Hazardous Materials 2020 Business Plans / CERS

Published by NES© 2020 NES, All Rights Reserved

NES, Inc.1141 Sibley Street, Folsom, CA 95630 (916) 353-2360 / 1-800-NES-ADVISE

By:

Prepared & Presented on Behalf Of:

2020Hazardous Materials Business Plans / CERSStudent Resource Packet

Table of Contents

Presentation ............................................................................................................... 1

HMBP Overview ................................................................................................... 2

Definitions ............................................................................................................. 4

Applicability........................................................................................................... 9

Submittals & Recertifications .............................................................................. 15

Employee Training Requirements ...................................................................... 22

Spill Reporting Requirements ............................................................................. 33

CalEPA New Federal Hazard Categories ................................................................ 37

Cross-Walk: Old and New Physical and Health Hazards ......................................... 41

Facility Site Plan and Storage Map for Use with CERS Electronic Reporting .......... 43

CERS Consolidated Emergency Response / Contingency Plan Form ..................... 45

OSHA Quick Card: Hazard Communication Standard Labels ................................. 49

OSHA Quick Card: Hazard Communication Standard Pictogram ............................ 51

Safety Data Sheet: Acetone ..................................................................................... 53

Cal OES California Hazardous Materials Spill/Release Notification Guidance ........ 63

Hazardous Materials Business Plans / CERS

www.NESgloba l .ne t


HSC Division 20, Chapter 6.95, Article 1

• The objectives of this training program are to:▪ Cover California’s Hazardous Materials Business Plan (HMBP)

reporting requirements

▪ Review the California Environmental Reporting System (CERS)

Objectives

1 of 82


• Topics to be covered within this program:▪ HMBP Overview

▪ Definitions

▪ Applicability

▪ Submittals & Recertifications

▪ Employee Training Requirements

▪ Spill Reporting Requirements

Outline

HMBP Overview

2 of 82


• HMBP program established in 1986

• Goal is to prevent potential damage to public health or theenvironment from the release of hazardous materials

• Requirements outlined in California Health and SafetyCode (HSC) Division 20, Chapter 6.95, Article 1

HMBP Overview

• Statutes enforced by the Certified Unified Program Agency(CUPA)▪ Merced County Department of Public Health

• Based on the Emergency Planning and Community Right-to-Know Act (EPCRA)

HMBP Overview

3 of 82


Definitions

HSC 25501(n)

Definitions

A hazardous material is a material that, because of its quantity, concentration, or physical or chemical characteristics, poses a significant present or potential hazard to human health and safety or to the environment if released into the workplace or environment.

4 of 82


• Hazardous materials include:▪ Products for which the manufacturer is required to prepare a

Safety Data Sheet (SDS)

▪ Listed radioactive materials

▪ DOT-regulated hazardous materials

▪ Hazardous substances listed in Title 8 California Code ofRegulations (CCR) §339

▪ Hazardous waste (RCRA and non-RCRA)

HSC 25501(n)

Definitions

8 CCR 5194(c)

Definitions

A hazardous chemical is any chemical that is classified as a physical or health hazard, simple asphyxiant, combustible dust, pyrophoric gas, or hazard not otherwise classified or is included in the List of Hazardous Substances prepared by the Director pursuant to Labor Code section 6382.

5 of 82


49 CFR 171.8

Definitions

A hazardous material is a substance or material that the Secretary of Transportation has determined is capable of posing an unreasonable risk to health, safety, and property when transported in commerce and has been designated as hazardous under section 5103 of federal hazardous materials transportation law.

HSC 25501(m)

Definitions

A handler is a business that handles a hazardous material.

6 of 82


HSC 25501(l)

Definitions

Handle means to use, generate, process, produce, package, treat, store, emit, discharge, or dispose of a hazardous material in any fashion.

• Store does NOT include:▪ Storage of hazardous materials incidental to transportation (per

49 CFR §171.8)

HSC 25501(l)

Definitions

7 of 82


HSC 25501(o)

Definitions

Office is the Governor’s Office of Emergency Services (Cal OES).

HSC 25501(p)

Definitions

A release is any spilling, leaking, pumping, pouring, emitting, emptying, discharging, injecting, escaping, leaching, dumping, or disposing into the environment (unless permitted or authorized by a regulatory agency).

8 of 82


HSC 25501(t)

Definitions

A threatened release is a condition, circumstance, or incident that makes it necessary to take immediate action to prevent, reduce, or mitigate a release with the potential to cause damage or harm to persons, property, or the environment.

Applicability

9 of 82


• A business shall establish and implement an HMBP if it handles a hazardous material (including mixtures containing hazardous materials) at any one time during a reporting year equal to or greater than reporting thresholds:▪ 55 gallons for liquids

▪ 500 pounds for solids

▪ 200 cubic feet for compressed gases

HSC 25507(a)(1)

Applicability

• A business shall establish and implement an HMBP if it is required to submit chemical inventory per 42 U.S. Code §11022▪ Tier I

▪ Tier II

HSC 25507(a)(2)

Applicability

10 of 82


• A business shall establish and implement an HMBP if ithandles at any one time during the reporting year ahazardous material equal to or greater than the thresholdplanning quantity per 40 CFR §355:▪ Appendix A – List of Extremely Hazardous Substances

▪ Appendix B – List of Extremely Hazardous Substances

HSC 25507(a)(3)

Applicability

HSC 25507(a)(4)

Applicability

A business shall establish and implement an HMBP if it handles at any one time during the reporting year 5,000 pounds of solids or 550 gallons of liquids that are solely classified as irritants or sensitizers per 8 CCR §5194.

11 of 82


• A business shall establish and implement an HMBP if it handles at any one time during the reporting year 1,000 cubic feet of a cryogenic, refrigerated, or compressed:▪ Gas that is only hazardous due to simple asphyxiation or

release of pressure

▪ Oxygen, nitrogen, or nitrous oxide maintained by a physician, dentist, podiatrist, veterinarian, pharmacist, or emergency medical service provider

▪ [Continued…]

HSC 25507(a)(5)

Applicability

▪ Carbon dioxide

▪ Nonflammable refrigerant gases

▪ Gases used in closed fire suppression systems

HSC 25507(a)(5)

Applicability

12 of 82


HSC 25507(a)(6)

Applicability

A business shall establish and implement an HMBP if it handles at any one time during the reporting year a radioactive material that requires an emergency plan per Chapter 1 of Title 10 CFR.

• A business shall establish and implement an HMBP if ithandles perchlorate material at any one time during a yearequal to or greater than reporting thresholds:▪ 55 gallons for liquids

▪ 500 pounds for solids

▪ 200 cubic feet for compressed gases

HSC 25507(a)(7)

Applicability

13 of 82


• A business shall establish and implement an HMBP if it handles a metal alloy that is a pyrophoric or water-reactive material at any one time during a year:▪ 100 pounds for combustible metal, metal alloy defined as

combustible dust, flammable solid, or magnesium

▪ 500 pounds for combustible metal or metal alloy that poses an explosive potential in molten form

HSC 25507(a)(8)

Applicability

• The following hazardous materials are exempt:▪ Refrigerant gases in a cooling system used for comfort or space

cooling for computer rooms

▪ Compressed air in cylinders, bottles, and tanks used by fire departments or other emergency response organizations

▪ Lubricating oil < 55 gallons of each type and total not more than 275 gallons

▪ [Continued…]

HSC 25507(b)

Exemptions

14 of 82


▪ Hazardous materials contained in consumer products at retailestablishments

▪ Propane not more than 500 gallons used for cooking, heatingemployee work areas, and heating water

HSC 25507(b)

Exemptions

Submittals & Recertifications

15 of 82


HMBP Submittals & Recertification

• HMBPs must be submitted electronically to CERS

• HMBPs must be recertified annually by March 1st

https://cersbusiness.calepa.ca.gov

HSC 25505


• Business owner/operator information▪ Site address

▪ Operator name & phone

▪ Owner name & phone

▪ Billing contact

▪ Primary emergency contact

▪ Secondary emergency contact

▪ Environmental contact

16 of 82


HSC 25505


• Business activities▪ Hazardous materials

▪ Underground storage tanks

▪ Hazardous waste

ᵒ Generate

ᵒ Treat

ᵒ Consolidate

▪ Excluded or exemptedrecyclable materials

▪ Aboveground petroleumstorage

▪ Regulated substances –California Accidental ReleasePrevention Program

HSC 25505


• Chemical inventory▪ Chemical name

▪ Common name

▪ CAS number

▪ Physical state

▪ Type

ᵒ Pure

ᵒ Mixture

ᵒ Waste

▪ Hazard classes & categories

▪ Location

▪ Amount

▪ Largest container

17 of 82


HSC 25505


• As of December 28, 2017, CalEPA replaced the existing 5 hazard categories with 24 federal hazard categories

Physical Hazard Pictograms

18 of 82


Health Hazard Pictograms

HSC 25505


• Site Map▪ North orientation

▪ Hazardous materials storage locations

▪ Gas/water/power shutoffs

▪ Storm drains

▪ Streets bordering facility

▪ Evacuation routes and assembly areas

19 of 82


HSC 25505


• Emergency Response / Contingency Plan▪ Emergency contacts

▪ Containment and cleanup procedures

▪ Evacuation procedures

▪ Emergency equipment

▪ Earthquake vulnerability

HSC 25505


• Employee Training Plan▪ Employees trained on

emergency response and evacuation procedures

20 of 82


• Preparation and submittal of the HMBPs also satisfiesrequirements for a Hazardous Materials Management Planand Inventory required by the California Fire Code

• HMBPs must be maintained, or made available, on-site

• Businesses on leased or rented property must notifyproperty owner in writing that a HMBP has been prepared▪ If a copy of the HMBP is requested, business owner must

provide a copy to the property owner within 5 working days

HSC 25508.1

HMBP Submittals & Recertifications

• HMBPs must be updated within 30 days in the case of:▪ 100% increase in quantity for a previously disclosed hazardous

material

▪ Handling of any previously undisclosed hazardous material thatequals or exceeds reporting thresholds

▪ Change of business or facility address

▪ Change of business ownership

▪ Change of business name

HSC 25508.1


21 of 82


• HMBPs must also be updated within 30 days in the case of:▪ Any substantial change in the handler’s operations that would

require modifications to the HMBPᵒ A substantial change is a change that would inhibit immediate response

during an emergency

HSC 25508.1


Employee Training Requirements

22 of 82


• All employees must be trained on:▪ Safety procedures in the event of a

release or threatened release of a hazardous material

▪ Notification contacts

▪ Procedures for mitigation of a release or threatened release of a hazardous material to minimize harm to people, property, or the environment

▪ Evacuation procedures

HSC 25505(a)(4)


• Training can take into consideration the position of each employee

• Training must be documented

• Training documentation must be made available for a minimum of three years

HSC 25505(a)(4)


23 of 82


• Flammables are gases and liquids that form an ignitable mixture with air▪ Gases

