How do Anti-Friction Coatings based on Binder Systems eliminate noise in automotive interiors?

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Applications of Anti- Friction Coatings based on Binder Systems Manfred Jungk - Vittorio Clerici January 12th 2016

Transcript of How do Anti-Friction Coatings based on Binder Systems eliminate noise in automotive interiors?

Applications of Anti-

Friction Coatings based on

Binder Systems

Manfred Jungk - Vittorio Clerici

January 12th 2016

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Introduction

• Modern passenger cars are equipped with sophisticated

measures to avoid propagation of noise from the engine

and gearboxes into the passenger compartment

• This creates a very comfortable environment for car

occupants

• On the other hand, this enables “new noises” to become

audible – particularly those generated by the sliding of

plastic components made of thermoplastics having poor

affinity under the tribological aspect

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Examples of noise development from the field

• Door panel sliding against clear coat/paint

– Show video

• Armrest sliding against door panel insert

– Show video

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Proven solution

• Apply a surface treatment to the tribological contact

areas of the mating parts generating noise or in

suspect of producing it

Application of a dry-film lubricant = anti-friction coating

SOLUTION

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Product requirement profile

• Noise elimination for a wide array of material combinations

used in interiors

• Friction reduction of mating surfaces; more important

constancy of a defined level (no stick-slip formation)

• Service life performance

• Good adhesion to plastic materials

• Compatibility with plastic materials (stress cracking)

• Transparent

• Water-based

• Air-curing (max drying temperature = 60°C)

• Easy industrialization – easy integration of application in

existing production processes/lines

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Technology description

• Anti-Friction coating:

– Organic binder system

– Solid lubricants

– Solvent = water

wet film

substrate

Drying& curing

dry film = 10/12 µm

substrate

Solvent (water)

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Anti-noise tester – overview

Sliding guideSpecimen

holder with

strain gages

for friction

force and load

measurement

and with

acceleration

detector for

stick-slip

measurement

Stick-slip intermittent movement

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Anti-noise performance – report example

PRODUCT

Material pairing Paint vs. PVC foam 2.5 mm black No

AFC Anti-Friction Coating

Anti-Friction Coating variation

Load [N] Characteristic

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BI [noise rating] 8.5 8.5

RPN [risk priority number] 1 1

COF static [µ] 0.64 0.47

COF dynamic [µ] 0.35 0.24

Max. acceleration [g] 0.07 0.06

Impulse frequency [1/mm] 0.00 0

Impulse count 0 0

10

BI [noise rating] 8.5 8.5

RPN [risk priority number] 1 1

COF static [µ] 0.47 0.37

COF dynamic [µ] 0.29 0.21

Max. acceleration [g] 0.06 0.06

Impulse frequency [1/mm] 0.00 0

Impulse count 0 0

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BI [noise rating] 4.0 8.1 8.5

RPN [risk priority number] 10 1 1

COF static [µ] 1.43 0.36 0.3

COF dynamic [µ] 0.92 0.25 0.18

Max. acceleration [g] 4.53 0.07 0.06

Impulse frequency [1/mm] 1.86 0.00 0

Impulse count 17 0 0

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BI [noise rating] 8.5 8.5

RPN [risk priority number] 1 1

COF static [µ] 0.31 0.26

COF dynamic [µ] 0.22 0.17

Max. acceleration [g] 0.06 0.06

Impulse frequency [1/mm] 0.00 0

Impulse count 0 0

SHORT TEST – RT VDA 230-206

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Anti-noise performance (short test, RT)

SHORT TEST ACCORDING TO VDA 230-206

PRODUCT

Material pairing Material pairing Anti-Friction Coating Anti-Friction Coating

variation

Paint PVC 1 mm

PVC 1 mm PVC 1 mm

Paint PVC 2.5 mm beige

Paint PVC 2.5 mm black

Paint TPO 1 mm

Paint Leather black

Leather black Leather black

PC-ABS Leather black

PC-ABS PVC 1 mm

Green = very

suitable

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Anti-noise performance (short test, climatic cond.)

