IGM RESINS B.V.

IGM RESINS B.V.P/O VN LOGISTICS B.V.DE PANOVEN 104191 GW GELDERMALSENTHE NETHERLANDS

VN LOGISTICS B.V.PANOVEN 10 VN LOGISTICS B.V.

PANOVEN 10

J. VAN KUIJL

(EMEA) +1 760 476 3961 access code 333 293

1 1

UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III MARINE POLLUTANT

S. de Vries

Frimpeks Kimya Ve Etiket San. Tic. A.S.Mermerciler Sanayi Sitesi, Cad. 15 834524 BEYLIKDUZU, ISTANBULTURKIJE

6 CARTON(4G one inner plastic bag) OF 20.000 KG, 120.000 KG NETTO / 131.000 KG GROSS

GELDERMALSEN 20-10-2021 GELDERMALSEN 20-10-2021



PANOVEN 10

J. VAN KUIJL

(EMEA) +1 760 476 3961 access code 333 293

1 1

UN 3077,ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Methyl 2-benzoylbenzoate), 9,III, marine pollutant.

S. de Vries


10 CARTONS(4G one inner plastic bag) OF 20.000 KG, 200.000 KG NETTO / 222.000 KG GROSS


IGM RESINS B.V.P/O VN LOGISTICS B.V.DE PANOVEN 10 - PAND 14191 GW GELDERMALSENTHE NETHERLANDS

(EMEA) +1 760 476 3961 ## 333 293

VN LOGISTICS B.V.VN LOGISTICS B.V.

J. VAN KUIJL

UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III.Marine Pollutant

J. VAN LOENEN


1 IBC (3H1) OF 1000 KG. TOTAL NET: 1000.00 KG, TOTAL GROSS: 1059.00 KG

GELDERMALSEN , 20-10-2021 GELDERMALSEN , 20-10-2021



PANOVEN 10

J. VAN KUIJL

UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide),9,III,(-)

1 1

(EMEA) +1 760 476 3961 access code 333 293

J. VAN LOENEN


3 CARTONS (4G one inner plastic bag) OF 20.000 KG, 60.00 KG NETTO / 66.00 KG GROSS


IGM RESINS B.V.P/O VN LOGISTICS B.V.DE PANOVEN 10 - PAND 14191 GW GELDERMALSENTHE NETHERLANDS

(EMEA) +1 760 476 3961 ## 333 293

VN LOGISTICS B.V.VN LOGISTICS B.V.

J. VAN KUIJL

UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate, Acrylic acid), 9, III. Marine Pollutant

1

2 IBC'S(31HA1) OF 1000 KG. TOTAL NET: 2000.000 KG, TOTAL GROSS: 2118.000 KG

S. de Vries


GELDERMALSEN , 20-10-2021 GELDERMALSEN , 20-10-2021

SAFETY DATA SHEETThis safety data sheet was created pursuant to the requirements of:

Regulation (EC) No. 1907/2006Commission Regulation (EU) No 2015/830 of 28 May 2015

Issuing Date 09-Jun-2020 Revision date 09-Jun-2020 Revision Number 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

Product Code(s) 10000161

Product Name Omnirad 379

REACH registration number 01-2120040688-50-0000

EC No 438-340-0

CAS No 119344-86-4

Chemical name 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one

Pure substance/mixture Substance

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Photoinitiator.

Uses advised against Consumer use.

1.3. Details of the supplier of the safety data sheet

For further information, please contact E-mail address [email protected] 1.4. Emergency telephone number

Emergency Telephone (EMEA) +1 760 476 3961 ## 333 293 Emergency Telephone §45 - (EC)1272/2008 Europe 112

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Reproductive toxicity Category 2 - (H361) Chronic aquatic toxicity Category 1 - (H410)

2.2. Label elements

SupplierIGM Resins B.V Gompenstraat 49 5145 RM Waalwijk T: +31 (0) 416 316 657 F: +31 (0) 416 564 632

_____________________________________________________________________________________________

EGHS / EN Page 1 / 12

_____________________________________________________________________________________________ OR379 - Omnirad 379 Revision date 09-Jun-2020

Signal wordWarning

Hazard statements H361 - Suspected of damaging fertility or the unborn childH410 - Very toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protectionP308 + P313 - IF exposed or concerned: Get medical advice/attentionP391 - Collect spillageP405 - Store locked upP501 - Dispose of contents/ container to an approved waste disposal plant

Additional informationThis product requires tactile warnings if supplied to the general public.

2.3. Other hazards No information available

SECTION 3: Composition/information on ingredients

3.1 Substances

Chemical name EC No CAS No Weight-% Classification according to Regulation (EC) No.

1272/2008 [CLP]

REACH registration

number 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]

butan-1-one

438-340-0 119344-86-4 >95% Repr. 2 (H361)Aquatic Chronic 1 (H410)

01-2120040688-50-XXXX

Chemical name CAS No Specific concentration limit (SCL)

M-Factor M-Factor (long-term)

2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one

119344-86-4 1

Full text of H- and EUH-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

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Page 2 / 12


General advice Show this safety data sheet to the doctor in attendance.

Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a doctor. Remove contact lenses, if present and easy to do. Continue rinsing.

Skin contact Wash skin with soap and water. In the case of skin irritation or allergic reactions see a doctor.

Ingestion Clean mouth with water and drink afterwards plenty of water.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms No information available.

4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors Treat symptomatically.

SECTION 5: Firefighting measures 5.1. Extinguishing media

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical.

Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the chemical

No information available.

Hazardous combustion products Thermal decomposition can lead to release of toxic and corrosive gases/vapours. Carbon monoxide.

5.3. Advice for firefighters

Special protective equipment for fire-fighters

Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions See Section 12 for additional Ecological Information.

6.3. Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

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Page 3 / 12


6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Remove contaminated clothing and shoes.

General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and immediately after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store locked up.

7.3. Specific end use(s)

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Exposure Limits .

Biological occupational exposure limits

Derived No Effect Level (DNEL)

Derived No Effect Level (DNEL) Worker

Derived No Effect Level (DNEL) 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Type Worker Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 1.4 mg/m³

Type Worker Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.2 mg/kg bw/d Derived No Effect Level (DNEL) General Population

Derived No Effect Level (DNEL) 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Type Consumer Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.35 mg/m³

_____________________________________________________________________________________________

Page 4 / 12


Type Consumer Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.1 mg/kg bw/d

Type Consumer Long term Systemic health effects Exposure route Oral Derived No Effect Level (DNEL) 0.1 mg/kg bw/d

Predicted No Effect Concentration (PNEC)

.

Predicted No Effect Concentration (PNEC) 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Environmental compartment Predicted No Effect Concentration (PNEC) Microorganisms in sewage treatment 10 mg/l

8.2. Exposure controls

Personal protective equipment

Eye/face protection Eye protection must conform to standard EN 166.

