Hazard Communication Alexander Archie Compliance Enforcement Supervisor Office of the Inspector...
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Hazard CommunicationHazard Communication
Alexander ArchieCompliance Enforcement SupervisorOffice of the Inspector GeneralNorthern Region5500 Snyder AvenueOffice: (775) 887-3255Cell: (775) 722-8703
Hazard CommunicationHazard Communication
Keith JaquillardCompliance Enforcement OfficerOffice of the Inspector GeneralSouthern Region3955 West Russell RoadOffice: (702) 486-9932Cell: (702) 308-0902
Chemical Safety on the Job
Hazard Communication 29 CFR Hazard Communication 29 CFR 1910.12001910.1200
NDOC Administrative Regulation 443NDOC Administrative Regulation 443
We want you to know how to use them We want you to know how to use them safelysafely
You will learn about…You will learn about… The Hazard Communication StandardThe Hazard Communication Standard NDOC Written ProgramNDOC Written Program LabelingLabeling Material Safety Data SheetsMaterial Safety Data Sheets Spill ResponseSpill Response Who to ask for more informationWho to ask for more information
We use many chemicals…We use many chemicals…
We encounter chemicals almost We encounter chemicals almost every dayevery day Filling your vehicle with gasFilling your vehicle with gas Cleaning the bathroomCleaning the bathroom Applying pesticides or insecticidesApplying pesticides or insecticides Using solvents or acids at workUsing solvents or acids at work
Many chemicals can cause injury or Many chemicals can cause injury or illness if not handled properlyillness if not handled properly
Close Encounters with ChemicalsClose Encounters with Chemicals
OSHA created the Hazard OSHA created the Hazard Communication Standard to help Communication Standard to help ensure safety when working with ensure safety when working with hazardous chemicalshazardous chemicals
You have a RIGHT TO KNOW about You have a RIGHT TO KNOW about the hazardous chemicals you use on the hazardous chemicals you use on the job and how to work safely with the job and how to work safely with those chemicalsthose chemicals
Right to KnowRight to Know
Chemical Manufacturers Must:Chemical Manufacturers Must: Determine a chemical’s hazardsDetermine a chemical’s hazards Provide labels and MSDSsProvide labels and MSDSs
Employers must:Employers must: Provide a hazard communication Provide a hazard communication
programprogram Maintain MSDSsMaintain MSDSs Train on hazardous materialsTrain on hazardous materials
Hazard Communication StandardHazard Communication Standard
Employees must:Employees must: Read labels and MSDSsRead labels and MSDSs Follow employer instructions and Follow employer instructions and
warningswarnings Identify hazards before starting a jobIdentify hazards before starting a job Participate in trainingParticipate in training
Hazard Communication Standard Hazard Communication Standard (cont)(cont)
Physical Hazards (external):Physical Hazards (external): FlammableFlammable ExplosiveExplosive ReactiveReactive
Health Hazards (internal):Health Hazards (internal): AcuteAcute ChronicChronic
Chemical HazardsChemical Hazards
DosageDosage Acute effects - immediate health Acute effects - immediate health
effect (irritation, tissue damage, effect (irritation, tissue damage, dizziness, nausea, rashes, or dizziness, nausea, rashes, or respiratory irritation)respiratory irritation)
Chronic effects – exposure over a Chronic effects – exposure over a long period of time (months, years)long period of time (months, years)
Chemical ExposureChemical Exposure
AbsorptionAbsorption
Routes of EntryRoutes of Entry
InhalationInhalation
Ingestion (swallowing)Ingestion (swallowing)
InjectionInjection
