In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona,...

16
In-situ capping of contaminated sediments Contaminated sediments in Sweden: A preliminary review SGI Publication 30-2E Linköping 2016 Joseph Jersak, Gunnel Göransson, Yvonne Ohlsson, Lennart Larsson, Peter Flyhammar, Per Lindh

Transcript of In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona,...

Page 1: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

In-situ capping of contaminated sediments

Contaminated sediments in Sweden: A preliminary review

SGI Publication 30-2E Linköping 2016

Joseph Jersak, Gunnel Göransson, Yvonne Ohlsson, Lennart Larsson, Peter Flyhammar, Per Lindh

Page 2: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

SGI Publication 30-2E

Cite as:

Jersak, J, Göransson, G, Ohlsson, Y, Larsson, L, Flyhammar, P & Lindh, P 2016. In-situ capping of contaminated sediments. Contaminated sediments in Sweden: A preliminary review. SGI Publication 30-2E, Swedish Geotechnical Institute, SGI, Linköping.

Diary number:1.1-1506-0400

Project number: 15573

Order information: Swedish Geotechnical Institute Information Service SE-581 93 Linköping, Sweden Phone: +46 13-20 18 04 E-mail: [email protected] Download this publication as a PDF-document at www.swedgeo.se Pictures on the cover: AquaBlok, Ltd. (left), B. Beylich, NIVA (middle), BioBlok Solutions AS (right).

Page 3: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

In-situ capping of contaminated sediments

Contaminated sediments in Sweden: A preliminary review

Joseph Jersak

Gunnel Göransson

Yvonne Ohlsson

Lennart Larsson

Peter Flyhammar

Per Lindh

SGI Publication 30-2E Linköping 2016

Page 4: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

SGI Publication 30-2E

4 (15)

Page 5: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

SGI Publication 30-2E

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Table of contents 1. Introduction .................................................................................................. 7

2. Results of preliminary review ..................................................................... 7

3. Summary ...................................................................................................... 7

Page 6: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

SGI Publication 30-2E

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The entire SGI Publication 30 set includes the following independent parts:

SGI Publication 30-1, Huvuddokument. In-situ övertäckning av förorenade sediment. Metodöver-

sikt. (In Swedish)

SGI Publication 30-1E, Main text. In-situ capping of contaminated sediments. Method overview.

SGI Publication 30-2E. In-situ capping of contaminated sediments. Contaminated sediments in

Sweden: A preliminary review.

SGI Publication 30-3E. In-situ capping of contaminated sediments. Established ex-situ and in-situ

sediment remediation technologies: A general overview.

SGI Publication 30-4E. In-situ capping of contaminated sediments. Remedial sediment capping

projects, worldwide: A preliminary overview.

SGI Publication 30-5E. In-situ capping of contaminated sediments. Capping Sweden’s contaminat-

ed fiberbank sediments: A unique challenge.

SGI Publication 30-6E. In-situ capping of contaminated sediments. An extensive, up-to-date collec-

tion of relevant technical and other international references.

SGI Publication 30-7. In-situ övertäckning av förorenade sediment. Övergripande sammanfattning.

(In Swedish)

SGI Publication 30-7E. In-situ capping of contaminated sediments. Overall summary.

Fact sheet. In-situ capping of contaminated sediments. Method overview.

Page 7: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

SGI Publication 30-2E

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1. Introduction

There appears to be no readily available and up-to-date, single document that inventories contami-

nated sediment sites in Sweden. What is available are summaries of contaminated areas each coun-

ty publishes and updates at least periodically (regional programs). Also available are documents

related to: regional or national environmental monitoring programs; methods for conducting risk

assessments, including risk classification of sites; and a mapping of fiberbank deposits and fiber-

rich sediments in selected counties.

Conducting a detailed review of the above (and additional) documentation to create a complete list

of contaminated sediment sites in Sweden was beyond the scope of this capping overview project.

Nevertheless, conducting a preliminary review of readily available information was necessary to

place focus of the capping overview project into more of a national context.

To underscore: This is only a preliminary review of contaminated sediment sites in Sweden. There

is considerable merit, for a number of reasons, in conducting a follow-up review of such sites that

is more expansive, detailed, up-to-date and which incorporates input from multiple informed par-

ties and perspectives.

2. Results of preliminary review

Results of the preliminary review conducted to obtain a general understanding of the occurrence of

contaminated sediments in Swedish waters are summarized in Table 1.

3. Summary

Results of the preliminary review conducted to obtain a general understanding of the occurrence of

contaminated sediments in Swedish waters are summarized in Table 1. Note, the table intends to

illustrate there are a significant number of contaminated sediment sites or areas identified through-

out Sweden. It is not intended to provide a complete listing of such sites.

Contaminated sediments of some type are identified to occur at specific sites or in certain

areas within at 19 of Sweden’s 21 counties.

Sediment contamination occurs in a wide variety of inland and coastal aquatic environ-

ments, including in lakes, ponds, rivers, creeks, harbors, and bays.

Different types of contaminated sediments occur in Sweden: mineral-based (minerogenic)

sediments and cellulose-based (fiberbank) sediments. Fiberbank sediments comprise either

more-or-less pure fiberbank deposits or fiber-rich sediments, which are a mix of fiberbank

and minerogenic sediment materials.

Contamination in minerogenic sediments comes from a wide variety of mainly historical

point-source releases from past industrial and other operations. The point sources can be

decades to centuries old and include shipyards, wood impregnation, glass and battery man-

ufacture, leather tanning, and gas and metal works. Contaminant inputs to surface waters

Page 8: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

SGI Publication 30-2E

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continue in a number of areas, but they are mainly non-point-source releases, e.g. com-

bined sewer overflows.