ᵒ Ignite at a concentration of 13% or less; OR

ᵒ Range of at least 12% between LFL and UFL

▪ Liquids

ᵒ Flash point of 199.4ºF or less (OSHA)

ᵒ Flash point of 140ºF or less (DOT)

• Examples:▪ Acetylene (2.5% – 100%)

▪ Propane (1.8% – 8.4%)

▪ Spray paint (1.8% – 9.5%)

▪ Acetone (-4ºF)

▪ Diesel (100ºF)

▪ Gasoline (-45ºF)

▪ Isopropyl alcohol (53ºF)

▪ Methanol (53ºF)

Flammables

• Compressed gases may present multiple hazards:▪ Asphyxiation

▪ Cryogenic

▪ Cylinder failure

• Examples:▪ Argon

▪ Carbon dioxide

▪ Nitrogen

Compressed Gases

24 of 82


• Evolve oxygen when heated

• Support combustion

• Never store oxidizers withflammables

• Examples:▪ Hydrogen peroxide

▪ Oxygen

▪ Potassium chlorate

▪ Potassium nitrate

▪ Silver nitrate

▪ Sodium nitrate

▪ Zinc nitrate

Oxidizers

• Poisons are substances that causeharm to living tissue

• Toxicity expressed in▪ LD50

▪ LC50

• Examples:▪ Arsenic (oral LD50 Rat = 763 mg/kg)

▪ Benzene (oral LD50 Rat = 930 mg/kg;inhalation LC50 Rat = 10,000 ppm)

▪ Cadmium (oral LD50 Rat = 2,330 mg/kg)

▪ Lead (oral LD50 = 450 mg/kg)

Poisons

25 of 82


Poisons

The lower the LD50 the more toxic the chemical is.

• Corrosives are solids and liquids that destroy skin or corrode metal

• Two types:▪ Acids (pH < 7)

▪ Bases (pH > 7)

• Acids and bases are not compatible

• Examples:▪ Hydrochloric acid (pH 0)

▪ Sulfuric acid (pH 0-1)

▪ Potassium hydroxide (pH 14)

▪ Sodium hydroxide (pH 14)

▪ Sodium hypochlorite (pH 13)

Corrosives

26 of 82


• Four routes by which a hazardousmaterial can enter your body:▪ Inhalation

▪ Absorption

▪ Ingestion

▪ Injection

Exposures

• Short duration

• High concentration

• Effects usually reversible

• Extended duration

• Low concentration

• Effects typically irreversible

Exposures

Acute Chronic

27 of 82


• Methods to control chemical exposures:▪ Engineering

ᵒ Ventilation, fume hoods, closed containers, replacing chemicals

▪ Administrativeᵒ Limiting exposure time, training, policies

▪ Personal protective equipment (PPE)ᵒ Safety glasses, chemical gloves

Exposures

Labels

• NFPA – National Fire Protection Association

• HMIS – Hazardous Materials Identification System

• DOT – Department of Transportation

• OSHA – Occupational Safety & Health Administration

28 of 82


• Colors▪ Blue: Health

▪ Red: Flammability

▪ Yellow: Reactivity

▪ White: Special Hazards

• Numbers▪ 4: Maximum Hazard

▪ 3: High Hazard

▪ 2: Moderate Hazard

▪ 1: Low Hazard

▪ 0: No Hazard

NFPA

• Colors▪ Blue: Health

▪ Red: Flammability

▪ Yellow: Reactivity

▪ White: Personal ProtectiveEquipment

• Numbers▪ 4: Maximum Hazard

▪ 3: High Hazard

▪ 2: Moderate Hazard

▪ 1: Low Hazard

▪ 0: No Hazard

HMIS

29 of 82


• CLASS 1 – Explosives

• CLASS 2 – Gases

• CLASS 3 – Flammable Liquids

• CLASS 4 – Flammable Solids

• CLASS 5 – Oxidizers

• CLASS 6 – Poisonous Materials

• CLASS 7 – Radioactive Materials

• CLASS 8 – Corrosive Materials

• CLASS 9 – Miscellaneous Hazardous Materials

DOT

• Must be used by manufacturers and distributors; includes:▪ Product and supplier information

▪ Precautionary statement

▪ Hazard statement

▪ Signal word: “Danger” or “Warning”

▪ Pictograms

OSHA

30 of 82


OSHA

• OSHA has 9 pictograms:▪ Health Hazard

▪ Flame

▪ Exclamation Mark

▪ Gas Cylinder

▪ Corrosion

▪ Exploding Bomb

▪ Flame-Over-Circle

▪ Environment (non-mandatory)

▪ Skull-and-Crossbones

Labels

• Comparison of labels foracetylene

31 of 82


Labels

• Comparison of labels for hydrochloric acid

• Safety Data Sheets (SDSs) must be maintained for all hazardous materials used on-site

• SDSs must be available to employees 24/7

• SDSs use a specific format that includes 16 sections

Safety Data Sheets

32 of 82


1. Identification

2. Hazard Identification

3. Composition/Ingredients

4. First Aid Measures

5. Fire Fighting Measures

6. Accidental Release Measures

7. Handling and Storage

8. Exposure Controls/PPE

9. Physical and Chemical Properties

10.Stability and Reactivity

11.Toxicological Information

12.Ecological Information (NOTMANDATORY)

13.Disposal Consideration (NOTMANDATORY)

14.Transport Information (NOTMANDATORY)

15.Regulation Information (NOTMANDATORY)

16.Other Information

Safety Data Sheets

Spill Reporting Requirements

33 of 82


• Upon discovery, any hazardous material release or threatened release must be immediately reported▪ Merced County Public Health

▪ Cal OESᵒ 800-852-7550

HSC 25510


• When reporting, provide:▪ Name of caller

▪ Location, date, and time of release

▪ Potential for impact to waterways or storm drains

▪ Hazardous material and amount released

HSC 25510


34 of 82


Thank You

Questions? Contact us at:N E S , I n c .

11 4 1 S i b l e y S t r e e tF o l s o m , C A 9 5 6 3 0

N E S g l o b a l . n e t9 1 6 - 3 5 3 - 2 3 6 08 0 0 - 6 3 7 - 2 3 8 4

35 of 82

36 of 82

Background: The California Environmental Protection Agency (CalEPA) Adopts the 24 New Federal Hazard Categories for use in Chemical Inventory Reporting of Annual 2018 Hazardous Materials Business Plan (HMBP) Submittals in the California Environmental Reporting System (CERS)

Effective December 28, 2017, CalEPA will replace the existing five (5) federal hazard categories available in CERS used for the completion of chemical inventories as part of the annual hazardous materials business plan submittal with twenty-four (24) new federal hazard categories adopted by the United States Environmental Protection Agency (U.S. EPA) as a result of changes to the Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (HCS). The table below depicts the existing and new federal hazard categories.

Table 1

Federal Hazard Categories Adopted by U.S. EPA

(40 CFR part 370.66)

Existing Categories

(CERS Data Fields 216a-216e)

NEW Categories

(New CERS Data Fields 216f-216cc)

PHYSICAL HEALTH HAZARD PHYSICAL HEALTH HAZARD

Fire Acute (Immediate) Flammable (gases, aerosols, liquids, or solids)

Carcinogenicity

Reactive Chronic (Delayed) Gas under pressure (compressed gas)

Acute toxicity (any route of exposure)

Sudden release of pressure

Explosive Reproductive toxicity

Self-heating Skin corrosion or irritation Pyrophoric (liquid or solid)

Respiratory or skin sensitization

Oxidizer (liquid, solid or gas)

Serious eye damage or eye irritation

Organic peroxide Specific target organ toxicity (single or repeated exposure)

Self-reactive Aspiration Hazard Pyrophoric gas Germ cell mutagenicity Corrosive to metal Simple asphyxiant In contact with water emits flammable gas

Hazard Not Otherwise Classified (HNOC)

Combustible dust Hazard Not Otherwise Classified (HNOC)

37 of 82

CalEPA Adopts the 24 New Federal Hazard Categories for use in the Chemical Inventory Reporting of the Annual Hazardous Materials Business Plan (HMBP) Submittals in CERS

Page 2 of 3

In June, 2016, the U.S. EPA amended its hazardous chemical reporting regulations (40 CFR part 370) as a result of changes to the OSHA HCS. OSHA’s HCS (29 CFR 1910.1200) was revised to conform to the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Core elements of the GHS include standardized hazard testing criteria, universal warning pictograms and harmonized SDSs. The revised OSHA HCS requires chemical manufacturers and importers to:

evaluate their chemicals according to the new criteria adopted from GHS to ensure chemicals are classified and labeled appropriately, and

develop standardized SDSs and distribute them to users of their chemicals.

To incorporate the adoption of the OSHA HCS, the U.S. EPA amended 40 CFR part 370 (Federal Register, Vol. 18, No. 113, June 13, 2016, page 38104) as it pertains to the implementation of EPCRA, and includes:

replacing the use of “Material Safety Data Sheets (MSDSs)” with “Safety Data Sheets (SDSs)” as both terms have the same meaning;

revising the definition of “hazardous chemical” to any chemical which is classified as a physical or health hazard, a simple asphyxiant, combustible dust, pyrophoric gas, or hazard not otherwise classified (HNOC); and

replacing the existing five federal hazard categories for list reporting (40 CFR part 370 section 311) and annual inventory reporting (40 CFR part 370 section 312) with 24 new physical and health hazard categories established by the GHS

The federal hazard categories used in completing chemical inventories of hazardous materials business plan submittals in CERS parallel the federal hazard categories utilized by U.S. EPA for Emergency Planning and Community Right-to-Know Act (EPCRA) reporting. This established equivalency between the California Hazardous Materials Release Response Plans and Inventory Program and U.S. EPA EPCRA reporting will remain in effect and will continue to benefit California businesses by eliminating the need for duplicate reporting when EPCRA requirements are applicable. Because the chemical inventory is completed utilizing the same federal hazard categories required by the U.S. EPA for EPCRA reporting, it is necessary to replace the existing 5 federal hazard categories with the new 24 federal hazard categories adopted by U.S. EPA in 40 CFR part 370. U.S. EPA reported in the Federal Register that adopting the new HCS hazard categories in place of the existing five federal hazard categories is supported by regulated businesses and the regulatory community as it is far less burdensome to replicate and compare chemical hazard information from the corresponding MSDS or SDS with the information provided on a list of hazardous chemicals and inventories. Utilizing the standardized categories of hazardous chemicals set forth by the OSHA HCS will also provide greater clarification and consistency and promote facilitation of emergency planning and response among the community regarding the presence of hazardous chemicals and the related physical effects of human and environmental health.

38 of 82

CalEPA Adopts the 24 New Federal Hazard Categories for use in the Chemical Inventory Reporting of the Annual Hazardous Materials Business Plan (HMBP) Submittals in CERS

Page 3 of 3

Though U.S. EPA has required use of the 24 new federal hazard categories for EPCRA since June 2016, states with their own reporting systems, such as California and CERS, are required to make the new federal hazard categories available to regulated business users by January 1, 2018.