Dust mask and respiratorsDust mask and respirators Glasses, goggles, and face shieldsGlasses, goggles, and face shields Hearing protectionHearing protection GlovesGloves Foot protectionFoot protection Head protectionHead protection Aprons or full-body suitsAprons or full-body suits
Personal Protective EquipmentPersonal Protective Equipment
Eyes: Flush with water for 30 minutesEyes: Flush with water for 30 minutes Skin: Wash with soap and waterSkin: Wash with soap and water Inhalation: Move to fresh airInhalation: Move to fresh air Ingestion: Get emergency medical Ingestion: Get emergency medical
assistanceassistance Injection: Get emergency medical Injection: Get emergency medical
assistance / call coronerassistance / call coroner
Hazardous Materials First AidHazardous Materials First Aid
Evacuate the areaEvacuate the area Notify a supervisor or emergency Notify a supervisor or emergency
response teamresponse team Remove ignition sources (if safe to Remove ignition sources (if safe to
do so)do so) Stay awayStay away
Spills and LeaksSpills and Leaks
The identity of the chemicalThe identity of the chemical Name, address, and emergency phone Name, address, and emergency phone
number of manufacturernumber of manufacturer Physical (Flammable) and health Physical (Flammable) and health
hazardshazards Special handling instructionsSpecial handling instructions Basic PPE recommendationsBasic PPE recommendations First aid, fire response, spill cleanupFirst aid, fire response, spill cleanup
Importance of LabelsImportance of Labels
NFPA Labeling SystemNFPA Labeling SystemHealth Hazard
4 Deadly
3 Extreme Danger
2 Hazardous
1 Slightly Hazardous0 Normal Material
Specific Hazard
ACID = acid
ALK = Alkali
COR = Corrosive
W = use no water
Fire Hazard
Flash Points
4 Below 73 F
3 Below 100F
2 Above 100 F not exceeding 200 F
1 Above 200 F
0 Will not Burn
Reactivity
4 May detonate
3 Shock & heat may
Detonate
2 Violent Chemical
Change
1 Unstable, if heatedNFPA 704 System
230
HMIS Labeling SystemHMIS Labeling System
Ethyl Alcohol
HEALTH 2
FLAMABILITY 3
Reactivity 0
Personal Protection B
Other Label WarningsOther Label Warnings
The identity of the chemicalThe identity of the chemical Name, address, and emergency phone Name, address, and emergency phone
number of manufacturernumber of manufacturer Physical (Flammable) and health Physical (Flammable) and health
hazardshazards Special handling instructionsSpecial handling instructions Basic PPE recommendationsBasic PPE recommendations First aid, fire response, spill cleanupFirst aid, fire response, spill cleanup
Read and become familiar with AR 443Read and become familiar with AR 443 Identify chemical hazards by reading Identify chemical hazards by reading
labels and MSDSslabels and MSDSs Follow warnings and instructions, or Follow warnings and instructions, or
ask your supervisor if in doubtask your supervisor if in doubt Practice sensible, safe work habitsPractice sensible, safe work habits Learn emergency proceduresLearn emergency procedures
Hazard Communication SummaryHazard Communication Summary
Sample MSDSSample MSDS
Click on MSDS to review
MSDS WaterMSDS Water
Identify how many times the MSDS indicates water is not hazardous
Click on MSDS to review
Water IntoxicationWater Intoxication
Click on document to view
1. Chemical manufacturers must label containers and provide? MSDS
2. Employers should keep material safety data sheets in a locked file cabinet? False
3. Dizziness, nausea, rashes, and respiratory irritation are signs of ________ exposure.Chemical
4. List three routes by which a chemical can enter the body.Inhalation, Ingestion, Absorption
5. Household chemicals are never as hazardous as chemicals used at work. False
Hazard Communication SummaryHazard Communication SummaryTestTest
6. On NFPA labels, a 4 in the red diamond indicates an extreme health hazard. False
7. Typical first aid for chemicals splashed in the eyes includes?At least 30 minutes of flushing the eyes with clear water.
