Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux...

229
Guide to LBNL pigment characterization charts March 9, 2003 Guide To LBNL Pigment Characterization Charts Each pigment is described by a series of four charts labelled (a) - (d). The following is a cursory introduction to these charts and to LBNL’s pigment characterization process, which will be detailed in a forthcoming paper. (a) Spectrometer Film Measurements. The reflectance and transmittance of an approximately 25-μm- thick free paint film (“reflectance over void”, “transmittance”) are measured across the solar spectrum (300 – 2,500 nm @ 5-nm intervals) with a Perkin-Elmer Lambda 900 UV-VIS-NIR spectrometer. Free- film absorptance is calculated from the relation absorptance = 1 - (reflectance + transmittance). The film’s reflectance is also measured over an opaque white background (“reflectance over white”) and over an opaque black background (“reflectance over black”). Film thickness is measured at the center of the film with a digital micrometer (precision ±1 μm, accuracy ± several μm). Note: the suffix after each pigment’s name (e.g., “[A]”) is just an LBNL identification tag. Optical properties are weighted with the ASTM air-mass 1.5 global solar irradiance spectrum to integrate averages over the solar (s; 300-2,500 nm), ultraviolet (u; 300-400 nm); visible (v; 400-700 nm), and near- infrared (n; 700-2,500 nm) spectra. (b) Kubelka-Munk Calculations. The pigment’s optical properties (strictly speaking, the optical properties of the pigment suspended in a vehicle of refractive index 1.5) are computed from the paint film’s optical properties. More specifically, an adaptation (see “ancillary calculations”, below) of the classic Kubelka-Munk two-flux theory is used to calculate the pigment’s absorption coefficient K and backscattering coefficient S from the transmittance and reflectance of the free film. The reflectance of an opaquely thick paint film made from this pigment is also shown. (The opaque reflectance is a function of the ratio K/S. When the free film is opaque at a given wavelength, the only pigment property that can be reported is opaque reflectance. When the free film is not opaque, the opaque reflectance is determined from the ratio of the computed values of K and S.) (c) Ancillary Calculations. The measured reflectance and transmittance of the paint film are influenced by “interface” reflectances that occur when light passes from air (refractive index 1) to film (refractive index 1.5) and vice-versa. Interface reflectances can depend strongly on the degree to which the spectrometer’s collimated light beam is diffused by passage through the film. The extent of this diffusion is parameterized by the film’s characteristic “diffuseness” which gauges the extent to which an initially collimated beam is diffused by a single passage through the film. The diffuseness ranges from zero (fully collimated) to one (fully diffuse). The film’s characteristic diffuseness is adjusted until the Kubelka-Munk calculations yield values of K and S that accurately predict the measured reflectance of the film over an opaque black background. A second parameter, the ratio of the pigment’s back scattering to its total scattering (forward and backward) is then adjusted to make the values of K and S consistent with the film’s characteristic diffuseness. (d) Calculated vs. Measured Reflectances. Film reflectances computed from K and S are compared to measured reflectances to validate the accuracy of K and S. We expect the predicted value of film- reflectance-over-black to match the measured value because the measured value is used in ancillary calculations that affect K and S. However, comparing predicted and measured values of film-reflectance- over-white is a good check, because the measured film-reflectance-over-white is not used in any of the calculations that yield K and S.

Transcript of Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux...

Page 1: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

Guide to LBNL pigment characterization charts March 9, 2003

Guide To LBNL Pigment Characterization Charts

Each pigment is described by a series of four charts labelled (a) - (d). The following is a cursory introduction to these charts and to LBNL’s pigment characterization process, which will be detailed in a forthcoming paper.

(a) Spectrometer Film Measurements. The reflectance and transmittance of an approximately 25-µm-thick free paint film (“reflectance over void”, “transmittance”) are measured across the solar spectrum (300 – 2,500 nm @ 5-nm intervals) with a Perkin-Elmer Lambda 900 UV-VIS-NIR spectrometer. Free-film absorptance is calculated from the relation

absorptance = 1 - (reflectance + transmittance).

The film’s reflectance is also measured over an opaque white background (“reflectance over white”) and over an opaque black background (“reflectance over black”). Film thickness is measured at the center of the film with a digital micrometer (precision ±1 µm, accuracy ± several µm). Note: the suffix after each pigment’s name (e.g., “[A]”) is just an LBNL identification tag.

Optical properties are weighted with the ASTM air-mass 1.5 global solar irradiance spectrum to integrate averages over the solar (s; 300-2,500 nm), ultraviolet (u; 300-400 nm); visible (v; 400-700 nm), and near-infrared (n; 700-2,500 nm) spectra.

(b) Kubelka-Munk Calculations. The pigment’s optical properties (strictly speaking, the optical properties of the pigment suspended in a vehicle of refractive index 1.5) are computed from the paint film’s optical properties. More specifically, an adaptation (see “ancillary calculations”, below) of the classic Kubelka-Munk two-flux theory is used to calculate the pigment’s absorption coefficient K and backscattering coefficient S from the transmittance and reflectance of the free film. The reflectance of an opaquely thick paint film made from this pigment is also shown. (The opaque reflectance is a function of the ratio K/S. When the free film is opaque at a given wavelength, the only pigment property that can be reported is opaque reflectance. When the free film is not opaque, the opaque reflectance is determined from the ratio of the computed values of K and S.)

(c) Ancillary Calculations. The measured reflectance and transmittance of the paint film are influenced by “interface” reflectances that occur when light passes from air (refractive index 1) to film (refractive index 1.5) and vice-versa. Interface reflectances can depend strongly on the degree to which the spectrometer’s collimated light beam is diffused by passage through the film. The extent of this diffusion is parameterized by the film’s characteristic “diffuseness” which gauges the extent to which an initially collimated beam is diffused by a single passage through the film. The diffuseness ranges from zero (fully collimated) to one (fully diffuse).

The film’s characteristic diffuseness is adjusted until the Kubelka-Munk calculations yield values of K and S that accurately predict the measured reflectance of the film over an opaque black background. A second parameter, the ratio of the pigment’s back scattering to its total scattering (forward and backward) is then adjusted to make the values of K and S consistent with the film’s characteristic diffuseness.

(d) Calculated vs. Measured Reflectances. Film reflectances computed from K and S are compared to measured reflectances to validate the accuracy of K and S. We expect the predicted value of film-reflectance-over-black to match the measured value because the measured value is used in ancillary calculations that affect K and S. However, comparing predicted and measured values of film-reflectance-over-white is a good check, because the measured film-reflectance-over-white is not used in any of the calculations that yield K and S.

Page 2: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (18 µm; s=0.76,u=0.10,v=0.71,n=0.86)reflectance over void (19 µm; s=0.51,u=0.09,v=0.53,n=0.53)reflectance over black (18 µm; s=0.42,u=0.09,v=0.50,n=0.38)transmittance (19 µm; s=0.32,u=0.00,v=0.21,n=0.45)absorptance (19 µm; s=0.16,u=0.90,v=0.25,n=0.02)

Primer [A]uv vis nir

Sunday, 09 March 2003 12:19 PM(a) Spectrometer Film Measurements

Page 3: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Primer [A] (19 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:19 PM(b) Kubelka−Munk Calculations

Page 4: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Primer [A] (19 µm)uv vis nir

Sunday, 09 March 2003 12:19 PM(c) Ancillary Calculations

Page 5: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (18 µm; s=0.76,u=0.10,v=0.71,n=0.86)reflectance over white [calc] (18 µm; s=0.74,u=0.09,v=0.67,n=0.85)reflectance over black [meas] (18 µm; s=0.42,u=0.09,v=0.50,n=0.38)reflectance over black [calc] (18 µm; s=0.42,u=0.09,v=0.50,n=0.38)

Primer [A]uv vis nir

Sunday, 09 March 2003 12:19 PM(d) Calculated vs. Measured Reflectances

Page 6: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (23 µm; s=0.35,u=0.16,v=0.14,n=0.55)reflectance over void (26 µm; s=0.23,u=0.16,v=0.13,n=0.33)reflectance over black (26 µm; s=0.19,u=0.16,v=0.13,n=0.25)transmittance (26 µm; s=0.21,u=0.03,v=0.05,n=0.37)absorptance (26 µm; s=0.55,u=0.81,v=0.82,n=0.31)

Cobalt Chromite Blue [A]uv vis nir

Sunday, 09 March 2003 12:20 PM(a) Spectrometer Film Measurements

Page 7: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Cobalt Chromite Blue [A] (26 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:20 PM(b) Kubelka−Munk Calculations

Page 8: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Cobalt Chromite Blue [A] (26 µm)uv vis nir

Sunday, 09 March 2003 12:20 PM(c) Ancillary Calculations

Page 9: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (23 µm; s=0.35,u=0.16,v=0.14,n=0.55)reflectance over white [calc] (23 µm; s=0.35,u=0.16,v=0.13,n=0.54)reflectance over black [meas] (26 µm; s=0.19,u=0.16,v=0.13,n=0.25)reflectance over black [calc] (26 µm; s=0.19,u=0.16,v=0.13,n=0.26)

Cobalt Chromite Blue [A]uv vis nir

Sunday, 09 March 2003 12:20 PM(d) Calculated vs. Measured Reflectances

Page 10: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (24 µm; s=0.44,u=0.19,v=0.25,n=0.62)reflectance over void (23 µm; s=0.20,u=0.20,v=0.16,n=0.23)reflectance over black (25 µm; s=0.13,u=0.18,v=0.13,n=0.12)transmittance (23 µm; s=0.41,u=0.17,v=0.22,n=0.59)absorptance (23 µm; s=0.39,u=0.63,v=0.62,n=0.18)

Cobalt Aluminum Blue [A]uv vis nir

Sunday, 09 March 2003 12:22 PM(a) Spectrometer Film Measurements

Page 11: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Cobalt Aluminum Blue [A] (23 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:22 PM(b) Kubelka−Munk Calculations

Page 12: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Cobalt Aluminum Blue [A] (23 µm)uv vis nir

Sunday, 09 March 2003 12:22 PM(c) Ancillary Calculations

Page 13: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (24 µm; s=0.44,u=0.19,v=0.25,n=0.62)reflectance over white [calc] (24 µm; s=0.43,u=0.19,v=0.24,n=0.60)reflectance over black [meas] (25 µm; s=0.13,u=0.18,v=0.13,n=0.12)reflectance over black [calc] (25 µm; s=0.13,u=0.18,v=0.13,n=0.12)

