Industrial Wastewater Discharge Monitoring, PSNH Merrimack ... · Franklin Wastewater Treatment...

180 I larvlty Road Munchc1cr New llainp~hirc 03103-3347 603-623-3600 F X 603-624-9463 WWW glJCOITI

IAR-1314 A GI

Inlt GcoLnvironmcntil

2012 16 January 04002930700 No File

Lesieur y NancMs rdinator CooPretreatment Industrial

Plant Treatment Wastewater Franklin Division Water

Services Environmental of Department Hampshire New Street River 528

03235 Hampshire New Franklin

Monitoring Discharge Wastewater trial IndusRe (PSNl-1) ampshirc lI New of Service Public

Station Merrimack Hampshire New Bow

Lessieur Ms Dear

Analytical attached the submit lo eased lpis Inc tal nGeoEnvironmeGZA PSNH of behalf On The (WWTS) system treatment wastewater advanced y ltechnologicalPSNHs from Report The weeks several for criteria desi1ll the with ce rdanaccoin g tinoperabeen now has WWTS the of e representativare 2012 5 January on sampling from obtained results analytical attached ed treate thof characteristics The generated wastewater treated (FGD) Desulfurization Gas Flue

forward going consistent be to expected are wastewater

State the that request respectfully we data cal lytianaative trepresenavailable of consideration In as requirements sampling month first the satisfy to report analytical attached the accept

Agreement l SpeciaPSNHs in established

NOTATION ANALYTICAL

on interference matrix overcome to techniques analytical specialized requires wastewater FGD an offer We this of unaware be may laboratories analytical Many analysis metals trace some

heir tto nk lia and site web (EPAs) s Agencyection Protl tanvironmenEthe from below excerpt guidance further contains that procedure draft

WASTEWATER FGD OF ANALYSIS LABORATORY

interferences matrix cause to known constituents contain can systems FGD from Wastewater MS) -(ICPspectrometry mass -plasma coupled inductively during that observed has EPA

cause may wastewater the in present commonly elements certain wastewater FGD of analysis of elements certain of quantization r andodetection the bias that es interferencpolyatomic at elements trace measuring when ant ignificsecome bmay rences interfepotential These interest

range billion -parts-perlow the in concentrations

An Equal Oppommity Employer MFVH

Franklin Wastewater Treatment Plant File No 04002930700

January 16 20 12 Page 2

As part or a recent sampling effort for the steam electric power generating effluent guidelines rulcmaking EPA developed a standard operating procedure (SOP) that was used in conjunction with EPA Method 2008 to conduct ICY-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR I 366 already allow the analytical community tlexihility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The drali SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (iebull a synthetic FGD wastewater matrix) EPA s draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater e ither for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs ~ tanltard QQ_erating Procedure Inductively Coupled PlasmaMass Spectrometry for _]race Elcrlent Analysis in flue Gas Dcsllfurilltion Wastcwaters (30 pp 174K)

We trus t that this submittal adequately address your infonnational needs Should you have any questions please contact me at 232-8744

Very truly yours

GZA GEOENVIRONMENTAL INC

rfJraquootJti ~ Ronald A Breton P E Principal

RABtmd p04jobs0029)00sl04002930700worklsamplinamp and rc-ponirgrcmiddotpomfonal 2930100 cover letter 0 11112dOCJlt

Attachment(s)

SUMMARY ANALYTICAL DATA Puhlic Service Company of New Ilampshirc

Merrimack Station Bow New Hampshirc

PARAMETER RESULTS (mgL) 1052012 Alkalinity IRO

Aluminum 004 11

Ammonia 092

Antimony 0 000520

Arcnic 000498

Barium 0 300

Brryllium 0000522

BOD lt 6

Cadmium 0000207

Calcium 5050

Chloride 11000

Chlorine (Total Rrsidual) lt 005

Chromium (T) lt 000050

COD 130

Copper lt 000050

Cyanide(T) 002

Fluoride 10

Iron lt 0050

Lead lt 0000200

Manganese 0293

Mrrcury (l0000105

Molybdenum 0140

Nitrate 100

Nickel 000803

OampG lt 5

pH 73

Selenium 0074

Silver lt0000100

Sodium 2774

Sulfate 1200

Sulfide lt 01

Sulfite lt 2

TDS 21000

Thallium 000664

TSS 14

ITO ND(I) Zinc lt0001

voe EPA624 (2) Semi VOCs 625 ND(3)

Phenolic Compounds lt03

PCBs ND(4)

NOTES

I No lTO compounds were detected above O0 I mglL 2 One compound was detected by Method 624 Toluene at 2 microgL 3 Semi VOCs were not detected by Method 625 above detection limits ( I microgL and 5 microgL depending on

parameter and 50 microgL for benzoic acid) 4 PCB compounds analyzed by method 608 were not detected at concentrations greater than 03 microgL

lt04M100HJOOl(l4QOf)01CIOlilflSAMlIJp(l l)PJllfIRl1~NMIAli 040090100 IUSlLT$011612AJNfJIW lflOIIIJI l 1 GZA GeoEnvironmental Inc

--~-------------e_a_s_t_e_r_n_a_n_a_ly_t_ic_a_l__

Arthur Auclair

Northeast Utilities

97 River Road

Bow NH 03304

Subject Laboratory Report

Eastern Analytical Inc ID 106677

Client Identification Merrimack Station

Date Received 152012

Dear Mr Auclair middot

Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QNQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certi fies that the enclosed test results meet all requirements of NE LAP and other applicable state certi fications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters

The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery

Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NHOOS) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)

The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory

If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date

We appreciate this opportunity to be of service and look forward to your continued patronage

Sincerely

-~~ l-t3-12shy of pages ( excluding cover letter) Lorraine Olashaw Lab Director Date

