Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis

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Highly Efficient Molybdenum-based Ca talysts for Enantioselective Alkene Metathesis Nature 2008, 456, 933-937

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Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis. Nature 2008 , 456 , 933-937. Organomet. Chem. 2005 , 15 , 271–278. Organomet. Chem. 2005 , 15 , 271–278. Nature 2007 , 450, 243–251. Moreover, by monitoring the reaction progress spectroscopically - PowerPoint PPT Presentation

Transcript of Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis

Page 1: Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis

Highly Efficient Molybdenum-based Catalysts for Enantioselective Alkene Metathesis

Nature 2008, 456, 933-937

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Organomet. Chem. 2005, 15, 271–278

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Organomet. Chem. 2005, 15, 271–278

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Nature 2007, 450, 243–251

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Moreover, by monitoring the reaction progress spectroscopically(400-MHz 1H NMR) in the presence of 13b, generated in situ:98% of the major isomer is consumed, the minor diastereomerremains largely intact (95%)

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