Cobalt Aluminum Blue [A]uv vis nir

Sunday, 09 March 2003 12:22 PM(d) Calculated vs. Measured Reflectances

Page 14: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (26 µm; s=0.33,u=0.06,v=0.14,n=0.51)reflectance over void (26 µm; s=0.30,u=0.06,v=0.14,n=0.45)reflectance over black (24 µm; s=0.27,u=0.06,v=0.14,n=0.39)transmittance (26 µm; s=0.11,u=0.00,v=0.00,n=0.20)absorptance (26 µm; s=0.60,u=0.94,v=0.86,n=0.35)

Chrome Green [A]uv vis nir

Sunday, 09 March 2003 12:23 PM(a) Spectrometer Film Measurements

Page 15: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Chrome Green [A] (26 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:23 PM(b) Kubelka−Munk Calculations

Page 16: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Chrome Green [A] (26 µm)uv vis nir

Sunday, 09 March 2003 12:23 PM(c) Ancillary Calculations

Page 17: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (26 µm; s=0.33,u=0.06,v=0.14,n=0.51)reflectance over white [calc] (26 µm; s=NA,u=NA,v=NA,n=0.50)reflectance over black [meas] (24 µm; s=0.27,u=0.06,v=0.14,n=0.39)reflectance over black [calc] (24 µm; s=NA,u=NA,v=NA,n=0.40)

Chrome Green [A]uv vis nir

Sunday, 09 March 2003 12:23 PM(d) Calculated vs. Measured Reflectances

Page 18: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (25 µm; s=0.26,u=0.05,v=0.12,n=0.40)reflectance over void (24 µm; s=0.21,u=0.05,v=0.11,n=0.30)reflectance over black (24 µm; s=0.19,u=0.05,v=0.12,n=0.27)transmittance (24 µm; s=0.14,u=0.01,v=0.04,n=0.24)absorptance (24 µm; s=0.65,u=0.95,v=0.85,n=0.46)

Cobalt Titanate Green Spinel [A]uv vis nir

Sunday, 09 March 2003 12:25 PM(a) Spectrometer Film Measurements

Page 19: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Cobalt Titanate Green Spinel [A] (24 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:25 PM(b) Kubelka−Munk Calculations

Page 20: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Cobalt Titanate Green Spinel [A] (24 µm)uv vis nir

Sunday, 09 March 2003 12:25 PM(c) Ancillary Calculations

Page 21: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (25 µm; s=0.26,u=0.05,v=0.12,n=0.40)reflectance over white [calc] (25 µm; s=0.24,u=0.05,v=0.11,n=0.36)reflectance over black [meas] (24 µm; s=0.19,u=0.05,v=0.12,n=0.27)reflectance over black [calc] (24 µm; s=0.19,u=0.05,v=0.11,n=0.26)

Cobalt Titanate Green Spinel [A]uv vis nir

Sunday, 09 March 2003 12:25 PM(d) Calculated vs. Measured Reflectances

Page 22: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (25 µm; s=0.04,u=0.04,v=0.04,n=0.04)reflectance over void (25 µm; s=0.04,u=0.04,v=0.04,n=0.04)reflectance over black (34 µm; s=0.04,u=0.04,v=0.04,n=0.04)transmittance (25 µm; s=0.00,u=0.00,v=0.00,n=0.00)absorptance (25 µm; s=0.96,u=0.96,v=0.96,n=0.96)

Lampblack [A]uv vis nir

Sunday, 09 March 2003 12:26 PM(a) Spectrometer Film Measurements

Page 23: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Lampblack [A] (25 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:26 PM(b) Kubelka−Munk Calculations

Page 24: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Lampblack [A] (25 µm)uv vis nir

Sunday, 09 March 2003 12:26 PM(c) Ancillary Calculations

Page 25: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (25 µm; s=0.04,u=0.04,v=0.04,n=0.04)reflectance over white [calc] (25 µm; s=NA,u=NA,v=NA,n=NA)reflectance over black [meas] (34 µm; s=0.04,u=0.04,v=0.04,n=0.04)reflectance over black [calc] (34 µm; s=NA,u=NA,v=NA,n=NA)

Lampblack [A]uv vis nir

Sunday, 09 March 2003 12:26 PM(d) Calculated vs. Measured Reflectances

Page 26: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (25 µm; s=0.05,u=0.04,v=0.04,n=0.05)reflectance over void (24 µm; s=0.05,u=0.04,v=0.04,n=0.06)reflectance over black (24 µm; s=0.05,u=0.04,v=0.04,n=0.06)transmittance (24 µm; s=0.00,u=0.00,v=0.00,n=0.01)absorptance (24 µm; s=0.95,u=0.96,v=0.96,n=0.94)

Copper Chromite Black [A]uv vis nir

Sunday, 09 March 2003 12:28 PM(a) Spectrometer Film Measurements

Page 27: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Copper Chromite Black [A] (24 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:28 PM(b) Kubelka−Munk Calculations

Page 28: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Copper Chromite Black [A] (24 µm)uv vis nir

Sunday, 09 March 2003 12:28 PM(c) Ancillary Calculations

Page 29: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (25 µm; s=0.05,u=0.04,v=0.04,n=0.05)reflectance over white [calc] (25 µm; s=0.05,u=0.04,v=0.04,n=0.06)reflectance over black [meas] (24 µm; s=0.05,u=0.04,v=0.04,n=0.06)reflectance over black [calc] (24 µm; s=0.05,u=0.04,v=0.04,n=0.06)

Copper Chromite Black [A]uv vis nir

Sunday, 09 March 2003 12:28 PM(d) Calculated vs. Measured Reflectances

Page 30: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (24 µm; s=0.21,u=0.05,v=0.10,n=0.32)reflectance over void (26 µm; s=0.20,u=0.05,v=0.10,n=0.30)reflectance over black (23 µm; s=0.19,u=0.05,v=0.10,n=0.28)transmittance (26 µm; s=0.07,u=0.00,v=0.00,n=0.12)absorptance (26 µm; s=0.73,u=0.95,v=0.89,n=0.58)

Red Iron Oxide (I) [A]uv vis nir

Sunday, 09 March 2003 12:37 PM(a) Spectrometer Film Measurements

Page 31: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Red Iron Oxide (I) [A] (26 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:37 PM(b) Kubelka−Munk Calculations

Page 32: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Red Iron Oxide (I) [A] (26 µm)uv vis nir

Sunday, 09 March 2003 12:37 PM(c) Ancillary Calculations

Page 33: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (24 µm; s=0.21,u=0.05,v=0.10,n=0.32)reflectance over white [calc] (24 µm; s=0.21,u=0.05,v=0.10,n=0.32)reflectance over black [meas] (23 µm; s=0.19,u=0.05,v=0.10,n=0.28)reflectance over black [calc] (23 µm; s=0.19,u=0.05,v=0.10,n=0.28)

Red Iron Oxide (I) [A]uv vis nir

Sunday, 09 March 2003 12:37 PM(d) Calculated vs. Measured Reflectances

Page 34: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (28 µm; s=0.34,u=0.05,v=0.14,n=0.54)reflectance over void (23 µm; s=0.29,u=0.04,v=0.14,n=0.44)reflectance over black (24 µm; s=0.26,u=0.05,v=0.14,n=0.38)transmittance (23 µm; s=0.13,u=0.00,v=0.00,n=0.24)absorptance (23 µm; s=0.58,u=0.96,v=0.85,n=0.32)

Red Iron Oxide (II) [A]uv vis nir

Sunday, 09 March 2003 12:38 PM(a) Spectrometer Film Measurements

Page 35: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Red Iron Oxide (II) [A] (23 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:38 PM(b) Kubelka−Munk Calculations

Page 36: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Red Iron Oxide (II) [A] (23 µm)uv vis nir

Sunday, 09 March 2003 12:38 PM(c) Ancillary Calculations

Page 37: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (28 µm; s=0.34,u=0.05,v=0.14,n=0.54)reflectance over white [calc] (28 µm; s=NA,u=NA,v=NA,n=0.53)reflectance over black [meas] (24 µm; s=0.26,u=0.05,v=0.14,n=0.38)reflectance over black [calc] (24 µm; s=NA,u=NA,v=NA,n=0.38)

Red Iron Oxide (II) [A]uv vis nir

Sunday, 09 March 2003 12:38 PM(d) Calculated vs. Measured Reflectances

Page 38: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (27 µm; s=0.85,u=0.13,v=0.90,n=0.88)reflectance over void (29 µm; s=0.73,u=0.13,v=0.83,n=0.71)reflectance over black (26 µm; s=0.69,u=0.13,v=0.81,n=0.64)transmittance (29 µm; s=0.18,u=0.00,v=0.10,n=0.26)absorptance (29 µm; s=0.09,u=0.87,v=0.07,n=0.04)

Inorganic Oxide White [A]uv vis nir

Sunday, 09 March 2003 12:40 PM(a) Spectrometer Film Measurements

Page 39: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Inorganic Oxide White [A] (29 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:40 PM(b) Kubelka−Munk Calculations

Page 40: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Inorganic Oxide White [A] (29 µm)uv vis nir

Sunday, 09 March 2003 12:40 PM(c) Ancillary Calculations

Page 41: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (27 µm; s=0.85,u=0.13,v=0.90,n=0.88)reflectance over white [calc] (27 µm; s=NA,u=NA,v=0.89,n=0.85)reflectance over black [meas] (26 µm; s=0.69,u=0.13,v=0.81,n=0.64)reflectance over black [calc] (26 µm; s=NA,u=NA,v=0.81,n=0.64)

Inorganic Oxide White [A]uv vis nir

Sunday, 09 March 2003 12:40 PM(d) Calculated vs. Measured Reflectances

Page 42: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (24 µm; s=0.70,u=0.07,v=0.66,n=0.78)reflectance over void (27 µm; s=0.62,u=0.06,v=0.61,n=0.68)reflectance over black (25 µm; s=0.60,u=0.07,v=0.60,n=0.64)transmittance (27 µm; s=0.15,u=0.00,v=0.09,n=0.22)absorptance (27 µm; s=0.22,u=0.94,v=0.30,n=0.10)

Nickel Titanate Yellow [A]uv vis nir

Sunday, 09 March 2003 12:42 PM(a) Spectrometer Film Measurements

Page 43: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Nickel Titanate Yellow [A] (27 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:42 PM(b) Kubelka−Munk Calculations

Page 44: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Nickel Titanate Yellow [A] (27 µm)uv vis nir

