Estimated Volumes for Discharge of Whole Drilling Mud
-
Upload
ferry-triyana-anirun -
Category
Documents
-
view
215 -
download
0
Transcript of Estimated Volumes for Discharge of Whole Drilling Mud
-
8/12/2019 Estimated Volumes for Discharge of Whole Drilling Mud
1/6
-
8/12/2019 Estimated Volumes for Discharge of Whole Drilling Mud
2/6
2 SPE 8669
Discharge Volumes. An estimate of the cuttings volume is
made using the well plan (drill bit diameters and interval
lengths) and an estimated amount of washout, i.e., the increase
in hole volume over that predicted by bit diameter and holelength. Estimates of washout can be obtained from experi-
enced drilling personnel based on the type of formation drilled
and the type of drilling fluid used.
Estimated volumes for discharge of whole drilling mud
solids (only WBM discharged) can be made using the mudplan. The mud plan is developed prior to drilling and should
include estimates of the quantity of drilling fluid that will beused drilling the well.
Bathymetry and Model Grid Size. The OOC Model requires
the water depth at the discharge site. For most cases, bathym-
etry data within 1 km of the well site are sufficient. Detailedbathymetry data are not necessary unless there are significant
bathymetry changes near the well. A flat or tilted plane may
describe many sites. The OOC Model can accept detailed
bathymetry data if available.The OOC Model tracks the deposition of solids on the
seabed only within a grid array that is specified by the user.The grid size is limited to 12,100 cells, which allows a squaregrid of 110 x 110 cells. Grid cells must be the same size,
however, there are no limits on the size of the grid cell.
Specifying a large grid cell to allow large grid array
coverage will limit the resolution of predicted loadings becausethe model provides the total seabed solids loading within a grid
cell (lbs/grid cell). No information about loading variation
within a grid cell is provided.
For most single-well discharges, a grid array that covers 4km2 or less is adequate. A 4-km2square grid allows a 110 x
110 array and approximately 18 m x 18 m grid cells. The grid
array coverage can be increased or decreased in size to match
specific discharge conditions. The predominant current speedsand directions combined with particle fall velocities allows the
user to estimate an acceptable grid array size that will maxi-
mize capture of solids within the grid array while maintaining
acceptable resolution.
Ambient Conditions. The OOC Model requires historic time-
series ambient current profiles throughout the water column for
stochastic modeling. Typically, this data is obtained fromAcoustic Doppler Current Profile (ADCP) instruments placed
near the project area.
The accuracy of model predictions depends on howclosely input current data represents the actual current condi-
tions that occur while drilling. In many situations, only limited
data are available. For discharges into deeper water, it is
important to have current data covering the entire water column
because extrapolating surface currents several hundred meterslikely will result in significant inaccuracies.
In addition, the OOC Model requires either temperature
and salinity profiles or a density profile. These data can beobtained from direct measurements or knowledgeable esti-
mates. The OOC Model will accept time-varying data. In
most cases, however, a single data set is adequate becausechanges in these parameters over time will not significantly
alter seabed-loading predictions.
Discharge rate. The OOC Model requires an estimate of th
discharge rate. The model accepts only a single rate within
run. To simulate changes in the discharge rate, two or mor
model runs are developed with different rates. The predictionfrom the multiple runs are summed to give the overall predic
tion. For most modeling, however, detailed information on th
discharge rate is not available. An average rate based on a
estimate of the volume of discharged solids and an estimate o
the time required to drill the well can be used.
Discharge pipe radius, depth, and orientation. The OOModel requires the discharge pipe radius, the depth of th
discharge pipe opening, the vertical orientation of the discharg
pipee.g., pointing straight down, and the azimuth orientatio
of the discharge pipe.
Discharge duration. The OOC Model requires an estimate o
the discharge duration. An exploration well might require 3
days to drill, however, discharges dont occur over this entir
period. Discharges likely correspond with periods when thdrill bit is advancingperhaps 1/3 of the total drilling time.
Discharge bulk density. The bulk density required by thOOC Model is the density of the material released at th
discharge point. For cuttings discharges, the discharge
usually a combination of the cuttings, associated drilling mu
and the seawater used to avoid plugging the discharge chuteThe discharge bulk density for these discharges can b
estimated by assuming an amount of seawater that will b
discharged with the cuttings. For whole mud discharges,
hole-averaged density can be determined using data in the muplan.
