Industrial Wastewater Discharge Monitoring PSNH Merrimack ...€¦ · l GZA AR-1312....

l AR-1312

GZA Inc GeoEnvironmental

Road Harvey 380 Manchester

middot HampshireNew 03103-3347 603-623-3600

603-624-9463 FAX gzacom www

16 January 2012 No File 04002930700

Kudrick Bruce Mr Commission Sewer Hooksett Superintendent

Hooksett of Town Drive Egawes 1

Hampshire New Hooksett 03106

Engineers and

Scientsu

Monitoring Discharge Wastewater Industrial Re (PSNH) Hampshire New of Service Public

Station Merrimack Hampshire New Bow

Bruce Dear

Analytical attached the submit to pleased is Inc GeoEnvironmental GZA PSNH of behalf Ori The (WWTS) system treatment wastewater advanced technologically PSNHs from Report The weeksseveral for criteria design the with accordance in operating been now has WWTS the of representative are 5 January on sampling from obtained results analytical attached 2012

treated the of characteristics The generated wastewater treated (FGD) Desulfurization Gas Flue forward going t steniconsbe to expected are wastewater

Town the that request respectfully we a tdaanalytical representative available of consideration In as requirements sampling month first the satisfy to report analytical attached the accept

No Agreement Disposal Waste PSNHs of 11 Condition Special in established WDA-001

NOTATION ANALYTICAL

on interference matrix overcome to techniques analytical specialized requires wastewater D FGan offer We this of unaware be may laboratories analytical Many analysis metals trace some

their to a and site web (EPAs) Agencys Protection Environmental the from below excerpt link guidance further contains that procedure draft

WASTEWATER FGD OF SIS ANALYLABORATORY

interferences matrix cause to known constituents contain can systems FGD from Wastewater (ICP-MS) spectrometry mass -plasma coupled inductively during that observed has EPA

cause may wastewater the in present commonly elements certain wastewater FGD of analysis of elements certain of quantization andor detection the bias that interferences polyatomic at elements trace measuring when significant become may interferences potential These interest

range parts-per-billion low the in concentrations

An Equal Opportunity Employer WFNIH

January 16 2012 Page2

Town ofHooksett New Hampshire File No 04002930700

As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed a standard operating procedure (SOP) that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs Standard Operating Procedure Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K)

We trust that this submittal adequately address your informational needs Should you have any questions please contact me at 232-8744

Very truly yours

GZA GEOENVIRONMENTAL INC

Ronald A Breton PE Principal

RABtmd p04jobs0029300$0400l930700lworklsampling and reportinefeportslfinal 2930700 cover letters 011612docx

Attachment(s)

SUMMARY ANALYTICAL DATA Public Service Company ofNew Hampshire

Merrimack Station Bow New Hampshire

PARAMETER RESULTS (m2L) 1052012 Alkalinity 180 Aluminum 00411 Ammonia 092 Antimony 0000520 Arsenic 000498 Barium 0300 Beryllium 0000522 BOD lt6 Cadmium 0000207 Calcium 5050 Chloride 11000 Chlorine (Total Residual) lt005 Chromium (T) lt 000050 COD 130 Copper lt000050 Cyanide(T) 002 Fluoride IO Iron lt 0050 Lead lt0000200 Manganese 0293 Mercwy 00000105 IMolybdenum 0140 Nitrate 100 Nickel 000803 OampG lt 5 pH 73 Selenium 0074 Silver lt 0000100 Sodium 2774 Sulfate 1200 Sulfide lt 01 Sulfite lt 2 TDS 21 000 Thallium 000664 TSS 14 TIO ND(l) Zinc lt 0001 VOCEPA624 (2)

Semi VOCs 625 ND(3) Phenolic Compounds lt03 PCBsI ND(4)

NOTES

I No TIO compounds were detected above 001 mgL 2 One compound was detected by Method 624 Toluene at 2 microgL 3 Semi VOCs were not detected by Method 625 above detection limits ( I microgL and 5 microgL depending on

parameter and 50 microgL for beozoic acid) 4 PCB compounds analyzed by method 608 were not detected at concentrations greater than 03 microgL

P-Q4JobiDQ2900(1)4009l07ooWori(SJMPUNO ANORElOkTfNGIMTAII

M00Hl0100MStTSOll6 t2dMPOTWtIOftilll t Ulffi OZA GeoEnvironmental Inc

__1AA____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l_~

Arthur Auclair

Northeast Utilities

97 River Road

Bow NH 03304

Subject Laboratory Report

Eastern Analytical Inc ID 106677

Client Identification Merrimack Station

Date Received 152012

Dear Mr Auclair

Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QNQC Program Unless otheiwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters

The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otheiwise noted lt less than followed by the reporting limit gt greater thanmiddot followed by the reporting limit R Recovery

Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)

The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory

If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date

We appreciate this opportunity to be of service and look foiward to your continued patronage

Sincerely

~~ l-1deg3-12shyDate of pages (excluding cover letter)Lorraine Olashaw Lab Director

11middot11middotetilthccm

SAMPLE CONDITIONS PAGE EAi ID 106677

Client Northeast Utilities

Client Designation Merrimack Station

Temperature upon receipt (degC) 47 Received on ice or cold packs (YesNo) y Acceptabre temperature range (degC) 0-6

Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)

10667701 Treat Tank Eff Composite 1512 1512 aqueous Adheres to Sample Acceptance Policy

10667702 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy


~middotmiddot

Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint =-gnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an as received basis

All results containedin this report relate only to the above listed samples

References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates IVA and IVB 4) Hach Water Analysis Handbook 2nd edition 1992

eastern analytical inc wwweailabscom Phone (603) 228-0525 1

bull LABORATORY REPORT EAi I 0 106677



Sample ID

Lab Sample ID Matrix

Date Sampled Date Received Units

Date of Analysis Analyst Method Dilution Factor

Chloromethane Vinyl chloride Bromomethane Chloroethane T richlorofluoromethane Acrolein Acetone 11-0ichloroethene Methylene chloride Carbon disulfide Acrylonitrile Methyl-I-butyl ether(MTBE) trans-12-Dichloroethene Vinyl acetate 11-Dichloroethane cis-12-Dichloroethene 2-Butanone(MEK) Chloroform 1 11-Trichloroethane Carbon tetrachloride Benzene 12-Dichloroethane Trichloroethene 12-Dichloropropane Bromodichloromethane 2-Chloroethylvinylether 4-Methyl-2-pentanone(MIBK) cis-13-Dichloropropene Toluene trans-13-Dichloropropene 1 12- Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene mp-Xylene o-Xylene Styrene Bromoform 1122-Tetrachloroethane 13-Dichtorobenzene 14-Dichlorobenzene 12-Dichlorobenzene 4-Bromofluorobenzene (surr) 12-Dichlorobenzene-d4 (surr) Toluene-d8 (surr)

Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt50 lt10 lt2

lt 10 lt2 lt2

lt10 lt2 lt2 lt2 lt 1 lt2 lt2 lt2 lt2 lt2

lt 10 lt2

2 lt2 lt2

lt 10 lt2 lt2 lt2 lt 1 lt 1 lt 1 lt 1 lt2 lt2 lt 1 lt 1 lt 1

98R 90R

100R


QC REPORT EAi ID 106677



Parameter Name Blank LCS LCSD Analysls Date Units Limits RPO Method

Chloromethane lt5 19 (97 R) 21 (105 R) (8 RPO) 162012 ug1 0-273 20 624 Vinyl chloride lt2 18 (91 R) 20 (101 R) (10 RPO) 162012 ug1 0- 251 20 624 Bromomethane lt2 21 (105 R) 23 (113 R) (7 RPO) 162012 ug1 0 - 242 20 624 Chloroethane lt5 19 (95 R) 20 (101 R) (6 RPO) 162012 ug1 14 - 230 20 624 Trichlorofluoromethane lt5 17 (84 R) 18 (88 R) (5 RPO) 162012 ug1 17 - 181 20 624 Acrolein lt50 lt 50 (RNA) lt 50 ( R) ( RPO) 162012 ug1 624 Acetone lt 50 lt50 (78 R) lt 50 (90 R) (14 RPO) 162012 ug1 624 1 1-Dichloroethene lt 1 17 (83 R) 18 (89 R) (7 RPD) 162012 ug1 0- 234 20 624 Methylene chloride lt5 18 (88 R) 19 (93 R) (6 RPD) 162012 ug1 0 - 221 20 624 Carbon disulfide lt5 17 ( R) 19 ( R) ( RPD) 162012 ug1 624 Acrylonitrie lt 50 lt 50 (R) lt 50 ( R) ( RPD) 162012 ug1 624 Methyl-t- butyl ether(MTBE) lt 10 20 (R) 20 ( R) ( RPO) 162012 ug1 624 trans-12-0ichloroethene lt2 18 (89 R) 18 (92 R) (3 RPD) 162012 ug1 54 - 156 20 624 Vinyl acetate lt 10 30(R) 30 ( R) ( RPD) 162012 ug1 624 1 1-Dichloroethane lt2 19 (93 R) 20 (98 R) (5 RPO) 162012 ug1 59 - 155 20 624 cis-12-0ichloroethene lt2 19 ( R) 20 ( R) ( RPD) 162012 ug1 624 2-Butanone(MEK) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624 Chloroform lt2 19 (94 R) 20 (99 R) (5 RPO) 162012 ug1 51 - 138 20 624 1 1 1-Trichloroethane lt2 18 (91 R) 19 (97 R) (6 RPD) 162012 ug1 52 - 162 20 624 Carbon tetrachloride lt2 18 (91 R) 19 (95 R) (4 RPO) 162012 ug1 70 - 140 20 624

Benzene lt 1 19 (97 ooR) 20 (102 R) (5 RPO) 162012 ug1 37 - 151 20 624 12-0ichloroethane lt2 18 (91 ooR) 19 (94 R) (3 RPO) 162012 ug1 49 shy 155 20 624 Trichloroethene lt2 19 (93 R) 20 (98 R) (5 RPO) 162012 ug1 71 - 157 20 624 12-Dichloropropane lt2 19 (95 R) 20 (98 R) (3 RPD) 162012 ug1 0- 210 20 624 Bromodichloromethane lt2 19 (96 R) 20 (100 R) (4 RPD) 162012 ug1 35 - 155 20 624 2-Chtoroethylvinylether lt2 23(115R) 24 (121 R) (5 RPD) 162012 ug1 0- 305 20 624 4-Methyl-2-pentanone(MIBK) lt10 20 ( R) 20 ( R) ( RPD) 162012 ug1 624 cis-1 3-Dichloropropene lt2 22 (109 R) 23 (113 R) (4 RPO) 162012 ug1 0- 227 20 624 Toluene lt 1 20 (101 R) 21 (103 R) (2 RPO) 162012 ugl 47 shy 150 20 624 trans-13-Dichloropropene lt2 18 (90 R) 19 (93 R) (3 RPD) 162012 ug1 17 - 183 20 624 112-Trichtoroethane lt2 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 52 - 150 20 624 2-Hexanone lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624 Tetrachloroethene lt2 20 (100R) 21 (106 R) (6 RPD) 162012 ug1 64-148 20 624 Dibromochloromethane lt2 20 (102 R) 21 (104 R) (2 RPD) 162012 ug1 53 - 149 20 624 Chlorobenzene lt2 20 (98 R) 20 (100 R) (2 RPO) 162012 ug1 37 - 160 20 624 Ethyl benzene lt1 20 (101 R) 21 (105 R) (4 RPO) 162012 ugl 37 - 162 20 624 mp-Xylene lt 1 40 (101 R) 43 (106 R) (5 RPD) 162012 ug1 70 - 130 20 624 a-Xylene lt 1 21 (104 R) 22 (109 R) (5 RPO) 162012 ugl 70 - 130 20 624 Styrene lt 1 21 ( R) 22 ( R) ( RPD) 162012 ug1 624 Bromoform lt2 18 (88 R) 18 (90 R) (2 RPO) 162012 ug1 45 - 169 20 624 1 122-Tetrachloroethane lt2 20 (99 R) 20 (100 R) (1 RPO) 162012 ug1 46 shy 157 20 624 13-Dichlorobenzene lt 1 20 (100 R) 21 (104 R) (4 RPD) 162012 ug1 59 - 156 20 624 14-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPD) 162012 ug1 18 - 190 20 624 12-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 4-Bromofluorobenzene (surr) 100 ooR 101 R 102R 162012 Rec 70 - 130 624





Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method

12-Dichlorobenzene-d4 (surr) 93R 90R 89R 162012 Rec 70 bull 130 624

Toluene-dB (surr) 100R 102R 102R 162012 Rec 70 - 130 624

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor laboratory Control-Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAJQC limits Any impact to data is addressed below


bull LABORATORY REPORT EAi ID 106677



Sample ID Treat Tank Eff Grab

Lab Sample ID

Matrix

Date Sampled Date Received

Units

Date of ExtractionPreparation Date of Analysis

Analyst

Method

Dilution Factor

Phenol 2-Chlorophenol 24-Dichlorophenol 245-Trichlorophenol 246-Trichlorophenol Pentachlorophenol 2-Nitrophenol 4-Nitllophenol 24-0initrophenol 2-Me1hyphenol 34-Methylphenol 24-Dimethylphenol 4-Chloro-3-methylphenol 46-Dinitro-2-methylphenol Benzoic Acid N-Nitrrosodimethylamine n-Nitroso-di-n-propylamine n-Nitrosodiphenylamine bls(2-Chloroethyl)ether bls(2-chloroisopropyl)ether bis(2-Chloroethoxy)methane 13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene 124-Trichlorobenzene 2-Chloronaphthalene 4-Chl orophenyl-phenylether 4-Bromophenyl-phenylether Hexachloroethane Hexachlorobutadiene Hexachlorocyclopentadiene Hexachlorobenzene 4-Chloroaniline 2-Nitroaniline 3-Nitroaniline 4-Nitroanillne Benzyl alcohol Nitrobenzene lsophorone 24-Dinitrotoluene 26middot0initrotoluene Benz[dine (estimated) 33-Dichlorobenzidine Pyridine Azobenzene

10667702

aqueous

1512 1512

ug1

1612

1612

JMR 625mod

1

lt 1 lt 1 lt 1 lt 1 lt 1 lt5 lt 1 lt5 lt5 lt 1 lt 1 lt 1 lt 1 lt5

lt50 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt5 lt 1 lt 1 lt5 lt 1 lt 1 lt5 lt 1 lt 1 lt 1 lt 1 lt5 lt 1 lt5 lt 1


bull LABORATORY REPORT EAi ID 1 06677 ~ Client Northeast Utilities



10667702Lab Sample 10

Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1

Date of ExtractionPreparation 1612

Date of Analysis 1612

Analyst JMR

625modMethod 1Dilution Factor

Carbazole lt 1 Dime1hylphthalate lt 1 Diethylphthalate lt 1 Di-n-butylphthalate lt5 Butylbenzylphthalate lt 1 bis(2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dlbenzofuran lt 1 Naphthalene lt 1

lt 12-Methyinaphthalene Acenaphthylene lt 1 Acenaphthene lt1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzofa]anthracene lt 1 Chrysene lt 1 Benzo[b]fluoranthene lt 1 Benzo[k]fluoranthene lt 1 Benzo[a]pyrene lt 1 lndeno[123-cd]pyrene lt 1 Dibenz[ah)anthracene lt 1 Benzoghi)perylene lt 1 2-Fluorophenol (surr) 33R Phenol-d6 (surr) 24R