Sunday, 09 March 2003 12:42 PM(c) Ancillary Calculations

Page 45: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (24 µm; s=0.70,u=0.07,v=0.66,n=0.78)reflectance over white [calc] (24 µm; s=NA,u=NA,v=NA,n=0.79)reflectance over black [meas] (25 µm; s=0.60,u=0.07,v=0.60,n=0.64)reflectance over black [calc] (25 µm; s=NA,u=NA,v=NA,n=0.64)

Nickel Titanate Yellow [A]uv vis nir

Sunday, 09 March 2003 12:42 PM(d) Calculated vs. Measured Reflectances

Page 46: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (26 µm; s=0.59,u=0.06,v=0.38,n=0.80)reflectance over void (26 µm; s=0.51,u=0.06,v=0.37,n=0.66)reflectance over black (27 µm; s=0.48,u=0.06,v=0.37,n=0.61)transmittance (26 µm; s=0.15,u=0.00,v=0.05,n=0.25)absorptance (26 µm; s=0.35,u=0.94,v=0.59,n=0.09)

Chrome Titanate Yellow [A]uv vis nir

Sunday, 09 March 2003 12:44 PM(a) Spectrometer Film Measurements

Page 47: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Chrome Titanate Yellow [A] (26 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:44 PM(b) Kubelka−Munk Calculations

Page 48: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Chrome Titanate Yellow [A] (26 µm)uv vis nir

Sunday, 09 March 2003 12:44 PM(c) Ancillary Calculations

Page 49: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (26 µm; s=0.59,u=0.06,v=0.38,n=0.80)reflectance over white [calc] (26 µm; s=NA,u=NA,v=NA,n=0.79)reflectance over black [meas] (27 µm; s=0.48,u=0.06,v=0.37,n=0.61)reflectance over black [calc] (27 µm; s=NA,u=NA,v=NA,n=0.61)

Chrome Titanate Yellow [A]uv vis nir

Sunday, 09 March 2003 12:44 PM(d) Calculated vs. Measured Reflectances

Page 50: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (26 µm; s=0.49,u=0.05,v=0.30,n=0.68)reflectance over void (28 µm; s=0.36,u=0.05,v=0.26,n=0.48)reflectance over black (27 µm; s=0.32,u=0.05,v=0.25,n=0.40)transmittance (28 µm; s=0.24,u=0.00,v=0.11,n=0.36)absorptance (28 µm; s=0.40,u=0.95,v=0.63,n=0.16)

Iron Titanium Brown Spinel [A]uv vis nir

Sunday, 09 March 2003 12:46 PM(a) Spectrometer Film Measurements

Page 51: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Iron Titanium Brown Spinel [A] (28 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:46 PM(b) Kubelka−Munk Calculations

Page 52: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Iron Titanium Brown Spinel [A] (28 µm)uv vis nir

Sunday, 09 March 2003 12:46 PM(c) Ancillary Calculations

Page 53: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (26 µm; s=0.49,u=0.05,v=0.30,n=0.68)reflectance over white [calc] (26 µm; s=0.47,u=0.05,v=0.29,n=0.67)reflectance over black [meas] (27 µm; s=0.32,u=0.05,v=0.25,n=0.40)reflectance over black [calc] (27 µm; s=0.32,u=0.05,v=0.25,n=0.40)

Iron Titanium Brown Spinel [A]uv vis nir

Sunday, 09 March 2003 12:46 PM(d) Calculated vs. Measured Reflectances

Page 54: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (23 µm; s=0.35,u=0.05,v=0.13,n=0.57)reflectance over void (26 µm; s=0.08,u=0.05,v=0.05,n=0.11)reflectance over black (23 µm; s=0.05,u=0.05,v=0.04,n=0.06)transmittance (26 µm; s=0.45,u=0.02,v=0.23,n=0.67)absorptance (26 µm; s=0.47,u=0.93,v=0.72,n=0.22)

Phthalo Blue [A]uv vis nir

Sunday, 09 March 2003 12:50 PM(a) Spectrometer Film Measurements

Page 55: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Phthalo Blue [A] (26 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:50 PM(b) Kubelka−Munk Calculations

Page 56: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Phthalo Blue [A] (26 µm)uv vis nir

Sunday, 09 March 2003 12:50 PM(c) Ancillary Calculations

Page 57: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (23 µm; s=0.35,u=0.05,v=0.13,n=0.57)reflectance over white [calc] (23 µm; s=0.36,u=0.05,v=0.14,n=0.57)reflectance over black [meas] (23 µm; s=0.05,u=0.05,v=0.04,n=0.06)reflectance over black [calc] (23 µm; s=0.05,u=0.05,v=0.04,n=0.06)

Phthalo Blue [A]uv vis nir

Sunday, 09 March 2003 12:50 PM(d) Calculated vs. Measured Reflectances

Page 58: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (25 µm; s=0.28,u=0.04,v=0.07,n=0.47)reflectance over void (25 µm; s=0.09,u=0.04,v=0.05,n=0.13)reflectance over black (25 µm; s=0.06,u=0.04,v=0.05,n=0.08)transmittance (25 µm; s=0.30,u=0.00,v=0.10,n=0.50)absorptance (25 µm; s=0.60,u=0.96,v=0.85,n=0.36)

Phthalo Green [A]uv vis nir

Sunday, 09 March 2003 12:52 PM(a) Spectrometer Film Measurements

Page 59: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Phthalo Green [A] (25 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:52 PM(b) Kubelka−Munk Calculations

Page 60: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Phthalo Green [A] (25 µm)uv vis nir

Sunday, 09 March 2003 12:52 PM(c) Ancillary Calculations

Page 61: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (25 µm; s=0.28,u=0.04,v=0.07,n=0.47)reflectance over white [calc] (25 µm; s=NA,u=NA,v=NA,n=NA)reflectance over black [meas] (25 µm; s=0.06,u=0.04,v=0.05,n=0.08)reflectance over black [calc] (25 µm; s=NA,u=NA,v=NA,n=NA)

Phthalo Green [A]uv vis nir

Sunday, 09 March 2003 12:52 PM(d) Calculated vs. Measured Reflectances

Page 62: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (25 µm; s=0.57,u=0.06,v=0.27,n=0.86)reflectance over void (26 µm; s=0.23,u=0.06,v=0.16,n=0.30)reflectance over black (22 µm; s=0.13,u=0.06,v=0.12,n=0.13)transmittance (26 µm; s=0.42,u=0.01,v=0.15,n=0.67)absorptance (26 µm; s=0.36,u=0.93,v=0.69,n=0.03)

Monstral Red [A]uv vis nir

Sunday, 09 March 2003 12:53 PM(a) Spectrometer Film Measurements

Page 63: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Monstral Red [A] (26 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:53 PM(b) Kubelka−Munk Calculations

Page 64: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Monstral Red [A] (26 µm)uv vis nir

Sunday, 09 March 2003 12:53 PM(c) Ancillary Calculations

Page 65: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (25 µm; s=0.57,u=0.06,v=0.27,n=0.86)reflectance over white [calc] (25 µm; s=0.54,u=0.06,v=0.25,n=0.82)reflectance over black [meas] (22 µm; s=0.13,u=0.06,v=0.12,n=0.13)reflectance over black [calc] (22 µm; s=0.13,u=0.06,v=0.12,n=0.13)

Monstral Red [A]uv vis nir

Sunday, 09 March 2003 12:53 PM(d) Calculated vs. Measured Reflectances

Page 66: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (30 µm; s=0.66,u=0.04,v=0.53,n=0.83)reflectance over void (24 µm; s=0.41,u=0.04,v=0.39,n=0.46)reflectance over black (25 µm; s=0.34,u=0.04,v=0.36,n=0.34)transmittance (24 µm; s=0.34,u=0.00,v=0.18,n=0.50)absorptance (24 µm; s=0.25,u=0.96,v=0.43,n=0.04)

Chrome Yellow [A]uv vis nir

Sunday, 09 March 2003 12:54 PM(a) Spectrometer Film Measurements

Page 67: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Chrome Yellow [A] (24 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:54 PM(b) Kubelka−Munk Calculations

Page 68: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Chrome Yellow [A] (24 µm)uv vis nir

Sunday, 09 March 2003 12:54 PM(c) Ancillary Calculations

Page 69: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (30 µm; s=0.66,u=0.04,v=0.53,n=0.83)reflectance over white [calc] (30 µm; s=0.63,u=0.04,v=0.49,n=0.79)reflectance over black [meas] (25 µm; s=0.34,u=0.04,v=0.36,n=0.34)reflectance over black [calc] (25 µm; s=0.34,u=0.04,v=0.36,n=0.34)

Chrome Yellow [A]uv vis nir

Sunday, 09 March 2003 12:54 PM(d) Calculated vs. Measured Reflectances

Page 70: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (27 µm; s=0.22,u=0.05,v=0.05,n=0.38)reflectance over void (26 µm; s=0.19,u=0.05,v=0.05,n=0.32)reflectance over black (28 µm; s=0.17,u=0.05,v=0.05,n=0.28)transmittance (26 µm; s=0.09,u=0.01,v=0.01,n=0.17)absorptance (26 µm; s=0.72,u=0.95,v=0.94,n=0.51)

Ferro IR Black 799 [A]uv vis nir

Sunday, 09 March 2003 12:56 PM(a) Spectrometer Film Measurements

Page 71: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Ferro IR Black 799 [A] (26 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:56 PM(b) Kubelka−Munk Calculations

Page 72: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Ferro IR Black 799 [A] (26 µm)uv vis nir

Sunday, 09 March 2003 12:56 PM(c) Ancillary Calculations

Page 73: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (27 µm; s=0.22,u=0.05,v=0.05,n=0.38)reflectance over white [calc] (27 µm; s=0.21,u=0.05,v=0.05,n=0.37)reflectance over black [meas] (28 µm; s=0.17,u=0.05,v=0.05,n=0.28)reflectance over black [calc] (28 µm; s=0.17,u=0.05,v=0.05,n=0.28)

Ferro IR Black 799 [A]uv vis nir

Sunday, 09 March 2003 12:56 PM(d) Calculated vs. Measured Reflectances

Page 74: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (22 µm; s=0.27,u=0.05,v=0.06,n=0.46)reflectance over void (19 µm; s=0.23,u=0.05,v=0.06,n=0.39)reflectance over black (20 µm; s=0.21,u=0.05,v=0.06,n=0.35)transmittance (19 µm; s=0.09,u=0.00,v=0.00,n=0.17)absorptance (19 µm; s=0.68,u=0.95,v=0.94,n=0.45)

Ferro IR Black 797 [A]uv vis nir

Sunday, 09 March 2003 12:57 PM(a) Spectrometer Film Measurements

Page 75: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Ferro IR Black 797 [A] (19 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:57 PM(b) Kubelka−Munk Calculations

