index

Introduction

Part 9

Index

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INDEX

Index Terms Links

A

ABS/MMT

emulsion copolymerisation 206

emulsion polymerisation 519

preparation 177

Acrylic CPNC 206

preparation 526

2-Acryl-amido-2-methyl-1-propane sulfonic acid 209

Aluminosilicates 465 477

Amino-aryl lactam 503

Amino dodecanoic acid 109 204 353 433 436

574

ω-Amino dodecyl acid 13 102 243 503

ω-Amino hexanoic acid 469

Amino lauric acid 127 228 400

Aminosilane 499

Ammonium intercalants

thermal instability 565

Annite 75

Aromatic amino-phthalimides 575

Aspect ratio 1 369

Atomic force microscopy 14

Attapulgite 76

Automotive 604

Avrami equation 397 405 414

Index Terms Links


B

Barium hexaferrite 2

Barrier films 586

Barrier properties 557 559 618

Batch mixing 150

Batteries 165

Beidellite 183

Bentonite 32 79

Biodegradable 246 252

Biological materials 5

Bonding

platelets/matrix 626

Brabender 605

Bulk polymerisation 525

Butadiene-acrylonitrile rubber/MMT 210

2-(N-Butyl-N,N-diethyl

ammonium bromide) ethyl acrylate 207 527

C

Cadmium selenide 54

Cadmium sulfide 5 226

Calcium phosphate 413

Carbon black 31 472 601

Carbon nanotubes 38

electrical conductivity 46

source 46

Catalyst poisoning 340

Catalytic activity 340

Cation exchange 254 525

capacity 98 215 221 274

reactions 88

Index Terms Links


Celadonite 75

Ceramic 2

foam 249

matrix 3

Cetyl-pyridinium chloride 176 415

Cetyl trimethyl ammonium bromide 528

Chalcogenides 35

Char 614

Chlorides 35

Chlorite 76

Clay

classification 73

Hudson grafting 499

origin 73

platelet edge treatment 505

purification 622

surface groups 626

thermal stability 333

treatment with epoxy 32

wetting 507

Co-solvent route 533

Co-vulcanisation 210

Cobalt 2 225

Combustion 614

Commercial 18 119 627

Companies 18 694

Compatibilisation 97 133 167 203 269

276

Compatibiliser 280 490

copolymers 134

Index Terms Links


Compatibilis (cont.)