90R246-Tribromophenol (surr) 71 R Nitrobenzene-D5 (surr) 72R2-Fluorobiphenyl (surr)

p-Terphenyl-D14 (surr) 84R


i

bull


Client Northeast Utilities Batch ID 734507-32510A010512E6251



Phenol lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625mod 2-Chlorophenol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod 24-Dichlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30 - 130 20 625mod 245-Trichlorophenol lt 1 18 (72 R) 19 (75 R) 4 RPO) 152012 ug1 30-130 20 625mod 246-Trichlorophenol lt 1 34 (68 R) 36 71 R) (4 RPO) 152012 ug1 30 - 130 20 625mod Pentachlorophenol lt5 34 (68 R) 39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625mod 2-Nitrophenol lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 - 130 20 625mod 4-Nitrophenol lt5 16 (32 R) 17 (35 R) 9 RPO) 152012 ug1 15 - 130 20 625mod 24-Dinitropheno lt5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 - 130 20 625mod 2-Methylphenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod 34-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 -130 20 625mod 24-Dimethylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 -130 20 625mod 4-Chloro-3-methylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod 46-0initro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO) 152012 ug1 30 - 130 20 625mod Benzoic Acid lt 50 lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 - 140 20 625mod N-Nitrosodimethylamine lt 1 12 (46 R) 12 (47 R) (2 RPO) 152012 ug1 40 -140 20 625mod n-Nitros o-oi-n-propylamine lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625mod n-Nitros odlphenylamine lt 1 22 (90 R) 23 (90 R) (0 RPO) 152012 ug1 40 -140 20 625mod bis(2-Chloroethyl)ether lt 1 16 (63 R) 16 (64 R) (2 RPO) 152012 ug1 40 -140 20 625mod bis(2-ch loroisopropylether lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 -140 20 625mod bis(2-Chloroethoxy)methane lt 1 17 (69 R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625mod 1 3-Dichlorobenzene lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 -140 20 625mod 14-Dichlorobenzene lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod 12-Dichlorobenzene lt 1 14 (54 R) 14 (55 R) (2 RPO) 152012 ug1 40 - 140 20 625mod 124-Trichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 -140 20 625mod 2-Chloronaphthalene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 -140 20 625mod 4-Chorophenyl-phenylether lt 1 18 (71 R) 18 (72 R) (1 RPO) 152012 ug1 40-140 20 625mod 4-Bromophenyl-phenylether lt1 19 (75 R) 19 (75 R) (0 RPO) 152012 ug1 40 - 140 20 625mod Hexachtoroethane lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625mod Hexachlorobutadiene lt 1 10 (40 R) 10 (42 R) (5 RPO) 152012 ug1 40 - 140 20 625mod Hexachlorocyclopentadiene lt5 9 (37 R) 10 (41 R) (10 RPD) 152012 ug1 40 - 140 20 625mod Hexachlorobenzene lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 middot ug1 40 - 140 20 625mod 4-Chloroaniline lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod 2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40-140 20 625mod 3-Nitroaniline lt 1 18 (73 R) 19 (76 R) (4 RPO) 152012 ug1 40 - 140 20 625mod 4-Nitroaniline lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod Benzyl alcohol lt5 16 (65 R) 17 (67 R) (3 RPO) 152012 ug1 40 - 140 20 625mod Nitro benzene lt 1 16 (65 R) 17 (68 R) (5 RPD) 152012 ug1 40- 140 20 625mod lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod 24-Dlnitrotoluene lt 1 20 (81 R) 21 (85 R) (5 RPO) 152012 ug1 40-140 20 625mod 26-Dinitrotofuene lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40-140 20 625mod Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod 33-Dichlorobenzidine lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40-140 20 625mod Pyridine lt5 11 (45R) 11 (46 R) (2 RPO) 152012 ug1 40-140 20 625mod Azobenzene lt 1 18 (71 R) 18 (71 R) (0 RPO) 1152012 uwt 40-140 20 625mod





Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method

Carbazole lt 1 20 (79R) 20 (81 R) (3 RPD) 152012 ug1 40 -140 20 625mod

Dimethylphthalate lt 1 18 (73 R) 18 (74 R) (1 RPD) 152012 ug1 40 - 140 20 625mod

Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPD) 152012 ug1 40 -140 20 625mod

Di-n-bufylphthalate lt5 19 (77 R) 19 (76 R) (1 RPD) 152012 ug1 40 - 140 20 625mod

Butylbenzylphthalate lt 1 19 (76 R) 19 (77 ~) (1 RPO) 152012 ug1 40 - 140 20 625mod

bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPD) 152012 ug1 40 - 140 20 625mod

Di-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPD) 152012 ug1 40 - 140 20 625mod

Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPD) 152012 ug1 40 - 140 20 625mod

Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPD) 152012 ug1 40- 140 20 625mod

2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPD) 152012 ug1 40 - 140 20 625mod

Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPD) 152012 ug1 40 - 140 20 625mod

Acenaplhthene lt 1 17 (70 R) 18 (71 R) (1 RPD) 152012 ug1 40 - 140 20 625mod

Fluorene lt 1 17 (70 R) 18 71 R) 1 RPO) 152012 ug1 40 - 140 20 625mod

Phenanthrene lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 - 140 20 625mod

Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPD) 152012 ug1 40 -140 20 625mod

Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPD) 152012 ug1 40 - 140 20 625mod

Pyrene lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 - 140 20 625mod

Benzo[a)anthracene lt 1 19 (75 R) 19 (76 R) (1 RPD) 152012 ug1 40 - 140 20 625mod

Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPD) 152012 ug1 40 - 140 20 625mod

Benzo[b)fluoranthene lt 1 19 (75 R) 19 (77 R) (3 RPD) 152012 ug1 40- 140 20 625mod

Benzo(kfluoranthene lt 1 19 (77 R) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625mod

Benzo[a]pyrene lt 1 19 (76 R) 19 (77 R) (1 RPD) 152012 ug1 40 - 140 20 625mod

lndeno[123-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod

Dibenz[ a h )anthracene lt 1 20 (80 R) 19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625mod

Benzo[ghl)perylene lt 1 20 (79 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625mod

2-Fluorophenol (surr) 39R 39R 39R 152012 Rec 21 - 110 20 625mod

Phenol-d6 (surr) 28R 28R 29R 152012 Rec 15 - 94 20 625mod

246-Tribromophenol (surr) 76R 92R 82R 152012 Rec 15 - 110 20 625mod

Nitrobenzene-05 (surr) 76R 75R 77R 152012 Rec 35 - 114 20 625mod

2-Fluorobiphenyl surr) 77R 73R 75R 152012 Rec 43 - 116 20 625mod

p-Terphenyl-D14 (surr) middot 89R 95R 90R 152012 Rec 33 - 130 20 625mod

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits

Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected In the sample

eastern analytical inc wwweaifabscom Phone (603) 228-0525 8

LABORATORY REPORT EAi ID 106677



Sample ID

Lab Sample ID

Matrix


Units

Date of ExtractionPrep

Date of Analysis

Analyst

Method

Diluti on Factor

Oil amp Grease (HEM)

Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5

eastern analyticalJ inc wwweailabscom Phone (603) 228-0525 9

EAi ID 106677QC REPORT



LCSD Analysis Date Units Limits RPO MethodParameter Name Blank LCS

33 (82 R) (13 RPD) 192012 mgL 78-114 18 1664AOil amp Grease (HEM) lt5 37 (93 R)

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below


LABORATORY REPORT EAi ID 106677f middotmiddot middot[



Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242

PCB-1248 PCB-1254 PCB-1260 TMX (surr) DCB (surr)

Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-

eastern analytical inc wwweailabscom Phone (603) 228-0525 1 1


Client Northeast Utilities Batch ID 734508-43146A010612E608P1


Parameter Name Blank LCS LCSD Analysis Date Units Limits RPD Method

PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012

PCB-1221 lt 03 lt 03 (R NIA) lt 03 (R NIA) (RPD NIA) 1162012

PCB-1232 lt 03 lt 03 (R NIA) lt 03 (R NA) (RPD NA) 1162012

PCB-1242 lt03 lt 03 (R NA) lt 03 (R NA) (RPO NIA) 162012

PCB-1248 lt03 lt 03 (R NIA) lt 03 (RNA (RPONIA) 1162012

PCB-1254 lt 03 lt 03 (R NIA lt 03 (R NA) (RPO NA) 1162012

PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012

88R 90R 162012TMX (surr) 84R 101 ooR 162012DCB (surr) 95R 100R

ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted bulltt Flagged analyte recoveries deviated from the QNQC limits