8. You will only know the health hazards and PPE requirements if you?Read the MSDS
9. A _________ can be used to protect against breathing hazardous vapors or gases.Face Mask
10. If you see a chemical spill, you should clean it immediately.False
Hazard Communication SummaryHazard Communication SummaryTestTest
Hazard CommunicationHazard CommunicationExample QuestionsExample Questions
RulesRules1. Each question has associated points, 20 questions total.
2. One minute to provide correct answer. Correct answer results in points awarded. Wrong answer, other group will be allowed chance to provide correct answer.
3. First spokesperson to get presenters attention and approval from spokesperson may relay answer.
4. Only spokesperson can relay answer to presenter. Anyone other than spokesperson providing answer will result in loss of points associated with question.
Hazard CommunicationHazard CommunicationExample QuestionsExample Questions
RulesRules5. Group with most points at end wins PRIZE.
6. Tie, presenter will provide final question of choice.
Hazard CommunicationHazard CommunicationExample QuestionsExample Questions
1. One of the ingredients of Ethyl Alcohol is Kerosene. What is Kerosene’s CAS numberSection 2, CAS Number - 8008-20-6
Hazard CommunicationHazard CommunicationQuestionsQuestions
1. What is the flashpoint for Ethyl Alcohol in degrees Fahrenheit? (3 points)Section 5, Flash Point (55 0F)
2. On the MSDS for Ethyl Alcohol, name one other ingredient listed as a component? (2 points)Section 2, Methyl Isobutyl Ketone or Kerosene
3. What is the NFPA health rating for Ethyl Alcohol? (4 points)Section 16, Health 2
4. What is the effective date of the MSDS for Ethyl Alcohol? (1 point)Top of MSDS, Effective Date 07/06/06
5. What first aid measures are to be taken if Ethyl Alcohol is inhaled? (1 point)Section 4, Inhalation
Hazard CommunicationHazard CommunicationQuestionsQuestions
6. What is the NFPA flammability rating for Ethyl Alcohol? (1 point)Section 16, Flammability: 3
7. When shipping Ethyl Alcohol a UN/NA assigned number must be used on the paperwork, what is the UN/NA assigned number? (3 points)Section 14, UN1993
8. Is Ethyl Alcohol stable under ordinary conditions of use and storage? (1 point)Section 10, Stable under ordinary conditions of use and storage.
9 Accidental Release Measures for Ethyl Alcohol is called out in what section of the MSDS? (1 point)Section 6
10. Chronic ethanol exposure may affect the? (5 points)Section 3, central nervous system, liver, blood and reproductive system.
Hazard CommunicationHazard CommunicationQuestionsQuestions
11. Name one of the four routes of entry Ethyl Alcohol could enter the human body? (1 point)Inhalation, Ingestion, injection, absorption (skin contact)
12. What is the name and address of the company that provided the MSDS for Ethyl Alcohol? (2 points)Top of MSDS, Mallinckrodt Baker, Inc. 222 Red School Lane Phillipsburg, NJ 08865
13. Handling and Storage for Ethyl Alcohol is called out in what specific section of the MSDS? (2 points)Section 7
14. Ethyl Alcohol has an autoignition temperature and will self ignite at what temperature in degrees Fahrenheit? (4 points)Section 5, (685 0F)
Hazard CommunicationHazard CommunicationQuestionsQuestions
15. What is the 24 hour emergency number for CHEMTREC as listed on the MSDS for Ethyl Alcohol? (3 points)Top of MSDS, 1-800-424-9300
16. The MSDS lists condition to avoid, what are they? (4 points)Section 10, Heat, flames, ignition sources and incompatibles.
17. The Nevada Department of Corrections Hazard Communication written program is found in Administrative Regulation number? (3 points)443
18. Chemical Manufacturers must label containers and provide a? (1 point)MSDS
19. An employer should keep all MSDS’s in a locked cabinet to keep them secure, true or false? (1 point)
False20. On the MSDS for ethyl alcohol what does PEL and TLV stand
for? (3 points)section 8, Permissible Exposure Limit and Threshold Limit Value