IMDG1998

INTERNATIONAL MARITIME ORGANIZATION

INTERNATIONAL MARITIME DANGEROUS GOODS CODE

(IMDG CODE)

Amendment 29-98 (including Supplement)

This publication has been prepared and printed in such a way that the replacement pages can be inserted into the loose-leaf volumes of the 1994 Consolidated Edition of the IMDG Code, entirely replacing the

amended/corrected pages

Published and printed in 1998

by the International Maritime Organization 4, Albert Embankment, London SE1-7SR ISBN 92-801-1465-4

Copyright © IMO 1998

All rights reserved No part of this publication may, for sales purposes, be reproduced, stored in a re-

trieval system or transmitted in any form or by any means, electronic, electrostatic,

magnetic tape, mechanical, photocopying or otherwise,

without prior permission in writing from the International Maritime Organization

Sales number: IMO-213E

FOREWORD

The International Convention for the Safety of Life at Sea, 1974 (SOLAS), as amended deals with various aspects of maritime safety and contains in part A of chapter VII the man-datory provisions governing the carriage of dangerous goods in packaged form or in solid form in bulk Regulation Vll/1-3 prohibits the carriage of dangerous goods except in accor-dance with the provisions of part A of chapter VII which are amplified by the International Maritime Dangerous Goods (IMDG) Code.

Regulation II-2/54 of the SOLAS Convention specifies the special requirements for a ship intended to carry dangerous goods, the keel of which was laid or which was at a similar stage of construction on or after 1 September 1984.

The International Convention for the Prevention of Pollution from Ships, 1973, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78), deals with various aspects of prevention of marine pollution, and contains in its Annex III the mandatory provisions for the prevention of pollution by harmful substances carried by sea in packaged form Regulation 1(2) prohibits the carriage of harmful substances in ships except in accordance with the provisions of Annex III, which are also amplified by the IMDG Code.

In accordance with the Provisions concerning Reports on Incidents Involving Harmful Sub-stances (Protocol I to MARPOL 73/78), incidents involving losses of such substances from ships must be reported by the master or other person having charge of the ship concerned. Each substance defined as harmful to the marine environment is identified as a MARINE POLLUTANT in its individual schedule of the IMDG Code and by the superscripts P

or PP

in the General Index. Substances which may be considered harmful to the marine envi-ronment only if they contain certain quantities of marine pollutants P or PP

are identified by the superscript • in the General Index.

The IMDG Code is recommended to Governments for adoption or for use as the basis for national regulations in pursuance of their obligations under regulation Vll/1-4 of the 1974 SOLAS Convention, as amended, and regulation 1(3) of Annex III of MARPOL 73/78 Obser-vance of the Code harmonizes the practices and procedures followed in the carriage of dan-gerous goods by sea and ensures compliance with the mandatory provisions of the SOLAS Convention and of Annex III of MARPOL 73/78.

The Code, which sets out in detail the requirements applicable to each individual substance, material or article, has undergone many changes, both in layout and content, in order to keep pace with the expansion and progress of industry IMO's Maritime Safety Committee (MSC) is authorized by the Organization's Assembly to adopt amendments to the Code, thus enabling IMO to respond promptly to developments in transport.

Amdt. 27-94

FOREWORD

During its seventeenth session (28 October to 8 November 1991), the Assembly adopted resolution A 717(17), "Co-ordination in Matters relating to Dangerous Goods and Hazardous Substances", in order to achieve and maintain a level of harmonization between the IMDG Code and the recommendations of the other transport modes.

A revision of the Code was undertaken resulting in the latest set of amended pages (Amendment 29-98) which was adopted by the MSC at its sixty-ninth session (11 to 20 May 1998).

The MSC unanimously agreed that Amendment 29 to the Code, its Annex I, the Emergency Procedures for Ships Carrying Dangerous Goods (EmS) and the Medical First Aid Guide for Use in Accidents Involving Dangerous Goods (MFAG) should be implemented on 1 January 1999, with a six month transitional period until 1 July 1999, on the understanding that Gov-ernments had the prerogative to implement an amendment in whole or in part at any earlier date following circulation of the adopted amendments by the Organization and that the Or-ganization would be notified of any such early implementation.

Note on pagination a new page which has been in-serted between existing pages is indicated by a number followed by -1, -2, -3 etc., a page which continues or extends a page is indicated by a number followed by a, b, c etc. (in a long sequence such as a table, this would continue as a1-, z1-, a4-, z4- etc.) Note on amended text changes to existing text or new texts are indicated by shading Where there are no changes resulting from Amendment 29 but a page does not exactly match a page of the 1994 Consolidated Edition as updated by Amendment 28-96 there is shad-ing around the page number.

Amdt. 29-98

GENERAL INTRODUCTION

5.1.9 Class 9 Miscellaneous dangerous substances and articles. In this Code class 9 comprises: 1

substances and articles not covered by other classes which experience has shown or may show to be of such a dangerous character that the provisions of part A of chapter VII of the International Convention for the Safety of Life at Sea 1974, as amended should apply these include substances that are transported or offered for transport at temperatures equal to or exceeding 100° C in a liquid state and solids that are transported or offered for trans-port at temperatures equal to or exceeding 240° C; and

2

substances not subject to the provisions of part A of chapter VII of the aforementioned Convention but to which the regulations of Annex III of the International Convention for the Prevention of Pollution from Ships 1973, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78) apply.

5.1.10

For the purposes of this Code dangerous goods with a melting point or initial melting point of 20° C or lower at a pressure of 101.3 kPa should be considered to be liquid unless there is an explicit or implicit indication to the con-trary. A viscous substance for which a specific melting point cannot be determined should be subjected to the ASTM D-4359.90 test or to the test for determining fluidity (penetrometer test) prescribed in Appendix A.3 of An-nex A of the European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR) with the modifications that the penetrometer shall conform to ISO 2137, 1985 and that the test shall be used for viscous substances of any class.

5.1.11 Non-classified materials:

A GENERIC or NOT OTHERWISE SPECIFIED (N.O.S.) entry may be used to offer for transport by sea a sub-stance material or article which is not listed by its name in the General Index. Such a substance material or article may be transported only after: - its dangerous hazardous and/or harmful properties have been determined; - it has been classified in accordance with the class definitions and criteria and; - the entry that most accurately describes the nature of the goods has been selected (see also subsection 7.1). Once the class of the goods has been established all applicable requirements for transport laid down in this Code should be complied with. Any substance material or article having or suspected of having explosive properties or characteristics should first be considered for classification in class 1.

5.2 Classification of substances, mixtures and solutions with multiple hazards 5.2.1

5.2.2

The table of precedence of hazard characteristics in 5.2.6 should be used as a guide in determining the class of a substance mixture or solution having more than one hazard when it is not specifically listed by name in this Code. For substances mixtures or solutions having multiple hazards which are not specifically Instead by name the most stringent packaging group of those assigned to the respective hazards of the goods takes precedence over other packaging groups irrespective of the precedence of hazard table in 5.2.6. The precedence of hazard table indicates which of the hazards should be regarded as the primary hazard. The class which appears at the intersection of the horizontal line and the vertical column is the primary hazard and the remaining class is the subsidiary hazard. The packaging groups for each of the hazards associated with the sub-stance mixture or solution should be determined by reference to the appropriate criteria. The most stringent of the groups so indicated should then become the packaging group of the substance mixture or solution.

IMDG CODE - PAGE 0019 Amdt. 29-98


5.2.3 The proper shipping name (see subsection 7.1 of this General Introduction) of a substance, mixture or solution when classified in accordance with 5.2.1 and 5.2.2 should be the most appropriate N.O.S. (not otherwise speci-fied) entry in this Code for the class shown as the primary hazard.

5.2.4 The precedence of hazard characteristics of the following substances materials and articles have not been dealt with in the precedence of hazard table as these primary hazards always take precedence:

1 substances and articles in class 1; 2 gases in class 2; 3 self-reactive and related substances and desensitized explosives in class 4.1; 4 pyrophoric substances in class 4.2; 5 substances in class 5.2; 6 substances in class 6.1 with a packaging group I vapour inhalation toxicity; 7 substances in class 6.2; and 8 materials in class 7. 5.2.5 Apart from excepted radioactive materials (where the other hazardous properties take precedence), radioactive

materials having other hazardous properties should always be classified in class 7, with the greatest of the additional hazards being identified.

5.2.6 Precedence of hazard table

Class and packaging group 4.2 4.3 6.1, I

Dermal 6.1, I Oral

6.1, II 6.1 8, I

Liquid 8, I

Solid 8, II

Liquid 8, II

Solid 8, III

Liquid 8, III Solid

3, I 3 3 3 3 3 - 3 - 3 - 3, II 3 3 3 3 8 - 3 - 3 - 3, III 6.1 6.1 6.1 3* 8 - 8 - 3 - 4.1, II** 4.2 4.3 6.1 6.1 4 1 4 1 - 8 - 4 1 - 4 1 4.1, III** 4.2 4.3 6.1 6.1 6.1 4 1 - 8 - 8 - 4 1 4.2, II 4.3 6.1 6.1 4 2 4.2 8 8 4.2 4.2 4.2 4.2 4.2, III 4.3 6.1 6.1 6.1 4 2 8 8 8 8 4 2 4 2 4.3, I 6.1 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3, II 6.1 4.3 4.3 4.3 8 8 4.3 4.3 4.3 4.3 4.3, III 6.1 6.1 6.1 4.3 8 8 8 8 4.3 4.3 51, I*** 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 51, II*** 6.1 5.1 5.1 5.1 8 8 5.1 5.1 5.1 5.1 5.1, III*** 6.1 6.1 6.1 5.1 8 8 8 8 5.1 5.1 6.1, I, Dermal 8 6.1 6.1 6.1 6.1 6.1 6.1, I, Oral 8 6.1 6.1 6.1 6.1 6.1 6.1, II, Inhalation 8 6.1 6.1 6.1 6.1 6.1 6.1, II, Dermal 8 6.1 8 6.1 6.1 6.1 6.1, II, Oral 8 8 8 6.1 6.1 6.1 6.1, III 8 8 8 8 8 8

For hazards not shown in this table see 5.2.4.

* 6.1 for pesticides. ** Substances of class 4.1 other than self-reactive and related substances and desensitized explosives. *** There are at present no established criteria for determining packaging groups for liquids in class 5.1. For the time being, the degree of hazard is to be assessed by analogy with listed substances, allocating the substance to packaging group I (great), II (medium) or III (minor) danger. - Denotes an impossible combination.



5.3 Classification of solutions and mixtures subject to the provisions of part A of chapter VII of the International Convention for the Safety of Life at Sea, 1974, as amended

5.3.1

A solution or mixture containing a dangerous substance identified by name in this Code and one or more non-dangerous substances should be shipped in accordance with the requirements for the dangerous substance except when

1 the solution or mixture is specifically listed elsewhere in this Code; or

2 the schedule for the dangerous substance specifically indicates that it applies only to the pure or technically pure substance; or

3 the class physical state or packaging group of the solution or mixture is not the same as that of the dangerous substance; or

4 there is a significant change in the measures to be taken in an emergency. 5.3.2

When considering a solution or mixture in accordance with 5.3.1 due account should be given to whether the danger-ous constituent comprising the solution or mixture has been identified as a marine pollutant. If this is the case the requirements of subsection 5.4 are also applicable.

5.3.3

For solutions and mixtures subject to 5.3.1 the qualifying word SOLUTION or MIXTURE as appropriate should be part of the proper shipping name e.g. BUTANE MIXTURE.

5.3.4

When the class physical state or packaging group has changed in comparison with the pure substance the solution or mixture should be shipped in accordance with the requirements for the changed hazard under an appropriate N.O.S. entry.

5.3.5

A mixture or solution containing one or more substances identified by name in this Code or classified under an N.O.S. or generic entry and one or more substances not subject to the provisions of this Code is not subject to the provisions of this Code if the hazard characteristics of the mixture or solution are such that they do not meet the criteria (includ-ing human experience criteria) for any class.

5.4 Classification of solutions, mixtures and isomers subject to the provisions of Annex III of the International Convention for the Prevention of Pollution from Ships, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78)

5.4.1 A solution or mixture contain no 10% or more of a marine pollutant or marine pollutants is a MARINE POLLUTANT 5.4.2 However certain marine pollutants do have an extreme pollution potential and are identified as severe marine pollut-

ants in the individual schedules A solution or mixture containing 1% or more of these specific marine pollutant is MARINE POLLUTANT

5.4.3

A solution or mixture which does not fall within the criteria of classes 1 to 8 but which meets the criteria for marine pollutants under 5.4.1 or 5.4.2 should be offered for transport as an ENVIRONMENTALLY HAZARDOUS SUB-STANCE, LIQUID, N.O.S. or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. under UN No. 3082 and UN No. 3077 respectively in class 9 even though it is not listed by name in the appendices thereto.

5.4.4

An isomer of a substance identified as a marine pollutant and covered by a generic entry in classes 1 to 8, but which does not fall within the criteria of these classes should be offered for transport as an ENVIRONMENTALLY HAZ-ARDOUS SUBSTANCE, LIQUID, N.O.S. or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. under UN No. 3082 and UN No. 3077 respectively in class 9 even though it is not listed by name in the ap-pendices thereto.



6 STANDARDIZATION OF THE FLASHPOINT TEST METHOD

6.1 The flashpoint of a flammable liquid is the lowest temperature of the liquid at which its vapour forms an ignitable mix-ture with air*. It gives a measure of the risk of formation of explosive or ignitable mixtures when the liquid escapes from its packing. A flammable liquid cannot be ignited so long as its temperature remains below the flashpoint.

6.2 The flashpoint is not an exact physical constant for a given liquid It depends to some extent on the construction of the test apparatus used and on the testing procedure. Therefore flashpoint data should specify the name of the test appa-ratus.

6.3 Several standard apparatuses are in current use. They all operate on the same principle a specified quantity of the liquid is introduced into a receptacle at a temperature well below the flashpoint to be expected then slowly heated periodically a small flame is brought near to the surface of the liquid. The flashpoint is the lowest temperature at which a flash is observed.

6.4 The test methods can be divided into two groups depending on the use in an apparatus of an open receptacle (open cup methods) or a closed one which is only opened to admit the flame (closed cup methods). As a rule the flashpoints found in an open cup test are a few degrees higher than in a closed cup test.

6.5 In general reproducibility in closed cup apparatus is better than in an open cup.

6.5.1 It's therefore recommended that flashpoints especially in the range around 23° C (73 F) should be determined by means of closed cup methods.

6.5.2 Flashpoint data in this Code are generally based on closed cup methods. In countries where it is customary to deter-mine flashpoints by the open cup method the temperatures given by that method would need to be reduced to corre-spond with those in this Code.

6.6 The following documents describe methods used in certain countries to determine the flashpoint of substances in class 3:

1 France (Association francaise de normalisation (AFNOR) Tour Europe Cedex, 7, 92080 Pans la Defense); French Standard NF M 07 019; French Standard NF M 07 011/NFT 30 050/NFT 66 009; French Standard NF M 07 036. 2 Germany (Deutscher Normenausschuss Burggrafenstrasse 6, 10787, Berlin) Standard DIN 53213 (for varnishes lacquers and similar viscous liquids with flashpoints below 65° C) 3 Netherlands ASTM D 93 90 ASTM D 3278 89 ISO 1516 ISO 1523 ISO 3679 ISO 3680

Note: The flashpoint should not be confused with the ignition temperature, which is the temperature to which an explosive vapour-air mixture must be heated to cause actual explosion. There is no relationship between the flashpoint and the ignition temperature.


7.1.3.2

When several names are in use for the same substance one or more of those names have been chosen as proper shipping names the rest being only synonyms are included on the individual schedules and in the General Index for reference purposes only. Initials or trade names alone should not be used to describe a substance unless they are abbreviations or names approved by the international Organisation for Standardization (ISO). Trade names may be utilized on documents and packages in addition to the proper shipping name.

7.1.4

A pesticide or pesticide preparation falling within the criteria of class 3 or class 6.1, which is a marine pollutant should be offered for transport under the appropriate pesticide entry as given in the Pesticides Table supplemented with the name and the concentration of the specific pesticide in parentheses and the words MARINE POLLUTANT (see subsection 9.3 of this General Introduction). Such a pesticide or pesticide preparation which does not fall under the criteria of these classes, but which meets the criteria for marine pollutants under 5.4.1 or 5.4.2 of this General Introduction should be offered for transport as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., UN No. 3082 or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE , SOLID, N.O.S., UN No. 3077 under these entries in class 9 even though it is not listed by name in the appendices thereto.

7.1.5

Care should be exercised in the selection of the portion of the entry, which constitutes the proper shipping name of the dangerous goods. Portions of an entry not highlighted by capital letters need not be considered as part of the proper shipping name. When conjunctions such as, and or on are not capitalized or when capitalized segments of an entry are punctuated by commas the entire capitalized portion of the entry need not necessarily be shown as the proper shipping name on documentation or packages. This is the case particularly when a combination of several distinct entries is listed under a single UN Number.

7.1.5.1

For proper shipping names to be used for dangerous goods shipped as limited quant ties see 18.7 and 18.8 of this General Introduction.

7.1.6

Proper shipping names may end with the qualifying words SOLUTION or MIXTURE, if the conditions stated in sub-section 5.3 of this General Introduction are met.

7.1.7

Where it is not already included the qualifying word LIQUID or SOLID as appropriate should be added to the proper shipping name of a substance which due to the differing physical states of the various isomers of the substance could be either liquid or solid (see 5.1.10 of this General Introduction)

7.1.8

Where it is not already included the qualifying word MOLTEN should be added to the proper shipping name when a substance which is solid in accordance with the definition in 5.1.10 of this General Introduction is offered for trans-port in the molten state (e.g. ALKYLPHENOL, SOLID, N.O.S., MOLTEN).

7.1.9

If the proper shipping name of a substance that is transposed or offered for transport in a liquid state at a tempera-ture equal to or exceeding 100° C or in a solid state at temperatures equal to or exceeding 240° C does not convey the elevated temperature condition (for example by using the term MOLTEN or ELEVATED TEMPERATURE as part of the shipping name) the word HOT should immediately precede the proper shipping name on the transport document.

7.1.10

Proper shipping names may be used in the singular or plural as appropriate. Proper shipping names may be shown in plural where isomers of similar classification exist. Hydrates of inorganic substances may be included under the equivalent proper shipping name for the anhydrous substance as appropriate. In addition when qualifying words are used as part of the proper.

IMDG CODE - PAGE 0025 Amdt. 2896


shipping name their sequence on documentation or packages is optional Commercial or military names for goods of class 1 which contain the proper shipping name supplemented by additional descriptive text may be used.

7.1.11 Examples illustrating the selection of proper shipping names for such entries are:

1 UN No. 11 70 ETHANOL or ETHANOL SOLUTIONS

The proper shipping name is the most appropriate of the following possible combinations: ETHANOL ETHANOL SOLUTIONS ETHANOL SOLUTION 2

UN No. 2583 ALKYLSULPHONIC or ARYLSULPHONIC ACIDS , SOLID with more than 5% free sulphuric acid

The proper shipping name is the most appropriate of the following: ALKYLSULPHONIC ACIDS , SOLID ARYLSULPHONIC ACIDS, SOLID 3

UN No. 3207 ORGANOMETALLIC COMPOUND or COMPOUND SOLUTION or COMPOUND DISPERSION, WATER REACTIVE, FLAMMABLE, N.O.S.

The proper shipping name is the most appropriate of the following: ORGANOMETALLIC COMPOUND, WATER-REACTIVE, FLAMMABLE, N.O.S. * ORGANOMETALLIC COMPOUND SOLUTION, WATER-REACTIVE, FLAMMABLE, N.O.S. * ORGANOMETALLIC COMPOUND DISPERSION, WATER-REACTIVE, FLAMMABLE, N.O.S. * 7.1.12

Practical considerations prohibit the listing of all dangerous goods by name in this Code. Therefore many dangerous goods must be transported under one of the N.O.S. (not otherwise specified) or generic entries in this Code Due to the highly generic nature of certain of these entries neither the entry itself nor its corresponding UN Number can provide sufficient information about the dangerous goods to ensure that appropriate response action is initiated in the event of an incident involving the goods. Thus, for the purpose of documentation and marking of packages, these entries should be supplemented, in parentheses, with the additional information required by 7.1.14.

7.1.13

Entries in this Code for which this additional information is necessary are listed below HOWEVER THERE ARE OTHER ENTRIES FOR WHICH THIS ADDITIONAL INFORMATION IS REQUIRED THIS IS INDICATED IN THE INDIVIDUAL SCHEDULES.

* These entries should be supplemented in parentheses, with the additional information required by 7.1.14

IMDG CODE - PAGE 0026 (first of thirteen pages) Amdt. 29-98


UN No. Proper Shipping Name IMDG Code Page

0020 AMMUNITION, TOXIC 1210 0021 AMMUNITION, TOXIC 1210 0190 SAMPLES, EXPLOSIVE, other than initiating explosive 1134 0248 CONTRIVANCES, WATER-ACTIVATED 1250 0249 CONTRIVANCES, WATER-ACTIVATED 1250 0349 ARTICLES, EXPLOSIVE, N.O.S. 1218 0350 ARTICLES, EXPLOSIVE, N.O.S. 1211 0351 ARTICLES, EXPLOSIVE, N.O.S. 1212 0352 ARTICLES, EXPLOSIVE, N.O.S. 1213 0353 ARTICLES, EXPLOSIVE, N.O.S. 1216 0354 ARTICLES, EXPLOSIVE, N.O.S. 1217 0355 ARTICLES EXPLOSIVE, N.O.S. 1217 0356 ARTICLES EXPLOSIVE, N.O.S. 1217 0357 SUBSTANCES, EXPLOSIVE, N.O.S. 1139 0358 SUBSTANCES, EXPLOSIVE, N.O.S. 1139 0359 SUBSTANCES, EXPLOSIVE, N.O.S. 1139 0382 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1249 0383 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1249 0384 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1249 0461 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1249 0462 ARTICLES, EXPLOSIVE, N.O.S. 1212 0463 ARTICLES, EXPLOSIVE, N.O.S. 1213 0464 ARTICLES, EXPLOSIVE, N.O.S. 1214 0465 ARTICLES, EXPLOSIVE, N.O.S. 1215 0466 ARTICLES, EXPLOSIVE, N.O.S. 1212 0467 ARTICLES, EXPLOSIVE, N.O.S. 1213 0468 ARTICLES, EXPLOSIVE, N.O.S. 1214 0469 ARTICLES, EXPLOSIVE, N.O.S. 1215 0470 ARTICLES, EXPLOSIVE, N.O.S. 1212 0471 ARTICLES, EXPLOSIVE, N.O.S. 1214 0472 ARTICLES, EXPLOSIVE, N.O.S. 1215 0473 SUBSTANCES, EXPLOSIVE, N.O.S. 1135 0474 SUBSTANCES, EXPLOSIVE, N.O.S. 1136 0475 SUBSTANCES, EXPLOSIVE, N.O.S. 1137 0476 SUBSTANCES, EXPLOSIVE, N.O.S. 1138 0477 SUBSTANCES, EXPLOSIVE, N.O.S. 1136 0478 SUBSTANCES, EXPLOSIVE, N.O.S. 1138

IMDG CODE - PAGE 0026a (page 0026b follows) Amdt. 27-94



0479 SUBSTANCES, EXPLOSIVE, N.O.S. 1136 0480 SUBSTANCES, EXPLOSIVE, N.O.S. 1137 0481 SUBSTANCES, EXPLOSIVE, N.O.S. 1140 0482 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE, N.O.S. 1137 0485 SUBSTANCES, EXPLOSIVE, N.O.S. 1138 1078 REFRIGERANT GAS, N.O.S. 2176 1224 KETONES, LIQUID, N.O.S. 3248/3360 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIX-

TURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3135/3249/3361

1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 4146 1383 PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. 4255

1409 METAL HYDRIDES, WATER REACTIVE, N.O.S. 4354-1 1479 OXIDIZING SOLID, N.O.S. 5163 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 6056

1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6115 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 6141 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC,

N.O.S. 6142

1693 TEAR GAS SUBSTANCE, LIQUID or SOLID, N.O.S. 6262 1719 CAUSTIC ALKALI LIQUID, N.O.S. 8136 1759 CORROSIVE SOLID, N.O.S. 8151 1760 CORROSIVE LIQUID, N.O.S. 8147 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 8167 1953 COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. 2125-1 1954 COMPRESSED GAS, FLAMMABLE, N.O.S. 2124 1955 COMPRESSED GAS, TOXIC, N.O.S. 2125 1956 COMPRESSED GAS, N.O.S. 2124 1964 HYDROCARBON GAS, COMPRESSED, N.O.S. or HYDROCARBON GAS

MIXTURE, COMPRESSED, N.O.S. 2147

1965 HYDROCARBON GAS, LIQUEFIED, N.O.S. or HYDROCARBON GAS MIX-TURE, LIQUEFIED, N.O.S.

2147

1967 INSECTICIDE GAS, TOXIC, N.O.S. 2152 1968 INSECTICIDE GAS, N.O.S. 2152 1986 ALCOHOLS, TOXIC, N.O.S. 3104/3176/3303 1987 ALCOHOLS, N.O.S. 3103/3175/3303

IMDG CODE - PAGE 0026b (page 0026c follows) Amdt. 29-98



1988 ALDEHYDES, TOXIC, N.O.S. 3105/3178/3305 1989 ALDEHYDES, N.O.S. 3105/3177/3305 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 3127/3232/3346-1 1993 FLAMMABLE LIQUID, N.O.S. 3126/3230/3345 2003 METAL ALKYLS, N.O.S. or METAL ARYLS, N.O.S. 4243 2006 PLASTICS, NITROCELLULOSE-BASED, SELF-HEATING, N.O.S. 4252 2206 ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. 6166

2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S.

3130/3242

2571 ALKYLSULPHURIC ACIDS 8104 2588 PESTICIDE, SOLID, TOXIC, N.O.S. 6221 2693 BISULPHITES, AQUEOUS SOLUTION, N.O.S. 8126 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE,

CORROSIVE, N.O.S. 3106/3182-1/3306

2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQ-UID, CORROSIVE, FLAMMABLE, N.O.S.

8109-1

2735 AMINES, LIQUID CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S.

8109-2

2757 CARBAMATE PESTICIDE, SOLID, TOXIC 6221 2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than

23°C 3270

2759 ARSENICAL PESTICIDE, SOLID, TOXIC 6221 2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than

23°C 3270

2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 6221 2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less

than 23°C 3270

2763 TRIAZINE PESTICIDE, SOLID, TOXIC 6221 2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23°C 3270

IMDG CODE - PAGE 0026c (page 0026d follows) Amdt. 29-98



2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 6221 2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less

than 23° C 3270

2775 COPPER-BASED PESTICIDE, SOLID, TOXIC 6221

2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23° C

3270

2777 MERCURY-BASED PESTICIDE , SOLID, TOXIC 6221 2778 MERCURY-BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less

than 23° C 3270

2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC 6221 2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC,

flashpoint less than 23° C 3270

2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 6221 2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than

23° C 3270

2788 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 6221 2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint

less than 23° C 3270

2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 6221 2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE TOXIC, flashpoint less than 23°

C 3270

2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 6214 2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORRO-

SIVE, N.O.S. 8168

2810 TOXIC LIQUID, ORGANIC, N.O.S. 6270-1 2811 TOXIC , SOLID, ORGANIC, N.O.S. 6270-6 2818 WATER REACTIVE SOLID, N.O.S. 4368 2814 INFECTIOUS SUBSTANCES, AFFECTING HUMANS 6321 2845 PYROPHORIC LIQUID, ORGANIC, N.O.S. 4254 2846 PYROPHORIC SOLID, ORGANIC, N.O.S. 4255 2900 INFECTIOUS SUBSTANCES, AFFECTING ANIMALS only 6322 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6219 2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flashpoint not less than 23° C 6220

2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. 8148 2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. 8151

IMDG CODE - PAGE 0026d (page 0026e follows) Amdt. 29-98



2922 CORROSIVE LIQUID, TOXIC, N.O.S. 8149 2923 CORROSIVE SOLID, TOXIC, N.O.S. 8152 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 3126/3231/3346 2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. 4146-1 2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 4147 2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 6270-2 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 6270-7 2929 TOXIC LIQUID, FLAMMABLE ORGANIC, N.O.S. 6270-3 2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 6270-8 2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23° C 6220

2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 6219 2993 ARSENICAL PESTICIDE, LIQUID, TOXIC FLAMMABLE, flashpoint not less than 23° C 6220 2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6219 2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less

than 23° C 6220

2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6219 2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23° C 6220 2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6219 3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC FLAMMABLE, flashpoint not less than

23° C 6220

3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6219 3009 COPPER-BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than

23° C 6220

3010 COPPER-BASED PESTICIDE, LIQUID, TOXIC 6219

IMDG CODE - PAGE 0026e (page 0026f follows) Amdt. 29-98



3011 MERCURY-BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23° C

6220

3012 MERCURY-BASED PESTICIDE, LIQUID, TOXIC 6219 3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-

point not less than 23° C 6220

3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 6219 3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than

23° C 6220

3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6219 3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not

less than 23° C 6220

3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 6219 3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than

23° C 6220

3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6219 3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flashpoint less than 23° C c.c. 3270

3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23° C

3270

3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23° C

6220

3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 6219 3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6221 3049 METAL ALKYL HALIDES, N.O.S. or METAL ARYL HALIDES, N.O.S. 4243

3050 METAL ALKYL HYDRIDES, N.O.S. or METAL ARYL HYDRIDES, N.O.S. 4244

3071 MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S.

6173

3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 9029 3080 ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION,

TOXIC, FLAMMABLE, N.O.S. 6167

3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 9028 3084 CORROSIVE SOLID, OXIDIZING, N.O.S. 8153 3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 5164 3086 TOXIC SOLID, OXIDIZING, N.O.S. 6270-4 3087 OXIDIZING SOLID, TOXIC, N.O.S. 5165 3088 SELF-HEATING SOLID, ORGANIC, N.O.S. 4260 3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. 8153

IMDG CODE - PAGE 0026f (page 0026g follows)

Amdt. 27-94



3094 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. 8150 3095 CORROSIVE SOLID, SELF-HEATING, N.O.S. 8150 3096 CORROSIVE SOLID, WATER-REACTIVE, N.O.S. 8150 3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 5164 3099 OXIDIZING LIQUID, TOXIC, N.O.S. 5165 3101 ORGANIC PEROXIDE, TYPE B, LIQUID 5221 3102 ORGANIC PEROXIDE, TYPE B, SOLID 5222 3103 ORGANIC PEROXIDE, TYPE C, LIQUID 5223 3104 ORGANIC PEROXIDE, TYPE C, SOLID 5224 3105 ORGANIC PEROXIDE, TYPE D, LIQUID 5225 3106 ORGANIC PEROXIDE, TYPE D, SOLID 5226 3107 ORGANIC PEROXIDE, TYPE E, LIQUID 5227 3108 ORGANIC PEROXIDE, TYPE E, SOLID 5228 3109 ORGANIC PEROXIDE, TYPE F, LIQUID 5229 3110 ORGANIC PEROXIDE, TYPE F, SOLID 5230 3111 ORGANIC PEROXIDE, TYPE B, LIQUID, TEMPERATURE CONTROLLED 5231 3112 ORGANIC PEROXIDE, TYPE B, SOLID, TEMPERATURE CONTROLLED 5232 3113 ORGANIC PEROXIDE, TYPE C, LIQUID, TEMPERATURE CONTROLLED 5233 3114 ORGANIC PEROXIDE, TYPE C, SOLID, TEMPERATURE CONTROLLED 5234 3115 ORGANIC PEROXIDE, TYPE D, LIQUID, TEMPERATURE CONTROLLED 5235 3116 ORGANIC PEROXIDE, TYPE D, SOLID, TEMPERATURE CONTROLLED 5236 3117 ORGANIC PEROXIDE, TYPE E, LIQUID, TEMPERATURE CONTROLLED 5237 3118 ORGANIC PEROXIDE, TYPE E, SOLID, TEMPERATURE CONTROLLED 5238 3119 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED 5239 3120 ORGANIC PEROXIDE, TYPE F, SOLID, TEMPERATURE CONTROLLED 5240 3122 TOXIC LIQUID, OXIDIZING, N.O.S. 62704 3123 TOXIC LIQUID, WATER-REACTIVE, N.O.S. 62705 3124 TOXIC SOLID, SELF-HEATING, N.O.S. 62705 3125 TOXIC SOLID WATER REACTIVE N.O.S. 62705

IMDG CODE - PAGE 0026g (page 0026h follows)

Amdt. 27-94



3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. 4261 3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 4261 3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 4367 3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 4367 3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 4369 3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O S 4369 3134 WATER-REACTIVE SOLID TOXIC N.O.S. 4369 3139 OXIDIZING LIQUID, N.O.S. 5163 3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. 6056 3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 6141 3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC N.O.S. 6142 3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 6214

3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE SOLID CORROSIVE, N.O.S. 8168

3148 WATER-REACTIVE LIQUID, N.O.S. 4366 3156 COMPRESSED GAS OXIDIZING, N.O.S. 2125 3157 LIQUEFIED GAS, OXIDIZING, N.O.S. 2155-1 3158 GAS, REFRIGERATED LIQUID, N.O.S. 2142-1 3160 LIQUEFIED GAS, TOXIC FLAMMABLE, N.O.S. 21552 3161 LIQUEFIED GAS FLAMMABLE, N.O.S. 2155-1 3162 LIQUEFIED GAS, TOXIC N.O.S. 2155-2 3163 LIQUEFIED GAS, N.O.S. 2155 3172 TOXINS, EXTRACTED FROM LIVING SOURCES, N.O.S. 6270-1 3175 SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. 4173-1 3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 4146-2 3178 FLAMMABLE SOLID INORGANIC, N.O.S. 4146 3179 FLAMMABLE SOLID TOXIC, INORGANIC, N.O.S. 4147 3180 FLAMMABLE SOLID CORROSIVE, INORGANIC, N.O.S. 4146-1 3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE N.O.S. 4157-1 3182 METAL HYDRIDES, FLAMMABLE, N.O.S. 4157-1 3183 SELF HEATING LIQUID ORGANIC, N.O.S. 4259-1 3184 SELF HEATING LIQUID, TOXIC ORGANIC, N.O.S. 4259-2 3185 SELF-HEATING LIQUID, CORROSIVE ORGANIC, N.O.S. 4259-2 3186 SELF-HEATING LIQUID, INORGANIC, N.O.S. 4259-1 3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 42592 3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. 4259-2

IMDG CODE - PAGE 0026h (page 0026i follows)

Amdt. 29-98



3303 COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. 2125-3

3304 COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. 2125-1

3305 COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 2125-2

3306 COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2125-3

3307 LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. 2155-4

3308 LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. 2155-2

3309 LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 2155-3

3310 LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2155-4

3311 GAS, REFRIGERATED, LIQUID, OXIDIZING, N.O.S. 2142-2

3312 GAS, REFRIGERATED, LIQUID, FLAMMABLE, N.O.S. 2142-1

3319 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin , by mass 4161-2

3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTANS MIXTURE, LIQUID, FLAM-MABLE, N.O.S.

3134-2/3248-2/3360-2

3343 NITROGLYCER!N MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin , by mass

3138-3/3265-1/3369-1

3344 PENTAERYTHRITE TETRANITRATE MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN, by mass 4164

3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 6221

3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC flashpoint less than 23° C 3270

3347 PHENOXYACETIC ACID, DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE flashpoint not less than 23° C 6220

3348 PHENOXYACETIC ACID, DERIVATIVE PESTICIDE, LIQUID, TOXIC 6219

3349 PYRETHROID PESTICIDE, SOLID, TOXIC 6221

3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC flashpoint less than 23° C 3270

3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE flashpoint not less than 23° C 6220

3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 6219

3354 INSECTICIDE GAS, FLAMMABLE, N.O.S. 2152-1

3355 INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. 2152-1

IMDG CODE - PAGE 0026k (page 0026l follows) Amdt. 28-96


UN No. Proper Shipping Name IMDG Code

Page

PAGE RESERVED

IMDG CODE - PAGE 0026l (page 0027 follows) Amdt. 28-96


7.1.14

The additional information to be shown in documentation and on packages should be a recognized chemical name currently used in readily available scientific and technical handbooks, journals and texts. Trade names should not be used for this purpose In the case of pesticides the technical name which should supplement the proper shipping name should be the ISO common name, other name(s) listed in The WHO Recommended Classification of Pesti-cides by Hazard and Guidelines to Classification or the name of the active substance. For pesticides, the concen-tration of the active substance(s) should be included in the documentation accompanying the shipment.

7.1.14.1

When a mixture of dangerous goods is described by one of the N.O.S. or generic entries listed in the preceding pages, the inclusion in parentheses of this additional information for each constituent that contributes to the hazard of the mixture may result in such a lengthy description that marking the entire description on the packages be-comes impractical. In general not more than the two constituents which contribute most to the hazard of a mixture need be shown.

7.1.14.2

If a package containing a mixture bears a subsidiary risk label, one of the chemical names shown in parentheses should be the name of the constituent which leads to the use of the subsidiary risk label.

7.1.14.3

If a package contains a marine pollutant, the recognized chemical name (or in the case of pesticides, the ISO approved name) of the marine pollutant should always be shown.

7.2 Marking and labelling of packages

7.2.1 Marking of packages

7.2.1.1

Unless otherwise provided in this Code, each package containing dangerous goods should be durably marked with the proper shipping name (see subsection 7.1) of the contents, and, when assigned, the corresponding United Nations UN Number preceded by the letters "UN". In the case of unpackaged articles, the marking should be dis-played on the article, on its cradle or on its handling, storage or launching device.

7.2.1.2

A package containing a marine pollutant should also be durably marked with the MARINE POLLUTANT mark except:

1 packages containing marine pollutants in inner packagings with: - contents of 5 / or less for liquids, or - contents of 5 kg or less for solids, or 2 packages containing severe marine pollutants in inner packagings with: - contents of 0.5 / or less for liquids, or - contents of 500 g or less for solids. (See subsection 23.5 of this General Introduction)

7.2.1.3

The methods of marking as required in 7.2.1 on packages should be such that this information will still be identifi-able on packages surviving at least three months immersion in the sea. In considering suitable marking methods, account should be taken of the durability of the packaging materials used and of the surface of the package.

7.2.1.4 Each package containing dangerous goods packed into a container should be marked as specified in this Code.



7.2.2 Labelling of packages

7.2.2.1 Unless otherwise provided in this Code e.g. as provided in section 18 of this General Introduction, each package containing dangerous goods should be durably identified with distinctive label(s) or stencil(s) of the label(s) so as to make clear the dangerous properties of the goods. For goods of class1 in division 1.4, compatibility group S each package may alternatively be marked 1.4S.

7.2.2.2 A package containing a dangerous substance with a low degree of danger and identified as such on the individ-ual schedule may be exempt from these labelling requirements In these cases the individual schedules indicate that no hazard label is required. However, for certain substances, the package should be marked with appropri-ate text as indicated on the schedule. For example

Proper shipping name UN No. Class Mark required on package Hay* 1327 4.1 - Fishmeal 1374 4.2 Class 4.2 Batteries, wet, non-spillable 2800 8 Class 8 * No mark is required for the carriage of hay 7.2.2.3 The method of affixing the label(s) or applying stencil(s) of label(s) on packages containing dangerous goods

should be such that the label(s) or stencil(s) will still be identifiable on packages surviving at least three months' immersion in the sea. In considering suitable labelling methods account should be taken of the durability of the packaging materials used and the surface of the package.

7.2.2.4 Substances which possess subsidiary dangerous properties should where so prescribed in the individual sched-ule also bear the label denoting this hazard. In all cases, subsidiary risk labels should not bear the class number.

7.2.2.5 Substances of class 8 need not carry a subsidiary risk label of class 6.1 if the " toxicity" arises solely from the destructive effect on tissue.

7.2.2.6 Substances of class 5.2 need not carry a subsidiary risk label of class 8 if the corrosivity hazard level is packag-ing group III.

7.3 Placarding and marking of cargo transport units

7.3.1 General requirements 7.3.1.1 For the purposes of this subsection, a cargo transport unit is:

1 a road freight vehicle; 2 a railway freight wagon; 3 a freight container ; 4 a road tank vehicle; 5 a railway tank wagon; and 6 a portable tank.

7.3.1.2 Enlarged labels (placards) and if applicable, marks and signs, should be affixed to the exterior surfaces of a cargo transport unit to provide a warning that the contents of the unit are dangerous goods and present risks, unless the labels and/or marks affixed to the packages are clearly visible from the exterior of the unit.

IMDG CODE - PAGE 0028

Amdt. 28-96


9 DOCUMENTATION OF DANGEROUS GOODS SHIPMENTS1 9.1 When dangerous goods are offered for shipment similar documents to those required for other categories of goods have

to be prepared. The form of these documents the particulars to be entered on them and the obligations they entail may be fixed by international conventions applying to certain modes of transport and by national legislation.

9.2 One of the primary requirements of a shipping document for dangerous goods is to convey the fundamental information relative to the hazards of the goods. It is, therefore necessary to include certain basic information on the document for a consignment of a (the) dangerous good(s) unless otherwise exempted or regulated in this Code.

9.3 The basic items of information necessary for each dangerous substance, material or article offered for shipment are:

1 The proper shipping name (see subsection 7.1 of this General Introduction).

2 The class and, when assigned the division of the goods In addition this may be followed by the class name:

- For substances and articles of , the division should be followed immediately by the compatibility group and the stowage arrangement;

- For gases possessing subsidiary hazards the information should be further amplified to indicate these hazards by adding the word "flammable" , 'oxidizing agent' and/or 'corrosive ', as appropriate;

- For AEROSOLS (UN No. 1950) transported as limited quantities see 1882;

- For class 7 radioactive materials the class should be followed immediately by the words 'RADIOACTIVE MATE-RIAL', unless this already appears in the proper shipping name.

3 The UN Number shown for the dangerous goods in the IMDG Code, preceded by the letters "UN" (Not required for consignments identified as dangerous goods in limited quantities of class/classes ).

4 Where assigned, the packaging group.

5 For class 7 radioactive materials only the class 7 schedule number.

6 Empty packagings including portable tanks and bulk packagings which contain the residue of dangerous goods should be so indicated by placing the words "EMPTY UNCLEANED" or "RESIDUE - LAST CONTAINED " before or after the proper shipping name.

7 If waste dangerous goods (other than radioactive wastes) are being transported for disposal, or for processing for disposal, the proper shipping name should be preceded by the word "WASTE".

8 The number and kind of packages and the total quantity of dangerous goods covered by the description (by volume or mass, and in the case of goods of by the net explosives mass of the contents).

1 See also section 7 of this General Introduction



9.4.1 If the dangerous goods documentation is presented to the carrier by means of electronic data processing (EDP) or electronic data interchange (EDI) transmission techniques the signature(s) may be replaced by the name(s) (in capi-tals) of the person authorized to sign.

9.5 The text of the above declaration, and the special information relative to the hazards of the goods to be carried (as in 9.3 above) should be incorporated into, or combined with, an existing transport or shipping document. The layout of the information on the document (or the order of transmission of the corresponding data by electronic or other auto-matic data processing (EDP) or electronic data interchange (EDI) techniques) should be as in 9.3.

9.6 When an existing transport or shipping document or cargo handling form cannot be used for the purposes of danger-ous goods documentation for multimodel transport a specimen declaration form has been prepared (see 9.11)*, which is suitable for use where the declaration is made on a separate document. It is not the intention to require a separate shipping document for dangerous goods when a shipment contains both dangerous and non-dangerous goods, or to restrict the number of individual descriptions that may appear on a single document. However if both dangerous and non-dangerous goods are listed on one document the dangerous goods should be listed first, or otherwise empha-sized.

9.7 Special information

9.7.1 Special information is required: 1 for goods of (see section 2 of the introduction to ); 2 for self reactive substances in class 4.1 exempted from displaying a subsidiary risk label of (see 6.1 of the intro-

duction to class 4.1);

3 for certain organic peroxides exempted from displaying a subsidiary risk label of (see 5.1.1 of the introduction to class 5.2);

4 for infectious substances (see introduction to class 6.2); 5 for radioactive materials (see section 8 of the introduction to class 7). 9.7.2 In certain circumstances special certificates are required, such as: 1 a container packing certificate (see 12.3.7 of this General Introduction); 2 a vehicle declaration (see 17.7.7 of this General Introduction); 3 a weathering certificate as required in the individual schedules; 4 a certificate exempting a substance, material or article from the provisions of the IMDG Code (e.g. see individual

entries for charcoal, fishmeal, seed cake);

5 for new self-reactive substances and organic peroxides or new formulations of currently assigned self-reactive substances and organic peroxides, a statement by the competent authority of the country of origin of the approved classification and conditions of carriage.

9.8 When packages containing dangerous goods are packed into a unit, e.g. freight container flat trailer or other vehicle intended for carriage by sea those responsible for the packing of the unit should provide a certificate or declaration in accordance with 12.3.7 or 17.7.7 of this General Introduction as appropriate. The container/vehicle/unit identification number(s) should also be indicated.

* The layout of this form complies with the recommendations contained in the Trade Data Elements Directory issued by the UN/ECE Working Party on Facilitation of International Trade Procedures (United Nations publication ECE/ TRADE/200) in particular Recommendation No.1 (United Nations Lay-out Key for Trade Documents) (ECE/TRADE/ 137, edition 82.2) and Recommendation No.11 (Documentary Aspects of the Interna-tional Transport of Dangerous Goods) (ECE/TRADE/204 edition 96.1).



9.9 Documentation of cargo transport units under fumigation

9.9.1 Transport documents associated with the carriage of cargo transport units under fumigation should show the date of fumigation and the type and amount of the fumigant used. In addition instructions for disposal of a residual fumigant, including fumigation devices (if used), should be provided.

9.10 Documentation required on board the ship

9.10.1 Each ship carrying dangerous goods or marine pollutants should have a special list or manifest setting forth, in ac-cordance with regulation 5 of chapter VII of the International Convention for the Safety of Life at Sea 1974 as amended, and with regulation 4 of Annex III of the International Convention for the Prevention of Pollution from Ships 1973, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78), the dangerous goods and their location. This dangerous goods or marine pollutants list or manifest should be based on the documentation and certification required in this Code and should at least contain, in addition to the information set forth in 9.3, the stow-age location of these goods.

9.10.2 For consignments of dangerous goods, appropriate information should be immediately available at all times for use in emergency response to accidents and incidents involving dangerous goods in transport. The information should be available away from packages containing the dangerous goods and immediately accessible in the event of an incident. Methods of compliance include:

1 appropriate entries in the special list manifest or dangerous goods declaration; or

2 provision of a separate document such as a safety data sheet; or

3 provision of a separate document such as the Emergency Procedures for Ships Carrying Dangerous Goods (EmS) and Medical First Aid Guide for Use in Accidents Involving Dangerous Goods (MFAG) for use in conjunc-tion with the transport document.



9.11 Example of a form which may be used as a combined transport document and container packing certificate for the multimodal transport of dangerous goods [new table].

MULTIMODAL DANGEROUS GOODS FORM

This form may be used as a dangerous goods declaration as it meets the requirements of SOLAS 74, chapter VII, regulation 5, MARPOL 73/78, Annex III, regulation 4 and section 9 of the General introduction to the IMDG Code.

1. Shipper/Consignor/Sender 2. Transport document number 3. Page 1 of ___ pages 4. Shipper's reference

5. Freight forwarders reference 6 Consignee 7. Carrier (to be completed by the carrier)

SHIPPER'S DECLARATION I hereby declare that the contents of this consignment are fully and accurately described below by the proper shipping name and are classified packaged marked and labelled/placarded and are in all respects in proper condition for transport according to the applicable international and national government regulations.

8. This shipment is within the limitations prescribed for (Delete non-applicable)

9. Additional handling information

PASSENGER AND CARGO AIRCRAFT

CARGO AIRCRAFT ONLY

10. Vessel/flight no and date 11. Port/place of loading

12. Port/place of discharge 13. Destination

14. Shipping marks * Number and kind of packages description of goods Gross mass (kg) Net mass Cube (m3)

15. Container identification no. / vehicle registration no.

16. Seal number(s) 17. Container/vehicle size & type

18. Tare mass (kg)

19. Total gross (including tare) (kg)

CONTAINER/VEHICLE PACKING CERTIFICATE 21. RECEIVING ORGANIZATION RECEIPT I hereby declare that the goods described above have been packed/loaded into the container/vehicle identified above in accordance with the applicable provisions ** MUST BE COMPLETED AND SIGNED FOR ALL CON-TAINER/VEHICLE LOADS BY PERSON RESPONSIBLE FOR PACKING/LOADING.

Received the above number of packages/containers/trailers in apparent good order and condition unless stated hereon RECEIVING ORGANISA-TION REMARKS.

Haulier's name 20. Name of company

Vehicle reg. no.

22. Name of company (OF SHIP-PER, PREPARING THIS NOTE)

Name/status of declarant Name/status of declarant

Place and date

Signature and date

Place and date

Signature of declarant DRIVER'S SIGNATURE Signature of declarant

* DANGEROUS GOODS

You must specify proper shipping name hazard class UN No., Packaging group (where assigned). Marine pollutant and observe the mandatory requirements under applicable national and international governmental regulations. For the pur-poses of the IMDG Code see paragraph 9.3. For the purposes of the IMDG Code see paragraphs 12.3.7 or 17.7.7.

IMDG CODE - PAGE 0039 (page 0039a follows) Amdt. 29-98


IMDG CODE - PAGE 0039 (page 0039a follows) Amdt 29-98


Documentary aspects of the international transport of dangerous goods

Container/Vehicle Packing Certificate (Box 20)

The signature given in Box 20 must be that of the person controlling the container/vehicle operation.

It is certified that.

The container/vehicle was clean dry and apparently fit to receive the goods.

If the consignments include goods of other than division 1.4 the container is structurally serviceable in con-formity with section 12 of the introduction to of the IMDG Code.

No incompatible goods have been packed into the container/vehicle unless specially authorized by the Competent Authority.

All packages have been externally inspected for damage and only sound packages packed.

Drums have been stowed in an upright position unless otherwise authorized by the Competent Authority.

All packages have been properly packed and secured in the container/vehicle.

When materials are transported in bulk packagings the cargo has been evenly distributed in the container/ vehicle.

The packages and the container/vehicle have been properly marked labelled and placarded Any irrelevant marks labels and placards have been removed.

When solid carbon dioxide (CO2 - dry ice) is used for cooling purposes the vehicle or freight container is externally marked or labelled in a conspicuous place e. g. at the door end with the words DANGEROUS CO2 GAS (DRY ICE) INSIDE - VENTILATE THOROUGHLY BEFORE ENTERING.

When this Dangerous Goods Form is used as a container/vehicle packing certificate only not a combined document a dangerous goods declaration signed by the shipper or supplier must have been issued/received to cover each dangerous goods consignment packed in the container.

Note: The container packing certificate is not required for tanks

IMDG CODE - PAGE 0039b (page 0040 follows) Amdt. 29-98


10 PACKING

10.1 The types of packages and packagings recommended in this Code are those which, based on extensive past ex-perience, ensure a high degree of safety.

10.2 Detailed specifications and a number of performance tests applicable to a wide range of packagings recommended in this Code are to be found in Annex I to this Code.

10.2.1 Dangerous goods of all classes other than classes 1, 2, 6.2 and 7 have for packing purposes been apportioned among three categories (packaging groups) according to the degree of danger they present great danger (packaging group I), medium danger (packaging group II) and minor danger (packaging group III). The packaging group to which a substance is assigned is given in the individual schedule.

10.2.2 Performance tests should be made on packagings representative of those to be used in commercial practices. A packaging destined to contain a dangerous substance with a low degree of danger, and identified as such in the individual schedule, may be exempt from the packaging performance tests.

10.2.3 Suitable evidence must be established and kept to enable the fact that the tests have been passed successfully to be verified.

10.2.4 Each packaging manufactured and intended for use according to this Code should bear the markings specified in section 6 of Annex I to this Code.

10.3 Equivalences

In order to take into account progress in science and technology, there is no objection to the use of packagings having specifications different from those recommended in this Code, provided that they are at least equally effective acceptable to authorities concerned and able successfully to withstand the tests described in Annex I to this Code. Moreover, methods of testing, other than those described in Annex I to this Code, are acceptable provided that they be at least equally effective.

10.4 The strength of packagings should be such that they will retain their contents and keep them free from contamination under the normal conditions of carriage by sea.

10.5 Parts of packagings which are in direct contact with dangerous substances should not be affected by chemical or other action of those substances. Where necessary, they should be provided with a suitable inner coating or treat-ment. Such parts of packagings should not incorporate constituents liable to react dangerously with the contents so as to form hazardous products or to weaken them significantly.

10.5.1 Cushioning and absorbent material should be inert and suited to the nature of the contents.

10.6 Particular recommendations in respect of certain packaging materials and specifications are dealt with in detail in the separate classes.



12 CONTAINER TRAFFIC

12.1 Applicability and definitions

12.1.1 For the purposes of this section, a 'container' is a freight container used for the transport of packaged dangerous goods, a bulk packaging for solid dangerous goods or a portable tank used for the transport of liquid and solid dangerous substances, non-refrigerated liquefied gases and refrigerated liquefied gases. For the transport of solid dangerous goods in bulk packagings see also section 25 of this General Introduction. The requirements for port-able tanks are given in section 13.

12.1.2 For the purposes of this Code, freight container means an article of transport equipment that is of a permanent character and accordingly strong enough to be suitable for repeated use, specially designed to facilitate the trans-port of goods, by one or more modes of transport, without intermediate reloading and designed to be secured and/or readily handled having fittings for these purposes. The term freight container includes neither vehicle nor packaging. However a container that is carried on a chassis is included.

12.1.3 Freight containers used for the transport of packaged dangerous goods or as bulk packagings for solid dangerous goods should be of adequate strength to resist the possible stress imposed by the conditions of the services in which they are employed and they should be adequately maintained. They should be approved in accordance with the International Convention for Safe Containers (CSC), 1972, as amended when applicable.

12.1.3.1 The International Convention for Safe Containers does not apply to offshore containers that are handled in open seas. The design and testing of offshore containers should take into account the dynamic lifting and impact forces that may occur when a container is handled in open seas in adverse weather and sea conditions. The requirement for such containers should be determined by the approving competent authority. Such requirements should be based on MSC/Circ.860 Guidelines for the approval of offshore containers handled in open seas. Such containers should be clearly marked with the words OFFSHORE CONTAINER on the safety approval plate.

12.1.4 Closed freight container means a freight container which totally encloses the contents by permanent structures. Freight containers with fabric sides or tops are not closed freight containers for the purposes of this section.

12.1.5 Open freight container means a freight container which is not a closed freight container.

12.1.6 Container space means a distance not less than 6 metres (20 feet) fore and aft or not less than 2.4 metres (8 feet) athwartship. This distance may be occupied by a container or containers containing non-dangerous materials.

12.1.7 Cellular ship means a ship in which containers are loaded under deck into specially designed slots giving a perma-nent stowage of the container during sea transport. Containers loaded on deck in such a ship are specially stacked and secured on fittings.



12.1.8 In relation to this section, the terms listed hereafter should be interpreted as described hereafter:

1 Packagings and packages refer to receptacles for dangerous goods and to receptacles containing dangerous goods respectively;

2 Packing and unpacking refer to the placing of packages containing dangerous goods into a freight container and their removal therefrom.

12.2 Permitted shipments

12.2.1 Dangerous goods which have to be segregated from each other should not be carried in the same freight container However, dangerous goods which should be segregated «AWAY FROM» each other may be carried in the same freight container with the approval of the competent authority. In such cases an equivalent standard of safety must be maintained.

12.2.2 Dangerous goods should only be transported in freight containers when they are packaged in accordance with section 10 of this General Introduction.

12.3 Freight container packing and certification

12.3.1 Packages containing dangerous substances and any other goods should be tightly packed within the freight con-tainer or adequately braced and secured for the voyage. The packages should be packed in such a way that there will be a minimum likelihood of damage to fittings during transport. Such fittings on packages should be adequately protected.

12.3.2 When a dangerous goods consignment forms only part of the load of a freight container , it should preferably be packed so as to be accessible from the doors of the freight container .

12.3.2.1 If container doors are locked, the means of locking should be such that, in case of emergency, the doors can be opened without delay (See IMO/ILO Guidelines for Packing Cargo in Freight Containers or Vehicles in the Sup-plement to this Code).

12.3.3 The requirements set out in section 9 of this General Introduction with respect to the documentation of packaged dangerous goods and freight containers used as bulk packagings for dangerous goods should be met.

12.3.4 Freight containers into which dangerous goods are to be packed should be examined visually for damage and if there is evidence of material damage the freight container should not be packed.

12.3.5 Irrelevant markings, labels, placards, orange panels and marine pollutant marks should be removed before pack-ing a freight container .

12.3.6 Packages should be examined and any found to be damaged, leaking or sifting should not be packed into a freight container . Care should be taken to see that excessive water, snow, ice or foreign matter adhering to packages is removed before packing into a freight container .



12.3.7 Those responsible for the packing of the dangerous goods into a freight container should provide a "container pack-ing certificate" certifying that this has been properly carried out and embodying the following provisions*:

-The freight container was clean, dry and apparently fit to receive the goods;

-If the consignments include goods of , other than division 1.4, the freight container is structurally serviceable in conformity with section 12 of the introduction to of the IMDG Code;

-Goods which should be segregated have not been packed together in the freight container , unless approved by the competent authority concerned in accordance with 12.2.1;

-All packages have been externally inspected for damage and only sound packages have been packed;

-Drums have been stowed in an upright position, unless otherwise authorized by the competent authority;

-All packages have been properly packed in the freight container and secured;

-When dangerous goods are transported in bulk packagings the cargo has been evenly distributed in the freight container ;

-The freight container and the packages therein are properly marked, labelled and placarded;

-When solid carbon dioxide (dry ice) is used for cooling purposes, the freight container is externally marked or la-belled in a conspicuous place at the door end, with the words "DANGEROUS CO2 GAS (DRY ICE) INSIDE, VENTI-LATE THOROUGHLY BEFORE ENTERING";

-The dangerous goods declaration required in subsection 9.4 of the General Introduction to the International Mari-time Dangerous Goods Code (IMDG Code) has been received for each dangerous goods consignment packed in the freight container .

The functions of the documents required in 12.3.3 and 12.3.7 above may be incorporated into a single document, if not, it may be desirable to attach these documents one to the other. If these functions are incorporated into a single document, e.g. a dangerous goods declaration, a shipping note, etc., the inclusion of a phrase such as "It is declared that the packing of the freight container has been carried out in accordance with the provisions of 12.3.7 of section 12 of the General Introduction to the IMDG Code" may suffice.

Note: The container packing certificate is not required for tanks.

12.3.8 The special dangerous goods list or manifest (required by regulation 5.3 of part A of chapter VII of the International Convention for the Safety of Life at Sea, 1974, as amended (and by regulation 4 (3) of Annex III of the International Convention for the Prevention of Pollution from Ships, 1973, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78)) and/or a cargo plan should indicate clearly those containers in which dangerous goods are loaded and their location aboard the ship. The total quantity of each dangerous substance, in addition to the description as required under the above regulation, should also be shown in the list, manifest and/or cargo plan.

* See also MSC/Circ. 506/Rev.1 of 10 January 1990 on container packing certificates and vehicle packing declarations (see the Supplement to this Code).



12.4 Marking, labelling and placarding*

12.4.1 Each package containing dangerous goods packed into a freight container should be marked and labelled in accor-dance with the requirements of sections 7 and 8 of this General Introduction.

12.4.2 Marking and placarding of freight containers containing packaged dangerous goods or used as bulk packagings for dangerous goods should be carried out in accordance with the requirements of sections 7 and 8 of this General Introduction.

12.5 Stowage of containers on board ships 12.5.1 Containers should be examined for external signs of damage leakage or sifting of contents. Any container found to

be damaged leaking or sifting should not be accepted for shipment until repairs have been effected or damaged receptacles removed.

12.5.2 The following requirements should apply for the stowage of containers on board ships:

1 A container packed or loaded with flammable gases or liquids having a flashpoint below 23°C c.c. should only be stowed under deck together in the same cargo space with refrigerated or heated containers the coolant or heating equipment of which could provide a possible source of ignition if

-the coolant compartment and the cooling or heating equipment of the cargo transport units comply with 21.4; and

-the design construction and equipment of the cargo space complies with the requirements of regulation II-2/54 of SOLAS 1974 as amended;

-otherwise the stowage is restricted to on deck only.

2 A temperature controlled container packed or loaded with flammable gases or liquids having a flashpoint below 23°C c.c. should only be stowed under deck if the requirements under 1 above are met otherwise the stowage is restricted to on deck only.

3 A container packed or loaded with flammable gases or liquids having a flashpoint below 23°C c.c. carried on deck should be stowed away from (as defined in 15.2 of this General Introduction) possible sources of ignition.

12.5.3 Where stowage is permitted on deck or under deck containers packed or loaded with marine pollutants should pref-erably be stowed under deck except when a weather deck provides equivalent protection.

12.5.4 Where stowage on deck only is required preference should be given to the stowage of containers packed or loaded with marine pollutants on well protected decks or to the stowage inboard in sheltered areas of exposed decks.

12.5.5 Containers should be secured in accordance with SOLAS, Chapter VII, regulation 6.6 - Cargo Securing Manual (See MSC/Circ.745 on the Guidelines for the Preparation of the Cargo Securing Manual in the Supplement to this Code).

* For containers under fumigation see subsection 3.5 of the IMO publication Recommendations on the Safe Use of Pesticides in Ships (See the Supplement to this Code).



13 PORTABLE TANKS AND ROAD TANK VEHICLES

13.1 GENERAL REQUIREMENTS FOR PORTABLE TANKS AND ROAD TANK VEHICLES FOR DANGEROUS SUBSTANCES OTHER THAN CLASS 2

13.1.1 Preamble

13.1.1.1 The requirements of this subsection apply to portable tanks and road tank vehicles intended for the transport of dangerous substances except for those of class 2, by sea. In addition to these requirements, or unless otherwise specified, the applicable requirements of the International Convention for Safe Containers (CSC) 1972 as amended, should be fulfilled by any tank which meets the definition of a container within the terms of that Con-vention. The International Convention for Safe Containers does not apply to offshore tank-containers that are handled in open seas. The design and testing of offshore tank-containers should take into account the dynamic lifting and impact forces that may occur when a tank is handled in open seas in adverse weather and sea condi-tions. The requirements for such tanks should be determined by the approving competent authority (see also MSC/Circ.613 in the annex at the end of this section). Such requirements should be based on MSC/Circ.860 Guidelines for the approval of offshore containers handled in open seas.

13.1.1.2 Attention is drawn to the fact that no requirements have been included in respect of any additional fire-fighting equipment which may be necessary on ships transporting these tanks.

13.1.1.3 In order to take into account progress in science and technology, the use of alternative arrangements may be considered where these offer at least equivalent safety in use in respect of compatibility with the properties of the substances transported and equivalent or superior resistance to impact, loading and fire.

13.1.1.4 The appendix to this subsection comprises the list of dangerous substances showing the particular requirements which modify or supplement these general requirements for each particular substance. The appendix will need updating from time to time in the light of technical progress and to include new substances.

13.1.1.4.1 In general, where a substance has not been allocated a UN Number, it should be carried under the most suitable N.O.S. entry. However, the competent authority of the country of origin may issue interim approvals for shipment of substances not listed in the appendix to this subsection to which individual UN Numbers have already been assigned. The approval should accompany the shipment concerned and contain at a minimum the information normally provided in the list of substances and the conditions under which the particular substance should be carried. The approval should contain a note to the effect that this competent authority has undertaken action to include this substance in the appendix to subsection 13.1.

13.1.1.4.2 Solid dangerous substances which do not appear on the list in the appendix to this section but which may be transported in portable tanks in accordance with paragraphs 13.1.28.2.1 and 13.1.28.2.3 are not subject to ap-proval by the competent authority of the country of origin as provided for in paragraph 13.1.1.4.1 in general. However, in the particular case provided for in paragraph 13.1.28.2.3 it is necessary to obtain competent author-ity approval but it is not necessary for that approval to contain a note to the effect that the competent authority has undertaken action to include this substance in the appendix to subsection 13.1.

13.1.1.5 These requirements do not apply to rail tank-wagons (except for materials of class 7), non-metallic tanks, tanks intended for the transport of liquids having a capacity of 450 litres or less, and tanks for substances of class 2.



13.1.2 Definitions 13.1.2.1 For the purposes of these requirements.

13.1.2.2 Portable tank means a tank having a capacity of more than 450 litres whose shell is fitted with items of service equipment and structural equipment necessary for the transport of dangerous substances whose vapour pressure is not more than 3 bar (absolute) at a temperature of 50° C. It is a tank that has stabilizing members external to the shell and is not permanently secured on board the ship Its contents should not be loaded or discharged while the tank remains on board. It should be capable of being loaded and discharged without the need of removal of its structural equipment and be capable of being lifted on and off the ship when loaded.

NOTES:

1 Portable tanks being in conformity with the requirements of this section are not considered to be intermediate bulk containers (IBCs);

2 IBCs being in conformity with the requirements of section 26 of this General Introduction are not considered to be portable tanks.

13.1.2.3 Shell means the tank proper including openings and their closures but does not include service equipment (see 13.1.2.4).

13.1.2.4 Service equipment of a shell means filling and discharge venting safety heating and heat insulating devices and measuring instruments.

13.1.2.5 Structural equipment means the reinforcing fastening protective or stabilizing members of the shell.

13.1.2.6 Maximum allowable working pressure means a pressure that is not less than the higher of the following two pres-sures measured at the top of the tank while in operating position:

1 The highest effective pressure allowed in the shell during filling or discharge; or

2 the maximum effective gauge pressure to which tanks for liquids should be designed which is the sum of the following partial pressures minus 1 bar;

2.1 The vapour pressure (in bar) at 65° C; and

2.2 the partial pressure (in bar) of air or other gases in the ullage space being determined by a maximum ullage temperature of 65° C and a liquid expansion due to the increase of the bulk mean temperature of tr - tf (tf - filling temperature usually 15° C, t - 50° C the maximum mean bulk temperature).

13.1.2.7 Test pressure means the maximum gauge pressure at the top of a tank during a hydraulic test.

13.1.2.8 Design pressure means the pressure used according to a recognized pressure vessel code as mentioned in 13.1.3.11 for the design of every element of the tank.

The design pressure should never be less than the highest of the following three pressures:

1 the working pressure as given in 13.1.2.6.1; or

2 the sum of the pressure as given in 13.1.2.6.2 and the dynamic head pressure determined on the basis of the dynamic forces due to inertia specified in 13.1.4.1 minus 1.0 bar such a dynamic head pressure should never be taken to be less than 0.35 bar; or

3 the required test pressure divided by 1.5.



13.1.3.11 Tanks should be designed manufactured and tested in accordance with a recognized pressure vessel code taking into account the design pressure as defined in 13.1.2.8.

13.1.3.12 Tanks should be of a design capable of being stress analysed mathematically or experimentally by resistance strain gauges or by any other acceptable method.

13.1.3.13 Tanks should be designed and manufactured to withstand a test pressure equal to at least 1.5 times the maxi-mum allowable working pressure. However the test pressure should never be lower than 1.5 bar. Specific re-quirements are laid down for various substances authorized to be carried in tanks in the appendix to this subsec-tion. Attention is also drawn to the minimum shell thickness requirements specified in 13.1.5.1 to 13.1.5.8.

13.1.3.14 Tanks without vacuum relief valves should be designed to withstand an external pressure at least 0.4 bar above the internal pressure. Tanks equipped with vacuum relief valves should be designed to withstand an external overpressure of 0.21 bar or greater and should have their vacuum relief valve set to relieve at minus (-) 0.21 bar except that a greater negative setting may be utilized provided the external design pressure is not exceeded. All vacuum relief valves used on tanks for the transport of liquids with flashpoints below 61° C (c.c.) should be equipped with a flame trap.

13.1.3.15 Tanks intended to contain certain dangerous substances should be provided with additional protection which may take the form of additional thickness of the shell or a higher test pressure the additional thickness or higher test pressure being determined in the light of the dangers inherent in the substances concerned. The requirements for each substance are given in the list in the appendix to this subsection.

13.1.4 Design criteria

13.1.4.1 Tanks and their fastenings should under the maximum permissible load be capable of absorbing the following dynamic forces:

1 in the direction of travel twice the total mass;

2 horizontally at right angles to the direction of travel the total mass (where the direction of travel is not clearly determined the maximum permissible load should be equal to twice the total mass);

3 vertically upwards the total mass; and

4 vertically downwards twice the total mass (total loading including the effect of gravity).

13.1.4.2 Under each of these loads the safety factors to be observed for the primary combined stress should be as fol-lows:

1 for metals having a clearly defined yield point a safety factor of 1.5 in relation to the determined yield stress; or

2 for metals with no clearly defined yield point a safety factor of 1.5 in relation to the guaranteed 0.2% (1.0% for austenitic steels) proof stress.

Note: The above loads do not give rise to an increase in the pressure in the vapour space.



13.1.4.3 At the test pressure the membrane stress in the shell should conform to the material-dependent limitations pre-scribed below:

1 for metals and alloys exhibiting a clearly defined yield point or characterized by a guaranteed conventional yield stress Re (generally 0.2% proof stress, for austenitic steels 1.0% proof stress) the membrane stress should not exceed 0.75Re or 0.50Rm, whichever is lower;

2 In the case of steel, the elongation at fracture in per cent should not be less than 10000/Rm, where Rm is in N/mm2, with an absolute minimum of 20% based on a standard gauge length of 50 mm In the case of alumin-ium, the elongation at fracture, in per cent should not be less than 10000/6Rm, where Rm is in N/mm2 with an absolute minimum of 12%.

13.1.4.4 The specimens used to determine the elongation at fracture should be taken transversely to the direction of rolling and be so secured that,

dL0 5=

or

where

Lo = gauge length of the specimen before the test; d = diameter; and A = cross-sectional area of the test specimen.

13.1.5 Minimum shell thickness

13.1.5.1 The minimum shell thickness referred to in this subsection may be used only if design criteria calculations do not indicate that a greater thickness is required.

13.1.5.2 The cylindrical portions and ends of tanks should have a thickness of not less than that determined by the follow-ing formula*.

3 ARmCe

×=

where e = minimum required thickness of the metal to be used, in mm; Rm = guaranteed minimum tensile strength of the metal to be used, in N/mm2 ; A = guaranteed minimum elongation (as a percentage) of the metal to be used on fracture under

tensile stress, see 13.1.4.3; C = 107 (equivalent to 5 mm mild steel) for tanks intended for the transport of powdery or granu-

lar solid substances and for tanks of not more than 1.80 m in diameter intended for the trans-port of liquids or

C = 128 (equivalent to 6 mm mild steel) for tanks of more than 1.80 m in diameter.

* The constant C is derived from the following formula 33000 ARmeARme ×=× , where the sub-index 'o' refers to

mild steel and the part of the equation without sub-index 'o' refers to the metal used. The relationship with mild steel as employed by this Code is attached to the constant C where 3

000 ARmeC ×= .


A.L 655O =


13.1.1.9.3 The shell and items of equipment of each tank should be inspected and tested either together or separately first before being put into service (initial inspection and test) and thereafter at no more than five year intervals (peri-odic inspection and test). The initial inspection and test should include a check of the design characteristics an internal and external examination and a hydraulic pressure test. If the shell and equipment have been pressure tested separately they should together be subjected after assembly to a leakage test. The periodic inspections and tests should include an internal and external examination and as a general rule a pressure test:

1 Sheathing thermal insulation and the like should be removed only to the extent required for reliable appraisal of the tanks condition. The initial and periodic pressure tests should be carried out by the competent authority at the test pressure indicated on the data plate of the tank except in cases where periodic tests at lower test pressures are authorized;

2 The tank should be inspected for corroded areas dents or other conditions which indicate weakness that might render the tank unsafe in transport and while under pressure for leakage. If any evidence of such unsafe condition is discovered the tank should not be placed in or returned to service until it has been repaired and the test repeated has been passed.

13.1.1.9.4 Before tanks are put into service and thereafter at intervals midway between the five yearly inspection and tests specified in 13.1.1.9.3 the following tests and inspections should be performed:

1 a leakage test where required;

2 a test of satisfactory operation of all service equipment; and

3 an internal and external inspection of the tanks and their fittings with due regard to the substances trans-ported.

13.1.1.9.5 The 2.5 year (midway) inspection and test may be carried out within 3 months of the specified date. The date of the 2.5 year inspection should be durably marked on or as near as possible to the metal identification plate re-quired in 13.1.20.1. When marking is not done on the plate the characters should be at least 32 mm in height and of a contrasting colour to the tank.

13.1.19.6 The 2.5 year internal inspections may be waived or substituted for by other test methods by the competent au-thority in the case of tanks intended for dedicated transport. A portable tank may not be filled and offered for transport after the date of expiry of the last 5 year or 2.5 year periodic inspection and test as required by 13.1.19.3 and 13.1.19.4/13.1.15.3 and 13.1.15.4/13.2.13.3 and 13.2.13.4. However a portable tank filled prior to the date of expiry of the last periodic inspection and test may be transported for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection In addition a portable tank may be trans-ported after the date of expiry of the last periodic test and inspection:

1 After emptying but before cleaning, for purposes of performing the next required test and inspection prior to refilling; and

2 Unless otherwise approved by the competent authority for a period not to exceed six months beyond the date of expiry of the last periodic test and inspection in order to allow the return of dangerous goods for proper disposal or recycling. Reference to this authorization should be entered in the dangerous goods shipping document.

13.1.19.7 When the tank is damaged it should be so repaired as to comply with these recommendations.



13.1.19.8 In all cases where cutting burning or welding operations on the shell of the tank have been effected that work should be to the approval of the competent authority and a hydrostatic test to at least the original test pressure should be carried out.

13.1.19.9 The certificate and the test report required under 13.1.19.1 and the certificate showing the results of the initial hydrostatic test for each tank issued by the competent authority or its approved inspecting agency should be retained by the authority or agency and the owners during the time the tank is in service. As a minimum the cer-tificate issued under 13.1.19.1 should provide the information required in 13.1.20.1.

IMDG CODE - PAGE 0072a (page 0073 follows) Amdt. 29-98


(This page intentionally blank)


13.1.20 Marking 13.1.20.1

Every tank should be fitted with a corrosion resistant metal plate permanently attached in a place readily accessible for inspection. At least the following particulars should be marked on the plate in characters at least 3 mm in height by stamping engraving embossing or any similar method. If for reasons of tank ar-rangements the plate cannot be permanently attached to the shell the shell should be marked with at least those particulars required by a recognized pressure vessel code in a manner prescribed by that code.

The plate should be kept free of paint to ensure that the markings will be legible at all times.

Country of manufacture

IMO tank type no Approval country Approval number

Manufacturers name or mark

Registration number

Year of manufacture

Test pressure (bar) / (MPa)*

Maximum allowable working pressure (bar) / (MPa)*

Water capacity at 20 ° C (litres)

(The water capacity should be established to within 1% by practical test rather than by calculation)

Maximum gross mass (kg)

Original hydrostatic test date and witness identification

Code to which tank is designed

Metallurgic design temperature (only if above+ 50 ° C or below -20 ° C)

Maximum allowable working pressure for coils (where coils used) (bar) / (MPa)*

Tank material

Equivalent thickness in mild steel (mm)

Lining material (if any)

Capacity of each compartment (in compartmented tanks) (litres)

Month year and test pressure of most recent periodic test

month year (bar) / (MPa)*

Stamp of expert who carried out most recent test

* The unit used should be marked



13.1.55.2 The following requirements apply to tanks intended for the transport of organic peroxides (type F) with a Self-Accelerating Decomposition Temperature (SADT) of 55 ° C or more In case of conflict, these requirements prevail over 13.1 to 13.1.26. Emergencies to be taken into account are the self accelerating decomposition of the or-ganic peroxide and the fire engulfment as described in 13.1.55.8.

13.1.55.3 Formulations of organic peroxides transported in portable tanks with an SADT less than 55° C have to be sub-jected to the temperature control requirements given in section 21 of this General Introduction. The additional requirements for transport in tanks of organic peroxides with an SADT less than 55° C should be specified by the competent authority of the country of origin and notification thereof should be sent to the competent authority of the country of destination.

13.1.55.4 Tanks should be designed for a test pressure of at least 0.4 MPa (4 bar).

13.1.55.5 Tanks should be fitted with temperature-sensing devices.

13.1.55.6 Tanks should be fitted with pressure relief devices and emergency relief devices. Vacuum-relief devices may also be used. Pressure relief devices should operate at pressures determined according to both the properties of the organic peroxide and the construction characteristics of the tank. Fusible elements are not allowed in the shell of the tank.

13.1.55.7 The pressure-relief devices should consist of spring loaded valves fitted to prevent significant build-up within the tank of the decomposition products and vapours released at a temperature of 50° C. The capacity and start-to-discharge pressure of the relief valves should be based on the results of the tests specified in 13.1.55.1. The start to discharge pressure should however in no case be such that liquid would escape from the valve or valves if the tank is overturned.

13.1.55.8 The emergency-relief devices may be of the spring-loaded or frangible types designed to vent all the decomposi-tion products and vapours evolved during a period of not less than one hour of complete fire-engulfment as calcu-lated by the following equations.

0.82AF 70961 q ⋅=

where

q = heat absorption [W];

A = wetted area [m2];

F = insulation factor [-];

F = 1 for non-insulated vessels; or

47032Tpo)U(923F −=

where K = heat conductivity of insulation layer (W m1 K1];

L = thickness of insulation layer [m];

U - K/L = heat transfer coefficient of the insulation [W m 2 K1];

Tpo = temperature of peroxide at relieving conditions [K].


for insulated vessels


The start-to-discharge pressure of the emergency-relief device (s) should be higher than that specified in 13.1.55.7 and based on the results of the tests referred to in 13.1.55.1. The emergency-relief devices should be dimensioned in such a way that the maximum pressure in the tank never exceeds the test pressure of the tank.

Note: An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Crite-ria.

13.1.55.9 For insulated tanks the capacity and setting of emergency relief device or devices should be determined assum-ing a loss of insulation of 1% of the surface area.

13.1.55.10 Vacuum-relief devices and spring-loaded valves should be provided with flame arresters. Due attention should be paid to the reduction of the relief capacity caused by the flame arrester.

13.1.55.11 Service equipment such as valves and external piping should be so arranged that no organic peroxide remains in them after filling of the tank.

13.1.55.12 Tanks may be either insulated or protected by a sun shield. If the SADT of the organic peroxide in the tank is 55°C or less, or the tank is constructed of aluminium, the tank should be completely insulated. The outer surface should be finished in white or bright metal.

13.1.55.13 The degree of filling should not exceed 90% at 15° C.



13.1.55.14 The marking as required in 13.1.20.2 should include the UN Number (UN No.) and the correct technical name with the approved concentration of the organic peroxide concerned.

13.1.60 Special requirements relating to tanks for the transport of toxic substances (class 6.1)

13.1.60.1 Reference should be made to the appendix to this subsection setting out the special requirements for individual substances of this class.

13.1.70 Special requirements relating to tanks for the transport of radioactive materials (class 7)

13.1.70.1

With the approval of the competent authority of the country of origin tanks may be used for the transport of radioactive materials listed in section 12 of the introduction to class 7 under the provisions of schedules 1,5,6,9,10 and 11 except uranium hexafluoride.

13.1.70.2

In addition to the requirements of this section the provisions of the appropriate class 7 schedule should be ap-plied.

13.1.70.3

The degree of filling for tanks should not exceed 90% or alternatively any other value approved by the compe-tent authority.

13.1.70.4 Tanks used for the transport of radioactive material should not be used for the transport of other goods.

13.1.80 Special requirements relating to tanks for the transport of corrosive substances (class 8)

13.1.80.1 The following general requirements relate particularly to tanks for the transport of corrosive substances (class 8).

13.1.80.2 The pressure relief devices of tanks used for the transport of class 8 substances should be inspected at intervals not exceeding one year.

13.1.80.3 Reference should be made to the appendix to this subsection setting out special requirements for individual substances of this class.

13.1.90 Special requirements relating to tanks for the transport of marine pollutants included in class 9

13.1.90.1 A tank used for the transport of an ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., MA-RINE POLLUTANT, UN No. 3082, should be at least a type 2 tank as defined in 13.1.2.14.



(s): No subsidiary risk label of class 8 required for concentrations below 80%. (t): Maximum quantity per portable tank 2, 000 kg, loaded and unloaded in the molten state, transported

as solid. (u): When transported under heated conditions, the heating device should be fitted outside the shell.

(v): To be carried under special temperature conditions - see relevant individual schedule.

(w): Special filling limits are to be observed. The tank should not be filled to more than 88% of its capacity at any time during transport.

(x): The portable tank may be fitted with a device located under maximum filling conditions in the vapour space of the shell to prevent the build-up of excess pressure due to the slow decomposition of the substance transported. This device should also prevent an unacceptable amount of leakage of liquid in the case of overturning or entry of foreign matter into the tank. This device should be approved by the competent authority or its authorized body.

STOWAGE REQUIREMENTS

For stowage requirements, see individual schedules and section 14 of this General Introduction.



UN No. Substance Class Subsidiary risk label

IMO tank type

Minimum test pres-

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Type of pressure-

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Bottom openings

Minimum shell

thickness in mild steel

Special re-quirements

1 2 3 4 5 6 7 8 9 10 1052 HYDROGEN FLUORIDE, ANHYDROUS 8 Toxic 1 6.0 NF C 8 mm — 1088 ACETAL 3.1/3.2 — 1 2.65 N A 13.1.5 — 1089 ACETALDEHYDE 3.1 — 1 6.0 N B 6 mm (a) 1090 ACETONE or ACETONE SOLUTIONS 3.1/3.2 — 1 2.65 N A 13.1.5 — 1091 ACETONE OILS (1) 3.2 — 1 2.65 N A 13.1.5 — 1091 ACETONE OILS (2) 3.2 — 2 1.5 N A 13.1.5 — 1092 ACROLEIN, INHIBITED 6.1 Flam Iiq. 1 4.0 NF C 6 mm (a), (b) 1093 ACRYLONITRILE, INHIBITED 3.2 Toxic 1 4.0 NF C 6 mm (b) 1098 ALLYL ALCOHOL 6.1 Flam Iiq. 1 4.0 NF C 13.1.5 (b) 1099 ALLYL BROMIDE 3.2 Toxic 1 4.0 NF C 13.1.5 (b) 1100 ALLYL CHLORIDE 3.1 Toxic 1 4.0 NF C 6 mm (b) 1104 AMYL ACETATES 3.3 — 2 1.5 N A 13.1.5 — 1105 PENTANOLS 3.2/3.3 — 2 1.5 N A 13.1.5 — 1106 AMYLAMINE 3.2/3.3 Corrosive 2 1.5 N A 13.1.5 — 1107 AMYL CHLORIDE 3.2 — 2 1.5 N A 13.1.5 — 1108 1-PENTENE 3.1 — 1 4.0 N B 13.1.5 — 1109 AMYL FORMATES 3.3 — 2 1.5 N A 13.1.5 — 1110 normal-AMYL METHYL KETONE 3.3 — 2 1.5 N A 13.1.5 — 1111 AMYL MERCAPTANS 3.2 — 1 2.65 N B 13.1.5 — 1112 AMYL NITRATES 3.3 — 2 1.5 N A 13.1.5 — 1113 AMYL NITRITE 3.1/3.2 — 1 2.65 N B 13.1.5 — 1114 BENZENE 3.2 — 1 2.65 N B 13.1.5 — 1120 BUTANOLS 3.2/3.3 — 2 1.5 N A 13.1.5 — 1123 BUTYL ACETATES 3.2/3.3 — 2 1.5 N A 13.1.5 — 1125 normal-BUTYLAMINE 3.2 Corrosive 1 2.65 N B 13.1.5 — 1126 1-BROMOBUTANE 3.2 — 2 1.5 N A 13.1.5 —

IMDG CODE - PAGE 0087 (first of fourty nine pages) Amdt. 29-98



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1 2 3 4 5 6 7 8 9 10 1127 CHLOROBUTANES 3.1/3.2 — 1 2.65 N B 13.1.5 — 1128 normal-BUTYL FORMATE 3.2 — 2 1.5 N A 13.1.5 — 1129 BUTYRALDEHYDE 3.2 — 1 2.65 N B 13.1.5 — 1130 CAMPHOR OIL 3.3 — 2 1.5 N A 13.1.5 — 1131 CARBON DISULPHIDE 3.1 Toxic 1 4.0 NF C 13.1.5 (a), (b) 1133 ADHESIVES (1) 3.1/3.2 — 1 2.65 N A 13.1.5 — 1133 ADHESIVES (2) 3.2/3.3 — 2 1.5 N A 13.1.5 — 1134 CHLOROBENZENE 3.3 — 2 1.5 N A 13.1.5 — 1135 ETHYLENE CHLOROHYDRIN 6.1 Flam Iiq. 1 6.0 NF C 13.1.5 — 1136 COAL TAR DISTILLATES, FLAMMABLE (1) 3.2 — 1 2.65 N B 13.1.5 — 1136 COAL TAR DISTILLATES, FLAMMABLE (2) 3.2/3.3 — 2 1.5 N A 13.1.5 — 1139 COATING SOLUTION (1) 3.1/3.2 — 1 2.65 N A 13.1.5 — 1139 COATING SOLUTION (2) 3.2/3.3 — 2 1.5 N A 13.1.5 — 1143 CROTONALDEHYDE, STABILIZED 6.1 Flam Iiq. 1 4.0 NF C 13.1.5 (b) 1144 CROTONYLENE 3.1 — 1 6.0 N B 13.1.5 — 1145 CYCLOHEXANE 3.1 — 1 2.65 N B 13.1.5 — 1146 CYCLOPENTANE 3.1 — 1 4.0 N B 13.1.5 — 1147 DECAHYDRONAPHTHALENES (cis-, trans-) 3.3 — 2 1.5 N A 13.1.5 — 1148 DIACETONE ALCOHOL 3.2/3.3 — 2 1.5 N A 13.1.5 — 1149 DIBUTYL ETHERS 3.3 — 2 1.5 N A 13.1.5 — 1150 1,2-DICHLOROETHYLENE 3.2 — 1 4.0 N B 13.1.5 — 1152 DICHLOROPENTANES 3.3 — 2 1.5 N A 13.1.5 — 1153 ETHYLENE GLYCOL DIETHYL ETHER 3.3 — 2 1.5 N A 13.1.5 — 1154 DIETHYLAMINE 3.1 Corrosive 1 4.0 N B 13.1.5 — 1155 DIETHYL ETHER 3.1 — 1 6.0 N C 13.1.5 — 1156 DIETHYL KETONE 3.2 — 2 1.5 N A 13.1.5 —




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Type of pressure-

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1 2 3 4 5 6 7 8 9 10 1157 DIISOBUTYL KETONE 3.3 — 2 1.5 N A 13.1.5 — 1158 DIISOPROPYLAMINE 3.2 Corrosive 1 2.65 N B 13.1.5 — 1159 DIISOPROPYL ETHER 3.1 — 1 2.65 N B 13.1.5 —

1160 DIMETHYLAMINE, AQUEOUS SOLUTION (up to and including 40%) 3.1/3.2 Corrosive 1 4.0 N B 13.1.5 —

1160 DIMETHYLAMINE, AQUEOUS SOLUTION (>40% TO ≤ 60%) 3.1 Corrosive 1 6.0 N B 13.1.5 —

1161 DIMETHYL CARBONATE 3.2 — 1 2.65 N B 13.1.5 — 1162 DIMETHYLDICHLOROSILANE 3.2 Corrosive 1 4.0 N C 6 mm (b)

1163 DIMETHYLHYDRAZINE, UNSYMMETRICAL 6.1 Flam liq. Corrosive 1 4.0 NF C 6 mm (b)

1164 DIMETHYL SULPHIDE 3.1 — 1 4.0 N B 13.1.5 — 1165 DIOXANE 3.2 — 1 2.65 N B 13.1.5 — 1166 DIOXOLANE 3.2 — 1 2.65 N B 13.1.5 — 1167 DIVINYL ETHER, INHIBITED 3.1 — 1 4.0 N B 13.1.5 — 1169 EXTRACTS AROMATIC, LIQUID (1) 3.2 — 1 2.65 N A 13.1.5 — 1169 EXTRACTS AROMATIC, LIQUID (2) 3.2/3.3 — 2 1.5 N A 13.1.5 — 1170 ETHANOL and ETHANOL SOLUTIONS 3.2/3.3 — 2 1.5 N A 13.1.5 — 1171 ETHYLENE GLYCOL MONOETHYL ETHER 3.3 — 2 1.5 N A 13.1.5 —

1172 ETHYLENE GLYCOL MONOETHYL, ETHER ACE-TATE 3.3 — 2 1.5 N A 13.1.5 —

1173 ETHYL ACETATE 3.2 — 2 1.5 N B 13.1.5 — 1175 ETHYLBENZENE 3.2 — 2 1.5 N A 13.1.5 — 1176 ETHYL BORATE 3.2 — 1 2.65 N B 13.1.5 — 1177 2-ETHYLBUTYL ACETATE 3.3 — 2 1.5 N A 13.1.5 — 1178 2-ETHYLBUTYRALDEHYDE 3.2 — 2 1.5 N A 13.1.5 — 1179 ETHYL BUTYL ETHER 3.2 — 2 1.5 N A 13.1.5 — 1180 ETHYL BUTYRATE 3.3 — 2 1.5 N A 13.1.5 —




IMO tank type

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Type of pressure-

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Minimum shell



1 2 3 4 5 6 7 8 9 10 1288 SHALE OIL (1) 3.2 — 1 2.65 N A 13.1.5 — 1288 SHALE OIL (2) 3.2/3.3 — 2 1.5 N A 13.1.5 —

1289 SODIUM METHYLATE, SOLUTIONS in alcohols 3.2/3.3 Corrosive 1 2.65 N B 13.1.5 — 1292 TETRAETHYL SILICATE 3.3 — 2 1.5 N A 13.1.5 — 1293 TINCTURES MEDICINAL (1) 3.2 — 1 2.65 N B 13.1.5 — 1293 TINCTURES MEDICINAL (2) 3.2/3.3 — 2 1.5 N A 13.1.5 — 1294 TOLUENE 3.2 — 2 1.5 N A 13.1.5 —

1295 TRICHLOROSILANE 4.3 Flam Iiq. Corrosive 1 6.0 NF C 6 mm (b)

1296 TRIETHYLAMINE 3.2 Corrosive 1 2.65 N B 13.1.5 —

1297 TRIMETHYLAMINE, AQUEOUS, SOLUTION 3.1/3.2/ 3.3 Corrosive 1 4.0 N B 13.1.5 —

1298 TRIMETHYLCHLOROSILANE 3.1 Corrosive 1 4.0 N B 6 mm (b) 1299 TURPENTINE 3.3 — 2 1.5 N A 13.1.5 — 1300 TURPENTINE SUBSTITUTE 3.2/3.3 — 2 1.5 N A 13.1.5 — 1301 VINYL ACETATE, INHIBITED 3.2 — 1 2.65 N B 13.1.5 — 1302 VINYL ETHYL ETHER, INHIBITED 3.1 — 1 4.0 N B 13.1.5 — 1303 VINYLIDENE CHLORIDE, INHIBITED 3.1 — 1 6.0 NF B 13.1.5 (a) 1304 VINYL ISOBUTYL ETHER, INHIBITED 3.2 — 1 2.65 N B 13.1.5 — 1305 VINYLTRICHLOROSILANE, INHIBITED 3.2 Corrosive 1 4.0 N B 6 mm (b) 1306 WOOD PRESERVATIVES, LIQUID (1) 3.2 — 1 2.65 N A 13.1.5 — 1306 WOOD PRESERVATIVES, LIQUID (2) 3.2/3.3 — 2 1.5 N A 13.1.5 — 1307 XYLENES 3.2/3.3 — 2 1.5 N A 13.1.5 — 1350 SULPHUR 4.1 — 2 1.5 N A 13.1.5 —

IMDG CODE - PAGE 0087g (page 0087h follows) Amdt. 28-96



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1 2 3 4 5 6 7 8 9 10

1366 DIETHYLZINC 4.2 Dangerous when wet 1 10.0 N C 10 mm (a)

1370 DIMETHYLZINC 4.2 Dangerous when wet 1 10.0 N C 10 mm (a)

1381 PHOSPHORUS, WHITE or YELLOW, UNDER WATER 4.2 Toxic 1 4.0 N C 6 mm (m) 1422 POTASSIUM SODIUM ALLOYS 4.3 — 1 4.0 N C 6 mm (a), (m) 1428 SODIUM 4.3 — 1 4.0 N C 6 mm (a), (m) 1445 BARIUM CHLORATE SOLUTION 5.1 Toxic 1 2.65 N B 13.1.5 — 1447 BARIUM PERCHLORATE SOLUTION 5.1 Toxic 1 2.65 N B 13.1.5 — 1470 LEAD PERCHLORATE SOLUTION 5.1 Toxic 1 2.65 N B 13.1.5 — 1541 ACETONE CYANOHYDRIN, STABILIZED 6.1 — 1 4.0 NF C 6 mm — 1545 ALLYL ISOTHIOCYANATE, STABILIZED 6.1 Flam liq. 1 4.0 NF B 13.1.5 — 1547 ANILINE 6.1 — 1 2.65 N B 13.1.5 — 1553 ARSENIC ACID, LIQUID 6.1 — 1 4.0 NF C 8 mm (a), (b) 1560 ARSENIC TRICHLORIDE 6.1 — 1 4.0 NF C 6 mm — 1569 BROMOACETONE 6.1 Flam Iiq. 1 4.0 NF B 13.1.5 (b) 1577 CHLORODINITROBENZENES, LIQUID 6.1 — 1 4.0 N B 13.1.5 — 1578 CHLORONITROBENZENES, LIQUID 6.1 — 1 4.0 N B 13.1.5 — 1580 CHLOROPICRIN 6.1 — 1 4.0 NF C 6 mm (b) 1590 DICHLOROANILINES, LIQUID 6.1 — 1 4.0 N B 13.1.5 — 1591 ortho-DICHLOROBENZENE 6.1 — 1 2.65 N A 13.1.5 — 1593 DICHLOROMETHANE 6.1 — 1 4.0 N A 13.1.5 — 1594 DIETHYL SULPHATE 6.1 — 1 4.0 N B 13.1.5 — 1595 DIMETHYL SULPHATE 6.1 Corrosive 1 4.0 NF C 6 mm (b) 1597 DINITROBENZENES, LIQUID 6.1 — 1 4.0 N B 13.1.5 — 1598 DINITRO-o-CRESOL 6.1 — 1 4.0 N B 13.1.5 —

IMDG CODE - PAGE 0087h (page 0087i follows) Amdt. 29-98



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Minimum test pres-

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Type of pressure-

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Minimum shell



1 2 3 4 5 6 7 8 9 10 1779 FORMIC ACID 8 — 1 2.65 N B 13.1.5 — 1780 FUMARYL CHLORIDE 8 — 1 2.65 N B 6 mm — 1781 HEXADECYLTRICHLOROSILANE 8 — 1 2.65 N B 13.1.5 — 1782 HEXAFLUOROPHOSPHORIC ACID 8 — 1 2.65 N C 8 mm (c) 1783 HEXAMETHYLENEDIAMINE SOLUTION 8 — 1 2.65 N B 13.1.5 — 1784 HEXYLTRICHLOROSILANE 8 — 1 2.65 N B 6 mm (b)

1786 HYDROFLUORIC ACID AND SULPHURIC ACID, MIXTURE 8 Toxic 1 4.0 NF C 8 mm (b), (c)

1787 HYDRIODIC ACID 8 — 1 2.65 N C 8 mm — 1788 HYDROBROMIC ACID 8 — 1 2.65 N C 8 mm —

1789 HYDROCHLORIC ACID (not more than 36% HCI) 8 — 1 2.65 N C 8 mm (c)

1790 HYDROFLUORIC ACID 8 Toxic 1 4.0 NF C 8 mm (c) 1791 HYPOCHLORITE SOLUTION 8 — 1 2.65 N A 13.1.5 (X) 1792 IODINE MONOCHLORIDE 8 — 1 2.65 N B 6 mm — 1793 ISOPROPYL ACID PHOSPHATE 8 — 1 2.65 N A 13.1.5 —

1796 NITRATING ACID, MIXTURE 8 Oxidizing agent* 1 2.65 NF C 8 mm (b), (c)

1798 NITROHYDROCHLORIC ACID 8 — 1 4.0 NF C 8 mm (b), (c) 1799 NONYLTRICHLOROSILANE 8 — 1 2.65 N B 6 mm (b) 1800 OCTADECYLTRICHLOROSILANE 8 — 1 2.65 N B 13.1.5 (b) 1801 OCTYLTRICHLOROSILANE 8 — 1 2.65 N B 6 mm (b)

1802 PERCHLORIC ACID not more than 50% acid 8 Oxidizing agent 1 2.65 N C 13.1.5 —

1803 PHENOLSULPHONIC ACID SOLUTION 8 — 1 2.65 N B 13.1.5 —

* Not required if nitric acid content not more than 50%.

IMDG CODE - PAGE 0087m (page 0087n follows) Amdt. 29-98



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Minimum shell



1 2 3 4 5 6 7 8 9 10 1804 PHENYLTRICHLOROSILANE 8 — 1 2.65 N B 6 mm — 1805 PHOSPHORIC ACID, LIQUID 8 — 1 2.65 N A 13.1.5 — 1808 PHOSPHORUS TRIBROMIDE 8 — 1 2.65 N B 6 mm — 1809 PHOSPHORUS TRICHLORIDE 6.1 Corrosive 1 4.0 NF C 6 mm (b) 1810 PHOSPHORUS OXYCHLORIDE 8 — 1 2.65 N B 6 mm —

1811 POTASSIUM HYDROGENDIFLUORIDE, SOLUTION 8 Toxic 1 2.65 N B 13.1.5 —

1812 POTASSIUM FLUORIDE, SOLUTION 6.1 — 1 2.65 N B 13.1.5 —

1814 POTASSIUM HYDROXIDE, SOLUTION (Packaging group II) 8 — 1 2.65 N B 13.1.5 —

1814 POTASSIUM HYDROXIDE, SOLUTION (Packaging group III) 8 — 1 2.65 N A 13.1.5 —

1815 PROPIONYL CHLORIDE 3.2 Corrosive 1 2.65 N B 6 mm — 1816 PROPYLTRICHLOROSILANE 8 Flam Iiq. 1 2.65 N B 6 mm (b) 1817 PYROSULPHURYL CHLORIDE 8 — 1 2.65 N C 8 mm (c) 1818 SILICON TETRACHLORIDE 8 — 1 4.0 NF C 6 mm (a)

1819 SODIUM ALUMINATE SOLUTION (Packaging group II) 8 — 1 2.65 N B 13.1.5 —

1819 SODIUM ALUMINATE SOLUTION (Packaging group III) 8 — 1 2.65 N A 13.1.5 —

1824 SODIUM HYDROXIDE, SOLUTION (Packaging group II) 8 — 1 2.65 N B 13.1.5 —

1824 SODIUM HYDROXIDE, SOLUTION (Packaging group III) 8 — 1 2.65 N A 13.1.5 —

1826 NITRATING ACID, MIXTURE, SPENT 8 Oxidizing agent* 1 2.65 NF C 8 mm (c)

1827 STANNIC CHLORIDE, ANHYDROUS 8 — 1 2.65 N B 6 mm —

* Not required if nitric acid content not more than 50%.

IMDG CODE - PAGE 0087n (page 0087o follows) Amdt. 28-96



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1 2 3 4 5 6 7 8 9 10

1828 SULPHUR CHLORIDES 8 — 1 4.0 NF C 8 mm (c)

1829 SULPHUR TRIOXIDE, INHIBITED or STABILIZED 8 — 1 4.0 NF C 8 mm (c), (f), (u), (v), (w)

1830 SULPHURIC ACID with more than 51% acid 8 — 1 2.65 N C 8 mm (c) 1831 SULPHURIC ACID, FUMING 8 Toxic 1 4.0 NF C 8 mm (c) 1832 SULPHURIC ACID, SPENT 8 — 1 2.65 N C 8 mm (c) 1833 SULPHUROUS ACID 8 — 1 2.65 N B 13.1.5 — 1834 SULPHURYL CHLORIDE 8 — 1 4.0 NF C 8 mm (c)

1835 TETRAMETHYLAMMONIUM HYDROXIDE (solutions) 8 — 1 2.65 N B 13.1.5 —

1836 THIONYL CHLORIDE 8 — 1 4.0 NF C 8 mm (b), (c) 1837 THIOPHOSPHORYL CHLORIDE 8 — 1 2.65 NF C 13.1.5 — 1838 TITANIUM TETRACHLORIDE 8 — 1 2.65 NF C 6 mm (b) 1840 ZINC CHLORIDE SOLUTION 8 — 1 2.65 N A 13.1.5 —

1843 AMMONIUM DINITRO-ortho-CRESOLATE, aqueous SOLUTION 6.1 — 1 2.65 N B 13.1.5 —

1846 CARBON TETRACHLORIDE 6.1 — 1 2.65 N B 13.1.5 — 1848 PROPIONIC ACID 8 Flam liq.* 1 2.65 N A 13.1.5 —

1849 SODIUM SULPHIDE, HYDRATED with at least 30% water (liquid) 8 — 1 2.65 N B 13.1.5 —

1862 ETHYL CROTONATE 3.2 — 2 1.5 N A 13.1.5 — 1863 FUEL AVIATION TURBINE ENGINE (1) 3.1/3.2 — 1 2.65 N A 13.1.5 — 1863 FUEL AVIATION TURBINE ENGINE (2) 3.2/3.3 — 2 1.5 N A 13.1.5 — 1865 normal-PROPYL NITRATE 3.2 — Prohibited in tanks 1866 RESIN SOLUTION, flammable (1) 3.1/3.2 — 1 2.65 N A 13.1.5 — 1866 RESIN SOLUTION, flammable (2) 3.2/3.3 — 2 1.5 N A 13.1.5 —

* If flashpoint 61°C c.c. or below.

IMDG CODE - PAGE 0087o (page 0087p follows) Amdt. 28-96



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1 2 3 4 5 6 7 8 9 10

1873 PERCHLORIC ACID, with more than 50% but not more than 72% acid , by mass 5.1 Corrosive 1 2.65 N C 8 mm (c)

1886 BENZYLIDENE CHLORIDE 6.1 — 1 2.65 N B 13.1.5 — 1887 BROMOCHLOROMETHANE 6.1 — 1 2.65 N A 13.1.5 — 1888 CHLOROFORM 6.1 — 1 4.0 N B 13.1.5 — 1891 ETHYL BROMIDE 6.1 — 1 4.0 NF B 13.1.5 (b) 1892 ETHYLDICHLOROARSINE 6.1 — 1 6.0 NF C 6 mm (b) 1897 TETRACHLOROETHYLENE 6.1 — 2 1.5 N A 13.1.5 — 1898 ACETYL IODIDE 8 — 1 2.65 N C 13.1.5 (b) 1902 DIISOOCTYL ACID PHOSPHATE 8 — 1 2.65 N A 13.1.5 — 1906 SLUDGE ACID 8 — 1 2.65 N C 8 mm (c) 1908 CHLORITE SOLUTION 8 — 1 2.65 N B 13.1.5 (x) 1914 BUTYL PROPIONATES 3.3 — 2 1.5 N A 13.1.5 — 1915 CYCLOHEXANONE 3.3 — 2 1.5 N A 13.1.5 — 1916 2,2-DICHLORODIETHYL ETHER 6.1 Flam Iiq. 1 2.65 N B 13.1.5 — 1917 ETHYL ACRYLATE, INHIBITED 3.2 — 1 2.65 N B 13.1.5 (b) 1918 ISOPROPYLBENZENE 3.3 — 2 1.5 N A 13.1.5 — 1919 METHYL ACRYLATE, INHIBITED 3.2 — 1 2.65 N B 13.1.5 (b) 1920 NONANES 3.3 — 2 1.5 N A 13.1.5 — 1921 PROPYLENEIMINE, INHIBITED 3.2 — 1 6.0 NF C 6 mm — 1922 PYRROLIDINE 3.2 Corrosive 2 1.5 N A 13.1.5 — 1935 CYANIDE SOLUTION, N.O.S. 6.1 — 1 4.0 NF C 6 mm (b) 1938 BROMOACETIC ACID SOLUTION 8 — 1 2.65 N C 13.1.5 — 1939 PHOSPHORUS OXYBROMIDE 8 — 1 2.65 N B 6 mm — 1940 THIOGLYCOLIC ACID 8 — 1 2.65 N B 13.1.5 — 1941 DIBROMODIFLUOROMETHANE 9 — 1 6.0 N A 13.1.5 —

IMDG CODE - PAGE 0087p (page 0087q follows) Amdt. 29-98



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1 2 3 4 5 6 7 8 9 10

1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3.1/3.2/ 3.3 Toxic 1 2.65 N B 13.1.5 (j)

1987 ALCOHOLS, N.O.S. 3.2 — 1 2.65 N B 13.1.5 — 1987 ALCOHOLS, N.O.S. 3.3 — 2 1.5 N A 13.1.5 —

1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3.1/3.2/ 3.3 Toxic 1 2.65 N B 13.1.5 —

1989 ALDEHYDES, N.O.S. 3.1/3.2 — 1 2.65 N B 13.1.5 (j) 1989 ALDEHYDES, N.O.S. 3.3 — 2 1.5 N A 13.1.5 — 1990 BENZALDEHYDE 9 — 2 1.5 N A 13.1.5 — 1991 CHLOROPRENE, INHIBITED 3.1 Toxic 1 4.0 N C 13.1.5 (b), (e)

1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 3.1/3.2/ 3.3 Toxic 1 4.0 NF C 13.1.5 (b), (j)

1993 FLAMMABLE LIQUID, N.O.S. 3.1/3.2 — 1 2.65 N B 13.1.5 (I) 1993 FLAMMABLE LIQUID, N.O.S. 3.3 — 2 1.5 N A 13.1.5 — 1994 IRON PENTACARBONYL 6.1 Flam Iiq. Prohibited in tanks 1999 TARS, LIQUID 3.2/3.3 — 3 1.5 N A 13.1.5 —

2003 METAL ALKYLS, WATER-REACTIVE, N.O.S. or METAL ARYLS, WATER-REACTIVE, N.O.S. 4.2 Dangerous

when wet 1 10.0 N C 10 mm (a)

2014 HYDROGEN PEROXIDE, AQUEOUS, SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary)

5.1 Corrosive 1 4.0 N B 13.1.5 (e), (x)

2015 HYDROGEN PEROXIDE, STABILIZED, or AQUEOUS SOLUTION, STABILIZED, with more than 60% hydro-gen peroxide

5.1 Corrosive 1 4.0 N C 13.1.5 (e), (x)

2018 CHLOROANILINES, SOLID 6.1 — 1 4.0 N B 13.1.5 (f) 2019 CHLOROANILINES, LIQUID 6.1 — 1 4.0 N B 13.1.5 — 2021 CHLOROPHENOLS, LIQUID 6.1 — 1 2.65 N A 13.1.5 — 2022 CRESYLIC ACID 6.1 Corrosive 1 2.65 N B 13.1.5 (b)

IMDG CODE - PAGE 0087q (page 0087r follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10 2023 EPICHLOROHYDRIN 6.1 Flam Iiq. 1 4.0 N B 13.1.5 (b)

2029 HYDRAZINE, ANHYDROUS 8 Flam Iiq., Toxic

Prohibited in tanks

2030 HYDRAZINE HYDRATE or HYDRAZINE AQUEOUS SOLUTION with not less than 37% but not more than 64% hydrazine, by mass

8 Toxic 1 4.0 N C 13.1.5 (b)

2031 NITRIC ACID, other than red fuming 8 Oxidizing agent* 1 2.65 N C 8 mm (c)

2032 NITRIC ACID, RED FUMING 8 Oxidizing agent, Toxic 1 4.0 NF C 8 mm (c)

2038 DINITROTOLUENES, LIQUID 6.1 — 1 2.65 N B 13.1.5 — 2045 ISOBUTYRALDEHYDE 3.1 — 1 2.65 N B 13.1.5 — 2046 CYMENES (ortho-, meta-, para-) 3.3 — 2 1.5 N A 13.1.5 — 2047 DICHLOROPROPENES 3.3 — 1 2.65 N B 13.1.5 — 2048 DICYCLOPENTADIENE 3.3 — 1 2.65 N A 13.1.5 — 2049 DIETHYLBENZENES (ortho, meta-, para-) 3.3 — 2 1.5 N A 13.1.5 —

2050 DIISOBUTYLENES, ISOMERIC, COMPOUNDS 3.2 — 2 1.5 N A 13.1.5 —

2051 2-DIMETHYLAMINOETHANOL 8 Flam Iiq. 1 2.65 N B 13.1.5 — 2052 DIPENTENE 3.3 — 2 1.5 N A 13.1.5 — 2053 METHYL ISOBUTYL CARBINOL 3.3 — 2 1.5 N A 13.1.5 — 2054 MORPHOLINE 3.3 — 1 2.65 N B 13.1.5 — 2055 STYRENE MONOMER, INHIBITED 3.3 — 2 1.5 N A 13.1.5 — 2056 TETRAHYDROFURAN 3.1/3.2 — 1 2.65 N B 13.1.5 — 2057 TRIPROPYLENE 3.2/3.3 — 2 1.5 N A 13.1.5 — 2058 VALERALDEHYDES 3.2 — 2 1.5 N A 13.1.5 —

* Packaging group I only.

IMDG CODE - PAGE 0087r (page 0087s follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10 2312 PHENOL, MOLTEN 6.1 — 1 2.65 N B 13.1.5 (f) 2313 PICOLINES 3.3 Corrosive 1 2.65 N B 13.1.5 (f)* 2315 POLYCHLORINATED BIPHENYLS 9 — 1 4.0 NF C 6 mm — 2317 SODIUM CUPROCYANIDE, SOLUTIONS 6.1 — 1 2.65 N B 6 mm (b) 2319 TERPENE HYDROCARBONS, N.O.S. 3.3 — 2 1.5 N A 13.1.5 — 2320 TETRAETHYLENEPENTAMINE 8 — 2 1.5 N B 13.1.5 — 2321 TRICHLOROBENZENES, LIQUID 6.1 — 1 2.65 N B 13.1.5 — 2322 TRICHLOROBUTENE 6.1 — 1 2.65 N B 13.1.5 — 2323 TRIETHYL PHOSPHITE 3.3 — 2 1.5 N A 13.1.5 — 2324 TRIISOBUTYLENE 3.3 — 1 2.65 N A 13.1.5 — 2325 1,3,5-TRIMETHYLBENZENE 3.3 — 2 1.5 N A 13.1.5 — 2326 TRIMETHYLCYCLOHEXYLAMINE 8 — 2 1.5 N B 13.1.5 — 2327 TRIMETHYLHEXAMETHYLENEDIAMINES 8 — 1 2.65 N A 13.1.5 —

2328 TRIMETHYLHEXAMETHYLENE DIISOCYANATE 6.1 — 1 2.65 N B 13.1.5 (b)

2329 TRIMETHYL PHOSPHITE 3.3 — 2 1.5 N A 13.1.5 — 2330 normal-UNDECANE 3.3 — 2 1.5 N A 13.1.5 — 2332 beta-ACETALDEHYDE OXIME 3.3 — 1 2.65 N B 13.1.5 — 2333 ALLYL ACETATE 3.2 Toxic 1 2.65 N B 13.1.5 (b) 2334 ALLYLAMINE 6.1 Flam liq. 1 4.0 NF C 6 mm (b) 2335 ALLYL ETHYL ETHER 3.2 Toxic 1 2.65 N B 13.1.5 (b) 2336 ALLYL FORMATE 3.2 Toxic 1 4.0 NF C 6 mm (b) 2337 PHENYL MERCAPTAN 6.1 Flam Iiq. 1 4.0 NF C 6 mm (b) 2338 BENZOTRIFLUORIDE 3.2 — 2 1.5 N B 13.1.5 — 2339 2-BROMOBUTANE 3.2 — 2 1.5 N A 13.1.5 —

* For gamma-PICOLINE only.