LABORATORY REPORT EAi ID 106677 middotmiddot



-----------shy- ------------shy- -----------middot---middotmiddotmiddot---shy middotshy-middotmiddotshySample ID Treat Tank Eff

Composite

Lab Sample ID 10667701

Matrix aqueous

Date Sampled 1512 Analysls Date Received 1512 Units Date Time Method Analyst

Solids Suspended Solids Dissolved

14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS

Fluoride Sulfate Chloride Nitrate-N

10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS

Alkalinity Total (CaC03) 180 mgL 0111 12 940 23208 SEL Ammonia-N BOD COD pH

092 lt6 130 73

mgL mgL mgL SU

011012 8304500NH3D SEL 010612 1405 sifoB SKC 011212 1020 HBOOO SKC 010512 1510 4500H+B NZ



Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis

Date Time Method Analyst

Cyanide Total Sulfide Sulfite Total Residual Chlorine Total Phenols

002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL

011112 845 4500CNE KJR 011112 13208131HACH KJR 010512 1730 3771 Jl 010512 1650 4500CIG NZ 010912 900 4201 JCC

Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences

eastern analytical inc wwweailabscom Phone (603) 228-0525

13


~bull Client Northeast Utilities


Date of

Blank LCS LCSD Units Analysis Limits RPO MethodParameter Name

Solids Suspended lt5 90 (90 R) 93 (93 R) 3 RPO) mgl 11012 90 - 110 20 25400

Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C

Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPD) rngL 11112 90 - 110 20 3000

~ulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgl 11112 90 - 110 20 3000

Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE

Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90- 110 20 3532

Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B

Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgL 11112 85 - 115 20 4500CNE

Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N

Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH

Sulfite lt2 NA NA mgL 1512 3771

Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgl 1512 80 - 120 20 4500CIG

BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000

Total Phenols lt005 028 (112 R) 027 (106 R) (6 RPO) mgL 1912 85 - 115 20 4201

pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B

Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QAQC limits


i

~ QC REPORT EAi ID 106677 ~

~ Client Northeast Utilities


lllil

middotmiddot-middotmiddot--middot--middot--middot---middot----

Ouplfcate Duplicate Date of

Parameter Name Parent ID Parent Duplicate Units Analysis RPD Method ----middot--middot---middot-- -----middot--middot-middotmiddotmiddot-middotmiddot-middotmiddotmiddotmiddot- __ middotmiddot-----~middot-middotmiddotmiddot~-- -middotmiddot--------------middotmiddot--middot-

Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 11112 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgl 11012 20 4500CIE Nitrate-N NA NA mgL 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt2 lt2 (RPO NA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1512 20 4500CIG BOD 10665702 410 400 (3 RPD) mgL 1612 20 5210B COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1512 10 4500H+B

shy

gt

bull bull

f



bull QC REPORT EAi ID 106677lllAAI



MSMSD MSMSD Date of

Parameter Name Parent ID Parent Matrix Spike MSD Units Analysis Limits RPD Method----

NA NA NA mgL 11012 20 25400Sottds Suspended NA NA mgL 11112 2540CSolids Dissolved NA

NA mgL 11112 20 3000 Fluoride NA NA NA mgL 11112 20 3000Sulfate NA NA

10663202 11 22(110R) 22 (109 R) (1 RPO) mgL 11012 80-120 20 4500CIEChloride

Nitrate-N 10667801 12 12(110R) 12 (109 R) (1 RPD) mgL 1612 80-120 20 3532

10660701 29 48 (98 R) NA mgL 11112 80-120 20 23208Alkalinity Total (CaC03) 025 (93 R) 023 (86 R) (8 RPD) mgl 11112 75-125 20 4500CNECyanide Total 10667702 002

Ammonia-N 10662702 13 16(115R) 15 (85 R) (30 RPO) mgl 11012 80-120 20 4500NH3

Sulfide NA NA NA mgL 11112 20 8131HAC

NA mgL 1512 3771Sulfite NA NA

NA NA NA mgL 1512 20 4500CIGTotal Residual Chlorine

BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000

Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO mgL 1912 80-120 20 4201

NA NA NA SU 1512 10 4500H+BpH

Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix interference

Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated In accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullJ Flagged analyle recoveries deviated from the QAQC limits

eastern analytical inc wwweaifabscom Phone (603 228-0525 16

414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870

FRONTJE~ GLOBAL SCIENCES

11 January 2012

Jeff Gagne

Eastern Analytical Inc

25 Chenell Drive

Concord NH 03301

RE Merrimack Station

Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control

measurements are within established control limits and there were no analytical difficulties encountered

with the exception of those listed in the case narrative section ofthis report

Ifyou have any questions concerning this report please feel free to contact me

Sincerely

Liz Siska

Project Manager

17

414 Pontius Ave North

Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER

GLOBAL SCIENCES

ANALYTICAL REPORT FOR SAMPLES

Laboratory Frontier Global Sciences Inc SDG

Project Merrimack Station Client Eastern Analytical Inc

Lab ID Matrix Date Sampled Date Received Sample ID

1201073-01 Water 05-Jan-12 1000 06-Jan-12 0950 Treat Tank EffComposite

1201073-02 Water 05-Jan-12 0800 06-Jan-I 2 0950 Treat Tank Eff Grab

The results In lhis report only apply to the samples analyzed in accordance wtth thechain ofcustody document This analytical report must be reproduced in itsentirety

Frontier Global Sciences Inc

Liz Siska Project Manager

of26 J201073 Final Report

OI1112012

18

FRONTlERshycLosAL SCIENCES

414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CASE NARRATIVE

SAMPLE RECEIPT

Samples were received at Frontier Global Sciences (FGS) on January 6th 2012 The samples were received intact on-ice with temperatures measured at 34 degrees Celsius

SAMPLE PREPARATION AND ANALYSIS

Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638

Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE

ANALYTICAL AND QUALITY CONTROL ISSUES

There were no analytical difficulties experienced with analysis ofthese samples with the exceptions flagged in the report

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document Ihis analytical report must be reproduced in its entirety

Page 2of26 I 201073 Final Report

OJll2012

19Liz Siska Project Manager

~ 414 Pontius Ave North

Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES

CHAIN OF CUSTODY FORMS

Oib ofCutO(fy Reccbullc amp L-Crtory Anal11is Requ1 11 J~s ~N SL1ilt(A et~~ M V~ter Sedin~nts Pl~nt ~nd 111middotma1ru~ 1middotCmiddotw tmiddotSUmiddotlrt

i~ J)IJ~2middottli7CEmiddotdbullcrubts ampcuer SPlos ~ ~ililtl~Ci2 O Cmiddot- ~ff70F-~~ttGSct-Llt I

~ ~JIS I td--~~ - rti KS bfs ~et middot middot~ LtylI ~~ a11tht ~~ IC 0(1~M ~~I Sttie tn ~L

bull Jrrmbull _ CJ~ft-0_- aJF7 V

Frontier Global Sciences Inc The resuits In this report onlyapply to the samples anayudin accordance with the chain ofcustody documenL This analytical report must be reproduced in its entirety

Pagdo26 1201073 Final ampport

OJIJJ2012

Liz Siska Project Manager 20

414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870

GLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank EffComposite

Matrix Water Laboratory ID 1201073-01

Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes

Aluminum 411 22 200 microgL 5 F201062 2Al0002 010912 FGS-054

Antimony 0520 0023 0100 microgL 5 F201062 2Al0002 010912 FGS-054

Barium 300 014 100 microgL 5 F201062 2Al0002 010912 FGS-054

Beryllium 0522 0114 0 300 microgL 5 F201062 2Al0002 010912 FGS-054

Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010912 FGS-054

Calcium 5050000 16200 200000 microgL 5000 F201077 2Al0015 011012 FGS-054

Chromium ND 004 050 microgL 5 F201062 2AI0002 010912 FGS-054 u Copper ND 005 050 microgL 5 F201062 2Al0002 010912 FGS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201062 2Al0002 010912 FGS-054 u Manganese 293 074 100 microgL 100 F201062 2Al0002 010912 FGS-054