Contamination inherently contained in fiberbank deposits – including the sediments them-

selves – come exclusively from past discharges from pulp and papermill operations. Con-

tamination in fiber-rich sediments may come from multiple sources.

Different types of dissolved-phase sediment contamination occurs across the country, in-

cluding metals (Pb, Cu, Zn, Cd, Ni, Hg, Cr, As, etc.), organics (dioxins, PCBs, PAHs, chlo-

rinated solvents, hydrocarbons, PCDD/PCDF, etc.), and organometallics (including tribu-

tyltin [TBT] and methylated Hg). New or “emerging” contaminants, which could include

PFOS (perfluorooctane sulfonate) and PFOA (perfluorooctanoic acid), have also been not-

ed in at least one county (Stockholm).

A broad range of organic, metallic, and/or organometallic contaminants can occur in

minerogenic sediments, given the broad range of possible contaminant sources. In contrast,

fiberbank deposits, and likely many fiber-rich sediments, are usually contaminated by a

smaller list of contaminants (DDTs, PCBs, PAHs, dioxins, and Hg [including methylated

Hg]).

Although apparently less common, sediments at some sites are also or instead contaminat-

ed by non-aqueous phase liquids (NAPLs), including oil (in Halland, Södermanland, Väs-

tra Götaland, and Östergötland) or creosote (in Jönköping and Örebro).

Contaminated minerogenic sediments occur more-or-less throughout the entire country. Fi-

berbank sediments occur mainly (but not only) in Norrland, where forest-industry activities

have historically been most concentrated. Contaminated fiberbank sediments occur in at

least 10 counties, and may also occur in a number of other counties as well (where pa-

permill operations have occurred).

Sediment risk assessments and risk classifications are referenced for some contaminated

sites or areas (in Dalarna, Jämtland, Jönköping, Uppsala, Västernorrland, and Örebro).

Sites at which risks have been classified (in Dalarna, Uppsala, and Örebro) occur at either

high (Class 2) or very high (Class 1) levels.

Ongoing site- and/or area-specific investigations to further characterize the nature and ex-

tent of sediment contamination are referenced for some counties (in Jämtland, Västernorr-

land, and Västra Götaland).

Implementation of regional and/or national programs for monitoring concentrations of var-

ious metallic and organic contaminants in sediments over time is referenced for some

counties (in Kalmar, Norrbotten, Skåne, Stockholm, Västerbotten, and Västra Götaland).

Implementation of programs and related projects for mapping the occurrence of fiberbank

deposits and fiber-rich sediments is referenced in some counties, mainly those in Norrland.

It is obvious (even from this preliminary review) many more contaminated sediment sites and/or

areas have been identified in some counties than in others. Why is that? Do some counties simply

have more sediment contamination than others? Have investigations been more thorough in some

counties than in others? Is addressing contaminated sediments a higher priority for some counties

than for others? Do some counties have more funding available to address contaminated sediments

than others?

Page 9: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

SGI Publication 30-2E

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In closing, based on results of this preliminary review, it is reasonable to conclude:

National, regional, and/or local authorities recognize some type of sediment remediation is

needed today – if not already being implemented or planned – at a number of sites at which

unacceptable sediment-related risks have been documented.

Sediment remediation will be needed in the near future at an additional number of sites,

once sediment risk assessments and classifications have been completed and unacceptable

sediment-related risks are documented.

Additional sites may require sediment remediation in the future, once the nature and occur-

rence of contamination has been investigated, risk assessments and classifications have

been completed, and unacceptable sediment-related risks have been documented.

Note: For all references cited herein, please see SGI Publication 30-6E.

Page 10: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

S

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(1

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Ta

ble

1

Sum

ma

ry o

f a

pre

limin

ary

re

vie

w o

f co

nta

min

ate

d s

ed

ime

nt site

s a

nd

are

as in S

we

de

n.

Co

un

ty

Refe

ren

ces

Oc

cu

rren

ce

of

co

nta

min

ate

d s

ed

ime

nts

in

Sw

ed

ish

su

rfac

e w

ate

rs (

se

lec

ted

hig

hli

gh

ts)

Ble

kin

ge

nssty

rels

en

B

lekin

ge

20

14

.

- G

en

era

l re

fere

nce

s to

:

P

rog

ram

fo

r m

onito

rin

g e

nvir

on

me

nta

l co

nta

min

an

ts, in

clu

din

g in s

ed

ime

nts

(L

än

ssty

rels

en

, B

lekin

ge

, no

da

te).

H

g-c

on

tam

ina

ted

dis

ch

arg

es fro

m p

ap

erm

ill (

pap

pe

rsb

ruk)

facto

rie

s.

- S

pe

cific

re

fere

nce

s t

o:

T

BT

se

dim

en

t co

nta

min

atio

n in

th

ree h

arb

ors

(K

arlskro

na

, R

on

ne

by, a

nd

lve

sbo

rg).

Als

o e

xp

ecte

d in

oth

er

ha

rbo

rs.

A

co

ppe

r w

ork

s s

ite

, w

he

re s

ed

imen

ts in

asso

cia

ted

su

rface

-wa

ter

bo

dy a

re c

on

tam

ina

ted

by C

u.

A

sa

wm

ill s

ite

(B

acka

ryd

gve

rke

t), w

he

re s

ed

ime

nts

in a

sso

cia

ted

su

rfa

ce

-wa

ter

bo

dy (

typ

e[s

] u

ncle

ar)

.