SAMPLE CONDITIONS PAGE EAi 10 106677

Client Northeast Utilities

Client Designation Merrimack Station

Temperature upon receipt (0 C) 47 Received on ice or cold packs (YesNo) y Acceptable temperature range ( C) 0-6

Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments jotherthan thermal preservation)

10667701 Treat Tank Eff Composite 1512 1512 aqueous Adheres to Sample Acceptance Policy

10667702 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy


Samples were property preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint middot middot lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis

All results contained in this report relate only to the above listed samples

References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992

eastern analytical inc wwweailabscom Phone(603)228-0525 1

LABORATORY REPORT EAi ID 106677bull Client Northeast Utilities


Sample ID

Lab Sample ID Matrix

Date Sampled Date Received

Units

Date of Analysis

Analyst

Method

Dilution Factor

Chlorornethane Vinyl chloride Brornornethane Chloroethane Trichloronuorornethane Acrolein Acetone 11-Dichloroethene Methylene chloride Carbon disulfide Acrylonitrile Methyl-I-butyl ether(MTBE) trans-12-Dichtoroethene Vinyl acetate 11-Dichloroethane cis-12-Dichloroethene 2-Butanone(MEK) Chloroform 111-Trichloroethane Carbon tetrachloride Benzene 12-Dichloroethane Trichloroethene 12-Dichloropropane Bromodichloromethane 2-Chloroethylvinylether 4-Methyl-2-pentanone(MIBK) cis-13-Dichloropropene Toluene trans-13-Dichloropropene 112-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene mp-Xylene o-Xylene Styrene Bromoform 1122-Tetrachloroethane 13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene 4-Bromofluorobenzene (surr) 12-Dichlorobenzene-d4 (surr) Toluene-lt18 (surr)

Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624

lt5 lt2 lt2 lt5 lt 5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt 10 lt2

lt 10 lt2 lt2

lt 10 lt2 lt2 lt 2 lt 1 lt2 lt 2 lt2 lt2 lt2

middotlt 10 lt2

2 lt2 lt 2

lt 10 lt2 lt2 lt2 lt 1 lt 1 lt 1 lt 1 lt2 lt2 lt 1 lt 1 lt1

98 R 90R

100 R

eastern analytical inc wwweailabscom Phone (603) 228-0525 2

QC REPORT EAi ID 106677



Parameter Name Blank LCS LCSD Analysls Date Units Limits RPO Method - -shy--middot----shy-shy-shy- ---shy --shy--middot-

Chloromethane lt5 19 (97 R) 21 (105 R) (8 RPD) 162012 ug1 0 - 273 20 624

Vinyl chloride lt2 18 (91 R) 20 (101 R) (10 RPD) 162012 ug1 0 - 251 20 624

Bromomethane lt2 21 (105 R) 23 (113 R) (7 RPD) 162012 ug1 0 bull 242 20 624 Chloroethane lt5 19 (95 R) 20 (101 R) (6 RPO) 162012 ug1 14 - 230 20 624

T richloronuoromethane lt5 17 (84 R) 18 (88 R) (5 RPO) 162012 ug1 17 - 181 20 624

Acrolein lt 50 lt 50 (RNA) lt 50 ( R) ( RPO) 1162012 ug1 624

Acetone lt 50 lt 50 (78 R) lt 50 (90 R) (14 RPD) 1162012 ug1 624 1 1-Dichloroethene lt 1 17 (83 R) 18 (89 R) (7 RPO) 162012 ug1 0 - 234 20 624

Methylene chloride lt5 18 (88 R) 19 (93 R) (6 RPO) 162012 ug1 0 bull 221 20 624

Carbon disulfide lt5 17 ( R) 19 ( R) ( RPO) 162012 ug1 624

Acrylonitrile lt 50 lt 50 ( R) lt 50 ( R) ( RPO) 162012 ug1 624 Methyl-I-butyl ether(MTBE) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624

trans-12-0ichloroethene lt 2 18 (89 R) 18 (92 R) (3 RPO) 162012 ug1 54 - 156 20 624

Vinyl acetate lt 10 30(R) 30 ( R) ( RPO) 162012 ug1 624 1 1-0ichloroethane lt2 19 (93 R) 20 (98 R) (5 RPD) 162012 ug1 59 shy 155 20 624

cis-12-0ichloroethene lt 2 19(R) 20 ( R) ( RPO) 162012 ug1 624

2-Butanone(MEK) lt 10 20(R) 20 ( ooR) ( RPO) 162012 ug1 624

Chloroform lt2 19 (94 R) 20 (99 R) (5 RPO) 162012 ug1 51 - 138 20 624

11 1-Trichloroethane lt2 18 (91 R) 19 (97 R) (6 RPO) 162012 ug1 52 bull 162 20 624

Carbon tetrachloride lt 2 18 (91 R) 19 (95 R) (4 RPO) 162012 ug1 70 - 140 20 624 Benzene lt 1 19 (97 R) 20 (102 R) (5 RPO) 162012 ug1 37 shy 151 20 624

12-0ichloroethane lt2 18 (91 R) 19 (94 R) (3 RPO) 162012 ug1 49 - 155 20 624 Trichloroethene lt2 19 (93 R) 20 (98 R) (5 RPO) 162012 ug1 71 bull 157 20 624 12-0ichloropropane lt2 19 (95 R) 20 (98 R) (3 RPO) 162012 ug1 0 bull 210 20 624

Bromodichloromethane lt2 19 (96 R) 20 (100 R) (4 RPO) 162012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 23 (115 R) 24 (121 R) (5 RPO) 162012 ug1 0 bull 305 20 624 4-Methyl-2-pentanone(MIBK) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624

cis-13-Dichloropropene lt2 22 (109 R) 23 (113 R) (4 RPO) 162012 ug1 0 - 227 20 624