CalEPA, CUPA data services vendors and UPA staff have been actively working on the development and implementation of CERS and local CUPA data systems to ensure regulated businesses will be able to submit chemical inventories utilizing the 24 new federal hazard categories in completing annual 2018 hazardous materials business plan submittals whether electronically reporting to CERS or the local CUPA data system.

For more information please contact:

Your local UPA (Directory: http://cersapps.calepa.ca.gov/Public/Directory) CalEPA Unified Program, [email protected] Dan Firth, CalEPA CERS Coordinator, at [email protected]

39 of 82

40 of 82

Cro

ss-W

alk:

Old

and

New

Phy

sica

l and

Hea

lth H

azar

ds

Phys

ical

Haz

ards

(O

SHA

orig

inal

- pr

ior t

o ad

optin

g G

HS

in 2

012)

Phys

ical

Haz

ards

(R

epor

ting

Yea

rs 1

987

– 20

16)

(OSH

A’s

orig

inal

phy

sical

haz

ards

con

solid

ated

into

thre

e ph

ysic

al h

azar

d ca

tego

ries f

or E

PA u

se)

Phys

ical

Haz

ards

(R

epor

ting

Yea

rs 2

017

and

beyo

nd)

(OSH

A’s

201

2 ph

ysic

al h

azar

ds th

at E

PA a

dopt

ed in

201

6)

Com

bust

ible

liqu

id

Fire

- (F

lam

mab

le; C

ombu

stib

le li

quid

; Pyr

opho

ric; O

xidi

zer)

Fl

amm

able

(gas

es, a

eros

ols,

liqui

ds, o

r sol

ids)

Flam

mab

le

Pyro

phor

ic (l

iqui

d or

solid

)

Oxi

dize

r Py

roph

oric

gas

Py

roph

oric

O

xidi

zer (

liqui

d, so

lid o

r gas

) C

ompr

esse

d G

as

Sudd

en R

elea

se o

f Pre

ssur

e –

(Exp

losi

ve; C

ompr

esse

d G

as)

Expl

osiv

e Ex

plos

ive

Gas

und

er p

ress

ure

Com

bust

ible

Dus

t C

orro

sive

Rea

ctiv

e –

(Uns

tabl

e R

eact

ive;

Org

anic

Per

oxid

e; W

ater

Rea

ctiv

e)

Self-

reac

tive

Org

anic

Per

oxid

e O

rgan

ic P

erox

ide

Uns

tabl

e R

eact

ive

Self-

heat

ing

Wat

er R

eact

ive

Cor

rosiv

e to

met

al

In c

onta

ct w

ith w

ater

em

its fl

amm

able

gas

Haz

ard

Not

Oth

erw

ise

Cla

ssifi

ed (H

NO

C)

Hea

lth H

azar

ds

(OSH

A o

rigin

al -

prio

r to

adop

ting

GH

S in

201

2)

Hea

lth H

azar

ds

(Rep

ortin

g Y

ears

198

7 –

2016

) (O

SHA

’s o

rigin

al h

ealth

haz

ards

con

solid

ated

into

two

heal

th h

azar

d ca

tego

ries f

or E

PA u

se)

Hea

lth H

azar

ds

Rep

ortin

g Y

ear

2017

and

bey

ond)

(O

SHA

’s 2

012

heal

th h

azar

ds th

at E

PA a

dopt

ed in

201

6)

Hea

lth H

azar

d (I

mm

edia

te-A

cute

)

Hig

hly

Toxi

c H

ighl

y To

xic;

Tox

ic; I

rrita

nt; S

ensi

tizer

; Cor

rosi

ves &

oth

er

haza

rdou

s che

mic

als t

hat c

ause

an

adve

rse

effe

ct to

a ta

rget

org

an

and

whi

ch e

ffec

t usu

ally

occ

urs r

apid

ly a

s a re

sult

of a

shor

t ter

m

expo

sure

and

is o

f sho

rt du

ratio

n.

Skin

Cor

rosi

on o

r Irr

itatio

n Ir

ritan

t A

cute

Tox

icity

(any

rout

e of

exp

osur

e Se

nsiti

zer

Res

pira

tory

or S

kin

Sens

itiza

tion

Toxi

c Se

rious

eye

dam

age

or e

ye ir

ritat

ion

Eye

Haz

ard

Sim

ple

Asp

hyxi

ant

Skin

Haz

ard

Asp

iratio

n H

azar

d H

ealth

Haz

ard

(Del

ayed

-Chr

onic

)

Kid

ney

Toxi

n C

arci

noge

ns &

oth

er h

azar

dous

che

mic

als t

hat c

ause

an

adve

rse

effe

ct to

a ta

rget

org

an a

nd w

hich

eff

ect g

ener

ally

occ

urs a

s a re

sult

of lo

ng te

rm e

xpos

ure

and

is o

f lon

g du

ratio

n.

Spec

ific

targ

et o

rgan

toxi

city

(sin

gle

or re

peat

ed e

xpos

ure)

Live

r Tox

in

Rep

rodu

ctiv

e To

xici

ty

Lung

Tox

in

Ger

m C

ell M

utag

enic

ity

Ner

vous

Sys

tem

Tox

in

Car

cino

geni

city

41 of 82

42 of 82

UN-020CERSMAP www.unidocs.org 1/2 - 12/28/09

FACILITY SITE PLAN AND STORAGE MAP FOR USE WITH CERS ELECTRONIC REPORTING

Complete This Map and Use the “Upload Document” Feature in CERS to Complete Your HMBP for Electronic Submittal

A Site Plan (public document) and Storage Map (confidential document) must be included with your Hazardous Materials Business Plan (HMBP). For relatively small facilities, these documents may be combined into one drawing. However, if combined, the combined Site Plan/Storage Map will become a public document. If you are concerned about displaying the storage locations of hazardous materials to the public, you must provide a separate facility Storage Map. Since these drawings are intended for use in emergency response situations, larger facilities (generally those with complex and/or multiple buildings) should provide an overall site plan and a separate storage map for each building/storage area. A blank Facility Site Plan/Storage Map sheet has been provided on the following page. You may complete that page or use any other drawing(s) that contain(s) the information required below. Scan and save your drawing(s) as Adobe Acrobat (PDF) or image files (e.g., JPG, BMP), then upload the files to the California Environmental Reporting System (CERS) with your HMBP.

Required Information:

1. Site Plan (public document): This drawing shall contain, at a minimum, the following information:

a. An indication of North Direction;b. Approximate scale (e.g., “1 inch = 10 feet”.);c. Date the map was drawn;d. All streets bordering the facility;e. Locations of all buildings and other structures;f. Parking lots and internal roads;g. Hazardous materials loading/unloading areas;h. Outside hazardous materials storage or use areas;i. Storm drain and sanitary sewer drain inlets;j. Wells for monitoring of underground tank systems;k. Primary and alternate evacuation routes, emergency exits, and primary and alternate staging areas.

2. Storage Map (confidential): The map(s) shall contain, at a minimum, the following information:

a. General purpose of each section/area within each building (e.g., “Office Area”, “Manufacturing Area”,etc.);

b. Location of each hazardous material/waste storage, dispensing, use, or handling area (e.g., individualunderground tanks, aboveground tanks, storage rooms, paint booths, etc.). Each area shall beidentifiable by a Grid Number, to be used in item 204 on the Hazardous Materials Inventory - ChemicalDescription pages of the Business Plan;

c. For tanks, the capacity limit in gallons and common name of the hazardous material contained in eachtank;

d. Entrances to and exits from each building and hazardous material/waste room/area;e. Location of each utility emergency shut-off point (i.e., gas, water, electric.);f. Location of each monitoring system control panel (e.g., underground tank monitoring, toxic gas

monitoring, etc.).

43 of 82

Facility Site Plan & Storage Map for Use With CERS Electronic Reporting – Page 2 of 2

UN-020CERSMAP www.unidocs.org 2/2 - 12/28/09

Facility Site Plan/Storage Map (Hazardous Materials Business Plan Module)

Site Address: Date Map Drawn: Map Scale:

A B C D E F G H I J K L M N O P Q R S T U V W X Y Z

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28 Instructions are printed on the previous page.

44 of 82

Rev. 03/07/17 Page 1 of 4

CALIFORNIA ENVIRONMENTAL REPORTING SYSTEM (CERS)

CONSOLIDATED EMERGENCY RESPONSE / CONTINGENCY PLAN Prior to completing this Plan, please refer to the INSTRUCTIONS FOR COMPLETING A CONSOLIDATED CONTINGENCY PLAN

A. FACILITY IDENTIFICATION AND OPERATIONS OVERVIEWFACILITY ID # A3.

BUSINESS NAME (Same as Facility Name or DBA - Doing Business As) A4.

BUSINESS SITE ADDRESS A5.

BUSINESS SITE CITY A6. ZIP CODE A7.

CA TYPE OF BUSINESS (e.g., Painting Contractor) A8. INCIDENTAL OPERATIONS (e.g., Fleet Maintenance) A9.

THIS PLAN COVERS CHEMICAL SPILLS, FIRES, AND EARTHQUAKES INVOLVING (Check all that apply): A10.

1. HAZARDOUS MATERIALS; 2. HAZARDOUS WASTES

B. INTERNAL RESPONSEINTERNAL FACILITY EMERGENCY RESPONSE WILL OCCUR BY (Check all that apply):

1. CALLING PUBLIC EMERGENCY RESPONDERS (e.g., 9-1-1) 2. CALLING HAZARDOUS WASTE CONTRACTOR3. ACTIVATING IN-HOUSE EMERGENCY RESPONSE TEAM

B1.

C. EMERGENCY COMMUNICATIONS, PHONE NUMBERS AND NOTIFICATIONSIn the event of an emergency involving hazardous materials and/or hazardous waste, all facilities must IMMEDIATELY: 1. Notify facility personnel and evacuate if necessary in accordance with the Emergency Action Plan (Title 8 California Code of Regulations §3220); 2. Notify local emergency responders by calling 9-1-1;3. Notify the local Unified Program Agency (UPA) at the phone number below; and4. Notify the State Warning Center at (800) 852-7550.

Facilities that generate, treat, store or dispose of hazardous waste have additional responsibilities to notify and coordinate with other response agencies. Whenever there is an imminent or actual emergency situation such as an explosion, fire, or release, the Emergency Coordinator must follow the appropriate requirements for the category of facility and type of release involved: 1. Title 22 California Code of Regulations §66265.56. Emergency Procedures for generators of 1,000 kilograms or more of hazardous waste in any calendar month. 2. Title 22 California Code of Regulations §66265.196. Response to Leaks or Spills and Disposition of Leaking or Unfit-for-Use Tank Systems.3. Title 40 Code of Federal Regulations §302.6. Notification requirements for a release of a hazardous substance equal to or greater than the reportable quantity.4. Title 22 California Code of Regulations §66262.34(d)(2) and Title 40 Code of Federal Regulations §262.34(d)(5)(ii) for generators of less than 1000 kilograms of

hazardous waste in any calendar month.

