G.4.4 Stage 3 Water Quality Laboratory

Results

CE

RT

IFIC

AT

E O

F A

NA

LY

SIS

SIN

CLA

IR K

NIG

HT

MER

Z1

of 5

P

ag

e:

La

bo

rato

ry:

Clie

nt

:En

viro

nmen

tal D

ivis

ion

Bris

bane

Co

nta

ct

:

Ad

dre

ss

:

Co

nta

ct

:

Ad

dre

ss

:LE

VEL

1 3

69 A

NN

STR

EET

BR

ISB

AN

E Q

LD

AU

STR

ALI

A 4

000

:K

AVI

TA P

RA

SAD

Tim

Kilm

iste

rEB

0711

541

32 S

hand

Str

eet S

taffo

rd Q

LD A

ustr

alia

405

3W

ork

Ord

er

E-m

ail

:E

-ma

il:

kpra

sad@

skm

.com

.au

Serv

ices

.Bris

bane

@al

senv

iro.c

omT

ele

ph

on

e:

Fa

csim

ile:

Te

lep

ho

ne

:

Fa

csim

ile:

3244

7381

+61-

7-32

43 7

222

0732

4473

06+6

1-7-

3243

721

88

Oct

200

7EN

/003

/05

Qu

ote

nu

mb

er

:Q

E064

55.0

04P

roje

ct

:

SKM

SQ

Ord

er

nu

mb

er

:

- Not

pro

vide

d -

C-O

-C n

um

be

r:

New

Acl

ands

EIS

Site

:A

na

lyse

d:

Re

ce

ive

d:

1010N

o.

of

sa

mp

les

-

16 O

ct 2

007

Da

te issu

ed

:

Da

te r

ece

ive

d:

AL

SE

- E

xc

ell

en

ce

in

An

aly

tic

al

Te

sti

ng

NA

TA A

ccre

dite

d La

bora

tory

825

This

doc

umen

t is

issu

ed in

ac

cord

ance

with

NA

TA's

ac

cred

itatio

n re

quire

men

ts.

Acc

redi

ted

for c

ompl

ianc

e w

ith

ISO

/IEC

170

25.

This

doc

umen

t has

bee

n el

ectro

nica

lly s

igne

d by

thos

e na

mes

that

app

ear o

n th

is re

port

and

are

the

auth

oris

ed s

igna

torie

s. E

lect

roni

c si

gnin

g ha

s be

en c

arrie

d ou

t in

com

plia

nce

with

pro

cedu

res

spec

ified

in 2

1 C

FR P

art 1

1.

Sig

na

tory

De

pa

rtm

en

tP

ositio

n

Kim

McC

abe

Inor

gani

cs -

NA

TA 8

25 (8

18 -

Bris

bane

)Se

nior

Inor

gani

c C

hem

ist

SIN

CLA

IR K

NIG

HT

MER

ZC

lien

t:

EB07

1154

1

2 of

5

Pa

ge

Nu

mb

er

: :W

ork

Ord

er

Co

mm

en

tsTh

is re

port

for t

he A

LSE

refe

renc

e E

B07

1154

1 su

pers

edes

any

pre

viou

s re

ports

with

this

refe

renc

e. R

esul

ts a

pply

to th

e sa

mpl

es a

s su

bmitt

ed. A

ll pa

ges

of th

is re

port

have

bee

n ch

ecke

d an

d ap

prov

ed fo

r rel

ease

.

This

repo

rt co

ntai

ns th

e fo

llow

ing

info

rmat

ion:

�A

naly

tical

Res

ults

for S

ampl

es S

ubm

itted

�Su

rrog

ate

Rec

over

y D

ata

The

anal

ytic

al p

roce

dure

s us

ed b

y A

LS E

nviro

nmen

tal h

ave

been

dev

elop

ed fr

om e

stab

lishe

d in

tern

atio

nally

-rec

ogni

zed

proc

edur

es s

uch

as th

ose

publ

ishe

d by

the

US

EP

A, A

PH

A, A

S a

nd N

EP

M. I

n ho

use

deve

lope

d pr

oced

ures

are

em

ploy

ed in

the

abse

nce

of d

ocum

ente

d st

anda

rds

or b

y cl

ient

requ

est.

The

follo

win

g re

port

prov

ides

brie

f des

crip

tions

of t

he a

naly

tical

pro

cedu

res

empl

oyed

for

resu

lts re

porte

d he

rein

. Ref

eren

ce m

etho

ds fr

om w

hich

ALS

E m

etho

ds a

re b

ased

are

pro

vide

d in

par

enth

esis

.

Whe

n m

oist

ure

dete

rmin

atio

n ha

s be

en p

erfo

rmed

, res

ults

are

repo

rted

on a

dry

wei

ght b

asis

. W

hen

a re

porte

d 'le

ss th

an' r

esul

t is

high

er th

an th

e LO

R, t

his

may

be

due

to p

rimar

y sa

mpl

e ex

tract

s/di

gest

ion

dilu

tion

and/

or in

suffi

ent s

ampl

e am

ount

for a

naly

sis.