Paint FF99-0141 PVC 1 mm Paint ApO Leather PVC 1 mm

PVC 1 mm PVC 1 mm Leather Leather PC-ABS

Anti-Friction Coating Anti-Friction Coating Anti-Friction Coating Anti-Friction Coating Anti-Friction Coating

Load [N] Climatic

conditions Max. acc.

[g] µ max.

Max. acc. [g]

µ max. Max. acc.

[g] µ max.

Max. acc. [g]

µ max. Max. acc.

[g] µ max.

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23°C – 50% 0.0 0.2 0.0 0.2 0.0 - 0.0 0.8 0.0 0.5

40°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.1 0.8 0.0 0.6

80°C – 30% 0.0 0.5 0.0 0.1 0.0 - 0.0 0.8 0.1 0.6

23°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.1 0.7 0.0 0.6

10°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.0 0.2 0.0 0.5

-30 °C 0.1 0.1 0.1 0.1 0.0 - 0.1 0.1 0.0 0.1

23°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.0 0.2 0.0 0.5

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23°C – 50% 0.0 0.2 0.0 0.1 0.0 - 0.0 0.4 0.0 0.3

40°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.1 0.4 0.0 0.3

80°C – 30% 0.0 0.5 0.0 0.1 0.0 - 0.0 0.4 0.0 0.3

23°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.1 0.4 0.0 0.3

10°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.0 0.1 0.0 0.3

-30 °C 0.0 0.1 0.0 0.1 0.0 - 0.1 0.1 0.0 0.1

23°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.0 0.1 0.0 0.3

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23°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.0 0.3 0.0 0.2

40°C – 50% 0.0 0.2 0.0 0.1 0.0 - 0.1 0.3 0.0 0.2

80°C – 30% 0.1 0.4 0.0 0.1 0.0 - 0.0 0.3 0.0 0.2

23°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.1 0.2 0.0 0.2

10°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.0 0.1 0.0 0.2

-30 °C 0.0 0.1 0.0 0.1 0.0 - 0.0 0.1 0.0 0.1

23°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.0 0.1 0.0 0.2

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23°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.0 0.2 0.0 0.2

40°C – 50% 0.0 0.2 0.0 0.1 0.0 - 0.1 0.2 0.0 0.2

80°C – 30% 0.0 0.4 0.0 0.1 0.0 - 0.0 0.2 0.0 0.2

23°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.1 0.2 0.0 0.1

10°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.0 0.1 0.0 0.1

-30 °C 0.0 0.1 0.0 0.1 0.0 - 0.0 0.1 0.0 0.1

23°C – 50% 0.0 0.1 0.0 0.1 0.0 - 0.0 0.1 0.0 0.2

SHORT TEST VDA 230-206

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Anti-noise performance (durability test, RT)

DURABILITY TEST BASED ON PARAMETERS OF VDA-230-206

PRODUCT

Material pairing Material pairing Anti-Friction Coating Anti-Friction Coating

variation

Paint PVC 1 mm

PVC 1 mm PVC 1 mm

Paint PVC 2.5 mm beige

Paint PVC 2.5 mm black

Paint TPO 1 mm

Paint Leather black

Leather black Leather black

PC-ABS Leather black

PC-ABS PVC 1 mm 100K cycles 100K cycles

10,000 cycles or

as indicated

Green = very

suitable

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PRODUCT

Material pairing PC-ABS vs. PVC foam 1 mm No

AFC Anti-Friction Coating

Anti-Friction Coating variation

Cycles Characteristic

0-2,500/0-5,000

BI [noise rating] 4.0 8.5 8.5

RPN [risk priority number] 10 1 1

COF static [µ] 1.33 0.30 0.23

COF dynamic [µ] 0.97 0.14 0.16

Max. acceleration [g] 6.2 0.23 0.06

Impulse frequency [1/mm] 18.2 0.00 0.00

Impulse count 168 0 0

2,500-5,000/0-5,000

BI [noise rating]

No need

8.5 8.5

RPN [risk priority number] 1 1

COF static [µ] 0.28 0.22

COF dynamic [µ] 0.12 0.15

Max. acceleration [g] 0.46 0.07

Impulse frequency [1/mm] 0.00 0.00

Impulse count 0 0

95,000-100,000

BI [noise rating]