Toluene lt 1 20 (101 R) 21 (103 R) (2 RPD) 162012 ug1 47 bull 150 20 624 trans-13-0ichloropropene lt2 18 (90 R) 19 (93 R) (3 RPO) 162012 ug1 17 - 183 20 624 1 12-Trichloroethane lt2 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 52 bull 150 20 624 2-Hexanone lt 10 20 (R) 20 ( R) ( RPO) 162012 ug1 624 Tetrachloroethene lt2 20 (100 R) 21 (106 R) (6 RPO) 162012 ug1 64 bull 148 20 624 Oibromochloromethane lt2 20 (102 R) 21 (104 R) (2 RPO) 162012 ug1 53 - 149 20 624 Chlorobenzene lt2 20 (98 R) 20 (100 R) (2 RPO) 162012 ug1 37 bull 160 20 624 Ethylbenzene lt 1 20 (101 R) 21 (105 R) (4 RPO) 162012 ug1 37 - 162 20 624 mp-Xylene lt 1 40 (101 R) 43 (106 R) (5 RPO) 162012 ug1 70 bull 130 20 624 o-Xylene lt 1 21 (104R) 22 (109 R) (5 RPO) 162012 ug1 70 - 130 20 624 Styrene lt 1 21 ( R) 22 ( R) ( RPO) 162012 ug1 624 Bromoform lt2 18 (88 R) 18 (90 R) (2 RPO) 162012 ug1 45 - 169 20 624 1 122-Tetrachloroethane lt2 20 (99 R) 20 (100 R) (1 RPO) 162012 ug1 46 - 157 20 624 13-Dichlorobenzene lt 1 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 59 - 156 20 624 14-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 12-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 4-Bromofluorobenzene (surr) 100R 101 R 102 R 162012 Rec 70 - 130 624





Parameter Name Blank LCS LCSD Analysis Date Units limits RPO Method

12-Dichlorobenzene-d4 (surr) 93 R 90R 89R 162012 Rec 70-130 624

Toluene-dB (surr 100 R 102R 102 R 162012 Rec 70 - 130 624

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below


bull ~ LABORATORY REPORT EAi ID 106677



-- ______ ___ - - -- -middotmiddot ----~ - middotmiddotmiddot

Sample ID Treat Tank Eff Grab

Lab Sample ID 10667702

Matrix aqueous

Date Sampled 1512

Date Received 1512

Units ug1

Date of ExtractionPreparation 1612

Date of Analysis 1612

Analyst JMR

Method 625mod

Dilution Factor

Phenol lt 1 lt 12-Chlorophenol lt 124-Dichlorophenol lt 1245-Trichlorophenol lt 1246-Trichlorophenol

Pentachlorophenol lt5 2-Nitrophenol lt 1 4-Nitrophenol lt5 24-0initrophenol lt5 2-Methylphenol lt 1

lt 134-Methylphenol lt 124-Dimethylphenol lt 14-Chloro-3-methylphenol

46-Qinitro-2-methylphenol lt5 Benzoic Acid lt 50 N-Nitrosodimethylamine lt 1 n-Nitroso-di-n-propylamine lt 1 n-Nitrosodiphenylamine lt 1

lt 1bis(2-Chloroethyl)ether lt 1bis(2-chloroisopropyl)ether lt 1bis(2-Chloroethoxy)methane

13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 124-Trichlorobenzene lt 1 2-Chloronaphthalene lt 1

lt 14-Chlorophenyl-phenylether lt 14-Bromophenyl-phenylether

Hexachloroethane lt 1 Hexachlorobutadiene lt 1 Hexachlorocyclopentadiene lt5 Hexachlorobenzene lt 1 4-Chloroaniline lt 1 2-Nitroaniline lt5 3-Nitroaniline lt 1 4-Nitroaniline lt 1 Benzyl alcohol lt5 Nitrobenzene lt 1 lsophorone lt 1 24-0initrotoluene lt 1

lt 126-Dinitrotoluene Benzidine (estimated) lt5 33-Dichlorobenzidine lt 1 Pyridine lt5 Azobenzene lt 1


ltmiddotbull lt

LABORATORY REPORT EAi ID 106677





Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1

Date of Ext ractionPreparation 1 612


Analyst JMR

Method 625mod

1Dilut ion Factor Carbazole lt 1

Oi-n-butylphthafate lt5

Phenol--06 surr) 24R

Dimethylphthalate lt 1 Diethylphthalate lt 1

Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1

lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1

lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R

90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)

p-Terphenyl-014 (surr) 84R


QC REPORT EAi 10 106677I

Batch ID 734507-32510A010512E6251Client Northeast Utilities


LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank

lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol

39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)

lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol

152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)

lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)

lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)

16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)

lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene

13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1

lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene

16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)

18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)

lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene

Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod

lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline

2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod

19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)

lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene

lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod

21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)

lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene

Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod

ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012

Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod

18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1





Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-

Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod

lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate

Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod

152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)

Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod

bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod

152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)

Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod

Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod

2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod

Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod

Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod

Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod

lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene

Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod

Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod

lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene

Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod

Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod

lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene

Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod

lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod

19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012

39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R

28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R

76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)

2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod

33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec

shy

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits

Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample

J eastern analytical inc wwweailabscom Phone (603) 228-0525 8




Sample ID

Lab Sample ID

Matrix


Units

Date of ExtractionPrep

Date of Analysis

Analyst

Method

Dilution Factor

Oil amp Grease (HEM)

Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5





Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD

lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)


eastern analytical inc wwweaiabscom Phone (603) 228-0525 10

LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R



Client Northeast Utilities Batch ID 734508-43146A010612E608P1


Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy

PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608

PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608

PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608


PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608

PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608

PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits





Sample ID Treat Tank Eff Composite


Matrix aqueous

Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst

Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ



Matrix aqueous

Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst

Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC

Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences


QC REPORT EAi ID 106677bull ~ Client Northeast Utilities


Date of

Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method

Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U

Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C

Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000

Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000

Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE

Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532

Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B

Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE

Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N

Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH

Sulfite lt2 NA NA mgL 1512 3771

Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG

BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106

COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000

Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201

pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B

Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits


QC REPORT EAi 10 1066774

l1LAAI Client Northeast Utilities


Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method

Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B

Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits


QC REPORT EAi 10 106677 IMAI Client Northeast Utilities

C lient Designation Merrimack Station

MSMSD MSMSD Date of

Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method

Solids Suspended NA NA NA mgll 110112 20 25400

Solids Dissolved NA NA NA rngL 1111112 2540C

Fluoride NA NA NA mgll 111112 20 3000

Sulfate NA NA NA mgll 111112 20 3000

Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE

Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532

Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208

Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE

Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3

Sulfide NA NA NA mgL 1111112 20 8131HAC

Sulfite NA NA NA mgL 11512 3771

Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG

BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108

COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000

Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201

pH NA NA NA SU 15112 10 4500H+B

Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix

interference



~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES

I I January 2012

Jeff Gagne

Eastern Jnalytical Inc

25 Chenell Drive

Concord NH 03301

RE Merrimack Station

Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control

measurements are within established control limits and there were no analytical difficulties encountered

with the exception of those listed in the case narrative section of this report

Ifyou have any questions concerning this rcpo11 please feel free to contact me

Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S

414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60

Fx 206-622-6870

ANALYTICAL REPORT FOR SAMPLES

Laboratory

Client

Frontier (ilobal_ Sciences_Inc

Eastern Anilitical)m

SDG

PrnjltmiddotltmiddotI Merrimack Slation

Sample ID Lah ID Matrix Date Samolcd Date Received

Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950

Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950

The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety

Frontier Global Sciences Inc

Liz Siska Project Manager

Pagel o26 1201073 Final Report

OlJl2012

18

414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870

GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT

Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius

SAMPLE PREPARATION AND ANALYSIS

Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638

Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E

ANALYTICAL AND QUALITY CONTROL ISSUES

There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report



The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety

Page2 o26 20073 Final Report

OJIJJ2012

19

1 ~bullbull bull bull bull bull bull

-middot bull

~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~

middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy

- - --shy ~-- -

- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot

middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--

- -- -1

~J middotmiddot h middot 1 C ~

-

Frontier Global Sciences Inc The results in this rchai11 ofcustody do

eport only apply to the sacument This ana1ica re

mples analyzed in accordance with the port must be reproduced in its entirety


114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60

FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S

CHAIN OF CUSTODY FORMS

shyshy

Page 3 o26 I 201073 Final Report

OJ1112012

20

4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960

~ Fx 206-622-6870 GLOllAL SCIENCl$

ANALYTICAL RESULTS

Treat Tank Eff Composite

Matrix W)Cf Lihorntory ILgt lWl07 l-Ol

Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes

A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054

Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054

Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054

Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054

Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054

Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054

Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054

Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054

Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054

Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054

Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u



The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 4 o26 I20073 Final Report

OJl 12012

21

-114 lonti11s vc North Slmiddotattk W 98109

~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab

L1boratory ID 120 I073-02 Matrix W[t_er

Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes

Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054

Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631

Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051

The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety



Page 5 o26 1201073 Final Report

Olll2012

22

1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960

FRONTIER Fx 206-622-6870 GLOBAL SCIENCES

MATRIX DUPLJCATESTIUPLICATES

SOURCE I 201073-02

Batch F201063 Sc1ucncc ]Alt)2SJll

Preparation rCI O[ idition Lab Number F201061 DUI

Sample Duplicate Concentration Concentration Yo RPD

Analyte ugL ngL MRL RPO Limit Method Noles

Mercury 1048 1054 202 0617 24 EPA 1631E



The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety

Page 6of26 1201073 Final Report

Ollll2012

23

414 Pontius vc Nonh Scank WA 98109

- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD

SOURCE 120middot1073-01

Batch F20106_f Sequence 2Al0002

Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21

Anilyte

Sample Concentration

(11gL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes

Beryllium 0522 20200 2676 107 75 shy 135 FGS-054

Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054

Selenium 7173 30300 1006 95J 59 shy 149 FGS-054

Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054

Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054

Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02

Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02

Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits

RlD Limit Method Notes

20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054

Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02

Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy


The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety

Page 7of26 I Z0073 Final Report

OIIIl2012

24

Frontier Global Sciences Inc The results in this reclain ofcustody docu


port only apply to lhe sme11t This analytical

amples analyzed in accordance with the report must be reproduced in its entirely

~

FRONTIER GLOBAL SCIENCES

41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870

MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO

SOURCE 1201073-01

Hatch l-20 I 062 ScIUllllC 2 I 0002

Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI

Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte

RPIgt Recovery Limits Limit Mclhod Notes

Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054

Page 8026 20073 FillOI Report

Olli112012

25

414 Ponti11s A vc North Scalllc- WA 9XI09

Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot

CL06AL S C IENCES

MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD

SOURCE 1201073-0lREI

Batch F20 I 0g Sequence 2A 10002

Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2

Sa mplc Spike MS MS Concentration Added Concentration lo Recovery

Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits

264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500

2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600

Spike MSD MSD o RPOAdded Concentration oo Recovery

RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc

- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n

Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety


Oll l 12012

26 Liz Siska Project Manager

4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960

~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES

MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01

Balch F201062 Scc1uc11cc 2A I 0002

Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1

Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles

AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS

Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPO Limit Metltod Notes

Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS


~ -__ - --lt1-lt--4-x-__~


The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety

Page Oo26 1201073 Final Report

0111112012

27

-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~

GLOBAL SCIENCES

shy

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01

Batch J2P1Pigt1 Sequence 2-1JQOOf

Preparation Clo~cd Vcs~cl Nitric Oven Digcstion

Analytc

Barium

Srikc MSO Added Concentration (JlgL) (microgL)