Molybdenum 140 003 030 microgL 5 F20I062 2Al0002 010912 FGS-054

Nickel 803 004 050 microgL 5 F201062 2Al0002 010912 FGS-054

Silver ND 0030 0100 microgL 5 F201062 2Al0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 F201062 2Al0002 010912 FGS-054

Thallium 664 0006 0025 microgL 5 F201062 2AI0002 010912 FGS-054 QB-01

Zinc ND 008 100 microgL 5 F201062 2A10002 010912 FGS-054 u

Frontier Global Sciences Inc The results in this report onlyapply lo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety

Page 4 of26 1201073 Final Report

OJll2012


bull 414 Pontius Ave North

Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab

Laboratory ID 1201073--02Matrix Water

Aoalyte Result MDL MRL Uoits Dilution Batch Sequence Analyzed Method Notes

Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012

FGS-054 EPA 1631E FGS-054

FB-1631



The results in this reporl only apply lo the samples analyzed in accordance wilh he chain ofcustody document This analytical report must be reproduced in ils entirety

Page 5 o26 1201073 Final Report

OlJl2012

22

414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870 ~

G LO BAL SC IE NC ES

MATRIX DUPLICATESffRIPLICATES

SOURCE 1201073-02

Batch F201063 Sequence 2A09010

Preparation BrCl Oxidation Lab Number F20I063-DUP1

Sample Duplicate Concentration Concentration RPD

Analyte ngL ngL MRL RPO Limit Method Notes

Mercwy 1048 1054 202 0617 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 6026 1201073 Final Report

OIIJI2012


414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960 Fx 206-622-6870

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01


Preparation Closed Vessel Nitric Oven Digestion Lab Number F20l062-MSMSD1

Analyte

Beryllium

Sample Concentration

(microgL)

Spike Addedmiddot (microgL)

middot MS

Concentration (microgL)

MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054

Chromium 047 70700 859 115 85 bull 115 FGS-054

Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02

Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02

Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPD Limit Method Notes

Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054

Chromium Iron Nickel Copper Zinc Arsenic Selenium Molybdenum Silver Cadmium

70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20

FGS-054 FGS-054 FGS-054 FGS-054 FGS-054 FGS-054 FGS-054 FGS-054 FGS-054 FGS-054

QM-02


Page 7 o26 1201073 Final Report ~--ltl~~shy

0112012



~

~CLOSAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01

Batch F201062 Sequence 2~10002

Preparation Closed Vessel Nitric Oven Dieestion Lab Number F201062-MSMSD 1

Spike Added

MSD Concentration

MSD Recovery RPD

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Antimony 080800 1373 106 0924 79- 122 20 FGS-054 Barium 10100 3071 71l 0703 80- 120 20 FGS-054 QM-02 Thallium 040400 6918 676 0520 64 - 137 20 FGS-054 QB-01 Lead 15150 1580 104 344 72 - 143 20 FGS-054

The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety


011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl

Batch F201062 Sequence 2AIOQ02

Preparation CIQsed Vessel titric Qven Digestion Lab Number F20I062-MSMSD2

Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodiwn 277400 50500 264500 -2560 75 - 125 FGS-054 QM-02 Manganese 2931 60600 287l -987 80- 120 FGS-054 QM-02

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO Limit Method Notes

Sodiwn 50500 270000 -1460 206 75 - 125 20 FGS-054 QM-02 Manganese 60600 2897 -553 0912 80 - 120 20 FGS-054 QM-02



The results in 1his report only apply to the samples analyzed in accordance with the chain Qfcustody document This analyticalreport must be reproduced in Its tnJirety

Page 9of26 1201073 Final Report

OlJJ2012

26


I

bull~

G LO BAL SC I~ NC ES


SOURCE 1201073-01

Batch F201062 Sequence 2Al0002


Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0522 10100 1096 103 75 - 135 FGS-054 AS Aluminum 41l 20200 2166 105 80- 115 FGS-054 AS Chromium 047 20200 2300 114 85 - 115 FGS-054 AS Iron ND 10100 1103 109 75 - 125 FGS-054 AS

Nickel 803 25250 2551 978 68 - 134 FGS-054 AS Copper 029 25250 2245 888 51 145 FGS-054 AS

Zinc 027 50500 4227 837 46 - 146 FGS-054 AS Arsenic 532 20200 2350 114 85 - ll5 FGS-054 AS Seienium 7173 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 10100 2447 103 80 - 115 FGS-054 AS

Silver ND 10100 8224 814 74 - 119 FGS-054 AS Cadmiwn 0207 20200 1918 939 84 - 113 FGS-054 AS Antimony 0520 10100 1116 105 79 - 122 FGS-054 AS Barium 3000 40400 7753 118 80- 120 FGS-054 AS

Thallium 6645 10100 1746 107 64- 137 FGS-054 AS QB-01

Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS

Iron 10100 1112 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59- 149 20 FGS-054 AS Molybdenum 10100 2467 105 0806 80 - 115 20 FGS-054 AS Silver 10100 8290 82l 0798 74 - 119 20 FGS-054 AS Cadmium 20200 1931 946 0670 84- 113 20 FGS-054 AS Antimony 10100 1131 107 129 79 - 122 20 FGS-054 AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain Qfcustody documenL This analytical report must be reproduced in its enJirety

Page 10 of261201073 Final Report

Oll ll2012

~-ltl-e~~ 27Liz Siska Project Manager

bull

414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER

GLOBAL SCIENCES


SOURCE 1201073-01


Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-MSMSD3

Spike MSD MSD Oo Recovery RPDAdded Concentration

RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Barium 40400 7798 119 0575 80 middot 120 20 FGS-054 AS

Thalliwn 10100 1756 108 0595 64 bull 137 20 FGS-054 ASQB-01

Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS

Frontier Global Sciences Inc The results in this report only apply to the samples analy-ed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page JJ o26 1201073 Final Report

Ollll1011


FRONTIER GLOBAL SCIENCES

1111



SOURCE 1201073-0lREl

Batch F201062 Sequence 2AI0002


Analyte

Sample Spike Concentration Added

(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc

Spike MSD Added Concentration (microgL) (microgL)

MSD

RPD Recovery

Recovery Limits

RPOLimit Method Notes

Sodium 202000 480300 100 125 75 - 125 20 FGS-054 AS Manganese 20200 2405 105 0346 80 shy 120 20 FGS-054 AS

Frontier Global Sciences Inc The results in this report 011y apply to the samples analyzed in accordance with the chain ofcustody doctmrenl This analytical report must be reproduced in its entirety

Page l2of26 1201073 Final Report

Olli112012


FRONT[ER GLOBAL SCIENCES

414 Pontius Ave North Seattle WA 98l 09 Ph 206-622-6960 Fx 206-622-6870


SOURCE 1201073-02


Lab Number F20l063-MSMSD1Preparation BrCl Oxidation

Sample Spike MS MS

Analyte Concentrationmiddot

(ogL) Added

(ogL) Concentration

(ngL) Recovery Recovery

Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery

Limits RPD Limit Method Notes

Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E

Frontie Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety


Ollll2012


I


GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1112278-02

Batch F20I063 Sequence 2A090IO

Preparation BrCl Oxidation Lab Number F20I 063-MSMSD2

Sample Spike MS MS Concentration Added Concentration Oo Recovery

Analyte (ngL) ngL) (ngL) Recovery Method Limits Notes

Mercwy 761 20400 2786 992 71 - 125 EPA I631E

Spike MSD MSD Oo Recovery RPD Added Concentration

RPD Limits Limit Method (ngL) (ngL) Recovery Notes Analyte

Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E



The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety


Ollll2012

31

Sample Spike MS MS oo Concentration Added Concentration Recovery

Analyte Method Notes (ngL) (ngL) (ngL) Recovery Limits

100 71 - 125 163 lE Mercury 534 10200 1558 EPA

Spike MSD MSD Oo Recovery RPO Added Concentration

RPD Limits Limit Method Notes (ngL) (ngL) Recovery Analyte 856 102 71 shy 125 24 EPA 1631E Mercury 10200 1407

