Installation Name & Address For inspection purposes only. · ISO 17025 Accreditation Number: 1668...

ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279

Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

Exova Catalyst Ireland, Unit D8 North City Business Park, North Road, Finglas, Dublin 11E: [email protected]

Your Exova Catalyst Ireland Contact: Patrick O'Brien (+353 86 416 1434)

Co MonaghanCastleblayney

Kingspan Insulation Ltd


A2-14 RTO Outlet

MM 13 1259

Stack Reference

Irish EPA IE Licence: P0057-03

Signature of Report Approver

Version 1

Team Leader

MCERTS Level 2

Donal O Faogain

Report Approved by

Deputy Regional Manager

TE1 TE2 TE3 TE4

MM 10 1074MCERTS Level 2

13th June 2018Report Date

TE1 TE2 TE3 TE4

Report Written by

John Glennon

Stack Emissions Testing Report Commissioned by

15th - 16th May 2018

Job Reference Number

CDU-1018

Installation Name & Address

Dates of the Monitoring Campaign

Version

CAT-RT (Version BV)

CDU-1018-Kingspan A2-14 Report

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EPA Export 18-08-2018:04:04:18

TITLE PAGE

CONTENTS

Summary of Sampling Deviations

EXECUTIVE SUMMARY

Monitoring Objectives

Monitoring Results

Monitoring Dates & Times

Process Details

Monitoring & Analytical Methods

Sampling Location

Plant Photos / Sample Points

APPENDIX 1 - Monitoring Personnel & List of Equipment

APPENDIX 2 - Raw Data, Sampling Equations & Charts

The testing performed fully meets the technical requirements in Irish EPA

Guidance Note, AG2.

Opinions and interpretations expressed herein are outside the scope of

Exova Catalyst Ireland's ISO 17025 accreditation.

This test report shall not be reproduced, except in full, without the

written approval of Exova Catalyst Ireland.

9

3

5

6

8

4

2

7

CONTENTS

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Job Number: CDU-1018, Version 1

Sample Date/s: 15th - 16th May 2018


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Overall Aim of the Monitoring Campaign

Special Requirements

Target Parameters

Exova Catalyst Ireland were commissioned by Kingspan Insulation Ltd to carry out stack emissions testing on the A2-14 RTO Outlet

at Castleblayney.

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in the

Site's Permit.

There were no special requirements.

Dioxins & Furans, Hydrogen Chloride, Hydrogen Fluoride, Organics Class I , Organics Class II , Formaldehyde , Total VOCs (as

Carbon), Oxides of Nitrogen (as NO₂), Sulphur Dioxide, Carbon Monoxide

MONITORING OBJECTIVES

Executive Summary

A2-14 RTO Outlet

15th - 16th May 2018

Kingspan Insulation Ltd, Castleblayney

(Page 1 of 7)

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EPA Export 18-08-2018:04:04:18

where MU = Measurement Uncertainty associated with the Result

Parameter

Dioxins & Furans (NATO I-TEQ) Dioxins & Furans ¹

Dioxins & Furans (WHO TEQ Humans / Mammals) ¹

Dioxins & Furans (WHO TEQ Fish) ¹

Dioxins & Furans (WHO TEQ Birds) ¹

Dioxins & Furans (NATO I-TEQ) ¹

Dioxins & Furans (WHO TEQ Humans / Mammals) ¹

Dioxins & Furans (WHO TEQ Fish) ¹

Dioxins & Furans (WHO TEQ Birds) ¹

Hydrogen Chloride ¹ - -

Hydrogen Fluoride ¹ < <

Organics Class I ¹ < <

Organics Class II ¹ < <

Formaldehyde ¹ < <

Total VOCs (as Carbon) ¹ - -

Oxides of Nitrogen (as NO₂) ¹ - -

Sulphur Dioxide ¹ - -

Carbon Monoxide ¹ - -

Carbon Dioxide Dry

Oxygen Dry

Water Vapour

Stack Gas Temperature

Stack Gas Velocity

¹

- -

NOTE: VOLUMETRIC FLOW RATE & VELOCITY DATA TAKEN FROM AN AVERAGE OF ALL OF THE ISOKINETIC RUNS.

¹ Reference Conditions (REF) are: 273K, 101.3kPa, dry gas.

mg/m³ 0.04 -

-

8000

8.60 16.8

6.436

0.24

1.17

6.305.28mg/m³ 1001.20

100 g/hr 167.7 34.9 500

mg/m³

-

g/hr

µg/hr


15th - 16th May 2018

+/-

0.0005

0.0021

Units Result

0.0004

Concentration

-

0.01 0.002

0.0005

-

MU

0.010.0021

0.022

MU

ng/m³

ng/m³

ng/m³

0.0004

0.01

0.0022 0.1

Units

µg/hr

-

ng/m³

0.0022ng/m³

0.0009

0.0026 -

0.002

-

Dioxins & Furans Upper Limit (worst case where <LOD = LOD)

Dioxins & Furans Lower Limit (best case where <LOD = 0)

0.032

-

0.0005

µg/hr

0.0043

mg/m³

12.02

-

Executive Summary

-

0.012 0.002

Mass Emission

- µg/hr

MONITORING RESULTS

µg/hr

A2-14 RTO Outlet

µg/hr

0.0004

Result Limit

-µg/hr

-

0.0026

ng/m³ 0.003

µg/hr

Limit

+/-

30

0.005

0.02 0.005

ng/m³

0.012 0.002 -

0.014 0.003

-

-

63.00.78 g/hr

0.4g/hr

5.21

0.0040.07

-

mg/m³ 65.9 10012.57 2.51 13.620

mg/m³ 32.00 6.46

0.01 4 0.043

m³/hr

20.46

268

g/hr

(Page 2 of 7)

1.23 300

4.60

g/hr

-

0.46

Volumetric Flow Rate (REF)

3.21 200

% v/v

mg/m³ 1.64

24.1

g/hr

% v/v

Volumetric Flow Rate (ACTUAL)

3.86

27.7

mg/m³

m³/hr

0.24

5240

0.55

10.3m/s

0.35

36.8

% v/v

7.428

6450

°C

-

329

-

-

-

0.0042 0.0009ng/m³

0.2

mg/m³ 2.69650 g/hr

6.11

g/hr

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EPA Export 18-08-2018:04:04:18

Parameter

(NATO) R1 - -

R1 - -

R1 < <

R1 < <

R1 < <

R1 < <

R1 - -

R1 - -

R1 - -

R1 - -

R1 -

R1 -

R1

All results are expressed at the respective reference conditions.

mg/m³

13:10 - 13:40

Date(s)

Mass Emission

12.0

Dioxins & Furans

167.7

Formaldehyde g/hr 15/05/2018 300.040

Velocity Traverse 15/05/2018 10:45 - 10:50

Sampling

Times

Units


Duration

0.012ng/m³ µg/hr

mg/m³ g/hr

A2-14 RTO Outlet

15th - 16th May 2018

Executive Summary

g/hr

11:18 - 11:48

09:10 - 09:40

g/hr

MONITORING DATE(S) & TIMES

0.002

mins

15/05/2018

(Page 3 of 7)

32.00

mg/m³ 15/05/201865.9

Total VOCs (as Carbon)

30

Organics Class II

g/hr

SamplingConcentration

30

10:57 - 16:57

Units

0.36

30

360

Hydrogen Chloride 16/05/201863.0

mg/m³ 15/05/2018Hydrogen Fluoride

mg/m³

0.069

g/hr12.57Organics Class I 12:30 - 13:00 30

15/05/2018 30

0.21 13:55 - 14:25

15/05/2018

20.46

24.1

g/hr

mg/m³ g/hr

4.60

1.64

30

8.60

15/05/2018

15/05/2018Oxides of Nitrogen (as NO₂) 30

30

15/05/2018Sulphur Dioxide

% v/v

301.20

15/05/2018mg/m³Carbon Monoxide 6.11

g/hr

Carbon Dioxide

6.30mg/m³

16:20 - 16:50

16:20 - 16:50

16:20 - 16:50mg/m³

1.17

16:20 - 16:50

% v/v

Oxygen

16:20 - 16:50

3.86

15/05/2018

3016:20 - 16:50

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EPA Export 18-08-2018:04:04:18

Standard Operating Conditions

Parameter

Extracted Air and LPG

White - Visible

Full Production

Value

Process Status

A2-14 RTO Outlet

15th - 16th May 2018

Fuel

Feedstock (if applicable)

PROCESS DETAILS


(Page 4 of 7)

Running

Continuous

Regenerative Thermal Oxidising Unit

Abatement System

Abatement System Running Status

Plume Appearance

Thermal Oxidiser

Executive Summary

Capacity (of 100%) and Tonnes / Hour

Continuous or Batch Process

N/A

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EPA Export 18-08-2018:04:04:18

0.0003 ng/m³

CAT-TP-10 Yes YesYes CAT

GC/MS

GC/MSOrganics Class II CEN/TS 13649

HPLC Yes

CAT

CAT-TP-16

NDIR by Horiba PG-250

Yes

Yes

0.62 mg/m³

CAT-TP-41

CAT

NDIR by Horiba PG-250

NDIR by Horiba PG-250Sulphur Dioxide

Carbon Monoxide

ISO 12039

CAT-TP-21

0.14 %CAT-TP-21 Yes

EN 12619:2013

CAT 1.64 mg/m³

CAT-TP-21

Yes

Yes

0.1 %

RPS Laboratories Ltd (RPS)

Marchwood Scientific Services Ltd (MAR)

CAT-TP-20

CAT Yes

1.11 mg/m³

Oxygen

ISO 17025 Accreditation Number: 4279


SUMMARY OF SAMPLING DEVIATIONS

(with short name reference as appears in the table above)

Exova Catalyst (CAT)

CAT-TP-05

Yes

CAT-TP-21

Velocity & Vol. Flow Rate

Yes

Yes

Deviation

Oxides of Nitrogen (as NO₂)

Parameter

1One out of two sampling lines was used due to sampling location restrictions, however the number of sample points used

on the available line were increased to the minimum required by the Standard

Pitot Tube and Thermocouple

ANALYSIS LABORATORIES

CAT

TGN M21

CAT-TP-05

Yes

0.1 % v/vYesEN 14790

Chemiluminescence by Horiba PG-250

Yes

EN 14792

EN 16911-1 (MID)

Yes

EN 14789

Carbon Dioxide

Yes

Dry Zirconia Cell by Horiba PG-250CAT


Yes

0.04 mg/m³

Yes CAT

Yes 1.2 m/s


CAT

CEN/TS 13649 CAT A40

GravimetricWater Vapour

EN 15058

Flame Ionisation Detection by Sick 3006 FID

Yes

CAT 0.32 mg/m³

RPS

Yes

Yes

Yes

Formaldehyde Yes

CEN/TS 13649

CAT-TP-16 Yes CAT

12.57 mg/m³Yes

0.052 mg/m³

CAT-TP-16 Yes

RPS

Hydrogen Fluoride

GC/MS

0.069 mg/m³IC

32.004 mg/m³

CAT CLSOrganics Class I

Yes

Dioxins & Furans

GC/MS

GC-HRMSYes

CAT Yes

ISO

Executive Summary

A2-14 RTO Outlet

ISO

Hydrogen Chloride EN 1911 CAT-TP-11

ISO 15713

Analysis

17025 Analysis

Technical LOD

Monitoring

Lab

CAT-TP-07 Yes MAR

CAT

Testing

Yes

IC

CAT

CAT

Lab

Yes CAT-AP-01

CAT-AP-01

EN 1948 WI 1122

Analysis

MONITORING & ANALYTICAL METHODS

(Average)

Analytical

15th - 16th May 2018

Parameter

Procedure

MCERTS

17025

Testing

Standard Analytical

TechniqueProcedure


(Page 5 of 7)

Testing

Dioxins & Furans

CAT-TP-21

Run

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EPA Export 18-08-2018:04:04:18

Duct Characteristics Location of Sampling Platform

Platform Details

Sampling Location / Platform Improvement Recommendations

EN 15259 Homogeneity Test Requirements

Sampling Plane Validation Criteria (from EN 15259)

Number of Ports -

Yes

Pa

Yes

--

0

10.16 -

Value

No Local Negative Flow

0.17

Orientation of Duct

Compliant

-

Yes

SUITABILITY OF SAMPLING LOCATION

Outside

cm

-

Port Depth

0.00

Permanent / Temporary Platform

Width

Platform has vertical base boards (approx. 0.25m high)

Vertical

Type

Yes

-

Units

-

Sufficient working area to manipulate probe and operate the measuring instruments

-

Permanent

0.00

-

-

0.00

-

-

Maximum Angle of Swirl

-Yes

Yes

-

-

All platforms should be designed in accordance with the requirements in EPA Guidance Note AG1 and EN 15259.