Hand protection Wear suitable gloves. Gloves must conform to standard EN 374.

Gloves Duration of contact PPE - Glove material Glove thickness Break through time

Long term (repeated) Nitrile rubber 0.4 mm 480 minutes Butyl rubber 0.4 mm 4 hours

Skin and body protection Wear suitable protective clothing.

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.


Environmental exposure controls No information available.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties Physical state Solid Appearance Powder. Colour light yellow. Odour Not determined. Odour threshold Not determined

Property Values Remarks • Method pH Not determined Melting point / freezing point 68 °C Boiling point / boiling range 270 °C Flash point 178 °C CC (closed cup) Evaporation rate Not determined Flammability (solid, gas) Does not ignite Flammability Limit in Air

Upper flammability or explosive

_____________________________________________________________________________________________

Page 5 / 12


9.2. Other information Softening point Not determined Molecular weight Not determined VOC Content (%) No information available Liquid Density Not determined Bulk density Not determined

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity No information available.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

Hazardous polymerisation Polymerisation can occur.

10.4. Conditions to avoid

Conditions to avoid Extremes of temperature and direct sunlight.

10.5. Incompatible materials

Incompatible materials None known based on information supplied.

10.6. Hazardous decomposition products

Hazardous decomposition products None known based on information supplied.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure

limits Lower flammability or explosive limits

Vapour pressure < 0.0000013 Pa @ 25 °C Vapour density Relative density 1.160 @ 20 °C Water solubility 0.0028 g/l @ 20 °C Solubility(ies) Not determined. Partition coefficient log Pow = 4.1 @ 25 °C Autoignition temperature Not auto-flammable °C Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic viscosity Not determined

_____________________________________________________________________________________________

Page 6 / 12


Product Information .

Symptoms related to the physical, chemical and toxicological characteristics


Numerical measures of toxicity

Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 50,000.00 mg/kg ATEmix (inhalation-dust/mist) 250.50 mg/l

Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50

2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-

yl)phenyl]butan-1-one

> 2000 mg/kg ( Rat ) > 2000 mg/kg ( Rat )

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Based on available data, the classification criteria are not met. Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 404: Acute Dermal Irritation/Corrosion Species Rabbit Exposure route Dermal Effective dose 0.5 g Exposure time 4 hours Results Erythema 0 edema non-irritant

Serious eye damage/eye irritation Based on available data, the classification criteria are not met. Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 405: Acute Eye Irritation/Corrosion Species Rabbit Exposure route Eye Effective dose 0.1 g Exposure time Single exposure Results non-irritant

Respiratory or skin sensitisation Based on available data, the classification criteria are not met. Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 406: Skin Sensitisation Species Guinea pig Exposure route Dermal Results Not a skin sensitiser

Germ cell mutagenicity Based on available data, the classification criteria are not met. Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 476: In vitro Mammalian Cell Gene Mutation Test Species in vitro

_____________________________________________________________________________________________

Page 7 / 12


Results Negative

Carcinogenicity Based on available data, the classification criteria are not met.

Reproductive toxicity Classification based on data available for ingredients.

Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 421: Reproduction/Developmental Toxicity Screening Test Species Rat Results NOEL (No observed effect level) 60 mg/kg bw/d

STOT - single exposure Based on available data, the classification criteria are not met.

STOT - repeated exposure Based on available data, the classification criteria are not met. Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 407: Repeated Dose 28-day Oral Toxicity Study in Rodents Species Rat Exposure route Oral Exposure time 28 days Results NOEL (No observed effect level) 15 mg/kg bw/d

SECTION 12: Ecological information

12.1. Toxicity

Ecotoxicity Very toxic to aquatic life with long lasting effects.

Chemical name Algae/aquatic plants Fish Toxicity to microorganisms

Crustacea

2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]

butan-1-one

EC50: > 100 mg/l (72h, Desmodesmus subspicatus)

LC50: > 100 mg/l (96h, Danio rerio)

EC50: > 100 mg/l (3h, Activated sludge)

EC50: > 100 mg/l (48h, Daphnia magna)NOEC = 64 µg/L

(21d,Daphnia Magna)

12.2. Persistence and degradability

Persistence and degradability No information available.

Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4)

Method Exposure time Value Results OECD Test No. 301B: Ready

Biodegradability: CO2 Evolution Test (TG 301 B)

28 days Biodegradation -7.4% Not readily biodegradable

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product.

Bioconcentration factor (BCF) No data available

Component Information

Chemical name Partition coefficient Bioconcentration factor (BCF) 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[ 4.1 689 - 758

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Page 8 / 12


4-(morpholin-4-yl)phenyl]butan-1-one

12.4. Mobility in soil

Mobility in soil No information available.

Chemical name Surface tension Henry’s Law Constant Adsorption coefficient 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]but

an-1-one 119344-86-4

70.4 mN/m @ 20 °C 2.23 x 10 -7 Pa m3/mol log Koc = 3.5

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment

Chemical name PBT and vPvB assessment 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phe

nyl]butan-1-one The substance is not PBT / vPvB

12.6. Other adverse effects

Other adverse effects No information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste from residues/unused products

Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.

Contaminated packaging Do not reuse empty containers.

SECTION 14: Transport information

IMDG 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9 14.4 Packing group III

Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III, Marine pollutant

14.5 Marine pollutant Not applicable Environmental hazards Yes

14.6 Special Provisions 274, 335, 966, 967, 969 EmS-No F-A, S-F

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

No information available

RID 14.1 UN number UN3077 14.2 UN proper shipping name

_____________________________________________________________________________________________

Page 9 / 12

ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.


14.3 Transport hazard class(es) 9 Labels 9

14.4 Packing group III Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.

(2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III

14.5 Environmental hazards Yes 14.6 Special Provisions None

Classification code M7

ADR 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9

Labels 9 14.4 Packing group III

Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III

14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601, 375


ADN 14.1 UN/ID no UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9

Hazard label(s) 9 14.4 Packing group III

Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III

14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601

IATA 14.1 UN number UN3077 14.2 UN proper shipping name Environmentally hazardous substances, solid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III

Description UN3077, Environmentally hazardous substances, solid, n.o.s. (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III


ERG Code 9L

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations

France Occupational Illnesses (R-463-3, France)

Germany Water hazard class (WGK) slightly hazardous to water (WGK 1)

_____________________________________________________________________________________________

Page 10 / 12


European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work

Authorisations and/or restrictions on use:This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)

Persistent Organic PollutantsNot applicable

Dangerous substance category per Seveso Directive (2012/18/EU)E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1

Named dangerous substances per Seveso Directive (2012/18/EU)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable

International Inventories

Chemical name

TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS TCSI NZIoC

2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one 119344-86-4

X X - - - - X X - X X X

Please note that the presence of a substance on an Inventory is not an indication that the substance can be supplied to that country. Additional registration (REACH, K-REACH, ...) might be required.