functionalised 500

homopolymer 535

multi-branched star-type polymers 542

PA CPNC 442

PP-MA 239

Computer model 299

Conductive polymers 196 577

Conductivity 253

Cone calorimetry 532 614

Configurational entropy 264

Consumption 6

Continuous mixing 152

Copper 3 56 225

Copper sulfide 18

Cost 70 553

Crown ethers 101

Crystallisation 395

Curing agent 580

Cyanides 35

DL-Cysteine 112

D

Di(2-ethylhexyl) phthalate 535

Di-onium 449

Dielectric spectroscopy 300

Diffusion 302 304

Diglycidyl ether of bisphenol-A/organoclay 192

N,N-Dimethyl-amino-methacrylate 112

Dimethyl aminopropyl acrylamide 207

Index Terms Links


Dimethyl ammonium chloride 483

Dimethyl benzyl hydrogenated

tallow ammonium chloride 327

Dimethyl-benzyl-octadecyl ammonium 105

Dimethyl benzyl stearyl ammonium chloride 136 207 484

Dimethyl dihydrogenated tallow ammonium chloride 17 111 112 144 161

170 493

Dimethyl dioctadecyl ammonium halide 102 105 145 160 165

168 171 209 488 565

Dimethyl ditallow ammonium 209 232

1,2-Dimethyl-3-N-hexadecyl

imidazolium tetrafluoroborate 565

Dimethyl hexadecyl-octadecyl

ammonium chloride 172

Dimethyl hydrogenated

tallow-2-ethylhexyl ammonium 111

Dimethyl isophthalate triphenyl phosphonium 117

Dimethyl vinylbenzyl dodecyl

ammonium chloride (2M 207

Discoloration 338

Disk extruders 158

Dispersion

degree of 201

forces 267 293

effects on mechanical properties 162

residence time 161

Dodecyl ammonium chloride 210

Dodecyl-trimethyl-ammonium 137

Domain flow theory 350

Dry compounding 477

Index Terms Links


Dye 115 558 592

Dye-hectorite complexes 255

Dynamic Extensional Flow Mixer 159

Dynamic secondary ion mass spectrometry 543

E

Eastonite 75

Elastomer CPNC 30 115 132 210 472

601

Electrolyte nanocomposites 165

Electrooptical effects 246

Electrorheological fluid 520

Emulsion polymerisation 205 255 516 519

CPNC seed 522

Engineering resins 553

Enthalpy 281

Entropy 264

Environmental variables 261

EPDM/MMT

preparation 607

properties 607

Epoxy

clay treatment 32

coating 504

Epoxy CPNC

clay type effects 585

flammability 615

preparation 218 579

properties 193 218 579

Epoxy/auorohectorite 222

Epoxy/CNT 47 49

Index Terms Links


Epoxy/hectorite 193

Epoxy/LDH 196

Epoxy/MMT 131 193

melt compounding 245

preparation 579

Epoxy/ZrP 198

EPR/MMT 239

Equation of state 309

ETFE CPNC

properties 572

EVAc CPNC

flammability 615

EVAc/MMT

preparation 550

properties 550

rheology 391

EVAl CPNC 543

fuel tanks 623

EVAl/MMT 240

Exfoliation 87 201

Extensional flow 392

field 158

mixer 159

mixing 629

F

Fatigue resistance 428

FEP CPNC 572

Fibrillar nanoparticles 38 441

Flame retardancy 339 531 611

Index Terms Links


Fluoroelastomer CPNC

preparation 605

Fluoroelastomer/mica 192

preparation 571

Fluorohectorite 145 233 270 304 496

526 567

Fluoromica 36 191 228 238 249

353 424 433 452 493

538 554 561

Fluoromica/DGEBA 192

Fluoroplastic CPNC 115 570

Foam CPNC 384 476 540 592

Fourier transform infrared spectroscopy 15

Free energy 267 274 279 288

Fuel tanks 623

G

Gas permeability 557 596

Gelimat 158

Glass fibre reinforced composites 201 444

Glass transition temperatures 257

Glass transition theory 258

Glauconite 76

Grafting density 274

Graphite 47 613

Guanadinium 114

H

Hairy clay platelet 325 543

Halpin-Tsai 418

Index Terms Links


HDPE/hectorite 207

preparation 484

HDPE/MMT 471

crystallisation 497

preparation 497

structure 497

HDPE/NBR 471

Hectorite 36 79 105 112 526

Hectorite/coumarin 255

Hectorite/DGEBA 193

Helmholtz free energy change 263

Hencky strain rates 384

Hexadecyl amine 211 503

High temperature

CPNC 32

polymers 574

stability 339

HIPS CPNC 521

Hole fraction 329

Hudson’s Clay Grafting method 499

Huggins-Flory binary interaction parameters 273

Huggins-Flory lattice model 264

Hui-Shia (H-S) theory 421

Hydrogen bonding 88 91 186 198 240

267 404 506

Hydrolytic degradation 550 553 561

Hydrophilic clays 202

Hydrophobic polymers 202

Hydroxides

types used in CPNC 35

Index Terms Links


Hydroxyapatite 198

I

Illite 74 553

Imidisation 211

Immiscibility 224

Imogolite 54 441

Inorganic nanotubes 55

Inorganic oxides 570

Interaction energy 282

Intercalant

acrylamide 128

amidine 123

cationic surfactant 524

commercial clays 118

copolymers 128

dye 115

epoxy 138

functional 254

herbicide 125

hydrophilic 127

hydrophobic 126

metal 142

methacrylate 128

nitrile groups 117

polar organic compounds 131

polyacrylic acid 128

P4VP 127

PA-6 CPNC 437

PEG 127

Index Terms Links


Intercalant (cont.)