A

no

the

r sa

wm

ill s

ite

(Jo

ha

nn

ish

us s

åg

), w

he

re s

ed

ime

nts

in a

sso

cia

ted s

urf

ace

-wa

ter

bo

dy c

on

tam

ina

ted

by d

ioxin

s.

Dala

rna

nssty

rels

en

D

ala

rna

, 2

01

1.

- G

en

era

l re

fere

nce

s to

:

S

urf

ace

sed

ime

nts

in

18

of

77

la

kes a

nd

po

nds s

ho

w “

gre

at”

to

“ve

ry g

rea

t” im

pa

cts

fro

m m

ain

ly m

eta

ls (

inclu

din

g C

u,

Cr,

Hg

, Z

n,

and

As)

an

d/o

r so

me

org

an

ics (

inclu

din

g h

exa

ch

loro

cyclo

he

xa

ne

, som

e P

CB

s,

and

som

e P

AH

s).

S

ed

ime

nt

risk a

ssessm

ents

con

du

cte

d f

or

se

ve

n o

f th

e 1

8 lake

s/p

ond

s.

All

se

ve

n fa

ll u

nde

r e

ithe

r risk-c

lass 1

or

2.

No

te: A

c-

co

rdin

g to

Na

turv

ård

sve

rke

t’s M

IFO

ris

k c

lassific

atio

n s

yste

m (

e.g

. N

atu

rvå

rdsve

rke

t, 2

009

b),

ris

k-c

lass 1

rep

rese

nts

a “

ve

ry

hig

h r

isk”

wh

ere

as r

isk-c

lass 4

re

pre

se

nts

“lit

tle

ris

k”

to h

um

an

he

alth

an

d/o

r th

e e

nvir

on

men

t.

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tla

nd

L

än

ssty

rels

en

, G

otla

nd

, 2

012

.

vle

bo

rg

nssty

rels

en

G

ävle

bo

rg,

20

14

, 2

016

.

- G

en

era

l re

fere

nce

s to

:

S

ed

ime

nt co

nta

min

atio

n b

y m

eta

ls (

Hg

, P

b,

Cd,

Zn

, an

d C

u)

in c

oasta

l w

ate

rs,

pa

rtic

ula

rly in

vle

fjä

rde

n.

P

rese

nce

(a

nd

syste

ma

tic in

ven

tory

) o

f fib

erb

an

k a

nd

fib

er-

rich

sed

ime

nts

(n

ort

h o

f D

alä

lve

n),

de

rive

d f

rom

fo

rme

r pu

lp/p

ap

er

mill

activitie

s,

wh

ich

are

con

tam

inate

d b

y H

g,

dio

xin

s,

an

d/o

r o

rga

no

chlo

rin

es.

P

rese

nce

of

hig

h le

ve

ls o

f d

ioxin

in B

altic

he

rrin

g a

lon

g t

he c

oa

st lin

e,

an

d t

ha

t co

nta

min

ate

d a

reas c

an

co

ntr

ibute

to t

his

pro

b-

lem

. -

Sp

ecific

re

fere

nce

s t

o:

O

ng

oin

g f

ibe

rban

k p

roje

ct

(i.e

. su

rve

yin

g fib

erb

ank d

ep

osit a

nd

fib

er-

rich

se

dim

en

t a

rea

s)

as w

ell

as d

redg

ing

in G

ävle

Harb

or.

F

or

refe

ren

ce

, se

e:

htt

p:/

/pu

re.ltu

.se

/po

rta

l/sv/s

tud

entt

hesis

/sta

bili

se

rin

g-o

ch

-solid

ifie

rin

g-a

v-m

ud

de

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sso

r-i-

ga

vle

-h

am

n(4

fc3

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edia

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n p

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ct

in H

åsta

ho

lmen

(risk c

lassific

atio

n, p

rio

rity

1,

rem

ed

iation

of d

ioxin

-co

nta

min

ate

d s

ed

ime

nt p

lan

ne

d).

U

se

of n

ew

me

thod

olo

gy f

or

risk c

lassific

atio

n o

f fib

er-

rich

sed

imen

ts,

as d

eve

lop

ed b

y V

äste

rno

rrla

nd

’s C

ou

nty

Bo

ard

. F

or

refe

rence

, see

: L

än

ssty

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en

ww

w.la

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en

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/Vaste

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nd

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20

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ge

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eto

dik

-fo

r-riskkla

ssn

ing

-av-

fib

erh

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t.asp

x.

Page 11: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

S

GI

Pu

blic

atio

n 3

0-2

E

11

(1

5)

Hall

an

d

nssty

rels

en

H

alla

nd

, 20

14

.

- G

en

era

l re

fere

nce

s to

:

M

ultip

le p

ap

erm

ill (

pa

pp

ers

bru

k)

facto

rie

s o

pe

rating

, p

ast o

r p

resen

t.

S

ed

ime

nt co

nta

min

atio

n in

sm

all-b

oa

t ha

rbo

rs.

Con

tam

inan

t ty

pe

(s)

un

cle

ar.

-

Sp

ecific

re

fere

nce

s t

o:

A

sh

ipya

rd s

ite

(in

Ätr

an

), w

here

sed

ime

nts

in a

ssocia

ted

su

rfa

ce

-wa

ter

bo

dy a

re c

on

tam

ina

ted

by T

BT

, C

u,

Cr,

Pb

, an

d P

CB

s.