IMDG CODE - PAGE 0087w (page 0087x follows) Amdt. 28-96



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10 2340 2-BROMOETHYL ETHYL ETHER 3.2 — 1 2.65 N A 13.1.5 — 2341 1-BROMO-3-METHYLBUTANE 3.3 — 2 1.5 N A 13.1.5 — 2342 BROMOMETHYLPROPANES 3.2 — 1 2.65 N A 13.1.5 — 2343 2-BROMOPENTANE 3.2 — 2 1.5 N A 13.1.5 — 2344 BROMOPROPANES 3.2/3.3 — 1 2.65 N B 13.1.5 — 2345 3-BROMOPROPYNE 3.2 — 1 2.65 N B 13.1.5 — 2346 BUTANEDIONE 3.2 — 2 1.5 N A 13.1.5 — 2347 BUTYL MERCAPTANS 3.1/3.2 — 1 2.65 N B 13.1.5 — 2348 BUTYL ACRYLATES INHIBITED 3.3 — 1 2.65 N B 13.1.5 — 2350 normal-BUTYL METHYL ETHER 3.2 — 1 2.65 N B 13.1.5 — 2351 BUTYL NITRITES 3.2/3.3 — 1 2.65 N B 13.1.5 — 2352 BUTYL VINYL ETHER, INHIBITED 3.2 — 1 2.65 N A 13.1.5 — 2353 BUTYRYL CHLORIDE 3.2 Corrosive 1 2.65 N C 6 mm (b), (c) 2354 CHLOROMETHYL ETHYL ETHER 3.2 Toxic 1 2.65 N B 13.1.5 (b) 2356 2-CHLOROPROPANE 3.1 — 1 4.0 N B 13.1.5 (b) 2357 CYCLOHEXYLAMINE 8 Flam Iiq. 1 4.0 N B 6 mm — 2358 CYCLOOCTATETRAENE 3.2 — 1 2.65 N B 13.1.5 —

2359 DIALLYLAMINE 3.2 Toxic, Corro-sive 1 2.65 N B 13.1.5 —

2360 DIALLYL ETHER 3.2 Toxic 1 2.65 N B 13.1.5 (b) 2361 DIISOBUTYLAMINE 3.3 Corrosive 1 2.65 N B 13.1.5 — 2362 1,1-DICHLOROETHANE 3.2 — 1 2.65 N A 13.1.5 — 2363 ETHYL MERCAPTAN 3.1 — 1 6.0 N C 13.1.5 (b) 2364 PROPYLBENZENE 3.3 — 2 1.5 N A 13.1.5 — 2366 DIETHYL CARBONATE 3.3 — 2 1.5 N A 13.1.5 —

IMDG CODE - PAGE 0087x (page 0087y follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10 2367 alpha-METHYLVALERALDEHYDE 3.2 — 2 1.5 N A 13.1.5 —

2368 alpha-PINENE 3.3 — 2 1.5 N A 13.1.5 —

2370 1-HEXENE 3.1 – 1 2.65 N B 13.1.5 – 2371 ISOPENTENES 3.1 — 1 6.0 N B 13.1.5 — 2372 1,2-DI(DIMETHYLAMINO)ETHANE 3.2 — 1 2.65 N B 13.1.5 — 2373 DIETHOXYMETHANE 3.1/3.2 — 1 2.65 N B 13.1.5 — 2374 3,3-DIETHOXYPROPENE 3.2 — 2 1.5 N A 13.1.5 — 2375 DIETHYL SULPHIDE 3.2 — 1 4.0 N B 13.1.5 (b) 2376 2,3-DIHYDROPYRAN 3.2 — 1 2.65 N A 13.1.5 — 2377 1,1-DIMETHOXYETHANE 3.1/3.2 — 1 4.0 N B 13.1.5 — 2378 2-DIMETHYLAMINOACETONITRILE 3.3 Toxic 1 2.65 N B 13.1.5 — 2379 1,3-DIMETHYLBUTYLAMINE 3.2 Corrosive 1 2.65 N B 13.1.5 — 2380 DIMETHYLDIETHOXYSILANE 3.2 — 1 2.65 N B 13.1.5 — 2381 DIMETHYL DISULPHIDE 3.2 — 1 2.65 N B 13.1.5 — 2382 DIMETHYLHYDRAZINE SYMMETRICAL 6.1 Flam Iiq. 1 4.0 NF C 6 mm (b) 2383 DIPROPYLAMINE 3.2 Corrosive 1 2.65 N B 13.1.5 — 2384 DI-normal-PROPYL ETHER 3.1/3.2 — 2 1.5 N A 13.1.5 — 2385 ETHYL ISOBUTYRATE 3.2 — 2 1.5 N A 13.1.5 — 2386 1-ETHYLPIPERIDINE 3.2 Corrosive 1 2.65 N B 13.1.5 — 2387 FLUOROBENZENE 3.2 — 1 2.65 N B 13.1.5 — 2388 FLUOROTOLUENES 3.2 — 1 2.65 N B 13.1.5 — 2389 FURAN 3.1 — 1 4.0 NF C 13.1.5 (b) 2390 2-IODOBUTANE 3.2 — 1 2.65 N B 13.1.5 — 2391 IODOMETHYLPROPANES 3.2 — 1 2.65 N B 13.1.5 — 2392 IODOPROPANES 3.3 — 1 2.65 N B 13.1.5 —

IMDG CODE - PAGE 0087y (page 0087z follows) Amdt. 28-96



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10 2393 ISOBUTYL FORMATE 3.2 — 2 1.5 N A 13.1.5 — 2394 ISOBUTYL PROPIONATE 3.2 — 1 2.65 N A 13.1.5 — 2395 ISOBUTYRYL CHLORIDE 3.2 Corrosive 1 2.65 N C 6 mm — 2396 METHACRYLALDEHYDE, INHIBITED 3.2 Toxic 1 2.65 N B 13.1.5 (b) 2397 3-METHYLBUTAN-2-ONE 3.2 — 2 1.5 N A 13.1.5 — 2398 METHYL-tertiary-BUTYL ETHER 3.1 — 1 4.0 N B 13.1.5 — 2399 1-METHYLPIPERIDINE 3.2 Corrosive 1 2.65 N B 13.1.5 — 2400 METHYL ISOVALERATE 3.2 — 2 1.5 N A 13.1.5 — 2401 PIPERIDINE 8 Flam Iiq. 1 4.0 NF B 6 mm — 2402 PROPANETHIOLS 3.1 — 1 2.65 N B 13.1.5 (b) 2403 ISOPROPENYL ACETATE 3.2 — 2 1.5 N A 13.1.5 — 2404 PROPIONITRILE 3.2 Toxic 1 4.0 N B 13.1.5 (b) 2405 ISOPROPYL BUTYRATE 3.3 — 2 1.5 N A 13.1.5 — 2406 ISOPROPYL ISOBUTYRATE 3.2 — 2 1.5 N A 13.1.5 —

2407 ISOPROPYL CHLOROFORMATE 6.1 Flam Iiq. Corrosive Prohibited in tanks

2409 ISOPROPYL PROPIONATE 3.2 — 2 1.5 N A 13.1.5 — 2410 1,2,3,6-TETRAHYDROPYRIDINE 3.2 — 1 2.65 N B 13.1.5 — 2411 BUTYRONITRILE 3.2 Toxic 1 4.0 N B 13.1.5 (b) 2412 TETRAHYDROTHIOPHENE 3.2 — 1 2.65 N A 13.1.5 — 2413 TETRAPROPYL ORTHOTITANATE 3.3 — 1 2.65 N B 13.1.5 — 2414 THIOPHENE 3.2 — 2 1.5 N B 13.1.5 — 2416 TRIMETHYL BORATE 3.2 — 1 4.0 N B 13.1.5 —

2426 AMMONIUM NITRATE, LIQUID (hot concentrated solution) 5.1 — 1 4.0 NF B 13.1.5 (f), (n), (p)

2427 POTASSIUM CHLORATE, AQUEOUS, SOLUTION 5.1 — 1 2.65 N B 13.1.5 —

IMDG CODE - PAGE 0087z (page 0087a1 follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell

thickness In mild steel


1 2 3 4 5 6 7 8 9 10 2606 METHYL ORTHOSILICATE 6.1 Flam Iiq. 1 6.0 NF C 6 mm (b) 2607 ACROLEIN DIMER, STABILIZED 3.3 — 1 2.65 N B 13.1.5 — 2608 NITROPROPANES 3.3 — 2 1.5 N A 13.1.5 — 2610 TRIALLYLAMINE 3.3 Corrosive 1 2.65 N B 13.1.5 — 2611 PROPYLENE CHLOROHYDRIN 6.1 Flam Iiq. 1 2.65 N C 13.1.5 (b) 2612 METHYL PROPYL ETHER 3.1 — 1 4.0 N B 13.1.5 — 2614 METHALLYL ALCOHOL 3.3 — 1 2.65 N B 13.1.5 — 2615 ETHYL PROPYL ETHERS 3.1 — 1 2.65 N B 13.1.5 — 2616 TRIISOPROPYL BORATE 3.2/3.3 — 1 2.65 N B 13.1.5 — 2617 METHYLCYCLOHEXANOLS, flammable 3.3 — 2 1.5 N B 13.1.5 —

2618 VINYLTOLUENES, INHIBITED (ortho- meta-, para-) 3.3 — 2 1.5 N A 13.1.5 —

2619 BENZYLDIMETHYLAMINE 8 Flam Iiq. 2 1.5 N A 13.1.5 — 2620 AMYL BUTYRATES 3.3 — 2 1.5 N A 13.1.5 — 2621 ACETYL METHYL CARBINOL 3.3 — 2 1.5 N A 13.1.5 — 2622 GLYCIDALDEHYDE 3.3 Toxic 1 2.65 N B 13.1.5 —

2626 CHLORIC ACID, AQUEOUS, SOLUTION with not more than 10% chloric acid 5.1 — Prohibited in tanks

2643 METHYL BROMOACETATE 6.1 — 1 2.65 N B 13.1.5 — 2644 METHYL IODIDE 6.1 — 1 4.0 NF C 13.1.5 (b) 2646 HEXACHLOROCYCLOPENTADIENE 6.1 — 1 4.0 NF C 6 mm (b) 2650 1,1-DICHLORO-1-NITROETHANE 6.1 — 1 2.65 N B 13.1.5 —

2651 4,4'-DIAMINODIPHENYLMETHANE, molten or resolidi-fied 6.1 — 1 2.65 N B 13.1.5 (f)

2653 BENZYL IODIDE, molten or resolidified 6.1 — 1 2.65 N B 13.1.5 — 2656 QUINOLINE 6.1 — 1 2.65 N B 13.1.5 — 2661 HEXACHLOROACETONE 6.1 — 1 2.65 N B 13.1.5 —

IMDG CODE - PAGE 0087e1 (page 0087f1 follows) Amdt. 28-96



IMO tank type

Minimum test pres-

sure in bar

Type of pressure

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10 2662 HYDROQUINONE, LIQUID 6.1 — 1 2.65 N B 13.1.5 —

2664 DIBROMOMETHANE 6.1 — 1 2.65 N B 13.1.5 —

2667 BUTYLTOLUENES 6.1 – 2 1.5 N B 13.1.5 –

2668 CHLOROACETONITRILE 6.1 Flam Iiq. 1 2.65 N B 13.1.5 — 2669 CHLOROCRESOLS, LIQUID 6.1 — 1 2.65 N B 13.1.5 — 2672 AMMONIA SOLUTION (10%-35% ammonia) 8 — 1 4.0 N B 13.1.5 —

2677 RUBIDIUM HYDROXIDE SOLUTION (Packaging group II)

8 –

1 2.65 N B 13.1.5 –

2677 RUBIDIUM HYDROXIDE SOLUTION (Packaging group III) 8 – 1 2.65 N A 13.1.5 –

2679 LITHIUM HYDROXIDE, SOLUTION 8 — 1 2.65 N B 13.1.5 —

2681 CAESIUM HYDROXIDE, SOLUTION (Packaging group II) 8 — 1 2.65 N B 13.1.5 —

2681 CAESIUM HYDROXIDE, SOLUTION (Packaging group III) 8 – 1 2.65 N A 13.1.5 —

2683 AMMONIUM SULPHIDE, SOLUTION 8 Toxic Flam Iiq.* 1 4.0 N B 13.1.5 (b)

2684 3-(DIETHYLAMINO)PROPYLAMINE 3.3 Corrosive 1 2.65 N B 13.1.5 — 2685 N,N-DIETHYLETHYLENEDIAMINE 8 Flam Iiq. 1 2.65 N B 13.1.5 — 2686 2-DIETHYLAMINOETHANOL 8 Flam Iiq. 1 2.65 N B 13.1.5 — 2688 1-CHLORO-3-BROMOPROPANE 6.1 — 2 1.5 N B 13.1.5 — 2689 GLYCEROL-alpha-MONOCHLOROHYDRIN 6.1 — 2 1.5 N B 13.1.5 — 2690 N-normal-BUTYLIMIDAZOLE 6.1 — 1 2.65 N B 13.1.5 — 2692 BORON TRIBROMIDE 8 — 1 4.0 NF C 8 mm (b), (c)

* If flashpoint 61° C c.c. or below.

IMDG CODE - PAGE 0087f1 (page 0087g1 follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10

2693 BISULPHITES, AQUEOUS, SOLUTION, N.O.S. 8 — 1 2.65 N B 13.1.5 —

2699 TRIFLUOROACETIC ACID 8 — 1 4.0 NF c 8 mm (c) 2705 1-PENTOL 8 — 1 2.65 N B 13.1.5 —

2707 DIMETHYLDIOXANES 3.2/33 — 1 2.65 N B 13.1.5 —

2709 BUTYLBENZENES 3.3 — 2 1.5 N A 13.1.5 –

2710 DIPROPYL KETONE 3.3 — 2 1.5 N A 13.1.5 —

2730 NITROANISOLES, LIQUID 6.1 — 1 2.65 N B 13.1.5 —

2732 NITROBROMOBENZENES 6.1 — 1 2.65 N B 13.1.5 (f)

2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. (1) 3.1/3.2 Corrosive 1 4.0 N B 13.1.5 (I)

2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. (2) 3.2/3.3 Corrosive 1 2.65 N B 13.1.5 (I)

2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (Packaging group I)

8 Flam liq. 1 4.0 NF C 6 mm –

2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (Packaging group II)

8 Flam Iiq. 1 2.65 N B 13.1.5 –

2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLY-AMINES, LIQUID, CORROSIVE, N.O.S. 8 — 1 2.65 N B 13.1.5 (j)

2738 N-normal-BUTYLANILINE 6.1 — 1 2.65 N B 13.1.5 — 2739 BUTYRIC ANHYDRIDE 8 — 2 1.5 N B 13.1.5 —

IMDG CODE - PAGE 0087g1 (page 0087h1 follows) Amdt. 28-96



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10

2740 normal-PROPYL CHLOROFORMATE 6.1 Flam Iiq. Corrosive Prohibited in tanks

2743 normal-BUTYL CHLOROFORMATE 6.1 Corrosive Flam Iiq. 1 4.0 NF C 13.1.5 (b)

2744 CYCLOBUTYL CHLOROFORMATE 6.1 Corrosive Flam Iiq. 1 4.0 NF C 13.1.5 (b)

2745 CHLOROMETHYL CHLOROFORMATE 6.1 Corrosive 1 4.0 NF C 13.1.5 (b) 2746 PHENYL CHLOROFORMATE 6.1 Corrosive 1 2.65 NF C 13.1.5 (b)

2747 tertiary-BUTYLCYCLOHEXYL CHLOROFORMATE 6.1 — 1 2.65 N B 13.1.5 —

2748 2-ETHYLHEXYL CHLOROFORMATE 6.1 Corrosive 1 2.65 NF C 13.1.5 (b) 2749 TETRAMETHYLSILANE 3.1 — 1 6.0 N C 6 mm — 2750 1,3-DICHLOROPROPANOL-2 6.1 — 1 2.65 N B 13.1.5 — 2751 DIETHYLTHIOPHOSPHORYL CHLORIDE 8 — 1 2.65 N B 13.1.5 — 2752 1,2-EPOXY-3-ETHOXYPROPANE 3.3 — 2 1.5 N A 13.1.5 — 2753 N-ETHYL-N-BENZYLTOLUIDINES, LIQUID 6.1 — 1 4.0 N B 13.1.5 — 2754 N-ETHYLTOLUIDINES 6.1 Flam Iiq. * 1 4.0 N B 13.1.5 —

2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMA-BLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)


IMDG CODE - PAGE 0087h1 (page 0087i1 follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10

2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMA-BLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMA-BLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

2785 4-THIAPENTANAL 6.1 — 1 2.65 N B 13.1.5 —

2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 6.1 — 1 4.0 N B 13.1.5 (b), (j)

2789 ACETIC ACID, GLACIAL or ACETIC ACID, SOLUTION more than 80% acid 8 Flam liq.* 1 2.65 N B 13.1.5 —

2790 ACETIC ACID, SOLUTION, not less than 50% but not more than 80% acid , by mass (Packaging group II) 8 — 1 2.65 N B 13.1.5 —

2790 ACETIC ACID, SOLUTION, more than 10% but less than 50% acid , by mass (Packaging group III) 8 — 1 2.65 N A 13.1.5 —

2796 SULPHURIC ACID, with not more than 51% acid or BATTERY FLUID, ACID 8 — 1 2.65 N C 8 mm (c)

2797 BATTERY FLUID ALKALI 8 — 1 2.65 N B 13.1.5 —


IMDG CODE - PAGE 0087i1 (page 0087j1 follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10 2798 PHENYLPHOSPHORUS DICHLORIDE 8 — 1 2.65 N B 6 mm — 2799 PHENYLPHOSPHORUS THIODICHLORIDE 8 — 1 2.65 N B 6 mm —

2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTER-MEDIATE, LIQUID, CORROSIVE, N.O.S. (Packaging groups I and II)

8 — 1 4.0 N B 13.1.5 —

2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTER-MEDIATE, LIQUID, CORROSIVE, N.O.S. (Packaging group III)

8 — 1 2.65 N A 13.1.5 —

2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 — 1 4.0 N B 13.1.5 (b), (j) 2815 N-AMINOETHYLPIPERAZINE 8 — 1 2.65 N A 13.1.5 —

2817 AMMONIUM HYDROGENDIFLUORIDE, SOLUTION 8 Toxic 1 4.0 N C 13.1.5 (b), (c)

2818 AMMONIUM POLYSULPHIDE, SOLUTION (Packaging group II) 8 Toxic 1 4.0 N B 13.1.5 (b)

2818 AMMONIUM POLYSULPHIDE, SOLUTION (Packaging group III) 8 Toxic 1 2.65 N A 13.1.5 (b)

2819 AMYL ACID PHOSPHATE 8 — 1 2.65 N A 13.1.5 — 2820 BUTYRIC ACID 8 — 2 1.5 N A 13.1.5 — 2821 PHENOL SOLUTION (Packaging group II) 6.1 — 1 4.0 N B 13.1.5 — 2821 PHENOL SOLUTION (Packaging group III) 6.1 — 1 2.65 N A 13.1.5 — 2822 2-CHLOROPYRIDINE 6.1 — 1 4.0 N B 13.1.5 — 2826 ETHYL CHLOROTHIOFORMATE 8 Flam liq. 1 4.0 N B 13.1.5 — 2829 CAPROIC ACID 8 — 2 1.5 N B 13.1.5 — 2831 1,1,1-TRICHLOROETHANE 6.1 — 1 2.65 N A 13.1.5 — 2834 PHOSPHOROUS ACID 8 — 1 2.65 N B 13.1.5 — 2837 BISULPHATES, AQUEOUS SOLUTION 8 — 1 2.65 N B 6 mm — 2838 VINYL BUTYRATE, INHIBITED 3.2 — 1 2.65 N A 13.1.5 — 2839 ALDOL 6.1 — 1 2.65 N B 13.1.5 —

IMDG CODE - PAGE 0087j1 (page 0087k1 follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10 2840 BUTYRALDOXIME 3.3 — 2 1.5 N A 13.1.5 —

2841 Dl-normal-AMYLAMINE 3.3 Toxic 1 2.65 N B 13.1.5 —

2842 NITROETHANE 3.3 — 1 2.65 N B 13.1.5 —

2845 PYROPHORIC LIQUID, ORGANIC, N.O.S. 4.2 — 1 10.0 N C 10 mm (a)

2849 3-CHLOROPROPANOL-1 6.1 — 1 2.65 N B 13.1.5 —

2850 PROPYLENE TETRAMER 3.3 — 2 1.5 N A 13.1.5 —

2851 BORON TRIFLUORIDE DIHYDRATE 8 — 1 2.65 N C 8 mm —

2872 DIBROMOCHLOROPROPANES 6.1 — 1 2.65 N A 13.1.5 —

2873 N-N-Dl-normal-BUTYLAMINOETHANOL 6.1 — 2 1.5 N A 13.1.5 —

2874 FURFURYI ALCOHOL 6.1 — 2 1.5 N B 13.1.5 —

2879 SELENIUM OXYCHLORIDE 8 Toxic 1 2.65 NF C 8 mm (b), (c)

2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 — 1 4.0 N B 13.1.5 (b), (j)

2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. (3) 6.1 Flam Iiq. 1 4.0 N B 13.1.5 (b), (j)

2912 RADIOACTIVE MATERIALS, low specific activity (LSA), N.O.S. 7 — 1 2.65 NF C 13.1.5 see 13.1.70

2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. (2) (Packaging group II) 8 Toxic 1 4.0 NF C 6 mm (k)

2922 CORROSIVE LIQUID, TOXIC, N.O.S. (Packaging group I) 8 Toxic 1 4.0 NF C 8 mm —

2922 CORROSIVE LIQUID, TOXIC, N.O.S. (Packaging group II) 8 Toxic 1 4.0 NF C 6 mm —

2922 CORROSIVE LIQUID, TOXIC, N.O.S. (Packaging group III) 8 Toxic 1 2.65 N B 13.1.5 —

2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. (1) 3.1/3.2 Corrosive 1 6.0 N C 6 mm (j), (k)

2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. (2) 3.2/3.3 Corrosive 1 4.0 N C 6 mm (j), (k)

2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (Packaging group II) 6.1 Corrosive 1 4.0 NF C 6 mm (b), (k)

IMDG CODE - PAGE 0087k1 (page 0087l1 follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10

2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. (3) 6.1 Flam Iiq. 1 4.0 N B 13.1.5 (b), (j)

2933 METHYL-2-CHLOROPROPIONATE 3.3 — 1 2.65 N B 13.1.5 —

2934 ISOPROPYL-2-CHLOROPROPIONATE 3.3 — 2 1.5 N A 13.1.5 —

2935 ETHYL-2-CHLOROPROPIONATE 3.3 — 2 1.5 N A 13.1.5 —

2936 THIOLACTIC ACID 6.1 — 1 2.65 N B 13.1.5 —

2937 alpha-METHYLBENZYL ALCOHOL, LIQUID 6.1 — 2 1.5 N A 13.1.5 —

2941 FLUOROANILINES 6.1 — 1 2.65 N B 13.1.5 —

2943 TETRAHYDROFURFURYLAMINE 3.3 — 2 1.5 N A 13.1.5 —

2945 NMETHYLBUTYLAMINE 3.2 Corrosive 1 2.65 N B 13.1.5 —

2946 2-AMINO-5-DIETHYLAMINOPENTANE 6.1 — 2 1.5 N A 13.1.5 —

2947 ISOPROPYL CHLOROACETATE 3.3 — 2 1.5 N A 13.1.5 —

2948 3-TRIFLUOROMETHYLANILINE 6.1 — 1 4.0 N B 13.1.5 —

2949 SODIUM HYDROSULPHIDE, SOLUTION 8 — 1 2.65 N B 13.1.5 —

2965 BORON TRIFLUORIDE DIMETHYL, ETHERATE 4.3 Corrosive Flam Iiq. 1 4.0 NF C 6 mm —

2966 THIOGLYCOL 6.1 — 1 2.65 N B 13.1.5 —

2983 ETHYLENE OXIDE AND PROPYLENE OXIDE, MIX-TURES, not more than 30% ethylene oxide 3.1 Toxic 1 6.0 NF C 13.1.5 (a)

2984 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary)

5.1 — 1 2.65 N B 13.1.5 (e), (x)

2985 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. 3.2 Corrosive 1 4.0 NF C 6 mm (b)

2986 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. 8 Flam Iiq. 1 4.0 NF C 6 mm —

2987 CHLOROSILANES, CORROSIVE, N.O.S. 8 — 1 4.0 N C 13.1.5 —

2988 CHLOROSILANES, WATER-REACTIVE, FLAMMA-BLE, CORROSIVE, N.O.S. 4.3 Corrosive

Flam Iiq. 1 4.0 NF C 6 mm (b)

2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAM-MABLE (3) 6.1 Flam Iiq. 1 4.0 N B 13.1.5 (b), (j)

IMDG CODE - PAGE 0087l1 (page 0087m1 follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMA-BLE (3) 6.1 Flam liq. 1 4.0 N B 13.1.5 (b), (j)

2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) 6.1 Flam liq. 1 4.0 N B 13.1.5 (b), (j)

2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMA-BLE (3) 6.1 Flam liq. 1 4.0 N B 13.1.5 (b), (j)

2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) 6.1 Flam liq. 1 4.0 N B 13.1.5 (b), (j)

3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

IMDG CODE - PAGE 0087m1 (page 0087n1 follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10

3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) 6.1 Flam liq. 1 4.0 N B 13.1.5 (b), (j)

3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) 6.1 Flam liq. 1 4.0 N B 13.1.5 (b), (j)

3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) 6.1 Flam Iiq. 1 4.0 N B 13.1.5 (b), (j)

3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N P 13.1.5 (b), (j)

3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAM-MABLE (3) 6.1 Flam Iiq. 1 4.0 N B 13.1.5 (b), (j)

3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) 6.1 Flam Iiq. 1 4.0 N B 13.1.5 (b), (j)

3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMA-BLE (3) 6.1 Flam Iiq. 1 4.0 N B 13.1.5 (b), (j)

3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

3022 1,2-BUTYLENE OXIDE, STABILIZED 3.2 — 1 2.65 N B 13.1.5 —

3023 2-METHYL-2-HEPTANETHIOL 6.1 Flam Iiq. 1 4.0 NF C 6 mm (b)

3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) 6.1 Flam Iiq. 1 4.0 N B 13.1.5 (b), (j)

IMDG CODE - PAGE 0087n1 (page 0087o1 follows) Amdt. 28-96



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10

3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (b), (j)

3049 METAL ALKYL HALIDES, WATER-REACTIVE, N.O.S. or METAL ARYL HALIDES, WATER-REACTIVE, N.O.S.

4.2 Dangerous when wet 1 10.0 N C 10 mm (a)

3050 METAL ALKYL HYDRIDES, WATER-REACTIVE, N.O.S. or METAL ARYL HYDRIDES, WATER-REACTIVE, N.O.S.

4.2 Dangerous when wet 1 10.0 N C 10 mm (a)

3051 ALUMINIUM ALKYLS 4.2 Dangerous when wet 1 10.0 N C 10 mm (a)

3052 ALUMINIUM ALKYL HALIDES 4.2 Dangerous when wet 1 10.0 N C 10 mm (a)

3053 MAGNESIUM ALKYLS 4.2 Dangerous when wet 1 10.0 N C 10 mm (a)

3054 CYCLOHEXYL MERCAPTAN 3.3 — 2 1.5 N A 13.1.5 —

3055 2-(2-AMINOETHOXY) ETHANOL 8 — 2 1.5 N B 13.1.5 —

3056 normal-HEPTALDEHYDE 3.3 — 2 1.5 N A 13.1.5 —

3064 NITROGLYCERIN SOLUTION IN ALCOHOL 3.2 — Prohibited in tanks

3065 ALCOHOLIC BEVERAGES 3.2/3.3 — 2 1.5 N A 13.1.5 —

3071 MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S.

6.1 Flam Iiq. 1 4.0 N B 13.1.5 (b)

3073 VINYLPYRIDINES, INHIBITED 6.1 Flam Iiq. Corrosive 1 2.65 N B 13.1.5 (b)

3076 ALUMINIUM ALKYL, HYDRIDES 4.2 Dangerous when wet 1 10.0 N C 10 mm (a)

3079 METHACRYLONITRILE, INHIBITED 3.2 Toxic 1 4.0 NF C 6 mm (b)

3080 ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S.

6.1 Flam Iiq. 1 4.0 N C 13.1.5 (b)

3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 9 — 2 1.5 N A 13.1.5 —

3092 1-METHOXY-2-PROPANOL 3.3 — 2 1.5 N A 13.1.5 —

IMDG CODE - PAGE 0087o1 (page 0087p1 follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10

3109 ORGANIC PEROXIDE, TYPE F, LIQUID

- tert-BUTYL HYDROPEROXIDE, not more than 72% with water 52 Corrosive 1 40 N B 13.1.5 (q), (r)

- CUMYL HYDROPEROXIDE, not more than 90% with diluent type A 52 Corrosive 1 40 N B 13.1.5 (q), (s)

- DI-tert-BUTYL PEROXIDE not more than 52% in diluent type B 52 Corrosive 1 4 0 N B 13.1.5 (q)

- ISOPROPYLCUMYL HYDROPEROXIDE not more than 72% in diluent type A 52 Corrosive 1 40 N B 13.1.5 (q)

- p-MENTHYL HYDROPEROXIDE, not more than 72% in diluent type A 52 Corrosive* 1 40 N B 13.1.5 (q)

- PINANYL HYDROPEROXIDE, not more than 55% with diluent type A 52 — 1 40 N B 13.1.5 (q)

3110 ORGANIC PEROXIDE, TYPE F, SOLID

- DICUMYL PEROXIDE 52 — 1 40 N B 13.1.5 (q), (t)

3119 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERA-TURE CONTROLLED

- tert-BUTYL PEROXYACETATE, not more than 32% in diluent type B 52 — 1 40 N B 13.1.5 (q)

- tert-BUTYL PEROXY-2-ETHYLHEXANOATE, not more than 32% in diluent type B 52 — 1 40 N B 13.1.5 (q)

- tert-BUTYL PEROXYPIVALATE, not more than 27% in diluent type B 52 — 1 40 N B 13.1.5 (q)

- tert-BUTYL PEROXY-3,5,5-TRIMETHYLHEXANOATE, not more than 32% in diluent type B

52 — 1 40 N B 13.1.5 (q)

- Dl-(3,5,5-TRIMETHYLHEXANOYL)PEROXIDE, not more than 38% in diluent type B 52 — 1 4 0 N B 13.1.5 (q)

* If concentration is greater than 56%.

IMDG CODE - PAGE 0087p1 (page 0087q1 follows) Amdt. 28-96



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10

3120 ORGANIC PEROXIDE, TYPE F SOLID, TEMPERA-TURE CONTROLLED

3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2 to C12 homologues) 8 — 1 2.65 N B 13.1.5 (j)

3149 HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE, with acid (s), water and not more than 5% peroxyacetic acid, STABILIZED

5.1 Corrosive 1 4.0 N B 13.1.5 (e), (x)

3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 4.1 — 1 2.65 N C 13.1.5 (a), (f), (u)

3203 PYROPHORIC ORGANOMETALLIC COMPOUND, WATER-REACTIVE, N.O.S. 4.2 Dangerous

when wet 1 10.0 N C 10 mm (a)

3207 ORGANOMETALLIC COMPOUND or COMPOUND SOLUTION or COMPOUND DISPERSION, WATER-REACTIVE, FLAMMABLE, N.O.S.

4.3 Flam Iiq. 1 10.0 N C 10 mm (a)

3210 CHLORATES INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 — 1 2.65 N B 13.1.5 —

3211 PERCHLORATES, INORGANIC, AQUEOUS SOLU-TION, N.O.S. 5.1 — 1 2.65 N B 13.1.5 —

3213 BROMATES INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 — 1 2.65 N B 13.1.5 —

3214 PERMANGANATES INORGANIC, AQUEOUS SOLU-TION, N.O.S. 5.1 — 1 2.65 N B 13.1.5 —

3216 PERSULPHATES, INORGANIC, AQUEOUS SOLU-TION, N.O.S. 5.1 — 2 1.5 N B 13.1.5 —

3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 — 1 2.65 N B 13.1.5 —

3219 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 — 1 2.65 N B 13.1.5 —

3246 METHANESULPHONYL CHLORIDE 6.1 Corrosive 1 6.0 NF C 6 mm (b), (c)

3250 CHLOROACETIC ACID, MOLTEN 6.1 Corrosive 1 2.65 N C 13.1.5 (f)

IMDG CODE - PAGE 0087q1 (page 0087r1 follows) Amdt. 29-98



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10

3256 ELEVATED, TEMPERATURE LIQUID, FLAMMABLE, N.O.S., with flashpoint above 61° C c.c. at or above its flashpoint

3.3 — 2 1.5 N A 13.1.5 (f)

3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100° C and below its flashpoint 9 — 2 1.5 N A 13.1.5 (f)

3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Packaging groups I and II) 8 — 1 4.0 N B 13.1.5 (j), (k)

3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Packaging group III) 8 — 1 2.65 N B 13.1.5 (k)

3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Packaging groups I and II) 8 — 1 4.0 N B 13.1.5 (j), (k)

3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Packaging group III) 8 — 1 2.65 N B 13.1.5 (k)

3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (Packaging groups I and II) 8 — 1 4.0 N B 13.1.5 (j), (k)

3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (Packaging group III) 8 — 1 2.65 N B 13.1.5 (k)

3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (Packaging groups I and II) 8 — 1 4.0 N B 13.1.5 (j), (k)

3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (Packaging group III) 8 — 1 2.65 N B 13.1.5 (k)

3271 ETHERS, N.O.S. (1) 3.1/3.2 — 1 2.65 N B 13.1.5 (j)

3271 ETHERS, N.O.S. (2) 3.2/3.3 — 2 1.5 N A 13.1.5 (j)

IMDG CODE - PAGE 0087r1 (page 0087s1 follows) Amdt. 28-96



IMO tank type

Minimum test pres-

sure in bar

Type of pressure-

relief devices

Bottom openings

Minimum shell



1 2 3 4 5 6 7 8 9 10

3302 2-DIMETHYLAMINOETHYL ACRYLATE 6.1 — 1 2.65 N B 13.1.5 —

3320

SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION with not more than 12% sodium boro-hydride and not more than 40% sodium hydroxide, by mass

8 — 1 4.0 NF B 6 mm —

3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S, or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (Packaging group I)

3.1/3.2 — 1 6.0 N C 6 mm —

3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S, or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (Packaging group II)

3.1/3.2 — 1 2.65 N B 13.1.5 —

3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S, or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (Packaging group III)

3.3 — 2 1.5 N B 13.1.5 —

3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1 Flam. liq. 1 4.0 N B 13.1.5 (j)

3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (j)

3350 PYRETHROID, PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2 Toxic 1 4.0 NF C 13.1.5 (b), (j)

3351 PYRETHROID, PESTICIDE, LIQUID, TOXIC, FLAM-MABLE 6.1 Flam. Iiq. 1 4.0 N B 13.1.5 (j)

3352 PYRETHROID, PESTICIDE, LIQUID, TOXIC 6.1 — 1 4.0 N B 13.1.5 (j)

IMDG CODE - PAGE 0087u1 (page 0087v1 follows) Amdt. 29-98


PAGE RESERVED

IMDG CODE - PAGE 0087V1 (page 0088 follows) Amdt. 29-98


13.100 GENERAL REQUIREMENTS FOR PORTABLE TANKS AND ROAD TANK VEHICLES FOR NON-REFRIGERATED LIQUEFIED GASES OF CLASS 2

13.101 Preamble

13.101.1 The requirements of this subsection apply to portable tanks (type 5 tanks) and road tank vehicles (type 6 tanks) intended for the transport of non-refrigerated liquefied gases of class 2. In addition to these requirements and unless otherwise specified, the applicable requirements of the International Convention for Safe Containers (CSC), 1972, as amended should be fulfilled by any portable tank which meets the definition of a "container" within the terms of that Convention. The International Convention for Safe Containers does not apply to offshore tank-containers that are handled in open seas. The design and testing of offshore tank-containers should take into account the dynamic lifting and impact forces that may occur when a tank is handled in open seas in ad-verse weather and sea conditions. The requirements for such tanks should be determined by the approving competent authority (see MSC/Circ.613 in the annex at the end of this section). Such requirements should be based on MSC/Circ.860 Guidelines for the approval of offshore containers handled in open seas.

13.101.2 In order to take into account progress in science and technology the use of alternative arrangements which offer at least equivalent safety in use in respect of compatibility with the properties of the gases transported and equivalent or superior resistance to impact, loading and fire may be considered by the national competent au-thority.

13.101.3 The requirements of this subsection are presented in two parts. The first contains general requirements applica-ble to portable tanks and road tank vehicles intended for the transport of non-refrigerated liquefied gases of class 2. The second contains the appendix* with a table showing the particular requirements which modify or supplement the general requirements of this subsection for each particular gas.

13.101.3.1 In general, where a substance has not been allocated a UN Number, it should be carried under the most suit-able N.O.S. entry. However, the competent authority of the country of origin may issue interim approvals for shipment of gases not listed in the appendix to this subsection to which individual UN Numbers have already been assigned. The approval should accompany the shipment concerned and contain at a minimum the infor-mation normally provided in the list of non-refrigerated liquefied gases and the conditions under which the par-ticular gases should be carried. The approval should contain a note to the effect that this competent authority has undertaken action to include this gas in the appendix to subsection 13.100.

13.101.4 Construction, equipment, testing, marking and operation of portable tanks and road tank vehicles should be subject to acceptance by the competent authority of the country in which they are approved.

13.101.5 The requirements of this subsection do not apply to rail tank-wagons, non-metallic tanks or tanks having a ca-pacity of 1.000 litres or less.

13.101.6 IMO type 5 tanks certified prior to the implementation of these revised requirements and constructed in accor-dance with the requirements in force at the time may be permitted for use with competent authority approval. The approval should refer to this paragraph.

* The appendix will need updating from time to time in the light of technical progress and to include new substances.



13.102 Definitions 13.102.1 For the purposes of these requirements.

13.102.2 For the purposes of this subsection tank means a portable tank or the carrying tank of a road tank vehicle the shell of which is fitted with items of service equipment and structural equipment necessary for the transport of gases. A tank should be capable of being transported loaded and discharged without the need of removal of its structural equipment.

13.102.3 Shell means the pressure vessel proper including openings and their closures.

13.102.4 Service equipment of a shell means filling and discharge venting safety heating and heat insulating devices and measuring instruments.

13.102.5 Structural equipment means the reinforcing fastening protective and stabilizing members external to the shell and for a road tank vehicle includes fastenings to running gear or chassis.

13.102.6 Maximum allowable working pressure (MAWP) means the maximum gauge pressure permissible at the top of the tank in its operating position. It may be no less than the vapour pressure at the design reference temperature less one bar of any product which can be loaded and carried and any pressure which might be used during loading or unloading In no case should the MAWP be less than 7 bar.

13.102.7 Test pressure means the highest pressure which arises in the shell during the hydraulic pressure test.

13.102.8 Discharge pressure means the highest pressure actually built up in the shell when it is being discharged by pressure.

13.102.9 Leakage test is the test which submits the shell complete with those items of service equipment necessary for filling discharge safety and measuring to an effective internal pressure equivalent to the MAWP. The procedure to be adopted should be approved by the competent authority.

13.102.10 Total mass means the mass of the portable tank or road tank vehicle with the heaviest load authorized for trans-port.

13.102.11 Design reference temperature means the temperature at which the vapour pressure of the tank contents is de-termined for the purpose of calculating the MAWP.

The design reference temperature should be less than the critical temperature of the gas to be transported to ensure that the gas at all times is liquefied.

For portable tanks the temperature to be taken is as follows:

1 for a tank with a diameter of 1.5 metres or less 65° C; 2 for a tank with a diameter of more than 1.5 metres; 2.1 without insulation or sun shield 60° C; 2.2 with sun shield 55° C; and 2.3 with insulation 50° C*. For a road tank vehicle the temperature to be taken is to be agreed by the competent authorities.

* This reference temperature is envisaged but dependent on the quality of the insulation system.



13.115.3 The shell and items of equipment of each tank should be inspected and tested either together or separately first before being put into service (initial inspection and test) and thereafter at not more than five year intervals (periodic inspection and test).

13.115.3.1 The initial inspection and test should include a check of the design characteristics and internal and external examination and a hydraulic pressure test. If the shell and equipment have been pressure tested separately they should together be subjected after assembly to a leakage test. All welds in the shell should be tested in the initial inspection by radiographic ultrasonic or another suitable non-destructive method. This does not apply to the metal sheathing of an insulation.

13.115.3.2 The periodic inspections and tests should include an internal and external examination and as a general rule a pressure rest.

13.115.3.2.1 Sheathing thermal insulation and the like should be removed only to the extent required for reliable appraisal of the tank's condition.

13.115.3.3 The initial and periodic pressure tests should be carried out by an expert approved by the competent authority at the test pressure indicated on the data plate of the tank except in cases where periodic tests at lower test pressures are authorized.

13.115.3.4 While under pressure the tank should be inspected for leakage or other conditions which indicate weaknesses that night render the tank unsafe in transport and if any evidence of such unsafe condition is discovered the tank should not be placed in or returned to service until it has been repaired and the test repeated has been passed.

13.115.4 Before tanks are put into service and thereafter at intervals midway between the inspections and tests speci-fied in 13.115.3 the following tests and inspections should be performed:

1 a leakage test where required;

2 a test of satisfactory operation of all service equipment; and

3 an internal and external inspection of the tanks and their fittings with due regard to the gases transported.

13.115.5 The 2.5 year (midway) inspection and test may be carried out within 3 months of the specified date. The date of the 2.5 year inspection should be durably marked on or as near as possible to the metal identification plate required in 13.117.1. When marking is not done on the plate the characters should be at least 32 mm in height and of a contrasting colour to the tank.

13.115.6 The 2.5 year internal inspections may be waived or substituted by other test methods by the competent authority in the case of tanks intended for the transport of one substance. A portable tank may not be filled and offered for transport after the date of expiry of the last 5 year or 2.5 year periodic inspection and test as re-quired by 13.1.19.3 and 13.1.19.4/13.115.3 and 13.115.4/13.213.3 and 13.213.4. However, a portable tank filled prior to the date of expiry of the last periodic inspection and test may be transported for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection In addition a portable tank may be transported after the date of expiry of the last periodic test and inspection.

1 After emptying but before cleaning for purposes of performing the next required test and inspection prior to refilling; and

2 Unless otherwise approved by the competent authority for a period not to exceed six months beyond the date of expiry of the last periodic test and inspection, in order to allow the return of dangerous goods for proper disposal or recycling. Reference to this authorization should be entered in the dangerous goods shipping document.



13.115.7 When a tank, other than its shell is damaged it should not be allowed for use unless it has been repaired, so as to comply with these requirements. When the shell is damaged it should be repaired and retested in conformity with 13.115.8.

13.115.8 In all cases where cutting, burning or welding operations on the shell of a tank have been effected that work should be to the approval of the competent authority and a hydrostatic test to at least the original test pressure should be carried out.



13.115.9 A certificate from the competent authority or its approved inspecting agency affirming that the tank complies with the requirements of this Code should be issued and should be retained by the authority and the owners during the time the tank is in service. All information required in 13.117.1 and 13.117.2 should also be included in this certifi-cate.

13.116 Approval, testing and marking of type 6 tanks

13.116.1 Road tank vehicles are to be authorized for short international voyages only.

13.116.2 For any road tank vehicles intended for transport of a substance listed in the appendix to this subsection there should be in existence a valid certificate issued by or on behalf of the competent authority for road transport au-thorizing transport of that substance by road.

13.116.3 The competent authority for sea transport or a body authorized by that authority should issue additionally in re-spect of a road tank vehicle a certificate attesting compliance with the relevant design construction and equipment requirements of this subsection and, where appropriate the special requirements for the gases listed in the ap-pendix to this subsection. The certificate should list the gases allowed to be transported.

13.116.4 A road tank vehicle should be periodically tested and inspected in accordance with the requirements of the com-petent authority for road transport.

13.116.5 Road tank vehicles should be marked in accordance with 13.117. However where the marking required by the competent authority for road transport is substantially in agreement with that of 13.117.1 it will be sufficient to endorse the plate attached to the road tank vehicle with "IMO type 6".

13.117 Marking

13.117.1 Every tank should be fitted with a corrosion resistant metal plate permanently attached in a place readily accessi-ble for inspection. At least the following particulars should be marked on the plate in characters at least 3 mm in height by stamping, engraving, embossing or any similar method. If for reasons of tank arrangements the plate cannot be permanently attached to the shell the shell should be marked with at least those particulars required by a recognized pressure vessel code in a manner prescribed by that code.

The plate should be kept free of any paint to ensure that the markings will be legible at all times.


IMO tank type no.

Approval country

Approval number

Manufacturer's name or mark

Registration number

Year of manufacture



UN No. Gas Class and subsidiary

risk (s)

Maximum allow-able working

pressure (bar) (i) Small; (ii) Bare; (iii) Sun shield; (iv) Insulated.

Opening below liquid

level Pressure relief

Filling (kg/l)

Special requirements

1 2 3 4 5 6 7 8

1983 1-CHLORO-2,2,2-TRIFLUORO-ETHANE (REFRIGERANT GAS R 133a)

2.2

7.0 7.0 7.0 7.0

Allowed Normal 1.18

2035 1,1,1-TRIFLUOROETHANE (REFRIG-ERANT GAS R 143a) 2.1

31.0 27.5 24.2 21.8

Allowed Normal 0.76

2424 OCTAFLUOROPROPANE (REFRIGER-ANT GAS R 218) 2.2

23.1 20.8 18.6 16.6

Allowed Normal 1.07

2517 1,CHLORO-1,1-DIFLUOROETHANE (REFRIGERANT GAS R 142b)

2.1

8.9 7.8 7.0 7.0

Allowed Normal 0.99

2602 DICHLORODIFLUOROMETHANE AND DIFLUOROETHANE, AZEOTROPIC MIXTURE, with approximately 74% di-chlorodifluoromethane (REFRIGERANT GAS R 500)

2.2 20.0 18.0 16.0 14.5

Allowed Normal 1.01




risk (s)





Filling (kg/l)


1 2 3 4 5 6 7 8

3057 TRIFLUOROACETYL CHLORIDE 2.3

Corrosive

14.6 12.9 11.3 9.9

Not allowed see 13.108.3 1.17

The wall thickness should not be less than 8 mm. Wall thickness should be ultra-sonically verified at intervals midway between the peri-odic hydraulic tests.

3070 ETHYLENE OXIDE AND DICHLORODI-FLUOROMETHANE, MIXTURE, with not more than 12.5% ethylene oxide

2.2 14.0 12.0 11.0 9.0

Allowed see 13.108.3 1.09

3153 PERFLUORO(METHYL VINYL ETHER) 2.1 14.3 13.4 11.2 10.2

Allowed Normal 1.14

3159 1,1,1,2-TETRAFLUOROETHANE (RE-FRIGERANT GAS R 134a) 2.2

17.7 15.7 13.8 12.1

Allowed Normal 1.04

3161 LIQUEFIED GAS, FLAMMABLE, N.O.S. 2.1 see 13.102.6 Allowed Normal see 13.119

3163 LIQUEFIED GAS, N.O.S. 2.2 see 13.102.6 Allowed Normal see 13.119

IMDG CODE - PAGE 0106i (page 0106j follows) Amdt. 29-98



risk (s)





Filling (kg/l)


1 2 3 4 5 6 7 8

3220 PENTAFLUOROETHANE (REFRIGERANT GAS R 125) 2.2

34.4 30.8 27.5 24.5

Allowed Normal 0.95

3252 DIFLUOROMETHANE (REFRIGERANT GAS R 32) 2.1

43.0 39.0 34.4 30.5

Allowed Normal 0.78

3296 HEPTAFLUOROPROPANE (REFRIG-ERANT GAS R 227) 2.2

16.0 14.0 12.5 11.0

Allowed Normal 1.20

3297 ETHYLENE OXIDE AND CHLORO-TETRAFLUOROETHANE MIXTURE, with not more than 8.8% ethylene oxide

2.2 8.1 7.0 7.0 7.0

Allowed Normal 1.16

3298 ETHYLENE OXIDE AND PENTA-FLUOROETHANE MIXTURE, with not more than 7.9% ethylene oxide

2.2 25.9 23.4 20.9 18.6

Allowed Normal 1.02

3299 ETHYLENE OXIDE AND TETRA-FLUOROETHANE MIXTURE, with not more than 5.6% ethylene oxide

2.2 16.7 14.7 12.9 11.2

Allowed Normal 1.03

IMDG CODE - PAGE 0106j (page 0106k follows) Amdt. 28-96



risk (s)





Filling (kg/l)


1 2 3 4 5 6 7 8

3318 AMMONIA SOLUTION, with more than 50% ammonia

2.3 Corrosive see 13.102.6 Allowed see 13.108.3 see 13.119

3337 REFRIGERANT GAS R 404A 2.2 31.6 28.2 25.2 22.1

Allowed Normal 0.82

3338 REFRIGERANT GAS R 407A 2.2 32.3 29.0 25.7 22.4

Allowed Normal 0.94

3339 REFRIGERANT GAS R 407B 2.2 34.0 30.5 27.0 23.6

Allowed Normal 0.93

3340 REFRIGERANT GAS R 407C 2.2 30.2 27.0 24.1 21.4

Allowed Normal 0.95

IMDG CODE - PAGE 0106k (page 0107 follows) Amdt. 29-98


13.200 GENERAL REQUIREMENTS FOR PORTABLE TANKS AND ROAD TANK VEHICLES FOR REFRIGERATED LIQUEFIED GASES OF CLASS 2

13.201 Preamble

13.201.1 The requirements of this subsection apply to portable tanks (type 7 tanks) and road tank vehicles (type 8 tanks) intended for the transport of refrigerated liquefied gases of class 2. In addition to the requirements of this subsec-tion and unless otherwise specified, the applicable requirements of the International Convention for Safe Contain-ers (CSC), 1972, as amended, should be fulfilled by any portable tank which meets the definition of a "container" within the terms of that Convention. The International Convention for Safe Containers does not apply to offshore tank-containers that are handled in open seas. The design and testing of offshore tank-containers should take into account the dynamic lifting and impact forces that may occur when a tank is handled in open seas in adverse weather and sea conditions. The requirements for such tanks should be determined by the approving competent authority (see also MSC/Circ.613 in the annex at the end of this section). Such requirements should be based on MSC/Circ.860 Guidelines for the approval of offshore containers handled in open seas.

13.201.2 In order to take into account progress in science and technology, the use of alternative arrangements which offer at least equivalent safety in use in respect of compatibility with the properties of the substances transported and equivalent or superior resistance to impact, loading and fire may be considered by the national competent author-ity.

13.201.3 Existing tanks and their service equipment not conforming strictly to the requirements set forth, but having ac-ceptable alternatives, may be considered by the competent authority for approval. In the approval it should be clearly stated that the basis for the issue of the certificate is this paragraph. In the certificate the entry should read "Approved in accordance with 13.201.3 of the IMDG Code ".

13.201.4 The appendix* to this subsection comprises the list of dangerous substances and also indicates any special re-quirements which modify or supplement these general requirements for each particular substance.

13.201.5 Construction, equipment, testing, marking and operation of portable tanks and road tank vehicles should be sub-ject to acceptance by the competent authority of the country in which they are approved.

13.201.6 These requirements do not apply to rail tank-wagons, non-metallic tanks or tanks having a capacity of 1.000 litres or less.

13.202 Definitions

13.202.1 For the purposes of these requirements.

13.202.2 Type 7 tank means a thermally insulated portable tank fitted with items of service and structural equipment nec-essary for the transport of refrigerated liquefied gases. The portable tank should be capable of being transported, loaded and discharged without the need of removal of its structural equipment and should be capable of being lifted when full. It should not be permanently secured on board the ship.

* The appendix will need updating from time to time in the light of technical progress and to include new substances.



Its contents should not be loaded or discharged while the portable tank remains on board.

13.202.2.1 Type 8 tank means a road tank vehicle and includes a semi-trailer with a permanently attached thermally insu-lated tank fitted with items of service equipment and structural equipment necessary for the transport of refriger-ated liquefied gases. It should be fitted with permanent attachments such that it can be secured on board ship. However, its contents should not be loaded or discharged whilst the vehicle remains on board. A road tank vehicle should only be carried on short international voyages.

13.202.3 Tank means a construction which normally consists of:

1 a jacket and one or more inner shells where the space between the shell or shells and the jacket incorpo-rates thermal insulation and is exhausted of air (vacuum insulation); or

2 a jacket and an inner shell with ah intermediate layer of solid thermally insulating material (e.g. solid foam); or

3 an outer shell with an inner layer of solid thermally insulating material.

13.202.4 Shell means a pressure vessel proper, including openings and their closures.

13.202.5 Service equipment of a tank means filling and discharge, venting, safety, thermal-insulating devices and measuring instruments.

13.202.6 Structural equipment means the reinforcing, fastening, protective and stabilizing members external to a tank and includes for a road tank vehicle fastenings to running gear or chassis.

13.202.7 Maximum allowable working pressure (MAWP) means the maximum effective gauge pressure permissible at the top of the shell of a loaded tank in its operating position.

13.202.8 Test pressure means the maximum gauge pressure which arises in the shell during the pressure test.

13.202.9 Leakage test means a test which consists of subjecting the shell, complete with its service equipment, to an effective internal pressure equivalent to the MAWP. The procedure to be adopted should be approved by the competent authority.

13.202.10 Total mass means the mass of the portable tank or road tank vehicle with the heaviest load authorized for trans-port.

13.202.11 Holding time means the time that will elapse from the moment the liquid starts boiling at atmospheric pressure up to the moment the pressure of the tank contents reaches the MAWP under equilibrium conditions.

13.202.12 Minimum design temperature means the lowest contents temperature at which the tank can be used.

13.202.13 Short international voyage means an international voyage in the course of which a ship is not more than 200 miles from a port or place in which the passengers and crew could be placed in safety. Neither the distance between the last port of call in the country in which the voyage begins.



13.213.4 Before a portable tank is put into service, and thereafter at intervals midway between the inspections and tests provided in 13.213.3, the following tests and inspections should be performed:

1 a leakage test, where required; 2 a test of satisfactory operation of all service equipment; 3 an external inspection of the portable tank and its fittings with due regard to the gases transported; and 4 a vacuum reading where applicable. 13.213.5 The 2.5 year (midway) inspection and test may be carried out within 3 months of the specified date. The date of

the 2.5 year inspection should be durably marked on or as near as possible to the metal identification plate re-quired in 13.215.1. When marking is not done on the plate, the characters should be at least 32 mm in height and of a contrasting colour to the tank. A portable tank may not be filled and offered for transport after the date of expiry of the last 5 year or 2.5 year periodic inspection and test as required by 13.1.19.3 and 13.1.19.4/13.115.3 and 13.115.4/13.213.3 and 13.213.4. However, a portable tank filled prior to the date of expiry of the last periodic inspection and test may be transported for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection In addition, a portable tank may be transported after the date of expiry of the last periodic test and inspection.

1 After emptying but before cleaning, for purposes of performing the next required test and inspection prior to refilling; and

2 Unless otherwise approved by the competent authority for a period not to exceed six months beyond the date of expiry of the last periodic test and inspection, in order to allow the return of dangerous goods for proper disposal or recycling. Reference to this authorization should be entered in the dangerous goods shipping document.

13.213.6 When a portable tank is damaged it should not be allowed to be used until it has been repaired so as to comply with these requirements. When the shell is damaged it should be repaired and re-tested in conformity with 13.213.7.

13.213.7 In all cases where cutting, burning or welding operations on the shell of a portable tank have been carried out, that work should be to the satisfaction of the competent authority and a pressure test to at least the original test pressure should be carried out.

13.213.8 Certificates showing the results of the test should be issued by the competent authority. All information required in 13.215.1 and 13.215.2 should also be included in this certificate.

13.214 Approval, testing and marking of type 8 tanks

13.214.1 Road tank vehicles are to be authorized for short international voyages only.

13.214.2 For any road tank vehicle intended for transport of a substance listed in the appendix to this subsection there should be in existence a valid certificate issued by or on behalf of the competent authority for road transport au-thorizing transport of that substance by road.



13.214.3 The competent authority for sea transport or a body authorized by that authority should issue additionally in re-spect of a road tank vehicle a certificate attesting compliance with the relevant design construction and equipment requirements of this subsection and where appropriate the special requirements for the gases in the appendix to this subsection. The certificate should list the gases allowed to be transported.

13.214.4 A road tank vehicle should be tested and inspected in accordance with the requirements of the competent author-ity for road transport.

13.214.5 Road tank vehicles should be marked in accordance with 13.215. However where the marking required by the competent authority for road transport is substantially in agreement with that of 13.215.1 it will be sufficient to endorse the metal plate attached to the road tank vehicle with IMO type 8, the reference to holding time may be omitted.



13.215 Marking

13.215.1 Every tank should be fitted with a corrosion-resistant metal plate permanently attached in a place readily accessi-ble for inspection. At least the following particulars should be marked on the plate in characters at least 3 mm in height by stamping, engraving, embossing or any similar method.

If, for reasons of tank arrangements, the plate cannot be permanently attached to the shell, the shell should be marked with at least those particulars required by a recognized pressure vessel code in a manner prescribed by that code.

The plate should be kept free of any paint to ensure that the markings will be legible at all times.


IMO tank type No.

Approval country

Approval number

Manufacturers name or mark

Registration number

Year of manufacture

Test pressure (bar) / (MPa)* gauge

Maximum allowable working pressure (bar) / (MPa)* gauge

Water capacity at 20° C of each compartment (litres)

(The water capacity should be established to within 1% by practical test rather than by calculation).

Original pressure test date and witness identification

Code to which the shell is designed

Minimum design temperature (° C)

Maximum total mass (kg)

Unladen (tare) mass (kg)

Shell material

Month year and test pressure of most recent periodic test

month year (bar) / (MPa)* gauge

Stamp of expert who carried out most recent test

The names, in full of the gases for whose transport the tank is approved

Either "thermally insulated" or "vacuum-insulated"

* The unit used should be indicated.



15 SEGREGATION

15.1 General

15.1.1 The requirements of this section should apply to all cargo spaces on deck or under deck of all types of ships and to all cargo transport units (CTUs).

15.1.2 The International Convention for the Safety of Life at Sea, 1974, as amended, requires in regulation 6.1 of part A of chapter VII that incompatible goods shall be segregated from one another.

15.1.3 For the Implementation of this requirement, two substances or articles are considered mutually incompatible when their stowage together may result in undue hazards In case of leakage or spillage, or any other accident.

15.1.4 The extent of the hazard arising from possible reactions between incompatible dangerous goods may vary and so the segregation arrangements required should also vary as appropriate. Such segregation is obtained by maintain-ing certain distances between incompatible dangerous goods or by requiring the presence of one or more steel bulkheads or decks between them, or a combination thereof. Intervening spaces between such dangerous goods may be filled with other cargo compatible with the dangerous substances in question.

The following segregation terms are used throughout this Code:

.1 «AWAY FROM»;

.2 "Separated from";

.3 "Separated by a complete compartment or hold from";

.4 "Separated longitudinally by an intervening complete compartment or hold from".

15.1.5

These terms are defined in 15.2 and their use in regard to the different modes of sea transport is explained further in the other subsections of this section.

The general requirements for segregation between the various classes of dangerous goods are shown in the "segregation table" of 15.1.17. in addition to these general requirements, there may be a need to segregate a particular substance, material or article from other goods which could contribute to its hazard. Particular require-ments for segregation are indicated in the individual schedules and, in the case of conflicting requirements, always take precedence over the general requirements.

For example:

On the schedule for ACETYLENE, DISSOLVED, Class 2.1, UN No. 1001 the following particular segregation requirement is specified:

15.1.6

«SEPARATED FROM» chlorine.

15.1.6.1 Where the Code Indicates a single secondary hazard (one subsidiary risk label), the segregation requirements applicable to that hazard should take precedence where they are more stringent than those of the primary hazard.



15.1.6.2 Except for , the segregation requirements for substances, materials or articles having more than two hazards (two or more subsidiary risk labels) are given in the individual schedules.

For example:

The schedule for BROMINE CHLORIDE, class 2.3, subsidiary risks 5.1 and 8, UN No. 2901 specifies Segregation as for class 5.1 but «SEPARATED FROM» class 7".

15.1.7 In the case of segregation from combustible material this should be understood not to include packaging materials or dunnage.

15.1.8 Whenever dangerous goods are stowed together whether or not in a cargo transport unit the segregation of such dangerous goods from others should always be in accordance with the most stringent requirements for any of the dangerous goods concerned.

15.1.9 For the purposes of 15.1.6.1 the segregation requirements corresponding to a subsidiary risk label of are those for division 1.3.

15.1.10 Notwithstanding 15.1.6.1, 15.1.6.2 and 15.1.13, substances of the same class may be stowed together without regard to segregation required by secondary hazards (subsidiary risk label (s)), provided the substances do not react dangerously with each other and cause.

1 combustion and/or evolution of considerable heat, 2 evolution of flammable, toxic or asphyxiant gases, 3 the formation of corrosive substances; or 4 the formation of unstable substances. 15.1.11 Where the individual schedule specifies that "Segregation as for class " applies, the segregation requirements

applicable to that class in table 15.1.17 should be applied However, for the purposes of interpreting paragraph 15.1.10 which permits substances of the same class to be stowed together provided they do not react dangerously with each other, the segregation requirements of the class as represented by the primary hazard class in the indi-vidual schedule should be applied

For example UN No. 2965 - BORON TRIFLUORIDE DIMETHYL ETHERATE, Class 4.3 The schedule specifies "Segregation as for class 3, but ' away from' classes 3, 4.1 and 8"

For the purposes of establishing the segregation requirements applicable in table 15.1.17, the class 3 column should be consulted

This substance may be stowed together with other class 4.3 substances when they do not react dangerously with each other see 15.1.10

15.1.12 No segregation need be applied between dangerous goods of different classes which comprise the same sub-stance but vary only in their water content, e. g. sodium sulphide in classes 4.2 and 8

15.1.13 Where for the purposes of segregation, terms such as " 'away from' class " are used in the individual schedules "class is deemed to include

1 all substances within class and

IMDG CODE - PAGE 0128 (page 0128a follows) Amdt 29-98


2 all substances for which a subsidiary risk label of ' class ' is required. 15.1.14 A closed cargo transport unit means a unit which totally encloses the contents by permanent structures. An open

cargo transport unit means a unit which is not a closed cargo transport unit. Cargo transport units with fabric sides or tops are not closed cargo transport units for the purposes of this section.

15.1.15 For the purposes of segregating incompatible dangerous goods, the terms compartment and hold mean a cargo space enclosed by steel bulkheads or shell plating and by steel decks. The boundaries of such a space should be resistant to fire and liquid.

15.1.16 Stowage in a shelter-tween-deck cargo space is not considered to be on-deck stowage.

IMDG CODE - PAGE 0128a (page 0729 follows) Amdt 29-98


15.1.17 Segregation table.

The following table shows the general requirements for segregation between the various classes of dangerous goods.

SINCE THE PROPERTIES OF SUBSTANCES OR ARTICLES WITHIN EACH CLASS MAY VARY GREATLY, THE INDIVIDUAL SCHEDULES SHOULD ALWAYS BE CONSULTED FOR PARTICULAR REQUIREMENTS FOR SEGREGATION AS, IN THE CASE OF CONFLICTING REQUIREMENTS. THESE TAKE PRECEDENCE OVER THE GENERAL REQUIREMENTS.

SEGREGATION SHOULD ALSO TAKE ACCOUNT OF A SINGLE SUBSIDIARY RISK LABEL.

1.1 1.3 1.2 CLASS 1.5 1.6

1.4 2.1 2.2 2.3 3 4.1 4.2 4.3 5.1 5.2 6.1 6.2 7 8 9

Explosives 1.1, 1.2, 1.5 * * * 4 2 2 4 4 4 4 4 4 2 4 2 4 X Explosives 1.3, 1.6 * * * 4 2 2 4 3 3 4 4 4 2 4 2 2 X Explosives 1.4 * * 2 1 1 2 2 2 2 2 2 X 4 2 2 X Flammable gases 2.1 4 4 2 X X X 2 1 2 X 2 2 X 4 2 1 X Non-toxic non-flammable gases 2.2 2 2 1 X X X 1 X 1 X X 1 X 2 1 X X Toxic gases 2.3 2 2 1 X X X 2 X 2 X X 2 X 2 1 X X Flammable liquids 3 4 4 2 2 1 2 X X 2 1 2 2 X 3 2 X X Flammable solids (including self reactive and related substances and desensitized explosives)

4.1 4 3 2 1 X X X X 1 X 1 2 X 3 2 1 X

Substances liable to spontaneous combustion 4.2 4 3 2 2 1 2 2 1 X 1 2 2 1 3 2 1 X

Substances which, in contact with water emit flammable gases 4.3 4 4 2 X X X 1 X 1 X 2 2 X 2 2 1 X

Oxidizing substances (agents) 5.1 4 4 2 2 X X 2 1 2 2 X 2 1 3 1 2 X Organic peroxides 5.2 4 4 2 2 1 2 2 2 2 2 2 X 1 3 2 2 X Toxic substances 6.1 2 2 X X X X X X 1 X 1 1 X 1 X X X Infectious substances 6.2 4 4 4 4 2 2 3 3 3 2 3 3 1 X 3 3 X Radioactive materials 7 2 2 2 2 1 1 2 2 2 2 1 2 X 3 X 2 X Corrosives 8 4 2 2 1 X X X 1 1 1 2 2 X 3 2 X X Miscellaneous dangerous sub-stances and articles 9 X X X X X X X X X X X X X X X X X

Numbers and symbols relate to the following terms as defined in this section 1 - «AWAY FROM» 2 - "Separated from" 3 – “Separated by a complete compartment or hold from" 4 - "Separated longitudinally by an intervening complete compartment or hold from" X - The segregation, if any, is shown in the individual schedules * - See subsection 6.2 of the introduction to for segregation within

IMDG CODE - PAGE 0129 Amdt 29-98


15.1.17 For the purposes of the segregation requirements for the various modes of carriage by sea this section has been subdivided as follows:

15.2 Segregation of packages.

15.3 Segregation of freight containers on board container ships. 15.4 Segregation of cargo transport units on board roll-on roll-off ships. 15.5 Segregation in shipborne barges and on board barge-carrying ships.

15.6 Segregation between bulk materials possessing chemical hazards and dangerous goods in packaged form.

15.2 Segregation of packages.

15.2.1 Applicability

15.2.1.1 The requirements of this subsection apply to the segregation of

.1 packages containing dangerous goods and stowed in the conventional way,

.2 dangerous goods within cargo transport units (as listed in 7.3.1.1 of this General Introduction); and

.3 dangerous goods stowed in the conventional way from those packed in such cargo transport units.

15.2.2 Segregation of packages containing dangerous goods and stowed in the conventional way. 15.2.2.1 Definitions of the segregation terms.

Legend:

(1) Reference package ....................................................................................

(2) Package containing incompatible goods ......................................................

(3) Deck resistant to fire and liquid .....................................................................

NOTE: Full vertical lines represent transverse bulkheads between cargo spaces (compartments or holds) resistant to fire and liquid.



15.4 Segregation of cargo transport units on board roll-on roll-off ships

15.4.1 Applicability

15.4.11 The requirements of this subsection apply to the segregation of cargo transport units which are carried on board roll on roll-off ships or in roll-on roll-off cargo spaces.

15.4.12 For roll-on roll off ships which carry freight containers on decks or in holds and when these cargo spaces are prop-erly arranged for the permanent stowage of such containers during transport, the requirements of subsection 15.3 should apply to such spaces.

15.4.13 For roll on roll-off ships which incorporate conventional cargo spaces or any other method of stowage the appropri-ate subsection of this section should apply to the relevant cargo space.



HORIZONTAL

CLOSED VERSUS CLOSED CLOSED VERSUS OPEN OPEN VERSUS OPEN SEGREGATION RE-

QUIREMENT ON DECK UNDER DECK ON DECK UNDER DECK ON DECK UNDER DECK

«AWAY FROM» FORE AND AFT

NO RESTRIC-TION NO RESTRICTION NO RESTRICTION

NO RESTRICTION

AT LEAST 3 METRES

AT LEAST 3 ME-TRES

1 ATHWART

SHIPS NO

RESTRICTION NO RESTRICTION

NO RESTRICTION

NO RESTRICTION AT LEAST 3 METRES

AT LEAST 3 METRES

"SEPARATED FROM" FORE AND AFT

AT LEAST 6 METRES

AT LEAST 6 METRES OR

ONE BULKHEAD

AT LEAST 6 METRES

AT LEAST 6 METRES OR

ONE BULKHEAD

AT LEAST 6 METRES

AT LEAST 12 METRES OR ONE

BULKHEAD

2 ATHWART-SHIPS

AT LEAST 3 METRES

AT LEAST 3 METRES OR ONE

BULKHEAD

AT LEAST 3 METRES

AT LEAST 6 METRES

OR ONE BULK-HEAD

AT LEAST 6 METRES

AT LEAST 12 METRES or ONE

BULKHEAD

"SEPARATED BY A COMPLETE COM-

PARTMENT

FORE AND AFT

AT LEAST 12 METRES

AT LEAST 24 METRES DECK

AT LEAST 24 METRES

AT LEAST 24 METRES +

DECK

AT LEAST 36 METRES

TWO DECKS OR TWO BULKHEADS

3 ATHWART SHIPS

AT LEAST 12 METRES

AT LEAST 24 METRES + DECK

AT LEAST 24 METRES

AT LEAST 24 METRES + DECK

AT LEAST 36 METRES PROHIBITED

SEPARATED LONGITUDI-NALLY BY AN INTERVEN-

ING COMPLETE COMPARTMENT OR HOLD

FROM"

FORE AND AFT

AT LEAST 36 METRES

TWO BULK-HEADS

OR AT LEAST 36 METRES + TWO

DECKS

AT LEAST 36 METRES

AT LEAST 48 METRES INCLUD-ING TWO BULK-

HEADS

AT LEAST 48 METRES PROHIBITED

4 ATHWART-SHIPS

PROHIBITED PROHIBITED PROHIBITED PROHIBITED PROHIBITED PROHIBITED

NOTE: ALL BULKHEADS AND DECKS SHOULD BE RESISTANT TO FIRE AND LIQUID



17 CARRIAGE OF DANGEROUS GOODS ON ROLL-ON ROLL-OFF SHIPS

17.1 General

17.1.1 Because of the structural differences between roll-on roll-off ships and conventional ships, this section contains alternative and special or additional provisions for the transport of dangerous goods on these ships.

17.2 Applicability

17.2.1 The provisions of this section should apply to the loading and unloading of dangerous goods by means of vehicles, containers and other cargo transport units via ramps, etc. and to the loading and unloading of units by means of fork-lift trucks, cranes etc.

17.3 Definitions

17.3.1 For the purposes of this section, unit means any vehicle, container, tank intermediate bulk container (IBC), unit load or receptacle which is loaded and unloaded separately as one piece*.

17.3.2 Vehicle means any road freight or tank vehicle or railway freight or tank wagon permanently attached to an under frame and wheels or chassis and wheels, which is loaded and unloaded as a unit It also includes a trailer, semi-trailer or similar mobile unit, except those used solely for the purposes of loading and unloading*.

17.3.3 For the purposes of this section, the term container includes a road or rail demountable container rigid or collapsible, having a net mass of more than 400 kg, a freight container , a demountable or portable tank a pressure vessel or any other receptacle having a capacity of 450 litres or more.

17.3.4 Closed type unit means a unit in which dangerous goods are totally enclosed by sufficiently strong boundaries such as a freight container , a tank or a vehicle Units with fabric sides or tops are not closed type units.

17.3.5 Ro-Ro ship (roll-on roll-off ship) means a ship which has one or more decks, either closed or open, not normally subdivided in any way and generally running the entire length of the ship, carrying goods which are normally loaded and unloaded in a horizontal direction.

17.3.6 Weather deck is a deck which is completely exposed to the weather from above and from at least two sides.

17.3.7 On Weather deck, for the purposes of this section, is equivalent to stowage "on deck" (see also appendix to section 14 of this General Introduction).

* For reasons of convenience, dangerous goods are generally referred to in this section as being loaded or packed into a unit or vehi-cle. Such references should be interpreted as including loading or packing on to a unit or vehicle, where the context so requires. The word "in", when used in relation to a unit or vehicle should be construed accordingly.

MDG CODE - PAGE 0141 Amdt. 27-94


17.3.8 Ro-Ro cargo space is a space not normally subdivided in any way and extending to either a substantial length or the entire length of the ship in which goods in or on rail or road cars, vehicles (including road or rail tankers) trail-ers, containers, pallets demountable tanks or in or on similar stowage units or other receptacles can be loaded and unloaded normally in a horizontal direction.

17.3.9 Open Ro-Ro cargo space is a Ro-Ro cargo space either open at both ends or open at one end and provided with adequate natural ventilation effective over its entire length through permanent openings in the side plating or deck-head to the satisfaction of the Administration.

17.3.10 Closed Ro-Ro cargo space is a Ro-Ro cargo space which is neither an open Ro-Ro cargo space nor a weather deck.

17.3.11 Special category space is an enclosed space above or below the bulkhead deck, intended for the carriage of motor vehicles with fuel in their tanks for their own propulsion, into and from which such vehicles can be driven and to which passengers have access.

13.7.12 Vehicle deck, for the purposes of this section is either a closed Ro-Ro cargo space an open Ro-Ro cargo space, a special category space or a weather deck.

17.4 Marking, labelling and placarding.

17.4.1 For marking, labelling and placarding requirements applicable to roll-on roll-off traffic see sections 7 and 8 of this General Introduction.

17.5 General handling.

17.5.1 Loading and unloading operations on each vehicle deck should take place under the surveillance of either a work-ing party consisting of officers and other crew members or responsible persons appointed by the master

17.5.1.1 Passengers and other unauthorized persons should be excluded from vehicle decks on which dangerous goods have been loaded All doors leading directly to these decks should be securely closed during the voyage and no-tices or signs prohibiting entrance to such decks should be conspicuously displayed.

17.5.1.2 During the voyage, access to such decks by passengers and other unauthorized persons should only be permitted when such persons are accompanied by an authorized crew member.

17.5.1.3 The transport of dangerous goods should be prohibited on any vehicle deck on which the foregoing requirements cannot be met.

17.5.2 Closing arrangements for the openings between Ro-Ro cargo spaces and machinery and accommodation spaces should be such as to avoid the possibility of dangerous vapours and liquids entering such spaces Such openings should normally be kept securely closed when dangerous cargo is on board except to permit access by authorized persons or for emergency use.

17.5.3 Flammable gases or liquids having a flashpoint of 23°C c.c. or less should not be stowed in a closed Ro-Ro space or special category space unless;

- the design, construction and equipment of the space comply with the requirements of Regulation II 2/54 of SOLAS as amended and the ventilation system is operated to maintain at least six air changes per hour, or;



- the ventilation system of the space is operated to maintain at least ten air changes per hour and non-certified safe electrical systems in the space are capable of being isolated by means other than removal of fuses in the event of failure of the ventilation system or any other circumstance likely to cause accumu-lation of flammable vapours.

Otherwise stowage is restricted to on deck only.

17.5.4 Certain dangerous goods are required to be stowed in a mechanically ventilated space' When such goods are carried in a closed Ro-Ro cargo space or a special category space this space should be mechanically ventilated.

17.5.5 Mechanically operated refrigeration or heating equipment fitted to any unit should not be operated during the voy-age when stowed in a dosed Ro-Ro cargo space or a special category space.

17.5.6 Electrically operated refrigeration or heating equipment fitted to any unit stowed in a closed Ro-Ro cargo space or special category space should not be operated when flammable gases or liquids having a flashpoint of 23°C c.c. or less may be present in the unit or in the same space, unless;

- the design, construction and equipment of the space comply with the requirements of Regulation II-2/54 of SOLAS as amended and the refrigeration or heating equipment of the unit complies with paragraph 21.4 of this General Introduction, or;

- the ventilation system of the space is operated to maintain at least ten air changes per hour and all electri-cal systems in the space are capable of being isolated by means other than removal of fuses in the event of ventilation failure or other circumstance likely to cause accumulation of flammable vapours;

17.5.7 The master of a ship carrying dangerous goods on vehicle decks should ensure that during loading and unloading operations and during the voyage regular inspections of these decks are made by an authorized crew member or responsible person in order to achieve early detection of any hazard.

17.5.8 Empty units not gas-free, or loaded with empty packagings or receptacles not gas-free, should comply with the provisions applicable to the products last contained in the unit packagings or receptacles.

17.6 Stowage, segregation and securing of units

17.6.1 Stowage of units on board roll-on roll off ships.

17.6.1.1 Units loaded with dangerous goods should be stowed in such a way that they are accessible at all times especially for fire fighting.

17.6.1.2 Stowage of tanks containing dangerous goods should be in accordance with the requirements of the individual schedules and section 14 of this General Introduction.

17.6.1.3 Stowage of dangerous goods in freight containers should be in accordance with the requirements of the individual schedules and section 12 of this General Introduction.

17.6.1.4 Ro-Ro ships may carry dangerous goods in units or stowed in the conventional way on vehicle decks, in cargo holds or on weather decks. The provisions for such stowage should be in compliance with the relevant provisions laid down elsewhere in this Code.



17.6.1.5 Dangerous goods required to be carried "on deck only" should not be carried on closed vehicle decks, but may be carried on open vehicle decks when authorized by the competent authority concerned.

17.6.1.6 Units packed or loaded with flammable gases or liquids having a flashpoint of 23°C c.c. or less and carried on deck should be stowed «AWAY FROM» (as defined in 15.1.13 of this Genera! Introduction) possible sources of igni-tion.

17.6.1.7 For "containers under fumigation", see the schedule on page 9025-1 in class 9 and section 12.12.



17.6.2 General stowage precautions for substances harmful to the marine environment (MARINE POLLUTANTS).

17.6.2.1 Where stowage is permitted on deck or under deck, units loaded with marine pollutants should preferably be stowed under deck, except when a weather deck provides equivalent protection.

17.6.2.2 Where stowage on deck only is required, preference should be given to the stowage of units loaded with marine pollutants on well-protected decks or to stowage inboard in sheltered areas of exposed decks.

17.6.3 Segregation of dangerous goods within units.

17.6.3.1 Dangerous goods which have to be segregated from each other should not be loaded into the same unit. However, dangerous goods which should be separated «AWAY FROM» each other may be loaded into the same unit with the approval of the competent authority concerned In such cases an equivalent standard of safety should be main-tained.

17.6.4 Segregation of units on board roll-on roll-off ships.

17.6.4.1 Requirements in this respect are laid down in section 15 of this General Introduction.

17.6.5 Securing of cargo transport units*.

17.6.5.1 On roll-on roll-off ships carrying dangerous goods, all units should be secured in accordance with SOLAS Chapter VII, regulation 6.6 (Cargo Securing Manual) and all securing should be completed before the ship leaves the berth.

17.7 Packing or loading of dangerous goods into a unit

17.7.1 The load carrying portion of a unit into which dangerous goods are to be loaded should be examined visually for damage and, if there is evidence of damage, the unit should not be used.

17.7.2 Irrelevant labels, placards and marine pollutant marks should be removed or masked before loading dangerous goods into a unit.

17.7.3 When dangerous goods form only part of the contents of a unit, they should preferably be loaded into the unit so as to be accessible.

* See also MSC/Circ. 745 on the Guidelines for the Preparation of the Cargo Securing Manual in the Supplement to this Code



18 DANGEROUS GOODS IN LIMITED QUANTITIES 18.1

The requirements of this section concern the transport of dangerous goods of certain classes packed in limited quanti-ties. The quantity limitations are specified in 18.3, but are subject to the exemptions provided elsewhere in this section. The full requirements of this Code apply equally to limited quantities except as provided elsewhere in this section.

18.2 The requirements contained in this section do not apply to:

1 Explosives of

2 Gases of (with exception of AEROSOLS, UN No. 1950) which exhibit a flammable corrosive, oxidizing or toxic risk;

3 Self-reactive and related substances and desensitized explosives of class 4.1; 4 Substances of class 4.2 which are liable to spontaneous combustion; 5 Organic peroxides of class 5.2 requiring temperature control; 6 Infectious substances of class 6.2; 7 Radioactive materials of class 7; 8 Dangerous goods in packaging group I, and;

9 ASBESTOS, UN Nos. 2212 and 2590, POLYCHLORINATED BIPHENYLS, UN No. 2315, POLYHALO-GENATED BIPHENYLS and POLYHALOGENATED TERPHENYLS, UN Nos. 3151 and 3152 c class 9.

18.3 Quantity limitations

Class Packaging group State Maximum quantity per inner packaging

2 a

Gas 120 ml (maximum inner volume in metal, plastics or glass

packaging) or 1000 ml b (AEROSOLS)

3 II Liquid 1l b 3 III Liquid 5 l b 4.1 c II Solid 500 g 4.1 c III Solid 3kg d

4.3 II Liquid or solid 500 g 4.3 III Liquid or solid 1 kg d

5.1 II Liquid or solid 500 g 5.1 III Liquid or solid 1 kg d

5.2 e II Solid 100 g 5.2 e II Liquid 25 ml 5.2 f II Solid 500 g 5.2 f II Liquid 125 ml

N.B. See footnotes on next page



Class Packaging group State Maximum quantity per inner packaging 6.1 II Solid 500 g 6.1 II Liquid 100 ml 6.1 III Solid 3 kg d 6.1 III Liquid 1 / b 8 II Solid 1 kg d 8 II Liquid 500 ml g 8 III Solid 2 kg d 8 III Liquid 1 / b 9 h II Solid 3 kg d 9 h II Liquid 1 / b 9 h III Solid 5 kg d 9 h III Liquid 5 / b

a Excluding gases (with the exception of AEROSOLS UN No.1950) which exhibit a flammable, corrosive, oxidizing or toxic risk.

b 500 ml for severe marine pollutants. c Excluding self reactive and related substances and desensitized explosives. d 500 g for severe marine pollutants. e The organic peroxide should be of type B or C and should not require temperature control. See introduction to

class 5.2.

f The organic peroxide should be of type D,E or F and should not require temperature control See sections 3 and 10.1 of the introduction to class 5.2.

g Glass porcelain or stoneware inner packagings should be enclosed in a compatible and rigid intermediate pack-aging.

h Excluding ASBESTOS UN Nos. 2212 and 2590 POLYCHLORINATED BIPHENYLS, UN No. 2315 and POLY-HALOGENATED BIPHENYLS AND POLYHALOGENATED TERPHENYLS, UN Nos. 3151 and 3152.

18.4 Packing

18.4.1 Dangerous goods transported according to these special requirements should be packaged only in inner packag-ings placed in a suitable outer packaging. The packagings should meet the requirements of Annex I, sections 3132 and 3.4 to 3.8 and be so designed that they meet the construction requirements of Annex I, section 7. The total gross mass of a package should not exceed 30 kg and should, in no case exceed that permitted in the indi-vidual schedules for the substances concerned.

18.4.2 Shrink- or stretch-wrapped trays meeting the conditions of Annex I, sections 3.1, 3.2 and 3.4 to 3.8 are acceptable as outer packagings for articles or inner packagings containing dangerous goods transported in accordance with these special requirements, except that inner packagings that are liable to break or be easily punctured, such as those made of glass, porcelain, stoneware or certain plastics, materials, etc. should not be transported in such packagings. The total gross mass of the package should not exceed 20 kg.



18.5 Stowage

18.5.1 Notwithstanding the stowage requirements given in the schedules, dangerous goods carried under the provisions of this section are allocated to stowage category A.

18.6 Segregation

18.6.1 Different dangerous goods in limited quantities may be packaged in the same outer packaging, provided the segre-gation requirements of section 15 are taken into account and the goods will not interact dangerously in the event of leakage.

18.6.2 The segregation requirements of section 15 of this General Introduction are not applicable for packagings containing dangerous goods in limited quantities or in relation to other dangerous goods.

18.7 Marking and labelling

18.7.1 Packages of dangerous goods transported in accordance with the special requirements of this section:

.1 need not be labelled nor bear the MARINE POLLUTANT mark;

.2 should, unless otherwise provided, be marked with either; .2.1 the proper shipping name together with the UN number; or .2.2 the words "ddaannggeerroouuss ggooooddss iinn lliimmiitteedd qquuaannttiittiieess ooff ccllaassss//ccllaasssseess............" which should be regarded as the proper shipping name, in which case no UN Number need be marked on the packaging.

18.7.2 Cargo transport units containing dangerous goods in only limited quantities need not be placarded. They should, however, be suitably marked on the exterior as "LIMITED QUANTITIES".

18.8 Documentation

18.8.1 In addition to the requirements for documentation specified in section 9 of this Genera] Introduction, the words "lim-ited quantity" should be included on the dangerous goods declaration together with the description of the shipment.

18.8.2 For AEROSOLS (UN No. 1950) no division is assigned and the class to be shown on the dangerous goods declara-tion is "2" (see 9.3.2).

18.9 Exemptions

18.9.1 Limited quantities of dangerous goods for personal or household use that are packaged and distributed in a form intended or suitable for safe through retail agencies may be exempted from marking of the proper shipping name and UN Number on the packaging.



19 CARRIAGE OF DANGEROUS GOODS IN SHIPBORNE BARGES ON BARGE-CARRYING SHIPS

19.1 General

19.1.1 Because of the structural differences of barge-carrying ships from conventional ships, this section contains alterna-tive and special or additional provisions for the transport of packaged dangerous goods or solid bulk materials pos-sessing chemical hazards on these ships.

19.2 Applicability

19.2.1 The provisions of this section are applicable to shipborne barges in which packaged dangerous goods or solid bulk materials possessing chemical hazards are carried while aboard barge-carrying ships or barge feeder vessels.

19.2.2 The provisions of this section are not intended to apply to shipborne barges designed for carriage aboard barge-carrying ships while the shipborne barges are operating independently of the barge-carrying ship.

19.2.3 Barges used for the shipborne carriage of packaged dangerous goods or solid bulk materials possessing chemical hazards should be of proper design and adequate strength to resist the stresses imposed by the conditions of the services in which they are employed and they should be adequately maintained. Shipborne barges should be ap-proved in accordance with requirements for certification of a recognized classification society, or any organization approved by and acting on behalf of the competent authority of the countries concerned.

19.2.4 Except as otherwise specified in this section, all the provisions laid down for each substance in this Code should apply to the carriage of packaged dangerous goods or solid bulk materials possessing chemical hazards in ship-borne barges on barge-carrying ships.

19.2.5 The provisions of this section apply only to shipborne barges of steel construction. Packaged dangerous goods or solid bulk materials possessing chemical hazards should only be carried in shipborne barges constructed of other materials, including the hatch covers, under conditions specified by the competent authority concerned.

19.3 Definitions

19.3.1 Shipborne barge or barge means, for the purposes of this section, an independent, non-self-propelled vessel, spe-cially designed and equipped to be lifted in a loaded condition and stowed aboard a barge-carrying ship or barge feeder vessel.

19.3.2 Barge-carrying ship means a ship specially designed and equipped to carry shipborne barges.

19.3.3 Barge feeder vessel means a vessel specially designed and equipped to transfer shipborne barges to or from a barge-carrying ship.

19.3.4 Loading and unloading means the placement or removal of cargo into or out of a shipborne barge.

19.3.5 Stowage means, for the purposes of this section, the placement of a shipborne barge aboard the barge-carrying ship or barge feeder vessel.



21 CONTROLLED TEMPERATURE REQUIREMENTS

21.1 Preamble

21.1.1 If the temperature of certain substances (e.g. organic peroxides and self-reactive and related substances) exceeds a value which is typical of the substance as packaged for transport, a self-accelerating decomposition, possibly of explosive violence, may result. To prevent such decomposition, it is necessary to control the temperature of the substance during transport. Other substances not requiring temperature control for safety reasons may be trans-ported under controlled temperature conditions for commercial reasons.

21.1.2 The requirements for the temperature control of certain specified substances are based on the assumption that the temperature in the immediate surroundings of the cargo does not exceed 55°C during transport and attains this value for a relatively short time only during each period of 24 hours.

21.1.3 If a substance which is not normally temperature-controlled is transported under conditions where the temperature may exceed 55°C, it may require temperature control; in such cases adequate measures should be taken.

21.2 Definitions

21.2.1 Control temperature is the maximum temperature at which certain substances (e.g. organic peroxides and self-reactive and related substances) can be safely transported during a prolonged period of time.

21.2.2 Emergency temperature is the temperature at which emergency procedures should be implemented.

21.2.3 Self-accelerating decomposition temperature (SADT)* is the lowest temperature at which self-accelerating decom-position may occur for a substance in the packaging as used in transport.

21.2.3.1 The relationship between SADT, the control temperature and the emergency temperature is as follows:

SADT Control temperature Emergency temperature 20°C or less 20°C below SADT 10°C below SADT over 20°C to 35°C 15°C below SADT 10°C below SADT over 35°C 10°C below SADT 5°C below SADT

21.3 General requirements

21.3.1 The substances for which a control temperature and an emergency temperature are indicated in the individual schedules should be transported under conditions of temperature control such that the temperature of the immedi-ate surroundings of the cargo does not exceed the control temperature.

* The self-accelerating decomposition temperature (SADT) should be determined in accordance with the latest version of the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria. Test methods for determining flammability are given In Part III, section 32.4 of the United Nations Recommendations on the Transport of Dan-gerous Goods, Manual of Tests and Criteria. Because organic peroxides may react vigorously when heated, it is recom-mended to determine their flashpoint using small sample sizes such as described in ISO 3679.



21.3.2 The actual transport temperature may be lower than the control temperature but should be selected so as to avoid dangerous separation of phases.

21.3.3 If, during transport the control temperature is exceeded, an alerting procedure should be initiated involving either repair of the refrigeration machinery or an increase in the cooling capacity (e.g. by adding liquid or solid refrigerants). If an adequate cooling capacity is not restored, emergency procedures, including preparation for disposal of the cargo, together with temperature checks at frequent intervals, should be started.

21.4 Methods of temperature control.

21.4.1 The suitability of a particular means of temperature control for transport depends on a number of factors. Among those to be considered are:

1 the control temperature (s) of the substance (s) to be transported; 2 the difference between the control temperature and the anticipated ambient temperature conditions;

3 the effectiveness of the thermal insulation of the cargo transport unit. The overall heat-transfer coefficient should not be more than 0.4 W/m2* K for freight containers and 0.6 W/m2* K for tanks;

4 the duration of the voyage.

21.4.2 Suitable methods for preventing the control temperature from being exceeded are in order of increasing capability:

1 thermal insulation, provided that the initial temperature of the substance is sufficiently below the control tem-perature;

2 thermal insulation and coolant system, provided that:

2.1 an adequate quantity of non-flammable coolant (e.g. liquid nitrogen or solid carbon dioxide) allowing a reason-able margin for delay, is carried;

2.2 liquid oxygen or air is not used as coolant. 2.3 there is a uniform cooling effect even when most of the coolant has been consumed; and 2.4 the need to ventilate the transport unit before entering is clearly indicated by a warning on the door (s).

3 single mechanical refrigeration provided that the unit is thermally insulated and for substances with a flashpoint lower than the sum of the emergency temperature plus 5°C explosion-proof electrical fittings are used within the coolant compartment to prevent ignition of flammable vapours from the substances;

4 combined mechanical refrigeration system and coolant system, provided that: 4.1 the two systems are independent of one another; and 4.2 the requirements of 21.4.2.2 and 21.4.2.3 are met. 5 dual mechanical refrigeration system, provided that:

5.1 apart from the integral power supply unit, the two systems are independent of one another;

5.2 each system alone is capable of maintaining adequate temperature control; and

5.3 for substances with a flashpoint lower than the sum of the emergency temperature plus 5°C explosion proof electrical fittings are used within the coolant compartment to prevent ignition of flammable vapours from the substances.



Survey Manager Australian Maritime Safety Authority

3rd Floor P.O. Box 1332 22 Queen Street Fremantie WA 6160 Fremantle WA6160

AUSTRALIA continued

Tel.+ 61 9 430 2100 Telefax+ 619 430 4757

Marine Surveyor Australian Maritime Safety Authority

Suite 4 P.O. Box 1 79 Ansett Building Port Hedland WA 6721 Wedge Street Port Hedland WA 6721

Tel.+ 61 91 73 2598 Telefax+ 61 91 73 2887

Senior Marine Surveyor Australian Maritime Safety Authority P.O. Box 860 Karratha WA 6714

Tel.+ 61 91 85 2640 Telefax+ 61 91 44 2023 Bahamas Maritime Authority

Bahamas House 10 Chesterfield Street London W1X 8AH United Kingdom

Tel.+ 44 171 290 1500 Telefax+ 44 171 290 1540

BAHAMAS

Telex 892617 BAHREG G

Head Office

Dutch Ministerie van Verkeer en Infrastructuur Bestuur van de Maritieme Zaken en van de Scheepvaart Aarlenstraat 104 1040 Brussel

Tel+ 32 2 233 1211 Telefax+ 32 2 230 30 02

BELGIUM

Telex 61880 VERTRA B

French

Ministere des Communications et de I' Infrastructure Administration des Affaires Maritimes et de la Navigation rue d' Arlon 104 1040 Bruxelles

Tel.+ 32 2 233 12 11 Telefax+ 32 2 230 30 02

Telex 61880 VERTRA B



BELGIUM Antwerp Office continued Ministerie van Verkeer en Infrastructuur Bestuur van de Maritieme Zaken en van de Scheepvaart Zeevaartinspektie Tavernierkaai 3 Loodsgebouw 2000 Antwerpen Telefax + 32 3 233 67 60 Tel.+ 32 3 222 08 11 Telex 35028 MARPOL B Ostend Office Ministerie van Verkeer en Infrastructuur Bestuur van de Maritieme Zaken en van de Scheepvaart Zeevaartinspektie Sir Winston Churchillkaal 2 8400 Oostende Tel. + 32 59 55 28 11 Telefax + 32 59 55 28 88

Telex 82125 LOODSW B BRAZIL Directoria de Portos e Costas Departamento do Material da Marinha Mercante (DPC-20) Rua 1° de marco, 118/16 andar 20010 Rio de Janeiro RJ Tel. + 55 21 216 5203 Telefax + 55 21 216 5402 + 55 21 216 5202 + 55 21 216 5207 + 55 21 216 5217 BULGARIA Main Office State Shipping Inspectorate Ministry of Transport Levski Str 9/11 1000 Sofia Tel. + 359 2 88 55 29 Sections 1 State Shipping Inspectorate Chervenoarmejski Blvd 1 Varna Tel. + 359 52 2 54 09 2 State Shipping Inspectorate Burgas-port Burgas Tel. + 359 56 4 31 40

IMDG CODE - PAGE 0160d (page 0160e follows) Amdt. 28-96


CANADA The Chairman Canada Building 344 Slater Street Ottawa Ontario K1A 0N7 Tel.+ 1 613 991 3143 Telefax + 1 613 993 8196 Telex 0533128 COASTGUARD OTT The Chairman Board of Steamship Inspection Transport Canada - Marine Safety Tower C Place de Ville 330 Sparks Street 11th floor Ottawa Ontario K1A ON8 Tel.+ 1 613991 3132 Telefax +1 613 993 8196 + 1 613 991 3143 + 1 613 991 3140 CHILE Direccion General del Territorio Maritime y de Marina Mercante Direccion de Seguridad y Operaciones Maritimas Depto Prevencion de Riesgos Errazuriz 537 Valparaiso Tel.+ 56 32 208256 Telefax + 56 32 208262 Telex 230602 DGTM CL 330461 DGTM CK CHINA The Bureau of Harbour Superintendency of the Peoples Republic of China 10 Fu Xing Road Beijing 100 845 Tel:+ 86 1 3260674 Telefax + 86 1 3264025 Telex 222258 CMSAR CN CROATIA Ministry of Maritime Affairs Transport and Communication Marine Safety Division Prisavlje 14 1000 Zagreb Tel:+ 385 1 611 5966 Telefax + 385 1 611 5968 E mail pomorski promet@29 Tel:hr Testing and certification of packagings Adriainspekt Ciottina 17/b 51000 Rijeka Tel:+ 385 51 511 133 Telefax + 385 51 36 176

IMDG CODE - PAGE 0160e (page 0160f follows) Amdt. 29-98


Classification society for CSC Containers (including IMO tanks) CROATIA continued Croation Register of Shipping Marasoviceva 67 21000 Split Tel:+ 385 21 358 933 Telefax + 385 21 358 159 CYPRUS Department of Merchant Shipping Ministry of Communications and Works Kyliinis Street Mesa Geltonia CY-4007 Lemesos PO Box 6193 CY 3305 Lemesos

Tel:+ 357 5 848100 Telefax + 357 5 848200 Telex 2004 CZECH REPUBLIC Implementation Ministry of Transport of the Czech Republic Navigation and Waterways Division Nabrezi L Svobody 12 11015 Praha 1 Tel:+ 42 2 230 312 25 Telefax + 42 2 248 105 96 Telex 42 2 12 10 96 DOMI C Packaging testing and certification institute CIMTO sp U Michelskeho lesa 336 146 23 Praha 4

Tel:+ 42 2 472 94 64 Telefax + 42 2 472 36 76 IMET s ro Bazantni 697 165 00 Praha 6

Tel:+ 42 2 39 32 96 Telefax + 42 2 29 23 70 Classification of dangerous goods of all classes except class 7 - radioactive materials Cesky lodni a prumyslovy registr s.r.o. (Czech Shipping and Industry Register Ltd. ) Jankovcova 10 1 70 00 Praha 7 Tel:+ 42 2 667 100 01 Telefax + 42 2 808 984 Telex 422 122 874 CSLR C

IMDG CODE - PAGE 0160f (page 0160g follows) Amdt. 29-98


DENMARK Danish Maritime Authority P.O. Box 2605 Vermundsgade 38C 2100 Copenhagen 0 Tel:+ 45 39 271515 Telefax + 45 39 271516 Teletex 119204 SOEFART DK Telex 31141 SOEFART DK Telegrams Soefart Packaging, testing and certification institute Emballage og Transportinstrtuttet (E T i ) Dansk Teknologisk Instrtut Emballage og Transportinstituttet Gregersensve) 2630 Tastrup ECUADOR Direccion General de la Marina Mercante y del Litoral P.O. Box 7412 Guayaquil Tel:+ 593 4 526 760 Telefax + 593 4 324 246 Telex 04 3325 DIGMER ED ESTONIA Estonian National Maritime Board 13 Tartu Road Tallinn EE 0001 Tel:+ 372 2 430202 Telefax + 3726 312303 Telex 173027 EVA EE FINLAND Finnish Maritime Administration P.O. Box 171 00181 Helsinki Tel:+ 358 2044840 Telefax + 358 204484500 + 358 204484336 Telex 121471 MKH FI Packaging and certification institute Safety Technology Authority P 0 Box 123 00181 Helsinki Tel:+ 358 9 61671 Telefax 358 9 6167466 FRANCE Ministere de I'equipement, des transports et du tourisme Direction des ports et de la navigation maritimes Bureau du controle des navires 3, Place de Fontenoy 75700 Pans Tel:+ 33 1 44 49 86 49 Telefax + 33 1 44 49 86 40 Telex 250823 F MIMER

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GAMBIA The Managing Director Gambia Ports Authority Banjul Tel: + 220 27266 Telefax: + 220 27268 Telex: 2235 GAMPORTS GV GERMANY Ministry of Transport Postfach 20 01 00 Robert-Schuman-Platz 1 53175 Bonn Tel: + 49 228 300 0 or 300 Extension Telefax: + 49 228 300 2409 + 49 228 300 2632 + 49 228 300 3428 + 49 228 300 2435 + 49 228 300 3429 Telex: 885700 BMV D Federal Institute for Materials Research and Testing for dangerous goods and packagings, IBCs and multi-modal tank containers: Bundesanstalt fur Materialforschung und -prufung (BAM) Unter den Eichen 87 12205 Berlin Tel: + 49 30 81 04 0 or Extension Telefax: + 49 30 81 04 12 01 + 49 30 81 04 1310 GREECE Ministry of Mercantile Marine Safety of Navigation Division (Section B) 150 Gr. Lambraki Av. 185 18 Piraeus Tel: + 30 1 4174480 Telefax: + 30 1 4112500 Telex: 212022 212239 YEN GR ICELAND Iceland Maritime Administration Vesturvor 2 IS-202 Kopavogur Tel: + 354 560 0000 Telefax: + 354 560 0060 E-mail: [email protected] Directorate of Shipping Hringbraut 121 P.O. Box 7200 127 Reykjavik Tel: + 354 1 25844 Telefax: + 354 1 29835 Telex: 2307 ISINFO



INDIA The Directorate General of Shipping Jahaz Bhawan Walchanc Hirachand Marg Bombay 400 001 Tel:+ 91 22 263651 Telex DEGESHIP 2813-BOMBAY Packaging, testing and certification institute Indian Institute of Packaging Bombay Madras Calcutta IRAN Ports and Shipping Organization 751 Enghelab Avenue Tehran Tel:+ 98 21 837041 to 49 Telex 212271 BNDR-IR IRELAND The Chief Surveyor Marine Survey Office Department of the Marine 26/27 Eden Quay Dublin 1 Tel:+ 353 18744900 Telefax + 353 872 4491 + 353 18722045 Telex 33358 MSO EI + 353 18743325 ISRAEL Technical Services Department Shipping and Ports Administration 102 Haatzmaut Rd Haifa Tel:+ 972 4 535640 Telex 46632 ITALY Ministero della Marina Mercantile Viale Asia-eur 00144 Roma Tel:+ 39 6 5908 Telex 612153 MIMERC I

Ministero del Transporti e della Navigazione Comando Generale del Corpo delle Capitanerie di Porto Direzione Servizi Sicurezza delta Navigazione Ponte del Mille 16100 - Geneva

Tel:+ 39 1024 12 443 Telefax + 39 10 24 12 797 Genera! Manager Comte A Verani IMDG Dept Compte F Carpinteri



JAMAICA Testing and certifying authority The Bureau of Standards 6 Winchester Road PO Box 113 Kingston Tel:+ 1 809 92 63140 7 Telex 2291 STANBUR Jamaica Cable STANBUREAU JAPAN Inspection and Measurement Division Marine Technology and Safety Bureau Ministry of Transport 2-1-3 Kasumigaseki, Chiyoda-ku Tokyo Tel:+813 3580 6398 Telefax + 81 3 3580 7960 Tetex 222 7381 Packaging, testing and certification institute Nippon Hakuyohin KenTel:Kyokal (HK) (The Ship Equipment Inspection Society of Japan) 3-32, KiOi-Cho, Chiyoda-ku Tokyo Tel:+ 81 3 3261 6611 Telefax +813 3261 6979 LATVIA Maritime Administration of Latvia 5 Trijadibas iela LV 1048 Riga Tel:+ 371 7 86 00 81 Telefax + 371 7 86 00 82 LIBERIA National Port Authority Monrovia Liberia Tel:+ 231 221 306 Telex 44275 NPA LBR Office of the Commissioner of Maritime Affairs, R L Bureau of Maritime Affairs Providence Building Monrovia, Liberia Tel:+ 231 224 604/908 Telefax + 231 226 069 Office of the Deputy Commissioner of Maritime Affairs, R L Technical Division Marine Operations Department c/o Liberian Services Inc 11495 Commerce Park Drive Reston, Virginia, 22091-15007 USA Tel:+ 703 620 4880 Telefax + 703 476 8522 Telex 248403 IRI UR

IMDG CODE - PAGE 0160j (page 0160k follows) Amdt. 29-98


MALAYSIA Director Marine Department Peninsular Malaysia P 0 Box 12 42009 Port Kelang Selangor Telex MA 39748 Director Marine Department, Sabah P 0 Box 5 87007 Labuan Sabah Director Marine Department, Sarawak P 0 Box 530 93619 Kuching Sarawak MEXICO Stowage, segregation labelling and documentation of goods Coordinacion General de Puertos y Marina Mercante Secretaria de Comunicaciones y Transportes Av MuniCipio Libre No 377 Piso 12, Ala B Col Santa Cruz Atoyac 03010, Mexico D F Tel:6 04 42 49 6 04 38 29 Coordinador General Lie Pedro Pablo Zepeda Bermudez Reporting procedures in the case of packages lost overboard Secretaria de Marina Eje 2 oriente tramo H Escuela Naval Militar No 861 04830, Mexico D F Tel:6 84 81 88 Telefax ext 3201 Subsecretario de Marina Almirante CG D E M Felix Jaime Perez y Elias Laboratory tests for packages containing dangerous goods Direccion General de la Sociedad Mexicana de Normalizacion y Certificacion S C (NORMEX) Alfredo Novel No 21, Centro Industrial Puente de Vigas 54070, TIalnepantIa Estado de Mexico Tel:5 65 72 72 Director General Lie Carlos Sauceda Alvarez MOROCCO Direction de la Marine Marchande et des Peches Maritimes Boulevard EI Hansali Casablanca Tel:+ 212 2 278 092 Telex 24613 MARIMAR M + 212 2 221 931 22824

IMDG CODE - PAGE 0160k (page 01601 follows) Amdt 28-96


NETHERLANDS Ministry of Transport, Public Works and Water Management State Traffic Inspectorate Transpprt Information Centre P.O. Box 11063 3004 EB Rotterdam Tel: + 31 10 4370888 Telefax:+ 31 104370437 Ministry of Transport, Public Works and Water Management Directorate-General for Freight Transport P.O. Box 20904 2500 EX The Hague Tel:+ 31 70351 6171 Telefax:+ 31 70 351 1479 P.O. Box 20904 2500 EX Den Haag Bezoekadres Willem Witsenplein, 6 2596 BK Den Haag Tel:+ 31 70 351 6171 Telefax:+ 31 70 351 7895 P.O. Box 5817 2280 HV Rijswijk Tel:+ 31 7039 5S 555 Telefax:+ 31 7039 96 274 Telex: 31040 DGSMNL Packaging, Testing and Certification Institute TNO Centrum voor Verpakking P.O. Box 6034 2600 JA Delft Classification societies have been designated as competent inspector agencies for the approval, acceptance and all consequential activities connected with portable tanks, tank containers and road tank vehicles to be registered in the Netherlands: Lloyd's Register of Shipping Bureau Veritas Germanischer Lloyd Det norske Veritas American Bureau of Shipping Registro Italiano Navale Nippon Kaiji Kyokai RDW, Dienst Wegverkeer* S.G.S, Redwood Nederland B.V.**

* roadtank vehicles only ** 2.5 year (midway) inspections' of IMO type 1 or 2 only

IMDG CODE - PAGE 01601 (page 0160m follows) Amdt. 29-98


NEW ZEALAND Director of Maritime Safety Maritime Safety Authority of New Zealand Level 8 AMP House 109 Featherstone Street P.O. Box 27006 Wellington Tel+ 6444730111 Telefax+ 64 4 473 0999 + 64 4 472 7367* * This number is for the Marine Duty Officer who is available 24 hours a day Competent inspection agencies for the approval, inspection and testing of all portable tanks tank containers and freight containers in New Zealand American Bureau of Shipping Bureau Veritas Det. Norske Veritas

Lloyd's Register of Shipping NORWAY Norwegian Maritime Directorate Stensberggt 27 P.O. Box 8123 Dep. 0032 Oslo Tel+ 47 22 45 45 00 Telefax+ 47 22 56 87 80 Telex 21557 SDIR N Classification societies: For CSC containers Det. norske Veritas Veritasveien 1 1322 Hovik For IMO tanks Det. norske Veritas Veritasveien 1 1322 Hovik Lloyd's Register of Shipping Arbiensgt 11 0253 Oslo 2 PAKISTAN Mercantile Marine Department 70/4 Timber Hard N M Reclamation Keamari, Post Box 4534 Karachi Tel+ 92 21 270117 Telex 2733 NSC KAR + 92 21 270118 2833 + 92 21 270119 2683 + 92 21 270289 2765



PANAMA Direccion General Consular y Naves Apartado Postal 5245 Panama 5 PAPUA NEW GUINEA First Assistant Secretary Department of Transport Division of Marine P 0 Box 457 Konedobu Tel.+ 675 211866 Telex 22203 PERU Direccion General de Capitanias y Guardacostas 102 de Nieto Plaza Grao Callao 1 Tel.+ 51 14 29 7278 Telefax+ 51 14 653908 + 51 14 29 4692 Telex 26071 PE DICAPI Empresa Nacional de Puertos S. A Av. Guardia Chalaca S/N Tel.+ 51 14 654280 Telefax+ 51 14 656415 + 51 14 290355 Telex 26010 PHILIPPINES Philippine Ports Authority Port of Manila Safety Staff P.O. 193, Port Area Manila, 2803 Tel.+ 63 2 47 34 41 to 49 POLAND Ministry of Transport and Maritime Economy Department of Maritime and Inland Waters Administration ul. Chalubinskiego 4/6 00-928 Warszawa Tel.+ 48 26 211 448 Telefax+ 48 26 288 515 Telex 816651 PKP PL Packaging, testing and certification institute Centralny Osrodek Badawczo-Rozwojowy Opakowan ul. Konstancinska, 11 02-942 Warszawa Tel.+ 48 22 42 20 11 Telefax+ 48 22 42 23 03 Telex 812473 Classification societies For CSC containers Polski Rejestr Statkow al Gen J. Hallera 126 80-416 Gdansk Tel.+ 48 58 41 17 64 Telefax+ 48 58 46 03 92 + 48 58 46 03 82 + 48 58 46 13 96 + 48 58 41 64 82 Telex 512952 PRS PL



PORTUGAL Direccao-Geral de Navegacao e dos Transportes Maritimos Praca Luis de Camoes, 22 - 2° Dto. 1200 Lisboa Tel:+ 351 1 373821 Telefax:+ 351 1 373826

Telex: 16753 SEMM PO REPUBLIC OF Ship Technology Division KOREA Ship Bureau Korea Maritime and Port Administration 112-2, Inui-dong, Chongno-gu Seoul, 110-410 Tel:+ 82 2 744 4742 Telefax:+ 82 2 3672 1175 Telex: K 26523 RUSSIAN Department of Shipping and Navigation FEDERATION Ministry of Transport Rozhdestvenka Street, 1/4 Moscow 103759 Tel:+ 7 095 228 38 82 Telex: 411197 MORFLOT

Classification society has been designated as competent inspector agency for the approval, acceptance and all consequential activities connected with IMO Type tanks, CSC containers, Intermediate Bulk Containers (IBCs) and Packaging to be registered in the Russian Federation: Russian Maritime Register of Shipping Tel:+ 781231288 78 Telefax:+ 7 812 314 1087 + 781231407 43 Telex; 121525 RSSU RU

E-mail: [email protected] Ministry of Transport of the Russian Federation Regulation of Maritime Transport Operation Department -1/4, Rozhdestvenka Street Moscow, 103759 Tel:+ 7095926 14 23 Telefax:+ 7 095 926 90 38 + 7 095 92S 18 62 + 7 095 926 91 28

Telex: 411197 MMF RU Packaging, Testing and Certification Institute Central Marine Research & Design Institute (CNIIMF) 6, Kavalergardskaja Street Saint-Petersburg, 193015 Tel:+ 7 812 275 89 47 Telefax:+ 7812 2743864 Tetex: 821483 CNIMF RU



SAUDI ARABIA Port Authority Saudi Arabia Civil Defence Riyadh Tel:+ 966 1 464 9477 SINGAPORE Maritime and Port Authority of Singapore 18th Storey PSA Building 460 Alexandra Road Singapore 119963 PSA Building Post Office P.O. Box 313 Singapore 911141 Tel:+ 65 375 1689 Telefax:+ 65 275 9247 SLOVENIA Uprava Republike Solvenije za pomorstvo Ukmarjev trg. 2 66 000 Koper Tel:+ 386 66 271 216 Telefax:+ 386 66 271 447 Telex: 34235 UP POM SI SOUTH AFRICA South African Maritime Safety Authority P.O. Box 13186 Hatfield 0028 Pretoria Tel:+ 12 342 3049 Telefax:+ 12 342 3160 South African Maritime Safety Authority Hatfield Gardens: Block E (Ground Floor) Corner Arcadia and Grosvenor Streets Hatfield 0083 Pretoria Head Office Administrations; Chief Director Chief Directorate: Shipping Department of Transport Private Bag X193 0001 Pretoria Tel:+ 27 12 2902904 Telefax:+ 27 12 3237009 Durban, East London, Port Elizabeth and Richards Bay; Chief Ship Surveyor Eastern Zone Department of Transport Marine Division Private Bag X54309 4000 Durban Tel:+ 27 12 3071501 Telefax:+ 27 12 3064983



SOUTH AFRICA Cape Town, Sal dan ha Bay and continued Mossel Bay Chief Ship Surveyor Western Zone Department of Transport Marine Division Private Bag X7025 8012 Roggebaal Tel:+ 27 21 216170 Telefax+ 27 21 4190730 SPAIN Direccion General de la Marina Mercante c/Ruiz de Alarcon, 1 28014 Madrid Tel:+ 34 1 580 1464 (Office hours) Telefax+ 34 1 521 9510 + 34 1 580 1465 (Office hours) Telex 41210 SAMAD E + 34 1 521 7943 (24 hours) 41224 SAMAD E SWEDEN Swedish Maritime Administration Maritime Safety Inspectorate Ship Division 601 78 Norrkoping Tel:+ 46 11 191000 Telefax+ 46 11 239934 Telex 64380 SHIPADMS S Packaging, testing and certification institute Swedish National Testing and Research Institute Materials and Mechanics Box 857 501 15 Boras SWITZERLAND Office suisse de la navigation maritime Elisabethenstrasse, 31 4002 Basel Tel:+ 41 61 287 14 44 Telefax+ 41 61 287 15 70 Telex 965514 SSU CH THAILAND Ministry of Transport and Communications Ratchadamnoen-Nok Avenue Bangkok 10 100 Tel:+ 66 2 2813422 Telefax+ 66 2 2801714 Telex 70000 MINOCOM TH TUNISIA Direction Generate de la Marine Marchande 24 Avenue de la Republique 1001 Tunis Tel:+ 216 1 259 117 Telefax+ 216 1 354 244 Telex



Maritime and Coastguard Agency UNITED KINGDOM Bay 2/25 Spring Place 105 Commercial Road Southampton SO15 1EG Tel+ 44 1703 329177 Telefax+ 44 1703 329204 Packaging, testing and certification institute PIRA International Randalls Road Leatherhead Surrey KT22 7RU UNITED STATES Hazardous Materials Standards Branch Operating and Environmental Standards Division (G MOS-3) 2100 Second Street SW Washington, DC 20593-0001 Tel+ 1 202 267 1577 Telefax+ 1 202 267 4570 + 1 202 267 1217 Telex 892427 US Department of Transportation Research and Special Programs Administration International Standards Coordinator (DHM-5) 400 Seventh Street SW Washington, DC 20590-0001 Tel+ 1 202 366 0656 Telefax+ 1 202 366 5713 AMERICAN SAMOA Silila Patane Harbourmaster Port Administration PagoPago American Samoa 96799 URUGUAY Prefectura del Puerto de Montevideo RambIa 25 de Agosto de 1825 S/N Montevideo Tel+ 598 2 960123 Telex 23929 COMAPRE UY + 598 2 960022 VANUATU Commissioner of Maritime Affairs Private Mail Bag 023 Port Vila Tel+ 678 22247 Telefax+ 678 22242



Associate Member The Director of Marine HONG KONG, CHINA Marine Department

GPO Box 4155 Tel: + 852 2852 3085 Telefax: + 852 2815 8596 + 852 2852 4538 + 852 2542 3199 Telex: 64553 MARHQ HX

IMDG CODE - PAGE 0160s (page 0167 follows) Amdt. 29-98


23 MARINE POLLUTANTS

23.1 General

23.1.1 Marine pollutants should be carried under the provisions of Annex III as amended of the International Convention for the Prevention of Pollution from Ships 1973 as modified by the Protocol of 1978 relating thereto (MARPOL 73/78). These substances materials or articles are identified in the individual schedules as MARINE POLLUTANT. When a substance material or are tide is suspected to possess properties that may meet the definition of a marine pollutant or severe marine pollutant but is not identified in this Code such substance material or article may be transported as a marine pollutant or severe marine pollutant in accordance with this section. All relevant data should be submitted to GESAMP* as appropriate.

