IFP : a research and industrial develment and training center- to design refining and petrochemical...
Transcript of IFP : a research and industrial develment and training center- to design refining and petrochemical...
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IFP : a research and industrial development and training center
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Active in the fields of :
- oil, gas and coal, their uses, in particular in transport,- the new energy and environmental technologies
IFP's staff : 1,125 researchers 239 doctoral and post doctoral researchers
An applied research : a portfolio of more than 12,000 living patents
A policy of commercial development of the results through the licensing of processes, software, equipment, etc.
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Objectives are :- to design refining and petrochemical processes that are clean and efficient- to diversify sources of energy for the production of fuels and hydrogen- to control emissions of CO2
Skill areas : catalysis, separation technologies, analysis and physico-chemical characterization, thermodynamics, chemical engineering, modeling of processes,molecular modeling, high-flow tests and experiments
1,800 industrial units worldwide
Recent achievements :
Esterfip-H: biodiesel production process by transesterification of vegetable oils. Marketed by Axens.
Esterfip-H unit under construction in Sète, France.
In refining-petrochemicals
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ASIEAM. NORDEUROPE
18 67
MOYEN ORIENT 1
AM. SUD 1
AFRIQUE 2
ASIEAM. NORDEUROPE
18 67
MOYEN ORIENT 1
AM. SUD 1
AFRIQUE 2
Dimersol Process : for gasoline
• One of the first examples of application of homogeneous catalysis in refining industry
• First industrial unit in 1977• 35 units in operation worldwide• 3.5 Mt products / year
+ +6% 72% 22%
Dimerization of propylene into isohexenes : octane booster for gasoline
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Dimersol Process : for chemistry
+ +6%59%34%
• First industrial unit in 1980• 0.4 Mt products / year
Dimerization of butenes into octenes : raw materials for the production of PVC phthalate plasticizers
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mole AlCl3
T°C
20°C
-60°C
liquid
solidsolid
AlCl3EMICl
Diagramme de phases
ClN-MeEt-N AlCl3+
EMICEthyl Methyl Imidazolium
Chlorure
Non-Aqueous Ionic Liquids
From non aqueous electrolytes for batteries
...to a new class of solvents for catalysis
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Products
Reactants solvent + catalyst
Reactants
Products
Ni
Liquid-Liquid Biphasic Catalysis
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Butenes
Catalyst
toward washing and distillation
section
Dimersol process
Difasol processProducts
Reactants Active Phase containing the catalyst
toward distillationsection
4 reactors of 120 m3
reactor of 50 m3
catalyst consumption divided by 10
higher yield in dimers
20t/h feed rate
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• Dimerization of ethylene into 1-butene (Ti homogeneous catalyst)
• 1-Butene is used as co-monomer for polyethylene manufacture
Alphabutol process
• First industrial unit in 1987• 20 units in operation• 0.4 Mt/Y
• 2005 : 3 new units 110 000t/Y total capacity
AFRIQUE 2
MOYEN ORIENT 9
ASIE 8
AFRIQUE 2
MOYEN ORIENT 9
ASIE 8
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M(CO)6/Al2O3 (M = Mo, W)
Ethylene 2-Butene(trans et cis)
Propylene
2 +90°C-315°C
Banks et Bailey (Philips Petroleum Co.)I. & E. C. Product Research and Development
1964, 3, 170-173.
1964 : a magic year...
WCl6/AlEt3n
nMoCl6/AlEt3
G. Natta Angew. Chem. Int. Ed. Engl. 1964, 3, 723
E. O. Fischer Angew. Chemie 1964, 76, 645
Heterogeneous catalysis...
Homogeneous catalysis
Metallocarbene
a new metal–carbon bond
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2 +
2-pentene 2-butene 3-hexene
Disproportionation of olefins
Ethylene 2-Butene(trans et cis)
Propylene
2 +
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"Pairwise" mechanism
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M(CO)6/Al2O3 (M = Mo, W)
Ethylene 2-Butene(trans et cis)
Propylene
2 +90°C-315°C
Banks et Bailey (Philips Petroleum Co.)I. & E. C. Product Research and Development
1964, 3, 170-173.
1964 : a magic year...
WCl6/AlEt3n
nMoCl6/AlEt3
G. Natta Angew. Chem. Int. Ed. Engl. 1964, 3, 723
E. O. Fischer Angew. Chemie 1964, 76, 645
Heterogeneous catalysis...
Homogeneous catalysis
Metallocarbene
a new metal–carbon bond
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R2
R1
+
R1
R2
R1
R1
R2
R2
R1 R1 R2 R2++++
cyclopentene 2-pentene
C10 C9 C11
homogeneous W catalyst
Co-reaction of cyclopentene with 2-pentene
Hérisson et Chauvin Die Makromolekular Chemie 1971, 141, 161-176.
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RC
HM
(CH2)n
CH
M CH CHRHC
HC(CH2)n+ etc…
Linear polymers with high molecular weight : observed at the beginning of
the reaction
Carbene mechanism
[W] CH
R
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R1CH=CHR2
Soufflet, Commereuc et Chauvin C. R. Acad. Sc. 1973, 276, 169-171
formation of -olefins
Formation of the metallocarbene :WCl6 + Sn(CH3)n
[W]=CH2
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Hérisson et Chauvin Die Makromolekular Chemie 1971, 141, 161-176.
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Cross Metathesis (CM)
Ring Closing Metathesis(RCM)
Acyclic Diene Polymerization (ADMET)
Ring Opening Metathesis (ROMP)
R1 R2
n
R1 R1
R2 R2+
+
n+
2