Sur

roga

te R

ecov

ery

Lim

its a

re s

tatic

and

bas

ed o

n U

SE

PA

SW

846

or A

LS-Q

WI/E

N38

(in

the

abse

nce

of s

peci

fied

US

EP

A

limits

). W

here

LO

R o

f rep

orte

d re

sult

diffe

r fro

m s

tand

ard

LOR

, thi

s m

ay b

e du

e to

hig

h m

oist

ure,

redu

ced

sam

ple

amou

nt o

r mat

rix in

terfe

renc

e. W

hen

date

(s) a

nd/o

r tim

e(s)

are

sho

wn

brac

kete

d,

thes

e ha

ve b

een

assu

med

by

the

labo

rato

ry fo

r pro

cess

pur

pose

s. A

bbre

viat

ions

: CA

S n

umbe

r = C

hem

ical

Abs

tract

Ser

vice

s nu

mbe

r, LO

R =

Lim

it of

Rep

ortin

g. *

Indi

cate

s fa

iled

Sur

roga

te

Rec

over

ies.

Clie

nt

:SI

NC

LAIR

KN

IGH

T M

ERZ

EB07

1154

1

3 of

5

Pa

ge

Nu

mb

er

:

Wo

rk O

rde

r:

An

aly

tic

al

Re

su

lts

E021

E019

(119

PGC

)E0

16 (1

18PG

C)

E016

(117

P)E0

12C

lient

Sam

ple

ID :

Sam

ple

Mat

rix T

ype

/ Des

crip

tion

:S

ampl

e D

ate

/ Tim

e :

Labo

rato

ry S

ampl

e ID

:

WA

TER

4 O

ct 2

007

15:0

0

WA

TER

4 O

ct 2

007

15:0

0

WA

TER

4 O

ct 2

007

15:0

0

WA

TER

5 O

ct 2

007

15:0

0

WA

TER

5 O

ct 2

007

15:0

0

EB07

1154

1-00

1EB

0711

541-

002

EB07

1154

1-00

3EB

0711

541-

004

EB07

1154

1-00

5A

naly

teC

AS

nu

mb

er

LO

RU

nit

s

ED

037P

: Alk

alin

ity b

y PC

Titr

ator

<1<1

<1<1

<1D

MO

-210

-001

mg/

L1

Hyd

roxi

de A

lkal

inity

as

CaC

O3

<1<1

<1<1

<138

12-3

2-6

mg/

L1

Car

bona

te A

lkal

inity

as

CaC

O3

482

206

195

409

430

71-5

2-3

mg/

L1

Bic

arbo

nate

Alk

alin

ity a

s C

aCO

348

220

619

540

943

0m

g/L

1To

tal A

lkal

inity

as

CaC

O3

ED

040F

: Dis

solv

ed M

ajor

Ani

ons

209

7831

743

5414

808-

79-8

mg/

L1

Sul

phat

e as

SO

4 2-

ED

045P

: Chl

orid

e by

PC

Titr

ator

1270

1330

3270

402

659

1688

7-00

-6m

g/L

1C

hlor

ide

ED

093F

: Dis

solv

ed M

ajor

Cat

ions

103

6531

938

7474

40-7

0-2

mg/

L1

Cal

cium

117

3616

440

3174

39-9

5-4

mg/

L1

Mag

nesi

um79

580

216

2033

850

774

40-2

3-5

mg/

L1

Sod

ium

66

144

674

40-0

9-7

mg/

L1

Pot

assi

um

EG

020F

: Dis

solv

ed M

etal

s by

ICP-

MS

<0.0

01<0

.001

<0.0

010.

002

<0.0

0174

40-3

8-2

mg/

L0.

001

Ars

enic

<0.0

001

<0.0

001

<0.0

001

0.00

10<0

.000

174

40-4

3-9

mg/

L0.

0001

Cad

miu

m<0

.001

<0.0

01<0

.001

<0.0

01<0

.001

7440

-47-

3m

g/L

0.00

1C

hrom

ium

0.00

40.

002

0.00

1<0

.001

<0.0

0174

40-5

0-8

mg/

L0.

001

Cop

per

0.00

9<0

.001

<0.0

01<0

.001

<0.0

0174

39-9

2-1

mg/

L0.

001

Lead

0.00

2<0

.001

<0.0

01<0

.001

<0.0

0174

40-0

2-0

mg/

L0.

001

Nic

kel

0.01

40.

008

0.00

90.

011

0.04

674

40-6

6-6

mg/

L0.

005

Zinc

EG

035F

: Dis

solv

ed M

ercu

ry b

y FI

MS

<0.0

001

<0.0

001

<0.0

001

<0.0

001

<0.0

001

7439

-97-

6m

g/L

0.00

01M

ercu

ry

EN

055:

Ioni

c B

alan

ce49

.843

.210

320

.428

.3m

eq/L

0.01

Tota

l Ani

ons

49.5

41.2

100

19.9

28.5

meq

/L0.