MSIgt o

Recovery

bully RPO

Recovery Limits

RPOLimit Method Notes

40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS

Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS



The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety

1 of26 1201073 Final Reporl

011111201)

28

4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull

FRONTIER b 206-622-6870 GLOBAL SCIENCES

MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO

SOURCE 1201073-0IRl~l

Scqucnctbull ~ tnool Prcparnlion

Analyle

Sodium

Closed Vc~scl Nilric Oven Di1eSlio11


(microgL)

277400

Spike Adclcd (microgL)

202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes

AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS

shy

The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety


OIll2012


Liz Siska Project Manager 29

1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60

FRONTER- Fx 06-6E 6K70

cLoBAL SC I ENCES

MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-02

Sequence 2 A090(0 Balch F201063

lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I

Sample Spike MS MS Concenlration uConcentration Atlded Rccocry

Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils

Mercury I048 20400 3136 102 71 - 125 EPA 16J JE

Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion

RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc

Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E



The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 13 of26 20073 FinaReport

01112012

30

I

414 Pontius Ave North Scallk W 9XIOIJ

lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES

MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1112278-02

Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ

Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm

Analyte

Sample Conccntrition

(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o

Recovery Rltcomiddote ry

Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits

RPOLimit Meihod Notes

Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E

Frontier G lobal Sciences Inc


The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety


Ol112012

31

414 Pontius Ave North

~ Scat k WA 11810)

Ph 206-022middotltgt0

~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)

SOlJRCE 1201029-01

Batch F20 I 063 Sequence 2A090 I 0

lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits

Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E

Spike MSD MSD bully

Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte

Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E

The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery


_~-f A i ~middot _ -ltlt~-- ~


Page 15 o26 1101073 Final Reporl

011 12012

32



II

middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960


MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201030-02

Btlch _F20 I063 Sclt1ucncc 2 A090 l 0

Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121

Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery

Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s

Mercury 551 10 200 11R2 910 71 - 125 EPA 16311

Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo

RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle

Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE

The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery

Page 16oj26 1201073 Final Report

0112012

33



middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60

~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD

SOURCE 1201073-01 RE2

Batch F201077 Scqucnc( 2A IOOl 5

Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I

Sample Spike MS MS Concentration Added Concentration Oo Rccowry

Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits

Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02

Spike MS D MS D Recovery RPO Added Concentration 0o

rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc

Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02

The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety

Page 17 026 1201073 Final Report

Ol112012

34

1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J

GLOBAL SCllNCES


SOURCE 1201073-01RE2

Batch F20 1077 Sequence ]_A 100 15

Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2

Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes

Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051

Spike MSD MSD Oo Added Concentration Recovery RlD 0o

RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc

Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054



The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety


0112012

35



41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt

Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20 I062 Sequence 2A I0002

Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I

LCS Source Blank Spike

Spike LCS ICS Added Concentration o Recove ry

Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles

DeryIlium 20000 2039 102 75 I5 FltiS-054

Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054

Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051

Manganese 60000 603 IOI RS - 11 5 FGS-054

Iron 50000 4815 963 80 middot 120 FGS-054

Nickel 40000 406 102 68 middot 134 FGS-054

Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J

Selenium 30000 3 150 105 59 middot 149 FGS-054

Molybdenum 20000 197 983 85 middot 115 FGS-054

Silver 15000 1569 105 74 middot 119 FGS-054

Cadmium 080000 0850 106 84 middot 11 3 FGS-054

Antimony 080000 0866 108 79 middot 122 FGS-054

Barium 10000 I041 104 85 middot 11 5 FGS-054

Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy

Spike LCSO LCSD Added Concentration Recovery RPO

Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes

Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054

Manganese 60000 615 103 197 85 shy 115 20 FGS-054

Iron 50000 4946 989 269 80 - 120 20 FGS-054

1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety

Page 9o26 1201073 Final Report

0111112012

36



-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~



RECOVERY AND RPD

Ballth F20 1062 Sequence 2A 10002

lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1

LCS Source Blan~_Spi~

Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt

Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054

Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054

Lead 15000 1641 109 185 72 shy 143 20 FGS-054

77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety

Page20of26 1201073 Final Report

0111112012

37

-11-1 1lt1111 ius w Nori fl Scal1lc W 98109

~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE

RECOVERY AND RPJgt

Balch F20106J Sequence ] OQ0 I 0

lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ

LCS Source Nist 164 Id

Spike LCS LCS Added Concentration oo Recovery

Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes

Mercury I5lti79 1550 98R 80- 120 EPA 16311

Spike LCSD Added Concentration

Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E


_ Amiddot1 ~- --lt-JltJ-to(__


The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety

Page 21 o26 120073 Final Rtporl

OJIJJ2012

38

414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960

FRONTIER rx 206-622-6870 CL08AL SCIEN CES

shy

LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F701077 Sequence _2A I 00L~

Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ


Spike LCS LCS Added Concentration Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Cakium 15000 1517 101 80 - 120 FGS-054

