a1 a2 a3 a4N2 7.709928 -5.503897 13.12136 -11.67955O2 7.361141 -5.369589 20.54179 -25.86526NO 8.462334 -10.40669 27.54876 -30.28119O 5.974134 -4.241883 7.931254 -7.94423N 4.966526 0.01150479 -0.03333487 0.04616989CH4 7.918404 -11.41722 63.73457 -75.25691CO2 4.324933 20.80895 -22.9459 16.84483H2O 7.98886 -1.506271 6.661376 -4.65597CO 7.812249 -6.668293 17.28296 -17.28709H2 6.183042 4.710657 -10.92135 12.54086Only Change B16!!!T initial (K) 298.15 0.29815 here we accountT final (K) 1613 1.613 for units in To and Tfinalcal to kcal 0.001 following Prothero (1969)N2 10124.503069707 5.3912249961 !4060.542490479 4239.269452252O2 10696.3300511779 62.292221652 !971.12101367 4473.39465271NO 32045.3267742 63.359294566 !70196.1773257206 134167.374613601O 6616.20619129 47.003461117 !964.923159114 277033.357296395N 119497.1673395 45.001246007 46910.1575269609 500310.740214749CH4 3153.66920075 6.36675634 !107125.0047103 13203.71037636CO2 !77720.6331745369 70.3062573 !191970.43270996 !325400.746975151H2O !4501.19270365 60.65753054 !142905.136137966 !144.792521179CO !16176.99493593 59.96135639 !11294.704601701 !67729.196117597H2 9546.67034031 43.275900223 !60261.676711155 39970.0315961134Reaction "eaction #NO+N=O+N2 21.97271607 34653240.77701 R1 2.70$%13N+O2=NO+O 11.536205945 102362.99962947 R2 9.00$%09O+O+M=O2+M 21.99144629 3.5544$%09 R3 1.20$%17CH4+H2O=CO+3H2 13.61909653 .2167$%05 R4 3.00$%02CH4+O2=2CO+4H2 50.7967096263 1.1501$%22 R5 4.40$%11Turbine Combustion Kinetics PSR-1; CVODE starts at line 100 on EXCEL Sheethi0 (cal&'ol) si0 (cal/mol-K) Gi0 (cal/mol) hi0 ((&'ol)ln KR = -)*i Gi0/RT KR2H2+O2=2H2O 23.55516546 1.7035$%10 R6 6.0$%15CO+H2O=CO2+H2 !1.1131625122 3.252$!01 R7 2.75$%09Temperature Out (K) see (o! 16" col 2) Coie!Preure Out (atm) 10 Solution from theRei!ence Time (ec) 1.00#-03 CVODE CodeOutlet Conditions see line 1"# belo$"olution from C#O$% N&out+i ,eight fraction -ut .olar /low -ut1%11&"'#&11()(#E-00# 0.147497 -2 0.165740457 357.6936312797#%'*1&*+(&*'#0#E-00# 0.766554 02 0.7546916702 15.960647093"%+"1+&&"0))1#&E-011 4.2763$!07 0- 0.000000451 0.0010371691%(#)0"&')1&1"*E-010 2.19455$!06 - 0.000001234 0.00532191"%1##('0&'10+&&E-01) 4.1760$!14 0 2.056032607$!014 1.012911105239$!010#%()E-1" 7.51754$!09 124 4.236029702$!009 1.23067734032$!005&%"1E-0( 0.057069 22- 0.0361327552 13.39649079541%")0)&)(+)0*#)E-00' 0.0012 1- 0.0017992062 4.4322654141%'+("(++'"**1&E-00) 0.00022 22 1.619102154$!005 0.5541299496+%0+(")1"&0""1+E-00( 0.02621 1-2 0.041444443 65.04304495411 su' +i & wi 1 2425.0656762,rom CVODE +&+#%0)(#)()'(+.,3.i4out 2.4537304249CVODE -./out +)%"'"0&+" 5 2.05746. ('olar densit+) 5 7.5552277907684#-0056olu'e 5 32098.13 (7ased on outlet)$%&'2 31.99 g&'ol$%&(2 2.0134 #ne)* +alance ,-T#R $%&(' 30.0061$a.eial +alance is /ol0e1 $%&' 15.9994 2&-ee1 (cal/s)$%&( 14.0067 2&'3. (cal/s)$%&454 16.04303 8added (cal&s)$%&52' 1.01534$%&4' 2.01055$%&52 2.01594$%&4'2 44.00995 g&'ol9g!'oles&c'3: c'3!at'&g'ol!;mol/cm3cm3 Inlet Conditions/e. -ee1 /.eam /uel % #ir (21< -2= 