Legend:

X - Listed TSCA - Toxic Substances Control Act Frank R. Lautenberg Chemical Safety for the 21st Century Act (active rule) DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals TCSI - Taiwan Chemical Substance Inventory

15.2. Chemical safety assessment

Chemical Safety Report A Chemical Safety Assessment has been carried out for this substance

SECTION 16: Other information

Key or legend to abbreviations and acronyms used in the safety data sheet

_____________________________________________________________________________________________

Page 11 / 12

Full text of H-Statements referred to under section 3H361 - Suspected of damaging fertility or the unborn child


H410 - Very toxic to aquatic life with long lasting effects Legend SVHC: Substances of Very High Concern for Authorisation:

Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme Organisation for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization

Issuing Date 09-Jun-2020

Revision date 09-Jun-2020

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value *

_____________________________________________________________________________________________

Page 12 / 12

Skin designation



Issuing Date 23-Jan-2020 Revision date 23-Jan-2020 Revision Number 1


Product Code(s) 10000219 10000220 Product Name Omnirad OMBB


EC No 210-112-3

CAS No 606-28-0

Chemical name Methyl 2-benzoylbenzoate


Formula C15H12O3

Molecular weight 240.3


Recommended use Photoinitiator.Production of UV inks, coatings and adhesives.For use in industrial installations or professional treatment only.




Emergency Telephone (EMEA) +1 760 476 3961 ## 333 293

Emergency Telephone - §45 - (EC)1272/2008 Europe 112


2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008


_____________________________________________________________________________________________


_____________________________________________________________________________________________ OROMBB - Omnirad OMBB Revision date 23-Jan-2020

Specific target organ toxicity — repeated exposure Category 2 - (H373) Chronic aquatic toxicity Category 2 - (H411)

2.2. Label elements

Signal wordWarning

Hazard statements H373 - May cause damage to organs through prolonged or repeated exposureH411 - Toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)P273 - Avoid release to the environmentP314 - Get medical advice/attention if you feel unwellP391 - Collect spillageP501 - Dispose of contents/ container to an approved waste disposal plant




3.1 Substances


1272/2008 [CLP]

REACH registration

number Methyl 2-benzoylbenzoate 210-112-3 606-28-0 > 99% STOT RE 2 (H373)

Aquatic Chronic 2 (H411) 01-2120103325-72

-XXXX






Skin contact Wash skin with soap and water. In the case of skin irritation or allergic reactions see a doctor.

_____________________________________________________________________________________________

Page 2 / 12






Note to doctors Treat symptomatically.






No information available.







Personal precautions Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas.

Other information Refer to protective measures listed in Sections 7 and 8.










_____________________________________________________________________________________________

Page 3 / 12




Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation.

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.


Storage Conditions Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.





Exposure Limits .




Derived No Effect Level (DNEL) Methyl 2-benzoylbenzoate (606-28-0) Type Worker Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.367 mg/m³ Safety factor 75

Type Worker Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.104 mg/kg bw/d Safety factor 300 Derived No Effect Level (DNEL) General Population

Derived No Effect Level (DNEL) Methyl 2-benzoylbenzoate (606-28-0) Type General Population Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.184 mg/m³ Safety factor 150

Type General Population Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.052 mg/kg bw/d Safety factor 600

Type General Population Long term Systemic health effects Exposure route Oral

_____________________________________________________________________________________________

Page 4 / 12


Derived No Effect Level (DNEL) 0.052 mg/kg bw/d Safety factor 600


.

Predicted No Effect Concentration (PNEC) Methyl 2-benzoylbenzoate (606-28-0) Environmental compartment Predicted No Effect Concentration (PNEC) Freshwater 9.16 µg/l Marine water 0.916 µg/l Microorganisms in sewage treatment 10 mg/l Freshwater sediment 0.219 mg/kg dry weight Marine sediment 0.022 mg/kg dry weight Soil 0.041 mg/kg dry weight Air No hazard identified



Eye/face protection Eye protection must conform to standard EN 166.

Hand protection Gloves must conform to standard EN 374.


Nitrile rubber 0.4 mm 4 hours Butyl rubber 0.4 mm 4 hours

Skin and body protection No special protective equipment required.





9.1. Information on basic physical and chemical properties Physical state Solid Appearance crystalline, Powder. Colour white, off-white. Odour Odourless. Odour threshold Not determined

Property Values Remarks • Method pH Not applicable Melting point / freezing point 48 - 54 °C Boiling point / boiling range 360 °C @97.2 kPa Flash point 154 °C Evaporation rate Not determined Flammability (solid, gas) Not determined Flammability Limit in Air

Upper flammability or explosive

_____________________________________________________________________________________________

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9.2. Other information Softening point Not determined Molecular weight 240.3 VOC Content (%) No information available Liquid Density Not determined Bulk density Not determined


10.1. Reactivity


















limits Lower flammability or explosive limits

Vapour pressure 0 @ 20 °C Vapour density Relative density 1.228 @ 20 °C Water solubility 0.1177 g/L @ 20 °C Solubility(ies) Not determined. Partition coefficient 2.8 Autoignition temperature Not determined Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic viscosity Not determined

_____________________________________________________________________________________________

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Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document ATEmix (inhalation-dust/mist) 501.00 mg/l


Methyl 2-benzoylbenzoate > 2000 mg/kg bw (rat) > 2000 mg/kg bw (rat)


Skin corrosion/irritation Based on available data, the classification criteria are not met. Component Information Methyl 2-benzoylbenzoate (606-28-0) Method OECD 439 Species EPISKIN™ Exposure route in vitro Exposure time 4 hours Results non-irritant

Serious eye damage/eye irritation Based on available data, the classification criteria are not met. Component Information Methyl 2-benzoylbenzoate (606-28-0) Method OECD Test No. 405: Acute Eye Irritation/Corrosion Species Rabbit Exposure route Eye Effective dose 0.1 g Exposure time Single exposure Results non-irritant

Respiratory or skin sensitisation Based on available data, the classification criteria are not met. Component Information Methyl 2-benzoylbenzoate (606-28-0) Method OECD Test No. 429: Skin Sensitisation: Local Lymph Node Assay Species Mouse Exposure route Dermal Results Not a skin sensitiser

Germ cell mutagenicity Based on available data, the classification criteria are not met.


Reproductive toxicity Based on available data, the classification criteria are not met.

The table below indicates ingredients above the cut-off threshold considered as relevant which are listed as reproductive toxins. Component Information Methyl 2-benzoylbenzoate (606-28-0) Method OECD Test No. 422: Combined Repeated Dose Toxicity Study with the

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Reproduction/Developmental Toxicity Screening Test Species Rat Results Reproductive toxicity NOAEL 500 mg/kg bw/d


STOT - repeated exposure May cause damage to organs. Component Information Methyl 2-benzoylbenzoate (606-28-0) Method OECD Test No. 422: Combined Repeated Dose Toxicity Study with the

Reproduction/Developmental Toxicity Screening Test Species Rat Exposure route Oral gavage Effective dose 31.25, 125, or 500 mg/kg bw/d Exposure time 30 days Results NOAEL 31.25 mg/kg bw/d


12.1. Toxicity

Ecotoxicity The environmental impact of this product has not been fully investigated.