23.1.2 Substances articles or materials that are identified as marine pollutants but do not possess any other hazard are listed in the appendices to the schedules for ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID N.O.S. UN No. 3077 or ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. UN No. 3082 in class 9. These appendi-ces do not list the solutions mixtures and isomers referred to in 23.2.3 and 23.2.4

23.1.3 Certain marine pollutants have an extreme pollution potential** and are identified as severe marine pollutants in the individual schedules.

23.1.4 Certain marine pollutants or severe marine pollutants are identified only in the General Index with an assignment to an appropriate N.O.S or generic entry of classes 1 to 8 although they are not listed in those schedules.

23.1.5 Certain other marine pollutants or severe marine pollutants are identified only in the General Index. These marine pollutants or severe marine pollutants have not been assigned to an N.O.S or generic entry. These marine pollutants or severe marine pollutants may possess properties of classes 1 to 8 and should be classified accordingly. A sub-stance which does not fall within the criteria of these classes should be offered for transport as an ENVIRONMEN-TALLY HAZARDOUS SUBSTANCE SOLID N.O.S. UN No. 3077 or as an ENVIRONMENTALLY HAZARDOUS SUB-STANCE LIQUID N.O.S. UN No. 3082 under these entries in class 9.

23.1.6 With the approval of the competent authority substances materials or articles that are identified as marine pollutants in this Code, but which on the basis of a revised GESAMP hazard profile no longer meet the criteria for designation, as a marine pollutant or a severe marine pollutant need not be transported in accordance with the provisions of this Code applicable to marine pollutants.

* Reference is made to the IMO/FAO/UNESCO-IOC/WMO/WHO/IAEA/UN/UNEP Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection. ** A substance is regarded to have an extreme pollution potential if it

- is bioaccumulated to a significant extent and known to produce a hazard to aquatic life or human health (Hazard Rating + in column A) and is highly toxic to aquatic life (Hazard Rating 4 in column B) or has particularly high toxicity to aquatic life as defined by LC50/96 hour of 0.01 ppm or less.

Refer to the guidelines for the identification of harmful substances in packaged form contained in the appendix to Annex III of MARPOL 73/78 as amended and reproduced in section 23.8 of this General Introduction.



23.2 Solutions, mixtures and isomers 23.2.1 A solution or mixture containing 10% or more of (a) marine pollutant (s) is a marine pollutant.

23.2.2 A solution or mixture containing 1 % or more of (a) severe marine pollutant (s) is a marine pollutant.

23.2.3 A solution or mixture which does not fall within the criteria of classes 1 to 8 but which meets the criteria for marine pollutants under 23.2.1 or 23.2.2 should be offered for transport as an ENVIRONMENTALLY HAZARDOUS SUB-STANCE SOLID N.O.S. or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. under the en-tries in class 9 even though it is not listed by name in the appendices thereto.

23.2.4 An isomer of a substance identified as a marine pollutant and covered by a generic entry in classes 1 to 8, but which does not fall within the criteria of these classes should be offered for transport as an ENVIRONMENTALLY HAZ-ARDOUS SUBSTANCE SOLID N.O.S. or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. under the entries in class 9 even though it is not listed by name in the appendices thereto.

23.3 Documentation

23.3.1 The basic items of information necessary for each substance material or article offered for transport which should be included in the transport documents to be prepared by the shipper are set out in subsection 9.3 of this General Intro-duction.

23.3.2 A marine pollutant should only be offered for transport under its proper shipping name given in the appropriate indi-vidual schedule It should also be identified as MARINE POLLUTANT in the transport documents When declared under an N.O.S. or generic entry a marine pollutant should always be identified by its recognized chemical name in parentheses. A pesticide or pesticide preparation which is a marine pollutant should be offered for transport under the appropriate pesticide entry supplemented with the name of the specific pesticide and percentage of active ingredient in parentheses. Examples of such a description are

ACROLEIN, INHIBITED, class 6.1, UN 1092, P.G. I (3), MARINE POLLUTANT

FLAMMABLE ,LIQUID, N.O.S., (ethanol and dodecylphenol) class 3.2, UN 1993, P.G. II, MARINE POLLUTANT

CADMIUM, COMPOUND, (cadmium chloride) class 6.1, UN 2570, P.G. I, II or III, MARINE POLLUTANT

ORGANOCHLORINE, PESTICIDE, SOLID, TOXIC, (Aldrin 19%) class 6.1, UN 2761, P.G. III MARINE POL-LUTANT

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (carbophenothion 1.5%), class 9, UN 3082, P.G. III, MARINE POLLUTANT

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (calcium naphthenate) class 9, UN 3077, P.G. III, MARINE POLLUTANT

23.4 Packaging

23.4.1 A marine pollutant should be offered for transport only in packagings which are resistant to the adverse effects of immersion in water.



26.1.5.1.3 Examples of marking:

11A/Y/02.89/

NL/...* 007/5500/1500

For a metal IBC for solids discharged by gravity and made from steel for packaging groups II and III, manufactured in February 1989 authorized by the Netherlands manufactured by* (name of manufacturer) and of a design type to which the competent au-thority has allocated serial number 007, showing the stacking test load and the maximum permissible gross mass in kilograms.

13H3/Z/03.89/ F/...* 1713/0/500

For a flexible IBC for solids discharged by gravity and made from woven plastics with a liner. Not designed to be stacked.

31H1/Y/04.89/ GB/...* 9099/10800/1200

For a rigid plastics IBC for liquids made from plastics with struc-tural equipment withstanding the stack load.

31HA1/Y/05.89/ D/...* 1683/10800/1200

For a composite IBC for liquids with a rigid plastics inner recepta-cle and a steel outer casing.

11C/X/01.93/ S/...* 9876/3000/910

For a wooden IBC for solids with an inner liner and authorized for packaging groups I, II or III.

11G/Z/06.89/ I/...* 962/0/500 For a fibreboard IBC Not designed to be stacked.

11D/Y/07.89/ E/...* 261/3240/600 For a plywood IBC with inner liner.

26.1.5.2 Additional marking

See specific requirements shown in the relevant subsections.



26.1.5.3 Conformity to design type. 26.1.5.3.1 The marking indicates that the IBCs correspond to a successfully tested design type and that the requirements

referred to in the certificate have been met. 26.1.6 Operational requirements 26.1.6.1 Before being filled and handed over for transport every IBC should be inspected to ensure, that it is free from

corrosion contamination or other damage, with particular regard to the proper functioning of any service equip-ment. Any IBC which shows signs of reduced strength as compared with the tested design type should no longer be used or should be so repaired that it is able to withstand the design type tests.

26.1.6.2 When filling IBCs with liquids sufficient ullage should be left to ensure that, at the mean bulk temperature of 50°C, the IBC is not filled to more than 98% of its water capacity.

Note: For a differing temperature the maximum degree of filling can be determined as follows:

Degree of filling = )tα(501

98F−+

per cent of the capacity of the IBC.

In this formula α represents the mean coefficient of cubic expansion of the liquid substance between 15°C and 50°C, that is to say, for a maximum rise in the temperature of 35°C, α is calculated according to the formula:

50

5015

d35ddα

×−= ,

where

d15 and d50 are the relative densities of the liquid at 15°C and 50°C and tf is the mean temperature of the liquid at the time of filling.

26.1.6.3 Where two or more closure systems are fitted in series, that nearest to the substance being transported should be closed first.

26.1.6.4 During transport, no dangerous residue should adhere to the outside of an IBC.

26.1.6.5 Empty uncleaned IBCs which have been used previously for the transport of dangerous substances should be subject to the requirements of this section for filled IBCs unless adequate measures have been taken to nullify any hazard.

26.1.6.6 When IBCs are used for the transport of liquids with a flashpoint of 61°C c.c. or lower or of powders liable to dust explosion measures should be taken to prevent a dangerous electrostatic discharge.

26.1.6.7 IBCs used for solids which may become liquid at temperatures likely to be encountered during transport should also be capable of containing the substance in the liquid state.

26.1.6.8 The periodic testing and inspection requirements for IBCs are provided in 26.2, 26.4 and 26.5. An IBC should not be filled and offered for transport after the date of expiry of the last periodic test required by 26.2.6, 26.4.6 or 26.5.6, or the date of expiry of the last periodic inspection required by 26.2.7, 26.4.7 or 26.5.7.

However, an IBC filled prior to the date of expiry of the last periodic test or inspection may be transported for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection.



In addition an IBC may be transported after the date of expiry of the last periodic test or inspection:

1 after emptying but before cleaning for purposes of performing the required test or inspection prior to refill-ing; and

2 unless otherwise approved by the competent authority for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection in order to allow the return of dangerous goods for proper disposal or recycling Reference to this exemption should be entered on the transport document.

26.1.7 Marking and labelling

26.1.7.1 Marking the proper shipping name (correct technical name) and labelling of an IBC containing a dangerous sub-stance should be carried out in accordance with the requirements of sections 7 and 8 of this General Introduction.

26.1.8 Stowage

26.1.8.1 IBCs should be stowed in accordance with section 14 of this General Introduction and with any requirements in this respect as included in the individual schedules of the substances to be transported.

26.1.8.2 During transport the IBCs should be securely fastened to or contained within the cargo transport unit so that lateral or longitudinal movement or impact is prevented and adequate external support is provided

26.1.9 Segregation

26.1.9.1 IBCs containing dangerous substances should be segregated in accordance with the requirements for the segre-gation of packages of section 15 of this General Introduction.

26.1.10 Special requirements relating to IBCs for the transport of organic peroxides (class 5.2)

26.1.10.1 Each organic peroxide should have been tested and a report made available indicating that transport in IBCs would be safe. The conditions for this transport should be specifically designated by the competent authority of the country of origin. A notification including the report should be sent to the competent authority of the country of destination. The tests undertaken should include those necessary:

.1 to prove that the organic peroxide complies with the principles for classification given in 3.3.6 of the intro-duction to class 5.2;

.2 to prove the compatibility of all materials normally in contact with the substance during transport;

.3 to determine when applicable the control and emergency temperatures derived from the SADT (Self Ac-celerating Decomposition Temperature see section 2.1 of this General Introduction). These temperatures may be lower than those indicated for packages in the appendix to the individual schedules; and



.4 to design, when applicable, pressure and emergency relief devices; and any special requirements neces-sary for the safe transport of the organic peroxide.

26.1.10.2 Emergencies to be taken into account are self-accelerating decomposition of the organic peroxide and fire en-gulfment.

26.1.10.3 To prevent explosive rupture of metal IBCs or composite IBCs with a complete metal casing, the emergency-relief devices should be designed to vent all the decomposition products and vapours evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire engulfment calculated by the equa-tions given in 13.1.55.8.

26.1.10.4 IBCs should be transported in a closed cargo transport unit.

26.1.10.5 Organic peroxides suitable for transport in IBCs are identified in the appendices to the individual class 5.2 sched-ules for UN Nos. 3109 and 3119, and in appendix 1 to this section together with the special requirements applica-ble for their transport.

26.1.11 Special requirements relating to IBCs for the transport of self-reactive substances of class 4.1

26.1.11.1 Self-reactive substances of class 4.1 should have been tested and a report made available indicating that the transport in IBCs would be safe. The conditions for transport should be specified by the competent authority of the country of origin. The tests undertaken should include those necessary:

.1 to prove that the self-reactive substance complies with the principles for classification given in 2.2.10.6 of the introduction to class 4.1;

.2 to prove the compatibility of all materials normally in contact with the substance;

.3 to determine the control and emergency temperatures, if required, for transport of the substance in the IBC concerned, as derived from the self-accelerating decomposition temperature;

.4 to determine, when applicable, types of emergency pressure-relief devices; and

.5 to determine if any special requirements are necessary.

26.1.11.2 Emergencies to be taken into account are the ability to ignite easily from external sources such as sparks and flames and the likelihood of a strongly exothermic reaction caused by excessively high transport temperatures or by contamination.

26.1.11.3 To prevent explosive rupture of metal IBCs or composite IBCs with complete metal casing, the emergency pres-sure-relief devices should be designed to vent all the decomposition products and vapours evolved during self-accelerating decomposition or during a period of not toss than one hour of fire engulfment calculated by the equa-tions given in 13.1, 55.8.

26.1.11.4 Self-reactive substances transported in IBCs with an SADT less than 55°C have to be subjected to the tempera-ture control requirements given in section 21 of this General Introduction.

26.1.11.5 IBCs should be transported in a closed cargo transport unit.

26.1.11.6 Self-reactive substances suitable for transport in IBCs are identified in the appendices to the individual class 4.1 schedules, together with the special requirements, if any, applicable to their transport.



26.2 SPECIFIC REQUIREMENTS FOR METAL IBCs.

26.2.1 Scope.

26.2.1.1 These requirements apply to metal IBCs for the transport of solids and liquids of the following types:

11A 11B 11N

Metal IBCs for solids, which are filled and discharged by gravity.

21A 21B 21N

Metal IBCs for solids, which are filled and discharged at a gauge pressure greater than 10 kPa.

31A 31B 31N

Metal IBCs for liquids except for liquids having a vapour pressure of more than 110 kPa at 50°C or 130 kPa at 55°C.

26.2.2 Definitions 26.2.2.1 A metal IBC consists of a metal body together with appropriate service and structural equipment. 26.2.2.2 Body means the receptacle proper including openings and their closures, but does not include service equipment

(see 26.2.2.4). 26.2.2.3 Protected means the IBC being provided with additional protection against impact, the protection taking the form of

for example, a multi-layer (sandwich) or double wall construction or a frame with a metal lattice-work casing. 26.2.2.4 Service equipment means filling and discharge, pressure-relief safety heating and heat insulating devices and

measuring instruments. 26.2.2.5 Structural equipment means the reinforcing fastening handling protective or stabilizing members of the body.

26.2.2.6 Maximum permissible gross mass means the mass of the body and its service equipment and structural equipment and the maximum permissible load.

26.2.3 Construction

26.2.3.1 Bodies should be made of suitable ductile metallic materials in which the weldability has been fully demonstrated Low-temperature performance should be taken into account when appropriate.



26.2.3.2 Care should be taken to avoid damage by galvanic action due to the juxtaposition of dissimilar metals.

26.2.3.3 Aluminium IBCs intended for the transport of flammable liquids should have no movable parts such as covers closures, etc., made of unprotected steel liable to rust which might cause a dangerous reaction by coming into frictional or percussive contact with the aluminium.

26.2.3.4 Metal IBCs should be made of metals which meet the following requirements:

1 For steel, the elongation at fracture, in per cent, should not be less than 10 000/Rm , with an absolute mini-mum of 20%,

where Rm = guaranteed minimum tensile strength of the reference steel to be used, in N/mm2.

2 For aluminium and aluminium alloys, the elongation at fracture in per cent, should not be less than 10 000/6Rm , with an absolute minimum of 8%.

Specimens used to determine the elongation at fracture should be taken transversely to the direction of rolling and be so secured that:

d5L0 =

or

A5.65L0 =

where

Lo = gauge length of the specimen before the test;

d = diameter; and

A = cross-sectional area of the test specimen.

Minimum wall thickness 26.2.3.5

1 For a reference steel having a product of Rm x AO = 10 000, the wall thickness should not be less than

Wall thickness in mm

IBCs of types 11A, 11B, 11N IBCs of types 21A, 21B, 21N, 31A, 31B, 31N Capacity in m3

Unprotected Protected Unprotected Protected

>0.25 to ≤1.0 2.0 1.5 2.5 2.0

> 1.0 to ≤ 2.0 2.5 2.0 3.0 2.5

>2.0 to ≤3.0 3.0 2.5 4.0 3.0

where AO = minimum elongation (as a percentage) of the reference steel to be used on fracture under ten-sile stress (see 26.2.3.4)



2 For metals other than the reference steel described in 26.2.3.5.1, the minimum wall thickness is given by the equivalence formula

311

01 ARm

e421e××= .

where e1 = required equivalent wall thickness of the metal to be used (in mm); e0 = required minimum wall thickness for the reference steel (in mm); Rm1 = guaranteed minimum tensile strength of the metal to be used in (N/mm2); and A1 = minimum elongation (as a percentage) of the metal to be used on fracture under tensile stress (see 26.2.3.4).

However, in no case should the wall thickness be less than 1.5 mm

26.2.3.6 Pressure-relief requirements

26.2.3.6.1 IBCs for liquids should be capable of releasing a sufficient amount of vapour in the event of fire engulfment to ensure that no rupture of the shell will occur. This can be achieved by conventional pressure relief devices or by other constructional means.

26.2.3.6.2 The start-to-discharge pressure should not be higher than 65 kPa and no lower than the total gauge pressure experienced in the IBC (i.e. the vapour pressure of the filling substance plus the partial pressure of the air or other inert gases minus 100 kPa) at 55°C determined on the basis of a maximum degree of filling as defined in 26.1.6.2.

26.2.3.6.3 The pressure-relief devices should be fitted in the vapour space. 26.2.4 Testing, certification and inspections.

Metal IBCs should be subject to:

1 type approval and certification including design type tests in accordance with 26.2.5;

2 initial and periodic tests in accordance with 26.2.6; and

3 inspections in accordance with 26.2.7.

26.2.5 Design type tests

26.2.5.1 One IBC of each design type size, wall thickness and manner of construction should be submitted to the tests in the order listed below and as set out in 26.2.8.1 to 26.2.8.5 inclusive. Another IBC of the same design may be used for the drop test as set out in 26.2.8.6. These design type tests should be carried out as required by the competent approval authority.



Tests Refer to IBCs of types 11A, 11B, 11N

IBCs of types 21A, 21B, 21N, 31A, 31B, 31N

Bottom lift 26.2.8.1 required1 required1

Top lift 26.2.8.2 required1 required1

Stacking 26.2.8.3 required2 required2

Leakproofness 26.2.8.4 not required required

Hydraulic pressure 26.2.8.5 not required required

Drop 26.2.8.6 required required

1 When the IBCs are designed for this method of handling at least one of these (bottom or top lift) tests should be performed.

2 When the IBCs are designed to be stacked.

26.2.5.2 The competent authority may permit the selective testing of IBCs which differ only in minor respects from the tested type e.g. with small reductions in external dimensions.

26.2.6 Initial and periodic testing of individual IBCs.

26.2.6.1 These tests should be carried out as required by the competent authority.

26.2.6.2 Each IBC should correspond in all respects to its design type and be subjected to the leak proofness test (see 26.2.8.4).

26.2.6.3 The leakproofness test in 26.2.8.4 should be repeated at intervals of not more than two and a half years.

26.2.6.4 The results of tests should be recorded in test reports to be kept by the owner of the IBC.

26.2.7 Inspections

26.2.7.1 Every IBC should be inspected to the satisfaction of the competent authority before it is put into service and there-after at intervals not exceeding five years with regard to:

1 conformity to the design type including marking 2 internal and external condition and 3 proper functioning of the service equipment

Thermal insulation need be removed only to the extent necessary for a proper examination of the body of the IBC.

IMDG CODE - PAGE 0182 Amdt. 27-94 (corrected)

GENERAL INTRODUCTION Appendix 1 to section 26

LIST OF LIQUID SUBSTANCES SUITABLE FOR TRANSPORT IN INTERMEDIATE BULK CONTAINERS (IBCs)

EXPLANATION OF COLUMNS

Column 1 United Nations Number (UN No.) of substance

Column 2 Proper shipping name of substance

Note: Depending on their hazards, mixtures or solutions should be treated in accordance with the require-ments of subsections 5.3 and 5.4 of this General Introduction.

Column 3 Class and subsidiary risk label(s) Types of IBCs

Columns 4, 5, 6 and 7 26.2 Metal.

26.4 Rigid plastics.

26.5 Composite only category 31HZ1, 31HA2 and 31HH2 are permitted for maritime transport.

X Allowed for transport

— Not allowed for transport



General requirement

Liquid substances carried in metal, rigid plastics or composite IBCs with rigid inner receptacle (31HZ1) should be provided with secondary protection. Secondary protection may be effected by placing the IBCs into freight containers or vehicles which should have rigid sides or fencing at least to the height of the IBCs. Liquid substances carried in composite IBCs with flexible inner receptacles (31HA2 and 31HH2) should always be transported in closed cargo transport units.


1 Allowed only if the vapour pressure does not exceed 110 kPa at 50°C or 130 kPa at 55°C. 2 Substances falling under packaging group I criteria not allowed. 3 Substances falling under packaging group III criteria only. 4 Hermetically sealed as defined in 10.9.1 of this General Introduction and in the introductions to the various classes. 5 Only with competent authority approval. 6 IBCs to be provided with a device or vent to allow venting during transport and to be stowed with the vent uppermost. 7 No bottom openings allowed. 8 Only for substances with a flashpoint of 0°C c.c. or above and with competent authority approval. 9 Accessible stowage of closed cargo transport units; see 21.4.3 of this General Introduction. 10 Only type 31HA1 is allowed. 11 To prevent the IBC bursting in any event, including fire engulfment, it should be provided with pressure-relief devices

which are adequate in relation to the capacity of the IBC and the nature of the substance carried. The device should also be compatible with the substance.

12 Control temperature+ 30°C; emergency temperature+ 35°C. The temperature indicated is based on a non-insulated IBC.

13 Control temperature+ 10°C; emergency temperature + 15°C. The temperature indicated is based on a non-insulated IBC.

14 Control temperature+ 15°C; emergency temperature+ 25°C. The temperature indicated is based on a non-insulated IBC.

15 Maximum capacity 1000 litres. 16 Maximum capacity 1250 litres. 17 Maximum capacity 1500 litres. 18 When consigning an organic peroxide in an IBC in accordance with these requirements, it is the responsibility of the

consignor to ensure that: .1 the pressure and emergency relief devices installed on the IBC are designed to take appropriate account of the self-

accelerating decomposition of the organic peroxide and of fire engulfment; and .2 when applicable, the control and emergency temperatures indicated are appropriate, taking into account the design

(e.g. insulation) of the IBC to be used.



Types of IBCs

UN No. Proper shipping name Class +

Subsidiary risk (s)

26.2 Metal

26.4 Rigid plas-

tics

26.5 Composite

(31HZ1)

26.5 Composite (31HA2 and

31HH2)

1 2 3 4 5 6 7 1088 ACETAL 3.1 X 4 — — — 1088 ACETAL 3.2 X 4 X 4,8 X 4,8 — 1090 ACETONE 3.1 X 4 — — — 1090 ACETONE SOLUTIONS 3.2 X 4 X 4,8 X 4,8 — 1091 ACETONE OILS 3.2 X 4 X 4,8 X 4,8 — 1104 AMYL ACETATES 3.3 X 4 X 4 X 4 X 4 1105 AMYL ALCOHOLS 3.2 X 4 X 4,5 X 4,5 — 1105 PENTANOLS 3.3 X 4 X 4 X 4 X 4 1106 AMYLAMINES 3.2+ 8 X 4 X 4,5 X 4,5 — 1106 AMYLAMINES 3.3+ 8 X 4 X 4 X 4 — 1107 AMYL CHLORIDES 3.2 X 4 X 4,5 X 4,5 — 1109 AMYL FORMATES 3.3 X 4 X 4 X 4 X 4 1110 normal-AMYL METHYL KETONE 3.3 X 4 X 4 X 4 X 4 1111 AMYL MERCAPTANS 3.2 X 4 X 4,5 X 4,5 — 1112 AMYL NITRATES 3.3 X 4 X 4 X 4 X 4 1113 AMYL NITRITE 3.1 X 4 — — — 1113 AMYL NITRITE 3.2 X 4 X 4,8 X 4,8 — 1114 BENZENE 3.2 X 4 — — — 1120 BUTANOLS 3.2 X 4 X 4,5 X 4,8 — 1120 BUTANOLS 3.3 X 4 X 4 X 4 X 4 1123 BUTYL ACETATES 3.2 X 4 X 4,5 X 4,5 — 1123 BUTYL ACETATES 3.3 X 4 X 4 X 4 X 4 1125 normal-BUTYLAMINE 3.2+ 8 X 4 — — — 1126 1-BROMOBUTANE 3.2 X 4 X 4,5 X 4,5 — 1127 CHLOROBUTANES 3.1 X 4 — — — 1127 CHLOROBUTANES 3.2 X 1,4 — — — 1128 normal-BUTYL FORMATE 3.2 X 4 X 4,5 X 4,5 — 1129 BUTYRALDEHYDE 3.2 X 4 — — — 1130 CAMPHOR OIL 3.3 X 4 X 4 X 4 X 4

1133 ADHESIVES containing a flammable liquid 3.1 X 1,2,4 — — —

1133 ADHESIVES containing a flammable liquid 3.2 X 1,2,4 X 1,2,4,8 X 2,4,8 —

IMDG CODE - PAGE 0223 (first of thirty pages) Amdt. 29-98


Types of IBCs


Subsidiary risk (s)

26.2 Metal

26.4 Rigid plas-

tics

26.5 Composite

(31HZ1)


31HH2)

1 2 3 4 5 6 7

1133 ADHESIVES containing a flammable liquid 3.3 X 1,4 X 1,4 X 1,4 X 1,4

1134 CHLOROBENZENE 3.3 X 4 X 4 X 4 X 4

1136 COAL TAR DISTILLATES, FLAMMABLE 3.2 X 4 X 4,8 X 4,8 —

1136 COAL TAR DISTILLATES, FLAMMABLE 3.3 X 4 X 4 X 4 X 4

1139 COATING SOLUTION 3.1 X 1,2,4 — — — 1139 COATING SOLUTION 3.2 X 2,4 X 2,4,8 X 2,4,8 — 1139 COATING SOLUTION 3.3 X 4 X 4 X 4 X 4 1145 CYCLOHEXANE 3.1 X 4 — — — 1146 CYCLOPENTANE 3.1 X 4 — — –

1147 DECAHYDRONAPHTHALENES (cis-, trans-) 3.3 X 4 X 4 X 4 X 4

1148 DIACETONE ALCOHOL 3.2 X 4 X 4,8 X 4,8 — 1148 DIACETONE ALCOHOL 3.3 X 4 X 4 X 4 X 4 1149 DIBUTYL ETHERS 3.3 X 4 X 4 X 4 X 4 1150 1, 2 DICHLOROETHYLENE 3.2 X 4 X 4,5 X 4,5 — 1152 DICHLOROPENTANES 3.3 X 4 X 4 X 4 X 4

1153 ETHYLENE GLYCOL DIETHYL ETHER 3.3 X 4 X 4 X 4 X 4

1154 DIETHYLAMINE 3.1+ 8 X 4 — — — 1156 DIETHYL KETONE 3.2 X 4 X 4,5 X 4,5 — 1157 DIISOBUTYL KETONE 3.3 X 4 X 4 X 4 X 4 1158 DIISOPROPYLAMINE 3.2+ 8 X 4 — — — 1159 DIISOPROPYL ETHER 3.1 X 4 — — —

1160 DIMETHYLAMINE, AQUEOUS SOLUTION 3.1+ 8 X 1,4 — — —

1160 DIMETHYLAMINE, AQUEOUS SOLUTION 3.2+ 8 X 4 X 4,8 X 4,8 —

1161 DIMETHYL CARBONATE 3.2 X 4 X 4,5 X 4,5 — 1165 DIOXANE 3.2 X 4 X 4,5 X 4,5 —

1169 EXTRACTS, AROMATIC LIQUID 3.2 X 4 X 4,8 X 4,8 —

1169 EXTRACTS, AROMATIC, LIQUID 3.3 X 4 X 4 X 4 X 4



Types of IBCs


Subsidiary risk (s)

26.2 Metal

26.4 Rigid plas-

tics

26.5 Composite

(31HZ1)


31HH2)

1 2 3 4 5 6 7 1793 ISOPROPYL ACID PHOSPHATE 8 X X X X

1800 OCTADECYLTRICHLOROSILANE 8 X4 X4 X4 –

1802 PERCHLORIC ACID with not more than 50% acid, by mass 8+ 5.1 X5,7 — — —

1803 PHENOLSULPHONIC ACID LIQUID 8 X X X –

1805 PHOSPHORIC ACID, LIQUID 8 X X X X

1811 POTASSIUM HYDROGENDIFLUORIDE, SOLUTION 8+ 6.1 X4 X4 X4 —

1812 POTASSIUM FLUORIDE, SOLUTION 6.1 X X X X

1814 POTASSIUM HYDROXIDE, SOLUTION 8 X X X X3

1819 SODIUM ALUMINATE, SOLUTION 8 X X X X8

1824 SODIUM HYDROXIDE, SOLUTION 8 X X X X3

1830 SULPHURIC ACID with more than 51% acid 8 — X X —

1833 SULPHUROUS ACID 8 X X X —

1835 TETRAMETHYLAMMONIUM HYDROXIDE, SOLUTION 8 X X X —

1837 THIOPHOSPHORYL CHLORIDE 8 X4,5,7 — — –

1840 ZINC CHLORIDE, SOLUTION 8 X X X X

1843 AMMONIUM DINITRO-ortho-CRESOLATE aqueous SOLUTION 6.1 X X X –

1846 CARBON TETRACHLORIDE 6.1 X X X —

1848 PROPIONIC ACID 8 X X X X

1849 SODIUM SULPHIDE, HYDRATED with at least 30% water (liquid) 8 X X X —

1862 ETHYL CROTONATE 3.2 X4 X4,5 X4,5 –

1863 FUEL, AVIATION, TURBINE ENGINE 3.1 X1,2,4 — — —

1863 FUEL AVIATION, TURBINE ENGINE 3.2 X2,4 X2,4,8 X2,4,8

1863 FUEL, AVIATION, TURBINE ENGINE 3.3 X4 X4 X4 X4,8

1866 RESIN SOLUTION flammable 3.1 X1,2,4 —

1866 RESIN SOLUTION, flammable 3.2 X2,4 X2,4,8 X2,4,8 —

1866 RESIN SOLUTION flammable 3.3 X4 X4 X4 X4

1886 BENZYLIDENE CHLORIDE 6.1 X4 X4 X4 —

1887 BROMOCHLOROMETHANE 6.1 X X X X

1888 CHLOROFORM 6.1 X X X X



Types of IBCs


Subsidiary risk(s) 26.2 Metal 26.4 Rigid

plastics

26.5 Com-posite

(31HZ1)

26.5 Com-posite

(31HA2 and 31HH2)

1 2 3 4 5 6 7 1897 TETRACHLOROETHYLENE 6.1 X X X X

1898 ACETYL IODIDE 8 X4,5 — — —

1902 DIISOOCTYL ACID PHOSPHATE 8 X X X X

1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 8 X2 X2 X2 X3

1908 CHLORITE SOLUTION 8 X X X X3

1914 BUTYL PROPIONATES 33 X4 X4 X4 X4

1915 CYCLOHEXANONE 33 X4 X4 X4 X4

1916 2,2-DICHLORODIETHYL ETHER 6.1+3 X4 X4 X4 —

1917 ETHYL ACRYLATE, INHIBITED 3.2 X4 X4 5 X4 5 —

1918 ISOPROPYLBENZENE 3.3 X4 X4 X4 X4

1919 METHYL ACRYLATE, INHIBITED 3.2 X4 — — —

1920 NONANES 3.3 X4 X4 X4 X4

1922 PYRROLIDINE 3.2+8 X4 X4,5 X4,5 —

1938 BROMOACETIC ACID, SOLUTION 8 X2,7 — — —

1940 THIOGLYCOLIC ACID 8 X X X —

1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3.1+6.1 X1,2,4,5 — —

1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3.2+6.1 X1,2,4,5 X1,2,4,8 X1,2,4,8 —

1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3.3+6.1 X 1,2,4,5 X1,4,5 X1,4,5 —

1987 ALCOHOLS, N.O.S. 3.2 X1,4 X1,4,8 X1,4,8 —

1987 ALCOHOLS, N.O.S. 3.3 X1,4 X1,4 X1,4 X1,4

1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3.1+6.1 X 1,2,4,5 — — —

1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3.2+6.1 X1,2,4,5 X1,2,4,8 X1,2,4,8 —

1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 3.3+6.1 X1,4,5 X1,4,5 X1,4,5 —

1989 ALDEHYDES, N.O.S. 3.1 X1,2,4 — — —

1989 ALDEHYDES, N.O.S. 3.2 X1,2,4 X1,2,4,8 X1,2,4,8 —



Types of IBCs


Subsidiary risk (s) 26.2 Metal 26.4 Rigid

plastics

26.5 Com-posite

(31HZ1)

26.5 Com-posite

(31HA2 and 31HH2)

1 2 3 4 5 6 7 2301 2-METHYLFURAN 3.1 X4 — —

2302 5-METHYLHEXAN-2-ONE 3.3 X4 X4 X4 X4

2303 ISOPROPENYLBENZENE 3.3 X4 X4 X4 X4

2305 NITROBENZENESULPHONIC ACIDS (ortho-, meta-, para-) 8 X X X —

2306 NITROBENZOTRIFLUORIDES, LIQUID 6.1 X X X —

2307 3-NITRO-4-CHLOROBENZO-TRIFLUORIDE 6.1 X X X —

2309 OCTADIENE 3.2 X4 X4,5 X4,5 —

2310 PENTANE-2-4-DIONE 3.3+ 6.1 X4 X4 X4 —

2311 PHENETIDINES 6.1 X X X X

2313 PICOLINES 3.3+ 8 X4 X4 X4 —

2315 POLYCHLORINATED BIPHENYLS 9 X4 X4 X4 —

2319 TERPENE HYDROCARBONS, N.O.S. 3.3 X4 X4 X4 X4

2320 TETRAETHYLENEPENTAMINE 8 X X X X

2321 TRICHLOROBENZENES, LIQUID 6.1 X X X X

2322 TRICHLOROBUTENE 6.1 X4 X4 X4 —

2323 TRIETHYL PHOSPHITE 3.3 X4 X4 X4 X4

2324 TRIISOBUTYLENE 3.3 X4 X4 X4 X4

2325 1,3,5-TRIMETHYLBENZENE 3.3 X4 X4 X X4

2326 TRIMETHYLCYCLOHEXYLAMINE 8 X X X X

2327 TRIMETHYLHEXAMETHYLENEDIAMINES 8 X X X X

2328 TRIMETHYLHEXAMETHYLENE DIISOCY-ANATE 6.1 X X X X

2329 TRIMETHYL PHOSPHITE 3.3 X4 X4 X4 X4

2330 normal-UNDECANE 3.3 X4 X4 X4 X4

2332 beta-ACETALDEHYDE OXIME 3.3 X4 X4 X4 X4

2333 ALLYL ACETATE 3.2+ 6.1 X4 X4,5 X4,5 —

2335 ALLYL ETHYL ETHER 3.2+ 6.1 X4 — — —

2338 BENZOTRIFLUORIDE 3.2 X4 X4,5 X4,5 —

2339 2-BROMOBUTANE 3.2 X4 X4,5 X4,5 —



Types of IBCs



plastics

26.5 Com-posite

(31HZ1)

26.5 Com-posite

(31HA2and 31HH2)

1 2 3 4 5 6 7 2340 2-BROMOETHYL ETHYL ETHER 3.2 X4 X4,8 X4,8 —

2341 1-BROMO-3-METHYLBUTANE 3.3 X4 X4 X4 X4

2342 BROMOMETHYLPROPANES 3.2 X4 X4,8 X4,8 —

2343 2-BROMOPENTANE 3.2 X4 X4,5 X4,5 —

2344 BROMOPROPANES 3.2 X4 X4,5 X4,5 —

2344 BROMOPROPANES 3.3 X4 X4 X* X4

2345 3-BROMOPROPYNE 3.2 X4 X4,5 X4,5 —

2346 BUTANEDIONE 3.2 X4 X4,5 X4,5 —

2347 BUTYL MERCAPTANS 3.1 X4 — — —

2347 BUTYL MERCAPTANS 3.2 X4 X4,8 X4,8 —

2348 BUTYL ACRYLATES, INHIBITED 3.3 X4 X4 X4 X4

2350 normal-BUTYL METHYL ETHER 3.2 X4 X4,8 X*,8 —

2351 BUTYL NITRITES 3.2 X4 X4,8 X4,8 —

2351 BUTYL NITRITES 3.3 X4 X4 X4 X4

2352 BUTYL VINYL ETHER, INHIBITED 3.2 X4 — — —

2354 CHLOROMETHYL ETHYL ETHER 3.2+6.1 X4 X4,8 X4,8 —

2358 CYCLOOCTATETRAENE 3.2 X4 X4,8 X4,8 —

2359 DIALLYLAMINE 3.2+6.1+8 X,4 X4,5 X4,5 —

2360 DIALLYL ETHER 3.2+6.1 X4 — — —

2361 DIISOBUTYLAMINE 3.3+8 X4 X4 X4 —

2362 1,1-DICHLOROETHANE 3.2 X4 — — —

2364 normal-PROPYLBENZENE 3.3 X4 X4 X4 X4

2366 DIETHYL CARBONATE 3.3 X4 X< X4 X4

2367 alpha-METHYLVALERALDEHYDE 3.2 X4 X4,5 X4,5 —

2368 alpha-PINENE 3.3 X4 X4 X4 X4

2370 1-HEXENE 3.1 X4 — — —

2372 1,2-DI-(DIMETHYLAMINO)ETHANE 3.2 X4 X<,5 X4,5 —

2373 DIETHOXYMETHANE 3.1 X4 — — —

2373 DIETHOXYMETHANE 3.2 X4 — — —

2374 3,3-DIETHOXYPROPENE 3.2 X4 X4,5 X4,5 —

2375 DIETHYL SULPHIDE 3.2 X4 — — —



Types of IBCs



plastics

26.5 Com-posite

(31HZ1)

26.5 Com-posite

(31HA2 and 31HH2)

1 2 3 4 5 6 7 2376 2,3-DIHYDROPYRAN 3.2 X4 — — —

2377 1,1- DIMETHOXYETHANE 3.1 X4 — — —

2377 1,1-DIMETHOXYETHANE 3.2 X4 X4,8 X4,8 —

2378 2- DIMETHYLAMINOACETONITRILE 3.3+6.1 X4 X4 X4 —

2379 1,3-DIMETHYLBUTYLAMINE 3.2+8 X4 X4,5 X4,5 —

2380 DIMETHYLDIETHOXYSILANE 3.2 X4 X4,5 X4,5 —

2381 DIMETHYL DISULPHIDE 3.2 X4 X4,5 X4,5 —

2383 DIPROPYLAMINE 3.2+8 X4 X4,5 X4,5 —

2384 DI-normal-PROPYL ETHER 3.1 X4 — — —

2384 DI-normal-PROPYL ETHER 3.2 X4 X4,8 X4,8 —

2385 ETHYL ISOBUTYRATE 3.2 X4 X4,5 X4,5 —

2386 1-ETHYLPIPERIDINE 3.2+8 X4 X4,5 X4,5 —

2387 FLUOROBENZENE 3.2 X4 — — —

2388 FLUOROTOLUENES (ortho-, meta-, para-) 3.2 X4 X4,5 X4,5 —

2390 2-IODOBUTANE 3.2 X4 X4,5 X4,5 —

2391 IODOMETHYLPROPANES 3.2 X4 X4,8 X4,8 —

2392 IODOPROPANES 3.3 X4 X4 X4 X4

2393 ISOBUTYL FORMATE 3.2 X4 X4,5 X4,5 —

2394 ISOBUTYL PROPIONATE 3.2 X4 X4,5 X4,5 —

2396 METHACRYLALDEHYDE, INHIBITED 3.2+6.1 X4 X4,5 X4,5 —

2397 3-METHYLBUTAN-2-ONE 3.2 X4 — — —

2398 METHYL-tertiary-BUTYL ETHER 3.1 X4 — — —

2399 1-METHYLPIPERIDINE 3.2+8 X4 X4,5 X4,5 —

2400 METHYL ISOVALERATE 3.2 X4 X4,8 X4,8 —

2401 PIPERIDINE 8+3 X4 X4,5 X4,5 —

2402 PROPANETHIOLS 3.1 X4 — — —

2403 ISOPROPENYL ACETATE 3.2 X4 X4,5 X4,5 —

2404 PROPIONITRILE 3.2+6.1 X4 X4,5 X4,5 —

2405 ISOPROPYL BUTYRATE 3.3 X4 X4 X4 X4

2406 ISOPROPYL ISOBUTYRATE 3.2 X4 X4,5 X4,5 —

2409 ISOPROPYL PROPIONATE 3.2 X4 X4,5 X4,5 —



Types of IBCs


Subsidiary risk(s) 26.2 Metal

26.4 Rigid plas-

tics

26.5 Com-posite

(31HZ1)


31HH2)

1 2 3 4 5 6 7 2410 1,2,3,6-TETRAHYDROPYRIDINE 3.2 X4 X4,5 X4,5 –

2411 BUTYRONITRILE 3.2+6.1 X4 X4,5 X4,5 – 2412 TETRAHYDROTHIOPHENE 3.2 X4 X4,5 X4,5 – 2413 TETRAPROPYL ORTHOTITANATE 3.3 X4 X4 X4 X4 2414 THIOPHENE 3.2 X4 – – – 2416 TRIMETHYL BORATE 3.2 X4 X4,8 X 4,8 – 2427 POTASSIUM CHLORATE, AQUEOUS SOLUTION 5.1 X – – – 2428 SODIUM CHLORATE AQUEOUS SOLUTION 5.1 X – – –

2429 CALCIUM CHLORATE, AQUEOUS SOLUTION 5.1 X – – –

2431 ortho-ANISIDINE 6.1 X X X X 2432 N,N-DIETHYLANILINE 6.1 X X X X 2433 CHLORO ortho-NITROTOLUENE 6.1 X X X –

2436 THIOACETIC ACID 3.2 X4 X4,8 X4,8 –

2457 2,3-DIMETHYLBUTANE 3.1 X4 – – –

2458 HEXADIENES 3.1 X4 – – –

2458 HEXADIENES 3.2 X4 X4,8 X4,8 –

2461 METHYLPENTADIENES 3.1 X4 — — –

2470 PHENYLACETONITRILE, LIQUID 6.1 X X X X 2474 THIOPHOSGENE 6.1 X4 X4 X4 –


3.2+6.1 X4,5,7 – – –


3.3+6.1 X4,5 – – –

2485 normal - BUTYL ISOCYANATE 6.1+3 X4,5,7 – – –

2486 ISOBUTYL ISOCYANATE 3.2+6.1 X 4,5,7 – – –

2490 DICHLOROISOPROPYL ETHER 6.1 X X X –

2491 ETHANOLAMINE or ETHANOLAMINE SOLUTION 8 X X X X 2493 HEXAMETHYLENEIMINE 3.2+8 X4 X4,5 X4,5 –



Types of IBCs


Subsidiary risk(s)

26.2 Metal

26.4 Rigid plastics

26.5 Compos-ite (31HZ1)

26.5 Compos-ite (31HA2

and 31HH2)

1 2 3 4 5 6 7 2656 QUINOLINE 6.1 X X X X 2662 HYDROQUINONE LIQUID 6.1 X X X X 2664 DIBROMOMETHANE 6.1 X X X X 2667 BUTYLTOLUENES 6.1 X X X X 2668 CHLOROACETONITRILE 6.1+3 X4 X4,5 X4,5 –

2669 CHLOROCRESOLS, LIQUID 6.1 X X X –

2672

AMMONIA aqueous SOLUTION, (relative density between 0.880 and 0.957 at 15°C) with more than 10% but not more than 35% ammo-nia, by mass

8 X X X X

2677 RUBIDIUM HYDROXIDE SOLUTION 8 X X X X3 2679 LITHIUM HYDROXIDE SOLUTION 8 X X X X3 2681 CAESIUM HYDROXIDE, SOLUTION 8 X X X X3 2683 AMMONIUM SULPHIDE SOLUTION 8 + 6.1 + 3* X4,5 — — –

2684 3-(DIETHYLAMINO)PROPYLAMINE 3.3+8 X4 X4 X4 –

2685 N,N-DIETHYLETHYLENEDIAMINE 8+3 X4 X4 X4 –

2686 2-DIETHYLAMINOETHANOL 8+3 X4 X4 X4 –

2688 1-CHLORO-3-BROMOPROPANE 6.1 X X X X 2689 GLYCEROL-alpha-MONOCHLORO-HYDRIN 6.1 X X X X 2690 N-normal-BUTYLIMIDAZOLE 6.1 X X X –

2693 BISULPHITES AQUEOUS SOLUTION N O S 8 X X X X

2705 1-PENTOL 8 X X X – 2707 DIMETHYLDIOXANES 3.3 X4 X4 X4 X4 2709 BUTYLBENZENES 3.3 X4 X4 X4 X4 2710 DIPROPYL KETONE 3.3 X4 X4 X4 X4 2730 NITROANISOLES, LIQUID 6.1 X X X X 2732 NITROBROMOBENZENES LIQUID 6.1 X X X X

* If flashpoint 61°C c.c. or below

IMDG CODE - PAGE 0223t (page 0223u follows) Amdt. 29-98


Types of IBCs


Subsidiary risk(s)

26.2, Metal

26.4 Rigid plastics

26.5 Compos-ite (31HZ1)

26.5 Compos-ite (31HA2

and 31HH2)

1 2 3 4 5 6 7

2733 AMINES, FLAMMABLE, CORROSIVE N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S.

3.1+8 X1,2,4 – – –

2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S.

3.2+8 X1,2,4 X1,2,4,8 X1,2,4,8 –

2733 AMINES FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S.

3.3+8 X4 X4 X4 –

2734 AMINES LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORRO-SIVE, FLAMMABLE, N.O.S.

8+3 X2,4 X2,4 X2,4 –

2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. 8 X2 X2 X2 X2,3

2738 N-normal-BUTYLANILINE 6.1 X X X

2739 BUTYRIC ANHYDRIDE 8 X X X X

2742 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 6.1+8 + 3* X4,5,7 – – –

2743 normal-BUTYL CHLOROFORMATE 6.1+8+3 X4,5,7 – – –

2744 CYCLOBUTYL CHLOROFORMATE 6.1+8+3 X4,5,7 – – –

2745 CHLOROMETHYL CHLOROFORMATE 6.1+8 X4,5,7 – – –

2746 PHENYL CHLOROFORMATE 6.1+8 X4,5,7 – – –

2747 tertiary-BUTYLCYCLOHEXYL CHLOROFOR-MATE 6.1 X X X X

2748 2-ETHYLHEXYL CHLOROFORMATE 6 1+8 X4,5,7 – – –

2750 1,3-DICHLOROPROPANOL-2 6.1 X X X –

2751 DIETHYLTHIOPHOSPHORYL CHLORIDE 8 X X X –

2752 1,2-EPOXY-3-ETHOXYPROPANE 3.3 X4 X4 X4 X4

* If flashpoint 61°C c. c. or below

IMDG CODE - PAGE 0223u (page 0223v follows) Amdt. 28-96


Types of IBCs



plastics 26.5 Compos-

ite (31HZ1) 26.5 Compos-

ite (31HA2 and 31HH2)

1 2 3 4 5 6 7

2753 N-ETHYL-N-BENZYLTOLUIDINES, LIQUID (ortho-, meta-, para- ) 6.1 X X X X

2754 N-ETHYLTOLUIDINES 6.1+3* X4 X4,5 X4,5 –

2758 CARBAMATE PESTICIDE, LIQUID, FLAMMA-BLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

2760 ARSENICAL PESTICIDE, LIQUID, FLAMMA-BLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

2776 COPPER BASED, PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

2778 MERCURY BASED, PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAM-MABLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

2785 4-THIAPENTANAL 6.1 X4,5 – – –

2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMA-BLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

* if flashpoint 61°C c.c. or below

IMDG CODE - PAGE 0223v (page 0223w follows) Amdt. 29-98


Types of IBCs






1 2 3 4 5 6 7 2788 ORGANOTIN COMPOUND LIQUID N O S 6.1 X2,4 X2,4 X2,4 X3,4

2789 ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, more than 80% acid, by mass 8+3 X4 X4 X4 –

2790 ACETIC ACID SOLUTION, not less than 10% but not more than 80% acid , by mass 8 X X X X8

2796 SULPHURIC ACID with not more than 51% acid 8 — X X –

2797 BATTERY FLUID, ALKALI 8 X X X –

2801 DYE, LIQUID, CORROSIVE N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE N.O.S.

8 X2,4,5 X2,4,5 X2,4,5 X3,4,5

2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 X2,4,5 X2,4,5 X2,4,5 X3,4,5

2815 N-AMINOETHYLPIPERAZINE 8 X X X X

2817 AMMONIUM HYDROGEN-DIFLUORIDE SOLUTION 8+6.1 X4,5,7 X4,5,7 X4,5,7 –

2818 AMMONIUM POLYSULPHIDE, SOLUTION 8+6.1 X4,5 X4,5 X4,5 –

2819 AMYL ACID PHOSPHATE 8 X X X X

2820 normal-BUTYRIC ACID 8 X X X X

2821 PHENOL SOLUTION 6.1 X X X X

2822 2-CHLOROPYRIDINE 6.1 X4 X4 X4 –

2826 ETHYL CHLOROTHIOFORMATE 8+3 X4 X4 X4 –

2829 CAPROIC ACID 8 X X X X

2831 1,1,1-TRICHLOROETHANE 6.1 X X X X

2834 PHOSPHOROUS ACID solution 8 X X X X

2838 VINYL BUTYRATE, INHIBITED 3.2 X4 X4,5 X4,5 –

2839 ALDOL 6.1 X X X –

2840 BUTYRALDOXIME 3.3 X4 X4 X4 X4

2841 DI-normal-AMYLAMINE 3.3+6.1 X4 X X –

2842 NITROETHANE 3.3 X4 X4 X4 X4

2849 3-CHLOROPROPANOL-1 6.1 X X X X

2850 PROPYLENE TETRAMER 3.3 X4 X4 X4 X4

2872 DIBROMOCHLOROPROPANES 6.1 X X X X3

IMDG CODE - PAGE 0223w (page 0223x follows) Amdt. 29-98


Types of IBCs






1 2 3 4 5 6 7 2873 N,N-DI-normal-BUTYLAMINO ETHANOL 6.1 X X X X

2874 FURFURYL ALCOHOL 6.1 X X X X

2902 PESTICIDE LIQUID, TOXIC, N.O.S. 6.1 X2,4,5 X2,4,5 X2,4,5 X3,4,5

2903 PESTICIDE LIQUID, TOXIC, FLAMMABLE, N.O.S. 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

2904 CHLOROPHENOLATES, LIQUID or PHE-NOLATES, LIQUID 8 X,5 X5 X5 X5

2920 CORROSIVE LIQUID FLAMMABLE N O S 8+3 X1,2,4,5 Xl,2,4,5 X1,2,4,5 –

2922 CORROSIVE LIQUID TOXIC N O S 8+6.1 X2,4,5 X2,4,5 X2,4,5 –

2924 FLAMMABLE LIQUID CORROSIVE N O S 3.2+8 XI,24,57 X1,2,4,7,8 X,1,2478 –

2924 FLAMMABLE LIQUID CORROSIVE N O S 3.3+8 X1,4,5 X1,4,5 Xl,4,5 –

2927 TOXIC LIQUID, CORROSIVE, ORGANIC N.O.S. 6.1+8 X2,4,5 X2,4,5 X2,4,5 –

2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

2933 METHYL-2-CHLOROPROPIONATE 3.3 X4 X4 X4 X4

2934 ISOPROPYL-2-CHLOROPROPIONATE 3.3 X4 X4 X4 X4

2935 ETHYL-2-CHLOROPROPIONATE 3.3 X4 X4 X4 X4

2936 THIOLACTIC ACID 6.1 X X X –

2937 alpha-METHYLBENZYL ALCOHOL LIQUID 6.1 X X X X

2941 FLUOROANILINES 6.1 X X X X

2942 2-TRIFLUOROMETHYLANILINE 6.1 X X X X

2943 TETRAHYDROFURFURYLAMINE 3.3 X4 X4 X4 X4

2945 N-METHYLBUTYLAMINE 3.2+8 X4 – – –

2946 2-AMINO-5-DIETHYLAMINO-PENTANE 6.1 X X X X

2947 ISOPROPYL CHLOROACETATE 3.3 X4 X4 X4 X4

2948 3-TRIFLUOROMETHYLANILINE 6.1 X X X –

IMDG CODE - PAGE 0223x (page 0223y follows) Amdt. 28-96


Types of IBCs






1 2 3 4 5 6 7 2949 SODIUM HYDROSULPHIDE, SOLUTION 8 X4 X4 X4 –

2966 THIOGLYCOL 6.1 X4 X4 X4 –

2984 HYDROGEN PEROXIDE, AQUEOUS SOLU-TION, with not less than 8% but less than 20% hydrogen peroxide

5.1 X6 X6 X6 –

2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

IMDG CODE - PAGE 0223y (page 0223z follows) Amdt. 29-98


Types of IBCs






1 2 3 4 5 6 7

3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

3009 COPPER-BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

3010 COPPER-BASED PESTICIDE LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

3011 MERCURY-BASED PESTICIDE, LIQUID, TOXIC FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

3012 MERCURY-BASED PESTICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

3016 BIPYRIDILIUM PESTICIDE, LIQUID TOXIC 6.1 X2 X2,5 X2,5 X3,5

3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

3019 ORGANOTIN PESTICIDE, LIQUID TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

3022 1,2-BUTYLENE OXIDE, STABILIZED 3.2 X4 – – –

IMDG CODE - PAGE 0223z (page 0223a1 follows) Amdt. 29-98


Types of IBCs




ite (31HZ1)

26.5 Compos-ite

(31HA2and 31HH2)

1 2 3 4 5 6 7

3024 COUMARIN DERIVATIVE, PESTICIDE, LIQ-UID, FLAMMABLE, TOXIC 3.2+6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

3025 COUMARIN DERIVATIVE, PESTICIDE, LIQ-UID, TOXIC, FLAMMABLE 6.1+3 X2,4,5 X2,4,5 X2,4,5 –

3026 COUMARIN DERIVATIVE, PESTICIDE, LIQ-UID, TOXIC 6.1 X2,5 X2,5 X2,5 X3,5

3054 CYCLOHEXYL MERCAPTAN 3.3 X4 X4 X4 X4

3055 2-(2-AMINOETHOXY)ETHANOL 8 X X X X

3056 normal-HEPTALDEHYDE 3.3 X4 X4 X4 X4

3065 ALCOHOLIC BEVERAGES 3.2 X4 X4 X4

3065 ALCOHOLIC BEVERAGES 3.3 X4 X4 X4 X4

3080 ISOCYANATES TOXIC, FLAMMABLE N.O.S. or ISOCYANATES, SOLUTION, TOXIC, FLAMMABLE N.O.S.

6.1+3 X4,5,7 – – –

3082 ENVIRONMENTALLY HAZARDOUS SUB-STANCE LIQUID N.O.S. 9 X5 X5 X5 X5

3109 ORGANIC PEROXIDE TYPE F LIQUID 5.2 – – – –

- tert-BUTYL PEROXYACETATE not more than 32% in diluent type A 5.2 X5,6,16,18 – X5,6,10,15,18 –

- tert-BUTYL-PEROXY-3,5,5-TRIMETHYLHEXANOATE not more than 32% in diluent type A

5.2 X5,6,16,18 – X5,6,10,15,18 –

- CUMYL HYDROPEROXIDE not more than 90% in diluent type A 5.2 — — X5,6,10,16,18 –

- DIBENZOYL PEROXIDE not more than 42% as a stable dispersion in water 5.2 – X5,6,15,18 – –

- DI-tert-BUTYL PEROXIDE not more than 32% in diluent type A 5.2 X5,6,16,18 — X5,6,10,15,18 –

- 1,1-DI-(tert-BUTYL-PEROXY) CYCLO-HEXANE not more than 42% in diluent type A

5.2 – X5,6,15,18 – –

- DILAUROYL PEROXIDE not more than 42% as a stable dispersion in water 5.2 – – X5,6,10,15,18 –

- ISOPROPYL CUMYL HYDROPEROX-IDE not more than 72% in diluent type A 5.2 – – X5,6,10,16,18 –

IMDG CODE - PAGE 0223a1 (page 0223b1 follows) Amdt. 29-98


Types of IBCs




ite (31HZ1) 26 5 Compos-


1 2 3 4 5 6 7

- p-MENTHYL HYDROPEROXIDE not more than 72% in diluent type A 5.2 – – X5,6,10,16,18 –

- PEROXYACETIC ACID, TYPE F stabilized, not more than 17% 5.2 X5,6,17,18 X5,6,17,18 X5,6,10,17,18 –

3119 ORGANIC PEROXIDE, TYPE F, LIQUID TEM-PERATURE CONTROLLED 5.2 – – – –

- tert-BUTYL PEROXY-2-ETHYL-HEXANOATE not more than 32% in diluent type B

5.2 X5,6,9,16,,18 – X5,6,9,10,12,15,18 –

- tert-BUTYL PEROXYPIVALATE not more than 27% in diluent type B 5.2 X5,6,9,16,18 – X5,6,9,10,13,15,18 –

- DI-(4-tert-BUTYLCYCLOHEXYL) PER-OXYDICARBONATE not more than 42% as a stable dispersion in water

5.2 – – X5,6,9,10,12,,15,18 –

- DICETYL PEROXYDICARBONATE not more than 42% as a stable dispersion in wa-ter

5.2 – – X5,6,9,10,12,15,,18 –

- DIMYRISTYL PEROXYDICARBONATE not more than 42% as a stable dispersion in wa-ter

5.2 – – X5,6,9,10,14,15,18 –

- DI-(3,5,5-TRIMETHYLHEXANOYL) PER-OXIDE, not more than 38% in diluent type A 5.2 X5,6,9,16,18 – X5,6,9,10,13,15,18 –

3139 OXIDIZING LIQUID, N.O.S. 5.1 X2,5 – – –

3141 ANTIMONY COMPOUND INORGANIC, LIQ-UID, N.O.S. 6.1 X2,5 X2,5 X2,5 X3,5

3142 DISINFECTANT, LIQUID, TOXIC N.O.S. 6.1 X5 X5 X5 X3,5

3144 NICOTINE COMPOUND LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, NOS 6.1 X2 X2 X2 X3

3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) 8 X X X X3

IMDG CODE - PAGE 0223b1 (page 0223c1 follows) Amdt. 29-98


Types of IBCs


Subsidiary risk(s) 26.2 Metal 26.4

Rigid plastics 26.5 Compos-



1 2 3 4 5 6 7

3149

HYDROGEN PEROXIDE AND PEROXYACE-TIC ACID, MIXTURE, with acid(s), water and not more than 5% peroxyacetic acid, STABI-LIZED

5.1+8 X6,11 X6,11 X,6,10,11 –

3151 POLYHALOGENATED BIPHENYLS, LIQUID and POLYHALOGENATED TERPHENYLS, LIQUID

9 X4 X4 X4 –

3210 CHLORATES, INORGANIC, AQUEOUS SO-LUTION, N.O.S. 5.1 X5 – – –

3211 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 X,5 – – –

3213 BROMATES, INORGANIC, AQUEOUS SOLU-TION, N.O.S. 5.1 X5 – – –

3214 PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 X5 – – –

3216 PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 X5 – – –

3218 NITRATES, INORGANIC, AQUEOUS SOLU-TION, N.O.S. 5.1 X5 – – –

3219 NITRITES, INORGANIC, AQUEOUS SOLU-TION, N.O.S. 5.1 X5 – – –

3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 8 X2,4,5 X2,4,5 X2,4,5 X3,4,5

3265 CORROSIVE LIQUID, ACIDIC ORGANIC, N.O.S. 8 X2,4,5 X2,4,5 X2,4,5 X3,4,5

3266 CORROSIVE LIQUID, BASIC INORGANIC, N.O.S. 8 X2,4,5 X2,4,5 X2,4,5 X3,4,5

3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 8 X2,4,5 X2,4,5 X2,4,5 X3,4,5

3276 NITRILES, TOXIC, N.O.S. 6.1 X2,4,5 X2,4,5 X2,4,5 X3,4,5

3287 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 X2,4,5 X2,4,5 X2,4,5 X3,4,5

3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 6.1+8 X2,4,5 X2,4,5 X2,4,5

3293 HYDRAZINE, AQUEOUS SOLUTION, with not more than 37% hydrazine, by mass 6.1 X4,5,7 X2,5,7 X4,5,7 X4,5,7

3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S

3.1 X1,2,4,5 – – –

IMDG CODE - PAGE 0223d (page 0223d1 follows) Amdt. 29-98


Types of IBCs


Subsidiary risk (s) 26.2 Metal 26.4 Rigid




1 2 3 4 5 6 7

3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S.

3.2 X1,2,4,8 X1,2,4,8 X1,2,4,8 –

3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN, MIXTURE, LIQUID, FLAMMABLE, N.O.S.

3.3 X4 X4,5 X4,5 X4,6

3346 PHENOXYACETIC ACID DERIVATIVE PES-TICIDE, LIQUID, FLAMMABLE, TOXIC 3.2+ 6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

3347 PHENOXYACETIC ACID DERIVATIVE PES-TICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+ 3 X2,4,5 X2,4,5 X2,4,5 –

3348 PHENOXYACETIC ACID DERIVATIVE PES-TICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

3350 PYRETHROID PESTICIDE, LIQUID, FLAM-MABLE, TOXIC 3.2+ 6.1 X2,4,5,7 X2,4,7,8 X2,4,7,8 –

3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE 6.1+ 3 X2,4,5 X2,4,5 X2,4,5 –

3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 X2 X2,5 X2,5 X3,5

IMDG CODE - PAGE 0223d1 (page 0224 follows) Amdt. 29-98


(This page is intentionally blank)

GENERAL INTRODUCTION Appendix 2 to section 26

LIST OF SOLID SUBSTANCES SUITABLE FOR TRANSPORT IN INTERMEDIATE BULK CONTAINERS (IBCs)

EXPLANATION OF COLUMNS

Column 1 United Nations Number (UN No.) of substance

Column 2 Proper shipping name of substance

Note: Depending on their hazards, mixtures or solutions should be treated in accordance with the require-ments of subsections 5.3 and 5.4 of this General Introduction.

Column 3 Class and subsidiary risk label(s) Types of IBCs Columns 4,

5, 6, 7, 8 and 9 26.2 Metal

26.3 Flexible

26.4 Rigid plastics

26 5 Composite

26.6 Fibreboard

26.7 Wooden

X Allowed for transport;

– Not allowed for transport.



General requirements For packaging group I solids Secondary protection is required for all IBCs except composite IBCs, which should be carried in closed cargo transport units. Secondary protection may be effected by placing the IBCs into freight containers or vehicles, which should have rigid sides or fencing at least to the height of the IBCs.

For packaging group II solids

Secondary protection should be provided for packaging group II solid substances and materials carried in flexible fibre-board composite or wooden IBCs.


1 Only packed in closed cargo transport units;

2 Substances falling under packaging group I criteria not allowed;

3 Only flexible IBCs or fibreboard IBCs fitted with a sift proof liner unless the IBC itself is made fully sift proof such as by application of a coating to the body of the IBC use of welded seams and sift proof closures etc.;

4 If textile IBCs are used only those with inner coating or inner liner should be used;

5 Hermetically sealed as defined in 10.9.1 of this General Introduction and in the introductions to the various classes;

6 Substances falling under packaging groups I or II criteria should be provided with secondary protection; 7 Only with competent authority approval;

8 Sift proof water resistant flexible fibreboard or wooden IBCs packed in closed cargo transport units;

9 Flexible fibreboard or wooden IBCs are intended for the transport of solids only and they should not be used when the contents are likely to melt or become liquid during the intended voyage;

10 Only water resistant flexible fibreboard or wooden IBCs;

11 May be transported without secondary protection subject to special requirements agreed between the competent authority of the country of loading and the flag State administration;

12 IBCs should be equipped with a self sealing venting device approved by the competent authority; 13 Substances falling under packaging group III criteria only; 14 Only water resistant wooden IBCs fitted with a sift proof liner; 15 Accessible stowage of closed cargo transport units see 21.4.3 of this General Introduction;

16 For packaging group I solid substances composite IBCs fitted with a flexible plastics inner receptacle (11HZ2 and 21HZ2) are not permitted;

17 Only 13H2,13H3,13H4,13L2,13L3 and 13L4 are permitted;

18 This is a wooden IBC containing a hermetically sealed flexible IBC with a liner. This flexible IBC should be approved in accordance with the requirements of 26.1 and 26.3. The assembled IBC should meet the standards of a compos-ite IBC and should be approved by the competent authority.



UN No. Substance Class +

subsidiary risk(s)

26.2 Metal

26.3 Flexi-ble

26.4 Rigid plas-

tics 26.5 Com-

posite 26.6 Fibre-

board 26.7

Wooden

1 2 3 4 5 6 7 8 91398 ALUMINIUM SILICON POWDER, UNCOATED 4.3 X X6 X X X8 X8 1402 CALCIUM CARBIDE 4.3 X5,6 – – – – –

1403 CALCIUM CYANAMIDE, with more than 0.1% calcium carbide 4.3 X – X X – –

1405 CALCIUM SILICIDE 4.3 X5 X5,8,13 X5 X5 X5,8,13 X5,8,13

1408 FERROSILICON, (with 30% or more but less than 90% silicon) 4.3 + 6.1 X X X X X X

1415 LITHIUM, solid fused only 4.3 X5,6 – – – – – 1417 LITHIUM SILICON 4.3 X5 – Xs X5 – – 1420 POTASSIUM METAL ALLOY, solid fused only 4,3 X5,6 – – – – – 1428 SODIUM, solid fused only 4.3 X5,6 – – – – – 1435 ZINC ASHES 4.3 X X6 X X X8 X8 1436 ZINC POWDER, or ZINC DUST 4.3 + 4.2 X X X X6,8 X6,8 1438 ALUMINIUM NITRATE 5.1 X X X X X X 1439 AMMONIUM DICHROMATE 5.1 X X3,4,6 X X X3,6 X6 1444 AMMONIUM PERSULPHATE 5.1 X X3,4 X X X3 X 1445 BARIUM CHLORATE, SOLID 5.1 X – X X X3,6,9 X6,9 1446 BARIUM NITRATE 5.1 + 6.1 X X3,4,6 X X X3,6 X6 1451 CAESIUM NITRATE 5.1 X X3,4,9 X X X3,9 X9 1452 CALCIUM CHLORATE 5.1 X X3,4,6,9,11 X X X3,6,9 X6,9 1453 CALCIUM CHLORITE 5.1 X X3,4,6,9 X X X3,6,9 X6,9 1454 CALCIUM NITRATE 5.1 X X X X X X 1458 CHLORATE AND BORATE, MIXTURE 5.1 X X3,4,6,9 X X X3,6,9 X6,9 1459 CHLORATE AND MAGNESIUM CHLORIDE, MIX- 5.1 X X1,4,6 X X X1,6 X1,6 1461 CHLORATES, INORGANIC, N.O.S, 5.1 X7 – X7 X7 – – 1462 CHLORITES, INORGANIC, N.O.S. 5.1 X7 – X7 X7 – – 1463 CHROMIUM TRIOXIDE, ANHYDROUS 5.1 + 8 X5 – X5 X5 – –




subsidiary risk(s)

26.2 Metal

26.3 Flexi-ble

26.4 Rigid plastics

26.5 Com-posite

26.6 Fibreboard

26.7 Wooden

1 2 3 4 5 6 7 8 9

1465 DIDYMIUM NITRATE 5.1 X X3,4,9 X X X3,9 X9

1466 FERRIC NITRATE 5.1 X X3,4,9 X X X3,9 X9

1467 GUANIDINE NITRATE 5.1 X X3,4 X X X3 X

1469 LEAD NITRATE 5.1+6.1 X X X X X X

1471 LITHIUM HYPOCHLORITE DRY or LITHIUM HY-POCHLORITE MIXTURE DRY 5.1 X – X X – –

1474 MAGNESIUM NITRATE 5.1 X X X X X X

1477 NITRATES INORGANIC, N.O.S. 5.1 X7 X3,4,6,7 X7 X7 X3,6,7, X6,7

1479 OXIDIZING SOLID N O S (Packaging group I) 5.1 X6,7 X6,7 X1,7,16 – –

1479 OXIDIZING SOLID, N.O.S. (Packaging groups II and III) 5.1 X7 X3,4,6,7 X7 X6,7 X3,6,7 X6,7

1485 POTASSIUM CHLORATE 5.1 X X3,4,6,9,11 X X X3,6,9 X6,9

1486 POTASSIUM NITRATE 5.1 X X X X X X

1487 POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE 5.1 X X3,4,6,9, X X X3,6,9 X6,9

1488 POTASSIUM NITRITE 5.1 X X3,4,6,9 X X X3,6,9 X6,9

1491 POTASSIUM PEROXIDE 5.1 X6,7 – X6,7 X6,7,16 – —

1492 POTASSIUM PERSULPHATE 5.1 X X3,4 X X X3 X

1493 SILVER NITRATE 5.1 X X3,1,6 X X X3,6 X6

1495 SODIUM CHLORATE 5.1 X X3,4,6,9,11 X X X3,6,9 X6,,9

1496 SODIUM CHLORITE 5.1 X X3,4,6,9 X X X3,6,9 X6,9

1498 SODIUM NITRATE 5.1 X X X X X X

1499 SODIUM NITRATE AND POTASSIUM NITRATE, MIXTURE 5.1 X X3,4 X X X3 X

1500 SODIUM NITRITE 5.1+6.1 X X3,4,9 X X X3,9 X9

1504 SODIUM PEROXIDE 5.1 X6,7 – X6,7 X6,7,16 – –

1505 SODIUM PERSULPHATE 5.1 X X3,4 X X X3 X

1506 STRONTIUM CHLORATE 5.1 X X3,4,6,9,11 X X X3,6,9 X6,9

1507 STRONTIUM NITRATE 5.1 X X3,4 X X X3 X




subsidiary risk(s)

26.2 Metal

26.3 Flexi-ble

26.4 Rigid plastics

26.5 Com-posite

26.6 Fibre-board

26.7 Wooden

1 2 3 4 5 6 7 8 9 1697 CHLOROACETOPHENONE, SOLID 6.1 X — X X — —

1707 THALLIUM COMPOUND, N.O.S. 6.1 X X3,6 X X X3,6 X6

1708 TOLUIDINE (para-), SOLID 6.1 X – X X – –

1709 2,4-TOLUYLENEDIAMINE, SOLID 6.1 X X3 X X X3 X

1711 3,4-DIMETHYLANILINE, SOLID 6.1 X – X X – –

1712 ZINC ARSENATE or ZINC ARSENITE or ZINC ARSENATE AND ZINC ARSENITE, MIXTURE 6.1 X X3,6 X X X3,6 X6

1713 ZINC CYANIDE 6.1 X5,6 — X5,6 X1,5,16 X1,5,14

1725 ALUMINIUM BROMIDE, ANHYDROUS 8 X5 X3,5,6,9,10 X5 X5 X3,5,6,9,10 X5,6,9,10

1726 ALUMINIUM CHLORIDE, ANHYDROUS 8 X5 y,3,5,6,9,10 X5 X5 X3,5,6,9,10 X5,6,9,10

1727 AMMONIUM HYDROGENDIFLUORIDE, SOLID 8 X5 X3,5,6,9,10 X5 X5 X3,5,6,9,10 X5,6,9,10

1733 ANTIMONY TRICHLORIDE, SOLID 8 X5 X3,5,6,9,10 X5 X5 X3,5,6,9,10 X5,6,9,10

1740 HYDROGENDIFLUORIDES, N.O.S. 8 X5 X3,5,6,7,10 X5 X5 X3,5,6,7,10 X5,6,7,10

1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HY-POCHLORITE, MIXTURE, DRY (more than 39% avail-able chlorine)

5.1 X — X X — —

1751 CHLOROACETIC ACID, SOLID 6.1+8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

1756 CHROMIC FLUORIDE, SOLID 8 X X3,6,10 X X y,3,6,10 X6,10

1759 CORROSIVE SOLID N O S (Packaging group I) 8 X6,7 – X6,7 X1,7 – X6,7

1759 CORROSIVE SOLID, N.O.S. (Packaging groups II and III) 8 X5,7 X3,5,6,7,9,10 X5,7 X5,6,7 X3,5,6,7,9,10 X5,6,7,9,10

1770 DIPHENYLMETHYL BROMIDE 8 X – X X – –

1773 FERRIC CHLORIDE, ANHYDROUS 8 X X3,10 X X X3,10 X10

1794 LEAD SULPHATE with more than 3% free acid 8 X – X X – –

1805 PHOSPHORIC ACID, SOLID 8 X – X X – –

1806 PHOSPHORUS PENTACHLORIDE 8 X5 X3,5,6,10 X5 X5 X3,5,6,10 X5,6,10

1807 PHOSPHORUS PENTOXIDE 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10



UN No. Substance Class+

subsidiary risk (s)

26.2 Metal

26.3 Flexi-ble

26.4 Rigid plastics

26.5 Com-posite

26.6 Fibre-board

26.7 Wooden

1 2 3 4 5 6 7 8 9

1811 POTASSIUM HYDROGENDIFLUORIDE, SOLID 8+ 6.1 X5 X3,5,6,9,10 X5 X5 X3,5,6,9,10 X5,6,9,10

1812 POTASSIUM FLUORIDE, SOLID 6.1 X X3,9 X X X3,9 X9

1813 POTASSIUM HYDROXIDE, SOLID 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

1823 SODIUM HYDROXIDE, SOLID 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

1825 SODIUM MONOXIDE 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

1830 SULPHURIC ACID with more than 51% acid 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

1835 TETRAMETHYLAMMONIUM HYDROXIDE 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

1839 TRICHLOROACETIC ACID SOLID 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

1841 ACETALDEHYDE AMMONIA 9 X X3 X X X3 X

1843 AMMONIUM DINITRO-ortho-CRESOL ATE, 6.1 X X3,6,9 X X X3,6,9 X6,9

1847 POTASSIUM SULPHIDE, HYDRATED 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

1849 SODIUM SULPHIDE, HYDRATED 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

1856 RAGS, OILY 4.2 – X — — — –

1868 DECABORANE 4.1+ 6.1 X5 — X5 X5 — –

1869 MAGNESIUM or MAGNESIUM ALLOYS 4.1 X X3 X X X3 X

1871 TITANIUM HYDRIDE 4.1 X5 — — – — –

1872 LEAD DIOXIDE 5.1 X X3,4 X X X3 X

1884 BARIUM OXIDE 6.1 X X3,10 X X X3,10 X10

1885 BENZIDINE 6.1 X X3,6 X X X3,6 X6

1894 PHENYLMERCURIC HYDROXIDE 6.1 X X3,6 X X X3,6 X6

1895 PHENYLMERCURIC NITRATE 6.1 X X3,6 X X X3,6 X6

1905 SELENIC ACID 8 X6 – X6 X1 — X6

1907 SODA LIME 8 X X3,9,10 X X X3,9,10 X9,10

1923 CALCIUM DITHIONITE 4.2 X5 — X5 X5 — –

1929 POTASSIUM DITHIONITE 4.2 X5 – X5 X5 – —

1931 ZINC DITHIONITE 9 X X3 X X X3 X

1938 BROMOACETIC ACID, SOLID 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

1939 PHOSPHORUS OXYBROMIDE, SOLID 8 X5 X3,5,6,9,10 X5 X5 X3,5,6,9,10 X5,6,9,10




subsidiary risk (s)

26.2 Metal

26.3 Flexi-ble

26.4 Rigid plastics

26.5 Com-posite

26.6 Fibre-board

26.7 Wooden

1 2 3 4 5 6 7 8 9

2305 NITROBENZENESULPHONIC ACID, (ortho-, meta, para-) 8 X X3,6,10 X X X3,6,10 X6,10

2306 NITROBENZOTRIFLUORIDES, SOLID 6.1 X - X X - -

2315 POLYCHLORINATED BIPHENYLS 9 X X3,6 X X X3,6 X6

2316 SODIUM CUPROCYANIDE, SOLID 6.1 X5,6 - X5,6 X1,5,16 - X1,5,14

2318 SODIUM HYDROSULPHIDE with less than 25% water of crystallization 4.2 X5 - X5 X5 - -

2331 ZINC CHLORIDE, ANHYDROUS 8 X X3,9,10 X X X3,9,10 X9,10

2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) (Packaging group I) 8 X6 — X6 X1 — X6

2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) (Packaging groups II and III) 8 X X3,6,9 X X6 X3,6,9 X6,9

2433 CHLORONITROTOLUENES 6.1 X - X X - -

2439 SODIUM HYDROGENDIFLUORIDE 8 X5 X3,5,6,10 X5 X5 X3,5,6,10 X5,6,10

2440 STANNIC CHLORIDE PENTAHYDRATE 8 X X3,9,10 X X X3,9,10 X9,10

2446 NITROCRESOLS 6.1 X - X X - -

2464 BERYLLIUM NITRATE 5.1+ 6.1 X X3,4,6 X X X3,6 X6

2465 DICHLOROISOCYANURIC ACID, DRY or DI-CHLOROISOCYANURIC ACID, SALTS 5.1 X X3,4,6,9 X X X3,6,9 X6,9

2466 POTASSIUM SUPEROXIDE 5.1 X6,7 - X6,7 X6,7,16 - —

2468 TRICHLOROISOCYANURIC ACID, DRY 5.1 X X3,4,6 X X X3,6 X6

2473 SODIUM ARSANILATE 6.1 X X3 X X X3 X

2475 VANADIUM TRICHLORIDE 8 X X3,9,10 X X X3,9,10 X9,10

2503 ZIRCONIUM TETRACHLORIDE 8 X X3,9,10 X X X3,9,10 X9,10

2505 AMMONIUM FLUORIDE 6.1 X X3 X X X3 X

2506 AMMONIUM HYDROGEN SULPHATE 8 X X3,6,10 X X X3,6,10 X6,10

2507 CHLOROPLATINIC ACID, SOLID 8 X X3,9,10 X X X3,9,10 X9,10

IMDG CODE - PAGE 0226l (page 0226m follows) Amdt. 29-98



subsidiary risk (s)

26.2 Metal

26.3 Flexi-ble

26.4 Rigid plastics

26.5 Com-posite

26.6 Fibre-board

26.7 Wooden

1 2 3 4 5 6 7 8 9

2508 MOLYBDENUM PENTACHLORIDE 8 X5 X3,5,9,10 X5 X5 X3,5,9,10 X5,9,10

2509 POTASSIUM HYDROGEN SULPHATE 8 X X3,6,10 X X X3,6,10 X6,10

2511 2-CHLOROPROPIONIC ACID, solid 8 X X3,9,10 X X X3,9,10 X9,10

2512 AMINOPHENOLS (-ortho,-meta,-para) 6.1 X X3 X X X3 X

2516 CARBON TETRABROMIDE 6.1 X X3,9 X X X3,9 X9

2538 NITRONAPHTHALENE 4.1 X X3 X X X3 X

2547 SODIUM SUPEROXIDE 5.1 X6,7 — X6,7 X6,7,16 —

2567 SODIUM PENTACHLOROPHENATE 6.1 X X3,6 X X X3,6 X6

2570 CADMIUM COMPOUND (Packaging group I) 6.1 X6 – X6 X1,16 – X6,14

2570 CADMIUM COMPOUND (Packaging groups II and 6.1 X X3,6 X X6 X3,6 X6

2573 THALLIUM CHLORATE 5.1+ 6.1 X X3,4,6,9 X X X3,6,9 X6,9

2578 PHOSPHORUS TRIOXIDE 8 X – X X —

2579 PIPERAZINE SOLID 8 X X3,9,10 X X X3,9,10 X9,10

2583 ALKYLSULPHONIC ACIDS, SOLID or ARYLSUL-PHONIC ACIDS, SOLID with more than 5% free sulphuric acid

8 X X3,6,10 X X X3,6,10 X6,10

2585 ALKYLSULPHONIC ACIDS, SOLID or ARYLSUL-PHONIC ACIDS, SOLID with not more than 5% free sulphuric acid

8 X X3,6,10 X X X3,6,10 X6,10

2587 BENZOQUINONE 6.1 X X3,6 X X X3,6 X6

2588 PESTICIDE SOLID TOXIC N O S (Packaging 6.1 X6 – X6 X1 – X6

2588 PESTICIDE, SOLID, TOXIC, N.O.S. (Packaging groups II and III) 6.1 X X3,6 X X6 X.3,6 X6

2590 ASBESTOS WHITE 9 X X3 X X X3 X

2623 FIRELIGHTERS, SOLID 4.1 X — X X X6 X6

2624 MAGNESIUM SILICIDE 4.3 X5 – X5 X – –




subsidiary risk (s)

26.2 Metal

26.3 Flexi-ble

26.4 Rigid plastics

26.5 Com-posite

26.6 Fibre-board

26.7 Wooden

1 2 3 4 5 6 7 8 9

2763 TRIAZINE PESTICIDE, SOLID, TOXIC (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC (Packaging group I) 6.1 X6 – X6 X1 – X6

2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

2775 COPPER BASED PESTICIDE, SOLID, TOXIC (Packaging group I) 6.1 X6 – X6 X1 – X6

2775 COPPER BASED PESTICIDE, SOLID, TOXIC (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

2777 MERCURY-BASED PESTICIDE, SOLID, TOXIC (Packaging group I) 6.1 X6 – X6 X1,16 – X6,14

2777 MERCURY-BASED PESTICIDE, SOLID, TOXIC (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC (Packaging group I) 6.1 X6 — X6 X1 – X6




subsidiary risk (s)

26.2 Metal

26.3 Flexi-ble

26.4 Rigid plastics

26.5 Com-posite

26.6 Fibre-board

26.7 Wooden

1 2 3 4 5 6 7 8 9

2779 SUBSTITUTED NITROPHENOL, PESTICIDE, SOLID, TOXIC (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

2781 BIPYRIDILIUM PESTICIDE, SOLID TOXIC (Pack-aging group I) 6.1 X6 – X6 X1 – X6

2781 BIPYRIDILIUM PESTICIDE, SOLID TOXIC (Pack-aging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC (Packaging group I) 6.1 X6 – X6 X1 – X6

2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

2786 ORGANOTIN PESTICIDE, SOLID, TOXIC (Packag-ing group I) 6.1 X6 – X6 X1,16 – X6,14

2786 ORGANOTIN PESTICIDE, SOLID, TOXIC (Packag-ing groups II and III) 6.1 X X3,6 X X6 X3,6, X6

2793 FERROUS METAL BORINGS, SHAVINGS, TURN-INGS or CUTTINGS in a form liable to self-heating 4.2 X – – – – –

2796 SULPHURIC ACID with not more than 51% acid 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

2802 COPPER CHLORIDE 8 X X3,9,10 X X X3,9,10 X9,10

2805 LITHIUM HYDRIDE, FUSED SOLID 4.3 X5 – – – – –

2806 LITHIUM NITRIDE 4.3 X5,6 – – – – –

2811 TOXIC SOLID, ORGANIC N.O.S. (Packaging group I) 6.1 X6,7 – X6,7 X1,7 – X6,7

2811 TOXIC SOLID, ORGANIC N.O.S. (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

2813 WATER REACTIVE SOLID, N.O.S. 4.3 X5,6,7 – – – – –

2823 CROTONIC ACID 8 X X3,10 X X X3,10 X10

2830 LITHIUM FERROSILICON 4.3 X5 — X5 X5

2834 PHOSPHOROUS ACID, solid 8 X X3,9,10 X X X3,9,10 X9,10

2844 CALCIUM MANGANESE SILICON 4.3 X5 – X5 X5 – –




subsidiary risk (s)

26.2 Metal

26.3 Flexi-ble

26.4 Rigid plastics

26.5 Com-posite

26.6 Fibre-board

26.7 Wooden

1 2 3 4 5 6 7 8 9 2853 MAGNESIUM FLUOROSILICATE 6.1 X X3 X X X3 X

2854 AMMONIUM FLUOROSILICATE 6.1 X X3 X X X3 X

2855 ZINC FLUOROSILICATE 6.1 X X3 X X X3 X

2856 FLUOROSILICATES, N.O.S. 6.1 X X3 X X X3 X

2859 AMMONIUM METAVANADATE 6.1 X X3,6 X X X3,6 X6

2861 AMMONIUM POLYVANADATE 6.1 X X3,6 X X X3,6 X6

2862 VANADIUM PENTOXIDE, non-fused form 6.1 X X3 X X X3 X

2863 SODIUM AMMONIUM VANADATE 6.1 X X3,6,9 X X X3,6,9 X6,9

2864 POTASSIUM METAVANADATE 6.1 X X3,6 X X X3,6 X6

2865 HYDROXYLAMINE SULPHATE 8 X X3,10 X X X3,10 X10

2869 TITANIUM TRICHLORIDE MIXTURE, non-pyrophoric 8 X5 X3,5,6,10 X5 X5 X3,5,6,10 X5,6,10

2871 ANTIMONY POWDER 6.1 X X3 X X X3 X

2875 HEXACHLOROPHENE 6.1 X X3 X X X3 X

2876 RESORCINOL 6.1 X X3 X X X3 X

2878 TITANIUM, SPONGE GRANULES, or TITANIUM, SPONGE POWDERS 4.1 X – X X X3 X

2880 CALCIUM HYPOCHLORITE, HYDRATED, or CAL-CIUM HYPOCHLORITE, HYDRATED MIXTURE, with more than 5.5% but not more than 10% water

5.1 X – X X – –

2905 CHLOROPHENOLATES, SOLID or PHENOLATES, SOLID 8 X X3,10 X X X3,10 X10

2921 CORROSIVE SOLID FLAMMABLE, N.O.S. (Pack-aging group I) 8+ 4.1 X6,7 – X6,7 X1,7,16 – –

2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. (Pack-aging group II) 8+ 4.1 X5,7 – X5,7 X5,6,7 – –

2923 CORROSIVE SOLID, TOXIC, N.O.S. (Packaging group I) 8+ 6.1 X6,7 – X6,7 X',7 – –

2923 CORROSIVE SOLID, TOXIC, N.O.S. (Packaging groups II and III) 8+ 6.1 X5,7 – X3,7 X5,6,7 – –

2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. 4.1+ 8 X2,5,7 — X2,5,7 X2,5,7 – –




subsidiary risk (s)

26.2 Metal

26.3 Flexi-ble

26.4 Rigid plastics

26.5 Com-posite

26.6 Fibreboard

26.7 Wooden

1 2 3 4 5 6 7 8 9

2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 4.1+ 6.1 X2,5,7 – X2,5,7 X2,5,7 – –

2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. (Packaging group I) 6.1+ 8 X6,7 – X6,7 X1,7 – –

2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. (Packaging group II) 6.1+ 8 X6,7 – X5,7 X5,6,7 – –

2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. (Packaging group I) 6.1+ 4.1 X6,7 – X6,7 X1,7,16 – –

2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. (Packaging group II) 6.1+ 4.1 X5 – X5,7 X5,6,7 – –

2931 VANADYL SULPHATE 6.1 X X3,6 X X X3,6 X6

2937 alpha -METHYLBENZYL ALCOHOL, SOLID 6.1 X – X X – –

2940 9-PHOSPHABICYCLONONANES 4.2 X5 – X5 X5 — —

2949 SODIUM HYDROSULPHIDE, SOLID with not less than 25% water of crystallization 8 X X3,6,9,10 X X X3,6,9,10 X6,9,10

2950 MAGNESIUM GRANULES, COATED containing more than 50% magnesium 4.3 X X8 X X X8 X8

2967 SULPHAMIC ACID 8 X X3,10 X X X3,10 X10

2968 MANEB or MANEB PREPARATIONS STABILIZED against self heating 4.3 X X8 X X X8 X8

2969 CASTOR BEANS or CASTOR MEAL or CASTOR POMACE or CASTOR FLAKE 9 X X3,6 X X X3,6 X6

2989 LEAD PHOSPHITE DIBASIC 4.1 X X3,6 X X X3,6 X6

3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC (Packaging group I) 6.1 X6 — X6 X1 — X6

3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

3077 ENVIRONMENTALLY HAZARDOUS, SUB-STANCE, SOLID, N.O.S. 9 X X3 X X X3 X

3078 CERIUM turnings or gritty powder 4.3 X5 – X5 X5 X3,5,6 X5,6

IMDG CODE - PAGE 0226s (page 0226t follows) Amdt. 28-96


26.2 26.3 26.4 26.5 26.6 26.7 UN No. Substance

Class+ subsidiary

risk (s) Metal Flexible Rigid plastics Composite Fibreboard Wooden

1 2 3 4 5 6 7 8 9

3088 SELF HEATING SOLID, ORGANIC, N.O.S. 4.2 X5 — X5 X5 – –

3096 CORROSIVE SOLID, WATER REACTIVE, N.O.S. 8+ 4.3 X5,6,7 – X2,6,7 X1,5,7,16 – –

3110 ORGANIC PEROXIDE, TYPE F, SOLID 5.2 X7,12 X3,6,7,9,10,12 X7,12 X7,12,15 X3,6,7,9,10,12 –

3120 ORGANIC PEROXIDE TYPE F, SOLID, TEMPERA-TURE CONTROLLED 5.2 X7,12,5 X3,6,9,10,12,15 X7,12 X7,12,15 X3,6,7,10,12,15 —

3131 WATER REACTIVE SOLID, CORROSIVE, N.O.S. 4.3+ 8 X5,6,7 – – – – –

3132 WATER REACTIVE SOLID, FLAMMABLE, N.O.S. 4.3+ 4.1 X2,5,6,7 – – – – –

3134 WATER REACTIVE SOLID, TOXIC, N.O.S. 4.3+ 6.1 X2,6,7 — — – – –

3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDI-ATE, SOLID, TOXIC, N.O.S. (Packaging group I) 6.1 X6,7 — X6 X1,7 — X6,7

3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDI-ATE, SOLID, TOXIC, N.O.S. (Packaging groups II and III)

6.1 X X3,6,9 X X6 X3,6,9 X6,9

3146 ORGANOTIN COMPOUND, SOLID, N.O.S. (Packag-ing group I) 6.1 X6 – X6 X1,16 — X6,14

3146 ORGANOTIN COMPOUND, SOLID, N.O.S. (Packag-ing groups II and III) 6.1 X X3,6 X X6 X3,6 X6

3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTER-MEDIATE, SOLID, CORROSIVE, N.O.S. (Packaging group I)

8 X6,7 — X6,7 X1,7 — X6,7,9,10

3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTER-MEDIATE, SOLID, CORROSIVE, N.O.S. (Packaging groups II and III)

8 X X3,6,9,10 X X X3,6,9,10 X6,9,9

3152 POLYHALOGENATED BIPHENYLS, SOLID or POLYHALOGENATED TERPHENYLS, SOLID 9 X X3,6 X X X3,6 X6

3174 TITANIUM DISULPHIDE 4.2 X5,7 X5,7 X5,7 X5,7 X5,7 X5,7

3178 FLAMMABLE SOLID, INORGANIC, N.O.S. 4.1 X2,5 X2,5,6,7 X2,5,7 X2,5,7 X2,5,6,7, X2,5,6,7

3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 4.1+ 6.1 X2,5,7 – X2,5,7 X2,5 – –

3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. 4.1+ 8 X2,5,7 – X2,5,7 X2,5,7 – –

IMDG CODE - PAGE 0226t (page 0226u follows) Amdt. 29-98


26.2 26.3 26.4 26.5 26.6 26.7 UN No. Substance

Class+ subsidiary

risk (s) Metal Flexible Rigid plas-tics Composite Fibreboard Wooden

1 2 3 4 5 6 7 8 9

3190 SELF-HEATING SOLID, INORGANIC, N.O.S. 4.2 X5,7 – – – – –

3208 METALLIC SUBSTANCE, WATER REACTIVE, N.O.S. 4.3 X5,6,7 – – – – –

3212 HYPOCHLORITES, INORGANIC, N.O.S. 5.1 X7 – X7 X7 — –

3215 PERSULPHATES, INORGANIC, N.O.S. 5.1 X7 – X7 X7 – –

3247 SODIUM PEROXOBORATE, ANHYDROUS 5.1 X X3,4,6,9 X X X3,6,9 X6,9

3253 DISODIUM TRIOXOSILICATE 8 X X3,10 X X X3,10 X10

3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLY-AMINES, SOLID, CORROSIVE, N.O.S. (Packaging group I)

8 X6,7 — X6,7 XI,7 — X6,7

3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES SOLID, CORROSIVE, N.O.S. (Packaging groups II and III)

8 X5,7 X3,5,6,7,9,10 X5,7 X5,6,7 X3,5,6,7,9,10 X5,6,7,9,10

3260 CORROSIVE SOLID ACIDIC, INORGANIC N.O.S. (Packaging group I) 8 X6,7 — X6,7 X1,7 — X6,7

3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Packaging groups II and III) 8 X5,7 X3,5,6,7,9,10 X5,7 X5,6,7 X3,5,6,7,9,10 X5,6,7,9,10

3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (Pack-aging group I) 8 X6,7 – X6,7 XI,7 – X6,7

3261 CORROSIVE SOLID ACIDIC, ORGANIC, N.O.S. (Pack-aging groups II and III) 8 X5,7 X3,5,6,7,9,10 X5,7 X5,6,7 X3,5,6,7,9,10 X5,6,7,9,10

3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (Packaging group I) 8 X6,7 – X6,7 X1,7 – X6,7

3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (Packaging groups II and III) 8 X5,7 X3,5,6,7,9,10 X5,7 X5,6,7 X3,5,6,7,9,10 X5,6,7,9,10

IMDG CODE - PAGE 0226u (page 0226v follows) Amdt. 28-96


26.2 26.3 26.4 26.5 26.6 26.7 UN No. Substance

Class+ subsidiary

risk (s) Metal Flexible Rigid plas-tics Composite Fibreboard Wooden

1 2 3 4 5 6 7 8 9

3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (Pack-aging group I) 8 X6,7 – X6,7 X1,7 – X6,7

3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (Pack-aging groups II and III) 8 X5,7 X3,5,6,7,9,10 X5,7 X5,6,7 X3,5,6,7,9,10 X5,6,7,9,10

3276 NITRILES, TOXIC, N.O.S. (Packaging group I) 6.1 X6,7 — X6 X1,7 — X6,7

3278 ORGANOPHOSPHORUS COMPOUND, TOXIC, N.O.S. 6.1 X6 – X6 X1 – X6

3280 ORGANOARSENIC COMPOUND, N.O.S. 6.1 X6 – X6 X1 – X6

3281 METAL CARBONYLS, N.O.S. (Packaging group I) 6.1 X6,7 – X6,7 X1,7 – X6,7

3281 METAL CARBONYLS, N.O.S. (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

3282 ORGANOMETALLIC COMPOUND, TOXIC, N.O.S. (Packaging group I) 6.1 X6,7 — X6,7 X1,7 — X6,7

3282 ORGANOMETALLIC COMPOUND, TOXIC, N.O.S. (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

3283 SELENIUM COMPOUND, N.O.S. (Packaging group I) 6.1 X6,7 – X6 X1,7 – X6,7

3283 SELENIUM COMPOUND, N.O.S. (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

3284 TELLURIUM COMPOUND, N.O.S. (Packaging group I) 6.1 X6,7 – X6 X1,7 – X6,7

3284 TELLURIUM COMPOUND, N.O.S. (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

3285 VANADIUM COMPOUND, N.O.S. (Packaging group I) 6.1 X6,7 – X6 X1,7 – X6,7

3285 VANADIUM COMPOUND, N.O.S. (Packaging groups II and III) 6.1 X X3,6, X X6 X3,6 X6

IMDG CODE - PAGE 0226v (page 0226w follows) Amdt. 29-98


26.2 26.3 26.4 26.5 26.6 26.7 UN No. Substance

Class + subsidiary

risk(s) Metal Flexible Rigid plastics Composite Fibreboard Wooden

1 2 3 4 5 6 7 8 9 3288 TOXIC SOLID, INORGANIC, N.O.S. (Packaging group I) 6.1 X6,7 – X6,7 X1,7 – X6,7

3288 TOXIC SOLID, INORGANIC, N.O.S. (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 6.1+8 X6,7 – X6,7 X1,7 – –

3313 ORGANIC PIGMENTS, SELF-HEATING 4.2 – X1,5,17 – — — —

3341 THIOUREA DIOXIDE 4.2 X5,7 X5,7 X5,7 X5,7 X5,7 X5,7

3342 XANTHATES 4.2 XI,5 — X1,5 X1,5,7 — X1,7,18

3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC (Packaging group I) 6.1 X6 — X6 X1 — X6

3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC (Packaging groups II and III) 6.1 X X3,6 X X6 X3,6 X6

3349 PYRETHROID PESTICIDE SOLID, TOXIC (Packaging group I) 6.1 X6 — X6 X1 — X6

3349 PYRETHROID PESTICIDE, SOLID, TOXIC (Packaging groups II and III) 6.1 X X3,6 X X6 X3,,6 X6

IMDG CODE - PAGE 0226w (page 0227 follows) Amdt. 29-98

ANNEX

Packagings are receptacles and any other components or materials necessary for the receptacle to perform its contain-ment function.

Receptacles are containment vessels for receiving and holding substances or articles including any means of closing.

Reconditioned packagings include:

(a) metal drums, that 1 are cleaned to original materials of construction with all former contents, internal and external corrosion and external

coatings and labels removed; 2 are restored to original shape and contour with chimes (if any) straightened and sealed and all non-integral gaskets

replaced; and 3 are inspected after cleaning but before painting with rejection of packagings with visible pitting significant reduction in

material thickness metal fatigue, damaged threads or closures, or other significant defects.

(b) plastics drums and jerricans, that 1 are cleaned to original materials of construction, with all former contents, external coating and labels removed; 2 have all non-integral gaskets replaced; and 3 are inspected after cleaning with rejection of packagings with visible damage such as tears creases or cracks, or dam-

aged threads or closures.

Recycled plastics material means material recovered from used industrial packagings that has been cleaned and prepared for processing into new packagings. The specific properties of the recycled material used for production of new packagings should be assured and documented regularly as part of a quality assurance programme recognized by the competent authority. The quality assurance programme should include a record of proper pre-sorting and verification, that each batch or recycled plastics material has the proper melt flow rate, density and tensile yield strength, consistent with that of the design type manufactured from such recycled material. This necessarily includes knowledge about the packaging material from which the recycled plastics have been derived, as well as awareness of the prior contents of those packagings, if those prior contents might reduce the capability of new packagings produced using that material In addition, the packaging manufacturer's quality assurance programme under 3.15 should include performance of the mechanical design type test in section 8 of this Annex on packagings manufactured from each batch of recycled plastics material. In this testing stacking performance may be verified by appropriate dynamic compression testing rather than static load testing. Remanufactured packagings include:

(a) metal drums, that:

1 are produced as a UN type from a non UN type; 2 are converted from one UN type to another UN type; or 3 undergo the replacement of integral structural components (such as non-removable heads).


ANNEX I

(b) plastics drums, that: .1 are converted from one UN type to another UN type (e.g. 1H1 to 1H2), or

.2 undergo the replacement of integral structural components.

Remanufactured drums are subject to the same requirements of this Annex as those that apply to a new drum of the same type.

Reused packagings are packagings to be refilled which have been examined and found free of defects affecting their ability to withstand the performance tests the term includes those, which are refilled with the same or similar compatible contents and are transported within distribution chains controlled by the consignor of the product. Salvage packagings are special packagings conforming to the applicable requirements of this Annex, into which, damaged, defective or leaking dangerous goods packages, or dangerous goods that have spilled or leaked are placed, for the purposes of transport, recovery or disposal.

Siftproof packagings are packagings impermeable to dry contents, including fine solid material produced during transport.

Wooden barrels are packagings made of natural wood, of round cross-section, having convex walls, consisting of staves and heads and fitted with hoops. The following explanations and examples are meant to assist in clarifying the use of the terms defined in 2.1 The definitions in 2.1 are consistent with the use of the defined terms throughout this Annex. However, other parts of this Code currently use some of the defined terms in other ways. This is particularly evident in respect of the term "inner receptacle", which is often used to describe the "inners" of a combination packaging.

In this Annex the "inners" of "combination packagings” are always termed “inner packagings", not "inner recepta-cles". A glass carboy is an example of such an "inner packaging".


ANNEX I


ANNEX I

2.2.3 In this Annex the inners of composite packagings are termed inner receptacles. For example the inner of a 6HA1

composite packaging (plastics material) is such an inner receptacle since it is normally not designed to perform a containment function without its outer packaging and is not, therefore, an inner packaging.

3 GENERAL PACKING REQUIREMENTS

3.1 Dangerous goods should be packaged in packagings of good quality which should be constructed and closed so as to prevent the package as prepared for transport from any leakage, which might be caused by vibration or by changes in temperature, humidity or pressure. No harmful quantity of a dangerous substance should adhere to the outside of a package. These provisions apply both to new and to reused packagings.

3.2 Parts of packagings which are in direct contact with dangerous substances should not be affected by chemical or other action of those substances. Where necessary they should be provided with a suitable inner coating or treat-ment. Such parts of packagings should not incorporate constituents liable to react dangerously with the contents so as to form hazardous products or to weaken them significantly.

3.3 Each packaging except inner packagings of combination packagings should conform to a design type successfully tested in accordance with the requirements laid down in section 8.

3.4 When filling packagings with liquids* sufficient ullage (outage) should be left to ensure that neither leakage nor per-manent distortion of the packaging occurs as a result of an expansion of the liquid caused by temperatures likely to occur during transport. Unless specific requirements are prescribed in national or international rules agreements or recommendations liquids should not completely fill a packaging at a temperature of 55°C.

3.5 Inner packagings should be packaged in an outer packaging in such a way that under normal conditions of transport they cannot break be punctured or leak their contents into the outer packaging Inner packagings that are liable to break or be punctured easily such as those made of glass porcelain or stoneware or of certain plastics materials etc should be secured in outer packagings with suitable cushioning material Any leakage of the contents should not substantially impair the protective properties of the cushioning material or of the outer packaging.

3.6 Dangerous goods should not be packed together in the same outer packaging with dangerous or other goods if they react dangerously with each other and cause

1. combustion and/or evolution of considerable heat;

2. evolution of flammable poisonous or asphyxiant gases;

3. the formation of corrosive substances; or

4. the formation of unstable substances.

* With respect to ullage limits only viscous substances with an outflow time via a DIN cup with a 4 mm diameter outlet exceeding 10 minutes at 20°C (corresponding to an outflow time via a Ford cup 4 of more than 690 seconds at 20°C or to a viscosity of more than 2.680 cent stokes at 20°C) should be subject to the provisions applicable for packagings destined for solid substances.


ANNEX I

7.3.3 Openings in jerricans (3A1 and 3B1) should not exceed 7 cm in diameter Jerricans with larger openings are con-

sidered to be of the removable head type (3A2 and 3B2). Closures should be so designed that they will remain secure and leakproof under normal conditions of transport. Gaskets or other sealing elements should be used with closures unless the closure is inherently leakproof.

7.3.4 If materials used for body heads, closures and fittings are not in themselves compatible with the contents to be transported, suitable internal protective coatings or treatments should be applied. These coatings or treatments should retain their protective properties under normal conditions of transport.

7.3.5 Maximum capacity of jerrican 60 litres.

7.3.6 Maximum net mass 120 kg.

7.4 Plywood drums 1D

7.4.1 The wood used should be well seasoned commercially dry and free from any defect likely to lessen the effective-ness of the drum for the purpose intended. If a material other than plywood is used for the manufacture of the heads, it should be of a quality equivalent to the plywood.

7.4.2 At least two-ply plywood should be used for the body and at least three ply plywood for the heads the plies should be firmly glued together by a water-resistant adhesive with their grain crosswise.

7.4.3 The body and heads of the drum and their joins should be of a design appropriate to the capacity of the drum and intended use.

7.4.4 In order to prevent sifting of the contents lids should be lined with kraft paper or some other equivalent material, which should be securely fastened to the lid and extend to the outside along its full circumference.

7.4.5 Maximum capacity of drum 250 litres.

7.4.6 Maximum net mass 400 kg.

7.5 Wooden barrels

2C1 bung type

2C2 slack type (removable head)

7.5.1 The wood used should be of good quality straight grained, well seasoned and free from knots bark, rotten wood, sapwood or other defects likely to lessen the effectiveness of the barrel for the purpose intended.

7.5.2 The body and heads should be of a design appropriate to the capacity of the barrel and intended use.

7.5.3 Staves and heads should be sawn or cleft with the grain so that no annual ring extends over more than half the thickness of a stave or head.


ANNEX I

7.5.4 Barrel hoops should be of steel or iron of good quality. The hoops of 2C2 barrels may be of a suitable hardwood. 7.5.5 Wooden barrels 2C1: the diameter of the bunghole should not exceed half the width of the stave in which it is

placed. 7.5.6 Wooden barrels 2C2: heads should fit tightly into the crozes.

7.5.7 Maximum capacity of barrel: 250 litres.

7.5.8 Maximum net mass: 400 kg.

7.6 Fibre drums 1G

7.6.1 The body of the drum should consist of multiple plies of heavy paper or fibreboard (without corrugations) firmly glued or laminated together and may include one or more protective layers of bitumen, waxed kraft paper, metal foil, plastics material, etc.

7.6.2 Heads should be of natural wood, fibreboard, metal, plywood, plastics or other suitable material and may include one or more protective layers of bitumen, waxed kraft paper, metal foil, plastics material, etc.

7.6.3 The body and heads of the drum and their joins should be of a design appropriate to the capacity of the drum and intended use.

7.6.4 The assembled packaging should be sufficiently water-resistant so as not to delaminate under normal conditions of transport.

7.6.5 Maximum capacity of drum: 450 litres.

7.6.6 Maximum net mass: 400 kg. 7.7 Plastics drums and jerricans

1H1 drums, non-removable head 1H2 drums, removable head 3H1 jerricans, non-removable head

3H2 jerricans, removable head

7.7.1 The packaging should be manufactured from suitable plastics material and be of adequate strength in relation to its capacity and intended use. Except for Recycled plastics material as defined in 2.1, no used material other than production residues or regrind from the same manufacturing process may be used. Packaging manufactured with such recycled plastics material should be marked "REC" near the marks prescribed in 6.2. The packaging should be adequately resistant to ageing and to degradation caused either by the substance contained or by ultraviolet radiation. Any permeation of the substance contained should not constitute a danger under normal conditions of transport.

7.7.2 Unless otherwise approved by the competent authority, the period of use permitted for the transport of dangerous substances should be five years from the date of manufacture of the packaging, except where a shorter period of use is prescribed because of the nature of the substance to be transported.


ANNEX I

(b) not less than 1.75 times the vapour pressure at 50°C of the substance to be transported minus 100 kPa, but with a minimum test pressure of 100 kPa;

(c) not less than 1.5 times the vapour pressure at 55°C of the substance to be transported minus 100 kPa but with a minimum test pressure of 100 kPa.

8.6.5 In addition packagings intended to contain substances of packaging group I should be tested to a minimum test pressure of 250 kPa (gauge) for a test period of 5 or 30 minutes depending upon the material of construction of the packaging.

8.6.6 Criterion for passing the test no packaging should leak.

8.7 Stacking test

All design types of packagings other than bags should be subjected to a stacking test.

8.7.1 Number of test samples three test samples per design type and manufacturer.

8.7.2 Test method the test sample should be subjected to a force applied to the top surface of the test sample equiva-lent to the total weight of identical packages, which might be stacked on it during transport where the contents of the test sample are non-dangerous liquids with relative density different from that of the liquid to be transported the force should be calculated in relation to the latter. The minimum height of the stack including the test sample should be 3 metres. The duration of the test should be 24 hours except that plastics drums, jerricans, and com-posite packagings 6HH1 and 6HH2 intended for liquids should be subjected to the stacking test for a period of 28 days at a temperature of not less than 40°C.

8.7.3 Criteria for passing the test no test sample should leak In composite packagings or combination packagings there should be no leakage of the filling substance from the inner receptacle or inner packaging. No test sample should show any deterioration which could adversely affect transport safety or any distortion liable to reduce its strength or cause instability in stacks of packages. Plastics packagings should be cooled to ambient temperature before the assessment.

8.8 Cooperage test for bung-type wooden barrels

8.8.1 Number of samples one barrel.

8.8.2 Method of testing remove all hoops above the bilge of an empty barrel at least two days old.

8.8.3 Criterion for passing the test the diameter of the cross section of the upper part of the barrel should not increase by more than 10%.

8.9 Test report

8.9.1 A test report containing at least the following particulars should be drawn up and should be available to the users of the packaging.

1 name and address of the test facility;


ANNEX I

2 name and address of the applicant (where applicable); 3 a unique test report identification;

4 date of the test report;

5 manufacturer of the packaging;

6 description of the packaging design type (e.g. dimensions materials, closures, thickness, etc.) including method of manufacture (e.g. blow moulding) and which may include drawing(s) and/or photograph(s);

7 maximum capacity;

8 characteristics of test contents, e.g., viscosity and relative density for liquids and particle size for solids;

9 test descriptions and results;

10 signature, with the name and status of the signatory.

8.9.2 The test report should contain statements that the packaging prepared as for transport was tested in accordance with the appropriate provisions of Annex I to the IMDG Code and that the use of other packaging methods or components may render it invalid. A copy of the test report should be available to the competent authority.

8.10 Leakproofness test for aerosol dispensers and small receptacles for gas. 8.10.1 Each receptacle should be subjected to a test performed in a hot water bath. The temperature of the bath and

the duration of the test should be such that the internal pressure reaches that which would be reached at 55°C (50°C if the liquid phase does not exceed 95% of the capacity of the receptacle at 50°C). If the contents are sensitive to heat or if the receptacles are made of plastics material which softens at this test temperature, the temperature of the bath should be set at between 20°C and 30°C but in addition one receptacle in 2.000 should be tested at the higher temperature.

8.10.2 No leakage or permanent deformation of a receptacle should occur, except that a plastics receptacle may be deformed through softening provided that it does not leak.

IMDG CODE - PAGE 0539 (pages 0540 to 9999 have been Amdt. 27-94 reserved for future amendments)

GENERAL INDEX

SUBSTANCE or ARTICLE IMDG CODE

PAGE UN No. CLASS

Pack-aging Group

Subsidiary Risk Label

(s) EmS No.

MFAG Table No.

ACETALP 3101 1088 3.1 II – 3-06 330

- ditto - 3171 1088 3.2 II – 3-06 330

ACETALDEHYDEP 3101 1089 3.1 I – 3-06 300

para-ACETALDEHYDE see 3372 1264 3.3 III – 3-06 300

ACETALDEHYDE AMMONIA 9021 1841 9 III – 8-07 320

ACETALDEHYDE DIETHYL ACETALP see 3101 1088 3.1 II – 3-06 330

- ditto - see 3171 1088 3.2 II – 3-06 330

beta-ACETALDEHYDE OXIME 3301 2332 3.3 III – 3-06 320

ACETALDOL see 6055 2839 6.1 II – 6.1-02 300

beta-ACETALDOXIME see 3301 2332 3.3 III – 3-06 320

ACETIC ACID, GLACIAL 8100 2789 8 II Flammable liquid

8-04 700

ACETIC ACID SOLUTION more than 80% acid , by mass 8100 2789 8 II Flammable

liquid 8-04 700

ACETIC ACID SOLUTION, more than 10% but not more than 80% acid, by mass 8100 2790 8 II* – 8-05 700

ACETIC ALDEHYDEP see 3101 1089 3.1 I – 3-06 300

ACETIC ANHYDRIDE 8101 1715 8 II Flammable liquid

8-04 700

ACETIC OXIDE see 8101 1715 8 II Flammable liquid

8-04 700

ACETOIN see 3301 2621 3.3 III – 3-06 305

ACETONE 3102 1090 3.1 II – 3-06 300

ACETONE CYANOHYDRIN STABILIZEDP 6051 1541 6.1 I – 6.1-02 215

ACETONE HEXAFLUORIDE see 2145 2420 2 (2.3) – Corrosive 2-08 750

ACETONE OILS 3171 1091 3.2 II – 3-07 300

ACETONE SOLUTIONS 3172 1090 3.2 II 3-06 300

* Packaging group III for solutions with more than 10% but less than 50% acid, by mass

P, PP or • see explanatory notes in the introduction to this index


GENERAL INDEX


PAGE UN No. CLASS

Pack-aging Group


(s) EmS No.

MFAG Table No.

ACETONITRILE 3173 1648 3.2 II – 3-06 215

3-ACETOXYPROPENE see 3180 2333 3.2 II Toxic 3-02 330

ACETYLACETONE see 3373 2310 3.3 III Toxic 3-06 300

ACETYL ACETONE PEROXIDE (concentra-tion ≤42%, with diluent type A and water available oxygen ≤4.7%)

see ORGANIC PEROXIDE TYPE D, LIQUID

ACETYL ACETONE PEROXIDE (concentra-tion ≤32%, as a paste, with diluent type A with or without water)

see ORGANIC PEROXIDE TYPE D, SOLID

ACETYL BENZOYL PEROXIDE (concentra-tion ≤45% with diluent type A)


ACETYL BROMIDE 8101 1716 8 II – 8-02 700

ACETYL CHLORIDE 3172 1717 3.2 II Corrosive 3-04 700

ACETYL CYCLOHEXANE-SULPHONYL PEROXIDE (concentration ≤ 82%, with water)

see ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED

ACETYL CYCLOHEXANE-SULPHONYL PEROXIDE (concentration ≤32%, with dilu-ent type B)

see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

ACETYLENE, DISSOLVED 2101 1001 2 (2.1) – – 2-07 310

ACETYLENE, ETHYLENE AND PROPYL-ENE MIXTURES, REFRIGERATED LIQUID

see ETHYLENE ACETYLENE AND PROPYLENE MIXTURES, REFRIGERATED LIQUID

ACETYLENE DICHLORIDE see 3205 1150 3.2 II – 3-07 340

ACETYLENE TETRABROMIDEP see 6263 2504 6.1 III – 6.1-02 345

ACETYLENE TETRACHLORIDE P see 6263 1702 6.1 II – 6.1-02 340

ACETYL IODIDE 8102 1898 8 II – 8-02 700

ACETYL KETENE INHIBITED see 6130–1 2521 6.1 I Flammable liquid

6.1-01 300

ACETYL METHYL CARBINOL 3301 2621 3.3 III – 3-06 305

P, PP or • see explanatory notes in the introduction to this index


GENERAL INDEX

SUBSTANCE or ARTICLE IMDG CODE PAGE

UN No. CLASS

Pack-aging Group


(s) EmS No.