No need

8.5 8.5

RPN [risk priority number] 1 1

COF static [µ] 0.24 0.19

COF dynamic [µ] 0.12 0.13

Max. acceleration [g] 0.13 0.05

Impulse frequency [1/mm] 0.00 0.00

Impulse count 0 0

Anti-noise performance (100K cycle durability test) –

PC-ABS vs. PVC foam foil 1 mm thickDURABILITY TEST

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Anti-noise performance (100K cycle durability test)

– PC-ABS vs. PVC foam foil 1 mm thick

PVC 1 mm foil uncoated Before durability test

No wear, no

adhesion loss

After 100,000 cycle durability test

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Modified anti-noise testing setup

• Instead of the common plastic

holder for the foil material, a cut-out

section of the door panel edge is

fixed in the testing machine

• Higher flexibility between machine

holder and tribological contact

enhances the sensitivity to stick-slip

formation

• Setup more similar to real

application

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DOOR PANEL SECTION

PRODUCT

Material pairing Paint vs. PVC foam 1 mm No AFC Anti-Friction Coating

Cycles Characteristic

0-5,000

BI [noise rating] 4.0 8.5

RPZ [risk priority number] 10 1

COF static [µ] 1.16 0.75

COF dynamic [µ] 0.72 0.47

Max. acceleration [g] 1.49 0.06

Impulse frequency [1/mm] 1.00 0.00

Impulse count 9 0

5,000-10,000

BI [noise rating]

No n

eed

8.5

RPZ [risk priority number] 1

COF static [µ] 0.73

COF dynamic [µ] 0.45

Max. acceleration [g] 0.06

Impulse frequency [1/mm] 0.00

Impulse count 0

Paint vs. PVC 1 mm foil – panel section

DURABILITY TEST LOAD = 20 N

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Paint vs. PVC 1 mm foil –

panel section – no AFC

Video – no AFC

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Paint vs. PVC 1 mm foil – panel section –

Anti-Friction Coating

Video – AFC

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DOOR PANEL SECTION

PRODUCT

Material pairing PC-ABS vs. PVC foam 1 mm No AFC Anti-Friction Coating

Cycles Characteristic

0-5,000

BI [noise rating] 4.0 8.5

RPZ [risk priority number] 10 1

COF static [µ] 1.21 0.78

COF dynamic [µ] 0.66 0.44

Max. acceleration [g] 13.42 0.10

Impulse frequency [1/mm] 39.90 0.00

Impulse count 366 0

5,000-10,000

BI [noise rating]

No

ne

ed

8.5

RPZ [risk priority number] 1

COF static [µ] 0.87

COF dynamic [µ] 0.50

Max. acceleration [g] 0.19

Impulse frequency [1/mm] 0.00

Impulse count 0

PC-ABS vs. PVC 1 mm foil – panel section

DURABILITY TEST LOAD = 20 N

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PC-ABS vs. PVC 1 mm foil –

panel section – no AFC

Video – no AFC

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PC-ABS vs. PVC 1 mm foil – panel section –

Anti-Friction Coating

Video – AFC

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Customized versions

• Depending on the application (part) and substrate material

and/or color, the dry film of the applied anti-friction coating

may not be easily detectable (transparency)

• Black pigments and/or UV tracers can be added to the basic

formulation without infringing on the physical properties and

anti-noise performance

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Customized version – aspect

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Anti-Friction Coating

Black version

Anti-Friction Coating

UV version

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PRODUCT

Material pairing Paint vs. PVC foam 1 mm Anti-Friction Coating (black) Anti-Friction Coating (UV)

Cycles Characteristic

0-5,000

BI [noise rating] 8.5 8.5

RPZ [risk priority number] 1 1

COF static [µ] 0.36 0.35

COF dynamic [µ] 0.22 0.22

Max. acceleration [g] 0.08 0.07

Impulse frequency [1/mm] 0.00 0.00

Impulse count 0 0

5,000-10,000

BI [noise rating] 8.5 8.5

RPZ [risk priority number] 1 1

COF static [µ] 0.26 0.27

COF dynamic [µ] 0.19 0.20

Max. acceleration [g] 0.08 0.07

Impulse frequency [1/mm] 0.00 0.00

Impulse count 0 0

Anti-noise data – paint vs. PVC 1 mm foil

DURABILITY TEST LOAD = 20 N

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PRODUCT

Material pairing PC-ABS vs. PVC foam 1 mm No

AFC Anti-Friction

Coating (black) Anti-Friction Coating

(UV)