Crustacea

Methyl 2-benzoylbenzoate

ErC50 = 29.7 mg/l ErC10 = 12.4 mg/L (72h,

Desmodesmus subspicatus)

LC50 = 9.16 mg/l (96h, Danio rerio)

EC50 = 1000 mg/l EC10 = 100 mg/L (3h,

activated sludge)

EC50 = 26.8 mg/l (48h, Daphnia magna)



Component Information Methyl 2-benzoylbenzoate (606-28-0)

Method Exposure time Value Results OECD Test No. 301F: Ready Biodegradability: Manometric Respirometry Test (TG 301 F)

28 days 0 Not readily biodegradable





Chemical name Partition coefficient Bioconcentration factor (BCF) Methyl 2-benzoylbenzoate 2.8



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Chemical name Surface tension Henry’s Law Constant Adsorption coefficient Methyl 2-benzoylbenzoate

606-28-0 0.001 Pa m³/mol @ 25 °C LogKoc: 2.6



Chemical name PBT and vPvB assessment Methyl 2-benzoylbenzoate The substance is not PBT / vPvB










Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Methyl 2-benzoylbenzoate), 9, III, Marine pollutant





RID 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9


Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Methyl 2-benzoylbenzoate), 9, III



ADR 14.1 UN number UN3077 14.2 UN proper shipping name

_____________________________________________________________________________________________

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ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.


14.3 Transport hazard class(es) 9 Labels 9

14.4 Packing group III Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Methyl

2-benzoylbenzoate), 9, III 14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601, 375




Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Methyl 2-benzoylbenzoate), 9, III

14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601


Description UN3077, Environmentally hazardous substances, solid, n.o.s. (Methyl 2-benzoylbenzoate), 9, III


ERG Code 9L





Germany Water hazard class (WGK) hazardous to water (WGK 2)

European Union


Authorisations and/or restrictions on use:This product contains one or more substance(s) subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)


Dangerous substance category per Seveso Directive (2012/18/EU)E2 - Hazardous to the Aquatic Environment in Category Chronic 2


_____________________________________________________________________________________________

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Chemical name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS TCSI NZIoC Methyl 2-benzoylbenzoate 606-28-0

X X X X X X X X X


Legend:






Full text of H-Statements referred to under section 3H225 - Highly flammable liquid and vapourH301 - Toxic if swallowedH304 - May be fatal if swallowed and enters airwaysH311 - Toxic in contact with skinH315 - Causes skin irritationH331 - Toxic if inhaledH336 - May cause drowsiness or dizzinessH361d - Suspected of damaging the unborn childH370 - Causes damage to organsH373 - May cause damage to organs through prolonged or repeated exposureH411 - Toxic to aquatic life with long lasting effects

Legend SVHC: Substances of Very High Concern for Authorisation:


Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR)

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value * Skin designation

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U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme Organisation for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization

Issuing Date 23-Jan-2020

Revision date 23-Jan-2020




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Issuing Date 12-Aug-2019 Revision date 22-Jul-2020 Revision Number 2.01


Product Code(s) 10000221

Product Name Omnirad TPO


EC No 278-355-8

CAS No 75980-60-8

Chemical name diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide



Recommended use Photoinitiator.

Uses advised against None known.



Emergency Telephone (EMEA) +1 760 476 3961 ## 333 293 Emergency Telephone §45 - (EC)1272/2008 Europe 112


2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Skin sensitisation Category 1B - (H317) Reproductive toxicity Category 2 - (H361) Chronic aquatic toxicity Category 2 - (H411)

2.2. Label elements

SupplierIGM Resins B.V Gompenstraat 49 5145 RM Waalwijk The Nederlands T: +31 (0) 416 316 657 F: +31 (0) 416 564 632

_____________________________________________________________________________________________


_____________________________________________________________________________________________ ORTPO - Omnirad TPO Revision date 22-Jul-2020

Signal wordWarning

Hazard statements H317 - May cause an allergic skin reactionH361 - Suspected of damaging fertility or the unborn childH411 - Toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP272 - Contaminated work clothing should not be allowed out of the workplaceP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of water and soapP308 + P313 - IF exposed or concerned: Get medical advice/attentionP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP391 - Collect spillageP405 - Store locked upP501 - Dispose of contents/ container to an approved waste disposal plant



Important health, safety and environmental informationThe classification as Repr. 2 (H361) is the harmonized classification as mentioned in Annex VI of Regulation (EC) No. 1272/2008. Test data mentioned in section 11 of this SDS however prove that classification as Repr. 1B (H360) is more suitable. IGM has updated the REACH dossier and requested that the Swedish authority start the process of amending the harmonized classification. This SDS was updated according to guidance of the Swedish Chemicals Agency.


3.1 Substances


1272/2008 [CLP]

REACH registration

number Diphenyl(2,4,6-trimethylbenzoyl)phos

phine oxide 278-355-8 75980-60-8 >99% Skin Sens. 1B (H317)

Repr. 2 (H361) Aquatic Chronic 2 (H411)

01-2119972295-29-XXXX


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Skin contact Wash with soap and water. May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a doctor.



Symptoms Itching. Rashes. Hives.


Note to doctors May cause sensitisation in susceptible persons. Treat symptomatically.






Product is or contains a sensitiser. May cause sensitisation by skin contact.







Personal precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.



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Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash it before reuse. Remove contaminated clothing and shoes.



Storage Conditions Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store locked up. Keep out of the reach of children.





Exposure Limits .




Derived No Effect Level (DNEL) Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Type Worker Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.822 mg/m³

Type Worker Long term Systemic health effects

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Exposure route Dermal Derived No Effect Level (DNEL) 0.233 mg/kg bw/d Derived No Effect Level (DNEL) General Population

Derived No Effect Level (DNEL) Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Type General Population Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.145 mg/m³

Type General Population Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.0833 mg/kg bw/d

Type General Population Long term Systemic health effects Exposure route Oral Derived No Effect Level (DNEL) 0.0833 mg/kg bw/d


.

Predicted No Effect Concentration (PNEC) Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Environmental compartment Predicted No Effect Concentration (PNEC) Freshwater 1.4 µg/l Marine water 0.14 µg/l Freshwater - intermittent 14 µg/l Marine water - intermittent 1.4 µg/l Freshwater sediment 0.115 mg/kg Marine sediment 0.0115 mg/kg Soil 0.0222 mg/kg



Eye/face protection Wear safety glasses with side shields (or goggles). Eye protection must conform to standard EN 166.