MFAG Table No.

ACETYL OXIDE see 8101 1715 8 II Flammable liquid 8-04 700

ACID BUTYL PHOSPHATE see 8132 1718 8 III – 8-05 700

ACID MIXTURE, HYDROFLUORIC AND SULPHURIC see 8184 1786 8 I Toxic 8-03 750

ACID MIXTURE, NITRATING ACID see 8194 1796 8 I/II Oxidizing agent* 8-03 700

ACID MIXTURE, SPENT, NITRATING ACID see 8194 1826 8 I/II Oxidizing agent* 8-03 700

ACRALDEHYDE, INHIBITEDP see 6053 1092 6.1 I Flammable liquid 6.1-01 300

ACRIDINE 6052 2713 6.1 III – 6.1-03 325

ACROLEIC ACID, INHIBITED see 8102 2218 8 II Flammable liquid 8-01 700

ACROLEIN, INHIBITEDP 6053 1092 6.1 I Flammable liquid 6.1-01 300

ACROLEIN DIETHYL ACETAL see 3208 2374 3.2 II – 3-06 330

ACROLEIN DIMER, STABILIZED 3302 2607 3.3 III – 3-06 300

ACRYLAMIDE, SOLID 6054 2074 6.1 III – 6.1-04 323

ACRYLAMIDE, SOLUTION 6054 2074 6.1 III – 6.1-02 323

ACRYLIC ACID, INHIBITED 8102 2218 8 II Flammable liquid 8-01 700

ACRYLIC ACID ISOBUTYL ESTER, INHIB-ITED see 3354 2527 3.3 III – 3-03 330

ACRYLIC ALDEHYDE, INHIBITEDP see 6053 1092 6.1 I Flammable liquid 6.1-01 300

ACRYLONITRILE, INHIBITED 3173 1093 3.2 I Toxic 3-02 215

ACTINOLITE see 9024 2590 9 III – 6.1-04 none

ACTIVATED CARBON see CARBON, ACTIVATED

ACTIVATED CHARCOAL see CHARCOAL, ACTIVATED

* Not required if nitric acid content is not more than 50%

p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UN No. CLASS

Pack-aging Group


(s) EmS No.

MFAG Table No.

ADHESIVES, containing a flammable liquid•

3102 1133 3.1 I/II* – 3 05 330

- ditto -• 3174 1133 3.2 I/II* – 3-05 330

- ditto -• 3302 1133 3.3 III – 305 330

ADIPONITRILE 6054 2205 6.1 III – 6.1-02 215

Aeroplane flares see FLARES AERIAL

AEROSOLS• 2102 1950 2 (†) – † 2-13 620‡

AGENTS, BLASTING TYPE B see 111 7 0331 1.5 D – – 1-05 **

AGENTS BLASTING, TYPE E see 1120 0332 1.5 D – – 1-05 **

AIR, COMPRESSED 2103 1002 2 (2.2) – – 2-04 none

AIR, REFRIGERATED LIQUID 2103 1003 2 (2.2) – Oxidizing agent 2-11 620

AIR BAG INFLATORS, pyrotechnic 9022-1 3268 9 III – †† none

AIR BAG INFLATORS, COMPRESSED GAS 2102-1 3353 2.2 – – †† none

AIR BAG MODULES, pyrotechnic 9022-1 3268 9 Ill – †† none

AIR BAG MODULES, COMPRESSED GAS 2102-1 3353 2.2 – – †† none

AIRCRAFT HYDRAULIC POWER, UNIT FUEL TANK (containing a mixture of anhy-drous hydrazine and methylhydrazine)

3174-2 3165 3.2 I Toxic, Corro-sive 3-02 720

ALCOHOL see 3219 1170 3.2 II – 3-06 305

ALCOHOL, DENATURED see 3219 1170 3.2 II – 3-06 305, 306

ALCOHOL, DENATURED SOLUTIONS see 3337-1 1170 3.3 III – 3-06 305, 306

ALCOHOL, INDUSTRIAL see 3219 1170 3.2 II – 3-06 305, 306

* Packaging group III under certain conditions † Label as approved by the competent authority of the country concerned. ‡ MFAG Table No 620 for classes 2.1 and 2.2 only For substances in class 2.3 and aerosols with a capacity of 1000 cm3 or less, if an MFAG table number is not supplied by the shipper refer to subsection 4.2 of the MFAG ** Explosive substance or article, refer to subsection 7.3 of the MFAG. †† To be declared by the shipper. p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UN No. CLASS

Pack-aging Group


(s) EmS No.

MFAG Table No.

ALCOHOL INDUSTRIAL, SOLUTIONS see 3337-1 1170 3.3 III – 3-06 305, 306

ALCOHOLATES, SOLUTION N.O.S. in alcohol•

3102-1 3274 3.1 II Corrosive 3-06 *

- ditto -• 3174-2 3274 3.2 II Corrosive 3-06 *

ALCOHOL C6-C17 (SECONDARY) POLY (3-6) ETHOXYLATE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

ALCOHOL C12-C16 POLY(1-6)ETHOXYLATE see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

ALCOHOL C13-C15 POLY(1-6)ETHOXYLATE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

ALCOHOLIC BEVERAGES 3174-3 3065 3.2 II – 3-06 305

- ditto - 3304 3065 3.3 III – 3-06 305

ALCOHOLS, N.O.S. • 3175 1987 3.2 II – 3-06 305

- ditto -• 3303 1987 3.3 III – 3-06 305

ALCOHOLS, FLAMMABLE, TOXIC, N.O.S.•

3104 1986 3.1 I/II Toxic 3-07 305

- ditto -• 3176 1986 3.2 I/II Toxic 3-07 305

- ditto -• 3303 1986 3.3 III Toxic 3-07 305

ALCOHOL SOLUTIONS see 3337-1 1170 3.3 III – 3-06 305

ALDEHYDES, N.O.S.• 3105 1989 3.1 I/II – 3-07 300

- ditto -• 3177 1989 3.2 I/II – 3-07 300

- ditto -• 3305 1989 3.3 III – 3-07 300 ALDEHYDES FLAMMABLE TOXIC N O S •

3105 1988 3.1 I/II Toxic 3-07 300

- ditto -• 3178 1988 3.2 I/II Toxic 3-07 300

- ditto -• 3305 1988 3.3 III Toxic 3-07 300

Aldicarb p see CARBAMATE PESTICIDE

ALDOL 6055 2839 6.1 II – 6.1-02 300

Aldrin pp see ORGANOCHLORINE PESTICIDE

ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S.•

4220-1 3206 4.2 II/III Corrosive 4.2-08 705

* If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


PAGE UN No. CLASS

Pack-aging Group

Subsidiary Risk Label(s) EmS No.

MFAG Table No.

ALKALI METAL ALLOY, LIQUID, N.O.S. • 4321 1421 4.3 I – 4.3-01 705

ALKALI METAL AMALGAM • 4322 1389 4.3 I – 4.3-04 705

ALKALI METAL AMIDE 4323 1390 4.3 II – 4.3-05 705

ALKALI METAL DISPERSION 4324 1391 4.3 I Flammable liquid*

4.3-01 705

ALKALINE CAUSTIC LIQUID, N.O.S. • see 8136 1719 8 II/III – 8-06 705

ALKALINE EARTH METAL, ALCOHOLATES, N.O.S. •

4220-1 3205 4.2 II/III – 4.2-08 705

ALKALINE EARTH METAL ALLOY, N.O.S. • 4325 1393 4.3 II – 4.3-04 705

ALKALINE EARTH METAL, AMALGAM • 4326 1392 4.3 I – 4.3-04 705

ALKALINE EARTH METAL, DISPERSION 4324 1391 4.3 I Flammable liquid* 4.3-01 705

ALKALOIDS, LIQUID, N.O.S.• 6056 3140 6.1 I/II/III – 6.1-02 805

ALKALOIDS, SOLID, N.O.S.• 6056 1544 6.1 I/II/III – 6.1-04 805

ALKALOID SALTS, LIQUID, N.O.S.• 6056 3140 6.1 I/II/III – 6.1-02 805

ALKALOID SALTS, SOLID, N.O.S.• 6056 1544 6.1 I/II/III – 6.1-04 805

Alkaloids and alkaloid salts (pesticides) see PESTICIDE, N.O.S.

ALKYLALUMINIUM see ALUMINIUM ALKYLS

ALKYLBENZENE SULPHONATES, branched and straight chain p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

ALKYL(C12-C14)DIMETHYLAMINE p see .1.5 of the General Introduction

ALKYL (C7-C9) NITRATES p see Section 23.1.5 of the General Introduction

ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) p

8103 3145 8 I/II/III – 8-15 710

ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) p

8103 2430 8 I/II/III 8-15 710

* If flashpoint 61°C c.c. or below p, pp or • see explanatory notes in the introduction to this index.

GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

ALKYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid 8105 2584 8 II – 8-06 700

ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid 8105 2586 8 III – 8-06 700

ALKYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid 8106 2583 8 II – 8-06 700

ALKYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid 8106 2585 8 III - 8-06 700

ALKYLSULPHURIC ACIDS 8104 2571 8 II – 8-06 700

ALLENE, INHIBITED see 2173 2200 2(2.1) – – 2-07 310

Allidochlor see PESTICIDE, N.O.S.

ALLYL ACETATE 3180 2333 3.2 II Toxic 3-02 330

ALLYL ALCOHOL 6058 1098 6.1 I Flammable liquid 6.1-01 307

ALLYLAMINE 6059 2334 6.1 I Flammable liquid 6.1-01 320

ALLYL BROMIDE p 3180 1099 3.2 I Toxic 3-03 345

ALLYL CHLORIDE 3105-1 1100 3.1 I Toxic 3-03 340

ALLYL CHLOROCARBONATE see 6060 1722 6.1 I Flammable

liquid, Corro-sive

6.1-01 740

ALLYL CHLOROFORMATE 6060 1722 6.1 I Flammable

liquid, Corro-sive

6.1-01 740

ALLYL ETHYL ETHER 3181 2335 3.2 II Toxic 3-03 330

ALLYL FORMATE 3181 2336 3.2 I Toxic 3-03 330

ALLYL GLYCIDYL ETHER 3305-1 2219 3.3 III – 3-02 330

ALLYL IODIDE 3182 1723 3.2 II Corrosive 3-03 345

ALLYL ISOTHIOCYANATE, STABILIZED 6060 1545 6.1 II Flammable liquid 6.1-01 740



GENERAL INDEX

SUBSTANCE or ARTICLEIMDG CODE

PAGEUNNo. CLASS

Pack-agingGroup

SubsidiaryRisk Label

(s)EmS No.

MFAGTableNo.

ALLYL MUSTARD OIL, STABILIZED see 6060 1545 6.1 II Flammableliquid 6.1-01 740

ALLYLTRICHLOROSILANE, STABILIZED 8107 1724 8 II Flammableliquid

8-01 700

alpha (or á -)This prefix is not taken into account in determining the alphabetical order of entries

see under the next part of the name shown in capital letters

ALUMINIUM, powder see ALUMINIUM, POWDER

ALUMINIUM ALKYL BROMIDES see 4221 3052 4.2 I Dangerouswhen wet 4.2-01 170

ALUMINIUM ALKYL CHLORIDES see 4221 3052 4.2 I Dangerouswhen wet

4.2-01 170

ALUMINIUM ALKYL HALIDES 4221 3052 4.2 I Dangerouswhen wet

4.2-01 170

ALUMINIUM ALKYL HYDRIDES 4222 3076 4.2 I Dangerouswhen wet 4.2-01 170

ALUMINIUM ALKYLS 4221 3051 4.2 I Dangerouswhen wet

4.2-01 170

ALUMINIUM BOROHYDRIDE 4222 2870 4.2 I Dangerouswhen wet

4.2-01 245

ALUMINIUM BOROHYDRIDE IN DEVICES 4222 2870 4.2 I Dangerouswhen wet 4.2-01 245

ALUMINIUM BROMIDE ANHYDROUS 8108 1725 8 II – 8-06 700

ALUMINIUM BROMIDE, SOLUTION 8108 2580 8 III – 8-06 700

ALUMINIUM CARBIDE 4327 1394 4.3 II – 4.3-03 none

ALUMINIUM CHLORIDE, ANHYDROUS 8109 1726 8 II – 8-06 700

ALUMINIUM CHLORIDE, SOLUTION 8109 2581 8 III – 8-06 700

Aluminium dross see ALUMINIUM PROCESSING BYPRODUCTS

ALUMINIUM FERROSILICON, POWDER 4327 1395 4.3 II – 4.3-03 601,605

ALUMINIUM HYDRIDE 4328 2463 4.3 I – 4.3-04 none

ALUMINIUM NITRATE 5121 1438 5.1 III – 5.1-06 235

ALUMINIUM PHOSPHIDE 4329 1397 4.3 I Toxic 4.3-02 205

IMDG CODE - PAGE 10012Amdt. 29-98

GENERAL INDEX

SUBSTANCE or ARTICLE IMDG CODEPAGE

UNNo. CLASS

Pack-agingGroup


(s)EmS No.

MFAGTableNo.

ALUMINIUM PHOSPHIDE PESTICIDE 6061 3048 6.1 I 6.1-04 205

ALUMINIUM POWDER, COATED 4121 1309 4.1 II/III – 4.1-02 none

ALUMINIUM POWDER, PYROPHORIC see 4255 1383 4.2 I – 4.2 02 none

ALUMINIUM POWDER, UNCOATED, non-pyrophoric 4330 1396 4.3 II/III – 4.3-06 none

ALUMINIUM REMELTING BY-PRODUCTS 4330-1 3170 4.3 II/III – 4.3-04 725

ALUMINIUM SMELTING BY-PRODUCTS 4330-1 3170 4.3 II/III – 4.3-04 725

Aluminium residues see ALUMINIUM PROCESSING BY-PRODUCTS

ALUMINIUM RESINATE 4121 2715 4.1 III – 4.1-06 none

ALUMINIUM SILICON POWDER, UN-COATED 4331 1398 4.3 III – 4.3-03 none

Aluminium skimmings see ALUMINIUM PROCESSING BY-PRODUCTS

Amatols see EXPLOSIVE BLASTING TYPE B

AMINES FLAMMABLE, CORROSIVE,N.O.S. • 3106 2733 3.1 I/II Corrosive 3-02 320

- ditto -• 3182-1 2733 3.2 I/II Corrosive 3-02 320

- ditto -• 3306 2733 3.3 III Corrosive 3-02 320

AMINES LIQUID CORROSIVE, N.O.S. • 8109-2 2735 8 I/II/III – 8-05 320

AMINES LIQUID CORROSIVE FLAMMA-BLE N.O.S. • 8109-1 2734 8 I/II Flammable

liquid 8-04 320

AMINES, SOLID, CORROSIVE, N.O.S. • 8109 2 3259 8 I/II/III – 8-15 760

1-AMINO-3-AMINOMETHYL-3, 5, 5-TRIMETHYLCYCLOHEXANE see 8188 2289 8 III – 8-05 320

ortho-AMINOANISOLE see 6069 2431 6.1 III – 6.1-02 335

AMINOBENZENE see 6068 1547 6.1 II – 6.1-02 335

2-AMINOBENZOTRIFLUORlDE see 6275 2942 6.1 III – 6.1-02 335

3-AMINOBENZOTRIFLUORIDE see 6275 2948 6.1 II – 6.1 02 335

1-AMINOBUTANE see 3192 1125 3.2 II Corrosive 3-02 320



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


(s)EmS No.

MFAGTableNo.

Aminocarb p see CARBAMATE PESTICIDE

2-AMINO-4-CHLOROPHENOL 6062 2673 6.1 II – 6.1-04 710

AMINOCYCLOHEXANE see 8156 2357 8 II Flammableliquid 8-04 320

2-AMINO-5-DIETHYLAMINO-PENTANE 6062 2946 6.1 III – 6.1-02 320

AMINODIMETHYLBENZENES, SOLID orLIQUID see 6280 1711 6.1 II – 6.1-02 335

2-AMINO-4, 6-DINITROPHENOL, WETTED,with not less than 20% water , by mass 4121 1 3317 4.1 I – 4.1-01 335

AMINOETHANE see 2136 1036 2 (21) – – 2-07 320

AMINOETHANE, AQUEOUS SOLUTION see 3121 2270 3.1 II Corrosive 3-02 320

- ditto - see 3221 2270 3.2 II Corrosive 3-02 320

1-AMINOETHANOL see 9021 1841 9 III – 8-07 320

2-AMINOETHANOL see 8169 2491 8 III – 8-05 320

2-(2-AMINOETHOXY) ETHANOL 8110 3055 8 III – 8-07 320

N-AMINOETHYLPIPERAZINE 8110 2815 8 III – 8-05 325

AMINOMETHANE, ANHYDROUS see 2157 1061 2 (2.1) – – 2-06 320

AMINOMETHANE, AQUEOUS SOLUTION see 3253 1235 3.2 II Corrosive 3-02 320

1-AMINO-2-METHYLPROPANE see 3239 1214 3.2 II Corrosive 3-02 320

3-AMINOMETHYL-3, 5, 5-TRIMETHYLCYCLOHEXYLAMINE see 8188 2289 8 III – 8-05 320

1-AMINO-2-NITROBENZENE see 6207 1661 6.1 II – 6.1-03 335



AMINOPHENETOLES see 6223 2311 6.1 III – 6.1-02 335

AMINOPHENOLS (ortho-, meta-, para-) 6063 2512 6.1 III – 6.1-04 335



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


(s)EmS No.

MFAGTableNo.

AMMONIUM PICRATE WETTED, with notless than 10% water by mass 4122 1310 4.1 I – 4.1-01 710

AMMONIUM POLYSULPHIDE, SOLUTION 8113 2818 8 II/III Toxic 8-05 225

AMMONIUM POLYVANADATE 6066 2861 6.1 II – 6.1-04 135

AMMONIUM SILICOFLUORIDE see 6250 2854 6.1 III – 6.1-04 750

AMMONIUM SULPHIDE, SOLUTION 8114 2683 8 II Toxic, Flam-mable liquid* 8-04 225

AMMONIUM VANADATE see 6066 2859 6.1 II 6.1-04 135

Ammunition blank see CARTRIDGES FOR WEAPONS, BLANK

Ammunition fixed, semi-fixed or separate-loading

see CARTRIDGES FOR WEAPONS, with bursting charge and CARTRIDGES FORWEAPONS, INERT PROJECTILE

1202 0171 1.2 G – – 1-02 †

0254 1.3 G – – 1-03 †AMMUNITION, ILLUMINATING with orwithout burster, expelling charge or propel-ling charge 0297 1.4 G — – 1-04 †

AMMUNITION, INCENDIARY, liquid or gel,with burster, expelling charge or propellingcharge

1204 0247 1.3 J — — 1-03 †

Ammunition incendiary (water-activatedcontrivances) see CONTRIVANCES WATER-ACTIVATED

1203 0009 1.2 G – – 1-02 †

0010 1.3 G – – 1-03 †AMMUNITION, INCENDIARY, with or with-out burster, expelling charge or propellingcharge 0300 1.4 G – – 1-04 †

1205 0243 1.2 H – – 1-02 †AMMUNITION INCENDIARY, WHITEPHOSPHORUS, with burster, expellingcharge or propelling charge 0244 1.3 H – – 1-03 †

Ammunition, industrial see CARTRIDGES, OIL WELL and CARTRIDGES, POWER DEVICE

Ammunition lachrymatory see AMMUNITION, TEAR-PRODUCING

* If flashpoint 61°C c.c. or below.† Explosive substance or article, refer to subsection 7.3 of the MFAG.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


(s)EmS No.

MFAGTableNo.

1206 0362 1.4 G – – 1.04 *AMMUNITION, PRACTICE

0488 1.3 G – – 1.03 *

AMMUNITION, PROOF 1206 0363 1.4 G – – 1.04 *

Ammunition smoke (water activated contriv-ances) see CONTRIVANCES WATER activated

1207 0015 1.2 G – Corrosive† 1.02 *0016 1.3 G – Corrosive† 1.03 *

AMMUNITION, SMOKE with or withoutburster expelling charge or propellingcharge 0303 1.4 G – Corrosive† 1.04 *

1208 0245 1.2 H – – 1.02 *AMMUNITION, SMOKE WHITE PHOS-PHORUS with burster expelling charge or pro-pelling charge 0246 1.3 H – – 1.03 *

Ammunition sporting see CARTRIDGES FOR WEAPONS INERT PROJECTILES

1209 0018 1.2 G – ToxicCorrosive 1.02 740*

0019 1.3 G – Toxic Corro-sive 1.03 740*

AMMUNITION, TEAR PRODUCING withburster expelling charge or propellingcharge

0301 1.4 G – Toxic Corro-sive 1.04 740*

AMMUNITION, TEAR PRODUCING NON-EXPLOSIVE with neithei burster nor expel-ling charge non-fuzed

6067 2017 6.1 II Corrosive 6.1-02 740

1210 0020 1.2 K – Toxic ‡ *AMMUNITION, TOXIC, with burster expel-ling charge or propelling charge

0021 1.3 K – Toxic ‡ *

AMMUNITION, TOXIC, NON-EXPLOSIVEwith neither burster nor expelling chargenon-fuzed

6067 2016 6.1 II – 6.1-02 740

Amorces see FIREWORKS

normal-AMYL ACETATE see 3307 1104 3.3 III – 3.07 330

secondary- AMYL ACETATE see 3307 1104 3.3 III – 3.07 330

AMYL ACETATES 3307 1104 3.3 III – 3.07 330

* Explosive substance or article, refer to subsection 7.3 of the MFAG.† Except for articles containing hexachloroethane or red phosphorus.‡ To be declared by the shipper after assignment by the competent authority who should allocate a schedule or develop a new schedule in asimilar format to the existing schedules.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


(s)EmS No.

MFAGTableNo.

AMYL ACID PHOSPHATE 8114 2819 8 III – 8-05 700

AMYL ALCOHOLS see 3269-1 1105 3.2 II – 3-06 305

- ditto - see 3373-1 1105 3.3 III – 3-06 305

AMYL ALDEHYDES see 3288 2058 3.2 II – 3-06 300

2-AMYLAMINE see 3308 1106 3.3 III Corrosive 3-02 320

normal-AMYLAMINE see 3183 1106 3.2 II Corrosive 3-02 320

tertiary-AMYLAMINE see 3183 1106 3.2 II Corrosive 3-02 320

AMYLAMINES 3183 1106 3.2 II Corrosive 3-02 320

- ditto - 3308 1106 3.3 III Corrosive 3-02 320

n-AMYLBENZENE p see Section 23.1.5 of the General Introduction

secondary-AMYL BROMIDE see 3189 2343 3.2 II – 3-07 345

AMYL BUTYRATES 3309 2620 3.3 III – 3-06 330

AMYL CARBINOL see 3351 2282 3.3 III – 3-06 305

normal-AMYL CHLORIDE see 3183 1107 3.2 II – 3-07 340

AMYL CHLORIDES 3183 1107 3.2 II – 3-07 340

normal-AMYLENE 3140 1108 3.1 I – 3-07 310

normal-AMYL FORMATE see 3309 1109 3.3 III – 3-07 330

AMYL FORMATES 3309 1109 3.3 III – 3-07 330

tert-AMYL HYDROPEROXIDE (con-centration - 88%, with diluent type A andwater)

see ORGANIC PEROXIDE TYPE E, LIQUID

normal-AMYL MERCAPTAN p see 3184 1111 3.2 II – 3-07 375

tertiary-AMYL MERCAPTAN p see 3184 1111 3.2 II – 3-07 375

AMYL MERCAPTANS p 3184 1111 3.2 II – 3-07 375

normal-AMYL METHYL KETONE 3310 1110 3.3 III – 3-07 300

normal-AMYL NITRATE see 3310 1112 3.3 III – 3-07 235

AMYL NITRATES 3310 1112 3.3 III – 3-07 235

AMYL NITRITE 3107 1113 3.1 || – 3-07 235

- ditto - 3184 1113 3.2 II – 3-07 235



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


(s)EmS No.

MFAGTableNo.

normal-AMYL NITRITE see 3184 1113 3.2 II – 3-07 235

tert-AMYL PEROXYACETATE (con-centration - 62%, with diluent type A) see ORGANIC PEROXIDE TYPE E, LIQUID

tert-AMYL PEROXYBENZOATE, (concen-tration - 96%, with diluent type A) see ORGANIC PEROXIDE TYPE D, LIQUID

tert-AMYL PEROXY-2-ETHYL-HEXANOATE (concentration - 100%) see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

tert-AMYL PEROXY-2-ETHYLHEXYLCARBONATE (concentration - 100%) see ORGANIC PEROXIDE TYPE D, LIQUID

tert-AMYL PEROXYNEODECAN-OATE(concentration - 77% with diluent type B) see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

tert-AMYL PEROXYPIVALATE, (concen-tration - 77%, with diluent type B) see ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED

tert-AMYL PEROXY-3, 5, 5-TRI-METHYLHEXANOATE (concentration -100%)

see ORGANIC PEROXIDE TYPE B, LIQUID

AMYLTRICHLOROSILANE 8115 1728 8 II – 8-01 700

ANILINE 6068 1547 6.1 II – 6.1-02 335

ANILINE CHLORIDE see 6068 1548 6.1 III – 6.1-04 335

ANILINE HYDROCHLORIDE 6068 1548 6.1 III – 6.1-04 335

ANILINE OIL see 6068 1547 6.1 II – 6.1-02 335

ANILINE SALT see 6068 1548 6.1 III – 6.1-04 335

ANIMAL FABRICS, oily • see 4233 1373 4.2 III – 4.2-05 none

ANIMAL FIBRES, burnt, wet or damp see 4233 - 4.2 III – 4.2-05 none

ANIMAL FIBRES, oily• see 4233 1373 4.2 III – 4.2-05 none

ortho-ANISIDINE 6069 2431 6.1 III – 6.1-02 335



GENERAL INDEX


UN No. CLASS

Pack-aging Group


(s) EmS No.

MFAG Table No.

BENZENE PHOSPHORUS, DICHLORIDE see 8202 2798 8 II - 8-05 700

BENZENE PHOSPHORUS, THIOCHLORIDE see 8202 2799 8 II - 8-05 700

BENZENESULPHONYL CHLORIDE 8122 2225 8 III - 8-05 700

BENZENE SULPHONYLHYDR-AZIDE (concentration 100%)

see SELF-REACTIVE, SOLID, TYPE D

BENZENETHIOL see 6228 2337 6.1 I Flammable liquid

6.1-01 375

BENZHYDRYL BROMIDE see 8166 1770 8 II - 8-02 345

BENZIDINE 6081 1885 6.1 II - 6.1-04 335

BENZOL see 3185 1114 3.2 II - 3-03 312

BENZOLENE see PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S.

BENZONITRILE 6082 2224 6.1 II - 6.1-02 215

BENZOQUINONE 6082 2587 6.1 II - 6.1-04 300

BENZOSULPHOCHLORIDE see 8122 2225 8 III - 8-05 700

BENZOTRICHLORIDE 8122 2226 8 II - 8-05 340

BENZOTRIFLUORIDE 3185 2338 3.2 II - 3-07 345

BENZOYL CHLORIDE 8123 1736 8 II - 8-02 700

BENZYL BROMIDE 6083 1737 6.1 II Corrosive 6.1-02 740


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


(s)EmS No.

MFAGTableNo.

BENZYL CHLORIDE 6083 1738 6.1 II Corrosive 6.1-02 740

BENZYL CHLOROCARBONATE p see 8124 1739 8 I – 8-03 740

BENZYL CHLOROFORMATE p 8124 1739 8 I – 8-03 740

BENZYL CYANIDE see 6226 2470 6 1 III – 6.1-02 215

BENZYL DICHLORIDE see 6084 1886 6.1 II – 6.1-02 340

BENZYLDIMETHYLAMINE 8124 2619 8 II Flammableliquid 8-04 320

4-[BENZYL (ETHYL) AMINO]-3-ETHOXYBENZENEDIAZONIUM ZINCCHLORIDE (concentration 100%)

see SELF-REACTIVE SOLID TYPE D

BENZYLIDENE CHLORIDE 6084 1886 6.1 II – 6.1-02 340

BENZYL IODIDE 6084 2653 6.1 II – 6.1-02 345

4-[BENZYL (METHYL) AMINO]-3-ETHOXYBENZENEDIAZONIUM ZINCCHLORIDE (concentration 100%)

see SELF-REACTIVE SOLID TYPE D TEMPERATURE CONTROLLED

BERYLLIUM COMPOUND, N.O.S. 6085 1566 6.1 II/III – 6.1-04 125

BERYLLIUM NITRATE 5130 2464 5.1 II Toxic 5.1-05 125

BERYLLIUM POWDER 6085 1567 6.1 II Flammablesolid 6.1-03 125

beta (or â) This prefix is not taken into account in determining the alphabetical order of en-tries, see under the next part of the name shown in capital letters

â-BHC pp see ORGANOCHLORINE PESTICIDE

BHUSA 4149 1327 4.1* – – 4.1-06 none

BICHLOROACETIC ACID see 8158 1764 8 II – 8-05 700

BICYCLO [2-2-1] HEPTA-2,5-DIENE, IN-HIBITED 3108 2251 3.1 II – 3-07 310

- ditto - 3186 2251 3.2 II – 3-07 310

* No label required p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack–agingGroup


(s)EmS No.

MFAGTableNo.

BORON TRICHLORIDE 2107 1741 2 (2.3) – Corrosive 2-08 700

BORON TRIFLUORIDE, COMPRESSED 2107 1008 2 (2.3) – Corrosive 2-03 750

BORON TRIFLUORIDE ACETIC ACIDCOMPLEX, LIQUID 8128 1742 8 II – 8-05 750

BORON TRIFLUORIDE ACETIC ACIDCOMPLEX SOLID 8128 1742 8 II – 8-05 750

BORON TRIFLUORIDE DIETHYL ETHER-ATE 8128 2604 8 é Flammable

liquid 8-01 750

BORON TRIFLUORIDE DIHYDRATE 8129 2851 8 II – 8-06 750

BORON TRIFLUORIDE DIMETHYLETHERATE 4333 2965 4.3 I

Corrosive,Flammable

liquid4.3-05 750

BORON TRIFLUORIDE PROPIONIC ACIDCOMPLEX, LIQUID 8129 1743 8 II – 8-05 750

BORON TRIFLUORIDE PROPIONIC ACIDCOMPLEX, SOLID 8129 1743 8 II – 8-05 750

Brodifacoum p p see COUMARIN DERIVATIVE PESTICIDE

BROMATES, INORGANIC, N.O.S.• 5131 1450 5.1 II – 5.1-05 745

BROMATES, INORGANIC, AQUEOUS,SOLUTION, N.O.S.• 5131 3213 5.1 II/III – 5.1-02 745

BROMINE 8130 1744 8 I Toxic 8-03 740

BROMINE CHLORIDE 2108 2901 2 (2.3) –Oxidizing

agent Corro-sive

2.08 740

BROMINE CYANIDE p see 6117 1889 6.1 I Corrosive 6.1-04 645

BROMINE PENTAFLUORIDE 5132 1745 5.1 I Toxic Corro-sive 5.1-01 750

BROMINE SOLUTION 8130 1744 8 I Toxic 8-03 740

BROMINE TRIFLUORIDE 5133 1746 5.1 I Toxic, Corro-sive 5.1-01 750

BROMOACETIC ACID, SOLID 8131 1938 8 II – 8-05 700



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup

SubsidiaryRisk Label(s) EmS No.

MFAGTableNo.

BROMOACETIC ACID, SOLUTION 8131 2645 8 II – 8-06 700

BROMOACETONE p 6086 1569 6.1 II Flammableliquid 6.1-01 740

omega-BROMOACETOPHENONE see 6223 2645 6.1 II – 6.1-04 740

BROMOACETYL BROMIDE 8132 2513 8 II – 8-03 700

BROMOALLYLENE p see 3180 1099 3.2 I Toxic 3-03 345

BROMOBENZENE p 3312 2514 3.3 III – 3-07 345

BROMOBENZYL CYANIDES, LIQUID orSOLID* 6087 1694 6.1 é – 6.1-02 215

1-BROMOBUTANE 3187 1126 3.2 II – 3-07 345

2-BROMOBUTANE 3187 2339 3.2 II – 3-07 345

1-BROMO-2-BUTANONE see 6191 6.1 II 6.1-02 740

BROMOCHLORODIFLUORO-METHANE see 2117 2340 2(2.2) – – 2-09 350

BROMOCHLOROMETHANE 6088 1887 6.1 Ill – 6.1-02 345

BROMOCYANE p see 6117 1889 6.1 I Corrosive 6.1-04 645

BROMODIPHENYLMETHANE see 8166 1770 8 II – 8-02 345

1-BROMO-2,3-EPOXYPROPANEP see 6143 2558 6.1 I Flammableliquid 6.1-01 740

BROMOETHANE see 6146 1891 6.1 II – 6.1-01 345

2-BROMOETHYL ETHYL ETHER 3188 2340 3.2 II – 3-06 345

BROMOFORM p 6088 2515 6.1 III – 6.1-02 345

BROMOMETHANE see 2158 1062 2(2.3) – Flammablegas 2-06 345

1-BROMO-3-METHYLBUTANE 3313 2341 3.3 Ill – 3-06 345

BROMOMETHYL ETHYL KETONE see 6191 - 6.1 II 6.1-02 740

BROMOMETHYLPROPANES 3188 2342 3.2 II – 3-07 345

BROMONITROBENZENES, LIQUID see 6209 2732 6.1 III – 6.1-02 335

* only ortho-BROMOBENZYL CYANIDE is a MARINE POLLUTANT



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

BROMONITROBENZENES, SOLID see 6209 2343 6.1 III – 6.1-04 335

2-BROMO-2-NITROPROPANE-1,3-DIOL 4131 3241 4.1 III – 4.1-05 335

2-BROMOPENTANE 3189 2343 3.2 II – 3-07 345

Bromophos-ethyl pp see ORGANOPHOSPHORUS PESTICIDE

BROMOPROPANES 3189 2344 3.2 II – 3-07 345

- ditto - 3313 2344 3.3 III – 3-07 345

3-BROMOPROPENE p see 3180 1099 3.2 I Toxic 3-03 345

3-BROMOPROPYNE 3190 2345 3,2 II – 3-07 345

3-BROMO-1-PROPYNE see 3190 2345 3.2 II – 3-07 345

alpha-BROMOTOLUENE see 6083 1737 6.1 II Corrosive 6.1-02 740

BROMOTRIFLUOROETHYLENE 2109 2419 2(2.1) – – 2-07 350

BROMOTRIFLUOROMETHANE 2109 1009 2(2.2) – – 2-09 350

Bromoxynil p see PESTICIDE, N.O.S.

BRONOPOL see 4131 1570 4.1 Ill – 4.1-05 335

BRUCINE 6089 1570 6.1 I – 6.1-04 805

BURSTERS, explosive 1229 0043 1.1 D – – 1-01 *

BUTADIENES, INHIBITED 2110 1010 2(2.1) – – 2-07 310

normal-BUTANAL p see 3196 1129 3.2 II – 3-07 300

BUTANAL OXIME see 3317 2840 3.3 III – 3-07 300

BUTANE 2147 1011 2(2.1) – – 2-07 310

BUTANEDIONE p 3190 2346 3.2 II – 3-06 300

1-BUTANETHIOL p see 3194 2347 3.2 II – 3-07 375

BUTANETHIOLS p see 3108 2347 3.1 || – 3-07 375

- ditto - p see 3194 2347 3.2 II – 3-07 375

BUTANOIC ACID see 8133 2820 8 III – 8-05 700

BUTANOIC ANHYDRIDE see 8134 2739 8 III – 8-05 700

* Explosive substance or article, refer to subsection 7.3 of the MFAG



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

1-BUTANOL see 3314 1120 3.3 III – 3-06 305

BUTAN-2-OL see 3191 1120 3.2 II – 3-06 305

normal-BUTANOL see 3314 1120 3.3 III – 3-06 305

secondary-BUTANOL see 3191 1120 3.2 II – 3-06 305

tertiary-BUTANOL see 3191 1120 3.2 II – 3-06 305

3-BUTANOLAL see 6055 2839 6.1 II – 6.1-02 300

BUTANOLS 3191 1120 3.2 II – 3-06 305

- ditto - 3314 1120 3.3 III – 3-06 305

2-BUTANONE see 3226 1193 3.2 II – 3-06 300

BUTANOYL CHLORIDE see 3197 2353 3.2 II Corrosive 3-04 700

2-BUTENAL, STABILIZED p see 6114-1 1143 6.1 I Flammableliquid 6.1-01 300

BUTENE see 2147 1012 2(2.1) – – 2-07 310

3-BUTENE-2-ONE, STABILIZED see 6198-2 1251 6.1 IFlammableliquid Corro-

sive6.1-01 300

1,2-BUTENE OXIDE, STABILIZED see 3192 3022 3.2 II – 3-06 365

2-BUTENOIC ACID see 8154 2823 8 III – 8-05 700

2-BUTEN-1-OL see 3362 2614 3.3 III – 3-06 305

Butocarboxim see CARBAMATE PESTICIDE

BUTYL ACETATES 3191 1123 3.2 || – 3-07 330

- ditto - 3314 1123 3.3 III – 3-07 330

BUTYL ACID PHOSPHATE 8132 1718 8 III – 8-05 700

BUTYL ACRYLATES, INHIBITED 3315 2348 3.3 III – 3-03 330

normal-BUTYL ALCOHOL see 3314 1120 3.3 III – 3-06 305

secondary-BUTYL ALCOHOL see 3191 1120 3.2 II – 3-06 305

tertiary-BUTYL ALCOHOL see 3191 1120 3.2 II – 3-06 305

normal-BUTYL ALDEHYDE p see 3196 1129 3.2 II – 3-07 300



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

Charcoal MATERIAL HAZARDOUS ONLY IN BULK*

CHARCOAL, ACTIVATED see 4224 1362 4.2 III – 4.2-05 none

CHARCOAL, non-activated see 4224 1361 4.2 II/III – 4.2 05 none

1240 0457 1.1 D – – 1-01 †

0458 1.2 D – – 1-02 †

0459 1.4 D – – 1-04 †

CHARGES. BURSTING, PLASTICS-BONDED

0460 1.4 S – – 1-04 †

CHARGES, DEMOLITION 1241 0048 1.1 D – – 1-01 †

CHARGES, DEPTH 1242 0056 1. 1 D – – 1-01 †

1243 0442 1.1 D – – 1-01 †

0443 1.2 D – – 1 02 †

0444 1.4 D – – 1-04 †CHARGES, EXPLOSIVE, COMMERCIAL,without detonator

0445 1.4 S – – 1-04 †

1245 0271 1.1 C – – 1-01 †

0415 1.2 C – – 1 02 †

0272 1.3 C – – 1-03 †CHARGES, PROPELLING

0491 1.4 C – – 1-04 †

1244 0279 1.1 C – – 1-01 †

0414 1.2 C – – 1-02 †CHARGES, PROPELLING, FOR CANNON0242 1.3 C – – 1-03 †

1246 0059 1.1 D – 1-01 †

0439 1.2 D – – 1-02 †

0440 1.4 D – – 1-04 †CHARGES, SHAPED, without detonator

0441 1.4 S – – 1-04 †

1247 0288 1.1 D 1-01 †CHARGES, SHAPED, FLEXIBLE, LINEAR

0237 1.4 D – – 1-04 †

CHARGES, SUPPLEMENTARY, EXPLO-SIVE 1248 0060 1.1 D – – 1-01 †

CHEMICAL KIT 9026-1 3316 9 II/III – ‡ §

CHEMICAL SAMPLE, TOXIC, liquid 6096-1 3315 6.1 I – 6.1-02 §

CHEMICAL SAMPLE, TOXIC, solid 6096-1 3315 6.1 I – 6.1-04 §

* See section 24 of the General Introduction.† Explosive substance or article, refer to subsection 7.3 of the MFAG.‡ To be declared by the shipper.§ If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.

IMDG CODE - PAGE 10053Amdt 29-98

GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

CHILE SALTPETRE see 5180 1498 5.1 III – 5.1-06 235

Chinomethionat see PESTICIDE, N.O.S.

CHLORAL, ANHYDROUS, INHIBITED 6097 2075 6.1 II – 6.1-02 300

CHLORATE AND BORATE MIXTURE• 5141 1458 5.1 II/III – 5.1 06 745

CHLORATE AND MAGNESIUM CHLORIDEMIXTURE• 5141 1459 5.1 II/III – 5.1-06 745

CHLORATES, INORGANIC, N.O.S. • 5142 1461 5.1 II – 5.1-05 745

CHLORATES, INORGANIC, AQUEOUSSOLUTION, N.O.S.• 5142 3210 5.1 II/III – 5.1-02 745

Chlordane pp see ORGANOCHLORINE PESTICIDE

Chlordimeform see ORGANOCHLORINE PESTICIDE

Chlordimeform hydrochloride see ORGANOCHLORINE PESTICIDE

Chlorfenvinphos p see ORGANOPHOSPHORUS PESTICIDE

CHLORIC ACID, AQUEOUS SOLUTIONwith not more than 10% chloric acid 5143 2626 5.1 II — 5.1-02 700

CHLORINATED PARAFFINS (C10 –C17) pp see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID or SOLIDN.O.S.

CHLORINE p 2116 1017 2(2.3) – Corrosive 2-08 740

CHLORINE BROMIDE see 2108 2901 2(2.3) –Oxidizing

agent, Corro-sive

2-08 740

CHLORINE CYANIDE, INHIBITED p see 2126 1589 2(2.3) – Corrosive 2-08 645

CHLORINE PENTAFLUORIDE 2116 2548 2(2.3) –Oxidizing

agent, Corro-sive

2-08 750



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

Copper (II) chlorate see COPPER CHLORATE

COPPER CHLORIDE p 8147 2802 8 III – 8-08 740

COPPER CHLORIDE (solution) pp see 8147 2802 8 III – 8-08 740

Copper compounds see COPPER BASED PESTICIDE

COPPER CYANIDE p p 6113 1587 6.1 II – 6.1-04 215

COPPER METAL POWDER pp see Section 23.1.5 of the General Introduction

COPPER SULPHATE ANHY-DROUS/HYDRATES pp see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O. S

COPRA 4227 1363 4.2* – – 4.2-05 none

1251 0065 1.1 D – – 1-01 †CORD DETONATING, flexible

0289 1.4 D – – 1-04 †

1252 0290 1.1 D – – 1-01 †CORD, DETONATING, metal-clad

0102 1.2 D – – 1-02 †

CORD, DETONATING, MILD EFFECT,metal clad 1253 0104 1.4 D – – 1-04 †

CORD, IGNITER 1254 0066 1.4 G – – 1-04 †

Cordite see POWDER, SMOKELESS

CORROSIVE LIQUID, N.O.S.• 8147 1760 8 I/II/III – 8-15 760,‡

CORROSIVE LIQUID, ACIDIC, INOR-GANIC, N.O.S.• 8147-1 3264 8 I/II/III – 8-15 760

CORROSIVE LIQUID ACIDIC ORGANIC,N.O.S. • 8147-1 3265 8 I/II/III – 8-15 760

CORROSIVE LIQUID, BASIC, INOR-GANIC, N.O.S.• 8147-1 3266 8 I/II/III – 8-15 760

CORROSIVE LIQUID, BASIC, ORGANIC,N.O.S. • 8147-1 3267 8 I/II/III – 8-15 760

CORROSIVE LIQUID, FLAMMABLE,N.O.S. • 8148 2920 8 I/II Flammable

liquid8-15 760,‡

* No label required.† Explosive substance or article, refer to subsection 7.3 of the MFAG.‡ In addition refer to subsection 4.3 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup

SubsidiaryRisk Label(s)

EmSNo.

MFAGTableNo.

CORROSIVE LIQUID, OXIDIZING, N.O.S.• 8153 3093 8 I/II Oxidizing agent 8-03 760,*

CORROSIVE LIQUID, SELF-HEATING,N.O.S. • 8147-2 3301 8 I/II Spontaneously

combustible 8-02 760, *

CORROSIVE LIQUID, TOXIC, N.O.S. • 8149 2922 8 I/II/III Toxic 8-15 760, *

CORROSIVE LIQUID, WATER REACTIVE,N.O.S. • 8150 3094 8 I/II Dangerous

when wet 8-15 760,*

CORROSIVE SOLID, N.O.S.• 8151 1759 8 I/II/III – 8-15 760, *

CORROSIVE SOLID, ACIDIC, INORGANIC,N.O.S. • 8150-1 3260 8 I/II/III – 8-15 760

CORROSIVE SOLID, ACIDIC, ORGANIC,N.O.S. • 8150-1 3261 8 I/II/III – 8-15 760

CORROSIVE SOLID, BASIC, INORGANIC,N.O.S. • 8150-1 3262 8 I/II/III – 8-15 760

CORROSIVE SOLID, BASIC, ORGANIC,N.O.S. • 8150 1 3263 8 I/II/III – 8-15 760

CORROSIVE SOLID, FLAMMABLE,N.O.S. • 8151 2921 8 I/II Flammable

solid 8-15 760,*

CORROSIVE SOLID, OXIDIZING, N.O.S.• 8153 3084 8 I/II Oxidizing agent 8-15 760 *

CORROSIVE SOLID, SELF-HEATING,N.O.S. • 8150 3095 8 I/II Spontaneously

combustible 8-15 760,*

CORROSIVE SOLID, TOXIC, N.O.S. • 8152 2923 8 I/II/III Toxic 8-15 760, *

CORROSIVE SOLID, WATER-REACTIVE,N.O.S. • 8150 3096 8 I/II Dangerous

when wet 8-15 760, *

COSMETICS • see 3269 1266 3.2 II † – 3-05 305

- ditto - • see 3374 1266 3.3 III – 3-05 305

COTTON, DRY see 4144 - 4.1 ‡ – – 4.1-06 none

* No label required.† Explosive substance or article, refer to subsection 7.3 of the MFAG.‡ In addition refer to subsection 4.3 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

1,1-DIETHOXYETHANE p see 3101 1088 3.1 II – 3-06 330

- ditto - p see 3171 1088 3.2 II – 3-06 330

1,2-DIETHOXYETHANE see 3340 1153 3.3 III – 3-07 330

DIETHOXYMETHANE 3116 2373 3.1 II – 3-06 330

- ditto - 3207 2373 3.2 II – 3-06 330

2,5-DIETHOXY-4-MORPHOLINO-BENZENEDIAZONIUM ZINC CHLORIDE(concentration 67-100%)

see SELF-REACTIVE, SOLID, TYPE D, TEMPERATURE CONTROLLED

2,5 DIETHOXY-4-MORPHOLINO-BENZENEDIAZONIUM ZINC CHLORIDE(concentration 66%)


2,5-DIETHOXY-4-MORPHOLINO-BENZENEDIAZONIUM TETRAFLUOROBORATE (concentration 100%)


2,5-DIETHOXY-4-(PHENYLSULPH-ONYL)BENZENEDIAZONIUM ZINCCHLORIDE (concentration 67%)


3,3-DIETHOXYPROPENE 3208 2374 3.2 II – 3-06 330

DIETHYLACETALDEHYDE p see 3223 1178 3.2 II – 3-07 300

DIETHYLALUMINIUM CHLORIDE see 4221 3052 4.2 I Dangerouswhen wet 4.2-01 170

DIETHYLAMINE 3116 1154 3.1 II Corrosive 3-02 320

1-DIETHYLAMINO-4-AMINOPENTANE see 6062 2946 6.1 III – 6.1-02 320

DIETHYLAMINOETHANOL see 8160 2686 8 II Flammableliquid 8-04 320

2-DIETHYLAMINOETHANOL 8160 2686 8 II Flammableliquid 8-04 320

3-(DIETHYLAMINO)-PROPYLAMINE 3331 2684 3.3 III Corrosive 3-02 320

N,N-DIETHYLANILINE 6130 2432 6.1 III – 6.1-02 335

DIETHYLBENZENES (ortho-, meta-, para-)p 3331-1 2049 3.3 III – 3-07 310



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

DIETHYL CARBINOL see 3373-1 1105 3.3 III – 3-06 305

DIETHYL CARBONATE 3332 2366 3.3 III – 3-07 330

DIETHYLDICHLOROSILANE 8161 1767 8 II Flammableliquid 8-01 700

DIETHYLENEDIAMINE, SOLID or SOLU-TION see 8211 2579 8 III – 8-05 320

1,4-DIETHYLENE DIOXIDE see 3217 1165 3.2 II – 3-06 330

DIETHYLENEGLYCOL BIS(ALLYL CAR-BONATE) +DI-ISOPROPYL PEROXYDI-CARBONATE (concentration - 88% +-12%)

see SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED

DIETHYLENEGLYCOL DINITRATE DE-SENSITIZED with not less than 25% non-volatile water-insoluble phlegmatizer, bymass

1108 0075 1.1 D – 1-01 *

DIETHYLENE OXIDE see 3217 1165 3.2 II – 3-06 330

DIETHYLENETRIAMINE 8161 2079 8 II – 8-05 320

N,N-DIETHYLETHANOLAMINE see 8160 2686 8 II Flammableliquid 8-04 320

DIETHYL ETHER 3117 1155 3.1 I – 3-07 330

N,N-DIETHYLETHYLENEDIAMINE 8162 2685 8 II Flammableliquid 8-04 320

DIETHYL FORMAL see 3116 2373 3.1 II – 3-06 330

- ditto - see 3207 2373 3.2 II – 3-06 330

DI-(2-ETHYLHEXYL) PEROXY-DICARBONATE (concentration > 77-100%) see ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED

DI-(2-ETHYLHEXYL) PEROXY-DICARBONATE (concentration -77%) see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

DI-(2-ETHYLHEXYL) PEROXY-DICARBONATE (concentration -52%, as astable dispersion in water)

see ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED

* Explosive substance or article, refer to subsection 7.3 of the MFAG.


GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

DI-(2-ETHYLHEXYL) PEROXY-DICARBONATE (concentration ≤42%, as a stable dispersion in water (frozen))

see ORGANIC PEROXIDE TYPE E, SOLID TEMPERATURE CONTROLLED

DI-(2-ETHYLHEXYL)PHOSPHORIC ACID see 8163 1902 8 III – 8-05 700

DIETHYL KETONE 3208 1156 3.2 II – 3-07 300

DIETHYLMAGNESIUM see 4240 3053 4.2 I Dangerous when wet 4.2-01 170

para-DIETHYLNITROSOANILINE 4247 - 4.2 II – 4.2-04 335

DIETHYL OXALATE see 6152 2525 6.1 III – 6.1-02 230

DIETHYL PEROXYDICARBONATE (con-centration ≤27%, with diluent type B) see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

N,N-DIETHYL-1,3-PROPANE-DIAMINE see 3331 2684 3.3 III Corrosive 3-02 320

DIETHYL SULPHATE 6130 1594 6.1 II – 6.1-02 315

DIETHYL SULPHIDE 3209 2375 3.2 II – 3-07 375

DIETHYLTHIOPHOSPHORYL CHLORIDE 8162 2751 8 II – 8-05 700

DIETHYLZINC 4230 1366 4.2 I Dangerous when wet 4.2-01 170

Difenacoum see COUMARIN DERIVATIVE PESTICIDE

Difenzoquat see PESTICIDE, N.O.S.

DIFLUOROCHLOROETHANE see 2118 2517 2(2.1) – – 2-07 350

DIFLUORODIBROMOMETHANE see 9027 1941 9 Ill – 6.1-02 350

1,1-DIFLUOROETHANE 2132 1030 2(2.1) – – 2-07 350

DIFLUOROETHANE AND DICHLORODI-FLUOROMETHANE, AZEOTROPIC MIX-TURE, with approximately 74% dichlorodi-fluoromethane

see DICHLORODIFLUOROMETHANE AND DIFLUOROETHANE, AZEOTROPIC MIXTURE

1,1-DIFLUOROETHYLENE 2132 1959 2(2.1) – – 2-07 350


GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

DIFLUOROMETHANE 2132-1 3252 2(2.1) – – 2-07 350

DIFLUOROMETHANE, PENTA-FLUOROETHANE AND 1,1,1,2-TET-RAFLUOROETHANE ZEOTROPIC MI X-TURE WITH APPROXIMATELY 10% DI-FLUOROMETHANE AND 70% PEN-TAFLUOROETHANE

see 2176-2 3339 2(2.2) – – 2-09 620


see 2176-1 3338 2(2.2) – – 2-09 620


see 2176-2 3340 2(2.2) – – 2-09 620

DIFLUOROPHOSPHORIC ACID, ANHY-DROUS

8163 1768 8 II – 8-06 700

2,2-DIHYDROPEROXYPROPANE (concen-tration -27%, with inert solid) see ORGANIC PEROXIDE TYPE B, SOLID

2,3-DIHYDROPYRAN 3209 2376 3.2 II – 3-06 310

meta-DIHYDROXYBENZENE see 6248 2876 6.1 III – 6.1-04 710

para-DIHYDROXYBENZENE, LIQUID see 6164 2662 6.1 III – 6.1-02 710

para-DIHYDROXYBENZENE, SOLID see 6164 2662 6.1 III – 6.1-04 710

DI-(1-HYDROXYCYCLOHEXYL) PEROX-IDE (concentration -100%) see ORGANIC PEROXIDE TYPE D, SOLID

DIISOBUTYLAMINE 3332 2361 3.3 III Corrosive 3-03 320

DIISOBUTYLENES, ISOMERIC COM-POUNDS 3210 2050 3.2 II – 3-07 310

alpha-DIISOBUTYLENE see 3210 2050 3.2 II – 3-07 310

beta-DIISOBUTYLENE see 3210 2050 3.2 II – 3-07 310

DIISOBUTYL KETONE 3333 1157 3.3 III – 3-07 300


GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

DIISOBUTYRYL PEROXIDE (concentration > 32-52%, with diluent type A or B) see ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED

DIISOBUTYRYL PEROXIDE (concentration ≤ 32%, with diluent type B) see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

DIISOOCTYL ACID PHOSPHATE 8163 1902 8 III – 8-05 700

DIISOPROPYL see 3119 2457 3.1 II – 3-07 310

DIISOPROPYLAMINE 3210 1158 3.2 II Corrosive 3-02 320

DIISOPROPYLBENZENE DIHYDROPER-OXIDE (concentration ≤ 82%, with diluent type A and water)


DIISOPROPYLBENZENES p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

DIISOPROPYL ETHER 3117 1159 3.1 II – 3-02 330

DIISOPROPYLNAPHTHALENE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

DIISOPROPYL PEROXYDICARBONATE (concentration >52-100%) see ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED

DIISOPROPYL PEROXYDICARBON ATE (concentration ≤52%, with diluent type B) see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

DIISOTRIDECYL PEROXYDICARBONATE (concentration ≤100%) see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

DIKETENE, INHIBITED 6130-1 2521 6.1 I Flammable liquid 6.1-01 300

DILAUROYL PEROXIDE (concentration ≤100%) see ORGANIC PEROXIDE TYPE D, SOLID

DILAUROYL PEROXIDE (concentration ≤42% as a stable dispersion in water) see ORGANIC PEROXIDE TYPE F, LIQUID

Dimefox see ORGANOPHOSPHORUS PESTICIDE



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

Dimetan see CARBAMATE PESTICIDE

Dimethoate pp see ORGANOPHOSPHORUS PESTICIDE

1,1-DIMETHOXYETHANE 3118 2377 3.1 II – 3-06 330

- ditto - 3211 2377 3.2 II – 3-06 330

1,2-DIMETHOXYETHANE 3211 2252 3.2 II – 3-06 330

DIMETHOXYMETHANE see 3136 1234 3.1 II – 3-06 330

2,5-DIMETHOXY-4-(4-METHYL-PHENYLSULPHONYL)BENZENE-DIAZONIUM ZINC CHLORIDE (con-centration 79%)

see SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED

DIMETHOXYSTRYCHNINE see 6089 1570 6.1 I – 6.1-04 805

DIMETHYL ACETAL see 3118 2377 3.1 II – 3-06 330

- ditto - see 3211 2377 3.2 II – 3-06 330

1,1-DIMETHYLACETONE see 3254 2397 3.2 II – 3-07 300

DIMETHYLACETYLENE see 3113 1144 3.1 I – 3-07 310

DIMETHYLAMINE, ANHYDROUS 2133 1032 2(2.1) – – 2-07 320

DIMETHYLAMINE, AQUEOUS SOLUTION 3118 1160 3.1 II Corrosive 3-02 320

- ditto - 3212 1160 3.2 II Corrosive 3-02 320

2-DIMETHYLAMINOACETONITRILE 3334 2378 3.3 II Toxic 3-02 215

4-DIMETHYLAMINO-6-(2-DIMETHYL-AMINOETHOXY'TOLUENE-2-DIAZONIUMZINC CHLORIDE (concentration 100%)


2-DIMETHYLAMINOETHANOL 8164 2051 8 II Flammableliquid

8-04 320

2-DIMETHYLAMINOETHYL ACRYLATE 6130-1 3302 6.1 II – 6.1-02 330

2-DIMETHYLAMINOETHYL METHACRYL-ATE

6131 2522 6.1 II – 6.1-02 330

3,4-DIMETHYLANILINE see 6280 1711 6.1 II – 6.1-02 335

N,N-DIMETHYLANILINE 6131 2253 6.1 II – 6.1-02 335



GENERAL INDEX


PAGE UN No. CLASS

Pack-aging Group


MFAG Table No.

DIMETHYLARSINIC ACID see 6093 1572 6.1 II – 6.1-04 100

DIMETHYLBENZENES see 3292 1307 3.2 II – 3-07 310

- ditto - see 3394 1307 3.3 III – 3-07 310

DI-(2-METHYLBENZOYL) PEROXIDE (concentration ≤87%, with water) see ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED

DI-(4-METHYLBENZOYL) PEROXIDE (concentration ≤52% as a paste with silicon oil)


DIMETHYLBENZYLAMINE see 8124 2619 8 ιι Flammable liquid

8-04 320

N,N-DIMETHYLBENZYLAMINE see 8124 2619 8 II Flammable liquid 8-04 320

2,3-DIMETHYLBUTANE 3119 2457 3.1 II – 3-07 310

1,3-DIMETHYLBUTYLAMINE 3212 2379 3.2 II Corrosive 3-03 320

N,N-DIMETHYLCARBAMOYL CHLORIDE 8164 2262 8 ιι – 8-05 700

DIMETHYL CARBINOL see 3244 1219 3.2 II – 3-06 305

DIMETHYL CARBONATE 3213 1161 3.2 II – 3-07 330

DIMETHYLCYCLOHEXANES 3213 2263 3.2 II – 3-07 310

N,N-DIMETHYLCYCLOHEXYLAMINE 8165 2264 8 II Flammable liquid

8-04 320

2,5-DIMETHYL-2,5-DI-(BENZOYL-PEROXY)HEXANE (concentration > 82-100%)

see ORGANIC PEROXIDE TYPE B, SOLID

2,5-DIMETHYL-2,5-DI-(BENZOYL-PEROXY)HEXANE (concentration ≤82%, with inert solid)


2,5-DIMETHYL-2,5-DI-(BENZOYL-PEROXY)HEXANE (concentration ≤82%, with water)

see ORGANIC PEROXIDE TYPE C, SOLID

2,5-DIMETHYL-2,5-DI-(tert-BUTYL-PEROXY)HEXANE (concentration > 52-100%)



GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

2,5-DIMETHYL-2,5-DI-(tert-BUTYL-PEROXY)HEXANE (concentration ≤47% as a paste)

see ORGANIC PEROXIDE TYPE E, SOLID

2,5-DIMETHYL-2,5-DI-(tert-BUTYL-PEROXY)HEXANE (concentration ≤52%, with diluent type A)

see ORGANIC PEROXIDE TYPE F, LIQUID

2,5-DIMETHYL-2,5-DI-(tert-BUTYL-PEROXY)HEXANE (concentration ≤52%, with inert solid)


2,5-DIMETHYL-2,5-DI-(tert-BUTYL-PEROXY)HEXYNE-3 (concentration > 52-86%, with diluent type A)

see ORGANIC PEROXIDE TYPE C, LIQUID

2,5-DIMETHYL-2,5-DI-(tert-BUTYL-PEROXY)HEXYNE-3 (concentration ≤52%, with inert solid)


DIMETHYLDICHLOROSILANE 3214 1162 3.2 II Corrosive 3-04 700

DIMETHYLDIETHOXYSILANE 3214 2380 3.2 II – 3-06 none

2,5-DIMETHYL-2,5-DI-(2-ETHYL HEXA-NOYLPEROXY)HEXANE (concentration ≤100%)


2,5-DIMETHYL-2,5-DIHYDROPEROXYHEXANE (concentration ≤82%, with water)

see ORGANIC PEROXIDE TYPE C, SOLID

see 3334 2707 3.3 III – 3-06 330 4,4-DIMETHYLDIOXANE-1,3-DIMETHYLDIOXANES 3215 2707 3.2 II – 3-06 330

- ditto - 3334 2707 3.3 III – 3-06 330

DIMETHYL DISULPHIDE p 3215 2381 3.2 II – 3-07 225

2,5 DIMETHYL-2,5-DI (3,5,5-TRIMETHYLHEXANOYL-PEROXY)HEXANE (concentration ≤77%, with diluent type A)


DIMETHYLENEIMINE, INHIBITED see 6151 1185 6.1 I Flammable liquid 6.1-01 320



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

DIMETHYLETHANOLAMINE see 8164 2051 8 II Flammableliquid 8-04 320

DIMETHYL ETHER 2133 1033 2(2.1) – – 2-07 330

N,N-DIMETHYLFORMAMIDE 3335 2265 3.3 III – 3-06 321

N,N-DIMETHYLGLYCINONITRILE see 3334 2378 3.3 II Toxic 3-02 215

DIMETHYLGLYOXAL p see 3190 2346 3.2 II – 3-06 300

2,6-DIMETHYL-4-HEPTANONE see 3333 1157 3.3 III – 3-07 300

1,1-DIMETHYLHYDRAZINE p see 6132 1163 6.1 IFlammable

liquid, Corro-sive

6.1-01 720

1,2-DIMETHYLHYDRAZINE p see 6131-1 2382 6.1 I Flammableliquid 6.1-01 720

DIMETHYLHYDRAZINE, SYMMETRICAL p 6131-1 2382 6.1 I Flammableliquid

6.1-01 720

DIMETHYLHYDRAZINE, UNSYMMETRI-CAL p

6132 1163 6.1 IFlammable

liquid, Corro-sive

6.1-01 720

1,1-DIMETHYL-3-HYDROXYBUTYL PER-OXYNEOHEPTANOATE (concentration -52%, with diluent type A)

see ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED

DIMETHYL KETONE see 3102 1090 3.1 II – 3-06 300

DIMETHYL KETONE SOLUTIONS see 3172 1090 3.2 II – 3-06 300

DIMETHYLMAGNESIUM see 4240 3053 4.2 I Dangerouswhen wet 4.2-01 170

N,N-DIMETHYL-4-NITROSO-ANILINE see 4247 1369 4.2 II – 4.2-04 335

para-DIMETHYLNITROSOANILINE see 4247 1369 4.2 II – 4.2-04 335

DIMETHYLPHENOLS, SOLID p see 6280 2261 6.1 II – 6.1-04 710

DIMETHYLPHENOLS LIQUID p see 6280 2261 6.1 II – 6.1-02 710

DIMETHYL PHOSPHOROCHLORIDO-THIONATE see 6133-1 2267 6.1 II Corrosive 6.1-02 700

2,2-DIMETHYLPROPANE 2147 2044 2(2.1) – – 2-07 310



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

DIMETHYL-N-PROPYLAMINE see 3216 2266 3.2 II Corrosive 3-02 320

N,N-DIMETHYLPROPYLAMINE 3216 2266 3.2 II Corrosive 3-02 320

DIMETHYL-normal-PROPYL CARBINOL see 3367 2560 3.3 III – 3-06 305

DIMETHYL SULPHATE 6133 1595 6.1 I Corrosive 6.1-02 315

DIMETHYL SULPHIDE p 3119 1164 3.1 II – 3-07 225

DIMETHYLTHIOPHOSPHORYL CHLO-RIDE

6133-1 2267 6.1 II Corrosive 6.1-02 700

DIMETHYLZINC 4231 1370 4.2 I Dangerouswhen wet 4.2-01 170

Dimetilan see CARBAMATE PESTICIDE

Dimexano see PESTICIDE, N.O.S.

DIMYRISTYL PEROXYDICARBONATE(concentration -100%)

see ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED

DIMYRISTYL PEROXYDICARBONATE(concentration -42%, as a stable dispersionin water)

see ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED

DI-(2-NEODECANOYLPEROXYISO-PROPYL)BENZENE (concentration -52%,with diluent type A)


DINGU 1104 0489 1.1 D – – 1-01 *

DINITROANILINES 6134 1596 6.1 II – 6.1-03 335

DINITROBENZENES, LIQUID (ortho-, meta-, para-) or (1,2-, 1,3-, 1,4-) 6134 1597 6.1 II – 6.1-01 335

DINITROBENZENES, SOLID (ortho-, meta-,para-) or (1,2-, 1,3-, 1 4-)

6134 1597 6.1 II – 6.1-03 335

DINITROCHLOROBENZENES, LIQUID orSOLID p see 6103 1577 6.1 II – 6.1-01 335

DINITRO-ortho-CRESOL p 6135 1598 6.1 II – 6 1-04 710

DINITROGEN OXIDE see 2166 1070 2(2.2) – Oxidizingagent 2-08 none




GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

DINITROGEN OXIDE, REFRIGERATED,LIQUID see 2166 2201 2(2.2) – Oxidizing

agent 2-11 620

DINITROGEN TETROXIDE AND NITRICOXIDE, MIXTURES

see NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURES

DINITROGEN TETROXIDE 2134 1067 2(2.3) —Oxidizing

agent, Corro-sive

2-08 610

DINITROGEN TRIOXIDE see 2164 2421 2(2.3) —Oxidizing

agent, Corro-sive

2-08 610

DINITROGLYCOLURIL 1104 0489 1.1 D – – 1-01 *

Dinitrophenates ( class 1) see DINITROPHENOLATES ( class 1)

DINITROPHENATES, WETTED p see 4139 1321 4.1 I Toxic 4.1-01 710

DINITROPHENOL, dry or wetted with lessthan 15% water, by mass p 1109 0076 1.1 D – Toxic 1-01 710,*

DINITROPHENOL WETTED with not lessthan 15% water, by mass p 4140 1320 4.1 I Toxic 4.1-01 710

DINITROPHENOLATES alkali metals, dryor wetted with less than 15% water, bymass p

1107 0077 1.3 C — Toxic 1-03 710,*

DINITROPHENOLATES, WETTED with notless than 15% water, by mass p

4139 1321 4.1 I Toxic 4.1-01 710

DINITROPHENOL SOLUTION p 6136 1599 6.1 II/III – 6.1-01 710

DINITRORESORCINOL, dry or wetted withless than 15% water, by mass 1109 0078 1.1 D – – 1-01 710,*

DINITRORESORCINOL, WETTED with notless than 15% water, by mass 4141 1322 4.1 I – 4.1-01 710

DINITROSOBENZENE 1115 0406 1.3 C – – 1-03 335,*

N,N'-DINITROSO-N,N -DIMETHYL-TEREPHTHALAMIDE, as a paste (concen-tration 72%)

see SELF-REACTIVE SOLID TYPE C




GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

N,N'-DINITROSOPENTAMETHYL-ENETETRAMINE (concentration 82%) see SELF-REACTIVE SOLID TYPE C

DINITROTOLUENES, LIQUID 6137 2038 6.1 II – 6.1-01 335

DINITROTOLUENES, MOLTEN 6137 1600 6.1 II – 6.1-01 335

DINITROTOLUENES, SOLID 6137 2038 6.1 II – 6.1-03 335

Dinobuton p see SUBSITUTED NITROPHENOL PESTICIDE

DI-n-NONANOYL PEROXIDE (concentra-tion ≤100%) see ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED

Dinoseb p see SUBSTITUTED NITROPHENOL PESTICIDE

Dinoseb acetate p see SUBSTITUTED NITROPHENOL PESTICIDE

Dinoterb see SUBSTITUTED NITROPHENOL PESTICIDE

Dinoterb acetate see SUBSTITUTED NITROPHENOL PESTICIDE

DI-n-OCTANOYL PEROXIDE (concentration ≤100%) see ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED

Dioxacarb p see CARBAMATE PESTICIDE

DIOXANE 3217 1165 3.2 II – 3-06 330

Dioxathion p see ORGANOPHOSPHORUS PESTICIDE

DIOXOLANE 3217 1166 3.2 II – 3-06 330

DIPENTENE p 3336 2052 3.3 III – 3-07 310

DI-normal-PENTYLAMINE see 3327 2841 3.3 III Toxic 3-03 320

DIPEROXYAZELAIC ACID (concentration ≤27%, with inert solid) see ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED

DIPEROXYDODECANE DIACID (con-centration > 13-42%, with inert solid) see ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED

Diphacinone p see PESTICIDE, N.O.S.



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

DI-(2-PHENOXYETHYL) PEROXYDICAR-BONATE (concentration >85-100%) see ORGANIC PEROXIDE TYPE B, SOLID

DI-(2-PHENOXYETHYL) PEROXYDICAR-BONATE (concentration -85%, with water) see ORGANIC PEROXIDE TYPE D, SOLID

DIPHENYL p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

DIPHENYLAMINE CHLORO-ARSINE pp 6138 1698 6.1 I – 6.1-04 101

DIPHENYLBROMOMETHANE see 8166 1770 8 II – 8-02 345

DIPHENYLCHLOROARSINE, LIQUID pp 6139 1699 6.1 I – 6.1-02 101

DIPHENYLCHLOROARSINE SOLID pp 6139 1699 6.1 I – 6.1-02 101

DIPHENYLDICHLOROSILANE 8166 1769 8 II – 8-02 700

DIPHENYL ETHER/BIPHENYL PHENYLETHER MIXTURES p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

DIPHENYL(DIPHENYL) ETHER (MI X-TURES) p

see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

DIPHENYLMAGNESIUM see 4241 2005 4.2 I – 4.2-01 170

DIPHENYLMETHYL BROMIDE 8166 1770 8 II – 8-02 345

DIPHENYLOXIDE-4,4'-DISULPHO-NYLHYDRAZIDE (concentration 100%) see SELF-REACTIVE SOLID TYPE D

DIPICRYLAMINE 1122 0079 1.1 D – – 1-01 *

DIPICRYL SULPHIDE, dry or wetted withless than 10% water, by mass 1104 0401 1.1 D – – 1-01 375,*

DIPICRYL SULPHIDE, WETTED with notless than 10% water, by mass

4143 2852 4.1 I – 4.1-01 375

DI-2-PROPENYLAMINE see 3204 2359 3.2 II Toxic, Corro-sive 3-02 320

* Explosive substance or article, refer to subsection 7.3 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

DIPROPIONYL PEROXIDE (concentration ≤ 27%, with diluent type A or B) see ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED

DIPROPYLAMINE 3218 2383 3.2 II Corrosive 3-02 320

DI-normal-PROPYLAMINE see 3218 2383 3.2 II Corrosive 3-02 320

4-DIPROPYLAMINOBENZENE-DIAZONIUM ZINC CHLORIDE (concentration 100%) see SELF-REACTIVE SOLID TYPE D

DIPROPYLENETRIAMINE see 8187 2269 8 III – 8-05 320

DI-normal-PROPYL ETHER 3120 2384 3.1 II – 3-06 330

- ditto - 3218 2384 3.2 II – 3-06 330

DIPROPYL KETONE 3336 2710 3.3 III – 3-07 300

DI-n-PROPYL PEROXYDICARBONATE (concentration ≤100%) see ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED

Diquat see BIPYRIDILIUM PESTICIDE

Direct reduced iron MATERIAL HAZARDOUS ONLY IN BULK *

DISINFECTANT, LIQUID, CORROSIVE, N.O.S •

8167 1903 8 I/II/III – 8-06 760,†

DISINFECTANT, LIQUID, TOXIC, N.O.S. • 6141 3142 6.1 I/II/III – 6.1-02 ‡

DISINFECTANT, SOLID, TOXIC, N.O.S. • 6141 1601 6.1 I/II/III – 6.1-04 ‡

DISODIUM TRIOXOSILICATE 8166-1 3253 8 III – 8-06 705

DISODIUM TRIOXOSILICATE, PENTAHY-DRATE see DISODIUM TRIOXOSILICATE

DISTEARYL PEROXYDICARBONATE (concentration ≤87%, with inert solid) see ORGANIC PEROXIDE TYPE D, SOLID

DISUCCINIC ACID PEROXIDE (concentra-tion > 72-100%) see ORGANIC PEROXIDE TYPE B, SOLID

DISUCCINIC ACID PEROXIDE (concentra-tion ≤ 72%, with water) see ORGANIC PEROXIDE TYPE D, SOLID TEMPERATURE CONTROLLED

* No label required. † Explosive substance or article, refer to subsection 7.3 of the MFAG. ‡ In addition refer to subsection 4.3 of the MFAG. p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

Disulfoton p see ORGANOPHOSPHORUS PESTICIDE

DISULPHURIC ACID see 8231 1831 8 I Toxic 8-06 700

DISULPHURYL CHLORIDE see 8218 1817 8 II – 8-03 700

DI-(3,5,5-TRIMETHYL-1,2-DIOX OLANYL-3) PEROXIDE (concentration -52%, as apaste, with diluent type A, with or withoutwater)

see ORGANIC PEROXIDE TYPE 0, SOLID, TEMPERATURE CONTROLLED

DI-(3,5,5-TRIMETHYLHEXANOYL) PER-OXIDE (concentration -52%, as a stabledispersion in water)

see ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED

DI-(3,5,5-TRIMETHYLHEXANOYL) PER-OXIDE (concentration > 38-82%, with dilu-ent type A)


DI-(3,5,5-TRIMETHYLHEXANOYL) PER-OXIDE (concentration -38%, with diluenttype B)

see ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED

DIVINYL, INHIBITED see 2110 1010 2(2.1) – – 2-07 310

DIVINYL ETHER, INHIBITED 3120 1167 3.1 I – 3-02 330

DIVINYL OXIDE, INHIBITED see 3120 1167 3.1 I – 3-02 330

DNOC p see 6135 1598 6.1 II 6.1-04 710

DNOC (pesticide) p see SUBSTITUTED NITROPHENOL PESTICIDE

DODECAHYDRODIPHENYLAMINE see 8160 2565 8 III – 8-05 320

DODECENE see 3378 2850 3.3 III – 3-07 310



GENERAL INDEX


PAGE UN No. CLASS

Pack–aging Group


MFAG Table No.

1-DODECYLAMINE p see Section 23.1.5 of the General Introduction

DODECYL DIPHENYL OXIDE DISULPHO-NATE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID N.O.S.

DODECYL HYDROXYPROPYL SULPHIDEp see Section 23.1.5 of the General Introduction

DODECYLPHENOL pp see 8103 3145 8 I/II/III – 8-15 710

DODECYLTRICHLOROSILANE 8167 1771 8 II – 8-02 700

Dolomitic quicklime MATERIAL HAZARDOUS ONLY IN BULK*

Drazoxolon p see PESTICIDE, N.O.S.

DRI see MATERIAL HAZARDOUS ONLY IN BULK*

DRY ICE 9025 1845 9 III – 8-08 615

DYE, LIQUID, CORROSIVE, N.O.S. • 8168 2801 8 I/II/III – 8-04 760,‡

DYE, LIQUID, TOXIC, N.O.S. • 6142 1602 6.1 I/II/III – 6.1-02 §

DYE, SOLID, CORROSIVE, N.O.S. • 8168 3147 8 I/II/III – 8-05 760, §

DYE, SOLID TOXIC, N.O.S. • 6142 3143 6.1 I/II/III – 6.1-04 §

DYE INTERMEDIATE LIQUID, CORRO-SIVE, N.O.S •

8168 2801 8 I/II/III – 8-04 760, §

DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. •

6142 1602 6.1 I/II/III – 6.1-02 §

DYE INTERMEDIATE, SOLID, CORRO-SIVE, N.O.S. •

8168 3147 8 I/II/III – 8-05 760, §

DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. •

6142 3143 6.1 I/II/III – 6.1-04 §

Dynamite see EXPLOSIVE, BLASTING, TYPE A

* See section 24 of the General Introduction ‡ In addition, refer to subsection 4.3 of the MFAG § If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

2-ETHYLBUTANOL 3338 2275 3.3 III – 3-06 305

2-ETHYLBUTYL ACETATE 3339 1177 3.3 III – 3-07 330

2-ETHYLBUTYL ALCOHOL see 3338 2275 3.3 III – 3-06 305

ETHYL BUTYL ETHER 3223 1179 3.2 II – 3-07 330

2-ETHYLBUTYRALDEHYDE p 3223 1178 3.2 II – 3-07 300

ETHYL BUTYRATE 3339 1180 3.3 III – 3-07 330

ETHYL CARBONATE see 3332 2366 3.3 III – 3-07 330

ETHYL CHLORIDE 2137 1037 2(2.1) – – 2-07 340

ETHYL CHLOROACETATE 6147 1181 6.1 II Flammable liquid 6.1-01 540

ETHYL CHLOROCARBONATE see 6148 1182 6.1 I Flammable liquid Corro-

sive 6.1-01 740

ETHYL CHLOROETHANOATE see 6147 1181 6.1 II Flammable liquid 6.1-01 540

ETHYL CHLOROFORMATE 6148 1182 6.1 I Flammable

liquid, Corro-sive

6.1-01 740

ETHYL-2-CHLOROPROPIONATE 3340 2935 3.3 III – 3-07 740

ETHYL CHLOROTHIOFORMATE p 8169 2826 8 I] Flammable liquid 8-04 740

ETHYL CROTONATE 3224 1862 3.2 II – 3-07 300

ETHYL CYANIDE see 3273 2404 3.2 II Toxic 3-02 215

ETHYL-3,3-DI-(tert-AMYLPEROXY)-BUTYRATE (concentration ≤67%, with diluent type A)


ETHYL-3,3-Dl-(tert-BUTYLPEROXY) BU-TYRATE (concentration > 77-100%) see ORGANIC PEROXIDE TYPE C, LIQUID



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

ETHYL-3,3-DI-(tert-BUTYLPEROXY)-BUTYRATE (concentration - 77%, with di-luent type A)


ETHYL-3,3-DI-(tert-BUTYLPEROXY) BU-TYRATE (concentration -52% with inertsolid)


ETHYLDICHLOROARSINE p 6149 1892 6.1 I – 6.1-02 101

ETHYLDICHLOROSILANE 4342 1183 4.3 IFlammable

liquid, Corro-sive

4.3-05 700

ETHYLENE ACETYLENE AND PROPY L-ENE MIXTURE, REFRIGERATED LIQUID,containing at least 71.5% ethylene, with notmore than 22.5% acetylene and not morethan 6% propylene

2137 3138 2(2.1) – – 2-10 310,620

ETHYLENE, COMPRESSED 2138 1962 2(2.1) – – 2-07 310

ETHYLENE, REFRIGERATED LIQUID 2138 1038 2(2.1) – – 2-10 310,620

ETHYLENE CHLORIDE see 3224 1184 3.2 II Toxic 3-03 340

ETHYLENE CHLOROHYDRIN 6150 1135 6.1 I Flammableliquid

6.1-01 740

ETHYLENEDIAMINE 8170 1604 8 II Flammableliquid 8-04 320

ETHYLENE DIBROMIDE 6150 1605 6.1 I – 6.1-02 345

ETHYLENE DIBROMIDE AND METHYLBROMIDE MIXTURE LIQUID see 6190 1647 6.1 I – 6.1-02 345

ETHYLENE DICHLORIDE 3224 1184 3.2 II Toxic 3-03 340

ETHYLENE FLUORIDE see 2132 1030 2(2.1) – – 2-07 350

ETHYLENE GLYCOL DIETHYL ETHER 3340 1153 3.3 Ill – 3-07 330

ETHYLENE GLYCOL DIMETHYL ETHER see 3211 2252 3.2 II – 3-06 330



GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

Fluoroacetamide see PESTICIDE N.O.S.

FLUOROACETIC ACID 6154 2642 6.1 I – 6.1-02 540

2-FLUOROANILINE see 6155 2941 6.1 III – 6.1-02 335

4-FLUOROANILINE see 6155 2941 6.1 III – 6.1-02 335

ortho-FLUOROANILINE see 6155 2941 6.1 III – 6.1-02 335

para-FLUOROANILINE see 6155 2941 6.1 III – 6.1-02 335

FLUOROANILINES 6155 2941 6.1 III – 6.1-02 335

FLUOROBENZENE 3233 2387 3.2 II – 3-07 345

FLUOROBORIC ACID 8175 1775 8 II – 8-06 750

FLUOROETHANE see 2140 2453 2(2.1) – – 2-07 345

FLUOROETHANOIC ACID see 6154 2642 6.1 I – 6.1-02 540

FLUOROFORMYL FLUORIDE, COM-PRESSED see 2115 2417 2(2.3) – Corrosive 2-08 750

FLUOROMETHANE see 2160 2454 2(2.1) – – 2-07 345

FLUOROPHOSPHORIC ACID, ANHY-DROUS 8175 1776 8 II – 8-06 700

FLUOROSILICATES, N.O.S. • 6250 2856 6.1 III – 6.1-04 750

FLUOROSILICIC ACID 8176 1778 8 II – 8-06 750

FLUOROSULPHONIC ACID 8176 1777 8 I – 8-03 750

2-FLUOROTOLUENE see 3233 2388 3.2 II – 3-07 345



FLUOROTOLUENES (ortho-, meta-, para- ) 3233 2388 3.2 II – 3-07 345

Fluorspar MATERIAL HAZARDOUS ONLY IN BULK *

Fly ash MATERIAL HAZARDOUS ONLY IN BULK *

* See section 24 of the General Introduction p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


PAGE UN No. CLASS

Pack-aging Group


MFAG Table No.

Fonofos pp see ORGANOPHOSPHORUS PESTICIDE

FORMAL see 3136 1234 3.1 II – 3-06 330

FORMALDEHYDE SOLUTION, FLAMMA-BLE 3347 1198 3.3 III Corrosive 3-06 300

FORMALDEHYDE SOLUTION, with not less than 25% formaldehyde

8176-1 2209 8 III – 8-07 300

FORMALDEHYDE DIMETHYL ACETAL see 3136 1234 3.1 II – 3-06 330

FORMALIN SOLUTION, FLAMMABLE see 3347 1198 3.3 III Corrosive 3-06 300

FORMALIN SOLUTION with not less than 25% formaldehyde see 8176-1 2209 8 III – 8-07 300

FORMAMIDINE SULPHINIC ACID see 4264 3341 4.2 II/III – 4.2-04 †

Formetanate p see CARBAMATE PESTICIDE

FORMIC ACID 8177 1779 8 II – 8-05 700

FORMIC ACID ETHYL ESTER see 3123 1190 3.1 II – 3-07 330

FORMIC ALDEHYDE SOLUTION, FLAM-MABLE see 3347 1198 3.3 III Corrosive 3-06 300

FORMIC ALDEHYDE SOLUTION, with not less than 25% formaldehyde

see 8176 1 2209 8 III – 8-07 300

Formothion see ORGANOPHORUS PESTICIDE

2-FORMYL-3,4-DIHYDRO-2H-PYRAN, STABILIZED

see 3302 2607 3.3 III – 3-06 300

N-FORMYL-2-(NITROMETHYLENE)-PERHYDRO-1,3-THIAZINE (concentration 100%)


FRACTURING DEVICES, EXPLOSIVE, for oil wells without detonator 1264 0099 1.1 D – – 1-01

* Explosive substance or article, refer to subsection 7.3 of the MFAG. † If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


PAGE UN No. CLASS

Pack-aging Group


MFAG Table No.

GALLIUM 8178 2803 8 III – 8 12 none

gamma- (or γ-) This prefix is not taken into account in determining the alphabetical order of entries, see under the next part of the name shown in capital letters

GAS CARTRIDGES without a release de-vice non-refillable 2175 2037 2(*) – * 2-13 †

GAS DRIPS hydrocarbon • see HYDROCARBONS, LIQUID, N.O.S.

GAS OIL 3375 1202 3.3 III – 3-07 311

GASOLINE 3141 1203 3.1 II – 3-07 311

GASOLINE, CASINGHEAD see CASINGHEAD GASOLINE

GAS REFRIGERATED LIQUID, N.O.S. • 2142-1 3158 2(2.2) – – 2-12 620

GAS, REFRIGERATED LIQUID, FLAMMA-BLE, N.O.S. •

2142-1 3312 2(2.1) – – 2-10 620

GAS, REFRIGERATED LIQUID, OXIDIZ-ING, N.O.S. •

2142-2 3311 2(2.2) – Oxidizing agent

2-11 620

GAS SAMPLE, NON-PRESSURIZED FLAMMABLE, N.O.S. , not refrigerated liquid •

2142-2 3167 2(2.1) – – 2-02 ‡

GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S. , not refrigerated liquid •

2142-3 3169 2(2.3) – – 2-03 ‡

GAS SAMPLE, NON-PRESSURIZED TOXIC FLAMMABLE, N.O.S., not refriger-ated liquid •

2142-3 3168 2(2.3) – Flammable gas

2-01 ‡

Gelatine, blasting see EXPLOSIVE, BLASTING TYPE A

Gelatine dynamite see EXPLOSIVE, BLASTING TYPE A

* According to properties. † MFAG Table No. 620 for classes 2.1 and 2.2. For substances in class 2.3, if an MFAG table number is not supplied by the shipper refer to subsection 4.2 of the MFAG. ‡ If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG. p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

GENETICALLY MODIFIED MICROOR-GANISMS 9031 3245 9 – – * n/a

GERMANE 2143 2192 2(2.3) – Flammablegas 2-05 606

GERMANIUM HYDRIDE see 2143 2192 2(2.3) – Flammablegas 2-05 606

GLYCEROL-1,3-DICHLOROHYDRIN see 6129 2750 6.1 II – 6.1-02 740

GLYCEROL-alpha-MONOCHLOROHYDRIN 6156 2689 6.1 III – 6.1-02 740

Glycerol trinitrate ( class 1) see NITROGLYCERIN ( class 1)

Glyceryl trinitrate ( class 1) see NITROGLYCERIN ( class 1)

GLYCERYL TRINITRATE see 3265-2 1204 3.2 II – 3-06 235

- ditto - see 3266 3064 3.2 II – 3-06 235

GLYCIDAL see 3349 2622 3.3 II Toxic 3-02 300

GLYCIDALDEHYDE 3349 2622 3.3 II Toxic 3-02 300

GLYCOL CHLOROHYDRIN see 6150 1135 6.1 é Flammableliquid 6.1-01 740

GLYCOL DIMETHYL ETHER see 3211 2252 3.2 II – 3-06 330

1271 0284 1.1 D – – 1-01 †GRENADES hand or rifle, with burstingcharge 0285 1.2 D – – 1-02 †

1272 0292 1.1 F – – 1-01 †

- ditto -0293 1.2 F – – 1-02 †

Grenades, illuminating see AMMUNITION, ILLUMINATING

1273 0372 1.2 G – – 1-02 †

0318 1.3 G – – 1-03 †

0452 1.4 G – – 1-04 †GRENADES, PRACTICE, hand or rifle

0110 1.4 S – – 1-04 †

Grenades, smoke see AMMUNITION, SMOKE

* To be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event ofdamage to, or leakage from, a package containing infectious substances refer to section 9 of the introduction to class 6.2.† Explosive substance or article, refer to subsection 7.3 of the MFAG. n/a - not applicable


GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

normal-HEPTYL ALDEHYDE p see 3350 3056 3.3 III – 3-06 300

normal-HEPTYLBENZENE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

normal-HEPTYL CHLORIDE p see 3319 – 3.3 III – 3-07 340

H.E.T.P. p see HEXAETHYL TETRAPHOSPHATE

H.E.T.P. (and compressed gas, mixtures) see 2145 1612 2(2.3) – – 2-08 505

HEXACHLOROACETONE 6158 2661 6.1 Ill – 6.1-02 740

HEXACHLOROBENZENE 6158 2729 6.1 III – 6.1-04 500

HEXACHLOROBUTADIENE pp 6159 2279 6.1 III – 6.1-02 340

HEXACHLORO-1,3-BUTADIENE pp see 6159 2279 6.1 III – 6.1-02 340

1,3-HEXACHLOROBUTADIENE pp see 6159 2279 6.1 III – 6.1-02 340

HEXACHLOROCYCLOPENTADIENE 6159 2646 6.1 I – 6.1-02 340

HEXACHLOROPHANE see 6160 2875 6.1 III – 6.1-04 711

HEXACHLOROPHENE 6160 2875 6.1 III – 6.1-04 711

HEXACHLORO-2-PROPANONE see 6158 2661 6.1 III – 6.1-02 740

HEXADECYLTRICHLOROSILANE 8179 1781 8 II – 8-02 700

1,3-HEXADIENE see 3236 2458 3.2 II – 3-07 310

1,4-HEXADIENE see 3128 2458 3.1 II – 3-07 310

1,5-HEXADIENE see 3128 2458 3.1 II – 3-07 310

2,4-HEXADIENE see 3236 2458 3.2 II – 3-07 310

2,4-HEXADIENE ALDEHYDE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

HEXADIENES 3128 2458 3.1 II – 3-07 310

- ditto - 3236 2458 3.2 II – 3-07 310

HEXAETHYL TETRAPHOSPHATE p 6160 1611 6.1 II – 6.1-02 505

HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS, MIXTURE 2145 1612 2(2.3) – – 2-08 505



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

HEXAFLUOROACETONE 2145 2420 2(2.3) – Corrosive 208 750

HEXAFLUOROACETONE HYDRATE 6161 2552 6.1 II – 6.1-02 750

HEXAFLUOROETHANE, COMPRESSED 2146 2193 2(2.2) – – 2-09 350

HEXAFLUOROPHOSPHORIC ACID 8179 1782 8 II – 8-06 750

HEXAFLUORO-2-PROPANONE see 2145 2420 2(2.3) – Corrosive 2-08 750

HEXAFLUOROPROPYLENE 2146 1858 2(2.2) – – 2-09 345

HEXAHYDROBENZENE see 3114 1145 3.1 II – 3-07 310

HEXAHYDROPYRIDINE see 8211-1 2401 8 I Flammable 8-01 325

HEXAHYDROTHIOPHENOL see 3323 3054 3.3 III – 3-03 375

HEXAHYDROTOLUENE see 3256 2296 3.2 II – 3-07 310

normal-HEXALDEHYDE p 3350 1207 3.3 III – 3-07 300

HEXAMETHYLENE see 3114 1145 3.1 II – 3-07 310

HEXAMETHYLENEDIAMINE, SOLID 8180 2280 8 III – 8-05* 320

HEXAMETHYLENEDIAMINE, SOLUTION 8180 1783 8 II/III – 8-05 320

HEXAMETHYLENE DIISOCYANATE 6161 2281 6.1 II – 6.1-02 370

HEXAMETHYLENEIMINE 3236 2493 3.2 II Corrosive 3-02 320

HEXAMETHYLENETETRAMINE 4150 1328 4.1 III – 4.1-06 320

3,3,6,6,9,9-HEXAMETHYL-1,2,4,5-TETRAOXACYCLONONANE (concentration>52-100%)

see ORGANIC PEROXIDE TYPE B, SOLID

3,3,6,6,9,9-HEXAMETHYL-1,2,4,5-TETRAOXACYCLONONANE (concentration-52%, with diluent type A)


3,3,6,6,9,9-HEXAMETHYL-1,2,4,5-TETRAOXACYCLONONANE (concentration-52%, with inert solid)


HEXAMINE see 4150 1328 4.1 III – 4.1-06 320

* 8-13 when in the molten statep, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


PAGE UN No. CLASS

Pack-aging Group


MFAG Table No.

3-HYDROXYPHENOL see 6248 2876 6.1 III – 6.1 04 710

HYPOCHLORITES, INORGANIC, N.O.S. • 5152-1 3212 5.1 II – 5.1-06 741

HYPOCHLORITE SOLUTION 8186 1791 8 II/III – 8-08 741



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

1274 0121 1.1 G – – 1-01 *

0314 1.2 G – – 1-02 *

0315 1.3 G – – 1-03 *

0325 1.4 G – – 1-04 *

IGNITERS

0454 1.4 S – – 1-04 *

Imazalil see PESTICIDE, N.O.S.

3,3-IMINODIPROPYLAMINE 8187 2269 8 Ill – 8-05 320

INFECTIOUS SUBSTANCES, AFFECTINGANIMALS only 6322 2900 6.2 – – † n/a

INFECTIOUS SUBSTANCES, AFFECTINGHUMANS 6321 2814 6.2 – – † n/a

INFLAMMABLE see FLAMMABLE

INSECTICIDE GAS, N.O.S.• 2152 1968 2(‡) – – 2-09 none

INSECTICIDE GAS, FLAMMABLE, N.O.S. • 2152-1 3354 2(2.1) – – 2-07 none

INSECTICIDE GAS TOXIC, N.O.S.• 2152 1967 2(2.3) – – 2-06 §

INSECTICIDE GAS, TOXIC, FLAMMABLE,N.O.S. • 2152-1 3355 2(2.3) – Flammable

gas 2-06 none

IODINE MONOCHLORIDE 8187 1792 8 II – 8-03 740

IODINE PENTAFLUORIDE 5153 2495 5.1 I Toxic Corro-sive 5.1-01 750

2-IODOBUTANE 3238 2390 3.2 II – 3-07 345

IODOMETHANE see 6197 2644 6.1 I – 6.1-02 345

IODOMETHYLPROPANES 3238 2391 3.2 II – 3-07 345

1-IODOPROPANE see 3353 2392 3.3 III – 3-07 345

2-IODOPROPANE see 3353 2392 3.3 III – 3-07 345

* Explosive substance or article, refer to subsection 7.3 of the MFAG.† Emergency procedure to be declared by the shipper after agreement with the competent authority of the country concerned. For action to be

taken in the event of damage to or leakage from a package containing infectious substances, refer to section 9 of the introduction to class 6.2.‡ Label according to properties.§ If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG.n/a - Not applicable.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

IODOPROPANES 3353 2392 3.3 III – 3-07 345

alpha-IODOTOLUENE see 6084 2653 6.1 II – 6.1-02 345

loxynil p see PESTICIDE, N.O.S.

Iprobenfos see ORGANOPHOSPHORUS PESTICIDE

IRON, powder see IRON POWDER

IRON CARBONYL see 6165 1994 6.1 é Flammableliquid 6.1-01 165

IRON CHLORIDE, ANHYDROUS see 8173 1773 8 III – 8-06 700

Iron (III) chloride, anhydrous see FERRIC CHLORIDE, ANHYDROUS

IRON CHLORIDE SOLUTION see 8173 2582 8 III – 8-08 700

IRON OXIDE, SPENT p 4238 1376 4.2 III – 4.2-04 none

IRON PENTACARBONYL 6165 1994 6.1 I Flammableliquid 6.1-01 165

IRON PERCHLORIDE, ANHYDROUS see 8173 1773 8 III – 8-06 700

IRON PERCHLORIDE, SOLUTION see 8173 2582 8 III – 8-08 700

IRON POWDER, PYROPHORIC see 4255 1383 4.2 I – 4.2-02 none

IRON SPONGE, SPENT p 4238 1376 4.2 III – 4.2-04 none

IRON SWARF see 4232 2793 4.2 – – 4.2-05 none

IRON TRICHLORIDE ANHYDROUS see 8173 1773 8 Ill – 8-06 700

IRON TRICHLORIDE, SOLUTION see 8173 2582 8 III – 8-08 700

ISOAMYL ACETATE see 3307 1104 3.3 III – 3-07 330

ISOAMYL ALCOHOL see 3373-1 1105 3.3 III – 3-06 305

ISOAMYL BROMIDE see 3313 2341 3.3 III – 3-06 345

ISOAMYL BUTYRATE see 3309 2620 3.3 III – 3-06 330

alpha-ISOAMYLENE see 3132 2561 3.1 I – 3-07 310

ISOAMYL FORMATE see 3309 1109 3.3 III – 3-07 330

ISOAMYL MERCAPTAN p see 3184 1111 3.2 II – 3-07 375

ISOAMYL NITRATE see 3310 1112 3.3 III – 3-07 235



GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

ISOAMYL NITRITE see 3107 1113 3.1 II – 3-07 235

Isobenzan p see ORGANOCHLORINE PESTICIDE

ISOBUTANAL p see 3130 2045 3.1 II – 307 300

ISOBUTANE 2147 1969 2(2.1) – – 2-07 310

ISOBUTANOL 3354 1212 3.3 III – 3-06 305

ISOBUTENE see 2147 1055 2(2.1) – – 2-07 310

ISOBUTENOL see 3362 2614 3.3 III – 3-06 305

ISOBUTENYL CHLORIDE see 3253 2554 3.2 II – 3-06 340

ISOBUTYL ACETATE 3239 1213 3.2 II – 3-07 330

ISOBUTYL ACRYLATE, INHIBITED 3354 2527 3.3 III – 3-03 330

ISOBUTYL ALCOHOL 3354 1212 3.3 III – 3-06 305

ISOBUTYL ALDEHYDE p 3130 2045 3.1 II – 3-07 300

ISOBUTYLAMINE 3239 1214 3.2 II Corrosive 3-02 320

ISOBUTYLBENZENE p see 3315 2709 3.3 III – 3-07 310

ISOBUTYL BROMIDE see 3188 2342 3.2 II – 3-07 345

ISOBUTYL BUTYRATE p see Section 23.1.5 of the General Introduction

ISOBUTYLENE 2147 1055 2(2.1) – – 2-07 310

ISOBUTYL FORMATE 3240 2393 3.2 II – 3-07 330

ISOBUTYL IODIDE see 3238 2391 3.2 II – 3-07 345

ISOBUTYL ISOBUTYRATE p 3355 2528 3.3 III – 3-07 330

ISOBUTYL ISOCYANATE 3240 2486 3.2 II Toxic 3-04 370

ISOBUTYL MERCAPTAN p see 3194 2347 3.2 II – 3-07 375

ISOBUTYL METHACRYLATE, INHIBITED 3355 2283 3.3 III – 3-07 330

ISOBUTYL PROPIONATE p 3241 2394 3.2 II – 3-07 330

ISOBUTYL VINYL ETHER see 3290 1304 3.2 II – 3-06 330

ISOBUTYRALDEHYDE p 3130 2045 3.1 II – 3-07 300



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

ISOPROPENYL CHLORIDE see 3112 2456 3.1 I – 3-07 340

2-ISOPROPOXYPROPANE see 3117 1159 3.1 II – 3-02 330

ISOPROPYL ACETATE 3245 1220 3.2 II – 3-07 330

ISOPROPYL ACID PHOSPHATE 8188 1793 8 III – 8-05 700

ISOPROPYL ALCOHOL 3244 1219 3.2 II – 3-06 305

ISOPROPYLAMINE 3133 1221 3.1 I Corrosive 3-02 320

ISOPROPYLBENZENE p 3357 1918 3.3 III – 3-07 310

ISOPROPYL BROMIDE see 3189 2344 3.2 II 3-07 345

- ditto - see 3313 2344 3.3 III – 3-07 345

ISOPROPYL-sec -BUTYL PEROXYDICAR-BONATE + DI-sec-BUTYL PEROXYDI-CARBONATE + DI-ISOPROPYL PER-OXYDICARBONATE (concentration -52%+ -28% + - 22%)

see ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED

ISOPROPYL-sec -BUTYL PEROXYDICAR-BONATE + DI-sec-BUTYL PEROXYDI-CARBONATE + DI-ISOPROPYL PER-OXYDICARBONATE (concentration -32%+- 15-18% + -12-15%)


ISOPROPYL BUTYRATE 3358 2405 3.3 III – 3-07 330

ISOPROPYL CARBINOL see 3354 1212 3.3 III – 3-06 305

ISOPROPYL CHLORIDE see 3111 2356 3.1 I – 3-07 340

ISOPROPYL CHLOROACETATE 3358 2947 3.3 III – 3-02 740

ISOPROPYL CHLOROCARBONATE see 6168-1 2407 6.1 ICorrosive,Flammable

liquid6.1-01 740

ISOPROPYL CHLOROFORMATE 6168-1 2407 6.1 IFlammable

liquid, Corro-sive

6.1-01 740

ISOPROPYL CHLOROMETHANOATE see 6168-1 2407 6.1 ICorrosive,Flammable

liquid6.1-01 740



GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

ISOPROPYL-2-CHLOROPROPIONATE 3359 2934 3.3 III – 3-07 740

ISOPROPYL-alpha-CHLOROPROPIONATE see 3359 2934 3.3 III – 3-07 740

ISOPROPYL CUMYL HYDROPER OXIDE (concentration ≤72% with diluent type A) see ORGANIC PEROXIDE TYPE F, LIQUID

ISOPROPYL CYANIDE see 3241 2284 3.2 II Toxic 3-03 215

ISOPROPYL ETHER see 3117 1159 3.1 II – 3-02 330

ISOPROPYL FORMATE see 3275 1281 3.2 II – 3-06 330

ISOPROPYLIDENEACETONE see 3362 1229 3.3 III – 3-06 300

ISOPROPYL ISOBUTYRATE 3246 2406 3.2 II – 3-07 330

ISOPROPYL ISOCYANATE 3246 2483 3.2 II Toxic 3-04 370

ISOPROPYL MERCAPTAN p see 3142 2402 3.1 II – 3-07 375

ISOPROPYL METHANOATE see 3275 1281 3.2 II – 3-06 330

ISOPROPYL NITRATE 3247 1222 3.2 II – 3-07 235

ISOPROPYL PROPIONATE 3247 2409 3.2 II – 3-07 330

ISOPROPYLTOLUENE pp see 3325 2046 3.3 III – 3-07 310

ISOPROPYLTOLUOL pp see 3325 2046 3.3 III – 3-07 310

ISOSORBIDE DINITRATE MIXTURE with hot less than 60% lactose, mannose, starch or calcium hydrogen phosphate

4151 2907 4.1 – 4.1-06 320

ISOSORBIDE-5-MONONITRATE 4151-1 3251 4.1 III – 4.1-10 235

ISOTETRAMETHYLBENZENE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID, N.O.S.

Isothioate see ORGANOPHOSPHORUS PESTICIDE

ISOVALERALDEHYDE p see 3288 2058 3.2 II – 3-06 300

ISOVALERONE see 3333 1157 3.3 III – 3-07 300

Isoxathion pp see ORGANOPHOSPHORUS PESTICIDE



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

LITHIUM BATTERIES 9033 3090 9 II 4.1-06 none

LITHIUM BATTERIES CONTAINED INEQUIPMENT 9033 3091 9 II – 4.1-06 none

LITHIUM BATTERIES PACKED WITHEQUIPMENT 9033 3091 9 II – 4.1-06 none

LITHIUM BOROHYDRIDE 4347 1413 4.3 I – 4.3-04 245

Lithium dispersions see ALKALI METAL DISPERSION

LITHIUM FERROSILICON 4347-1 2830 4.3 II – 4.3-03 160,605

LITHIUM HYDRIDE 4348 1414 4.3 I – 4.3-01 160

LITHIUM HYDRIDE FUSED SOLID 4348 2805 4.3 II – 4.3-01 160

LITHIUM HYDROXIDE SOLID see 8190 2680 8 II – 8-06 160

LITHIUM HYDROXIDE SOLUTION 8190 2679 8 II/III – 8-06 160

LITHIUM HYDROXIDE MONOHYDRATE 8190 2680 8 II – 8-06 160

LITHIUM HYPOCHLORITE DRY with morethan 39% available chlorine (8.8% availableoxygen)

5156 1471 5.1 II – 5.1-06 160,741

LITHIUM HYPOCHLORITE MIXTURE DRYwith more than 39% available chlorine(8.8% available oxygen)

5156 1471 5.1 II 5.1 06 160,741

LITHIUM NITRATE 5157 2722 5.1 III – 5.1-06 160

LITHIUM NITRIDE 4349 2806 4.3 I – 4.3-05 160,725

LITHIUM PEROXIDE 5157 1472 5.1 II – 5.1 04 160,735

LITHIUM SILICON 4349 1417 4.3 II – 4.3-03 160

L.N.G. see NATURAL GAS, REFRIGERATED LIQUID

LONDON PURPLE p 6171 1621 6.1 II – 6.1 04 100

L.P.G. see PETROLEUM GASES LIQUEFIED


IMDG CODE - PAGE 10145Amdt 28 96

GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


EmSNo.

MFAGTableNo.

m see meta-

M86 fuel see 3174-1 3165 3.2 I Toxic Corrosive 3-02 720

Magnesia (unslaked) MATERIAL HAZARDOUS ONLY IN BULK *

MAGNESIUM granules coated see MAGNESIUM GRANULES, COATED

MAGNESIUM powder see MAGNESIUM POWDER

MAGNESIUM with more than 50% magne-sium in pellets, turnings or ribbons

4153 1869 4.1 III — 4.1-02 none

MAGNESIUM ALKYLS 4240 3053 4.2 I Dangerouswhen wet 4.2-01 170

Magnesium alloys see also ALKALINE EARTH METAL ALLOY, N.O.S.

MAGNESIUM ALLOYS, POWDER contain-ing more than 50% magnesium non-pyrophoric

4353 1418 4.3 I/II/III Spontaneouslycombustible 4.3-06 none

MAGNESIUM ALLOYS, with more than 50%magnesium in pellets turnings or ribbons 4153 1869 4.1 III – 4.1-02 none

MAGNESIUM ALUMINIUM PHOSPHIDE 4350 1419 4.3 I Toxic 4.3-02 205

Magnesium amalgams see ALKALINE EARTH METAL AMALGAM

MAGNESIUM ARSENATE p 6172 1622 6.1 II 6.1-04 100

MAGNESIUM BISULPHITE SOLUTION see 8126 2693 8 III – 8-08 635

MAGNESIUM BROMATE 5158 1473 5.1 II – 5.1-06 745

MAGNESIUM CHLORATE 5158 2723 5.1 II – 5.1-06 745

Magnesium chloride and chlorate, mixture • see CHLORATE AND MAGNESIUM CHLORIDE MIXTURE

MAGNESIUM DIAMIDE 4240 2004 4.2 II – 4.2-01 725

MAGNESIUM DIPHENYL 4241 2005 4.2 I – 4.2-01 170

Magnesium dispersions see ALKALINE EARTH METAL DISPERSION

* See section 24 of the General Introduction.



GENERAL INDEX


UN No. CLASS

Pack-aging Group

Subsidiary Risk Label(s)

EmS No.

MFAG Table No.

MAGNESIUM FLUOROSILICATE 6250 2853 6.1 III – 6.1-04 750

MAGNESIUM GRANULES, COATED, con-taining more than 50% magnesium particle size not less than 149 microns

4351 2950 4.3 III – 4.3-06 none

MAGNESIUM HEXAFLUOROSILICATE see 6250 2853 6.1 III – 6.1-04 750

MAGNESIUM HYDRIDE 4351 2010 4.3 I – 4.3-01 none

MAGNESIUM NITRATE 5159 1474 5.1 III – 5.1-06 235

MAGNESIUM PERCHLORATE 5159 1475 5.1 II – 5.1-06 745

MAGNESIUM PEROXIDE 5160 1476 5.1 II – 5.1-04 735

MAGNESIUM PHOSPHIDE 4352 2011 4.3 I Toxic 4.3-02 205

MAGNESIUM POWDER containing more than 50% magnesium non-pyrophoric 4353 1418 4.3 I/II/III Spontaneously

combustible 4.3-06 none

MAGNESIUM SILICIDE 4353 2624 4.3 II – 4.3-05 none

MAGNESIUM SILICOFLUORIDE see 6250 2853 6.1 III – 6.1-04 750

MAGNESIUM SILICON see 4353 2624 4.3 II – 4.3-05 none

MALATHION p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

MALEIC ANHYDRIDE (a) solid (b) molten

8191 2215 8 III – (a) 8-05 (b) 8-13 700

MALONODINITRILE see 6172 2647 6.1 II – 6.1-02 215

MALONONITRILE 6172 2647 6.1 II – 6.1-02 215

MANCOZEB p (ISO) see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

MANEB p 4242 2210 4.2 III Dangerous when wet 4.2-04 506

MANEB STABILIZED against self-heating p 4354 2968 4.3 III – 4.3-05 506



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

MANEB PREPARATION, STABILIZEDagainst self-heating p 4354 2968 4.3 III – 4.3-05 506

MANEB PREPARATION with not less than60% maneb p

4242 2210 4.2 III Dangerouswhen wet

4.2-04 506

MANGANESE ETHYLENE-BIS-DITHIOCARBAMATE p see 4242 2210 4.2 III Dangerous

when wet 4.2-04 506

MANGANESE ETHYLENE-1,2-BIS-DITHIOCARBAMATE p see 4242 2210 4.2 III Dangerous

when wet4.2-04 506

MANGANESE ETHYLENE-BIS-DITHIOCARBAMATE, STABILIZED p

see 4354 2968 4.3 III – 4.3-05 506

MANGANESE ETHYLENE-1,2-BIS-DITHIOCARBAMATE, STABILIZED p see 4354 2968 4.3 III – 4.3-05 506

MANGANESE NITRATE 5160 2724 5.1 III – 5.1-06 none

Manganese (II) nitrate see MANGANESE NITRATE

MANGANESE RESINATE 4153 1330 4.1 III – 4.1-06 none

MANGANOUS NITRATE see 5160 2724 5.1 III – 5.1-06 none

MANNITOL HEXANITRATE, WETTED withnot less than 40% water, or mixture of alco-hol and water, by mass

1123 0133 1.1 D – – 1-01 –

MATCHES, FUSEE 4154 2254 4.1 III – 4.1-06 none

MATCHES, SAFETY (book card or strike onbox)

4155 1944 4.1 III – 4.1-06 none

MATCHES, "STRIKE ANYWHERE" 4155 1331 4.1 III – 4.1-06 200

MATCHES, WAX "VESTA" 4156 1945 4.1 III – 4.1-06 none

MEAL, oily see 4257 1386 4.2 † 4.2-05 none

- ditto - see 4258 1386 4.2 † 4.2-05 none

- ditto - see 4259 2217 4.2 † – – 4.2-05 none

Mecarbam p see ORGANOPHOSPHORUS PESTICIDE

* Explosive substance or article, refer to subsection 7.3 of the MFAG.† No label required.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

MEDICAL WASTE, N.O.S 6320 3291 6.2 II – * n/a

MEDICINE, LIQUID, FLAMMABLE TOXIC,N.O.S. • 3134-1 3248 3.1 II Toxic 3-07 †

- ditto - • 3248-1 3248 3.2 II Toxic 3-07 †

- ditto - • 3360-1 3248 3.3 III Toxic 3-07 †

MEDICINE, LIQUID, TOXIC, N.O.S • 6172-1 1851 6.1 II/III – 6.1-02 †

MEDICINE SOLID, TOXIC, N.O.S. • 6172-1 3249 6.1 II/III – 6.1-04 †

Medinoterb see SUBSTITUTED NITROPHENOL PESTICIDE

p-MENTHYL HYDROPEROXIDE (concen-tration > 72-100%) see ORGANIC PEROXIDE TYPE D LIQUID

p-MENTHYL HYDROPEROXIDE (concen-tration -72% with diluent type A) see ORGANIC PEROXIDE TYPE F, LIQUID

Mephosfolan p see ORGANOPHOSPHORUS PESTICIDE

MERCAPTAN MIXTURE, LIQUID, FLAM-MABLE, N.O.S.• 3134-2 3336 3.1 I/II – 3-07 †

- ditto -• 3248-2 3336 3.2 l/ll – 3-07 †

- ditto -• 3360-2 3336 3.3 III – 3-07 †

MERCAPTAN MIXTURE, LIQUID, FLAM-MABLE, TOXIC, N.O.S. • 3135 1228 3.1 II Toxic 3-03 375

- ditto - • 3249 1228 3.2 II Toxic 3-03 375

- ditto - • 3361 1228 3.3 III Toxic 3-07 375

MERCAPTAN MIXTURE, LIQUID, TOXIC,FLAMMABLE, N.O.S.• 6173 3071 6.1 II Flammable

liquid 6.1-01 375

MERCAPTANS, LIQUID, FLAMMABLE,N.O.S.* 3134-2 3336 3.1 I/II – 3-07 †

- ditto -• 3248-2 3336 3.2 I/II – 3-07 †

- ditto -• 3360-2 3336 3.3 III – 3-07 †

MERCAPTANS, LIQUID, FLAMMABLE,TOXIC, N.O.S.• 3135 1228 3.1 II Toxic 3-03 375

- ditto - • 3249 1228 3.2 II Toxic 3-03 375

- ditto -• 3361 1228 3.3 III Toxic 3-07 375

* To be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to, or leakage from, a package containing infectious substances, refer to section 9 of

the introduction to class 6.2.† If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG. n/a - not applicablep, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

MERCAPTANS LIQUID, TOXIC, FLAMMA-BLE, N.O.S.• 6173 3071 6 1 II Flammable

liquid 6.1-01 375

MERCAPTOACETIC ACID see 8235 1940 8 II – 8-05 700

Mercaptodimethur p see CARBAMATE PESTICIDE

2-MERCAPTOETHANOL see 6267 2966 6.1 II – 6.1-02 375

2-MERCAPTOPROPIONIC ACID see 6267 2936 6.1 II – 6.1-02 375

5-MERCAPTOTETRAZOL-1-ACETIC ACID 1141 0448 1.4 C – – 1-04 700 *

MERCURIC ACETATE pp see 6178 1629 6.1 II – 6.1-04 105

MERCURIC AMMONIUM CHLORIDE pp see 6178 1630 6.1 II – 6.1-04 105

MERCURIC ARSENATE pp 6174 1623 6.1 II – 6.1-04 100,105

MERCURIC BENZOATE pp see 6179 1631 6.1 II – 6.1-04 105

MERCURIC BISULPHATE pp see 6187 1645 6.1 II – 6.1-04 105

MERCURIC BROMIDE p p see 6179 1634 6.1 II – 6.1-04 105

MERCURIC CHLORIDE pp 6175 1624 6.1 II – 6.1-04 105

MERCURIC CYANIDE p p see 6182 1636 6.1 II – 6.1-04 215

MERCURIC GLUCONATE pp see 6182 1637 6.1 II 6.1-04 105

MERCURIC IODIDE p see 6183 1638 6.1 II – 6.1-04 105

MERCURIC NITRATE pp 6175 1625 6.1 II 6.1-04 105

MERCURIC OLEATE pp see 6184 1640 6.1 II – 6.1-02 105

MERCURIC OXIDE pp see 6184 1641 6.1 II – 6.1-04 105

MERCURIC OXYCYANIDE, DESENSI-TIZED pp see 6185 1642 6.1 II – 6.1-04 215

MERCURIC POTASSIUM CYANIDE pp 6176 1626 6.1 I – 6.1-04 105,215

MERCURIC SULPHATE pp see 6187 1645 6.1 II – 6.1-04 105

MERCURIC THIOCYANATE p p see 6187 1646 6.1 II – 6.1-04 105

MERCUROL p p see 6183 1639 6.1 II – 6.1-04 105

MERCUROUS ACETATE pp see 6178 1629 6.1 II – 6.1-04 105



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

MERCUROUS BISULPHATE pp see 6187 1645 6.1 II – 6.1-04 105

MERCUROUS BROMIDE p p see 6179 1634 6.1 II – 6.1-04 105

MERCUROUS CHLORIDE pp see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

MERCUROUS NITRATE pp 6177 1627 6.1 II – 6.1-04 105

MERCUROUS SALICYLATE p p see 6186 1644 6.1 II – 6.1-04 105

MERCUROUS SULPHATE pp see 6187 1645 6.1 II – 6.1-04 105

MERCURY metal 8191 2809 8 III – 8-12 none

MERCURY ACETATE pp 6178 1629 6.1 II – 6.1-04 105

MERCURY AMMONIUM CHLORIDE p p 6178 1630 6.1 II – 6.1-04 105

MERCURY BASED PESTICIDE LIQUID,FLAMMABLE TOXIC, flashpoint less than23°C c.c. pp

3270 2778 3.2 I/II Toxic 3-03 105

MERCURY-BASED PESTICIDE, LIQUIDTOXIC pp 6219 3012 6.1 I/II/III – 6.1-02 105

MERCURY-BASED PESTICIDE LIQUID,TOXIC, FLAMMABLE, flashpoint between23°C and 61°C c.c. pp

6220 3011 6.1 I/II/III Flammableliquid 6.1-01 105

MERCURY-BASED PESTICIDE, SOLID,TOXIC pp 6221 2777 6.1 I/II/III – 6.1-04 105

MERCURY BENZOATE pp 6179 1631 6.1 II – 6.1-04 105

MERCURY BICHLORIDE pp see 6175 1624 6.1 II – 6.1-04 105

MERCURY BISULPHATE pp see 6187 1645 6.1 II – 6.1-04 105

MERCURY BROMIDES pp 6179 1634 6.1 II – 6.1-04 105

MERCURY COMPOUND, LIQUID,N.O.S.p p 6180 2024 6.1 I/II/III – 6.1-02 105

MERCURY COMPOUND SOLID, N.O.S. pp* 6181 2025 6.1 I/II/III – 6.1-04 105

Mercury (II) (mercuric) compounds pp orMercury (l) (mercurous) compounds p p see also MERCURY-BASED PESTICIDE

* p for mercuric sulphide.