Criteria in EN 15259

-10.40

-

Mean Velocity

-

Safe Access Available

There are no obstructions present which hamper insertion of sampling equipment

-

Parameter

(Page 6 of 7)

5" Flange

Easy Access Available

Units

m

Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements

-

Yes

Traverse 1

Inside / Outside0.47

-

Sample Port Size

There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.

81.0

Circular

Value

-

-

Highest Gas Velocity

Area

Yes

4

-

Lowest Gas Velocity

m/s

Yes

9.96

-

-

Required

-

Platform has chains / self closing gates at top of ladders

-

m/s

-

-

m²

m

-

-

-

-

-

Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)

-m/s

Executive Summary

General Platform Information

> 5 Pa Yes

-

Lowest Differential Pressure

Depth

Value

Ratio of Above < 3 : 1

- Yes-

-

: 1 Yes

< 15°

0.001.04

° 8

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EPA Export 18-08-2018:04:04:18

Executive Summary

Photo 2

PLANT PHOTOS

(Page 7 of 7)

SAMPLE POINTS

Photo 1

where = isokinetic point sampled at

= isokinetic point not sampled at

= combustion gases sample point

Line A

A1

A4

A3

A2

= non-isokinetic sample point

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EPA Export 18-08-2018:04:04:18

APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDIX CONTENTS

APPENDICES

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EPA Export 18-08-2018:04:04:18

Bioaerosols Temperature Logger -

Electronic Refrigerator -

ABB AO2020-URAS26

Stack Thermocouple (2)

Servomex 4900

-

Stopwatch

CAT 7.23

Position

CAT 9.19

Equipment Type

APPENDIX 1

CAT 3.168-

-

CAT 21P.14

MM16 1413 TE1

CAT 25.12

CEN/TS 13649

Miscellaneous Items

-

MM 10 1074 TE1 TE2 TE3 TE4

Technician Brian Walsh MCERTS Level 1

Oven Box (2)

Eco Physics CLD 822Mh

CAT 3.59

5m Heated Line (1) -

Barometer

Digital Manometer (2)

MCERTS Number

CAT-TP-16Organics Class II

Technical Endorsements

S-Pitot (1)

L-Pitot

SELECT FTIR

SELECT Horiba Model (2)

CEN/TS 13649

CAT 6.21


ISO 12039

TGN M21

CAT-TP-21

CAT-TP-21

Velocity & Vol. Flow Rate

Organics Class I

Hydrogen Fluoride

Water Vapour

Sulphur Dioxide

EN 15058

CAT-TP-21


Oxides of Nitrogen (as NO₂)

Oxygen

EN 14790

Formaldehyde

EN 16911-1 (MID) CAT-TP-41

EN 14789

Carbon Monoxide

Carbon Dioxide

EN 14792

CAT-TP-16

CAT-TP-21

CAT-TP-16

CAT-TP-21

CAT 12.83

-

Mass Flow Controller (2)

Name

Site Balance

M&C PSS

Control Box DGM (2)

-

John Glennon MCERTS Level 2

Extractive Sampling

CAT 23.26

STACK EMISSIONS MONITORING PERSONNEL

CAT 4.491

-

Umbilical (2) Servomex 5200MP

LIST OF EQUIPMENT

MCERTS Accreditation

-

Equipment I.D.

CAT 6.1

CAT 3.168

- 20m Heated Line (1)

20m Heated Line (2)

-


Gasmet Sampling System

Instrumental Analysers

CAT 25.11

-

JCT JCC P1 Cooler

CAT 13.27

Mass Flow Controller (1)

Umbilical (1)

Box Thermocouples (2)

Box Thermocouples (1)

SELECT Logger 2 -

Dual Channel Heater Controller -500g / 1Kg Check Weights

METHODS & TECHNICAL PROCEDURES USED

Single Channel Heater Controller

Tubes Kit Thermocouple CAT 4.0005

CAT 11.58

EN 1911

Mass View (1)

Hioki 5043 (V)

CAT 20.71

Equipment Type

CAT 4.605

-

CAT 14.65

-

Bernath 3006 FID CAT 8.16

15m Heated Line (1)

CAT 17.24

-

- 1m Heated Line (2)Heated Probe (2)

Team Leader

S-Pitot (2) CAT 21S.42

CAT 17.24

Last Impinger Arm CAT 4.405

Callipers

Mass View (2)

Dioxins & Furans

1m Heated Line (1)

Technical ProcedureStandard

Heated Probe (1)

Control Box DGM (1)

CAT 3.59

-

-

Parameter

1m Heated Line (3)

-

Oven Box (1)

CAT 20.71

Laboratory Balance

Equipment I.D.

Digital Manometer (1)Horiba PG-250

CAT 5.3

EN 1948

CEN/TS 13649

Hydrogen Chloride

Equipment I.D.Equipment Type

CAT-TP-10

CAT-TP-11

CAT-TP-07

CAT-TP-20

CAT-TP-05

Digital Temperature Meter

Heated Probe (3) -

EN 12619:2013

CAT 16.35Tape Measure

-

CAT 12.115

-

CAT 4.568

ISO 15713

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EPA Export 18-08-2018:04:04:18

General Stack Details

Stack Gas Composition & Molecular Weights

CO₂

O₂

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p

Calculation of Stack Gas Densities

Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)

P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)

P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)

P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)

Calculation of Stack Gas Volumetric Flowrate, Q

Gas Volumetric Flowrate (from Traverse)

m²

Stack Diameter / Depth, D

PRELIMINARY STACK SURVEY: CALCULATIONS

Average Barometric Pressure, Pb

Dry Density (STP), P STD

0.0386

5204

Value

34.5

Units

0.47

Dry

0.05970

20.46 32.00

Conc

Gas Volumetric Flowrate (Actual)

kg/m³

ConcMolar Conc

-

0.2046

m³/hr

REF ¹

1.130

Dry Density (Actual), P Actual

APPENDIX 2

kg/m³

m³/hr

7.43

m³/hr

°C

84.0

m³/hr

Gas Volumetric Flowrate (STP, Dry)

18.02

Determinand

kg/m³

0.17

Result

-

mStack Width, W

Stack Details (from Traverse)

Moisture

Stack Area, A

3.86

Units

Average Pitot Tube Calibration Coefficient, Cp

ppm

Average Stack Gas Pressure

Conc

kg/m³

0.7568

Average Stack Gas Temperature, Ta

-0.0

5204

0.085Average Stack Static Pressure, Pstatic

-

28.01

Pa

Result

1.9635

-

Volume

kPa

kPa

0.84

-

-

1.2498

44.01

0.94587

1.314

70.06

34.5

101.1

Gas Volumetric Flowrate REF ¹

1.4277 0.29217

Mass

Component

N₂

101.0

7.43

M

Wet

r% v/v

kg/m³

-

Units

Fraction

Density

Total Pressure

Average Wet Density (Actual), P ActualW

°C

Gas Volumetric Flowrate (STP, Wet)

101.3

Temperature

Duct gas flow conditions

75.68

p pi

3.57 0.07573

kPa

0.0743

5622

18.94

6345

1.164

Wet Density (STP), P STW

% v/v

Units

0.00

kg/m³ 1.276

0.8037

m

Actual

%

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EPA Export 18-08-2018:04:04:18

Parameter Parameter

Date of Survey Initial Pitot Leak Check

Time of Survey Final Pitot Leak Check

Atmospheric Pressure Orientation of Duct

Average Stack Static Pressure Pitot Tube, Cp

Result of Pitot Stagnation Test Number of Lines Available

Are Water Droplets Present? Number of Lines Used

Device Used

15/05/2018

Value

S-Type Pitot with KIMO MP 200 (500Pa)

101.0

Velocity

Units

Pa

Depth

-

∆P -

-

-

Temp

APPENDIX 2

1-

-Swirl

No

Pass

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID)

Pass

-

-

(1 of 1)

1

Wet Density

5.085.0

4

2.088.0

Units

kPa

-

-

-

1.134

0.35

Point

35.0

Mean

0.12

3

34.5

10.05

10.40

1.128

1.128

--° -°C

85.0

0.03

kg/m³ -m/sPa

1.130

m

Value

-

--

-

-

Traverse

0.84

2

0.44

10.23

34.6

33.481.0

35.0

- -

Sampling Line A

4.0

-

-

-

-

-

-

- --

- -

-

-

-

-

-

-

-

-

-- - --

1.130

STATIC (Units: Pa)

85 -

-

1

82.0

84.0 -

-

-

-

-

-

-

8.09.96

-

-

--

-

--

-

-

- -

--

10:45 - 10:50

-

-

-

10.16

-

-

-

-

--

-

-

- -

-

- -

-

-

-

-

-

-

-

-

-

-

-

-

-

Vertical

Pass

-

-

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EPA Export 18-08-2018:04:04:18

- u²(qV,w)/q²V,w

1.569

-

1.534

u(φO₂,d) 0.626

u(φCO₂,w) 0.110

- u²(a)/a²

u(Tc)

APPENDIX 2

- 27352

- 165.4

Uc,rel(qV,w) 5.11

%

- Static Pressure

Standard uncertainty associated with the density in the duct

Standard uncertainty associated with the volume flow rate (95% Confidence)

m/s

u(φCO₂,d) 0.118

Standard uncertainty associated with the local velocities

- φCO₂,w

- Oxygen, dry

- Carbon Dioxide, dry

Standard uncertainty associated with the mean velocity

175.692

1.534

u(ρ) 0.00609

u(fit) 0.535

Standard Uncertainty associated with the mean local dynamic pressures

Standard uncertainty associated with the mean velocity (95% Confidence), relative

0.005

Uc,rel(v) 2.37

Standard uncertainty associated with the absolute pressure in the duct

- Atmospheric Pressure

u(drift) 0.083- Drift

- Lack of Fit

- Water Vapour

- Oxygen, wet

- Carbon Dioxide, wet

-

Pa

u(res) 0.00087

u(vi)

K

u(pc)

0.241

1.354

u(∆pi)

324.2 m³/hr

- u²(qV,w)

Performance characteristics (Uncertainty Components) UnitsValueUncertainty

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID) - MEASUREMENT UNCERTAINTY(1 of 1)

Standard uncertainty associated with the mean velocity (95% Confidence)

- Overall corrections to dynamic measurements

Standard uncertainty associated with the molar mass of the gas

- φO₂,w

- Resolution

- Calibration

0.00068

%

- u(qV,w)

18.944

- 3.570

u(M) 0.00005

0.147

u(v) 0.123

Standard Uncertainty on the coefficient of the Pitot Tube -

0.00053

-

Uc(qV,w)

Standard uncertainty associated with the stack temperature

Uc(v)

-

-

Pa

m/s

u(Cf)

u(φH₂O) 0.379

u(pstat)

u(k)

u(cal) 0.735

u(φO₂,w) 0.585

Standard uncertainty associated with the volume flow rate (95% Confidence), relative

175.699 Pa

u(patm)

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EPA Export 18-08-2018:04:04:19

Sample Runs (UPPER NATO I-TEQ)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Humans / Mammals)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Fish)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Birds)

- -

- -

- -

- -

- -

0.0224

0.0009

Mass Emission

0.0043

±ng/m³

Mass Emission µg/hr

0.0026

ng/m³

0.012

TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)

Uncertainty

Uncertainty

0.0047

0.0005

±ng/m³ 0.0004

0.0005

Mass Emission µg/hr

Uncertainty

0.0043

Mean

APPENDIX 2

0.002

Parameter

0.0009

µg/hr 0.0138

0.0224

Mean

Parameter Units

Units Run 1

0.0029

0.0022Concentration ng/m³

DIOXINS & FURANS: RESULTS SUMMARY

Mass Emission

±ng/m³

Parameter Units

0.002

Parameter Units

Uncertainty

0.012

Uncertainty ±µg/hr 0.002

ng/m³ 0.0022 0.0022

±µg/hr

Concentration

A2-14 RTO Outlet

0.002

0.012

0.0026

Uncertainty ±µg/hr

Concentration

0.0138

Uncertainty ±µg/hr 0.0029

Concentration ng/m³

Run 1

(PAGE 1 OF 4)

Uncertainty ±ng/m³ 0.0005


0.0022

0.0005

Mean

Run 1 Mean

µg/hr 0.012

Run 1

0.0047

0.0004

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EPA Export 18-08-2018:04:04:19

Sample Runs (LOWER NATO I-TEQ)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Humans / Mammals)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Fish)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Birds)