Note that the bulk density primarily influences th
behavior of the plume that develops from the discharge. Fo
surface discharge of cuttings in deep water, the fast fallinparticles exit the plume quickly so that plume behavior doesn
significantly influence the ultimate fate of these particle
Therefore, predictions of cuttings accumulations on the seabe
are not sensitive to the choice of bulk density.
Solids density and volume fraction. The OOC Mode
requires an estimate of the density of the discharged solids an
the volume fraction of the solids in the bulk discharge. Unlessite-specific information is available, 2.65 g/ml (the density o
quartz), can be used for WBM cuttings density. For NAF
cutting discharges, the cuttings contain adhering NAF, whiclowers the average density. Solids density can be determine
using assumed ratios of cuttings, base fluid, and other mu
solids (e.g., barite) adhering to the mud.
The WBM drilling mud solids are either primarily barit(4.3 g/ml), bentonite (2.3 g/ml), or a combination of the two
The volume fraction solids specified should be consistent wit
the discharge flow rate and discharge time to allow complet
discharge of all the solids from the well.
Discharge solids fall velocities. The OOC Model does no
calculate fall velocities from an equation such as Stokes Lawrather it requires specification of particle fall velocities. Th
modeler can estimate fall velocities from particle-size distribu
tions and theoretical (e.g. Stokes Law) or empirical correla
tions. Correlations, however, have limitations. Theoretic
-
8/12/2019 Estimated Volumes for Discharge of Whole Drilling Mud
3/6
SPE 86699 3
correlations such as Stokes law are valid over a limited
particle-size range. Users should be aware of the size range
limits and other assumptions of these correlations. Addition-
ally, discharged cuttings and associated drilling mud solids fallas interacting aggregates that can break up or combine such
that the representativeness of velocities developed from
particle-size correlations is questionable. Measured fall-
velocities obtained from column studies may provide more
representative data.Two general categories of cuttings are identified because
of inherent fall velocity differencescuttings from WBMdrilling and cuttings from NAF drilling.
Generally, cuttings generated with WBM have greater
dispersion of fines as they fall in seawater compared to NAF
cuttings. NAF cuttings and associated drilling mud solids,
because they are coated with hydrocarbons, tend to remain asaggregates.
Site-specific fall-velocity data are rarely available. In the
absence of site-specific data, the distributions shown in Table 1
for WBM cuttings and Table 2 for NAF cuttings can be used.Fall-velocity distributions for bentonite and WBM solids are
provided in Tables 3 and 4.
Table 1. Fall Velocity Distribution for WBM Cuttings*Solids
Class
Solids Density
(g/cm3)
Solids Volume
Fraction
Fall Velocity
(ft/sec)
1 2.65 0.04272 4.430x10-6
2 2.65 0.03204 5.530x10-5
3 2.65 0.03738 7.160x10-4
4 2.65 0.01602 7.638x10-3
5 2.65 0.01068 4.748x10-2
6 2.65 0.09612 1.316x10-1
7 2.65 0.08544 3.214 x10-1
8 2.65 0.0801 4.435 x10-1
9 2.65 0.1335 8.522 x10-1
*Data from drill cuttings collected at 2,500 m from a well in the Lower CookInlet, Alaska(7).
Table 2. Fall Velocity Distribution for NAF Cuttings*Solids
Class
Solids Density
(g/cm3)**
Solids Volume
Fraction
Fall Velocity
(ft/sec)
1 1.97 0.0882 1.083
2 1.97 0.0882 1.017
3 1.97 0.0882 0.951
4 1.97 0.0992 0.886
5 1.97 0.0375 0.755
6 1.97 0.0176 0.591
7 1.97 0.0055 0.394
8 1.97 0.0166 0.197*Data from column measurements on cuttings collected in Brazil Campos Basin.
**Density assumes approximately 10% NAF base fluid on cuttings by weight.
Table 3. Fall Velocity Distribution for Bentonite Particles*Solids
Class
Solids Density
(g/cm3)
Solids Volume
Fraction
Fall Velocity
(ft/sec)
1 2.30 0.0007 0.3040
2 2.30 0.0300 0.1720
3 2.30 0.0300 0.0746
4 2.30 0.0250 0.0035
5 2.30 0.0050 0.0007
6 2.30 0.0093 0.0002*Data from column measurements of bentonite particles used in drilling mud.
