Introduction of Liquid Organic Hydrogen Carrier and the ... · Introduction of Liquid Organic...
Transcript of Introduction of Liquid Organic Hydrogen Carrier and the ... · Introduction of Liquid Organic...
Introduction of Liquid Organic Hydrogen Carrier
and the Global Hydrogen Supply Chain Project
Daisuke Kurosaki
Chiyoda Corporation
Advanced Hydrogen Energy Chain Association for Technology Development (AHEAD)
12th September 2018
SPERA derives from the Latin word for “hope”. We at Chiyoda Corporation chose the name to represent our desire that hydrogen technology will give people around the world the hope they need to build a better future.
1
INDEX
I. Chiyoda’s Hydrogen Technology & Projects
II. The Global H2 Supply Chain Project
I. Chiyoda’s Hydrogen Technology & Projects
Hydrogen Storage & Transportation Technology
• Chiyoda has established an efficient and large scale hydrogen storage and
transportation system.
• Methylcyclohexane (MCH), Liquid Organic Hydrogen Carrier (LOHC), stays in liquid
state under ambient temperature and pressure anywhere.
3
DHGHGN
Petro Refining,Chemicals
FEEDSTOCK
H2 H2Hydrogenation De-hydrogenation
StorageStorage
Electrolysis
Renewable Energy
Steel MillsCO2 Recycle(Reverse Shift)
+3H2
CH3CH3
TOL MCH
Power Gen.City Gas, Mobility
ENERGY
MCH
TOL
CCS
Hydrocarbon
By-ProductReforming
GasificationCCU
HGN: hydrogenation, DHG: dehydrogenationTOL: toluene, MCH: Methylcyclohexane
Oil, Gas, Coal
CO2
Solar, Wind, Hydro, etc.
Key Technology is New Catalyst of Dehydrogenation.
LOHC Technology
4
Long term storage & long distance
transport
Easy to handle
Use of existing oil
infrastructure
Chemically stableVery minor loss by long term storage & long distance transport
Liquid under ambient temperature & pressure
Conventional Oil & Chemicals Infrastructure can beUsed for storage & transportation.
Combination of Proven technologies
Combination of conventional equipmentexcept for new catalyst for dehydrogenation.
Reduced risk of H2 storage &
transport
Hydrogen gas is converted tochemical liquid.
5
通油時間 (hr)
MC
H転化率
(%)
2000 4000 6000 8000 1000000
10
20
30
40
50
60
70
80
90100
原料: 工業製品MCH(純度:99.85%)
触媒性能転化率 : 95.0%以上選択率 : 99.9%以上触媒寿命 : 連続8,000時間以上水素発生速度 : 1NL/cc-cat/hr
Time on stream
MC
H C
on
ver
sion
(%
)
Catalyst performance
MCH Conversion : >95% Toluene Selectivity : >99.9% H2 Yield : >95%
H2 generation rate : > 1,000 Nm3-H2/h/m3-cat. (1,000 Ncc-H2/h/cc-cat.)
Catalyst life : > 8,000 (1year)
Catalyst: S(0.8%)-Pt(1.0%)/Al2O3
Temp. : 345→351℃Press. : 0.3MPa
LHSV : 2.0h-1
Feed : Methylcycrohexane
(purity : 99.85%)
S-Pt/Al2O3
LOHC Technology - lab test
・Catalyst developed by Chiyoda
・Life longer than 1 year was
confirmed by lab test – longer life
possible
6
Process Plant Storage Tank
H2
MCH
MCH
TOLTank
MCH
Dehydrogenation
TOL
MCH
50Nm3/h
TOL
TOL
Hydrogenation
LOHC Technology - demo plant
• After lab tests, another 10,000hr of demo plant operation was successfully
completed.
• Expected performance was confirmed.
Hydrogen Demonstration Projects
7
8
Chiyoda and its partners established the Advanced Hydrogen Energy Chain Association for Technology Development (AHEAD), and started the world’s first global hydrogen supply chain demonstration project toward 2020.
Brunei
Darussalam
Kawasaki
City, Japan
1. Global Hydrogen Supply Chain Demonstration
2. Power to X Technology
Demonstration project to produce hydrogen by variable renewable energy, funded by the
New Energy and Industrial Technology Development Organization (NEDO)
9
TOL
MCH*HGN*
TOL
MCH De HGN**
Existing
demo plant
MCH***
TOL****
H2
electricity
Heat
Solid Oxide Fuel Cell
Heat Exchange
Purification
New
laboratory
test
New
demo
plant
Electro-lyser
Rectifier
Purifi-cation
Electricity
H2
Variable outputof wind power
(simulated)HGN* : hydrogenation
DeHGN**:Dehydrogenation,
MCH***: Methylcyclohexane
TOL****: Toluene
Location : Chiyoda Koyasu Office & Research Park (Yokohama - city)
3. Hydrogen Fueling Station Technology
Develop compact-type dehydrogenation facility (downsizing and automatic operation) in
order to fit for FCV fuel stations, funded by NEDO.