01To

tal C

atio

ns0.

242.

261.

331.

220.

28%

0.01

Ioni

c B

alan

ce

A C

am

pbell

Bro

thers

Lim

ited C

om

pany

Clie

nt

:SI

NC

LAIR

KN

IGH

T M

ERZ

EB07

1154

1

4 of

5

Pa

ge

Nu

mb

er

:

Wo

rk O

rde

r:

An

aly

tic

al

Re

su

lts

113P

GC

B11

3PG

C A

(E01

4) 1

11PG

C

LOW

ER(E

014)

111

PGC

UPP

ER10

9P (E

003)

Clie

nt S

ampl

e ID

:

Sam

ple

Mat

rix T

ype

/ Des

crip

tion

:S

ampl

e D

ate

/ Tim

e :

Labo

rato

ry S

ampl

e ID

:

WA

TER

4 O

ct 2

007

15:0

0

WA

TER

4 O

ct 2

007

15:0

0

WA

TER

4 O

ct 2

007

15:0

0

WA

TER

5 O

ct 2

007

15:0

0

WA

TER

5 O

ct 2

007

15:0

0

EB07

1154

1-00

6EB

0711

541-

007

EB07

1154

1-00

8EB

0711

541-

009

EB07

1154

1-01

0A

naly

teC

AS

nu

mb

er

LO

RU

nit

s

ED

037P

: Alk

alin

ity b

y PC

Titr

ator

<1<1

<1<1

<1D

MO

-210

-001

mg/

L1

Hyd

roxi

de A

lkal

inity

as

CaC

O3

<1<1

<1<1

<138

12-3

2-6

mg/

L1

Car

bona

te A

lkal

inity

as

CaC

O3

108

527

411

413

453

71-5

2-3

mg/

L1

Bic

arbo

nate

Alk

alin

ity a

s C

aCO

310

852

741

141

345

3m

g/L

1To

tal A

lkal

inity

as

CaC

O3

ED

040F

: Dis

solv

ed M

ajor

Ani

ons

1531

812

934

218

414

808-

79-8

mg/

L1

Sul

phat

e as

SO

4 2-

ED

045P

: Chl

orid

e by

PC

Titr

ator

6819

2012

5016

2011

9016

887-

00-6

mg/

L1

Chl

orid

e

ED

093F

: Dis

solv

ed M

ajor

Cat

ions

628

914

719

013

174

40-7

0-2

mg/

L1

Cal

cium

121

150

180

100

7439

-95-

4m

g/L

1M

agne

sium

8888

679

188

974

874

40-2

3-5

mg/

L1

Sod

ium

212

109

874

40-0

9-7

mg/

L1

Pot

assi

um

EG

020F

: Dis

solv

ed M

etal

s by

ICP-

MS

0.00

3<0

.001

<0.0

01<0

.001

<0.0

0174

40-3

8-2

mg/

L0.

001

Ars

enic

<0.0

001

<0.0

001

<0.0

001

<0.0

001

<0.0

001

7440

-43-

9m

g/L

0.00

01C

adm

ium

<0.0

01<0

.001

<0.0

01<0

.001

0.00

874

40-4

7-3

mg/

L0.

001

Chr

omiu

m0.

002

<0.0

01<0

.001

<0.0

01<0

.001

7440

-50-

8m

g/L

0.00

1C

oppe

r0.

001

<0.0

01<0

.001

<0.0

01<0

.001

7439

-92-

1m

g/L

0.00

1Le

ad0.

002

<0.0

010.

002

0.00

1<0

.001

7440

-02-

0m

g/L

0.00

1N

icke

l0.

011

0.00

50.

021

0.00

80.

022

7440

-66-

6m

g/L

0.00

5Zi

nc

EG

035F

: Dis

solv

ed M

ercu

ry b

y FI

MS

<0.0

001

<0.0

001

<0.0

001

<0.0

001

<0.0

001

7439

-97-

6m

g/L

0.00

01M

ercu

ry

EN

055:

Ioni

c B

alan

ce4.

3971

.346

.061

.146

.5m

eq/L

0.01

Tota

l Ani

ons

4.28

70.6

46.1

63.2

47.5

meq

/L0.

01To

tal C

atio

ns1.

360.

460.

031.

681.

10%

0.01

Ioni

c B

alan

ce

A C

am

pbell

Bro

thers

Lim

ited C

om

pany

Clie

nt

:SI

NC

LAIR

KN

IGH

T M

ERZ

EB07

1154

1

5 of

5

Pa

ge

Nu

mb

er

:

Wo

rk O

rde

r:

Su

rro

ga

te C

on

tro

l L

imit

s

�N

o su

rrog

ates

pre

sent

on

this

repo

rt.

A C

am

pbell

Bro

thers

Lim

ited C

om

pany

Re

po

rt v

ers

ion

: C

OA

NA

3.0

2