Spike LCSIgt LCSD Added Concentration 0o Recovery RPO

Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes

Calcium 15000 1571 105 347 80 - 120 20 FGS-054



The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I

Page22o26 1201073 Final Report

Ol112012

39

4 14 10111 ius Avc Nor1h Scatlh WA 981(1)

lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS

Instrument J_g-17 Seq uence 2~Q20

Prcpa ration BrCI Oxidatitm

Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles

F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06



The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety

Page 23 oj26 120073 Final Report

Oll12012

40

middot11 bulll Pnnl iu~ Ave Nor1h

II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS

lnslrument JCPMS-6 Sr(Jurnce 2 A 10002

P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion

Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes

F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ

F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ

F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ

(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054

F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10

f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ



The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety


OJ112012

41

~ shy

FRONTIER--

4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870

GLOBAL SCIENCES

Instrument JCPMS-6 Sequence I A I001 5

Preparation ~loscd Vcsscl_Nitric Oven Digestion

Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes

F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u

PREPARATJON BLANKS


--1 I ~- ---lti-~~middotK-o__~


The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety


012012

42

114 10111i11s Avlt N(gt11h

SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870

GLOUAL SCIENCES

Nofes and Definitions

lJ Analyte included in the analysis hut not detected

QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO

QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)

QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL

QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result

FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110

med 163 IE criteria

AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analytc Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Ditlerence

RSD Relative Standard Deviation



The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety

Page 26026 1201073 Final Report

011111202

43

-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677

SAMPLING

DATE TtME

BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS

is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -

c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO

Q ~ - ~ ~ 0 Q ~~

i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES

3 MEOH VIAL SAMPLE ID

i( f ft h~ pound f-j f~ I

IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH

DATE I T1ME f1tJ lt bullmiddot TV

-i _ 1_0 bullltshy

- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=

bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n

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r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I

bull I 1 I I I I I I I I I I 1 I Il I I I i I --I

1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm

WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH

PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -

C bull7 7 (ADOEII IS fpjc kl

ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _

ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _

Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -

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MA ME YT OHE_ ___ _ _ _ _IUIE NH

REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk

GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---

PO uJJ-Jc-l

METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc

QAQC REPORTING-~VEL

A CCD OR

PRESUMPTIVE CERTAINTY

RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _

FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY

REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No

ICE G_j) No

0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF

Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII

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eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH

rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)

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Franklin Wastewater Treatment Plant File No 04002930700

January 16 20 12

As part or a recent sampling effort for the steam electric power generating effluent guidelines rulcmaking EPA developed a standard operating procedure (SOP) that was used in conjunction with EPA Method 2008 to conduct ICY-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR I 366 already allow the analytical community tlexihility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The drali SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (iebull a synthetic FGD wastewater matrix) EPA s draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater e ither for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs ~ tanltard QQ_erating Procedure Inductively Coupled PlasmaMass Spectrometry for _]race Elcrlent Analysis in flue Gas Dcsllfurilltion Wastcwaters (30 pp 174K)

We trus t that this submittal adequately address your infonnational needs Should you have any questions please contact me at 232-8744

Very truly yours

GZA GEOENVIRONMENTAL INC

rfJraquootJti ~ Ronald A Breton P E Principal

RABtmd p04jobs0029)00sl04002930700worklsamplinamp and rc-ponirgrcmiddotpomfonal 2930100 cover letter 0 11112dOCJlt

Attachment(s)




Aluminum 004 11

Ammonia 092

Antimony 0 000520

Arcnic 000498

Barium 0 300

Brryllium 0000522

BOD lt 6

Cadmium 0000207

Calcium 5050

Chloride 11000



COD 130

Copper lt 000050

Cyanide(T) 002

Fluoride 10

Iron lt 0050

Lead lt 0000200

Manganese 0293

Mrrcury (l0000105

Molybdenum 0140

Nitrate 100

Nickel 000803

OampG lt 5

pH 73

Selenium 0074

Silver lt0000100

Sodium 2774

Sulfate 1200

Sulfide lt 01

Sulfite lt 2

TDS 21000

Thallium 000664

TSS 14




PCBs ND(4)

NOTES





Arthur Auclair

Northeast Utilities

97 River Road

Bow NH 03304












Sincerely
















Sample ID



Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624


lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt 10 lt2

lt 10 lt2 lt2


middotlt 10 lt2

2 lt2 lt 2


98 R 90R

100 R









































Matrix aqueous

Date Sampled 1512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod

Dilution Factor











ltmiddotbull lt






Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod









































































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Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS




Page 11 of26 1201073 Final Reporl

011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy




Aluminum 004 11

Ammonia 092

Antimony 0 000520

Arcnic 000498

Barium 0 300

Brryllium 0000522

BOD lt 6

Cadmium 0000207

Calcium 5050

Chloride 11000



COD 130

Copper lt 000050

Cyanide(T) 002

Fluoride 10

Iron lt 0050

Lead lt 0000200

Manganese 0293

Mrrcury (l0000105

Molybdenum 0140

Nitrate 100

Nickel 000803

OampG lt 5

pH 73

Selenium 0074

Silver lt0000100

Sodium 2774

Sulfate 1200

Sulfide lt 01

Sulfite lt 2

TDS 21000

Thallium 000664

TSS 14




PCBs ND(4)