414 Pontius Ave North Seattle WA 98109

~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3

The results in this report011y apply to the samples analyzed in accordance wi1h lhechain ofcustody document This analytical report must be reproduced in its entirety


OJll2012


~ 32Liz Siska Project Manager

II


GLOEAL SCIENCES


SOURCE 1201030-02


Preparation BrCl Oxidation Lab Number F201063-MSMSD4

Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte ngL) (ngL) (ngL) Recovery Method Limits Notes

Mercury 554 10200 1482 910 71 - 125 EPA 163IE

Spike MSD MSD Added Recovery Concentration RPD (ogL) (ngL) Recovery RPD Limits Limit Method Notes Aoalyte

Mercury 10200 1461 890 140 71 - 125 24 EPA I631E



The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document Ihis analytical report must be reproduced in its entirety


Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES


SOURCE 1201073-01RE2


Preparation Closed Vessel Nitric Oven Digestion Lab Number F20I077-MSMSD1

Sample Spike MS MS Concentration Added Concentration bull1o Recovery

Analyte (pgL) (JlgL) (microgL) Recovery Method Notes Limits

Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02

Spike MSD MSD Oo Recovery Added Concentration RPD

RPD Limits Limit Method (microgL) (JlgL) Recovery Notes Analyte

Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02



The results in this report only apply to the samples analyud in accordance with the chain ofcustody document This analytical report must be reproduced in its enJirety

Page 17 o26 I 20073 Final Report

OJ12012

34

~r 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870 ~

GLOBAL SC IE NC ES

MATRIX SPIKEmiddot MATRIX SPIKE DUPLICATE RECOVERY AND RPO




Analyte


(microgL)


MS MS Concentration

(microgL) Recovery Recovery

Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054



The results in this report only apply to the samples analyzed in acccrdance with the chain ofcustody document This analytical report must be reproduced in its enrirety


01112012

35


GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD


Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-BSBSD1

LCS Source ~lank Siiilse

Spike LCS LCS Added Concentration Recovery

Analyte (JtgL) JtgL) Recovery Limits Method Notes

Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054

Spike LCSD LCSD Added Concentration Recovery RPD

Analyte (microgL) (pgL) Recovery RPD Limits Limit Method Notes

Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy

Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the cha11 ofcustody document This analytical report must be reproduced in its entirety

Pa~ 9o26~~ 1201073 Final Report 012012

36Liz Siska Project Manager ~

i 414 Pontius Ave North

Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870 FRONTIER

G LOB AL SCIENCES


RECOVERY AND RPD


Preparation Closed Ve~sel Nitric Oven Digestion Lab Number F20 I062-BSBSDI

LCS Source Blank S12ike



Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054

Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 20of26 1201073 FinalReport

01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063

Preparation BrCl Oxidation

Sequence 2A09010

Lab Number F201063-BSBSD1

LCS Source Nist 1641d

Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679

Frontier Global Sciences Inc The results In this repert only apply to the samples anoydd in accordance with the chain ofcustody document This analytical report muit be reproduced In itsentirety

Page 21 o26 120073 Fino Report

Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD

Batch F20I077 Sequence 2Al0015


LCS Source Blank Spike

Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054



The results In this report only apply to the samples analyzed in accordanat with the chain ofcustody document This analytical report must be reproduced in its entirety


OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS

Instrument Hg-17 Sequence 2A09010

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20I063-BLK1 Mercury -0009 050 ngL F201063 EPA 163JE u F201063-BLK2 Mercury -0006

I 050 ngL F201063 EPA 163IE u

F20l063-BLK3 Mercury -002 050 ngL F201063 EPA 16318 u F20I063-BLK4 Mercury 003 050 ngL F201063 EPA 163IE U QB-04

F201063-BLK5 Mercury 011 052 ngL F20I063 EPA 163IE U QB-06



The results in this report only apply to the samples analyzed inaccordance with the chain ofcustody document This analytical report must ~ reproduced in iJs entirety


01112012

40

1

~

Ill ~GLOBAt SCIENCES

414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

~

6

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2AI0002

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample JD Analyte Found MRL Units Batch Method Notes

F201062-BLKl Beryllium 00002 0060 microgL F201062 FGS-054 u F201062-BLK1 Sodium 009 20 microgL F201062 FGS-054 u F201062-BLK1 Aluminum 009 40 microgL F201062 FGS-054 u F20I062-BLKl Calcium 05 40 microgL F201062 FGS-054 u F20I062-BLK1 Chromium 003 010 microgL F201062 FGS-054 u F20 I062-BLK1 Manganese -0002 010 microgL F201062 FGS-054 u F201062-BLKl Iron -006 100 microgL F201062 FGS-054 u F20 I062-BLKl Nickel 0004 010 microgL F20I062 FGS-054 u F201062-BLK1 middot Copper -00003 010 microgL F20l062 FGS-054 u F201062-BLKI Zinc 004 020 microgL F201062 FGS-054 u F201062-BLKI Arsenic -007 015 microgL F201062 FGS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F201062-BLKl Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-BLKl Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKl Cadmium -000002 0020 microgL F201062 FGS-054 u F201062-BLKI Antimony -00003 0020 microgL F201062 FGS-054 u F201062-BLKI Barium -004 020 microgL F201062 FGS-054 u F201062-BLKl Thallium 0007 0005 microgL F20I062 FGS-054 QB-10 F20 l062-BLKI Lead 0003 0040 microgL F201062 FGS-054 u

Frontier Global Sciences Inc The results in this report only apply to the samples analy-ed in accordance with the chain ofcustody docwnent This analytical report must be reproduced in its entirety


Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS

Iostrumeot ICPMS-6 Sequence 2AIOOI5



F20I077-BLK1 Calcium 02 40 microgL F201077 FGS-054 u

Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance wllh the chain ofcustody doCUTl1$nt This analytical report must be reproduced in its entirety

Page15of26 1201073 Final Report

OlJl2012


bull


G LO BA L SC I E N CE S

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD

QB-10 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL Only report sample results greater than 10 times the contamination value (QB-01) or samples less than the MRL (QB-02)

QB-06 The blank was preserved to 5 BrCl rather than 1 The control limit for blanks preserved to greater than 1 BrCI is the preservation percentage multiplied by the l1RL

QB-04 The blank was preserved to 2 BrCl rather than 1 The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the l1RL

QB-01 middot The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the blank concentration(s) are less than 10 ofthe sample result

FBshy1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 1631E but does not meet 1631E criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected middot

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation



The results in this report only apply to Jhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety


OIll2012

43

bull

CHAIN-OF-CUSTODY RECORD

BoLD F1ELDS REQUIRED PLEASE C1RCLE REQUESTED ANALYSIS Page of~ 106677 ~

SAMPLING 3 w 0 0ATE T1ME deg

11

lw 0IF COMPOSITE

w ~ u

INDICATE B OTH gtlt -ltbull-er ell

SAMPLE 10 I START amp FINISH i ltt c

DATETIME

1s-12

11s--J o5A Iwv 16--

HATllX A-AllS-SOII GWmiddotGlOUNOWATEl swsuampUCE WATEA DWmiddotDllNllNG WATU WWbullWAm WATU

PmmATIVE HmiddotHCL NmiddotHN01 ~H1S01 Na-NaOH H-HEOH

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DATE NEEDED _J--i_l-_j2~----shy

RELINQUISHED BY

REPORTING OPTIONS

PAELIMS YES 0~ No II YEI fAX Ok PDF

DATE

ELECTRONIC OPTIONS

No FAX EmiddotHAIL PDF

TIME

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ImiddotRELINQUISHED BY DATE TIME RECEIVlD Bl I FIELD READ INGS

