resin comes in contact with moisture
again, the resins may crack due to osmotic shock.
Freeze and Defrost
Sudden freezing and defrosting of resins can take place and this may have a physical effect on the ion
exchange resin.
(Note: Freezing and defrosting should be avoided especially for Porous type.)
Abrupt temperature change
Sudden temperature changes can cause cracks on the surface of the ion exchange resin and cause
physical deterioration.
Physical shock
Over loading of resins on pallet for transport and storage should be avoided. Care should be taken as ion
exchange resins are susceptible to physical shock.
3. Disposal
Unused resins may be discarded in the landfill or by incineration following local regulations and the cautions
mentioned above. A suitable fitted furnace is necessary for incineration because SOX, NOX, COX and others will
be generated from the incineration.
Used resins may also be land-filled or incinerated as long as they contain no toxic or poisonous material such
as heavy metals. Resin can only be discarded, as above, after removal of poisonous material.
● The contents in this catalog might be changed without previous notice. March 2019 Edition
Cautions on Use of Ion Exchange ResinsQuality Certificates
Packing & Container Loading
TRILITE Ion Exchange Resins are supplied in various types of packaging, 25ℓ PE bag, 1,000ℓ bag (supersack),
5~7ft3 fiber drums and others to ensure customer preference when handling resins. Systematic manuals for
shipment and container loading assure minimization of any probable damage to products while transporting.
The work footages are shared with customers in real-time for customer satisfaction.
25ℓ PE bag1,000ℓ Ton bag
50ℓ Plastic drum
5 or 7ft3
Fiber Drum5ℓ
Vacuum Packing
Palletizing, Container Loading (1000ℓ)
Automatic Packing Manual Packing
HALAL Certificate
MUI JAKIMKMF
ISO9001 Certificate Veritas Certificate
Palletizing, Container Loading (25ℓ)
※ Bureau Ver i tas ( f rance) i s an institution which has the world wide experience and expertise to take on the quality certification of ion exchange resins for power plant applications.
TRILITE is being audited regularly to maintain ISO9001 Quality Assurance System and also being carried on
improvement of its QA & QC proceses. TRILITE is granted for its qualification in accordance with international
certificate authorities, Halal for Islamic countries and Veritas for power plants.
Contact us from your
mobile with messengers
WhatsApp+82 10-2790-4819
LineID : TRILITE
Kakao talkID : TRILITE
We chatID : TRILITEor Scan QR-code
Samyang Corporation Ion Exchange Resin Team
31, Jong-ro 33-gil, Jongno-gu, Seoul, Korea
TEL : +82 2 740 7732~7
E-mail : [email protected]
http://www.samyangtrilite.com