NOTES





Arthur Auclair

Northeast Utilities

97 River Road

Bow NH 03304












Sincerely
















Sample ID



Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624


lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt 10 lt2

lt 10 lt2 lt2


middotlt 10 lt2

2 lt2 lt 2


98 R 90R

100 R









































Matrix aqueous

Date Sampled 1512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod

Dilution Factor











ltmiddotbull lt






Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod









































































shy







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy

o26 I 201073 Final Report

OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


Arthur Auclair

Northeast Utilities

97 River Road

Bow NH 03304












Sincerely
















Sample ID



Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624


lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt 10 lt2

lt 10 lt2 lt2


middotlt 10 lt2

2 lt2 lt 2


98 R 90R

100 R









































Matrix aqueous

Date Sampled 1512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod

Dilution Factor











ltmiddotbull lt






Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod









































































shy







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS


















o26 I20073 Final Report

OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy















Sample ID



Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624


lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt 10 lt2

lt 10 lt2 lt2


middotlt 10 lt2

2 lt2 lt 2


98 R 90R

100 R









































Matrix aqueous

Date Sampled 1512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod

Dilution Factor











ltmiddotbull lt






Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod









































































shy







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab









o26 1201073 Final Report

Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy



Sample ID



Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

1512

1512

ug1

1612

KJP

624


lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt 10 lt2

lt 10 lt2 lt2


middotlt 10 lt2

2 lt2 lt 2


98 R 90R

100 R









































Matrix aqueous

Date Sampled 1512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod

Dilution Factor











ltmiddotbull lt






Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod









































































shy







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E




of26 1201073 Final Report

Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy








































Matrix aqueous

Date Sampled 1512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod

Dilution Factor











ltmiddotbull lt






Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod









































































shy







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy



of26 I Z0073 Final Report

OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy















Matrix aqueous

Date Sampled 1512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod

Dilution Factor











ltmiddotbull lt






Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod









































































shy







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01






026 20073 FillOI Report

Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy







Matrix aqueous

Date Sampled 1512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod

Dilution Factor











ltmiddotbull lt






Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod









































































shy







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy

ltmiddotbull lt






Matrix aqueous

Date Sampled 1 512

Date Received 1512

Units ug1



Analyst JMR

Method 625mod









































































shy







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy































































shy







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS




of26 1201073 Final Reporl

011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy

































shy







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy




Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Eff Grab

10667702

aqueous

151 2

t 512

mgL

1912

191 2

LAS

1664A

lt5









LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E




of26 20073 FinaReport

01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy








LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy

LABORATORY REPORT



EAi ID 106677

Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor

PCB-1016

PCB-1221

PCB-1232

PCB-1242

PCB-1248

PCB-1254

PCB-1260 TMX (surr)

DCB (surr)

T reat Tank EH Grab

10667702

aqueous

1512 1512

ug1

1612

1612

JW

608

lt 03

lt 03 lt03

lt 03

lt 03

lt 03 lt 03

81 R 96R






PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E





o26 1101073 Final Reporl

011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy





PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608






PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608

162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R

95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)








Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE


oj26 1201073 Final Report

0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy






Matrix aqueous





Matrix aqueous







Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02


026 1201073 Final Report

Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy



Date of















COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000














MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy










MSMSD MSMSD Date of














BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108



pH NA NA NA SU 15112 10 4500H+B


interference




I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


I I January 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301






Sincerely

Liz Siska

Project Manager

17

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E





o26 120073 Final Rtporl

OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy

~ FRONTIER

GLOBAL SCIENC E S


Fx 206-622-6870


Laboratory

Client



SDG









OlJl2012

18


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


GLOBAL SCIENCES

CASE NARRATIVE

SAMPLE RECEIPT











OJIJJ2012

19


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06




oj26 120073 Final Report

Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


-middot bull



- - --shy ~-- -



- -- -1


-








shyshy


OJ1112012

20



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy



ANALYTICAL RESULTS



















OJl 12012

21


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


~ Ph 206-lt7J-(960 t Fx 206-622-6870

GLOBAL SC IENC ES

ANALYTICAL RESULTS

Treat Tm1k Eff Grab










Olll2012

22




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria













026 1201073 Final Report

011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy




SOURCE I 201073-02





Mercury 1048 1054 202 0617 24 EPA 1631E





Ollll2012

23



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy



GLOBAL SCIENCES





Anilyte


(11gL)


MS Concentration

(microgL)

MS

Recovery Kccovcry

Limits Method Notes


Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054

Chromium 047 70700 859 115 85 - 115 FGS-054

Iron ND 50500 5636 11 2 75 - 125 FGS-054

Nickel 803 40400 1198 977 68 shy 134 FGS-054

Copper 029 40400 400 918 51 - 145 FGS-054

Zinc 027 I0100 910 874 46 - 146 FGS-054

Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054


Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054

Silver ND 15150 1216 803 74 shy 119 FGS-054


Antimony 0520 080800 1360 104 79 shy 122 FGS-054

Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02


Lead ND 15150 1635 108 72 shy 143 FGS-054

Analyte

Berylliwn


MSD Cooce11tration

(microgL)

MSD

Recovery

1o RPD

Recovery Limits


20200 2639 105 139 75 - 135 20 FGS-054

Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054

Chromium 70700 859 115 0061] 85 - 115 20 FGS-054

Iron 50500 5538 I 10 176 75-125 20 FGS-054

Nickel 40400 1220 103 183 68 - 134 20 FGS-054

Copper 40400 395 907 115 51 - 145 20 FGS-054

Zinc 10100 887 852 251 46- 146 20 FGS-054

Arsenic 15150 2281 115 284 85 - 115 20 FGS-054

Selenium 30300 1108 129 965 59 - 149 20 FGS-054


Silver 15150 1226 810 0852 74 - 119 20 FGS-054

Cadmium 080800 0956 927 118 84 - 113 20 FGS-054


~

I ---lt1shy-~~-shy




OIIIl2012

24





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy





~




SOURCE 1201073-01







Olli112012

25



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy



CL06AL S C IENCES







264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500







Oll l 12012


4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy

4111nlius Avl Norlh

~ Scat1lc WA 98109bull Ph 206-622-6960



SOURCE 1201073-01



Analytc

Bcrylli11111


(microgL)

0522

Spike Atlded JtgL)

10 100

MS Conccnlralion

(microgL)

10 96

MS Yo

Recomiddotcry

103

RccovClyLimits

75 shy 135

Mclhod

FltiS-054

Noles


Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits




~ -__ - --lt1-lt--4-x-__~




0111112012

27


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


GLOBAL SCIENCES

shy


SOURCE 1201073-01



Analytc

Barium


MSIgt o

Recovery

bully RPO

Recovery Limits



Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01

Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS





011111201)