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

MERCURY CYANIDE p p 6182 1636 6.1 II – 6.1-04 215

MERCURY FULMINATE, WETTED with notless than 20% water or mixture of alcohol andwater, by mass

1105 0135 1.1 A — – 1-01

MERCURY GLUCONATE pp 6182 1637 6.1 II – 6.1-04 105

MERCURY IODIDE pp 6183 1638 6.1 II – 6.1-04 105

MERCURY NUCLEATE pp 6183 1639 6.1 II – 6.1-04 105

MERCURY OLEATE pp 6184 1640 6.1 II – 6.1-02 105

MERCURY OXIDE pp 6184 1641 6.1 II – 6.1-04 105

MERCURY OXYCYANIDE, DESENSITIZEDp p 6185 1642 6.1 II – 6.1-04 215

MERCURY POTASSIUM CYANIDE pp see 6176 1626 6.1 I – 6.1-04 105,215

MERCURY POTASSIUM IODIDE p p 6185 1643 6.1 II – 6.1-04 105

MERCURY SALICYLATE p p 6186 1644 6.1 II – 6.1-04 105

MERCURY SULPHATE pp 6187 1645 6.1 II – 6.1-04 105

MERCURY THIOCYANATE pp 6187 1646 6.1 II – 6.1-04 105

MESITYLENE p see 3389-1 2325 3.3 III – 3-03 310

MESITYL OXIDE 3362 1229 3.3 III – 3-06 300

MESYL CHLORIDE see 6188 3246 6.1 I Corrosive 6.1-02 700

meta- (or m-) This prefix is not taken into account in determining the alphabetical order ofentries; see under the next part of the name shown in CAPITAL letters.

METAARSENIC ACID see 6072 1554 6.1 II – 6.1-04 100

METACETONE see 3208 1156 3.2 II – 3-07 300

METAL ALKYL HALIDES, WATER-REACTIVE, N.O.S. 4243 3049 4.2 I Dangerous

when wet 4.2-01 170

METAL ALKYL HYDRIDES, WATER-REACTIVE, N.O.S. 4244 3050 4.2 I Dangerous

when wet 4.2-01 170

METAL ALKYLS, WATER-REACTIVE,N.O.S. • 4243 2003 4.2 I Dangerous

when wet 4.2-01 170



GENERAL INDEX

SUBSTANCE or ARTICLEIMDGCODEPAGE

UNNo.

CLASSPack-agingGroup

Subsidiary RiskLabel(s)

EmSNo.

MFAGTableNo.

METAL ARYL HALIDES, WATER REACTIVE,N.O.S. • 4243 3049 4.2 I Dangerous

when wet 4.2-01 170

METAL ARYL HYDRIDES WATER-REACTIVE,N.O.S. • 4244 3050 4.2 I Dangerous

when wet4.2-01 170

METAL ARYLS, WATER REACTIVE, N.O.S.• 4243 2003 4.2 I Dangerouswhen wet

4.2-01 170

METAL CARBONYLS, N.O.S. • 6187-1 3281 6.1 I/II/III – 6.1-02 165

METAL CATALYST, DRY 4245 2881 4.2 I/II/III – 4.2-02 none

METAL CATALYST, WETTED with a visibleexcess of liquid 4246 1378 4.2 II – 4.2-05 none

METALDEHYDE 4157 1332 4.1 III – 4.1-03 300

METAL HYDRIDES FLAMMABLE, N.O.S. • 4157-1 3182 4.1 II/III – 4.1 06 *

METAL HYDRIDES WATER REACTIVEN.O.S. • 4354-1 1409 4.3 I/II – 4.3-01 760†

METALLIC SUBSTANCE WATER REACTIVEN.O.S. • 4354-2 3208 4.3 I/II/III – 4.3-08 *

METALLIC SUBSTANCE, WATER-REACTIVE,SELF-HEATING, N.O.S. • 4354-3 3209 4.3 I/II/III Spontaneously

combustible4.3-08 *

METAL POWDER, FLAMMABLE, N.O.S. ‡ 4157 3089 4.1 II/III – 4.1-02 *

METAL POWDER SELF-HEATING, N.O.S. • 4260 3189 4.2 II/III – 4.2-04

METAL SALTS OF ORGANIC COMPOUNDS,FLAMMABLE, N.O.S.• 4157-1 3181 4.1 II/III – 4.1-06 *

Metal sulphide concentrates MATERIAL HAZARDOUS ONLY IN BULKS §

Metam-sodium p see DITHIOCARBAMATE PESTICIDE

MFTHACRALDEHYDE, INHIBITED see 3250 2396 3.2 II Toxic 3-02 300

MFTHACRYLALDEHYDE, INHIBITED 3250 2396 3.2 II Toxic 3-02 300

* If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.† In addition refer to subsection 4.3 of the MFAG.‡ COPPER METAL POWDER carried under this entry is a severe marine pollutant.§ See section 24 of the General Introduction.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

3-METHACRYLIC ACID see 8154 2823 8 III – 8-05 700

METHACRYLIC ACID, INHIBITED 8192 2531 8 III – 8-02 700

METHACRYLONITRILE INHIBITED 3250 3079 3.2 I Toxic 3-06 215

METHALLYL ALCOHOL 3362 2614 3.3 III – 3-06 305

Methamidophos p see ORGANOPHOSPHORUS PESTICIDE

METHANE COMPRESSED 2156 1971 2(2.1) – – 2-02 620

METHANE, REFRIGERATED LIQUID 2156 1972 2(2.1) – – 2-10 620

METHANE AND HYDROGEN, MIXTURES,COMPRESSED see HYDROGEN AND METHANE MIXTURES, COMPRESSED

METHANESULPHONYL CHLORIDE 6188 3246 6.1 I Corrosive 6.1-02 700

METHANETHIOL p see 2160 1064 2(2.3) – Flammablegas 2-06 375

METHANOL 3251 1230 3.2 II Toxic 3-06 306

Methasulfocarb see CARBAMATE PESTICIDE

Methidathion p see ORGANOPHOSPHORUS PESTICIDE

Methomyl p see CARBAMATE PESTICIDE

ortho-METHOXYANILINE see 6069 2431 6.1 III – 6.1-02 335

METHOXYBENZENE p see 3311 2222 3.3 III – 3-07 330

1-METHOXYBUTANE see 3195 2350 3.2 II – 3-07 330

METHOXYETHANE see 2140 1039 2(2.1) – – 2-06 330

2-METHOXYETHANOL see 3342 1188 3.3 III – 3-06 330

2-METHOXYETHYL ACETATE see 3342 1189 3.3 III – 3-06 330

METHOXYMETHYL ISOCYANATE 3251 2605 3.2 I Toxic 3-04 370

4-METHOXY-4-METHYLPENTAN-2-ONE 3363 2293 3.3 III – 3-07 300



GENERAL INDEX


PAGEUNNo.



EmS No.MFAGTableNo.

4-METHOXY-4-METHYL-2-PENTANONE see 3363 2293 3.3 III – 3-07 300

METHOXYNITROBENZENES SOLID orLIQUID

see 6207 2730 6.1 III – 6.1-02 335

1-METHOXYPROPANE see 3138 2612 3.1 II – 3-06 330

1-METHOXY-2-PROPANOL 3363 3092 3.3 III – 3-06 330

METHYL ACETATE 3252 1231 3.2 II – 3-06 330

METHYLACETIC ACID see 8216 1848 8 III Flammableliquid* 8-04 700

METHYLACETYLENE AND PROPADIENEMIXTURE, STABILIZED 2157 1060 2(2.1) – — 2-07 310

2-METHYLACROLEIN, INHIBITED see 3250 2396 3.2 II Toxic 3-02 300

3-METHYLACROLEIN STABILIZED p see 6114-1 1143 6.1 I Flammableliquid

6.1-01 300

METHYL ACRYLATE, INHIBITED 3252 1919 3.2 II – 3-03 330

METHYLAL 3136 1234 3.1 II – 3-06 330

METHYL ALLYL ALCOHOL see 3362 2614 3.3 III – 3-06 305

METHYL ALLYL CHLORIDE 3253 2554 3.2 II – 3-06 340

METHYLALUMINIUM SESQUIBROMIDE see 4221 3052 4.2 I – 4.2-01 170

METHYLALUMINIUM SESQUICHLORIDE see 4221 3052 4.2 I Dangerouswhen wet 4.2-01 170

METHYLAMINE, ANHYDROUS 2157 1061 2(2.1) – – 2-06 320

METHYLAMINE, AQUEOUS SOLUTION 3253 1235 3.2 II Corrosive 3-02 320

2-(N,N-METHYLAMINOETHYLCARBONYL)-4-(3,4- DIMETHYLPHENYL-SULPHONYL)BENZENEDIAZONIUM HY-DROGEN SULPHATE (concentration 96%)


* If flashpoint 61° C c.c. or below.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

METHYLAMYL ACETATE 3364 1233 3.3 III – 3-07 330

METHYLAMYL ALCOHOL see 3366 2053 3.3 III – 3-02 305

METHYL-normal-AMYL KETONE see 3310 1110 3.3 III – 3-07 300

N-METHYLANILINE 6188 2294 6.1 III – 6.1-02 335

METHYLATED SPIRITS see 3219 1170 3.2 II – 3-06 305,306

METHYLBENZENE see 3285 1294 3.2 II – 3-07 310

4-METHYLBENZENESULPHONYL-HYDRAZIDE (concentration 100%) see SELF-REACTIVE SOLID TYPE D

METHYLBENZOL see 3285 1294 3.2 II – 3-07 310

alpha-METHYLBENZYL ALCOHOL, SOLIDor LIQUID 6189 2937 6.1 III – 6.1-02 305

METHYL BORATE see 3287 2416 3.2 II – 3-06 240

METHYL BROMIDE 2158 1062 2(2.3) – Flammablegas 2-06 345

METHYL BROMIDE AND CHLOROPICRIN,MIXTURE see 2120 1581 2(2.3) – – 2-08 345

METHYL BROMIDE AND ETHYLENE DI-BROMIDE, MIXTURE, LIQUID p 6190 1647 6.1 I – 6.1-02 345

METHYL BROMOACETATE 6191 2643 6.1 II – 6.1-02 740

METHYLBROMOACETONE 6191 - 6.1 II – 6.1-02 740

2-METHYL-1,3-BUTADIENE, INHIBITED see 3133 1218 3.1 I – 3-07 310

2-METHYLBUTANE see 3140 1265 3.1 I – 3-07 310

METHYLBUTANOLS see 3269-1 1105 3.2 II 3-06 305

- ditto - see 3373-1 1105 3.3 III – 3-06 305

3-METHYLBUTAN -2-ONE 3254 2397 3.2 II – 3-07 300

3-METHYL-2-BUTANONE see 3254 2397 3.2 II – 3-07 300

2-METHYL-1-BUTENE 3132 2459 3.1 I – 3-07 310



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

METHYLENE CHLORIDE see 6127 1593 6.1 III – 6.1-02 340

METHYLENE CHLORIDE AND METHYLCHLORIDE, MIXTURE see METHYL CHLORIDE AND METHYLENE CHLORIDE, MIXTURE

METHYLENE CHLOROBROMIDE see 6088 1887 6.1 III – 6.1-02 345

METHYLENE CYANIDE see 6172 2647 6.1 II – 6.1-02 215

p.p'-METHYLENEDIANILINE p see 6119 2651 6.1 III – 6.1-04 335

METHYLENE DIBROMIDE see 6122 2664 6.1 III – 6.1-02 345

METHYL ETHER see 2133 1033 2(2.1) – – 2-07 330

1-METHYL-2-ETHYLBEN2ENE p see Section 23.1.5 of the General Introduction

1-METHYL-4-ETHYLBENZENE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S.

METHYL ETHYL CARBINOL see 3191 1120 3.2 || – 3-06 305

- ditto - see 3314 1120 3.3 III – 3-06 305

METHYL ETHYL ETHER see 2140 1039 2(2.1) – – 2-06 330

METHYL ETHYL KETONE 3226 1193 3.2 II – 3-06 300

METHYL ETHYL KETONE PEROXIDE(S)(concentration -52%, with diluent type A,available oxygen >10%)

see ORGANIC PEROXIDE TYPE B, LIQUID

METHYL ETHYL KETONE PEROXIDE(S)(concentration -45%, with diluent type Aavailable oxygen - 10%)


METHYL ETHYL KETONE PEROXIDE(S)(concentration -40%, with diluent type Aavailable oxygen -82%)

see ORGANIC PEROXIDE TYPE E LIQUID

2-METHYL-5-ETHYLPYRIDINE p 6195 2300 6.1 III – 6.1-02 325

METHYL FLUORIDE 2160 2454 2(2.1) – – 2-07 345

METHYLFLUOROBENZENES (ortho-,meta-, para-) see 3233 2388 3.2 II – 3-07 345

METHYL FORMATE 3137 1243 3.1 I – 3-06 330



GENERAL INDEX


PAGE UN No. CLASS

Pack-aging Group


MFAG Table No.

2-METHYLFURAN 3137-1 2301 3.1 II – 3-07 330

METHYL GLYCOL see 3342 1188 3.3 III – 3-06 330

METHYL GLYCOL ACETATE see 3342 1189 3.3 III – 3-06 330

2-METHYLHEPTANE see 3267 1262 3.2 II – 3-07 310

2-METHYL-2-HEPTANETHIOL 6213 3023 6.1 I Flammable liquid

6.1-01 375

5-METHYL-2-HEXANONE see 3366 2302 3.3 III – 3-07 300

5-METHYLHEXAN-2-ONE 3366 2302 3.3 III – 3-07 300

METHYLHYDRAZINE 6196 1244 6.1 I Flammable

liquid, Corro-sive

6.1-01 720

METHYL IODIDE 6197 2644 6.1 I – 6.1-02 345

METHYL ISOBUTENYL KETONE see 3362 1229 3.3 III – 3-06 300

METHYL ISOBUTYL CARBINOL 3366 2053 3.3 III – 3-02 305

METHYL ISOBUTYL CARBINOL ACETATE see 3364 1233 3.3 III – 3-07 330

METHYL ISOBUTYL KETONE 3257 1245 3.2 II – 3-07 300

METHYL ISOBUTYL KETONE PEROXIDES (concentration ≤62% with diluent types A and B)


METHYL ISOCYANATE 6197-1 2480 6.1 I Flammable liquid

6.1-01 370

METHYL ISOCYANATE SOLUTION 6197-1 2480 6.1 I Flammable liquid

6.1-01 370

METHYL ISONITRILE see 6197-1 2480 6.1 I Flammable liquid 6.1-01 370

METHYL ISOPROPENYL KETONE, INHIB-ITED 3258 1246 3.2 II – 3-07 300

METHYL ISOPROPYL KETONE see 3254 2397 3.2 II – 3-07 300

METHYL ISOTHIOCYANATE 6198 2477 6.1 I Flammable liquid*

6.1-01 370

* If shipped as a liquid. p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS Packaging

GroupSubsidiary Risk

Label(s)EmSNo.

MFAGTable No.

METHYL ISOVALERATE 3258 2400 3.2 II – 3-07 330

METHYLMAGNESIUM BROMIDE IN ETHYLETHER 4355-1 1928 4.3 I Flammable liquid 4.3-01 170, 330

METHYL MERCAPTAN p 2160 1064 2(2.3) – Flammable gas 2-06 375

METHYLMERCAPTOPROPIONALDEHYDE p see 6266 2785 6.1 III – 6.1-01 300

METHYL METHACRYLATE, MONOMER, IN-HIBITED 3259 1247 3.2 II – 3-07 330

4-METHYLMORPHOLINE 3259 2535 3.2 II Corrosive 3-02 322

N-METHYLMORPHOLINE 3259 2535 3.2 II Corrosive 3-02 322

METHYLNAPHTHALENES p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE. LIQUID or SOLID,N.O.S.

METHYL NITRITE - 2455 CARRIAGE PROHIBITED

METHYLNITROPHENOLS p see 6210 2446 6.1 III – 6.1-02 710

METHYL ORTHOSILICATE 6198-1 2606 6.1 I Flammable liquid 6.1-01 360

METHYLPENTADIENES 3138 2461 3.1 II – 3-07 310

2-METHYLPENTANE see 3129 1208 3.1 II – 3-07 310


2-METHYLPENTAN -2-OL 3367 2560 3.3 III – 3-06 305

4-METHYLPENTAN-2-OL see 3366 2053 3.3 III – 3-02 305

4-METHYL-2-PENTANONE see 3257 1245 3.2 II – 3-07 300

4-METHYL-3-PENTEN-2-ONE see 3362 1229 3.3 III – 3-06 300

3-METHYL-2-PENTEN-4-YN OL see 8200 2705 8 II – 8-05 305

METHYLPHENYLDICHLOROSILANE 8192 2437 8 II – 8-02 700

METHYL PHENYL ETHER p see 3311 2222 3.3 III – 3-07 330

2-METHYL-2-PHENYLPROPANE p see 3315 2709 3.3 III – 3-07 310



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

1-METHYLPIPERIDINE 3260 2399 3.2 II Corrosive 3-02 325

N-METHYLPIPERIDINE see 3260 2399 3.2 II Corrosive 3-02 325

2-METHYLPROPANOL-1 see 3354 1212 3.3 III – 3-06 305

2-METHYL-2-PROPANOL see 3191 1120 3.2 II – 3-06 305

2-METHYLPROPANOYL CHLORIDE see 3242 2395 3.2 II Corrosive 3-04 700

2-METHYL-2-PROPEN-1-OL see 3362 2614 3.3 III – 3-06 305

METHYL PROPIONATE 3261 1248 3.2 II – 3-07 330

2-METHYLPROPIONIC ACID see 3356 2529 3.3 III Corrosive 3-02 700

METHYLPROPYL ACRYLATE, INHIBITED see 3354 2527 3.3 III – 3-03 330

METHYLPROPYLBENZENES pp see 3325 2046 3.3 III – 3-07 310

METHYL PROPYL ETHER 3138 2612 3.1 II – 3-06 330

2-METHYLPROPYL ISOBUTYRATE p see 3355 2528 3.3 III – 3-07 330

METHYL PROPYL KETONE 3261 1249 3.2 II – 3-07 300

METHYLPYRIDINES (2-, 3-, 4 ) see 3376 2313 3.3 III Corrosive 3-02 325

3-METHYL-4-(PYRROLIDIN-1-YL)-BENZENEDIAZONIUM TETRA-FLUOROBORATE (concentration 95%)

see SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED

METHYL SALICYLATE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

METHYLSTYRENES, INHIBITED p see 3392 2618 3.3 III – 3-02 310

alpha-METHYLSTYRENE p see 3357 2303 3.3 III – 3-07 310

METHYL SULPHATE see 6133 1595 6.1 I Corrosive 6.1-02 315

METHYL SULPHIDE p see 3119 1164 3.1 II – 3-07 225

METHYLTETRAHYDROFURAN 3262 2536 3.2 II – 3-07 330

METHYL TRICHLOROACETATE 6198-1 2533 6.1 III – 6.1-02 540

METHYLTRICHLOROSILANE 3262 1250 3.2 I Corrosive 3-04 700



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

METHYL ISOVALERATE 3258 2400 3.2 II – 3-07 330

METHYLMAGNESIUM BROMIDE INETHYL ETHER 4355-1 1928 4.3 I Flammable

liquid 4.3-01 170,330

METHYL MERCAPTAN p 2160 1064 2(2.3) – Flammablegas 2-06 375

METHYLMERCAPTOPROPION ALDE-HYDE p see 6266 2785 6.1 III – 6.1-01 300

METHYL METHACRYLATE, MONOMER,INHIBITED 3259 1247 3.2 II – 3-07 330

4-METHYLMORPHOLINE 3259 2535 3.2 II Corrosive 3-02 322

N-METHYLMORPHOLINE 3259 2535 3.2 II Corrosive 3-02 322

METHYLNAPHTHALENES p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE. LIQUID or SOLID, N.O.S.

METHYL NITRITE - 2455 CARRIAGE PROHIBITED

METHYLNITROPHENOLS p see 6210 2446 6.1 III – 6.1-02 710

METHYL ORTHOSILICATE 6198-1 2606 6.1 I Flammableliquid 6.1-01 360

METHYLPENTADIENES 3138 2461 3.1 II – 3-07 310



2-METHYLPENTAN-2-OL 3367 2560 3.3 III – 3-06 305

4-METHYLPENTAN -2-OL see 3366 2053 3.3 III – 3-02 305

4-METHYL-2-PENTANONE see 3257 1245 3.2 II – 3-07 300

4-METHYL-3-PENTEN-2-ONE see 3362 1229 3.3 III – 3-06 300

3-METHYL-2-PENTEN-4-YN OL see 8200 2705 8 II – 8-05 305

METHYLPHENYLDICHLOROSILANE 8192 2437 8 II – 8-02 700

METHYL PHENYL ETHER p see 3311 2222 3.3 III – 3-07 330

2-METHYL-2-PHENYLPROPANE p see 3315 2709 3.3 III – 3-07 310



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

1-METHYLPIPERIDINE 3260 2399 3.2 II Corrosive 3-02 325

N-METHYLPIPERIDINE see 3260 2399 3.2 II Corrosive 3-02 325

2-METHYLPROPANOL-1 see 3354 1212 3.3 III – 3-06 305

2-METHYL-2-PROPANOL see 3191 1120 3.2 II – 3-06 305

2-METHYLPROPANOYL CHLORIDE see 3242 2395 3.2 II Corrosive 3-04 700

2-METHYL-2-PROPEN-1-OL see 3362 2614 3.3 III – 3-06 305

METHYL PROPIONATE 3261 1248 3.2 II – 3-07 330

2-METHYLPROPIONIC ACID see 3356 2529 3.3 III Corrosive 3-02 700

METHYLPROPYL ACRYLATE, INHIBITED see 3354 2527 3.3 III – 3-03 330

METHYLPROPYLBENZENES pp see 3325 2046 3.3 III – 3-07 310

METHYL PROPYL ETHER 3138 2612 3.1 II – 3-06 330

2-METHYLPROPYL, ISOBUTYRATE p see 3355 2528 3.3 III – 3-07 330

METHYL PROPYL KETONE 3261 1249 3.2 II – 3-07 300

METHYLPYRIDINES (2-, 3 , 4-) see 3376 2313 3.3 III Corrosive 3-02 325

3-METHYL-4-(PYRROLIDIN-1-YL)BENZENEDIAZONIUM TETR A-FLUOROBORATE (concentration 95%)

see SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED

METHYL SALICYLATE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID N.O.S.

METHYLSTYRENES, INHIBITED p see 3392 2618 3.3 III – 3-02 310

alpha-METHYLSTYRENE p see 3357 2303 3.3 III – 3-07 310

METHYL SULPHATE see 6133 1595 6.1 I Corrosive 6.1-02 315

METHYL SULPHIDE p see 3119 1164 3.1 II – 3-07 225

METHYLTETRAHYDROFURAN 3262 2536 3.2 II – 3-07 330

METHYL TRICHLOROACETATE 6198-1 2533 6.1 III – 6.1-02 540

METHYLTRICHLOROSILANE 3262 1250 3.2 I Corrosive 3-04 700


IMDG CODE - PAGE 10162Amdt. 29 98

GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

NATURAL GASOLINE see MOTOR SPIRIT or GASOLINE or PETROL

Neodymium nitrate and praseodymium ni-trate, mixture see DIDYMIUM NITRATE

NEOHEXANE see 3129 1208 3.1 II – 3-07 310

NEON, COMPRESSED 2161 1065 2(2.2) – – 2-04 none

NEON, REFRIGERATED LIQUID 2161 1913 2(2.2) – – 2-12 620

Neon and nitrogen mixtures see RARE GASES AND NITROGEN MIXTURES

Neon and oxygen mixtures see RARE GASES AND OXYGEN MIXTURE

Neon in rare gases mixtures see RARE GASES MIXTURES

NEOPENTANE see 2147 2044 2(2.1) – – 2-07 310

NICKEL CARBONYL pp 6202 1259 6.1 I Flammableliquid 6.1-01 165

NICKEL CYANIDE pp 6203 1653 6.1 II – 6.1-04 215

Nickel (II) cyanide see NICKEL CYANIDE

NICKEL NITRATE 5161 2725 5.1 III – 5.1-06 none

Nickel (II) nitrate see NICKEL NITRATE

NICKEL NITRITE 5161 2726 5.1 III – 5.1-06 235

Nickel (II) nitrite see NICKEL NITRITE

NICKELOUS NITRATE see 5161 2725 5.1 III – 5.1-06 none

NICKELOUS NITRITE see 5161 2726 5.1 III – 5.1-06 235

NICKEL TETRACARBONYL pp see 6202 1259 6.1 I Flammableliquid 6.1-01 165

NICOTINE 6203 1654 6.1 II – 6.1-02 800

NICOTINE COMPOUND, LIQUID, N.O.S. 6204 3144 6.1 I/II/III – 6.1-02 800

NICOTINE COMPOUND, SOLID, N.O.S. 6204 1655 6.1 I/II/III – 6.1-04 800

NICOTINE HYDROCHLORIDE, LIQUID 6205 1656 6.1 II – 6.1-02 800



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

NICOTINE HYDROCHLORIDE SOLID 6205 1656 6.1 II – 6.1-04 800

NICOTINE HYDROCHLORIDE SOLUTION 6205 1656 6.1 II – 6.1-02 800

NICOTINE PREPARATION LIQUID, N.O.S. 6204 3144 6.1 I/II/III – 6.1-02 800

NICOTINE PREPARATION, SOLID, N.O.S. 6204 1655 6.1 I/II/III – 6.1-04 800

NICOTINE SALICYLATE 6205 1657 6.1 II – 6.1-04 800

NICOTINE SULPHATE, SOLID 6206 1658 6.1 II – 6.1-04 800

NICOTINE SULPHATE, SOLUTION 6206 1658 6.1 II – 6.1 02 800

NICOTINE TARTRATE 6206 1659 6.1 II – 6.1-04 800

NITRATES, INORGANIC, N.O.S. • 5162 1477 5.1 II/III – 5.1-05 235

NITRATES, INORGANIC, AQUEOUS SO-LUTION, N.O.S. • 5162 3218 5.1 II/III – 5.1 02 235

NITRATING ACID, MIXTURE 8194 1796 8 I/II Oxidizingagent * 8-03 700

NITRATING ACID, MIXTURE, SPENT 8194 1826 8 I/II Oxidizingagent * 8-03 700

NITRIC ACID, other than red fuming, allconcentrations 8195 2031 8 I † /ll Oxidizing

agent ‡ 8-03 610 †,700

NITRIC ACID, RED FUMING 8196 2032 8 I Oxidizingagent. Toxic 8-03 610,

700

NITRIC OXIDE, COMPRESSED 2162 1660 2(2.3) —Oxidizing

agent. Corro-sive

2-03 610

NITRIC OXIDE AND DINITROGENTETROXIDE, MIXTURE 2162 1975 2(2.3) –

Oxidizingagent. Corro-

sive2-08 610

* Not required if nitric acid content is not more than 50%.† Concentrations over 70%.‡ For packaging group I only.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

NITROCOTTON WITH ALCOHOL see 4159 2556 4.1 II – 4.1-01 610

NITROCOTTON WITÇ PLASTICIZINGSUBSTANCE • see 4160 2557 4.1 II – 4.1-01 610

NITROCOTTON WITH WATER see 4161 2555 4.1 II – 4.1-01 610

NITROCRESOLS p 6210 2446 6.1 III – 6.1-02 710

NITROETHANE 3369 2842 3.3 III – 3-06 335

NITROGEN COMPRESSED 2163 1066 2(2.2) – – 2-04 none

NITROGEN, REFRIGERATED LIQUID 2163 1977 2(2.2) – – 2-12 620

NITROGEN DIOXIDE AND NITRIC OXIDEMIXTURES see NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURES

NITROGEN DIOXIDE 2134 1067 2(2.3) –Oxidizing

agent, Corro-sive

2-08 610

NITROGEN MIXTURES WITH RAREGASES see RARE GASES AND NITROGEN MIXTURES

NITROGEN PEROXIDE see 2134 1067 2(2.3) –Oxidizing

agent Corro-sive

2-08 610

NITROGEN SESQUIOXIDE see 2164 2421 2(2.3) –Oxidizing

agent Corro-sive

2-08 610

NITROGEN TRIFLUORIDE, COM-PRESSED 2164 2451 2(2.2) – Oxidizing

agent 2-03 750

NITROGEN TRIOXIDE 2164 2421 2(2.3) —Oxidizing

agent Corro-sive

2-08 610

NITROGLYCERIN DESENSITIZED with notless than 40% non-volatile water-insolublephlegmatizer by mass

1108 0143 1.1 D – Toxic 1-01 –


IMDG CODE - PAGE 10171

Amdt. 29 98

GENERAL INDEX


PAGEUNNo. CLASS

Pack–agingGroup


MFAGTableNo.

NITROGLYCERIN MIXTURE, DESENSI-TIZED, LIQUID, FLAMMABLE, N.O.S. , •with not more than 30% nitroglycerin, bymass

3138-3 3343 3.1 † – ‡ ‡

- ditto - • 3265-1 3343 3.2 † – ‡ ‡

- ditto -• 3369-1 3343 3.3 † – ‡ ‡

NITROGLYCERIN MIXTURE, DESENSI-TIZED, SOLID, N.O.S. ,• with more than 2%but not more than 10% nitroglycerin, bymass

4161-2 3319 4.1 – – 4.1-01 235

NITROGLYCERIN SOLUTION IN ALC O-HOL, with more than 1% but not more than10% nitroglycerin

1126 0144 1.1 D – – 1-01 –

NITROGLYCERIN SOLUTION IN ALC O-HOL, with more than 1% but not more than5% nitroglycerin

3266 3064 3.2 II – 3-06 235

NITROGLYCERIN SOLUTION IN ALC O-HOL, with not more than 1% nitroglycerin 3265-2 1204 3.2 II – 3-06 235

NITROGUANIDINE, dry or wetted with lessthan 20% water, by mass 1127 0282 1.1 D – – 1-01 610 *

NITROGUANIDINE, WETTED with not lessthan 20% water, by mass 4162 1336 4.1 I – 4.1-01 610

NITROHYDROCHLORIC ACID 8197 1798 8 I – 8-03 700

NITROMANNITE, WETTED with not lessthan 40% water, or mixture of alcohol andwater, by mass

see 1123 0133 1.1 D – – 1-01 –

NITROMETHANE 3370 1261 3.3 II – 3-06 335

NITRONAPHTHALENE 4163 2538 4.1 III – 4.1-05 335

NITROPHENOLS (ortho-, meta-, para-) 6210 1663 6.1 III – 6.1-04 710

1-NITROPROPANE see 3370 2608 3.3 III – 3-06 335

2-NITROPROPANE see 3370 2608 3.3 III – 3-06 335

* Explosive substance or article, refer to subsection 7.3 of the MFAG.† Packaging group as assigned by the competent authority on the basis of the criteria set out in paragraph 3.1.2 of the Introduction to class 3.‡ As approved by the competent authority.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

NITROPROPANES 3370 2608 3.3 III – 3-06 335

para-NITROSODIETHYLANILINE 4247 4.2 II – 4.2-04 335

para-NITROSODIMETHYLANILINE 4247 1369 4.2 II – 4.2-04 335

4-NITROSOPHENOL see SELF-REACTIVE SOLID, TYPE D, TEMPERATURE CONTROLLED

NITROSTARCH dry or wetted with lessthan 20% water, by mass 1128 0146 1.1 D – – 1-01 *

NITROSTARCH, WETTED with not lessthan 20% water , by mass 4163-1 1337 4.1 I – 4.1-01 610

NITROSYL CHLORIDE 2165 1069 2(2.3) – Corrosive 2-08 740

NITROSYLSULPHURIC ACID, SOLID orLIQUID 8198 2308 8 II – 8-03 700

NITROTOLUENES (ortho-, meta-, para-),LIQUID p 6211 1664 6.1 II – 6.1-02 335

NITROTOLUENES (ortho-, meta-, para-),SOLID p 6211 1664 6.1 II – 6.1-02 335

NITROTOLUIDINES 6211 2660 6.1 III – 6.1-04 335

NITROTRIAZOLONE 1104 0490 1.1 D – – 1-01 *

NITROTRICHLOROMETHANE see 6108 1580 6.1 I – 6.1-02 740

NITRO-UREA 1129 0147 1.1 D – – 1-01 *

NITROUS ETHER, SOLUTION see 3124 1194 3.1 I Toxic 3-02 235

- ditto - see 3227 1194 3.2 I Toxic 3-02 235

NITROUS OXIDE 2166 1070 2(2.2) – Oxidizingagent 2-08 none

NITROUS OXIDE, REFRIGERATED LIQ-UID 2166 2201 2(2.2) – Oxidizing

agent 2-11 620

NITROUS OXIDE AND CARBON, DIOXIDEMIXTURES see CARBON DIOXIDE AND NITROUS OXIDE, MIXTURES

NITROXYLENES, LIQUID or SOLID p 6212 1665 6.1 II – 6.1-02 335

N,N- see N-



GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

1-NONANAL p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

NONANES 3371 1920 3.3 III – 3-07 310

1-NONANAL p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

NONYLPHENOL p see 8103 3145 8 I/II/III – 8-15 710

NONYLTRICHLOROSILANE 8198 1799 8 II – 8-02 700

Norbormide see PESTICIDE, N.O.S.

2,5-NORBORNADIENE, INHIBITED 3108 2251 3.1 II – 3-07 310

- ditto - 3186 2251 3.2 II – 3-07 310

- normal This prefix is not taken into account in determining the alphabetical order of en-tries, see under the next part of the name shown in capital letters

NTO 1104 0490 1.1 D

1-01 *

* Explosive substance or article, refer to subsection 7.3 of the MFAG. p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


PAGE UN No. CLASS

Pack-aging Group


MFAG Table No.

OXYGEN AND CARBON DIOXIDE, MIX-TURE, COMPRESSED

see 2113 1014 2(2.2) – Oxidizing agent

2-04 615

OXYGEN AND RARE GASES, MIXTURES see RARE GASES AND OXYGEN, MIXTURE

OXYGEN DIFLUORIDE, COMPRESSED 2170 2190 2(2.3) – Oxidizing

agent. Corro-sive

2-03 750

OXYGEN FLUORIDE, COMPRESSED see 2170 2190 2(2.3) – Oxidizing

agent, Corro-sive

2-03 750

OXYGEN GENERATOR, CHEMICAL 5165-1 3356 5.1 II – 5.1-11 *

* If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

p see para–

PAINT (including paint, lacquer, enamel,stain, shellac solutions varnish polish, liquidfiller and liquid lacquer base) or PAINT RE-LATED MATERIAL (including paint thinningor reducing compound)*

3139 1263 3.1 I/II * 3–05 310,313

– ditto – • 3268 1263 3.2 l/ll * – 3–05 310,313

– ditto – • 3372 1263 3.3 III – 3–05 310,313

PAPER, UNSATURATED OIL TREATED,incompletely dried 4248 1379 4.2 III – 4.2–05 none

para– (or p–) This prefix is not taken into account in determining the alphabetical order of en-tries, see under the next part of the name shown in CAPITAL letters

PARAFFIN see 3375 1223 3.3 III – 3–07 311

PARAFORMALDEHYDE 4164 2213 4.1† – – 4.1–03 300

PARALDEHYDE 3372 1264 3.3 Ill – 3–06 300

Paraoxon p see ORGANOPHOSPHORUS PESTICIDE

Paraquat see BIPYRIDILIUM PESTICIDE

Parathion pp see ORGANOPHOSPHORUS PESTICIDE

Parathion–methyil p see ORGANOPHOSPHORUS PESTICIDE

PCB's p p see 9034 2315 9 II – 6.1–02 none

PENTABORANE 4248–1 1380 4.2 I Toxic 4.2–01 245

PENTACHLOROETHANE p 6217 1669 6.1 II – 6.1–02 340

PENTACHLOROPHENOL p p 6217 3155 6.1 II – 6.1–04 711

Pentachlorophenol pp see also ORGANOCHLORINE PESTICIDE

* Packaging group III under certain conditions.† No label required.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

PENTAERYTHRITE TETRANITRATE, DE-SENSITIZED with not less than 15%phlegmatizer, by mass

1106 0150 1.1 D – – 1-01 *

PENTAERYTHRITE TETRANITRATE,MIXTURE, DESENSITIZED, SOLID,N.O.S., • with more than 10% but not morethan 20% PETN, by mass

4164 3344 4.1 Ill – † †

PENTAERYTHRITE TETRANITRATE,WETTED with not less than 25% water, bymass

1106 0150 1.1 D – – 1-01 –

PENTAERYTHRITE TETRANITRATE withnot less than 7% wax, by mass 1130 0411 1.1 D – – 1-01 –

PENTAERYTHRITOL TETRANITRATE,DESENSITIZED, with not less than 15%phlegmatizer, by mass

1106 0150 1.1 D – – 1-01 –

PENTAERYTHRITOL TETRANITRATE,WETTED with not less than 25% water, bymass

1106 0150 1.1 D – – 1-01 –

PENTAERYTHRITOL TETRANITRATE withnot less than 7% wax, by mass

1130 0411 1.1 D – – 1-01 –

PENTAFLUOROETHANE 2170 1 3220 2(2.2) – – 2-09 350

PENTAFLUOROETHANE,1,1,1-TRIFLUOROETHANE AND 1,1,1,2-TETRAFLUOROETHANE ZEOTROPICMIXTURE WITH APPROXIMATELY 44%PENTAFLUOROETHANE AND 52% 1,1,1-TRIFLUOROETHANE

see 2176-1 3337 2(2.2) – – 2-09 620

PENTAFLUOROETHYL, TRIFLUOROVI-NYL ETHER see 2171 3154 2(2.1) – – 2-07 620,

615

PENTAFLUOROETHOXY-TRIFLUOROETHYLENE

see 2171 3154 2(2.1) – – 2-07 620,615

PENTALIN p see 6217 1669 6.1 II – 6.1-02 340

PENTAMETHYLENE see 3115 1146 3.1 II – 3-07 310

PENTAMETHYLHEPTANE 3373 2286 3.3 III – 3-07 310

* Explosive substance or article, refer to subsection 7.3 of the MFAG.† As approved by the competent Authority.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

PENTANALS see 3288 2058 3.2 II – 3-06 300

normal-PENTANE see 3140 1265 3.1 II – 3-07 310

PENTANE-2,4-DIONE 3373 2310 3.3 III Toxic 3-06 300

2,4-PENTANEDIONE see 3373 2310 3.3 III Toxic 3-06 300

PENTANES, liquid 3140 1265 3.1 I/II – 3-07 310

PENTANETHIOLS p see 3184 1111 3.2 II – 3-07 375

PENTANOLS see 3269-1 1105 3.2 II – 3-06 305

- ditto - see 3373-1 1105 3.3 III – 3-06 305

2-PENTANONE see 3261 1249 3.2 II – 3-07 300

3-PENTANONE see 3208 1156 3.2 II – 3-07 300

1-PENTENE 3140 1108 3.1 I – 3-07 310

1-PENTOL 8200 2705 8 II – 8-05 305

PENTOLITE, dry or wetted with less than15% water, by mass 1110 0151 1.1 D – – 1-01 *

1-PENTYLAMINE see 3183 1106 3.2 II Corrosive 3-02 320

2-PENTYLAMINE see 3308 1106 3.3 III Corrosive 3-02 320

3-PENTYLAMINE see 3183 1 106 3.2 II Corrosive 3-02 320

PENTYLAMINES see 3183 1106 3.2 II Corrosive 3-02 320

- ditto - see 3308 1106 3.3 III Corrosive 3-02 320

n-PENTYLBENZENE p see Section 23.1.5 of the General Introduction

PENTYL BUTANOATES see 3309 2620 3.3 III – 3-06 330

PENTYL BUTYRATES see 3309 2620 3.3 III – 3-06 330

PENTYL FORMATES see 3309 1109 3.3 III – 3-07 330

PENTYL NITRATES see 3310 1112 3.3 III – 3-07 235

PERCHLORATES, INORGANIC, N.O.S. • 5166 1481 5.1 II/III – 5.1-05 745

PERCHLORATES, INORGANIC, AQU E-OUS SOLUTION, N.O.S.• 5166 321 I 5.1 II/III – 5.1-02 745

PERCHLORIC ACID, with more than 50%but not more than 72% acid , by mass 5167 1873 5.1 I Corrosive 5.1-02 700



GENERAL INDEX


PAGEUNNo.



EmS No.MFAGTableNo.

PERCHLORIC ACID with not more than 50%acid , by mass 8200 1802 8 II Oxidizing

agent 8-03 700

PERCHLOROBENZENE see 6158 2729 6.1 III – 6.1-04 500

PERCHLOROCYCLOPENTADIENE see 6159 2646 6.1 I – 6.1-02 340

PERCHLOROETHYLENE p see 6264 1897 6.1 III – 6.1-02 340

PERCHLOROMETHYL MERCAPTAN p 6218 1670 6.1 I – 6.1-02 376

PERCHLORYL FLUORIDE 2170-1 3083 2(2.3) – Oxidizingagent 2-08 750

PERFLUOROACETYL CHLORIDE see 2183 3057 2(2.3) – Corrosive 2-08 700

PERFLUORO-2-BUTENE see 2167 2422 2(2.2) – – 2-09 350

PERFLUORO(ETHYL VINYL ETHER) 2171 3154 2(2.1) – – 2-07 620,615

PERFLUORO(METHYL VINYL ETHER) 2171 3153 2(2.1) – – 2-07 620,615

PERFLUOROPROPANE see 2168 2424 2(2.2) – – 2-09 350

PERFUMERY PRODUCTS with flammableliquid • 3269 1266 3.2 II – 3-05 305

- ditto - • 3374 1266 3.3 III – 3-05 305

PERMANGANATES, INORGANIC, N.O.S.• 5167-1 1482 5.1 II/III – 5.1-05 715

PERMANGANATES, INORGANIC, AQU E-OUS SOLUTION, N.O.S.• 5167-1 3214 5.1 II – 5.1-02 715

PEROXIDES, INORGANIC, N.O.S.• 5168 1483 5.1 II/III 5.1-04 735

PEROXYACETIC ACID, TYPE D (concentra-tion -43%) stabilized

see ORGANIC PEROXIDE, TYPE D, LIQUID

PEROXYACETIC ACID, TYPE E (concentra-tion -43%) stabilized see ORGANIC PEROXIDE, TYPE E, LIQUID

PEROXYACETIC ACID, TYPE F (concentra-tion -43%) stabilized see ORGANIC PEROXIDE, TYPE F, LIQUID

PEROXYACETIC ACID AND HYDROGENPEROXIDE MIXTURE

see HYDROGEN PEROXIDE AND PEROXYACETIC ACID, MIXTURE

PERSULPHATES, INORGANIC, N.O.S.• 5168-1 3215 5.1 III – 5.1-05 700

* Packaging group III under certain conditionsp, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

PERSULPHATES, INORGANIC, AQUEOUSSOLUTION, N.O.S.• 5168–1 3216 5.1 III – 5.1–02 700

PESTICIDE, LIQUID, FLAMMABLE, TOXIC,N.O.S., flashpoint less than 23° C c.c. • 3270 3021 3.2 I/II Toxic 3–03

PESTICIDE, LIQUID, TOXIC, N.O.S. • 6219 2902 6.1 I/II/III – 6.1–02 *PESTICIDE, LIQUID, TOXIC, FLAMMABLE,N.O.S., flashpoint between 23° C and 61° Cc.c. •

6220 2903 6.1 I/II/III Flammableliquid 6.1–01

PESTICIDE, SOLID, TOXIC, N.O.S. • 6221 2588 6.1 I/II/III – 6.1–04 *PETN, DESENSITIZED with not less than15% phlegmatizer, by mass 1106 0150 1.1 D – – 1–01 *

PETN, WETTED, with not less than 25%water , by mass 1106 0150 1.1 D – – 1–01 †

PETN, with not less than 7% wax by mass 1130 0411 1.1 D – – 1–01 †

PETN/TNT see PENTOLITE

PETROL ‡ 3141 1203 3.1 II – 3–07 311

Petroleum coke calcined or uncalcined MATERIAL HAZARDOUS ONLY IN BULK §

PETROLEUM CRUDE OIL 3141 1267 3.1 I/II – 3–07 311

– ditto – 3271 1267 3.2 I/II – 3–07 311

– ditto – 3375 1267 3.3 III – 3–07 311

PETROLEUM DISTILLATES, N.O.S. • 3141 1268 3.1 I/II – 3–07 311

– ditto – • 3271 1268 3.2 I/II – 3–07 311

– ditto – • 3375 1268 3.3 III – 3–07 311

PETROLEUM ETHER see PETROLEUM DISTILLATES N.O.S. or PETROLEUM PRODUCTS, N.O.S.

* If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.† Explosive substance or article refers to subsection 7.3 of the MFAG.‡ PETROL leaded is a MARINE POLLUTANT .§ See section 24 of the General Introduction.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

PETROLEUM GASES, LIQUEFIED • 2147 1075 2(2.1) – – 2-07 311

PETROLEUM NAPHTHA see NAPHTHA, PETROLEUM

PETROLEUM OIL see PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S.

PETROLEUM PRODUCTS, N.O.S. • 3141 1268 3.1 I/II – 3-07 311

- ditto -• 3271 1268 3.2 I/II – 3-07 311

- ditto - • 3375 1268 3.3 – 3-07 311

Petroleum products see class 3.1, page 3271 Class 3.3, page 3375

PETROLEUM SPIRIT see PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S.

PHENACYL BROMIDE 6223 2645 6.1 II – 6.1-04 740

PHENARSAZINE CHLORIDE p p see 6138 1698 6.1 I – 6.1-04 101

PHENETIDINES (ortho-; para-) 6223 2311 6.1 III – 6.1-02 335

Phenkapton see ORGANOPHOSPHORUS PESTICIDE

PHENOL, MOLTEN 6224 2312 6.1 II – 6.1-02 710

PHENOL, SOLID 6225 1671 6.1 II – 6.1-04 710

PHENOL, SOLUTION 6225 2821 6.1 II/III – 6.1-02 710

PHENOLATES, LIQUID • 8139 2904 8 III – 8-05 711

PHENOLATES, SOLID • 8139 2905 8 III – 8-05 711

PHENOLSULPHONIC ACID, LIQUID 8201 1803 8 II – 8-06 700

d-PHENOTHRIN p see Section 23.1.5 of the General Introduction

PHENOXYACETIC ACID DERIVATIVEPESTICIDE, LIQUID, FLAMMABLE,TOXIC, flashpoint less than 23°C c.c. •

3270 3346 3.2 I/II Toxic 3-03 510

PHENOXYACETIC ACID DERIVATIVEPESTICIDE, LIQUID, TOXIC • 6219 3348 6.1 I/II/III – 6.1-02 510

PHENOXYACETIC ACID DERIVATIVEPESTICIDE, LIQUID, TOXIC, flashpointbetween 23°C and 61°C c.c. •




GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

PHENOXYACETIC ACID DERIVATIVE,SOLID, TOXIC • 6221 3345 6.1 I/II/III – 61-04 510

Phenthoater pp see ORGANOPHOSPHORUS PESTICIDE

PHENYLACETONITRILE, LIQUID 6226 2470 6.1 III – 6.1-02 215

PHENYLACETYL CHLORIDE 8201 2577 8 II – 8-02 700

PHENYLAMINE see 6068 1547 6.1 II – 6.1-02 335

PHENYL BROMIDE p see 3312 2514 3.3 III – 3-07 345

1-PHENYLBUTANE p see 3315 2709 3.3 III – 3-07 310

2-PHENYLBUTANE p see 3315 2709 3.3 III – 3-07 310

PHENYL CARBIMIDE see 6228 2487 6.1 I Flammableliquid 6.1-01 370

PHENYLCARBYLAMINE CHLORIDE 6226 1672 6.1 I – 6.1-02 740

PHENYLCHLOROFORM see 8122 2226 8 II – 8-05 340

PHENYL CHLOROFORMATE 6104 1 2746 6.1 II Corrosive 6.1-02 740

PHENYL CHLOROMETHYL KETONE,LIQUID or SOLID see 6099 1697 6.1 II – 6.1 02 740

PHENYL CYANIDE see 6082 2224 6.1 II – 6.1-02 215

PHENYLCYCLOHEXANE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID N.O.S.

PHENYLDICHLOROPHOSPHINE see 8202 2798 8 II – 8-05 700

PHENYLDICHLOROPHOSPHINE SU L-PHIDE see 8202 2799 8 II – 8-05 700

PHENYLENEDIAMINES (ortho-, meta-,para-) 6227 1673 6.1 III – 6.1-04 320

PHENYLETHANE see 3222 1175 3.2 II – 3-07 310

PHENYLETHYLENE, INHIBITED p see 3381 2055 3.3 III – 3-07 310

PHENYL FLUORIDE see 3233 2387 3.2 II – 3-07 345

PHENYLHYDRAZINE 6227 2572 6.1 II – 6.1-02 720



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

PHENYLIMINOPHOSGENE see 6226 1672 6.1 I – 6.1-02 740

PHENYL ISOCYANATE 6228 2487 6.1 I Flammableliquid 6.1-01 370

PHENYLISOCYANODICHLORIDE see 6226 1672 6.1 I – 6.1-02 740

PHENYL MERCAPTAN 6228 2337 6.1 I Flammableliquid 6.1-01 375

PHENYLMERCURIC ACETATE p p 6229 1674 6.1 II – 6.1 04 105

PHENYLMERCURIC COMPOUND, N.O.S.pp 6229 2026 6.1 I/II/III – 6.1-04 105

PHENYLMERCURIC HYDROXIDE pp 6230 1894 6.1 II – 6.1-04 105

PHENYLMERCURIC NITRATE pp 6230 1895 6.1 II – 6.1-04 105

PHENYL METHYL CARBINOL, SOLID or LIQ-UID see 6189 2937 6.1 III – 6.1-02 305

PHENYL METHYL ETHER p see 3311 2222 3.3 III – 3-07 330

PHENYLPHOSPHORUS DICHLORIDE 8202 2798 8 II – 8-05 700

PHENYLPHOSPHORUS THIODICHLORIDE 8202 2799 8 II – 8-05 700

2-PHENYLPROPENE p see 3357 2303 3.3 III – 3-07 310

PHENYLTRICHLOROSILANE 8203 1804 8 II – 8-02 700

PHENYLTRIFLUOROMETHANE see 3185 2338 3.2 II – 3-07 345



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

Phorate pp see ORGANOPHOSPHORUS PESTICIDE

Phosalone pp see ORGANOPHOSPHORUS PESTICIDE

Phosfolan see ORGANOPHOSPHORUS PESTICIDE

PHOSGENE 2172 1076 2(2.3) – Corrosive 2-08 600

Phosmet p see ORGANOPHOSPHORUS PESTICIDE

9-PHOSPHABICYCLONONANES 4249 2940 4.2 II – 42-04 310

Phosphamidon pp see ORGANOPHOSPHORUS PESTICIDE

PHOSPHINE 2172 2199 2(2.3) – Flammablegas 2-05 601

PHOSPHORETTED HYDROGEN see 2172 2199 2(2.3) – Flammablegas 2-05 601

PHOSPHORIC ACID, LIQUID 8204 1805 8 III – 8-08 700

PHOSPHORIC ACID, SOLID 8204 1805 8 III – 8-08 700

PHOSPHORIC ANHYDRIDE see 8208 1807 8 II – 8-06 700

PHOSPHORIC CHLORIDE see 8208 1806 8 II – 8-03 700

PHOSPHORIC PENTACHLORIDE see 8208 1806 8 II – 8-03 700

PHOSPHORIC PERCHLORIDE see 8208 1806 8 II – 8-03 700

PHOSPHOROUS ACID, solid or solution 8205 2834 8 III – 8-08 700

PHOSPHOROUS BROMIDE see 8209 1808 8 II – 8-03 700

PHOSPHOROUS CHLORIDE see 6231 1809 6.1 I Corrosive 6.1-02 700

PHOSPHORUS, AMORPHOUS 4165 1338 4.1 III – 4.1-06 none

PHOSPHORUS, RED see 4165 1338 4.1 III – 4.1-06 none

PHOSPHORUS, WHITE, DRY pp 4249 1381 4.2 I Toxic 4.2-04 200

PHOSPHORUS, WHITE, MOLTEN pp 4251 2447 4.2 I Toxic 4.2-03 200



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

PHOSPHORUS, WHITE, UNDER WATER p p 4250 1381 4.2 I Toxic 4.2-04 200

PHOSPHORUS, YELLOW, DRY p p 4249 1381 4.2 I Toxic 4.2-04 200

PHOSPHORUS, YELLOW, MOLTEN p p 4251 2447 4.2 I Toxic 4.2-03 200

PHOSPHORUS, YELLOW, UNDER WATER pp 4250 1381 4.2 I Toxic 4.2-04 200

PHOSPHORUS HEPTASULPHIDE, free fromyellow or white phosphorus 4165 1339 4.1 II – 4.1-03 225

PHOSPHORUS OXYBROMIDE, MOLTEN 8206 2576 8 II – 8-13 700

PHOSPHORUS OXYBROMIDE, SOLID 8206 1939 8 II – 8-03 700

PHOSPHORUS OXYCHLORIDE 8207 1810 8 II – 8-03 700

PHOSPHORUS PENTABROMIDE 8207 2691 8 II – 8-06 700

PHOSPHORUS PENTACHLORIDE 8208 1806 8 II – 8-03 700

PHOSPHORUS PENTAFLUORIDE, COM-PRESSED 2173 2198 2(2.3) – Corrosive 2-08 750

PHOSPHORUS PENTASULPHIDE, free fromyellow or white phosphorus 4355-3 1340 4.3 II Flammable

solid 4.3-03 225

PHOSPHORUS PENTOXIDE 8208 1807 8 II – 8-06 700

PHOSPHORUS SESQUISULPHIDE, free fromyellow or white phosphorus 4166 1341 4.1 II ~ 4.1-03 225

Phosphorus (V) sulphide, free from yellow orwhite phosphorus see PHOSPHORUS PENTASULPHIDE

PHOSPHORUS SULPHOCHLORIDE see 8237 1837 8 II – 8-03 740

PHOSPHORUS TRIBROMIDE 8209 1808 8 II – 8-03 700

PHOSPHORUS TRICHLORIDE 6231 1809 6.1 I Corrosive 6.1-02 700



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

PHOSPHORUS TRIOXIDE 8210 2578 8 III – 8-06 700

PHOSPHORUS TRISULPHIDE, free fromyellow or white phosphorus 4166 1343 4.1 II – 4.1-03 225

PHOSPHORYL BROMIDE, MOLTEN see 8206 2576 8 II – 8-13 700

PHOSPHORYL BROMIDE, SOLID see 8206 1939 8 II – 8-03 700

PHOSPHORYL CHLORIDE see 8207 1810 8 II – 8-03 700

PHTHALIC ANHYDRIDE with more than0.05% of maleic anhydride, solid or molten 8210 2214 8 III 8-05 *

8-13 †700

PICOLINES (alpha-, beta-, gamma-) 3376 2313 3.3 III Corrosive 3-02 325

PICRAMIC ACID WETTED with not lessthan 20% water see 4121-1 3317 4.1 I – 4.1-01 335

PICRAMIDE 1104 0153 1.1 D – – 1-01 ‡

PICRIC ACID, dry or wetted with less than30% water, by mass 1109 0154 1.1 D – – 1-01 ‡

PICRIC ACID, WETTED see 4180 1344 4.1 I – 4.1-01 710

PICRITE, dry or wetted with less than 20%water, by mass 1127 0282 1.1 D – – 1-01 610 ‡

* Solid† Molten‡ Explosive substance or articles refer to subsection 7.3 of the MFAG.


GENERAL INDEX


PAGEUNNo.



EmS No.MFAGTableNo.

PICRITE, WETTED with not less than 20%water, by mass see 4162 1336 4.1 I – 4.1–01 610

PICRYL CHLORIDE 1104 0155 1.1 D – – 1–01 –

PINANYL HYDROPEROXIDE (concentra-tion 56–100%) see ORGANIC PEROXIDE TYPE D, LIQUID

PINANYL HYDROPEROXIDE (concentra-tion <56% with diluent type A) see ORGANIC PEROXIDE TYPE F, LIQUID

Pindone (and salts of) p see PESTICIDE, N.O.S.

alpha–PINENE p 3377 2368 3.3 Ill – 3–03 313

PINE OIL 3377 1272 3.3 III – 3–07 313

PIPERAZINE, SOLID or SOLUTION 8211 2579 8 III – 8–05 320

1–PIPERAZINEETHYLAMINE see 8110 2815 8 III – 8–05 325

PIPERIDINE 8211–1 2401 8 I Flammable 8–01 325

Pinmicarb p see CARBAMATE PESTICIDE

Pinmiphos ethyl pp see ORGANOPHOSPHORUS PESTICIDE

Pitch prill MATERIAL HAZARDOUS ONLY IN BULK †

PIVALOYL CHLORIDE see 6275–1 2438 6.1 ICorrosiveFlammable

liquid6.1–01 700

Plastic explosives see EXPLOSIVE, BLASTING TYPE D

PLASTICS MOULDING COMPOUND indough sheet or extruded rope form, evolvingflammable vapour

9036 3314 9 III – 4.1–06 none

PLASTICS NITROCELLULOSEBASEDSELF–HEATING, N.O.S. • 4252 2006 4.2 III – 4.2–07 610

PLATINIC CHLORIDE, SOLID see 8140 2507 8 III – 8–06 700

Polish see PAINT

* Explosive substance or article, refer to subsection 7.3 of the MFAG.† See section 24 of the General Introduction.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

POLYAMINES, FLAMMABLE, CORROSIVE,N.O.S. • 3106 2733 3.1 I/II Corrosive 3-02 320

- ditto - • 3182-1 2733 3.2 I/I I Corrosive 3-02 320

- ditto -• 3306 2733 3.3 III Corrosive 3-02 320

POLYAMINES, LIQUID, CORROSIVE, N.O.S. • 8109-2 2735 8 I/II/III – 8-05 320

POLYAMINES, LIQUID, CORROSIVE, FLAMMA-BLE, N.O.S.• 8109-1 2734 8 I/II Flammable

liquid8-04 320

POLYAMINES, SOLID, CORROSIVE, N.O.S. • 8109-2 3259 8 I/II/III – 8-15 760

POLYCHLORINATED BIPHENYLS pp 9034 2315 9 II – 6.1-02 none

POLYESTER RESIN KIT • 3272 3269 3.2 II 3-07 *

- ditto - • 3377-1 3269 3.3 III – 3-07 *

POLYHALOGENATED BIPHENYLS, LIQUID pp 9035 3151 9 II – 6.1-02 none

POLYHALOGENATED BIPHENYLS, SOLID p p 9035 3152 9 II – 6.1-04 none

POLYHALOGENATED TERPHENYLS, LIQUID p p 9035 3151 9 II – 6.1-02 none

POLYHALOGENATED TERPHENYLS, SOLID p p 9035 3152 9 II – 6.1-04 none

POLYMERIC BEADS EXPANDABLE, evolvingflammable vapour 9036 2211 9 III – 4.1-06 none

Polystyrene beads, expandable see POLYMERIC BEADS EXPANDABLE

POLYSTYRENE BEADS, EXPANDABLE evolvingflammable vapour see 9036 2211 9 III – 4.1-06 none

POTASSIUM 4356 2257 4.3 I – 4.3-01 705

POTASSIUM ACID FLUORIDE, SOLID see 8212 1811 8 II Toxic 8-06 750

POTASSIUM ACID FLUORIDE, SOLUTION see 8212 1811 8 II Toxic 8-06 750

* If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

PROPYL BROMIDES see 3189 2344 3.2 II – 3-07 345

- ditto - see 3313 2344 3.3 III – 3-07 345

PROPYL CHLORIDE see 3111 1278 3.1 II – 3-07 340

normal-PROPYL CHLOROCARBONATE see 6244 2740 6.1 IFlammableliquid Corro-

sive6.1-01 740

normal- PROPYL CHLOROFORMATE 6244 2740 6.1 IFlammableliquid Corro-

sive6.1-01 740

PROPYL CYANIDE see 3197 2411 3.2 II Toxic 3-03 215

PROPYLENE 2147 1077 2(2.1) – – 2-07 310

PROPYLENE ACETYLENE AND ETHYL-ENE MIXTURE, REFRIGERATED LIQUID

see ETHYLENE ACETYLENE AND PROPYLENE MIXTURE, REFRIGERATEDLIQUID

PROPYLENE CHLOROHYDRIN 6245 2611 6.1 II Flammableliquid 6.1-01 740

PROPYLENEDIAMINES (1,2 or 1,3 ) 8217 2258 8 II Flammableliquid 8-04 320

PROPYLENE DICHLORIDE see 3206 1279 3.2 II – 3-07 340

PROPYLENEIMINE, INHIBITED 3274 1921 3.2 I Toxic 3-02 320

PROPYLENE OXIDE 3143 1280 3.1 I – 3-06 365

PROPYLENE TETRAMER 3378 2850 3.3 III – 3-07 310

PROPYLENE TRIMER see 3287 2057 3.2 II – 3-07 310

- ditto - see 3391 2057 3.3 III – 3-07 310

normal-PROPYL ETHER see 3120 2384 3.1 II 3-06 330

- ditto - see 3218 2384 3.2 II – 3-06 330

PROPYL FORMATES 3275 1281 3.2 II – 3-06 330

PROPYLFORMIC ACID see 8133 2820 8 III – 8-05 700

PROPYLIDENE DICHLORIDE* see 3230 1993 3.2 II – 3-07 340

PROPYL IODIDES see 3353 2392 3.3 III – 3-07 345

* PROPYLIDENE DICHLORIDE(1,1-DICHLOROPROPANE) should be shipped under the entry FLAMMABLE, LIQUID, N.O.S in class 3.2.


GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

normal-PROPYL ISOCYANATE 6245-1 2482 6.1 I Flammableliquid 6.1-01 370

PROPYL MERCAPTAN p see 3142 2402 3.1 II – 3-07 375

PROPYL METHANOATES see 3275 1281 3.2 II – 3-06 330

normal-PROPYL NITRATE 3276 1865 3.2 II – 3-07 235

PROPYLTRICHLOROSILANE 8218 1816 8 II Flammableliquid 8-01 700

Prothoate p see ORGANOPHOSPHORUS PESTICIDE

PRUSSIC ACID, ANHYDROUS, STABILIZED,containing less than 3% water p see 6163 1051 6.1 I Flammable

liquid 6.1-01 645

PRUSSIC ACID, ANHYDROUS, STABILIZED,containing less than 3% water and absorbed ina porous inert material p

see 6163 1614 6.1 I – 6.1-01 645

PRUSSIC ACID, AQUEOUS SOLUTION p see 6162 1613 6.1 I – 6.1-01 645

PRUSSIC ACID, AQUEOUS SOLUTION withnot more than 20% hydrogen cyanide p see 6162 1613 6.1 I – 6.1-01 645

PYRAZINE HEXAHYDRIDE, SOLID or SOLU-TION see 8211 2579 8 III – 8-05 320

Pyrazophos p p see ORGANOPHOSPHORUS PESTICIDE

Pyrazoxon see ORGANOPHOSPHORUS PESTICIDE

PYRETHROID PESTICIDE, LIQUID, FLAMMA-BLE, TOXIC, flashpoint less than 23° C c.c. • 3270 3350 3.2 I/II Toxic 3-03 510

PYRETHROID PESTICIDE, LIQUID, TOXIC • 6219 3352 6.1 I/II/III – 6.1-02 510

PYRETHROID PESTICIDE, LIQUID, TOXIC,FLAMMABLE, flashpoint between 23° C and61° C c.c. •


PYRETHROID, PESTICIDE, SOLID, TOXIC • 6221 3349 6.1 I/II/III – 6.1-04 510



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

PYRIDINE 3277 1282 3.2 II – 3-02 325

Pyntic ash MATERIAL HAZARDOUS ONLY IN BULK *

PYROPHORIC ALLOY, N.O.S.• 4255 1383 4.2 I – 4.2-02 760,†

PYROPHORIC ARTICLES see ARTICLES PYROPHORIC

PYROPHORIC LIQUID, INORGANIC, N.O.S.• 4254 3194 4.2 I – 4.2-01 760,†

PYROPHORIC LIQUID, ORGANIC, N.O.S. • 4254 2845 4.2 I – 4.2-01 760, †

PYROPHORIC METAL, N.O.S.• 4255 1383 4.2 I – 4.2-02 760, †

PYROPHORIC ORGANOMETALLIC COM-POUND (liquid), WATER-REACTIVE, N.O.S. • 4254 3203 4.2 I Dangerous

when wet 4.2-01 760, †

PYROPHORIC ORGANOMETALLIC COM-POUND (solid) WATER-REACTIVE, N.O.S.• 4255 3203 4.2 I Dangerous

when wet 4.2-01 760, †

PYROPHORIC SOLID, INORGANIC, N.O.S. • 4255 3200 4.2 I – 4.2-01 760, †

PYROPHORIC SOLID, ORGANIC, N.O.S. • 4255 2846 4.2 I – 4.2-01 760, †

PYROSULPHURIC ACID see 8231 1831 8 I Toxic 8-06 700

PYROSULPHURYL CHLORIDE 8218 1817 8 II – 8-03 700

PYROXYLIN SOLUTION see 3138 2 2059 3.1 I/II – 3-05 610

- ditto - see 3265 2059 3.2 – – 3-05 610

- ditto - see 3369 2059 3.3 III – 3-05 610

PYRROLIDINE 3277 1922 3.2 II Corrosive 3-02 325

* See section 24 of trie General Introduction.† In addition, refer to subsection 4.3 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UN No. CLASS

Pack-aging Group


MFAG Table No.

Quicklime, dolomitic MATERIAL HAZARDOUS ONLY IN BULK *

Quinalphos p see ORGANOPHOSPHORUS PESTICIDE

QUINOL, LIQUID see 6164 2662 6.1 III – 6.1–02 710

QUINOL SOLID see 6164 2662 6.1 III – 6.1–04 710

QUINOLINE 6246 2656 6.1 III – 6.1–01 335,610

QUINONE see 6082 2587 6.1 II – 6.1–04 300

QUIZALOFOP pp see Section 23.1.5 of the General Introduction

QUIZALOFOP–P–ETHYL pp see Section 23.1.5 of the General Introduction

* See section 24 of the General Introduction. p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

RECEPTACLES, SMALL CONTAININGGAS, without a release device not refillable 2175 2037 2(*) – * 2-13 †

REFRIGERANT GAS, N.O.S. • 2176 1078 2(2.2) – – 2-06 350

REFRIGERANT GAS R 12 2129 1028 2(2.2) – – 2-09 350

REFRIGERANT GAS R 12B1 2117 1974 2(2.2) – – 2-09 350


REFRIGERANT GAS R 13B1 2109 1009 2(2.2) – – 2-09 350

REFRIGERANT GAS R 14, COM-PRESSED 2182 1982 2(2.2) – – 2-09 350




REFRIGERANT GAS R 32 2132-1 3252 2(2.1) – – 2-07 350


REFRIGERANT GAS R 41 2160 2454 2(2.1) – – 207 345



REFRIGERANT GAS R 116 COM-PRESSED 2146 2193 2(2.2) – – 2-09 350



REFRIGERANT GAS R 133a 2121 1983 2(2.2) – – 2-09 350


REFRIGERANT GAS R 142b 2118 2517 2(2.1) – – 2-07 350


* According to properties† Class 2.1, 6.20, Class 2.2, 6.20,Class 2.3. If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.





REFRIGERANT GAS R 404a 2176-1 3337 2(2.2) – – 2-09 620

REFRIGERANT GAS R 407a 2176-1 3338 2(2.2) – – 2 09 620

REFRIGERANT GAS R 407b 2176-2 3339 2(2.2) – – 2-09 620

REFRIGERANT GAS R 407c 2176-2 3340 2(2.2) – – 2 09 620







REFRIGERANT GAS RC 318 2167 1976 2(2.2) – – 2-09 350

REFRIGERATING MACHINES containingnon-flammable, non-toxic liquefied gas orammonia solution (UN 2672)

2176 2857 2(2.2) – – 2-13 350

REGULATED MEDICAL, WASTE, N.O.S. 6320 3291 6.2 II – * n/a

RELEASE DEVICES EXPLOSIVE 1287 0173 1.4 S – – 1-04 †

RESIN SOLUTION flammable • 3143-1 1866 3.1 I/II ‡ – 3-05 310

- ditto - • 3278 1866 3.2 I/II ‡ – 3-05 310

- ditto - • 3379 1866 3.3 III – 3-05 310

* To be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event ofdamage to or leakage from a package containing infectious substances, refer to section 9 of the introduction to class 6.2.

† Explosive substance or article, refer to subsection 7.3 of the MFAG .‡ Packaging group III under certain conditions.n/a not applicable .p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

Sahthion p see ORGANOPHOSPHORUS PESTICIDE

SAMPLES, EXPLOSIVE, other than initiat-ing explosive 1134 0190 1(*) – – † ‡

- ditto - 1298 0190 1(*) – – † ‡

Sawdust MATERIAL HAZARDOUS ONLY IN BULKS §

Schradan see ORGANOPHOSPHORUS PESTICIDE

SEAT BELT PRETENSIONERS, pyrotech-nic 9022-1 3268 9 Ill – ** none

SEAT-BELT PRETENSIONERS, COM-PRESSED GAS 2102-1 3353 2.2 – – ** none

secondary (or sec-) This prefix is not taken into account in determining the alphabetical order of entriessee under the next part of the name shown in capital letters

SEED CAKE, containing vegetable oil me-chanically expelled seeds, containing morethan 10% of oil or more than 20% of oil andmoisture combined

4257 1386 4.2 ¶ – – 4.2-05 none

SEED CAKE, containing vegetable oil sol-vent extractions and expelled seeds, con-taining not more than 10% of oil and whenthe amount of moisture is higher than 10%,not more than 20% of oil and moisturecombined

4258 1386 4.2 ¶ – – 4.2-05 none

SEED CAKE, containing vegetable oil, sol-vent extractions containing not more than1.5% of oil and 11% of moisture

4259 2217 4.2 ¶ – – 4.2-05 none

SEED EXPELLERS, oily see 4257 1386 4.2 ¶ – – 4.2-05 none

- ditto - see 4258 1386 4.2 ¶ – – 4.2-05 none

- ditto - see 4259 2217 4.2 ¶ – – 4.2-05 none

SELENATES • 6249 2630 6.1 I – 6.1-04 175

* As appropriate† To be declared by the shipper after assignment by the competent authority, who should allocate a schedule or

develop a new schedule in a similar format to the existing schedules.‡ Explosive substance or article, refer to subsection 7.3 of the MFAG.§ See section 24 of the General Introduction.¶ No label required.** To be declared by the shipper.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

SELENIC ACID 8220 1905 8 I – 8-06 175,700

SELENINYL CHLORIDE see 8220 2879 8 I Toxic 8-06 175,700

SELENITES • 6249 2630 6.1 I – 6.1-04 175

SELENIUM COMPOUND, N.O.S.• 6249-1 3283 6.1 I/II/III – 6.1-0216.1-042

175

SELENIUM DISULPHIDE 6249 2657 6.1 II – 6.1-04 175,225

SELENIUM HEXAFLUORIDE 2177 2194 2(2.3) – Corrosive 2-08 175,750

SELENIUM HYDRIDE see 2151 2202 2(2.3) – Flammablegas 2-05 175

SELENIUM OXYCHLORIDE 8220 2879 8 I Toxic 8-06 175,700

SELF HEATING LIQUID, CORROSIVE, INOR-GANIC, N.O.S.• 4259-2 3188 4.2 II/III Corrosive 4.2-04 *

SELF-HEATING LIQUID, CORROSIVE, OR-GANIC, N.O.S.• 4259-2 3185 4.2 II/III Corrosive 4.2-04 *

SELF-HEATING LIQUID, INORGANIC, N.O.S.• 4259-1 3186 4.2 II/III – 4.2-04 *

SELF-HEATING LIQUID, ORGANIC, N.O.S. • 4259-1 3183 4.2 II/III – 4.2-04 *

SELF-HEATING LIQUID, TOXIC, INORGANIC,N.O.S. • 4259-2 3187 4.2 II/III Toxic 4.2-04 *

SELF-HEATING LIQUID, TOXIC, ORGANIC,N.O.S. • 4259-2 3184 4.2 II/III Toxic 4.2-04 *

SELF-HEATING SOLID, CORROSIVE, INOR-GANIC, N.O.S.• 4261 3192 4.2 II Corrosive 4.2-04 760 †

SELF-HEATING SOLID, CORROSIVE, OR-GANIC, N.O.S.• 4261 3126 4.2 II Corrosive 4.2-04 760 †

* If an MFAG Table No is not supplied by the shipper refer to subsection 4.2 of the MFAG.† In addition refer to subsection 4.3 of the MFAG.1 For liquids.2 For solids.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

SODIUM METHYLATE, SOLUTIONS inalcohols 3280 1289 3.2 II Corrosive 3-04 306,

705

- ditto - 3381 1289 3.3 III Corrosive 3-04 306,705

SODIUM MONOCHLOROACETATE see 6255 2659 6.1 III – 6.1-04 540

SODIUM MONOXIDE 8226 1825 8 II – 8-06 705

SODIUM NITRATE 5180 1498 5.1 III – 5.1-06 235

SODIUM NITRATE AND POTASSIUM NI-TRATE, MIXTURE 5181 1499 5.1 III – 5.1-06 235

SODIUM NITRITE 5181 1500 5.1 III Toxic 5.1-06 235

SODIUM NITRITE AND POTASSIUM NI-TRATE, MIXTURE see 5171 1487 5.1 II – 5.1-06 235

SODIUM ORTHOARSENATE see 6253 1685 6.1 II – 6.1-04 100

SODIUM OXIDE see 8226 1825 8 II – 8-06 705

SODIUM PENTACHLOROPHENATE pp 6259 2567 6.1 II – 6.1-04 711

SODIUM PERBORATE, ANHYDROUS see 5185 3247 5.1 II – 5.1-06 735

SODIUM PERCHLORATE 5182 1502 5.1 II – 5.1-06 745

SODIUM PERMANGANATE 5183 1503 5.1 II – 5.1-06 715

SODIUM PEROXIDE 5184 1504 5.1 I – 5.1-04 735

SODIUM PEROXOBORATE, ANHY-DROUS 5185 3247 5.1 II – 5.1-06 735

SODIUM PERSULPHATE 5185 1505 5.1 III – 5.1-06 700

SODIUM PHOSPHIDE 4363 1432 4.3 I Toxic 4.3-02 205

SODIUM PICRAMATE, dry or wetted withless than 20% water , by mass 1107 0235 1.3 C – – 1-03 710,*

SODIUM PICRAMATE, WETTED with notless than 20% water, by mass 4173 1349 4.1 I – 4.1-01 710

* Explosive substance or articles refer to subsection 7.3 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

SODIUM POTASSIUM ALLOYS see 4356 1422 4.3 I – 4.3-01 705

SODIUM SILICOFLUORIDE see 6250 2674 6.1 III – 6.1-04 750

SODIUM SULPHIDE, ANHYDROUS 4263 1385 4.2 II – 4.2-04 225,705

SODIUM SULPHIDE, HYDRATED with atleast 30% water 8227 1849 8 II – 8-08 225

SODIUM SULPHIDE with less than 30%water of crystallization

4263 1385 4.2 II – 4.2-04 225,705

SODIUM SULPHYDRATE see 4262 2318 4.2 II – 4.2-04 225

- ditto - see 8225 2949 8 II – 8-05 225

SODIUM SUPEROXIDE 5186 2547 5.1 I – 5.1-04 735

SOLIDS CONTAINING CORROSIVE LIQ-UID, N.O.S. • 8227-1 3244 8 II – 8-15 760

SOLIDS CONTAINING FLAMMABLE, LIQ-UID, N.O.S. • 4173-1 3175 4.1 II – 4.1-06 †

SOLIDS CONTAINING TOXIC, LIQUID,N.O.S. • 6259-1 3243 6.1 II – 6.1-04 †

SOUNDING DEVICES, EXPLOSIVE 1303 0374 1.1 D – – 1-01 *

0375 1.2 D – – 1-02 *

- ditto - 1304 0296 1.1 F – – 1-01 *

0204 1.2 F – – 1-02 *

Squibs see IGNITERS, UN Nos. 0325 and 0454

Stain see PAINT

STANNIC CHLORIDE, ANHYDROUS 8228 1827 8 II – 8-03 700

STANNIC CHLORIDE PENTAHYDRATE 8228 2440 8 III – 8-06 700

STANNIC PHOSPHIDE 4364 1433 4.3 I Toxic 4.3-02 205

STEEL SWARF see 4232 2793 4.2 – 4.2-05 none

* Explosive substance or article, refer to subsection 7.3 of the MFAG.† If an MFAG number is not supplied by the shipper, refer to subsection 7.3 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

TETRAHYDROBENZENE see 3114 2256 3.1 II – 3-07 310

- ditto - see 3203 2256 3.2 II – 3-07 310

TETRAHYDROFURAN 3144 2056 3.1 II – 3-06 330

- ditto - 3282 2056 3.2 II – 3-06 330

TETRAHYDROFURFURYLAMINE 3385 2943 3.3 III – 3-02 320

TETRAHYDROMETHYLFURAN see 3262 2536 3.2 II – 3-07 330

TETRAHYDRONAPHTHYL HYDROPER-OXIDE (concentration -100%) see ORGANIC PEROXIDE, TYPE D, SOLID

TEFRAHYDRO-1,4-OXAZINE see 3367 2054 3.3 III – 3-02 322

TETRAHYDROPHTHALIC ANHYDRIDESwith more than 0.05% maleic anhydride 8234 2698 8* III – 8-05 700

1,2,3,6-TETRAHYDROPYRIDINE 3282 2410 3.2 II – 3-06 325

1,2,5,6-TETRAHYDROPYRIDINE 3282 2410 3.2 II – 3-06 325

TETRAHYDROTHIOPHENE 3283 2412 3.2 II – 3-07 375

TETRAMETHOXYSILANE see 6198-1 2606 6.1 é Flammableliquid 6.1-01 360

TETRAME TURIN p see Section 23.1.5 of the General Introduction

TETRAMETHYLAMMONIUM HYDROXIDE,LIQUID or SOLID 8235 1835 8 II – 8-05 705

n-TETRAMETHYLBENZENE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

1,1,3,3-TETRAMETHYLBUTYL HYDRO-PEROXIDE (concentration - 100%) see ORGANIC PEROXIDE, TYPE D, LIQUID

1,1,3,3-TETRAMETHYLBUTYL PEROXY-2-ETHYL HEXANOATE (concentration-100%)


TETRAMETHYLENE see 2127 2601 2(2.1) – – 2-07 310

TETRAMETHYLENE CYANIDE see 6054 2205 6.1 Ill – 6.1-02 215

N,N,N',N'-TETRAMETHYL-ETHYLENEDIAMINE see 3207 2372 3.2 II – 3-06 320

* No label requiredp, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

TETRAMETHYLLEAD p see 6199 1649 6.1 I Flammableliquid* 6.1-01 111

TETRAMETHYLSILANE 3144 2749 3.1 I – 3-07 none

TETRAMINE PALLADIUM (II) NITRATE(concentration 100%) see SELF-REACTIVE SOLID, TYPE C, TEMPERATURE CONTROLLED

TETRANITROANILINE 1104 0207 1.1 D – – 1-01 335,†

TETRANITROMETHANE 5189 1510 5.1 I Toxic 5.1-02 335

TETRAPROPYLENE see 3378 2850 3.3 III – 3-07 310

TETRAPROPYL ORTHOTITANATE 3385 2413 3.3 III – 3-06 330

TETRAZENE, WETTED with not less than30% water, or mixture of alcohol and water,by mass

1105 0114 1.1 A – – 1-01 †

TETRAZOL-1-ACETIC ACID 1141 0407 1.4 C – – 1-04 700,†

TETRYL 1112 0208 1.1 D – – 1-01 †

TEXTILE WASTE, WET 4264 - 4.2 Ill – 4.2-05 none

THALLIUM CHLORATE p 5190 2573 5.1 II Toxic 5.1-05 140,745

Thallium (l) chlorate see THALLIUM CHLORATE

THALLIUM COMPOUND, N.O.S.p 6265 1707 6.1 II – 6.1-04 140

THALLIUM NITRATE p 6265 2727 6.1 II Oxidizingagent

6.1-04 140

Thallium (l) nitrate see THALLIUM NITRATE

Thallium sulphate p see THALLIUM COMPOUND, N.O.S.

THALLOUS CHLORATE p see 5190 2573 5.1 II Toxic 5.1-05 140,745

4-THIAPENTANAL p 6266 2785 6.1 III – 6.1-01 300

THIOACETIC ACID 3283 2436 3.2 II – 3-06 700

THIOCARBAMATE PESTICIDE, LIQUID,FLAMMABLE, TOXIC, flashpoint less than23°C c.c. •

3270 2772 3.2 I/II Toxic 3-03 506

* If flashpoint 61 °C c. c. or below.† Explosive substance or article refer to subsection 7.3 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

THIOCARBAMATE PESTICIDE, LIQUID,TOXIC • 6219 3006 6.1 I/II/III – 6.1-02 506

THIOCARBAMATE PESTICIDE, LIQUID,TOXIC, FLAMMABLE, flash point between23° C and 61° C c.c. •


THIOCARBAMATE PESTICIDE, SOLID,TOXIC • 6221 2771 6.1 I/II/III – 6.1-04 506

THIOCARBONYL CHLORIDE see 6268 2474 6.1 II – 6.1-02 600

THIOCARBONYL TETRACHLORIDE p see 6218 1670 6.1 I – 6.1-02 376

THIOGLYCOL 6267 2966 6.1 II – 6.1-02 375

THIOGLYCOLIC ACID 8235 1940 8 II – 8-05 700

THIOLACETIC ACID see 3283 2436 3.2 II – 3-06 700

THIOLACTIC ACID 6267 2936 6.1 II – 6.1-02 375

Thiometon see ORGANOPHOSPHORUS PESTICIDE

Thionazin see ORGANOPHOSPHORUS PESTICIDE

THIONYL CHLORIDE 8236 1836 8 I – 8-03 635700

THIOPHENE 3284 2414 3.2 II – 3-07 375

THIOPHENOL see 6228 2337 6.1 I Flammableliquid 6.1-01 375

THIOPHOSGENE 6268 2474 6.1 II – 6.1 02 600

THIOPHOSPHORYL CHLORIDE 8237 1837 8 II – 8-03 740

THIOPROPYL ALCOHOLS p see 3142 2402 3.1 II – 3-07 375

THIOUREA DIOXIDE 4264 3341 4.2 II/III – 4.2-04 †

THORIUM METAL PYROPHORIC - in TypeA packages 7109 2975 7 – Spontaneously

combustible 7-03 *

- in Type B(U) packages 7110 2975 7 – Spontaneouslycombustible 7-03 *

- in Type B(M) packages 7111 2975 7 – Spontaneouslycombustible 7-03 *

- under special arrangement 7113 2975 7 – Spontaneouslycombustible 7-03 *

* See subsection 7.4 of the MFAG.† If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UN No. CLASS

Pack-aging Group


EmS No.

MFAG Table No.

THORIUM METAL, PYROPHORIC - in Type A packages 7109 2975 7 – Spontaneously

combustible 7-03 *

- in Type B(U) packages 7110 2975 7 – Spontaneously combustible 7-03 *

- in Type B(M) packages 7111 2975 7 – Spontaneously combustible 7-03 *

- under special arrangement 7113 2975 7 – Spontaneously combustible 7-03 *

THORIUM NITRATE, SOLID - as LSA-I 7105 2976 7 – Oxidizing agent 7-05 *

- as LSA-ll 7106 2976 7 – Oxidizing agent 7-05 *

- in Type A packages 7109 2976 7 – Oxidizing agent 7-05 *

- in Type B(U) packages 7110 2976 7 – Oxidizing agent 7-05 *

- in Type B(M) packages 7111 2976 7 – Oxidizing agent 7-05 *

- under special arrangement 7113 2976 7 — Oxidizing agent 7-05 *

Tin (IV) chloride, anhydrous see TIN TETRACHLORIDE

TIN CHLORIDE, fuming see 8228 1827 8 II – 8-03 700

Tin (IV) chloride, pentahydrate see STANNIC CHLORIDE PENTAHYDRATE

TINCTURES, MEDICINAL • 3284 1293 3.2 II – 3-06 305

- ditto - • 3386 1293 3.3 III – 3-06 305

TIN MONOPHOSPHIDE see 4364 1433 4.3 I Toxic 4.3-02 205

TIN TETRACHLORIDE see 8228 1827 8 II – 8-03 700

TITANIC CHLORIDE see 8237 1838 8 II – 8-03 700

TITANIUM, SPONGE GRANULES 4177 2878 4.1 III – 4.1-02 none

TITANIUM, SPONGE POWDERS 4177 2878 4.1 III – 4.1-02 none

* See subsection 7.4 of the MFAG p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


PAGE UN No. CLASS

Pack-aging Group


MFAG Table No.

TITANIUM DISULPHIDE 4264-1 3174 4.2 III – 4.2-05 *

TITANIUM HYDRIDE 4176 18/1 4.1 II – 4.1-06 none

TITANIUM POWDER, DRY 4265 2546 4.2 I/II/III – 4.2-02 none

TITANIUM POWDER, WETTED with not less than 25% water (a visible excess of water must be present)

4176 1352 4.1 II – 4.1-02 none

(a) mechanically produced having a particle size less than 53 microns, or

(b) chemically produced having a particle size less than 840 microns

TITANIUM TETRACHLORIDE 8237 1838 8 II – 8-03 700

TITANIUM TRICHLORIDE, PYROPHORIC 4266 2441 4.2 I Corrosive 4.2-04 700

TITANIUM TRICHLORIDE MIXTURE non-pyrophoric

8238 2869 8 II/III – 8-06 700

TITANIUM TRICHLORIDE MIXTURE, PY-ROPHORIC 4266 2441 4.2 I Corrosive 4.2-04 700

TITANOUS CHLORIDE, PYROPHORIC see 4266 2441 4.2 I Corrosive 4.2-04 700

TNT, dry or wetted with less than 30% water, by mass 1144 0209 1.1 D – – 1-01 †

TNT, WETTED see 4181 1356 4.1 I – 4.1-01 335

TNT AND HEXANITROSTILBENE, MIX-TURE 1104 0388 1.1 D – – 1.01 †

TNT AND TRINITROBENZENE, MIXTURE 1104 0388 1.1 D – – 1.01 †

TNT, MIXTURE CONTAINING TRINITRO-BENZENE AND HEXANITROSTILBENE 1104 0389 1.1 D – — 1-01 †

Toe puffs nitrocellulose base see 4144 1 1353 4. 1 Ill – 4.1-06 610

* If an MFAG numbei is not supplied by the shipper, refer to subsection 4.2 of the MFAG. † Explosive substance or article, refer to subsection 7.3 of the MFAG.


GENERAL INDEX

BSTANCE or ARTICLE IMDG CODEPAGE

UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

TOLUENE 3285 1294 3.2 II – 3-07 310

TOLUENE DIISOCYANATE 6269 2078 6.1 II – 6.1-02 370

TOLUENE TRICHLORIDE see 8122 2226 8 II – 8-05 340

TOLUIDINES (ortho-, meta-, para- ), LIQUID orSOLID 6270 1708 6.1 II – 6.1-02 335

TOLUOL see 3285 1294 3.2 II – 3-07 310

2,4-TOLUYLENEDIAMINE, LIQUID 6270 1709 6.1 III – 6.1-02 335

2,4-TOLUYLENEDIAMINE, SOLID 6270 1709 6.1 III – 6.1-04 335

TOLUYLENE DIISOCYANATE see 6269 2078 6.1 II – 6.1-02 370

TOLYLENE DIISOCYANATE see 6269 2078 6.1 II – 6.1-02 370

TORPEDOES, LIQUID-FUELLED, with inerthead 1308 0450 1.3 J – – 1-03 *

TORPEDOES, LIQUID-FUELLED, with or with-out bursting charge 1308 0449 1.1 J – – 1-01 *

TORPEDOES with bursting charge 1306 0451 1.1 D – 1-01 •- ditto - 1305 0329 1.1 E – – 1-01 *

- ditto - 1307 0330 1.1 F – – 1-01 *

TOXIC LIQUID, CORROSIVE, INORGANIC,N.O.S. • 6270-2 3289 6.1 I/II Corrosive 6.1-02 †

TOXIC LIQUID, CORROSIVE, ORGANIC,N.O.S. • 6270-2 2927 6.1 I/II Corrosive 6.1-02 †

TOXIC LIQUID, FLAMMABLE, ORGANIC,N.O.S. • 6270-3 2929 6.1 I/II Flammable

liquid 6.1-01 †

TOXIC LIQUID, INORGANIC, N.O.S. • 6270-1 3287 6.1 I/II/III – 6.1-02 †

TOXIC LIQUID, ORGANIC, N.O.S. • 6270-1 2810 6.1 I/II/III – 6.1-02 †

TOXIC LIQUID, OXIDIZING, N.O.S. • 6270-4 3122 6.1 I/II Oxidizingagent 6.1-02 †

TOXIC LIQUID, WATER-REACTIVE, N.O.S. • 6270-5 3123 6.1 I/II Dangerouswhen wet 6.1-07 †

* Explosive substance or article, refer to subsection 7.3 of the MFAG.† If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX

BSTANCE or ARTICLE IMDG CODE PAGE

UN No. CLASS

Pack-aging Group


EmS No.

MFAG Table No.

TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. •

6270–7 3290 6.1 I/II Corrosive 6.1–04 *

TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. •

6270–7 2928 6.1 I/II Corrosive 6.1–04 *

TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. •

62708 2930 6.1 I/II Flammable solid 6.1–03 *

TOXIC SOLID, INORGANIC, N.O.S. • 6270–6 3288 6.1 I/II/III – 6.1–04 *

TOXIC SOLID, ORGANIC, N.O.S. • 62706 2811 6.1 I/II/III – 6.1–04 *

TOXIC SOLID, OXIDIZING, N.O.S. • 62704 3086 6.1 I/II Oxidizing agent 6.1–04 *

TOXIC SOLID, SELF–HEATING, N.O.S. • 6270–5 3124 6.1 I/II Spontaneously combustible 6.1–08 *

TOXIC SOLID, WATER–REACTIVE, N.O.S. •

6270–5 3125 6.1 I/II Dangerous when wet 6.1–07 +

TOXINS, EXTRACTED FROM LIVING SOURCES, N.O.S. •

6270–9 3172 6.1 I/II/III – 6.1–02 1

6.1–04 2 *

TRACERS FOR AMMUNITION 1309 0212 0306

1.3 G 1.4 G

– 1–03

1–04 † †

trans– This prefix is not taken into account in determining the alphabetical order of en-tries, see under the next part of the name shown in capital letters

TREMOLITE see 9024 2590 9 III – 6.1–04 none

Triadimefon see PHENOXY PESTICIDE

TRIALLYLAMINE 3387 2610 3.3 III Corrosive 3–02 320

TRIALLYL BORATE 6271 2609 6.1 III – 6.1–01 240

Triamiphos see ORGANOPHOSPHORUS PESTICIDE

TRIARYL PHOSPHATES, N.O.S. pp see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

TRIARYL PHOSPHATES, ISOPROPY-LATED p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

* If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. † Explosive substance or article, refer to subsection 7.3 of the MFAG. 1 For liquids. 2 For solids. p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

TRIAZINE PESTICIDE, LIQUID, FLAMMA-BLE, TOXIC, flashpoint less than 23° C c.c.•

3270 2764 3.2 I/II Toxic 3-03 530

TRIAZINE PESTICIDE, LIQUID, TOXIC • 6219 2998 6.1 I/II/III – 6.1-02 530

TRIAZINE PESTICIDE, LIQUID, TOXIC,FLAMMABLE, flashpoint between 23° and61° C c.c. •


TRIAZINE PESTICIDE, SOLID, TOXIC • 6221 2763 6.1 I/II/III – 6.1-04 530

Triazophos p see ORGANOPHOSPHORUS PESTICIDE

TRIBROMOBORANE see 8127 2692 8 I – 8-03 245

TRIBROMOMETHANE p see 6088 2515 6.1 III – 6.1-02 345

TRIBUTYLALUMlNIUM see 4221 3051 4.2 I – 4.2-01 170

TRIBUTYLAMINE 6271 2542 6.1 II – 6.1-02 320

TRIBUTYLPHOSPHANE 4266-1 3254 4.2 I – 4.2-04 760

Tributyltin compounds p p see ORGANOTIN PESTICIDE

Tricamba see BENZOIC DERIVATIVE PESTICIDE

Trichlorfon p see ORGANOPHOSPHORUS PESTICIDE

TRICHLOROACETALDEHYDE, ANHY-DROUS, INHIBITED see 6097 2075 6.1 II – 6.1-02 300

TRICHLOROACETIC ACID, SOLID 8239 1839 8 II – 8-06 700

TRICHLOROACETIC ACID, SOLUTION 8239 2564 8 II/III – 8-06 700

TRICHLOROACETIC ALDEHYDE, ANHY-DROUS, INHIBITED see 6097 2075 6.1 II – 6.1-02 300

TRICHLOROACETYL CHLORIDE 8240 2442 8 II – 8-02 700

TRICHLOROBENZENES, LIQUID p 6271-1 2321 6.1 III – 6.1-02 340

TRICHLOROBUTENE p 6272 2322 6.1 II – 6.1-02 340

TRICHLOROBUTYLENE p see 6272 2322 6.1 II – 6.1-02 340



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

1,1,1-TRICHLOROETHANE 6272-1 2831 6 1 III – 6.1-02 340

1,1,2-TRICHLOROETHANE see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

TRICHLOROETHYLENE 6273 1710 6.1 III – 6.1-02 340

TRICHLOROISOCYANURIC ACID, DRY 5190 2468 5.1 II 5.1-05 740

TRICHLOROMETHANE see 6103 1888 6.1 III – 6.1-02 340

TRICHLOROMETHANESULPHURYLCHLORIDE p see 6218 1670 6.1 I – 6.1 02 376

TRICHLOROMETHYL SULPHOCHLORIDE p see 6218 1670 6.1 I – 6.1 02 376

Trichloronat p see ORGANOPHOSPHORUS PESTICIDE

TRICHLORONITROMETHANE see 6108 1580 6.1 I – 6.1-02 740

TRICHLOROSILANE 4365-1 1295 4.3 ICorrosiveFlammable

liquid4.3-05 700

2,4,6-TRICHLORO-1,3,5-TRIAZINE see 8155 26/-0 8 II – 8-06 740

1,3,5-TRICHLORO-s-TRIAZINE 2,4,6-TRIONE see 5190 2468 5.1 II – 5.1-05 740

TRICRESYL PHOSPHATE, less than 1%ortho-isomer p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

TRICRESYL PHOSPHATE, not less than 1%but not more than 3% ortho-isomer pp see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

TRICRESYL PHOSPHATE with more than3% ortho-isomer p p 6274 2574 6.1 II – 6.1-02 355

TRICYANOGEN CHLORIDE see 8155 2670 8 II – 8-06 740

TRIETHOXYBORON see 3222 1176 3.2 II – 3-06 240

TRIETHOXYM ETHANE see 3344 2524 3.3 III – 3-07 330

TRIETHYLALUMINIUM see 4221 3051 4.2 I Dangerouswhen wet 4.2-01 170

TRIETHYLAMINE 3285 1296 3.2 || Corrosive 3-02 320



GENERAL INDEX

BSTANCE or ARTICLEIMDG CODE

PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

TRIETHYLBENZENE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

TRIETHYL BORATE see 3222 1176 3.2 II – 3-06 240

TRIETHYLENEPHOSPHORAMIDE, SOLU-TION

see 6276 2501 6.1 II/III – 6.1-02 205

TRIETHYLENETETRAMINE 8240 2259 8 II – 8-05 320

TRIETHYL ORTHOFORMATE see 3344 2524 3.3 III – 3-07 330

TRIETHYL PHOSPHITE 3387 2323 3.3 III – 3-07 330

TRIFLUOROACETIC ACID 8241 2699 8 I – 8-05 750

TRIFLUOROACETYL CHLORIDE 2183 3057 2(2.3) – Corrosive 2-08 700

TRIFLUOROBROMOMETHANE see 2109 1009 2(2.2) – – 2-09 350

TRIFLUOROCHLOROETHANE see 2121 1983 2(2.2) – – 2-09 350

TRIFLUOROCHLOROETHYLENE, INHIB-ITED

2183 1082 2(2.3) – Flammablegas

2-07 350

TRIFLUOROCHLOROMETHANE see 2122 1022 2(2.2) – – 2-09 350

1,1,1-TRIFLUOROETHANE 2184 2035 2(2.1) – – 2-07 350

TRIFLUOROMETHANE 2184 1984 2(2.2) – – 2-09 350

TRIFLUOROMETHANE, REFRIGERATEDLIQUID 2184-1 3136 2(2.2) – – 2-12 620

TRIFLUOROMETHANE AND CHLOROTR I-FLUOROMETHANE, AZEOTROPIC MIX-TURE

see CHLOROTRIFLUOROMETHANE AND TRIFLUOROMETHANE, AZEO-TROPIC MIXTURE

TRIFLUOROMETHOXY-TRIFLUOROETHYLENE see 2171 3153 2(2.1) – – 2-07 620,

615

2-TRIFLUOROMETHYLANILINE 6275 2942 6.1 Ill – 6.1-02 335

3-TRIFLUOROMETHYLANILINE 6275 2948 6.1 II – 6.1-02 335

TRIFLUOROMETHYLBENZENE see 3185 2338 3.2 II – 3-07 345

TRIFLUOROMETHYLPHENYL ISOCYA-NATES

see 6168 2285 6.1 II Flammableliquid *

6.1-01 *6.1-02 †

370

* If flashpoint 61° C c.c. or below.† If flashpoint higher than 61° C c.c.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


EmSNo.

MFAGTableNo.

TRIFLUOROMETHYL TRIFLUOROVINYLETHER see 2171 3153 2(2.1) – – 2-07 620,

615

TRIFLUOROMONOCHLOROETHYLENE,INHIBITED see 2183 1082 2(2.3) – Flammable

gas 2-07 350

TRIISOBUTYLALUMINIUM see 4221 3051 4.2 I Dangerouswhen wet 4.2-01 170

TRIISOBUTYLENE 3388 2324 3.3 III – 3-07 310

TRIISOPROPYLATED PHENYL, PHOS-PHATES p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

TRIISOPROPYL BORATE 3286 2616 3.2 II – 3-06 240

- ditto - 3389 2616 3.3 III – 3-06 240

TRIMETHYLACETYL CHLORIDE 6275-1 2438 6.1 IFlammable

liquid, Corro-sive

6.1-01 700

TRIMETHYLALUMINIUM see 4221 3051 4.2 I Dangerouswhen wet 4.2-01 170

TRIMETHYLAMINE, ANHYDROUS 2185 1083 2(2.1) – – 2-06 320

TRIMETHYLAMINE, AQUEOUS SOLU-TION, not more than 30% trimethylamine,by mass

3286 1297 3.2 I/II Corrosive 3-02 320

- ditto - 3389-1 1297 3.3 III Corrosive 3-02 320

TRIMETHYLAMINE, AQUEOUS SOLU-TION, 30% to 50% trimethylamine, by mass 3145 1297 3.1 I/II Corrosive 3-02 320

1,2,3-TRIMETHYLBENZENE p see Section 23.1.5 of the General Introduction

1,2,4-TRIMETHYLBENZENE p see Section 23.1.5 of the General Introduction

1,3,5-TRIMETHYLBENZENE p 3389-1 2325 3.3 III – 3-03 310

TRIMETHYL BORATE 3287 2416 3.2 II – 3-06 240

TRIMETHYL CARBINOL see 3191 1120 3.2 II – 3-06 305

TRIMETHYLCHLOROSILANE 3145 1298 3.1 II Corrosive 3-04 700

TRIMETHYLCYCLOHEXYLAMINE 8242 2326 8 III – 8-05 320

TRIMETHYLENE CHLOROBROMIDE see 6102 2688 6.1 III – 6.1-02 345



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

TRIMETHYLENE CHLOROHYDRIN see 6110 2849 6.1 III – 6.1-02 740

TRIMETHYLENE DICHLORIDE * see 3230 1993 3.2 II – 3-07 340

- ditto - † see 3345 1993 3.3 III – 3-07 340

TRIMETHYLHEXAMETHYLENEDIAMINES 8243 2327 8 III – 8-05 320

TRIMETHYLHEXAMETHYLENE DIISO-CYANATE 6276 2328 6.1 III – 6.1-02 370

2,2,4-TRIMETHYLPENTANE see 3267 1262 3.2 II – 3-07 310

2,4,4-TRIMETHYLPENTENE-1 see 3210 2050 3.2 II – 3-07 310

2,4,4-TRIMETHYLPENTENE-2 see 3210 2050 3.2 II – 3-07 310

2,4,4-TRIMETHYLPENTYL-2-PEROXYNEODECANOATE (concentration-72%, with diluent type A)

see ORGANIC PEROXIDE, TYPE D, LIQUID, TEMPERATURE CONTROLLED

2,4,4-TRIMETHYLPENTYL-2-PEROXYNEODECANOATE (concentration-52% as a stable dispersion in water)

see ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED

2,4,4-TRIMETHYLPENTYL-2-PEROXYPHENOXYACETATE (concentra-tion -37%, with diluent type B)


TRIMETHYL PHOSPHITE 3390 2329 3.3 III – 3-07 330

2,4,6-TRIMETHYL-1,3,5-TRIOXANE see 3372 1264 3.3 III – 3-06 300

TRINITROANILINE 1104 0153 1.1 D – – 1-01 ‡

TRINITROANISOLE 1104 0213 1.1 D – – 1-01 ‡

TRINITROBENZENE, dry or wetted withless than 30% water, by mass 1104 0214 1.1 D – – 1-01 ‡

TRINITROBENZENE, WETTED with notless than 30% water, by mass 4178 1354 4.1 I – 4.1-01 335

TRINITROBENZENESULPHONIC ACID 1104 0386 1.1 D – – 1-01 700, ‡

* TRIMETHYLENE DICHLORIDE (1,3-DICHLOROPROPANE) under a flashpoint of less than 23° C should be shippedunder the entry FLAMMABLE LIQUID, N.O.S.in class 3.2.

† TRIMETHYLENE DICHLORIDE (1,3-DICHLOROPROPANE) with a flashpoint of 23° C or higher should be shippedunder the entry FLAMMABLE LIQUID, N.O.S.in class 3.3.

‡ Explosive substance or article, refer to subsection 7.3 of the MFAG.


GENERAL INDEX

BSTANCE or ARTICLE IMDG CODE

PAGE UN No. CLASS

Pack-aging Group


MFAG Table No.

TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass

1142 0215 1.1 D – – 1-01 335, 700 *

TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass 4179 1355 4.1 I – 4.1-01 335,

700

TRINITROCHLOROBENZENE 1104 0155 1.1 D – – 1-01 *

TRINITRO-meta-CRESOL 1109 0216 1.1 D – – 1-01 *

TRINITROFLUORENONE 1104 0387 1.1 D – – 1 01 *

TRINITRONAPHTHALENE 1104 0217 1.1 D – – 1-01 *

TRINITROPHENETOLE 1104 0218 1.1 D – – 1-01 *

TRINITROPHENOL, dry or wetted with less than 30% water, by mass

1109 0154 1.1 D – – 1 01 *

TRINITROPHENOL, WETTED with not less than 30% water, by mass 4180 1344 4.1 I – 4.1-01 710

TRINITROPHENYLMETHYLNITRAMINE 1112 0208 1.1 D – – 1-01 *

TRINITRORESORCINOL, dry or wetted with less than 20% water or mixture of alco-hol and water , by mass

1109 0219 1.1 D – – 1-01 *

TRINITRORESORCINOL, WETTED with not less than 20% water or mixture of alco-hol and water, by mass

1143 0394 1.1 D – – 1-01 *

TRINITROTOLUENE, dry or wetted with less than 30% water, by mass 1144 0209 1.1 D – – 1-01 *

TRINITROTOLUENE, WETTED with not less than 30% water, by mass 4181 1356 4.1 I – 4.1-01 335

TRINITROTOLUENE AND HEXANI-TROSTILBENE MIXTURES

1104 0388 1.1 D – – 1-01 *

TRINITROTOLUENE AND TRINITROBEN-ZENE MIXTURES 1104 0388 1.1 D – – 1-01 *

TRINITROTOLUENE MIXTURES, CON-TAINING TRINITROBENZENE AND HEX-ANITROSTILBENE

1104 0389 1.1 D – – 1-01 *



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

TRINITROTOLUOL, WETTED see 4181 1356 4.1 I – 4.1-01 335

Triphenyltin compounds pp (other than fentinacetate and fentin hydroxide) see ORGANOTIN PESTICIDE

TRIPHENYL PHOSPHATE pp see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

TRIPHENYL PHOSPHATE/tert-BUTYLATED TRIPHENYL PHOSPHATES,MIXTURES containing 5 to 10% of TRI-PHENYL PHOSPHATE p

see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

TRIPHENYL PHOSPHATE/tert-BUTYLATED TRIPHENYL PHOSPHATES,MIXTURES containing 10 to 48% of TRI-PHENYL PHOSPHATE p p

see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

TRIPROPYLALUMINIUM see 4221 3051 4.2 I Dangerouswhen wet 4.2-01 170

TRIPROPYLAMINE 3390 2260 3.3 III Corrosive 3-02 320

TRIPROPYLENE 3287 2057 3.2 II – 3-07 310

- ditto - 3391 2057 3.3 III – 3-07 310

TRIS-(1-AZIRIDINYL)PHOSPHINE OXIDE,SOLUTION 6276 2501 6.1 II/III – 6.1-02 205

TRITOLYL PHOSPHATE pp see 6274 2574 6.1 II – 6.1-02 355

TRITONAL 1104 0390 1.1 D – – 1-01 *

TRIXYLENYL PHOSPHATE p see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

TROPILIDENE see 3202 2603 3.2 II Toxic 3-03 310

TUNGSTEN HEXAFLUORIDE 2185 2196 2(2.3) – Corrosive 2-08 750

TURPENTINE p 3391 1299 3.3 Ill – 3-07 313

TURPENTINE SUBSTITUTE † 3271 1300 3.2 II – 3-07 311

- ditto - † 3375 1300 3.3 III – 3-07 311

* Explosive substance or article, refer to subsection 7.3 of the MFAG.† WHITE SPIRIT, low aromatic (15%-20%) is a MARINE POLLUTANTp, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

normaI-VALERALDEHYDE p see 3288 2058 3.2 II – 3-06 300

VALERALDEHYDES 3288 2058 3.2 II – 3-06 300

VALERIC ALDEHYDES see 3288 2058 3.2 II – 3-06 300

normal-VALERYL CHLORIDE 8244 2502 8 II Flammableliquid * 8-01 700

Vamidothion see ORGANOPHOSPHORUS PESTICIDE

VANADIUM COMPOUND, N.O.S. • 6276-1 3285 6.1 I/II/III – 6.1-02 16.1-04 2 135

Vanadium ore MATERIAL HAZARDOUS ONLY IN BULK †

Vanadium (IV) oxide sulphate see VANADIUM SULPHATE

VANADIUM OXYSULPHATE see 6278 2931 6.1 II – 6.1-04 135,700

VANADIUM OXYTRICHLORIDE 8244 2443 8 II – 8-03 135

VANADIUM PENTOXIDE, non-fused form 6277 2862 6.1 III – 6.1-04 135

VANADIUM TETRACHLORIDE 8245 2444 8 I – 8-03 135,700

VANADIUM TRICHLORIDE 8246 2475 8 III – 8-06 135,700

VANADYL SULPHATE 6278 2931 6.1 II – 6.1-04 135,700

Varnish see PAINT – – – – – –

VEGETABLE FABRICS, oily • see 4233 1373 4.2 III – 4.2-05 none

VEGETABLE FIBRES, burnt, wet or damp see 4233 – 4.2 III – 4.2-05 none

VEGETABLE FIBRES, DRY see 4144 – 4.1‡ – – 4.1-06 none

VEGETABLE FIBRES, oily • see 4233 1373 4.2 Ill – 4.2-05 none

VINYL ACETATE, INHIBITED 3289 1301 3.2 II – 3-07 330

VINYLBENZENE, INHIBITED p see 3381 2055 3.3 III – 3-07 310

* If flashpoint between 23°C and 61° C c.c.† See section 24 of the General Introduction.‡ No label required.1 For liquids.2 For solids.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX

BSTANCE or ARTICLE IMDG CODE

PAGE UN No. CLASS

Pack-aging Group


MFAG Table No.