79et #?o*e@ see (row 44@col 2) Mass Flo !g"s#6$%%&'(6Initial )uessfrom *S+,1 0%1&)+*)*')& 0%'(#)"'"()' 4.255163653$!007 2.1930529445$!006CVODE0$8 10&A nu'?er of eBuationsA&0-CT15 &A nu'?er of outDut ti'es A& "T-E1.00$!06 &A scalar relati*e toleranceA& T00 &A initial ti'e A& T1 0.0000001 &A first outDut ti'eA& T.CET10 &A outDut ti'e factor A&initial ' component *ector a?solute tolerance co'Donents' component ()*mol+cm3,91 1.120432563$!005 #T-E1 1.00$!1 9-2: 92 5.76075771$!005 #T-E2 1.00$!1 902: F33.21473093$!011 #T-E3 1.00$!1 90-:94 1.65690549$!010 #T-E4 1.00$!1 9-:F5 5.703992219$!016 #T-E5 1.00$!1 90:96 1.650972519$!010 #T-E6 1.00$!1 9124: 97 0.000004271 #T-E7 1.00$!1 922-:+-2+02+0-+- F0.000000243 #T-E 1.00$!1 91-:99 5.351077622$!00 #T-E9 1.00$!1 922:910 1.91925404$!006 #T-E10 1.00$!1 91-2:4om:3s.ion Res3l.s 6/R-1 9-2: 902: 90-: 9-:1.00#-07 1.12#-05 5.79#-05 3.21#-11 1.65691046684065#-0101.00#-06 1.12#-05 5.79#-05 3.21#-11 1.65691076793328#-0101.00#-05 1.12#-05 5.79#-05 3.22#-11 1.65690770408386#-0101.00#-04 1.12#-05 5.79#-05 3.22#-11 1.6569038687366#-0101.00#-03 1.11#-05 5.79#-05 3.22#-11 1.65731911404031#-0101.00#-02 1.11#-05 5.79#-05 3.23#-11 1.65803466548512#-0100.1 1.11#-05 5.79#-05 3.23124430827505#-011 1.65803478152459#-0101 1.1143754116865#-005 5.79149264975048#-005 3.23124430881534#-011 1.65803478141391#-01010 1.1143754116865#-005 5.79149264975049#-005 3.23124430881536#-011 1.65803478141391#-010100 1.1143754116865#-005 5.79149264975049#-005 3.23124430881536#-011 1.65803478141391#-0101000 1.1143754116865#-005 5.79149264975049#-005 3.23124430881536#-011 1.65803478141391#-01010000 1.11437541169#-005 5.791492649750#-005 3.231244308815#-011 1.65803478141391#-010100000 1.1144#-05 5.7915#-05 3.2312#-11 1.6580#-101000000 1.1143754116865#-005 5.79149264975049#-005 3.23124430881536#-011 1.65803478141391#-01010000000 1.1143754116865#-005 5.79149264975049#-005 3.23124430881536#-011 1.65803478141391#-010a5 a6 a75.233997 -1.173185 0.103883 0 45.7715.94566 -4.85889 0.5861501 0 49.00417.18511 -4.95726 0.5755281 21580 50.3474.403357 -1.271341 0.1491408 59559 38.468-0.03242073 0.01094605 -0.001373727 112965 36.61443.29269 -12.56732 1.469695 -17895 44.49-7.935665 2.121672 -0.2408713 -94054 51.0721.696464 -0.3706212 0.03992444 -57798 45.1068.860125 -2.314819 0.2447785 -26417 47.214-7.016263 1.923395 -0.2084091 0 31.208cal to -oule 4.16244.4723013 !351944.600039260.053269695 !37595.59774347265.3420944 !29397.35522733196.7957029003 !4039.1114173031.411216791 196403.447533 " 5 .31(&'ole!;26.2459711477 !44510.97042364296.553664405 !03741.0766603254.079622726 !59315.2239244251.046329513 !472667.549226411.19007052 !252303.63394143cal&g'ol?0 355 24169334361054.2 34653240.77701 6.92794$%031 6@500 191067226702 102362.99962947 1.6650$%07!1 0 7439553626723.9 470454090674297 0.1513559232 30@000 672401692.0372 4.690224177764$!005 14337911032224303 30@000 15909075374971000 4959905.2277115 3207536135.56CVODE starts at line 100 on EXCEL Sheet;2f0(cal&'ol) ;/70(cal/mol-K)si0 (