Page 76: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Ferro IR Black 797 [A] (19 µm)uv vis nir

Sunday, 09 March 2003 12:57 PM(c) Ancillary Calculations

Page 77: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (22 µm; s=0.27,u=0.05,v=0.06,n=0.46)reflectance over white [calc] (22 µm; s=NA,u=NA,v=NA,n=0.44)reflectance over black [meas] (20 µm; s=0.21,u=0.05,v=0.06,n=0.35)reflectance over black [calc] (20 µm; s=NA,u=NA,v=NA,n=0.35)

Ferro IR Black 797 [A]uv vis nir

Sunday, 09 March 2003 12:57 PM(d) Calculated vs. Measured Reflectances

Page 78: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (27 µm; s=0.25,u=0.05,v=0.06,n=0.43)reflectance over void (22 µm; s=0.22,u=0.05,v=0.06,n=0.37)reflectance over black (24 µm; s=0.20,u=0.05,v=0.06,n=0.33)transmittance (22 µm; s=0.08,u=0.00,v=0.00,n=0.16)absorptance (22 µm; s=0.69,u=0.95,v=0.94,n=0.47)

Shepherd IR Black 411 [A]uv vis nir

Sunday, 09 March 2003 12:59 PM(a) Spectrometer Film Measurements

Page 79: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Shepherd IR Black 411 [A] (22 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 12:59 PM(b) Kubelka−Munk Calculations

Page 80: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Shepherd IR Black 411 [A] (22 µm)uv vis nir

Sunday, 09 March 2003 12:59 PM(c) Ancillary Calculations

Page 81: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (27 µm; s=0.25,u=0.05,v=0.06,n=0.43)reflectance over white [calc] (27 µm; s=0.24,u=0.05,v=0.06,n=0.42)reflectance over black [meas] (24 µm; s=0.20,u=0.05,v=0.06,n=0.33)reflectance over black [calc] (24 µm; s=0.21,u=0.05,v=0.06,n=0.34)

Shepherd IR Black 411 [A]uv vis nir

Sunday, 09 March 2003 12:59 PM(d) Calculated vs. Measured Reflectances

Page 82: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (24 µm; s=0.31,u=0.06,v=0.09,n=0.52)reflectance over void (24 µm; s=0.25,u=0.05,v=0.09,n=0.40)reflectance over black (25 µm; s=0.23,u=0.05,v=0.09,n=0.36)transmittance (24 µm; s=0.14,u=0.00,v=0.01,n=0.25)absorptance (24 µm; s=0.62,u=0.95,v=0.91,n=0.34)

Ferro V−12600 Camo Green [A]uv vis nir

Sunday, 09 March 2003 01:01 PM(a) Spectrometer Film Measurements

Page 83: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Ferro V−12600 Camo Green [A] (24 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:01 PM(b) Kubelka−Munk Calculations

Page 84: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Ferro V−12600 Camo Green [A] (24 µm)uv vis nir

Sunday, 09 March 2003 01:01 PM(c) Ancillary Calculations

Page 85: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (24 µm; s=0.31,u=0.06,v=0.09,n=0.52)reflectance over white [calc] (24 µm; s=0.32,u=0.05,v=0.09,n=0.53)reflectance over black [meas] (25 µm; s=0.23,u=0.05,v=0.09,n=0.36)reflectance over black [calc] (25 µm; s=0.23,u=0.05,v=0.09,n=0.36)

Ferro V−12600 Camo Green [A]uv vis nir

Sunday, 09 March 2003 01:01 PM(d) Calculated vs. Measured Reflectances

Page 86: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (23 µm; s=0.44,u=0.05,v=0.10,n=0.76)reflectance over void (22 µm; s=0.11,u=0.05,v=0.07,n=0.16)reflectance over black (24 µm; s=0.07,u=0.05,v=0.06,n=0.08)transmittance (22 µm; s=0.47,u=0.00,v=0.12,n=0.79)absorptance (22 µm; s=0.42,u=0.95,v=0.81,n=0.05)

Acra Burnt Orange [B]uv vis nir

Sunday, 09 March 2003 01:04 PM(a) Spectrometer Film Measurements

Page 87: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Acra Burnt Orange [B] (22 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:04 PM(b) Kubelka−Munk Calculations

Page 88: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Acra Burnt Orange [B] (22 µm)uv vis nir

Sunday, 09 March 2003 01:04 PM(c) Ancillary Calculations

Page 89: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (23 µm; s=0.44,u=0.05,v=0.10,n=0.76)reflectance over white [calc] (23 µm; s=NA,u=NA,v=NA,n=0.74)reflectance over black [meas] (24 µm; s=0.07,u=0.05,v=0.06,n=0.08)reflectance over black [calc] (24 µm; s=NA,u=NA,v=NA,n=0.07)

Acra Burnt Orange [B]uv vis nir

Sunday, 09 March 2003 01:04 PM(d) Calculated vs. Measured Reflectances

Page 90: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (24 µm; s=0.59,u=0.07,v=0.33,n=0.85)reflectance over void (27 µm; s=0.12,u=0.07,v=0.10,n=0.13)reflectance over black (25 µm; s=0.07,u=0.07,v=0.07,n=0.06)transmittance (27 µm; s=0.58,u=0.04,v=0.32,n=0.85)absorptance (27 µm; s=0.30,u=0.89,v=0.58,n=0.01)

Acra Red [B]uv vis nir

Sunday, 09 March 2003 01:12 PM(a) Spectrometer Film Measurements

Page 91: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Acra Red [B] (27 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:12 PM(b) Kubelka−Munk Calculations

Page 92: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Acra Red [B] (27 µm)uv vis nir

Sunday, 09 March 2003 01:12 PM(c) Ancillary Calculations

Page 93: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (24 µm; s=0.59,u=0.07,v=0.33,n=0.85)reflectance over white [calc] (24 µm; s=0.57,u=0.07,v=0.33,n=0.82)reflectance over black [meas] (25 µm; s=0.07,u=0.07,v=0.07,n=0.06)reflectance over black [calc] (25 µm; s=0.06,u=0.07,v=0.06,n=0.06)

Acra Red [B]uv vis nir

Sunday, 09 March 2003 01:12 PM(d) Calculated vs. Measured Reflectances

Page 94: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (24 µm; s=0.28,u=0.05,v=0.10,n=0.45)reflectance over void (23 µm; s=0.20,u=0.05,v=0.10,n=0.30)reflectance over black (25 µm; s=0.15,u=0.05,v=0.10,n=0.20)transmittance (23 µm; s=0.20,u=0.00,v=0.02,n=0.36)absorptance (23 µm; s=0.60,u=0.95,v=0.88,n=0.35)

Burnt Sienna [B]uv vis nir

Sunday, 09 March 2003 01:15 PM(a) Spectrometer Film Measurements

Page 95: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Burnt Sienna [B] (23 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:15 PM(b) Kubelka−Munk Calculations

Page 96: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Burnt Sienna [B] (23 µm)uv vis nir

Sunday, 09 March 2003 01:15 PM(c) Ancillary Calculations

Page 97: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (24 µm; s=0.28,u=0.05,v=0.10,n=0.45)reflectance over white [calc] (24 µm; s=NA,u=NA,v=NA,n=0.45)reflectance over black [meas] (25 µm; s=0.15,u=0.05,v=0.10,n=0.20)reflectance over black [calc] (25 µm; s=NA,u=NA,v=NA,n=0.20)

Burnt Sienna [B]uv vis nir

Sunday, 09 March 2003 01:15 PM(d) Calculated vs. Measured Reflectances

Page 98: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (18 µm; s=0.64,u=0.05,v=0.42,n=0.87)reflectance over void (17 µm; s=0.45,u=0.05,v=0.34,n=0.57)reflectance over black (18 µm; s=0.39,u=0.05,v=0.34,n=0.47)transmittance (17 µm; s=0.25,u=0.00,v=0.09,n=0.40)absorptance (17 µm; s=0.30,u=0.95,v=0.56,n=0.03)

Cadmium Orange [B]uv vis nir

Sunday, 09 March 2003 01:18 PM(a) Spectrometer Film Measurements

Page 99: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Cadmium Orange [B] (17 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:18 PM(b) Kubelka−Munk Calculations

Page 100: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Cadmium Orange [B] (17 µm)uv vis nir

Sunday, 09 March 2003 01:18 PM(c) Ancillary Calculations

Page 101: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (18 µm; s=0.64,u=0.05,v=0.42,n=0.87)reflectance over white [calc] (18 µm; s=NA,u=NA,v=NA,n=0.84)reflectance over black [meas] (18 µm; s=0.39,u=0.05,v=0.34,n=0.47)reflectance over black [calc] (18 µm; s=NA,u=NA,v=NA,n=0.47)

Cadmium Orange [B]uv vis nir

Sunday, 09 March 2003 01:18 PM(d) Calculated vs. Measured Reflectances

Page 102: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (19 µm; s=0.72,u=0.05,v=0.61,n=0.87)reflectance over void (20 µm; s=0.54,u=0.05,v=0.51,n=0.60)reflectance over black (19 µm; s=0.47,u=0.05,v=0.49,n=0.49)transmittance (20 µm; s=0.24,u=0.00,v=0.13,n=0.36)absorptance (20 µm; s=0.22,u=0.95,v=0.37,n=0.03)

Cadmium Yellow Light [B]uv vis nir

Sunday, 09 March 2003 01:21 PM(a) Spectrometer Film Measurements

Page 103: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Cadmium Yellow Light [B] (20 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:21 PM(b) Kubelka−Munk Calculations

Page 104: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Cadmium Yellow Light [B] (20 µm)uv vis nir

Sunday, 09 March 2003 01:21 PM(c) Ancillary Calculations

Page 105: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (19 µm; s=0.72,u=0.05,v=0.61,n=0.87)reflectance over white [calc] (19 µm; s=NA,u=NA,v=NA,n=0.85)reflectance over black [meas] (19 µm; s=0.47,u=0.05,v=0.49,n=0.49)reflectance over black [calc] (19 µm; s=NA,u=NA,v=NA,n=0.49)

Cadmium Yellow Light [B]uv vis nir

Sunday, 09 March 2003 01:21 PM(d) Calculated vs. Measured Reflectances

Page 106: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (23 µm; s=0.47,u=0.28,v=0.25,n=0.67)reflectance over void (23 µm; s=0.26,u=0.29,v=0.19,n=0.33)reflectance over black (23 µm; s=0.17,u=0.27,v=0.16,n=0.18)transmittance (23 µm; s=0.34,u=0.17,v=0.16,n=0.50)absorptance (23 µm; s=0.40,u=0.54,v=0.65,n=0.18)