Following notification and before facility operations are resumed in areas of the facility affected by the incident, the Emergency Coordinator shall notify the local UPA and the local fire department’s hazardous materials program, if necessary, that the facility is in compliance with requirements to: 1. Provide for proper storage and disposal of recovered waste, contaminated soil or surface water, or any other material that results from an explosion, fire, or release at

the facility; and2. Ensure that no material that is incompatible with the released material is transferred, stored, or disposed of in areas of the facility affected by the incident until cleanup

procedures are completed.

EMERGENCY RESPONSE PHONE NUMBERS:

AMBULANCE, FIRE, POLICE AND CHP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9-1-1CALIFORNIA STATE WARNING CENTER (CSWC)/CAL OES. . . . . . . . . . . . . . . . . . . . . . . . . . . . (800) 852-7550

NATIONAL RESPONSE CENTER (NRC) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (800) 424-8802

POISON CONTROL CENTER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (800) 222-1222

LOCAL UNIFIED PROGRAM AGENCY (UPA) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .C1.

OTHER (Specify): C2. C3.

NEAREST MEDICAL FACILITY / HOSPITAL NAME: C4. C5.

AGENCY NOTIFICATION PHONE NUMBERS: CALIFORNIA DEPT. OF TOXIC SUBSTANCES CONTROL (DTSC) . . . . (916) 255-3545 REGIONAL WATER QUALITY CONTROL BOARD (RWQCB). . . . . . . .

C6.

U.S. ENVIRONMENTAL PROTECTION AGENCY (US EPA) . . . . . . . . . . . (800) 300-2193

CALIFORNIA DEPT. OF FISH AND WILDLIFE (CDFW) . . . . . . . . . . . . . . (916) 358-2900

U.S. COAST GUARD (USCG) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (202) 267-2180

CAL OSHA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (916) 263-2800 CAL FIRE OFFICE OF THE STATE FIRE MARSHAL (OSFM) . . . . . . . . . (916) 323-7390



A1. CERS ID # A2. DATE OF PLAN PREPARATION/REVISION — — (MM/DD/YYYY)

45 of 82

CERS Consolidated Emergency Response / Contingency Plan

Rev. 03/07/17 Page 2 of 4

INTERNAL FACILITY EMERGENCY COMMUNICATIONS OR ALARM NOTIFICATION WILL OCCUR BY (Check all that apply): C11.

1. VERBAL WARNINGS; 2. PUBLIC ADDRESS OR INTERCOM SYSTEM; 3. TELEPHONE; 4. PAGERS; 5. ALARM SYSTEM; 6. PORTABLE RADIO

NOTIFICATIONS TO NEIGHBORING FACILITIES THAT MAY BE AFFECTED BY AN OFF-SITE RELEASE WILL OCCUR BY (Check all that apply): C12.

1. VERBAL WARNINGS; 2. PUBLIC ADDRESS OR INTERCOM SYSTEM; 3. TELEPHONE; 4. PAGERS; 5. ALARM SYSTEM; 6. PORTABLE RADIO

C13.EMERGENCY COORDINATOR CONTACT INFORMATION:

PRIMARY EMERGENCY COORDINATOR NAME: PHONE NO.:

ALTERNATE EMERGENCY COORDINATOR NAME: PHONE NO.:

PHONE NO.:

PHONE NO.:

Check if additional Emergency Coordinator contact and address information is available onsite or by calling

Note: If more than one alternate emergency coordinator is designated, attach a list in order of responsibility.

D. EMERGENCY CONTAINMENT AND CLEANUP PROCEDURES Check the applicable boxes to indicate your facility’s procedures for containing spills and preventing and mitigating releases, fires and/or explosions.

1. MONITOR FOR LEAKS, RUPTURES, PRESSURE BUILD-UP, ETC.;D1.

2. PROVIDE STRUCTURAL PHYSICAL BARRIERS (e.g., Portable spill containment walls, built-in berms); 3. PROVIDE ABSORBENT PHYSICAL BARRIERS (e.g., Pads, spill pigs, spill pillows); 4. COVER OR BLOCK FLOOR AND/OR STORM DRAINS; 5. LINED TRENCH DRAINS AND/OR SUMPS; 6. AUTOMATIC FIRE SUPPRESSION SYSTEM; 7. ELIMINATE SOURCES OF IGNITION FOR FLAMMABLE HAZARDS; 8. STOP PROCESSES AND/OR OPERATIONS; 9. AUTOMATIC / ELECTRONIC EQUIPMENT SHUT-OFF SYSTEM; 10. SHUT OFF WATER, GAS, ELECTRICAL UTILITIES; 11. CALL 9-1-1 FOR PUBLIC EMERGENCY RESPONDER ASSISTANCE AND/OR MEDICAL AID; 12. NOTIFY AND EVACUATE PERSONS IN ALL THREATENED AND/OR IMPACTED AREAS; 13. ACCOUNT FOR EVACUATED PERSONS IMMEDIATELY AFTER EVACUATION; 14. PROVIDE PROTECTIVE EQUIPMENT FOR ON-SITE EMERGENCY RESPONSE TEAM; 15. REMOVE CONTAINERS AND/OR ISOLATE AREAS;

16. HIRE LICENSED HAZARDOUS WASTE CONTRACTOR; 17. USE ABSORBENT MATERIAL FOR SPILL CONTAINMENT; 18. VACUUM SUCTION USING APPROPRIATE VACUUM (e.g., Intrinsically safe) FOR SPILL CONTROL AND/OR CLEANUP;

19. DECONTAMINATE PERSONNEL AND EQUIPMENT WITHIN DESIGNATED AREA AND DISPOSE OF WASTEWATER AS HAZARDOUS WASTE; 20. PROVIDE SAFE TEMPORARY STORAGE OF HAZARDOUS WASTE GENERATED DURING EMERGENCY ACTIONS; 21. OTHER (Specify): D2.

E. FACILITY EVACUATIONTHE FOLLOWING ALARM SIGNAL(S) WILL BE USED TO BEGIN EVACUATION OF THE FACILITY (Check all that apply): E1.

1. BELLS; 2. HORNS/SIRENS; 3. VERBAL (i.e., Shouting); 4. OTHER (Specify):

E2.

THE FOLLOWING LOCATION(S) WILL BE USED FOR AN EMERGENCY ASSEMBLY AREA(S) (e.g., Parking lot, street corner): E3.

Note: The Emergency Coordinator must account for all onsite employees and visitors after evacuation. EVACUATION ROUTE S AND ALTERNATE EVACUATION ROUTES ARE DESCRIBED AS FOLLOWS: E4.

1. WRITTEN PROCEDURES DESCRIBING ROUTES, EXITS, AND ASSEMBLY AREAS; 2. EVACUATION MAP(S) DEPICTING ROUTES, EXITS, AND ASSEMBLY AREAS; 3. OTHER (Specify): E5.

Note: Evacuation procedures and/or maps should be posted in visible facility locations and must be included in the Contingency Plan.

F. ARRANGEMENTS FOR EMERGENCY SERVICES

ADVANCE ARRANGEMENTS FOR LOCAL EMERGENCY SERVICES (Check one of the following):

1. HAVE BEEN DETERMINED NOT NECESSARY;

F1.

2. THE FOLLOWING ARRANGEMENTS HAVE BEEN MADE (Specify): F2.

Note: Advance arrangements with local fire and police departments, hospitals, state and local emergency response teams, and/or emergency services contractors should be made for your facility, if necessary. Large Quantity Generators must describe arrangements in the Contingency Plan.

PHONE NO.:

46 of 82


Rev. 03/07/17 Page 3 of 4

G. EMERGENCY EQUIPMENTCheck the applicable boxes to list emergency response equipment available at the facility, identify the location(s) where the equipment is kept, and indicate the equipment’s capability, if applicable.

TYPE EQUIPMENT AVAILABLE G1. LOCATION G2. CAPABILITY G3.

EXAMPLE CHEMICAL PROTECTIVE GLOVES SPILL RESPONSE KIT SINGLE USE, OIL RESISTANT ONLY

Safety and First Aid

1. CHEMICAL PROTECTIVE SUITS, APRONS,AND/OR VESTS

2. CHEMICAL PROTECTIVE GLOVES

3. CHEMICAL PROTECTIVE BOOTS

4. SAFETY GLASSES, GOGGLES, AND FACE SHIELDS

5. HARD HATS

6. AIR-PURIFYING RESPIRATORS

7. SELF-CONTAINED BREATHING APPARATUS (SCBA)

8. FIRST AID KITS

9. PLUMBED EYEWASH FOUNTAIN AND/OR SHOWER

10. PORTABLE EYEWASH KITS AND/OR STATION

11. OTHER

Fire Fighting

12. PORTABLE FIRE EXTINGUISHERS

13. FIXED FIRE SUPPRESSION SYSTEMS AND/OR SPRINKLERS

14. FIRE ALARM BOXES

15. OTHER

Spill Control and Clean-Up

16. ALL-IN-ONE SPILL KIT

17. ABSORBENT MATERIAL

18. CONTAINER FOR USED ABSORBENT

19. BERM AND/OR DIKING EQUIPMENT

20. BROOM

21. SHOVEL

22. VACUUM

23. EXHAUST HOOD

24. SUMP AND/OR HOLDING TANK

25. CHEMICAL NEUTRALIZERS

26. GAS CYLINDER LEAK REPAIR KIT

27. SPILL OVERPACK DRUMS

28. OTHER

Communi- cations and Alarm Systems

29. TELEPHONES (e.g., Cellular)

30. INTERCOM AND/OR PA SYSTEM

31. PORTABLE RADIOS

32. AUTOMATIC ALARM CHEMICALMONITORING EQUIPMENT

Other 33. OTHER

34. OTHER

47 of 82


Rev. 03/07/17 Page 4 of 4

H. EARTHQUAKE VULNERABILITY

Identify areas of the facility that are vulnerable to hazardous materials releases due to seismic motion. These areas require immediate isolation and inspection. VULNERABLE AREAS (Check all that apply): H1. LOCATIONS (e.g., Shop, outdoor shed, lab): H2.

1. HAZARDOUS MATERIALS AND/OR WASTE STORAGE AREAS2. PROCESS LINES AND PIPING3. LABORATORY 4. WASTE TREATMENT AREA

Identify mechanical systems vulnerable to releases / spills due to earthquake-related motion. These systems require immediate isolation and inspection. VULNERABLE SYSTEMS AND/OR EQUIPMENT (Check all that apply): H3. LOCATIONS: H4.