Table 4. Fall Velocity Distribution for WBM Solids*SolidsClass
Solids Density(g/cm3)**
Solids VolumeFraction
Fall Velocity(ft/sec)
1 3.377 0.00053 3.68x10-2
2 3.377 0.00211 1.40x10-2
3 3.377 0.01016 2.70x10-3
4 3.377 0.01016 2.10x10-3
5 3.377 0.00700 1.68x10-3
6 3.377 0.00700 1.43x10-3
7 3.377 0.00528 9.84x10-4
8 3.377 0.00264 4.86x10-4
9 3.377 0.00422 2.00x10-4
10 3.377 0.00370 8.99x10-5*Data from OOC Model manualBrandsma and Smith, 1999.
**Solids density is an average of bentonite and barite.
Simulation Duration. The OOC Model requires the discharg
duration and the simulation duration as inputs. The dischargduration should be shorter than the simulation duration to allow
time for particles to settle to the seabed.
The time required for slow-falling solids to reach thseabed could be tens to hundreds of hours for deepwate
discharges. Slow falling particles have wide dispersion andunder most current conditions in deep water, insignificaneffect on accumulations near the well site. For deskto
computers, memory and computing time considerations mak
extended duration simulations impractical or inconvenient.
An appropriate simulation duration can be determineusing the solids fall-velocity distributions and the water dept
to calculate the time required for various solids classes to reac
the seabed. Run times should maximize the total amount o
solids reaching the seabed considering memory and computation-time limitations. Note that particles that take tens of hour
to reach the seabed will likely be distributed over a wide are
considering the currents in most environments.
Model Output ProcessingThe OOC Model provides predictions of solids concentration
in the water column and seabed loading. The predictions o
solids concentrations in the water column can be used directl
to generate plots showing, for example, the water columconcentrations versus distance from the discharge point.
Seabed loading as provided by the model (lbs/grid cell)
a parameter that is difficult to interpret. The first step i
processing seabed loading predictions is to convert fromlbs/grid cell to lbs (or kilograms)/unit area using the specifie
grid-cell size. Seabed loading predictions can be further pos
processed to provide more easily understood parameters, sucas seabed accumulation thickness and seabed-sedimen
hydrocarbon concentration. The following discussion presentassumptions and equations to make these conversions.
Drilling Solid Accumulation Thickness. Converting mode
predicted loading to drilling solids thickness improve
comprehension of the magnitude of the accumulations. Severassumptions are required to convert seabed loading to accumu
lation thickness. The primary assumption is that the drillin
solids remain on top of ambient sediments. In reality, th
drilling solids would intermix with ambient sediments.Other important parameters that require assumptions ar
as follows:
The weight percent water in the drilling solids on th
seabed
-
8/12/2019 Estimated Volumes for Discharge of Whole Drilling Mud
4/6
4 SPE 8669
The salinity of the drilling solids pore water
The density of the drilling solids pore water
The density of the discharged drilling solids.In the absence of site-specific information, the following
values can be used:
The weight percent water (Ww) in the drilling solids is
30%. The 30% by weight water is based on measure-
ments made on cuttings piles in the North Sea. The salinity of the drilling solids pore water is equiva-
lent to seawater (ppt=35.03 parts per thousand).
The density of the drilling solids pore water is equivalent
to seawater density (seawater=1.02 g/ml).
The density of the discharged drilling solids (solid) is
2.65 g/ml for WBM cuttings. A somewhat lower density
may be needed for NAF-coated cuttings to account forthe adhering drilling fluid.
For a sample area A (see Figure 1), the thickness of drilling
solids over A is
))100(
1(
wseawater
w
solid
solidW
WMT
+= in meters. (1)
where Msolidis the OOC Model-predicted seabed loading,)1000(1 pptppt +=
For a complete derivation of equation (1) see Appendix
A.
T
AmbientSediment
Deposited
Cuttings
Area of surface
A
Figure 1. Schematic diagram used for drilling solids deposition
thickness estimate.
Hydrocarbon Concentration in Seabed Sediments. Thefollowing assumptions simplify conversion of model-predicted
seabed loading to sediment hydrocarbon concentration:
The WBM solids contain no hydrocarbons.
The NAF drilling solids accumulated on the seabed re-
main on top of all drilling discharges.