- -

- -

- -

- -

- -

Concentration

Uncertainty

0.0026

Concentration ng/m³ 0.0021

0.0021

0.0111

0.0021

APPENDIX 2

µg/hr 0.0220

±ng/m³

µg/hr

±µg/hrUncertainty

ng/m³

±µg/hr

MeanRun 1

±µg/hr 0.0024

Mean

ng/m³


0.0111

Mass Emission

±ng/m³

Mass Emission

0.0023

0.0028

0.0005Uncertainty

0.0028

0.0009

0.0004

Mass Emission

0.0009

Parameter Units

±ng/m³

µg/hr 0.0134

0.0004

µg/hr

Parameter

0.00420.0042

Mean

0.0026

0.0112


A2-14 RTO Outlet

TEQ2 - LOWER LIMITS (best case where <LOD = 0)

Parameter

0.0112

Parameter

(PAGE 2 OF 4)

Mass Emission

Units Run 1

Uncertainty

Uncertainty 0.0004

Concentration

Uncertainty

±ng/m³

0.0220

Uncertainty

0.0021

0.0024

Units

0.0023

±µg/hr 0.0046

Run 1Units Mean

Run 1

0.0004

Uncertainty

0.0005

0.0134


0.0046

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EPA Export 18-08-2018:04:04:19

Blank Runs (UPPER NATO I-TEQ)

- -

- -

Blank Runs (UPPER WHO TEQ Humans / Mammals)

- -

- -

Blank Runs (UPPER WHO TEQ Fish)

- -

- -

Blank Runs (UPPER WHO TEQ Birds)

- -

- -

Blank Runs (LOWER NATO I-TEQ)

- -

- -

Blank Runs (LOWER WHO TEQ Humans / Mammals)

- -

- -

Blank Runs (LOWER WHO TEQ Fish)

- -

- -

Blank Runs (LOWER WHO TEQ Birds)

- -

- -


0.00002

0.0002

Parameter

Blank 1

ng/m³

0.0003

Concentration

0.0002

ng/m³

ng/m³

0.0002

TEQ2 - LOWER LIMITS (best case where <LOD = 0)

0.00002

APPENDIX 2

Units

Units Blank 1

Blank 1

A2-14 RTO Outlet

Maximum

TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)

Parameter Units Blank 1

0.0002

Maximum

Blank 1

0.0002

Parameter


Blank 1

Concentration

0.00002

Parameter Units

Maximum

0.0003


Concentration

Maximum

0.00002

Units

Parameter

Maximum

ng/m³

Concentration

0.00002

Maximum

0.00002

DIOXINS & FURANS: RESULTS SUMMARY(PAGE 3 OF 4)

Units

Maximum

Concentration

Blank 1

ng/m³

Units

Parameter


0.00002


Maximum

Parameter

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EPA Export 18-08-2018:04:04:19

- -

- -

- -

General Sampling Information

FORMAT: Number Used / Number Required


Reference Conditions

Reference Conditions are: 273K, 101.3kPa, dry gas.

Name of Analytical Laboratory

Value

(PAGE 4 OF 4)


MAR

Titanium

Borosilicate Glass

Uncertainty ±% v/v 0.41

Yes

Positioning of Filter

Probe Material

Parameter

Technical Procedure

A2-14 RTO Outlet

Water Vapour % v/v

4 / 4

CAT-TP-07

Out Stack

90mm Quartz Fibre

Number of Sampling Lines Used 1 / 1

XAD-2

Glassware Material

Absorption Material

7.41

APPENDIX 2

Analytical Laboratory's Procedure

07/06/2018


7.41

Mean

Date of Sample Analysis

Filter Size and Material

Parameter Units

ISO 17025 Accredited Analysis?

Number of Sampling Points Used

WI 1122

Run 1

EN 1948

0.41

Filter Housing Material Borosilicate Glass

Standard

Sample Point I.D.'s A1 - A4

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EPA Export 18-08-2018:04:04:19

Absolute pressure of stack gas, Ps

Volume of water vapour collected, Vwstd

Volume of gas metered dry, Vmstd

Moisture content, Bwo & Rwv

Bwo as a percentage

Reported Water Vapour, checked with Tables in EN 14790, Rwv

Volume of gas metered wet, Vmstw

Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂

Molecular weight of dry gas stream, Md

CO₂

O₂

Molecular weight of stack gas (wet), Ms

Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)

Percent isokinetic, %I

Average square root of velocity heads, √∆P

8.47

107.5

0.17

30.3

756.8

-9.2

Vmstw = (Vmstd)(100/(100 - Rwv))

% v/v

m³

757.5

N/A

Barometric pressure, Pb mmHg

Units Run 1

mmHg

Gas meter correction factor, Yd - 0.9220

Vmstd@X%oxygen = (Vmstd) / (O₂REFd)

Test

N/A

m³

Bwo = Vwstd / (Vmstd + Vwstd)

-

N/A

m³/min

m³

297.0

gTotal mass collected in impingers (silica trap)

0.4283

0.84

5.7831

Ps = (Pb + (Pstatic / 13.6)

g

% v/v 0.36

N/A

27.62

% v/v 20.36

N/A

mmH₂OAverage of velocity heads, ∆Pavg

- 34.97

Total mass of liquid collected, Vlc g

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol

Pitot tube velocity constant, Kp

79.64

N/A

% v/v

Qa = (60)(As)(Vs)

√mmH₂O

343.7

N/A

28.05

Velocity pressure coefficient, Cp -

87.3

-

36.8

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))

20.4

No

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol

5.3548

mmH₂O

Total mass collected in impingers (liquid trap)

m³ 6.2450

% v/v

mmH₂O

DIOXINS & FURANS: ISOKINETIC SAMPLING CALCULATIONS

7.41

46.7

Stack static pressure, Pstatic

APPENDIX 2

% dry oxygen measured in gas stream, ACT%O₂d % v/v

°CAverage dry gas meter temperature, Tm

Volume of gas sample through gas meter, Vm

% v/v

% wet oxygen measured in gas stream, ACT%O₂w

Average pressure drop across orifice, ∆H

% oxygen reference condition, REF%O₂ % v/v N/A

Vwstd = (0.001246)(Vlc)

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³

7.41

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min

% 107.0

Area of stack, As m²

Average stack gas temperature, Ts °C

N₂ % v/v

28.86

Velocity of stack gas, Vs

Conversion factor (K/mm.Hg), Cf

10.33

m³/min

Vmstw@X%oxygen = (Vmstw) / (O₂REFw)

Total sampling time, q min

m³ 0.0741

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 94.3

2.91

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s

20.00

-

Nozzle area, An

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)

m³ N/A

Total

-

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min

360

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)

0.3592

mm²

Nozzle diameter, Dn mm 5.93

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EPA Export 18-08-2018:04:04:19

Where: ISO stands for Manual Isokinetic Sampling Train

2378-TCDD

12378-PeCDD

123478-HxCDD

123678-HxCDD

123789-HxCDD

1234678-HPeCDD

OCDD

Total Dioxins

2378-TCDF

12378-PeCDF

23478-PeCDF

123478-HxCDF

123678-HxCDF

234678-HxCDF

123789-HxCDF

1234678-HPeCDF

1234789-HPeCDF

OCDF

Total Furans

Totals

Total Concentration

Limit of Detection

Where: ND stands for Non Detected

DL stands for Analytical Detection Limit

TEQ1 refers to Non Detected Congeners at the Detection Limit

TEQ2 refers to Non Detected Congeners at Zero

% Rec stands for the Recovery Percentage of the Sample

- - -

0.0007

102

0.00350.0035

0.0004

0.0009

0.0035

0.0000

0.0001

0.0002

0.0000

ND

1010.0002

0.0185

0.0017

ng

960.0004

0.0003

0.0003

0.0035

0.0009

0.0037

-

0.0000

0.0082 0.0064

0.0000

-

ng/m³ -

-

- 0.0003

-

0.0185

0.00000.0000

0.0026

0.0776

0.0022

0.0119

- 0.0003

0.0142

0.0026

0.0118

0.00020.0023

0.0000

0.0007

-

0.0000

0.0007

0.0003

0.0004

0.0007

0.0000

0.0035

0.0043

0.0000

0.0007

0.0000

0.0000

121

0.0005

0.0010 0.0006

0.0003

92

84

0.0000

0.0003

0.0043

0.0000

0.0002

0.0026

0.0000

128

TEQ1 TEQ2 TEQ1

0.0010

0.0026

ng 0.0007

0.0002

0.0001

0.0002

0.0017

0.0202

0.00000.0026

0.0006

0.0021

0.0086

0.00000.0036

-

0.0000

0.0002

0.0007

0.0001

ng

0.0000

0.0000

140

0.0003

ng

-

0.0004

0.0000

0.0002

0.0000

0.0003

Sampling Dates

Sampling Device

ng

0.0007

82

0.00030.0063ng

91

85

0.0001

0.0002

Units

0.0023

0.0000

0.0063

0.0023

0.0062ng

0.0007

0.0000

0.0006

0.0000

0.0000

0.0082

0.0001

0.0000

0.0079

0.0002

0.0005

-

0.0079

0.0005

0.0000

0.0063

m³

Value

ISO

ng

- -

ng 0.1374 0.0229

0.0043

0.0000

0.0000

10:57 - 16:57

0.0033

Sampling Times

0.0050

0.0006

0.0035

WHO

Birds

-

0.0010

0.0002

0.0005

0.00440.0597

0.0002 0.0002

0.0021

DL

93

0.0063

0.0010

0.0001

0.0086

0.0002

0.0007

ng 0.0005

WHO Humans /

Mammals

WHO

Fish

ng

0.0086

0.0007

0.0010

0.0009 0.0009

0.0054

0.0002ng

0.0072

0.0228

0.0000

0.0000

0.0009

ng

0.0000

0.0002

0.0000

0.0005

0.0002

0.0004

0.0004

0.0006

0.0137

0.0007

ng/m³

Volume Sampled (REF)

TEQ2

0.0006

0.0007

0.0010

ng

0.0006

0.0010

0.0063

0.0043

0.0094

TEQ2

76

0.0010

0.0009

-

114

139

81

Parameter Units Result

RUN 1

0.0035

0.0002

0.0100 0.0005

0.0005 0.0009

0.0002

0.0009

ng

0.0006

0.0002

0.0001

0.0002

0.0000

0.0003

0.0043

TEQ1 TEQ2 TEQ1

Parameter

0.0022

0.0115 0.0225

0.0042

0.0113

0.0045

0.0003

0.00010.0065

15/05/2018

5.3548

NATO

I-TEQ

ND

0.0010ng

APPENDIX 2

DIOXINS & FURANS: SAMPLING DETAILS

0.0004

0.0002

0.0000ng

ng

0.0058

0.0237

0.0007

0.0007

0.0000

-

0.0004

% Rec

0.0002

0.0040

-

ng

ng

0.0000

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EPA Export 18-08-2018:04:04:19

Where: ISO stands for Manual Isokinetic Sampling Train

2378-TCDD

12378-PeCDD

123478-HxCDD

123678-HxCDD

123789-HxCDD

1234678-HPeCDD

OCDD

Total Dioxins

2378-TCDF

12378-PeCDF

23478-PeCDF

123478-HxCDF

123678-HxCDF

234678-HxCDF

123789-HxCDF

1234678-HPeCDF

1234789-HPeCDF

OCDF

Total Furans

Totals

Total Concentration

Where: ND stands for Non Detected

DL stands for Analytical Detection Limit

TEQ1 refers to Non Detected Congeners at the Detection Limit

TEQ2 refers to Non Detected Congeners at Zero

% Rec stands for the Recovery Percentage of the Sample

0.0000

Parameter

TEQ1

0.0000 0.0000

132

TEQ2 TEQ1

0.0000

ng

Units

85

0.0000ND

0.0000

TEQ2

Sampling Device -

0.0000

0.0000

TEQ2

0.0000

0.00000.0003

0.0000

0.0000

0.0000

0.0000

-

0.0000

0.0000

0.0004 0.0000

0.00000.0000

107

TEQ2 TEQ1

WHO Humans /

Mammals

0.0001

NATO

I-TEQ

(Continued)

