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Evaluation of dioxin inventories in Candidate Countries

Herman Kok, Tinus Pulles

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Outline

• Comments 2nd inventory (January 2004)• Cyprus• Hungary• Estonia• Czech Republic

• Info presentations 1st workshop• JRC (extra info CC)• Poland

• EU Dioxin Emission Inventory II (2000)

•Recommendations for new EF• Missing sources

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Cyprus (inventories)Emission [g I - TEQ]

Parent NFR description (spec. TNO 2004) TNO JRC TNO/CC activity

2000 1999 Jan.04 Jan.04

1. ENERGY 0 0,16

1.A.1 Energy ind. (public electricity and heat) 0 0,1

1.A.2 Manufact. industries and construction 0

1.A.3 Transport ?

1.A.4 Other sectors (residential: only diesel oil ?) 0 0,06 5600 TJ

2. INDUSTRIAL PROCESSES 1,08

2.A MINERAL PRODUCTS (cement and lime) 1,06

2.C METAL PRODUCTION 0,02

2.C.1 Iron and Steel Production (sinter plants ?) x ?

2.C.2 Ferroalloys Production (ferrous foundries) 0,001

2.C.3 Aluminium Production (sec. Al smelters) 0,02

6. WASTE 358 11

6.C WASTE INC. (not municipal/industrial ?) 358 10,2

6.D OTHER WASTE (accidental fires) 0,72

7. OTHER (preservation of wood) 0,7

Total 358 13

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Hungary (inventories)Emission [g I -TEQ]

Parent NFR description (spec. Jan.04) TNO TNO/CC activity

2000 Jan.04 Jan.04

1. ENERGY 0 7,4

1.A.1 Energy industries 0 2,1

1.A.2 Manufacturing industries and construction 0 0,1

1.A.3 Transport

1.A.4 Other sectors (residential) 0 5,2 25 k TJ

2. INDUSTRIAL PROCESSES 7 57

2.A MINERAL PRODUCTS (cement and lime) 20

2.C METAL PRODUCTION 7 37

2.C.1 Iron and Steel Production (only sinter plants) 6,4 32 1,6 Mt

2.C.2 Ferroalloys Production

2.C.3 Aluminium Production (secondary smelters) 0,2 0,9

2.C.5 Other (non-ferrous metal production/recovery) 0,3 4,1

6. WASTE 15840 39

6.C WASTE INCINERATION 15850 29

6.D OTHER WASTE (accidental fires) 10

7. OTHER (preservation of wood) 10Total 15850 113

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Hungary (extra info)

Parent Description JRC activity

1999 Jan.04

1.A.4.b.ii Non-industrial combustion plants

. Coal comb. in households [TJ/capita] 3,7 37 M TJ ?

. Wood comb. in households [TJ/capita] 5,1 51 M TJ ?

Production processes

2.C.1.2 . Pig iron production [kg/capita] 130 1,3 Mt

2.C.1.5 . Scrap steel consumption [kg/capita] 80 0,8 Mt

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Estonia (inventories)Emission [g I - TEQ]

Parent NFR description TNO CC TNO/CC activity

2000 UNEP jan.04 jan.04

1. ENERGY 0 4,9 4,6

1.A.1 Energy industries (public electricity and heat) 0 2,1 0,1 M TJ

1.A.2 Manufacturing industries and construction 0 0,39 1,2 2,4 k TJ

1.A.3 Transport 0,04 ?

1.A.4 Other sectors (residential) 0 1,3 16 k TJ

2. INDUSTRIAL PROCESSES 0,25

2.A MINERAL PRODUCTS (cement and lime) 0,25

2.C METAL PRODUCTION ? 0 ?

6. WASTE 725 0,19 24

6.C WASTE INCINERATION (not municipal/industrial ?) 725 0,19 23

6.D OTHER WASTE (accidental fires) 1,4

7. OTHER (preservation of wood) 0,04 1,4

Total 725 14 31

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Estonia (extra info)

Parent Description JRC activity

1999 jan.04

1.A.4.b.ii Non-industrial combustion plants

. Coal comb. in households [TJ/capita] 1,9 2,7 M TJ ?

. Wood comb. in households [TJ/capita] 18,3 26 M TJ ?