PI 576

PVAl 127

PET 561

quaternary ammonium 103 626

secondary 94 209 505


toxicity 123

types 102

vinyl monomer 126

water-soluble polymer 124

Intercalation 87 97 625

ε-caprolactan 204

cyclomers 139

diffusion-controlled 162

dynamic melt 149

epoxy 138

inorganic intercalants 140

kinetics 270 302

methods 198

molecular modelling 298

monomers 126

oligomers 126 497

organic cations 102 139

organic liquids 124

polymers 126 302

silylation 136

solvents and solutions 100

Interfacial energy 267

Interlamellar spacing

pressure effects 183

Index Terms Links


Interlamellar spacing (cont.)

temperature effects 183

Internal mixer 441 456 463 467 483

484 490 493 503 506

529 535 537 541 543

561 566 569 572 573

574

Interphase modulus 422

Inverted intercalation method 522

IR/MMT

preparation 606

impurities 84

purification 84

Iron 2 225

Iron chloride 253

Iron oxide 2

Irradiation polymerisation 254

J

Journals 29

K

K-mixer 158

Kaolinite 74 469 553

intercalation 186

PA-6 188

structure 186

L

Laponite 402 442 478 522 528

Latex method 606

Index Terms Links


Layered double hydroxides 195 459 515

LDPE CPNC

patent literature 477

properties 477

Leistritz co-rotating TSE 487

Liquid crystal polymers 5

phase structures 347

Liquid crystal CPNC

preparation 567

properties 567

Liquid crystal/MMT 210 245

LLDPE CPNC

Copolymer 485

crystallisation 410


properties 410 477

LLDPE/hectorite 207

LLDPE/MMT 183

Loading 6

Lower critical solution temperature 535

M

Macromolecular diffusion 302

Magadiite 137 183 218

Magnetic oxides 2

Magnetic properties 2

Manton-Gaulin mill 112 139

Margarite 75

Matrix polymers 18

Maximum packing volume fraction 1 625

Index Terms Links


Mechanical properties 611

Melamine 338 456 601

Melt blending 232

Melt compounding 52 245

PA 465

vinyl CPNC 533

Melt exfoliation 232

Melt intercalation 142

effects of MW 162

PA 236

simulation of kinetics 306

Melt mixing 149

Metallic matrix 3

Metallic nanoparticles 2 18

Metallocene 478 485 488 496 527

530 550 551

Methyl benzyl dehydrogenated

tallow ammonium chloride 105

2-(N-Methyl-N,N-diethyl

ammonium iodide) ethyl acrylate 207 527

2-Methyl 2-hydrogenated tallow

ammonium chloride 13 234

Methyl octadecyl bis-2-hydroxyethyl

ammonium methyl-sulfate 165

N-Methyl-2-pyrrolidone 187

Methyl-rapeseed-bis(hydroxy-ethyl)