VINYL BROMIDE, INHIBITED 2186 1085 2(2.1) – – 2-07 345

VINYL normaI-BUTYL ETHER, INHIBITED see 3196 2352 3.2 II – 3-06 330

VINYL BUTYRATE, INHIBITED 3289 2838 3.2 II – 307 330

VINYL CHLORIDE, INHIBITED 2186 1086 2(2.1) – – 2-07 340

VINYL CHLORIDE, STABILIZED 2186 1086 2(2.1) – – 2-07 340

VINYL CHLOROACETATE 6278 2589 6.1 II Flammable liquid 6.1-01 540

VINYL CYANIDE, INHIBITED see 3173 1093 3.2 I Toxic 3-02 215

VINYL ETHER, INHIBITED see 3120 1167 3.1 I – 3-02 330

VINYL ETHYL ETHER, INHIBITED 3146 1302 3.1 I – 3-07 330

VINYL FLUORIDE, INHIBITED 2187 1860 2(2.1) – – 2-07 350

VINYLIDENE CHLORIDE, INHIBITED p 3146 1303 3.1 I – 3-07 340

VINYLIDENE FLUORIDE see 2132 1959 2(2.1) – – 2-07 350

VINYL ISOBUTYL ETHER, INHIBITED 3290 1304 3.2 II – 3-06 330

VINYL METHYL ETHER, INHIBITED 2187 1087 2(2.1) – – 2-07 330

VINYLPYRIDINES, INHIBITED 6279 3073 6.1 II Flammable liquid Corro-

sive 6.1-01 325

VINYLTOLUENES, INHIBITED (ortho-, meta-, para-) p

3392 2618 3.3 III – 3-02 310

VINYLTRICHLOROSILANE, INHIBITED 3290 1305 3.2 I Corrosive 3-04 700



GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

Warfarin (and salts of) p see COUMARIN DERIVATIVE PESTICIDE

WARHEADS, ROCKET, with burster or ex-pelling charge 1312 0370 1.4 D – – 1-04 *

- ditto - 1313 0371 1.4 F – – 1-04

WARHEADS, ROCKET, with bursting charge 1310 02860287

1.1 D1.2 D – – 1-01

1-02 *

- ditto - 1311 0369 1.1 F – – 1-01 *

WARHEADS, TORPEDO, with burstingcharge 1314 0221 1.1 D – – 1-01 *

Warheads for guided missiles see WARHEADS, ROCKET

WATER-ACTIVATED CONTRIVANCES see CONTRIVANCES, WATER-ACTIVATED

WATER GAS, COMPRESSED see 2114 2600 2(2.3) – Flammablegas 2-01 616

Water gels see EXPLOSIVE, BLASTING, TYPE E

WATER-REACTIVE LIQUID, N.O.S. • 4366 3148 4.3 I/II/III – 4.3-08 †

WATER-REACTIVE LIQUID, CORROSIVE,N.O.S. • 4367 3129 4.3 I/II/III Corrosive 4.3-08 760 ‡

WATER-REACTIVE LIQUID, TOXIC,N.O.S. • 4367 3130 4.3 I/II/III Toxic 4.3-08 †

WATER REACTIVE SOLID, N.O.S.• 4368 2813 4.3 I/II/III – 4.3-08 †

WATER-REACTIVE SOLID, CORROSIVE,N.O.S. • 4369 3131 4.3 I/II/III Corrosive 4.3-08 760 ‡

WATER-REACTIVE SOLID, FLAMMABLE,N.O.S. • 4369 3132 4.3 I/II/III Flammable

solid 4.3-08 †

WATER-REACTIVE SOLID, TOXIC, N.O.S.• 4369 3134 4.3 I/II/III Toxic 4.3-08 †

WHITE ARSENIC see 6078 1561 6.1 II – 6.1-04 100

WHITE ASBESTOS see 9024 2590 9 III – 6.1-04 none

WHITE PHOSPHORUS, DRY pp see 4249 1381 4.2 I Toxic 4.2-04 200

* Explosive substance or article, refer to subsection 7.3 of the MFAG.† If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.‡ In addition, refer to subsection 4.3 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

WHITE PHOSPHORUS, WET pp see 4250 1381 4.2 I Toxic 4.2-04 200

WHITE SPIRIT * see 3271 1300 3.2 II 3-07 311

- ditto - see 3375 1300 3.3 III – 3-07 311

Woodchips MATERIAL HAZARDOUS ONLY IN BULK †

WOOD PRESERVATIVES, LIQUID • 3291 1306 3.2 II 3-05 310, ‡

- ditto - • 3393 1306 3.3 III – 3-05 310, ‡

Wood pulp, pellets MATERIAL HAZARDOUS ONLY IN BULK †

WOOL WASTE, WET 4264 - 4.2 III – 4.2-05 none

* WHITE SPIRIT, low aromatic (15%-20%) is a MARINE POLLUTANT .† See section 24 of the General Introduction.‡ In addition, refer to subsection 4.3 of the MFAG.p, pp or • see explanatory notes in the introduction to this index.


GENERAL INDEX


UNNo. CLASS

Pack-agingGroup


MFAGTableNo.

XANTHATES 4266-2 3342 4.2 II/III – 4.2-04 •XENON, COMPRESSED 2188 2036 2(2.2) – – 2-09 none

XENON, REFRIGERATED LIQUID 2188 2591 2(2.2) – – 2-12 350

Xenon and nitrogen mixtures see RARE GASES AND NITROGEN MIXTURES

Xenon and oxygen mixture see RARE GASES AND OXYGEN MIXTURE

Xenon in rare gases mixtures see RARE GASES MIXTURES

meta-XYLENE see 3394 1307 3.3 Ill – 3-07 310

ortho-XYLENE see 3292 1307 3.2 II – 3-07 310

para-XYLENE see 3394 1307 3.3 III – 3-07 310

XYLENES 3292 1307 3.2 II – 3-07 310

- ditto - 3394 1307 3.3 III – 3-07 310

XYLENOLS, LIQUID p 6280 2261 6.1 II – 6.1-02 710

XYLENOLS, SOLID p 6280 2261 6.1 II – 6.1-04 710

XYLIDINES, SOLID or LIQUID 6280 1711 6.1 II – 6.1-02 335

XYLOLS see 3292 1307 3.2 II – 3-07 310

- ditto - see 3394 1307 3.3 III – 3-07 310

XYLYL BROMIDE 6281 1701 6.1 II – 6.1-02 345

YELLOW PHOSPHORUS, DRY pp see 4249 1381 4.2 I Toxic 4.2-04 200

YELLOW PHOSPHORUS, WET pp see 4250 1381 4.2 I Toxic 4.2-04 200

* If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.



GENERAL INDEX


PAGEUNNo. CLASS

Pack-agingGroup


MFAGTableNo.

ZINC, dust see ZINC DUST

ZINC, powder see ZINC POWDER

ZINC AMMONIUM NITRITE - 1512 CARRIAGE PROHIBITED

ZINC ARSENATE 6282 1712 6.1 II – 6.1-04 100

ZINC ARSENATE AND ZINC ARSENITEMIXTURE 6282 1712 6.1 II – 6.1 04 100

ZINC ARSENITE 6282 1712 6.1 II – 6.1 04 100

ZINC ASHES 4371 1435 4.3 III – 4.3-06 none

ZINC BISULPHITE, SOLUTION see 8126 2693 8 III – 8-08 635

ZINC BROMATE 5192 2469 5.1 III – 5.1-06 745

ZINC BROMIDE p see ENVIRONMENTALLY HAZARDOUS, SUBSTANCE, SOLID, N.O.S.

ZINC CHLORATE 5192 1513 5.1 II – 5.1-06 745

ZINC CHLORIDE, ANHYDROUS 8247 2331 8 III – 8-06 145

ZINC CHLORIDE, SOLUTION 8247 1840 8 III – 8-06 145

ZINC CYANIDE p 6282 1713 6.1 I – 6.1-04 215

ZINC DIETHYL see 4230 1366 4.2 I Dangerouswhen wet

4.2-01 170

ZINC DIMETHYL see 4231 1370 4..2 I Dangerouswhen wet

4.2-01 170

ZINC DITHIONITE 9037 1931 9 III – 4.2-04 635

ZINC DROSS 4371 1435 4.3 III – 4.3-06 none

ZINC DUST, non-pyrophoric 4373 1436 4.3 II/III Spontaneouslycombustible

4.3-06 none

ZINC DUST, PYROPHORIC see 4255 1383 4.2 I – 4.2-02 none

ZINC ETHYL see 4230 1366 4.2 I Dangerouswhen wet

4.2-01 170



UN Nos. / IMDG CODE PAGE Nos. / EmS Nos. / MFAG TABLE Nos.

UN No. ... 0 ... 1 ... 2 ... 3 ... 4 ... 5 ... 6 ... 7 ... 8 ... 9

110... 3105-1, 3-03, 340 ⁄ ⁄ ⁄ 3307,

3-07, 330

32691, 3373-1, 3-06, 3-05

3183, 3308, 3-02, 320

3183, 3-07, 340

3140, 3-07, 310

3309, 3-07, 330

111... 3310, 3-07, 300

3184, 3-07, 375

3310, 3-07, 235

3107, 3184, 3-07, 235

3185, 3-03, 312 ⁄ ⁄ ⁄ ⁄ ⁄

112...

3191, 3314, 3-06, 3-05

⁄ ⁄ 3191, 3314, 3-07, 330

⁄ 3192, 3-02, 320

3187, 3-07, 345

3110, 3198, 3-07, 340

3193, 3-06, 330

3196, 3-07, 300

113... 3318, 3-07, 331

3109, 3-01, 210 ⁄

3102, 3174, 3302, 3-05, 330

3318, 3-07, 340

6150, 6.1-01,

740

3200, 3321, 3-07, 310

⁄ ⁄ 3112, 3200, 3321, 3-05, 310

114... ⁄ ⁄ ⁄ 6114-1, 6.1-01,

300

3113, 3-07, 310

3114, 3-07, 310

3115, 3-07, 310

3326, 3-07, 310

3203-1, 3327, 3-06, 3-05

3328, 3-07, 330

115... 3205, 3-07, 340 ⁄ 3329,

3-07, 340

3340, 3-07, 330

3116, 3-02, 320

3117, 3-07, 330

3208, 3-07, 300

3333, 3-07, 300

3210, 3-02, 320

3117, 3-02, 330

116...

3118, 3212, 3-02, 320

3213, 3-07, 330

3214, 3-04, 700

6132, 6.1-01,

720

3119, 3-07, 225

3217, 3-06, 330

3217, 3-06, 330

3120, 3-02, 330 ⁄

3229, 3344, 3-06, 3-05

117...

3219, 3337-1, 3-06, 3-05*

3341, 3-06, 330

3341, 3-06, 330

3220, 3-07, 330 ⁄ 3222,

3-07, 310

3222, 3-06, 240

3339, 3-07, 330

3223, 3-07, 300

3223, 3-07, 330

118... 3339, 3-07, 330

6147, 6.1-01,

540

6148, 6.1-01,

740

4342, 4.3-05,

700

3224, 3-03, 340

6151, 6.1-01,

320 ⁄ ⁄ 3342, 3-06, 330

3342, 3-06, 330

119... 3123, 3-07, 330

3343, 3-07, 300

3343-1, 3-06, 330

3226, 3-06, 300

3124, 3227, 3-02, 235

3228, 3-07, 330

3228, 3-04, 700

3229, 3344, 3-06, 3-05

3347, 3-06, 300

6155, 6.1-01,

300

NOTE: * 305-306 for ALCOHOL DENATURED for ALCOHOL INDUSTRIAL and for METHYLATED SPIRITS


UN No.

...0 ...1 ...2 ...3 ...4 ...5 ...6 ...7 ...8 ...9

120... ⁄ 3234, 3348, 3-06, 3-05

3375, 3-07, 311

3141, 3-07, 311

3265-2, 3-06, 235

⁄ 3235, 3-07, 310

3350, 3-07, 300

3129, 3-07, 310

⁄

121...

3141-1, 3272-1, 3377-1, 3-05, 311

⁄ 3354, 3-06, 3-05

3239, 3-07, 330

3239, 3-02, 320

⁄ 3243, 3-07, 310

⁄ 3133, 3-07, 310

3244, 3-06, 3-05

122... 3245, 3-07, 330

3133, 3-02, 320

3247, 3-07, 235

3375, 3-07, 311

3248, 3360, 3-07, 300

⁄ ⁄ ⁄ 3135, 3249, 3361, 3-03*, 375

3362, 3-06, 300

123... 3251, 3-06, 3-06

3252, 3-06, 330

⁄ 3364, 3-07, 330

3136, 3-06, 330

3253, 3-02, 320

⁄ 3255, 3-07, 330

6193, 61-01,

740

6194, 61-01,

340

124... ⁄ ⁄ 4355, 43-05,

700

3137, 3-06, 330

6196, 61-01,

720

3257, 3-07, 300

3258, 3-07, 300

3259, 3-07, 330

3261, 3-07, 330

3261, 3-07, 300

125. 3262, 3-04, 700

6198-2, 61-01,

300 ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄

6202, 6,

1-01, 165

126... ⁄ 3370, 3-06, 335

3267, 3-07, 310

3139, 3268, 3372, 3-05, 310, 313

3372, 3-06, 300

3140, 3-07, 310

3269, 3374, 3-05, 3-05

3141.3271, 3375, 3-07, 311

3141, 3271, 3375, 3-07, 311

⁄

127... ⁄ ⁄ 3377, 3-07, 313

⁄ 3272-1, 3377-2, 3-06, 3-05

3142, 1,

3-06, 300

3274, 3-07, 330

3143, 3-02, 320

3111, 3-07, 340

3206, 3-07, 340

128... 3143, 3-06, 365

3275, 3-06, 330

3277, 3-02, 325

⁄ ⁄ ⁄ 3278, 3380, 3-07, 310

3279, 3380, 3-05, 310

3271,3375, 3-07, 311

3280, 3381, 3-04, 3-06, 705

129... ⁄ ⁄ 3384, 3-06, 360

3284, 3386, 3-06, 3-05

3285, 3-07, 310

4365-1, 43-05,

700

3285, 3-02, 320

3145, 3286,

3389-1, 3-02, 320

3145, 3-04, 700

3391, 3-07, 313

NOTE: * 3-07 for class 3.3


UN No. ...0 ...1 ...2 ...3 ...4 ...5 ...6 ...7 ...8 ...9

130…

3271, 3375, 3-07, 311

3289, 3-07, 330

3146, 3-07, 330

3146, 3-07, 340

3290, 3-06, 330

3290, 3-04, 700

3291, 3393, 3-05, 310*

3292, 3394, 3-07, 310

3147, 3293, 3395, 3-07, 310*

4121, 4.1-02, none

131… 4122,

4.1-01, 710

⁄ 4130, 4.1-06, 3-05

4132, 4.1-06,

705

4132, 4.1-06,

705 ⁄ ⁄ ⁄ 4135,

4.1-06, none

⁄

132… 4140,

4.1-01, 710

4139, 4.1-01,

710

4141, 4.1-01,

710

4144, 4.1-06, none

4145, 4.1-06,

610

4146, 4.1-05†

4148, 4.1-02, none

4149, 4.1-06, none

4150, 4.1-06,

320 ⁄

133… 4153,

4.1-06, none

4155, 4.1-06,

200

4157, 4.1-03,

300

4133, 4.1-06, none

4158, 4.1-05,

314 ⁄ 4162,

4.1-01, 610

4163-1, 4.1-01,

610

4165, 4.1-06, none

4165, 4.1-03,

225

134… 4355-3, 4.3-03,

225

4166, 4.1-03,

225 ⁄ 4166,

4.1-03, 225

4180, 4.1-01,

710

4167, 4.1-06, none

4170, 4.1-02, none

4170, 4.1-01,

710

4172, 4.1-01,

710

4173, 4.1-01,

710

135… 4174,

4.1-06, none

⁄ 4176, 4.1-02, none

4144-1, 4.1-06,

610

4178, 4.1-01,

335

4179, 4.1-01,

335, 700

4181, 4.1-01,

335

4182, 4.1-01,

610

4184, 4.1-02, none

⁄

136… 4338,

4.3-02, 205

4224, 4.2-05, none

4224, 4.2-05, none

4227, 4.2-05, none

4228, 4.2-05, none

4229, 4.2-05, none

4230, 4.2-01,

170 ⁄ ⁄ 4247,

4.2-04, 335

137… 4231,

4.2-01, 170

⁄ ⁄ 4233, 4.2-05, none

4234,4235, 4.2-05, none

⁄ 4238, 4.2-04, none

⁄ 4246, 4.2-05, none

4248, 4.2-05, none

138… 4248-1, 4.2-01,

245

4249, 4250,

4.2-04, 200

4253, 4.2-04,

225

4255, 4.2-02, 760*

4262, 4.2-04, 635,700

4263, 4.2-04,

225, 705

4257, 4258,

4.2-05, none

⁄ ⁄ 4322, 4.3-04,

705

139… 4323,

4.3-05, 705

4324, 4.3-01,

705

4326, 4.3-04,

705

4325, 4.3-04,

705

4327, 4.3-03, none

4327, 4.3-03,

605, 601

4330, 4.3-06, none

4329, 4.3-02,

205

4331, 4.3-03, none

⁄ NOTES: * In addition, refer to subsection 4.3 of the MFAG. † If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.


UN No.

…0 …1 …2 …3 …4 …5 …6 …7 …8 …9

140… 4332,

4.3-04, 120

4335, 4.3-04,

705

4335, 4.3-03,

705

4336, 4.3-03,

705

4337, 4.3-04,

705

4339, 4.3-03,

705 ⁄ 4334,

4.3-01, 705

4343, 4.3-03,

601, 605

4354-1, 4.3-01, 760*

141… 43451, 4.3-01,

160

4346, 4.3-01,

160, 330

⁄ 4347, 4.3-04,

245

4348, 4.3-01,

160

4345, 4.3-01,

160 ⁄ 4349,

4.3-03, 160

4353, 4.3-06, none

4350, 4.3-02,

205

142… 4356,

4.3-01, 705

4321, 4.3-01,

705

4356, 4.3-01,

705

4359, 4.3-01,

705 ⁄ ⁄ 4361,

4.3-04, 245

4362, 4.3-01,

705

4360, 4.3-01,

705 ⁄

143… ⁄ 4263, 42-08,

705

4363, 4.3-02,

205

4364, 4.3-02,

205 ⁄ 4371,

4.3-06, none

4373, 4.3-06, none

4185, 4.1-06, none

5121, 5.1-06,

235

5121, 5.1-06,

155

144… ⁄ ⁄ 5126, 5.1-09,

745 ⁄ 5126,

5.1-06, 725

5127, 5.1-05†,

120, 745

5128, 5.1-05,

120

5129, 5.1-05†,

120, 745

5129, 5.1-05,

715

5130, 5.1-04,

120, 735

145… 5131,

5.1-05, 745

5134, 5.1-06, none

5134, 5.1-06,

745

5136, 5.1-06,

741

5139, 5.1-06,

235

5139, 5.1-06,

745

5140, 5.1-06,

715

5140, 5.1-04,

735

5141, 5.1-06,

745

5141, 5.1-06,

745

146… ⁄ 5142, 5.1-05,

745

5144, 5.1-05,

741

5145, 5.1-05,

700 ⁄ 5147,

5.1-06, none

5148, 5.1-06,

700

5148, 5.1-06,

235 ⁄ 5154,

5.1-05, 110

147…

5155, 5.1-05†,

110, 745

5156, 5.1-06,

160, 741

5157, 5.1-04,

160, 735

5158, 5.1-06,

745

5159, 5.1-06,

235

5159, 5.1-06

745

5160, 5.1-04,

735

5162, 5.1-05,

235 ⁄ 5163,

5111, 760*

148… ⁄ 5166, 5.1-05,

745

5167-1, 5.1-05,

715

5168, 5.1-04,

735

5169, 5.1-06,

745

5169, 5.1-06,

745

5171, 5.1-06,

235

5171, 5.1-06,

235

5172, 5.1-06,

235

5172, 5.1-06,

745

149… 5173,

5.1-06, 715

5174, 5.1-04,

735

5175, 5.1-06,

700

5177, 5.1-06,

235

5178, 5.1-06,

745

5178, 5.1-06,

745

5180, 5.1-06,

741 ⁄ 5180,

5.1-06, 235

5181, 5.1-06,

235

NOTES: * In addition, refer to subsection 4.3 of the MFAG. † 5.1-02 for SOLUTIONS


UN No.

…0 …1 …2 …3 …4 …5 …6 …7 …8 …9

170… 6261,

6.1-03, 740

6281, 6.1-02,

345

6263, 6.1-02,

340 *

6264, 6.1-02,

505 * ⁄ 6265,

6.1-04, 140

6270, 6.1-02,

335

6270, 6.1-02†, 6.1-04,

335

171… 6273,

6.1-02, 340

6280, 6.1-02,

335

6282, 6.1-04,

100

6282, 6.1-04,

215

4372, 43-02,

205

8101, 8-04, 700

8101, 8-02, 700

3172, 3-04, 700

8132, 8-05, 700

8136, 8-06, 705

172… ⁄ ⁄ 6060, 6.1-01,

740

3182, 3-03, 345

8107, 8-01, 700

8108, 8-06, 700

8109, 8-06, 700

8112, 8-06, 750

8115, 8-01, 700

8115, 8-02, 700

173… 8116, 8-03, 130

8116, 8-03, 130

8117, 8-03, 130

8118, 8-06, 8-03†, 130

⁄ ⁄ 8123, 8-02, 700

6083, 6.1-02,

740

6083, 6.1-02,

740

8124, 8-03, 740

174… 8184-1, 8-06, 750

2107, 2-08, 700

8128, 8-05, 750

8129, 8-05, 750

8130, 8-03, 740

5132, 5.1-01,

750

5133, 5.1-01,

750

8133, 8-01, 700

5137, 51-06,

741

2117, 2-08, 750

175… 6097-1, 6.1-02,

540

6097-1, 6.1-04,

540

6099, 6.1-02,

700

8140, 8-02

700

8144, 8-03, 700

8144, 8-03, 700

8145, 8-06, 750

8145, 8-06, 750

8146, 8-03, 155

8151, 8-15, 760‡

176… 8147, 8-15, 760‡

8154, 8-06, 320

8155, 8-02, 700

8156, 8-02, 700

8158, 8-05, 700

8158, 8-02, 700

8159, 8-02, 700

8161, 8-01, 700

8163, 8-06, 700

8166, 8-02, 700

177… 8166, 8-02, 345

8167, 8-02, 700

⁄ 8173, 8-06, 700

8174, 8-06, 700

8175, 8-06, 750

8175, 8-06, 700

8176, 8-03, 750

8176, 8-06, 750

8177, 8-05, 700

178… 8177, 8-02, 700

8179, 8-02, 700

8179, 8-06, 750

8180, 8-05, 320

8181, 8-02, 700

⁄ 8184, 8-03, 750

8182, 8-03, 700

8183, 8-03, 700

8183, 8-03, 700

179… 8184, 8-03, 750

8186, 8-08

741

8187, 8-03, 740

8188, 8-05, 700

8189, 8-08, 700

⁄ 8194, 803, 700

⁄ 8197, 8-03, 700

8198, 8-02, 700

NOTES: * This UN number should not be used for sea transport. Use appropriate N.O.S. entry in class 2. † Liquid or solutions. ‡ In addition, refer to subsection 4.3 of the MFAG.


UN No. …0 …1 …2 …3 …4 …5 …6 …7 …8 …9

180… 8199, 8-02, 700

8199, 8-02, 700

8200, 8-03, 700

8201, 8-06, 700

8203, 8-02, 700

8204, 8-08, 700

8208, 8-03, 700

8208, 8-06, 700

8209, 8-03, 700

6231, 61-02,

700

181… 8207, 8-03, 700

8212, 8-06, 750

6242, 6.1-02*, 6.1-04,

750

8214, 8-06, 705

8214, 8-06, 705

3273, 3-04, 700

8218, 8-01, 700

8218, 8-03, 700

8221, 8-03, 700

8222, 8-06, 705

182… ⁄ ⁄ ⁄ 8225-1, 8-06, 705

8226, 8-06, 705

8226, 8-06, 705

8194, 8-03, 700

8228, 8-03, 700

8229, 8-02, 740

8233, 8-06, 700

183… 8230, 8-06, 700

8231, 8-06, 700

8232, 8-06, 700

8232, 8-06, 700

8233, 8-03, 700

8235, 8-05, 705

8236, 8-03, 635, 700

8237, 8-03, 740

8237, 8-03, 700

8239, 8-06, 700

184… 8247, 8-06, 145

9021, 8-07, 320 ⁄

6064, 6.1-02*, 6.1-03,

710 ⁄ 9025,

8-08, 615

6096, 6.1-02,

340

8215, 8-07, 225

8216, 8-04, 700

8227, 8-08, 225

185… ⁄ 6172-1, 6.1-02† ⁄ ⁄ 4255,

4.2-02, 120

4255, 4.2-02,

705

4256, 4.2-05, none ⁄ 2146,

2-09, 345

2178, 2-08, 750

186… 2187, 2-07, 350 ⁄ 3224,

3-07, 300

3141, 3271, 3375, 3-07, 311

⁄ 3276, 3-07, 235

3143-1, 3278, 3379, 3-05, 310

⁄ 4136, 4.1-03,

245

4153, 4.1-02, none

187… 4357,

4.3-04, 245

4176, 4.1-06, none

5154, 5.1-06

110

5167, 5.1-02,

700 ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ 188… ⁄ ⁄ ⁄ ⁄ 6081,

6.1-04, 705

6081, 6.1-04,

335

6084, 6.1-02,

340

6088, 6.1-02,

345

6103, 6.1-02,

340

6117, 6.1-04,

645

189… ⁄ 6146, 6.1-01,

345

6149, 6.1-02,

101 ⁄ 6230, 6.1-04,

105

6230, 6.1-04,

105 ⁄ 6264, 6.1-02,

340

8102, 8-02, 700 ⁄

NOTES: * Solutions † If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.


UN No. …0 …1 …2 …3 …4 …5 …6 …7 …8 …9

190… ⁄ ⁄ 8163, 8-05, 700

8167, 8-06, 760* ⁄

8220, 8-06, 175, 700

8221, 8-06, 700

8222, 8-06, 705

8137, 8-06, 741 ⁄

191… † 2128, 2-05, 245

2159, 2-07, 340

2161, 2-12, 620

3317, 3-07, 330

3322, 3-07, 300

6126, 6.1-01,

340

3220, 3-07, 330

3357, 3-07, 310

3252, 3-03, 330

192… 3371, 3-07, 310

3274, 3-02, 320

3277, 3-02, 325

4223 4.2-04,

635 ⁄ ⁄ ⁄ ⁄ 4355-1, 4.3-01,

170, 330

4253, 4.2-04,

635, 700

193… ⁄ 9037, 4.2-04,

635

4269, 4.2-02, none ⁄ ⁄ 6116,

6.1-02, 215 ⁄ ⁄

8131, 8-05, 8-06‡,

700

8206, 8-03, 700

194… 8235, 8-05, 700

9027, 6.1-02,

350

5122, 5.1-06,

610 ⁄ 4155, 4.1-06, none

4156, 4.1-06, none ⁄ ⁄ ⁄ ⁄

195… 2102, 2-13, 620§

2105, 2-12, 620

2138-1, 2-08, 365

2125-1 2-01¶

2124, 2-02, 620

2125, 2-03¶

2124, 2-04, 620

2127, 2-02, none

2131, 2-09, 350

2132, 2-07, 350

196… ⁄ 2135, 2-10, 310, 620

2138, 2-07, 310

2144, 2-12, 620

2147, 2-02, 310

2147, 2-07, 310

2148, 2-10, 620

2152, 2-06¶

2152, 2-09, none

2147, 2-07, 310

197… 2153, 2-12, 620

2156, 2-02, 620

2156, 2-10, 620

2119, 2-09, 350

2117, 2-09, 350

2162, 2-08, 610

2167, 2-09, 350

2163, 2-12, 620

2147, 2-07, 310

2174, 2-04, none

198… 2175, 2-04, none

2174, 2-04, none

2182, 2-09, 350

2121, 2-09, 350

2184, 2-09, 350 ⁄

3104, 3176, 3303, 3-07, 3-05

3175, 3303, 3-06, 3-05

3105, 3178, 3305, 3-07, 300

3105, 3177, 3305, 307, 300

199… 9024-1, 6.1-02,

300

3110, 3-01, 340

3127, 3232,

3346-1, 3-07¶

3126,3230, 3345, 3-07¶

6165, 6.1-01,

165 ⁄ ⁄ ⁄ ⁄ 3281, 3382, 3-05, 311

NOTES: * In addition, refer to subsection 4.3 of the MFAG. † Classified as hazardous for air transport only. ‡ Solution. § MFAG Table No. 620 for classes 2.1 and 2.2 only. For substances in class 2.3 and aerosols with a capacity of 1000 cm3 or less, if an MFAG table number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. ¶ If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.


UN No. …0 …1 …2 …3 …4 …5 …6 …7 …8 …9

200… 4133,

4.1-06, 610

4135, 4.1-06, none

4226, 4.2-05,

610

4243, 4.2-01,

170

4240, 4.2-01,

725

4241, 4.2-01,

170

4252, 4.2-07,

610 ⁄ 4268, 4.2-02, none

4267, 4.2-02, none

201… 4351,

4.3-01, none

4352, 4.3-02,

205

4358, 4.3-02,

205

4365, 4.3-02,

205

5151, 5.1-02,

735

5152, 5.1-02,

735

6067, 6.1-02,

740

6067, 6.1-02

740

6100, 6.1-03,

335

6100, 6.1-02,

335

202… 6107,

6.1-04, 711

6107, 6.1-02,

711

6114, 6.1-02,

710

6143, 6.1-01,

740

6180, 6.1-02,

105

6181, 6.1-04,

105

6229, 6.1-04,

105

6254, 6.1-04,

100

8127, 8-05, 700

8181, 801, 720

203… 8182, 8-11, 720

8195, 803, 610*, 700

8196, 8-03, 610, 700

8215, 8-06, 705

2149, 2-02, none

2184, 2-07, 350

2188, 2-09, none

2175, 2-13†

6137, 6.1-01‡, 6.1-03,

335 ⁄

204… ⁄ ⁄ ⁄ ⁄ 2147, 2-07, 310

3130, 3-07, 300

3325, 3-07, 310

3206, 3330, 3-07, 340

3330, 3-07, 310

3331-1, 3-07, 310

205… 3210, 3-07, 310

8164, 8-04, 320

3336, 3-07, 310

3366, 3-02, 3-05

3367, 3-02, 322

3381, 3-07, 310

3144, 3282, 3-06, 330

3287, 3391, 3-07, 310

3288, 3-06, 300

3138-2, 3265, 3369, 3-05, 610

206… ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ 5123, 5.1-06,

610

5123, 51-06,

610

5123, 5.1-06,

610

207… 5123,

5.1-06, 610

9023, 5.1-06,

610

5124, 5.1-06,

610

2104-1, 2-08, 725

6054, 6.1-02‡, 6.1-04,

323

6097, 6.1-02,

300

6114, 6.1-02,

710

6200, 6.1-02‡, 6.1-04,

320

6269, 6.1-02,

370

8161, 8-05, 320

208… ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ 209… ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄

NOTES: * Concentration over 70%. † MFAG Table No. 620 for classes 2.1 and 2.2. For class 2.3, if an MFAG table number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. ‡ Solution or liquid.


UN No.

…0 …1 …2 …3 …4 …5 …6 …7 …8 …9

230… 6195,

6.1-02, 325

3137-1, 3-07, 330

3366, 3-07, 300

3357, 3-07, 310

4158, 4.1-04,

314

8197, 8-05, 700

6208, 6.1-02,

335

6209, 6.1-02,

335

8198, 803, 700

3267, 307, 310

231… 3373, 3-06, 300

6223, 6.1-02,

335

6224, 6.1-02,

710

3376, 3-02, 325

⁄ 9034, 6.1-02, none

6256, 6.1-04,

215

6256, 6.1-02,

215

4262, 4.2-04,

225

3383, 3-07, 310, 313

232… 8234, 8-05, 320

6271-1, 6.1-02,

340

6272, 6.1-02,

340

3387, 3-07, 330

3388, 3-07, 310

3389-1, 3-03, 310

8242, 8-05, 320

8243, 8-05, 320

6276, 6.1-02,

370

3390, 3-07, 330

233… 3392, 307, 310

8247, 8-06, 145

3301, 3-06, 320

3180, 3-02, 330

6059, 6.1-01,

320

3181, 3-03, 330

3181, 3-03, 330

6228, 6.1-01,

375

3185, 3-07, 345

3187, 3-07, 345

234… 3188, 3-06, 345

3313, 3-06, 345

3188, 3-07, 345

3189, 3-07, 345

3189, 3313, 3-07, 345

3190, 3-07, 345

3190, 3-06, 300

3108, 3194, 3-07, 375

3315, 3-03, 330

⁄

235… 3195, 3-07, 330

3195, 3316, 3-06, 235

3196, 3-06, 330

3197, 3-04, 700

3198, 3-02, 340

⁄ 3111, 3-07, 340

8156, 8-04, 320

3203, 3-07, 310

3204, 3-02, 320

236… 3204, 3-03, 330

3332, 3-03, 320

3205, 3-03, 340

3123, 3-07, 375

3378, 3-07, 310

⁄ 3332, 3-07, 330

3263, 3-07, 300

3377, 3-03, 313

⁄ 237…

3129, 3-07, 310

3132, 3-07, 310

3207, 3-06, 320

3116, 3207, 3-06, 330

3208, 3-06, 330

3209, 3-07, 375

3209, 3-06, 310

3118, 3211, 3-06, 330

3334, 3-02, 215

3212, 3-03, 320

238… 3214, 3-06, none

3215, 3-07, 225

6131-1, 6.1-01,

720

3218, 3-02, 320

3120, 3218, 3-06, 330

3225, 3-07, 330

3227, 3-02, 325

3233, 3-07, 345

3233, 3-07, 345

3127, 3-07, 300

239… 3238, 3-07, 345

3238, 3-07, 345

3353, 3-07, 345

3240, 3-07, 330

3241, 3-07, 330

3242, 3-04, 700

3250, 3-02, 300

3254, 3-07, 300

3136, 3-07, 330

3260, 3-02, 325


UN No.

…0 …1 …2 …3 …4 …5 …6 …7 …8 …9

240... 3258, 3-07, 330

8211-1, 8-01, 325

3142, 3-07, 375

3244, 307, 330

3273, 3-02, 215

3358, 3-07, 330

3246, 3-07, 330

6168-1, 6.1-01,

740 ⁄ 3247,

3-07, 330

241... 3282, 3-06, 325

3197, 3-03, 215

3283, 3-07, 375

3385, 3-06, 330

3284, 3-07, 375

⁄ 3287, 3-06, 240

2115, 2-08, 750

2180, 2-08, 750

2109, 207, 350

242... 2145, 2-08, 750

2164, 2-08, 610

2167, 2-09, 350

⁄ 2168, 2-09, 350

⁄ 5125, 51-10,

235

5170, 5.1-03,

745

5179, 5.1-03,

745

5135, 5.1-03,

745

243... 8103, 8-15, 710

6069, 6.1-02,

335

6130, 6.1-02,

335

6106, 6.1-02,

335

8157, 8-02, 700

8171, 8-02, 700

3283, 3-06, 700

8192, 8-02, 700

6275-1, 6.1-01,

700

8223, 8-06, 750

244... 8228, 8-06, 700

4266, 4.2-04,

700

8240, 8-02, 700

8244, 8-03, 135

8245, 8-03, 135,, 700

4239, 4.2-01,

160, 170

6210, 6.1-02,

710

4251, 4.2-03,

200

4175, 4.1-04, 635*

⁄

245... ⁄ 2164, 2-03, 750

2136, 2-07, 310

2140, 2-07, 345

2160, 2-07, 345

†Carriage, prohibited

3112, 3-07, 340

3119, 307, 310

3128, 3236, 3-07, 310

3132, 3-07, 310

246... 3132, 3-07, 310

3138, 3-07, 310

⁄ 4328, 4.3-04, none

5130, 5.1-05,

125

5147, 5.1-06,

740

5176, 5.1-04,

735 ⁄ 5190,

5.1-05, 740

5192, 5.1-06,

745

247... 6226,

6.1-02, 215

6215, 6.1-04,

181 ⁄ 6252,

6.1-04, 100

6268, 6.1-02,

600

8246, 8-06, 135, 700

⁄ 6198, 6.1-01,

370

3130, 3242,

3356-1, 3-04, 370

⁄

248... 6197-1, 6.1-01,

370

3225, 3-04, 370

6245-1, 6.1-01,

370

3246, 3-04, 370

6091, 6.1-01,

370

6091, 6.1-01,

370

3240, 3-04, 370

6228, 6.1-01,

370

6118, 6.1-01,

370 ⁄

249... 6127,

6.1-02, 340

8169, 8-05, 320

⁄ 3236, 3-02, 320

⁄ 5153, 5.1-01,

750

8216, 8-05, 700

⁄ 3384, 3-07, 300

⁄ NOTES: * Fire risk only † METHYL NITRITE


UN No.

…0 …1 …2 …3 …4 …5 …6 …7 …8 …9

270... ⁄ ⁄ ⁄ ⁄ ⁄ 8200, 8-05, 305

⁄ 3215, 3334, 3-06, 330

⁄ 3315-1, 3-07, 310

271... 3336, 3-07, 300

⁄ ⁄ 6052, 6.1-03,

325

4183, 4.1-06,

145

4121, 4.1-06, none

6092, 6.1-03,

305

4132, 4.1-06,

331 ⁄ 5127,

5.1-05, 1745

272... 5145-1, 5.1-06,

155

5146, 5.1-06,

745

5157, 5.1-06,

160

5158, 5.1-06,

745

5160, 5.1-06, none

5161, 5.1-06, none

5161, 5.1-06,

235

6265-1, 6.1-04,

140

5194, 5.1-06, none

6158, 6.1-04,

500

273... 6207,

6.1-02, 335

⁄ 6209,

6.1-02*, 6.1-04,

335

3106,3306, 3182-1, 3-02, 320

8109-1, 8-04, 320

8109-2, 8-05, 320

⁄ ⁄ 6089, 6.1-02,

335

8134, 8-05, 700

274... 6244,

6.1-01, 740

5128, 5.1-05,

741

6104, 6.1-01,

740

6104, 6.1-01,

740

6104, 6.1-01,

740

6104-1, 6.1-02,

740

6104-1, 6.1-02,

740

6090, 6.1-02,

740

6104-1, 6.1-02,

740

3144, 3-07, none

275... 6129,

6.1-02, 740

8162, 8-05, 700

3337, 3-07, 365

6145-1, 6.1-02,

335

6152, 6.1-01,

335 ⁄ ⁄ 6221,

6.1-04, 505

3270, 3-03, 505

6221, 6.1-04,

100

276... 3270, 3-03, 100

6221, 6.1-04,

500

3270, 3-03, 500

6221, 6.1-04,

530

3270, 3-03, 530

⁄ ⁄ ⁄ ⁄ ⁄ 277... ⁄ 6221,

6.1-04, 506

3270, 3-03, 506

⁄ ⁄ 6221, 6.1-04,

150

3270, 3-03, 150

6221, 6.1-04,

105

3270, 3-03, 105

6221, 6.1-03,

515

278... 3270, 3-03, 515

6221, 6.1-04,

525

3270, 3-03, 525

6221, 6.1-04,

505

3270, 3-03, 505

6266, 6.1-01,

300

6221, 6.1-04,

545

3270, 3-03, 545

6214, 6.1-02,

545

8100, 8-04, 700

279... 8100, 8-05, 700

⁄ ⁄ 4232, 4.2-05, none

8120, 8-10, 700

8120, 8-10, 705

8230, 8-06, 700

8119, 8-06, 705

8202, 8-05, 700

8202, 8-05, 700

NOTE: * Liquids


UN, No. …0 …1 …2 …3 …4 …5 …6 …7 …8 …9

280. 8121, 8-10, none

8168, 8-04, 760*

8147, 8-08, 740

8178, 8-12, none

⁄ 4348, 4.3-01,

160

4349, 4.3-05,

160, 725

† ⁄ 8191, 8-12, none

281. 6270-1, 6.1-02

6270-6 6.1-04†

† 4368, 4.3-08‡

6321§, not applica-

ble

8110, 8-05, 325

⁄ 8112, 8-06, 750

8113, 8-05, 225

8114, 8-05, 700

282. 8133, 8-05, 700

6225, 6.1-02,

710

6110, 6.1-02,

325

8154, 8-05, 700

⁄ ⁄ 8169, 8-04, 740

⁄ ⁄ 8136, 8-07, 700

283.

4347-1, 4.3-03,

160, 605

6272-1, 6.1-02,

340 ⁄ ⁄ 8205,

8-08, 700

4361, 4.3-01,

705 ⁄ 8125,

8-08, 700

3289, 3-07, 330

6055, 6.1-02,

300

284. 3317, 3-07, 300

3327, 3-03, 320

3369, 3-06, 335

⁄ 4337, 4.3-03,

705

4254, 4.2-01, 760*

4255, 4.2-01, 760*

⁄ ⁄ 6110, 6.1-02,

740

285. 3378, 3-07, 310

8129, 8-06, 750

4143, 4.1-01,

375

6250, 6.1-04,

750

6250, 6.1-04,

750

6250, 6.1-04,

750

6250, 6.1-04,

750

2176, 2-13, 350

4183, 4.1-02, none

6066, 6.1-04,

135

286. ⁄ 6066, 6.1-04,

135

6277, 6.1-04,

135

6252, 6.1-04,

135

6243, 6.1-04,

135

8185, 8-06, none

⁄ ⁄ ⁄ 8238, 8-06, 700

287. 4222,

4.2-01, 245

6071, 6.1-03,

130

6120, 6.1-02,

345

6122, 6.1-02,

320

6156, 6.1-02,

305

6160, 6.1-04,

711

6248, 6.1-04,

710 ⁄ 4177,

4.1-02, none

8220, 8-06, 175, 700

288. 5138,

5.1-06, 741

4245, 4.2-02, none

⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ 289. ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄

NOTES: * In addition, refer to subsection 4.3 of the MFAG. † Classified as hazardous for air transport only. ‡ If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. § Emergency procedures to be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to or leakage from, a package containing infectious substances, refer to section 9 of the introduction to class 6.2.


UN No. …0 …1 …2 …3 …4 …5 …6 …7 …8 …9

290... 6322 not

applicable

2108, 2-08, 740

6219, 6.1-02

†

6220, 6.1-01,

†

8139, 805, 711

8139, 8-05, 711 ⁄ 4151,

4.1-06, 320 ⁄ ⁄

291... ‡

7-07, § ⁄ ‡

7-02 §

‡ 7-02,

§ ⁄ ⁄ ⁄ ⁄ ‡, 7-01,

§ ⁄ 292...

8148, 8-15, 760¶

8151, 8-15 760¶

8149, 8-15, 760¶

8152, 8-15, 760¶

3126, 3231, 3346, 3-02, 760¶

4146-1, 4.1-03, 760¶

4147, 4.1-03

†

6270-2, 6.1-02

†

6270-7, 6.1-04

†

6270-3, 6.1-01

†

293... 6270-8, 6.1-03,

†

6278, 6.1-04,

135, 700

⁄ 3364, 3-06, 740

3359, 3-07, 740

3340, 3-07, 740

6267, 6.1-02,

375

6189, 6.1-02,

305 ⁄ ⁄ 294...

4249, 4.2-04,

310

6155, 6.1-02,

335

6275, 6.1-02,

335

3385, 3-02, 320 ⁄ 3254,

3-02, 320

6062, 6.1-02,

320

3358, 3-02, 740

6275, 6.1-02,

335

8225, 8-05, 225

295... 4351,

4.3-06, none ⁄ ⁄ ⁄ ⁄ ⁄ 4131-1,

4.1-05, 335 ⁄ ⁄ ⁄

296... ⁄ ⁄ ⁄ ⁄ ⁄ 4333, 4.3-05,

750

6267, 6.1-02,

375

8229, 8-08, 700

4354, 4.3-05,

506

9026, 6.1-04,

851

297... ⁄ ⁄ ⁄ ⁄ ‡ 7-01,

§

‡ 7-03,

§

‡ 7-05,

§

‡ 7-04, 750§

‡ 7-04, 750§

‡ 7-03

§

298... ‡

706, §

‡ 7-05

§

‡ 7-01,

§

3122, 3-02, 365

5150, 5.1-02,

735

3199, 3-04, 700

8143, 8-01, 700

8142, 8-02, 700

4341, 4.3-05,

700

4152, 4.1-03,

110, 700

299... 9032** none

6220, 6.1-01,

505

6219, 6.1-02,

505

6220, 6.1-01,

100

6219, 6.1-02,

100

6220, 6.1-01,

500

6219, 6.1-02,

500

6220, 6.1-01,

530

6219, 6.1-02,

530 ⁄ NOTES: * Emergency procedures to be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to or leakage from, a package containing infectious substances, refer to section 9 of the introduction to class 6.2. † If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG. ‡ See section 12 of the introduction to class 7. § See subsection 7.4 of the MFAG. ¶ If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. • In addition, refer to subsection 4.3 of the MFAG. ** EmS to be declared by the shipper.


UN, No. …0 …1 …2 …3 …4 …5 …6 …7 …8 …9

300… ⁄ ⁄ ⁄ ⁄ ⁄ 6220, 6.1-01,

506

6219, 6.1-02,

506 ⁄ ⁄ 6220, 6.1-01,

150

301… 6219,

6.1-02, 150

6220, 6.1-01,

105

6219, 6.1-02,

105

6220, 6.1-01,

515

6219, 6.1-02,

515

6220, 6.1-01,

525

6219, 6.1-02,

525

6220, 6.1-01,

505

6219, 6.1-02,

505

6220, 6.1-01,

545

302… 6219,

6.1-02, 545

3270, 3-03*

3192, 3-06, 365

6213, 6.1-01,

375

3270, 3-03, 535†

6220, 6.1-01 535†

6219, 6.1-02, 535†

6221, 6.1-04, 535†

8119, 8-10, 705 ⁄

303… ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ 304… ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ 6061,

6.1-04, 205

4243, 4.2-01,

170

305… 4244,

4.2-01, 170

4221, 4.2-01,

170

4221, 4.2-01,

170

4240, 4.2-01,

170

3323, 3-03, 375

8110, 8-07, 320

3350, 3-06, 300

2183, 2-08, 700 ⁄ ⁄

306… ⁄ ⁄ ⁄ ⁄ 3266, 3-06, 235

3174-3, 3304, 3-06, 305

⁄ ⁄ ⁄

307… 2138-3, 2-09, 350

6173, 6.1-01,

375

9032, † †

none

6279, 6.1-01,

305 ⁄ ⁄ 4222, 4.2-01,

170

9029, none, none

4340, 4.3-06, none

3250, 3-06, 215

308… 6167,

6.1-01, 370 ⁄ 9028,

none, none

2170-1, 2-08, 750

8153, 8-15, 760§

5164, 5.1-05, 760§

6270-4, 6.1-04

5165, 5.1-05, 760§

4260, 4.2-04

4157, 4.1-02

309… 9033,

4.1-06, none

9033, 4.1-06, none

3363, 3-06, 330

8153, 8-03, 760§

8150, 8-15, 760§

8150, 8-15, 760§

8150, 8-15, 760§

5164, 5.1-02, 760§

5165, 5.1-02, 760§

NOTES: * If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. † MFAG Table No. 505 for Coumaphos. ‡ EmS to be declared by the shipper. § In addition refer to subsection 4.3 of the MFAG.


UN No. …0 …1 …2 …3 …4 …5 …6 …7 …8 …9

310. ⁄ 5221, 52-01,

735

5222, 5.2-01,

735

5223, 5.2-01,

735

5224, 5.2-01,

735

5225, 5.2-01,

735

5226, 5.2-01,

735

5227, 5.2-01,

735

5228, 5.2-01,

735

5229*, 735

311. 5230*, 735

5231, 5.2-02,

735

5232, 5.2-02,

735

5233, 5.2-02,

735

5234, 5.2-02,

735

5235, 5.2-02,

735

5236, 5.2-02,

735

5237, 5.2-02,

735

5238, 5.2-02,

735

5239†, 735

312. 5240†, 735 ⁄ 6270-4,

6.1-02 ‡

6270-5, 6.1-07

‡

6270-5, 6.1-08

‡

6270-5, 6.1-07

‡

4261, 4.2-04, 760§ ⁄ 4261,

4.2-04‡

4367, 4.3-08, 760§

313. 4367,

4.3-08, ‡

4369, 4.3-08, 760§ ⁄ ⁄ 4369,

4.3-08 ‡ ⁄ 2184-1,

2-12, 620 ⁄

2137, 2-10, 310, 620

5163, 5.1-11, 760§

314. 6056,

6.1-02, 805

6070, 6.1-02,

130

6141, 6.1-02‡

6142 6.1-04‡

6204, 6.1-02,

800

8103, 8-15, 710

6214, 6.1-04,

545

8168, 8-05, 760‡

4366, 4.3-08,

‡

5149, 5.1-02,

735

315. 2128, 2-13, none

9035, 6.1-02, none

9035, 6.1-04, none

2171, 2-07, 620, 615

2171, 2-07, 620, 615

6217, 6.1-04,

711

2125, 204, 620

2155-1, 2-08, 620

214.2-1, 2-12, 620

2181, 209, 350

316. 2155-3,

2-06 ‡

2155-1, 2-07, 620

2155-2, 2-08

‡

2155, 2-09, 620

2106, 2-13, 620

3174-1, 3-02, 720 ⁄ 214.2-2,

202 ‡

214.2-3, 2-01

‡

21423, 2-03

‡

317. 4330-1, 4.3-04,

725 ¶

6270-9, 6.1-021, 6.1-042

‡ ⁄ 4264-1,

4.2-05, ‡

4173-1, 4.1-06

‡

4146-2, 4.1-04,

‡ ⁄ 4146,

4.1-023, 4.1-054

‡

4147, 4.1-03

‡

318. 4146-1, 4.1-03, 760§

4157-1 4.1-06

‡

4157-1, 4.1-06

‡

4259-1, 4.2-04,

‡

4259-2, 4204†,

†

42592, 4.2-04

‡

4259-1, 4.2-04

‡

4259-2, 4.2-04,

‡

4259-2, 4.2-04,

‡

4260, 4.2-04,

‡

319. 4260

4.2-04, ‡

4261, 4.2-04

‡

4261, 4.2-04, 760§ ⁄ 4254,

4.2-01, 760§ ⁄ ⁄ ⁄ ⁄ ⁄

NOTES:

*5.2-01 in packagings. 5.2-03 in IBCs.

5.2-05 in tanks. † 5.2-02 in packagings. 5.2-04 in IBCs.

‡ If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG. § In addition, refer to subsection 4.3 of the MFAG. ¶ Classified as hazardous for air transport only 1 For liquids. 2 For solids. 3 Metals other than metal powders. 4 Other than metals.


UN, No. …0 …1 …2 …3 …4 …5 …6 …7 …8 …9

320... 4255,

4.2-01, 760* ⁄ ⁄ 4254,4255,

4.2-01, 760* ⁄ 4220-1,

4.2-08, 705

4220-1, 4.2-08,

705

4355-2, 4.3-08,

†

4354-2, 4.3-08,

†

4354-3, 4.3-08,

†

321... 5142,

5.1-02, 745

5166, 5.1-02,

745

5152-1, 5.1-06,

741

5131, 5.1-02,

745

5167-1, 5.1-02,

715

5168-1, 5.1-05,

700

5168-1, 5.1-02,

700 ⁄ 5162, 5.1-02,

235

5162-1, 5.1-06,

235

322... 2170-1, 2-09, 350

4168, 4.1-10,

†

4168-1, 4.1-10

†

4168-2, 4.1-10

†

4168-3, 4.1-10

†

4168-4, 4.1-10

†

4168-5, 4.1-10,

†

4168-6, 4.1-10

†

4168-7, 4.1-10

†

4168-8, 4.1-101,

4.1-122,

†

323... 4168-9, 4.1-101, 4.1-122,

†

4169, 4.1-11

†

4169-1, 4.1-11,

†

4169-2, 4.1-11,

†

4169-3, 4.1-11,

†

41694, 4.1-11,

†

4169-5, 4.1-11

†

4169-6, 4.1-11,

†

4169-7, 4.1-11,

†

4169-8, 4.1-111, 4.1-132

†

324... 4169-9, 4.1-111, 4.1-132,

†

4131, 4.1-05,

335

4122-1, 4.1-10,

240

6259-1, 6.1-04

†

8227-1, 8-15, 760

9031, ‡,

not applicable

6188, 6.1-02,

700

5185, 5.1-06,

735

3134-1, 3248-1, 3360-1,

3-07 †

6172-1, 6.1-04

†

325... 6097-2, 6.1-09,

540

4151-1, 4.1-10,

235

2132-1, 2-07, 350

8166-1, 8-06, 705

4266-1, 4.2-04,

760

4221-1, 4.2-04,

741

3336-1, 3-07

† 9027-1 9027-2

8109-2, 8-15, 760

326... 8150-1, 8-15, 760

8150-1, 815, 760

8150-1, 815, 760

8150-1, 815, 760

8147-1, 8-15, 760

8147-1, 8-15, 760

8147-1, 8-15, 760

8147-1, 8-15, 760

9022-1, §,

none

3272, 3377-1,

3-07 †

327... 4161-1, 4.1-06, none

3120-1, 3219,

3337-1, 307

*

3218-1, 3337, 307

*

3138-1, 3264, 3-03, 215

3102-1, 3174-2,

3-06 *

6206-2, 6.1-01,

215

6206-1, 6.1-02,

215

6104-1, 6.1-021,

6.1-042,

740

6213-2, 6.1-021, 6.1-042,

505

62132, 6.1-011, 6.1-032,

505

NOTES: 1 For self-reactive substances in packagings. 2 For self-reactive substances in IBCs. * In addition refer to subsection 4.3 of the MFAG. † If an MFAG Table No is not supplied by the shipper, refer to subsection 4.2 of the MFAG. ‡ To be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to or leakage from, a package containing infectious substances refer to section 9 of the introduction to class 6.2. § To be declared by the shipper.


UN No. …0 …1 …2 …3 …4 …5 …6 …7 …8 …9

328...

6213-1, 6.1-021,

6.1-042,

100

61871, 6.1-02,

165

62131, 6.1-021, 6.1-042

*

6249-1, 6.1-021, 6.1-042,

175

6262-1, 6.1-021,

6.1-042 *

6276-1, 6.1-021, 6.1-042,

135

3126-1, 3232-1,

3-03 *

6270-1, 6.1-02

*

62706, 6.1-04

*

6270-2, 6.1-02

*

329... 6270-7, 6.1-04

*

6320, †,

not applicable

4332-1, 4.3-09,

705

6161-1, 6.1-02,

720

6163-1, 6.1-01,

215

3129-1, 3237, 3352, 3-07, 310

2144-1, 2-09, 350

2138-2, 2-09, 350

21384, 2-09, 350

2138-4, 2-09, 350

330... 2138-2, 2-06, 365

8147-2, 8-02, 760‡

6130-1, 6.1-02,

330

2125-3, 2-03

*

2125-1, 2-03

*

2125-2, 2-01

*

2125-3, 2-03

*

21554, 2-08

*

2155-2, 2-08

*

2155-3, 2-06

*

331... 2155-4,

2-08 *

2142-2, 2-11, 620

2142-1, 2-10, 620

4247-1, 4.2-05

*

9036, 4.1-06, none

6096-1, 6.1-021, 6.1-042

9026-13 *

4121-1, 4.1-01,

335

2104, 2-083, 725

4162-2, 4.1-01,

235

332... 8222-1, 8-06, 705 ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ ⁄

333... ⁄ ⁄ ⁄ ⁄ ⁄ ⁄ 3134-2, 3248-2, 3360-2,

3-07 *

2176-1, 2-09, 620

2176-1, 2-09, 620

2176-2, 2-09, 620

334... 2176-2, 2-09, 620

4264, 4.2-04

*

4266-2, 4.2-04

*

3138-3, 3265-1, 3369-1,

§, §

4164 § §

6221, 6.1-04,

510

3270, 3-03, 510

6219, 6.1-02,

510

6219, 6.1-02,

510

6221, 6.1-04,

510

NOTES: * If an MFAG Table No is not supplied by the shipper refer to subsection 4.2 of the MFAG. † To be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to, or leakage from a package containing infectious substances, refer to section 9 of the introduction to class 6.2. ‡ In addition, refer to subsection 4.3 of the MFAG. § As approved by the competent authority. 1 For liquids. 2 For solids. 3 To be declared by the shipper.


UN No. …0 …1 …2 …3 …4 …5 …6 …7 …8 …9

335… 3270, 3-03, 510

6220, 6.1-02,

510

6219, 6.1-02

510

2102-1, none

2152-1, 2-07, none

2152-1, 2-06, none

5165-1, 5.1-11,

† ⁄

⁄

⁄

* To be declared by the shipper. † If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG.

CLASS 1 - E x p l o s i v e s

3.2 Introduction 3.2.1 All packagings for goods should be so designed and constructed that:

1. they will protect the explosives prevent them escaping and cause no increase in the risk of unin-tended ignition or initiation when subjected to normal conditions of transport including foreseeable changes in temperature humidity and pressure;

2. the complete package can be handled safely in normal conditions of transport; and

3. the packages will withstand any loading imposed on them by foreseeable stacking to which they will be subject during transport so that:

they do not add to the risk presented by the explosives; the containment function of the packagings is not harmed; and

they are not distorted in a way or to an extent which will reduce their strength or cause instability of the stack.

3.2.2 Packing requirements for consist of general packing provisions which apply to all or a broad spectrum of goods in and additional requirements which only apply to specific UN (substance/article identification) Numbers. The general packing provisions are given in section 3.3 and the relevant additional requirements appear as notes to the explosive packing method tables which are found in section 3.4 of this introduction.

3.3 General packing provisions

3.3.1 The general provisions given below are in addition to those in Annex I of the General Introduction.

3.3.2 All explosive substances and articles as prepared for transport should have been classified in accordance with the procedures given in the United Nations Recommendations on the Transport of Dangerous Goods.

3.3.3 goods should be packed in accordance with:

1 the appropriate packing method shown on the schedules for substances and articles in this class; and

2 any relevant additional requirements for specific UN Numbers which are given as notes in the packing method tables in section 3.4 of this introduction.

Note: In section 3.4 the following convention is used: Packing methods EP-01 to EP-09 - reserved for methods requiring competent authority approval. Packing methods EP-10 to EP-29 - reserved for explosive substances; and Packing methods EP-30 onwards - reserved for explosive articles.

3.3.4 Packages should conform to the requirements of Annex I of the General Introduction in particular to meeting the test requirements of section 8 and should be subject to the requirements of paragraphs 3.14 and 5.4. IBCs should comply with the provisions of section 26 of the General Introduction.

3.3.5 The closure device of packagings containing liquid explosives should ensure a double protection against leak-age.

3.3.6 The closure device of metal drums should include a suitable gasket if a closure device includes a screw thread the ingress of explosive substances into the screw thread should be prevented.

IMDG CODE - PAGE 1006-1 (page 1006-2 follows) Amdt. 28-96


3.3.7 Packagings for water soluble substances should be water resistant. Packagings for desensitized or phlegmatized substances should be closed to prevent changes in concentration during transport.

3.3.8 When the packaging includes a double envelope filled with water which may freeze during transport, a sufficient quantity of an antifreeze agent should be added to the water to prevent freezing. Antifreeze that could create a fire hazard because of its inherent flammability should not be used.

3.3.9 Nails, staples and other closure devices made of metal without protective covering should not penetrate to the inside of the outer packaging unless the inner packaging adequately protects the explosives against contact with the metal.

3.3.10 Inner packagings, fittings and cushioning materials and the placing of explosive substances or articles in pack-ages should be accomplished in a manner which prevents the explosive substance or article from becoming loose in the outer packaging under normal conditions of transport. Metallic components of articles should be prevented from making contact with metal packagings. Articles containing explosive substances not enclosed in an outer casing should be separated from each other in order to prevent friction and impact. Padding, trays partitioning in the inner or outer packaging, mouldings or receptacles may be used for this purpose.

3.3.11 Packagings should be made of materials compatible with, and impermeable to, the explosives contained in the package, so that neither interaction between the explosives and the packaging materials, nor leakage, causes the explosive to become unsafe for transport, or the hazard division or compatibility group to change.

3.3.12 The ingress of explosive substances into the recesses of seamed metal packagings should be prevented.

3.3.13 Plastics packagings should not be liable to generate or accumulate sufficient static electricity so that a discharge could cause the packaged explosive substances or articles to initiate ignite or function.

3.3.14 Large and robust explosives articles, normally intended for military use without their means of initiation or with their means of initiation containing at least two effective protective features, may be carried unpacked. When such articles have propelling charges or are self propelled their ignition systems should be protected against stimuli encountered during normal conditions of transport. A negative result in Test Series 4 of the United Na-tions Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria on an unpacked article indicates that the article can be considered for transport unpacked. Such unpacked articles may be fixed to cradles or contained in crates or other suitable handling, storage or launching devices in such a way that they will not become loose during normal conditions of transport.

3.3.14.1 Where, as part of their operational safety and suitability tests, such large explosive articles are subjected to test regimes which are at least equivalent or more stringent that the tests prescribed in the United Nations Recom-mendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, as referred to in this Code and such tests have been successfully undertaken the competent authority may approve the transport of such arti-cles under the requirements of this Code.

3.3.15 Explosive substances should not be packed in inner or outer packagings where the differences in internal and external pressures, due to thermal or other effects, could cause an explosion or rupture of the package.



3.3.16 Whenever loose explosive substances or the explosive substances of an uncased or partly cased article may come into contact with the inner surface of metal packagings (1A2, 1B2, 4A, 4B and metal receptacles) the metal packaging should be provided with an inner liner or coating (see 3.2 of Annex I to this code).

3.3.17 Notwithstanding the explosive packing methods listed in section 3.4 of this introduction EP-01 may be adopted for any explosive substance or article provided the package has been approved by a national competent authority. For the declaration of such goods see 2.5 of this introduction.

3.4 Packing methods for explosives

General Notes:

(1) Whenever Boxes natural wood ordinary (4C1) are listed in the following tables a Box natural wood sift proof walls (4C2) may be used instead;

(2) Leakproof packagings should correspond to a design type that has passed a leakproofness test at the Packag-ing Group II level;

(3) The term receptacle used in the inner and intermediate packaging columns of the following tables includes boxes bottles cans drums jars and tubes including any means of closure;

(4) Reels are devices made of plastics wood fibreboard metal or other suitable material comprising a central spin-dle with or without side walls at each end of the spindle Articles and substances can be wound onto the spindle and may be retained by side walls;

(5) Trays are sheets of metal plastics wood fibreboard or other suitable material which are placed in the inner intermediate or outer packaging and achieve a close fit in such packagings. The surface of the tray may be shaped so that packagings or articles can be inserted held secure and separated from each other;

(6) Some UN Numbers cover substances which may be transported dry or wetted. Where appropriate the heading of the packing method indicates whether it is suitable for the dry powder or wetted substance.



METHOD EP-01

Inner packagings and ar-rangements

Intermediate packagings and ar-rangements

Outer packagings and ar-rangements

As approved by the competent authority. The State's distinguishing sign for motor vehicles in international traffic of the country for which the authority acts, should be marked on the shipping documents as follows: "Packaging approved by the competent authority of "

Note: For UN Nos. 0020, 0021, 0190 0349 to 0359 inclusive, 0382, 0383, 0384, 0461 to 0482 inclusive and

0485. For the purposes of documentation and package marking, the proper shipping name should be supplemented with the correct technical name (see 7.1.12 of the General Introduction)



UN No. Division Compatibility Group 0059 1.1 D 0439 1.2 D 0440 1.4 D 0441 1.4 S

Packing, Stowage & Segregation See also General Introduction and introduction to this class.

OR labelled with Label of class


CHARGES, SHAPED without detonator

For UN Nos. 0059 and 0439 only Label of class

Properties or descriptions Articles consisting of a casing containing a charge of detonating explosive with a cavity lined with rigid material without means of initiation. They are designed to produce a powerful penetrating jet effect.

1 Observations

(the appropriate division number and the letter D should be placed on the label) Packagings

Packing Method EP-37 applies.

For UN No. 0440 only Label of class

1 Division 1.4 Compati-bility Group D

Stowage Cargo ships. ON DECK IN CONTAINERS OR THE LIKE

UNDER DECK ORDINARY STOWAGE Passenger ships SEE SECTION 9 OF INTRODUCTION TO

THIS CLASS

For UN No. 0441 only the package should be EITHER marked

1.4S

1 Division 1.4 Compati-bility Group S

CLASS 2 - G a s e s

Properties

MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. "AEROSOLS" meaning aerosol dispensers are any non-refillable re-ceptacles meeting the requirements of paragraph 8.9 of Annex I, made of metal, glass or plastics and containing a gas compressed, liquefied or dissolved under pressure, with or without a liquid, paste or powder, and fitted with a release device allowing the contents to be ejected as solid or liquid particles in suspension in a gas, as a foam, paste or powder or in a liquid state or in a gaseous state.

Observations

IMDG CODE - PAGE 2102 (first of two pages) Amdt. 29-98

AEROSOLS UN No.

1950 Formula

Explosive limits

Label ACCORDING TO PROPER-TIES. However for aerosols with a capacity of 1000 cm3 or less the mark "AEROSOLS" may be applied instead of a label.

MARINE POLLUTANT mark (for marine pollutants only)

The aerosols should comply with the provisions of the country in which they are filled. They should be provided with protection against inadvertent discharge They should be of a type which shows no visible leakage or loss of contents of more than 1% in mass (or 1 gram if the total contents are less than 100 grams) when stored for 18 hours at 55° C. This tempera-ture may be reduced to 45° C for carriage solely within temperate cli-mates (i.e. in latitudes greater than 30 North or South). A label of class 2.1 applies if the contents include more than 45%, by mass, or more than 250 g of flammable components. Flammable components are gases which are flammable in air at normal pressure or substances or preparations in liquid form which have a flashpoint less than or equal to 100° C. The provisions of this Code should not apply to aerosols with a ca-pacity of less than 50 cm3 . The provisions of this Code should not apply to aerosols with a capac-ity of 1000 cm3 or less when the following conditions are met: - no flammable gas present; - internal pressure not greater than 8.4 kg/cm8 gauge at 55° C; - less than 10% , by mass of the total contents consisting of flammable

liquid; - less than 1% , by mass of toxic substances present in liquid concen-

trate; - less than 0.2%, by mass of corrosive substances present in the liquid

concentrate.

CLASS 2 - G a s e s

Packing The outer packagings should comply with the provisions of An-nex 1 to this Code for packagings of packaging group II (medium danger). For AEROSOLS with a capacity of 1000 cm3 or less the following packagings* may also be used.

Package gross

1 Wooden box 125 kg 2 Fibreboard box 55 kg 3 Shrink-wrapped or stretch-wrapped trays

(meeting the conditions set out in sections 3.1, 3.2 and 3.4 to 3.8 of Annex I to this Code).

20 kg

* The packaging performance tests referred to in section 10 of the General Introduction and in Annex I of this Code need not apply.

Stowage For AEROSOLS with a capacity above 1000 cm3 Category B. For AEROSOLS with a capacity of 1000 cm3 or less Category A. Seg-regation as for class 9 but "away from sources of heat and «SEPA-RATED FROM» goods of except from those in division 1.4.

Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

IMDG CODE - PAGE 2102a (page 2102-1 follows) Amdt. 28-96

CLASS 2 - G a s e s

Observations The provisions of this Code should not apply to air bags or seat-belts installed in vehicles or in completed vehicle components such as steering columns, door panels, seats, etc.

Packing Units should be designed or packaged for transport so that when engulfed in a fire there will be no fragmentation of the pressure ves-sel or projection hazard. This should be determined by analysis. The pressure vessel should be in compliance with the requirements for the gas(es) contained in the pressure vessel.

Stowage Category A


IMDG CODE - PAGE 2102-1 (page 2703 follows) Amdt. 29-98

AIR BAG INFLATORS, COMPRESSED GAS or AIR BAG MODULES, COM-PRESSED GAS or SEAT-BELT PRE-TENSIONERS, COMPRESSED GAS [new schedule]

UN No. 3353

Formula Explosive

limits

Properties This entry applies to articles which are used as life-saving vehicle air bag inflators or air bag modules or seat-belt pretensioners, containing a gas or a mixture of compressed gases classified under class 2.2, with or without small quantities of pyrotechnic material. For units with pyrotechnic material, initiated explosive effects should be contained within the pressure vessel such that the unit, when tested, may be excluded from in accordance with 1.11 (b), in conjunction with 16.61.4.7 (a) (ii) of the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Part 1.

Label of class

2.2

CLASS 2 - G a s e s


CLASS 2 - G a s e s

UN No. Formula Explosive limits

2188 AsH3 3.9% to 77.8%

Properties Flammable, toxic colourless gas with a garlic odour. Much heavier than air (2.8) Observations Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D Clear of living quarters Packing, Stowage & Segregation See also General Introduction and introduction to this class.

IMDG CODE – PAGE 2106 Amdt. 29-98

ARSINE

ARSENIC HYDRIDE HYDROGEN ARSENIDE

Label of class

2.3 Subsidiary risk label

of class

2.1

ARTICLES, PRESSUR-IZED PNEUMATIC or HYDRAULIC (containing non-flammable gas)

Label of class

2.2 MARINE POLLUTANT mark

(for marine pollutants only)


3164 None

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with " P " or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Articles containing non-flammable, non-toxic gas necessary for their operation. Observations Articles intended to function as shock absorbers are not subject to the provisions of this Code provided that each article: 1. has a gas space capacity not exceeding 1 litre and a charge pres-

sure not exceeding 50 bar; 2. has a minimum burst pressure of 4 times the charge pressure at

20° C; 3. is manufactured from material which will not fragment upon rup-

ture; 4. when subjected to fire, is protected from rupture by means of a

fire degradable seal or a pressure relief device to relieve internal pressure; and

5. is manufactured in accordance with a quality assurance standard acceptable to the competent authority.

Packing The outer packagings should comply with the provisions of Annex I to this Code for packagings of packaging group III. Stowage Category A Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

CLASS 2 - G a s e s


1741 BCI3 None

Properties Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen chloride, and irritat-ing and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Much heavier than air.

Observations Highly irritating to skin, eyes and mucous membranes. Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Shade from radiant heat. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


1008 BF3 None

Properties Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. Corrosive to glass and to most metals. Much heavier than air (2.35).

Observations Highly irritating to skin, eyes and mucous membranes. Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


BORON TRICHLORIDE

Label of class


of class

8

BORON TRIFLUORIDE, COMPRESSED

BORON FLUORIDE, COMPRESSED

Label of class

2.3 Subsidiary risk label of

class

8

CLASS 2 - G a s e s


2202 H2Se

Properties Flammable, toxic, colourless gas with a disagreeable odour Much heavier than air (2.8).

Observations Highly irritating to skin, eyes and mucous membranes.

Packing For packing specifications, see section 2 of the introduction to this class.

Stowage Category D. Clear of living quarters.



HYDROGEN SELENIDE, ANHYDROUS

SELENIUM HYDRIDE HY-DROSELENIC ACID, ANHY-DROUS

Label of class


class

2.1

HYDROGEN SULPHIDE

SULPHURETTED HYDROGEN


1053 H2S 4% to 46% Properties Liquefied, flammable, toxic gas with a foul odour. Heav-ier than air (1.2).

Observations




Label of class


of class

2.1

CLASS 2 - G a s e s

Properties

MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Toxic mixtures of insecticides with liquefied gases. These mixtures may be flammable.

Observations

Packing For packing specifications see section 2 of the introduction to this class.



IMDG CODE - PAGE 2152 (page 2152-1 follows) Amdt. 28-96


1968 Variable Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with " P " or 1% or more of substance(s) identified with "PP” in the General Index to this Code. Mixtures of insecticides with liquefied gases. These mixtures may be flammable. Observations


Stowage Non-flammable gas category A. Flammable gas category D.


INSECTICIDE GAS, N.O.S.

Label ACCORDING TO PROPERTIES MARINE POLLUTANT mark (for marine pollutants only)

INSECTICIDE GAS, TOXIC, N.O.S. UN No. Formula Explosive limits

1967 Variable

Label of class



CLASS 2 - G a s e s


3354 Variable

INSECTICIDE GAS, FLAM-MABLE, N.O.S. [new schedule]

Properties

MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Flammable mixtures of insecti-cides with liquefied gases. Observations

Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.


3355 Variable INSECTICIDE GAS, TOXIC, FLAMMA-BLE, N.O.S. [new schedule]

Properties

MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Toxic flammable mixtures of in-secticides with liquefied gases. Observations

Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.


Label of class



Label of class


class



CLASS 2 - G a s e s


CLASS 2 - G a s e s

Properties Non-flammable, odourless gas. Lighter than air (0.97).

Observations


Stowage Category A.


Properties Liquefied, non-flammable, odourless gas. Lighter than air (0.97)

Observations The provisions of this schedule should not apply to liquid nitrogen carried on board ship for cooling purposes for certain goods shipped in closed freight containers or vehicles. Arrangements for the con-tainment of the liquid nitrogen and fittings in use should be appropri-ate to the potential danger to the structure of the freight container or ship from the effect of misuse or accidental spillage of the gas.

Packing For packing specifications, see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction.

Stowage Category D.



NITROGEN COMPRESSED UN No. Formula Explosive limits

1066 N2 None

Label of class

2.2

NITROGEN, REFRIGERATED, LIQUID UN No. Formula Explosive limits

1977 N2 None

Label of class

2.2

CLASS 2 - G a s e s


2451 NF3 None

Properties Non-flammable non-toxic colourless odourless stable gas. Strong oxidizing agent reacts violently with many substances e.g. grease oil etc. Much heavier than air (2.4).

Observations May cause slight eye irritation.





2421 N2O3 None

Properties Liquefied non-flammable toxic and corrosive gas. At lower tem-peratures present as a blue liquid. Strong oxidizing agent. Much heavier than air (2.6). Boiling point 3.5° C.

Observations Highly irritating to skin eyes and mucous membranes.


Stowage Category D. Clear of living quarters. Segregation as for class 51, but separated from class 7.



NITROGEN TRIFLUORIDE, COM-PRESSED

Label of class


of class

5.1

NITROGEN TRIOXIDE

NITROGEN SESQUIOXIDE

DINITROGEN TRIOXIDE

Label of class

2.3 Subsidiary risk labels of

classes

5.1and 8

CLASS 2 - G a s e s


3083 ClO3F

Properties Non-flammable toxic colourless gas with a characteristic sweet odour. Strong oxidizing agent may cause fire in contact with organic materials. Reacts with water or moist air to produce toxic and corrosive fumes. Mixtures with oils or combustible materials may explode. Much heavier than air (3.6).

Observations Irritating to skin eyes and mucous membranes.





PENTAFLUOROETHANE RE-FRIGERANT GAS R 125

Label of class

2.2

UN No Formula Explosive limits

3220 C2HF5 None Properties Liquefied non-flammable gas with a mild ethereal odour. Much heavier than air (4.2).

Observations

Packing For packing specifications see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction.

Stowage Category A.


PERCHLORYL FLUORIDE

Label of class


class

5.1

CLASS 2 - G a s e s


PERFLUORO(ETHYL, VINYL ETHER)

PENTAFLUOROETHYL TRIFLUOROVINYL ETHER, PEN-

TAFLUOROETHOXY- TRIFLUOROETHYLENE.

Label of class

2.1


3154 CF3CF2OCF-CF2 7% to 73% Properties Liquefied, flammable gas. Much heavier than air (6.4). Boiling point. 12°C.

Observations


Stowage Category E. Clear of living quarters.


PERFLUORO(METHYL, VINYL ETHER)

TRIFLUOROMETHYL TRIFLUOROVINYL ETHER TRIFLUOROMETHOXY- TRIFLUOROETHYLENE

Label of class

2.1


3153 CF3OCF-CF2 7% to 73%

Properties Liquefied, flammable gas. Much heavier than air (4.8). Boiling point -27°C.

Observations




CLASS 2 - G a s e s


1078 None REFRIGERANT GAS, N.O.S.

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Different chloro-fluoro-hydrocarbons or other non-flammable, non-toxic gases considered as refrigerant agents.

Observations


Stowage Category A.



Label of class



REFRIGERATING MACHINES con-taining non-flammable, non-toxic liq-uefied gas or ammonia solution (UN No. 2672)

Label of class

2.2


2857

Properties Refrigerating machines include air conditioning units and machines or other appliances which have been designed for the specific purpose of keeping food or other items at a low temperature in an internal compartment.

Observations The provisions of this Code should not apply to refrigerating machines containing less than 12 kg non-flammable, non-toxic liquefied gas or if containing less than 12 l of ammonia solution. (UN No. 2672)

Packing May be carried unpacked or in crates.

Stowage Category A.


CLASS 2 - G a s e s


REFRIGERANT GAS R 404A

PENTAFLUOROETHANE 1,1,1-TRIFLUOROETHANE, AND 1,1,1,2-TETRAFLUORO-ETHANE ZEOTROPIC MIXTURE WITH AP-PROXIMATELY 44% PENTA-FLUOROETHANE AND 52% 1,1,1-TRIFLUOROETHANE [new schedule]

Label of class

2.2


3337 Properties Liquefied non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.06).

Observations Very high exposures may cause anaesthetic effects and asphyxia-tion.


Stowage Category A.


REFRIGERANT GAS R 407A

DIFLUOROMETHANE PENTA-FLUOROETHANE AND 1,1,1,2-TETRAFLUOROETHANE ZEOTROPIC MIXTURE WITH AP-PROXIMATELY 20% DIFLUORO-METHANE AND 40% PENTA-FLUOROETHANE (new schedule]

Label of class

2.2


3338 Properties Liquefied non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.1 7).


Packing For packing specifications see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction.

Stowage Category A.


CLASS 2 - G a s e s


REFRIGERANT GAS R 407B

DIFLUOROMETHANE PENTAFLUORO-ETHANE AND 1,1,1,2-TETRAFLUOROETHANE ZEOTROPIC MIXTURE WITH APPROXI-MATELY 10% DIFLUOROMETHANE AND 70% PENTAFLUOROETHANE [new schedule]

Label of class

2.2


3339 Properties Liquefied non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.19).



Stowage Category A.


REFRIGERANT GAS R 407C

DIFLUOROMETHANE, PENTA-FLUOROETHANE AND 1,1,1,2-TETRAFLUOROETHANE ZEOTROPIC MIXTURE WITH AP-PROXIMATELY 23% DIFLUORO-METHANE AND 25% PENTA-FLUOROETHANE [new schedule]

Label of class

2.2


3340 Properties Liquefied, non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.16).

Observations Very high exposures may cause anaesthetic effects and asphyxiation.


Stowage Category A.


CLASS 2 - G a s e s


2203 SiH4 1% to 100%

Properties Flammable, colourless gas with a foul odour. Ignites spontaneously in air. Strong reducing agent which reacts violently with oxidizing substances. Heavier than air (1.1).

Observations


Stowage Category E. Clear of living quarters. «SEPARATED FROM» bromine and chlorine.



SELENIUM HEXAFLUORIDE

Label of class


class

8


2194 SeF6 Properties Colourless, toxic and corrosive gas. Corro-sive to glass and to most metals. Heavier than air.

Observations Highly irritating to skin, eyes and mucous membranes.


Stowage Category D. Clear of liv-ing quarters.


SILANE, COMPRESSED

HYDROGEN SILICIDE, COMPRESSED SILICON TET-RAHYDRIDE, COMPRESSED

Label of class

2.1

CLASS 3 – F l a m m a b l e l i q u i d s

1.25 The substances are arranged in alphabetical order of proper shipping names within each flashpoint group, and commonly used synonyms have been included.

1.3 The vapours from all substances of class 3 have a narcotic effect, and prolonged inhalation may result in uncon-sciousness. Deep or prolonged narcosis may lead to death.

1.31 Some flammable liquids also have specific toxic or corrosive effects, and this has been indicated in the individual schedules where appropriate.

1.32 A number of flammable liquids have been identified as harmful to the marine environment (MARINE POLLUT-ANT), and this has been indicated in the individual schedules where appropriate.

1.4 Some substances in this class, under conditions incident to transport, are liable to polymerize (combine or react with themselves) so as to cause dangerous liberation of heat or gas, possibly resulting in rupture of the recepta-cle. These substances should not be transported unless they are properly inhibited.

1.5 Where explosive limits are given, these refer to the volume percentage of the vapour of the substance when mixed with air.

1.6 The ease and extent to which different liquids mix with water varies greatly and most individual schedules have included an indication of miscibility. In these cases "miscible with water" normally means capable of being mixed with water in all proportions to form a completely homogeneous liquid.

2 STANDARDIZATION OF THE FLASHPOINT TEST METHOD

2.1 Information in this respect will be found in section 6 of the General Introduction.

3 PACKING

3.1 Classification and grouping criteria.

3.1.1 Flammable liquids have for packing purposes been apportioned among three categories (packaging groups) according to the degree of danger they present great danger (packaging group I), medium danger (packaging group II) and minor danger (packaging group III). The packaging group to which a substance is assigned is given in its individual schedule.



3.1.2 The packaging group of a flammable liquid for which no specific packaging group is given in the individual sched-ule should be assigned in accordance with the following table. However, if the liquid possesses more than one hazard the packaging group should be determined in accordance with subsection 5.2 of the General Introduction.

Hazard grouping based on flammability

Flammable liquids are grouped for packing purposes according to their flashpoint their boiling point and their viscosity. The table shows the relationship existing between two of these characteristics.

Packaging group Flashpoint in °C closed cup (c.c. ) Initial boiling point in °C

| - ≤35 II <23 >35 III >23 to ≤61 >35

Viscous substances having a flashpoint below 23° C c.c. may be placed in packaging group III in conformity with 3.1.3 and 3.1.4.

Substances classified as flammable liquids due to their being transported or offered for transport at elevated temperatures are included in packaging group III.

3.1.3 Determination of grouping of flammable viscous substances with a flashpoint of less than 23° C c.c.

The packaging group of paints adhesives and other viscous flammable liquids with a flashpoint of less than 23° C c.c. is determined by reference to:

1 the viscosity expressed as the flow time in seconds (refer to ISO standard 2431-84); 2 the closed cup flashpoint; and 3 a solvent separation test.

3.1.4 Criteria for inclusion in packaging group III

Viscous flammable liquids such as paints and adhesives with a flashpoint below 23° C c.c. are included in pack-aging group III provided that:

1 less than 3% of the clear solvent layer separates in the solvent separation test;

2 the mixture does not contain any substances with a primary or a subsidiary risk of class 6.1 or class 8.



3.3.1.1 Glass receptacles packaged in an outer packaging should be surrounded by inert cushioning material so arranged as to prevent breakage and leakage from the package. For substances in class 3.1 this cushioning material should also be absorbent. This is not necessary if close-fitting parts of expanded plastics are used as cushioning material and the requirements of the second sentence of 3.3.1.5 are met when appropriate.

3.3.1.2 Where glass is permitted, it should be understood to include earthenware, porcelain and other comparable mate-rials unless stipulated otherwise.

3.3.1.3 Where glass or plastics receptacles are permitted it should be understood that glass or plastics bottles or jars are included.

3.3.1.4 Where wooden boxes are permitted as outer packaging it should be understood that boxes of natural wood (4C1, 4C2), plywood boxes (4D) and reconstituted wood boxes (4F) are included.

3.3.1.5 Moulded expanded plastics boxes (4H1) should be constructed of a fire-resistant grade of plastics material. When the contents are not compatible with the outer packaging, each glass bottle should be enclosed in a bag made of plastics material compatible with the contents and the bag should be effectively closed.

3.3.1.6 Where for substances in the intermediate and high flashpoint groups, packaging groups I or II fibreboard boxes are specified a fibreboard box reinforced by wood or other suitable material with a maximum gross mass of 55 kg may be used provided that it is water-resistant and compatible with the substance to be carried.

3.3.2 A cylinder of the kind normally used for compressed gases, approved by the competent authority of the country concerned and with suitable valve protection may be used to contain any flammable liquid, provided that this liquid is compatible with the material of construction.

3.3.3 Removable head packagings should not be used for the transport of liquids except that steel and aluminium re-movable head drums or jerricans may be used for liquids in packaging groups II and III, when these packagings successfully pass the test for liquids.

3.3.4 Viscous flammable liquids in the low or intermediate flashpoint groups are included in packaging group III if they meet the criteria in 3.1.4. In such cases, packagings indicated in the table for liquids in the high flashpoint group, packaging group III, may be used.

IMDG CODE - PAGE 3007 (page 3009 follows) Amdt. 29-98


3.4 Packaging specifications [new table]

Maximum gross mass or maximum liquid contents

Packaging group Inner packaging Outer packaging Packaging code (Annex I)

I II III Drums - Steel 1A2 75 kg 125 kg 125 kg Aluminium 1B2 75 kg 125 kg 125 kg Plywood 1D 75 kg 125 kg 125 kg

Receptacles, glass, por-celain and stoneware, maximum contents 10 litres or Fibre 1G 75 kg 125 kg 125 kg Plastics 1H2 75 kg 125 kg 125 kg

Jerricans - Steel 3A2 60 kg 120 kg 120 kg Aluminium 3B2 60 kg 120 kg 120 kg

Receptacles, plastics, maximum contents 30 litres, or Plastics 3H2 30 kg 60 kg 60 kg

Boxes - Steel 4A 75 kg 125 kg 125 kg Aluminium 4B 75 kg 125 kg 125 kg Plywood 4D 75 kg 125 kg 125 kg

Receptacles, metal, maximum contents 40 litres

Natural wood 4C1, 4C2 75 kg 125 kg 125 kg Reconstituted wood 4F 75kg 125 kg 125 kg

Solid plastics 4H2 75 kg 125 kg 125 kg Boxes - Fibreboard 4G 401 kg 551 kg 551 kg

Boxes - Moulded expanded plastics 4H1 40 kg 55 kg 55 kg

Drums - Steel 1A1 250 litres 250 litres 250 litres Steel 1A2 Prohibited 2504 litres 2504 litres Aluminium 1B1 250 litres 250 litres 250 litres Aluminium 1B2 Prohibited 2504 litres 2504 litres Drums - Plastics 1H1 2502 litres 250 litres 250 litres Jerricans - Steel 3A1 60 litres 60 litres 60 litres Steel 3A2 Prohibited 604 litres 604 litres Aluminium 3B1 60 litres 60 litres 60 litres Aluminium 3B2 Prohibited 604 litres 604 litres Plastics 3H1 602 litres 60 litres 60 litres Cylinders According to the design type3 Plastics receptacle in a: steel crate or box 6HA2 602 litres 60 litres 60 litres aluminium crate or box 6HB2 602 litres 60 litres 60 litres wooden box 6HC 602 litres 60 litres 60 litres plywood box 6HD2 602 litres 60 litres 60 litres fibreboard box 6HG2 602 litres 60 litres 60 litres solid plastics box 6HH2 602 litres 60 litres 60 litres

Notes: 1 When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100 kg for packaging

groups II and III and 75 kg for packaging group I.

2 Not permitted for class 3, packaging group I.

3 Cylinders of carbon steel, special steels, copper alloy and aluminium alloy ≤ 150 litres Receptacles of carbon steel, special steels, copper alloy and aluminium alloy ≥ 100 to ≤1000 litres.

4 Tested for liquids.



[new table]


Packaging group Table 3.4 (continued) Packaging code (Annex 1)

I II III Plastics receptacle in a plywood drum 6HD1 1202 litres 250 litres 250 litres fibre drum 6HG1 1202 litres 250 litres 250 litres plastics drum 6HH1 1202 litres 250 litres 250 litres Plastics receptacle in a steel drum 6HA1 250 litres 250 litres 250 litres aluminium drum 6HB1 250 litres 250 litres 250 litres Glass receptacle in a steel drum 6PA1 602 litres 60 litres 60 litres steel crate or box 6PA2 602 litres 60 litres 60 litres aluminium drum 6PB1 602 litres 60 litres 60 litres aluminium crate or box 6PB2 602 litres 60 litres 60 litres wooden box 6PC 602 litres 60 litres 60 litres plywood drum 6PD1 602 litres 60 litres 60 litres plywood box 6PD2 602 litres 60 litres 60 litres fibre drum 6PG1 602 litres 60 litres 60 litres fibreboard box 6PG2 602 litres 60 litres 60 litres expanded plastics drum 6PH1 602 litres 60 litres 60 litres solid plastics drum 6PH2 602 litres 60 litres 60 litres


CLASS 3.1 – F l a m m a b l e l i q u i d s


Low flashpoint group

MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S.

Packaging group: II

Label of class

3 Subsidiary risk label of class

6.1


UN No. Formula Explosive Limits Flashpoint

3248 * below -18° C c.c.

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code.

Observations Toxic if swallowed by skin contact or by inhalation. The technical name of only the flammable liquid component of this solution or mixture should be shown in parentheses immediately following the proper shipping name. * Also listed in intermediate and high flashpoint groups.

Packing See table 3.4 in the introduction to this class. Maximum net quan-tity per inner receptacle 5 litres or 5 kg.






MERCAPTANS, LIQUID, FLAMMA-BLE, N.O.S. or MERCAPTAN MIX-TURE, LIQUID FLAMMABLE, N.O.S. [new schedule]

Packaging group: I or II according to the grouping criteria for each hazard

Label of class

3



3336 * below -18° C c.c.

Properties MARINE POLLUTANT

Applicable only to products containing 10% or more of substance(s) identified with "P" or 1 % or more of substance(s) identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour which may affect all odour absorbing cargoes. Immiscible with water.

Observations *Also listed in intermediate and high flashpoint groups.

Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.

Stowage Category E. «SEPARATED FROM» foodstuffs.





MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or

MERCAPTAN MIXTURE, LIQUID, FLAMMA-BLE, TOXIC, N.O.S.

Packaging group: II Label of class


6.1



1228 * below -18° C c.c.


Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour. Immiscible with water.

Observations Toxic if swallowed by skin contact or by inhalation. For MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S., UN No. 3071, see class 6.1. * Also listed in intermediate and high flashpoint groups.


Stowage Category E. Clear of living quarters. «SEPARATED FROM» foodstuffs and all other odour-absorbing cargoes.





NITRITES, FLAMMABLE, TOXIC, N.O.S.

CYANIDES, ORGANIC, FLAMMABLE, TOXIC, N.O.S.

Packaging group: I or II according to the grouping criteria for

each hazard

Label of class


6.1



3273 * below -18° C c.c.


Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids evolving toxic vapour. React with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas.

Observations Toxic if swallowed, by skin contact or by inhalation. For NITRILES, TOXIC, FLAMMABLE, N.O.S. , UN No. 3275, see class 6.1 * Also listed in intermediate flashpoint group.

Packing See table 3.4 in the introduction to this class. For tanks see section 13 of the General Introduction.

Stowage Category E. Clear of living quarters. «SEPARATED FROM» acids.





NITROCELLULOSE SOLUTION, FLAMMA-BLE, with not more than 12 6% nitrogen, by dry mass, and not more than 55% nitrocellu-lose

CELLULOSE NITRATE SOLUTION, COL-LODION SOLUTION, LACQUER BASE SO-LUTION, NITROCOTTON SOLUTION, PY-ROXYLIN SOLUTION

Packaging group: I or II according to the grouping crite-ria for flammable liquids

Label of class

3


2059 *below -18°C c.c. Properties When involved in a fire, evolves toxic nitrous fumes.

Observations For NITROCELLULOSE WETTED with not less than 25% alcohol by mass, UN No. 0342, see . For PAINT or PAINT RELATED MATERIAL containing 20% or less nitrocellulose with not more than 12.6% nitrogen, see UN No. 1263 in this class. For PRINTING INK, flammable, containing 20% or less nitrocellulose, see UN No. 1210 in this class. * Also listed in intermediate and high flashpoint groups.


Stowage Category E.





NITROGLYCERIN MIXTURE, DESENSI-TIZED, LIQUID, FLAMMABLE, N.O.S., with not more than 30% nitroglycerin, by mass [new schedule]

Packaging group: as assigned by the competent authority on the basis of the criteria set out in paragraph 3.1.2 of the introduction to this class.

Label of class

3



3343 * below -18° C c.c.


Observations * Also listed in intermediate and high flashpoint groups. These substances should not be classified and transported unless authorized by the competent authority on the basis of results from. Series 2 tests and a Series 6(c) test on packages as prepared for transport (see the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria).

Packing As approved by the competent authority who should assign the pack-age type according to that used for the Series 6(c) test (see the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria).

Stowage Category D.




Intermediate flashpoint group

2-BROMOETHYL, ETHYL, ETHER

Packaging group: II

Label of class

3


2340 BrCH2CH2OC2H5 -18°C to 23°C c.c.

Properties Colourless liquid with an ethereal odour. Partially miscible with water.

Observations Harmful by inhalation.


Stowage Category B. Clear of living quarters.



BROMOMETHYLPROPANES

ISOBUTYL BROMIDE tertiary-BUTYL BROMIDE

Packaging group: II

Label of class

3


2342 C4H9Br -18°C to 23°C c.c. Properties Colourless liquids. Im-miscible with water.



Stowage Category B.





2-BROMOPENTANE

secondary-AMYL BROMIDE

Packaging group: II

Label of class

3


2343 C5H11Br 21° C c.c.

Properties Colourless or yellow liquid with a strong odour. Im-miscible with water.



Stowage Category B.



BROMOPROPANES

ISOPROPYL BROMIDE PROPYL BROMIDES

Packaging group: II

Label of class

3


2344 C3H7Br * -18° C to 23° C c.c. Properties Colourless liquids. Immiscible with water. When involved in a fire evolve toxic fumes.

Observations Harmful by inhalation. * Also listed in high flashpoint group.







MEDICINE LIQUID, FLAMMABLE, TOXIC, N.O.S.

Packaging group: II

Label of class


6.1



3248

-18° C to 23° C c.c.


Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code.

Observations Toxic if swallowed by skin contact or by inhalation. The technical name of only the flammable liquid component of this solution or mixture should be shown in parentheses immediately following the proper shipping name. * Also listed in low and high flashpoint groups.

Packing See table 3.4 in the introduction to this class. Maximum net quan-tity per inner receptacle 5 litres or 5 kg.






MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN FLAMMABLE, N.O.S. [new schedule] MIXTURE, LIQUID,

Packaging group: I or II according to the grouping criteria

for flammable liquids.

Label of class

3



3336 * -18° C c.c. to 23°C c.c.


Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour which may affect all odour absorbing cargoes. Immiscible with water.

Observations *Also listed in low and high flashpoint groups.


Stowage Category B. Separated from foodstuffs.





MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S.

Packaging group: II

Label of class


6.1



1228 * -18° C to 23° C c.c. Properties MARINE POLLUTANT

Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substances identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour. Immiscible with water.

Observations Toxic if swallowed by skin contact or by inhalation. For MERCAPTANS LIQUID TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. UN No. 3071, see class 6.1. * Also listed in low and high flashpoint groups.


Stowage Category B. Clear of living quarters. Separated from foodstuffs and all other odour-absorbing cargoes.





NITRILES, FLAMMABLE, TOXIC, N.O.S. CYANIDES, ORGANIC, FLAMMABLE, TOXIC, N.O.S.

Packaging group: I or II accord-ing to the grouping criteria for

each hazard

Label of class


6.1



3273 * 18° C to 23° C c.c.


Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids evolving toxic vapour. React with acid or acid fumes evolving hydrogen cyanide a highly toxic and flammable gas.

Observations Toxic if swallowed by skin contact or by inhalation. For NITRILES, TOXIC, FLAMMABLE, N.O.S., UN No. 3275 see class 6.1. * Also listed in low flashpoint group.


Stowage Category B. Clear of living quarters. Separated from acids.





NITROCELLULOSE SOLUTION, FLAMMABLE, with not more than 12.6% nitrogen by dry mass, and not more than 55% nitrocellulose. CELLULOSE NITRATE SOLUTION, COL-LODION SOLUTION, LACQUER BASE SO-LUTION, NITROCOTTON SOLUTION, PY-ROXYLIN SOLUTION.

Packaging group: I or II according to the grouping criteria for flammable liquids.

Label of class

3


2059 * -18° C to 23° C c.c.

Properties When involved in a fire, evolves toxic nitrous fumes.

Observations For NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass, UN No. 0342, see . For PAINT or PAINT, RELATED MATERIAL containing 20% or less nitrocellulose, with not more than 12.6% nitrogen, see UN No. 1263 in this class. For PRINTING INK, flammable, containing 20% or less nitrocellulose, see UN. No 1210 in this class. * Also listed in low and high flashpoint groups.


Stowage Category B.





NITROGLYCERIN MIXTURE, DESENSI-TIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass

[new schedule]

Packaging group: as assigned by the competent authority on the basis of the criteria set out in paragraph 3.1.2 of the introduc-tion to this class.

Label of class

3



3343 * -18° C c.c. to 23° C c.c.


Observations

*Also listed in low and high flashpoint groups. These substances should not be classified and transported unless authorized by the competent authority on the basis of results from. Series 2 tests and a Series 6(c) test on packages as prepared for transport (see the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria).


Stowage Category D.





NITROGLYCERIN SOLUTION IN ALCO-HOL with not more than 1% nitroglycerin. GLYCERYL TRINITRATE.

Packaging group: II

Label of class

3


1204 C3H5(NO3)3 -18° C to 23° C c.c.

Properties Immiscible with water. Ignites readily. When involved in a fire evolves toxic nitrous fumes.

Observations Not explosive in this state but damage to or leakage from a package may allow solvent to evaporate and thus leave the nitroglycerin in an explosive state. Refuse for shipment damaged or leaking packages For NITROGLYCERIN SOLUTION IN ALCOHOL containing more than 1% but not more than 10% nitroglycerin in solution in alcohol, see UN No. 0144 . For NITROGLYCERIN, SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin, see UN No. 3064 in this class.

Packing See table 3 4 in the introduction to this class. Transport in tanks p r o h i b i t e d .

Stowage Category B.





PAINT (including paint, lacquer, enamel, stain shellac, solutions, varnish, polish liquid, filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound).

Packaging group: I or II according to the grouping cri-teria for flammable liquids.**

Label of class

3



1263

* -18° C to 23° C c.c.


Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Miscibility with water depends upon the composition

Observations May contain 20% or less nitrocellulose provided the nitrocellulose contains not more than 12.6% nitrogen. A substance specifically identified by name in this Code should not be shipped under this entry. * Also listed in low and high flashpoint groups. ** Packaging group III if the criteria set out in 3.1.4 of the introduction to this class are met.

Packing See 3.2.6 and table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.

Stowage Category B.





PERFUMERY PRODUCTS, flammable liquid. COSMETICS.

Packaging group: II**

Label of class

3



1266 *-18°C to 23° C c.c.


Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Miscibility with water depends upon the composition.

Observations * Also listed in high flashpoint group. ** Packaging group III if the criteria set out in 3.1.4 of the introduction. to this class are met.


Stowage Category B.





PENTANOLS. AMYL ALCOHOLS, METHYLBU-TANOLS.

Packaging group: II

Label of class

3


1105 C5H11OH 1.2% to 10.5% * -18° C to 23° C c.c. Properties Colourless liquids with a strong odour. Immiscible with water. tertiary-AMYL ALCOHOL, flashpoint 19°C to 21°C c.c.

Observations * Also listed in high flashpoint group.


Stowage Category B.



Intermediate flashpoint group UN No.

PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3021

CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2758

ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2760

ORGANOCHLORINE PESTICIDE, LIQUID, FLAM-MABLE, TOXIC 2762

TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2764

THIOCARBAMATE PESTICIDE, LIQUID, FLAM-MABLE, TOXIC 2772

COPPER BASED PESTICIDE, LIQUID, FLAMMA-BLE, TOXIC 2776

MERCURY-BASED PESTICIDE, LIQUID, FLAM-MABLE, TOXIC 2778

SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2780

BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMA-BLE, TOXIC 2782

ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2784

ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2787

COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3024

PHENOXYACETIC ACID DERIVATIVE PESTI-CIDE, LIQUID, FLAMMABLE, TOXIC 3346

PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3350

Formula Explosive Lim-

its Flashpoint

-18° C to 32° C c.c.

Properties

MARINE POLLUTANT

Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composi-tion.

Observations Toxic if swallowed, by skin contact or by inhalation. The name and concentration of the active pesticide substance or substances should be mentioned in the shipping documents when a pesticide is offered for shipment. For PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., with a flashpoint between 23° C and 61° C c.c., see UN No. 2903, class 6.1.

Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduc-tion. For tanks see section 13 of the General Introduc-tion.

Packaging group: I or II according to grouping

criteria for each hazard

Label of class





Stowage Category B. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollu-tion Aspects See also General Introduction and introduction to this class.



AMYL ALCOHOLS

entry moved to page 3269-1





AMYLAMINES. PENTYLAMINES, normaI-AMYLAMINE, 1-PENTYLAMINE, tertiary-AMYLAMINE, 3-PENTYLAMINE.

Packaging group: II

Label of class


8


1106 C5H11NH2 2.2% to 22% * -7°C to 23°C c.c. Properties Colourless, clear liquids. normal-AMYLAMINE (1-PENTYLAMINE) flashpoint 4° C c.c. tertiary-AMYLAMINE (3-PENTYLAMINE) flashpoint 2° C c.c. Miscible with water.

Observations Harmful by inhalation. Cause burns to skin eyes and mucous membranes. * Also listed in high flashpoint group.


Stowage Category B.



AMYL CHLORIDES. CHLOROPENTANES, 1-CHLORO-3-METHYLBUTANE, 2-CHLORO-2-METHYLBUTANE, nor-maI-AMYL CHLORIDE.

Packaging group: II

Label of class

3


1107 C5H11CI -18° C to 23°C c.c. Properties Colourless or light brown liquids with an aromatic odour. Explosive limits normal AMYL CHLORIDE 1.4% to 8.6% Immiscible with water.

Observations


Stowage Category B.



CLASS 3.2 - Flammable liquids

Intermediate flashpoint group UN No. Formula Explosive Limits Flashpoint

Petroleum products* * -18° C to 23° C c.c.

FUEL, AVIATION, TURBINE ENGINE, AVIATION GASOLINE 1863

PETROLEUM CRUDE OIL 1267

PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 1268 ‡

SHALE OIL 1288 §

TURPENTINE SUBSTITUTE, WHITE SPIRIT

1300 ‡§


Packaging group: I or II accord-ing to the grouping criteria for flammable liquids.

Label of class

3



‡ WHITE SPIRIT low aromatic (15% - 20%) is a MARINE POLLUTANT § Packaging group II only. Immiscible with water.

Observations * Also listed in low and high flashpoint groups.


Stowage Category B.




Intermediate flashpoint group UN No. Formula Explosive Limits Flashpoint

POLYESTER RESIN KIT 3269 * -18° C to 23° C c.c.

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Polyester resin kits consist of two components a base material (flammable liquid, packaging group II) and an activator (organic peroxide), each separately packed in an inner packaging.

Observations The organic peroxide should be type D, E or F, not requiring tem-perature control and should be limited to a quantity of 125 ml per inner packaging, if liquid, and 500 grams, if solid. The components may be placed in the same outer packaging provided they will not interact dangerously in the event of leakage.

* Also listed in high flashpoint group.

Packing Package gross Wooden box (4C1), (4D), (4F) 125 kg Fibreboard box (4G) 40 kg Moulded expanded plastics box (4H1) 40 kg Solid plastics box (4H2) 125 kg

Stowage Category B.

Packing, Stowage, Segregation and Marine Pollution Aspects See also General Introduction and introduction to this class.


Packaging group: II

Label of class

3





PRINTING INK, flammable

Packaging group: I or II** according to the grouping crite-

ria for flammable liquids

Label of class

3


1210 * -18° C to 23° C c.c. Properties Fluid or viscous liquid containing colouring matter in solution or suspension. Miscibility with water depends upon the solvent. Observations May contain 20% or less nitrocellulose provided the nitrocellulose contains not more than 12.6% nitrogen. A substance specifically iden-tified by name in this code should not be shipped under this entry. * Also listed in low and high flashpoint groups. ** Packaging group III if the criteria set out in 3.1.4 of the introduction to this class are met. Packing See table 3.2.6 and 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


normal-PROPANOL 1-PROPANOL, normal-PROPYL ALCOHOL

Packaging group: II

Label of class

3

UN No. Formula Explosive Lim-its Flashpoint

1274 CH3CH2CH2OH 2% to 12% * 15° C to 23° C c.c.

Properties Colourless liquid. Mis-cible with water. Observations * Also listed in high flashpoint group.

Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.



PROPIONITRILE. ETHYL CYANIDE.

Packaging group: II

Label of class


6.1


2404 CH3CH2CN 3.1 % to 2° C c.c. Properties Colourless volatile liquid with an ethereal odour. Miscible with water. When involved in a fire, evolves highly toxic cyanide fumes.

Observations Toxic if swallowed by skin contact or by inhalation.





PROPIONYL CHLORIDE. PROPANOYL CHLORIDE.

Packaging group: II

Label of class


8


1815 CH3CH2COCI 12° C c.c.

Properties Colourless liquid. Reacts violently with water evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. In the presence of moisture, highly corrosive to most metals.

Observations Causes burns to skin, eyes and mucous membranes.








normal-PROPYL ACETATE.

Packaging group: II

Label of class

3


1276 C3H7OOCCH3 1.8% to 8% 10° C c.c. Properties Colourless, clear liquid with a pleasant odour. Im-miscible with water.

Observations


Stowage Category B.



PROPYLENEIMINE, INHIBITED.

Packaging group: I

Label of class


6.1


1921 CH3CHNHCH2 -4° C c.c. Properties Colourless liquid with an ammoniacal odour. Mis-cible with water.

Observations Toxic, if swallowed, by skin contact or by inhalation. Causes burns to skin and eyes.






1104 CH3COOC5H11 1.1 % to 23° C to 61° C c.c.

Properties Colourless liquids with a pear or banana like odour. normal AMYL ACETATE flashpoint 25° C c.c. secondary AMYL ACETATE flash-point 32° C c.c. Immiscible with water.

Observations


Stowage Category A.



High flashpoint group

AMYL ACETATES. normal-AMYL ACETATE, secon-dary-AMYL ACETATE, ISOAMYL ACETATE.

Packaging group: III

Label of class

3




AMYL ALCOHOLS.

entry moved to page 3373-1


1106 C5H11NH2 2.2% to 22% * 23° C to 61° C c.c.

Properties Colourless liquids. Mis-cible with water.

Observations Harmful by inhalation. Irritating to skin, eyes and mucous membranes. * Also listed in intermediate flashpoint group.


Stowage Category A.




AMYLAMINES. 2-PENTYLAMINE, 2-AMYLAMINE.


Label of class

3 Subsidiary risk label

of class

8



2344 * 23° C to 61° C c.c.

Properties Colourless liquids. Immiscible with water. When involved in a fire evolve toxic fumes.

Observations Harmful by inhalation. * Also listed in intermediate flashpoint group.


Stowage Category A.




2341 C5H11Br

23° C to 32° C c.c.


1-BROMO-3-METHYLBUTANE. ISOAMYL BROMIDE.

Packaging group III

Label of class

3

Properties Colourless liquid. Im-miscible with water.

Observations


Stowage Category A.



BROMOPROPANES.

ISOPROPYL BROMIDE, PROPYL BROMIDES [new schedule]

Packaging group III

Label of class

3



1123 C4H9OOCCH3 1.5% to 15% * 23° C to 61° C c.c.

Properties Colourless liquids with a pineapple-like odour normal-BUTYL ACETATE flashpoint 27° C c.c. Immiscible with water.

Observations Also listed in intermediate flashpoint group.


Stowage Category A.




BUTANOLS.

normal-BUTANOL, normal-BUTYL ALCOHOL, 1-BUTANOL, METHYL ETHYL CARBINOL.

Packaging group III

Label of class

3


1120 C4H9OH 23° C to 35° C c.c.

Properties Colourless liquids with a disagreeable odour. Explo-sive limits normal-BUTANOL 1.4% to 11.2%, nor-mal-BUTANOL is immiscible with water.

Observations Irritating to skin eyes and mucous membranes. * Also listed in intermediate flashpoint group.


Stowage Category A.



BUTYL ACETATES.

Packaging group III

Label of class

3




ISOBUTYRIC ACID.

2-METHYLPROPIONIC ACID

Packaging group III

Label of class

3 Subsidiary risk label of

class

8


2529 (CH3)2CHCOOH 2% to 9.2% 55° C c.c. Properties Colourless liquid with a pungent odour. Miscible with water.

Observations Causes burns to skin and eyes. Irritating to skin eyes and mucous membranes.


Stowage Category A.



ISOBUTYRIC ANHYDRIDE.

Packaging group III

Label of class


class

8


2530 [(CH3)2CHCO]2O 1 % to 6.2% 59° C c.c. Properties Colourless liquid. Decom-poses in water.

Observations Causes burns to skin and eyes. Irritating to skin eyes and mucous membranes.


Stowage Category A.





ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S.


Label of class


6.1



2478 * 23° C to 61° C c.c. Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1 % or more of substance(s) identified with "PP" in the General Index to this Code. Toxic liquids with a pungent odour. Immiscible with water but react with it to form carbon dioxide.

Observations Toxic if swallowed, by skin contact or by inhalation. For ISOCY-ANATES, TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLU-TION, TOXIC, FLAMMABLE, N.O.S. , UN No. 3080, see class 6.1. * Also listed in low and intermediate flashpoint groups.


Stowage Category E, If under deck, with mechanical ventilation.



IMDG CODE - PAGE 3360-1 (page 3360 2 follows) Amdt. 27-94


MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S.


Label of class


6.1



3248 * 23° C to 61° C c.c. Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code.

Observations Toxic if swallowed, by skin contact or by inhalation. The technical name of only the flammable liquid component of this solution or mixture should be shown in parentheses immediately following the proper shipping name. * Also listed in low and intermediate flashpoint groups.

Packing See table 3.4 in the introduction to this class. Maximum net quantity per inner receptacle 5 litres or 5 kg.

Stowage Category A.





MERCAPTANS, LIQUID, FLAMMA-BLE, N.O.S. or MERCAPTAN MIX-TURE, LIQUID, FLAMMABLE, N.O.S. [new schedule]


Label of class

3



3336 * 23° C c.c. to 61° C c.c.

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour which may affect all odour-absorbing cargoes. Immiscible with water.

Observations * Also listed in low and intermediate flashpoint groups.


Stowage Category B. «SEPARATED FROM» foodstuffs.





MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S.

Packaging group III

Label of class


6.1



1228 C2H5SH * 23° C to 61° C c.c. Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour. Immiscible with wa-ter.

Observations Toxic, if swallowed, by skin contact or by inhalation. For MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S., UN No. 3071, see class 6.1. * Also listed in low and intermediate flashpoint groups.


Stowage Category B. Clear of living quarters. «SEPARATED FROM» foodstuffs and all other odour absorbing car-goes.


Bookshelf and K&M

A sulfur-containing organic compound with the general formula RSH where R is any radical, especially ethyl mercaptan, C2H5SH. Also called thiol.


PAGE RESERVED




2842 C2H5NO2 3.4% to 28° C c.c.

Properties Colourless oily liquid. When involved in a fire evolves nitrous toxic fumes. Slightly soluble in water.



Stowage Category A.




NITROCELLULOSE SOLUTION, FLAMMA-BLE, with not more than 12.6% nitrogen by dry mass and not more than 55% nitrocellu-lose.

CELLULOSE NITRATE SOLUTION, COL-LODION SOLUTION, LACQUER BASE SOLUTION, NITROCOTTON SOLUTION, PYROXYLIN SOLUTION.

Packaging group III

Label of class

3


2059 (C6H10O5)n * 23° C to 61° C c.c. Properties When involved in a fire evolves toxic nitrous fumes.

Observations For NITROCELLULOSE, WETTED, with not less than 25% alcohol by mass, UN No. 0342, see . For PAINT or PAINT, RELATED MATERIAL, containing 20% or less nitrocellulose with not more than 126% nitrogen, see UN No. 1263 in this class. For PRINTING INK, flammable, containing 20% or less nitrocellulose, see UN No. 1210 in this class. * Also listed in low and intermediate flashpoint groups.


Stowage Category A.



NITROETHANE.

Packaging group III

Label of class

3

Bookshelf and K&M

NITROCELLULOSE - A pulpy or cottonlike polymer derived from cellulose treated with sulfuric and nitric acids and used in the manufacture of explosives, collodion, plastics, and solid monopropellants. Also called guncotton, cellulose nitrate. ------------------------------------------------------------- НИТРОЦЕЛЛЮЛОЗА - Мясистый или подобный вате полимер, производный от целлюлозы, обработанной серными и азотными кислотами и используемый в изготовлении взрывчатых веществ, коллодия, пластических масс, и твердых однокомпонентных топлив. Также называемый нитроклетчаткой, нитроклетчаткой.

Bookshelf and K&M

CELLULOSE - A complex carbohydrate, (C6H10O5)n, that is composed of glucose units, forms the main constituent of the cell wall in most plants, and is important in the manufacture of numerous products, such as paper, textiles, pharmaceuticals, and explosives. A highly flammable, colorless or yellowish syrupy solution of pyroxylin, ether, and alcohol, used as an adhesive to close small wounds and hold surgical dressings, in topical medications, and for making photographic plates.

Bookshelf and K&M

COLLODION - a highly flammable, colorless or yellowish syrupy solution of pyroxylin, ether, and alcohol, used as an adhesive to close small wounds and hold surgical dressings, in topical medications, and for making photographic plates. --------------------------------------------------------------------------------------------- КОЛЛОДИЙ - высоко огнеопасный, бесцветный или желтовато- густой раствор пироксилина, эфира, и этилового спирта, используется как клей, чтобы заклеивать маленькие раны при хирургических операциях и для создания фотопластинок.

Bookshelf and K&M

1.Any of various clear or colored synthetic coatings made by dissolving nitrocellulose or other cellulose derivatives together with plasticizers and pigments in a mixture of volatile solvents and used to impart a high gloss to surfaces. 2.A glossy, resinous material, such as the exudation of the lacquer tree, used as a surface coating. 3.A finish that is baked onto the inside of food and beverage cans.

Bookshelf and K&M

A sweet-tasting crystalline nonessential amino acid, C2H5NO2, that is the principal amino acid occurring in sugar cane. It is derived from the alkaline hydrolysis of gelatin and used in biochemical research and medicine.




NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. , with not more than 30% nitroglycerin, by mass [new schedule]

Packaging group: as assigned by the competent authority on the ba-sis of the criteria set out in para-graph 3.1.2 of the introduction to this class.

Label of class

3



3343 CH2NO3CHNO3CH2NO3 * 23°C c.c. to 61° C c.c.


Observations * Also listed in low and intermediate flashpoint groups. These substances should not be classified and transported unless authorized by the competent authority on the basis of results from Series 2 tests and a Series 6(c) test on packages as prepared for transport (see the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria).


