Graffiti Remover SDS - June 2016 -...

SafetyDataSheet

GraffitiRemoverMountainCleaningProducts

IssueDate:June2016Validto:June2021

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SECTION1:IDENTIFICATIONOFPRODUCTANDCOMPANY

TradeName: GraffitiRemoverSynonyms: NA

ChemicalFormula: NACASNumber: NAProductUses: Cleaningoffgraffiti

Supplier/Manufacturer: MountainCleaningProducts

Address: 7/7/SnowSt,SouthLismore,NSW2480Telephone: 0266228733

Fax: 0266228744Email: [email protected]

Website: www.mountaincleaning.com.auEmergencyTelephone: 131126(PoisonsInformationCentre)

SECTION2:HAZARD(S)IDENTIFICATION

GHSClassification: Skincorrosion(Category1A).Skinsensitisation(Category1).

LABELLINGELEMENTS:

SignalWord: DangerPictogram(s):

CorrosiveHealthhazards

HazardStatements(s): H227Combustibleliquid.H314Causessevereskinburnsandeyedamage.H317Maycauseallergicskinreaction.

PrecautionaryStatement(s):

PreventionP210Keepawayfromheat,hotsurfaces,sparks,openflamesandotherignitionsources.Nosmoking.P260Donotbreathefumes/gas/mist/vapours/spray.P264Washhandsthoroughlyafterhandling.

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P272.Contaminatedworkclothingshouldnotbeallowedoutoftheworkplace.P280Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.ResponseP301+P330+P331IFSWALLOWED:Rinsemouth.DoNOTinducevomiting.P303+P361+P353IFONSKIN(orhair):Immediatelytakeoffallcontaminatedclothing.Rinseskinwithwater/shower.P333+P313Ifskinirritationorrashoccurs,seekmedicaladvice.P362+P364Takeoffcontaminatedclothingandwashbeforereuse.P304+P340IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.P305+P351+P338IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.P310ImmediatelycallaPOISONCENTRE(131126)ordoctor.P321Specifictreatment,seeFirstAidMeasuresonthisSafetyDataSheet.P370+P378Incaseoffireusemedia,asoutlinedinSection5ofthisSDS,toextinguish.

Storage: P403Storeinawellventilatedplace.P405Storelockedup.

Disposal: P501Disposeofcontents/containertoanapprovedwastedisposalplant.

SECTION3:COMPOSITIONANDINFORMATIONONINGREDIENTSIngredients CASNo.s Percentage(w/w) ClassificationD-limonene 5989-27-5 10-30% H315+H402+H413Potassiumhydroxide 1310-58-3 10-20% H290+H3141-methoxy-2-propanol 107-98-2 10-20% H226+H336Cocamidopropylbetaine 61789-40-0 <5% H318Alkylpolyglucoside 110615-47-9 <10% H318Ethylalcohol

64-17-5 10–20% H225+H319

Otheringredients <10%

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determinedtobenonhazardousorbelowconcentrationcutoffsSECTION4:FIRSTAIDMEASURES

FirstAidFacilities: Normalwashroomfacilities.Safetyshowerandemergencyeyewash.

EyeContact: Immediatelyirrigatewithcopiousquantitiesofwaterforatleast30minutes.Eyelidstobeheldopen.Avoidrinsewaterenteringuncontaminatedeye.Seekmedicaladvice(e.g.ophthalmologist).

SkinContact: Removecontaminatedclothing.Immediatelywashcontaminatedskinwithplentyofwater.Seekmedicaladviceifirritation,burningorrednessdevelops.

Inhalation: Removevictimtofreshairawayfromexposure-avoidbecomingacasualty.Removecontaminatedclothingandloosenremainingclothing.Allowpatienttoassumemostcomfortableposition,keepwarmandatrest.Ifbreathinglabouredandpatientcyanotic(blue),ensureairwaysareclearandhavequalifiedpersongiveoxygenthroughafacemask.Ifbreathinghasstoppedapplyartificialrespirationatonce.Seekmedicaladvice.

Ingestion: DoNOTinducevomiting.DoNOTattempttogiveanythingbymouthtoanunconsciousperson.Ifconscious,rinsemouththoroughlywithwaterandgivewatertodrink.Ifvomitingoccurs,givefurtherwatertoachieveeffectivedilution.Seekmedicaladvice.

AdvicetoDoctor: Nospecificantidote.Treatsymptomaticallyforchemicalburns.Alltreatmentsshouldbebasedonobservedsignsandsymptomsofdistressofthepatient.PoisonsInformationCentreineachAustralianStatecapitalcityorinChristchurch,NewZealandcanprovideadditionalassistanceforscheduledpoisons.

ScheduledPoisons: PoisonsInformationCentreineachAustralianStatecapitalcitycanprovideadditionalassistanceforscheduledpoisons.PhoneAustralia131126.

