Heimerle and Meule Gold Plating Solution Concentrate All Colours 998 201Y - 201R Material Safety...

7/25/2019 Heimerle and Meule Gold Plating Solution Concentrate All Colours 998 201Y - 201R Material Safety Data Sheet

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Safety data sheetaccordi ng to 1907/2006/EC, Ar ticle 31

Printing date: 25.04.2013 Revision: 25.04.2013Version number 2

* 1I denti fi cation of the substance/mixtu re and of the company/undertaking

Product identi fi er

Trade name: Gold bath FG 200 Concentrate 1g/100 ml Au

Farbgoldbad FG 200 Konzentrat 1g/100ml Au

Ar ticle number:86902000 Relevant i denti fi ed uses of the substance or mixtu re and uses advised againstNo further relevant information available.

Appl icati on of the substance / the preparati onGalvanic bath Manufacturer/Supplier:

Heimerle + Meule GmbHDennigstrasse 16D-75179 Pforzheim

Telefon +49 (0) 7231 940-0Telefax +49 (0) 7231 940-2199

www.heimerle-meule.com

Fu rther inf ormation obtainable fr om:Department chemistry and environmentAbteilung Chemie und Umwelt Emergency telephone number:

Phone : +49 172 739 6970

[email protected]

* 2Hazards identi fi cation

Classif ication of the substance or mi xtur e Classif ication according to Regulation (EC) No 1272/2008

GHS06 skull and crossbones

Acute Tox. 3 H311 Toxic in contact with skin.

Acute Tox. 3 H331 Toxic if inhaled.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.

Classif ication according to Di rective 67/548/EEC or Di rective 1999/45/EC

T; Toxic

R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.

R32-52/53: Contact with acids liberates very toxic gas. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

(Contd. on page 2)GB


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(Contd. of page 1)

Classifi cation system:The classification is according to the latest editions of the EU-lists, and extended by company and literaturedata.

Label elements

Labell ing according to EU gu idelines:The product has been classified and marked in accordance with EU Directives / Ordinance on HazardousMaterials.

Code letter and hazard designation of product:

T Toxic

Hazard-determining components of l abell ing:Potassium dicyanoaurate

Risk phr ases:23/24/25 Toxic by inhalation, in contact with skin and if swallowed.32 Contact with acids liberates very toxic gas.52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases:4 Keep away from living quarters.9 Keep container in a well-ventilated place.20 When using do not eat or drink.36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

45 In case of accident or if you feel unwell, seek medical advice immediately (show the label wherepossible).61 Avoid release to the environment. Refer to special instructions/safety data sheets.

Other hazards Resul ts of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable.

* 3Compositi on/in formation on ingredients

Chemical characteri zation: M ix tures Description:Mixture of substances listed below with nonhazardous additions.

Dangerous components / Information on ingredients:CAS: 13967-50-5EINECS: 237-748-4

Potassium dicyanoaurateT+ R26/27/28; N R50/53

R32

Acute Tox. 2, H300; Acute Tox. 1, H310; Acute Tox. 1, H330;Aquatic Acute 1, H400; Aquatic Chronic 1, H410

1.0-2.5%

Additional information:For the wording of the listed risk phrases refer to section 16.

* 4F ir st aid measures

Description of fi rst aid measures General inf ormation:

Immediately remove any clothing soiled by the product.Remove breathing equipment only after contaminated clothing have been completely removed.

(Contd. on page 3)

GB


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(Contd. of page 2)

In case of irregular breathing or respiratory arrest provide artificial respiration. Af ter inhalation:Supply fresh air or oxygen; call for doctor.In case of unconsciousness place patient stably in side position for transportation. Af ter skin contact:Immediately wash with water and soap and rinse thoroughly. Af ter eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor. Af ter swallowing:Rinse out mouth and then drink plenty of water.A person vomiting while laying on their back should be turned onto their side.Drink plenty of water and provide fresh air. Call for a doctor immediately. I nformation for doctor:Cyanides poisoning Most important symptoms and eff ects, both acute and delayedCyanides poisoningCyanosis

I ndication of any immediate medical attenti on and special treatment neededNo further relevant information available.

5F ir efi ghting measures

Extinguishing media Suitable extingui shing agents:CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

For safety reasons unsui table exti nguishing agents:Water with full jet Special hazards arising f rom the substance or mix tureFormation of very toxic gases is possible during heating or in case of fire.In case of fire, the following can be released:

Hydrogen cyanide (HCN) Advice for fi refighters Protective equipment:Wear self-contained respiratory protective device. Additional informationDispose of fire debris and contaminated fire fighting water in accordance with official regulations.

6Accidental release measur es

Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.Wear protective equipment. Keep unprotected persons away.

Environmental precautions:

Inform respective authorities in case of seepage into water course or sewage system.Dilute with plenty of water.Do not allow to enter sewers/ surface or ground water. Methods and materi al for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Dispose contaminated material as waste according to item 13.Ensure adequate ventilation. Reference to other sectionsSee Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.