Cerulean Blue [B]uv vis nir

Sunday, 09 March 2003 01:23 PM(a) Spectrometer Film Measurements

Page 107: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Cerulean Blue [B] (23 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:23 PM(b) Kubelka−Munk Calculations

Page 108: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Cerulean Blue [B] (23 µm)uv vis nir

Sunday, 09 March 2003 01:23 PM(c) Ancillary Calculations

Page 109: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (23 µm; s=0.47,u=0.28,v=0.25,n=0.67)reflectance over white [calc] (23 µm; s=0.46,u=0.28,v=0.24,n=0.66)reflectance over black [meas] (23 µm; s=0.17,u=0.27,v=0.16,n=0.18)reflectance over black [calc] (23 µm; s=0.17,u=0.27,v=0.16,n=0.18)

Cerulean Blue [B]uv vis nir

Sunday, 09 March 2003 01:23 PM(d) Calculated vs. Measured Reflectances

Page 110: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (22 µm; s=0.31,u=0.06,v=0.12,n=0.49)reflectance over void (21 µm; s=0.29,u=0.06,v=0.12,n=0.46)reflectance over black (22 µm; s=0.29,u=0.06,v=0.12,n=0.44)transmittance (21 µm; s=0.07,u=0.00,v=0.00,n=0.13)absorptance (21 µm; s=0.64,u=0.94,v=0.88,n=0.41)

Chromium Oxide Green [B]uv vis nir

Sunday, 09 March 2003 01:26 PM(a) Spectrometer Film Measurements

Page 111: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Chromium Oxide Green [B] (21 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:26 PM(b) Kubelka−Munk Calculations

Page 112: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Chromium Oxide Green [B] (21 µm)uv vis nir

Sunday, 09 March 2003 01:26 PM(c) Ancillary Calculations

Page 113: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (22 µm; s=0.31,u=0.06,v=0.12,n=0.49)reflectance over white [calc] (22 µm; s=NA,u=NA,v=NA,n=0.48)reflectance over black [meas] (22 µm; s=0.29,u=0.06,v=0.12,n=0.44)reflectance over black [calc] (22 µm; s=NA,u=NA,v=NA,n=0.44)

Chromium Oxide Green [B]uv vis nir

Sunday, 09 March 2003 01:26 PM(d) Calculated vs. Measured Reflectances

Page 114: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (22 µm; s=0.42,u=0.17,v=0.22,n=0.62)reflectance over void (23 µm; s=0.21,u=0.17,v=0.15,n=0.26)reflectance over black (22 µm; s=0.12,u=0.16,v=0.12,n=0.12)transmittance (23 µm; s=0.34,u=0.11,v=0.16,n=0.52)absorptance (23 µm; s=0.45,u=0.71,v=0.69,n=0.22)

Cobalt Blue [B]uv vis nir

Sunday, 09 March 2003 01:29 PM(a) Spectrometer Film Measurements

Page 115: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Cobalt Blue [B] (23 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:29 PM(b) Kubelka−Munk Calculations

Page 116: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Cobalt Blue [B] (23 µm)uv vis nir

Sunday, 09 March 2003 01:29 PM(c) Ancillary Calculations

Page 117: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (22 µm; s=0.42,u=0.17,v=0.22,n=0.62)reflectance over white [calc] (22 µm; s=0.41,u=0.17,v=0.21,n=0.60)reflectance over black [meas] (22 µm; s=0.12,u=0.16,v=0.12,n=0.12)reflectance over black [calc] (22 µm; s=0.12,u=0.16,v=0.12,n=0.12)

Cobalt Blue [B]uv vis nir

Sunday, 09 March 2003 01:29 PM(d) Calculated vs. Measured Reflectances

Page 118: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (20 µm; s=0.48,u=0.07,v=0.29,n=0.67)reflectance over void (27 µm; s=0.39,u=0.07,v=0.28,n=0.52)reflectance over black (23 µm; s=0.37,u=0.07,v=0.27,n=0.47)transmittance (27 µm; s=0.14,u=0.00,v=0.05,n=0.22)absorptance (27 µm; s=0.47,u=0.93,v=0.67,n=0.26)

Cobalt Teal [B]uv vis nir

Sunday, 09 March 2003 01:32 PM(a) Spectrometer Film Measurements

Page 119: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Cobalt Teal [B] (27 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:32 PM(b) Kubelka−Munk Calculations

Page 120: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Cobalt Teal [B] (27 µm)uv vis nir

Sunday, 09 March 2003 01:32 PM(c) Ancillary Calculations

Page 121: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (20 µm; s=0.48,u=0.07,v=0.29,n=0.67)reflectance over white [calc] (20 µm; s=NA,u=NA,v=0.30,n=0.66)reflectance over black [meas] (23 µm; s=0.37,u=0.07,v=0.27,n=0.47)reflectance over black [calc] (23 µm; s=NA,u=NA,v=0.27,n=0.47)

Cobalt Teal [B]uv vis nir

Sunday, 09 March 2003 01:32 PM(d) Calculated vs. Measured Reflectances

Page 122: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (22 µm; s=0.42,u=0.05,v=0.05,n=0.75)reflectance over void (20 µm; s=0.08,u=0.05,v=0.05,n=0.11)reflectance over black (22 µm; s=0.05,u=0.05,v=0.05,n=0.06)transmittance (20 µm; s=0.46,u=0.01,v=0.06,n=0.84)absorptance (20 µm; s=0.46,u=0.94,v=0.89,n=0.05)

Dioxazine Purple [B]uv vis nir

Sunday, 09 March 2003 01:35 PM(a) Spectrometer Film Measurements

Page 123: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Dioxazine Purple [B] (20 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:35 PM(b) Kubelka−Munk Calculations

Page 124: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Dioxazine Purple [B] (20 µm)uv vis nir

Sunday, 09 March 2003 01:35 PM(c) Ancillary Calculations

Page 125: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (22 µm; s=0.42,u=0.05,v=0.05,n=0.75)reflectance over white [calc] (22 µm; s=NA,u=0.05,v=NA,n=0.70)reflectance over black [meas] (22 µm; s=0.05,u=0.05,v=0.05,n=0.06)reflectance over black [calc] (22 µm; s=NA,u=0.05,v=NA,n=0.05)

Dioxazine Purple [B]uv vis nir

Sunday, 09 March 2003 01:35 PM(d) Calculated vs. Measured Reflectances

Page 126: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (17 µm; s=0.23,u=0.09,v=0.19,n=0.28)reflectance over void (20 µm; s=0.22,u=0.09,v=0.19,n=0.26)reflectance over black (17 µm; s=0.22,u=0.09,v=0.19,n=0.26)transmittance (20 µm; s=0.07,u=0.00,v=0.02,n=0.13)absorptance (20 µm; s=0.70,u=0.90,v=0.79,n=0.61)

Iridescent Rich Bronze [B]uv vis nir

Sunday, 09 March 2003 01:37 PM(a) Spectrometer Film Measurements

Page 127: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Iridescent Rich Bronze [B] (20 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:37 PM(b) Kubelka−Munk Calculations

Page 128: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Iridescent Rich Bronze [B] (20 µm)uv vis nir

Sunday, 09 March 2003 01:37 PM(c) Ancillary Calculations

Page 129: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (17 µm; s=0.23,u=0.09,v=0.19,n=0.28)reflectance over white [calc] (17 µm; s=0.24,u=0.09,v=0.19,n=0.28)reflectance over black [meas] (17 µm; s=0.22,u=0.09,v=0.19,n=0.26)reflectance over black [calc] (17 µm; s=0.22,u=0.09,v=0.19,n=0.25)

Iridescent Rich Bronze [B]uv vis nir

Sunday, 09 March 2003 01:37 PM(d) Calculated vs. Measured Reflectances

Page 130: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (23 µm; s=0.86,u=0.29,v=0.91,n=0.88)reflectance over void (21 µm; s=0.47,u=0.28,v=0.58,n=0.39)reflectance over black (25 µm; s=0.43,u=0.29,v=0.54,n=0.36)transmittance (21 µm; s=0.46,u=0.05,v=0.36,n=0.58)absorptance (21 µm; s=0.07,u=0.67,v=0.06,n=0.02)

Iridescent White [B]uv vis nir

Sunday, 09 March 2003 01:40 PM(a) Spectrometer Film Measurements

Page 131: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Iridescent White [B] (21 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:40 PM(b) Kubelka−Munk Calculations

Page 132: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Iridescent White [B] (21 µm)uv vis nir

Sunday, 09 March 2003 01:40 PM(c) Ancillary Calculations

Page 133: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (23 µm; s=0.86,u=0.29,v=0.91,n=0.88)reflectance over white [calc] (23 µm; s=0.81,u=0.28,v=0.85,n=0.82)reflectance over black [meas] (25 µm; s=0.43,u=0.29,v=0.54,n=0.36)reflectance over black [calc] (25 µm; s=0.43,u=0.28,v=0.54,n=0.35)

Iridescent White [B]uv vis nir

Sunday, 09 March 2003 01:40 PM(d) Calculated vs. Measured Reflectances

Page 134: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (27 µm; s=0.04,u=0.04,v=0.04,n=0.04)reflectance over void (25 µm; s=0.04,u=0.04,v=0.04,n=0.04)reflectance over black (27 µm; s=0.04,u=0.05,v=0.04,n=0.04)transmittance (25 µm; s=0.02,u=0.00,v=0.00,n=0.03)absorptance (25 µm; s=0.94,u=0.95,v=0.96,n=0.93)

Ivory Black [B]uv vis nir

Sunday, 09 March 2003 01:43 PM(a) Spectrometer Film Measurements

Page 135: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Ivory Black [B] (25 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:43 PM(b) Kubelka−Munk Calculations

Page 136: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Ivory Black [B] (25 µm)uv vis nir

Sunday, 09 March 2003 01:43 PM(c) Ancillary Calculations

Page 137: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (27 µm; s=0.04,u=0.04,v=0.04,n=0.04)reflectance over white [calc] (27 µm; s=NA,u=NA,v=0.04,n=0.04)reflectance over black [meas] (27 µm; s=0.04,u=0.05,v=0.04,n=0.04)reflectance over black [calc] (27 µm; s=NA,u=NA,v=0.04,n=0.04)