The ambient sediments contain no hydrocarbons.
The NAF base fluids remain adhered to the NAF cut-
tings.
The deposited hydrocarbons do not degrade over time.
The NAF cuttings includes the cuttings, the base fluidadhering to the cuttings, and the barite in the NAF.
In addition, assumptions must be made regarding the
following:
The thickness of a hypothetical control volume (see Fig-ure 2)a common thickness used for field sampling is
the top 2 cm
The wet-weight percent hydrocarbons adhering to thedeposited NAF drilling solidsan average value for
base fluid retained on cuttings for wells drilled wit
similar cuttings cleaning equipment can be used.
The composition of the NAFthe composition shoul
be based on project-specific mud or, if not available, us
the EPA generic mud from EPA(8)(47% base fluid, 33%
solids as barite, and 20% brine by weight).
The density of benthic sedimentsin the absence o
site-specific data, assume the density is the same as tha
of the WBM drilling solids.
The porosity of the ambient sediments and non-NA
drilling depositsin the absence of site-specific information, a porosity of 0.4 can be used.
The calculation of hydrocarbon concentration in sedimen
is developed using a control volume consisting of an area ACand total thickness TCV. This volume is intended to represen
the sediment material sampled for analysis during a hypothet
cal field sampling operation. The equation to calculat
hydrocarbon concentration in sediments containing NA
cuttings is as follows:For the control volume shown in Figure 2, the hydroca
bon concentration can be calculated using the followin
equation:
lCV MT
xMppmHC
l
)1()(
)101()(
6
+++= (2)
where Ml=the OOC Model-predicted NAF-cuttings anassociated drilling fluid loading
)( SWoilBFoilBF FFFFF =
))100((1 wseawaterwsolid WW +=
)1( pamb =
pSalseawater =
)100( www WWW =
FBF=fraction base fluid in NAF
Foil=fraction base fluid adhering to cuttings
Fseawater=fraction of saltwater in NAFp=porosity of ambient sediments or WBM deposits
Sal=is seawater salinity (kg salt/kg seawater)
SalSal)1( =
For a complete derivation of equation (2) see Appendix A.
T cv
Ambient
Sediment/
WBM
Deposits
Deposited
Cuttings
Area of surface
Acv
TNAF
Figure 2. Conceptual control volume needed for convertin
model-predicted seabed loading to seabed-sediment hydrocarbon concentration. Acv should correspond to the area of
model grid cell as specified in the model input.
Contour Plot Examples. The figures below provide exampleof the type of visuals that can be generated from mode
predictions. The plots were generated from modeling th
surface and seabed discharges of a single exploration well i
-
8/12/2019 Estimated Volumes for Discharge of Whole Drilling Mud
5/6
SPE 86699 5
625 m of water. The bathymetry was simulated as a flat plane.
The concentration of base fluid on the cuttings at the seabed
was assumed to be 10%.
-500 -400 -300 -200 -100 0 100 200 300 400 500
Distance East-West (m)
-500
-400
-300
-200
-100
0
100
200
300
400
500
DistanceNorth-South(m)
Figure 3. Thickness contours for the discharge of all drillingsolids in 625 m water. The cross marks the discharge point.
Thickness contours are in centimeters and the maximum
thickness is 57 cm.
-500 -400 -300 -200 -100 0 100 200 300 400 500
Distance East-West (m)
-500
-400
-300
-200
-100
0
100
200
300
400
500
DistanceNorth-South(m)
Figure 4. NAF base fluid concentration (ppm) contours for the
discharge of all drilling solids in 625 m water. The cross marks
the discharge point. Hydrocarbon concentration contours are inparts per million and maximum concentration is 100,000 ppm.
References1. Policastro, A.: Evaluation of Selected Models. In:An Evaluation
of Effluent Dispersion and Fate Models for OCS Platforms. Vol-
ume I, Summary and Recommendations. U.S. Dept. of Interior,Minerals Management Service. Workshop Proceedings. 7-10
February. Santa Barbara, California (1983) 33.2. Brandsma, M.G., Smith, J.P., O'Reilly, J.E., Ayers, R.C.,Jr.,
Holmquist, A.L.: Modeling Offshore Discharges of ProducedWater. In: Produced Water. J.P. Ray and F.R. Engelhart, Eds.