Nitrile rubber 0.4 mm 4 hours Butyl rubber 0.4 mm 4 hours





_____________________________________________________________________________________________

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9.1. Information on basic physical and chemical properties Physical state Solid Appearance Powder. Colour yellow. Odour Not determined. Odour threshold Not determined

9.2. Other information Softening point Not determined Molecular weight Not determined VOC Content (%) No information available Liquid Density Not determined Bulk density Not determined


10.1. Reactivity









Property Values Remarks • Method pH Not applicable Melting point / freezing point 93 °C Boiling point / boiling range > 200 °C Flash point Not applicable Evaporation rate Not determined Flammability (solid, gas) Not determined Flammability Limit in Air

Upper flammability or explosive limits

unknown

Lower flammability or explosive limits

Vapour pressure 0 hPa @ 20 °C Vapour density Relative density 1.218 @ 20 °C Water solubility 0.0119 g/l @ 20 °C Solubility(ies) Not determined. Partition coefficient log Pow = 3.1 @ 23 °C Autoignition temperature > 400 °C Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic viscosity Not determined

_____________________________________________________________________________________________

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Skin contact May cause sensitisation by skin contact. Specific test data for the substance or mixture is not available. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. (based on components).




Acute toxicity


Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide

> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rat )


Skin corrosion/irritation Based on available data, the classification criteria are not met. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Species Rabbit Exposure route Dermal Effective dose 0.5 g Exposure time 24 hours Results Erythema 0 edema non-irritant

Serious eye damage/eye irritation Based on available data, the classification criteria are not met. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Species Rabbit Exposure route Eye Effective dose 0.056 g Exposure time 5 days Results non-irritant

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Respiratory or skin sensitisation May cause sensitisation by skin contact. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Method OECD Test No. 429: Skin Sensitisation: Local Lymph Node Assay Species Mouse Exposure route Dermal Results Sensitising

Germ cell mutagenicity Based on available data, the classification criteria are not met. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Method OECD Test No. 471: Bacterial Reverse Mutation Test Species in vitro Results Negative

Method OECD Test No. 473: In vitro Mammalian Chromosome Aberration Test Species in vitro Results Negative


Reproductive toxicity Classification based on data available for ingredients.

The table below indicates ingredients above the cut-off threshold considered as relevant which are listed as reproductive toxins. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Method OECD Test No. 414: Pre-natal Development Toxicity Study Species Rat Results Developmental toxicity NOAEL 150 mg/kg bw/d

Method OECD Test No. 421: Reproduction/Developmental Toxicity Screening Test Species Rat Results Reproductive toxicity NOAEL 60 mg/kg bw/d

Method OECD Test No. 421: Reproduction/Developmental Toxicity Screening Test Species Rat Results Developmental toxicity NOAEL 200 mg/kg bw/d

Method OECD Test No. 421: Reproduction/Developmental Toxicity Screening Test Species Rat Results Parental NOAEL 200 mg/kg bw/d

Chemical name European Union Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide Repr. 2


STOT - repeated exposure Based on available data, the classification criteria are not met. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Method OECD Test No. 408: Repeated Dose 90-Day Oral Toxicity Study in Rodents Species Rat Exposure route Oral Results NOAEL 100 mg/kg bw/d

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12.1. Toxicity



Crustacea


EC50 > 2.01 mg/l (72h, Pseudokirchneriella

subcapitata) EC10 = 1.56 mg/l (72h,

Pseudokirchneriella subcapitata)

LC50 = 6.53 mg/l (48h, Oryzias latipes)

EC50 > 1000 mg/l (3h, Activated sludge)




Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8)


28 days Biodegradation 0 - 10% Not readily biodegradable





Chemical name Partition coefficient Bioconcentration factor (BCF) Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide 3.1 18 - 72



Chemical name Surface tension Henry’s Law Constant Adsorption coefficient Diphenyl(2,4,6-trimethylbenzoyl)phosp

hine oxide 75980-60-8

0 Pa m³/mol @ 25 °C log Koc = 784.8



Chemical name PBT and vPvB assessment Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide The substance is not PBT / vPvB



_____________________________________________________________________________________________

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Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III, Marine pollutant





RID 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9


Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III



ADR 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9


Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III




Hazard label(s) 9

_____________________________________________________________________________________________

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14.4 Packing group III Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.

(Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide), 9, III 14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601


Description UN3077, Environmentally hazardous substances, solid, n.o.s. (Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III


ERG Code 9L






European Union








Chemical name

TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS TCSI NZIoC


X X - X - X X X X X X X

_____________________________________________________________________________________________

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75980-60-8


Legend:






Full text of H-Statements referred to under section 3H317 - May cause an allergic skin reactionH361 - Suspected of damaging fertility or the unborn childH411 - Toxic to aquatic life with long lasting effects Legend SVHC: Substances of Very High Concern for Authorisation:


Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme Organisation for Economic Co-operation and Development Screening Information Data Set


_____________________________________________________________________________________________

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Skin designation


RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization

Issuing Date 12-Aug-2019

Revision date 22-Jul-2020




_____________________________________________________________________________________________

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Issuing Date 12-Feb-2021 Revision date 15-Oct-2020 Revision Number 1.01


Product Code(s) 10000222 10000223

Product Name Omnirad TPO-L


EC No 282-810-6

CAS No 84434-11-7

Chemical name Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate


Molecular weight 316.4 g/mol


Recommended use Photoinitiator.For use in industrial installations or professional treatment only.




Emergency Telephone (GB) +44 20 35147487 ## 333 293 TF (UK) 0 800 680 0425 ## 333 293

Emergency Telephone §45 - (EC)1272/2008 Europe 112


2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Skin sensitisation Category 1B - (H317)

SupplierIGM Resins B.V. Gompenstraat 49 5145 RM Waalwijk The Netherlands T: +31 (0) 416 316 657 F: +31 (0) 416 564 632

_____________________________________________________________________________________________


_____________________________________________________________________________________________ ORTPO-L - Omnirad TPO-L Revision date 15-Oct-2020

Chronic aquatic toxicity Category 2 - (H411)

2.2. Label elements

Signal wordWarning

Hazard statements H317 - May cause an allergic skin reactionH411 - Toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)P272 - Contaminated work clothing should not be allowed out of the workplaceP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of water and soapP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP391 - Collect spillageP501 - Dispose of contents/ container to an approved waste disposal plant



3.1 Substances


1272/2008 [CLP]

REACH registration

number Ethyl

phenyl(2,4,6-trimethylbenzoyl)phosphinate

282-810-6 84434-11-7 >98% Skin Sens. 1B (H317) Aquatic Chronic 2 (H411)

01-2119987994-10-XXXX






Skin contact Wash with soap and water. May cause an allergic skin reaction. In the case of skin irritation

_____________________________________________________________________________________________

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or allergic reactions see a doctor.




























_____________________________________________________________________________________________

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Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash it before reuse.



Storage Conditions Store locked up. Keep out of the reach of children. Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.