Stowage Category D.


Bookshelf and K&M

A thick, pale yellow liquid, CH2NO3CHNO3CH2NO3, that is explosive on concussion or exposure to sudden heat. It is used in the production of dynamite and blasting gelatin and as a vasodilator in medicine.




PAINT (including paint, lacquer, enamel, stain, shellac solution, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound).

Packaging group: Ill

Label of class

3 MARINE POLLUTANT mark



1263 * 23° C to 61° C c.c. Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Miscibility with water depends upon the composition.

Observations May contain 20% or less nitrocellulose provided the nitrocellulose contains not more than 12.6% nitrogen. A substance specifically identified by name in this Code should not be shipped under this entry. * Also listed in low and intermediate flashpoint groups.

Packing See 3.2.6 and table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.

Stowage Category A.



PARALDEHYDE. para-ACETALDEHYDE-2,4,6-TRIMETHYL-1,3,5-TRIOXANE Packaging group: Ill Label of

class

3


1264 C6H12O3 1.3% to 27° C c.c. Properties Colourless liquid. Misci-ble with water.

Observations


Stowage Category A.


Bookshelf and K&M

A colorless liquid polymer, C6H12O3, of acetaldehyde, used as a solvent and a sedative. --------------------------------------------------------------- Бесцветный полимер, C6H12O3, уксусного альдегида, используется как растворитель и седативное средство.

Bookshelf and K&M

A colorless, flammable liquid, C2H4O, used to manufacture acetic acid, perfumes, and drugs. Also called aldehyde. ---------------------------------------------------------- Бесцветная, огнеопасная жидкость, C2H4O, используемая при производстве уксусной кислоты, парфюмерии и лекарств. Также называется альдегидом.



2286 C12H26 43° C c.c.

Properties Colourless liquid. Immis-cible with water.

Observations


Stowage Category A.


UN No. Formula Explosive

Limits Flashpoint

2310 CH3COCH2COCH3 1.7% to 34° C c.c.

Properties Colourless liquid. Misci-ble with water.



Stowage Category A.




PENTAMETHYLHEPTANE. ISODODECANE.


Label of class

3


PENTANE-2,4-DIONE. 2,4-PENTANEDIONE ACE-TYLACETONE


Label of class


of class

6.1

Bookshelf and K&M

ПЕНТАНЫ, насыщенные ациклические углеводороды C5H12; бесцветные жидкости: нормальный пентан (tкип 36,1 С), изопентан (tкип 27,9 С) и неопентан. Содержатся в нефти, сланцевой смоле. Входят в состав моторных топлив. Применяются как растворители. Из изопентана получают изопрен. (К&M)

Bookshelf and K&M

The acetic acid radical CH3CO. АЦЕТОН, СН3СОСН3, бесцветная жидкость, tкип = 56,1 С. Сырье для синтеза многих важных химических продуктов; растворитель, напр., в производстве лаков, взрывчатых и лекарственных веществ. (К&M)



1105 C5H11OH 1.2% to 10.5% * 23° C to 61° C c.c.

Properties Colourless liquids with a strong odour. Immiscible with water.

Observations * Also listed in intermediate flashpoint group.


Stowage Category A.




PENTANOLS. AMYL ALCOHOLS, DI-ETHYL CARBINOL, ISOA-MYL ALCOHOL, METHYL-BUTANOLS.


Label of class

3

Bookshelf and K&M

CARBINOL - An alcohol derived from methanol.

Bookshelf and K&M

Изоамиловый спирт (CH3)2CHCH2CH2OH — основной компонент сивушного масла; бесцветная с неприятным запахом жидкость, tкип 132,1 C. Из амиловых спиртов получают главным образом сложные эфиры — амилацетат, изоамилацетат.(K&M)

Bookshelf and K&M

METHYLBUTANOLS - Either of two butyl alcohols derived from butane and used as solvents and in organic synthesis. БУТИЛОВЫЕ СПИРТЫ (бутанолы): CH3CH2CH2CH2OH (1-бутанол), tкип 117,4 С; CH3CH2CH(OH)CH3 (2-бутанол), tкип 99,5 С; (CH3)2CHCH2OH (изобутанол), tкип 108,1 С; (CH3)3COH (трет-бутанол), tкип 82,5 С. Растворители, напр. нитролаков и этилцеллюлозы, экстрагенты для жиров, сырье для получения пластификаторов (дибутилфталата) и др.

Bookshelf and K&M

Any of eight isomers of the alcohol composition C5H11OH, one of which is the principal constituent of fusel oil.

CLASS 4.1 – F l a m m a b l e s o l i d s

Stowage Category E. «AWAY FROM» class 3 and lead and its compounds.



2-AMINO-4,6-DINITROPHENOL, WET-TED, with not less than 20% water, by mass. PICRAMIC ACID, WETTED.

Packaging group: I

Label of class

4.1

UN No. Formula 3317 C6H2(NO2)2(NH2)OH

Properties Desensitized explosive. Red crystals. Insoluble in water. Explosive in the dry state. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes, in closed compartments these fumes may form an explosive mixture with air.

Observations Harmful if swallowed or by skin contact. Refuse for shipment damaged or leaking receptacles. This substance may be carried under the provisions of this class only if it is so packaged that the percentage of water will not fall below that stated above at any time during transport.

Packing Receptacle net Package gross

kg kg Hermetically sealed:

1 Glass or plastics inner packagings, packed together in a

wooden box (4C1), (4D), (4F) - 50 fibreboard box (4G) - 30 fibre drum (1G) - 50 2 Liner in a wooden box (4C2, 4D, 4F) - 125 fibre drum (1G) - 50 3 Drum, plastics (1H2) - 90


Note: Packagings should be lead-free.

Stowage Category D. «AWAY FROM» class 3 and lead and its com-pounds.



AMMONIUM PICRATE, WETTED with not less than 10% water, by mass

Packaging group: I

UN No. Formula 1310 NH4C6H2(NO2)3O

Properties Desensitized explosive. Substance in pure form consists of yellow crystals. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts.

Observations Harmful if swallowed or by skin contact. Refuse for shipment damaged or leaking receptacles. This substance may be carried under the provisions of this class only if it is so packaged that the percentage of water will not fall below that stated above at any time during transport. For AMMONIUM PICRATE, dry or wetted with less than 10% water, by mass, UN No. 0004, see .


/ kg Hermetically sealed: 1 Glass or plastics inner packagings, packed together in a

wooden box (4C1), (4D), (4F) - 50 fibreboard box (4G) - 30 fibre drum (1G) - 50 2 Liner in a wooden barrel (2C2) or fibre drum (1G) - 50

Bookshelf and K&M

AMMONIUM PICRATE - A salt or an ester of picric acid. ---------------------------------------------------------------------------------- ПИКРАТ АММОНИЯ - соль или сложный эфир пикриновой кислоты.




DIPICRYL SULPHIDE, WETTED, with not less than 10% water, by mass.

HEXANITRODIPHENYL SULPHIDE, WET-TED.

Packaging group: I

UN No. Formula 2852 [(NO2)3C6H2]2S

Properties Desensitized explosive. Golden-yellow, crystalline leaflets. Explosive and sensitive to shock and heat in the dry state.

Observations Refuse for shipment damaged or leaking receptacles. This substance may be carried under the provisions of this class only if it is so packaged that the percentage of water will not fall below that stated above at any time during transport. For DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass, UN No. 0401, see

Packing Package net Hermetically sealed. Glass receptade(s), sealed with soft stopper(s) compatible with the substance enclosed, packed in a wooden box (4C1), (4D), (4F).

500 g

Stowage

Category D. «AWAY FROM» class 3.


UN No. Formula

1323 Properties Alloy derived from cerium or misch metal with the addition of 10% to 65% iron. Emits sparks when struck. Observations The provisions of this Code should not apply to Ferrocerium stabi-lized against corrosion with a minimum iron content of 10%. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

UN No. Formula Properties Ignite readily. Observations The packaging performance tests referred to in section 10 of the General Introduction and in Annex I to this Code should not apply to these materials. For COTTON, WET, UN No. 1365, FIBRES, VEGETABLE, N.O.S., with animal or vegetable oil, UN No. 1373, and FIBRES, VEGETA-BLE, burnt, wet or damp, see class 4.2. The provisions of this Code should not apply to consignments of COTTON DRY having a density of not less than 360 kg/m3 (accord-ing to ISO Standard 8115 (1986)) and carried in closed cargo trans-port units (CTUs). Packing Tightly secured bales. Stowage Category A. «AWAY FROM» animal or vegetable oils. Unless carried in closed

cargo transport units bales should be properly covered by tarpaulins or the like Cargo spaces should be clean dry and free from oil or grease. Ventilator cowls leading into the cargo space should have spark preventing screens. All other openings entrances and hatches leading to the cargo space should be securely closed. During tempo-rary interruption of loading when the hatch remains uncovered a fire watch should be kept. During loading or discharge smoking in the vicinity should be prohibited and firefighting appliances kept ready for immediate operation. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


FERROCERIUM.

Packaging group: II

Label of class

4.1

FIBRES, VEGETABLE, DRY.

COTTON, DRY FLAX, DRY HEMP, DRY JUTE, DRY KAPOK, DRY SISAL, DRY VEGETABLE FIBRES, DRY

Label NO LABEL REQUIRED

Bookshelf and K&M

1. a. Any of various shrubby plants of the genus Gossypium, having showy flowers and grown for the soft, white, downy fibers surrounding oil-rich seeds. b. The fiber of any of these plants, used in making textiles and other products. c. Thread or cloth manufactured from the fiber of these plants. 2. The crop of these plants. 3. Any of various soft, downy substances produced by other plants, as on the seeds of a cottonwood. ----------------------------------------------------------------------------------------------------- ХЛОПОК, волокна, покрывающие семена хлопчатника. При его созревании плоды (коробочки) раскрываются, и из них собирают т. н. хлопок-сырец (волокно с неотделенными семенами). При переработке от семян отделяют хлопок-волокно (волокна длиной более 20 мм), пух (менее 20 мм) и подпушек (менее 5 мм). Из хлопка вырабатывают ткани, трикотаж, нити, вату и др. Пух и подпушек хлопка применяют в химической промышленности как сырье для изготовления искусственного волокна и нитей, пленки, лаков и т. п. (K&M)

Bookshelf and K&M

a. Any of several plants of the genus Linum, especially the widely cultivated L. usitatissimum, having blue flowers, seeds that yield linseed oil, and slender stems from which a textile fiber is obtained. b. The fine, light-colored textile fiber obtained from this plant. c. Any of several similar plants. ---------------------------------------------------------------------------------------------------- ЛЕН, род одно- и многолетних трав и кустарников семейства льновых, прядильная и масличная культура. Св. 200 видов. Возделывают в основном лен-долгунец — в стеблях 20-28% волокна, и лен масличный, или лен-кудряш, — в семенах 35-52% льняного масла. Некоторые виды декоративны. Наибольшие посевные площади льна-долгунца — в европейских странах, а также в Египте, Турции и др., льна масличного — в Индии, Аргентине, США. (K&M)

Bookshelf and K&M

1. Cannabis. 2. The tough, coarse fiber of the cannabis plant, used to make cordage. 3. a. Any of various plants similar to cannabis, especially one yielding a similar fiber. b. The fiber of such a plant. --------------------------------------------------------------------------------------------------- ПЕНЬКА, грубое лубяное волокно, полученное из стеблей конопли. Из пеньки делают канаты, веревки, шпагат и т. п.

Bookshelf and K&M

1. Either of two Asian plants (Corchorus capsularis or C. olitorius) yielding a fiber used for sacking and cordage. 2. The fiber obtained from these plants. ----------------------------------------------------------------------------------------------------- ЖУТ, род кустарников, полукустарников и трав семейства липовых, прядильная культура. Ок. 100 видов, в тропиках Азии, Африки, Америки, Австралии. Возделывают однолетние джут короткоплодный и джут длинноплодный; в сухих стеблях 20-25% волокна для технических, упаковочных, мебельных тканей, ковров. Наибольшая посевная площадь в Индии, Бангладеш.(K&M)

Bookshelf and K&M

A silky fiber obtained from the fruit of the silk-cotton tree and used for insulation and as padding in pillows, mattresses, and life preservers. ---------------------------------------------------------------------------------------------- Шелковистое волокно, полученное от плода шелково-ватного дерева и используется для изоляции и как наполнитель для подушек, матрацов, и спасательных жилетов.

Bookshelf and K&M

1. A Mexican and Central American plant (Agave sisalana) widely cultivated for its large, sword-shaped leaves that yield stiff fibers used for cordage and rope. 2. The fiber of this plant or of other members of the genus Agave. ----------------------------------------------------------------------------------------------------- СИЗАЛЬ (правильнее сисаль), грубое волокно, получаемое из листьев агавы. Из сизаля изготовляют канаты, сети, щетки и пр. Иногда сизалем называют и само растение.(K&M)

Bookshelf and K&M

Coarse, indigestible plant matter, consisting primarily of polysaccharides such as cellulose, that when eaten stimulates intestinal peristalsis. In this sense, also called bulk, roughage. ---------------------------------------------------------------------------------------------------- ВОЛОКНА ПРИРОДНЫЕ (волокна натуральные), текстильные волокна растительного (напр., хлопок, лен, пенька), животного (шерсть, натуральный шелк) и минерального (асбест) происхождения, пригодные для изготовления пряжи.(K&M)



HAFNIUM POWDER, WETTED with not less than 25% water (a visible excess of wa-ter must be present),

(a) mechanically produced having a particle size less than 53 microns; or

(b) chemically produced having a particle size less than 840 microns.

Packaging group: II

Label of class

4.1

UN No. Formula 1326 Hf

Properties Insoluble in water. Liable to spontaneous combustion when dry. Forms explosive mixtures with most oxidizing substances such as chlorates nitrates perchlorates and permanganates.

Observations Refuse for shipment damaged or leaking receptacles. For HAFNIUM POWDER, DRY, UN No. 2545, see class 4.2. The provisions of this Code should not apply to this substance: (a) mechanically produced having a particle size of 53 microns or

greater; or (b) chemically produced having a particle size of 840 microns or

greater.

Packing Hermetically sealed. See TABLE 2 in the introduction to this class. BAGS ARE NOT ALLOWED. For IBCs see section 26 of the General Introduction.

Stowage Category E.


Bookshelf and K&M

A brilliant, silvery, metallic element separated from ores of zirconium and used in nuclear reactor control rods, as a getter for oxygen and nitrogen, and in the manufacture of tungsten filaments. Atomic number 72; atomic weight 178.49; melting point 2,220°C; boiling point 5,400°C; specific gravity 13.3; valence 4. ----------------------------------------------------------------------------------------------------- ГАФНИЙ (лат. Hafnium), Hf, химический элемент IV группы периодической системы, атомный номер 72, атомная масса 178,49. Назван от позднелат. Hafnia — Копенгаген. Серебристо-белый тугоплавкий металл; плотность 13,35 г/см3, tпл 2230 °С. Материал для регулирующих стержней и защиты ядерных реакторов, электродов плазмотронов, компонент жаропрочных и тугоплавких сплавов для авиации и ракетной техники. (K&M)


UN No. Formula 1327

Properties Ignites readily. Liable to spontaneous combustion when wet, damp or contaminated with oil.

Observations Refuse for shipment when loose, damp, wet or contaminated with oil. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to Its low degree of danger. The provisions of this Code should not apply to consignments of compressed baled hay with a moisture content of less than 14% shipped in closed cargo transport units and accompanied by a certificate from the shipper stating that the product does not present any Class 4.1, UN No. 1327 hazard in transport and that its moisture content is less than 14%.

Packing Tightly secured bales. For IBCs see section 26 of the General Introduction.

Stowage Category A. «AWAY FROM» animal or vegetable oils. Unless carried in closed cargo transport units, bales should be properly covered by tarpaulins or the like. Cargo spaces should be clean, dry and free from oil or grease. Ventilator cowls leading into the cargo space should have spark-preventing screens. All other openings, entrances and hatches leading to the cargo space should be securely closed. During tempo-rary interruption of loading, when the hatch remains uncovered, a fire-watch should be kept. During loading or discharge, smoking In the vicinity should be prohibited and fire-fighting appliances kept ready for immediate operation.



HAY STRAW BHUSA


Bookshelf and K&M

Grass or other plants, such as clover or alfalfa, cut and dried for fodder. СЕНО, трава, скошенная и высушенная до влажности 15-17% и ниже; один из основных кормов для жвачных животных в стойловый период. (K&M)

Bookshelf and K&M

a. Stalks of threshed grain, used as bedding and food for animals, for thatching, and for weaving or braiding, as into baskets. b. A single stalk of threshed grain.


Stowage Category D. «AWAY FROM» class 3.

Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class


Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) iden-tified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Nitrocellulose may be in granular form or in flakes. This product may also contain added pigments. When involved in a fire evolves toxic fumes, in closed compartments, these fumes may form an explosive mixture with air Burns extremely rapidly with intense heat radiation.

Observations The formulation should be prepared so that it remains homogeneous and does not separate during transport. The provisions of this Code do not apply to formulations with low nitrocellulose contents which, 1. do not show dangerous properties when tested for their liability to detonate

deflagrate or explode when heated under defined confinement in tests of Test Series 1(a), 2(b) and 2(c) respectively in the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Part I; and

2. are not shown to be flammable solids when tested in accordance with chapter 14 of the United Nations Recommendations on the Transport of Dangerous Goods, or test N1 in the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria Part III, sub-section 33.2.1.4 (chips, if necessary crushed and sieved to a particle size of less than 1.25 mm). Refuse for shipment damaged or leaking receptacles. For NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass, UN No. 0341, see . For NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance by mass, UN No. 0343, see .

NITROCELLULOSE with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH or WITHOUT PLASTICIZER, WITH or WITHOUT PIGMENT.

CELLULOSE NITRATE WITH PLASTICIZING SUBSTANCE COLLO-

DION COTTON WITH PLASTICIZING SUBSTANCE NITRO-

COTTON WITH PLASTICIZING SUBSTANCE

Packaging group: II

Label of class

4.1


UN No. Formula

2557 [C6H7O2(OH)3-Х(ONO2)X]n

Packing Hermetically sealed

Receptacle net

Package gross

1 Cans, packed together in a l kg wooden box (4C1),(4D),(4F) 20 125 f ibreboard box (4G) 20 40 fibre drum (1G) 20 125 2 Plastics receptacles or bags, packed to-gether in a

wooden box (4C2), (4D), (4F) - 125 fibreboard box (4G) - 40 3 Liner in a wooden box (4C1), (4D), (4F) - 125 4 Plastics bag packed in a fibre drum (1G) - 225 5 Water-resistant fibre drum with vapour bar-rier (1G) 225 6 Drum, steel (1A2) - 225 7 Paper bag (5M2) should be carried in cargo transport units (CTUs) - 55

Note: Receptacles should be so constructed that explosion is not possible by reason of

increased internal pressure

Bookshelf and K&M

A pulpy or cottonlike polymer derived from cellulose treated with sulfuric and nitric acids and used in the manufacture of explosives, collodion, plastics, and solid monopropellants. Also called guncotton, cellulose nitrate. ---------------------------------------------------------------------------------------------------- НИТРАТЫ ЦЕЛЛЮЛОЗЫ (нитроцеллюлоза, нитроклетчатка) [C6H7O2(OH)3-Х(ONO2)X]n, продукты обработки целлюлозы нитрующей смесью, твердые бесцветные вещества. Горючи, нестойки к действию кислот и щелочей. По содержанию азота подразделяются на коллоксилин (10,7-12,2% N; используется в производстве взрывчатых веществ, нитролаков, этролов, целлулоида) и пироксилин (12,2-13,5% N; производство бездымного пороха). (K&M)

Bookshelf and K&M

Any of various substances added to plastics or other materials to make or keep them soft or pliable. ---------------------------------------------------------------------------------------------------- 1.Пластификатор – вещества , вводимые в полимерные материалы ( пластмассы, резины) для повышения их пластичности и эластичности. 2.Поверхностно-активные добавки, вводимые в строительные растворы и бетонные смеси для повышения их пластичности.

Bookshelf and K&M

1.A substance used as coloring. 2.Dry coloring matter, usually an insoluble powder to be mixed with water, oil, or another base to produce paint and similar products.

Bookshelf and K&M

A highly flammable, colorless or yellowish syrupy solution of pyroxylin, ether, and alcohol, used as an adhesive to close small wounds and hold surgical dressings, in topical medications, and for making photographic plates. ----------------------------------------------------------------------------------------------------- Густой клейкий раствор на смеси спирта и эфира, употребляется в медицине и фотографии.


Note: Receptacles should be so constructed that explosion is not possible by reason of in-

creased internal pressure.

Stowage Category E. «AWAY FROM» class 3.



NITROCELLULOSE WITH not less than 25% WATER, by mass

CELLULOSE NITRATE WITH WATER COLLODION COTTON WITH WATER NITROCOTTON WITH

WATER

Packaging group: II

Label of class

4.1

UN No. Formula 2555

Properties Desensitized explosive. Nitrocellulose may be granular or in flakes blocks or fibrous form. When involved in a fire, evolves toxic fumes in closed compartments these fumes may form an explosive mixture with air.

Observations Refuse for shipment damaged or leaking receptacles. This substance may be carried under the provisions of this class only if it is so packaged that the percentage of water will not fall below that stated above at any time during transport. For NITROCELLULOSE, dry or wetted with less than 25% water, by mass, UN No. 0340, see .

Packing Receptacle net

Package gross

l kg Hermetically sealed: 1 Cans, packed together in a wooden box (4C1), (4D), (4F) 20 125 2 Plastics receptacles or bags packed to-gether in a wooden box (4C1), (4D), (4F) - 125 fibreboard box (4G) - 40 3 Liner in a wooden box (4C1), (4D), (4F) - 125 4 Plastics bag, packed in a fibre drum (1G) - 225 5 Water resistant fibre drum with vapour bar-rier (1G) - 225 6 Drum steel (1A2) - 225


UN No. Formula 3270

Properties Filters may be small round pieces or large sheets. When involved in a fire, evolves toxic fumes in closed compartments these fumes may form an explosive mixture with air. Burns rapidly with intense heat radiation.

Observations The nitrogen content of the nitrocellulose should not exceed 11.5%.

Packing Each single filter sheet should be packed between sheets of glazed paper. The proportion of glazed paper between the filter sheets should be not less than 65%, by mass. The membrane filters/paper arrangement should not be liable to propagate a detonation as tested by one of the tests described in the United Nations Recommendations on the Transport of Dangerous Goods, Tests and Criteria, Part I, Test Series I (a),

Receptacle net

Package gross

kg kg Suitable small quantities in fibreboard boxes, plastics packagings or wrapped in paper, in a

fibreboard box (4G) - 30 Note: Packagings should be so constructed that explosion is not possible by

reason of increased internal pressure.

Stowage Category D.



NITROCELLULOSE, MEM-BRANE FILTERS

Packaging group: II

Label of class

4.1



NITROGLYCERIN MIXTURE, DESEN-SITIZED, SOLID, N.O.S., with more than 2% but not more than 10% nitro-glycerin, by mass.

Packaging group:

Label of class

4.1


UN No. Formula 3319

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Desensitized explosive with lactose, glucose or cellulose. White solid Soluble in water. When involved in a fire the nitroglycerin may accumulate and may produce an explosion. Contact with water may dissolve the desensitizer (lactose or glucose) causing migration and accumulation of the nitroglycerin which may explode. Nitroglycerin is more dense than water. When involved in a fire, evolves toxic fumes, in closed compartments these fumes may form an explosive mixture with air Inhalation of vapours may cause headaches, dizziness and fainting.

Observations This substances should not be transported under the provisions of this class unless specifically authorized by the competent authority.

Packing As approved by the competent authority.

Stowage Category E.



Stowage Category D. «AWAY FROM» class 3.



NITROSTARCH, WETTED, with not less than 20% water, by mass.

Packaging group I

Label of class

4.1

UN No. Formula

1337 C12

H12

(NO2)8O

10

Properties Desensitized explosive. Orange powder. Explosive and sensitive to friction in the dry state. When involved in a fire evolves toxic fumes in closed compart-ments these fumes may form an explosive mixture with air.

Observations Refuse for shipment damaged or leaking receptacles. This substance may be carried under the provisions of this class only if it is so packaged that the percentage of water will not fall below that stated above at any time during transport. For NITROSTARCH, dry or wetted with less than 20% water, by mass, UN No. 0146, see .


Pack-age

l kg Hermetically sealed 1 Cans packed together in a wooden box (4C1), (4D), (4F) 20 125

2 Liner in a wooden box (4C2), (4D), (4F) - 125

3 Plastics bag packed individually in a fibre drum (1G) - 75

4 Drum steel (1A2) - 225

Bookshelf and K&M

A highly explosive orange powder, C12H12(NO2)8O10, derived from starch and used for demolition. ---------------------------------------------------------------------------------------------------- НИТРОКРАХМАЛ - чрезвычайно взрывоопасный оранжевый порошок, C12H12(NO2)8O10, производный от крахмала и используемый в подрывных работах.


UN No. Formula

2213 [HCHO] n or HO [CH2O] H Properties White powder with a pungent odour. Evolves formaldehyde particularly when heated which is irritating to eyes and mucous membranes. Observations Refuse for shipment damaged or leaking receptacles. Harmful if swallowed by skin contact or by inhalation. Packages carried as a full load in a cargo transport unit are exempted from displaying the class number provided the unit in which they are packed is marked CLASS 4.1. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. Packing Any sift proof tear proof receptacles. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers road or rail vehicles) or portable tanks see section 25 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


PARAFORMALDEHYDE

Label NO LABEL REQUIRED. Package to be marked

CLASS

4.1

PENTAERYTHRITE, TETRANITRATE MIXTURE, DESENSITIZED, SOLID, N.O.S., with more than 10% but not more than 20% PETN, by mass [new schedule]

Packaging group: III Label of

class

4.1 MARINE POLLUTANT mark (for marine pollutants only)

UN No. Formula

3344

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Observations This substance should not be transported under the provisions of this class unless specifically authorized by the competent authority. Packing Unless otherwise approved by the competent authority based on a Series 6(c) test (see United Nations Recommendations on the Trans-port of Dangerous Goods Manual of Tests and Criteria) the packag-ing should be: Receptacle net Package gross kg kg Plastics liner in a fibre drum (1G) 20

Stowage Category E. Packing, Stowage, Segregation & Marine Pollution As-pects See also General Introduction and introduction to this class.

Bookshelf and K&M

A white solid polymer of formaldehyde, (HCHO)n, where n is at least 6, used as a disinfectant, fumigant, and fungicide. Белый твердый полимер формальдегида, (HCHO) n, где n по крайней мере 6, используется как дезинфекционное средство, фумигант и фунгицид. (KS) --------------------------------------------------------------------------------------------------- ПАРАФОРМАЛЬДЕГИД (параформ), продукт полимеризации формальдегида формулы НО[-CH2O-]nН, где n = 8-100; бесцветные кристаллы, tпл 120-150 С. Параформальдегид — источник формальдегида; удобен при хранении и транспортировке. Применяется в органическом синтезе и производстве полимеров. (K&M)



PHOSPHORUS, AMORPHOUS

PHOSPHORUS, RED


Label of class

4.1

UN No. Formula 1338 P

Properties Reddish-brown powder. Insoluble in water. Ignites readily by friction. When involved in a fire, evolves irritating fumes. Forms explosive and extremely sensitive mixtures with most oxidiz-ing substances, such as chlorates, nitrates, perchlorates or permanganates. Observations Harmful, if swallowed, or by dust inhalation Packing See TABLE 2 in the introduction to this class. BAGS ARE NOT ALLOWED. For IBCs see section 26 of the General Introduction. Stowage Category A. «SEPARATED FROM» class 5.1. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

PHOSPHORUS HEPTASULPHIDE, free from yellow or white phosphorus

Packaging group: II

Label of class

4.1

UN No. Formula 1339 P4S7

Properties Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flam-mable gases. Forms explosive and extremely sensitive mixtures with most oxi-dizing substances, such as chlorates, nitrates, perchlorates or permanganates. Observations Harmful if swallowed or by dust inhalation. Packing Hermetically sealed. See TABLE 2 in the introduction to this class. BAGS ARE NOT ALLOWED. For IBCs see section 26 of the General Introduction. Stowage Category B. «SEPARATED FROM» class 5.1. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

Bookshelf and K&M

Symbol P. A highly reactive, poisonous, nonmetallic element occurring naturally in phosphates, especially apatite, and existing in three allotropic forms, white (or sometimes yellow), red, and black. An essential constituent of protoplasm, it is used in safety matches, pyrotechnics, incendiary shells, and fertilizers and to protect metal surfaces from corrosion. Atomic number 15; atomic weight 30.9738; melting point (white) 44.1°C; boiling point 280°C; specific gravity (white) 1.82; valence 3, 5. ---------------------------------------------------------------------------------------------------- ФОСФОР (лат. Phosphorus), Р, химический элемент V группы периодической системы Менделеева, атомный номер 15, атомная масса 30,97376. Название от греч. phosphoros — светоносный. Образует несколько модификаций — белый фосфор (плотность 1,828 г/см3, tпл 44,14 °С), красный фосфор (плотность 2,3 г/см3, tпл 590 °С) и др. Белый фосфор легко самовоспламеняется, светится в темноте (отсюда название), ядовит; красный менее активен химически, ядовит. Добывают из апатитов и фосфоритов. Главный потребитель — сельское хозяйство (фосфорные удобрения); применяется в спичечном производстве, металлургии (раскислитель и компонент некоторых сплавов), в органическом синтезе и др. Присутствует в живых клетках в виде орто- и пирофосфорной кислот и их производных. (K&M)



PHOSPHORUS SESQUISULPHIDE, free from yellow or white phosphorus

Packaging group: II

Label of class

4.1

UN No. Formula 1341 P4S3

Properties Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flamma-ble gases. Forms explosive and extremely sensitive mixtures with most oxidiz-ing substances, such as chlorates, nitrates perchlorates or permanganates. Observations Harmful if swallowed or by dust inhalation. Packing Hermetically sealed. See TABLE 2 in the introduction to this class. BAGS ARE NOT ALLOWED.

For IBCs see section 26 of the General Introduction. Stowage Category B. «SEPARATED FROM» class 5.1. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

PHOSPHORUS TRISULPHIDE, free from yellow or white phosphorus

Packaging group: II

Label of class

4.1

UN No. Formula 1343 P2S3 or P4S6

Properties Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive and extremely sensitive mixtures with most oxidizing substances, such as chlorates, nitrates, perchlorates or permanganates. Observations Harmful if swallowed or by dust inhalation. Packing Hermetically sealed. See TABLE 2 in the introduction to this class.

BAGS ARE NOT ALLOWED. For IBCs see section 26 of the General Introduction. Stowage Category B. «SEPARATED FROM» class 5.1. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

CLASS 4.2 – S p o n t a n e o u s l y c o m b u t i b l e

UN No. Formula 3051

Properties Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water, acids, halogens, alcohols and amines, evolving flammable gas. Observations

Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


ALUMINIUM ALKYLS

TRIBUTYLALUMlNIUM TRIETHYLALUMINIUM TRIISOBUTYLALUMINIUM TRIMETHYLALUMINIUM TRIPROPYLALUMINIUM

Packaging group: I Label of class


class

4.3 ALUMINIUM ALKYL HALIDES

ALUMINIUM ALKYL BROMIDES METHY-LALUMINIUM SESQUIBROMIDE

ALUMINIUM ALKYL CHLORIDES DI-ETHYLALUMINIUM CHLORIDE ETHY-LALUMINIUM CHLORIDE ETHYLALU-MINIUM

SESQUICHLORIDE ME-THYLALUMINIUM

SESQUICHLORIDE

Packaging group: I

Label of class

4.2 Subsidiary risk label of class

4.3

UN No. Formula 3052

Properties Liquids or solids. Ignite on exposure to air or carbon dioxide. React violently in contact with water, acids, halogens, alcohols and amines, evolving flammable gas. Observations

Packing Hermetically sealed. For liquids see table 1 in the introduc-tion to this class.

For solids Receptacle net

Package gross

Hermetically sealed: kg kg 1 Glass receptacles, packed with inert cushioning material together in a

wooden box (4C1), (4D), (4F) 1 75

fibreboard box (4G) 1 40 2 Cans, packed together in a wooden box (4C2), (4D), (4F) - 75

fibreboard box (4G) - 40 3 Drum, metal (1A2), (1B2) - 250

For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

Bookshelf and K&M

ALKYLS - A monovalent radical, such as ethyl or propyl, having the general formula CnH2n+1. ---------------------------------------- АЛКИЛ - Одновалентный радикал, типа этила или пропила, имеющих общую формулу CnH2n+1.

Bookshelf and K&M

HALIDE -A chemical compound of a halogen with a more electropositive element or group. ----------------------------------------------------- ГАЛОИДНОЕ СОЕДИНЕНИЕ -Химическое соединение галогена с более электроположительным элементом или группой.



ALUMINIUM ALKYL HYDRIDES

Packaging group: I

Label of class


4.3

UN No. Formula 3076

Properties Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water acids halogens alcohols and amines evolving flammable gas.

Observations

Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction.

Stowage Category D.


ALUMINIUM BOROHYDRIDE or ALUMINIUM BOROHYDRIDE IN DEVICES

Packaging group: I

Label of class


class

4.3

UN No. Formula 2870 AI(BH4)3

Properties Liquid. Ignites spontaneously in air. Reacts with water or steam to produce heat or hydrogen which may form explosive mixtures with air.

Observations

Packing Hermetically sealed. See table 1 in the introduction to this class. Note: The number of inner packagings should be restricted to 8 (eight) receptacles of maxi-

mum 1 litre each.

Stowage Category D.



UN No. Formula 1362

Properties Black powder or granules. Liable to heat slowly and ignite spontaneously in air. Ob-servations The material as offered for shipment should have been sufficiently heat-treated and cooled down before packing. Carbons made by a steam activation process are not subject to the provisions of this Code. The provisions of this Code should not apply to a consignment of carbon or charcoal if it passes the test for self-heating substances as reflected in the United Nations Recommendations on the Trans-port of Dangerous Goods, Manual of Tests and Criteria (see 33.3.1.3.3), and is accompanied by an appropriate certificate from a laboratory accredited by the competent authority, stating that the consignment to be loaded has been correctly sampled by trained staff from that laboratory and that the sample was correctly tested and has passed the test. Packing Hermetically sealed. See TABLE 2 in the introduction to this class. BAGS (5M1), 55 kg, in hermetically sealed plastics bags or wrapping, shrink- or stretch-wrapped on to pallets ARE ALLOWED. For IBCs see section 26 of the General Introduction. Stowage Category A. Keep as cool as possible. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


CARBON, animal or vegetable origin

CHARCOAL, non-activated

CARBON BLACK

Packaging group: II or III according to the grouping criteria.

Label of class

4.2

UN No. Formula 1361

Properties Black powder or granules. Liable to heat slowly and ignite spontaneously in air. Observations The material as offered for shipment should have been sufficiently heat-treated and cooled down before packing. The provisions of this Code should not apply to non-activated carbon blacks of mineral ori-gin. The provisions of this Code should not apply to a consignment of carbon or charcoal if it passes the test for self-heating substances as reflected in the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria (see 33.3.1.3.3), and is accompanied by an appropriate certificate from a laboratory ac-credited by the competent authority stating that the consignment to be loaded has been correctly sampled by trained staff from that labora-tory and that the sample was correctly tested and has passed the test. Packing See TABLE 2 in the introduction to this class.

BAGS (5M1), 55 kg, ARE ALLOWED For IBCs see section 26 of the General Introduction. Stowage Category A. Keep as cool as possible. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

CARBON, ACTIVATED

CHARCOAL, ACTIVATED


Label of class

4.2

Bookshelf and K&M

ACTIVATED CARBON - Highly absorbent carbon obtained by heating granulated charcoal to exhaust contained gases, resulting in a highly porous form with a very large surface area. It is used primarily for purifying gases by adsorption, solvent recovery, or deodorization and as an antidote to certain poisons. Also called activated carbon. ------------------------------------------------------------------------- АКТИВНЫЙ УГОЛЬ (активированный уголь), пористое тело, получаемое из ископаемых или древесных углей удалением смолистых веществ, а также обугливанием полимеров. Используют как адсорбент в противогазах, вакуумной технике, медицине и как носитель катализаторов. (K&M).

Bookshelf and K&M

CARBON - Symbol C. A naturally abundant nonmetallic element that occurs in many inorganic and in all organic compounds, exists freely as graphite and diamond and as a constituent of coal, limestone, and petroleum, and is capable of chemical self-bonding to form an enormous number of chemically, biologically, and commercially important molecules. Atomic number 6; atomic weight 12.01115; sublimation point above 3,500 C; boiling point 4,827 C; specific gravity of amorphous carbon 1.8 to 2.1, of diamond 3.15 to 3.53, of graphite 1.9 to 2.3; valence 2, 3, 4. ---------------------------------------------------------------------------------------------------- УГЛЕРОД (лат. Carboneum), С, химический. элемент IV группы периодической системы Менделеева, атомный номер 6, атомная масса 12,011. Основные кристаллические модификации — алмаз и графит. При обычных условиях углерод химически инертен; при высоких температурах соединяется с многими элементами (сильный восстановитель). Содержание углерода в земной коре 6,5.1016 т. Значительное количество углерода (ок. 1013 т) входит в состав горючих ископаемых (уголь, природный газ, нефть и др.), а также в состав углекислого газа атмосферы (6.1011 т) и гидросферы (1014 т). Главные углеродсодержащие минералы — карбонаты. Углерод обладает уникальной способностью образовывать огромное количество соединений, которые могут состоять практически из неограниченного числа атомов углерода. Многообразие соединений углерода определило возникновение одного из основных разделов химии — органической химии. Углерод — биогенный элемент; его соединения играют особую роль в жизнедеятельности растительных и животных организмов (среднее содержание углерода — 18%). Углерод широко распространен в космосе; на Солнце он занимает 4-е место после водорода, гелия и кислорода. (K&M)

Bookshelf and K&M

CHARCOAL - A black, porous, carbonaceous material, 85 to 98 percent carbon, produced by the destructive distillation of wood and used as a fuel, filter, and absorbent. -------------------------------------------------------------- ДРЕВЕСНЫЙ УГОЛЬ, микропористый высокоуглеродистый продукт, образующийся при пиролизе древесины без доступа воздуха. Применяется в производстве кристаллического кремния, сероуглерода, черных и цветных металлов, активного угля и т. д., а также как топливо в быту (теплота сгорания 31,5-34 МДж/кг). (K&M)

Bookshelf and K&M

CARBON BLACK - Any of various finely divided forms of carbon derived from the incomplete combustion of natural gas or petroleum oil and used to reinforce rubber and as an ingredient in inks, paints, crayons, and polishes. ------------------------------------------------------------------------ ТЕХНИЧЕСКИЙ УГЛЕРОД (сажа), дисперсный продукт черного цвета, образующийся в результате неполного сгорания или термического разложения углеводородов. Состоит из сферических частиц (размер 10-350 нм), образованных слоями углеродных атомов, подобных слоям в графите, но не плоских, а изогнутых. Наполнитель в производстве резины, пластмасс, пигмент для лакокрасочных материалов и др. (K&M)


PAGE RESERVED



UN No. Formula 2002

Properties Plastics composed mainly of nitrocellulose containing not more than 11.5% nitrogen, and camphor. Comprises trimmings, clippings and other waste obtained in the manufacture of celluloid articles. Ignites readily. When involved in a fire, evolves toxic fumes, in enclosed cargo spaces,these fumes may form an explosive mixture with air.

Observations For CELLULOID, UN No. 2000, see class 4.1.

Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction.

Stowage Category D.



CELLULOID SCRAP


Label of class

4.2

Bookshelf and K&M

CELLULOID SCRAP - A colorless, flammable material made from nitrocellulose and camphor and used to make photographic film. ---------------------------------------------------------------- ЦЕЛЛУЛОИД, пластмасса на основе пластифицированного нитрата целлюлозы. Применяется, напр., для остекления приборов, изготовления канцелярских товаров, игрушек и др. Из-за горючести заменяется другими пластмассами. (K&M)


UN No. Formula

1363

Properties Dried kernels of coconuts with a penetrating rancid odour, which may taint other cargoes.

Observations This substance should preferably have been weathered for not less than one month before shipment unless a certificate from a person recognized by the competent authority of the country of shipment states a maximum moisture content of 5%. The packaging perform-ance tests referred to in sections 10 and 26 of the General Introduc-tion and in Annex I to this Code should not apply to this substance due to its low degree of danger.

Packing Any sift proof tear proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers road or rail vehi-cles) or portable tanks see section 25 of the General Introduction. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes.

Stowage Category A. Keep as dry as reasonably practicable. Protect from sparks and open flame. Provide a good through ventilation for bagged cargo. Double strip stowage recommended. The illustration on page 4236 shows how this can be achieved. The cargo should be stowed away from pipes and bulkheads, which are liable to become heated (e.g. engine room or heated fuel tank bulkheads). During the voyage, regular temperature readings should be taken at varying depths in the hold and recorded If the temperature of the cargo exceeds the ambient temperature and continues to increase ventilation should be closed down.



COPRA

Label NO LABEL REQUIRED Cargo transport units carry-ing a full load of copra to be marked CLASS 4.2.

Bookshelf and K&M

COPRA - The dried white flesh of the coconut from which coconut oil is extracted. ------------------------------------------------------------- КОПРА (португ. copra, от малаяльского коппара), высушенная питательная ткань (эндосперм) плода кокосовой пальмы — кокосового ореха. Используется для получения кокосового масла, производства маргарина и мыла. (K&M)


CLASS 4.2 - Spontaneously combustible


COTTON WASTE, OILY, impregnated with 5%, or more, of animal or vegeta-ble oil.

Packaging group: III Label of

class

4.2

UN No. Formula 1364

Properties Fibres of vegetable origin.

Observations


Stowage Category A.


COTTON WASTE, OILY impregnated with less than 5% of animal or vegetable oil.

Label of class

4.2

UN No. Formula 1364

Properties Fibres of vegetable origin in a dry state.

Observations Bales carried as a full load in a cargo transport unit are exempted from displaying the label, provided the unit in which the bales are packed is placarded. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of dan-ger.


Stowage Category A. «SEPARATED FROM» animal or vegetable oils.



UN No. Formula

1365

Properties Readily combustible, liable to ignite spontaneously according to moisture content.

Observations COTTON, DRY is entered under FIBRES, VEGETABLE, DRY in class 4.1. Bales carried as a full load in a cargo transport unit are exempted from displaying the label, provided the unit in which they are packed is placarded. The packaging performance tests referred to in sec-tions 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger.


Stowage Category A.



COTTON, WET

Label of class

4.2


UN No. Formula1366 Zn(C2H5)2

PropertiesLiquid.Ignites spontaneously in air or carbon dioxide.Decomposes in contact with water, evolving ethane, a flammablegas.

Observations

PackingHermetically sealed.See table 1 in the introduction to this class.For tanks see section 13 of the General Introduction.

StowageCategory D.Prohibited on any ship carrying goods of class 1 with the exceptionslisted in 6.1.4.2 of the introduction to class 1.

Packing, Stowage & SegregationSee also General Introduction and introduction to this class.


DIETHYLZINC

ZINC DIETHYL ZINCETHYL

Packaging group: I

Label of class

4.2Subsidiary risk labelof class

4.3


UN No. Formula

1370 Zn(CH3)2

PropertiesLiquid.Boiling point 46°C.Ignites spontaneously in air or carbon dioxide.Decomposes in contact with water, evolving methane, a flammablegas.

Observations

PackingHermetically sealed.See table 1 in the introduction to this class.For tanks see section 13 of the General Introduction.

StowageCategory D.Prohibited on any ship carrying goods of class 1 with the exceptionslisted in 6.1.4.2 of the introduction to class 1.

Packing, Stowage & SegregationSee also General Introduction and introduction to this class.


DIMETHYLZINC

ZINC DIMETHYL

Packaging group: I

Label of class

4.2Subsidiary risk label

of class

4.3




FERROUS METAL BORINGS, SHAV-INGS, TURNINGS, or CUTTINGS, in a form liable to self-heating.

IRON SWARF. STEEL SWARF.

Label of class

4.2

UN No. Formula 2793

Properties These cargoes are liable to self-heating and to ignite spontaneously, particularly when in a finely divided form, wet or contaminated with such materials as unsaturated cutting oil, oily rags and other combus-tible matter. Self-heating or inadequate ventilation may cause danger-ous depletion of oxygen in the stowage spaces.

Observations Excessive amounts of cast iron borings or organic materials may en-courage heating. The swarf should be protected from moisture prior to and after loading. If, during loading, the weather is inclement hatches should be closed and otherwise protected to keep the material dry. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. The provisions of this Code should not apply to consignments of this substance which are accompanied by a declaration of the shipper stating that it has no self-heating properties.

Packing Any sift-proof, tear-proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers road or rail vehi-cles) or portable tanks, see section 25 of the General Introduction. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes.

Stowage

Category A. Notes: (1) Prior to loading, temperature of the swarf should not exceed 55°C. Wooden

sweat battens, dunnage and debris should be removed from the hold be-fore the swarf is loaded;

(2) Surface temperature of the swarf should be taken prior to, during and after loading and daily during the voyage. If the surface temperature exceeds 90°C during loading, further loading should cease and should not recom-mence until the temperature has fallen to at least 85°C. The vessel should not sail on an international voyage unless the temperature is below 65°C, and has shown a steady or downward trend in temperature for at least eight hours. During loading and carriage, the bilge of each hold in which the swarf is stowed should be as dry as practicable. During loading, the swarf should be compacted in the hold as frequently as practicable with a bull-dozer or by other means. After loading, the swarf should be trimmed to eliminate peaks and should be compacted;

(3) Whilst at sea, any rise in surface temperature of the swarf indicates a self-heating reaction problem. If the temperature should rise to 80°C, a potential fire situation is developing and the vessel should make for the nearest suit-able port. Water should not be used at sea. Early application of an inert gas to a smouldering situation may be effective In port, copious quantities of wa-ter may be used but due consideration should be given to stability;

(4) Entry into cargo spaces containing swarf should only be made with the main hatches open or when using breathing apparatus.

Bookshelf and K&M

SWARF - Fine metallic filings or shavings removed by a cutting tool. -------------------------------------- Металлическая стружка

Translation these paragraphs.

(1) До погрузки, температура металлической стружки не должна превысить 55 C. Деревянные доски, прокладочный и подстилочный материал и остатки органических веществ должны быть удалены из трюма до погрузки стужки; (2) Температура стружки должна замеряться до, в течение и после погрузки и ежедневно в течение рейса. Если поверхностная температура превышает 90 C в течение погрузки, далее погрузка должна быть прекращена и не должна возобновляться, пока температура не упадет по крайней мере до 85 C. Судно не должно выходить в рейс до тех пор, пока температура не будет ниже 65 C, и будет показывать устойчивый или нисходящий тренд по крайней мере восемь часов. В течение погрузки и транспортировки, колодцы трюмов, в которые металлическая стружка погружена, должены быть как можно сухими. В течение погрузки, металлическая стружка должна уплотняться бульдозером или другими средствами так часто как возможно . После погрузки, стружка должна быть разравнена и уплотнена. (3), В море, любое повышение поверхностной температуры металлической стружки говорит о реакции само-нагревания. Если температура повысилась до 80 C, ситуация возникновения пожара развивается, и судно должно идти в ближайший порт. Вода не должна использоваться в море. Раннее применение инертного газа может быть эффективно при развитии ситуации тления. В порту, обильное количество воды может использоваться, но стабильность судна должна приниматься во внимание; (4) Вход в грузовые помещения, содержащие металлическую стружку разрешается только при открытых крышках трюмов или при использовании дыхательного аппарата.


Reserve page



UN No. Formula 2445

Properties Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water, acids, halogens, alcohols and amines, evolving flammable gas.

Observations


Stowage Category D.



LITHIUM ALKYLS

BUTYL LITHIUM

Packaging group: I

Label of class


of class

4.3


UN No. Formula 3053

Properties Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water acids, halogens, alcohols and amines, evolving flammable gas. Observations

Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Prohibited on any ship carrying goods of class 1 with the exceptions listed in 6.1.4.2 of the introduction to class 1. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

UN No. Formula 2004 Mg(NH2)2

Properties White powder. Ignites spontaneously in air. Reacts violently in contact with water. Observations


Package gross

g kg Hermetically sealed. Glass ampoules, with inert cushioning and absorbent material of sufficient capacity to absorb contents, each in a metal can, packed together in a

wooden box (4C1), (4D), (4F) 50 45

wooden barrel (2C2) 50 45 Stowage Category C. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


MAGNESIUM ALKYLS

DIETHYLMAGNESIUM DIMETHYLMAGNESIUM

Packaging group: I La-

bel of class


class

4.3

MAGNESIUM DIAMIDE

Packaging group: II

Label of class

4.2

Bookshelf and K&M

ГИДРАЗИН (диамид), N2H4, бесцветная жидкость, tпл 1.5 С, tкип 113.5 С; неограниченно растворим в воде; взрывоопасен и ядовит. Применяют в производстве пластмасс, каучуков, инсектицидов, порообразователей, ВВ; горючий компонент ракетного топлива. (K&M)



METAL ALKYLS, WATER-REACTIVE, N.O.S. or METAL ARYLS, WATER-REACTIVE, N.O.S.

Packaging group: I

Label of class


4.3


UN No. Formula 2003

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water, acids, halogens, alcohols and amines evolving flammable gas.

Observations

Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

METAL ALKYL HALIDES, WATER-REACTIVE, N.O.S. or METAL ARYL HALIDES, WATER-REACTIVE, N.O.S.

Packaging group: I Label of

class


4.3


UN No. Formula 3049

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water acids, halogens, alcohols and amines, evolving flammable gas. Observations

Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.



METAL ALKYL HYDRIDES, WATER-REACTIVE, N.O.S. or METAL ARYL HYDRIDES, WATER-REACTIVE, N.O.S.

Packaging group: I

Label of class

4.2 Subsidiary risk label of class.

4.3


UN No. Formula 3050

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water, acids, halogens, alcohols and amines, evolving flammable gas.

Observations


Stowage Category D.




POTASSIUM DITHIONITE

POTASSIUM HYDROSULPHITE

Packaging group: II

Label of class

4.2

UN No. Formula 1929 K2S2O4

Properties Liable to heat and ignite spontaneously in air and to evolve sulphur dioxide, an irritating gas.

Observations


Stowage Category E. Keep as dry as reasonably practicable.


POTASSIUM SULPHIDE, ANHY-DROUS or POTASSIUM SUL-PHIDE, with less than 30% water of crystallization.

Packaging group: II

Label of class

4.2

UN No. Formula 1382 K2S

Properties Black solid, absorbs moisture to become crystalline. Liable to ignite spontaneously. In contact with acids, evolves hydrogen sulphide, a toxic and flammable gas.

Observations For POTASSIUM SULPHIDE HYDRATED with not less than 30% water of crystallization, UN No. 1847, see class 8.


Stowage Category A.


Bookshelf and K&M

POTASSIUM - Symbol K A soft, silver-white, highly or explosively reactive metallic element that occurs in nature only in compounds. It is obtained by electrolysis of its common hydroxide and found in, or converted to, a wide variety of salts used especially in fertilizers and soaps. Atomic number 19; atomic weight 39.102; melting point 63.65 C; boiling point 774 C; specific gravity 0.862; valence 1. ------------------------------------------------------------------------------------------------------ КАЛИЙ (лат. Kalium), К, химический элемент I группы периодической системы, атомный номер 19, атомная масса 39,0983, относится к щелочным металлам. Название от араб. алькали — поташ (давно известное соединение калия, добывающееся из древесной золы). Серебристо-белый металл, мягкий, легкоплавкий; плотность 0,8629 г/см3, tпл 63,51 С. Быстро окисляется на воздухе, с водой реагирует со взрывом. По распространенности в земной коре занимает 7-е место (минералы: сильвин, каинит, карналлит и др.; см. Калийные соли). Входит в состав тканей растительных и животных организмов. Ок. 90% добываемых солей используется как удобрения. Сам металл применяют в химических источниках тока, как геттер в электронных лампах, для получения надпероксида KO2; сплавы K с Na — теплоносители в ядерных реакторах. (K&M)


CLASS 4.2 - Spontaneously combustible


PYROPHORIC LIQUID, ORGANIC, N.O.S.

PYROPHORIC LIQUID, INORGANIC, N.O.S.

PYROPHORIC ORGANOMETALLIC COM-POUND (liquid), WATER-REACTIVE, N.O.S.

Packaging group: I

Label of class

4.2 For UN No. 3203 only.

Subsidiary risk label of class

4.3


UN No. Formula

2845

3194

3203

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP'' in the General Index to this Code. Highly flammable liquids, may ignite spontaneously in moist air. In contact with air, evolve irritating and slightly toxic fumes.

Observations


g g Hermetically sealed:

1 Glass ampoule packed with inert cushioning material individually in a wooden box (4C1), (4D), (4F)

500 -

2 Cylinder - - For carriage in tanks of UN Nos. 2845 and 3203 see section 13 of the General Introduction.

Stowage Category D. Prohibited on any ship carrying goods of with the exceptions listed in 6.1.4.2 of the introduction to .


Bookshelf and K&M

PYROPHORIC - 1. Spontaneously igniting in air. 2. Producing sparks by friction. ----------------------------------------------- 1. Спонтанно загорающийся в воздухе. 2. Производящий искры при трении.


UN No. PYROPHORIC SOLID, INORGANIC, N.O.S. 3200

PYROPHORIC SOLID ORGANIC, N.O.S. 2846

1383 PYROPHORIC METAL, N.O.S. or PYRO-PHORIC ALLOY, N.O.S. ALUMINIUM POWDER, PYROPHORIC BARIUM POWDER, PYROPHORIC CAESIUM POWDER, PYROPHORIC CERIUM POWDER, PYROPHORIC IRON POWDER, PYROPHORIC STRONTIUM ALLOY, PYROPHORIC STRONTIUM POWDER, PYROPHORIC ZINC POWDER, DUST, PYROPHORIC

PYROPHORIC ORGANOMETALLIC COM-POUND (solid) WATER-REACTIVE, N.O.S. 3203

BARIUM ALLOY, PYROPHORIC 1854 CALCIUM PYROPHORIC or CALCIUM AL-LOYS, PYROPHORIC 1855

Formula

Properties

MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liable to ignite spontaneously in air. If shaken may produce sparks In contact with water, evolve hydrogen, a flammable gas.

Observations

Packing Receptacle

net Package gross

Hermetically sealed: kg kg 1 Glass receptacles packed with inert cushioning material to-gether in a

wooden box (4C1), (4D), (4F) 2 75

fiberboard box (4G) 2 40 2 Cans, packed together in a wooden box (4C2), (4D), (4F)

15 75

fiberboard box (4G) 15 40 3 Drum, metal (1A2), (1B2) - 250

Stowage Category D.

Packing, Stowage, Segregation & Ma-rine Pollution Aspects See also General Introduction and introduction to this class.


Packaging group: I

Label of class

4.2 For UN No. 3203 only


4.3

MARINE POLLUTANT mark


Bookshelf and K&M

ORGANOMETALLIC - Of, relating to, or constituting an organic compound containing a metal, especially a compound in which a metal atom is bonded directly to a carbon atom.

Bookshelf and K&M

BARIUM - Symbol Ba A soft, silvery-white alkaline-earth metal, used to deoxidize copper and in various alloys. Atomic number 56; atomic weight 137.34; melting point 725 C; boiling point 1,140 C; specific gravity 3.50; valence 2. -------------------------------------------------------------------------- БАРИЙ (лат. Barium), Ba, химический элемент II группы периодической системы, атомный номер 56, атомная масса 137,33, относится к щелочноземельным металлам. Название от греч. barys — тяжелый. Серебристо-белый мягкий металл; плотность 3,78 г/см3, tпл 727 C. Химически очень активен, при нагревании воспламеняется. Минералы: барит и витерит. Применяют в вакуумной технике как газопоглотитель, в сплавах (типографские, подшипниковые); соли бария — в производстве красок, стекол, эмалей, в пиротехнике, медицине. (K&M)


UN No. Formula 1856

Properties Liable to ignite spontaneously according to the oil content.

Observations Bales carried as a full load in a cargo transport unit are exempted from displaying the label, provided the unit in which they are packed is placarded. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to these materials due to their low degree of danger.


Stowage Category A.

Packing, Stowage & Segregation See also General introduction and introduction to this class.


RAGS, OILY

Label of class

4.2

Bookshelf and K&M

Rags - Threadbare or tattered clothing. ----------------------------------------------------------- ВЕТОШЬ, разреженная суровая хлопчатобумажная ткань полотняного переплетения (типа марли). Применяют для покрытия слоя ваты или ватина при пошиве зимней верхней одежды. Ветошью также называют отходы текстильного производства, старые вещи. (K&M)



SEED CAKE, containing vegetable oil (a) me-chanically expelled seeds, containing more than 10% of oil or more than 20% of oil and moisture combined.

MEAL, oily OIL CAKE SEED EXPELLERS, oily

Label NO LABEL REQUIRED. Package to be marked CLASS 4.2.

UN No. Formula 1386

Properties Residue remaining after oil has been expelled mechanically from oil-bearing seeds. Used mainly as animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop), Niger seed palm kernel, rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes, pellets, meal etc. May self-heat slowly and, if wet or containing an excessive proportion of unoxidized oil, ignite spontaneously.

Observations Refuse for shipment wet, oil-stained or damaged bags. Before shipment this cargo should be properly aged, the duration of ageing required varies with the oil content. Smoking and the use of naked lights should be prohibited during load-ing and unloading and on entry to the hold(s) at any other time. If satisfied as a result of tests that such relaxation is justified, the competent authority may permit the seed cakes described in this schedule to be carried under conditions governing SEED CAKE on page 4258. Certificates from the shipper should state oil content and moisture content and should accompany the shipment. For SEED CAKES with other oil and moisture contents, see pages 4258 and 4259. Packages carried as a full load in a cargo transport unit are exempted from displaying the class number provided the unit in which they are packed is marked CLASS 4.2. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger.

Packing Any sift-proof, tear-proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers, road or rail vehi-cles) or portables tanks, see section 25 of the General Introduction. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes.


Stowage Category E. Keep dry. Notes: (1) Through and surface ventilation is required; (2) If the voyage exceeds 5 days, the vessel should be equipped with facilities

for introducing carbon dioxide or inert gas into the hold(s); (3) Bags should always be stowed in double strip as shown on page 4236 of

this Code for fishmeal, unstabilized; (4) Regular temperature readings should be taken at varying depths in the

hold and recorded If the temperature of the cargo exceeds 55° C and con-tinues to increase, ventilation to the holds should be restricted If self-heating continues then carbon dioxide or inert gas should be introduced;

(5) The cargo should be stowed «AWAY FROM» pipes and bulkheads which are liable to become heated (e. g. engine-room bulkhead).





SEED CAKE, containing vegetable oil (b) solvent extractions and expelled seeds, con-taining not more than 10% of oil and, when the amount of moisture is higher than 10%, not more than 20% of oil and moisture com-bined

MEAL, oily OIL CAKE, SEED EXPELLERS, oily


Package to be marked CLASS 4.2.

UN No. Formula 1386

Properties Residue remaining after oil has been extracted by a solvent proc-ess or expelled mechanically from oil bearing seeds. Used mainly as animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (pea-nut), linseed maize (hominy chop), Niger seed, palm kernel rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes, pellets meal etc. May self-heat slowly and, if wet or containing an excessive pro-portion of unoxidized oil, ignite spontaneously.

Observations Refuse for shipment wet, oil stained or damaged bags. Before shipment this cargo should be properly aged, the duration of ageing required varies with the oil content. The seed cake should be substantially free from flammable sol-vent. Smoking and the use of naked lights should be prohibited during loading and unloading and on entry to the cargo space(s) at any other time. If satisfied as a result of tests that such relaxation is justified, the competent authority may permit the seed cakes described in this schedule to be carried under conditions governing SEED CAKE, UN No. 2217, on page 4259. Certificates from the shipper should state oil content and moisture content and should accompany the shipment. For SEED CAKES with other oil and moisture contents, see pages 4257 and 4259. Packages carried as a full load in a cargo transport unit are ex-empted from displaying the class number provided the unit in which they are packed is marked CLASS 4.2. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger.

Packing Any sift-proof, tear-proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers, road or rail vehicles) or portable tanks, see section 25 of the General Intro-duction For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes.


Stowage Category A. Keep dry. Notes:

(1) Surface ventilation is required to assist in removing any residual solvent vapour;

(2) The cargo should be stowed “away from” pipes and bulkheads which are liable to become heated (e.g. engine-room bulkhead);

(3) If bags are stowed without provision for ventilation to circulate throughout the stow and the voyage exceeds 5 days regular temperature readings should be taken at varying depths in the hold and recorded;

(4) If the voyage exceeds 5 days the vessel should be equipped with facilities for introducing carbon dioxide or inert gas into the hold(s).





SEED CAKE, containing vegetable oil (c) sol-vent extractions containing not more than 1.5% of oil and 11% of moisture.

MEAL, oily OIL CAKE, SEED EXPELLERS, oily

Label NO LABEL REQUIRED Package to be marked CLASS 4.2.

UN No. Formula 2217

Properties Residue remaining after oil has been extracted by a solvent proc-ess from oil-bearing seeds Used mainly as an animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop), Niger seed, palm kernel, rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes pellets, meal etc. May self-heat slowly if wet and ignite spontaneously.

Observations Refuse for shipment wet, oil-stained or damaged bags. The seed cake should be substantially free from flammable sol-vent. Smoking and the use of naked lights should be prohibited during loading and unloading and on entry to the hold(s) at any other time. For SEED CAKES with other oil and moisture contents, see pages 4257 and 4258. Packages carried as a full load in a cargo transport unit are ex-empted from displaying the class number, provided the unit in which they are packed is marked CLASS 4.2. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. The provisions of this Code should not apply to a consignment of solvent-extracted SOYA BEAN MEAL containing not more than 1.5% oil and 11% moisture, being substantially free from flamma-ble solvent, which is accompanied by a certificate from the shipper stating that the substance, as offered for shipment meets these requirements.

Packing

Any sift-proof, tear-proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers, road or rail vehicles) or portable tanks, see section 25 of the General Intro-duction. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes.

Stowage

Category A. Keep dry. Notes: (1) Surface ventilation is required to assist in removing any residual sol-

vent vapour; (2) The cargo should be stowed «AWAY FROM» pipes and bulkheads,

which are liable to become heated (e.g. engine-room bulkhead).



UN No. Formula

SELF-HEATING LIQUID, INORGANIC, N.O.S. 3186

SELF-HEATING LIQUID, ORGANIC, N.O.S. 3183


Packaging group: II or III according to the grouping crite-

ria.

Label of class

4.2


Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Any self-heating liquid which, by the definition found in the introduc-tion, is included in this class and which is not specified elsewhere in this class. Liable to self-heating or spontaneous combustion.

Observations

Packing Hermetically sealed. See table 1 in the intro-duction to this class.

Stowage Category C.


Bookshelf and K&M

INORGANIC - Of or relating to compounds not containing hydrocarbon groups.


UN No. Formula 1431 CH3ONa

Properties White, amorphous, free-flowing, hygroscopic powder. Decomposed by water to form methanol a flammable liquid, which may be ignited by the heat of the reaction.

Observations Causes burns to skin eyes and mucous membranes. For SODIUM METHYLATE, SOLUTION in alcohol UN No. 1289, see class 3.2.

Packing Hermetically sealed. See TABLE 2 in the introduction to this class. BAGS ARE NOT ALLOWED.

Stowage Category B.



SODIUM METHYLATE

SODIUM METHOXIDE

Packaging group: II

Label of class


of class

8

SODIUM SULPHIDE, ANHYDROUS or SODIUM SULPHIDE with less than 30% water of crystallization.

Packaging group: II

Label of class

4.2

UN No. Formula 1385 Na2S

Properties Black solid, absorbs moisture to become crystalline. Liable to ignite spontaneously. In contact with acids evolves hydrogen sulphide a toxic and flammable gas.

Observations For SODIUM SULPHIDE HYDRATED with at least 30% water, UN No. 1849, see class 8.


Stowage Category A.



UN No. Formula

Properties Liable to ignite spontaneously according to the moisture content. Observations Packing Hermetically sealed. See TABLE 2 in the introduction to this class. BAGS ARE NOT ALLOWED.

Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

For IBCs see section 26 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


TEXTILE WASTE, WET

WOOL WASTE, WET


Label of class

4.2

THIOUREA DIOXIDE

FORMAMIDINE SULPHINIC ACID [new schedule]

Packaging group: II or III according to the grouping criteria

Label of class

4.2

UN No. Formula 3341 CH4N202S

Properties White to yellow-white crystalline powder. Virtually odourless. Strong reducing agent Violent exothermic decomposition above 100° C with emission of large amounts of sulphur oxides, ammonia, car-bon monoxide, carbon dioxide, nitrogen oxides and hydrogen sul-phide. Extended exposure to temperatures above 50° C and moisture may cause visible decomposition. Observations Dust irritating to skin, eyes and mucous membranes.


Package gross

kg Hermetically sealed: Drum, fibre (1G) - 250 Bags (5H3), (5H4), (5L3), (5M2) - 55


UN No. Formula 3174 TiS2

Properties Yellow or grey powder with an unpleasant odour.

Observations In contact with water slowly evolves hydrogen sulphide gas.

Packing Hermetically sealed. See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction.

Stowage Category A.



TITANIUM DISULPHIDE


Label of class

4.2


UN No. Formula 3254 (C4H9)3P

Properties Colourless yellowish liquid. Insoluble in water. Strong garlic odour (phosphine). Liable to heat and ignite spontaneously in air. If involved in a fire evolves phosphine, a flammable and highly toxic gas. Reacts violently with oxidizing substances (peroxides, halogens, nitric oxides and carbon tetrachloride).

Observations Irritating to mucous membranes.


Package gross

Hermetically sealed:

Contents completely covered under an inert gas blanket such as nitrogen or carbon dioxide in

1 Glass metal or plastics receptacles, packed with cushioning material together in a

wooden box (4C1), (4D), (4F) 2 kg 55 kg fibreboard box (4G) 2 kg 40 kg

2 Composite packaging (glass, porcelain or stoneware) with a hermetically sealed inner receptacle in a

steel drum (6PA1) 5 l - 3 Steel jerrican (3A1) - 60 /

Stowage Category D. «SEPARATED FROM» peroxides halogens nitric oxides and carbon tetra-chloride



TRIBUTYLPHOSPHANE

Packaging group: I

Label of class

4.2



XANTHATES [new schedule]

Packaging group: II or III according to the grouping criteria

Label of class

4.2

UN No. Formula 3342

Properties Hygroscopic yellow powder with an unpleasant odour. On contact with moisture, evolves highly flammable vapours such as carbon disulphide (UN No. 1131 which has a flashpoint of -30° C and a very low ignition temperature of 100° C). When confined, can cause an explosion due to the wide explosive limits of the vapours. Finely divided dust forms explosive mixtures in air.

Observations Care should be taken when opening cargo transport units (CTUs) in case carbon disulphide vapours are present.




Bookshelf and K&M

XANTHATE - A salt of a xanthic acid, especially a simple xanthic acid salt, as of sodium or potassium, used as a flotation collector for copper, silver, and gold. ------------------------------------------------------------- КСАНТОГЕНАТ - соль ксантогеновой кислоты, простая ксантогеновая кислая соль натрия или калия, используется как коллектор флотации для меди, серебра, и золота.



ZIRCONIUM, DRY, finished sheets, strip or coiled wire (thinner than 18 microns)


Label of class

4.2

UN No. Formula 2009 Zr

Properties Hard, silvery metal, liable to ignite spontaneously in air.

Observations For ZIRCONIUM, DRY, not thinner than 18 microns. UN No. 2858, see class 4.1.


Package gross

kg Plastics wrapper in a wooden box (4C1), (4D), (4F) - 225 fibreboard box (4G) - 55

Stowage Category D.


Bookshelf and K&M

Symbol Zr A lustrous, grayish-white, strong, ductile metallic element obtained primarily from zircon and used chiefly in ceramic and refractory compounds, as an alloying agent, and in nuclear reactors as a highly corrosion-resistant alloy. Atomic number 40; atomic weight 91.22; melting point 1,852 C; boiling point 3,578 C; specific gravity 6.56 (20 C); valence 2, 3, 4. ----------------------------------------------------------------------------------------------------- ЦИРКОНИЙ (лат. Zirconium), Zr, химический элемент IV группы периодической системы Менделеева, атомный номер 40, атомная масса 91,224. Назван по минералу циркону. Серебристо-белый металл, твердый, тугоплавкий; плотность 6,50 г/см3, tпл 1855 С. Химически очень стоек (на воздухе покрывается защитной пленкой ZrO2). Промышленные источники — минералы циркон и бадделеит. Сплавы на основе циркония — конструкционные материалы в ядерной энергетике. Цирконий входит также в состав сплавов для изготовления химической аппаратуры, хирургических инструментов и пр. Некоторые сплавы циркония — сверхпроводники. Сверхтугоплавкие карбид (tпл 3800 С), борид и нитрид циркония — материалы для жаростойкой керамики. (K&M)

CLASS 4.3 – D a n g e r o u s w h e n w e t


CERIUM turnings or gritty powder

Packaging group: II

Label of class

4.3

UN No. Formula 3078 Ce

Properties Grey ductile metal or powder. Decomposes in water and reacts violently with acids evolving hydrogen which may be ignited by the heat of the reaction.

Observations For PYROPHORIC METAL, UN No. 1383, see class 4.2.


Package gross

kg kg Hermetically sealed 1 Glass receptacles packed together in a sift proof

wooden box (4C2), (4D), (4F) 1 115 2 Metal cans packed together in a wooden box (4C2), (4D), (4F) 10 115 fibreboard box (4G) 10 40 3 Drum metal (1A2), (1B2) - 250 For IBCs see section 26 of the General Introduction.

Stowage Category E.


Bookshelf and K&M

CERIUM - A lustrous, iron-gray, malleable metallic rare-earth element that occurs chiefly in the minerals monazite and bastnaesite, exists in four allotropic states, is a constituent of lighter flint alloys, and is used in various metallurgical and nuclear applications. Atomic number 58; atomic weight 140.12; melting point 795 C; boiling point 3,468 C; specific gravity 6.67 to 8.23; valence 3, 4. --------------------------------------------------------------------------------------------------- ЦЕРИЙ (лат. Cerium), Се, химический элемент III группы периодической системы Менделеева, атомный номер 58, атомная масса 140,12, относится к лантаноидам. Назван по малой планете Церера (открыты почти одновременно). Серый металл, плотность 6,789 г/см3, tпл 804 С. Основные минералы — монацит и бастнезит (Ce, La...) FCO3. Главный компонент миш-металла. Присадки церия (и его сплавов с лантаном) улучшают свойства стали, чугуна, сплавов алюминия, магния и др. (K&M)



CHLOROSILANES, WATER-REACTIVE, FLAMMABLE, CORROSIVE, N.O.S.

Packaging group: I

Label of class

4.3 Subsidiary risk labels of

classes

3 and 8


UN No. Formula 2988

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless, very volatile liquids, flammable and corrosive, with a pungent odour. Immiscible with water. React violently with water or steam to produce heat which may lead to self-ignition, toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances.



Package gross

Hermetically sealed 1 Glass receptacles, packed with inert cushion-ing and absorbent material together in a

wooden box (4C2), (4D), (4F) 1 l 30 kg metal drum (1A2), (1B2) 1 l 30 kg 2 Drum metal (1A1), (1B1) - 250 / For tanks see section 13 of the General Introduction.

Stowage Category D. Clear of living quarters. Segregation as for class 3 but «AWAY FROM» classes 3, 4.1 and 8.



UN No. Formula 1183 C2H5SiHCl2

Properties Colourless, very volatile liquid with a pungent odour. Flashpoint -1° C c. c. Immiscible with water. Reacts violently with water or steam to produce heat which may lead to self-ignition, toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances.



Package gross

Hermetically sealed 1 Glass receptacles, packed with inert cushion-ing and absorbent material together in a

wooden box (4C2), (4D), (4F) 1 / 30 kg metal drum (1A2), (1B2) 1 / 30 kg 2 Drum, metal (1A1), (1B1) - 250 / For tanks see section 13 of the General Introduction

Stowage Category D. Clear of living quarters. Segregation as for class 3 but «AWAY FROM» classes 3, 4.1 and 8.



ETHYLDICHLOROSILANE

Packaging group: I

Label of class

4.3 Subsidiary risk labels

of classes

3 and 8



FERROSILICON with 30% or more but less than 90% silicon.

Label of class


class

6.1

UN No. Formula 1408

Properties In contact with moisture water alkalis or acids may evolve hydrogen a flammable gas which may form explosive mixtures with air and also arsine and phosphine which are highly toxic gases. These gases are evolved in proportions which under mechanically ventilated conditions make the poison hazard by far predominant over the explosion haz-ard. The rate of gas evolution is greatest from freshly broken surfaces so is liable to increase whenever the cargo is disturbed e.g. during loading.

Observations Toxic if swallowed by skin contact or by vapour inhalation. Requires a certificate from maker or shipper stating the percentage of silicon and that after manufacture the shipment was stored under cover but in the open air, in the particle size in which it is to be shipped for not less than 3 days prior to shipment. The provisions of this Code should not apply to a consignment of ferrosilicon carried in packaged form if it passes the test for class 4.3, as reflected in the United Nations Rec-ommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria Part III - 33.4.1.4 and is accompanied by an appro-priate certificate stating that the product was correctly tested and has passed the test. The packaging performance tests referred to in sec-tions 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger.

Packing Any sift proof tear proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers road or rail vehi-cles) or portable tanks see section 25 of the General Introduction. For carriage in bulk (including shipborne barges; see the Code of Safe Practice for Solid Bulk Cargoes).

Stowage Category A. Only to be loaded under dry weather conditions. Keep as dry as reasonably practicable. Under deck in a mechanically ventilated cargo space. Clear of living quarters.


Bookshelf and K&M

FERROSILICON - An alloy of iron and silicon used in the production of carbon steel. -------------------------------------- ФЕРРОСИЛИЦИЙ - сплав железа и кремния используется в производстве углеродистой стали.



ORGANOMETALLIC COMPOUND or COM-POUND SOLUTION or COMPOUND DISPER-SION, WATER-REACTIVE, FLAMMABLE, N.O.S.

Packaging group I, II or III according to the grouping criteria.

Label of class


class

3


UN No. Formula 3207

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Any organometallic compound compound solution or compound dis-persion which in contact with water emits flammable gases, which itself is flammable and which is neither specified by name in this class nor on account of its characteristics is proper to some other class.

Observations


Package gross

Hermetically sealed:

1 Metal cans packed together in a

wooden box (4C2), (4D), (4F) 15 kg 125 kg fibreboard box (4G) 15 kg 40 kg* 2 Drum metal (1A1), (1B1) - 250 / 3 Cylinder -

* 55 kg for substances in packaging group III. For tanks see section 13 of the

General Introduction.





PHOSPHORUS PENTASULPHIDE free from yellow and white phosphorus

Packaging group: II

Label of class


4.1

UN No. Formula 1340 P2S5 or P4S10

Properties Yellow solid. Ignites readily by friction. Develops heat in contact with moist air evolving toxic and flammable gases. Forms explosive and extremely sensitive mixtures with most oxidizing substances, such as chlorates, nitrates, perchlorates or permanga-nates.

Observations Harmful if swallowed or by dust inhalation.

Packing Hermetically sealed. See table 2.4 in the introduction to this class. BAGS ARE NOT ALLOWED. For IBCs see section 26 of the General Introduction.

Stowage Category D.



UN No. Formula

WATER-REACTIVE SOLID CORROSIVE N.O.S. 3131 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 3132 WATER-REACTIVE SOLID TOXIC N.O.S. 3134


Packaging group: I, II or III according to the grouping crite-

ria for each hazard

Label of class

4.3 UN No. 3131 only


8 UN No. 3132 only


4.1 UN No. 3134 only


6.1


Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Any solid which in contact with water emits flammable gases which is corrosive or toxic and which is neither specified by name in this class nor, on account of its characteristics, is proper to some other class.

Observations The conditions of transport should be approved by the competent authority of the country of origin.

Packing As specifically designated by the competent authority of the country of origin. For IBCs see section 26 of the General Introduction.

Stowage Packaging group I category D. Packaging group II and III category E. If under deck in a mechanically ventilated space.



PAGE RESERVED


CLASS 5.1 – O x i d i z i n g s u b s t a n c e s

UN No. Formula OXIDIZING SOLID, TOXIC, N.O.S. 3087 OXIDIZING LIQUID, TOXIC, N.O.S. 3099


Packaging group for UN No. 3087 I, II or III according

to the grouping criteria for each hazard

for UN No. 3099 I, II or III according to 5.2.6 of the General Introduction.

Label of class


6.1


Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Any oxidizing solid or liquid which is toxic and which is neither speci-fied by name in this class nor on account of its characteristics is proper to some other class. Observations Toxic if swallowed by skin contact or by dust inhalation. Should be handled with care to minimize exposure particularly to dust. For TOXIC SOLID, OXIDIZING, N.O.S., UN No. 3086, see class 6.1. For TOXIC LIQUID, OXIDIZING, N.O.S., UN No. 3122, see class 6.1.


Package gross

For solids of packaging group I only kg kg 1 Glass receptacles in a wooden box (4C1), (4D), (4F) 5 75 fibreboard box (4G) 5 40 2 Metal cans or plastics receptacles in a wooden box (4C2), (4D), (4F) 5 75 fibreboard box (4G) 5 40 3 Drum metal (1A2), (1B2) - 250 4 Liner in a wooden barrel (2C2) - 300 fibre drum (1G) - 180 plywood drum (1D) - 180 5 Plastics bags each in a fibreboard box in a wooden box (4C1), (4D), (4F) 1 125

6 Plastics bags in a fibreboard box (4G) - 40 7 Plastics drum (1H2) - 40

UN No. 3087, packaging groups II and III see table 2.4 in the introduc-tion to this class. UN No. 3099, packaging group I see table 2.6 in the introduction to this class. Packaging groups II and III see table 2.5 in the introduction to this class. Stowage Packaging group I category D. Packaging groups II and III category B. Separated from powdered metals ammonium compounds cyanides and hydrogen peroxide. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.


UN No. Formula

3356

Properties Oxygen generators chemical are devices containing chemicals which upon activation release oxygen as a product of chemical reaction. Chemical oxygen generators are used for the generation of oxygen for respiratory support e.g. in aircraft submarines spacecraft bomb shelters and breathing apparatus. Oxidizing salts such as chlorates and perchlorates of lithium sodium and potassium which are used in chemical oxygen generators evolve oxygen when heated. These salts are mixed (compounded) with a fuel usually iron powder, to form a chlorate candle which produces oxygen by continuous reac-tion. The fuel is used to generate heat by oxidation. Once the reac-tion begins oxygen is released from the hot salt by thermal decompo-sition (a thermal shield is used around the generator). A portion of the oxygen reacts with the fuel to produce more heat which produces more oxygen, and so on. Initiation of the reaction can be achieved by a percussion device friction device or electric wire. Observations An oxygen generator chemical containing oxidizing substances should meet the following conditions: 1 the generator when containing an explosive actuating device

should only be transported under this entry when excluded from in accordance with paragraph 2.1.3 of the United Nations Rec-ommendations on the Transport of Dangerous Goods;

2 in addition to the requirements of packaging group II applicable to the package the generator without its packaging, should be capa-ble of withstanding a 1.8 m drop test onto a rigid non-resilient flat and horizontal surface in the position most likely to cause damage without loss of its contents and without actuation;

3 when a generator is equipped with an actuating device it should have at least two positive means of preventing unintentional ac-tuation.

Packing See table 2.4 in the Introduction to this class. In addition the generator(s) should be transported in a package which will meet the following requirements when one generator in the pack-age is actuated:

1. other generators in the package will not be actuated; 2. packaging material will not ignite; and 3. the outside surface temperature of the completed pack-

age must not exceed 100° C. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


OXYGEN GENERATOR CHEMICAL [new schedule]

Packaging group: II

Label of class

5.1


UN No. Formula

1496 NaCIO2 Properties Colourless deliquescent solid Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire may cause an explosion. Observations For SODIUM CHLORITE SOLUTION, UN No. 1908, see class 8. Packing See table 2.4 in the introduction to this class. Bags 5H3, 5H4, 5L3 and 5M2 allowed only in closed cargo transport units. For IBCs see section 26 of the General Introduction. Stowage Category A. Separated from powdered metals ammonium compounds and cyanides. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

UN No. Formula 1498 NaNO3

Properties Colourless deliquescent solid Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Observations Harmful if swallowed. This substance in the impure form is known as Chile Saltpetre. Packing See table 2.4 in the introduction to this class. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes. For carriage in bulk packagings (freight containers road or rail vehicles) or portable tanks see section 25 of the General Introduc-tion. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


SODIUM CHLORITE

Packaging group: II

Label of class

5.1

SODIUM NITRATE CHILE

SALTPETRE


Label of class

5.1

Bookshelf and K&M

SODIUM NITRATE A white crystalline compound, NaNO3, used in solid rocket propellants, in the manufacture of explosives and glass and pottery enamel, and as fertilizer. Also called caliche, Chile saltpeter, saltpeter, soda niter. ---------------------------------------------------------------------------- ЧИЛИЙСКАЯ СЕЛИТРА (нитронатрит), минерал, натрия нитрат, NaNO3. Главным образом почвенные выцветы, корки, порошковатые массы белого, желтоватого, красно-коричневого, серого цвета. Твердость 1,5-2; плотность 2,3 г/см3. Образуется в основном за счет вулканической деятельности или окисления азота. Сырье для удобрений, изготовления взрывчатых веществ и др. Главные месторождения — в Чили. (K&M)


UN No. Formula 1500 NaNO2

Properties Colourless deliquescent solid Soluble in water. Mixtures with com-bustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Decomposes if heated, giving off toxic nitrous fumes and gases supporting com-bustion.

Observations Toxic if swallowed or by dust inhalation.

Packing See table 2.4 in the introduction to this class. For IBCs see section 26 of the General Introduction.

Stowage Category A. «SEPARATED FROM» ammonium compounds and cyanides.



SODIUM NITRATE AND POTASSIUM NITRATE, MIXTURE

POTASSIUM NITRATE AND SODIUM NITRATE, MIXTURE


Label of class

5.1

UN No. Formula 1499 NaNO3+ KNO3

Properties Colourless hygroscopic solid Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely.

Observations Harmful if swallowed. Mixture prepared as a fertilizer.

Packing See table 2.4 in the introduction to this class. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes. For carriage in bulk packagings (freight containers road or rail. vehicles) or portable tanks see section 25 of the General Introduction. For IBCs see section 26 of the General Introduction.

Stowage Category A.


SODIUM NITRITE


Label of class


of class

6.1

Bookshelf and K&M

SODIUM NITRATE A white crystalline compound, NaNO3, used in solid rocket propellants, in the manufacture of explosives and glass and pottery enamel, and as fertilizer. Also called caliche, Chile saltpeter, saltpeter, soda niter. --------------------------------------------------------------------- НАТРИЯ НИТРАТ (натриевая селитра), NaNO3, бесцветные кристаллы. Гигроскопичен, растворяется в воде. Природный нитрат натрия называется чилийской селитрой. Азотное удобрение (16% N). (K&M)

Bookshelf and K&M

POTASSIUM NITRATE A transparent white crystalline compound, KNO3, used to pickle meat and in the manufacture of pyrotechnics, explosives, matches, rocket propellants, and fertilizers. Also called saltpeter. --------------------------------------------------------------- КАЛИЯ НИТРАТ, (калийная селитра), KNO3, бесцветные кристаллы. Хорошо растворим в воде. Применяют как удобрение (калиевая селитра), в стекольном производстве, для приготовления черного пороха и т. д. (K&M)

CLASS 5.2 – O r g a n i c p e r o x i d e s

6 PACKING

6.1 General packing requirements

6.1.1 To avoid unnecessary confinement metal packagings meeting the test criteria of packaging group I should not be used. Organic peroxides are assigned to packaging group II (medium danger).

6.1.2 The packagings to be used should be appropriate to the physical state of the material to be transported.

6.1.3 The packagings of an organic peroxide required to bear a subsidiary risk label of should comply with the provi-sions in 3.3.9 and 3.3.10 of the introduction to .

6.1.4 All receptacles should be effectively closed. Where significant internal pressure may develop in a package by the evolution of gas a vent may be fitted provided the qas emitted will not cause danger, otherwise the degree of filling should be limited. Any venting device should be so constructed, that liquid will not escape when the pack-age is in an upright position and it should be able to prevent ingress of impurities. The outer packaging, if any, should be so designed as not to interfere with the operation of the venting device.

6.1.5 When plastics drums plastics jerricans or composite packagings are used the compatibility of the plastics mate-rial with a liquid organic peroxide should be tested in accordance with 8.3.5 of Annex I to this Code. Organic peroxides may show damaging effects on plastics by, for example, stress, cracking, swelling or oxidative degra-dation. This can be tested by storing over a long period for example six months the packaging filled with the organic peroxide or with appropriate substitutes approved by the competent authority of the country of origin.

6.1.6 Packagings for organic peroxides should meet the requirements of Annex I to this Code and should be so con-structed that none of the materials which are in contact with the contents will catalyse or otherwise dangerously affect the properties of their contents. For instance a metal drum should only be constructed of:

1 material compatible with its intended contents; or

2 material effectively treated so as to make it compatible with its contents or should be lined inter-nally with an inert material.

6.1.7 For combination packagings cushioning materials should not be readily combustible and should not cause de-composition of the organic peroxide, if leakage occurs.

6.1.8 Except for classes 1.6.2 and 7 packaging requirements can be found in section 10 and Annex I of the General Introduction to this Code Provisions for the carriage of limited quantities of dangerous goods can be found in section 18.

6.2 Types of packagings and limits

6.2.1 The packing methods for organic peroxides are listed in 6.3 and are designated as OP1A to OP8A for liquids and OP1B to OP8B for solids. The quantities specified for each packing method represent the maximum currently considered good practice. The following kinds of packagings may be used:

- drums conforming to 7.1, 7.2, 7.4, 7.6 or 7.7 of Annex I; or

- jerricans conforming to 7.3 or 7.7; or



- boxes conforming to 7.8, 7.9, 7.10, 7.11, 7.12 or 7.13; or

- composite packagings with a plastics inner receptacle conforming to 7.18 of Annex I to this Code; provided that:

I. the provisions of Annex I are complied with;

II. metal packagings (including inner packagings of combination packagings and outer packagings of combination or composite packagings) are used only for packing methods OP7 and OP8;

III. in combination packagings, glass receptacles are used only as inner packagings with a maximum con-tent of 0.5 kg or 0.5 l.

6.2.2 The packing methods appropriate for the individual currently assigned organic peroxides are listed in the appen-dices to the individual schedules. A packing method corresponding to a smaller package size (i.e. with a lower OP number) may be used but a packing method corresponding to a larger package size (i.e. with a higher OP number) should not be used.

6.2.3 For new organic peroxides or new formulations of currently assigned organic peroxides, the following procedure should be used to assign the appropriate packing method.

1 ORGANIC PEROXIDE TYPE B

Packing method OP5A or OP5B should be assigned provided that the organic peroxide satisfies the criteria in 3.3.2 in one of the packagings shown for this packing method. If the organic peroxide can only satisfy these criteria in a smaller packaging than those listed for packing method OP5A or OP5B (i.e. one of the packagings listed for OP1A to OP4A or OP1B to OP4B) then the corresponding packing method with the lower OP number has to be assigned.

2 ORGANIC PEROXIDE TYPE C

Packing method OP6A or OP6B should be assigned provided that the organic peroxide satisfies the criteria in 3.3.3 in one of the packagings shown for this packing method. If the organic peroxide can only satisfy these criteria in a smaller packaging than those listed for packing method OP6A or OP6B then the corresponding pack-ing method with the lower OP number has to be assigned.

3 ORGANIC PEROXIDE TYPE D

Packing method OP7A or OP7B should be assigned to this type of organic peroxide.

4 ORGANIC PEROXIDE TYPE E


5 ORGANIC PEROXIDE TYPE F




TABLE 1 - ORGANIC PEROXIDE LIQUID1

Packing method Type and material

Packaging code

(Annex I) OP1A OP2A2 OP3A OP4A2 OP5A OP6A OP7A OP8A

Steel drum 1A1 P P P P P P 60 l 225 l

Steel drum3 1A2 P P P P P P 50 kg 200 kg

Aluminium drum 1B1 P P P P P P 60 I 225 l

Aluminium drum 1B2 P P P P P P 60 I 225 l

Plywood drum3 1D 0.5 kg 0.5 l / 10 kg 5 kg 5 l / 25 kg 25 kg 50 kg 50 kg 200 kg

Fibre drum3 1G 0.5 kg 0.5 l / 10 kg 5 kg 5 l / 25 kg 25 kg 50kg 50 kg 200 kg

Plastics drum 1H1 0.5 I - 5 l - 30 l 60 l 60 l 225 l

Plastics drum 1H2 0.5 l - 5 l - 30 l 60 l 60 l 225 l

Steel jerrican 3A1 P P P P P P 60 I 60 l

Steel jerrican 3A2 P P P P P P 60 l 60 l

Aluminium jerrican 3B1 P P P P P P 60 l 60 l

Aluminium jerrican 3B2 P P P P P P 60 l 60 l

Plastics jerrican 3H1 0.5 l - 5 l - 30 l 60 l 60 l 60 l

Plastics jerrican 3H2 0.5 l - 5 l - 30 l 60 l 60 I 60 l

Steel box3 4A P P P P P P 50kg 200 kg

Aluminium box3 4B P P P P P P 50kg 200 kg

Wooden box3 4C1 0.5 kg 0.5 l / 10 kg 5 kg 5 l / 25 kg 25 kg 50 kg 50 kg 200 kg

Wooden box3 4C2 0.5 kg 0.5 l / 10 kg 5 kg 5 l / 25 kg 25 kg 50 kg 50 kg 200 kg

Plywood box3 4D 0.5 kg 0.5 l / 10 kg 5 kg 5 l / 25 kg 25 kg 50 kg 50 kg 200 kg

Reconstituted wood box3 4F 0.5 kg 0.5 l / 10 kg 5 kg 5 l / 25 kg 25 kg 50 kg 50 kg 200 kg

Fibreboard box3 4G 0.5 kg 0.5 l / 10 kg 5kg 5 l / 25 kg 25 kg 50 kg 50 kg 200 kg

Plastics box3 4H2 0 5 kg 0.5 l / 10 kg 5 kg 5 l / 25 kg 25 kg 50 kg 50 kg 200 kg


TABLE 1 - ORGANIC PEROXIDE LIQUIDS1 (continued)

Packing method Type and material

Packaging code

(Annex I) OP1A OP2A2 OP3A OP4A2 OP5A OP6A OP7A OP8A

Plastics receptacle with outer steel drum 6HA1 P P P P p P 60 l 225 l

Plastics receptacle with outer steel crate or box 6HA2 P P P P P P 60 l 225 l

Plastics receptacle with outer aluminium drum 6HB1 P P P P P P 60 l 225 l

Plastics receptacle with outer aluminium crate or box 6HB2 P P P P P P 60 l 225 I

Plastics receptacle with outer wooden box 6HC 0.5 l 0.5 l / 10 kg 5 l 5 l / 25 kg 25 l 50 l 60 l 225 l

Plastics receptacle with outer plywood drum 6HD1 0.5 l 0.5 l / 10 kg 5 l 5 l / 25 kg 25 I 50 l 60 l 225 l

Plastics receptacle with outer plywood box 6HD2 0.5 l 0.5 l / 10 kg 5 l 5 l / 25 kg 25 l 50 l 60 I 225 l

Plastics receptacle with outer fibre drum 6HG1 0.5 l 0.5 l / 10 kg 5 I 5 l / 25 kq 25 l 50 I 60 l 225 l

Plastics receptacle with outer fibreboard box 6HG2 0.5 l 0.5 l / 10 kg 5 l 5 l / 25 kg 25 l 50 l 60 l 225 l

Plastics receptacle with outer plastics drum 6HH1 0.5 l 0.5 l / 10 kg 5 l 5 l / 25 kg 25 l 50 l 60 l 225 l

Plastics receptacle with outer solid elastics box 6HH2 0.5 l 0.5 l 5 l 5 l / 25 kg 25 l 50 l 60 l 225 l

P = Prohibited 1 Viscous liquids should be treated as solids if the criterion in 5.1.10 of the General Introduction is met. 2 If two values are given, the first applies to the maximum net volume per inner packaging and the second to the maximum net mass of the complete package. 3 Only allowed as part of a combination packaging. Inner packagings should be suitable for liquids.


UN No. 3115 - Appendix

ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED

Concentra-tion

Diluent type A

Diluent type B Water

Formulations (%) (%) (%) (%)

Packing method

Control tempe-rature (˚C)

Emer-gency tempe-rature (˚C)

Remarks

ACETYL CYCLOHEXANESULPHONYL PEROXIDE ≤32 ≥68 OP7A -10 0

tert-AMYL PEROXY-2-ETHYLHEXANOATE ≤100 OP7A +20 +25 tert-AMYL PEROXYNEODECANOATE ≤77 ≥23 OP7A 0 +10 tert -BUTYL PEROXY-2-ETHYLHEXANOATE+ 2,2-Dl-( tert- BUTYLPEROXY)BUTANE ≤31+ ≤36 ≥33 OP7A +35 +40

tert - BUTYL PEROXYISOBUTYRATE ≤52 ≥48 OP/A +15 +20 tert-BUTYL PEROXYNEODECANOATE ≥77-100 OP7A -5 +5 tert-BUTYL PEROXYNEODECANOATE ≤77 ≥ 23 OP7A 0 +10 tert-BUTYL PEROXYNEOHEPTANOATE ≤77 ≥23 OP7A +5 +10 tert-BUTYL PEROXYPIVALATE >27-67 ≥33 OP7A 0 +10 CUMYL PEROXYNEODECANOATE ≤77 ≥23 OP7A -10 0 CUMYL PEROXYNEOHEPTANOATE ≤77 ≥23 OP7A -10 0 CUMYL PEROXYPIVALATE ≤77 ≥23 OP7A -5 +5 DIACETONE ALCOHOL PEROXIDES ≤57 ≥2b ≥8 OP7A +40 +45 1 DIACETYL PEROXIDE ≤27 ≥ 73 OP7A +20 +25 2, 3 Dl-n-BUTYL PEROXYDICARBONATE >27-52 ≥48 OP7A -15 -1 Dl-sec- BUTYL PEROXYDICARBONATE ≤52 ≥48 OP7A -15 -5 Dl-(2-ETHYLHEXYL) PEROXYDICARBONATE ≤77 OP7A -15 -5 DIETHYL PEROXYDICARBONATE ≤27 ≥73 OP7A -10 0 DIISOBUTYRYL PEROXIDE ≤32 ≥68 OP7A -20 -10 DIISOPROPYL PEROXYDICARBONATE ≤52 >48 OP7A 10 0 DIISOTRIDECYL PEROXYDICARBONATE ≤ 100 OP7A 10 0 2,5-DIMETHYL-2,5-Dl-(2-ETHYLHEXANOYL-PEROXV)HEXANE ≤100 OP7A +20 +25

Dl-(2-NEODECANOYLPEROXY-ISOPROPYLBENZENE ≤52 ≥48 OP7A -10 0

Dl-(3,5,5-TRIMETHYLHEXANOYL) PEROXIDE >38-82 ≥18 OP7A 0 +10 ISOPROPYL sec-BUTYL ≤32+ ≤15-

18≥38 OP7A -20˚ C -10˚ C

PEROXYDICARBONATE + Dl-sec-BUTYL PEROXYDICARBONATE + Dl-ISOPROPYL PEROXYDICARBONATE

+≤12-15

METHYLCYCLOHEXANONE PEROXIDE(S) ≤67 ≥33 OP/A +35 +40 1,1,3,3-TETRAMETHYLBUTYL-PEROXY-2-ETHYLHEXANOATE ≤100 OP7A +20 +25

2,4,4-TRIMETHYLPENTYL-2-PEROXY

NEODECANOATE ≤72 ≥28 OP7A -5 +'5

2,4,4-TRIMETHYLPENTYL-2-PEROXY

PHENOXYACETATE ≤37

≥63

OP/A -10 0

Remarks: 1 With ≤9% hydrogen peroxide available oxygen ≤ 10%. 2 Only non-metallic packaging is allowed. 3 Subsidiary risk label of class 8 is required.




ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED

Packaging group: II

Label of class

5.2

UN No. 3116

Properties Decomposes at temperatures higher than the emergency tempera-ture or in a fire. Burns vigorously. Insoluble in water unless otherwise indicated in the "Remarks" col-umn of the appendix to this schedule.

Observations Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in the appendix to this schedule. The temperature must be checked regularly. New organic peroxides or new formulations of currently assigned organic peroxides may be carried under the provisions of this schedule, see 2.5 of the introduction to this class.

Packing See 6.2 of the introduction to this class. For packing methods, see appendix to this schedule. For the permitted packagings and their maximum contents see TABLE 2 in the introduction to this class.

Stowage Category D. Must be transported under temperature control.


CLASS 6.1 – T o x i c s u b s t a n c e s

2.1.4 In assigning the packaging group of a toxic substance for which no specific packaging group is given in the individual schedule, due account should be taken of the toxicity exhibited by all three routes of administration and of the provisions in 2.1.3 above. The packaging group of a substance or mixture possessing more than one hazard should be determined in accordance with subsection 5.2 of the General Introduction.

2.2 Definitions

2.2.1 LD50 for acute oral toxicity

That dose of the substance administered which is most likely to cause death within 14 days in one half of both male and female young adult albino rats. The number of animals tested should be sufficient to give a statisti-cally significant result and be in conformity with good pharmacological practices. The result is expressed in milligrams per kilogram body mass.

2.2.2 LD50 for acute dermal toxicity

That dose of the substance which, administered by continuous contact for 24 hours with the bare skin of the albino rabbit is most likely to cause death within 14 days in one half of the animals tested. The number of ani-mals tested should be sufficient to give a statistically significant result and be in conformity with good pharma-cological practices. The result is expressed in milligrams per kilogram body mass.

2.2.3 LC50 for acute toxicity on inhalation

That concentration of vapour, mist or dust which, administered by continuous inhalation to both male and fe-male young adult albino rats for one hour, is most likely to cause death within 14 days in one half of the animals tested. A solid substance should be tested if at least 10% (by mass) of its total mass is likely to be dust in the respirable range, e.g. the aerodynamic diameter of that particle fraction is 10 microns or less. A liquid sub-stance should be tested if a mist is likely to be generated in a leakage of the transport containment. For both solid and liquid substances more than 90% (by mass) of a specimen prepared for inhalation toxicity testing should be in the respirable range as defined above. The result is expressed in milligrams per litre of air for dusts and mists or in millilitres per cubic metre of air (parts per million) for vapours.

2.3 Grouping criteria

2.3.1 The criteria for grouping a substance according to the toxicity it exhibits by all three routes of administration are presented in the following paragraphs.



2.3.2 The grouping criteria for the oral and dermal routes as well as for inhalation of dusts and mists are shown in the following table

Grouping criteria for administration through oral ingestion, dermal contact and inha-lation of dusts and mists

Packaging group Oral toxicity

LD50 (mg/kg)

Dermal toxicity LD50

(mg/kg)

Inhalation toxicity by dusts and mists LD50 (one hour)

(mg/l)

I ≤ 5 ≤ 40 ≤ 0.5

II > 5 - 50 > 40 - 200 > 0.5 - 2

III Solids 1 > 50 - 200 > 200 – 1.000 > 2 - 10

Liquids > 50 - 500 > 200 - 1.000 > 2 - 10

1 Tear gas substances whose toxicity data correspond to the values shown for packaging group III should nevertheless be included in packaging group II.

Note: Substances meeting the criteria of class 8 and with an inhalation toxicity of dusts and mists (LD50), leading

to packaging group I should only be accepted for an allocation to class 6.1 if the toxicity through oral in-gestion or dermal contact is at least in the range of packaging group I or II. Otherwise an allocation to class 8 should be appropriate (see 2.1.2 of the introduction to class 8)

2.3.3 Liquids having toxic vapours should be assigned to the following packaging groups where “V” is the saturated vapour concentration in ml/m3 an at 20˚C and standard atmospheric pressure:

Packaging group I - If V≥ 10 LD50 and LD50 ≤ 1.000 ml/m3

Packaging group II - If V≥ 10 LD50 and LD50 ≤ 3.000 ml/m3 and do not meet the criteria for packaging group I

Packaging group III* - If V≥ 1/5 LD50 and LD50 ≤ 5.000 ml/m3 and do not meet the criteria for packaging group I or II

* Tear gas substances whose toxicity data correspond to the values shown for packaging group III should nevertheless be included in packaging group II.



2.5.3 In the absence of LC50 data on the toxic (poisonous) constituent substances the mixture may be assigned a packaging group based on the following simplified threshold toxicity tests. When these threshold tests are used the most restrictive packaging group should be determined and used for transporting the mixture.

1 A mixture is assigned to packaging group I only if it meets both of the following criteria:

1.1 A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 1000 ml/m3 vaporized mixture in air. Ten albino rats (five male and five female) are exposed to the test atmosphere for one hour and observed for 14-days. If five or more of the animals die within the 14-day observation period the mix-ture is presumed to have an LC50 equal to or less than 1000 ml/m3.

1.2 A sample of the vapour in equilibrium with the liquid mixture at 20° C is diluted with nine equal volumes of air to form a test atmosphere. Ten albino rats (five male and five female) are exposed to the test atmosphere for one hour and observed for 14 days. If five or more of the animals die within the 14-day observation period the mixture is presumed to have a volatility equal to or greater than 10 times the mixture LC50.

2. A mixture is assigned to packaging group II only it, it meets both of the following criteria and the mixture does not meet the criteria for packaging group I.


2.2 A sample of the vapour in equilibrium with the liquid mixture at 20° C is used to form a test atmosphere. Ten albino rats (five male and five female) are exposed to the test atmosphere for one hour and observed for 14-days. If five or more of the animals die within the 14-day observation period the mixture is presumed to have a volatility equal to or greater than the mixture LC50.

3 A mixture is assigned to packaging group III only if it meets both of the following criteria and the mixture does not meet the criteria for packaging groups I or II.


3.2 The vapour pressure of the liquid mixture is measured and if the vapour concentration is equal to or greater than 1000 ml/m3 the mixture is presumed to have a volatility equal to or greater than 1/5 the mixture LC50.

2.6 Methods for determining oral and dermal toxicity of mixtures.

2.6.1 When classifying and assigning the appropriate packaging group to mixtures in class 6.1 in accordance with the oral and dermal toxicity criteria in 2.3.2 it is necessary to determine the acute LD50 of the mixture.



2.6.2 If a mixture contains only one active substance, and the LD50 of that constituent is known, in the absence of reliable acute oral and dermal toxicity data on the actual mixture to be transported, the oral or dermal LD50 may be ob-tained by the following method:

LD50 value of active substance x 100 LD50 value of preparation = percentage of active substance by mass

2.6.3 If a mixture contains more than one active constituent, there are three possible approaches that may be used to determine the oral or dermal LD50 of the mixture. The preferred method is to obtain reliable acute oral and der-mal toxicity data on the actual mixture to be transported. If reliable, accurate data is not available, then either of the following methods may be performed:

.1 Classify the formulation according to the most hazardous constituent of the mixture as if that constituent were present in the same concentration as the total concentration of all active constituents; or

.2 Apply the formula:

MZ

Z

B

B

A

A

TTC

TC

TC 100=++

where: C = the % concentration of constituent A, B ... Z in the mixture; T = the oral LD50 values of constituent A, B ... Z; TM = the oral LD50 value of the mixture.

Note: This formula can also be used for dermal toxicities provided that this information is available on the same species for all constituents. The use of this formula does not take into account any potentiation or protec-tive phenomena.

2.7 Classification of pesticides

2.7.1 Alt active pesticide substances and their preparations for which the LC50 and/or LD50 values are known and which are classified in class 6.1 should be classified under appropriate packaging groups in accordance with the crite-ria given in subsection 2.1 of the introduction to this class. Substances and preparations which are character-ized by subsidiary risks should be classified according to the Precedence of hazard table with the assignment of appropriate packaging groups (see 5.2.7 of the General Introduction).

2.7.2 If the oral or dermal LD50 value for a pesticide preparation is not known but the LD50 value of its active substance(s) is known, the LD50 value for the preparation may be obtained by applying the procedures described in section 2.6 of the introduction to this class.

Note: LD50 toxicity data for a number of common pesticides may be obtained from the most current edition of the WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification available from the International Programme on Chemical Safety, World Health Organization (WHO), 1211 Geneva 27, Switzerland. White that publication may be used as a source of LD50 data for pesticides, its classifica-tion system should not be used for purposes of transport classification of, or assignment of packaging groups to pesticides, which should be in accordance with the provisions of this Code.



2.7.3 The proper shipping name used in the transport of the pesticide should be selected on the basis of the active ingredient, of the physical state of the pesticide and any subsidiary risks it may exhibit.

2.7.4 A marine pollutant is indicated by either a "P" or "PP" adjacent to its name in the pesticides table. A solution or mixture containing 10% or more of a marine pollutant or marine pollutants, indicated by a "P", is a marine pollut-ant. A solution or mixture containing 1% or more of a marine pollutant or marine pollutants with a severe pollution potential, indicated by a "PP", is a marine pollutant. See also 2.3.2 of the General Introduction.

2.8 Packing - general requirements

2.8.1 All packagings should be at least "effectively closed" However for substances which fall within the class 6.1, packaging group I or II inhalation toxicity criteria all packagings should be hermetically sealed

2.8.2 Parts of packagings which are in direct contact with dangerous substances should not be affected by chemical or other action of those substances. Where necessary, they should be provided with a suitable inner coating or treatment. Such parts of packagings should not incorporate constituents liable to react dangerously with the con-tents so as to form hazardous products or to weaken them significantly.

2.8.3 Where significant internal pressure may develop in a package by the evolution of gas from the contents (arising from temperature increase or other causes), a vent may be fitted provided the gas emitted will not cause danger, taking into account toxicity, flammability and quantity. The venting device should be so constructed that liquid will not escape when the package is in an upright position. The outer packaging should be so arranged as not to interfere with the operation of the venting device.



2.8.4 As the vapour pressure of liquids with a low boiling point is usually high, the strength of packagings for these liquids should be sufficient to withstand, with an ample factor of safety, the internal pressures likely to be gen-erated.

2.8.5 When filling packagings with liquids* sufficient ullage should be left to ensure that neither leakage nor perma-nent distortion of the packagings occurs as a result of an expansion of the liquid caused by temperatures likely to occur during transport. Unless specific requirements are prescribed in national or international rules agree-ments, or recommendations liquids should not completely fill a packaging at a temperature of 55° C.

2.8.6 Unless otherwise indicated where a percentage of a substance, or of its active ingredient is stipulated, this refers to the percentage by mass in relation to the total mass of the substance in the state in which it is to be transported.

2.8.7 Packaging requirements can be found in section 10 and Annex I of the General Introduction to this Code whilst provisions for the carriage of limited quantities of dangerous goods can be found in section 18.

2.9 Packing - packaging types and limits

2.9.1 Except where there are special packing requirements in the individual schedules, the packagings indicated in the tables in subsection 2.4 of this introduction should be used.

2.9.2 Glass receptacles packaged in an outer packaging should be surrounded by inert cushioning material so ar-ranged as to prevent breakage and leakage from the package. For liquids, this cushioning material should also be absorbent. This is not necessary if close fitting parts of expanded plastics are used as cushioning material and the requirements of the second sentence of 2.3.1.5 are met, when appropriate.

2.9.3 Where glass is permitted, it should be understood to include earthenware, porcelain and other comparable materials unless stipulated otherwise.

2.9.4 Where glass or plastics receptacles are permitted it should be understood that glass or plastics bottles or jars are included.

2.9.5 Where wooden boxes are permitted as outer packagings, it should be understood that boxes of natural wood (4C1) plywood boxes (4D) and reconstituted wood boxes (4F) are included.

2.9.6 Moulded expanded plastics boxes (4H1) should be constructed of a fire-resistant grade of material. When the contents are not compatible with the outer packaging, each glass bottle should be enclosed in a bag made of plastics material compatible with the contents and the bag should be effectively closed.

2.9.7 A cylinder of the kind normally used for compressed gases, approved by the competent authority of the country concerned and with suitable valve protection, may be used to contain any toxic liquid provided that this liquid is compatible with the material of construction.

2.9.8 Removable head packagings should not be used for the transport of liquids, except that steel and aluminium removable head drums or jerricans may be used for liquids in packaging groups II and III when these packag-ings successfully pass the test for liquids.

2.9.9 Non-removable head packagings (1A1, 3A1, 1B1, 1H1 and 3H1) tested for liquids in accordance with the provi-sions of Annex I may also be used as packagings for solids on condition that the testing qualifications indicated in the UN mark are observed.

* With respect to ullage limits only, viscous substances with an outflow time via a DIN-cup with a 4 mm diameter outlet ex-ceeding 10 minutes at 20° C (corresponding to an outflow time via a Ford cup 4 of more than 690 seconds at 20° C, or to a viscosity of more than 2.680 centistokes at 20° C) should be subject to the provisions applicable for packagings destined for solid substances.



2.10 Packaging specificationsTABLE 1 - LIQUIDS [new table]


Packaging group

Inner packaging Outer packaging Packaging code (Annex 1)

I II III Drums - Steel 1A2 75 kg 125 kg 125 kg Aluminium 1B2 75 kg 125 kg 125 kg Plywood 1D 75 kg 125 kg 125 kg Fibre 1G 75 kg 125 kg 125 kg

Receptacles, glass, porce-lain and stoneware maxi-mum contents 10 litres, or

Plastics 1H2 75 kg 125 kg 125 kg Jerricans - Steel 3A2 60 kg 120 kg 120 kg Aluminium 3B2 60 kg 120 kg 120 kg

Receptacles, plastics, maximum contents 30 litres or Plastics 3H2 30 kg 60 kg 60 kg

Boxes - Steel 4A 75 kg 125 kg 125 kg Aluminium 4B 75 kg 125 kg 125 kg Plywood 4D 75 kg 125 kg 125 kg Natural wood 4C1, ,4C2 75 kg 125 kg 125 kg Reconstituted wood 4F 75 kg 125 kg 125 kg


Solid plastics 4H2 75 kg 125 kg 125 kg Boxes - Fibreboard 4G 401 kg 551 kg 551 kg Boxes - Moulded expanded

plastics 4H1 40 kg 55 kg 55 kg

Drums - Steel 1A1 250 litres 250 litres 250 litres Steel 1A2 Prohibited 2504 litres 2504 litres Aluminium 1B1 250 litres 250 litres 250 litres Aluminium 1B2 Prohibited 2504 litres 2504 litres Drums - Plastics 1H1 2502 litres 250 litres 250 litres Jerricans - Steel 3A1 60 litres 60 litres 60 litres Steel 3A2 Prohibited 604 litres 604 litres Aluminium 3B1 60 litres 60 litres 60 litres Aluminium 3B2 Prohibited 604 litres 604 litres Plastics 3H1 602 litres 60 litres 60 litres Cylinders According to the design type3 Plastics receptacle in a steel crate or box 6HA2 602 litres 60 litres 60 litres aluminium crate or box 6HB2 602 litres 60 litres 60 litres wooden box 6HC 602 litres 60 litres 60 litres plywood box 6HD2 602 litres 60 litres 60 litres fibreboard box 6HG2 602 litres 60 litres 60 litres solid plastics box 6HH2 602 litres 60 litres 60 litres Notes: 1 When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to

100 kg for packaging groups II and III and 75 kg for packaging group I. 2 Not permitted for class 3 packaging group I. 3 Cylinders of carbon steel, special steels copper alloy and aluminium alloy �” 150 litres.

Receptacles of carbon steel special steels, copper alloy and aluminium alloy �• 100 to �”1000 litres. 4 Tested for liquids.



[new table]


Packaging group Table 1 (continued) Packaging code (Annex I)

I II III Plastics receptacle in a plywood drum 6HD1 1202 litres 250 litres 250 litres fibre drum 6HG1 1202 litres 250 litres 250 litres plastics drum 6HH1 1202 litres 250 litres 250 litres Plastics receptacle in a steel drum 6HA1 250 litres 250 litres 250 litres aluminium drum 6HB1 250 litres 250 litres 250 litres Glass receptacle in a steel drum 6PA1 602 litres 60 litres 60 litres steel crate or box 6PA2 602 litres 60 litres 60 litres aluminium drum 6PB1 602 litres 60 litres 60 litres aluminium crate or box 6PB2 602 litres 60 litres 60 litres wooden box 6PC 602 litres 60 litres 60 litres plywood drum 6PD1 602 litres 60 litres 60 litres plywood box 6PD2 602 litres 60 litres 60 litres fibre drum 6PG1 602 litres 60 litres 60 litres fibreboard box 6PG2 602 litres 60 litres 60 litres expanded plastics drum 6PH1 602 litres 60 litres 60 litres solid plastics drum 6PH2 602 litres 60 litres 60 litres Note: 2 Not permitted for class 3, packaging group I.