0.0000

104

-

-

0.00000.0003

0.0000

0.0000 0.0004 0.0000

0.0000

BLANK 1

% Rec

0.0002

0.0037

0.00000.0000

Sampling Dates

930.0000

ND

82

-

0.0000

90

150

ng 0.0003

0.0000

0.0013

0.0012

0.0000

0.0002 0.00000.0002ng/m³

0.0000

0.0000

0.0000

0.0003

0.0000

0.0003

0.0000

ND

0.0002

0.0000

0.0002

0.0000

0.0000 0.0000 0.0000

ng

0.0004

0.0000

0.0002

0.0000 0.0000 0.0000

0.0001

0.0010 0.0001

0.0000 0.0000

0.0001 0.0015

0.0003

0.0000

0.0005

0.0000

0.0000

0.0001ng

0.0000

0.0000

0.0000

0.0000 0.0000 0.0000 0.0000ng

0.0000 0.0000 0.0000

0.0000

0.0000 0.0000

0.0000

0.0000 0.0000 0.0000

0.0000

ND

0.0169

87

0.0003

0.0011 0.0001ng

- - 0.0003

0.0011

0.0008

ng

0.0003 0.0000

75

0.0000

95

0.0000

0.0000

0.00000.0000

0.0000

ND

0.0000

ng ND

0.0000ng

ng

0.0000

0.0000

0.0000

0.0000 0.0000

0.0000

0.0000 0.0000 0.0000

0.0003

154

0.0000 0.0000

0.0000

0.0003

0.0008

0.0000

ng

ng 0.0000 0.0000

TEQ1

0.0002

0.0003

ISO

WHO

Fish

DLResult

-

0.0000

0.0000

ND

0.0000

0.0002

0.0007

0.0000

0.0002

0.0000

ng ND 0.0002 0.0000 81

0.0000

0.0000

0.0137

0.0000

0.0001

0.0000

0.0100

-

0.0003

5.3548

0.0003 0.0000

0.0000 0.0000

ng ND

0.0006 0.0000 0.0008

Average Volume Sampled (REF)

APPENDIX 2

DIOXINS & FURANS: SAMPLING DETAILS

0.0000

0.0006

0.0000

0.0000

0.0000 0.0000

0.0000

0.0000

0.0000

0.0004

ND

0.0000

ng

Parameter Units

-

0.0000

0.0000

15/05/2018

m³

Value

0.0000

0.0000

WHO

Birds

0.0003

0.0000

0.0000

ng

0.0000

120

ng 0.0032 - 0.0003 0.0001

126

0.0000

-

0.0000

ng 0.0002

0.0000

0.0004

0.0000

0.0003 0.0001 0.0001

0.0000

ND

0.0003

0.0000

ng

96

0.0003

0.0000

ng

0.0002

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EPA Export 18-08-2018:04:04:19

Sample Runs

(PAGE 1 OF 2)

Run 1

MU (Concurrent Water Vapour) Run 1

Maximum Allowable Temperature

Pre-Sampling Leak Rate

APPENDIX 2

DIOXINS & FURANS: QUALITY ASSURANCE

Units

Allowable Isokinetic Range

Units Run 1

19

Units

Units

Water Droplets

Measurement Uncertainty (MU)

%

% Yes

Allowable MU

Isokinetic Variation

°C

l/min 0.24

Mean Sampling Rate

107.0

-

Test Conditions Units

YesAmbient Temperature Recorded?

- Yes

-

%

No

Isokinetic Criterion Compliance

Post-Sampling Leak Rate

Leak Test Acceptable

Units

%

Are Water Droplets Present

Maximum Temperature Recorded

Condenser Exit Temperature

Run 1

Isokineticity Acceptable -

Temperature Acceptable - Yes

Yes

Leak Test Results

Units

5.6

Yes

°C

l/min

°C 120Maximum Filter Temperature

Maximum Allowable Temperature

Units

125

%

Allowable Leak Rate l/min 0.80

20

Run 1

Less than 50% Faded

MU Acceptable -

0.21

95 - 115

Yes

Filter Temperatures

Run 1

15.99

Run 1

l/min

Silica Gel (Concurrent Water Vapour)

-

Exit Temperature Acceptable

Run 1

°C

20

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EPA Export 18-08-2018:04:04:19

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

(PAGE 2 OF 2)

Nature of Deviation


Yes

One out of two sampling lines was used due to sampling location restrictions, however the number of sample points used on the available

line were increased to the minimum required by the Standard

l/min 0.15

Units Blank 1

Yes

-

l/min

Blank Acceptable

Validity of NATO I-TEQ Blank vs ELV

-

l/min 15.00

Units

DIOXINS & FURANS: QUALITY ASSURANCE

Blank 1

Expected Sampling Rate

0.0100

Allowable Leak Rate

Allowable Blank

0.75

ng/m³

Sampling Leak Rate

Leak Test Results

APPENDIX 2

Run Number

(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)

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Sampled Volume (Actual)

Sampled Gas Temperature

Sampled Gas Pressure

Sampled Gas Humidity

Leak

Laboratory Result

Sampled Volume (Actual)

Sampled Gas Temperature

Sampled Gas Pressure

Sampled Gas Humidity

Leak

Laboratory Result

Sampled Volume (STP)

Leak

Laboratory Result


Leak

Laboratory Result

O₂ Correction Factor

Stack Gas O₂ Content

MU for O₂ Correction

Combined uncertainty

Expanded uncertainty (95% confidence), without Oxygen Correction

Expanded uncertainty (95% confidence), with Oxygen Correction

Expanded uncertainty (95% confidence), estimated with Method Deviations

Reported Uncertainty





% N/A

ng/m³

0.0005

20.4

0.68

1.00

Parameter

ng/m³ 0.0002

Measured Quantities

%

- N/A

%

N/A

%

0.0002

ng/m³

Symbol

Units Run 1

10.00 No Requirement

ng/m³

m³ 5.3548

ng/m³

Vm 0.00

Run 1

0.0000

%

- N/A

%

uTm

N/A

≤5%

Oxygen Correction Part of MU Budget

uLr

Run 1

K

Measured Quantities

1.00

1.00

% v/v N/A

Uncertainty in Result

Measured Quantities

20.4

%

0.0000

≤1%

0.5

Units

ng/m³

20.4

Requirement of Standard

uL

% v/v 1.0

L

ng/m³

ng/m³

kPa

0.0

0.0002

0.0005

Units

Units Run 1

0.0005

Symbol

%

ρm

≤1%

Uncertainty in Measurement Units

2.00

L

%

uρm

Units

Lr

uHm

Run 1

Run 1

%

ng/m³ 0.0001

Sensitivity Coefficient

%

Standard uncertainty

Vm

Measured Quantities

0.50

%

Uncertainty as a Percentage

1.50

≤1%

Symbol Run 1

Tm

%

m³6.2450

Lr 10.00

-

Hm

Measured Quantities

APPENDIX 2

UnitsRun 1

uVm 0.1249

100.9

2.0293.4

ng/m³

-

1.50

DIOXINS & FURANS (NATO I-TEQ): MEASUREMENT UNCERTAINTY CALCULATIONS

Value

≤2%

Overall MU For O₂ Measurement

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Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

< <






MeanRun 1

0.06

5.2

Units

Blank 1

Uncertainty

Parameter Units

Uncertainty

0.06

12.02

5.56

63.0


Concentration


A2-14 RTO Outlet

APPENDIX 2

0.25

Maximum

Stainless Steel

Filter Housing Material Titanium

CAT


0.1μm Glass Fibre

HPLC Grade Water

mg/m³ 12.02

Impinger Material Polyethylene

Absorption Solution

1 / 1

Out Stack Heated Head

Filter Size and Material

Run 1

5.56Water Vapour % v/v

0.78

0.25

24/05/2018

Units

Positioning of Filter

5.2

63.0

±% v/v

Mass Emission

Sample Point I.D.'s

Probe Material

CAT-TP-11

Concentration mg/m³

0.78

Number of Sampling Lines Used

A1

1 / 4

±g/hr

Standard EN 1911

Technical Procedure

Parameter

Parameter

±mg/m³

Yes

Name of Analytical Laboratory

CAT-AP-01

Value

Uncertainty

Mean

HYDROGEN CHLORIDE: RESULTS SUMMARY


Parameter


g/hr

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EPA Export 18-08-2018:04:04:19

Sample Runs

-

-

-

-

-

-

-

-

Where: MFC stands for Mass Flow Controller, MV stands for Mass View Flowmeter

Blank Runs

<

-

<

<

0.05

ml

Laboratory Result for Impingers µg/ml

Total Mass Of Water Vapour g

Calculated Concentration mg/m³

Parameter

Duration

Volume in Impingers

Units Blank 1

Total Mass Collected µg 15.5

Blank Dates - 16/05/2018

Average Volume Sampled (REF) m³ 0.2813

Sample Flow Rate l/min

HYDROGEN CHLORIDE: SAMPLING DETAILS

- 16/05/2018

Sampling Device - MFC / MV

1.62

240.8

µg

54.1

Sampling Times - 11:18 - 11:48

mins 30

Sampling Dates

2113.2Liquid Trap End Mass

Volume Sampled (STP, Wet) m³

Mass in Back Impinger µg 87.6

Total Mass Collected µg 3381.8

Mass in Front Impingers

g

0.06

Laboratory Result for Front Impingers

Silica Trap Start Mass

13.68

Laboratory Result for Back Impinger

Volume Sampled (STP, Dry) m³ 0.2813

g 2101.3

µg/ml

12.02Calculated Concentration mg/m³

Liquid Trap Start Mass

13.3

Calculated Water Vapour % v/v 5.56

APPENDIX 2

3294.1

0.2978

310.1

Parameter Units Run 1

Volume in Front Impingers

Volume in Back Impinger

µg/ml

g 899.5

9.36

ml

ml

g 898.1

Volume Sampled (REF) m³ 0.2813

Silica Trap End Mass

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Sample Runs

¹ The concentration in the last absorber was less than 5 times the analytical detection limit. 1 0 11 12

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

Pre-Sampling Leak Rate l/min 0.04

APPENDIX 2

HYDROGEN CHLORIDE: QUALITY ASSURANCE

Leak Test Results Units


Yes

Measurement Uncertainty (MU) % 4.5

Allowable MU % 20

MU (Concurrent Water Vapour) Units Run 1

Test Conditions Units Run 1

Expected Sampling Rate l/min 9.50

Are Water Droplets Present

Mean Sampling Rate

0.14

Absorption Efficiency Units Run 1

Absorption Efficiency % 97.4

l/min

Run 1

Water Droplets Units

Yes

Run 1

Allowable Absorption Efficiency % N/A ¹



Blank 1

Leak Test Acceptable -

Yes-

Yes ¹


Ambient Temperature Recorded? -

-

- No

Units Run 1

l/min

Nature of Deviation Run Number


There are no deviations associated with the sampling employed.

Allowable Blank

Absorption Efficiency Acceptable -

mg/m³ 3.0

Blank 1

Blank Acceptable


Units


Validity of Blank vs ELV

Less than 50% Faded % Yes


Yes

MU Acceptable % Yes

9.36

l/min 0.11

Post-Sampling Leak Rate l/min 0.01

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EPA Export 18-08-2018:04:04:19


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













mg/m³ 0.78

% v/v

Measured Quantities Run 1


1.00

L

HYDROGEN CHLORIDE: MEASUREMENT UNCERTAINTY CALCULATIONS


%

Symbol

mg/m³

mg/m³


mg/m³

N/A

%

2.00

0.104

%


≤2%

%

Lr

0.2813

mg/m³

0.1038

uL

Lr

Vm

1.50

uLr

%

Symbol

APPENDIX 2

m³

Run 1Units

42.75

% 6.5

0.2813 uVm

L 1.50

Run 1

Value

≤2%

0.2405

Vm

Measured Quantities

Run 1

1.00

mg/m³

N/A

UnitsParameter

Measured Quantities Units Run 1

mg/m³

6.5

-

- N/A

0.40

6.5

mg/m³

Measured Quantities

-


% N/A

0.78

mg/m³ 0.78

Units Run 1

0.301

mg/m³ 0.3006

No Requirement

Measured Quantities Symbol


2.50

Run 1

% -

0.0056

Units Run 1

2.50

m³


N/A

%

% N/A

Units


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EPA Export 18-08-2018:04:04:19

Sample Runs

- -

< <

- -

< <

- -

- -

- -

- -

Blank Runs

- -

< <






Parameter

APPENDIX 2

Units


A2-14 RTO Outlet

0.030 0.030

CAT-TP-10

Name of Analytical Laboratory CAT

0.38 0.38

1 / 4

ISO 15713

Technical Procedure

Sample Point I.D.'s A1

Value

Probe Material Monel

29/05/2018

0.07

MeanRun 1

Water Vapour % v/v

Concentration mg/m³ 0.07

HYDROGEN FLUORIDE: RESULTS SUMMARY

0.004

MeanUnits

Uncertainty ±mg/m³

±g/hr

0.004

Mass Emission g/hr 0.4

9.32 9.32

Parameter Run 1

Uncertainty ±% v/v

0.4

Uncertainty

Parameter Units Blank 1 Maximum


Parameter

1 / 1


0.05

Filter Housing Material Monel

Impinger Material Polyethylene

Absorption Solution 0.1 mol/l Sodium Hydroxide

Positioning of Filter Out Stack Heated Head

Filter Size and Material 0.1μm Glass Fibre

CAT-AP-01

ISO 17025 Accredited Analysis? Yes

Standard




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EPA Export 18-08-2018:04:04:19

