FDA 10007

8/10/2019 FDA 10007

1/5

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE [email protected] 31.03.2009Codes: 10007, DPR 5060, document code: FDS10007 1/5

SAFETY DATA SHEET

I - IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY

IDENTIFICATION OF THE SUBSTANCE OR PREPARATION

DECAPAGE Z orDEGREASER AL (code: 10007)

orCleaning & Deoxidising Z (code: DPR 5060)

USE OF THE SUBSTANCE/ PREPARATIONThis solution is used at ambient temperature with the brush electrolysis process for degreasing all cuprous metals,aluminium, aluminium alloys, silver and white metals. It is not sufficiently effective on ferrous metals. In that case, werecommend using the DEGREASER ST solution.The specificity of the brush process is it can be applied locally, just where it is necessary, i.e. without immersion of the part.Thus, only small quantities of solutions are stored or used.

COMPANY IDENTIFICATIONDALIC - ZI de Plagu - 41, rue des Eaux - B.P. 90139 - 35501 VITRE CEDEX, FRANCE

Manufacturer and Seller, tel: (33) 2.99.75.36.99, fax: (33) 2.99.74.49.31.For information:[email protected], tel.: (33) 2.99.75.53.88.

RELEVANT OFFICIAL ADVISORY BODY (France): INRS / Orfila, tel. (33) 1.45.42.59.59.________________________________________________________________________________________________

2 HAZARDS IDENTIFICATION

CHEMICAL NATUREAlkaline aqueous preparation which notably contains diethylenetriamine.

PRODUCT CLASSIFICATION ACCORDING TO 1999/45/EC and 67/548/ECXi symbol, risk phrases:R 36/38-43.

MAIN HAZARDSAdverse physicochemical effects- Fire or explosion: this product is not classified as flammable or explosive.Adverse effects on healthThis preparation must be considered as IRRITATING and SENSITIZING by skin contact.

Effects on the environmentIs not classified as dangerous for the environment providing that the recommendations of the section 13 relative to disposalas well as the national or local provisions are followed.

Refer also to the paragraphs 11, 12, 13 and 15.________________________________________________________________________________________________

3 - COMPOSITION / INFORMATION ON INGREDIENTS

COMPONENTS OR IMPURITIES CONTRIBUTING TO THE HAZARDS (according to 1999/45/EC and 67/548/EC)Substances present in concentrations higher than the minimal level of danger: YES

Regulated substance

DETA (19th

adapt.)Diethylenetriamine

EC index N: 612-058-00-XEC N: 203-865-4CAS N: 111-40-0

Classification of thepure substance

C R34Xn R21/22

R43

Symbols C

S phrases (1/2)-26-36/37/39-45

Classification of thesubstance according toits concentration (in %)

25%10-25%5-10%1-5%

C R21/22-34-43C R34-43Xi R36/38-43Xi R43

Weight % in thepreparation

8/10/2019 FDA 10007

2/5

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE [email protected] 31.03.2009Codes: 10007, DPR 5060, Safety Data Sheet, document code: FDS10007 2/5

OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: NO.OTHER INFORMATION: presence also of not EC regulated chemicals.________________________________________________________________________________________________

4 - FIRST AID MEASURES

CONTACT WITH SKINTake off contaminated clothing and shoes. Wash immediately with plenty of water. Take a shower if necessary.

CONTACT WITH EYESRinse immediately with plenty of water for approximately 15 minutes.Consult an ophthalmologist in all cases.

INHALATIONTheoretically, not applicable. Under abnormal conditions of use causing considerable inhalation, remove the casualty fromthe contaminated area, let him take a rest in a well-ventilated room and seek medical advice. Delayed symptoms mayappear. Consequently, hospitalize quickly the person for a supervision of the effects and the starting of a treatment. Beginan ocular and cutaneous decontamination while waiting for the first aid.

INGESTIONDo not give anything to drink. Do not induce vomiting. Call immediately the medical service. Hospitalize quickly the personfor a supervision of the effects and the starting of a treatment.