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SECTION5:FIREFIGHTINGMEASURESFireandExplosionHazard: Combustible.Ifinvolvedinafirewillemittoxicfumes.Canreact

withmetalstoproduceflammablehydrogengas.ExtinguishingMedia: Ifmaterialisinvolvedinafireusefinewaterspray,normal

foamordryagentextinguisher(carbondioxideordrychemicalpowder).

FireFighting°: Keepcontainersexposedtoextremeheatcoolwithfinewaterspray.Firefighterstowearself-containedbreathingapparatusifriskofexposuretoproductsofcombustionordecomposition.Evacuateareaandmoveupwindoffire.

FlashPoint: >61°CHazchemCode: 2X.

SECTION6:ACCIDENTALRELEASEMEASURES

MinorSpills: Donotnormallyrequirespecialclean-upmeasures.Sweepupresiduesandrinseareawithwater.

MajorSpills: Forexampletransportaccidentorbulkspill.Clearareaofunprotectedpersonnel.Workupwindorincreaseventilation.Preventspillagefromenteringdrainsorwatercourses.Wearappropriateprotectiveequipment(seesection8)topreventskinandeyecontaminationandinhalationoffumes.Containspillage,thencover/absorbspillintodry,inertmaterial(e.g.sand,earthorvermiculite),collectandplaceintosuitablecontainers,appropriatelylabeled,fordisposalbyanapprovedagentaccordingtolocalconditions.Spillageareamayremainslippery.Flushspillareawithwater.Ifcontaminationofsewersorwaterwayshasoccurredadvisethelocalemergencyservices.Intheeventofalargespillagenotifythelocalenvironmentprotectionauthorityoremergencyservices.

PPE: PersonalprotectiveequipmentadviceiscontainedinSection8ofthisdocument.

SECTION7:HANDLINGANDSTORAGE

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Handling: Avoidskinandeyecontactandavoidbreathinginvapours.Keepoutofreachofchildren.Alwayswashhandswithwaterafterhandling.

Storage: Storeinacool,dry,placewithgoodventilation.Avoidstoringinaluminiumandalloycontainers.Storeawayfromincompatiblematerials(seeSection10).Keepcontainersclosedatalltimeswhennotinuse.

SECTION8:EXPOSURECONTROLSANDPERSONALPROTECTIONOCCUPATIONALEXPOSURELIMITS:Noneestablishedforthisproduct.Ingredient TWA STEL NotesPotassiumhydroxide 2mg/m3 2mg/m3Peak 1-methoxy-2-propanol 369mg/m3 553mg/m3

PersonalProtection: Chemicalgogglesorfaceshieldandrubbergloves(LONG)undernormalconditionsofuse.Faceshield,gloves(LONG),coveralls,apronandrubberbootswherecontaminationislikely.

EngineeringControls: Ensureventilationisadequate.Useonlyinawellventilatedarea.Avoidgeneratingmistsofproduct.Whereaninhalationriskexists,mechanicalextractionventilationisrecommendedtomaintainvapourlevelsbelowrecommendedexposurestandard.Ensureairflow,wherethisproductisused,isdirectedawayfromoperators.

EyeandFaceProtection: Chemicalgoggles,safetyglassesorfaceshield.HandandSkinProtection: WearimperviousPVCorrubbergloves(long)todispense.

Whenusinglargequantitiesorwhereheavycontaminationislikely,wearcoverallsandfootwearthatprovidesprotectionagainstacids/alkalisandaPVCapron.

InhalationProtection: Notnormallyrequiredundernormaluseconditionsinwell-ventilatedareas.WhereaninhalationriskexistsweararespiratorthatmeetsAS/NZS1715andAS/NZS1716.Foremergencies,orwhereexposurelevelsareunknown,useafullface-piecepositivepressureairsuppliedrespirator.Warning:Airpurifyingrespiratorsdonotprotectworkersinoxygen-deficientatmospheres.Emergency,orplannedentryintounknownconcentrationusepositivepressurewithfullface-pieceSCBA(selfcontainedbreathingapparatus).Expertadvice

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mayberequiredtoselectcorrectrespiratorinunknownandemergencyconditions.

SECTION9:PHYSICALANDCHEMICALPROPERTIES

Appearance: Clear,deepstrawliquid

Odour: Citrus VapourPressure: NotavailableOdourThreshold: Notavailable VapourDensity: Notavailable

pH: >13.0neat RelativeDensity(Water=1):

1.0–1.1@25°C

Melting/FreezingPoint:

0°Capprox. WaterSolubility: Miscibleinallportions

BoilingPoint: 100°Capprox. PartitionCoefficientn-Octanol/Water

Notavailable

FlashPoint: >61°C Auto-ignitionTemperature

Notavailable

EvaporationRate: Notavailable DecompositionTemperature

Notavailable

Flammability: Notflammable Viscosity NonviscousUpper/LowerFlammability:

Notavailable

SECTION10:STABILITYANDREACTIVITY

Reactivity: Low.ChemicalStability: Stableundernormalconditionsofstorageandhandling.

Contaminationofproductandexposuretolightwillacceleratedecomposition.