Sample Runs

<

<

-

-

<

<

<

<

Where: MFC stands for Mass Flow Controller, MV stands for Mass View Flowmeter

Blank Runs

<

-

<

<

Volume in Impingers

Laboratory Result for Impingers µg/ml

ml

1270.2

µg 20.2

MFC / MV

- 15/05/2018

Calculated Water Vapour % v/v

g 1255.9

Sampling Device

Duration 30

Volume Sampled (REF) m³

Sample Flow Rate l/min 9.81

mins

Volume Sampled (STP, Dry)

APPENDIX 2

HYDROGEN FLUORIDE: SAMPLING DETAILS

Parameter

m³ 0.2948

-

Sampling Times

Sampling Dates

- 09:10 - 09:40

Units Run 1

Blank Dates -

Volume Sampled (STP, Wet) m³ 0.3250

0.2948

9.32

Silica Trap End Mass g 884.9

mg/m³ 0.07

µg/ml 0.05

305.8

Total Mass Collected

Liquid Trap End Mass

Calculated Concentration

g

0.05

g

Laboratory Result for Front Impingers µg/ml 0.05

Laboratory Result for Back Impinger

Volume in Back Impinger ml 122.7

Mass in Front Impingers µg 14.1

Mass in Back Impinger µg 6.1

Total Mass Of Water Vapour 24.3

Total Mass Collected µg

Silica Trap Start Mass g 874.9

15.3

0.05

Liquid Trap Start Mass

15/05/2018


Volume in Front Impingers ml 281.9

Calculated Concentration mg/m³


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EPA Export 18-08-2018:04:04:19

Sample Runs

² The concentration is less than 30% of the ELV, therefore no assessment against an allowable efficiency is required. 1 7 0 8

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

MU (Concurrent Water Vapour) Units Run 1

%

9.81

Leak Test Acceptable - Yes

Water Droplets

Mean Sampling Rate l/min

Units Run 1

APPENDIX 2

HYDROGEN FLUORIDE: QUALITY ASSURANCE

Allowable Absorption Efficiency


Are Water Droplets Present - No

Absorption Efficiency % 100.0

N/A ²


-

Units

Units


Measurement Uncertainty (MU) % 4.1

Less than 50% Faded

Allowable MU

%

Run 1

Run 1


Nature of Deviation

Blank 1

l/min 0.08

l/min 0.08

Blank Acceptable -

Leak Test Results



Absorption Efficiency Units Run 1

Allowable Leak Rate

Absorption Efficiency Acceptable - Yes ²

l/min 0.20

Yes


% Yes

Leak Test Results

Units Run 1

mg/m³ 0.2

Yes


MU Acceptable

% 20

Test Conditions

l/min 10.00

Units Blank 1

Yes

Ambient Temperature Recorded?

Validity of Blank vs ELV Units

Run Number



Allowable Blank

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EPA Export 18-08-2018:04:04:19


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













-

≤2%

% 0.41


Units Run 1

L 0.41

Measured Quantities Symbol Run 1

2.00

0.00

0.00

0.0014

Run 1

% 6.5

UnitsParameter

6.5

uVm m³

Symbol

% N/A

%

mg/m³ 0.00

%

Lr 2.65

m³

mg/m³

Run 1

HYDROGEN FLUORIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

uL % -

Measured Quantities

mg/m³

Units


Measured Quantities Units

1.00

Lr mg/m³

0.0059

0.002

Vm

0.0018

Uncertainty in Measurement Units Sensitivity Coefficient

- N/A

L

0.00

%

N/A

%

-

Overall MU For O₂ Measurement N/A

Vm

mg/m³

1.00

0.2948


mg/m³

%

≤2%

mg/m³

N/A

mg/m³

2.65

mg/m³

0.000

Value Standard uncertainty

APPENDIX 2

uLr

Units

Symbol

% v/v

Units Run 1

%

Measured Quantities

0.2948

mg/m³ 0.0002

0.23

Run 1

Measured Quantities

Run 1

6.5

Run 1

N/A

No Requirement


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EPA Export 18-08-2018:04:04:19

Sample Runs

- -

< <

< <

< <

< <

< <

< <

< <






Total mg/m³ 12.57

CEN/TS 13649

Probe Material Stainless Steel

2.03Trichloroethylene

Carbon Tetrachloride

4.05

2.03

4.05

mg/m³

mg/m³

Benzene

2.03

2.03

2.03

2.03

Parameter

Chloroform

2.03

A2-14 RTO Outlet

mg/m³

mg/m³

mg/m³ 2.03

mg/m³

Yes


12.57

Technical Procedure CAT-TP-16

Name of Analytical Laboratory CLS

Standard

Dichloromethane

Tetrachloroethylene



1 / 4

ORGANICS CLASS I : RESULTS SUMMARY

Mean

Value

Coconut Shell Charcoal

Date of Sample Analysis 31/05/2018

Sample Tube Type

Units Run 1

Parameter

APPENDIX 2

Analytical Laboratory's Procedure GC/MS

ISO 17025 Accredited Analysis? See Executive Summary

0.41 0.41

Dynamic Dilution Employed


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EPA Export 18-08-2018:04:04:19

Where: MV stands for Mass View (Mass Flow Controller Technology)

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

- < <


Tube Lot Number and Unique ID: 739340-1

100.0

Dichloromethane

5.0

Trichloroethylene 5.0

2.027 2.027

Concentration

mg/m³

2.027 2.027 2.027

Sampling Times

Duration

1.0

10.0

ORGANICS CLASS I : SAMPLING DETAILS

-

5.0 10.0

5.0

10.0 20.0

Value

Sampling Dates

Lab Result

(Back)

µg

Lab Result

(Total)

µg

-

12.57062.0 12.570

mins

62.0

Tetrachloroethylene

5.0 5.0 10.0

Total 12.570

30

Benzene

1.5

Chloroform

10.0

APPENDIX 2

-

-

AG2 Reporting Format ELV (mg/m³)

Organics Class I 20 > 0 and < 12.57 > (sum of ) and < (sum of 1+2+3+4+5+6)

10.0

10.0 2.027 2.027 2.027 100.0

Sampling Device

LOD

(Total)

µg

Parameter

20.0 4.055

MV


RUN 1

Parameter

5.0 10.0

2.0 1.0 0.405

4.055 4.055 100.0

LOD

(Back)

µg

Reported

Concentration

(Blank Reviewed)

mg/m³

2.0 0.405

2.0275.0

- 15/05/2018

1.0 1.0

12:30 - 13:00

10.0

LOD

(Front)

µg

0.405 100.0

Carbon Tetrachloride 5.0

Reported

LOD

mg/m³

Adsorption

Efficiency

%

2.027 2.027 2.027 100.0

: 1N₂ to Stack Gas Dilution Ratio

Results (mg/m³) Breakdown of Results Exceedance?

100.0

5.0

10.0 10.0

5.0 5.0 10.0 5.05.0

5.0

5.0

Lab Result

(Front)

µg

Units

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< < - <

< < - <

< < - <

< < - <

< < - <

< < - <



APPENDIX 2

Benzene

Dichloromethane

2.027

2.027

20.0 4.055

Tetrachloroethylene 5.0 5.0

Trichloroethylene 5.0 5.0 10.0

10.0

Units

Sampling Device - MV


Parameter Lab Result

(Front)

µg

Lab Result

(Back)

µg

5.0

15/05/2018

ORGANICS CLASS I : SAMPLING DETAILS

BLANK 1

Parameter

10.0

5.0 10.0 2.027

10.0 2.027

Chloroform

Lab Result

(Total)

µg

Concentration

mg/m³

1.0 2.0 0.405

Carbon Tetrachloride 5.0 5.0

10.0

1.0

Sampling Dates -

Value

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Sample Runs

Allowable Leak Rate

0.000

Yes

°C 11

%

-

%

%

APPENDIX 2

l/min

0.000

ORGANICS CLASS I : QUALITY ASSURANCE


Run 1

Trichloroethylene

Adsorption Efficiency Units

l/min

%

Benzene %

-Leak Test Acceptable

100.0

Dichloromethane

%


Carbon Tetrachloride

l/min

95

0.400

l/min

0.020

100.0Chloroform

% 100.0

100.0

Run 1

Mean Sampling Rate

Tetrachloroethylene

Yes

100.0


100.0

(PAGE 1 OF 2)

Yes

Run 1

Allowable Temperature

-

Adsorption Efficiency Acceptable

°C

-Ambient Temperature Recorded?

Allowable Adsorption Efficiency

Temperature

40


Yes

Run 1

Temperature Acceptable

Temperature at Sample Tubes Units

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Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

12.6 2.0

0.400

0.020


Allowable Leak Rate

Allowable for Chloroform

2.0

mg/m³


Allowable for TOTAL

(x = deviation applies to the associated run)

Nature of Deviation

Allowable for Benzene

UnitsLeak Test Results

Sampling Leak Rate


2.0 N/A

l/min

Allowed

mg/m³ N/A

mg/m³

mg/m³

0.000

(PAGE 2 OF 2)


N/A

l/min

2.0

Allowable for Carbon Tetrachloride

Blank 1

N/A

Allowable for Dichloromethane

Allowable for Tetrachloroethylene

Allowable for Trichloroethylene

0.4

N/A

mg/m³

mg/m³

mg/m³

l/min

- Yes

4.1

Run Number

Blank 1

APPENDIX 2

ORGANICS CLASS I : QUALITY ASSURANCE

2.0

N/A

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Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













NOTE: Uncertainties reported in mg/m ³ are based upon the summation of all Speciated VOCs Measured.

mg/m³

Run 1

Run 1

Run 1

mg/m³

Measured Quantities

2548.52Vm

mg/m³ 1.282

20.0

m³

1.2570

0.00

Run 1

-

Symbol

L

0.0

1.00

Run 1

1.257

% ≤5%

uLr


0.2514

mg/m³ 0.0000

2.00

Run 1

APPENDIX 2

10.00

m³

Measured Quantities

% ≤2%

0.000 uL %

Vm uVm

ORGANICS CLASS I : MEASUREMENT UNCERTAINTY CALCULATIONS

Run 1Units

0.0049

mg/m³

L mg/m³

Lr -

mg/m³


No Requirement

N/A

0.000


0.0049

% 10.00


2.513

%

Lr

- N/A

N/A

Units

N/A

2.513

20.0

mg/m³ N/A

%

Parameter


2.513


Symbol Units

Measured Quantities Symbol

Value

Requirement of StandardUnits

Measured Quantities

1.00

Units


Run 1

mg/m³

mg/m³

%

% N/A

% v/v

Measured Quantities

%

20.0

%

-

Units

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Sample Runs

- -

< <

< <

< <

< <

< <

< <

< <

< <

< <

< <

< <

< <

< <

< <

< <







Coconut Shell Charcoal

Methyl-iso-butyl

1.95

Cyclohexane mg/m³ 1.95

0.39

Total mg/m³ 32.00

Name of Analytical Laboratory RPS


1.95

mg/m³

Tetrahydrofuran mg/m³

Probe Material

GC/MS

ISO 17025 Accredited Analysis? See Executive Summary

1 / 1

Yes

1.95

1.95

mg/m³

1.95

mg/m³ 0.39

o-Xylene mg/m³

3.90

ORGANICS CLASS II : RESULTS SUMMARY


0.39

3.90

3.90

Heptane mg/m³ 1.95

1 / 4

31/05/2018


Units Run 1

CAT-TP-16

Dynamic Dilution Employed

Value

A1


3.90

mg/m³ 3.90

1.95

32.00

Standard CEN/TS 13649

Technical Procedure

A2-14 RTO Outlet

Parameter

1.95

3.90

Ethyl Acetate

3.90 3.90

m + p-Xylene

1.95

Stainless Steel

Cyclohexanone

Acetone

Parameter

1.95

Mean

mg/m³ 1.95

1.95

Hexane

Sample Point I.D.'s

APPENDIX 2

mg/m³

Toluene

Sample Tube Type

Ethanol mg/m³

Methyl Ethyl Ketone mg/m³ 1.95

0.39

1.95

2-Propanol mg/m³

1.95

mg/m³

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< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

< < - < <

- < <



Units Value

Reported

Concentration

(Blank Reviewed)

mg/m³

100.0

Duration

m + p-Xylene 1.0

Lab Result

(Total)

µg

LOD

(Front)

µg

LOD

(Back)

µg

LOD

(Total)

µg

Concentration

mg/m³

5.0 5.0

5.0 10.0

Methyl-iso-butyl Ketone 5.0 5.0 10.0 5.0 5.0 100.0

1.951 1.951

100.0

Heptane 5.0 10.0 1.951

5.0 10.0 5.0

10.0 1.951 1.951

20.0 3.903

1.951 1.951 100.0

Hexane 10.0

1.951

20.0 3.903


(Front)