Ivory Black [B]uv vis nir

Sunday, 09 March 2003 01:43 PM(d) Calculated vs. Measured Reflectances

Page 138: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (27 µm; s=0.04,u=0.05,v=0.04,n=0.04)reflectance over void (27 µm; s=0.04,u=0.05,v=0.04,n=0.04)reflectance over black (27 µm; s=0.04,u=0.05,v=0.04,n=0.04)transmittance (27 µm; s=−0.00,u=0.00,v=0.00,n=−0.00)absorptance (27 µm; s=0.96,u=0.95,v=0.96,n=0.96)

Mars Black [B]uv vis nir

Sunday, 09 March 2003 01:46 PM(a) Spectrometer Film Measurements

Page 139: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Mars Black [B] (27 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:46 PM(b) Kubelka−Munk Calculations

Page 140: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Mars Black [B] (27 µm)uv vis nir

Sunday, 09 March 2003 01:46 PM(c) Ancillary Calculations

Page 141: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (27 µm; s=0.04,u=0.05,v=0.04,n=0.04)reflectance over white [calc] (27 µm; s=NA,u=NA,v=NA,n=NA)reflectance over black [meas] (27 µm; s=0.04,u=0.05,v=0.04,n=0.04)reflectance over black [calc] (27 µm; s=NA,u=NA,v=NA,n=NA)

Mars Black [B]uv vis nir

Sunday, 09 March 2003 01:46 PM(d) Calculated vs. Measured Reflectances

Page 142: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (23 µm; s=0.59,u=0.05,v=0.31,n=0.86)reflectance over void (29 µm; s=0.28,u=0.05,v=0.22,n=0.35)reflectance over black (24 µm; s=0.19,u=0.05,v=0.19,n=0.20)transmittance (29 µm; s=0.37,u=0.00,v=0.10,n=0.62)absorptance (29 µm; s=0.35,u=0.95,v=0.68,n=0.02)

Naphthol Red Light [B]uv vis nir

Sunday, 09 March 2003 01:49 PM(a) Spectrometer Film Measurements

Page 143: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Naphthol Red Light [B] (29 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:49 PM(b) Kubelka−Munk Calculations

Page 144: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Naphthol Red Light [B] (29 µm)uv vis nir

Sunday, 09 March 2003 01:49 PM(c) Ancillary Calculations

Page 145: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (23 µm; s=0.59,u=0.05,v=0.31,n=0.86)reflectance over white [calc] (23 µm; s=NA,u=0.05,v=NA,n=0.84)reflectance over black [meas] (24 µm; s=0.19,u=0.05,v=0.19,n=0.20)reflectance over black [calc] (24 µm; s=NA,u=0.05,v=NA,n=0.20)

Naphthol Red Light [B]uv vis nir

Sunday, 09 March 2003 01:49 PM(d) Calculated vs. Measured Reflectances

Page 146: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (20 µm; s=0.30,u=0.05,v=0.07,n=0.52)reflectance over void (19 µm; s=0.10,u=0.06,v=0.05,n=0.14)reflectance over black (20 µm; s=0.07,u=0.06,v=0.05,n=0.09)transmittance (19 µm; s=0.34,u=0.00,v=0.09,n=0.58)absorptance (19 µm; s=0.56,u=0.94,v=0.86,n=0.28)

Phthalocyanine Blue [B]uv vis nir

Sunday, 09 March 2003 01:55 PM(a) Spectrometer Film Measurements

Page 147: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Phthalocyanine Blue [B] (19 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:55 PM(b) Kubelka−Munk Calculations

Page 148: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Phthalocyanine Blue [B] (19 µm)uv vis nir

Sunday, 09 March 2003 01:55 PM(c) Ancillary Calculations

Page 149: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (20 µm; s=0.30,u=0.05,v=0.07,n=0.52)reflectance over white [calc] (20 µm; s=NA,u=NA,v=NA,n=NA)reflectance over black [meas] (20 µm; s=0.07,u=0.06,v=0.05,n=0.09)reflectance over black [calc] (20 µm; s=NA,u=NA,v=NA,n=NA)

Phthalocyanine Blue [B]uv vis nir

Sunday, 09 March 2003 01:55 PM(d) Calculated vs. Measured Reflectances

Page 150: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (21 µm; s=0.26,u=0.05,v=0.06,n=0.44)reflectance over void (25 µm; s=0.10,u=0.05,v=0.05,n=0.15)reflectance over black (21 µm; s=0.07,u=0.05,v=0.05,n=0.08)transmittance (25 µm; s=0.26,u=0.00,v=0.06,n=0.46)absorptance (25 µm; s=0.63,u=0.95,v=0.89,n=0.39)

Phthalocyanine Green [B]uv vis nir

Sunday, 09 March 2003 01:58 PM(a) Spectrometer Film Measurements

Page 151: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Phthalocyanine Green [B] (25 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 01:58 PM(b) Kubelka−Munk Calculations

Page 152: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Phthalocyanine Green [B] (25 µm)uv vis nir

Sunday, 09 March 2003 01:58 PM(c) Ancillary Calculations

Page 153: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (21 µm; s=0.26,u=0.05,v=0.06,n=0.44)reflectance over white [calc] (21 µm; s=NA,u=NA,v=NA,n=0.44)reflectance over black [meas] (21 µm; s=0.07,u=0.05,v=0.05,n=0.08)reflectance over black [calc] (21 µm; s=NA,u=NA,v=NA,n=0.08)

Phthalocyanine Green [B]uv vis nir

Sunday, 09 March 2003 01:58 PM(d) Calculated vs. Measured Reflectances

Page 154: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (20 µm; s=0.13,u=0.05,v=0.05,n=0.21)reflectance over void (20 µm; s=0.06,u=0.05,v=0.04,n=0.09)reflectance over black (20 µm; s=0.05,u=0.05,v=0.04,n=0.06)transmittance (20 µm; s=0.17,u=0.07,v=0.08,n=0.26)absorptance (20 µm; s=0.77,u=0.89,v=0.88,n=0.66)

Prussian Blue [B]uv vis nir

Sunday, 09 March 2003 02:03 PM(a) Spectrometer Film Measurements

Page 155: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Prussian Blue [B] (20 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:03 PM(b) Kubelka−Munk Calculations

Page 156: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Prussian Blue [B] (20 µm)uv vis nir

Sunday, 09 March 2003 02:03 PM(c) Ancillary Calculations

Page 157: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (20 µm; s=0.13,u=0.05,v=0.05,n=0.21)reflectance over white [calc] (20 µm; s=NA,u=0.05,v=NA,n=NA)reflectance over black [meas] (20 µm; s=0.05,u=0.05,v=0.04,n=0.06)reflectance over black [calc] (20 µm; s=NA,u=0.05,v=NA,n=NA)

Prussian Blue [B]uv vis nir

Sunday, 09 March 2003 02:03 PM(d) Calculated vs. Measured Reflectances

Page 158: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (22 µm; s=0.17,u=0.05,v=0.06,n=0.26)reflectance over void (23 µm; s=0.10,u=0.04,v=0.06,n=0.13)reflectance over black (22 µm; s=0.07,u=0.04,v=0.06,n=0.08)transmittance (23 µm; s=0.21,u=−0.00,v=0.03,n=0.38)absorptance (23 µm; s=0.69,u=0.96,v=0.91,n=0.48)

Raw Umber [B]uv vis nir

Sunday, 09 March 2003 02:05 PM(a) Spectrometer Film Measurements

Page 159: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Raw Umber [B] (23 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:05 PM(b) Kubelka−Munk Calculations

Page 160: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Raw Umber [B] (23 µm)uv vis nir

Sunday, 09 March 2003 02:05 PM(c) Ancillary Calculations

Page 161: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (22 µm; s=0.17,u=0.05,v=0.06,n=0.26)reflectance over white [calc] (22 µm; s=NA,u=NA,v=NA,n=0.26)reflectance over black [meas] (22 µm; s=0.07,u=0.04,v=0.06,n=0.08)reflectance over black [calc] (22 µm; s=NA,u=NA,v=NA,n=0.08)

Raw Umber [B]uv vis nir

Sunday, 09 March 2003 02:05 PM(d) Calculated vs. Measured Reflectances

Page 162: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (24 µm; s=0.36,u=0.05,v=0.15,n=0.57)reflectance over void (27 µm; s=0.29,u=0.05,v=0.15,n=0.42)reflectance over black (24 µm; s=0.25,u=0.05,v=0.15,n=0.34)transmittance (27 µm; s=0.14,u=0.00,v=0.00,n=0.27)absorptance (27 µm; s=0.57,u=0.95,v=0.85,n=0.31)

Red Oxide [B]uv vis nir

Sunday, 09 March 2003 02:08 PM(a) Spectrometer Film Measurements

Page 163: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Red Oxide [B] (27 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:08 PM(b) Kubelka−Munk Calculations

Page 164: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Red Oxide [B] (27 µm)uv vis nir

Sunday, 09 March 2003 02:08 PM(c) Ancillary Calculations

Page 165: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (24 µm; s=0.36,u=0.05,v=0.15,n=0.57)reflectance over white [calc] (24 µm; s=NA,u=NA,v=NA,n=0.56)reflectance over black [meas] (24 µm; s=0.25,u=0.05,v=0.15,n=0.34)reflectance over black [calc] (24 µm; s=NA,u=NA,v=NA,n=0.34)

Red Oxide [B]uv vis nir

Sunday, 09 March 2003 02:08 PM(d) Calculated vs. Measured Reflectances

Page 166: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (17 µm; s=0.86,u=0.29,v=0.88,n=0.89)reflectance over void (17 µm; s=0.48,u=0.29,v=0.42,n=0.55)reflectance over black (17 µm; s=0.42,u=0.29,v=0.34,n=0.50)transmittance (17 µm; s=0.46,u=0.06,v=0.53,n=0.43)absorptance (17 µm; s=0.06,u=0.65,v=0.05,n=0.01)

Interference Orange [B]uv vis nir

Sunday, 09 March 2003 02:13 PM(a) Spectrometer Film Measurements

Page 167: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Interference Orange [B] (17 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:13 PM(b) Kubelka−Munk Calculations

Page 168: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Interference Orange [B] (17 µm)uv vis nir

Sunday, 09 March 2003 02:13 PM(c) Ancillary Calculations

Page 169: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (17 µm; s=0.86,u=0.29,v=0.88,n=0.89)reflectance over white [calc] (17 µm; s=0.83,u=0.29,v=0.84,n=0.86)reflectance over black [meas] (17 µm; s=0.42,u=0.29,v=0.34,n=0.50)reflectance over black [calc] (17 µm; s=0.42,u=0.28,v=0.34,n=0.49)