GB

(Contd. on page 4)


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(Contd. of page 3)

* 7Handling and storage

Handling: Precautions for safe handlingStore in cool, dry place in tightly closed receptacles.Wear suitable respiratory protective device when decanting larger quantities without extractor facilities.Do not dry clean dust covered objects and floors. Wash thoroughly with plenty of water.Ensure good ventilation/exhaustion at the workplace.Open and handle receptacle with care.Only handle and refill product in closed systems.

I nformation about fi re - and explosion protection:Keep respiratory protective device available.

Conditions for safe storage, including any incompatibili ties

Storage: Requi rements to be met by storerooms and receptacles:Observe official regulations on storing packagings . I nformation about storage in one common storage facil ity:Do not store together with oxidizing and acidic materials.Do not store together with acids. Fur ther in formation about storage conditions:Keep container tightly sealed. Storage class:6.1 C Specif ic end use(s)No further relevant information available.

* 8Exposure controls/personal protection

Additi onal in formation about design of techni cal facili ties:No further data; see item 7.

Control parameters

I ngredients with l imi t values that requir e monitor ing at the workplace:

13967-50-5 Potassium dicyanoaurate

WEL (Great Britain) Long-term value: 5 mg/mas CN; Sk

MAK (Germany) vgl.Abschn.IIb

Additional information:The lists valid during the making were used as basis.

Exposure control s Personal protective equipment: General protective and hygienic measur es:According to EC Directive 89/686/EEC

The usual precautionary measures are to be adhered to when handling chemicals.Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.Store protective clothing separately.Do not inhale gases / fumes / aerosols.Avoid contact with the eyes and skin. Respir atory protection :according EN 14387according to EN 143Use suitable respiratory protective device in case of insufficient ventilation.Use suitable respiratory protective device only when aerosol or mist is formed.Not necessary if room is well-ventilated.

(Contd. on page 5)

GB


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(Contd. of page 4)

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposureuse self-contained respiratory protective device.Beware: Filter masks provide protection for a short period of time only. They should only be used inexceptional cases, that is if a small amount of the substance has spilled out or in order to fight spillages andfire. Recommended fi lter device for short term use:Combination filter B-P2 Protection of hands:Alkaline resistant glovesOnly use chemical-protective gloves with CE-labelling of category III.Sensibilization by the components in the glove materials is possible.Check protective gloves prior to each use for their proper condition.Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradationPrior to working with gloves the rubbing in with tanniferous skin-protecting agents for the avoidance of skinsoftening due to perspiration is recommended.

Protective gloves

Materi al of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marks of qualityand varies from manufacturer to manufacturer.Chloroprene rubber, CRRecommended thickness of the material: 0.65 mmNitrile rubber, NBRRecommended thickness of the material: 0.65 mm

Penetration time of glove materi alThe exact break trough time has to be found out by the manufacturer of the protective gloves and has to beobserved.

Not sui table are gloves made of the foll owing materi als:Leather gloves Eye protection:

Tightly sealed goggles

according to EN 166 Body protection:Protective work clothing

* 9Physical and chemical properties

I nformation on basic physical and chemical properti es General I nformation Appearance:

Form: FluidColour: Colourless

Odour: Odourless Odour thr eshold: Not determined.

pH -value at 20 C (68 F): 9

Change in condi tionMelting point/Melting r ange: Undetermined.

Boil ing point/Boili ng range: Undetermined.(Contd. on page 6)

GB


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(Contd. of page 5)

Fl ash point: Not applicable.

F lammabil ity (solid, gaseous): Not applicable.

I gniti on temperatur e:

Decomposit ion temperatu re: Not determined.

Self-igniting: Product is not selfigniting.

Danger of explosion: Product does not present an explosion hazard.

Explosion limits:Lower: Not determined.Upper: Not determined.

Vapour pressur e: Not determined.

Densi ty at 20 C (68 F): 1.006 g/cm (8.395 lbs/gal) Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined.

Solubili ty in / M iscibil ity withwater: Fully miscible.

Parti tion coeff icient (n-octanol/water):Not determined.

Viscosity:Dynamic: Not determined.Kinematic: Not determined.

Solvent content:Organic solvents: 0.0 %

Other i nformation No further relevant information available.

10 Stabil ity and reactivity

Reactivity Chemical stabili ty Thermal decomposit ion / condit ions to be avoided:No decomposition if used according to specifications. Possibi li ty of hazardous reactionsContact with acids releases very toxic gases Conditions to avoidNo further relevant information available. I ncompatible materi als:Acids

Hazardous decomposit ion products:Hydrogen cyanide (prussic acid)

11 Toxicological inf ormation

I nformation on toxicological effects Acute toxicity:

LD/L C50 values relevant for classif ication:

13967-50-5 Potassium dicyanoaurate

Oral LD50 29 mg/kg (Rat)

Primary ir ri tant eff ect: on the skin:No irritant effect.

on the eye:No irritating effect. Sensitization:No sensitizing effects known.