µg

100.0

Reported

LOD

mg/m³

Adsorption

Efficiency

%

2-Propanol 5.0 10.0 5.0

10.0 20.0

10.0

10.0 5.0 5.0 10.0

-

: 1 1.5

Lab Result

(Back)

µg

5.0

5.0

Acetone 10.0

5.0 5.0 10.0 5.0

1.951 1.951 1.951

10.0 1.951 1.951 1.951

10.0 10.0

20.0 10.0 10.0

0.390

164.0

5.0

10.0 5.0 5.0

3.903

3.903 3.903Ethyl Acetate 10.0

1.0 2.0

20.0 3.903 3.903

Cyclohexane

Ethanol 10.0

10.0

1.951 1.951 1.951 100.0

100.0

5.0

1.0 1.0 2.02.0 1.0 100.0

1.0 2.0 1.0

10.0 10.0 3.903 100.010.0 20.0

100.0

3.903 100.0

1.0 0.390

5.0 10.0

0.390

10.0 10.0 20.0 3.903

3.903 3.903

5.0

5.0

1.951 1.951 1.951

5.0 5.010.0

10.0 20.0

0.390 0.390

1.95110.0 1.951

Tetrahydrofuran 5.0

> 0 and < 32> (sum of ) and < (sum of

1+2+3+4+5+6+7+8+9+10+11+12+13+14)-

164.0 32.004 32.004 -

1.951 100.0

Total

-

1.951

ORGANICS CLASS II : SAMPLING DETAILS

RUN 1

Parameter

Cyclohexanone 5.0 5.0 10.0

100.0

Methyl Ethyl Ketone

100.0

Toluene 5.0

MV

N₂ to Stack Gas Dilution Ratio

mins 30

32.004

-

Sampling Times

APPENDIX 2


13:10 - 13:40

Sampling Dates

o-Xylene 0.390

15/05/2018

Sampling Device

AG2 Reporting Format ELV (mg/m³) Results (mg/m³) Breakdown of Results Exceedance?

Organics Class II 100

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< < - <

< < - <

< < - <

< < - <

< < - <

< < - <

< < - <

< < - <

< < - <

< < - <

< < - <

< < - <

< < - <

< < - <



Hexane 10.0 10.0 20.0 3.903

m + p-Xylene 1.0 1.0 2.0 0.390

Methyl Ethyl Ketone 5.0 5.0 10.0 1.951

Methyl-iso-butyl Ketone 5.0 5.0 10.0 1.951

o-Xylene 1.0 1.0 2.0 0.390

Tetrahydrofuran 5.0 5.0 10.0 1.951

Toluene 5.0 5.0 10.0 1.951

5.0 10.0 1.951

Acetone 10.0 10.0 20.0 3.903

Cyclohexane 5.0 5.0 10.0 1.951

Cyclohexanone 5.0 5.0 10.0 1.951

Ethanol 10.0 10.0 20.0 3.903

Ethyl Acetate 10.0 10.0 20.0 3.903

Heptane 5.0 5.0 10.0 1.951

APPENDIX 2

ORGANICS CLASS II : SAMPLING DETAILS

BLANK 1

Parameter Units Value

Sampling Dates - 15/05/2018




(Front)

µg

Lab Result

(Back)

µg

Lab Result

(Total)

µg

Concentration

mg/m³

2-Propanol 5.0

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Sample Runs

Adsorption Efficiency Acceptable - Yes

Temperature at Sample Tubes Units Run 1

Test Conditions

Ambient Temperature Recorded? - Yes

Units Run 1

Temperature °C 12

Allowable Temperature °C 40


Allowable Adsorption Efficiency % 95

o-Xylene % 100.0

Tetrahydrofuran % 100.0

Toluene % 100.0

Heptane % 100.0

Hexane % 100.0

m + p-Xylene % 100.0

Methyl Ethyl Ketone % 100.0

Methyl-iso-butyl Ketone % 100.0

Acetone % 100.0

Cyclohexane % 100.0

Cyclohexanone % 100.0

Ethanol % 100.0

Ethyl Acetate % 100.0




Adsorption Efficiency Units Run 1

2-Propanol % 100.0

APPENDIX 2

ORGANICS CLASS II : QUALITY ASSURANCE(PAGE 1 OF 2)

Leak Test Results Units Run 1

Mean Sampling Rate l/min 0.400


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Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

Nature of Deviation

N/A

Allowable for Ethanol mg/m³ 3.9 N/A

Run Number


APPENDIX 2

ORGANICS CLASS II : QUALITY ASSURANCE(PAGE 2 OF 2)

Leak Test Results Units Blank 1

0.400

Allowable for Acetone mg/m³

Allowable for Cyclohexane mg/m³

Allowable for Cyclohexanone mg/m³

2.0 N/A

3.9

Allowable for TOTAL mg/m³


3.9 N/A

32.0 10.0

Allowable for o-Xylene mg/m³

Allowable for Tetrahydrofuran mg/m³

Allowable for Toluene mg/m³ 2.0 N/A

0.4 N/A

2.0 N/A

mg/m³

Allowable for Hexane mg/m³

Allowable for m + p-Xylene mg/m³

Allowable for Methyl Ethyl Ketone mg/m³

Allowable for Methyl-iso-butyl Ketone mg/m³

2.0 N/A

3.9 N/A

0.4 N/A

2.0 N/A

2.0 N/A

Allowable for Heptane

Allowable for Ethyl Acetate mg/m³

Sampling Leak Rate l/min 0.000




Allowable for 2-Propanol mg/m³

Blank 1 Allowed

2.0 N/A

2.0 N/A

Expected Sampling Rate l/min

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Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result














% -

% 20.2

uLr

Units Run 1

Vm 0.0051

1.00

Lr mg/m³ 3.200 1.00

Vm m³

uL % -

Measured Quantities Symbol Run 1 Symbol Units

APPENDIX 2

L

≤2%

% 2.50


mg/m³

Units

3.296

Run 1

mg/m³ 6.461

2.500

0.0051

% 20.2

≤5%

% 10.00 No Requirement

Measured Quantities

ORGANICS CLASS II : MEASUREMENT UNCERTAINTY CALCULATIONS

mg/m³ 0.462


uVm m³ 0.0


L

% 2.00



Lr 10.00

6245.34

Measured Quantities Symbol Units Run 1



mg/m³

N/A

mg/m³ 0.6401

mg/m³ 0.4619

mg/m³

% 20.2

6.461

mg/m³

Run 1

%

Measured Quantities

Measured Quantities Units Run 1

mg/m³ 3.2004

6.461

% v/v N/A


- N/A

Run 1

N/A

N/AOverall MU For O₂ Measurement %

- N/A

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Sample Runs

- -

< <






APPENDIX 2

FORMALEHYDE : RESULTS SUMMARY



A2-14 RTO Outlet

Parameter Units Run 1 Mean

Formaldehyde mg/m³ 0.04 0.04

Value

Sample Tube Type

Date of Sample Analysis 29/05/2018

Technical Procedure CAT-TP-16

Number of Sampling Points Used 1 / 4


Name of Analytical Laboratory RPS


DNPH Coated Silica Gel

Dynamic Dilution Employed Yes

CEN/TS 13649

Analytical Laboratory's Procedure A40


Parameter

Standard

See Executive Summary

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EPA Export 18-08-2018:04:04:19


< < - < <


Tube Lot Number and Unique ID: WK18-3398

LOD

(Back)

µg

LOD

(Total)

µg

100.0

Reported

Concentration

(Blank Reviewed)

mg/m³

Reported

LOD

mg/m³

0.040

- 13:55 - 14:25

N₂ to Stack Gas Dilution Ratio

Duration mins 30

m³


0.0050


(Front)

µg

Lab Result

(Back)

µg

Sampling Dates

0.040 0.040

Adsorption

Efficiency

%

Parameter Value

Sampling Times

0.2 0.1

- 15/05/2018

APPENDIX 2

FORMALEHYDE : SAMPLING DETAILS

RUN 1

0.2Formaldehyde 0.1 0.1

Units

: 1 1.5

0.1

Volume Sampled (REF)

Lab Result

(Total)

µg

LOD

(Front)

µg

Concentration

mg/m³

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< < - <


Tube Lot Number and Unique ID: WK18-3398

APPENDIX 2

FORMALEHYDE : SAMPLING DETAILS

BLANK 1

Parameter Units Value

Sampling Dates - 15/05/2018




(Front)

µg

Lab Result

(Back)

µg

Lab Result

(Total)

µg

Concentration

mg/m³

Formaldehyde 0.1 0.1 0.2 0.040

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Sample Runs

APPENDIX 2

FORMALEHYDE : QUALITY ASSURANCE(PAGE 1 OF 2)

Leak Test Results Units Run 1

Mean Sampling Rate l/min 0.400




- Yes

Adsorption Efficiency Units Run 1

Formaldehyde % 100.0


13

Temperature at Sample Tubes Units Run 1

Adsorption Efficiency Acceptable -

Allowable Temperature °C 40

Units


Run 1

Yes

Temperature °C

Allowable Adsorption Efficiency % 95

Test Conditions

Ambient Temperature Recorded? -

Yes

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Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

0.0

Allowed

Allowable for TOTAL mg/m³


l/min 0.020

Yes


Allowable for Formaldehyde

Leak Test Results Units Blank 1

0.400

Sampling Leak Rate l/min 0.010

Allowable Leak Rate

Blank 1

Expected Sampling Rate l/min

0.4

0.0 N/A




FORMALEHYDE : QUALITY ASSURANCE(PAGE 2 OF 2)

-

mg/m³

APPENDIX 2

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Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result














Run 1


mg/m³ 0.008


1.00

mg/m³

10.00

Lr mg/m³ 0.004 1.00

2.500

uVm m³ 0.0

Units Run 1 Run 1

%

L

2.00



%

APPENDIX 2

Run 1

10.00 uLr % -

FORMALEHYDE : MEASUREMENT UNCERTAINTY CALCULATIONS


Measured Quantities Symbol Run 1 Symbol Run 1

Measured Quantities

Vm 0.0050

uL

20.2

% -

Lr

Uncertainty in Measurement Units Sensitivity Coefficient

Units

≤2%

% 2.50

No Requirement

Measured Quantities

Measured Quantities Units

Vm m³ 0.0050

Units

% 20.2

7.93

% N/A

0.0040

%

0.0008

N/A

0.008

Measured Quantities

mg/m³

mg/m³

mg/m³

0.004

N/A

-

0.0006

N/A

0.001

Symbol


L mg/m³


mg/m³

N/A

% 20.2

mg/m³

mg/m³ 0.008

% v/v

%

Units Run 1

- N/A

≤5%

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Sample Runs

- -

- -

- -

- -

- -






Span Gas Type Propane In Synthetic Air (5 Grade)


Heated Head Filter Used

Span Gas Set Point (ppm)

Span Gas Expiry Date

4.60

N/A

Yes

24.1

2.7

Concentration

g/hr

86.1


Uncertainty

Value

Run 1

APPENDIX 2

Mass Emission

Synthetic Air (5 Grade)

180°C

Standard


A1

Mean

0.46

A2-14 RTO Outlet

TOTAL VOCs (as CARBON): RESULTS SUMMARY

Sample Point I.D.'s

Technical Procedure

1 / 1

INPUT

Uncertainty


Gas Cylinder Concentration (ppm)

Span Gas Start Pressure (bar)

Span Gas Reference Number

100

Span Gas Uncertainty (%)

Parameter Units

±mg/m³

4.60

CAT-TP-20

2.7

Parameter

Heated Line Temperature

INPUT

mg/m³

0.46

EN 12619:2013

86.10

0.1µm Glass Fibre

24.1

Filtration Type / Size

±g/hr

Zero Gas Type

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Graphical Trend of Data

TOTAL VOCs (as CARBON): DATA TREND

APPENDIX 2

COVER ME WITH CHART/S

0.0

2.0

4.0

6.0

8.0

10.0

12.0

14.0 1

6:2

0

16

:21

16

:22

16

:23

16

:24

16

:25

16

:26

16

:27

16

:28

16

:29

16

:30

16

:31

16

:32

16

:33

16

:34

16

:35

16

:36

16

:37

16

:38

16

:39

16

:40

16

:41

16

:42

16

:43

16

:44

16

:45

16

:46

16

:47

16

:48

16

:49

16

:50

Co

nce

ntr

atio

n (

mg/

m³)

Total VOCs At Reference Conditions

- Run 1

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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

- - -

- - -

- 15/05/2018

- Yes

Units

0.20

Instrument Range ppm 100

0.20

Sampling Dates

Units

Zero Drift Acceptable

Span Drift

Zero Down Sampling Line (Post) ppm

Span Down Sampling Line (Post)