Interference Orange [B]uv vis nir

Sunday, 09 March 2003 02:13 PM(d) Calculated vs. Measured Reflectances

Page 170: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (19 µm; s=0.87,u=0.27,v=0.90,n=0.90)reflectance over void (19 µm; s=0.50,u=0.27,v=0.43,n=0.57)reflectance over black (19 µm; s=0.46,u=0.28,v=0.37,n=0.55)transmittance (19 µm; s=0.45,u=0.06,v=0.53,n=0.42)absorptance (19 µm; s=0.05,u=0.67,v=0.05,n=0.01)

Interference Red [B]uv vis nir

Sunday, 09 March 2003 02:20 PM(a) Spectrometer Film Measurements

Page 171: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Interference Red [B] (19 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:20 PM(b) Kubelka−Munk Calculations

Page 172: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Interference Red [B] (19 µm)uv vis nir

Sunday, 09 March 2003 02:20 PM(c) Ancillary Calculations

Page 173: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (19 µm; s=0.87,u=0.27,v=0.90,n=0.90)reflectance over white [calc] (19 µm; s=0.84,u=0.27,v=0.85,n=0.87)reflectance over black [meas] (19 µm; s=0.46,u=0.28,v=0.37,n=0.55)reflectance over black [calc] (19 µm; s=0.44,u=0.27,v=0.36,n=0.52)

Interference Red [B]uv vis nir

Sunday, 09 March 2003 02:20 PM(d) Calculated vs. Measured Reflectances

Page 174: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (19 µm; s=0.87,u=0.24,v=0.89,n=0.90)reflectance over void (18 µm; s=0.48,u=0.24,v=0.41,n=0.56)reflectance over black (19 µm; s=0.40,u=0.24,v=0.31,n=0.49)transmittance (18 µm; s=0.46,u=0.07,v=0.54,n=0.43)absorptance (18 µm; s=0.06,u=0.69,v=0.05,n=0.01)

Interference Violet [B]uv vis nir

Sunday, 09 March 2003 02:27 PM(a) Spectrometer Film Measurements

Page 175: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Interference Violet [B] (18 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:27 PM(b) Kubelka−Munk Calculations

Page 176: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Interference Violet [B] (18 µm)uv vis nir

Sunday, 09 March 2003 02:27 PM(c) Ancillary Calculations

Page 177: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (19 µm; s=0.87,u=0.24,v=0.89,n=0.90)reflectance over white [calc] (19 µm; s=0.84,u=0.24,v=0.85,n=0.87)reflectance over black [meas] (19 µm; s=0.40,u=0.24,v=0.31,n=0.49)reflectance over black [calc] (19 µm; s=0.40,u=0.23,v=0.31,n=0.49)

Interference Violet [B]uv vis nir

Sunday, 09 March 2003 02:27 PM(d) Calculated vs. Measured Reflectances

Page 178: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (23 µm; s=0.71,u=0.05,v=0.58,n=0.87)reflectance over void (28 µm; s=0.27,u=0.05,v=0.33,n=0.24)reflectance over black (24 µm; s=0.20,u=0.05,v=0.24,n=0.18)transmittance (28 µm; s=0.50,u=0.00,v=0.27,n=0.74)absorptance (28 µm; s=0.23,u=0.95,v=0.40,n=0.02)

Yellow Medium Azo [B]uv vis nir

Sunday, 09 March 2003 02:35 PM(a) Spectrometer Film Measurements

Page 179: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Yellow Medium Azo [B] (28 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:35 PM(b) Kubelka−Munk Calculations

Page 180: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Yellow Medium Azo [B] (28 µm)uv vis nir

Sunday, 09 March 2003 02:35 PM(c) Ancillary Calculations

Page 181: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (23 µm; s=0.71,u=0.05,v=0.58,n=0.87)reflectance over white [calc] (23 µm; s=NA,u=0.05,v=NA,n=0.82)reflectance over black [meas] (24 µm; s=0.20,u=0.05,v=0.24,n=0.18)reflectance over black [calc] (24 µm; s=NA,u=0.05,v=NA,n=0.16)

Yellow Medium Azo [B]uv vis nir

Sunday, 09 March 2003 02:35 PM(d) Calculated vs. Measured Reflectances

Page 182: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (25 µm; s=0.66,u=0.05,v=0.50,n=0.86)reflectance over void (24 µm; s=0.29,u=0.05,v=0.29,n=0.32)reflectance over black (26 µm; s=0.16,u=0.05,v=0.23,n=0.11)transmittance (24 µm; s=0.44,u=0.00,v=0.23,n=0.66)absorptance (24 µm; s=0.26,u=0.95,v=0.48,n=0.02)

Yellow Orange Azo [B]uv vis nir

Sunday, 09 March 2003 02:42 PM(a) Spectrometer Film Measurements

Page 183: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Yellow Orange Azo [B] (24 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:42 PM(b) Kubelka−Munk Calculations

Page 184: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Yellow Orange Azo [B] (24 µm)uv vis nir

Sunday, 09 March 2003 02:42 PM(c) Ancillary Calculations

Page 185: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (25 µm; s=0.66,u=0.05,v=0.50,n=0.86)reflectance over white [calc] (25 µm; s=NA,u=0.05,v=NA,n=0.83)reflectance over black [meas] (26 µm; s=0.16,u=0.05,v=0.23,n=0.11)reflectance over black [calc] (26 µm; s=NA,u=0.05,v=NA,n=0.12)

Yellow Orange Azo [B]uv vis nir

Sunday, 09 March 2003 02:42 PM(d) Calculated vs. Measured Reflectances

Page 186: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (30 µm; s=0.41,u=0.05,v=0.27,n=0.56)reflectance over void (31 µm; s=0.31,u=0.05,v=0.26,n=0.37)reflectance over black (30 µm; s=0.27,u=0.05,v=0.26,n=0.29)transmittance (31 µm; s=0.20,u=0.00,v=0.04,n=0.36)absorptance (31 µm; s=0.49,u=0.95,v=0.70,n=0.27)

Yellow Oxide [B]uv vis nir

Sunday, 09 March 2003 02:45 PM(a) Spectrometer Film Measurements

Page 187: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Yellow Oxide [B] (31 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:45 PM(b) Kubelka−Munk Calculations

Page 188: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Yellow Oxide [B] (31 µm)uv vis nir

Sunday, 09 March 2003 02:45 PM(c) Ancillary Calculations

Page 189: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (30 µm; s=0.41,u=0.05,v=0.27,n=0.56)reflectance over white [calc] (30 µm; s=NA,u=NA,v=NA,n=0.55)reflectance over black [meas] (30 µm; s=0.27,u=0.05,v=0.26,n=0.29)reflectance over black [calc] (30 µm; s=NA,u=NA,v=NA,n=0.29)

Yellow Oxide [B]uv vis nir

Sunday, 09 March 2003 02:45 PM(d) Calculated vs. Measured Reflectances

Page 190: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (18 µm; s=0.87,u=0.16,v=0.90,n=0.90)reflectance over void (17 µm; s=0.45,u=0.16,v=0.41,n=0.52)reflectance over black (19 µm; s=0.40,u=0.16,v=0.34,n=0.47)transmittance (17 µm; s=0.49,u=0.08,v=0.54,n=0.48)absorptance (17 µm; s=0.06,u=0.75,v=0.05,n=0.01)

Interference Blue [B]uv vis nir

Sunday, 09 March 2003 02:48 PM(a) Spectrometer Film Measurements

Page 191: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Interference Blue [B] (17 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:48 PM(b) Kubelka−Munk Calculations

Page 192: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Interference Blue [B] (17 µm)uv vis nir

Sunday, 09 March 2003 02:48 PM(c) Ancillary Calculations

Page 193: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (18 µm; s=0.87,u=0.16,v=0.90,n=0.90)reflectance over white [calc] (18 µm; s=0.83,u=0.16,v=0.85,n=0.88)reflectance over black [meas] (19 µm; s=0.40,u=0.16,v=0.34,n=0.47)reflectance over black [calc] (19 µm; s=0.40,u=0.16,v=0.34,n=0.47)

Interference Blue [B]uv vis nir

Sunday, 09 March 2003 02:48 PM(d) Calculated vs. Measured Reflectances

Page 194: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (25 µm; s=0.87,u=0.14,v=0.95,n=0.88)reflectance over void (24 µm; s=0.73,u=0.14,v=0.85,n=0.68)reflectance over black (26 µm; s=0.69,u=0.14,v=0.84,n=0.61)transmittance (24 µm; s=0.20,u=0.00,v=0.11,n=0.29)absorptance (24 µm; s=0.07,u=0.86,v=0.04,n=0.03)

Titanium White [B]uv vis nir

Sunday, 09 March 2003 02:51 PM(a) Spectrometer Film Measurements

Page 195: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Titanium White [B] (24 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:51 PM(b) Kubelka−Munk Calculations

Page 196: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Titanium White [B] (24 µm)uv vis nir

Sunday, 09 March 2003 02:51 PM(c) Ancillary Calculations

Page 197: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (25 µm; s=0.87,u=0.14,v=0.95,n=0.88)reflectance over white [calc] (25 µm; s=NA,u=NA,v=NA,n=0.85)reflectance over black [meas] (26 µm; s=0.69,u=0.14,v=0.84,n=0.61)reflectance over black [calc] (26 µm; s=NA,u=NA,v=NA,n=0.62)

Titanium White [B]uv vis nir

Sunday, 09 March 2003 02:51 PM(d) Calculated vs. Measured Reflectances

Page 198: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (31 µm; s=0.85,u=0.18,v=0.86,n=0.90)reflectance over void (37 µm; s=0.53,u=0.18,v=0.56,n=0.53)reflectance over black (31 µm; s=0.43,u=0.18,v=0.47,n=0.42)transmittance (37 µm; s=0.39,u=0.02,v=0.35,n=0.46)absorptance (37 µm; s=0.08,u=0.79,v=0.09,n=0.01)

Interference Green [B]uv vis nir

Sunday, 09 March 2003 02:54 PM(a) Spectrometer Film Measurements

Page 199: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Interference Green [B] (37 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:54 PM(b) Kubelka−Munk Calculations

Page 200: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Interference Green [B] (37 µm)uv vis nir

Sunday, 09 March 2003 02:54 PM(c) Ancillary Calculations

Page 201: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (31 µm; s=0.85,u=0.18,v=0.86,n=0.90)reflectance over white [calc] (31 µm; s=0.83,u=0.18,v=0.83,n=0.88)reflectance over black [meas] (31 µm; s=0.43,u=0.18,v=0.47,n=0.42)reflectance over black [calc] (31 µm; s=0.43,u=0.18,v=0.47,n=0.42)