10Location : Chiyoda Koyasu Office and Research Park (Yokohama - city)
MCH Large
Storage
Tanks
Storage Tank
(underground)
Dehydrogenation
Reactor
Compressor
MCH
Tanker
lorry
Fuel
Dispenser
Pressure
Reservoir
Dehydrogenation facility downsized
Hydrogen
Purification
UnitFCV, FC
Fork LiftHydrogen Fueling Station
II. Global H2 Supply Chain Project
PROJECT OVERVIEW
LNG Plant(BLNG)
MCH
ProcessedGas Hydrogenation
Plant
TOL
ContainerYard
ContainerYard
Power Generation
(Kawasaki)
TOL
MCH
TOL
MCH
ContainerVessel
Brunei
Japan
ISO ContainerLand Transport
MCH : Methyl cyclohexane, TOL : Toluene
De-Hydrogenation
Plant
ISO Container Land Transport
SPARKIndustrial Park
LUMUT
KAWASAKI
[Plant Scale] 300 Nm3/h – H2 (Plant Capacity)
[Transport] ISO Tank Container (5 Containers / week)
HydrogenGas
MUARA
KAWASAKI
Gas Liquid
12
1. Brunei
1) GEOGRAPHICAL LOCATION
• Hydrogen production / hydrogenation plant will be located at SPARK, and hydrogen will be transported on land using ISO tank containers (in form of MCH) to Muara Port for shipping.
SPARK
Muara Port
ISO lorry
Hydrogenation Storage & Shipping
To Japan
13
1. Brunei
2) HYDROGENATION PLANT (IMAGE)
Hydrogenation plant will consist of Hydrogenation unit, H2 production unit, utility & offsite facilities, administration/control building and ISO tanks area.
14
1. Brunei
3) GROUND BREAKING CEREMONY
15
• Ground breaking ceremony was hold on April 21, 2018, and the guest of honor was Deputy Minister of Ministry of Energy and Industry, together with 150 other guests.
1. Brunei
4) CONSTRUCTION WORK (as of July 2018)
16
• Construction started in April 2018, and foundation/building work is ongoing.
2. Kawasaki
1) GEOGRAPHYICAL LOCATIONThe site of dehydrogenation will be located at Keihin Industrial Zone in Kawasaki, and ISO tank containers from Brunei Darussalam will arrive at Kawasaki Port.
17
Tokyo International Airport(Haneda)
Tokyo
Kawasaki
Yokohama
Kawasaki PortContainer Terminal
Keihin Industrial Zone
2. Kawasaki
2) H2 SUPPLY INFRASTRUCTURE
Dehydrogenation Plant will be located inside TOA OIL's Keihin Refinery, and extracted hydrogen gas will be transported to existing power generation by pipeline.
18
[ Keihin Waterfront District ]
[ Cooperation with TOA OIL ]
Land in TOA OIL’s refinery
Utility supply to Dehydrogenation plant
Operation of Dehydrogenation plant
ISO TankContainer Trailer
TOA OIL (Zone - F)• Dehydrogenation plant• MCH /TOL storage tank• Loading/unloading facility
EXISTING POWER PLANT• Output 79,300kW• Fuel Refinery gas• Type Gas Turbine
2. Kawasaki
3) DEHYDROGENATION PLANT (IMAGE)
• Dehydrogenation plant will consists of Process unit, MCH/TOL storage tanks, administration/control building and loading/unloading facility.
19
2. Kawasaki
4)PROJECT SCHEDULE
Construction will begin from October 2018, and Hydrogen Supply Chain will operate between Brunei and Japan in 2020.
2017 2018 2019 2020
Engineering & Procurement
AHEAD
Establishment(Jul)
Construction
Comm. Operation
Site Prep
Tokyo
Olympic(Jul-Aug)
Opening
Ceremony(Dec)
Grand
Breaking in
Kawasaki city(Oct)
20
ADVANCED HYDROGEN ENERGY CHAIN ASSOCIATION
FOR TECHNOLOTY DEVELOPMENT
© Chiyoda Corporation 2018, All Rights Reserved.
© Advanced Hydrogen Energy chain Association for technology Development 2018, All Rights Reserved.
Thank you !
21