[ernest_w._flick]_cosmetic_and_toiletry_formulatio(bookfi.org).pdf_pdoc

COSMETIC AND TOILETRY FORM U LATIONS

Second Edition

Volume 6

by

Ernest W. Flick

NOYES PUBLICATIONS Westwood, New Jersey, U S A . ("PI

Copyright 0 1997 by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying, recording or by any informa- tion storage and retrieval system, without permission in writing from the Publisher.

Library of Congress Catalog Card Number: 89-39099

Printed in the United States ISBN 0-8155-1412-3

Published in the United States of America by Noyes Publications 369 Fairview Avenue Westwood, New Jersey 07675

10 9 8 7 6 5 4 3 2 1

Library of Congress Cataloging-in-Publication Data (Revised for vol. 6)

Flick, Ernest W. Cosmetic and toiletry formulations.

1. Cosmetics. 2. Toilet preparations. I. Title. TP983.F55 1989 668l.55 89-39099 ISBN 0-8155-1218-X (v. 1) ISBN 0-8155-1306-2 (v. 2) ISBN 0-8155-1367-4 (v. 3) ISBN 0-8155-1383-6 (v. 4) ISBN 0-8155-1395-X (v. 5) ISBN 0-8155-1412-3 (v. 6)

To

Ryan Eric Taylor

V

CONTENTS AND SUBJECT INDEX

SECTION I: ANTIPERSPIRANTS AND DEODORANTS . . . . . . . . . . 1 Solid Antiperspirant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Anti Perspirant Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

SECTION 11: BABY PRODUCTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Baby Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 Spray-On Detangler for Children . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 Baby Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Conditioning Baby Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Baby Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Baby Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Baby Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 Diaper Rash Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 Baby Skin Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Diaper Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 BabyWash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Economy Baby Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 Shampoo-Baby . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 Baby Shampoo with Olive Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

Foam Bath for Children . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

SECTION 111: BATH AND SHOWER PRODUCTS . . . . . . . . . . . . . . 14 After Bath Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 3-Phase Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Bath and Body Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Bath and Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 BathOil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 Bath and Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 Body Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 Economy Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 Bath & Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 Bubble Bath-Children’s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 Bubble Bath-Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

ix

x Contents and Subject Index

Bubble Bath. Emollient . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 Bubble Bath - Economy Foam Bath . . . . . . . . . . . . . . . . . . . . . . . 21 Bubble Bath - Moisturizing Foam Bath . . . . . . . . . . . . . . . . . . . . . 21 Bubble Bath . Premium Foam Bath . . . . . . . . . . . . . . . . . . . . . . . . 22 Bath and Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 Clear Body Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 Foaming Bath Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 Creamy Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Skin Conditioning Body Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . 24 Deodorizing Body Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 Economy Foam Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 Moisturizing Foam Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 Hand and Bath Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 Creamy "2 in 1" Body Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 Luxury Shower Gelee . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 Combo Bar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 Mild Body Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 Hand Cleaning Cream with Solvent . . . . . . . . . . . . . . . . . . . . . . . . 29 Mild Body Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30 Hand Washing Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30 Moisturizing Body Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 Pearlescent Body Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 Pearlescent Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 After Bath Talc . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 Spreading Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 Pearlized Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Premium Foam Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Bath Body Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Rona/Shampoo/Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 Pearlized Bath Salts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 Shebu Shower Gelee . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 Shower Gel with Mbaruti Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Shower Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Shower Gel with Softigen 767 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 Shower Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 Skin Conditioning Bath Gelee with Ritavena 5 . . . . . . . . . . . . . . . . 39 Dispersible Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 Floating Bath-Oil Bar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 Washing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 2 in 1 Shower Gel and Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . 41 Creamy Bath Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41

Contents and Subject Index xi

SECTION IV: BEAUTY AIDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 Aloe Vera Cream Scrub . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43 Moisture Stick Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43 Aloe Vera Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Liposome Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Anti-Wrinkle Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 Facial Firming Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 Biorepair Skin Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 Anti-Aging Leave On Mask . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 Blusher . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 Starlight Body Freshener . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 Body Emulsion, Type O N , with MPC - Milk Peptide

Complex and Calendula Oil CLR . . . . . . . . . . . . . . . . . . . . . . . 48 Ceramide Complex CLR (P) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Eye Gel with Ceramide Complex CLR (P) . . . . . . . . . . . . . . . . . . . 48 Clear Facial Cleansing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 Conditioning Skin Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 Silky Blush . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 Cooling Facial Balm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 Cream Eye Shadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Creamy Lipstick (Summer Mauve) . . . . . . . . . . . . . . . . . . . . . . . . . 53 Petrolatum SticWLip Balm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 Enriched Emollient Liquid Makeup . . . . . . . . . . . . . . . . . . . . . . . . 54 Exfoliant Scrub . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 Exfoliating Foot Scrub . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 Exfoliant Scrub . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 Foaming Facial Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 Exfoliating Foot Scrub . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 Extra Light W/O Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 Pearlescent Eye Shadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 Eye Mascara . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Powder Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Eye Shadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60 Facial Cleanser with Pemulen TR-2 Polymer

Emulsifier and Carbopol Ultrez 10 Polymer . . . . . . . . . . . . . . . 61 Facial Scrub . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 Facial Cleansing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 Gel with MPC-Liposomes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Body Moisturiser with Wild Borage Oil . . . . . . . . . . . . . . . . . . . . . 63

Lipcare - Emollient Lipstick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Medicated Lip Balm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Lipcare - Lip Pomade . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 66