Interference Green [B]uv vis nir

Sunday, 09 March 2003 02:54 PM(d) Calculated vs. Measured Reflectances

Page 202: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (25 µm; s=0.87,u=0.25,v=0.90,n=0.89)reflectance over void (21 µm; s=0.45,u=0.24,v=0.44,n=0.47)reflectance over black (25 µm; s=0.42,u=0.24,v=0.40,n=0.45)transmittance (21 µm; s=0.51,u=0.18,v=0.53,n=0.52)absorptance (21 µm; s=0.04,u=0.58,v=0.03,n=0.01)

Interference Gold [B]uv vis nir

Sunday, 09 March 2003 02:59 PM(a) Spectrometer Film Measurements

Page 203: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Interference Gold [B] (21 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 02:59 PM(b) Kubelka−Munk Calculations

Page 204: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Interference Gold [B] (21 µm)uv vis nir

Sunday, 09 March 2003 02:59 PM(c) Ancillary Calculations

Page 205: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (25 µm; s=0.87,u=0.25,v=0.90,n=0.89)reflectance over white [calc] (25 µm; s=0.83,u=0.24,v=0.87,n=0.86)reflectance over black [meas] (25 µm; s=0.42,u=0.24,v=0.40,n=0.45)reflectance over black [calc] (25 µm; s=0.41,u=0.22,v=0.40,n=0.44)

Interference Gold [B]uv vis nir

Sunday, 09 March 2003 02:59 PM(d) Calculated vs. Measured Reflectances

Page 206: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (25 µm; s=0.85,u=0.31,v=0.87,n=0.88)reflectance over void (23 µm; s=0.48,u=0.30,v=0.58,n=0.41)reflectance over black (22 µm; s=0.44,u=0.30,v=0.54,n=0.37)transmittance (23 µm; s=0.42,u=0.09,v=0.31,n=0.54)absorptance (23 µm; s=0.10,u=0.61,v=0.11,n=0.05)

Exterior Bright White [A]uv vis nir

Sunday, 09 March 2003 03:03 PM(a) Spectrometer Film Measurements

Page 207: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Exterior Bright White [A] (23 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 03:03 PM(b) Kubelka−Munk Calculations

Page 208: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Exterior Bright White [A] (23 µm)uv vis nir

Sunday, 09 March 2003 03:03 PM(c) Ancillary Calculations

Page 209: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (25 µm; s=0.85,u=0.31,v=0.87,n=0.88)reflectance over white [calc] (25 µm; s=0.75,u=0.30,v=0.76,n=0.78)reflectance over black [meas] (22 µm; s=0.44,u=0.30,v=0.54,n=0.37)reflectance over black [calc] (22 µm; s=0.42,u=0.29,v=0.53,n=0.34)

Exterior Bright White [A]uv vis nir

Sunday, 09 March 2003 03:03 PM(d) Calculated vs. Measured Reflectances

Page 210: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (20 µm; s=0.72,u=0.20,v=0.62,n=0.85)reflectance over void (20 µm; s=0.42,u=0.19,v=0.36,n=0.48)reflectance over black (22 µm; s=0.38,u=0.19,v=0.34,n=0.44)transmittance (20 µm; s=0.44,u=0.09,v=0.43,n=0.48)absorptance (20 µm; s=0.15,u=0.72,v=0.21,n=0.04)

Exterior Brass [A]uv vis nir

Sunday, 09 March 2003 03:06 PM(a) Spectrometer Film Measurements

Page 211: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Exterior Brass [A] (20 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 03:06 PM(b) Kubelka−Munk Calculations

Page 212: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Exterior Brass [A] (20 µm)uv vis nir

Sunday, 09 March 2003 03:06 PM(c) Ancillary Calculations

Page 213: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (20 µm; s=0.72,u=0.20,v=0.62,n=0.85)reflectance over white [calc] (20 µm; s=0.68,u=0.19,v=0.59,n=0.80)reflectance over black [meas] (22 µm; s=0.38,u=0.19,v=0.34,n=0.44)reflectance over black [calc] (22 µm; s=0.37,u=0.19,v=0.32,n=0.43)

Exterior Brass [A]uv vis nir

Sunday, 09 March 2003 03:06 PM(d) Calculated vs. Measured Reflectances

Page 214: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (22 µm; s=0.82,u=0.22,v=0.82,n=0.88)reflectance over void (20 µm; s=0.44,u=0.21,v=0.42,n=0.47)reflectance over black (22 µm; s=0.39,u=0.20,v=0.37,n=0.42)transmittance (20 µm; s=0.49,u=0.16,v=0.50,n=0.51)absorptance (20 µm; s=0.07,u=0.64,v=0.08,n=0.01)

Exterior Bright Gold [A]uv vis nir

Sunday, 09 March 2003 03:08 PM(a) Spectrometer Film Measurements

Page 215: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Exterior Bright Gold [A] (20 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 03:08 PM(b) Kubelka−Munk Calculations

Page 216: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Exterior Bright Gold [A] (20 µm)uv vis nir

Sunday, 09 March 2003 03:08 PM(c) Ancillary Calculations

Page 217: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (22 µm; s=0.82,u=0.22,v=0.82,n=0.88)reflectance over white [calc] (22 µm; s=0.79,u=0.20,v=0.78,n=0.86)reflectance over black [meas] (22 µm; s=0.39,u=0.20,v=0.37,n=0.42)reflectance over black [calc] (22 µm; s=0.38,u=0.19,v=0.36,n=0.41)

Exterior Bright Gold [A]uv vis nir

Sunday, 09 March 2003 03:08 PM(d) Calculated vs. Measured Reflectances

Page 218: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (23 µm; s=0.53,u=0.11,v=0.35,n=0.72)reflectance over void (22 µm; s=0.35,u=0.11,v=0.32,n=0.40)reflectance over black (22 µm; s=0.33,u=0.11,v=0.31,n=0.37)transmittance (22 µm; s=0.32,u=0.03,v=0.13,n=0.51)absorptance (22 µm; s=0.32,u=0.85,v=0.55,n=0.09)

Exterior Bright Bronze [A]uv vis nir

Sunday, 09 March 2003 03:11 PM(a) Spectrometer Film Measurements

Page 219: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Exterior Bright Bronze [A] (22 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 03:11 PM(b) Kubelka−Munk Calculations

Page 220: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Exterior Bright Bronze [A] (22 µm)uv vis nir

Sunday, 09 March 2003 03:11 PM(c) Ancillary Calculations

Page 221: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (23 µm; s=0.53,u=0.11,v=0.35,n=0.72)reflectance over white [calc] (23 µm; s=0.53,u=0.11,v=0.35,n=0.71)reflectance over black [meas] (22 µm; s=0.33,u=0.11,v=0.31,n=0.37)reflectance over black [calc] (22 µm; s=0.31,u=0.11,v=0.30,n=0.34)

Exterior Bright Bronze [A]uv vis nir

Sunday, 09 March 2003 03:11 PM(d) Calculated vs. Measured Reflectances

Page 222: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (22 µm; s=0.48,u=0.10,v=0.27,n=0.68)reflectance over void (24 µm; s=0.36,u=0.10,v=0.24,n=0.48)reflectance over black (25 µm; s=0.34,u=0.10,v=0.24,n=0.44)transmittance (24 µm; s=0.25,u=0.02,v=0.11,n=0.38)absorptance (24 µm; s=0.39,u=0.88,v=0.65,n=0.14)

Exterior Bright Copper [A]uv vis nir

Sunday, 09 March 2003 03:13 PM(a) Spectrometer Film Measurements

Page 223: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Exterior Bright Copper [A] (24 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 03:13 PM(b) Kubelka−Munk Calculations

Page 224: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Exterior Bright Copper [A] (24 µm)uv vis nir

Sunday, 09 March 2003 03:13 PM(c) Ancillary Calculations

Page 225: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (22 µm; s=0.48,u=0.10,v=0.27,n=0.68)reflectance over white [calc] (22 µm; s=0.48,u=0.10,v=0.27,n=0.68)reflectance over black [meas] (25 µm; s=0.34,u=0.10,v=0.24,n=0.44)reflectance over black [calc] (25 µm; s=0.33,u=0.10,v=0.23,n=0.44)

Exterior Bright Copper [A]uv vis nir

Sunday, 09 March 2003 03:13 PM(d) Calculated vs. Measured Reflectances

Page 226: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

, Tra

nsm

ittan

ce, A

bsor

ptan

ce

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white (19 µm; s=0.46,u=0.09,v=0.23,n=0.68)reflectance over void (22 µm; s=0.33,u=0.09,v=0.19,n=0.47)reflectance over black (22 µm; s=0.31,u=0.09,v=0.18,n=0.43)transmittance (22 µm; s=0.28,u=0.04,v=0.16,n=0.40)absorptance (22 µm; s=0.39,u=0.87,v=0.65,n=0.13)

Exterior Russet [A]uv vis nir

Sunday, 09 March 2003 03:16 PM(a) Spectrometer Film Measurements

Page 227: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Abs

orpt

ion,

Sca

tterin

g [m

m−1

]

10−

110

010

110

210

3

absorption (K)scattering (S)opaque reflectance (R∞)

Exterior Russet [A] (22 µm)uv vis nir

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

Ref

lect

ance

Sunday, 09 March 2003 03:16 PM(b) Kubelka−Munk Calculations

Page 228: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Diff

usen

ess,

Diff

usen

ess

Err

or, S

catte

ring

Rat

io

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

characteristic diffuseness (q̂)absolute error in characteristic diffuseness (|q̂ − q0

+|)back scattering / total scattering (φ)

Exterior Russet [A] (22 µm)uv vis nir

Sunday, 09 March 2003 03:16 PM(c) Ancillary Calculations

Page 229: Guide To LBNL Pigment Characterization Charts...Mar 11, 2003  · classic Kubelka-Munk two-flux theois used to ry calculate the pigment’s absorption coeK afnd ficient backscattering

500 1000 1500 2000 2500

Wavelength (nanometers)

Ref

lect

ance

00.

10.

20.

30.

40.

50.

60.

70.

80.

91

reflectance over white [meas] (19 µm; s=0.46,u=0.09,v=0.23,n=0.68)reflectance over white [calc] (19 µm; s=0.47,u=0.09,v=0.24,n=0.69)reflectance over black [meas] (22 µm; s=0.31,u=0.09,v=0.18,n=0.43)reflectance over black [calc] (22 µm; s=0.30,u=0.09,v=0.17,n=0.42)

Exterior Russet [A]uv vis nir

Sunday, 09 March 2003 03:16 PM(d) Calculated vs. Measured Reflectances