Introduction & Atomic Structure, Molecular Structure and Bonding.
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Transcript of Introduction & Atomic Structure, Molecular Structure and Bonding.
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Introduction&
Atomic Structure, Molecular Structure and Bonding
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Organic Chemistry: IntroductionWhat Is Chemistry? Chemistry Is The Study Of Matter & The Changes It Undergoes
Two Main “Branches” of Chemistry
Organic Chemistry
Inorganic Chemistry
• Term Coined by Berzelius ~ 1807
• Matter Derived From Living Things
• Study of Carbon Compounds (C,H,N,O)
• Matter Derived From Nonliving Things
• Vast Majority of the Periodic Table
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Influence of Organic Chemistry
Organic Chemistry Is Important to Medicine: Ancient and Modern
• Plant Extracts as Medicines…Active Ingredients are Organic Compounds
• Prescription Drugs….Prepared by “Synthetic Chemists”
Organic Chemistry and Dyes:
• 1st Solid Link of Industry and Research
• $$ Derived From Research
Organic Chemistry and Materials Development:
• Synthetic Fibers….Nylon
• Synthetic Rubber….Neoprene
• Chemistry of Polymers (Plastics)
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Organic Chemistry and You?
Redox ReactionsAlcoholsAldehydesKetones Alkanes/alkenes
EthersCarboxylic acids
ConcentrationRedox ReactionsSpectrometry
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In this unit, we will review…
1. Atomic Structure2. Lewis Dot Structures and Formal Charge3. Ionic and Covalent Bonds4. Electronegativity and Polarity5. Molecular Geometry6. Multiple Bonds
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Modern Atomic Theory
Atoms have an internal structure consisting of one or more subatomic particles:
proton positive chargemass = 1.673 x 10-27 kg
neutron no chargemass = 1.675 x 10-27 kg
electron negative chargemass = 9.109 x 10-31 kg
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Most of the mass of an atom is concentrated in the nucleus, which contains one or more positively charged protons and neutrons with no electrical charge.
proton
neutron
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One or more negatively charged electrons are in constant motion outside the nucleus.
What is the overall electrical charge if the number of electrons equals the number of protons?
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Valence and Core Electrons
Electrons contained in the outermost shell are called ________electrons.
All other electrons are called ______ electrons.
e-
e-
e-e-
e-
How many valence electrons does this atom have? Core electrons? Which number matters more?
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How many valence electrons (ve-’s) does carbon have? Calcium? What element is depicted in the image on the right?
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Chemical Bonding
Chemical bonds are the forces that hold atoms together in compounds. We use Lewis Dot structures to represent these atoms and compounds.
C O OC
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Drawing Lewis Dot Structures
1. Count total ve-’s available2. Draw a Lewis sketch
– H is never central; C is often central3. Draw in electrons to fulfill octet and duet rules
– C “likes” 8 electrons; H “likes” 2 electrons4. Count ve-’s and compare to #25. If too many e-’s, make a double bond6. Calculate formal charge (FC) to double check structure
– No or low FCs (e.g. +1) more likely than large FCs (e.g. +2)
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Example
NH3
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Formal Charge
Formal charge = ve-’s – (lone pairs + bonds)
In a neutral molecule, the sum of the FCs = zero. For an ion, the sum of the FCs = the charge of the ion.
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Formal Charge –the easy way!1. Circle the atom of interest.2. Count the electrons inside the circle. If the circle
“breaks” a bond, only count one electron of the bond.3. Take the ve-’s for the atom (its group number) and
subtract #2.
O OCFC of oxygen= 6 – (6) = 0
FC of carbon= 4 – (4) = 0
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Resonance StructuresResonance structures result when more than
one valid Lewis dot structure can be drawn for one molecule. – The positions of the nuclei can’t change (C, H, etc.)– The positions of multiple bonds or lone pairs can
move– Low FCs are still favored
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CH O
O
CH O
O
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Computing Formal Charges“Normal” covalent bonding patterns:
C
C
C
C
Carbon Nitrogen
N
N
N
Oxygen
O
O
Halogens
X
Four bondsNo lone pairs
Three bondsOne lone pair
Two bondsTwo lone pairs
One bondThree lone pairs
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Computing Formal ChargesCommon structures with formal charges:
C
C
Carbon Nitrogen
N
N
N
Oxygen
O
O
Halogens
X
N
N
N
O
2
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Ionic versus CovalentBonds formed by the transfer of electrons from one atom to
another are __________.
Example:Sodium chloride (NaCl)
Na Na+ + e-
Cl + e- Cl- __Na + Cl NaCl
+ + + +
+ + + +
+ + + +
_ _ _
_ _ _
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Bonds formed by the sharing of electrons between two atoms are __________.
Example:Glucose (C6H12O6)
CH
O
CH2OH
H
OH
H
H
OH
H
OH
OH
CHO
OHH
HHO
OHH
OHH
CH2OH
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Polar Covalent Bonds
Polar bonds are bonds between atoms created by sharing electrons unevenly.
H F
F F
Uneven sharing is the result of electron “greedy” atoms (i.e. more electronegative atoms).
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ElectronegativityElectronegativity is a measure of the tendency of an
atom to attract a bonding pair of electrons.
Electronegativity differences result in polar covalent bonds.
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Polar Covalent MoleculesA polar molecule is a molecule that is electrically
asymmetrical, resulting in charges at two points. The molecule is said to have a molecular dipole or dipole moment.
H Cl OH H
O
CH3C CH3
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Polar Covalent Molecules
Not all molecules that contain polar bonds will be polar molecules!
O C O
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Molecular GeometryCommon geometries:
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C
C
C
O
H
HHHH
H
Acetone C3H6O
Is acetone ionic or covalent?What its geometry?
PQ
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Atomic orbitals (AOs)are the probability distribution about one atomic nucleus(found using wave functions ψ)
AOs relate to quantum numbers (n, l, ml, ms)
Each AO can have, at most, two e- (Pauli Exclusion Principle)
AOs are filled with e-’s from the lowest energy to the highest (Aufbau Principle)
The electron configuration with the highest number of unpaired spin is more stable (Hund’s rule)
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AtomElectronicStructure
ElectronicConfiguration
Lewis DotStructure
Boron
Phosphorus
1s22s22p1
[Ne] 3s23p3
3p
3s
2p
2s
1s
3p
3s
2p
2s
1s
B
P
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CarbonAtomic Number = 6
2p
2s
1s
Atomic Number = 6
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Hybridized Orbitals5
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Hybridized OrbitalsWhen carbon double bonds, the 2s, 2px and 2py orbitals on
carbon form three sp2 hybrid orbitals.
C
A trigonal planar atom has sp2 hybridization.
The three hybrid orbitals form the points of a triangle.
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Double Bonds
C C
H
H
H
H
The three sp2 hybrid orbitals of carbon and 1s orbitals of hydrogen make up the σ-framework of ethene.
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Double Bonds
When the double bond is formed between the two carbons of ethene, a different type of bond is needed (a π bond). This bond is formed with the remaining 2pz orbitals and is higher energy than the σ bonds.
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