TABLE 2 - SOLIDS [new table]

Maximum gross mass


I II III Drums - Steel 1A2 125 kg 225 kg 225 kg Aluminium 1B2 125 kg 225 kg 225 kg Plywood 1D 125 kg 225 kg 225 kg

Fibre 1G 125 kg 225 kg 225 kg

Receptacles, glass, porcelain and stoneware, maximum contents 10 kg; or


Receptacles, plastics, maxi-mum contents 30 kg, or

Plastics 3H2 75 kg 120 kg 120 kg Boxes - Plywood 4D 125 kg 225 kg 225 kg Natural wood 4C1 125 kg 225 kg 225 kg Reconstituted 4F 125 kg 225 kg 225 kg

Receptacles, metal, maximum contents 40 kg, or

wood 4A 125 kg 225 kg 225 kg Steel 4B 125 kg 225 kg 225 kg Aluminium 4H2 125 kg 225 kg 225 kg

Bags maximum contents 50 kg

Solid plastics Boxes - 4C2 400 kg 400 kg 400 kg

Natural wood with sift proof walls

Boxes - Fibreboard 4G 402 kg 552 kg 552 kg Boxes - Expanded plastics 4H1 40 kg 55 kg 55 kg

Drums - Steel 1A1, 1A2 400 kg 400 kg 400 kg Aluminium 1B1,1B2 400 kg 400 kg 400 kg Plywood 1D1 400 kg 400 kg 400 kg Fibreboard 1G1 400 kg 400 kg 400 kg Plastics

1H1,1H2 400 kg 400 kg 400 kg Jerricans - Steel 3A1, 3A2 120 kg 120 kg 120 kg Aluminium 3B1, 3B2 120 kg 120 kg 120 kg Plastics 3H1, 3H2 120 kg 120 kg 120 kg Boxes - Steel 4A Prohibited 225 kg 225 kg Aluminium 4B Prohibited 225 kg 225 kg Natural wood 4C11 Prohibited 225 kg 225 kg Fibreboard 4G1 Prohibited 225 kg 225 kg Plywood 4D1 Prohibited 225 kg 225 kg Reconstituted wood 4F1 Prohibited 225 kg 225 kg Solid plastics 4H21 Prohibited 225 kg 225 kg Moulded expanded plastics 4H1 Prohibited 60 kg 60 kg Barrels 4C21 400 kg 400 kg 400 kg Notes: 1 These packagings should not be used when the contents are likely to melt during the voyage.

2 When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100 kg for packaging groups II and III and 75 kg for packaging group I.



[new table]

Maximum gross mass Packaging group Table 2 (continued)

Packaging code

(Annex I) I II III

Bags woven plastics, water-resistant 5H31 Prohibited 503 kg 502 kg plastics film 5H41 Prohibited 502 kg 502 kg textile water-resistant 5L31 Prohibited 502 kg 502 kg paper multiwall, water-resistant 5M21 Prohibited 502 kg 502 kg Plastics receptacle in a steel drum 6HA1 400 kg 400 kg 400 kg aluminium drum 6HB1 400 kg 400 kg 400 kg Plastics receptacle in a plywood drum 6HD1 120 kg 250 kg 250 kg fibre drum 6HG1 120 kg 250 kg 250 kg plastics drum 6HH1 120 kg 250 kg 250 kg

Plastics receptacle in a fibreboard box 6HG2 40 kg 55 kg 55 kg Glass receptacle in a steel drum 6PA1 75 kg 75 kg 75 kg steel crate or box 6PA2 75 kg 75 kg 75 kg aluminium drum 6PB1 75 kg 75 kg 75 kg aluminium crate or box 6PB2 75 kg 75 kg 75 kg wooden box 6PC 75 kg 75 kg 75 kg plywood drum 6PD1 75 kg 75 kg 75 kg wickerwork hamper 6PD2 75 kg 75 kg 75 kg fibre drum 6PG1 75 kg 75 kg 75 kg fibreboard box 6PG2 75 kg 75 kg 75 kg expanded plastics drum 6PH1 75 kg 75 kg 75 kg solid plastics drum 6PH2 75 kg 75 kg 75 kg Notes: 1 These packagings should not be used when the contents are likely to melt during the voyage.

2 When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100

kg for packaging groups II and III and 75 kg for packaging group I.

3 For bags 50 kg net mass applies.



3 STOWAGE

3.1 Class 6.1 substances should be stowed as indicated in the individual schedules in accordance with one of the categories specified below.

3.1.1 Stowage category A

Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length, whichever is the greater number.

ON DECK OR UNDER DECK

Other passenger ships in which the limiting number of passengers carried is exceeded. ON DECK OR UNDER DECK

3.1.2 Stowage category B



Other passenger ships in which the limiting number of passengers carried is exceeded. ON DECK ONLY

3.1.3 Stowage category C

Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length whichever is the greater number.

ON DECK ONLY

Other passenger ships in which the limiting number of passengers carried is exceeded. ON DECK ONLY

3.1.4 Stowage category D


ON DECK ONLY

Other passenger ships in which the limiting number of passengers carried is exceeded. PROHIBITED

3.1.5 Stowage category E

Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length whichever is the greater number.


Other passenger ships in which the limiting number of passengers carried is exceeded.

PROHIBITED



UN No. Formula ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S.

1544

ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S.

3140


Packaging group: I, II or III according to toxicity criteria

Label of class

6.1


Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. A wide range of toxic solids or liquids generally of vegetable origin.

Observations Toxic if swallowed by skin contact or by inhalation. When offered for carnage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).

Packing For liquids see table 1 in the introduction to this class. For solids see TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction.

Stowage Category A.



PAGE RESERVED



UN No. Formula 1547 C6H5NH2

Properties Colourless oily volatile liquid. Reacts with acids.


Packing See table 1 of the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.

Stowage Category A. Clear of living quarters.



ANILINE

AMINOBENZENE

ANILINE OIL

PHENYLAMINE

Packaging group: II

Label of class

6.1

ANILINE HYDROCHLORIDE

ANILINE CHLORIDE

ANILINE SALT


Label of class

6.1

UN No. Formula 1548 C6H5NH2 HCI

Properties White crystalline solid. Soluble in water. Decomposes to aniline in contact with alkalis.



Stowage Category A.


Bookshelf and K&M

ANILINE - A colorless, oily, poisonous benzene derivative, C6H5NH2, used in the manufacture of rubber, dyes, resins, pharmaceuticals, and varnishes. -------------------------------------------------------- АНИЛИН, C6H5NH2, бесцветная жидкость, tкип 184,4 C. Применяется в производстве красителей, фармацевтических препаратов, взрывчатых веществ, полимеров, ускорителей вулканизации каучука. (K&M)


UN No. Formula

2431 H2NC6H4OCH3

Properties

Reddish or yellowish oily liquid. Immiscible with water.

Observations Toxic if swallowed, by skin contact or by inhalation.

Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.

Stowage Category A.



ortho-ANISIDINE

ortho-METHOXYANILINE

ortho-AMINOANISOLE


Label of class

6.1


UN No. Formula 1562

Properties Fine powder.

Observations Toxic if swallowed, by skin contact or by dust inhalation.


Stowage Category A.


UN No. Formula

1555 AsBr3

Properties White deliquescent crystals. Melting point approximately 33° C. Decomposed by water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes.



Stowage Category A. Keep as cool as reasonably practicable. Clear of living quarters.



ARSENICAL DUST

ARSENICAL FLUE DUST

Packaging group: II

Label of class

6.1

ARSENIC BROMIDE

ARSENIC TRIBROMIDE

ARSENOUS BROMIDE

Packaging group: II

Label of class

6.1



ARSENIC COMPOUND, LIQUID, N.O.S., inorganic

ARSENATES, LIQUID, N.O.S., inorganic ARSENIC SULPHIDES, LIQUID, N.O.S., inorganic ARSENITES, LIQUID, N.O.S., inorganic


Label of class

6.1


UN No. Formula 1556

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. A wide variety of toxic liquids.

Observations Toxic if swallowed by skin contact or by inhalation. When offered for carriage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduc-tion to this class). Substances with a flashpoint between 23° C and 61° C should be classified under TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. , UN No. 2929 in this class or under FLAMMABLE LIQUID, TOXIC, N.O.S., UN No. 1992 in class 3.3 according to toxicity criteria.

Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction.




UN No. Formula 1559 As2O5

Properties White, deliquescent powder. Soluble in water.



Stowage Category A.



ARSENIC COMPOUND, SOLID N.O.S., inorganic

ARSENATES, SOLID, N.O.S., inorganic

ARSENIC SULPHIDES, SOLID, N.O.S., inorganic

ARSENITES, SOLID, N.O.S., inor-ganic


Label of class


UN No. Formula 1557


Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. A wide variety of toxic solids.

Observations Toxic if swallowed by skin contact or by dust inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesti-cide provisions (see sections 2.6 and 2.7 in the introduction to this class).


Stowage Category A.

Packing, Stowage, Segregation and Marine Pollution Aspects See also General Introduction and introduction to this class.

ARSENIC PENTOXIDE

Packaging group: II

Label of class

6.1


UN No. Formula

1560 AsCl3

Properties Colourless, oily liquid. Fumes in moist air, evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. Reacts with water.

Observations Highly toxic if swallowed, by skin contact or by inhalation.


Package gross

Hermetically sealed: 1 Glass receptacles with inert cushion-ing material, or plastics receptacles, in a

wooden box (4C1), (4D), (4F) 15 / 75 kg fibreboard box (4G) 5 / 40 kg

2 Metal cans in a wooden box (4C2), (4D), (4F) 20 / 75 kg fibreboard box (4G) 20 / 40 kg

3 Drum, steel (1A1) - 250 / 4 Cylinder - -

For tanks see section 13 of the General Introduction.




ARSENIC TRICHLORIDE

ARSENIC CHLORIDE

ARSENIOUS CHLORIDE

ARSENOUS CHLORIDE

Packaging group: I

Label of class

6.1


UN No. Formula 1570 C23H26N2O4

Properties White crystals or powder.

Observations Highly toxic if swallowed by skin contact or by dust inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).


Stowage Category A.


UN No. Formula 2738 C6H5NH(C4H9)

Properties Amber liquid with a perceptible odour. Immiscible with water. May react vigorously with oxidizing substances.



Stowage Category A.



BRUCINE DIMETHOXYSTRYCHNINE

Packaging group: I

Label of class

6.1

N-normal-BUTYLANILINE

Packaging group: II

Label of class

6.1

Bookshelf and K&M

BRUCINE - A poisonous white crystalline alkaloid, C23H26N2O4, derived from the seeds of nux vomica and closely related plants and used to denature alcohol. ----------------------------------------------------------------- БРУЦИН, алкалоид, содержащийся (наряду с близким по строению стрихнином) в тропических растениях из рода стрихнос (чилибуха). Сильный яд, вызывает судороги. (K&M)



tertiary-BUTYLCYCLOHEXYL CHLOROFORMATE


Label of class

6.1

UN No. Formula 2747 (CH3)3CC6H10OCOCI

Properties Colourless to yellowish liquid. Reacts with water or decomposes if heated, evolving hydrogen, chloride, an irritating and corrosive gas apparent as white fumes.



Stowage Category A. Keep as cool and dry as reasonably practicable. Shaded from radiant heat.


N-normal-BUTYLIMIDAZOLE

N-normal-BUTYLIMINAZOLE

Packaging group: II

Label of class

6.1

UN No. Formula 2690 C7H12N2

Properties Colourless to amber mobile liquid. Miscible with water.



Stowage Category A.



UN No. Formula 2250 CI2C6H3NCO

Properties Colourless to yellowish crystalline solid with an irritating odour. Insoluble in water. Reacts with water evolving carbon dioxide.

Observations Toxic if swallowed by skin contact or by inhalation. May be carried in the molten state.

Packing See table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. The transport temperature should be indicated on the tank.

Stowage Category B. Shaded from radiant heat. Clear of living quarters.



1,1-DICHLORO-1-NITROETHANE

Packaging group II

Label of class

6.1

UN No. Formula 2650 CH3CCI2NO2

Properties Liquid. Immiscible with water. May react vigorously with oxidizing substances. Decomposes when heated evolving highly toxic fumes (oxides of nitrogen).





DICHLOROPHENYL ISOCYANATES

Packaging group II

Label of class

6.1



1,3-DICHLOROPROPANOL-2 -DICHLOROISOPROPYL ALCOHOL alpha-DICHLOROHYDRIN alpha-PROPENYLDICHLOROHYDRIN GLYCEROL-1,3-DICHLOROHYDRIN

Packaging group: II

Label of class

6.1

UN No. Formula 2750 CICH2CH(OH)CH2CI

Properties Colourless, slightly viscous liquid with a chloroform-like odour Immiscible with water. Decomposes when heated, evolving extremely toxic fumes (phosgene).






UN No. Formula 1598 CH3C6H2(NO2)2OH

Properties

MARINE POLLUTANT Yellow crystals or crystallized mass. Slightly soluble in water.

Observations Toxic if swallowed, by skin contact or by dust inhalation. When of-fered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the rele-vant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).

Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.

Stowage Category A.



DINITRO-ortho-CRESOL

DNOC

Packaging group: II

Label of class

6.1




DINITROPHENOL SOLUTION

Packaging group: II or III according to toxicity criteria

Label of class


UN No. Formula 1599 C6H3(NO2)2OH

Properties MARINE POLLUTANT Substance when pure consists of yellow crystals. Slightly soluble in water. May form extremely sensitive compounds with heavy metals or their salts.

Observations Toxic if swallowed, by skin contact or by inhalation. For DINITROPHENOL, dry or wetted with less than 15% water, by mass, UN No. 0076, see . For DINITROPHENOL, WETTED with not less than 15% water, by mass, UN No. 1320, see class 4.1.


Stowage Category A. Away from lead and its compounds.




ETHYLDICHLOROARSINE

Packaging group: I

Label of class

6.1 MARINE POLLUTANT

mark

UN No. Formula 1892 C2H5AsCl2


Colourless liquid evolving irritating vapour ("Tear Gas'').


Packing Cylinder. For tanks see section 13 of the General Introduction.


Packing, Stowage, Segregation & Marine Pollution As-pects See also General Introduction and introduction to this class.


UN No. Formula 1605 CH2BrCH2Br

Properties Colourless, volatile liquid.


Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction.




ETHYLENE CHLOROHYDRIN

2-CHLOROETHYL ALCOHOL

2-CHLOROETHANOL

GLYCOL CHLOROHYDRIN

Packaging group: I

Label of class


3

UN No. Formula 1135 CICH2CH2OH

Properties Colourless flammable liquid with a faint, ethereal odour. Flashpoint 60° C c.c. Explosive limits 4.9% to 15.9%. Miscible with water. When involved in a fire, evolves extremely toxic (phosgene) and corrosive (hydrogen chloride) fumes.





ETHYLENE DIBROMIDE

1,2-DIBROMOETHANE

Packaging group: I

Label of class

6.1


UN No. Formula

2552 CF3COCF3 H20

Properties This entry covers the solid hydrate and hexafluoroacetone in aque-ous solutions. Melting point of the pure substance 23° C.






HEXAFLUOROACETONE HYDRATE

Packaging group: II

Label of class

6.1

HEXAMETHYLENE DIISOCYANATE HMDI

Packaging group: II Label of class

6.1

UN No. Formula 2281 OCN(CH2)6NCO

Properties Colourless to light yellow liquid with a pungent odour. Immiscible with water but reacts with it evolving heat and carbon dioxide gas. When heated, evolves toxic nitrous fumes.



Stowage Category C. Keep as dry as reasonably practicable. Clear of living quarters.




HYDRAZINE, AQUEOUS SOLUTION, with not more than 37% hydrazine, by mass

DIAMINE, AQUEOUS SOLUTION HYDRA-ZINE BASE, AQUEOUS SOLUTION


Label of class

6.1

UN No. Formula 3293 H2NNH2

Properties Colourless liquid.



Stowage Category A.


Bookshelf and K&M

DIAMINE - Any of various chemical compounds containing two amino groups, especially hydrazine. ----------------------------------------------- ДИАМИН - Один из химических составов, содержащих две амино группы и гидразин.


UN No. Formula

1994 Fe(CO)5

Properties Yellow to dark red volatile flammable liquid. Flashpoint -15° C c. c. Explosive limits 3.7% to 12.5%. May react with water or steam evolving carbon monoxide which is a toxic gas.



kg Hermetically sealed: 1 Glass receptacle sufficiently strong to with-stand the internal pressures generated sur-rounded with inert cushioning and absorbent material in a metal can individually packed in a

1

wooden box (4C), (4D), (4F) 35 2 Cylinder - Carriage in tanks is prohibited




IRON PENTACARBONYL IRON

CARBONYL

Packaging group: I

Label of class


class

3



ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S.

Packaging group: II or III according to toxicity criteria

Label of class

6.1


UN No. Formula 2206


Liquids with a pungent odour. Immiscible with water but react with it to form carbon dioxide.



Stowage Category E. If under-deck, with mechanical ventilation. Six air changes per hour except when carried in closed containers, when two air changes per hour are required.

Shaded from radiant heat. Clear of living quarters.




ISOCYANATES TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION TOXIC FLAMMABLE, N.O.S.

Packaging group: II

Label of class


3


UN No. Formula 3080

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP' in the General Index to this Code.

Flammable liquids or solutions with a pungent odour. Immiscible with or insoluble in water, but react with it to form carbon dioxide.

Observations Toxic if swallowed, by skin contact or by inhalation. For ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S., UN No. 2478, see class 3.


Stowage Category D.

Shaded from radiant heat. Clear of living quarters.




ISOCYANATOBENZOTRIFLUORIDES (ortho-, rneta-, para-)

TRIFLUOROMETHYLPHENYL ISOCYANATES

Packaging group: II

Label of class


3

if flashpoint is 61° C c.c. or below

UN No. Formula 2285 C8H4F3NO

Properties Colourless or yellowish liquids with a pungent odour. Flashpoint of ortho- and meta- isomers 56° C. Immiscible with water but react with it to form carbon dioxide gas.



Stowage Category D. Shaded from radiant heat. Clear of living quarters.

Packing, Stowage & Segregation See also General Introduction and introduction TO this class.

ISOPHORONE DIISOCYANATE

3-ISOCYANATOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYL ISOCY-ANATE


Label of class

6.1

UN No. Formula 2290 C12H18N2O2

Properties Colourless or yellowish liquid. Immiscible with water. When involved in a fire evolves nitric fumes.


Packing See table 1 in the introduction to tins class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.




UN No. Formula

1618 Pb3(AsO3)2 H2O Properties

MARINE POLLUTANT

White powder. Insoluble in water.

Observations Toxic if swallowed by skin contact or by dust inhalation.


Stowage Category A.



LEAD ARSENITES

Packaging group II Label

of class


mark

LEAD COMPOUND, SOLUBLE, N.O.S.


Label of class


mark

UN No. Formula 2291

Properties MARINE POLLUTANT Colourless crystals or powder. Soluble in water.

Observations Lead compounds which when mixed in a ratio of 1/1000 with 0.07, molar hydrochloric acid and stirred for one hour at a temperature of 23° C ± 2° C and which exhibit a solubility of 5% or less are consid-ered insoluble. See ISO Standard 3711 1990. Toxic if swallowed, by skin contact or by dust inhalation.


Stowage Category A.



UN No. Formula 1620 Pb(CN)2

Properties MARINE POLLUTANT White powder. Slightly soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas.



Stowage Category A. «AWAY FROM» acids.


UN No. Formula 1621


Mixture of arsenic trioxide, lime and ferric oxide, used as an insecti-cide. Insoluble in water.

Observations Toxic if swallowed, by skin contact or by dust inhalation. When of-fered for carriage as a pesticide, this substance should be shipped under the relevant pesticide entry and in accordance with the rele-vant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).


Stowage Category A.



LEAD CYANIDE

Packaging group: II

Label of class


mark

LONDON PURPLE

Packaging group: II Label

of class


mark



MERCURY BENZOATE

MERCURIC BENZOATE

Packaging group: II

Label of class


mark

UN No. Formula 1631 Hg(C6H5COO)2 H2O

Properties MARINE POLLUTANT Severe marine pollutant see 23.2.2 of the General Introduction. White crystals.

Observations Toxic if swallowed by skin contact or by dust inhalation.


Stowage Category A.


MERCURY BROMIDES

MERCURIC BROMIDE

MERCUROUS BROMIDE

Packaging group: II

Label of class


mark

UN No. Formula 1634 HgBr2 or Hg2Br2

Properties MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. White crystals or powder.



Stowage Category A.




MERCURY COMPOUND, LIQUID, N.O.S.


Label of class

6.1


UN No. Formula 2024


Severe marine pollutant see 23.2.2 of the General Introduction.

Observations Toxic if swallowed by skin contact or by inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).

Packing See table 1 in the introduction to this class. Category B. Clear of living quarters.




MERCURY COMPOUND, SOLID, N.O.S.


Label of class

6.1


UN No. Formula 2025

Properties MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction Mercuric sulphide is a marine pollutant, not severe.

Observations Toxic if swallowed, by skin contact or by dust inhalation. When offered for carnage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). The provisions of this class should not apply to mercurous chloride in the pure state (see however UN No. 3077 in class 9).


Stowage Category A.



UN No. Formula 1636 Hg(CN)2

Properties

MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. White crystals or powder. Soluble in water. Reacts with acid or acid fumes evolving hydrogen cyanide, a highly toxic and flammable gas.



Stowage Category A «AWAY FROM» acids.


UN No. Formula 1637 Hg[OOC(CHOH)4CH2OH]2

Properties

MARINE POLLUTANT

Severe marine pollutant, see 23.2.2 of the General Introduc-tion. Solid. Soluble in water.



Stowage Category A.



MERCURY CYANIDE

MERCURIC CYANIDE


of class


mark

MERCURY GLUCONATE

MERCURIC GLUCONATE

Packaging group: II

Label of class


mark


UN No. Formula 1652 C10H7NHCONH2

Properties Crystals or powder.



Stowage Category A.



NAPHTHYLTHIOUREA

alpha-APHTHYLTHIOUREA-1-NAPHTHYLTHIOUREA

Packaging group: II

Label of class

6.1

UN No. Formula 1651 C10H7NHCSNH2

Properties White crystals or powder.

Observations Toxic if swallowed, by skin contact or by dust inhalation. When offered for carriage as a pesticide, this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).


Stowage Category A.


NAPHTHYLUREA

Packaging group: II

Label of class

6.1



NICKEL CARBONYL

NICKEL TETRACARBONYL

Packaging group: I La-

bel of class


class

3


UN No. Formula 1259 Nl(CO)4


Severe marine pollutant see 23.2.2 of the General Introduction. Colourless or yellow volatile flammable liquid. Flashpoint below -20° C c.c. Oxidizes in air and explodes at a temperature of 60° C. Lower explosive limit 2.0%. Immiscible with water.

Observations Highly toxic if swallowed by skin contact or by inhalation.


kg Hermetically sealed: 1 Glass receptacle sufficiently strong to with-stand the internal pressures generated sur-rounded with inert cushioning and absorbent material in a metal can individually packed in

a wooden box (4C), (4D), (4F) 35 2 Cylinder - Transport in tanks is prohibited

Stowage Category D. Clear of living quarters. Prohibited on any ship carrying goods of with the exceptions listed in 6.1.4.2 of the introduction to .



UN No. Formula 1653 Ni(CN)2

Properties

MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. Green crystals or powder. Insoluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide a highly toxic and flammable gas.



Stowage Category A. «AWAY FROM» acids.


UN No. Formula 1654 C10H14N2

Properties Thick colourless oil, turning brown on exposure to air. Miscible with water.


Packing See table 1 in the introduction to this class.

Stowage Category A.



NICKEL CYANIDE


of class


mark

NICOTINE

Packaging group: II

Label of class

6.1

Bookshelf and K&M

NICOTINE - A colorless, poisonous alkaloid, C10H14N2, derived from the tobacco plant and used as an insecticide. It is the substance in tobacco to which smokers can become addicted. ----------------------------------------------------------------------------- НИКОТИН, алкалоид, содержащийся в табаке (до 2%) и некоторых других растениях. При курении табака всасывается в организм. Сильный яд; в малых дозах действует возбуждающе на нервную систему, в больших — вызывает ее паралич (остановку дыхания, прекращение сердечной деятельности). Многократное поглощение никотина небольшими дозами при курении вызывает никотинизм. Сульфат никотина применяют для борьбы с вредителями сельскохозяйственных растений. (K&M)



NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S.


Label of class

6.1

UN No. Formula

3144

Properties A wide variety of toxic liquids.

Observations Toxic if swallowed, by skin contact or by inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Liquids with a flashpoint between 23° C and 61° C c.c. should be classified under TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S., UN No. 2929 in this class or under FLAMMABLE LIQUID, TOXIC, N.O.S. , UN No. 1992 in class 3.3, according to toxicity criteria.




NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S.


Label of class

6.1

UN No. Formula 1655

Properties A wide variety of toxic solids.

Observations Toxic if swallowed, by skin contact or by dust inhalation. When of-fered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).


Stowage Packaging group I category B. Packaging groups II and III category A.



UN No. Formula 1657 C10H14N2C7H6O3

Properties White crystals. Soluble in water.



Stowage Category A.



NICOTINE HYDROCHLORIDE SOLID or LIQUID, or NICOTINE HYDROCHLORIDE SOLU-TION

Packaging group: II

Label of class

6.1

UN No. Formula 1656 C10H14N2 2HCI

Properties Deliquescent crystals, solids pastes or liquids. Soluble in water.

Observations Toxic if swallowed by skin contact or by inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).

Packing For liquids see table 1 in the introduction to this class. For solids see TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction.

Stowage Category A.


NICOTINE SALICYLATE

Packaging group: II

Label of class

6.1


ORGANOPHOSPHORUS COM-POUND, TOXIC, N.O.S.

Packaging group: I, II or III according to toxicity enter a

Label of class


mark (for marine pollutants only)

UN No. Formula 3278

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. A wide variety of toxic liquids and solids. Observations Toxic if swallowed, by skin contact or by inhalation. When offered for carriage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing For liquids see table 1 in the introduction to this class. For solids see TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Packaging groups I and II category B. Packaging group III category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

ORGANOPHOSPHORUS, COMPOUND, TOXIC, FLAMMABLE, N.O.S.

Packaging group: I, II or III according to grouping crite-ria for each hazard

Label of class


3 MARINE POLLUTANT mark (for marine pollutants only)

UN No. Formula 3279 Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. A wide variety of toxic flammable liquids. Observations Toxic if swallowed, by skin contact or by inhalation. When offered for carriage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pes-ticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.


Bookshelf and K&M

ORGANOPHOSPHORUS - Any of several organic compounds containing phosphorus, some of which are used as fertilizers and pesticides. ---------------------------------------------- ФОСФОРОРГАНИЧЕСКИЙ - Органические соединения, содержащие фосфор, некоторые из которых используются как удобрения и пестициды.


ORGANOTIN COMPOUND, LIQUID, N.O.S. 2788

ORGANOTIN COMPOUND, SOLID, N.O.S. 3146

Properties MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. A wide variety of toxic solids and liquids.

Observations Toxic if swallowed, by skin contact or by inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pes-ticide provisions (see sections 2.6 and 2.7 in the introduction to this class).

Packing For liquids see table 1 in the introduction to this class. For solids see TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.

Stowage Packaging group I category B. Packaging groups II and III category A. Clear of living quarters.




Label of class

6.1



UN No. Formula

1669 CHCI2CCI3 Properties

MARINE POLLUTANT

Colourless liquid.





UN No. Formula 3155 C6Cl5OH

Properties

MARINE POLLUTANT Severe marine pollutant see 23.2.2 of the General Introduction. White powder or crystals.

Observations Toxic if swallowed, by skin contact or by dust inhalation. When of-fered for carriage as a pesticide this substance should be shipped under the relevant pesticide entry and in accordance with the rele-vant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).

Packing See TABLE 2 in the introduction to this class.

Stowage Category A.



PENTACHLOROETHANE

PENTALIN

Packaging group: II

Label of class


mark

PENTACHLOROPHENOL

Packaging group: II

Label of class


mark

Bookshelf and K&M

PENTACHLOROPHENOL - A toxic white crystalline compound, C6Cl5OH, used in solution as a fungicide and wood preservative. --------------------------------------------------------- ПЕНТАХЛОРФЕНОЛ - ядовитый белый прозрачный состав, C6Cl5OH, используется как фунгицид и консервант дерева (K&M)



PERCHLOROMETHYL MERCAPTAN

THIOCARBONYL TETRACHLORIDE TRICHLOROMETHYL,

SULPHOCHLORIDE TRICHLORO-METHANE,

SULPHURYL CHLORIDE

Packaging group: I

Label of class

6.1


UN No. Formula 1670 CISCCI3


Yellow oily volatile liquid evolving irritating vapour ( Tear Gas ). Slowly decomposes in contact with water producing hydrochloric acid. Reacts with iron or steel evolving carbon tetrachloride. Corrosive to most metals...



Package gross

Hermetically sealed: 1 Glass receptacles with inert cushioning material or plastics receptacles in a

wooden box (4C), (4D), (4F) 15 / 75 kg fibreboard box (4G) 5 / 40 kg 2 Metal cans in a wooden box (4C), (4D), (4F) 20 / 75 kg fibreboard box (4G) 20 / 40 kg 3 Drum steel (1A1) - 250 / 4 Cylinder - - For tanks see section 13 of the General Introduction.




UN No. PESTICIDE, LIQUID, TOXIC N.O.S. 2902

CARBAMATE PESTICIDE, LIQUID, TOXIC 2992

ARSENICAL PESTICIDE LIQUID, TOXIC 2994

ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 2996

TRIAZINE PESTICIDE, LIQUID, TOXIC 2998

THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 3006

COPPER-BASED PESTICIDE, LIQUID, TOXIC 3010

MERCURY-BASED PESTICIDE LIQUID, TOXIC 3012

SUBSTITUTED NITROPHENOL, PESTICIDE, LIQUID, TOXIC 3014

BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 3016

ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 3018

ORGANOTIN PESTICIDE, LIQUID, TOXIC 3020

COUMARIN DERIVATIVE PESTICIDE, LIQUID TOXIC 3026

PHENOXYACETIC ACID DERIVATIVE PESTI-CIDE, LIQUID, TOXIC 3348

PYRETHROID PESTICIDE, LIQUID, TOXIC 3352

Packaging group: I, II or III according to toxicity criteria.

Label of class


Formula

Properties

MARINE POLLUTANT

Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition.

Observations Toxic if swallowed, by skin contact or by inhalation. The name and concentration of the active substance(s) should be mentioned in the shipping documents when a pesticide is offered for shipment.


Stowage Packaging groups I and II category B. Packaging group III category A. Clear of living quarters.



Bookshelf and K&M

ORGANOCHLORINE - Any of various hydrocarbon pesticides, such as DDT, that contain chlorine. ------------------------------------------ ОРГАНОХЛОРИН - Любой из различных пестицидов углеводорода, типа DDT, которые содержат хлор.

Bookshelf and K&M

TRIAZINE - 1. Any of three isomeric compounds, C3H3N3, each having three carbon and three nitrogen atoms in a six-membered ring. 2. A compound derived from one of these isomers.

Bookshelf and K&M

Thiourea - THIOCARBAMATE - A lustrous white crystalline compound, (NH2)2CS, used as a developer in photography and photocopying and in various organic syntheses. Also called thiocarbamide. -------------------------------------------------- ТИОМОЧЕВИНА (тиокарбамид), (NH2)2CS, бесцветные кристаллы, tпл 182 С. Применяют в органическом синтезе, для разделения углеводородов, как ростовое вещество. (K&M)

Bookshelf and K&M

COUMARIN - A fragrant crystalline compound, C9H6O2, extracted from several plants, such as tonka beans and sweet clover, or produced synthetically and widely used in perfumes. -------------------------------------------------- КУМАРИН, бесцветные кристаллы с запахом свежего сена, tпл 70 С. Применяют как душистое вещество (в парфюмерии и для ароматизации табака). (K&M)

Bookshelf and K&M

CARBAMATE - A salt or ester of carbamic acid, especially one used as an insecticide. ---------------------------------------------- КАРБАМИНАТ - соль или сложный эфир карбаминовой кислоты, используется как инсектицид.


UN No. PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. 2903

CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 2991

ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE 2993

ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 2995

TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAM-MABLE 2997

THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3005

COPPER-BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3009

MERCURY-BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3011

SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3013

BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3015

ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3017

ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3019

COUMARIN DERIVATIVE PESTICIDE LIQUID, TOXIC, FLAMMABLE 3025

PHENOXYACETIC ACID DERIVATIVE PESTI-CIDE, LIQUID, TOXIC, FLAMMABLE 3347

PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3351


Label of class




Formula


Liquid flammable pesticides having a flashpoint between 23°C and 61 °C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition.

Observations Toxic if swallowed, by skin contact or by inhalation. The name and concentration of the active substance or sub-stances should be mentioned in the shipping documents when a pesticide is offered for shipment. For PESTI-CIDE, LIQUID, FLAMMABLE, TOXIC, UN No. 3021, with a flashpoint below 23° C c.c., see class 3.2.

Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction

Stowage Packaging groups I and II category B. Packaging group III category A. Clear of living quarters.




UN No. PESTICIDE, SOLID, TOXIC, N.O.S. 2588

CARBAMATE PESTICIDE, SOLID, TOXIC 2757 ARSENICAL PESTICIDE, SOLID, TOXIC 2759

ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 2761

TRIAZINE PESTICIDE SOLID, TOXIC 2763

THIOCARBAMATE PESTICIDE, SOLID, TOXIC 2771

COPPER-BASED PESTICIDE, SOLID, TOXIC 2775

MERCURY-BASED PESTICIDE, SOLID, TOXIC 2777

SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC 2779

BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 2781

ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 2783

ORGANOTIN PESTICIDE, SOLID, TOXIC 2786

COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 3027

PHENOXYACETIC ACID DERIVATIVE PESTI-CIDE, SOLID, TOXIC 3345

PYRETHROID PESTICIDE, SOLID, TOXIC 3349


Label of class


Formula Properties MARINE POLLUTANT

Solid pesticides present a very wide range of toxic haz-ard.

Observations Toxic if swallowed, by skin contact or by inhalation. The name and concentration of the active substance or sub-stances should be mentioned in the shipping documents when a pesticide is offered for shipment.


Package gross

1 Glass receptacles with inert cushion-ing material, or plastics receptacles, in a

wooden box (4C), (4D,) (4F) 15 / 75 kg fibreboard box (4G) 5 / 40 kg* 2 Plastics or metal receptacles in a wooden box (4C), (4D), (4F) 20 / 75 kg fibreboard box (4G) 20 / 40 kg* 3 Drum, steel (1A2) - 250 kg 4 Paper, plastics or metal foil bags in a

wooden box (4C), (4D), (4F) 15 kg † 75 kg fibreboard box (4G) 15 kg † 40 kg* 5 Wooden barrel (2C1) or fibre drum (1G) or plywood drum (1D) - 200 kg 6 ‡ Multiwall paper bag, water-resistant (5M2) - 50 kg 7 ‡ Plastics bags in a fibreboard box (4G) - 55 kg 8 Drum, plastics (1H2) - 200 kg 9. ‡ Strong plastics film bag (5H4) - 25 kg * 55 kg for substances in packaging group III. † Inner receptacles made of plastics materials may contain up to 25 kg of substance when transported as full container load (FCL). ‡ For substances in packaging group III only. For IBCs see section 26 of the General Introduction.





[tables deleted]



UN No. Formula 2311 H2NC6H4OC2H5

Properties Colourless to yellowish liquids. Immiscible with water.



Stowage Category A.



PHENACYL BROMIDE

omega-BROMOACETOPHENONE

Packaging group: II Label of

class

6.1

UN No. Formula 2645 BrCH2COC6H5

Properties White crystals changing to a greenish colour under the influence of light. Melting point: 50° C. Insoluble in water. Lachrymatory.





PHENETIDINES

ortho-PHENETIDINE para-PHENETIDINE AMINOPHENETOLES


Label of class

6.1


UN No. Formula 2487 C6H5NCO

Properties Colourless to yellowish liquid with a pungent odour. Flashpoint 51° C c.c. Immiscible with water. Reacts with water evolving carbon dioxide.





UN No. Formula

2337 C6H5SH

Properties Colourless flammable liquid with a foul odour. Flashpoint 50° C c.c. Immiscible with water. In contact with acids or when involved in a fire evolves highly toxic sulphurous fumes.

Observations Highly toxic if swallowed by skin contact or by inhalation.


Stowage Category B. Clear of living quarters. Away from acids.



PHENYL ISOCYANATE

PHENYL CARBIMIDE CARBANIL

Packaging group: I

Label of class


of class

3

PHENYL MERCAPTAN

BENZENETHIOL THIOPHENOL

Packaging group: I

Label of class


of class

3



PHENYLMERCURIC ACETATE

Packaging group: II

Label of class


mark

UN No. Formula 1674 C6H5HgOOCCH3

Properties MARINE POLLUTANT Severe marine pollutant see 23.2.2 of the General Introduction. White crystals or powder.

Observations Toxic if swallowed, by skin contact or by dust inhalation. When of-fered for carriage as a pesticide this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).


Stowage Category A.


PHENYLMERCURIC COMPOUND, N.O.S.


Label of class


mark

UN No. Formula 2026

Properties MARINE POLLUTANT Severe marine pollutant see 23.2.2 of the General Introduction. Usually white crystals or powder.

Observations Toxic if swallowed, by skin contact or by dust inhalation. When of-fered for carriage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).


Stowage Category A.



UN No. Formula 1686 NaAsO2

Properties Colourless liquid.

Observations Toxic if swallowed by skin contact or by inhalation. When offered for carriage as pesticides this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).


Stowage Category A.



SODIUM ARSENATE SODIUM

ORTHOARSENATE


of class

6.1

UN No. Formula 1685 Na3AsO4:12H2O

Properties Colourless crystals. Soluble in water.



Stowage Category A.


SODIUM ARSENITE, AQUEOUS SOLUTION

Packaging group: II or III according to toxicity crite-

ria

Label of class

6.1


UN No. Formula 1687 NaN3

Properties Colourless crystals. May react vigorously with acids to form hydrazoic acid, which is an explosive. May form extremely sensitive compounds with heavy metals or their salts. May explode if involved in a fire.



Stowage Category A. Away from lead and its compounds. Separated from class 3 and from acids.



SODIUM ARSENITE, SOLID

SODIUM METAARSENITE

Packaging group: II

Label of class

6.1

UN No. Formula 2027 NaAsO2

Properties Grayish white powder. Soluble in water. Reacts with oxidizing substances evolving heat.

Observations Toxic if swallowed by skin contact or by dust inhalation. When offered for carriage as a pesticide this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).


Stowage Category A.


SODIUM AZIDE

Packaging group: II

Label of class

6.1



TETRABROMOETHANE

1,1,2,2-TETRABROMOETHANE ACETYLENE TETRABROMIDE


Label of class


mark

UN No. Formula 2504 CHBr2CHBr2


Colourless to yellowish liquid with a camphor like odour.



Stowage Category A.


1,1,2,2-TETRACHLOROETHANE

ACETYLENE TETRACHLORIDE

Packaging group: II

Label of class


mark

UN No. Formula 1702 CHCI2CHCl2


Colourless liquid with a chloroform-like odour.






UN No. Formula 1704 (C2H5)4P2O5S2

Properties MARINE POLLUTANT Colourless liquid. In the presence of moisture corrosive to most metals.

Observations Toxic if swallowed by skin contact or by inhalation. When offered for carnage as a pesticide, this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).





TETRACHLOROETHYLENE

PERCHLOROETHYLENE


Label of class


mark

UN No. Formula 1897 CI2C:CCI2

Properties MARINE POLLUTANT Colourless liquid with an ethereal odour. When involved in a fire evolves extremely toxic fumes (phosgene).





TETRAETHYL DITHIOPYROPHOSPHATE


of class


mark

Bookshelf and K&M

PERCHLOROETHYLENE - A colorless, nonflammable organic solvent, Cl2C:CCl2, used in dry-cleaning solutions and as an industrial solvent. ------------------------------------------------------------------ ТЕТРАХЛОРЭТИЛЕН (перхлорэтилен), Cl2C=CCl2, бесцветная жидкость, tкип 121 С. Растворитель и экстрагирующий агент, напр., для каучуков, пластмасс, жиров. Используется при химической чистке одежды. (K&M)


UN No. Formula 2727 TINO3

Properties

MARINE POLLUTANT

Colourless crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely.



Stowage Category A.



THALLIUM COMPOUND, N.O.S.

Packaging group: II

Label of class


mark

UN No. Formula 1707


White crystals or powder.

Observations Toxic if swallowed by skin contact or by dust inhalation. When offered for carriage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesti-cide provisions (see sections 2.6 and 2.7 in the introduction to this class).


Stowage Category A.


THALLIUM NITRATE

Packaging group: II

Label of class


of class

5.1

Bookshelf and K&M

THALLIUM - A soft, malleable, highly toxic metallic element, used in photocells, infrared detectors, low-melting glass, and formerly in rodent and ant poisons. Atomic number 81; atomic weight 204.37; melting point 303.5 C; boiling point 1,457 C; specific gravity 11.85; valence 1, 3. ------------------------------------------------------------------------------------------------- ТАЛЛИЙ (лат. Тhallium), Tl, химический элемент III группы периодической системы, атомный номер 81, атомная масса 204,383. Название от греч. thallos — зеленая ветка (по ярко-зеленой линии спектра). Серебристо-белый металл с сероватым оттенком, мягкий и легкоплавкий; плотность 11,849 г/см3, tпл 303,6 С. На воздухе легко окисляется. В природе рассеян, добывают из сульфидных руд. Компонент сплавов, главным образом с оловом и свинцом (кислотоупорные, подшипниковые и др.). Амальгама талия — жидкость для низкотемпературных термометров. Соединения талия (ТlCl, ТlBr, TlI) — оптические материалы для инфракрасной техники. (K&M)


UN No. Formula 2785 CH3SCH2CH2CHO

Properties

MARINE POLLUTANT Colourless liquid with an extremely foul and persistent odour. Miscible with water. Decomposes rapidly in contact with acids and bases.



Package gross

Hermetically sealed

1. Glass receptacles with inert cushioning material, or plastics receptacles, in a

wooden box (4C), (4D) (4F) - 75 kg fibreboard box (4G) - 55 kg 2 Metal cans in a wooden box (4C), (4D), (4F) - 75 kg fibreboard box (4G) - 55 kg 3 Drum, steel (1A1) - 250 l 4 Cylinder - - For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.

Stowage Category D. Shaded from radiant heat. «AWAY FROM» class 8.



4-THIAPENTANAL

METHYLMERCAPTO-PROPIONALDEHYDE


Label of class

6.1




TOLUENE DIISOCYANATE

TOLUYLENE DIISOCYANATE TOLYLENE DIISOCYANATE

Packaging group: II

Label of class

6.1

UN No. Formula 2078 CH3C6H3(NCO)2

Properties Colourless to pale yellow liquid with a pungent odour. Immis-cible with water but reacts with it to form carbon dioxide. Melting point 20° C (pure product).



Stowage Category D.

Clear of living quarters. Shaded from radiant heat.


Bookshelf and K&M

TOLUENE - A colorless flammable liquid, CH3C6H5, obtained from coal tar or petroleum and used in aviation fuel and other high-octane fuels, in dyestuffs, explosives, and as a solvent for gums and lacquers. Also called methylbenzene. ----------------------------------------------------------------------- ТОЛУОЛ, C6H5CH3, бесцветная жидкость, tкип 110,6 С. Содержится в больших количествах в каменноугольной смоле и продуктах нефтепереработки. Применяется для получения взрывчатого вещества (тринитротолуол), красителей, фармацевтических препаратов, для синтеза различных соединений и как растворитель. (K&M)


UN No. Formula 1709 CH3C6H3(NH2)2

Properties White crystals or powder or solution.



Stowage Category A.


IMDG CODE - PAGE 6270 (page 6270 7 follows) Amdt. 27-94

TOLUIDINES LIQUID or SOLID (ortho-, meta-, para-)

Packaging group: II

Label of class

6.1

UN No. Formula 1708 CH3C6H4NH2

Properties Colourless liquids or solids. para-TOLUIDINE is solid in pure form with a melting point of approximately 45° C.



Stowage Category A.


2,4-TOLUYLENEDIAMINE, LIQUID or SOLID


Label of class

6.1



VANADIUM COMPOUND, N.O.S.


Label of class

6.1


UN No. Formula 3285



Packing For liquids see table 1 of the introduction to this class. For solids see TABLE 2 of the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General introduction.

Stowage Packaging groups I and II category B. Packaging group III category A.


Bookshelf and K&M

VANADIUM - Symbol V A bright white, soft, ductile metallic element found in several minerals, notably vanadinite and carnotite, having good structural strength and used in rust-resistant high-speed tools, as a carbon stabilizer in some steels, as a titanium-steel bonding agent, and as a catalyst. Atomic number 23; atomic weight 50.942; melting point 1,890 C; boiling point 3,000 C; specific gravity 6.11; valence 2, 3, 4, 5. -------------------------------------------------------------------------------------------------- ВАНАДИЙ (лат. Vanadium), V, химический элемент V группы периодической системы, атомный номер 23, атомная масса 50,9415. Название от имени древнескандинавской богини красоты Ванадис. Серо-стальной твердый металл. Плотность 6,11 г/см3, tпл 1920 C. Устойчив к действию воды и многих кислот. В земной коре рассеян, часто сопутствует железу (железные руды — важный промышленный источник ванадия). Легирующий компонент конструкционных сталей и сплавов, применяемых в авиационной и космической технике, морском судостроении, компонент сверхпроводящих сплавов. Соединения ванадия используют в текстильной, лакокрасочной, стекольной промышленности. (K&M)


UN No. Formula 2862 V2O5

Properties Brownish powder. Slightly soluble in water.



Stowage Category A.



VANADIUM PENTOXIDE, non-fused form


Label of class

6.1

Bookshelf and K&M

VANADIUM PENTOXIDE - A yellow to red crystalline powder, V2O5, used as a catalyst in various organic reactions and as a starting material for other vanadium salts. Also called vanadic acid. -------------------------------------------------------------- ВАНАДИЯ ОКСИД, V2O5, красные или желто-красные кристаллы; tпл 680 C. Плохо растворяется в воде. Катализатор при получении серной кислоты, компонент специальных стекол, глазурей и люминофоров. (K&M)

CLASS 6.2 – I n f e c t i o u s s u b s t a n c e s

4. except when authorized for unconditional use by the Governments of the countries of origin transit and destination genetically modified micro-organisms which do not meet the definition of infectious substances but which are capable of altering animals plants or microbiological substances in a way not normally the result of natural reproduction should be classified in class 9 and assigned to UN No. 3245.

1.4 Biological products are those products derived from living organisms that are manufactured and distributed in accor-dance with the requirements of national governmental authorities which may have special licensing requirements, and are used either for prevention, treatment, or diagnosis of disease in humans or animals or for development experimen-tal or investigational purposes related thereto. They include, but are not limited to, finished or unfinished products such as vaccines and diagnostic products. For the purposes of this Code, biological products are divided into the following groups.

1. those which contain pathogens in Risk Group 1, those which contain pathogens under such conditions that their ability to produce disease is very low to none; and those known not to contain pathogens. Substances in this group are not considered to be infectious substances for the purposes of this Code.

2. those manufactured and packaged in accordance with the requirements of national governmental health authorities and transported for the purposes of final packaging or distribution, and use for personal health care by medical professionals or individuals. Substances in this group are not considered to be infectious substances for the purposes of this Code.

3. those known or reasonably expected to contain pathogens in Risk Groups 2, 3 or 4 and which do not meet the criteria of 1.41 above Substances in this group should be classified in class 6.2 under UN No. 2814 or UN No. 2900, as appropriate.

Note: Some licensed biological products may present a biohazard in certain parts of the world only. As a result, competent authorities may require these biological products to comply with the requirements for infectious substances or may impose other restrictions.

1.5 Diagnostic specimens are any human or animal material including but not limited to, excreta, secreta blood and its components, tissue and tissue fluids being shipped for diagnostic or investigational purposes, but excluding live in-fected animals. For the purposes of this Code diagnostic specimens are divided into the following groups.

1. those known or reasonably expected to contain pathogens in risk groups 2, 3 or 4 and those where a rela-tively low probability exists that pathogens of risk group 4 are present. Such substances should be classi-fied in Class 6.2 and assigned to UN No. 2814 or UN No. 2900, as appropriate. Specimens transported for the purpose of initial or confirmatory testing for the presence of pathogens fall within this group;

2. those where a relatively low probability exists that pathogens of risk group 2 or 3 are present. Specimens transported for the purpose of routine screening tests or for initial diagnosis other than for the presence of pathogens fall within this group;

3. those known not to contain pathogens;

1.6 Wastes transported under UN No. 3291 are wastes derived from the medical treatment of humans or animals or from bio research where there is a relatively low probability that infectious substances are present. Waste infectious sub-stances which can be specified should be assigned to UN No. 2814 or to UN No. 2900. The provisions of this Code should not apply to decontaminated wastes which previously contained infectious substances unless the criteria of another class are met.



2 BIOLOGICAL PRODUCTS, DIAGNOSTIC SPECIMENS AND CLINICAL OR (BIO) MEDICAL WASTE

2.1 Biological products known to contain or thought likely to contain any infectious substances should meet the re-quirements for infectious substances. Biological products referred to in 1.4.1 and 1.4.2 are not subject to the re-quirements of class 6.2.

2.2 Diagnostic specimens known to contain or thought likely to contain any infectious substances should meet the requirements for infectious substances. Diagnostic specimens referred to in 1.5.2 need not meet the provisions for infectious substances when the following conditions are met.

1 the primary receptacle(s) do not contain more than 100 ml; 2 the outer packaging does not contain more than 500 ml; 3 the primary receptacles are leak proof and; 4 the packaging is in accordance with the provisions of 5.1 of this introduction. 2.3 Provided an equivalent level of performance is maintained the following variations in the primary receptacles placed

within an intermediate packaging are allowed without further testing of the completed package.

1 Primary receptacles of equivalent or smaller size as compared to the tested primary receptacles may be used provided:

1.1 the primary receptacles are of similar design to the tested primary receptacle (e.g. shape round rectangular etc.);

1.2 the material of construction of the primary receptacle (glass plastics metal etc ) offers resistance to impact and stacking forces equal to or greater than that of the originally tested primary receptacle;

1.3 the primary receptacles have the same or smaller openings and the closure is of similar design (e.g. screw cap friction lid etc.);

1.4 sufficient additional cushioning material is used to take up void spaces and to prevent significant movement of the primary receptacles; and

1.5 primary receptacles are oriented within the intermediate packaging in the same manner as in the tested pack-age.

2 A lesser number of the tested primary receptacles or of the alternative types of primary receptacles identified in 1 above may be used provided sufficient cushioning is added to fill the void space(s) and to prevent significant movement of the primary receptacles.

3 RESPONSIBILITY OF CONSIGNOR

3.1 The transport of infectious substances requires co-coordinated action by the consignor the carrier and the con-signee to ensure safety and arrival on time and in proper condition.

1 Dispatch of infectious substances should not take place before advance arrangements have been made between consignor carrier and consignee nor before the consignee has confirmed with his competent authorities that the substances can legally be imported and that no delay will be incurred in the delivery of the consignment to its desti-nation.



2 In order to secure transmission without hindrance it is necessary to prepare all dispatch documents including the transport document (see section 9 of the General Introduction) in strict accordance with rules governing the acceptance of the goods to be dispatched. If the substance is perishable warnings should appear on the trans-port document for instance. Keep cool between +2° C and +4° C or Keep frozen or Do not freeze. The full ad-dress of the consignee should be shown on the appropriate dispatch document together with the name of a responsible person and his telephone number.

3 Whatever the mode used transport should be by the quickest possible routing. If trans-shipment is necessary precautions should be taken to ensure special care expeditious handling and monitoring of the substances in transit. Transport documents should show the number of the flight or train its date and the name(s) of the air-port(s) or station(s) of trans-shipment.

4 The consignor should notify the consignee in advance of transport details such as means of transport flight or train number(s) transport document number and date and hour of expected arrival at the point of destination so that the consignment can be collected promptly. The most rapid means of communication should be used for this notification.

4 GENERAL PACKING REQUIREMENTS AND COMMUNICATION OF INFORMATION

4.1 Consignors of infectious substances should ensure that packages are prepared in such a manner that they arrive at their destination in good condition and present no hazard to persons or animals during transport.

4.2 The packaging should as demonstrated by tests be capable of successfully passing the design type tests de-tailed in section 6 of this introduction.

4.3 The terms and definitions of section 2 of Annex I and the general packing requirements of section 3 of the same Annex (except 3.3, 3.9 to 3.12 and 3.16) are applicable to the packing of infectious substances.

4.4 Information should be provided as follows:

1 inside the package an itemized list of contents should be enclosed between the secondary packaging and the outer packaging; and

2 outside the package an infectious substance primary label (see 8.4 of the General Introduction) should be affixed to the outer packaging together with any other label or marking required by the nature of the contents;

4.5 Before an empty packaging is returned to the consignor or sent elsewhere it should be thoroughly disinfected or sterilized and any label or marking indicating that it had contained an infectious substance should be removed or obliterated.

5 PACKING

5.1 A packaging should include the following essential elements:

1 An inner packaging comprising: 1.1 watertight primary receptacle(s); 1.2 a watertight secondary packaging; and

1.3 absorbent material in sufficient quantity to absorb the entire contents placed between the primary recepta-cle(s) and the secondary packaging, if several primary receptacles are placed in a single secondary packaging they should be individually wrapped so as to prevent contact between them.



2 An outer packaging of adequate strength for its capacity mass and intended use and with a minimum external dimension of 100 mm

5.2 Inner packagings containing infectious substances should not be consolidated with inner packagings containing unrelated types of goods. Complete packages may be overpacked in accordance with the requirements of para-graph 10.19 of the General Introduction such an overpack may contain dry ice.

5.3 Other than for exceptional consignments e.g., whole organs which require special packaging, infectious substances should be packed in accordance with the following guidelines.

1 Lyophilized substances.

Primary receptacles should include flame-sealed glass ampoules or rubber-stoppered glass vials fitted with metal seals.

2 Liquid or solid substances

2.1 For substances consigned at ambient temperature or at a higher temperature, primary receptacles should be of glass metal or plastics. Positive means of ensuring a leakproof seal should be provided, e.g. , a heat seal, a skirted stopper or a metal crimp seal. If screw caps are used, they should be reinforced with adhesive tape.

2.2 For substances consigned refrigerated or frozen, ice, dry ice or other refrigerant should be placed around the secondary packaging(s) or alternatively in an overpack with one or more complete packages marked in accordance with 5.6 Interior supports should be provided to secure secondary packaging(s) or packages in position after the ice or dry ice has dissipated. If ice is used, the outer packaging or overpack should be leakproof If dry ice is used, the outer packaging or overpack should permit the release of carbon dioxide gas. The primary receptacle and the sec-ondary packaging should maintain their integrity at the temperature of the refrigerant used.

2.3 For substances consigned in liquid nitrogen, plastics primary receptacles capable of withstanding very low temperature should be used. The secondary packaging should also be capable of withstanding very low tempera-tures and in most cases will need to be fitted over the primary receptacle individually. Requirements for the con-signment of liquid nitrogen should also be fulfilled. The primary receptacle and the secondary packaging should maintain their integrity at the temperature of the liquid nitrogen.

5.4 Whatever the intended temperature of the consignment, the primary receptacle or the secondary packaging should be capable of withstanding, without leakage, an internal pressure producing a pressure differential of not less than 95 kPa and temperatures in the range -40° C to +55° C.

5.5 Unless an infectious substance cannot be consigned by any other means live vertebrate or invertebrate animals should not be used to consign such a substance infected animals should be consigned in accordance with condi-tions specified by the competent authority.

5.6 A packaging that meets the requirements in sections 5 and 6 of this introduction may, after decision by the compe-tent authority be marked with

(a) the United Nations (UN) packaging symbol;

(b) the Code designating the type of packaging according to the provisions of section 5 of Annex 1 to this Code;

(c) the text CLASS 6.2.



(d) the last two digits of the year of manufacture of the packaging; (e) the State authorizing the allocation of the mark, indicated by the distinguishing sign for motor vehicles in interna-

tional traffic; (f) the name of the manufacturer or other identification of the packaging specified by the competent authority;

(g) for packagings meeting the requirements of 6.8 the letter 'U' should be inserted immediately following the mark-ing required in (b) above.

5.7 Example of marking

4G CLASS 6.2/92 as in 5.6(a), (b), (c) and (d) S/SP-9989-ERIKSSON as in 5.6 (e) and (f)

6 TEST REQUIREMENTS FOR PACKAGINGS 6.1 Other than for packagings for live animals and organisms samples of each packaging should be prepared for testing

as described in 6.2 and then subjected to the tests in 6.3 to 6.5. If the nature of the packaging makes it necessary, equivalent preparation and tests are permitted, provided that these may be demonstrated to be at least as effective.

6.2 Samples of each packaging should be prepared as for transport except that a liquid or solid infectious substance should be replaced by water or, where conditioning at -18°C is specified by water containing antifreeze. Each pri-mary receptacle should be filled to 98% capacity.

6.3 Packagings prepared as for transport should be subjected to the tests in table 1 which, for test purposes, catego-rizes packagings according to their material characteristics. For outer packagings, the headings in the table relate to fibreboard or similar materials whose performance may be rapidly affected by moisture, plastics which may embrit-tle at low temperature, and other materials such as metal whose performance is not affected by moisture or tem-perature. If a primary receptacle and a secondary packaging of an inner packaging are made of different materials, the material of the primary receptacle determines the appropriate test. In instances where a primary receptacle is made of two materials, the material most liable to damage should determine the appropriate test.

Table 1 - Tests required

Material of Tests required outer packaging inner packaging Refer to 6.4

Fibreboard Plastics Other Plastics Other .1 .2 .3 .4 Refer to 6.5

x x x x xx x x x

x x x x x x x x x x x x x x x

when dry ice

is used

x 6.4.1 Samples should be subjected to free-fall drops on to a rigid, non-resilient, flat, horizontal surface from a height

of 9 m. Where the samples are in the shape of a box, five should be dropped, in sequence.



- flat on to the base; - flat on to the top;

- flat on to the longest side; - flat on to the shortest side; - on to a corner;

Where the samples are in the shape of a drum, three should be dropped in sequence:

- diagonally on to the top chime, with the center of gravity directly above the point of impact;

- diagonally on to the base chime;

- flat on to the side.

Following the appropriate drop sequence there should be no leakage from the primary receptacle(s) which should remain protected by the absorbent material in the secondary packaging.

(Note: While the sample should be released in the required orientation, it is accepted that for aerodynamic rea-sons the impact may not take place in that orientation )

6.4.2 The sample should be subjected to a water spray that simulates exposure to rainfall of approximately 5 cm per hour for at least one hour It should then be subjected to the test described in 6.4.1.

6.4.3 The sample should be conditioned in an atmosphere of -18° C or less fora period of at least 24 hours and within 15 minutes of removal from that atmosphere be subjected to the test described in 6.4.1. Where the sample contains dry ice, the conditioning period may be reduced to 4 hours.

6.4.4 Where the packaging is intended to contain dry ice, a test additional to that specified in 6.4.1 or 6.4.2 or 6.4.3 or 6.4.2 and 6.4.3 should be carried out. One sample should be stored so that all the dry ice dissipates and then be subjected to the test described in 6.4.1.

6.5 Packagings with a gross mass of 7 kg or less should be subjected to the tests described in 1 below and packag-ings with a gross mass exceeding 7 kg to the tests in 2 below:

1 Samples should be placed on a level hard surface A cylindrical steel rod with a mass of at least 7 kg, a diame-ter not exceeding 38 mm and the impact end edges having a radius not exceeding 6 mm should be dropped in a vertical free fall from a height of 1 m, measured from the impact end to the impact surface of a sample. One sample should be placed on its base. A second sample should be placed in an orientation perpendicular to that used for the first. In each instance the steel rod should be aimed to impact the primary receptacle. Following each impact, penetration of the secondary packaging is acceptable, provided that there is no leakage from the primary receptacle(s).

2 Samples should be dropped on to the end of a cylindrical steel rod. The rod should be set vertically in a level hard surface It should have a diameter of 38 mm and the edges of the upper end a radius not exceeding 6 mm. The rod should protrude from the surface a distance at least equal to that between the primary receptacle(s) and the outer surface of the outer packaging with a minimum of 200 mm. One sample should be dropped in a verti-cal free fall from a height of 1 m, measured from the top of the steel rod. A second sample should be dropped from the same height in an orientation perpendicular to that used for the first. In each instance the packaging should be so orientated that the steel rod would penetrate the primary receptacle(s). Following each impact, penetration of the secondary packaging is acceptable, provided that there is no leakage from the primary recep-tacle(s).



6.6 The competent authority may permit the selective testing of packagings that differ only in minor respects from a tested type, e.g. smaller sizes of inner packagings or inner packagings of lower net mass, and packagings such as drums bags and boxes which are produced with small reductions in external dimension(s).

6.7 Inner receptacles of any type may be assembled within an intermediate (secondary) packaging and transported without testing in the outer packaging under the following conditions:

1 The intermediate/outer packaging combination should have been successfully tested in accordance with 6.4.1 with fragile (e.g. glass) inner receptacles;

2 The total combined gross mass of inner receptacles should not exceed one half of the gross mass of inner receptacles used for the drop test in 6.8.1; above

3 The thickness of cushioning between inner receptacles and between inner receptacles and the outside of the intermedi-ate packaging should not be reduced below the corresponding thicknesses in the originally tested packaging, and if a single inner receptacle was used in the original test, the thickness of cushioning between inner receptacles should not be less than the thickness of cushioning between the outside of the intermediate packaging and the inner receptacle in the original test. When either fewer or smaller inner receptacles are used (as compared to the inner receptacles used in the drop test), sufficient additional cushioning material should be used to take up the void;

4 The outer packaging should have successfully passed the stacking test in 8.7 of Annex I to this Code while empty. The total mass of identical packages should be based on the combined mass of inner receptacles used in the drop test in 6.8.1 above;

5 For inner receptacles containing liquids, an adequate quantity of absorbent material to absorb the entire liquid content of the inner receptacles should be present;

6 If the outer packaging is intended to contain inner receptacles for liquids and is not leak proof or is intended to contain inner receptacles for solids and is not sift proof, a means of containing any liquid or solid contents in the event of leakage should be provided in the form of a leak proof liner, plastics bag or other equally effective means of containment; and

7 In addition to the markings prescribed in 5.6 (a) to (f), packagings should be marked in accordance with 5.6 (g).

6.8 Waste clinical or (bio) medical substances should meet all the requirements for infectious substances except the packag-ing requirements of sections 5 and 6 of this introduction. Such waste should be transported in rigid leak proof packagings or IBCs in accordance with the provisions of section 26 of the General Introduction and Annex I for solids, at the packag-ing group II performance level, provided there is sufficient absorbent material to absorb the entire amount of liquid present and the packaging or IBC is capable of retaining liquids. Packages containing larger quantities of liquid should be carried in rigid packagings or IBCs in accordance with the provisions of section 26 of the General Introduction and Annex I at the packaging group II performance level for liquids. Packagings or IBCs intended to contain sharp objects such as broken glass and needles should be resistant to puncture and retain liquids under the performance test conditions in section 26 of the General Introduction and Annex I.



7 RESPONSIBILITY OF CARRIER

7.1 Carriers and their staff should fully understand all applicable regulations for the packing labelling transport and documentation of consignments of infectious substances. The carrier should accept and expedite the transport of consignments conforming to the rules in force. If the carrier finds any error in the labelling or documentation he should immediately notify the consignor or consignee so that the appropriate corrective measures may be taken.

8 RESPONSIBILITY OF CONSIGNEE

8.1 The consignee should obtain from the competent authorities the necessary licence for the import of infectious substances. The consignee should also provide the consignor with any import licences authorizations or other documents required by the competent authorities. Upon receipt of known or suspected high risk infectious sub-stances of human or animal origin the consignee should immediately acknowledge receipt to the consignor by the most rapid means of communication available to him.

8.2 The consignee should have a suitably equipped and adequately staffed receiving area. All incoming consign-ments of infectious substances should be unpacked in areas designated for this purpose and under conditions of containment commensurate with the degree of danger presented by the infectious substances. A record should be kept of the receipt of all substances.

9 ACTION TO BE TAKEN IN THE EVENT OF DAMAGE OR LEAKAGE

9.1 If any person responsible for the carriage or opening of packages containing infectious substances becomes aware of damage to or leakage from such packages he should

1 avoid handling the package or keep handling to a minimum;

2 inspect adjacent packages for contamination and put aside any that may have been contaminated;

3 inform the appropriate public health authority or veterinary authority and provide information on any other coun-tries of transit where persons may have been exposed to danger; and

4 notify the consignor and/or the consignee.

10 INTERNATIONAL NOTIFICATION

10.1 A public health or veterinary authority to which actual or suspected leakage from or damage to a package is reported should notify the authorities of any countries in which the package may have been handled including countries of transit.


CLASS 8 – C o r r o s i v e s

2.3 Packing - packaging types and limits 2.3.1 Except where there are special packaging requirements in the individual schedules, the packagings indicated in

the tables in section 3 of this introduction should be used

2.3.1.1 Glass receptacles packaged in an outer packaging should be surrounded by inert cushioning material so ar-ranged as to prevent breakage and leakage from the package. For liquids, this cushioning material should also be absorbent. This is not necessary if close fitting parts of expanded plastics are used as cushioning material and the requirements of the second sentence of 2.3.1.5 are met, when appropriate;

2.3.1.2 Where glass is permitted, it should be understood to include earthenware, porcelain and other comparable mate-rials unless stipulated otherwise;

2.3.1.3 Where glass or plastics receptacles are permitted, it should be understood that glass or plastics bottles or jars are included;

2.3.1.4 Where wooden boxes are permitted as outer packagings, it should be understood that boxes of natural wood (4C), plywood boxes (4D) and reconstituted wood boxes (4F) are included;

2.3.1.5 Moulded expanded plastics boxes (4H1) should be constructed of a fire-resistant grade of material. When the contents are not compatible with the outer packaging each glass receptacle should be enclosed in a bag made of plastics material compatible with the contents and the bag should be effectively closed.

2.3.2 A cylinder of the kind normally used for compressed gases, approved by the competent authority of the country concerned and with suitable valve protection, may be used to contain any corrosive liquid provided that this liquid is compatible with the material of construction.

2.3.3 Removable head packagings should not be used for the transport of liquids, except that steel and aluminium removable head drums or jerricans may be used for liquids in packaging groups II and III, when these packagings successfully pass the test for liquids.

2.3.4 Non-removable head packagings (1A1, 3A1, 1B1, 1H1 and 3H1) tested for liquids in accordance with the provi-sions of Annex I may also be used as packagings for solids, on condition that the testing qualifications indicated in the UN Mark are observed.



3 PACKAGING SPECIFICATIONS

TABLE 1 - LIQUIDS [new table]



I II III Drums - Steel 1A2 75 kg 125 kg 125 kg Aluminium 1B2 75 kg 125 kg 125 kg Plywood 1D 75 kg 125 kg 125 kg Fibre 1G 75 kg 125 kg 125 kg

Receptacles, glass, porce-lain and stoneware, maxi-mum contents 10 litres, or


Receptacles, plastics maximum contents 30 litres, or Plastics 3H2 30 kg 60 kg 60 kg

Boxes - Steel 4A 75 kg 125 kg 125 kg Aluminium 4B 75 kg 125 kg 125 kg Plywood 4D 75 kg 125 kg 125 kg Natural wood 4C1, 4C2 75 kg 125 kg 125 kg Reconstituted wood 4F 75 kg 125 kg 125 kg


Solid plastics 4H2 75 kg 125 kg 125 kg Boxes - Fibreboard 4G 401 kg 551 kg 551 kg Boxes - Moulded expanded

plastics 4H1 40 kg 55 kg 55 kg

Drums - Steel 1A1 250 litres 250 litres 250 litres Steel 1A2 Prohibited 2504 litres 2504 litres Aluminium 1B1 250 litres 250 litres 250 litres Aluminium

1B2 Prohibited 2504 litres 2504 litres Drums - Plastics 1H1 2502 litres 250 litres 250 litres Jerricans - Steel 3A1 60 litres 60 litres 60 litres Steel 3A2 Prohibited 604 litres 604 litres Aluminium 3B1 60 litres 60 litres 60 litres Aluminium 3B2 Prohibited 604 litres 604 litres Plastics

3H1 602 litres 60 litres 60 litres Cylinders According to the design type3 Plastics receptacle in a steel crate or box 6HA2 602 litres 60 litres 60 litres

aluminium crate or box 6HB2 602 litres 60 litres 60 litres wooden box 6HC 602 litres 60 litres 60 litres plywood box 6HD2 602 litres 60 litres 60 litres fibreboard box 6HG2 602 litres 60 litres 60 litres

solid plastics box 6HH2 602 litres 60 litres 60 litres Notes: 1 When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100 kg for packaging

groups II and III and 75 kg for packaging group I. 2 Not permitted for class 3, packaging group I. 3 Cylinders of carbon steel, special steels, copper alloy and aluminium alloy ≤ 150 litres.

Receptacles of carbon steel, special steels, copper alloy and aluminium alloy ≥ 100 to ≤1000 litres. 4 Tested for liquids.



[new table]


Packaging group Table 1 (continued) Packaging code (Annex I)

I II III Plastics receptacle in a: plywood drum 6HD1 120 2 litres 250 litres 250 litres

fibre drum 6HG1 120 2 litres 250 litres 250 litres plastics drum 6HH1 120 2 litres 250 litres 250 litres Plastics receptacle in a: steel drum 6HA1 250 litres 250 litres 250 litres aluminium drum 6HB1 250 litres 250 litres 250 litres Glass receptacle in a: steel drum 6PA1 60 2 litres 60 litres 60 litres

steel crate or box 6PA2 60 2 litres 60 litres 60 litres aluminium drum 6PB1 60 2 litres 60 litres 60 litres aluminium crate or box 6PB2 60 2 litres 60 litres 60 litres wooden box 6PC 60 2 litres 60 litres 60 litres plywood drum 6PD1 60 2 litres 60 litres 60 litres plywood box 6PD2 60 2 litres 60 litres 60 litres fibre drum 6PG1 60 2 litres 60 litres 60 litres fibreboard box 6PG2 60 2 litres 60 litres 60 litres expanded plastics drum 6PH1 60 2 litres 60 litres 60 litres

solid plastics drum 6PH2 60 2 litres 60 litres 60 litres Note: 2 Not permitted for class 3, packaging group I.



TABLE 2 - SOLIDS [new table]

Maximum gross mass Packaging group Inner packaging Outer packaging Packaging

code (Annex I) I II III

Drums - Steel 1A2 125 kg 225 kg 225 kg Aluminium 1B2 125 kg 225 kg 225 kg Plywood 1D 125 kg 225 kg 225 kg Fibre 1G 125 kg 225 kg 225 kg

Receptacles, glass, porcelain and stoneware, maximum contents 10 kg or

Plastics 1H2 125 kg 225 kg 225 kg Jerricans - Steel 3A2 75 kg 120 kg 120 kg

Aluminium 3B2 75 kg 120 kg 120 kg Receptacles, plastics, maxi-mum contents 30 kg, or

Plastics 3H2 75 kg 120 kg 120 kg Boxes - Plywood 4D 125 kg 225 kg 225 kg

Natural wood 4C1 125 kg 225 kg 225 kg Reconstituted 4F 125 kg 225 kg 225 kg wood 4A 125 kg 225 kg 225 kg Steel 4B 125 kg 225 kg 225 kg Aluminium 4H2 125 kg 225 kg 225 kg

Receptacles, metal maximum contents 40 kg or Bags 1 maximum contents 50 kg

Solid plastics Boxes - 4C2 400 kg 400 kg 400 kg

Natural wood with sift proof

walls Boxes - Fibreboard 4G 40 2 kg 55 2 kg 55 2 kg Boxes - Expanded plastics 4H1 40 kg 55 kg 55 kg Drums - Steel 1A1, 1A2 400 kg 400 kg 400 kg

Aluminium 1B1, 1B2 400 kg 400 kg 400 kg Plywood 1D 1 400 kg 400 kg 400 kg Fibreboard 1G 1 400 kg 400 kg 400 kg

Plastics 1H1, 1H2 400 kg 400 kg 400 kg Jerricans - Steel 3A1, 3A2 120 kg 120 kg 120 kg Aluminium 3B1, 3B2 120 kg 120 kg 120 kg Plastics 3H1, 3H2 120 kg 120 kg 120 kg Boxes - Steel 4A Prohibited 225 kg 225 kg Aluminium 4B Prohibited 225 kg 225 kg Natural wood 4C1 1 Prohibited 225 kg 225 kg Fibreboard 4G 1 Prohibited 225 kg 225 kg Plywood 4D 1 Prohibited 225 kg 225 kg Reconstituted wood 4F 1 Prohibited 225 kg 225 kg Solid plastics 4H2 1 Prohibited 225 kg 225 kg Moulded expanded plastics 4H1 Prohibited 60 kg 60 kg Barrels 4C2 1 400 kg 400 kg 400 kg Notes: 1 These packagings should not be used when the contents are likely to melt during the voyage. 2 When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100 kg for packaging

groups II and III and 75 kg for packaging group I.



[new table]

Maximum gross mass Packaging group Table 2 (continued) Packaging

code (Annex 1) I II III

Bags - woven plastics water resistant 5H3 1 Prohibited 50 3 kg 50 3 kg plastics film 5H4 1 Prohibited 50 3 kg 50 3 kg textile water-resistant 5L3 1 Prohibited 50 3 kg 50 3 kg paper multiwall, water-resistant 5M2 1 Prohibited 50 3 kg 50 3 kg Plastics receptacle in a steel drum 6HA1 400 kg 400 kg 400 kg aluminium drum 6HB1 400 kg 400 kg 400 kg Plastics receptacle in a plywood drum 6HD1 120 kg 250 kg 250 kg fibre drum 6HG1 120 kg 250 kg 250 kg plastics drum 6HH1 120 kg 250 kg 250 kg Plastics receptacle in a fibreboard box 6HG2 40 kg 55 kg 55 kg Glass receptacle in a steel drum 6PA1 75 kg 75 kg 75 kg steel crate or box 6PA2 75 kg 75 kg 75 kg aluminium drum 6PB1 75 kg 75 kg 75 kg aluminium crate or box 6PB2 75 kg 75 kg 75 kg wooden box 6PC 75 kg 75 kg 75 kg plywood drum 6PD1 75 kg 75 kg 75 kg wickerwork hamper 6PD2 75 kg 75 kg 75 kg fibre drum 6PG1 75 kg 75 kg 75 kg fibreboard box 6PG2 75 kg 75 kg 75 kg expanded plastics drum 6PH1 75 kg 75 kg 75 kg solid plastics drum 6PH2 75 kg 75 kg 75 kg Notes: 1 These packagings should not be used when the contents are likely to melt during the voyage. 3 For bags, 50 kg net mass applies.



4 STOWAGE

4.1 Class 8 substances should be stowed as indicated in the individual schedules in accordance with one of the cate-gories specified below:

4.1.1 Stowage category A

Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length which-ever is the greater number.




4.1.2 Stowage category B




ON DECK ONLY

4.1.3 Stowage category C


ON DECK ONLY


ON DECK ONLY

4.1.4 Stowage category D


ON DECK ONLY


PROHIBITED

4.1.5 Stowage category E




PROHIBITED



SCHEDULES FOR CLASS 8 SUBSTANCES




ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, more than 80% acid, by mass

Packaging group: II

Label of class


class

3

UN No. Formula 2789 CH3COOH

Properties Colourless flammable liquid with a pungent odour. When pure, crystallizes below 16° C. Flashpoint 40° C c.c. (pure product), 61°C c.c. (80% solution). Explosive limits 4% to 17%. Miscible with water. Corrosive to lead and most other metals.

Observations Corrosive to skin, eyes and mucous membranes.

Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction For tanks see section 13 of the General Introduction.

Stowage Category A.


ACETIC ACID SOLUTION, more than 10% but not more than 80% acid, by mass

Packaging group: II

for solutions with not less than 50% but not more than 80% acid, by mass III for solutions with more than 10% and less than 50% acid, by mass

Label of class

8

UN No. Formula 2790 CH3COOH

Properties Colourless liquid with a pungent odour. Miscible with water. Corrosive to lead and most other metals.

Observations Corrosive to skin, eyes and mucous membranes.


Stowage Category A.




2-CHLOROPROPIONIC ACID, solid or so-lution

alpha-CHLOROPROPIONIC ACID, solid or solution


Label of class

8

UN No. Formula 2511 CH3CHCICOOH

Properties Crystals or a colourless aqueous solution with a specific odour.

Observations Dust and liquid cause burns to skin, eyes and mucous membranes.

Packing For liquids see table 1 in the introduction to this class. For solids see table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.

Stowage Category A. For glass carboys category E.




CHLOROSILANES, CORROSIVE, N.O.S.

Packaging group: II

Label of class

8


UN No. Formula 2987

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless liquids with a pungent odour. Immiscible with water. React violently with water or steam evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire evolve toxic gases. In the presence of moisture, highly corrosive to most metals.

Observations Cause burns to skin, eyes and mucous membranes.


Stowage Category C. Clear of living quarters.



CLASS 8 - Corrosives


CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S.

Packaging group: I or II accord-ing to the grouping criteria for each

hazard

Label of class


3


UN No. Formula 2920

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless, flammable liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence of moisture, highly corrosive to most metals.

Observations Cause burns to skin, eyes and mucous membranes. For CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S., UN No. 2985, see class 3.2.






CHLOROSULPHONIC ACID with or with-out sulphur trioxide

Packaging group: I

Label of class

8

UN No. Formula 1754 CISO2OH

Properties Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture highly corrosive to most metals.

Observations Causes severe burns to skin eyes and mucous membranes.


Stowage Category C For glass carboys category D. Clear of living quarters.


CHROMIC ACID, SOLUTION

Packaging group: II or III ac-cording to corrosivity criteria

Label of class

8

UN No. Formula 1755 H2CrO4

Properties Orange liquid. Powerful oxidant. May cause fire in contact with organic materials such as wood, cotton or straw. Corrosive to most metals.

Observations Causes burns to skin eyes and mucous membranes. For CHROMIC ACID, SOLID, UN No. 1463 (CHROMIUM TRIOXIDE, ANHYDROUS) see class 5.1.





UN No. Formula 2802 CuCI or CuCl2

Properties MARINE POLLUTANT COPPER CHLORIDE (solution) is a severe marine pollutant, see 23.2.2 of the General Introduction. White to yellow-brown crystals or powder. Partially to fully soluble in water. Both the solid and the solution are corrosive to steel. Observations Causes burns to skin, eyes and mucous membranes. Packing See TABLE 2 in the introduction to this class. For COPPER CHLORIDE (solid) in IBCs see section 26 of the General introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.


COPPER CHLORIDE

CUPROUS CHLORIDE

CUPRIC CHLORIDE


Label of class

8 MARINE POLLUTANT

mark

CORROSIVE LIQUID, N.O.S.

Packaging group: I, II or III according to corrosivity crite-

ria

Label of class

8 MARINE POLLUTANT mark (for marine pollutants only)

UN No. Formula 1760

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Any liquid which, by the definition found in the introduction, is included in this class and which is not specified by name elsewhere in this class. Observations Causes burns to skin eyes and mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage For packaging groups I and II, category B. For packaging group III, category A. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.


UN No. Formula CORROSIVE LIQUID, ACIDIC, INOR-GANIC, N.O.S. 3264

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 3265

CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 3266

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 3267


Packaging group: I, II or III according to corrosivity criteria

Label of class

8


Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this code. Any liquid, acidic or basic, inorganic or organic, which, by the definition found in the introduction, is included in this class and which is not specified elsewhere in this class.



Stowage For packaging groups I and II, category B. For packaging group III, category A. Clear of living quarters.




NITRIC ACID, other than red fuming all concentrations

Packaging group: I*

Label of class

8 For packaging Group I only


5.1

UN No. Formula 2031 HNO3

Properties Colourless liquid. Powerful oxidant, may cause fire in contact with organic materials such as wood, cotton or straw, evolving highly toxic gases (brown fumes). Highly corrosive to most metals.

Observations Causes severe burns to skin eyes and mucous membranes. * Packaging group II if concentration does not exceed 70% acid.

Packing See table 1 in the introduction to this class. Plastics receptacles may only be used for concentrations not exceed-ing 55% unless approved otherwise by the competent authority of the country concerned. For tanks see section 13 of the General Introduction.

Stowage Category D. If concentration exceeds 50% acid, segregation as for class 5.1, but «SEPARATED FROM» classes 4.1, 5.1 and 7.


Bookshelf and K&M

NITRIC ACID - A transparent, colorless to yellowish, fuming corrosive liquid, HNO3, a highly reactive oxidizing agent used in the production of fertilizers, explosives, and rocket fuels and in a wide variety of industrial metallurgical processes. Also called aqua fortis. ------------------------------------------------------------------------------------------------ АЗОТНАЯ КИСЛОТА, HNO3, бесцветная жидкость с резким удушливым запахом; плотность 1,513 г/см3, tпл —41,59 C, tкип 82,6 C. С водой смешивается во всех отношениях. В промышленности получают каталитическим окислением аммиака. Применяют для получения удобрений, нитратов целлюлозы, красителей, серной кислоты, для травления металлов и полупроводниковых материалов, как окислитель ракетного топлива, компонент «нитрующей смеси» (с серной кислотой). Соли и эфиры азотной кислоты — нитраты. (K&M)



NITRIC ACID, RED FUMING

Packaging group: I

Label of class

8 Subsidiary risk labels of

classes

5.1 and 6.1

UN No. Formula 2032 HNO3 + NaO4

Properties Brown liquid. Powerful oxidant may cause fire in contact with organic materials such as wood cotton or straw. Highly corrosive to most metals.

Observations Toxic if swallowed, by skin contact or by vapour inhalation. Causes severe burns to skin eyes and mucous membranes.


Package gross

1 Receptacles, glass or plastics, in a wooden box (4C), (4D), (4F) 10 / 75 kg 2 Glass receptacle in a steel drum (6PA1) - 60 / wooden box (6PC) - 60 / 3 Drum, steel (1A1) - 250 / For tanks see section 13 of the General Introduction Stowage Category D. Clear of living quarters. Segregation as for class 5.1, but «SEPARATED FROM» classes 4.1,5.1 and 7.




OCTADECYLTRICHLOROSILANE

Packaging group: II

Label of class

8

UN No. Formula 1800 C18H37SiCl3

Properties Colourless liquid with a pungent odour. Reacts violently with water evolving hydrogen chloride an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture highly corrosive to most metals.

Observations Vapour irritates mucous membranes.




OCTYLTRICHLOROSILANE

Packaging group: II

Label of class

8

UN No. Formula 1801 C8H17SiCl3

Properties Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire evolves toxic gases. In the presence of moisture highly corrosive to most metals.

Observations Vapour irritates mucous membranes.





UN No. Formula 1802 HCLO4

Properties Colourless liquid. Oxidant. Highly corrosive to most metals.

Observations For PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass, UN No. 1873, see class 5.1. The carriage of PERCHLORIC ACID with more than 72% acid by mass, is prohibited.


Stowage Category C. «SEPARATED FROM» class 4.1.



1-PENTOL

3-METHYL-2-PENTEN-4-YNOL 1-HYDROXY-3-METHYL-2-PENTEN-4-YNE

Packaging group: II

Label of class

8

UN No. Formula 2705 CH2OHCH:C(CH3)C:CH

Properties Colourless liquid with a perceptible odour. May react in con-tact with a strongly alkaline substance.



Stowage Category B. «AWAY FROM» all other substances in this class.


PERCHLORIC ACID with not more than 50% acid, by mass

Packaging group: II

Label of class


of class

5.1

Bookshelf and K&M

PERCHLORIC ACID - A clear, colorless liquid, HClO4, explosively unstable under some conditions, that is a powerful oxidant used as a catalyst and in explosives. ------------------------------------------------------------------- ХЛОРНАЯ КИСЛОТА, HClO4, одна из самых сильных кислот. В свободном состоянии бесцветная жидкость, дымящая на воздухе; со временем темнеет и становится взрывоопасной. Применяют при разложении сложных руд, при анализе минералов, в качестве катализатора. Соли хлорной кислоты — перхлораты. (K&M)



PIPERAZINE, SOLID or SOLUTION

DIETHYLENEDIAMINE, SOLID or SOLUTION PYRAZINE HEXAHYDRIDE, SOLID or SOLUTION


Label of class

8

UN No. Formula 2579 NHCH2CH2NHCH2CH2

Properties Colourless deliquescent crystals turning dark on exposure to light. Soluble in water. Decomposes when heated and when involved in afire evolving highly toxic nitrous fumes. The solution in water is a strong base and is highly corrosive.



Stowage Category A. Keep as cool as reasonably practicable.


Bookshelf and K&M

PIPERAZINE - A colorless crystalline compound, C4H10N2, used as a hardener for epoxy resins, an antihistamine, and an anthelmintic. -------------------------------------------------------------------- ПИПЕРАЗИН, бесцветные кристаллы, tпл 112 С; растворим в воде и спирте, нерастворим в эфире. Применяют в аналитической химии (для определения Mo, V, W) и в медицине (как противоглистное средство); ингибитор коррозии. (K&M)


UN No. Formula

2401 (CH2)5NH

Properties Colourless liquid with a fishy odour. Miscible with water. The solution in water is a strong alkali and is corrosive. When involved in a fire evolves toxic nitrous fumes. Flashpoint 3° C to 16° C c.c.

Observations Harmful by inhalation. Causes severe burns to skin eyes and mucous membranes.


Stowage Category D.



PIPERIDINE

HEXAHYDROPYRIDINE [new schedule]

Packaging group: I

Label of class


class

3

Bookshelf and K&M

PIPERIDINE - A strongly basic, colorless liquid, C5H10NH, used in the manufacture of rubber and as a curing agent in epoxy resins. ------------------------------------------------------------ ПИПЕРИДИН - основной компонент, бесцветная жидкость, C5H10NH, используемый в изготовлении каучука и как отвердитель в эпоксидных смолах.



POTASSIUM HYDROGEN DIFLUORIDE, SOLID

POTASSIUM ACID FLUORIDE, SOLID, PO-TASSIUM BIFLUORIDE, SOLID, POTASSIUM HYDROGEN, FLUORIDE, SOLID

Packaging group: II

Label of class


6.1

UN No. Formula 1811 KHF2

Properties White crystalline solid. Decomposed by heat or acids evolving hydrogen fluoride a toxic ex-tremely irritating and corrosive gas apparent as white fumes. In the presence of moisture highly corrosive to glass other siliceous materials and most metals.

Observations Toxic if swallowed by skin contact or by inhalation. Causes burns to skin eyes and mucous membranes.


Stowage Category A. Shade from radiant heat. Clear of living quarters. Away from acids.


POTASSIUM HYDROGEN DIFLUORIDE SOLUTION

POTASSIUM ACID FLUORIDE, SOLUTION POTASSIUM

BIFLUORIDE, SOLUTION POTASSIUM

HYDROGEN, FLUORIDE, SOLUTION

Packaging group: II

Label of class


6.1

UN No. Formula 1811 KHF2

Properties Colourless liquid. Decomposed by acids evolving hydrogen fluoride a toxic extremely irritating and corrosive gas apparent as white fumes. Highly corrosive to glass other siliceous materials and most metals.

Observations Toxic if swallowed by skin contact or by inhalation. Causes burns to skin eyes and mucous membranes.


Stowage Category A. Clear of living quarters. Away from acids.



UN No. Formula 1830 H2SO4

Properties Colourless, oily liquid, mixture over 1.405 up to 1.840 specific grav-ity. In the presence of moisture, highly corrosive to most metals.



Stowage Category C. For steel drums, category B.



SULPHURIC ACID, with not more than 51% acid or BATTERY FLUID, ACID

BATTERY ACID

Packaging group: II

Label of class

8

UN No. Formula 2796 H2SO4

Properties Colourless liquid, mixture not exceeding 1.405 specific gravity. Highly corrosive to most metals.



Stowage Category B.


SULPHURIC ACID, with more than 51% acid

Packaging group: II

Label of class

8

Bookshelf and K&M

SULPHURIC ACID - A highly corrosive, dense, oily liquid, H2SO4, colorless to dark brown depending on its purity and used to manufacture a wide variety of chemicals and materials including fertilizers, paints, detergents, and explosives. Also called oil of vitriol, vitriol. ------------------------------------------------------------------------------------------------------ СЕРНАЯ КИСЛОТА, H2SO4, сильная двухосновная кислота. Безводная серная кислота — бесцветная маслянистая жидкость, плотность 1,9203 г/см3, tпл 10,3 С, tкип 296,2 С. С водой смешивается во всех отношениях. Концентрированная серная кислота реагирует почти со всеми металлами, образуя соли — сульфаты. Серную кислоту получают растворением в воде SO3, образующегося при окислении SO2; последний получают главным образом обжигом природных сульфидов — пирита и др. (т. н. контактный и башенный способы). Серная кислота — один из основных продуктов химической промышленности. Идет на производство минеральных удобрений (суперфосфат, сульфат аммония), различных кислот и солей, лекарственных и моющих средств, красителей, искусственных волокон, взрывчатых веществ. Применяется в металлургии (разложение руд, напр. урановых), для очистки нефтепродуктов, как осушитель и др. Мировое производство 139 млн. т. (нач. 1990-х гг.). (K&M)



SULPHURIC ACID, FUMING

DISULPHURIC ACID OLEUM PY-ROSULPHURIC ACID

Packaging group: I

Label of class


class

6.1

UN No. Formula 1831 H2SO4 + SO3

Properties Colourless, oily liquid, may be partly crystallized. Solution of vary-ing quantities of sulphur trioxide in sulphuric acid. Reacts violently with water and organic material, generating heat. In the presence of moisture, highly corrosive to most metals.

Observations Toxic if swallowed, by skin contact or by inhalation. Causes se-vere burns to skin, eyes and mucous membranes.


Package gross

1 Receptacles, glass or plastics, in a wooden box (4C), (4D), (4F) 10 / 75 kg moulded expanded plastics box (4H1) 10 / 40 kg 2 Cans, metal, in a wooden box (4C), (4D), (4F) 30 / 125 kg 3 Drum, steel (1A1) - 250 / For tanks see section 13 of the General Introduction Stowage Category C. For steel drums, category B. Clear of living quarters.




TETRAETHYLENEPENTAMINE


Label of class

8

UN No. Formula 2320 HN[(CH2)2NH(CH2)2NH2]2

Properties Viscous liquid. Miscible with water. When involved in a fire, evolves toxic gases. Observations Causes burns to skin, eyes and mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. For glass carboys, category E. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% maleic anhydride


Label NO LABEL REQUIRED Package to be marked

CLASS 8

UN No. Formula 2698 C6H8(CO)2O

Properties White crystalline powders. React with water, evolving heat and form-ing tetrahydrophthalic acid. Observations Cause burns to skin, eyes and mucous membranes. When heated, evolve acrid fumes which are irritating to skin, eyes and mucous membranes. Packages carried as a full load in a cargo transport unit are exempted from displaying the class number provided the unit in which they are packed is marked CLASS 8. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to these substances due to their low degree of danger. The provisions of this Code should not apply to a consignment of tetrahydrophthalic anhydrides which is accompanied by a certificate from the shipper stating that the substance as offered for shipment does not contain more than 0.05% maleic anhydride. Packing See table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.



TETRAMETHYLAMMONIUM HYDROXIDE, SOLID OR LIQUID

Packaging group: II

Label of class

8

UN No. Formula 1835 (CH3)4NOH

Properties Solid in the hydrated form. Melting point 60° C. More usual in liquid state very soluble in water. Reacts violently with acids.

Observations


Stowage Category A.


THIOGLYCOLIC ACID

MERCAPTOACETIC ACID

Packaging group: II

Label of class

8

UN No. Formula 1940 HSCH2COOH

Properties Colourless liquid with a strong very unpleasant odour. Corrosive to most metals.

Observations Harmful if swallowed.


Stowage Category A.


CLASS 9 – M i s c e l l a n e o u s d a n g e r o u s s u b s t a n c e s & a r t i c l e s

PAGE RESERVED




AIR BAG INFLATORS, pyrotechnic or AIR BAG MODULES, pyrotechnic or SEAT-BELT PRETENSIONERS, pyrotechnic


Label of class

9

UN No. Formula 3268

Properties This entry applies to articles which may be classified in in accordance with paragraph 1.1 of the introduction to , which are used as life-saving vehicle air bags or seat-belts, when transported as component parts and when "air bag inflators" or "seat-belt pretensioners" or "air bag modules" as presented for transport have been tested in accor-dance with test series 6 (c) of Part I of the United. Nations Recom-mendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, with the following results:

1. no explosion of the device; 2. no fragmentation of device casings; and 3. no projection hazard or thermal effect which would signifi-

cantly hinder fire-fighting or other emergency response ef-fects in the immediate vicinity.

If the air bag inflator unit satisfactorily passes the test series 6 (c) test, it is not necessary to repeat the test on the air bag module itself. Observations The provisions of this Code should not apply to air bags or seat-belts installed in vehicles or in completed vehicle components such as steering columns, door panels, seats, etc.

Packing Package gross

1 Wooden box (4C), (4D), (4F) - 2 Fibreboard box (4G) - Air bag inflators, air bag modules and seat-belt pretensioners may be transported unpackaged in dedicated handling devices or cargo transport units when they are transported from the manufacturing site to an assembly plant. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


UN No. Formula 1845 CO2

Properties Non-flammable gas in a white solid form. Slowly evolves vapours which are heavier than air (1.5). Observations Inhalation of vapours may lead to unconsciousness. Can cause severe burns when in contact with the skin. The provisions of this schedule should not apply to solid carbon diox-ide carried on board ship for cooling purposes for certain goods shipped in a closed freight container or vehicle. Packing Only freight containers, vehicles and other receptacles that can be closed in such a way that the escape of gas is reduced to a minimum should be used for the carriage of this substance. Where the sub-stance is loaded in a closed freight container or vehicle, special atten-tion should be paid to the requirements of 12.7.2 and 17.8.2. respec-tively of the General Introduction. Stowage Category C. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


CARBON DIOXIDE, SOLID

DRY ICE


Label of class

9

Bookshelf and K&M

DRY ICE - Solid carbon dioxide that sublimates at -78.5 C (-110 F) and is used primarily as a coolant. ----------------------------------------------------- «СУХОЙ ЛЕД», твердый диоксид углерода (CO2); испаряется при ?78,5 С, не переходя в жидкое состояние (отсюда название), хладагент в пищевой промышленности. (K&M)



CARGO TRANSPORT UNIT, UNDER FUMIGATION

CONTAINER UNDER FUMIGATION

Fumigation Warning sign NO CLASS 9 LABEL REQUIRED

UN No. Formula Properties A closed cargo transport unit loaded with cargoes under fumigation. The fumigant gases are either poisonous or asphyxiant. The gases are evolved from solid or liquid preparations distributed within the closed cargo transport unit. Observations Reference is made to the IMO/ILO/UN ECE Guidelines for Packing of Cargo Transport Units (CTUs) and the Recommendations on the Safe Use of Pesticides in Ships Only a cargo transport unit that can be closed in such a way that the escape of gas is reduced to a minimum should be used for the carriage of fumigated cargo. A closed cargo transport unit containing cargo under fumigation should not be al-lowed on board until sufficient time has elapsed to allow the attain-ment of a reasonably uniform gas concentration throughout the cargo. Because of variations due to types and amounts of fumigants and commodities and temperature levels, the period which should elapse between fumigant application and loading should be determined by the competent authority. Twenty-four hours is normally adequate for this purpose. The master should be informed prior to loading of a cargo transport unit under fumigation. These should be identified with a warning sign affixed to the access door(s) incorporating the identity of the fumigant and the date and time of fumigation. The transport documents for a closed cargo transport unit should show the date of fumigation and the type and amount of fumigant used. Equipment for detecting the fumigant gas or gases should be carried on the ship with the instruction for its use. The provisions of this Code should not apply to a closed cargo trans-port unit which has been ventilated after fumigation to ensure that no harmful concentrations of gas remain. Such a unit should also have the warning sign(s) removed. Fumigants should not be applied to the contents of a cargo transport unit once it has been loaded aboard a ship. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.


IMDG CODE - PAGE 9028 (first of three pages) Amdt. 28-96

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.


Label of class

9


UN No. Formula 3082

Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. The provisions of this schedule are applicable to - liquid substances designated as marine pollutants under this entry as listed in the appendix to this schedule: - solutions and liquid mixtures or isomers of substances identified as marine pollutants in this Code and which meet the criteria of section 23.2 of the General Introduction and which do not meet the classifica-tion criteria of any other hazard class. Observations The following liquid substances which do not meet the classification criteria of any other hazard class may also be transported under this schedule: - liquid substances, solutions and mixtures which are subject to other transport regulations due to their potential to cause harm to environ-ments other than the marine environment; and - wastes not otherwise subject to the provisions of this Code but cov-ered under the Basel Convention*, in such a case the proper shipping name should be preceded by the word "WASTE" (see 9.3.7 and 27.5.2 of the General Introduction).

* Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal (1989). Packing Any suitable packaging complying with the provisions of Annex I to this Code. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.


Appendix

LIQUID SUBSTANCES DESIGNATED AS MARINE POLLUTANTS UNDER UN No. 3082*

1 Severe marine pollutants (PP) (see 23.2.2 of the General Introduction).

CHLORINATED PARAFFINS (C10-C13), CHLORINATED PARAFFINS (C14-C17) with more than 1% shorter chain length, CRESYL DIPHENYL PHOSPHATE, TRIARYL PHOSPHATES, N.O.S., TRICRESYL PHOSPHATE not less than 1% but not more than 3% ortho-isomer.

2 Marine pollutants (P)

ALCOHOL C6-C17(SECONDARY)-POLY(3-6)ETHOXYLATE, ALCOHOL C12-C16 POLY(1-6)ETHOXYLATE, ALCOHOL C13-C15 POLY(1-6)ETHOXYLATE, ALKYLBENZENESULPHONATES, branched and straight chain, BUTYL BENZYL PHTHALATE, 1-CHLOROOCTANE, COAL TAR, COCONITRILE, CREOSOTE(COAL TAR), CREOSOTE (WOOD TAR), normal-DECALDEHYDE, normal-DECANOL, DECYL ACRYLATE, 1,3-DIBROMOBENZENE, DI-n-BUTYL PHTHALATE, para-DICHLOROBENZENE, 1,6-DICHLOROHEXANE, DIISOPROPYLBENZENES, DIISOPROPYLNAPHTHALENE, DIPHENYL/DIPHENYL ETHER (MIXTURES), DIPHENYL OXIDE and BIPHENYL PHENYL ETHER, MIXTURES, EPTC (ISO), normal-HEPTYLBENZENE, normal-HEXYLBENZENE, 2,4-HEXADIENE ALDEHYDE, ISODECALDEHYDE, ISODECANOL.

* See also the note to the appendix to the schedule for ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., UN No. 3077.



Appendix

SOLID SUBSTANCES DESIGNATED AS MARINE POLLUTANTS UNDER UN No. 3077

1 Severe marine pollutants (PP) (see 23.2.2 of the General Introduction)

CHLORINATED PARAFFINS (C10-C13), COPPER SULPHATE, ANHYDROUS/HYDRATES, CHLORINATED PARAFFINS (C14-C17) with more than 1% shorter chain length, MERCUROUS CHLORIDE, TRIPHENYL PHOSPHATE, TRIPHENYL PHOSPHATE/tert-BUTYLATED TRIPHENYL PHOSPHATES MIXTURES, containing 10% to 48% of TRIPHENYL PHOSPHATE.

2 Marine pollutants (P)

N2-tert-BUTYL-N4-CYCLOPROPYL-6-METHYLTHIO-1,3,5-TRIAZINE-2,4 DIAMINE, 1,4-DI-tert-BUTYLBENZENE, CALCIUM NAPHTHENATE, CRESYLIC ACID SODIUM SALT, para-DICHLOROBENZENE, 2,4-DICHLOROPHENOXYACETIC ACID, 2,4-DICHLOROPHENOXYACETIC ACID DIETHANOLAMINE SALT, 2,4-DICHLOROPHENOXYACETIC ACID DIMETHYLAMINE SALT, 2,4-DICHLOROPHENOXYACETIC ACID TRIISOPROPYLAMINE SALT, DIPHENYL,

DODECYL DIPHENYL OXIDE DISULPHONATE, MANCOZEB (ISO), METHYLNAPHTHALENES, NAPHTHENIC ACIDS, n-TETRAMETHYLBENZENE, TRIISOPROPYLATED PHENYL PHOSPHATES, TRIPHENYL PHOSPHATE/tert-BUTYLATED TRIPHENYL PHOSPHATES MIXTURES, containing 5% to 10% of TRIPHENYL PHOSPHATE, ZINC BROMIDE.

Note: Solutions and liquid mixtures containing 10% or more of substance(s) designated as marine pollutants in this appen-dix or 1 % or more of substance(s) designated as severe marine pollutants in this appendix should be carried under the provisions for ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. , UN No. 3082, in this class, unless they fall within the criteria of classes 1 to 8.




FISHMEAL, STABILIZED FISHSCRAP, STABILIZED anti-oxidant treated. Moisture content greater than 5% but not

exceeding 12% by mass. Fat content not more than 15% by mass.



UN No. Formula 2216

Properties Brown to greenish brown product obtained through heating and drying of oily fish. Strong odour which may affect other cargo. Liable to heat spontaneously unless of low fat content or effectively anti-oxidant treated.

Observations (a) Stabilization of fishmeal should be achieved to prevent sponta-

neous combustion; by effective application of between 400 and 1000 mg/kg (ppm) ethoxyquin or liquid BHT (butylated hydroxytoluene) or between 1000 and 4000 mg/kg (ppm) BHT in powder form at the time of production. The said application should occur no longer than twelve months prior to shipment. Anti-oxidant remnant concen-tration should be not less than 100 mg/kg (ppm) at the time of shipment.

(b) Certificates from a recognized authority should state: - moisture content; - fat content; - details of anti-oxidant treatment for meals older than 6 months; anti-oxidant concentration at the time of shipment which must exceed 100 mg/kg (ppm);

- packing number of bags and total mass of the consignment; - temperature of fishmeal at the time of despatch from the fac-tory; and - date of production.

Note: No weathering/curing is required prior to loading. (c) The provisions of this Code should not apply to consignments of

fishmeal which are accompanied by a certificate issued by a recognized authority of the country of shipment or other recog-nized authority stating that the product has no self heating properties when carried in packaged form;

(d) At the time of loading the temperature of the cargo should not exceed 35° C or 5° C above ambient temperature whichever is higher;

(e) Refuse for shipment wet or damaged bags; (f) For UNSTABILIZED FISHMEAL and UNSTABILIZED, FISH-

SCRAP, UN No. 1374, see class 4.2.


UN No. Formula 3072 Properties A life-saving appliance other than a self-inflating one which includes one or more of the following dangerous goods as equipment signal devices (), gases (class 2.2) small quantities of flammable sub-stances (classes 3.41 and 5.2), electric storage batteries (classes 8 and 9).

Observations Dangerous goods packaged as part of the complete life-saving ap-pliance are exempt from internal segregation when the appliance complies with the relevant requirements of the International. Conven-tion for the Safety of Life at Sea, 1974 as amended.

Packing As approved by the competent authority of the country concerned.

Stowage Category A. «SEPARATED FROM» class 6.2.


UN No. Formula 2990 Properties A life saving appliance that presents a hazard if the self-inflating device is activated accidentally and which may also include one or more of the following dangerous goods as equipment signal devices (), non-toxic gases (class 2.2) small quantities of flammable sub-stances (classes 3.41 and 5.2) electric storage batteries (class 8) and lithium batteries (class 9).

Observations Dangerous goods packaged as part of the complete life-saving ap-pliance are exempt from internal segregation when the appliance complies with the relevant requirements of the International Conven-tion for the Safety of Life at Sea, 1974, as amended.

Packing As approved by the competent authority of the country concerned.

Stowage Category A. «SEPARATED FROM» class 6.2.



LIFE SAVING APPLIANCES, NOT SELF-INFLATING

Label of class

9

LIFE SAVING APPLIANCES, SELF-INFLATING

Label of class

9


IMDG CODE - PAGE 9033 (first of three pages) Amdt. 29-98

LITHIUM BATTERIES

LITHIUM BATTERIES CONTAINED IN EQUIPMENT or LITHIUM BATTERIES PACKED WITH EQUIPMENT

Packaging group II

Label of class

9

UN No. Formula 3090

3091 Properties or descriptions Electrical batteries containing lithium or lithium alloy encased in a rigid metallic body. Lithium batteries may also be shipped in or packed with equipment. Electrical lithium batteries may cause fire due to an explosive rupture of the body caused by improper construction or reaction with contami-nants. Observations Lithium cells and batteries may be transported under this entry if they meet the following requirements: (a) each cell or battery type has been determined to meet the criteria

for assignment to class 9 on the basis of tests earned out in ac-cordance with the United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria Part III sub section 38.3;

(b) Each cell contains not more than 12 grams of lithium or lithium alloy;

(c) Each battery contains not more than 500 grams of lithium or lith-ium alloy;

(d) Each cell and battery incorporates a safety venting device or is designed to preclude a violent rupture under conditions nor-mally incident to transport;

(e) Each cell and battery is equipped with an effective means of preventing external short circuits;

(f) Each battery containing cells or series of cells connected in paral-lel is equipped with diodes to prevent reverse current flow;

(g) Cells and batteries are packed in inner packagings to effectively prevent short circuits and to prevent movement which could lead to short circuits.

The provisions of this Code should not apply to lithium cells and bat-teries provided: (a) Each cell with a liquid cathode contains not more than 0.5 gram of

lithium or lithium alloy and each cell with a solid cathode contains not more than 1 gram of lithium or lithium alloy;

(b) Each battery with a solid cathode contains not more than an ag-gregate quantity of 2 grams of lithium or lithium alloy and each battery with a liquid cathode contains not more than an aggre-gate quantity of 1 gram of lithium or lithium alloy;

(c) Each cell or battery containing a liquid cathode is hermetically sealed;

(d) Cells are separated so as to prevent short circuits; (e) Batteries are separated so as to prevent short circuits and are

packaged in strong packagings except when installed in elec-tronic equipment.


(f) In the case of a liquid cathode battery containing more than 0.5 gram of lithium or lithium alloy, or a solid cathode battery con-taining more than 1 gram of lithium or lithium alloy, it does not contain a liquid or gas which is considered dangerous unless the liquid or gas, if free, would be completely absorbed or neu-tralized by other materials in the battery.

The provisions of this Code should also not apply to lithium cells and batteries provided: (a) Each cell contains not more than 5 grams of lithium or lithium al-loy; (b) Each battery contains not more than 25 grams of lithium or lith-ium alloy; (c) Each cell or battery is of the type proved to be non-dangerous by testing in accordance with the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria; such testing should be carried out on each type prior to the initial transport of that type; (d) Cells and batteries are designed or packed in such a way as to

prevent short circuits under conditions normally encountered in transport.

The competent authority may establish conditions under which the lithium contents per individual cell may be increased to 60 grams and the total lithium contents per package to 2500 grams. Such conditions should include the requirements for packing, stowage and segrega-tion of the cells, batteries or the equipment from other dangerous goods. The certificate of approval should accompany the shipment, Spent batteries - Cells which have been discharged to the extent that the open-circuit voltage is less than the lower of: (a) 2 volts; or (b) 2/3 of the voltage of the undischarged cell or battery containing one or more such cells, should not be transported except under pro-visions specified by the competent authority.

Packing Cells or batteries should be packaged with hot more than 500 grams of lithium in each package. They should be packed in such manner so as to effectively prevent short circuits and be securely cushioned so as to prevent movement which could lead to short circuits. When lith-ium cells and batteries included in class 9 are packed with equipment, they should be packed in inner fibreboard packagings that meet the requirements for packaging group II. When lithium cells and batteries included in class 9 are contained in equipment, the equipment should be packed in strong outer packagings in such a manner as to prevent accidental operation during transport. The quantity of lithium metal contained in any battery in a piece of equipment should not exceed 12 grams per cell and 500 grams per battery. Not more than ten lith-ium batteries should be contained in any piece of equipment.



Package gross

kg 1 Wooden box (4C), (4D), (4F) or fibre-board box (4G) 250 2 Plywood drum (1D), fibre drum (1G) or plastics drum (1H2) 250 3 *Steel drum (1A2) or aluminium drum (1B2) 400

* When steel or aluminium drums are used, the cells or batteries should be packaged in strong inner fibreboard packagings which should be separatee from each other and from the inner surfaces of the drum by at least 25 mm thickness of non-combustible cushioning mate-rial. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

IMDG CODE - PAGE 9033b (page 9034 follows) Amdt. 27-94



POLYCHLORINATED BIPHENYLS PCB's

Packaging group: II

Label of class

9 MARINE POLLUTANT

mark

UN No. Formula 2315 C12H(8+X)CI(2 +X)

Properties MARINE POLLUTANT Severe marine pollutant see 23.2.2 of the General Introduction. Colourless liquids with perceptible odours. Immiscible with water.

Observations Harmful by ingestion or by skin contact. This entry also covers appli-ances such as transformers and condensers containing polychlori-nated biphenyls and absorbent materials such as rags, cotton waste, clothing, sawdust, etc., contaminated with polychlorinated biphenyls.

Packing In general liquids or solids containing or contaminated with polychlori-nated biphenyls should be packaged in accordance with table 1 or 2 respectively in the introduction to class 6.1. In general, transformers and condensers should be carried in leakproof metal packagings which are capable of holding, in addition to the transformers and con-densers, at least 1.25 times the volume of the liquid present in them. There should be sufficient inert absorbent material in the packagings to absorb at least 11 times the volume of liquid which is contained in the transformers or condensers. The transformers or condensers should not be overstowed. Notwithstanding the above, liquids and solids not packaged in accordance with table 1 or 2 of the introduction to class 6.1 and unpackaged transformers and condensers should be stowed in cargo transport units (CTUs) fitted with a leakproof metal tray to a height of 800mm containing sufficient inert absorbent material to absorb at least 1.1 times the volume of any free liquid. Adequate provision should be made to seal the transformers and condensers to ensure that leakage during transport is minimized. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.

Stowage Category A. «SEPARATED FROM» foodstuffs.




POLYHALOGENATED BIPHENYLS, LIQUID or POLYHALOGENATED TERPHENYLS, LIQUID

POLYHALOGENATED BIPHENYLS, SOLID or POLYHALOGENATED TERPHENYLS, SOLID

Packaging group: II

Label of class


UN No. Formula 3151

3152 Properties MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. Solid or viscous liquids with a perceptible odour. Melting point of solids varies from 2° C to 164° C. Observations Harmful by ingestion or by skin contact. The UN Nos. 3151 and 3152 should not be used for POLYCHLORI-NATED BIPHENYLS. This entry also covers appliances such as transformers and condens-ers containing polyhalogenated biphenyls or terphenyls and absorbent materials, such as rags, cotton waste, clothing, sawdust, etc., con-taminated with polyhalogenated biphenyls or terphenyls. Packing In general, liquids or solids containing or contaminated with polychlori-nated biphenyls should be packaged in accordance with table 1 or 2 respectively in the introduction to class 6.1. In general, transformers and condensers should be carried in leakproof metal packagings which are capable of holding, in addition to the transformers and con-densers, at least 1.25 times the volume of the liquid present in them. There should be sufficient inert absorbent material in the packagings to absorb at least 1.1 times the volume of liquid which is contained in the transformers or condensers. The transformers or condensers should not be overstowed. Notwithstanding the above, liquids and solids not packaged in accordance with table 1 or 2 of the introduction to class 6.1 and unpackaged transformers and condensers should be stowed in cargo transport units fitted with a leakproof metal tray to a height of 800mm, containing sufficient inert absorbent material to ab-sorb at least 1.1 times the volume of any free liquid. Adequate provision should be made to seal the transformers and con-densers to ensure that leakage during transport is minimized. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. «SEPARATED FROM» foodstuffs. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.


CLASS 9 - Miscellaneous dangerous substances & articles

For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers, road or rail vehi-cles) or portable tanks, see section 25 of the General Introduction.

Stowage Category A. When stowed under-deck, mechanical ventilation should be provided to prevent the formation of a flammable atmosphere. «SEPARATED FROM» goods of except from those in division 1.4



POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour

POLYSTYRENE BEADS, EX-PANDABLE, evolving flammable vapour

PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flamma-ble vapour


Label of class

9

UN No. Formula 2211

3314

Properties A moulding material in bead or granular form consisting predominantly of polystyrene poly (methyl methacrylate) or other polymeric material and containing 5% to 8% of a volatile hydrocarbon which is predomi-nantly pentane. During storage a small proportion of this pentane is released to the atmosphere, this proportion increases at elevated temperatures.

Observations When shipped in secondary protection, the packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. Where the substance is loaded in a closed freight container or vehicle, special attention should be paid to the requirements of 12.7.2 and 17.8.2 respectively of the General Introduction.


Package gross

kg 1 Glass receptacles in a wooden box (4C), (4D), (4F) - 125 fibreboard box (4G) - 55 2 Metal cans in a wooden box (4C), (4D), (4F) - 225 fibreboard box (4G) - 55 3 Wooden box (4C2) - 125 4 Wooden barrel (2C2), fibre drum (1G) or plywood drum (1D)

200

5 Steel drum (1A2) - 250


UN No. Formula

1931 ZnS2O4

Properties White, amorphous solid material. Soluble in water. Liable to heat on contact with moisture and heating results in evolu-tion of sulphur dioxide, an intensely irritating gas. Also evolves sulphur dioxide on contact with acids.

Observations


Package gross

kg kg 1 Glass receptacles in a wooden box (4C), (4D), (4F) 2 125 2 Metal cans in a wooden box (4C), (4D), (4F) 15 125 fibreboard box (4G) 15 55

3 Plastics bags in a metal drum (1A2), ply-wood drum (1D) or fibre drum (1G) - 200

4 Paper bag (5M2) - 55 5 Textile bag (5L2), (5L3) - 100 6 Fibre drum (1G) or plywood drum (1D) - 200 7 Steel drum (1A2) - 400 8 Drum, plastics (1H2) - 200 For IBCs see section 26 of the General Introduction.

Stowage Category A. Keep as dry as reasonably practicable. «AWAY FROM» classes 6.2 and 8.



ZINC DITHIONITE

ZINC HYDROSULPHITE


Label of class

9

IMDG1998

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Transcript of IMDG1998