Identified Uses Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

SECTION 8: Exposure controls/personal protection


Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.



Derived No Effect Level (DNEL) Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Type Worker Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 5.88 mg/m³


Derived No Effect Level (DNEL) Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Type General Population Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.87 mg/m³


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Predicted No Effect Concentration (PNEC) Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Environmental compartment Predicted No Effect Concentration (PNEC) Freshwater 0.001 mg/l Freshwater - intermittent 0.035 mg/l Marine water 0 mg/l Freshwater sediment 0.24 mg/kg Marine sediment 0.024 mg/kg Soil 0.047 mg/kg



Eye/face protection Wear safety glasses with side shields (or goggles). Eye protection must conform to standard EN 166.



Nitrile rubber 0.4 mm 60 minutes Butyl rubber 0.4 mm 60 minutes






9.1. Information on basic physical and chemical properties Physical state Liquid Appearance viscous. Colour yellow. Odour Not determined. Odour threshold Not determined

Property Values Remarks • Method pH No data available pH (as aqueous solution) 3.2 - 4.3 solution 35 mg/L Melting point / freezing point -12 °C Boiling point / boiling range 257.4 °C Flash point 144 °C CC (closed cup) Evaporation rate Not determined Flammability (solid, gas) Not determined

_____________________________________________________________________________________________

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9.2. Other information Softening point Not determined Molecular weight 316.4 g/mol VOC Content (%) No information available Liquid Density Not determined Bulk density Not determined


10.1. Reactivity
















Flammability Limit in Air Upper flammability or explosive limits Lower flammability or explosive limits

Vapour pressure 0 hPa @ 20 °C Vapour density Relative density 1.13 @ 20 °C Water solubility 0.035 g/L @ 20 °C Solubility(ies) 71.8 g/L.

Organic solvents.

Partition coefficient log Pow = 2.91 @ 25 °C Autoignition temperature 423 °C Decomposition temperature Kinematic viscosity Not determined Dynamic viscosity 1483 mPa s @ 20 °C

_____________________________________________________________________________________________

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Product Information

Skin contact May cause sensitisation by skin contact. Specific test data for the substance or mixture is not available. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. (based on components).




Acute toxicity


Ethyl phenyl(2,4,6-trimethylbenzoyl)p

hosphinate 84434-11-7

> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rat )


Skin corrosion/irritation Based on available data, the classification criteria are not met.

Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 404: Acute Dermal Irritation/Corrosion Species Rabbit Exposure route Dermal Effective dose 0.5 mL Exposure time 4 hours Results Erythema edema 0 non-irritant

Serious eye damage/eye irritation Based on available data, the classification criteria are not met.

Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 405: Acute Eye Irritation/Corrosion Species Rabbit Exposure route Eye Effective dose 0.1 mL Exposure time 24 hours Results non-irritant

Respiratory or skin sensitisation May cause sensitisation by skin contact.

Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 429: Skin Sensitisation: Local Lymph Node Assay Species Mouse Exposure route Injection Results Sensitising

_____________________________________________________________________________________________

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Germ cell mutagenicity Based on available data, the classification criteria are not met.

Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 471: Bacterial Reverse Mutation Test Species in vitro Results Not mutagenic



Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 414: Pre-natal Development Toxicity Study Species Rat Results NOAEL 300 mg/kg bw/d

Developmental toxicity Based on available data, the classification criteria are not met.


STOT - repeated exposure Based on available data, the classification criteria are not met.

Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 407: Repeated Dose 28-day Oral Toxicity Study in Rodents Species Rat Exposure route Oral Exposure time 28 days Results NOAEL >= 500 mg/kg bw/d


12.1. Toxicity


Product Information Chemical name Algae/aquatic plants Fish Toxicity to

microorganisms Crustacea

Ethyl phenyl(2,4,6-trimethylben

zoyl)phosphinate

EC50 = 1.01 mg/l (72h, Desmodesmus subspicatus)

LC50 = 1.89 mg/l (96h, Danio rerio)

EC50 > 1000 mg/l (3h, Activated sludge)






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Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7)



28 days Biodegradation <10% Not readily biodegradable





Chemical name Partition coefficient Bioconcentration factor (BCF) Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate 2.91



Chemical name Surface tension Henry’s Law Constant Adsorption coefficient Ethyl

phenyl(2,4,6-trimethylbenzoyl)phosphinate

84434-11-7

log Koc = 3.37 @ 26 °C



Chemical name PBT and vPvB assessment Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate The substance is not PBT / vPvB









IMDG 14.1 UN number or ID number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9 14.4 Packing group III

Description

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UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III, Marine pollutant



14.6 Special Provisions 274, 335, 969 EmS-No F-A, S-F



RID 14.1 UN number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9


Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III



ADR 14.1 UN number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9




Classification code M6 Tunnel restriction code (-)

ADN 14.1 UN/ID no UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9




IATA 14.1 UN number or ID number UN3082 14.2 UN proper shipping name Environmentally hazardous substances, liquid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III

Description UN3082, Environmentally hazardous substances, liquid, n.o.s. (Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III


ERG Code 9L




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European Union







Chemical name

AICS DSL NDSL EINECS ELINCS ENCS IECSC KECL NZIoC PICCS TCSI TSCA

Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate 84434-11-7

x X - X - - X X X - X X


Legend:

X - Listed CBI - Confidential Business Information EU-LVE - Low Volume exemption < 1T LCP - Low concern polymer PMN - indicates a commenced PMN substance S - indicates a substance that is identified in a final Significant New Use Rule US-LVE - Low volume exemption < 10 T annually of the active substance US-PE - Polymer Exemption

AICS - Australian Inventory of Chemical Substances DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals PICCS - Philippines Inventory of Chemicals and Chemical Substances TCSI - Taiwan Chemical Substance Inventory TSCA - Toxic Substances Control Act Frank R. Lautenberg Chemical Safety for the 21st Century Act (active rule)

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Classification procedure Classification according to Regulation (EC) No. 1272/2008 [CLP] Method Used Acute oral toxicity Calculation method Acute dermal toxicity Calculation method Acute inhalation toxicity - gas Calculation method Acute inhalation toxicity - Vapour Calculation method Acute inhalation toxicity - dust/mist Calculation method Skin corrosion/irritation Calculation method Serious eye damage/eye irritation Calculation method Respiratory sensitisation Calculation method Mutagenicity Calculation method Carcinogenicity Calculation method Reproductive toxicity Calculation method STOT - single exposure Calculation method STOT - repeated exposure Calculation method Acute aquatic toxicity Calculation method Chronic aquatic toxicity Calculation method Aspiration hazard Calculation method Ozone Calculation method Health hazards not otherwise classified (HHNOC) Calculation method

Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australian National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme Organisation for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value * Skin designation

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Issuing Date 12-Feb-2021

Revision date 15-Oct-2020




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Issuing Date 09-Dec-2019 Revision date 09-Dec-2019 Revision Number 1


Product Code(s) 10000300 10000301 Product Name Photomer 4012

REACH registration number 01-2119957862-25-XXXX

EC No 227-561-6

CAS No 5888-33-5

Chemical name Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate

Synonyms Isobornyl acrylate (IBOA)


Molecular weight 208.30 g/mol


Recommended use Monomer.Reactive.Production of UV inks, coatings and adhesives.For use in industrial installations or professional treatment only.