28






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy






Analyle

Sodium



(microgL)

277400


202000

Lah Numhcr

MS Cn11cc11tration

(microgL)

474400

F20 I 0lt2-

MS Oo

Recovery

975

MS MSD1

Rccovuy Limil-

75 - 125

Mclhod

FGS-054

Noles

AS Mingancsc

Analytc

Sodium

293 1


202000

20200

MSO Concc11tration

(microgL)

480300

2

MSD Yo

Recovery

100

396

o RPO

125

104

Recovery Limits

75 - 125

80 120

RPD Limit

20

FGS-054

Method

FGS-051

AS

Notes


shy



OIll2012





cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy



cLoBAL SC I ENCES


SOURCE 1201073-02





Mercury I048 20400 3136 102 71 - 125 EPA 16J JE



Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E





01112012

30

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy

I


lh 206-622-6960 Fx 206-622-6870~~~~

GLO BA L SCIEN CES


SOURCE 1112278-02



Analyte


(ngL)

Spike Added (ngL)

MS Concc11tr1tion

(ngL)

MS o


Limits Method Noles

Mcrcury

Analyte

761 20400 2786 992 71 - 125 EPJ 1631E

Spike Added (ng1)

MSD ltonccnlralion

(ngL)

MS D oo Yo

RPO Recovery

Recovery Limits







Ol112012

31


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


~ Scat k WA 11810)




SOlJRCE 1201029-01






Spike MSD MSD bully


Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E






011 12012

32



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy



II




SOURCE 1201030-02





Mercury 551 10 200 11R2 910 71 - 125 EPA 16311



Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE



0112012

33






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy






SOURCE 1201073-01 RE2








Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02



Ol112012

34


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


GLOBAL SCllNCES






Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051



Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054





0112012

35






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy






RECOVERY AND RPD








Calcium 15000 1550 103 80 - 120 FGS-054

Chromium 70000 682 974 85 11 5 FGS-051


Iron 50000 4815 963 80 middot 120 FGS-054


Copper 40000 4 15 104 5 1 - 145 FGS-054

Zinc 10000 10 16 102 46- 146 FGS-054

Arsenic 15000 1538 103 85 115 FGS-05J







Thallium 040000 0433 108 64 - 134 FGS-054

Lead 15000 1611 107 72 middot 143 FGS-054

shy

shy

shy

shy



Beryllium 20000 2078 104 191 75 - 135 20 FGS-054

Sodiwn 50000 496 992 188 80 - 120 20 FGS-054

Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054

Calcium 15000 1583 106 210 80 shy 120 20 FGS-054

Chromium 70000 695 993 190 85 - 115 20 FGS-054


Iron 50000 4946 989 269 80 - 120 20 FGS-054



0111112012

36






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy






RECOVERY AND RPD






Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054

Copper 40000 428 107 301 51 - 145 20 FGS-054

Zinc 10000 1052 105 348 46 shy 146 20 FGS-054

Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054

Selenium 30000 3257 109 335 59 shy 149 20 FGS-054

Molybdenum 20000 193 966 172 85 - 115 20 FGS-054

Silver 15000 1557 104 0768 74 - 119 20 FltoS-054

Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054

Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054

Barium 10000 1054 105 125 85 shy 115 20 FGS-054


Lead 15000 1641 109 185 72 shy 143 20 FGS-054



0111112012

37


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870

GLOBAL SCIENCES


RECOVERY AND RPJgt








Analytc (n~L) (ngL)

Mercury 15679 1595

LCSD Oo

Recovery Yo

RPO Recovery

Limits

llI)

Limit Mcthocl Notes

102 289 80 - 120 2middot1 EPA 1631E






OJIJJ2012

38



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy



shy


RECOVERY AND RPD






Cakium 15000 1517 101 80 - 120 FGS-054



Calcium 15000 1571 105 347 80 - 120 20 FGS-054





Ol112012

39


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


lh 206-622-6960 Fx 2ltl6-622-6S70

PREPARAT ION BLANKS




F201063-BLK I

F201063-BLK2

F201063-BLK3

F20 I063-13LK4

r20 I063-I3LK5

Mercury

Mercury

Mercury

Mercury

Mercury

-0009

-0006

-002

003

011

050

050

050

050

052

ngL

ngL

ngL

ngL

ngL

F20 1063

f201063

F20 1063

f-20 1063

F201063

EP 163 IE

EPA 1631E

EPA 163 IE

fPA 163 1E

EPA 1631E

u lJ

u u Q13-04

u QIJ-06





Oll12012

40


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


II ~-~ FRONTIER

GLOUAL SCIENC[S

Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70

PREPARATION BLANKS














OJ112012

41

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy

~ shy

FRONTIER--


GLOBAL SCIENCES





PREPARATJON BLANKS






012012

42

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy

114 10111i11s Avlt N(gt11h


GLOUAL SCIENCES









med 163 IE criteria














011111202

43


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy


SAMPLING

DATE TtME


is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -


Q ~ - ~ ~ 0 Q ~~




IFCOMPOSITE

I N D ICATE 80TH

START amp F tNISH


-i _ 1_0 bullltshy




I











hoJE[ 5ltji1




PO uJJ-Jc-l


QAQC REPORTING-~VEL

A CCD OR





ICE G_j) No



I Cmiddot c



l) N $ middot Hj



~1- - ~

e lt-shy



shy

shy

shy

shy

shy

shy

Industrial Wastewater Discharge Monitoring, PSNH Merrimack ... · Franklin Wastewater Treatment...

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Transcript of Industrial Wastewater Discharge Monitoring, PSNH Merrimack ... · Franklin Wastewater Treatment...