(Contd. on page 7)

GB


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(Contd. of page 6)

Additional toxicological in formation:The product shows the following dangers according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version:Toxic

* 12 Ecological inf ormation

Toxicity Aquatic toxici ty:No further relevant information available. Persistence and degradabil it yNo further relevant information available. Behaviour in envi ronmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Additional ecological inf ormation: General notes:Water hazard class 2 (German Regulation) (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.Danger to drinking water if even small quantities leak into the ground. Resul ts of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse eff ectsNo further relevant information available.

* 13 Disposal considerations

Waste treatment methods Recommendation

Must not be disposed together with household garbage. Do not allow product to reachsewage system.

Contact manufacturer for recycling information. Waste disposal key:The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC,specific to the industry and process. European waste catalogueThere are no uniform EC regulations for the disposal of chemicals or residues. Chemical residues generallycount as special waste. The disposal of the latter is regulated in the EC member countries throughcorresponding laws and regulations. We recommend that you contact either the authorities in charge orapproved waste disposal companies which will advise you on how to dispose of special waste

11 00 00 WASTES FROM CHEMICAL SURFACE TREATMENT AND COATING OF METALS ANDOTHER MATERIALS; NON-FERROUS HYDRO-METALLURGY

11 01 00 wastes from chemical surface treatment and coating of metals and other materials (for examplegalvanic processes, zinc coating processes, pickling processes, etching, phosphating, alkalinedegreasing, anodising)

11 01 98* other wastes containing dangerous substances

Uncleaned packaging: Recommendation:Disposal must be made according to official regulations.

Packaging which is uncleaned or soiled with product remains is to be treated like the product itself(Contd. on page 8)GB


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(Contd. of page 7)

Packaging free of product remains is to be supplied refuse for recycling. Only if no adequate collectingsystem is available, they may be disposed of through the domestic rubbish Recommended cleansing agents:Water, if necessary together with cleansing agents.

* 14 Transport information

UN-Number ADR, ADN, IM DG, IATA Void

UN proper shipping name ADR, ADN, IM DG, IATA Void

Transport hazard class(es)

ADR, ADN, IM DG, IATA Class Void

Packing group ADR, IMDG, I ATA Void

Environmental hazards: Marine pollutant: No

Special precautions for user Not applicable.

Transport in bulk according to Annex I I ofMARPOL73/78 and the I BC Code Not applicable.

UN " Model Regulation" : -

* 15 Regulatory information

Safety, health and environmental regulations/legislation specif ic f or the substance or mix ture

TSCA (Toxic Substances Control Act)

All ingredients are listed.

Labell ing according to EU gu idelines:The product has been classified and marked in accordance with EU Directives / Ordinance on HazardousMaterials.

Code letter and hazard designation of product:

T Toxic

Hazard-determining components of l abell ing:Potassium dicyanoaurate

Risk phr ases:23/24/25 Toxic by inhalation, in contact with skin and if swallowed.32 Contact with acids liberates very toxic gas.52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases:4 Keep away from living quarters.

9 Keep container in a well-ventilated place.20 When using do not eat or drink.

(Contd. on page 9)

GB


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(Contd. of page 8)

36/37/39 Wear suitable protective clothing, gloves and eye/face protection.45 In case of accident or if you feel unwell, seek medical advice immediately (show the label wherepossible).

61 Avoid release to the environment. Refer to special instructions/safety data sheets.

National regulations:

Waterhazard class:Water hazard class 2 (Self-assessment): hazardous for water. Chemical safety assessment:A Chemical Safety Assessment has not been carried out.

* 16Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.

Reasons for reviseIf necessary, this saftey data sheet can revised according to legal guidelines.

Our current version for your reference is available on our websitewww.heimerle-meule.com

Date fr om last issue :28.04.2008

Relevant phrasesH300 Fatal if swallowed.H310 Fatal in contact with skin.H330 Fatal if inhaled.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.

R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.R32 Contact with acids liberates very toxic gas.R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Department i ssuing M SDS:Department chemistry and environment Contact:[email protected]

Abbreviati ons and acronyms:RID: Rglement international concernant le transport des marchandises dangereuses par chemin de fer (Regulat ions Concerning theInternational Transport of Dangerous Goods by Rail)IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)ICAO: International Civil Aviation OrganizationICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)

ADR: Accord europen sur le transport des marchandises dangereuses par Route (European Agreement concerning the InternationalCarriage of Dangerous Goods by Road)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationGHS: Globally Harmonized System of Classification and Labelling of ChemicalsLC50: Lethal concentration, 50 percentLD50: Lethal dose, 50 percent

* Data compared to the previous version altered. GB

Heimerle and Meule Gold Plating Solution Concentrate All Colours 998 201Y - 201R Material Safety...

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