1. SHELVES, CABINETS AND/OR RACKS2. TANKS AND SHUT-OFF VALVES3. PORTABLE GAS CYLINDERS4. EMERGENCY SHUT-OFF AND/OR UTILITY VALVES5. SPRINKLER SYSTEMS6. STATIONARY PRESSURIZED CONTAINERS (e.g., Propane tank)

I. EMPLOYEE TRAINING Employee training is required for all employees and/or contractors handling hazardous materials and/or hazardous wastes during normal and/or emergency operations. Most facilities will need to submit a separate Training Plan. However, your CUPA may accept this section as the Training Plan for some small facilities.Employee training plans may include the following content:

Applicable laws and regulations; Emergency response plans and procedures; Safety Data Sheets; Hazard communication related to health and safety; Methods for safe handling of hazardous substances; Hazards of materials and processes (e.g., fire, explosion, asphyxiation); Hazard mitigation, prevention and abatement procedures; Coordination of emergency response actions; Notification procedures for local emergency responders, CUPA,

Cal OES, and onsite personnel;

Communication and alarm systems; Personal protective equipment; Use and maintenance of emergency response equipment and supplies

(e.g. Fire extinguishers, respirators, spill control materials); Decontamination procedures; Evacuation procedures and evacuation staging locations; Identification of facility areas, equipment, and systems vulnerable to

earthquakes and other natural disasters.

OTHER (Specify):

Check the applicable boxes below to indicate how the employee training program is administered.

1. FORMAL CLASSROOM 2. VIDEOS 3. SAFETY MEETINGS 4. STUDY GUIDES / MANUALS I1.

5. OTHER (Specify): I2.

6. NOT APPLICABLE SINCE FACILITY HAS NO EMPLOYEES 7. CHECK IF A SEPARATE EMPLOYEE TRAINING PLAN IS USED AND UPLOADED TO CERS AS A PDF DOCUMENT 8. CHECK IF EMPLOYEE TRAINING IS COVERED BY THE ABOVE REFERENCED CONTENT AND OTHER DOCUMENTS ONSITE

I3. I4.

EMPLOYEE TRAINING FREQUENCY AND RECORDKEEPING TRAINING MUST BE: Provided initially for new employees as soon as possible following the date of hire. New employees should not work in an unsupervised position that involves

hazardous materials handling and/or hazardous waste management without proper training; Provided within six months from the date of hire for new employees at a large quantity generator; Ongoing and provided at least annually; Amended prior to a change in process or work assignment; Given upon modification to the Emergency Response/Contingency Plan.

Large Quantity Generator Training: Large quantity generators (1,000 kg or more) must retain written plan and documentation of employee training which includes: A written description of the type and amount of both initial and ongoing training that will be given to persons filling each job position having responsibility for hazardous

waste management and/or emergency response. The name, job title and job description for each position at the facility related to hazardous waste management. Current employee training records must be retained until closure of the facility and former employee training records must be retained for at least three years after

termination of employment.

Small Quantity Generator Training: Small quantity generators (less than 1,000 kg) must include basic hazardous waste management and emergency response procedures but a written employee training plan and training records are not required. In order to show that the facility has met the small quantity generator employee training requirement, an employee training plan and training records may be made available.

Hazardous Materials Business Plan Training: Businesses must provide initial and annual employee training that includes the content referenced above. The training may be based on the job position and training records must be made available for a period of at least three years.

J. LIST OF ATTACHMENTS Check one of the following:

1. NO ATTACHMENTS ARE REQUIRED; or J1.

2. THE FOLLOWING DOCUMENTS ARE ATTACHED: J2.

48 of 82

Pro

duct

Identi

fier

Sig

nal W

ord

Supplier

Identi

ficati

on

Haza

rdS

tate

ments

Haza

rd P

icto

gra

ms

Com

pany

Nam

e___

____

____

____

____

____

Stre

et A

ddre

ss__

____

____

____

____

____

__Ci

ty__

____

____

____

____

____

_ St

ate_

____

Post

al C

ode_

____

____

____

_Cou

ntry

____

_Em

erge

ncy

Phon

e N

umbe

r___

____

____

__

Hig

hly

flam

mab

le li

quid

and

vap

or.

May

cau

se li

ver

and

kidn

ey d

amag

e.

Keep

con

tain

er ti

ghtly

clo

sed.

Sto

re in

a c

ool,

wel

l-ven

tilat

ed p

lace

that

is lo

cked

.Ke

ep a

way

from

hea

t/spa

rks/

open

flam

e. N

o sm

okin

g.On

ly u

se n

on-s

park

ing

tool

s.Us

e ex

plos

ion-

proo

f ele

ctric

al e

quip

men

t.Ta

ke p

reca

utio

nary

mea

sure

s ag

ains

t sta

tic d

isch

arge

.Gr

ound

and

bon

d co

ntai

ner a

nd re

ceiv

ing

equi

pmen

t.Do

not

bre

athe

vap

ors.

Wea

r pro

tect

ive

glov

es.

Do n

ot e

at, d

rink

or s

mok

e w

hen

usin

g th

is p

rodu

ct.

Was

h ha

nds

thor

ough

ly a

fter h

andl

ing.

Disp

ose

of in

acc

orda

nce

with

loca

l, re

gion

al, n

atio

nal,

inte

rnat

iona

l reg

ulat

ions

as

spec

ified

.

In C

ase

of F

ire: u

se d

ry c

hem

ical

(BC)

or C

arbo

n Di

oxid

e (C

O 2)

fire

extin

guis

her t

o ex

tingu

ish.

Fir

st A

idIf

expo

sed

call

Pois

on C

ente

r.If

on s

kin

(or h

air):

Tak

e of

f im

med

iate

ly a

ny c

onta

min

ated

cl

othi

ng.

Rins

e sk

in w

ith w

ater

.Fi

ll w

eigh

t:___

____

____

_ L

ot N

umbe

r:___

____

____

Gros

s w

eigh

t:___

____

___

Fill

Dat

e:__

____

____

____

Expi

ratio

n Da

te:_

____

___

Danger

}

COD

E __

____

____

____

____

____

____

____

_Pr

oduc

t Nam

e___

____

____

____

____

____

_

Dire

ctio

ns fo

r Use

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

____

__

Pre

cauti

onary

Sta

tem

ents }S

upple

menta

l In

form

ati

on

} }

SA

MP

LE L

AB

EL

OS

HA

has

up

dat

ed t

he

req

uir

emen

ts f

or

lab

elin

g o

f

haz

ard

ou

s ch

emic

als

un

der

its

Haz

ard

Co

mm

un

icat

ion

S

tan

dar

d (

HC

S).

As

of

Jun

e 1,

201

5, a

ll la

bel

s w

ill b

e re

qu

ired

to

hav

e p

icto

gra

ms,

a s

ign

al w

ord

, haz

ard

an

d

pre

cau

tio

nar

y st

atem

ents

, th

e p

rod

uct

iden

tifi

er, a

nd

su

pp

lier

iden

tifi

cati

on

. A s

amp

le r

evis

ed H

CS

lab

el,

iden

tify

ing

th

e re

qu

ired

lab

el e

lem

ents

, is

sho

wn

on

th

e ri

gh

t. S

up

ple

men

tal i

nfo

rmat

ion

can

als

o b

e p

rovi

ded

on

th

e la

bel

as

nee

ded

.

For m

ore

info

rmat

ion:

Haza

rd C

omm

unic

atio

n St

anda

rd L

abel

s

(80

0) 3

21-

OS

HA

(6

74

2)

ww

w.o

sha.g

ov

OSHA 3492-02 2012

QU

ICK

C

AR

DT

M

49 of 82

50 of 82

As of June 1, 2015, the Hazard Communication Standard (HCS) will require pictograms on labels to alert users of the chemical hazards to which they may be exposed. Each pictogram consists of a symbol on a white background framed within a red border and represents a distinct hazard(s). The pictogram on the label is determined by the chemical hazard classification.

For more information:

Hazard Communication Standard Pictogram

OS

HA

349

1-02

201

2

• Gases Under Pressure • Skin Corrosion/ Burns

• Eye Damage• Corrosive to Metals

• Explosives• Self-Reactives• Organic Peroxides

Health Hazard Flame Exclamation Mark

• Carcinogen• Mutagenicity• Reproductive Toxicity• Respiratory Sensitizer• Target Organ Toxicity• Aspiration Toxicity

• Oxidizers

Gas Cylinder Corrosion Exploding Bomb

Flame Over Circle Environment Skull (Non-Mandatory) and Crossbones

• Flammables • Pyrophorics• Self-Heating• Emits Flammable Gas• Self-Reactives• Organic Peroxides

• Irritant (skin and eye)• Skin Sensitizer• Acute Toxicity (harmful)• Narcotic Effects• Respiratory Tract

Irritant• Hazardous to Ozone

Layer (Non-Mandatory)

• Aquatic Toxicity • Acute Toxicity (fatal or toxic)

HCS Pictograms and Hazards

U.S. Department of Laborwww.osha.gov (800) 321-OSHA (6742)

QUICK CARDTM

51 of 82

52 of 82

Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/12/1998 Revision date: 09/20/2016 Supersedes: 10/01/2013 Version: 1.2

09/20/2016 EN (English US) Page 1

SECTION 1: Identification 1.1. Identification Product form : Substance Substance name : Acetone Chemical name : 2-Propanone CAS No : 67-64-1 Product code : LC10420, LC10425 Formula : C3H6O Synonyms : 2-propanone / beta-ketopropane / dimethyl formaldehyde / dimethyl ketone / dimethylketal /

DMK (=dimethyl ketone) / keto propane / methyl ketone / pyroacetic acid / pyroacetic ether / pyroacetic spirit

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Solvent

Cleaning product Chemical raw material

1.3. Details of the supplier of the safety data sheet LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 [email protected] - www.labchem.com

1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887

SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture

GHS-US classification Flammable liquids Category 2 H225 Serious eye damage/eye irritation Category 2A H319 Specific target organ toxicity (single exposure) Category 3 H336 Full text of H statements : see section 16

2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) :

GHS02 GHS07

Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapor

H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness

Precautionary statements (GHS-US) : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P261 - Avoid breathing mist, spray, vapors P264 - Wash exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection, face protection, protective clothing, protective gloves P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position

53 of 82

mailto:[email protected]

Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

09/20/2016 EN (English US) 2/9

comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER or doctor/physician if you feel unwell P337 + P313 - If eye irritation persists: Get medical advice/attention P370 + P378 - In case of fire: Use dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2) to extinguish P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P501 - Dispose of contents/container to comply with local, state and federal regulations P235 - Keep cool

2.3. Other hazards Other hazards not contributing to the classification

: None.

2.4. Unknown acute toxicity (GHS US) Not applicable

SECTION 3: Composition/Information on ingredients 3.1. Substance Substance type : Mono-constituent

Name Product identifier % GHS-US classification Acetone (Main constituent)

(CAS No) 67-64-1 100 Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H336

Full text of hazard classes and H-statements : see section 16 3.2. Mixture Not applicable

SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory

arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital.