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Czech Republic (inventories)Emission [g I - TEQ]

Parent NFR description (spec. Jan.04) TNO Holou- TNO/CC activity2000 bek Jan.04 Jan.04

1. ENERGY 0,01 396 281.A.1 Energy ind. (public electricity and heat) 0,01 6 5,7 0,7 M TJ1.A.2 Manufact. industries and construction 0 ?1.A.3 Transport 0,15 ?1.A.4 Other sectors (residential: coal/oil/wood) 0 390 22,1 77 k TJ2. INDUSTRIAL PROCESSES 26 94 1732.A MINERAL PRODUCTS (cement/lime) 3,2 272.C METAL PRODUCTION 26 91 1462.C.1 Iron/Steel prod. (tap/sinter/pellet/steel) 26 82 144 6,5 Mt2.C.2 Ferroalloys Production 0,252.C.3 Aluminium prod. (sec. Al smelters) 4,8 1,4 120 kt2.C.5 Other (prim./sec. Pb, Cu,Zn ) 0,12 0,76. WASTE 5045 1,2 1916.C WASTE INC. 5045 1,2 1816.D OTHER WASTE (accidental fires) 107. OTHER 163 10Total 5072 650 402

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Czech Republic (extra info)

JRC activityParent Description 19991.A.4.b.ii Non-industrial combustion plants

. Coal comb. in households [TJ/capita] 5,1 53 M TJ ?

. Wood comb. in households [TJ/capita] 5,6 58 M TJ ?Production processes

2.C.1.1 . Steel production [Mton] 6,2 6,2 M t2.C.1.2 . Pig iron production [kg/capita] 450 4,6 M t2.C.1.5 . Scrap steel consumption [kg/capita] 210 2,2 M t

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Poland (inventories)Emission [g I - TEQ]

Parent NFR description (specification TNO 2004) TNO JRC CC TNO activity

2000 1999 2000 Jan.04 Jan.04

1. ENERGY 0,04 236 95

1.A.1 Energy ind. (public electricity and heat) 0,02 5 15 1,5 M TJ

1.A.2 Manufact. industries and construction 0,01 50 10 20 k TJ

1.A.3 Transport 1,5 ?

1.A.4 Other sectors (residential: coal/oil/wood) 0,01 180 69,1 0,5 M TJ

2. INDUSTRIAL PROCESSES 36,93 50 296

2.A MINERAL PRODUCTS (cement/lime) 11,9 95

2.C METAL PRODUCTION 36,93 38,3 201

2.C.1 Iron/Steel prod. (sinter: no steel/pig iron ?) 35,36 38,3 176 8,8 Mt

2.C.2 Ferroalloys Production

2.C.3 Aluminium Production (sec. Al smelters ?) x ?

2.C.5 Other (sec. copper and zinc) 1,57 25,1 40 kt

6. WASTE 18846 183 353

6.C WASTE INC. (not municipal/industrial) 18846 121 314

6.D OTHER WASTE (accidental fires) 62 39

7. OTHER (preservation of wood) 35 39

Total 18883 505 782

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Poland (extra info)

Parent NFR description (specification TNO 2004) JRC activity

1999 Jan.04

1.A.4.b.iiNon-industrial combustion plants

. Coal comb. in households [TJ/capita] 20,3 780 M TJ ?

. Wood comb. in households [TJ/capita] 3,3 127 M TJ ?

Production processes

2.C.1.1 . Steel production [Mton] 10,5 10,5 Mt

2.C.1.2 . Pig iron production [kg/capita] 170 6,5 Mt

2.C.1.5 . Scrap steel consumption [kg/capita] 140 5,4 Mt

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European Dioxin Emission Inventory Stage II, 2000

• Recommendations for new EF (old)•New Municipal Waste inc.

• High tech comb., sophist. APCS: 0,1 ug TEQ/t (0,5)

•Coal fired industrial power plants: 20-60 ug TEQ/TJ

•Domestic heating (coal fired stoves): 5–20 ug TEQ/t (2)

• Polish hard coal (high chlorine): 20–300 ug TEQ/t

• Czech/German brown/hard coal: 1 – 10 ug TEQ/t

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Missing sources

• Transport (1.A.3.b)•Road transport (diesel)•Traffic (leaded gasoline)

• Hazardous waste incineration •Uncontrolled factor 10 higher than

municipal waste• Petroleum refineries (1.A.1.b)

•Combustion of liquid waste fuels (35 ug TEQ/TJ)

• Cremation