Zero Down Sampling Line (Pre)

Run Ambient Temperature Range 11

CA

L 1

ppm 82.00

Span Gas Value

Run 1

Run 1

Sampling Times -

ppm

ppm

4.31

Zero Drift

0.00ppm

4.31

Units

86.1

Span Down Sampling Line (Pre)

Run 1

Parameter

Yes

CA

L 1

ppm -2.40

16:20 - 16:50

APPENDIX 2

Span Drift Acceptable

Allowable Span Drift ± ppm

TOTAL VOCs (as CARBON): SAMPLING DETAILS & QUALITY ASSURANCE

Nature of Deviation


Allowable Zero Drift ± ppm

Run 1


Units

ppm

84.40

°C

Run Number

Test Conditions

-

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k =

mg/m³

-

N/A

RUN 1 Units

Result of Compliance with Uncertainty Requirement in M2 COMPLIANT

0.23

RUN 1

Losses in the line (leak) 1.97 % of value

Uncertainty of calibration gas 2.00 % of value

Units

mg/m³

Uncertainty of calibration gas 0.05

Atmospheric pressure dependence 0.01 mg/m³

Lack of fit 0.04

Lower of [A] or [B]

mg/m³

Measurement uncertainty

0.00

mg/m³ (REF)

Dependence on voltage

4.60 mg/m³


Result

mg/m³

Losses in the line (leak) 0.05

0.20

2.00

15.0 mg/m³

Cal gas conc. 138.3

% of value/kPa

Combined interference

mg/m³

0.06

seconds

Number of readings in measurement

Atmospheric pressure dependence 0.30

% full scale

Conversion 1.61


Standard deviation of repeatability at span level

% full scale

Deviation from linearity 0.46

Volume or pressure flow dependence

Standard deviation of repeatability at zero mg/m³

ppm to mg/m³

MCERTS Range [B]

use rep at span

0.45

Performance characteristic

Performance characteristics

% full scale

Span drift 0.00

% of full scale

mg/m³

Drift 0.00

1.40

mg/m³

mg/m³

0.00

-

ppm

15.0

% range

0.50 % full scale/10V

mg/m³

Cal gas conc. 86.1 ppm

Range Used [A]

mg/m³

% of value

Zero drift

Measured concentration

TGN M2 Allowable MU

Limit value

%

4.60 mg/m³ (STP, dry)

mg/m³

1.60

15.0

50.0

RUN 1 Units

Response time 45

Performance characteristics RUN 1 Units

% full scale/10K

% full scale


Repeatability at zero

TOTAL VOCs (as CARBON): MEASUREMENT UNCERTAINTY CALCULATIONS

Units

% of Value

RUN 1

% at ELVN/A

Expanded uncertainty (with O₂) - at 95% Confidence

N/A

% at ELVExpanded uncertainty (with O₂) - at 95% Confidence N/A

Overall Allowable uncertainty (with O₂) - at 95% Confidence

Requirement for SRM is that Uncertainty should be <15% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 15% + the

uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.

Result of Compliance with Uncertainty Requirement in M2 -

0.92 % at ELV

Units

mg/m³ (REF)

% of Value

RUN 1

Expanded uncertainty (no O₂) - at 95% Confidence

0.46

Expanded uncertainty (no O₂) - at 95% Confidence 9.95

Overall Allowable uncertainty (no O₂) - at 95% Confidence 15.0

mg/m³

Combined interference (from MCERTS Certificate) 0.04

mg/m³

% at ELV

Ambient temperature dependence

Expanded uncertainty 1.96 0.46 mg/m³

Uncertainty corrected to std conds. (O₂)

0.00

30

0.00

Repeatability at span level


Range Used 100.0

160.6

APPENDIX 2

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Sample Runs

- -

- -

- -

- -

- -


NOTE: Dilution performed to achieve correct span value





Span Gas Type Nitrogen Monoxide

Technical Procedure

A2-14 RTO Outlet

Parameter Units Mean


Mass Emission

APPENDIX 2

OXIDES OF NITROGEN (as NO₂): RESULTS SUMMARY

1 / 4

8.6

Span Gas Expiry Date

1.64

Stainless Steel


415.9

Yes

16.8

CYL 12.0146

3.21

22/03/2020



2

A1



CAT-TP-21

g/hr

Probe Material

Span Gas Start Pressure (bar) 100


16.8

1.64

Uncertainty ±mg/m³

Date & Result of Last Converter Check

Zero Gas Type Nitrogen (5 Grade)


Sample Point I.D.'s

Run 1

EN 14792

0.1µm Glass Fibre

Uncertainty

8.6

Value

18/04/2018 - 96.1%


Parameter


Standard

180°C

3.21

±g/hr

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APPENDIX 2

OXIDES OF NITROGEN (as NO₂): DATA TREND

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

10.0 1

6:2

0

16

:21

16

:22

16

:23

16

:24

16

:25

16

:26

16

:27

16

:28

16

:29

16

:30

16

:31

16

:32

16

:33

16

:34

16

:35

16

:36

16

:37

16

:38

16

:39

16

:40

16

:41

16

:42

16

:43

16

:44

16

:45

16

:46

16

:47

16

:48

16

:49

16

:50

Co

nce

ntr

atio

n (

mg/

m³)

Oxides of Nitrogen (as NO₂) At Reference Conditions

- Run 1

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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

± ppm 4.87

< °C

ppm -1.20

97.5


Units

-

Run 1

Zero at Analyser (Post) ppm -1.20

Sampling Dates


APPENDIX 2

0.00

Units

OXIDES OF NITROGEN (as NO₂): SAMPLING DETAILS & QUALITY ASSURANCE

Zero Drift

Zero at Analyser (Pre)

- Yes

Units

Instrument Range

4.0

15/05/2018

ParameterC

AL

1

Sampling Times - 16:20 - 16:50

Span at Analyser (Pre) ppm 97.50

Average Temperature °C 1.2

250

Span Gas Value ppm

Run 1


ppm

± ppm


Run Ambient Temperature Range 11

4.87

Test Conditions

°C


Yes

ppm -2.50

Span Drift

-

- Yes

Units Run 1

CA

L 1

Nature of Deviation

Run 1

Run Number

Conditioning Unit Temperature

Span at Analyser (Post) ppm 95.00

Allowable Zero Drift

Allowable Span Drift

Run 1

Units


ppm

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EPA Export 18-08-2018:04:04:19

k =

use rep at span

0.40

% of full scale

0.52 mg/m³

Drift

513.1

200.0

OXIDES OF NITROGEN (as NO₂): MEASUREMENT UNCERTAINTY CALCULATIONS

% full scale/10K

Performance characteristics RUN 1

Repeatability at span level


Units

-

Repeatability at zero 0.40

125.0 mg/m³

Cal gas conc.

mg/m³

250.0

Response time 60

mg/m³

125.0

ppm

Range Used [A]

0.07

N/A

N/A % at ELV

Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A % at ELV

1.64

ppm

Conversion 2.05 ppm to mg/m³

MCERTS Range [B]

Units

% of Value195.62

% full scale

% full scale

seconds

Units

mg/m³


% full scale/10V

96.1

Ration NO / NO₂


TGN M2 Allowable MU

Limit value

mg/m³

% range

% of value

mg/m³ (REF)

Converter efficiency


mg/m³

Result

-

RUN 1

mg/m³

0.00Converter efficiency


Units

Expanded uncertainty (with O₂) - at 95% Confidence

Result of Compliance with Uncertainty Requirement in M2

-1.42

0.05

mg/m³

Atmospheric pressure dependence 0.30 % of value/kPa

0.72

Span drift 0.00 % full scale

Volume or pressure flow dependence 0.40

%

Range Used

%

Lower of [A] or [B]

30

mg/m³

% full scale

Deviation from linearity

Standard deviation of repeatability at zero

1.61 % at ELV


mg/m³ (REF)

mg/m³ (STP, dry)

5

0.18

mg/m³

0.60

%

% at ELV



10.0

0.02

Lack of fit

Uncertainty of calibration gas

97.5

1.64

mg/m³

RUN 1

RUN 1

3.21

mg/m³

Atmospheric pressure dependence 0.11 mg/m³

Overall Allowable uncertainty (no O₂) - at 95% Confidence 10.0

% of Value


Units

mg/m³

Uncertainty corrected to std conds. (O₂) 3.21


mg/m³

Standard deviation of repeatability at span level


Zero drift -1.23



-

Expanded uncertainty 1.96

Uncertainty of calibration gas blending 0.01


0.03

% of value

% of value

0.21

Expanded uncertainty (with O₂) - at 95% Confidence N/A

Cal gas conc. 200.0

RUN 1


2.00

Losses in the line (leak)



mg/m³

Combined uncertainty 1.64

APPENDIX 2

Units

% of value

mg/m³

mg/m³

mg/m³




0.40

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EPA Export 18-08-2018:04:04:19

Sample Runs

- -

- -

- -

- -

- -







Span Gas Type Sulphur Dioxide



SULPHUR DIOXIDE: RESULTS SUMMARY

Mass Emission

CAT-TP-21

Zero Gas Type

Mean


105.9

1.20

±mg/m³


g/hr 6.3

Span Gas Expiry Date 22/03/2020

180°C

100

APPENDIX 2

Uncertainty

Parameter



Nitrogen (5 Grade)

Yes

Span Gas Start Pressure (bar)

Standard TGN M21

Uncertainty

2



27.7

5.28

6.3

0.1µm Glass Fibre


5.28


A2-14 RTO Outlet


Run 1

Parameter Value

Units

Technical Procedure

CYL 12.0146

1 / 4

±g/hr 27.7

1.20

1 / 1


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APPENDIX 2

SULPHUR DIOXIDE: DATA TREND

0.0

5.0

10.0

15.0

20.0

25.0 1

6:2

0

16

:21

16

:22

16

:23

16

:24

16

:25

16

:26

16

:27

16

:28

16

:29

16

:30

16

:31

16

:32

16

:33

16

:34

16

:35

16

:36

16

:37

16

:38

16

:39

16

:40

16

:41

16

:42

16

:43

16

:44

16

:45

16

:46

16

:47

16

:48

16

:49

16

:50

Co

nce

ntr

atio

n (

mg/

m³)

Sulphur Dioxide At Reference Conditions

- Run 1

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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

Sampling Dates

Run Ambient Temperature Range

35.0


15/05/2018


< °C 4.0

CA

L 1

± ppm

Conditioning Unit Temperature


Yes

Units Run 1

-

ppm

Units

1.75

Run Number


°C 11

Average Temperature

ppm

Span Drift

Zero Drift

-

SULPHUR DIOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE


Yes


1.75

Parameter

Nature of Deviation

Span Drift Acceptable -

APPENDIX 2

Units Run 1

°C

34.60

0.20

± ppm



Run 1Units


Yes

Zero Down Sampling Line (Post) ppm

ppm -0.20

Run 1

0.00

Units Run 1

-

CA

L 1

200

ppm

1.2

-

ppm -0.60

ppm


Instrument Range

Span Gas Value

Test Conditions

34.00

ppm

16:20 - 16:50Sampling Times

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EPA Export 18-08-2018:04:04:19

k =

mg/m³

1.40

mg/m³ (REF)

5.28

% at ELV

Overall Allowable uncertainty (no O₂) - at 95% Confidence 10.0 % at ELV

seconds

ppm

Zero drift

35.0


Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELV

% of Value

mg/m³

Uncertainty of calibration gas blending 0.01 mg/m³

Uncertainty of calibration gas 0.01 mg/m³

RUN 1 Units

Measurement uncertainty Result 1.20 mg/m³

Combined uncertainty 2.69

Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -

RUN 1 Units

Units


Range Used [A] 571.1


% full scale

Span drift -1.73

mg/m³

160

Expanded uncertainty 1.96 5.28

mg/m³

Atmospheric pressure dependence

% of Value


% of value


Conversion 2.86

% of value

Cal gas conc. 100.0

10.0

Repeatability at span level 0.40

30

Expanded uncertainty (with O₂) - at 95% Confidence N/A


Response time

2.00

mg/m³


mg/m³

% full scale


TGN M2 Allowable MU


SULPHUR DIOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

-0.58

Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A % at ELV

% full scale

Result of Compliance with Uncertainty Requirement in M2 N/A -

mg/m³ (REF)

mg/m³

0.01

Dependence on voltage 0.05

Ambient temperature dependence 0.02



RUN 1


mg/m³

% full scale

Cal gas conc.

