Food Reology

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    One may classify fluids in two different ways:

    Classification of fluid behaviour

    either according to their response to the externallyapplied pressure or

    according to the effects produced under the action of ashear stress.

    Newtonian

    Fluids

    Non-Newtonian

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    Newtonian fluids

    Consider a thin layer of a fluid contained between two

    parallel planes a distance dy apart

    Newtonian fluids

    At any shear plane there are two equal

    and opposite shear stress

    a positive one on the slower moving fluid

    and

    a negative on the faster moving fluid layer

    The Negative sign on the right hand side

    of equation indicates that shear stress

    is a measure of the resistance to

    motion.

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    Newtonian fluids

    For an incompressible fluid of density

    x x

    d( V )

    y

    The quantity Vx is the linear momentum in the

    x direction per unit volume (momentum

    concentration).

    yx represent the momentum flux in y directionThe negative sign indicates that the momentum

    transfer occurs in the direction of decreasing

    velocity

    Newtonian fluids

    The constant of proportionality, , is called

    Newtonian viscosity

    Independent of shear rate or shear stress

    Depends only on the material and its T and PThe plot of shear stress against shear rate for a

    ,

    straight line of slope, , and passing through

    the origin

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    Newtonian fluids

    Gases, simple organic liquids, solution of low

    molecular wei ht inor anic salts molten metal

    and salts are Newtonian fluids.

    Newtonian fluids

    Typicalshearstresscookingoilandacornsyrup

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    Newtonian fluids

    For the more complex case of three-dimensional flow, it is necessary to

    set up the appropriate partial differential equations.

    For instance, the more general case of an incompressible Newtonian

    u may e expresse or e x -p ane area or en e norma o e x

    -direction) as follows ( Bird et al ., 1987, 2002 ):

    Stress components in three-dimensionalflow

    By considering the equilibrium of a fluid element, it can be shown that:

    yx xy xz zx yz zy

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    Stress components in three-dimensional

    flowThenormalstressescanbevisualizedasbeingmadeupoftwocomponents:

    isotropicpressure acontributionduetoflow

    xx xxP p

    yy yyP p

    zz zz

    xx yy zz

    1p (P P P )

    3

    ForanincompressibleNewtonianfluid,theisotropicpressureisgivenby:

    1P P P xx yy zz

    3

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    Non-Newtonian fluids

    Time independent fluids (purely viscous,

    inelastic, or generalized Newtonian

    fluids (GNF))

    Time dependent fluids

    sco-e ast c u s

    Time-independent fluid behaviour

    In simple shear, the flow behaviour of this class

    of materials may be described by a constitutive

    relation of the form,

    This equation implies that the value of the

    shear rate at any point within the sheared fluid

    is determined only by the current value of shear

    stress at that point or vice versa.

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    Time-independent fluid behaviour

    these fluids may be further subdivided into

    three types:

    (a)Shear-thinning or pseudoplastic

    (b)Viscoplastic

    (c)Shear-thickening or dilatant.

    Types of time-independent flow behaviour

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    Shear-thinning or pseudoplastic fluids

    Shear-thinning or pseudoplastic fluids

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    Shear-thinning or pseudoplastic fluids

    Mathematical models for shear-thinningfluid behaviour

    More widely used viscosity models:

    i. The power-law or Ostwald de Waele

    model

    ii. The Carreau viscosity equation

    iii. The Cross viscosit e uation

    iv. The Ellis fluid model

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    The power-law or Ostwald de Waele model

    An expression of the following form is applicable:n

    yx yxm( )

    Thus the apparent viscosity is given by:

    n 1

    app yx yx yxm( )

    m: fluid consistenc coefficient

    For n1, the fluid shows shear thickening behavior

    n: flow behavior index

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    The Carreau viscosity equation

    When there are significant deviations from the

    power-law model at very high and very low

    s ear ra es , s necessary o use a mo e

    which takes account of the limiting values of

    viscosities 0 and

    (n 1) / 2app 2

    yx

    0

    1 ( )

    The Carreau viscosity equation

    Another four parameter model (Cross 1965),

    which in simple shear, is written as:

    app

    n0 yx

    1

    1 k( )

    n (

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    The Ellis fluid model

    When the deviations from the power-law modelare significant only at low shear rates, it is

    perhaps more appropriate to use the Ellis model.

    0app 1

    yx 1/ 21 ( )

    When the deviations from the power-law model

    are significant only at low shear rates, it isperhaps more appropriate to use the Ellis model.