ammonium chloride 162 164

Methyl tallow bis-2-hydroxyethyl

quaternary ammonium 23 114 161 415

Methyl-trioctyl ammonium chloride 207

Index Terms Links


Methylene blue 301

Mica 74 172 400 483

structure 189

synthetic 190

Microemulsion polymerisation 518

Micromechanics 417

Mill 107 111 112 139 571

Miscibility 244 514 570

Mixed clays 553

Mixing equipment 150

Molecular dynamics 271 298 307

Molecular repair 561

Monomer modification 206

Monte Carlo 271 298

Montmorillonite 36 78 625

composition 80

properties 82

structure 80

Muscovite 75

MXD-6 CPNC

preparation 449

properties 449

N

Nanoparticles 258

classification 1

types 18 35

Nanoscale engineering 30

Natural rubber CPNC 603

properties 608

Index Terms Links


Natural rubber/fluorohectorite 608

Natural rubber/MMT 607

Nickel 2 225

Nickel-containing amines 336

Nuclear magnetic resonance spectroscopy 16

Nucleation 395

O

Octadecyl ammonium chloride 166 168 171 234

Oligo-ethylene-glycol diethyl

methyl ammonium chloride 207

Oligomeric intercalant 126 497

Optoelectronic applications 3

Organometallic 626

Organosilanes 109 443 566

Organotitanates 137 443

Organozirconates 137 443

Orientation 150 165 169

flow-induced 370

Oxides 35

4,4´-Oxydianiline 212

P

P4VP intercalant 124

P4VP/fluorohectorite 270

P4VP/kaolinite 187

P4VP/MMT 270

preparation 543 552

P4VP/saponite 270

PA 435

Index Terms Links


PA CPNC

melt blending 441

melt exfoliation 31

melt intercalation 160

preparation 110 436

properties 438 443

PA/fluoromica

preparation 452

properties 452

PA/hydroxyapatite 198

PA/MMT

preparation 550

rheology 356

PA-1010/MMT 408

PA-11/MMT 408

PA-12/fluoromica

fatigue resistance 433

flow behaviour 353

PA-12/MMT

flow behaviour 353

PA-1212/MMT 409

PA-6

crystallisation 399

properties 399

PA-6 CPNC

compounding 462

interlayer spacing 205

melt exfoliation 466

properties 445 465

PA-6/hectorite

crystallisation 402

Index Terms Links


PA-6/kaolinite 188

preparation 469

properties 469

PA-6/mica 192

crystallisation 400 405

in microporous membrane 195

preparation 457

properties 400

PA-6/MMT 109 400

compression moulding 406

crystallisation 399

fatigue resistance 431 433

flammability 615

flow behaviour 350

injection moulding 358

intercalants 233

melt blending 276

melt exfoliation 233

NMR data 16

preparation 357 457

properties 176 204 233 417 431

457

PVT behaviour 319

silane coupling 136

tensile properties 423


PA-6/saponite

crystallisation 401

PA-66

crystallisation 399

properties 399

Index Terms Links


PA-66 CPNC

properties with glass fibre 456

PA-66/MMT 403

Packaging 443 458 459 465 477

482 492 543 556 557

559

Palygorskite 76 112

Paragonite 75

Patent information 435

PBT/MMT

preparation 554 561

properties 554 565

PC/fluorohectorite

preparation 567

PC/CNT 53

PC/MMT 148 209

preparation 554 566

properties 566

PCL/MMT 13 252

compatibiliser 535

flow behaviour 351

preparation 242 559

properties 242 559

PDMS/fluorohectorite

preparation 607

PE

melting temperature 292

nanoparticles 292

PE CPNC

metallocene 496

Index Terms Links


PE/hectorite

properties 206

PE/MMT 206 239

flammability 617


rheology 376

XRD data 10

Peak heat release rate 616

PEBAX CPNC 469

PEEK CPNC

properties 572

PEG/FH

analysis data 147

PEG/kaolinite 187

PEG/MMT

melt intercalation 144 165 551

NMR data 16

preparation 543

rheology 390

solution method 551

PEG/vermiculite 12

PEI CPNC

properties 572

PEI/MMT

preparation 465 574

PEK CPNC

properties 572

Permeability 557 596 603 607

control 618

enhanced 622

polyimide 190

Index Terms Links


PET containers 557

PET CPNC

crystallisation 414

PET/fluoromica

crystallisation 415

PET/LCP blends 567

PET/MMT 209

permeability 451 555

preparation 550 553 557 565

properties 555 557

PETN 414

rheology 391

PETN/MMT

preparation 563

properties 563

PFA CPNC 572

Phase behaviour 280

Phase separation 395

Phase structures 347

Phenolic CPNC

preparation 216

2-Phenylethylamine 387 538

Phlogopite 75

Phosphonium 559 574 585 626


Photo-oxidative stability 340

PI CPNC

permeability 190

photosensitive 216

preparation 210 574

properties 210 574

Index Terms Links


PI/LDH 196

preparation 575

PI/fluoromica 191

PI/mica 190

PI/POSS 217

PLA CPNC 246

PLA/fluoromica 249

PLA/MMT

foams 250 386


plasticised 252


Planetary roller extruder 155

Platelets

hairy clay 325 543

morphology 342

types of dispersion 83

PMMA CPNC

copolymer intercalant 134

foaming 386

translucent 209

PMMA/CNT 50 52

PMMA/MMT

bulk polymerisation 513

emulsion polymerisation 205 516

exfoliation 209

flame retardancy 336

in dentistry 540

inverted intercalation 522


Index Terms Links


PMMA/MMT (cont.)