-l)VJ east ern analytical inc 2s CHENEu DRrve I CoNco~o NH 03301 I TEL 6032280525 I 1aoo281os2s I FAx 6032284591 I E-MAIL cusT0Mu1_seRv1ceEA1LABscoMI wwweA1LA11scoM

p1middotofassio110l1bomtorymmiddotvim (WHITE ORIGINAL GREEN PROJECT MANAGER)

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QAQC REPORTIN9~EL

Cm f1 - STATE bullH ZIP 0gt 01( A lt) C PHONE 2h(- i(u-f EXT ____

OR FAX _ _ _ ---- - -------------- shy

PRESUMPTIVE CERTAINTY EmiddotHAl CUt c 4 QJ e 1fl CWA Sm HANE Mi30M JtfMbull PlOJECT 3

OTHEk_________STATE NH MA ME VT

REGULATORY PROGRAM NPDES RGP POTW STOlHWATU Ol

QUOTpound ~I

January 16 2012 Page2

Town ofHooksett New Hampshire File No 04002930700

As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed a standard operating procedure (SOP) that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs Standard Operating Procedure Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K)

We trust that this submittal adequately address your informational needs Should you have any questions please contact me at 232-8744

Very truly yours

GZA GEOENVIRONMENTAL INC

Ronald A Breton PE Principal

RABtmd p04jobs0029300$0400l930700lworklsampling and reportinefeportslfinal 2930700 cover letters 011612docx

Attachment(s)





NOTES






Arthur Auclair

Northeast Utilities

97 River Road

Bow NH 03304





Dear Mr Auclair







Sincerely











~middotmiddot








Sample ID





Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt50 lt10 lt2

lt 10 lt2 lt2


lt 10 lt2

2 lt2 lt2


98R 90R

100R





















Lab Sample ID

Matrix


Units


Analyst

Method

Dilution Factor


10667702

aqueous

1512 1512

ug1

1612

1612

JMR 625mod

1








Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR







i

bull
















































Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Diluti on Factor


Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES










Page 1 of26 J201073 Final Report

OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT








of26 I 201073 Final Report

OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I





NOTES






Arthur Auclair

Northeast Utilities

97 River Road

Bow NH 03304





Dear Mr Auclair







Sincerely











~middotmiddot








Sample ID





Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt50 lt10 lt2

lt 10 lt2 lt2


lt 10 lt2

2 lt2 lt2


98R 90R

100R





















Lab Sample ID

Matrix


Units


Analyst

Method

Dilution Factor


10667702

aqueous

1512 1512

ug1

1612

1612

JMR 625mod

1








Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR







i

bull
















































Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Diluti on Factor


Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


Arthur Auclair

Northeast Utilities

97 River Road

Bow NH 03304





Dear Mr Auclair







Sincerely











~middotmiddot








Sample ID





Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt50 lt10 lt2

lt 10 lt2 lt2


lt 10 lt2

2 lt2 lt2


98R 90R

100R





















Lab Sample ID

Matrix


Units


Analyst

Method

Dilution Factor


10667702

aqueous

1512 1512

ug1

1612

1612

JMR 625mod

1








Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR







i

bull
















































Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Diluti on Factor


Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS

















of26 1201073 Final Report

OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I









~middotmiddot








Sample ID





Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt50 lt10 lt2

lt 10 lt2 lt2


lt 10 lt2

2 lt2 lt2


98R 90R

100R





















Lab Sample ID

Matrix


Units


Analyst

Method

Dilution Factor


10667702

aqueous

1512 1512

ug1

1612

1612

JMR 625mod

1








Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR







i

bull
















































Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Diluti on Factor


Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631




o26 1201073 Final Report

OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I




Sample ID





Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt50 lt10 lt2

lt 10 lt2 lt2


lt 10 lt2

2 lt2 lt2


98R 90R

100R





















Lab Sample ID

Matrix


Units


Analyst

Method

Dilution Factor


10667702

aqueous

1512 1512

ug1

1612

1612

JMR 625mod

1








Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR







i

bull
















































Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Diluti on Factor


Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E


026 1201073 Final Report

OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I




















Lab Sample ID

Matrix


Units


Analyst

Method

Dilution Factor


10667702

aqueous

1512 1512

ug1

1612

1612

JMR 625mod

1








Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR







i

bull
















































Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Diluti on Factor


Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02


o26 1201073 Final Report ~--ltl~~shy

0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I













Lab Sample ID

Matrix


Units


Analyst

Method

Dilution Factor


10667702

aqueous

1512 1512

ug1

1612

1612

JMR 625mod

1








Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR







i

bull
















































Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Diluti on Factor


Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I





Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR







i

bull
















































Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Diluti on Factor


Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS



of261201073 Final Report

Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

i

bull
















































Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Diluti on Factor


Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I










































Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Diluti on Factor


Treat Tank Eff Grab

10667702 aqueous

1512 1512

mgL

1912

1912

LAS

1664A 1

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I











Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242


Treat Tank Eff Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW 608

1

lt03 lt 03 lt03 lt 03 lt 03 lt03 lt 03

81 R 96R

-






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I





PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPD) 11612012






PCB-1260 lt 03 20 (102 ooR) 21 (105 R) (3 RPD) 1612012


ugll 40 - 140 20 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 608

ug1 40 - 140 20 608

Rec 30-150 608

Rec 30- 150 608







Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I





Composite


Matrix aqueous



14 21000

mgL mgL

011012 1540 011112 1315

2540D 2540C

DLS DLS


10 1200

11000 100

mgL mgL mgL mgL

011112 1123 3000 011112 11 23 3000 011012 1217 4500CIE 010612 1257 3532

KL KL DLS DLS


092 lt6 130 73

mgL mgL mgL SU




Matrix

Date Sampled

Date Received

aqueous

1512

1512 Units

Analysis



002 lt 01

lt2 lt 005 lt 03

mgL mgl mgL mgL mgL




13




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02




o26 I 20073 Final Report

OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I




Date of














BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 11612 84 - 115 20 5210B

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000


pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 - 607 10 4500H+B



i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

i




lllil





shy

gt

bull bull

f






MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I




MSMSD MSMSD Date of











BOD 10665702 410 760 (82 R) NA mgL 1612 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO mgL 11212 80-120 20 H8000








11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054


of26 1201073 FinalReport

01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I



11 January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679


o26 120073 Fino Report

Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I



GLOBAL SCIENCES











OI1112012

18



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I



CASE NARRATIVE

SAMPLE RECEIPT









OJll2012



Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


Seattle WA 98109 Ph 206-622-6960Fx 206-622-6870

GLOBAL SCIENCES








OJIJJ2012



GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


GLOBAL SCIENCES

ANALYTICAL RESULTS


















OJll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Eff Grab



Arsenic

Mercury

Selenium

498 105

740

l02 034 388

300 202 120

microgJ ngL microgL

20 4

20

F201062 F201063 F201062

2Al0015 2A09010 2Al0015

011012 010912 011012


FB-1631





OlJl2012

22




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I




SOURCE 1201073-02





Mercwy 1048 1054 202 0617 24 EPA 1631E



OIIJI2012



GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


GLOBAL SCIENCES


SOURCE 1201073-01



Analyte

Beryllium


(microgL)


middot MS


MS

Recovery Recovery

Limits Method Notes

0522 20200 2676 107 75 bull 135 FGS-054

Aluminum 41l 15150 2107 112 80- ll5 FGS-054


Iron ND 50500 5636 112 75- 125 FGS-054

Nickel 803 40400 1198 977 68 bull I34 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 10100 910 874 46 - 146 FGS-054

Arsenic 532 15150 2217 111 85 - 115 FGS-054

Selenium 7173 30300 1006 953 59 - 149 FGS-054

Molybdenum 1403 20200 142l 888 80- 115 FGS-054

Silver ND 15150 1216 803 74 - 119 FGS-054

Cadmium 0207 080800 1076 108 84 - 113 FGS-054

Antimony 0520 080800 1360 104 79 - 122 FGS-054

Barium 3000 10100 3050 498 80 - 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium Aluminum