PROTECTION OF THE FIRST-AIDERS

According to the situation, wear: clothes and protective shoes or masks Wear at least gloves and glasses.________________________________________________________________________________________________

5 - FIRE-FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIAWater spray, powders and special foams for polar liquids.

EXTINGUISHING MEDIA WHICH SHALL NOT BE USEDNo.

SPECIFIC HAZARDSAvoid contact with powerful oxidizing agents, acids or organic products.Dangerous thermal decomposition products: toxic and pungent fumes; notably emission of carbon oxides and of nitrogenoxides.For diethylenetriamine:- Flash point : 98C (closed cupel), 102C (open cupel),- Boiling point: 207C at atmospheric pressure.- Ignition point: 358 to 399C.

Prevent any material from entering drains or waterways or soil.

PROTECTION OF THE FIRE-FIGHTERSBecause of the substances that are produced during thermal decomposition, use approved self-contained breathingequipment and protective clothing in case of intervention.________________________________________________________________________________________________

6 - ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONSAvoid contact with the skin, the clothes and the eyes: wear at least gloves, glasses and if needed a FFP3 mask.Dispose of all contaminated clothing or shoes and wash thoroughly with water.

ENVIRONMENTAL PRECAUTIONSDo not allow the product to be thrown away. Recover as much as possible for processing within the firm or by an approvedcentre.

METHODS FOR CLEANING UPRinse with water to remove all non-recoverable products. Before throwing rinsing water, check the pH is between 5.5 and8.5.________________________________________________________________________________________________

7 - HANDLING AND STORAGE

HANDLINGUse as supplied. Close containers (in PE) tightly after use with the original cap. Do not re-use containers with anotherproduct.

STORAGEStore away from acids, powerful oxidizing agents and organic products in general. Keep in original containers only,

between 5 and 30C in a room away from direct sun-light. The maximum recommended shelf life is three years from thedate of manufacture under normal conditions of storage.________________________________________________________________________________________________

8/10/2019 FDA 10007

3/5


8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLSTECHNICAL MEASURESNo drinking, eating or smoking on the workplace.Maintain the premises and the workplace in a perfect state of cleanliness and clean them frequently.As the product is used at ambient temperature during a short time, the values below are generally not reached. They

depend on the treatment time, the surface area treated and on the quality of the workshop air extraction.

EXPOSURE LIMIT VALUES IN AIR

Diethylenetriamine

Directives 2006/15/EC,2000/39/EC and 91/322/EC

No

France: decisions of 26October 2007, of 30 June2004, INRS file nND 2098

Average value (8h)= 4 mg/m3

(1 ppm) (INRS file nND 2098)

PERSONAL PROTECTIONProvide a shower, a powerful tap and sink unit, and an eye basin in the vicinity of the work place.- Respiratory protection: during brush electrolysis, provide if possible an inhaling of the vapours / sprays where they are

created and extraction out of the premises, or at least work in a ventilated room and wear if necessary a filtering FFP3mask (EN 149:2001 standard) or an A2P3 or K2P3 cartridge (EN 405:2002 standard).

- Hand protection: wear imperatively gloves (in latex or nitrile for example).- Eye protection: wear imperatively glasses with lateral protections or a facial screen. Do not wear contact lenses.- Skin protection: wear overalls and safety shoes.________________________________________________________________________________________________

9 - PHYSICAL AND CHEMICAL PROPERTIES

- Appearance: pale yellow liquid between -8C and 100C.- Odour: odourless.- pH: 9.7.- Relative density: 1.11.- Solubility: miscible in water in all proportions.- Boiling point: approximately 100C.- Crystallisation / melting point: - 8C.- Flammability: nil.

- Oxidising properties: nil.- Risk of explosion or fire: when the temperature permits evolution of diethylenetriamine vapours, these can formexploding mixtures with air in the limits of 1 to 10% in volume. The vapours are heavier than air.