Uses advised against Consumer use.Nail polish/lacquer.Skin contact.



Emergency Telephone (EMEA) +1 760 476 3961 ## 333 293

Emergency Telephone - §45 - (EC)1272/2008 Europe 112



_____________________________________________________________________________________________


_____________________________________________________________________________________________ PH4012 - Photomer 4012 Revision date 09-Dec-2019

2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Skin corrosion/irritation Category 2 - (H315) Serious eye damage/eye irritation Category 2 - (H319) Skin sensitisation Category 1 - (H317) Specific target organ toxicity — single exposure Category 3 - (H335) Acute aquatic toxicity Category 1 - (H400) Chronic aquatic toxicity Category 1 - (H410)

2.2. Label elements

Signal wordWarning

Hazard statements H315 - Causes skin irritationH317 - May cause an allergic skin reactionH319 - Causes serious eye irritationH335 - May cause respiratory irritationH410 - Very toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)P264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of water and soapP304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathingP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingP312 - Call a POISON CENTER or doctor if you feel unwellP332 + P313 - If skin irritation occurs: Get medical advice/attentionP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP337 + P313 - If eye irritation persists: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP391 - Collect spillageP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP405 - Store locked upP501 - Dispose of contents/ container to an approved waste disposal plant



3.1 Substances


REACH registration

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1272/2008 [CLP] number Exo-1,7,7-trimethylbicyclo[2.2.1]hept-

2-yl acrylate 227-561-6 5888-33-5 > 98% Skin Irrit. 2 (H315)

Eye Irrit. 2 (H319)Skin Sens. 1 (H317)STOT SE 3 (H335)

Aquatic Acute 1 (H400)Aquatic Chronic 1 (H410)

01-2119957862-25-XXXX





Inhalation Remove to fresh air. IF exposed or concerned: Get medical advice/attention. Get medical attention immediately if symptoms occur.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Do not rub affected area.

Skin contact May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a doctor. Wash off immediately with soap and plenty of water for at least 15 minutes.

Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a doctor.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section 8).


Symptoms Itching. Rashes. Hives. Burning sensation.











Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout

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fire-fighters gear. Use personal protection equipment.




Other information Refer to protective measures listed in Sections 7 and 8.



Environmental precautions Prevent further leakage or spillage if safe to do so.









Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash it before reuse. Avoid breathing vapours or mists.

General hygiene considerations Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. Avoid contact with skin, eyes or clothing.


Storage Conditions Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store locked up. Keep out of the reach of children.





Exposure Limits .

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Derived No Effect Level (DNEL) Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Type Worker Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 4.9 mg/m³


Derived No Effect Level (DNEL) Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Type General Population Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 1.45 mg/m³




.

Predicted No Effect Concentration (PNEC) Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Environmental compartment Predicted No Effect Concentration (PNEC) Freshwater 0.007 mg/l Marine water 0 mg/l Microorganisms in sewage treatment 2 mg/l Freshwater sediment 0.145 mg/kg dry weight Marine sediment 0.015 mg/kg dry weight Soil 0.029 mg/kg dry weight



Eye/face protection Wear safety glasses with side shields (or goggles). If splashes are likely to occur, wear safety glasses with side-shields. Eye protection must conform to standard EN 166.

Hand protection Wear suitable gloves. Impervious gloves. Gloves must conform to standard EN 374.

Skin and body protection Wear suitable protective clothing. Long sleeved clothing.


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General hygiene considerations Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. Avoid contact with skin, eyes or clothing.



9.1. Information on basic physical and chemical properties Physical state Liquid Colour colourless. Odour Ester. Odour threshold Not determined

9.2. Other information Softening point Not determined Molecular weight 208.30 g/mol VOC Content (%) No information available Liquid Density Not determined Bulk density Not determined


10.1. Reactivity





Property Values Remarks • Method pH Not determined Melting point / freezing point < -20 °C Boiling point / boiling range 275 °C Flash point 104 °C Pensky-Martens Closed Cup (PMCC) Evaporation rate Not determined Flammability (solid, gas) Not determined Flammability Limit in Air

Upper flammability or explosive limits Lower flammability or explosive limits

Vapour pressure 0.013 hPa @ 20 °C Vapour density Relative density 0.99 @ 25 °C Water solubility 19.8 mg/l @ 20 °C Solubility(ies) Not determined. Partition coefficient 4.52 Autoignition temperature 375 °C @10088 kPa Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic viscosity 7.5 - 9.5 mPa s

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@ 20 °C






Conditions to avoid None known based on information supplied.


Incompatible materials Strong acids. Strong bases. Strong oxidising agents.







Inhalation Specific test data for the substance or mixture is not available. May cause irritation of respiratory tract.

Eye contact Specific test data for the substance or mixture is not available. Irritating to eyes. (based on components). Causes serious eye irritation.

Skin contact May cause sensitisation by skin contact. Specific test data for the substance or mixture is not available. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. (based on components). Causes skin irritation.

Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.


Symptoms Itching. Rashes. Hives. Redness. May cause redness and tearing of the eyes.


Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 4,964.50 mg/kg ATEmix (dermal) 5,081.20 mg/kg


Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate

= 4350 mg/kg ( Rat ) > 3000 mg/kg ( Rabbit )


Skin corrosion/irritation Classification based on data available for ingredients. Irritating to skin.

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Serious eye damage/eye irritation Classification based on data available for ingredients. Causes serious eye irritation.

Respiratory or skin sensitisation May cause sensitisation by skin contact. Component Information Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Method OECD Test No. 429: Skin Sensitisation: Local Lymph Node Assay Species Mouse Exposure route Dermal Results Sensitising

Germ cell mutagenicity Based on available data, the classification criteria are not met. Component Information Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Method OECD Test No. 471: Bacterial Reverse Mutation Test Species in vitro Results Not mutagenic

Method OECD Test No. 476: In vitro Mammalian Cell Gene Mutation Test Species in vitro Results Not mutagenic

Method OECD Test No. 487: In Vitro Mammalian Cell Micronucleus Test Species in vitro Results Not mutagenic



Component Information Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Method OECD Test No. 422: Combined Repeated Dose Toxicity Study with the

Reproduction/Developmental Toxicity Screening Test Species Rat Results Parental NOAEL 100 mg/kg bw/d

Method OECD Test No. 415: One-Generation Reproduction Toxicity Study Species Rat Results NOAEL 300 mg/kg bw/d

STOT - single exposure May cause respiratory irritation.