Cycles Characteristic

0-5,000

BI [noise rating] 4.0 8.5 8.5

RPZ [risk priority number] 10 1 1

COF static [µ] 1.33 0.28 0.27

COF dynamic [µ] 0.97 0.15 0.15

Max. acceleration [g] 6.2 0.06 0.07

Impulse frequency [1/mm] 18.2 0.00 0.00

Impulse count 168 0 0

5,000/10,000

BI [noise rating]

No need

8.5 8.5

RPZ [risk priority number] 1 1

COF static [µ] 0.26 0.18

COF dynamic [µ] 0.13 0.12

Max. acceleration [g] 0.07 0.07

Impulse frequency [1/mm] 0.00 0.00

Impulse count 0 0

Anti-noise data – PVC 1 mm foil vs. PC-ABS

DURABILITY TEST LOAD = 20 N

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Temperature resistance - COF

• Application of the AFC on metal

Q-Panels

• After curing at proper conditions:

conditioning of the coated Q-

Panels under following conditions:

– RT as reference

– 4 h @ -40°C

– 4 h @ 100°C

– 4 h @ 150°C

– 4 h @ 200°C

• After conditioning the following

tests were carried out:

– Bending and cross-cut

– COF evaluation on oscillating

polymer tester

0.000

0.050

0.100

0.150

0.200

0.250

0.300

none 4 h @ -40°C

4 h @100°C

4 h @150°C

4 h @200°C

COF dyn

COF static

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Ball/plate oscillating test machine

Test conditions:

Substrate = AFC coated Q-Panel

Ball = POM

Load = 2 N

Speed = 1 cm/s

Time = 1 and/or 8 h

Room temperature (23°C) and

40% rel. humidity

COF = mean coefficient of friction

measured during test

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Temperature resistance – bending test

after 4 h @ -40°C after 4 h @ 100°C

after 4 h @ 150°C after 4 h @ 200°C

No peeling no

cracks formation

ASTM-D 1737

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Temperature resistance – cross-cut test

after 4 h @ -40°C after 4 h @ 100°C

after 4 h @ 150°C after 4 h @ 200°C

No peeling no

cracks formation

ASTM-D 3359B

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Summary

• Anti-friction coatings are a proven

solution that can provide the following

advantages for automotive interior

components:

– Excellent anti-squeak characteristics

– Long-term noise protection

– Low coefficient of friction

– Transparent; water-based

– Compatible with typical plastic

materials used in interiors

– Easy to integrate into

existing production lines

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WITH RESPECT TO THE UTILITY OR COMPLETENESS OF THE INFORMATION AND DISCLAIMS THE IMPLIED

WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. DOW CORNING DISCLAIMS

LIABILITY FOR ANY INCIDENTAL OR CONSEQUENTIAL DAMAGES.

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Application process

• Anti-friction coatings can

be applied with traditional

painting equipment

• For interior components,

the most established

process is spraying

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Application process

• Process can be fully

automated (robot spraying)

– Adv. for parts of

complicated geometry

• Specific automatic plants

are available on the market

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Process integration

• Possible integration into existing production lines:

– Water-based system (no flash point, no emissions)

• Processability:

– Drying time: Water elimination; can be reduced to 2 min with 60°C

hot air; coated area touch dry

– Curing time: Fully cured after 2 hours (application of intended max.

load)

• Aspect after drying/curing:

– Dry film adhering to substrate

– Transparent if applied at recommended film thickness (10-12 µm)

– Dry film changes the gloss of the coated surface

– Not suitable for visible areas

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Processability

• Spraying application

generally carried out

with 0.5 or 0.3 mm

nozzles

• Sedimentation/clogging

can be critical: High

stability is required

After 1 day After 6 months @ 40°C

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