FDA 10021

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DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE [email protected] 26.05.2008Code: 10021, document code: FDS10021 1/5

SAFETY DATA SHEET

1 - IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY

IDENTIFICATION OF THE PREPARATION

INHIBITEUR N10

or

ADDITIVE AC (code: 10021)

MAIN USE OF THE PREPARATIONThis solution contains inhibitors that reduce the corrosion of steel.It is used at ambient temperature, 10% diluted in tap water for rinsing after each etching step before localized DALICplating (with brush or sometimes with the DALISTICK tool). Its use permits to improve the adhesion of the coatings insome plating ranges.Specifically, the DALIC processes can be applied locally just where it is necessary, which means without immersion ofthe part. Thus, only small quantities of solutions are stored or used.

COMPANY IDENTIFICATIONDALIC - ZI de Plagu - 41, rue des Eaux - B.P. 90139 - 35501 VITRE CEDEX, FRANCEManufacturer and Seller, tel.: (33) 2.99.75.36.99, fax: (33) 2.99.74.49.31.

For information: [email protected], tel.: (33) 2.99.75.53.88.RELEVANT OFFICIAL ADVISORY BODY (France): INRS / Orfila, tel. (33) 1.45.42.59.59.________________________________________________________________________________________________

2 HAZARDS IDENTIFICATION

CHEMICAL NATUREAlkaline aqueous preparation.

PRODUCT CLASSIFICATION ACCORDING TO 1999/45/EC and 67/548/ECPreparation not classified as dangerous with regard to these directives.

MAIN HAZARDSAdverse physicochemical effects- Fire or explosion: this product is not considered as flammable or explosive.Adverse effects on healthNo particular effects but Diethanolamine is suspected to be a cutaneous and respiratory allergen on some sensitivepeople.

Effects on the environmentThis preparation doest not present a special risk to environment providing that the recommendations of the section 13relative to disposal as well as the national or local provisions are followed. Refer also to the paragraphs 11, 13 and 15.________________________________________________________________________________________________

3 - COMPOSITION / INFORMATION ON INGREDIENTS

COMPONENTS OR IMPURITIES CONTRIBUTING TO THE HAZARDS (according to 1999/45/EC and 67/548/EC)Substances present in concentrations higher than the minimal level of danger: NO.Substances present in concentrations lower than the minimal level of danger (if 1%): YES.

Regulated substance

DEA (25th

adaptation)(Diethanolamine)

CAS N: 111-42-2EC index N: 603-071-00-1EC N: 203-868-0

Classification of thepure substance

Xn R22-48/22Xi R38-41

Symbol:Xn

S phrases (2) 26-36/37/39-46

Classification of thesubstance according toits concentration (in %)

No limit concentration in67/548/EC >> 1999/45/EC

25%: Xn R22

20%: Xi R38

10%: Xn R48/22-415-10%: Xi R36

Concentration range inthe preparation

< 5%

Other substances with the R33 phrase (if 1%), the R64 phrase (if 1%) or sensitizing substances (if 0.1%): NO.OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: NO.OTHER INFORMATION: contains also not classified components.________________________________________________________________________________________________

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DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE [email protected] 26.05.2008Codes: 10021, Safety Data Sheet, document code: FDS10021 2/5

4 - FIRST AID MEASURES

CONTACT WITH SKINTake off contaminated clothing and shoes. Wash immediately with plenty of water.

CONTACT WITH EYESRinse immediately with plenty of water for approximately 15 minutes. In case of pain, redness or visual discomfort, callan ophthalmologist.

INHALATIONTheoretically, not applicable. Under abnormal conditions of use causing considerable inhalation, remove the casualtyfrom the contaminated area, let him take a rest in a well-ventilated room and seek medical advice.

INGESTIONTry to induce vomiting and give water to drink. Seek medical advice to decide to transfer or not into hospital.

PROTECTION OF THE FIRST-AIDERSAccording to the situation, wear gloves, glasses, masks ________________________________________________________________________________________________

5 - FIRE-FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIADry ice, chemical powders, special foam for polar liquids, water spray.

EXTINGUISHING MEDIA WHICH SHALL NOT BE USEDNo contraindication.

SPECIFIC HAZARDSDangerous thermal decomposition products: decomposition of some components begins at 230C and auto-inflammationmay occur near 305C. Then the combustion gives notably nitrogen oxides and carbon oxides.

PROTECTION OF THE FIRE FIGHTERSBecause of the substances produced during thermal decomposition, use approved self-contained breathing equipmentand protective clothing.________________________________________________________________________________________________

6 - ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONSAvoid contact with skin: wear at least gloves and preferably glasses.

ENVIRONMENTAL PRECAUTIONSDo not allow the product to be thrown away. Recover as much as possible for processing within the firm or by anapproved centre.