First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. First-aid measures after skin contact : Wash immediately with lots of water. Soap may be used. Do not apply (chemical) neutralizing

agents. Remove clothing before washing. Take victim to a doctor if irritation persists. First-aid measures after eye contact : Rinse immediately with plenty of water. Do not apply neutralizing agents. Take victim to an

ophthalmologist if irritation persists. First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not give

milk/oil to drink. Do not induce vomiting. Give activated charcoal. Call Poison Information Centre (www.big.be/antigif.htm). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital. Doctor: gastric lavage.

4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/injuries after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Feeling of weakness. Irritation of the respiratory

tract. Nausea. Vomiting. Headache. Central nervous system depression. Dizziness. Narcosis. Excited/restless. Drunkenness. Disturbed motor response. Respiratory difficulties. Disturbances of consciousness.

Symptoms/injuries after skin contact : ON CONTINUOUS EXPOSURE/CONTACT: Dry skin. Cracking of the skin. Symptoms/injuries after eye contact : Irritation of the eye tissue. Symptoms/injuries after ingestion : Dry/sore throat. Risk of aspiration pneumonia. Symptoms similar to those listed under

inhalation. AFTER ABSORPTION OF LARGE QUANTITIES: Irritation of the gastric/intestinal mucosa. Change in the blood composition. Change in urine output. Renal disease. Enlargement/disease of the liver.

Symptoms/injuries upon intravenous administration

: Not available.

Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Skin rash/inflammation. Dry/sore throat. Headache. Nausea. Feeling of weakness. Loss of weight. Possible inflammation of the respiratory tract.

54 of 82


09/20/2016 EN (English US) 3/9

4.3. Indication of any immediate medical attention and special treatment needed Obtain medical assistance.

SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Preferably: alcohol resistant foam. Water spray. Polyvalent foam. Alcohol-resistant foam. BC

powder. Carbon dioxide. Unsuitable extinguishing media : Solid water jet ineffective as extinguishing medium.

5.2. Special hazards arising from the substance or mixture Fire hazard : DIRECT FIRE HAZARD. Highly flammable. Gas/vapor flammable with air within explosion

limits. INDIRECT FIRE HAZARD. May be ignited by sparks. Gas/vapor spreads at floor level: ignition hazard. Reactions involving a fire hazard: see "Reactivity Hazard".

Explosion hazard : DIRECT EXPLOSION HAZARD. Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD. Heat may cause pressure rise in tanks/drums: explosion risk. may be ignited by sparks. Reactions with explosion hazards: see "Reactivity Hazard".

Reactivity : Upon combustion: CO and CO2 are formed. Violent to explosive reaction with many compounds. Prolonged storage: on exposure to light: release of harmful gases/vapours. Reacts violently with (strong) oxidizers: peroxidation resulting in increased fire or explosion risk.

5.3. Advice for firefighters Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Physical explosion risk:

extinguish/cool from behind cover. Do not move the load if exposed to heat. After cooling: persistant risk of physical explosion.

Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Large spills/in enclosed spaces: compressed

air apparatus. See "Material-Handling" to select protective clothing. Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Seal off low-lying areas. Close

doors and windows of adjacent premises. Stop engines and no smoking. No naked flames or sparks. Spark- and explosion-proof appliances and lighting equipment. Keep containers closed. Wash contaminated clothes.

6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area.

6.2. Environmental precautions Prevent spreading in sewers.

6.3. Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to

select material of containers. Plug the leak, cut off the supply. Dam up the liquid spill. Try to reduce evaporation. Measure the concentration of the explosive gas-air mixture. Dilute/disperse combustible gas/vapour with water curtain. Provide equipment/receptacles with earthing. Do not use compressed air for pumping over spills.

Methods for cleaning up : Take up liquid spill into inert absorbent material, e.g.: sand, earth, vermiculite. Scoop absorbed substance into closing containers. See "Material-handling" for suitable container materials. Spill must not return in its original container. Carefully collect the spill/leftovers. Damaged/cooled tanks must be emptied. Do not use compressed air for pumping over spills. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.

6.4. Reference to other sections See Heading 8. Exposure controls and personal protection.

55 of 82


09/20/2016 EN (English US) 4/9

SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean

contaminated clothing. Handle uncleaned empty containers as full ones. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Do not use compressed air for pumping over. Use spark-/explosionproof appliances and lighting system. Take precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Avoid prolonged and repeated contact with skin. Keep container tightly closed. Measure the concentration in the air regularly. Work under local exhaust/ventilation.

Hygiene measures : Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Heat sources,

Direct sunlight, incompatible materials. Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage temperature : 15 - 20 °C Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources. Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. reducing agents. strong acids. (strong)

bases. halogens. amines. Storage area : Store in a cool area. Keep out of direct sunlight. Store in a dry area. Store in a dark area.

Ventilation at floor level. Fireproof storeroom. Provide for an automatic sprinkler system. Provide for a tub to collect spills. Provide the tank with earthing. Meet the legal requirements.

Special rules on packaging : SPECIAL REQUIREMENTS: closing. with pressure relief valve. clean. opaque. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers.

Packaging materials : SUITABLE MATERIAL: steel. stainless steel. carbon steel. aluminium. iron. copper. nickel. bronze. glass. MATERIAL TO AVOID: synthetic material.

SECTION 8: Exposure controls/personal protection 8.1. Control parameters

Acetone (67-64-1) ACGIH ACGIH TWA (ppm) 500 ppm (Acetone; USA; Time-weighted average

exposure limit 8 h; TLV - Adopted Value) ACGIH ACGIH STEL (ppm) 750 ppm (Acetone; USA; Short time value; TLV -

Adopted Value) OSHA OSHA PEL (TWA) (mg/m³) 2400 mg/m³

OSHA OSHA PEL (TWA) (ppm) 1000 ppm

IDLH US IDLH (ppm) 2500 ppm

NIOSH NIOSH REL (TWA) (mg/m³) 590 mg/m³

NIOSH NIOSH REL (TWA) (ppm) 250 ppm

8.2. Exposure controls Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate

vicinity of any potential exposure. Personal protective equipment : Safety glasses. Gloves. Protective clothing. Face shield. High gas/vapor concentration: gas

mask with filter type A.

Materials for protective clothing : GIVE EXCELLENT RESISTANCE: No data available. GIVE GOOD RESISTANCE: butyl rubber. tetrafluoroethylene. GIVE LESS RESISTANCE: chlorosulfonated polyethylene. natural rubber. neoprene. polyurethane. PVA. styrene-butadiene rubber. GIVE POOR RESISTANCE: nitrile rubber. polyethylene. PVC. viton. nitrile rubber/PVC.

Hand protection : Gloves.

56 of 82


09/20/2016 EN (English US) 5/9

Eye protection : Safety glasses. Skin and body protection : Head/neck protection. Protective clothing. Respiratory protection : Wear gas mask with filter type A if conc. in air > exposure limit. Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Color : Colourless Odor : Aromatic odour Sweet odour Fruity odour Odor threshold : 306 - 653 ppm

737 - 1574 mg/m³ pH : 7 Melting point : -95 °C Freezing point : No data available Boiling point : 56 °C Critical temperature : 235 °C Critical pressure : 47010 hPa Flash point : -18 °C Relative evaporation rate (butyl acetate=1) : 6 Relative evaporation rate (ether=1) : 2 Flammability (solid, gas) : Non flammable. Vapor pressure : 247 hPa (20 °C) Vapor pressure at 50 °C : 828 hPa (50 °C) Relative vapor density at 20 °C : 2.0 Relative density : 0.79 Relative density of saturated gas/air mixture : 1.2 Specific gravity / density : 786 kg/m³ Molecular mass : 58.08 g/mol Solubility : Soluble in water. Soluble in ethanol. Soluble in ether. Soluble in dimethyl ether. Soluble in

petroleum spirit. Soluble in chloroform. Soluble in dimethylformamide. Soluble in oils/fats. Water: Complete Ethanol: Complete Ether: Complete

Log Pow : -0.24 (Test data) Auto-ignition temperature : 465 °C Decomposition temperature : No data available Viscosity, kinematic : 0.417 mm²/s Viscosity, dynamic : 32 mPa.s (20 °C; 0,27 mPa.s; 40 °C) Explosion limits : 2 - 12.8 vol %

60 - 310 g/m³ Explosive properties : No data available. Oxidizing properties : None.

9.2. Other information Minimum ignition energy : 1.15 mJ Specific conductivity : 500000 pS/m Saturation concentration : 589 g/m³ VOC content : 100 % Other properties : Gas/vapour heavier than air at 20°C. Clear. Highly volatile. Substance has neutral reaction.

SECTION 10: Stability and reactivity 10.1. Reactivity Upon combustion: CO and CO2 are formed. Violent to explosive reaction with many compounds. Prolonged storage: on exposure to light: release of harmful gases/vapours. Reacts violently with (strong) oxidizers: peroxidation resulting in increased fire or explosion risk.

57 of 82


09/20/2016 EN (English US) 6/9

10.2. Chemical stability Unstable on exposure to light.

10.3. Possibility of hazardous reactions Not established.

10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures.

10.5. Incompatible materials Strong acids. Strong bases.

10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects Likely routes of exposure : Inhalation; Skin and eye contact

Acute toxicity : Not classified

Acetone (67-64-1) LD50 oral rat 5800 mg/kg (Rat; Equivalent or similar to OECD 401; Experimental value) LD50 dermal rabbit 20000 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >7426 mg/kg

bodyweight; Rabbit; Weight of evidence) LC50 inhalation rat (mg/l) 71 mg/l/4h (Rat; Experimental value; 76 mg/l/4h; Rat; Experimental value) LC50 inhalation rat (ppm) 30000 ppm/4h (Rat; Experimental value) ATE US (oral) 5800.000 mg/kg body weight ATE US (dermal) 20000.000 mg/kg body weight ATE US (gases) 30000.000 ppmV/4h ATE US (vapors) 71.000 mg/l/4h ATE US (dust, mist) 71.000 mg/l/4h

Skin corrosion/irritation : Not classified pH: 7

Serious eye damage/irritation : Causes serious eye irritation. pH: 7

Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified

Based on available data, the classification criteria are not met Carcinogenicity : Not classified

Reproductive toxicity : Not classified Based on available data, the classification criteria are not met

Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness.

Specific target organ toxicity (repeated exposure)

: Not classified

Aspiration hazard : Not classified

Potential Adverse human health effects and symptoms

: Based on available data, the classification criteria are not met.

Symptoms/injuries after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Feeling of weakness. Irritation of the respiratory tract. Nausea. Vomiting. Headache. Central nervous system depression. Dizziness. Narcosis. Excited/restless. Drunkenness. Disturbed motor response. Respiratory difficulties. Disturbances of consciousness.

Symptoms/injuries after skin contact : ON CONTINUOUS EXPOSURE/CONTACT: Dry skin. Cracking of the skin. Symptoms/injuries after eye contact : Irritation of the eye tissue. Symptoms/injuries after ingestion : Dry/sore throat. Risk of aspiration pneumonia. Symptoms similar to those listed under

inhalation. AFTER ABSORPTION OF LARGE QUANTITIES: Irritation of the gastric/intestinal mucosa. Change in the blood composition. Change in urine output. Renal disease. Enlargement/disease of the liver.