1.00


1.20

mg/m³


mg/m³

100.0

Range Used 200.0


ppm to mg/m³

Uncertainty of calibration gas blending

Limit value

APPENDIX 2

mg/m³ (STP, dry)

% range

Units

%

mg/m³

Volume or pressure flow dependence 0.01 mg/m³

% full scale/10V


0.40

Drift

% of value/kPa


0.40

Standard deviation of repeatability at span level 0.07

Performance characteristic RUN 1 Units

Standard deviation of repeatability at zero use rep at span mg/m³

2.23 mg/m³

RUN 1

Lower of [A] or [B] 460.0

mg/m³

Uncertainty corrected to std conds. (O₂)

0.38

-

% full scale/10K


Combined interference (from MCERTS Certificate)

% of value

ppm

-0.35

MCERTS Range [B] 460.0

mg/m³

Lack of fit

% of value

% of full scale

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EPA Export 18-08-2018:04:04:19

Sample Runs

- -

- -

- -

- -

- -







Span Gas Type Carbon Monoxide

Uncertainty

Gas Cylinder Concentration (ppm) 100.9

Technical Procedure

Parameter

Sample Point I.D.'s

Mean

CARBON MONOXIDE: RESULTS SUMMARY

6.1


Run 1

1.23

1 / 4

Uncertainty

Value

6.1


APPENDIX 2


Mass Emission

Yes


Span Gas Uncertainty (%) 2

EN 15058

1 / 1

1.23

CAT-TP-21

Zero Gas Type

6.4

Standard


Parameter

g/hr

A2-14 RTO Outlet





1.17

22/03/2020Span Gas Expiry Date

Units


6.4

±mg/m³

180°C

A1

CYL 12.0146

0.1µm Glass Fibre

Nitrogen (5 Grade)

±g/hr

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APPENDIX 2


CARBON MONOXIDE: DATA TREND

0.0

5.0

10.0

15.0

20.0

25.0

16

:20

16

:21

16

:22

16

:23

16

:24

16

:25

16

:26

16

:27

16

:28

16

:29

16

:30

16

:31

16

:32

16

:33

16

:34

16

:35

16

:36

16

:37

16

:38

16

:39

16

:40

16

:41

16

:42

16

:43

16

:44

16

:45

16

:46

16

:47

16

:48

16

:49

16

:50

Co

nce

ntr

atio

n (

mg/

m³)

Carbon Monoxide At Reference Conditions

- Run 1

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EPA Export 18-08-2018:04:04:20

Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

Zero Drift Acceptable -

ppm

Span Gas Value

CA

L 1

Units

Units

34.80

- 15/05/2018

Instrument Range

Sampling Dates

CARBON MONOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE

Run 1

Zero Drift

Units

16:20 - 16:50

APPENDIX 2

Span Drift

ppm

Parameter

ppm

Run 1

Zero at Analyser (Post)

Conditioning Unit Temperature Run 1

°C 1.2

ppm

Run 1

Run Number

Zero at Analyser (Pre)

Average Temperature

Allowable Temperature < °C 4.0

0.20

Yes

Run 1

Test Conditions

1.75

1.75

Units

35.0

Nature of Deviation

Span at Analyser (Pre)

Units

ppm -0.20

-Temperature Acceptable


ppm

0.20

-

Yes

± ppm

Allowable Span Drift ± ppm




200

CA

L 1

ppm 0.00

°C 11

Span at Analyser (Post)

35.00

- YesSpan Drift Acceptable

Sampling Times

ppm

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EPA Export 18-08-2018:04:04:20

k =

Measurement uncertainty Result

mg/m³

Uncertainty corrected to std conds. (O₂) 1.23

RUN 1 Units

mg/m³


-

RUN 1

mg/m³

mg/m³

mg/m³


Uncertainty of calibration gas 0.01 mg/m³

RUN 1 Units

mg/m³ (REF)

Ambient temperature dependence 0.01 mg/m³


Units

0.63 mg/m³


Result of Compliance with Uncertainty Requirement in M2 N/A -

Expanded uncertainty (with O₂) - at 95% Confidence N/A % of Value

Requirement for SRM is that Uncertainty should be <6% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 6% + the uncertainty

associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.


Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELV

Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A

% full scale/10V


Uncertainty of calibration gas blending 1.40 % of value



Zero drift 0.57

mg/m³

Range Used

95.0

mg/m³

Cal gas conc. 43.7

Response time

Repeatability at span level 0.40 % full scale


% range

-



0.40

Units

ppm

Conversion 1.25

mg/m³

Lower of [A] or [B] 95.0


% of full scale



Limit value


1.17

% of Value

0.05

% at ELV

Overall Allowable uncertainty (no O₂) - at 95% Confidence 6.0 % at ELV


0.00Volume or pressure flow dependence

60

% full scale

2.00 % of valueUncertainty of calibration gas

0.41


300.0 mg/m³ (REF)

6.0

mg/m³

Losses in the line (leak) 0.00 mg/m³

mg/m³


ppm to mg/m³

MCERTS Range [B]

0.14 mg/m³

Units

Standard deviation of repeatability at zero use rep at span mg/m³

Standard deviation of repeatability at span level 0.07

Drift

mg/m³


% at ELV

mg/m³


Lack of fit 0.20

200.0 ppm

Range Used [A] 249.8 mg/m³

Cal gas conc. 35.0

% full scale/10K

Combined interference 0.73

% of value

Performance characteristic RUN 1

APPENDIX 2

CARBON MONOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

%

1.17 mg/m³ (STP, dry)

TGN M2 Allowable MU

RUN 1

seconds

30

% full scale

Span drift -0.57 % full scale

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Sample Runs

- -

- -




- -

Span Gas Type Carbon Dioxide

3.86

0.24


Stainless Steel


1 / 1



0.24

Technical Procedure

Yes



Gas Cylinder Concentration (% v/v)


Value

16.02

A2-14 RTO Outlet

Parameter

CAT-TP-21

180°C

Concentration % v/v 3.86

Nitrogen (5 Grade)


0.1µm Glass Fibre



Standard ISO 12039

1 / 4

Zero Gas Type

CYL 6.0042

Probe Material

Units

±% v/vUncertainty

Parameter

Span Gas Uncertainty (%) 2.00

APPENDIX 2

CARBON DIOXIDE: RESULTS SUMMARY

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EPA Export 18-08-2018:04:04:20


APPENDIX 2

CARBON DIOXIDE: DATA TREND


0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

10.0 1

6:2

0

16

:21

16

:22

16

:23

16

:24

16

:25

16

:26

16

:27

16

:28

16

:29

16

:30

16

:31

16

:32

16

:33

16

:34

16

:35

16

:36

16

:37

16

:38

16

:39

16

:40

16

:41

16

:42

16

:43

16

:44

16

:45

16

:46

16

:47

16

:48

16

:49

16

:50

Co

nce

ntr

atio

n (

% v

/v)

Carbon Dioxide Carbon Dioxide

- Run 1

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EPA Export 18-08-2018:04:04:20

Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

0.80



-

Run 1

Yes

Yes

°C

Span Gas Value % v/v 16.02

°C 1.2


Conditioning Unit Temperature Units

Average Temperature

Parameter Units

11

Zero Down Sampling Line (Post) % v/v 0.00

% v/v 0.00

± % v/v

Units

± % v/v

APPENDIX 2

Units

0.00

CA

L 1


Allowable Temperature < °C 4.0

- Yes

Zero Drift

- 16:20 - 16:50

Instrument Range % v/v 30

Run 1

Sampling Dates -

% v/v 15.94





% v/v

Run 1

Run 1

CARBON DIOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE

CA

L 1

15/05/2018

15.90



Sampling Times

-

0.80

-0.04

Span Drift




Run 1

% v/v

% v/v

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EPA Export 18-08-2018:04:04:20

k =


TGN M2 Allowable MU

Limit value

Drift

%vol


N/A

%

3.86 %vol

%vol

APPENDIX 2

Zero drift 0.00

%vol


Units

Measurement uncertainty Result 3.86 %vol

Units

Standard deviation of repeatability at span level %vol

-0.01

% full scale


RUN 1


%volCombined uncertainty 0.12

%vol

RUN 1

%vol

Units

% of Value

%vol

% of value/kPa

Cal gas conc. 16.0

%vol

Dependence on voltage 0.05 %vol

%vol


0.40 % full scale

Repeatability at span level 0.40

Performance characteristic Units


seconds

Number of readings in measurement 30 -


%vol

25.0

% of value

%vol

CARBON DIOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

% of value

Lack of fit 0.07

0.30

RUN 1

Range Used 30.0

2.00

% full scale

RUN 1


Dependence on voltage 0.40 % full scale/10V



%vol

%vol

% full scale/10K

Combined interference 0.00 % range




% full scale

0.00

0.40 % of full scale

0.07

%vol


Span drift -0.25


use rep at span

Units

Response time 160


Standard deviation of repeatability at zero


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EPA Export 18-08-2018:04:04:20

Sample Runs

- -

- -

- -





20.46




Span Gas Type Synthetic Air (5 Grade)

CAT-TP-21

Parameter



EN 14789

Technical Procedure

Mean

0.1µm Glass Fibre

20.46


Units Run 1



Gas Cylinder Concentration (% v/v) 21.02


Value

Standard

Parameter

180°C

0.55

Span Gas Uncertainty (%) 2

Zero Gas Type Nitrogen (5 Grade)

A2-14 RTO Outlet

0.55

CYL 11.0345

Uncertainty ±% v/v

Heated Head Filter Used Yes


Concentration % v/v

APPENDIX 2

OXYGEN: RESULTS SUMMARY

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EPA Export 18-08-2018:04:04:20


OXYGEN: DATA TREND

APPENDIX 2


0.0

5.0

10.0

15.0

20.0

25.0 1

6:2

0

16

:21

16

:22

16

:23

16

:24

16

:25

16

:26

16

:27

16

:28

16

:29

16

:30

16

:31

16

:32

16

:33

16

:34

16

:35

16

:36

16

:37

16

:38

16

:39

16

:40

16

:41

16

:42

16

:43

16

:44

16

:45

16

:46

16

:47

16

:48

16

:49

16

:50

Co

nce

ntr

atio

n (

% v

/v)

Oxygen Oxygen

- Run 1

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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

Average Temperature

Conditioning Unit Temperature Units

Span Gas Value

- 15/05/2018

Allowable Temperature < °C

0.00

Zero at Analyser (Post) % v/v 0.14

1.2

Allowable Zero Drift ± % v/v


Instrument Range

°C

% v/v 21.02

16:20 - 16:50

Sampling Dates

4.0

0.14

CA

L 1

Zero at Analyser (Pre) % v/v

Sampling Times -

APPENDIX 2

% v/v

OXYGEN: SAMPLING DETAILS & QUALITY ASSURANCE






Run 1

0.03

11

Span Drift Acceptable - Yes

Span at Analyser (Post) % v/v

Run 1

% v/v

21.05

Span at Analyser (Pre)


± % v/v 1.05

% v/v

Run Number

Run 1

Run Ambient Temperature Range °C

-

- Yes

Span Drift Units

21.02

25

Yes

Units Run 1

Nature of Deviation

1.05

CA

L 1

% v/v

Zero Drift

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EPA Export 18-08-2018:04:04:20

k =

-0.07 % full scale/10K



Volume or pressure flow dependence 0.20 % of full scale

N/A %vol

6.0 %

Expanded uncertainty (no O₂) - at 95% Confidence 2.70 % of Value

Expanded uncertainty 1.96 0.55 %vol

RUN 1 Units

%vol


% range


% full scale

20.46

RUN 1

% of value

% full scale/10V

% of value

%vol

RUN 1

Deviation from linearity

% full scale

Span drift


0.14


Range Used


-


0.16

%vol

% of value

Zero drift

0.02

seconds

0.00

Standard deviation of repeatability at zero use rep at span %vol

Standard deviation of repeatability at span level 0.01 %vol

Lack of fit 0.02


Result 20.46

RUN 1 Units

Limit value

TGN M2 Allowable MU

%volVolume or pressure flow dependence 0.00

Units

Drift 0.10

Units

Response time 60

0.67

Repeatability at span level 0.04 % full scale

%vol


%vol


Requirement for SRM is that Uncertainty should be 0.5%vol absolute or 6% relative whichever is the lower, on a dry gas basis. Ref EA TGN M2.

%vol


25.0

% full scale

%vol

Cal gas conc. 21.0

Combined interference 0.56

RUN 1

-0.01 %vol

Combined uncertainty 0.28 %vol

Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -

Combined interference (from MCERTS Certificate) 0.08 %vol

Dependence on voltage 0.00 %vol

Losses in the line (leak) 0.00 %vol

Uncertainty of calibration gas 0.24 %vol

APPENDIX 2

OXYGEN: MEASUREMENT UNCERTAINTY CALCULATIONS

Number of readings in measurement 30


Units

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Installation Name & Address For inspection purposes only. · ISO 17025 Accreditation Number: 1668...

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