Plenum Press. New York (1992) 59.3. Nedwed, T. J., Smith, J. P., Brandsma, M. G.: Verification of the
OOC Mud and Produced Water Discharge Model Using Lab-ScalePlume Behavior Experiments.J. of Marine Science,in press.
4. O'Reilly, J.E., Sauer, T.C., Ayers, R.C. Jr., Brandsma, M.G., Meek,
R.: Field Verification of the OOC Mud Discharge Model. In:
Drilling Fluids. F.R. Engelhart, J.P. Ray, A.H. Gillam, Eds
Elsevier Applied Science. New York (1989) 647.5. Smith, J.P., Mairs, H.L., Brandsma, M.G., Meek, R.P., Ayers, R.C
Jr. 1994. Field Validation of the Offshore Operators Committe(OOC) Produced Water Discharge Model. Proceedings of SP
Annual Technical Conference. SPE28350. New Orleans. (25-2September 1994).
6. Smith J. P., Brandsma, M. G., Nedwed, T. J.: Field Validation othe Offshore Operators Committee (OOC) Mud and Produce
Water Discharge ModelJ. of Marine Science,in press7. Brandsma, M.G. and Smith, J.P.: Offshore Operators Committe
Mud and Produced Water Discharge Model -- Report and UseGuide. Offshore Operators CommitteeP.O. Box 50751New
Orleans, LA 70150-0751 www.offshoreoperators.com(1999).8. EPA: "Development Document for Proposed Effluent Limitation
Guidelines and Standards for Synthetic Based Drilling Fluids another Non-Aqeuous Drilling Fluids in the Oil and Gas Extractio
Point Source Category" EPA-821-B-98-021 (19990) VII-6.
Appendix ADerivation of Drilling Solid Accumulation Thicknes
Equation. Using the assumptions and parameters described i
the main body of the report and with reference to Figure 1, th
volume of drilling solids over A with thickness T is))(( seawatersaltwatersolidsolid MMMAATV ++== (1)
Therefore
seawatersaltwatersolidsolid MMMT )( ++= (2)
where M represents the loading (kg/m2) of the individua
components making up the drill solid accumulations; eithecuttings solid (solid), pure water (water), or salt in pore wate
(salt). Msolidis the OOC Model-predicted seabed loading.
The Msaltcan be determined using the assumed pore watesalinity (35.03 g/kg) and the assumed weight percent water.
)1000( pptMpptM watersalt = (3)
Express Mwater in terms of Ww (weight percent water) an
Msolids.)(100 saltwatersolidwaterw MMMMW ++= (4)
Substituting Msalt into (4) gives
)1000
1(
100
ppt
pptMM
MW
watersolid
water
w
++
=
(5)
Let
)1000(1 pptppt += (6)
then
)100( wsolidwwater WMWM = (7)
Substituting Mwaterand Msaltinto thickness equation gives
))100(
1
(
wseawater
w
solidsolid W
W
MT +=in m. (8)
0363.1= for kggppt 03.35=
The following values can be used as an equation check
If Msolid=1000 kg/m2, Ww=30%, ppt = 35.03 g/kg, solid=265
kg/m3, and seawater=1020 kg/m3then T=0.8197 m.
Derivation of Hydrocarbon Concentration in Seabe
Sediments Equation. Using the assumptions and parameterdescribed in the main body of the report and with reference t
Figure 2, the equation to calculate hydrocarbon concentratio
in sediments containing NAF cuttings is derived as follows:
-
8/12/2019 Estimated Volumes for Discharge of Whole Drilling Mud
6/6
6 SPE 8669
saltsedsaltambambBaBFC
BF
MMMMMM
xMppmHC
+++++=
)101()(
6
(9)
where MBFis the loading of base fluid in the control volume,
MCis the loading of cuttings in the control volume,MBais the loading of barite in the control volume,
Mamb is the loading of ambient sediment in the control
volume,
Msaltamb is the loading of salt in the control volumeambient sediment or WBM solids pore water,
Msaltsed is loading of salt in the NAF sediment in the
control volume.
Transform (9) into a function of the model predicted NAFcuttings loading (Ml) starting with an expression for Foil, the
wet-weight fraction of NAF base fluid retained on the cuttings.
)( SWBaBFcBFoil MMMMMF +++= (10)
where Foil is fraction oil in discharged NAF cuttings (oil oncuttings by retort test), and
MSW is mass of the aqueous phase in the NAF that is
discharged with the cuttings.