20200 15150

2639 2138

105 II4

139 150

75 - 135 80 bull 115

20 20

FGS-054 FGS-054


70700 50500 40400 40400 10100 15150 30300 20200 15150

080800

859 5538 1220 395 887 2281 1108 1435 l226 0956

115 llO 103 907 852 115 129 159 810 927

00611 176 183 115 251 284 965

0993 0852 118

85 bull 115 75 - 125 68 bull 134 51-145 46 - 146 85 - 115 59 - 149 80 - 115 74 - 119 84 bull 113

20 20 20 20 20 20 20 20 20 20


QM-02



0112012



~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


~

~CLOSAL SCIENCES


SOURCE 1201073-01



Spike Added

MSD Concentration

MSD Recovery RPD





011112012



Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

Ii

~GL06AL S CIENC ES



SOURCE 12010730tREl



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes


Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits







OlJJ2012

26


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


I

bull~



SOURCE 1201073-01



Analyte


(microgL)


MS Concentration

(pgL)

MS

Recovery Recovery

Limits Method Notes






Lead ND 50500 5195 103 72 - 143 FGS-054 AS

shy

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits


Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS

Aluminum 20200 2171 105 0234 80 - 115 20 FGS-054 AS

Chromium 20200 2313 114 0528 85 - 115 20 FGS-054 AS




Oll ll2012


bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

bull


GLOBAL SCIENCES


SOURCE 1201073-01







Lead 50500 5216 103 0399 72 - 143 20 FGS-054 AS



Ollll1011



1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


1111






Analyte


(microgL) (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Sodium

Manganese

277400 202000

293l 20200

474400

2396

975

104

75 - 125 80 - 120

FGS-054

FGS-054

AS AS

Analytc


MSD

RPD Recovery

Recovery Limits





Olli112012





SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I




SOURCE 1201073-02



Sample Spike MS MS


(ogL) Added

(ogL) Concentration


Limits Method Notes

l Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

middot

Analyte

Spike Added (ngL)

MSD Concentration

(ngL)

MSD

Recovery

Oo

RPD Recovery


Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E



Ollll2012


I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

I


GLOBAL SCIENCES


SOURCE 1112278-02





Mercwy 761 20400 2786 992 71 - 125 EPA I631E



Mercury 20400 2837 102 l82 71 - 125 24 EPA 1631E





Ollll2012

31



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I



100 71 - 125 163 lE Mercury 534 10200 1558 EPA




~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201029-01

Batch

Preparation

F201063

BrCl Oxidation

Sequence

Lab Number

2A02010

F20 I 063-MSMSD3



OJll2012



II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

II


GLOEAL SCIENCES


SOURCE 1201030-02




Mercury 554 10200 1482 910 71 - 125 EPA 163IE


Mercury 10200 1461 890 140 71 - 125 24 EPA I631E





Ollll2012

33


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

CLOBA L SCIENCES







Calciwn 5052000 15150 5067000 1010 70- 130 FGS-054 QM-02



Calcium 15150 5034000 -1 190 0660 70- 130 20 FGS-054 QM-02





OJ12012

34


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


GLOBAL SC IE NC ES





Analyte


(microgL)


MS MS Concentration


Limits Method Notes

Calcium 5052000 10100000 15570000 104 70-130 FGS-054

Analyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits


Calcium 10100000 15550000 104 0125 70 shy 130 20 FGS-054





01112012

35


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


GLOBAL SCIENCES


RECOVERY AND RPD






Beryllium 20000 2039 102 75 - 135 FGS-054

Sodium 50000 487 974 80- 120 FGS-054

Aluminum 15000 1524 102 85 - 115 FGS-054

Calcium 15000 1550 103 80- 120 FGS-054

Chromium 70000 682 974 85 - 115 FGS-054

Manganese 60000 603 101 85 - 115 FGS-054

Iron 50000 4815 963 80- 120 FGS-054

Nickel 40000 406 102 68 - 134 FGS-054

Copper 40000 415 04 51 - 145 FGS-054

Zinc 10000 1016 102 46 - 146 FGS-054

Arsenic 15000 1538 103 85 - 115 FGS-054

Selenium 30000 3150 105 59 - 149 FGS-054

Molybdenum 20000 197 983 85 - 115 FGS-054

Silver 15000 1569 105 74 - 119 FGS-054

Cadmiwn 080000 0850 106 84 - 113 FGS-054

Antimony 080000 0866 108 79- 122 FGS-054

Barium 10000 1041 104 85 - 115 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 - 143 FGS-054



Beryllium 20000 2078 104 191 15 - 135 20 FGS-054

Sodium 50000 496 992 188 80 120 20 FGS-054

Aluminum 15000 1544 103 128 85 ll5 20 FGS-054

Calcium 15000 1583 106 210 80 - 120 20 FGS-054

Chromium 70000 695 993 190 85 - ll5 20 FGS-054

Manganese 60000 615 103 197 85 115 20 FGS-054

Iron 50000 4946 989 269 80 120 20 FGS-054

shy

shy

shy

shy


Pa~ 9o26~~ 1201073 Final Report 012012




G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I



G LOB AL SCIENCES


RECOVERY AND RPD






Nickel 40000 415 104 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 -115 20 FGS-054

Selenium 30000 3257 109 335 59 - 149 20 FGS-054

Molybdenum 20000 l93 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FGS-054

Cadmium 080000 0868 108 204 84 - 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 FGS-054

Barium 10000 1054 105 125 85 - 115 20 FGS-054

Thallium 040000 0443 111 227 64 - 134 20 FGS-054

Lead 15000 1641 109 l85 72 shy 143 20 FGS-054



01112012



GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


GLOBAL SCIENCES


RECOVERY AND RPD

Batch F201063


Sequence 2A09010



Analyte

Spike Added (ngL)

LCS Concentration

(ngL)

LCS

Recovery Recovery

Limits Method Notes

Mercury 15679 1550 988 80 - 120 EPA 1631E

Analyte

Spike Added (ngL)

LCSD Concentration

(ogL)

1595

LCSD

Recovery

102

RPD

289

Recovery Limits

80- 120

RPO Limit

24

Method

EPA 1631E

Notes

Mercury 15679



Ollll2012



Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I


Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

~Ji ~NT~if

GLOBAL SCIENCES


RECOVERY AND RPD




Analyte


LCS Concentration

microgL)

LCS

Recovery Recovery

Limits Method Notes

Calcium 15000 1517 101 80- 120 FGS-054

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPD Recovery


Calcium 15000 1571 105 347 80- 120 20 FGS-054





OllI2012

39

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

GLOBAL SCIENC ES


PREPARATION BLANKS





I 050 ngL F201063 EPA 163IE u







01112012

40

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

1

~



~

6

PREPARATION BLANKS







Ollll2012


GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

GLOBAL SCIENCES


PREPARATION BLANKS







OlJl2012


bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

bull
























OIll2012

43

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

bull




11

lw 0IF COMPOSITE

w ~ u



DATETIME

1s-12

11s--J o5A Iwv 16--




I ~ le Q

- fbull - Q~ ~-1

a

)

i~~ ~

1shyI- i ~

~ ~ z C)

~ s t ~cz

~ = C z ~ii isect~ el g Q 5 ~ U) ~ ~ 2 = - -- ~

d

1 I ~ I NOTES

~ MEOH VIAL

3



RELINQUISHED BY

REPORTING OPTIONS


DATE

ELECTRONIC OPTIONS


TIME

TEIIPyen (

rm No

EQUJS

~ECIIVED Bl





1 cJQJ1









~J( bull - bull

QAQC REPORTIN9~EL


OR FAX _ _ _ ---- - -------------- shy




QUOTpound ~I

Industrial Wastewater Discharge Monitoring PSNH Merrimack ...€¦ · l GZA AR-1312....

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Transcript of Industrial Wastewater Discharge Monitoring PSNH Merrimack ...€¦ · l GZA AR-1312....