A

pu

lp/p

ape

r m

ill s

ite

(O

ska

rstr

öm

s s

ulfitfa

brik),

wh

ere

se

dim

en

ts in

asso

cia

ted

su

rfa

ce

-wa

ter

bo

dy a

re c

on

tam

ina

ted b

y m

ain

-ly

oil

an

d H

g.

A

n in

du

str

ial site

(In

du

str

i Z

ink),

wh

ere

se

dim

en

ts in

asso

cia

ted

su

rfa

ce

-wa

ter

bo

dy c

on

tam

ina

ted

by m

eta

ls a

nd

/or

chlo

rina

ted

so

lve

nts

an

d/o

r chlo

rin

ate

d a

liph

atics.

A

no

the

r p

rodu

ctio

n s

ite

(R

yd

öb

ruk S

ulfit),

wh

ere

se

dim

en

ts in

associa

ted

su

rface

-wa

ter

bod

y a

re c

on

tam

ina

ted b

y v

ari

ous

me

tals

an

d/o

r o

rga

nic

s.

mtl

an

d

nssty

rels

en

, Jä

mtla

nd

201

3.

- G

en

era

l re

fere

nce

to

in

ve

nto

ry a

nd

in

vestiga

tion

s o

f fib

erb

an

k s

ed

ime

nts

(a

sso

cia

ted

with

old

mill

s),

wh

ich

are

lik

ely

co

nta

min

ate

d

by v

ari

ou

s o

rga

nic

po

lluta

nts

an

d m

eta

ls (

inclu

din

g H

g).

-

Sp

ecific

re

fere

nce

s t

o:

A

pu

lp-m

ill s

ite

(Jä

rpe

ns m

assa

fab

rik),

wh

ere

se

dim

en

ts in

associa

ted

riv

er

an

d lake

are

con

tam

ina

ted

by m

eta

ls.

A

ch

arc

oal-

pro

du

ctio

n s

ite

(T

järf

ab

rik G

rötin

ge

n),

wh

ere

sed

ime

nts

in

associa

ted

su

rfa

ce

-wa

ter

bod

y a

re c

on

tam

ina

ted

by

PA

Hs,

alip

hatics, a

nd

aro

ma

tics,

as w

ell

as s

om

e m

eta

ls.

Ris

k a

ssessm

en

ts a

lso

re

fere

nced

.

A

pro

ductio

n s

ite

(U

lrik

sfo

rs s

ulfitfa

brik),

wh

ere

se

dim

en

ts in

asso

cia

ted lake

are

co

nta

min

ate

d b

y H

g.

nk

öp

ing

L

än

ssty

rels

en

nkö

pin

g,

20

11

.

- S

pe

cific

re

fere

nce

s t

o:

A

wo

od

-im

pre

gn

atio

n s

ite

(in

Gri

msto

rp),

wh

ere

se

dim

ents

in

associa

ted

la

ke (

Lill

esjö

n),

are

con

tam

inate

d b

y A

s.

Ris

k a

s-

se

ssm

en

ts a

lso

re

fere

nced

.

A

pa

pe

r-m

ill s

ite

, w

he

re f

ibe

r se

dim

en

ts in a

ssocia

ted

la

ke

(M

un

ksjö

n)

are

co

nta

min

ate

d b

y H

g,

oth

er

me

tals

, h

yd

roca

rbo

ns,

an

d o

rga

nic

su

bsta

nces s

uch a

s P

CB

s a

nd

dio

xin

. P

ossib

le/lik

ely

im

pa

cts

fro

m d

isch

arg

es fro

m m

unic

ipa

l w

ate

r-tr

ea

tme

nt

pla

nt a

lso

refe

rence

d.

Ris

k a

sse

ssm

en

ts a

lso

re

fere

nced

.

A

no

the

r w

oo

d-im

pre

gn

ation

site

(B

an

ve

rke

ts Im

pre

gne

rin

gsan

läg

gn

ing

), w

he

re s

ed

ime

nts

in

associa

ted

su

rface

-wa

ter

bod

y

are

co

nta

min

ate

d b

y A

s a

nd

cre

osote

.

Kalm

ar

nssty

rels

en

K

alm

ar,

201

4;

20

15

.

- G

en

era

l re

fere

nce

to

ch

ara

cte

rizin

g c

on

tam

ina

nt

sta

tus in la

ke

se

dim

en

ts,

inclu

din

g im

ple

me

ntin

g N

atu

rvå

rdve

rke

t’s m

on

ito

rin

g

pro

gra

m f

or

spe

cific

ally

do

cum

en

ting

occu

rre

nce

of m

eta

l con

tam

ina

tio

n.

- S

pe

cific

re

fere

nce

s t

o:

O

ska

rsh

am

n’s

ha

rbo

r ba

sin

, w

he

re s

ed

imen

ts a

re c

on

tam

inate

d b

y d

ioxin

s a

nd v

ari

ous m

eta

ls.

F

ou

r gla

ss-f

acto

ry s

ites,

or

gla

sfa

brik (

Als

terb

ro,

Åfo

rs,

Gu

llaskru

v,

an

d M

åle

rås),

wh

ere

sed

imen

ts in

asso

cia

ted

su

rface

-wa

ter

bo

die

s a

re c

on

tam

ina

ted

by A

s,

Pb

, a

nd

/or

Cd

.

T

wo

ba

tte

ry-f

acto

ry s

ite

s (

Batte

rifa

brike

n,

in H

ultsfr

ed

; E

ns),

wh

ere

sed

ime

nts

in

associa

ted

su

rface

-wa

ter

bo

die

s a

re c

on

-ta

min

ate

d b

y P

b a

nd

Cd

. E

mån

s s

ite

als

o p

revio

usly

con

tain

ed

a fo

rme

r p

ape

r pla

nt

(sed

ime

nts

in

associa

ted

su

rfa

ce

-wa

ter

bo

dy a

re c

on

tam

ina

ted

by P

CB

s).