- Other properties: diethylenetriamine is hardly volatile at ambient temperature.________________________________________________________________________________________________

10 - STABILITY AND REACTIVITY

STABILITYGood at normal temperature with water evaporation for only risk.Good in humidity. Exposed to air, diethylenetriamine tends to oxidize very slowly becoming yellow. The reaction isaccelerated by light.

CONDITIONS TO AVOIDHigh temperatures.

MATERIALS TO AVOIDAcids, metals like copper, nickel and cobalt, powerful oxidizers and organic products in general especially if the producthas been concentrated or has been dehydrated.

HAZARDOUS THERMAL DECOMPOSITION PRODUCTSNotably emission of carbon oxides and of nitrogen oxides.________________________________________________________________________________________________

11 - TOXICOLOGICAL INFORMATION

No data are available regarding the preparation. The evaluation of health hazards has been realised thanks todirectives 67/548/EC, 1999/45/EC and bibliographical data.

METABOLISMExperimentation on animals has shown that diethylenetriamine is easily absorbed from the gastro-intestinal tractus as bypercutaneous way.

SKINIrritating (the severity depends on the contact length). Due to the presence of diethylenetriamine, may also cause theappearance of recurring eczemas on some sensitive people.

8/10/2019 FDA 10007

4/5


EYE MUCOSAIrritating (the severity depends on the length of contact). Possible conjunctivitises. In case of contact, risk of superficiallesions of the cornea with oedema. These lesions are more or less serious and heal slowly.

RESPIRATORY SYSTEMMay cause sensitisation by inhalation (asthma) on some sensitive people because of diethylenetriamine presence.

IN CASE OF INGESTIONPains, gastro-intestinal problems and vomiting are possible. Diethylenetriamine eliminates naturally within 48 h (96%).

INDUSTRIAL DISEASES: tables n49, 49a (in FRANCE).________________________________________________________________________________________________

12 - ECOLOGICAL INFORMATION

There are no ecological data on the preparation.Prevent any material from entering drains or waterways or earth .

Bibliographic data concerning diethylenetriamine:ECOTOXICITYFISHES: Leuciscus idus, CL50 (96 h): 248 mg/LAQUATIC INVERTEBRATES: Daphnia magna, CE50 (48 h): 16 mg/LAQUATIC PLANTS: Scenedesmus subspicatus, (72 h): 611 mg/LMICROORGANISMS / Effect on activated sludge: Pseudomonas putida, CE50 (17 h): 96 g/LLow concentrations in adapted biologic purification station don't disrupt the cycle of biologic action of activated sludge.

BIOACCUMULATIVE POTENTIALNo bio-concentration is considered because of the high solubility in water. Log Pow < 0.

PERSISTENCE AND DEGRADABILITYNot easily biodegradable.Elimination from water: < 10 % (13 j), OCDE 302B, industrial activated sludge.

Chemical demand in oxygen: 1.315 mg/g.

Dangerous for the aquatic organisms because of the alkaline pH.

In line with the applicable EC directives, it is not appropriate to apply the N symbol DANGEROUS FOR THE

ENVIRONMENTto this preparation.________________________________________________________________________________________________

13 - DISPOSAL CONSIDERATIONS

This product and water used for rinsing must not be thrown away notably because of their pH. They must be processedwithin the firm or destroyed by an approved organization.Contaminated packaging if not re-used with the same product is also special waste to be sent to an approved organizationfor recycling or disposal.Classification according to the commission directive 2000/532/EC of 3 May 2000 and its modifications (in particular2001/118/EC, OJ L47). Use the mandatory documents to follow-up the waste products.

06 03 13*or 11 01 13*

Solid salts and solutions containing heavy metalsDegreasing wastes containing dangerous substances

11 01 11* Aqueous rinsing liquids containing dangerous substances

15 01 10* Packaging containing residues of or contaminated by dangerous substances

As the volume of rinsing water is small, it can be added to the waste solutions.

NOTE: in addition to the community provisions, it can be specific legislative and administrative, national or local provisionson this topic.________________________________________________________________________________________________

14 - TRANSPORT INFORMATION

A.D.R. (road transport)

Amines, liquid, corrosive, n.o.s.(diethylenetriamine, mixture), class 8, classification code C7, packaging group III, hazardlabel model n 8, restricted quantities LQ7, hazard identification n 80, material identification n 2735.