PossibilityofHazardousReactions:

Reactsvigorouslywithacids,producingheatandpressurethatcanburstaclosedcontainer.Reactswithreactivemetalssuchasaluminium,magnesiumzincalloys,releasingflammablehydrogengasthatmaybeafireorexplosionhazard.Reactsslowlywithambientair(particularlycarbondioxide),whichmaycauseinsolublesaltstoforminsolution.

ConditionstoAvoid: Avoidheatsources,contactwithincompatiblematerialsand

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storageinmetalcontainers.IncompatibleMaterials: Acids,salts,peroxidesandreducingagents.

SECTION11:TOXICOLOGICALINFORMATION

Inhaled: Breathinginmistsoraerosolsmayproducemucousmembraneandrespiratoryirritation.Exposuretohighconcentrationsofproductmayleadtoharmfulcorrosiveeffectsincludinglesionsofthenasalseptum,pulmonaryoedema,pneumonitisandemphysema.

SkinContact: Corrosivetoskin.Maycauseskinburnsandsevereirritation.Corrosionwillcontinueuntilproductremoved.Severitydependsonconcentrationanddurationofcontact.Burnsmaynotbeimmediatelypainful;onsetofpainmaybeminutestohours.Repeatedcontactmayleadtosensitizationorallergicreaction.

EyeContact: Corrosivetoeyes.Contactcancauseirritation;redness,cornealburnsandcanpossiblyresultinpermanentinjury,includinglossofsight.Highconcentrationsofvapoursmaycauseirritation.

Ingestion: Swallowingcanresultinnausea,vomitingofbloodanderodedtissue,diarrhoea,abdominalpainandchemicalburnstothemouth,throat,abdomenandgastrointestinaltract.

AcuteToxicity: NoLD50dataavailableforthisproduct.Foractiveconstituent,potassiumhydroxide(at100%):OralLD50(rat)-333mg/kg Foractiveconstituent,d-Limonene(at>99%):OralLD50(rat)-4400mg/kgDermalLD50(rabbit)->2000mg/kgDermalLD50(mice)–5600-6000mg/kgForactiveconstituent,1-methoxy-2-propanol(at50%):OralLD50(rat)->5000mg/kgDermalLD50(rabbit)–13-14gm/kg

Chronic: Noinformationavailable.SECTION12:ECOLOGICALINFORMATION

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Ecotoxicity: Acuteaquatictoxicity(Category3).Chronicaquatictoxicity(Category4).Harmfultoaquaticlifewithlonglastingeffects.Nodataavailableforthisproduct.Foractiveconstituent,potassiumhydroxide(at100%):LC50(Gambusiaaffinis(Mosquitofish))–80mg/l-96h.Foractiveconstituent,d-Limonene(at>99%):LC50(fish)-<1mg/l–96h.Avoidcontaminatingwaterways.AcuteandchroniceffectsexpectedinadditiontopossiblelocalisedpHeffect.

PersistenceandDegradability:

D-limonenestatedtobeamarinepollutant–slighthazardforwater;abiodegradablesolventoccurringinnatureasthemaincomponentofpeeloil.100%in28days.

BioaccumulativePotential:

Highlywatersolubleandunlikelytobioconcentrateinorganisms.

MobilityinSoil: Miscibleinwatersolubleandmobile.OtherAdverseAffects: Noneknown.

SECTION13:DISPOSALCONSIDERATIONS

DisposalMethods: RefertoWasteManagementAuthority.Disposeofmaterialthroughalicensedwastecontractor.Decontaminationanddestructionofcontainersshouldbeconsidered.

SECTION14:TRANSPORTINFORMATIONADGCodeClassification: DangerousGoods.

UNNo.: 1760ProperShippingName: CORROSIVELIQUID,N.O.S.TransportHazardClass: 8–Corrosive

PackingGroup: IIIHazchemCode: 2X

EnvironmentalHazardsforTransport:

Corrosiveliquid.Avoidgettingintowaterways.

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SECTION15:REGULATORYINFORMATIONSUSMP(PoisonSchedule): S6PoisonSECTION16:OTHERINFORMATION

Abbreviations: ADG–AustralianCodefortheTransportofDangerousGoodsbyRoadandRail.CASNo.-ChemicalAbstractServiceNumberusedtouniquelyidentifychemicalcompounds.GHS-GloballyHarmonisedSystem.IARC-InternationalAgencyforResearchonCancer.LD50-LethalDose,50%/medianLethalDose.Mg/m3-Milligramspercubicmetre.PPM–Partspermillion.STEL–ShortTermExposureLimit.STOT-RE–SpecificTargetOrganToxicity(repeatedexposure).STOT–SE-SpecificTargetOrganToxicity(singleexposure).SUSMP–StandardfortheUniformSchedulingofMedicinesandPoisons.TWA/OEL–TimeWeightedAverageorOccupationalExposurelimit.

RevisionHistory: Rev1.0InitialSDSforGHScompliance.PreparedBy: MountainCleaningProductsRegulatoryService.

ENDOFSDS

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