T

wo

site

s (

Ne

dsjö

n a

nd

töfjä

rde

n),

wh

ere

fib

er-

rich

se

dim

en

ts in

asso

cia

ted

su

rfa

ce

-wa

ter

bo

die

s a

re c

onta

min

ate

d b

y H

g.

A

site (

Va

pen

bäckså

n),

wh

ere

se

dim

ents

in

asso

cia

ted

su

rface

-wa

ter

bo

dy c

on

tam

ina

ted

by P

b a

nd

As.

A

site (

Hu

ling

en

), w

he

re s

ed

ime

nts

in

asso

cia

ted

su

rfa

ce

-wa

ter

bo

dy c

on

tam

ina

ted

by H

g a

nd

Pb

.

A

site (

Skep

psb

rofjä

rden

), w

he

re s

ed

ime

nts

in

associa

ted

su

rfa

ce

-wa

ter

bo

dy c

on

tam

ina

ted

by T

BT

.

Kro

no

be

rg

nssty

rels

en

Page 12: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

S

GI

Pu

blic

atio

n 3

0-2

E

12

(1

5)

Kro

no

be

rg,

20

12

.

No

rrb

ott

en

L

än

ssty

rels

en

N

orr

bo

tten

, 2

01

4a;

201

4b

.

- G

en

era

l re

fere

nce

s to

:

O

ccu

rren

ce

of co

nta

min

ate

d s

ed

ime

nts

alo

ng

coa

st, inclu

din

g t

he

in

flu

ence

lo

ng

-te

rm lan

d u

plif

t (d

ue

to

po

st-

gla

cia

l re

bou

nd

) co

uld

ha

ve

on

: (1

) in

cre

ased

co

nta

min

an

t dis

pe

rsio

n d

ue

to

in

cre

ase

d c

oa

sta

l e

rosio

n, a

nd

(2

) sig

nific

an

t re

du

ction

s in

pH

(d

ue

to o

xid

atio

n o

f p

yri

te-b

ea

ring

cla

y s

oils

), w

hic

h m

ay, in

turn

, aff

ect m

ob

ility

of

so

me

me

tals

.

C

ha

racte

rizin

g m

eta

l-co

nta

min

atio

n s

tatu

s in

ma

rin

e s

edim

ents

(co

mplim

en

t to

na

tion

al m

onito

ring

pro

gra

m).

T

he

ne

ed

fo

r stu

dy o

f T

BT

in

ha

rbo

r a

rea

s.

R

esu

lts f

rom

pre

vio

us s

urv

eys o

f sm

all

co

asta

l rive

rs,

wh

ich

in

dic

ate

d s

ed

ime

nt co

nta

min

atio

n b

y m

eta

ls.

- S

pe

cific

re

fere

nce

s t

o:

A

pu

lp/p

ape

r m

ill s

ite

(K

arlshä

ll),

wh

ere

fib

erb

ank a

nd

fib

er-

rich

se

dim

ents

in

asso

cia

ted w

ate

r b

od

y (

ba

y)

are

co

nta

min

ate

d b

y

Hg.

A

site (

Sjö

n A

la L

om

bo

lo)

wh

ere

am

mu

nitio

n w

as d

um

ped

in a

lake

an

d s

ed

imen

ts a

re c

on

tam

ina

ted b

y H

g.

Sk

ån

e

nssty

rels

en

S

ne

, 2

01

3;

20

14

.

- G

en

era

l re

fere

nce

s to

:

M

ultip

le p

ap

erm

ill (

pa

pp

ers

bru

k)

facto

rie

s o

pe

rating

, p

ast o

r p

resen

t.

M

on

ito

rin

g p

rog

ram

focuse

d o

n,

am

on

g o

the

r th

ing

s,

org

an

ic a

nd

oth

er

co

nta

min

an

ts in

sed

imen

ts.

Sto

ck

ho

lm

nssty

rels

en

S

tockh

olm

, 2

01

4a;

201

4b

; 2

01

4c;

20

15

.

- G

en

era

l re

fere

nce

s to

:

C

on

tam

ina

tio

n o

f se

dim

en

ts in s

urf

ace

-wa

ter

bo

die

s in

ma

ny s

ub

urb

an

are

as.

M

eta

ls-c

on

tam

ina

ted

se

dim

ents

in

urb

an

-are

a lakes.

S

ed

ime

nts

co

nta

min

ate

d b

y m

eta

ls (

e.g

. P

b,

Cd,

Cu,

Hg,

and Z

n)

and

org

an

ics in

Sto

ckh

olm

vic

inity a

nd

in t

he

arc

hip

ela

go

. H

igh

le

ve

ls o

f H

g in

fis

h in

Centr

al S

tockh

olm

lin

ke

d to

Hg

con

tam

ina

tio

n in

se

dim

en

t.

S

ed

ime

nts

in L

ake

lare

n c

on

tam

ina

ted

by m

eta

ls a

nd

oth

er

en

vir

onm

en

tal to

xin

s.

C

on

tam

ina

ted

se

dim

en

ts in

ma

ny o

the

r la

ke

s o

ccu

rrin

g a

dja

ce

nt to

bu

ildin

gs,

roa

ds,

an

d ind

ustr

ial a

reas.