preparation 207 508 527

properties 207 529

strain hardening 384


PMMA/silicon alkoxide 57

Polyacetylene/MMT 255

Polyaniline/CNT 52

Polyaniline/MMT 254 557

Polybenzoxazole 214 574

Poly-3-bromostyrene/MMT 534

Polybutadiene/mica

nanorheology 296

Polybutadiene/MMT

preparation 473 602

Polybutylenesuccinate/MMT 252

Polycondensation 204 243 246

Polydiacetylene/MMT 101 254

Polyelectrolytes 92

Poly(ethylene-methacrylic acid)/MMT

Polyhedral oligomeric silsesquioxanes 5

polyimide 217

polyolefin 63

preparation 58

properties 60

Polyhydroxybutyrate/kaolinite 187

Polymer adsorption 293

Polymer blends 244 501

Polymer diffusion

kinetics 274

Index Terms Links


Polymeric brushes 271

Polymerisation rate 203 204

Poly(methyl silsesquioxane) 70

Polyolefin CPNC 136

crystallisation 409


preparation 31 481

secondary intercalants 481

Polyolefin/MMT


preparation 471

properties 168 171

Polyolefin/POSS 63

Polyols 226

Poly (p-phenylene benzobisoxazole)/CNT 51

Polyphenylene vinylene/CNT 46

Polypyrrole/CNT 47

Polytrimethylene terephthalate/MMT 415

Polyvinyl butyral/MMT 483

Poly(N-vinyl carbazole)/MMT 252

Polyvinyl cyclohexane 270

Polyvinyl methyl ether/vermiculite

SANS data 11

Polyvinylcarbazole/MMT 101

POM/MMT

crystallisation 398

Porosity 622

PP CPNC

crystallisation 410

nucleating agents 409

Index Terms Links


PP CPNC (cont.)

flammability 614 615

foaming 384

properties 237 410 611

summary 178

PP/calcium phosphate 177

crystallisation 413

PP/CNT 52

PP/fluorohectorite 496

PP/fluoromica 191 238


preparation 493

properties 493


PP/MMT 239

crystallisation 398

fatigue resistance 433

melt intercalation 177 238 240

photo-oxidative stability 340


properties 495

rheology 379



PP/MMT/EPR

preparation 502

PP/PA-6/MMT 241

PP/PP-MA/MMT 241

PP/vermiculite


properties 417 492

Index Terms Links


PPE/MMT

preparation 554

Pressure effects 185

Pressure-volume-temperature

behaviour 319 331

dependence 309

Pressurised extruder 553

Processing temperature 203

Properties

by PNC type 68

determination 18

PNCs 3

PS CPNC

copolymer intercalant 134

emulsion polymerisation 255

flammability 614

rheology 387


PS/CNT 50

PS/fluorohectorite 270 302 304

PS/fluoromica

rheology 387

PS/graphite 48

PS-IR copolymer CPNC 306

rheology 388

PS-IR/MMT

flow behaviour 354

solution method 530

PS/mica 294 296

PS/MMT 101 270

Index Terms Links


PS/MMT (cont.)


crystallisation 416

emulsion polymerisation 389 516 520 526

exfoliation 208

flammability 616

flow behaviour 355

melt compounding 245 534 537


microstructure 539

NMR data 17


PVT behaviour 327


thermal stability 335 336

ultrasonics 518

XRD data 8

PS/PEMA/hectorite

co-solvent route 533

PS/PPE CPNC 500

PTFE PNC 570

PU/cadmium sulfide 226 591

PU CPNC 225 590

flammability 615

foaming 386

preparation 226

properties 226

thermoset 594

PU elastomer/MMT 230

PU/fluoromica 193 228

preparation 593

Index Terms Links


PU/metal nanoparticles 225 591

PU/MMT

preparation 595

properties 595

PU/silica 225 591

PVAc/fluoromica 233

PVAl/CNT 50

PVAl coating 563

PVAl/hectorite

SANS data 13

PVAl/imogolite 54

PVAl intercalant 124

PVAl/sulfide 56

PVC CPNC

preparation 528

PVC/MMT


PVC/PMMA/clay 528

PVDF 573

Q

Quaternary ammonium

intercalants 103 626

R

Radical polymerisation 204

Reactive extrusion 561

Reactive method 52 522

Reactor 523 525

Rheology 341 629

Index Terms Links


Rheology (cont.)

