Improved Graphical Representation of Sedimentary …...Improved Graphical Representation of...

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Improved Graphical Representation of Sedimentary Organic Matter as Paleoenvironmental Parameters Mohamed K. Zobaa 1, 2 , Salah Y. El Beialy 3 , Asmaa A. Taha 3 , Francisca E. Oboh - Ikuenobe 1 1 Department of Geosciences and Geological and Petroleum Engineering, Missouri University of Science and Technology, Rolla, MO, U SA. [email protected] ; [email protected] 2 Department of Geology, Faculty of Science, Benha University, EGYPT. [email protected] 3 Department of Geology, Faculty of Science, Mansoura University, EGYPT. [email protected] ; [email protected] Abstract A ternary plot is proposed to represent the paleoenvironmental context of palynologically recovered sedimentary particulate organic matter (POM) . This plot identifies three major marine paleoenvironmental parameters, namely redox conditions, proximal - distal distribution, and terrestrial influence . It also facilitates hydrocarbon source - rock (kerogen type) interpretation on the basis of the overall POM composition as well as the ratio of marine to non - marine organic components . In this plot, palynofacies data are categorized into three end - members, each of which has a paleoenvironmental indication . Phytoclasts and non - marine palynomorphs are combined in the top end - member to indicate the degree of terrestrial and freshwater influx . A morphous m arine organic matter (AMOM) is plotted base - left to reflect the oxygenation state, while the base - right end - member represents marine palynomorphs , which together with AMOM mark the approximate basin - ward distance from the shoreline . Although inspired by the widely used plot of Tyson ( 1989 , 1993 , and 1995 ) and the subsequent modifications by Roncaglia and Kuijpers ( 2006 ), the proposed sedimentary POM ternary plot has the advantage of categorizing genetically related palynofacies components based on their paleoenvironmental significance rather than diagenetic structural morphology or palynological classification . This prevents illusive proximal distal and redox interpretations arising from ( 1 ) combining decomposition products from marine and non - marine sources into one (AOM) end - member based solely on the lack of visible definitive internal structure under the light microscope, and ( 2 ) grouping Terrestrial and marine palynomorph taxa under one ( palynomorphs ) end - member . Such problems have been resolved by counting the amorphous non - marine macrophytes as degraded phytoclasts preserving their correct paleoenvironmental implication . In addition, non - marine palynomorphs have been separated from the marine palynomorphs and grouped with terrestrial phytoclasts . One important precaution to consider is that this sedimentary POM ternary plot is not intended to interpret the depositional conditions of submarine fan systems and turbidite sequences where large terrigenous components are known to be transported to the deep sea realm . Paper No. 135 - 30 Session No. 135 -- Booth# 402 T193. Sedimentary Environment and Process Studies: The Emerging Generation of Scientists (Posters) Monday, 2 November 2015: 9:00 AM - 6:30 PM Exhibit Hall (Baltimore Convention Center) Geological Society of America Abstracts with Programs. Vol. 47, No. 7, p.365 Differential Diagnosis Structureless particles of terrestrial origin (i . e . , from the degradation of terrestrial phytoclasts ) are herein named degraded phytoclasts and are not referred to as amorphous organic matter (AOM) . Degraded phytoclasts , particularly those of vascular plants, are lignified (contain lignin in their internal cellular structures) . Lignin is a complex organic compound that tends to be firm and decay resistant . Therefore, degraded, structureless phytoclasts can be differentiated from AMOM under the light microscope by a thicker and darker appearance . In addition , degraded phytoclasts often show remnants of their original structures, such as cell walls and pitting . Definitions Palynomorphs encompass both continental and marine - dwelling organic - walled microfossils such as spores, pollen, dinoflagellate cysts, acritarchs , freshwater algae, fungal remains, and foraminiferal test linings . Phytoclasts are all terrestrial plant fragments, including translucent types with clear internal structures, degraded structureless , and opaques (e . g . , cuticles, tracheids , and vessel elements ) . The opaque phytoclasts are black kerogen particles derived from the oxidation of translucent phytoclasts , carbonization (coalification) during post - depositional alteration, or as a result of wildfires . Amorphous marine organic matter (AMOM) includes all semi - transparent, nearly colorless, fuzzy, structureless kerogen particles derived essentially from the bacterial degradation of marine phytoplankton, such as dinoflagellate cysts and acritarchs . Opaque p hytoclast Degraded p hytoclast Degraded ( structureless ) phytoclast showing remnants of its original cellular framework (black arrows) Structured phytoclasts Terrestrial Phytoclasts Sedimentary Particulate O rganic Matter Ternary Plot Amorphous Marine Organic Matter Terrestrial Palynomorphs Pollen Spores Fungal fruiting body Freshwater alga ( Pediastrum ) Freshwater alga ( Botryococcus ) Marine Palynomorphs Acritarch Dinoflagellate cysts A digital copy of this poster and a clean copy of the ternary plot (for use with your own data) can be obtained from the following link: http://www.researchgate.net/profile/Mohamed_Zobaa/publications References Roncaglia , L., and Kuijpers , A., 2006, Revision of the palynofacies model of Tyson (1993) based on recent high - latitude sediments from the North Atlantic: Facies, v. 52, p. 19 39 Tyson , R.V., 1989, Late Jurassic palynofacies trends, Piper and Kimmeridge Clay Formations , UK onshore and offshore, in Batten, D.J., and Keen, M.C., eds., Northwest European micropalaeontology and palynology: British Micropalaeontological Society Series : Chichester , U.K., Ellis Horwood , p. 135 172 . Tyson , R.V., 1993, Palynofacies analysis, in Jenkins, D.G., ed., Applied micropaleontology : Dordrecht , Netherlands, Kluwer Academic Publishers, p. 153 191 . Tyson , R.V., 1995, Sedimentary organic matter. Organic facies and palynofacies : London , Chapman and Hall, 615 p.