M

on

ito

rin

g t

o d

ocu

me

nt/

tra

ck m

eta

l a

nd

PA

H c

on

tam

ina

tion

of

su

rfa

ce

se

dim

en

ts in

the

arc

hip

ela

go a

nd L

ake

lare

n.

P

rese

nce

of

se

dim

ent

con

tam

ina

tion

by n

ew

or

“em

erg

ing

” co

nta

min

an

ts,

wh

ich

co

uld

in

clu

de

PF

OS

(p

erf

luo

roo

cta

ne s

ul-

fon

ate

) a

nd

PF

OA

(p

erf

luo

roocta

no

ic a

cid

).

- S

pe

cific

re

fere

nce

s t

o:

T

wo

pa

pe

rmill

(p

ap

pe

rsb

ruk)

site

s (

on

La

ke

s T

uri

ng

en

an

d T

olla

re)

at

wh

ich

Hg

-co

nta

min

ate

d s

ed

ime

nts

, in

clu

din

g fib

erb

an

k

se

dim

ents

, h

ave

be

en

ca

pp

ed

.

A

su

rface

-wa

ter

bo

dy (

Bru

nnsvik

en

), w

he

re s

edim

en

ts a

re c

on

tam

inate

d b

y P

CB

s a

nd

PA

Hs.

S

urf

ace

-wa

ter

bo

die

s (

de

rtälje

ka

nal; S

ckvik

en

), w

he

re s

ed

ime

nts

are

co

nta

min

ate

d b

y H

g.

S

urf

ace

-wa

ter

bo

die

s (

Oxu

nd

asjö

n;

Rose

rsbe

rgsvik

en

), w

he

re s

ed

ime

nts

are

con

tam

inate

d b

y P

CB

s a

nd d

ioxin

s.

de

rma

nla

nd

L

än

ssty

rels

en

S

öd

erm

an

lan

d,

20

14

.

- G

en

era

l re

fere

nce

s to

mu

ltip

le p

ape

rmill

(p

ap

pe

rsb

ruk)

facto

rie

s o

pe

ratin

g,

pa

st o

r p

resent.

-

Sp

ecific

re

fere

nce

s t

o:

A

ga

s-w

ork

s s

ite

(S

lott

svakte

n g

asve

rk),

wh

ere

sp

rea

d o

f con

tam

ina

nts

, in

clu

din

g P

AH

s a

nd

cya

nid

e,

to a

ssocia

ted

riv

er

(Nykö

pin

gså

n)

possib

le.

A

me

tal-

wo

rks s

ite

(T

un

ave

rken

, V

alh

alla

), w

he

re s

om

e s

pre

ad

of m

eta

ls t

o a

sso

cia

ted

sm

all

cre

ek.

A

la

nd

fill

site

(K

un

gsh

age

ns d

ep

on

i),

wh

ere

sed

ime

nts

in

an a

sso

cia

ted r

ive

r (S

tad

sfjä

rden

) a

re c

on

tam

ina

ted

by P

AH

s.

A

oil-

pro

ductio

n s

ite

(B

ränsle

de

BP

), w

he

re s

pre

ad

ing

of oil-b

ase

d c

on

tam

inan

ts t

o a

ssocia

ted

riv

er

(Nyköp

ing

sån

) p

ossib

le.

Page 13: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

S

GI

Pu

blic

atio

n 3

0-2

E

13

(1

5)

A

site (

Ålö

fjä

rde

n),

wh

ere

se

dim

en

ts c

on

tam

ina

ted

by P

b,

Cd

, P

AH

s,

an

d P

CB

s,

and

the

re is h

igh r

isk f

or

con

tam

ina

nt spre

ad

-in

g b

y b

oa

t tr

aff

ic.

A

site (

rdka

se

n 5

, B

åts

lipe

ri),

wh

ere

se

dim

en

ts c

on

tam

inate

d b

y P

AH

s, a

nd

th

e e

xte

nt

of sp

read

ing

is u

nkn

ow

n.

Up

ps

ala

L

än

ssty

rels

en

U

pp

sala

, no

d

ate

; 2

01

5.

Sp

ecific

re

fere

nce

s to

:

A

min

ing

are

a (

Da

nn

em

ora

gru

vo

mrå

de

), w

he

re s

ed

ime

nts

in

th

e a

sso

cia

ted

su

rface

-wa

ter

bo

dy a

re c

onta

min

ate

d b

y m

eta

ls,

inclu

din

g A

s.

A

n in

du

str

ial site

(S

ku

tskä

rs b

ruk),

wh

ere

se

dim

ents

– inclu

din

g f

ibe

r se

dim

ents

– in a

ssocia

ted

su

rface

-wa

ter

bo

dy a

re c

on

-ta

min

ate

d b

y H

g,

dio

xin

s,

Pb

, C

u,

an

d Z

n.

A

n in

du

str

ial a

rea

ste

rbyve

rke

ns ind

ustiom

råde

), w

he

re s

ed

imen

ts in

asso

cia

ted

su

rface

-wa

ter

bo

die

s,

inclu

din

g a

lake

(F

ilmsjö

n)

are

co

nta

min

ate

d b

y v

ari

ou

s m

eta

ls.