BaBFCl MMMM ++= (11)
Substituting (11) into (10) gives
)( SWlBFoil MMMF += (12)
also
NAFBaBaNAFBFBFNAFSWSW MFMandMFMMFM === ,, (13)
where FSWis fraction seawater in the NAF,
MNAF is the loading of whole NAF in the discharged
NAF cuttings (MNAF=MBF+MBa+MSW), (14)FBF and FBaare the fractions of base fluid and barite in
the NAF.
Combining equations in (13) and rearranging gives
BFBFSWSW FMFM = (15)
Substituting (15) into (12) gives
)( BFBF
SW
lBFoil MF
FMMF += (16)
Solve (16) for MBFto give
lSWoilBFloilBFBF MFFFMFFM == )( (17)
Now determine Mambas a function of Ml.
))(1( NAFCVambamb TTpM = (18)
for TCV>TNAF, zero otherwise
where ambis density of ambient sediments,
p is porosity of ambient sediments or WBM drilling
deposits,
TCVis the thickness of the control volume,TNAFis the thickness of NAF drilling deposits as defined
in (8).lwseawaterwsolidlNAF MWWMT =+= )))100((1( (19)
where , Ww, and seawaterare defined in the previous thickness
derivation. The value of solid is determined based on thecomposition of the NAF solids, i.e., the relative loadings of Mc,
MBF, and MBain Ml determined by (12) and (13). The determi-
nation of solidis as follows:
Ba
Ba
BF
BF
c
C
BaBFC
BaBFC
BaBFC
solid MMM
MMM
VVV
MMM
++
++=
++
++=
(20)
where c, BF, and Ba are the densities of dry cuttings, basefluid and barite, respectively, and VC, VBF, and VBarep-
resent the volume of dry cuttings, base fluid, and barit
respectively, in the discharged drilling solids.
From (10) and (13)
)()( NAFcoilSWBaBFcoilNAFBFBF MMFMMMMFMFM +=+++==(21)
Rearranging gives
)( oilBFcoilNAF FFMFM = (22)
Since solid is constant if we assume the ratio of cuttings
base fluid, and barite is constant, we can let Mc= 1 lb/grid ceto simplify (20) and (22).
Then
)( oilBFoilNAF FFFM = (23)
Substituting into (20) gives
Ba
NAFBa
BF
NAFBF
c
NAFBaNAFBF
solid MFMF
MFMF
++
++=
1
1 (24)
Now, substituting (19) into (18) gives
))(1( lCVambamb MTpM = (25)
for TCV>Ml, zero otherwise
Next determine Msaltambas a function of Ml.
SalMMamb
SWsaltamb= (26)
where MSWambis mass seawater in ambient sediment or WBM
drilling deposits,
Sal is salinity of seawater (kg salt/kg seawater).
)()( lCVseawaterNAFCVseawaterSW MTpTTpM amb == (27)
Substituing (27) into (26) gives
SalMTpM lCVseawatersaltamb )( = (28)
for TCV>Ml, zero otherwise
Finally determine Msaltsedas a function of Ml.
saltsedwl
w
saltsedwBaBFc
ww
MMM
M
MMMMM
MW
++=
++++=
100100 (29)
)1( SalSalMMwsaltsed
= (30)
rearrange (30) to give
SalMSalM saltsedw )1( = (31)
Substitute (31) into (29) and solve for Msaltsed.
Sal
Salwhere
WW
MWM
ww
lw
saltsed
=
=
1
100
(32)
Now substitute (32), (28), (25), (17), & (11) into (9).
lCV MT
eMppmHC
l
)1()(
)61()(
+++= (33)
where )1( pamb = , pSalseawater = , and
)100( www WWW =
The following values can be used to check equation (33):
Foil 0.100 amb 2650 kg/m3FBF 0.47 c 2650 kg/m
3
FBa 0.33 solid(eqtn. 23 & 24) 2166 kg/m3
Fsw 0.20 p 0.400
sw 1020 kg/m3 Sal 0.03503 kgsalt/kgseawater
BF 780 kg/m3 Ww 30%
Ba 4200 kg/m3 Tcv 0.02 m
Ml HC (ppm) from eqtn (33)
20 89,275
15 61,269
10 37,648
1 3,300