I.M.D.G. (sea transport)

Amines, liquid, corrosive, n.o.s.*(diethylenetriamine, mixture), UN N 2735, class 8, packaging group III, subsidiary risk

label: not applicable, restricted quantities: 5 L, stowing and separation: category A, away from acids, safety sheets F-A, S-B.

I.A.T.A. (air transport)

Amines, liquid, corrosive, n.o.s.

*

(diethylenetriamine, mixture), UN N 2735, class 8, subsidiary risk: not applicable, risklabel: CORROSIVE, packaging group III, Passenger- and Cargo aircraft: packaging instructions 818, maximum quantity perpackage: 5 L, Cargo aircraft only: packaging instructions 820, maximum quantity per package: 60 L, instruction IDC 8L.________________________________________________________________________________________________

8/10/2019 FDA 10007

5/5


15 - REGULATORY INFORMATION

This safety data sheet has been established in accordance with the Corrigendum to Regulation (EC) n 1907/2006 of theEuropean Parliament and of the Council of December 18, 2006, OJ L136, 29.05.2007.The preparation labelling has been established in compliance with the directive 67/548/EC (until the 29

th adaptation:

directive 2004/73/EC of April 29, 2004) and the directive 1999/45/EC reviewed in last in January 23, 2006 by the directive2006/8/EC.

EC LABELLING: IRRITANTAlkaline aqueous preparation containing particularly diethylenetriamine.

R36/38: irritating to eyes and skin.R43: may cause sensitization by skin contact.S26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S36/37: wear suitable protective clothing and gloves.

HEALTH SURVEILLANCECouncil Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related tochemical agents at workAn appropriate health surveillance of workers must be carried out according to the risk.For each worker who undergoes this health surveillance, individual health and exposure records are to be made and keptup-to-date.

Other paragraphs in the French version of this safety data sheet summarize French rules regarding: occupational diseases,

health surveillance,

administrative declarations and rules,

environment laws regarding rinsing water treatment.

See please the specific legislative and administrative, national or local provisions on these topics.Additional information is provided in paragraphs 8, 11, 12, 13 and 14.________________________________________________________________________________________________

16 - OTHER INFORMATION

RESTRICTION OF USEFor industrial use only. We remain available to bring you the training or advice you may need.

R PHRASES OF THE PURE COMPONENTS LISTED IN SECTION 3R21/22: harmful in contact with skin and if swallowed.R34: causes burns.R43: may cause sensitization by skin contact.

R PHRASES OF THE PREPARATION ACCORDING TO THE SECTIONS 2 AND 15R36/38: irritating to eyes and skin.R43: may cause sensitization by skin contact.

BIBLIOGRAPHIC REFERENCESEuropean directives, INRS files, safety data sheets of the components established by their manufacturers or distributors,information of European Office of the chemical substances (ECB).

MODIFICATIONSUpdating in relation to directives 2006/8/EC, 2006/15/EC, to the corrigendum to regulation (EC) n 1907/2006 published inMay 29, 2007 and French decisions of October 26, 2007.Revised paragraphs: n1, 2, 3, 8, 14, 15, 16.

OTHER INFORMATIONThis sheet is provided to complement, not replace, the user instructions.Information contained herein is bona fide and based on current knowledge relating to the product on the date ofpublication. Furthermore, the attention of the user is drawn to the risks which may be incurred when the product is used forpurposes other than those for which it is designed.Information provided herein relates to this product only; it cannot take account of every situation which may arise at everywork place. This safety data sheet therefore represents only a part of the information required for establishing a safetyprogramme.Under no circumstances does this sheet dispense the user from the need to know and to apply all of the regulationsgoverning its activity, which are not all necessarily quoted herein in an exhaustive manner.________________________________________________________________________________________________

FDA 10007

Documents

Transcript of FDA 10007