STOT - repeated exposure Based on available data, the classification criteria are not met. Component Information Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Method OECD Test No. 422: Combined Repeated Dose Toxicity Study with the

Reproduction/Developmental Toxicity Screening Test Species Rat Exposure route Oral Effective dose 25/100/500 mg/kg bw/d Results NOAEL 100 mg/kg bw/d

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12.1. Toxicity

Ecotoxicity Very toxic to aquatic life with long lasting effects.


Crustacea

Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate

EC50 = 1.98 mg/L (72h, Pseudokirchneriella

subcapitata) NOEC = 0.405 mg/L

(72h, Pseudokirchneriella subcapitata)

LC50 = 0.704 mg/L (96h, Danio rerio)

- NOEC = 0.092 mg/L (21d, Daphnia magna)



Component Information Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5)

Method Exposure time Value Results OECD Test No. 310: Ready

Biodegradability - CO2 in Sealed Vessels (Headspace Test)

28 days 57% Biodegradation Not readily biodegradable







Chemical name Surface tension Henry’s Law Constant Adsorption coefficient Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2

-yl acrylate 5888-33-5

23.3 Pam³/mole at 25°C Koc at 20°C = 3.71



Chemical name PBT and vPvB assessment Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate The substance is not PBT / vPvB





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IMDG 14.1 UN number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9 14.4 Packing group III

Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate, acrylic acid), 9, III, Marine pollutant


14.6 Special Provisions 274, 335, 969 EmS-No F-A, S-F



RID 14.1 UN number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9


Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate, acrylic acid), 9, III



ADR 14.1 UN number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9


Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate, acrylic acid), 9, III



ADN 14.1 UN/ID no UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9


Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate), 9, III


IATA 14.1 UN number UN3082

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14.2 UN proper shipping name Environmentally hazardous substances, liquid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III

Description UN3082, Environmentally hazardous substances, liquid, n.o.s. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate, acrylic acid), 9, III


ERG Code 9L





European Union




Dangerous substance category per Seveso Directive (2012/18/EU)E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1



Chemical name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS TCSI NZIoC Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate 5888-33-5

X X X X X X X X


Legend:

X - Listed TSCA - Toxic Substances Control Act Frank R. Lautenberg Chemical Safety for the 21st Century Act (active rule) DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances

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KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals TCSI - Taiwan Chemical Substance Inventory





Full text of H-Statements referred to under section 3H226 - Flammable liquid and vapourH302 - Harmful if swallowedH312 - Harmful in contact with skinH314 - Causes severe skin burns and eye damageH315 - Causes skin irritationH317 - May cause an allergic skin reactionH319 - Causes serious eye irritationH332 - Harmful if inhaledH335 - May cause respiratory irritationH400 - Very toxic to aquatic lifeH410 - Very toxic to aquatic life with long lasting effects



Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme Organisation for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization

Issuing Date 09-Dec-2019


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Skin designation


Revision date 09-Dec-2019




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236 Kap isolierte chemisch einheitliche organische 13,122.00 KgUN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, VG III M6 2 Pallet 2118kgUN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, VG III M7 4 Bag (on 3 Carton ) 66kgUN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, VG III M6 1 Pallet 1059kgUN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, VG III M7 4 Bag (on 10 Carton ) 222kgUN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, VG III M7 4 Bag (on 6 Carton ) 131kg HSCODE = 29144090Ekipman Adet Spanzet 23 Stange 3 Sunta (OSB) 2 Konteyner Stangesi 2

CMR

6 7 8 9 10 11Marka ve Numara Parça Adedi Ambalaj Cinsi Malın Cinsi İstatistik No Brüt Kg HacimMarks and No Number of Pacakges Method of Packing Nature of the goods Statistical number Gross weight Volume in m312

1 Gönderen Sender

2 Alıcı Consignee

3 Malların teslim alındığı yer ve gün Collection Place and Date

4 Malların gönderildiği yer Delivery Place

5 Ek Dökümanlar Attached document

16 Diğer Nakliyeci Successive Carrier

17-18 Özel Talimatlar Special Instructions

21

IGM RESINS BVGOMPENSTRAAT 49NL-5145 RM WAALWIJK - TAX:Supplier Nr:

FRİMPEKS KİMYA VE ETİKET SANAYİ TİCARET AŞMERMERCİLER SANAYİ SİTESİ 8 CADDE NO 15TR-34520 BEYLİKDÜZÜ / İSTANBUL VKN:3880603783EORI Nr: Plant Nr:

NL-4191 GW GELDERMALSEN 21/10/2021

TR-34555 ARNAVUTKÖY / İSTANBUL -

1 ATR(O);1 IMO(C);1 EX-1(O);1 Fatura(C);1 Çeki Liste(C);

Our : 12110960 348264943PO14686; 2000010501; 80022695Your :Dokuman No :0012014667

FCA - Freight Collect

EKOE 597197-7

INTERNATIONAL CONSIGNMENT NOTEBu taşıma karşılıklı birsözleşme olsa bile karayolu ile eşya taşımacılığı(CMR)şartlatına tabidir.

ULUSLARARASI HAMULA SENEDİCMR convention for the internationalcarraige of goods by road is bindingfor this consignment, howeverthe agrement can be bilateral.

Delivery Address19-20 Teslim AdresiCustoms Clearance13 Gümrükleme Adresi

14 Navlunun ödenmesi için talimatlar Instruction as to payment carriage 15 Teslimatta ödenecek meblağReimboursement/cash on delivery

Established inTanzim TR-34149 BAKIRKÖY / İSTANBUL 22/10/2021

SIL

A

24 Mallar teslim alındıGoods received TarihOn

--------------/---------------

Signature and stamp of consigneeMal cinsi ve ambalaj gönderenin muhteviyatına göre yazılmıştır.Condition and nature of the goods and the content of the packagesare as per sender's declaration

Malın sigortasından, kalitesinden tahmilTahliyesi ve Gümrüklemesinden Ambalaj İstifHatasından Nakliyeci Mesul Değildir.Süreyi aşan hergün için 180 EUR karşılığı TL tahsil edilir

Malı gönderenin imzası ve kaşesiSignature and stamp of the sender Nakliyeci kaşesiSignature and stamp of the carrier

22 23

CUSTOMS CLEARANCE :DOUANE KANTOOR VENLO ABCOLUMBUSWEG 57NL-5928 LA VENLODELIVERY ADDRESS :LOTUS ANTREPO LOJİSTİK VE TAŞIMACILIK HİZMETLERİ DIŞYEŞİLBAYIR MAHALLESİ YAPI CADDESİ NO:21/ATR-34555 ARNAVUTKÖY / İSTANBUL

DELIVERED TOAlıcının imzası ve kaşesi

04/11/2021Lotus Yanýcý Antrepo

TRANSPORTER HAS NOT COUNTED THE UNITS

IGM RESINS B.V.

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