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Page 1: Improved Graphical Representation of Sedimentary …...Improved Graphical Representation of Sedimentary Organic Matter as Paleoenvironmental Parameters Mohamed K. Zobaa 1, 2, Salah

Improved Graphical Representation of Sedimentary Organic Matter as Paleoenvironmental Parameters

Mohamed K. Zobaa1, 2, Salah Y. El Beialy3, Asmaa A. Taha3, Francisca E. Oboh-Ikuenobe1

1 Department of Geosciences and Geological and Petroleum Engineering, Missouri University of Science and Technology, Rolla, MO, USA. [email protected]; [email protected] Department of Geology, Faculty of Science, Benha University, EGYPT. [email protected]

3 Department of Geology, Faculty of Science, Mansoura University, EGYPT. [email protected]; [email protected]

Abstract

A ternary plot is proposed to represent the paleoenvironmental context ofpalynologically recovered sedimentary particulate organic matter (POM).This plot identifies three major marine paleoenvironmental parameters,namely redox conditions, proximal-distal distribution, and terrestrialinfluence. It also facilitates hydrocarbon source-rock (kerogen type)interpretation on the basis of the overall POM composition as well as theratio of marine to non-marine organic components.

In this plot, palynofacies data are categorized into three end-members, eachof which has a paleoenvironmental indication. Phytoclasts and non-marinepalynomorphs are combined in the top end-member to indicate the degree ofterrestrial and freshwater influx. Amorphous marine organic matter (AMOM)is plotted base-left to reflect the oxygenation state, while the base-right end-member represents marine palynomorphs, which together with AMOM markthe approximate basin-ward distance from the shoreline.