disc suspensions 344

Fourier tranform 356 376

nanoscale 294

Rheometer 353

Rheometrics Mechanical Spectrometer 497

Ring-opening polymerisation 210 246

Rubber-toughened thermoplastic CPNC 465

S

SAN/MMT

emulsion polymerisation 518 520

Saponite 270 400 401 526

SBR CPNC 517 607

Scaling theory 290

Secondary intercalant 94 209 505

Self-consistent field lattice modelling 272

Self-consistent-field theory 278

Semiconductors 3

Sepiolite 76 112

Serpentine 74

Shear stress field 158

Shear thinning 353

Shearing 523

dispersive mixers 149

methods 130 132

Silane 136 240 441 486 499

Silica nanoparticles 56

Simha-Somcynsky Equation of State 310

Single screw extruder 131 152 153 159 160

Index Terms Links


161 164 171 173 176

412

Small-angle neutron scattering 11 341

Small-angle X-ray scattering 220

Smectite clays 76

types used in CPNC 35

Sol-gel hybrids 56

Sol-gel process 226

Solid phase 291

Solution method 50

Solution polymerisation 50 519 526

Specific surface area 298

Stability 489

Static mixer 158

Steady-state flow 372

Strain hardening 383

Strain softening 384

Styrenic copolymer CPNC 539

Supercritical carbon dioxide 384 530

Surface effects 260 627

Surface energy 291

Surface force analyser 294

Surfactant 523

Suspension polymerisation 516 525

Synthetic clays 35

T

Tallow di-amine chloride 449

Tannate 91

Telechelic polymers 287

Index Terms Links


Temperature effects 183

Tensile modulus 417

Tensile strength

prediction 426

Testing 629

Tetraethyl orthosilicate 2

Tetraphenyl phosphonium 464

Thermal degradation 333 553

Thermal stability 333 465 493 562 612

Thermodynamics 257

Thermoplastic polyesters (PEST) 114 553

dye intercalant 115

with mixed-onium organoclays 133

Thermoset CPNC 132 138 579

Toxicity 626

Transmission electron microscopy 14

Transparency 246

Trimethyl aluminium-depleted methyl aluminoxane 206

Trimethyl cetyl ammonium bromide 520

Trimethyl hexadecyl ammonium bromide 175 403

Trimethyl octadecyl ammonium 250

Tungsten disulfide 55

Twin screw extruder 114 132 135 136 137

139 152 153 155 159

160 161 162 164 167

168 169 170 172 174

175 176 177 188 192

Tyre 603 604

Index Terms Links


U

Ultrasonics 130 170 207 215 484

518

Unsaturated polyester CPNC 588

preparation 586

Unsaturated polyester/MMT

preparation 588

properties 588

UV-photoinitiation 253

V

Vaia’s Lattice Model 263

Vanadium pentoxide 54 441

Vermiculite 76 110 417 492

Vinyl polymer CPNC 542


epoxy CPNC 506

Vinyl-benzyl-dimethyl dodecyl ammonium 388

Vinyl-benzyl-trimethyl ammonium chloride 526

Viscosity 344 523

Volume fraction

maximum packing 1

W

Water-soluble polymers 390 448 460 543 549

568

Weathering 565

Wonesite 75

Index Terms Links


X

X-ray diffraction 8 509

m-Xylylene-diamine 221

Y

Yield stress 368

Yttrium garnet 2

Z

Zeolites 477

Zero-shear viscosity 369

Ziegler-Natta 496 530

Zirconium phosphate 198

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