HBD-CF4Transmittance (The case of the Anomalous O2 Spikes) HBD Meeting 1/5/2010 B.Azmoun, S.Stoll...

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HBD-CF4Transmittance HBD-CF4Transmittance (The case of the Anomalous O2 (The case of the Anomalous O2 Spikes) Spikes) HBD Meeting 1/5/2010 HBD Meeting 1/5/2010 B.Azmoun, S.Stoll Brookhaven National Lab

Transcript of HBD-CF4Transmittance (The case of the Anomalous O2 Spikes) HBD Meeting 1/5/2010 B.Azmoun, S.Stoll...

Page 1: HBD-CF4Transmittance (The case of the Anomalous O2 Spikes) HBD Meeting 1/5/2010 B.Azmoun, S.Stoll Brookhaven National Lab.

HBD-CF4Transmittance HBD-CF4Transmittance (The case of the Anomalous O2 (The case of the Anomalous O2 Spikes)Spikes)

HBD Meeting 1/5/2010HBD Meeting 1/5/2010

B.Azmoun, S.Stoll

Brookhaven National Lab

Page 2: HBD-CF4Transmittance (The case of the Anomalous O2 Spikes) HBD Meeting 1/5/2010 B.Azmoun, S.Stoll Brookhaven National Lab.

PPM History since 12/3/09PPM History since 12/3/09

No Spikes, just ppm’s getting lower as expected

Spikes Appear, and with inc. freq.

H2O

O2

2

Page 3: HBD-CF4Transmittance (The case of the Anomalous O2 Spikes) HBD Meeting 1/5/2010 B.Azmoun, S.Stoll Brookhaven National Lab.

O2 Spikes do not Correlate with HBD Diff. O2 Spikes do not Correlate with HBD Diff. Press. Press. (cause unknown, but we have theories….)(cause unknown, but we have theories….)

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Page 4: HBD-CF4Transmittance (The case of the Anomalous O2 Spikes) HBD Meeting 1/5/2010 B.Azmoun, S.Stoll Brookhaven National Lab.

Zoom InZoom In…(Still no correlation observed)…(Still no correlation observed)

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Page 5: HBD-CF4Transmittance (The case of the Anomalous O2 Spikes) HBD Meeting 1/5/2010 B.Azmoun, S.Stoll Brookhaven National Lab.

Compare moment spikes occur to Trans. Compare moment spikes occur to Trans. Scan ResultsScan Results

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Transmittance (HBD IN) Raw Data

FIT fcn.(Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe (Fit ppms:108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

0.1 0.0100.0100.0

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_123109_02.txt

HBD-CF49.5

0.01 0.4

100.6

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Transmittance (HBD WEST)Raw Data

FIT fcn. (Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe(Fit ppms:108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

23.1 1.992.191.9

4.752.8 3.0

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_123109_02.txt

HBD-CF4

93.00.00

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Transmittance (HBD EAST) Raw Data

FIT fcn.(Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe(Fit ppms: 108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

21.0 1.492.992.8

4.752.3 1.0

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_123109_02.txt

HBD-CF4

93.5

12/31/09 Scan of HBD-CF4

Time of Scan

Note: Three Scans are done in succession:1st: Input, 2nd: West, 3rd: East5

Page 6: HBD-CF4Transmittance (The case of the Anomalous O2 Spikes) HBD Meeting 1/5/2010 B.Azmoun, S.Stoll Brookhaven National Lab.

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Tra

nsm

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Wavelength [Angstroms]

Transmittance (HBD IN) Raw Data

FIT fcn.(Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe (Fit ppms:108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

1.8 1.298.998.8

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_010110_01.txt

HBD-CF49.5

0.0 0.1

98.7

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Transmittance (HBD WEST)Raw Data

FIT fcn. (Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe(Fit ppms:108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

23.8 2.091.991.7

4.752.9 5.4

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_010110_01.txt

HBD-CF4

92.80.00

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Transmittance (HBD EAST) Raw Data

FIT fcn.(Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe(Fit ppms: 108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

22.0 1.992.492.2

4.752.4 2.3

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_010110_01.txt

HBD-CF4

92.9

01/01/10 Scan of 01/01/10 Scan of HBD-CF4HBD-CF4

Note: Analyzer values are recorded at beginning of scan 6

Page 7: HBD-CF4Transmittance (The case of the Anomalous O2 Spikes) HBD Meeting 1/5/2010 B.Azmoun, S.Stoll Brookhaven National Lab.

01/03/10 Scan of HBD-CF401/03/10 Scan of HBD-CF4

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nsm

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Wavelength [Angstroms]

Transmittance (HBD IN) Raw Data

FIT fcn.(Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe (Fit ppms:108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

0.8 0.099.799.7

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_010310_01.txt

HBD-CF410

0.0 0.2

100.4

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Transmittance (HBD WEST)Raw Data

FIT fcn. (Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe(Fit ppms:108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

20.4 1.193.293.1

5.02.3 2.6

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_010310_01.txt

HBD-CF4

94.50.00

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FIT fcn.(Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe(Fit ppms: 108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

18.5 1.293.893.6

5.01.8 1.1

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_010310_01.txt

HBD-CF4

94.3

It seems elevated analyzer values have little effect on Trans. Results!

Note: Last scan is done at about the same time a spike appears! 7

Page 8: HBD-CF4Transmittance (The case of the Anomalous O2 Spikes) HBD Meeting 1/5/2010 B.Azmoun, S.Stoll Brookhaven National Lab.

01/04/10 Scan of HBD-CF401/04/10 Scan of HBD-CF4

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Wavelength [Angstroms]

Transmittance (HBD IN) Raw Data

FIT fcn.(Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe (Fit ppms:108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

1.6 0.699.299.2

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_010410_01.txt

HBD-CF49.5

0.0 0.9

98.0

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Wavelength [Angstroms]

Transmittance (HBD WEST)Raw Data

FIT fcn. (Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe(Fit ppms:108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

20.3 3.592.291.9

4.752.9 2.8

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_010410_01.txt

HBD-CF4

92.10.00

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Wavelength [Angstroms]

Transmittance (HBD EAST) Raw Data

FIT fcn.(Fit:120-180nm)

Smpl. Scan:

Ref . Scan:

Scan Type:Gas Flow: slpmAnlz: H= ppm, O= ppmTrans: H = ppm, O= ppm%Npe(Fit ppms: 108-200nm)= %Int. Trans.(Fit: 112-186nm)= %Int. Trans.(Data: 134-168nm)=

22.2 2.991.991.7

4.752.3 1.5

SpectVessel-Ar_Cells-Vac_122909_01.txt

SpectVessel-Ar_Cells-HBD-CF4_010410_01.txt

HBD-CF4

92.0

It seems elevated analyzer values have little effect on Trans. Results!

Note: 2nd scan is done at about the same time a spike appears! 8