58 of 82


09/20/2016 EN (English US) 7/9

Symptoms/injuries upon intravenous administration

: Not available.

Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Skin rash/inflammation. Dry/sore throat. Headache. Nausea. Feeling of weakness. Loss of weight. Possible inflammation of the respiratory tract.

SECTION 12: Ecological information 12.1. Toxicity Ecology - general : Not classified as dangerous for the environment according to the criteria of Directive

67/548/EEC. Not classified as dangerous for the environment according to the criteria of Regulation (EC) No 1272/2008.

Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Not included in the list of substances which may contribute to the greenhouse effect (Regulation (EC) No 842/2006). TA-Luft Klasse 5.2.5.

Ecology - water : Not harmful to fishes (LC50(96h) >1000 mg/l). Not harmful to invertebrates (Daphnia). Not harmful to algae (EC50 >1000 mg/l). Not harmful to plankton. Inhibition of activated sludge.

Acetone (67-64-1) LC50 fish 2 5540 mg/l (LC50; EU Method C.1; 96 h; Salmo gairdneri; Static system; Fresh water;

Experimental value) EC50 Daphnia 2 12600 mg/l (LC50; Other; 48 h; Daphnia magna; Static system; Fresh water; Experimental

value)

12.2. Persistence and degradability Acetone (67-64-1) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under

anaerobic conditions. No test data on mobility of the substance available. Biochemical oxygen demand (BOD) 1.43 g O₂/g substance Chemical oxygen demand (COD) 1.92 g O₂/g substance ThOD 2.20 g O₂/g substance BOD (% of ThOD) 0.872 (20 days; Literature study)

12.3. Bioaccumulative potential Acetone (67-64-1) BCF fish 1 0.69 (BCF) BCF other aquatic organisms 1 3 (BCF; BCFWIN) Log Pow -0.24 (Test data)Bioaccumulative potential Not bioaccumulative.

12.4. Mobility in soil Acetone (67-64-1) Surface tension 0.0237 N/m

12.5. Other adverse effects

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not

be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Recycle by distillation. Remove to an authorized waste incinerator for solvents with energy recovery. Do not discharge into drains or the environment.

Additional information : LWCA (the Netherlands): KGA category 03. Hazardous waste according to Directive 2008/98/EC.

Ecology - waste materials : Avoid release to the environment.

59 of 82


09/20/2016 EN (English US) 8/9

SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1090 Acetone, 3, II

UN-No.(DOT) : UN1090 Proper Shipping Name (DOT) : Acetone Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Packing group (DOT) : II - Medium Danger Hazard labels (DOT) : 3 - Flammable liquid

DOT Packaging Non Bulk (49 CFR 173.xxx) : 202 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Special Provisions (49 CFR 172.102) : IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite

(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling

DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27)

: 5 L

DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75)

: 60 L

DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded

Other information : No supplementary information available.

SECTION 15: Regulatory information 15.1. US Federal regulations

Acetone (67-64-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory RQ (Reportable quantity, section 304 of EPA's List of Lists) 5000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard

Fire hazard

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory

This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.

15.2. International regulations CANADA

Acetone (67-64-1) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class B Division 2 - Flammable Liquid

Class D Division 2 Subdivision B - Toxic material causing other toxic effects

60 of 82


09/20/2016 EN (English US) 9/9

EU-Regulations No additional information available

National regulations

Acetone (67-64-1) Listed on the Canadian IDL (Ingredient Disclosure List)

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information Revision date : 09/20/2016 Other information : None.

Full text of H-phrases: see section 16: ------ H225 Highly flammable liquid and vapor ------ H319 Causes serious eye irritation ------ H336 May cause drowsiness or dizziness

NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given.

NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all ambient conditions.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature

conditions. Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)

Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives.

Personal protection : C C - Safety glasses, Gloves, Synthetic apron

SDS US LabChem

Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application.

61 of 82

62 of 82

CaliforniaHazardous Materials

Spill / ReleaseNotification Guidance

February 2014

To Report all significant releases or threat-ened releases of hazardous materials:

First Call:9-1-1

(or local emergency response agency)

Then Call:Cal OES State Warning Center(800) 852 - 7550 or (916) 845 - 8911

63 of 82

Edmund G. Brown Jr., GovernorMark S. Ghilarducci, DirectorRevised by: Trevor Anderson, Bill Potter & Jon KolmanLayout by: Jon Kolman

February 2014

This guidance summarizes pertinent emergency notification requirements. For precise legal requirements, review specific laws and regulations. This guidance applies to all significant re-leases of hazardous materials. Refer to the Safe Drinking Water Act of 1986, better known as Proposition 65, and §9030 of the California Labor Code for additional reporting requirements.

The State of California makes no warranty, expressed or im-plied, and assumes no liability for omissions or errors con-tained in this publication.

64 of 82

SPILL OR RELEASE NOTIFICATIONQ: What are the emergency notification requirements in case of a spill or release of hazardous materials?A: All significant releases or threatened releases of a hazardous material, including oil and radioactive materials, require emer-gency notification to government agencies. The law specifies:• Who must notify• What information is needed• Which government agencies must be notified• When must government agencies be notified• Release quantity or basis for the report

WHO MUST NOTIFYQ: Who is obligated to notify?A: Requirements for immediate notification of all significant spills or threatened releases cover:• Owners• Operators• Licensees• Persons in Charge• EmployersNotification is required regarding significant releases from:• Facilities• Vehicles• Vessels• Pipelines• Railroads

State law: Handlers, any employees, authorized representa-tives, agent or designees of handlers shall, upon discovery, im-mediately report any release or threatened release of hazardous materials (Health and Safety Code §25510).

Federal law: Notification to the National Response Center is required for all releases that equal or exceed federal reporting quantities:• (EPCRA) Owners and Operators to report, and• (CERCLA) Person in Charge to report

3

65 of 82

WHEN TO NOTIFYQ: When must emergency notification be made?A: All significant spills or threatened releases of hazardous materials, including oil and radioactive materials, must be im-mediately reported. Notification shall be made by telephone.

Also, written Follow-Up Reports (Section 304) are required within 7 days if the release equals or exceeds the Federal Re-portable Quantities. (see web site for more information)

WHAT INFORMATIONQ: What information is required?A: State notification requirements for a spill or threatened release include (as a minimum):• Identity of caller• Exact location, date and time of spill, release or threatened

release• Location of threatened or involved waterway or

stormdrains• Substance, quantity involved, and isotope if necessary• Chemical name (if known, it should be reported if the

chemical is extremely hazardous)• Description of what happened

Federal notification required additional information for spills (CERCLA chemicals) that exceed federal reporting require-ments, which includes:• Medium or media impacted by the release• Time and duration of the release• Proper precautions to take• Known or anticipated health risks• Name and phone number for more information

4

66 of 82

WHICH AGENCIESQ: Who must be notified?A: Notification must be given to the following agencies:• The Local Emergency Response Agency

9-1-1 or the local Fire Department• The Local Unified Program Agency (UPA), if

different from local fire.Note: The UPA may designate a call to the 9-1-1 emergency number as meeting the requirement for notifying the UPA.

Phone:______________________________ enter local number

And

• The California Governor’s Office of Emergen-cy Services, California State Warning Center:

Phone (800) 852-7550 or (916) 845-8911

And, if appropriate:

• The California Highway Patrol:Phone: 9-1-1

(The California Highway Patrol must be notified for spills oc-curing on highways in the State of California. (CVC 23112.5))

5

67 of 82

In Addition, as necessary, one or more of the following:

National Response CenterIf the spill equals or exceeds CERCLA Federal Report-

able Quantities, Phone: (800) 424-8802United States Coast Guard

Waterway Spill / Release Sectors:

San Francisco: (415) 399-3547Los Angeles/Long Beach: (310) 521-3805San Diego: (619) 278-7033

California Occupational Safety and Health Administra- tion (Cal/OSHA)

For serious injuries or harmful exposures to workers, contact the local Cal/OSHA District Office

California Department of Health Services, Radiological Health Branch

All radiological incidents, contact the California State Warning Center

Department of Toxic Substances Control (DTSC)Hazardous waste tank system releases, and secondary containment containment releases, contact the appropri-

ate DTSC Regional OfficeDepartment of Conservation

Division of Oil, Gas, and Geothermal Resources (DOG GR) Release of Oil and Gas at a Drilling and Production Facility, contact the appropriate DOGGR Office

Public UtilitiesNatural Gas Pipeline Releases, contact the Public Utilities Commission (PUC)

Department of Fish and Wildlife, Office of Spill Preven- tion and Response (DFW)

Waterway Spill/Release, contact the appropriate DFW Office or the California State Warning Center

Regional Water Quality Control Board (RWQCB)Waterway Spill/Release, contact the appropriate RWQCB

Office

6

68 of 82

Notification must also be made to the California Governor’s Office of Emergency Services, California State Warning Center for the following:• Discharges or threatened discharges of oil in marine

waters• Any spill or other release of one barrel (42 gallons) or

more of petroleum products at a tank facility• Discharges of any hazardous substances or sewage, into or

on any waters of the state• Discharges that may threaten or impact water quality• Any found or lost radioactive materials• Discharges of oil or petroleum products, into or on any

waters of the state• Hazardous Liquid Pipeline releases and every rupture,

explosion or fire involving a pipeline

WRITTEN REPORTSQ: When are written reports required?A: Different laws have different time requirements and cri-teria for submitting written reports. After a spill or release of hazardous materials, including oil and radioactive materials, immediate verbal emergency notification should be followed up as soon as possible with a Written Follow-Up Report, if required, to the following agencies:

1) California Governor’s Office of Emergency ServicesSection 304 Follow Up Report.

2) The responsible regulating agency such as:• California Department of Health Services, Radiological

Health Branch, Radiological Incident Reporting.• Department of Toxic Substances Control, Facility Incident

or Tank System Release Report.• Cal/OSHA, serious injury or harmful exposure to workers.

3) U.S. DOT and DOE, transportation-related incidents.

7

69 of 82

PENALTIESFederal and state laws provide for administrative penalties of up to $25,000 per day for each violation of emergency notifica-tion requirements. Criminal penalties may also apply.