Although inspired by the widely used plot of Tyson (1989, 1993, and 1995) andthe subsequent modifications by Roncaglia and Kuijpers (2006), the proposedsedimentary POM ternary plot has the advantage of categorizing geneticallyrelated palynofacies components based on their paleoenvironmentalsignificance rather than diagenetic structural morphology or palynologicalclassification. This prevents illusive proximal–distal and redox interpretationsarising from (1) combining decomposition products from marine and non-marine sources into one (AOM) end-member based solely on the lack ofvisible definitive internal structure under the light microscope, and (2)grouping Terrestrial and marine palynomorph taxa under one (palynomorphs)end-member. Such problems have been resolved by counting the amorphousnon-marine macrophytes as degraded phytoclasts preserving their correctpaleoenvironmental implication. In addition, non-marine palynomorphs havebeen separated from the marine palynomorphs and grouped with terrestrialphytoclasts. One important precaution to consider is that this sedimentaryPOM ternary plot is not intended to interpret the depositional conditions ofsubmarine fan systems and turbidite sequences where large terrigenouscomponents are known to be transported to the deep sea realm.

Paper No. 135-30Session No. 135--Booth# 402T193. Sedimentary Environment and Process Studies: The Emerging Generation of Scientists (Posters)Monday, 2 November 2015: 9:00 AM-6:30 PMExhibit Hall (Baltimore Convention Center)Geological Society of America Abstracts with Programs. Vol. 47, No. 7, p.365

Differential DiagnosisStructureless particles of terrestrial origin (i.e., from the degradation of terrestrialphytoclasts) are herein named degraded phytoclasts and are not referred to asamorphous organic matter (AOM). Degraded phytoclasts, particularly those ofvascular plants, are lignified (contain lignin in their internal cellular structures).Lignin is a complex organic compound that tends to be firm and decay resistant.Therefore, degraded, structureless phytoclasts can be differentiated from AMOMunder the light microscope by a thicker and darker appearance. In addition,degraded phytoclasts often show remnants of their original structures, such as cellwalls and pitting.

DefinitionsPalynomorphs encompass both continental and marine-dwelling organic-walledmicrofossils such as spores, pollen, dinoflagellate cysts, acritarchs, freshwateralgae, fungal remains, and foraminiferal test linings.

Phytoclasts are all terrestrial plant fragments, including translucent types withclear internal structures, degraded structureless, and opaques (e.g., cuticles,tracheids, and vessel elements). The opaque phytoclasts are black kerogenparticles derived from the oxidation of translucent phytoclasts, carbonization(coalification) during post-depositional alteration, or as a result of wildfires.

Amorphous marine organic matter (AMOM) includes all semi-transparent,nearly colorless, fuzzy, structureless kerogen particles derived essentially fromthe bacterial degradation of marine phytoplankton, such as dinoflagellate cystsand acritarchs.

Opaque phytoclast Degraded phytoclast Degraded (structureless) phytoclastshowing remnants of its original

cellular framework (black arrows)

Structured phytoclasts

Terrestrial Phytoclasts

Sedimentary Particulate Organic Matter Ternary Plot

Amorphous Marine Organic Matter

Terrestrial Palynomorphs

Pollen

Spores

Fungal fruiting body Freshwater alga (Pediastrum)

Freshwater alga (Botryococcus)

Marine Palynomorphs

Acritarch Dinoflagellate cysts

A digital copy of this poster and a clean copy of the ternary plot (for use with your own data) can beobtained from the following link: http://www.researchgate.net/profile/Mohamed_Zobaa/publications

References

Roncaglia, L., and Kuijpers, A., 2006, Revision of the palynofacies model of Tyson (1993) based on recent high-latitude sediments from the North Atlantic: Facies, v. 52, p. 19–39

Tyson, R.V., 1989, Late Jurassic palynofacies trends, Piper and Kimmeridge Clay Formations, UK onshore and offshore, in Batten, D.J., and Keen, M.C., eds., Northwest European micropalaeontology and palynology: British Micropalaeontological Society Series: Chichester, U.K., Ellis Horwood, p. 135–172.

Tyson, R.V., 1993, Palynofacies analysis, in Jenkins, D.G., ed., Applied micropaleontology: Dordrecht, Netherlands, Kluwer Academic Publishers, p. 153–191.

Tyson, R.V., 1995, Sedimentary organic matter. Organic facies and palynofacies: London, Chapman and Hall, 615 p.