A

n in

du

str

ial site

(T

ärn

sjö

Ån

gg

arv

eri

), w

he

re s

ed

ime

nts

in

associa

ted

la

ke

(T

ärn

sjö

n)

are

co

nta

min

ate

d b

y C

r. R

esu

lt o

f ri

sk

asse

ssm

en

ts p

lace

site

in r

isk-c

lass 1

.

rmla

nd

L

än

ssty

rels

en

V

ärm

lan

d,

20

11

. G

en

era

l re

fere

nces to

mu

ltip

le p

ap

er

indu

str

ies (

pap

pe

rsin

dustr

i) o

pe

ratin

g,

past

or

pre

se

nt.

ste

rbo

tten

L

än

ssty

rels

en

V

äste

rbo

tten

, 2

01

0; 2

015

. G

en

era

l re

fere

nce t

o U

me

å U

niv

ers

ity’s

mo

nito

ring

pro

gra

m fo

r m

ea

su

rin

g d

ioxin

co

nta

min

atio

n in

ba

y s

ed

ime

nts

.

ste

rno

rrla

nd

L

än

ssty

rels

en

V

äste

rno

rrla

nd

, 2

01

4.

Ge

ne

ral re

fere

nces to

:

In

ve

stig

atio

ns in

Su

ndsva

ll B

ay,

wh

ere

co

nta

min

ation

of sed

ime

nts

by v

ari

ou

s p

ollu

tants

(P

AH

s,

Hg

, an

d o

rga

no

chlo

rin

e c

om

-p

ou

nds)

is k

no

wn

or

su

spe

cte

d.

O

ccu

rren

ce

of

fib

er-

rich s

ed

ime

nts

(in

su

rface

-wa

ter

bo

die

s)

ou

tsid

e o

f S

va

an

d H

alls

tanä

s,

as in

ve

stig

ate

d b

y S

GU

.

S

GU

’s f

ibe

rba

nk m

ap

pin

g p

roje

ct,

to

pro

vid

e in

form

atio

n o

n o

ccu

rre

nce

an

d c

on

tam

ina

tio

n s

tatu

s o

f fib

erb

an

ks a

lon

g t

he

co

ast.

De

ve

lop

me

nt o

f m

eth

odo

log

y f

or

risk c

lassific

atio

n o

f fib

erb

anks a

nd f

ibe

r-rich

se

dim

en

ts a

lso

re

fere

nce

d.

stm

an

lan

d

nssty

rels

en

V

ästm

an

lan

d,

20

14

. -

Ge

ne

ral re

fere

nce

to

se

dim

en

t stu

die

s in

Ha

llsta

ham

ma

rs b

ruk d

elo

mrå

de

; no

sp

ecific

s o

n c

on

tam

inan

t ty

pe

(s).

str

a G

öta

l-a

nd

nssty

rels

en

V

ästr

a G

öta

l-a

nd

, 20

13

.

- G

en

era

l re

fere

nce

s to

:

M

on

ito

rin

g p

rog

ram

fo

r a

fo

rme

r in

du

str

ial a

rea

, w

he

re p

ast

dis

ch

arg

es/r

ele

ases r

esulte

d in

con

tam

inatio

n o

f se

dim

en

ts in

an

a

sso

cia

ted lake

(La

xsjö

n)

by m

ultip

le p

ollu

tan

ts (

dio

xin

s,

PC

P,

oil,

Hg

and

oth

er

me

tals

, ph

tha

late

s a

nd

mo

re).

O

ng

oin

g s

pre

ad

of

TB

T (

as w

ell

as C

u a

nd

Zn

) to

th

e m

arin

e e

nvir

onm

en

t.

M

ap

pin

g o

f T

BT

co

nta

min

ation in

se

dim

ents

in

sm

all-b

oa

t ha

rbo

rs in

diffe

ren

t a

reas (

ne

rn,

Mjö

rn,

ta R

ive

r, a

nd

the

we

st

co

ast)

in

dic

ate

s c

on

tin

ued

hig

h c

on

cen

tra

tio

ns.

M

ultip

le p

ap

er

ind

ustr

ies a

nd

mill

s (

pa

ppe

rsin

dustr

ier,

pa

ppe

rsb

ruk)

op

era

tin

g, p

ast

or

pre

se

nt.

- S

pe

cific

re

fere

nce

s t

o:

M

ap

pin

g o

f dio

xin

-co

nta

min

ate

d s

ed

ime

nts

in V

än

ern

, lin

ke

d m

ain

ly t

o p

ap

er-

mill

in

dustr

ies.

Ele

va

ted

dio

xin

le

ve

ls in

fis

h a

lso

re

fere

nce

d.

M

ultip

le c

on

tam

ina

nts

in s

ed

ime

nts

in

La

xsjö

n, a

ppa

ren

tly r

ela

ted

to

– a

mo

ng

oth

er

possib

le/lik

ely

sou

rces –

op

era

tion

s a

t

Page 14: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

S

GI

Pu

blic

atio

n 3

0-2

E

14

(1

5)

local p

ap

er

mill

s (

pa

pp

ers

industr

ier)

.

A

gla

ss-p

rod

uction

site

(A

rda

gh

Gla

ss L

imm

are

d A

B),

wh

ere

co

nta

min

atio

n o

f se

dim

en

ts b

y v

ari

ou

s m

eta

ls (

Pb

, A

s,

an

d C

d)

in

an

associa

ted

su

rfa

ce

-wa

ter

bo

dy in

ve

stig

ate

d.

A

n in

du

str

ial site

(G

öta

rgeri M

ossg

rop

en

), w

he

re s

ed

ime

nts

in a

n a

sso

cia

ted

pon

d a

re c

on

tam

inate

d b

y o

il, m

eta

ls,

and

n

on

ylp

he

no

l.

In

ve

stig

atio

n o

f sed

ime

nt con

tam

ina

tion

in

su

rfa

ce

-wa

ter

bod

ies a

ssocia

ted

with

tw

o f

ore

st-

ind

ustr

y s

ite

s (

Mu

nksjö

Pa

pe

r a

nd

R

exce

ll T

issu

e).