STATUTESQ: What statutory provisions require emergency notification?A: Many statutes require emergency notification of a hazard-ous chemical release, including:• Health and Safety Code §25270.8, 25510• Vehicle Code §23112.5• Public Utilities Code §7673 (General Orders #22-B, 161)• Government Code §51018, 8670.25.5 (a)• Water Code §13271, 13272• California Labor Code §6409.1 (b)• Title 42, U.S. Code §9603, 11004

Q: What are the statutory provisions for written Follow-Up Reports (Section 304)?A: Written reports are required by several statutes, including:• Health and Safety Code §25503 (c) (9)• California Labor Code §6409.1 (a)• Water Code §13260, 13267• Title 42, U.S. Code §11004• Government Code §51018

REGULATIONSIn addition to statutes, several agencies have notification or reporting regulations:• Title 8, CCR, §342• Title 13, CCR, §1166• Title 14, CCR, §1722 (h)• Title 17, CCR, §30295• Title 19, CCR, §2703, 2705• Title 22, CCR, §66265.56 (j), 66265.196 (e)• Title 23, CCR, §2230, 2250, 2251, 2260• Title 40, CFR, §263 esp. Section §263.30• Title 49, CFR, §171.16

8

70 of 82

WEBSITESState Regulationshttp://www.oal.ca.gov

State Statuteshttp://leginfo.legislature.ca.gov

Federal Regulationshttp://www.gpo.gov/fdsys/

Federal Reportable Quantitieshttp://www.epa.gov/superfund/policy/release/rq/index.htm

See California Labor Code §9030 and the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) for other reporting requirements.

DEFINITIONSQ: What is a “Hazardous Material”?A: “Any material that, because of its quantity, concentration, or physical or chemical characteristics, poses a significant present or threatened hazard to human health and safety or to the environment, if released into the workplace or the environ-ment....” (Health and Safety Code, §25501 (m))

Q: What is a release?A: “Any spilling, leaking, pumping, pouring, emitting, empty-ing, discharging, injecting, escaping, leaching, dumping, or dis-posing into the environment, unless permitted or authorized by a regulatory agency”.(Health and Safety Code, §25501 (q) and CERCLA §101 (22))

Q: What is a threatened release?A: A threatened release is a condition creating a substantial probability of harm that requires immediate action to prevent, reduce, or mitigate damages to persons, property, or the envi-ronment. (Health and Safety Code §25501 (u))

9

71 of 82

DEFINITIONS...contQ: What hazardous material release requires notification?A: All significant spills, releases, or threatened releases of haz-ardous materials must be immediately reported.

In addition, all releases that result in injuries, or workers harm-fully exposed, must be immediately reported to Cal/OSHA (CA Labor Code §6409.1 (b)). Notification covers significant releases or threatened releases relating to all of the following:

“Hazardous Substances”As listed in 40 CFR §302.4; Clean Water Act §307, §311; CERCLA §102; RCRA §3001; Clean Air Act §112; Toxic Substance Control Act §7, and as defined by California Health and Safety Code §25501 (n).

“Extremely Hazardous Substances”As required by Chapter 6.95 Health and Safety Code, EPCRA §302

“Radioactive Materials”As required by Title 17 §30100

Illegal releases of hazardous waste

Employee exposures resulting in injuriesAs required by California Labor Code §6409.1 (b)

“Sewage”As required by Title 23 CCR §2250 (a) (Reportable quantity is 1,000 gallons or more for municipal and private utility waste water treatment plants).

10

72 of 82

SEWAGE RELEASESState Law requires that an unauthorized discharge of sewage into or onto state waters must be reported to the Cal OES Warning Center. The Reportable Quantity for sewage spills is 1000 gallons or more, as established in regulation (Title 23, CCR, §2250 (a)).

Please note that the Regional Water Quality Control Boards and Local Health Departments may have additional reporting requirements - Please contact these offices to determine what requirements may pertain to you.

PETROLEUM (OIL) DISCHARGESIf a release of oil in any way causes harm or threatens to cause harm to public health and safety, the environment, or property, immediate notification must be made to the Cal OES Warning Center.

State Law requires that ANY discharge or threatened discharge of oil into STATE WATERS must be reported to Cal OES. (California Government Code (GC) §8670.25.5; California Water Code (WC) §13272, California State Oil Spill Contin-gency Plan).

If the release of oil is on LAND and is not discharged or threatening to discharge into State Waters; and (a) does not cause harm or threaten to cause harm to the public health and safety, the environment, or property; AND (b) is under 42 gallons, then no notification to the Cal OES Warning Center is required.

11

73 of 82

INCIDENT/RELEASE ASSESSMENT FORMHandlers of hazardous materials are required to report releases. The following is a tool to be used for assessing if a release is potentially reportable as required by Chapter 6.95 of the California Health and Safety Code. This assessment tool does not replace good judgement, Chapter 6.95, or other state or federal release report-ing requirements. If in doubt, report the release. If an emergency, call 9-1-1.

Questions for Incident Assessment Yes No1. Was anyone killed or injured, or did they require medical care

or admitted to a hospital for observation?

2. Did anyone, other than employees in the immediate area of therelease, evacuate?

3. Did the release cause off-site damage to public or private property?

4. Is the release greater than or equal to a reportable quantity (RQ)?

5. Was there an uncontrolled or unpermitted release to the air?

6. Did an uncontrolled or unpermitted release escape secondarycontainment, or extend into any sewers, storm water convey-

ance systems, utility vaults and conduits, wetlands, waterways, public roads, or off-site?

7. Will control, containment, decontamination, and/or clean up require the assistance of federal, state, county, or municipalresponse elements?

8. Did the release or threatened release involve an unknownmaterial or contain an unknown hazardous constituent?

9. Is the incident a threatened release? (a condition creating asubstantial probability of harm that requires immediate actionto prevent, reduce, or mitigate damages to persons, property,or the environment.)

10. Is there an increased potential for secondary effects includingfire, explosion, line rupture, equipment failure, or otheroutcomes that may endanger or cause exposure to employees,the general public, or the environment?

If the answer is YES to any of the above questions - report the release to the California Governor’s Office of Emergency Services Warning Center at (800) 852-7550 or (916) 845-8911, and to your local UPA. Note: Other state and federal agencies may require notification depending on the circumstances.

If in doubt, report the release!

12

74 of 82

EMERGENCY NOTIFICATION SUMMARYTelephone Calls are Required For All Significant Releases of Hazardous

Materials.At a MINIMUM, the Spiller should call:

9-1-1 or the Local Emergency Response Agency(e.g. Fire Department)

AND/ORLocal Unified Program Agency

ANDThe California Governor’s Office of Emergency Services, California

State Warning Center(800) 852-7550 or (916) 845-8911

In addition to 9-1-1 and Cal OES, the following apply under varying circumstances:

Spill Type/Location/Injuries Who to Call

Releases that equal or exceed Feder-al Reportable Quantities (CERCLA)

Call the National Response Center (NRC)

All releases on-highway Call California Highway Patrol (CHP)

All hazardous waste tank releases Call Department of Toxic Substanc-es Control Regional Office (DTSC)

All serious worker injuries or harm-ful exposures

Call Cal/OSHA District Office

All oil spills at drilling and produc-tion fixed facilities

Call Department of Conservation, Division of Oil, Gas, and Geother-mal Resources (DOGGR)

All spills with a potential to impact water quality

Call Cal OES

All potential or actual railroad releases (California definition of hazardous materials)

Call the Local Emergency Response Agency and the Public Utilities Commission (PUC)

All Hazardous Liquid Pipelines Call local fire department (Hazard-ous Liquid Pipeline Safety is State Fire Marshal jurisdiction)

All Natural Gas Pipelines Call Public Utilities Commission (PUC)

All incidents involving Radioactive Material

Call California Department of Public Health (CDPH), Radiological Preparedness Branch

13

75 of 82

IMPORTANT PHONE NUMBERSSpace has been provided below to allow you to enter important phone numbers for easy reference.

Agency Name Phone NumberCalifornia State Warning Center (Cal OES)

(800) 852-7550 or(916) 845-8911

National Response Center (800) 424-8802United States Coast GuardSan Francisco Sector:Los Angeles/Long Beach Sector:San Diego Sector:

(415) 399-3547(310) 521-3805(619) 278-7033

Unified Program Agency (UPA) (Local #)California Occupational Safety and Health Administration(Cal/OSHA) (Local #)Department of Toxic Substances and Control (DTSC) (Local #)California Department of Health Services, Radiological Health Branch (Local #)Department of ConservationCalifornia Public Utilities Com-mission (PUC)

(800) 649-7570

Department of Fish and Wildlife, Office of Spill Prevention and Re-sponse (OSPR) (Local #)Regional Water Quality Control Board (RWQCB) (Local #)

14

76 of 82

ACRONYMSCal EPA - California Environmental Protection AgencyCal OES - California Governor’s Office of Emergency ServicesCal/OSHA - California Occupational Safety and Health Ad-ministrationCCR - California Code of RegulationsCDPH - California Department of Public HealthCERCLA - Comprehensive Environmental Response, Com-pensation, and Liability Act (aka Superfund)CFR - Code of Federal RegulationsCHP - California Highway PatrolDFW - Department of Fish and Wildlife (formerly Depart-ment of Fish and Game)DOGGR - California Division of Oil, Gas, and Geothermal ResourcesDTSC - Department of Toxic Substances ControlU.S. EPA - U.S. Environmental Protection Agency EPCRA - Emergency Planning and Community Right-to- Know Act (SARA Title III)GC - California Government CodeHSC - Health and Safety CodeLEPC - Local Emergency Planning CommitteeNRC - National Response CenterOEHHA - Office of Environmental Health Hazard Assessment OSFM - Office of the State Fire MarshalOSPR - Office of Spill Prevention and ResponsePUC - Public Utilities CommissionRCRA - Resource Conservation and Recovery ActSERC - State Emergency Response CommissionUPA - Unified Program AgencyUSCG - Unitied States Coast GuardU.S. DOT - U.S. Department of TransportationWC - California Water Code

15

77 of 82

CONTRIBUTORSThis guidance was developed with input from the following agencies:California Governor’s Office of Emergency Services (Cal OES)Office of the State Fire Marshal (OSFM)California Highway Patrol (CHP)California Environmental Protection Agency (Cal EPA)• Department of Toxic Substances Control (DTSC)• State Water Resources Control Board (SWRCB)• Air Resources Board (ARB)• Department of Pesticide Regulation (DPR)• Department of Resources, Recycling, and Recovery

(Cal Recycle)• Office of Environmental Health Hazard Assessment

(OEHHA)Department of Fish and Wildlife (DFW)• Office of Spill Prevention and Response (OSPR)Department of Food and Agriculture (DFA)Department of Public Health (CDPH)Department of Industrial Relations• California Occupational Safety and Health Administration

(Cal/OSHA)Department of Transportation (CalTrans)U.S. Environmental Protection Agency, (U.S. EPA) Region IXDepartment of Conservation, Division of Oil, Gas, and Geo-thermal Resources (DOGGR)Department of Water Resources (DWR)San Diego County Department of Environmental HealthState Lands Commission (SLC)

16

78 of 82

ADDITIONAL NOTES

17

79 of 82

ADDITIONAL NOTES

18

80 of 82

For questions concerning thefederal Emergency Planning and Community Right-to-Know Act

Call EPCRA Title III Hotline:(800) 424 - 9346

81 of 82

California G

overnor’s Offi

ce of Emergency Services

Fire and Rescue Division

Hazardous M

aterials Section3650 Schriever AveM

ather, California 95655

82 of 82

Hazardous Materials 2020 Business Plans / CERS

Documents

Transcript of Hazardous Materials 2020 Business Plans / CERS