METHODS FOR CLEANING UPWith water to remove all non-recoverable product. Before throwing rinsing water, check the pH is between 5.5 and 8.5.________________________________________________________________________________________________

7 - HANDLING AND STORAGE

HANDLINGUse after dilution at 10% in tap water. Close containers (in PE) tightly after use with the original cap. Do not re-usecontainers with another product.STORAGEStore in a room away from acid products, powerful oxidising agents, away from some metals (as copper, aluminium andtheir alloys) and from nitrozating agents (for example, nitrites, nitrogen oxides). Keep in original containers only, between

5 and 30C, if possible away from direct sunlight. The maximum recommended shelf life is three years from the date ofmanufacture under normal conditions of storage.________________________________________________________________________________________________

8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLSTECHNICAL MEASURESNo drinking, eating or smoking on the workplace.Maintain the premises and the workplace in a perfect state of cleanliness and clean them frequently.As the product is weakly concentrated and used at room temperature, the values below are not reached.

EXPOSURE LIMIT VALUES IN AIR

Diethanolamine

French decisions of 26 October 2007,

of 30 June 2004, INRS file ND 2098

Average value (8h):3 ppm (or 15 mg/m

3,

INRS file ND 2098)

Directives 2006/15/EC, 2000/39/EC and91/322/EC

-

ACGIH TLV-TWA: 2 mg/m3

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PERSONAL PROTECTIONProvide a shower, a powerful tap and sink unit and an eye basin near the work place.- Respiratory protection: no in normal conditions of use as described in the technical data sheet (ambient

temperature, 10% dilution).- Hand protection: wear gloves (in latex or nitrile for example).- Eye protection: wear glasses with lateral protections. Do not wear contact lenses.

- Skin protection: wear overalls and safety boots.________________________________________________________________________________________________

9 - PHYSICAL AND CHEMICAL PROPERTIES

- Appearance: pale yellow liquid.- Odour: odourless.- pH: 10.5.- Relative density: 1.04- Solubility: miscible in water.- Boiling point: approximately 100C.- Crystallisation / melting point: -3C.- Flammability: nil.- Oxidising properties: nil.- Other properties: not applicable.________________________________________________________________________________________________

10 - STABILITY AND REACTIVITY

STABILITYGood at ambient temperature with water evaporation for only risk.Good in humidity. Slow oxidation and slight possible yellowing with air and light.

CONDITIONS TO AVOIDIncompatible components, heat (decomposition of some constituents from 230C).

MATERIALS TO AVOIDIn particular, if accidentally the preparation is in a concentrated or dehydrated state:- Exothermic reaction with acids, powerful oxidizers,- Attack of copper, aluminium and their alloys,- Reaction with nitrozating agents (for example, nitrites, nitrogen oxides). Some nitrosamines can grow in particular

conditions. They proved to be carcinogenic in animal experimentation.

HAZARDOUS THERMAL DECOMPOSITION PRODUCTSThe combustion gives notably nitrogen oxides and carbon oxides.________________________________________________________________________________________________

11 - TOXICOLOGICAL INFORMATION

No data are available regarding the preparation. The evaluation of health hazards has been realised thanks todirectives 67/548/EC, 1999/45/EC and bibliographical data.

SKINThe risk of skin allergies is probably very weak but it can appear on some sensitive people.

EYE MUCOSAIs not classified as irritating.

RESPIRATORY SYSTEM

The risk of respiratory allergies is probably very weak but it can appear on some sensitive people.IN CASE OF INGESTIONPossible gastrointestinal troubles.

OCCUPATIONAL DISEASES: tables n49 and 49a (France, aliphatic amines, ethanolamines).________________________________________________________________________________________________

12 - ECOLOGICAL INFORMATION

There are no ecological data on the preparation.

ECOTOXICITYBibliographic data concerning Diethanolamine:FISHES - LC50 (96 h) = 250 - 301 mg/L, DAPHNIAS - EC50 (48 h) = 55 mg/L, ALGAE - LC50 (72 h) = 75 mg/L.

MOBILITY - PERSISTENCE AND DEGRADABILITY - BIOACCUMULATIVE POTENTIAL OTHER ADVERSEEFFECTSAccording to the available data, the involved raw materials are easily biodegradable and are not bioaccumulative.

With regard to the applicable EC directives, it is not appropriate to apply theN symbol DANGEROUS FOR THE

ENVIRONMENTto this preparation.________________________________________________________________________________________________

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OTHER INFORMATIONThis sheet is provided to complement, not replace, the user instructions.Information contained herein is bona fide and based on current knowledge relating to the product on the date ofpublication. Furthermore, the attention of the user is drawn to the risks, which may be incurred when the product is usedfor purposes other than those for which it is designed.Information provided herein relates to this product only; it cannot take account of every situation, which may arise atevery work place. This safety data sheet therefore represents only a part of the information required for establishing asafety programme.Under no circumstances does this sheet dispense the user from the need to know and to apply all of the regulationsgoverning its activity, which are not all necessarily quoted herein in an exhaustive manner.________________________________________________________________________________________________

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