Gardobond_additive h 7375 Msds Ver1

8/11/2019 Gardobond_additive h 7375 Msds Ver1

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SAFETY DATA SHEETaccording to EC directive 91/155/EC

Gardobond-Additive H 7375

Version: 1. 07.04.2003

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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE

COMPANY/UNDERTAKING

English

Product information

Commercial Product Name Gardobond-Additive H 7375

Company: Chemetall plc

Denbigh Road

Bletchley Milton Keynes MK1 1PB

Lead Organisation:

Telephone: 01908 649333

Telefax: 01908 373939

Emergency telephone number: 01908 649333

Contact person:

2. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components CAS-No.

EINECS-No.

ELINCS-No.

Symbol(s): R-

phrase(s)

Concentration

Fatty alcohol polyglycol ether 97043-91-9 Xn R22, R41 10.00 - 25.00 %

Dodecyl benzol sulfonate,

sodium salt

Xi R41 10.00 - 25.00 %

Ethane-1,2-diol 107-21-1

203-473-3

Xn R22 2.50 - 10.00 %

3. HAZARDS IDENTIFICATION

Risk advice to man and the environment

Indication of danger: Xn Harmful

R22 Harmful if swallowed.

R41 Risk of serious damage to eyes.

4. FIRST AID MEASURES

General advice:

Take off contaminated clothing and shoes immediately.

Eye contact:

In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Skin contact:

Wash off immediately with plenty of water.


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Inhalation:

Move to fresh air. If symptoms persist, call a physician.

Ingestion:

Rinse mouth. Call a physician immediately.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media:

carbon dioxide (CO2), dry powder, water spray, alcohol-resistant foam

Further information:

Water mist may be used to cool closed containers.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions:

Wear personal protective equipment.

Environmental precautions:

Do not flush into surface water or sanitary sewer system.

Methods for cleaning up:

Soak up with liquid binder (sand, kieselguhr, acid binder, universal binder). Take up mechanically and

collect in suitable container for disposal.

7. HANDLING AND STORAGE

Handling

Safe handling advice:

No special precautions required

Advice on protection against fire and explosion:

Normal measures of preventive fire protection. No special protective measures against fire required

Storage

Requirements for storage areas and containers:

Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the original

container.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Components with workplace control parameters

Ethane-1,2-diol 107-21-1

Value Update Basis

TWA 10.00 mg/m3 2001 EH40 OES

TWA 60.00 mg/m3 2001 EH40 OES

STEL 125.00 mg/m3 2001 EH40 OES

TWA 52.00 mg/m3 20.00 ppm 05 2001 EU ELV

STEL 104.00 mg/m3 40.00 ppm 05 2001 EU ELV

SKIN_DES Can be absorbed through the skin. 05 2001 EU ELV

Personal protective equipment

Respiratory protection:


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Not required; except in case of aerosol formation.

Hand protection:

impervious gloves

Eye protection:

tightly fitting safety goggles

Skin and body protection:

protective suit

Hygiene measures:

Take off contaminated clothing and shoes immediately. Avoid contact with the skin and the eyes. Keep

away from food, drink and animal feedingstuffs. Wash hands before breaks and at the end of workday.

Protective measures:

Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form: liquid

Colour: light yellow

Odour: perceptible

Change in physical state

Solidification

temperature/range:

< -7.0 C

Flash point: not applicable

Autoignition temperature : not applicable

Lower explosion limit: not applicable

Density: 1.02 - 1.06 g/cm3

at 20.0 C

Method: DIN 51757

Water solubility: completely miscible

pH: 3.4 - 4.4

at: 10.0 g/l

at: 20.0 C

Viscosity: ca. 16.0 sec.at 20.0 C

Method: ISO 2431/4mm

10. STABILITY AND REACTIVITY

Hazardous decomposition products

No decomposition if used as directed.

Hazardous reactions:

No dangerous reaction known.

Note:

No decomposition if used as directed.


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11. TOXICOLOGICAL INFORMATION

Skin irritation:

May cause skin irritation in susceptible persons.

Eye irritation:

Risk of serious damage to eyes.

Sensitization:

unknown


Degreases the skin.Harmful if swallowed.

12. ECOLOGICAL INFORMATION

Elimination information (persistence and degradability)


water endangering


Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Even leakage ofsmall amounts in the subsoil can contaminate drinking water. The surfactants contained in the product are

covered by legal regulations on biodegradability.

13. DISPOSAL CONSIDERATIONS

Waste key for the unused product:

070608 other still bottoms and reaction residues

Product:

Dispose of as special waste in compliance with the Control of Pollution (Special Waste) Regulations 1980.

Contaminated packaging:

Dispose of as special waste in compliance with the Control of Pollution (Special Waste) Regulations 1980.

14. TRANSPORT INFORMATION

Not classified as dangerous in the meaning of transport regulations.


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15. REGULATORY INFORMATION

Hazardous components which must be listed on the label:

Fatty alcohol polyglycol ether

Ethane-1,2-diol

Labelling: Xn Harmful

R-phrase(s): R22 Harmful if swallowed.

R41 Risk of serious damage to eyes.

S-phrase(s): S26 In case of contact with eyes, rinse immediately with plenty

of water and seek medical advice.

S28 After contact with skin, wash immediately with plenty ofwater.

S36/37/39 Wear suitable protective clothing, gloves and eye/face

protection.

Exceptional labelling of special preparations:

Ingredients according to EC recommendation (89/542/EWG):

Non ionic surfactants, 15 - 30 %

Anionic surfactants, 15 - 30 %

Other regulations:

The product is classified and labelled in accordance with EC directives or respective national laws.

16. OTHER INFORMATION

Text of R phrases mentioned in Section 2+3

R22 Harmful if swallowed.R41 Risk of serious damage to eyes.R41 Risk of serious damage to eyes.

R22 Harmful if swallowed.R22 Harmful if swallowed.R41 Risk of serious damage to eyes.

The information provided is based on our current knowledge and experience and apply to the product asdelivered. Regarding the product properties, these are not guaranteed. The delivery of this safety datasheet

does not free the recipient of the product from his own responsibility to follow the relevant rules and

regulations concerning this product.

Gardobond_additive h 7375 Msds Ver1

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