Öre

bro

L

än

ssty

rels

en

Ö

reb

ro,

201

3.

- G

en

era

l re

fere

nce

to

at

lea

st o

ne

pa

pe

rmill

(p

ap

pe

rsb

ruk)

facto

ry o

pera

tin

g in

the

past.

-

Sp

ecific

re

fere

nce

s t

o:

W

ood

-im

pre

gn

atio

n s

ite

s (

Åsbro

), w

he

re s

ed

ime

nts

in a

ssocia

ted

la

ke

(T

isa

ren

) a

re c

on

tam

ina

ted

by c

reo

so

te.

A

sa

wm

ill s

ite

(S

ilve

rhö

jde

ns s

aw

mill

), w

he

re s

ed

ime

nts

in

asso

cia

ted

lake

(H

örk

en

) a

re c

onta

min

ate

d b

y P

CP

, d

ioxin

s,

and

ch

loro

phe

no

ls.

A

sh

ooting

-ra

nge

site

(B

ofo

rs),

wh

ere

se

dim

en

ts in

asso

cia

ted

lake

(Lå

ngssjö

n)

are

co

nta

min

ate

d b

y m

eta

ls, m

ain

ly H

g a

nd

P

b (

bu

t a

lso

As;

Cu a

nd

Ni)

. R

isk a

sse

ssm

en

t re

sults in

dic

ate

site is r

isk-c

lass 1

.

A

n in

du

str

ial site

(S

ikfo

rs b

ruk),

wh

ere

se

dim

en

ts in

asso

cia

ted

su

rfa

ce

-wa

ter

bo

dy c

on

tam

ina

ted

. C

onta

min

an

t ty

pe

(s)

no

t id

en

tified

. R

isk a

sse

ssm

en

t re

su

lts in

dic

ate

site

is r

isk-c

lass 2

.

Ös

terg

ötl

an

d

nssty

rels

en

Ö

ste

rgö

tla

nd

, 2

01

4.

- G

en

era

l re

fere

nce

s to

the

occu

rre

nce

of

mu

ltip

le p

ap

erm

ills (

pa

ppe

rsb

ruk),

bo

th p

ast

an

d p

resen

t.

- S

pe

cific

re

fere

nce

s t

o:

A

pa

pe

rmill

site

(K

isa

sjö

n),

nea

rby t

o w

hic

h o

ccu

rs f

ibe

rba

nk s

edim

en

ts c

on

tam

inate

d b

y H

g.

A

le

ath

er-

tan

nin

g s

ite

(L

und

berg

s L

äd

er)

, w

he

re s

edim

en

ts in

associa

ted

su

rface

-wa

ter

bod

y (

Va

ldem

ars

vik

en

) a

re c

onta

mi-

na

ted

by C

r.

A

sa

wm

ill s

ite

(Y

dre

fors

trä

förä

dlin

g),

wh

ere

se

dim

en

ts in

asso

cia

ted

la

ke

(B

rosjö

n)

are

con

tam

ina

ted b

y d

ioxin

s.

A

no

the

r sa

wm

ill s

ite

(B

esto

rp s

åg

ve

rk),

wh

ere

sed

ime

nts

in

asso

cia

ted lake

(S

tora

ng

en

) a

re c

on

tam

ina

ted

by d

ioxin

s.

A

site (

Gusum

n)

impa

cte

d b

y d

isch

arg

e o

f un

trea

ted

in

du

str

ial w

aste

wa

ter,

wh

ere

se

dim

en

ts in

asso

cia

ted

riv

er

(Gusum

sån

) a

re c

on

tam

ina

ted b

y P

CB

s,

Cu

, Z

n, a

nd

Pb

).

A

gla

ss-f

acto

ry s

ite (

Re

ijmyre

gla

sb

ruk),

wh

ere

sed

ime

nts

in

asso

cia

ted lake

(H

un

n)

are

con

tam

ina

ted

by A

s.

A

n in

du

str

ial a

rea

(S

ku

tbo

sjö

n),

wh

ere

se

dim

en

ts c

on

tam

inate

d b

y m

eta

ls (

Cu

, C

r, H

g,

Ni, a

nd

Zn

) a

s w

ell

as P

AH

s,

PC

Bs,

an

d h

ea

vy a

liph

atic h

yd

roca

rbo

ns.

A

n in

du

str

ial m

ill s

ite (

Qva

rnsha

mm

ars

Je

rnb

ruk [

De G

ee

rsfo

rs])

, w

he

re s

ed

ime

nts

in

asso

cia

ted r

ive

r (G

od

eg

ård

n)

are

co

nta

min

ate

d b

y m

eta

ls (

Cr,

Cu

, P

b,

Zn

, an

d C

d)

an

d o

il. C

on

tam

ina

tio

n a

lso

de

tecte

d in

cra

yfish

.

A

wo

od

-in

dustr

y s

ite

(P

er

Blo

mq

uis

t A

B),

wh

ere

se

dim

en

ts in

associa

ted

riv

er

(Lill

ån

) a

re c

on

tam

inate

d b

y d

ioxin

s.

Page 15: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

SGI Publication 30-2E

15 (15)

Page 16: In-situ capping of contaminated sedimentsTBT sediment contamination in three harbors (Karlskrona, Ronneby, and Sölvesborg). Also expected in other harbors. A copper works site, where

Swedish Geotechnical Institute

SE-581 93 Linköping, Sweden

Phone: +46 13-20 18 00

E-mail: [email protected]

www.swedgeo.se