Hand and Body Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Liquid Makeup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64

xii Contents and Subject Index

Lip Gloss . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 66 Lip Salve with Glycyrrhetinic Acid . . . . . . . . . . . . . . . . . . . . . . . . 67 Lip Salve Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 Lip Fix . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 Lipstick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68 Lip Care Stick with Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 Lipstick. Glossy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70 Lip Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70 Lipstick “Soft and Moist” (Modified) . . . . . . . . . . . . . . . . . . . . . . . 71 Lipstick Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71 Lipstick with A-C 400, No . 162 . . . . . . . . . . . . . . . . . . . . . . . . . . 72 Lip Gloss . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 Liquid Make-up . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 Luxurious Makeup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 Cleansing Milk . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 Makeup Foundation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 Lash-Conditioning Mascara . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 Make-up Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 AHA Facial Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 Mascara Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78 Pressed Powder Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78 Medicated Lip Balm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 Lip Stick Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 Men’s Active Wrinkle Smoother . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 Skin Tightening Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 Moisturizing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 Moisturizing Lip Balm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Lipstick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82 MPC - Milk Peptide Complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83 Anti-Cellulite Emulsion, Type O N with

MPC - Milk Peptide Complex . . . . . . . . . . . . . . . . . . . . . . . . . 83 Night Cream Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84 Skin Nutrient Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84 Nonionic Liquid Makeup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Oil Free Make-up with Hypan SR15OH . . . . . . . . . . . . . . . . . . . . . 86 Oil Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87 Oil Moisturizer with Ritavena 5 . . . . . . . . . . . . . . . . . . . . . . . . . . . 87 ON-Skin Milk . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88 Petroleum OiVPetroleum Wax Free Lipstick . . . . . . . . . . . . . . . . . . 98 Lip Gloss with Sun Protection . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90 Pressed Powder Blush . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91 Pressed Powder Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91 Purified Bentonite Refining Mask . . . . . . . . . . . . . . . . . . . . . . . . . 92 Silky Shadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93

Contents and Subject Index xiii

Powder Eyeshadow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93 Silky Smooth Emollient Liquid Makeup . . . . . . . . . . . . . . . . . . . . . 94 Mascara . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94 Topical Spray Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 Hydroalcoholic Fragranced Spray Gel . . . . . . . . . . . . . . . . . . . . . . . 95 Vitamin F Skin Moisturizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 Body Smoother . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 Waterproof Special Effects Mascara . . . . . . . . . . . . . . . . . . . . . . . . 97 W/O Liquid Foundation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 W/O Moisturizing Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 Skin Care Oil with Citric Acid Ester . . . . . . . . . . . . . . . . . . . . . . . 99 W/O Sheer Make-up . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100

SECTION V:CFCEAMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 AEC Cocoa Butter Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102 Cocoa Butter Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102 AHA Renewal Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103 Glycerin Cream with Citric Acid Esters . . . . . . . . . . . . . . . . . . . . 103 Alpha Hydroxy Acid Liposome Cream . . . . . . . . . . . . . . . . . . . . . 104 Washable Cleansing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104 Anti-Wrinkle Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 AEC Cocoa Butter Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 Cocoa Butter Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . p05 Anti-Wrinkle Moisturizing Cream . . . . . . . . . . . . . . . . . . . . . . . . 106 Anti-Wrinkle Treatment Cream . . . . . . . . . . . . . . . . . . . . . . . . . . 106 Night Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 Basic-Cream with AHA-Esters, Food Approved . . . . . . . . . . . . . . 108 Eye Wrinkle Cream with UV Absorber . . . . . . . . . . . . . . . . . . . . . 108 Bleaching Night Cream Against Age Spots . . . . . . . . . . . . . . . . . . 109 Cleansing Cold Cream W/O . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110 Hand Care Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110 Cream Foundation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111 Cream, Type O/W, with MPC-Milk Peptide Complex . . . . . . . . . . 112 Cream, Type W/O, with MPC-Milk Peptide Complex . . . . . . . . . . 112 Day Cream with Evening Primrose Oil . . . . . . . . . . . . . . . . . . . . . 113 Basic O/W Cream, with Citric Acid Esters . . . . . . . . . . . . . . . . . . 113 Dry Skin Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 Aloe Night Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 Emollient Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115 Hand Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115 Emollient Eye Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116 Enriched W/O Cream with Vitamin E Oil . . . . . . . . . . . . . . . . . . . 117 Anti-Wrinkle Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117

xiv Contents and Subject Index

Eye Contour Cream. Type W/O. with MPC-Milk Peptide Complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118

Gentle Night Repair Cream Water in Oil Emulsion . . . . . . . . . . . . 119 Intensive Anti-Wrinkle Soft Cream

with AH-Acids ( O N ) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120 W/O Cream with 17% Pigments . . . . . . . . . . . . . . . . . . . . . . . . . 120 Light Moisturizing Cream for Dry Skin . . . . . . . . . . . . . . . . . . . . 121 Light Skin-Feel Cleansing Cream W/O . . . . . . . . . . . . . . . . . . . . 122 Hand Care Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122 Moisturizer O/W Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123 Moisturizing Cream w/Tritisol . . . . . . . . . . . . . . . . . . . . . . . . . . . 124 Makeup Remover Cleansing Creme . . . . . . . . . . . . . . . . . . . . . . . 124 Moisturizing Hand & Body Cream . . . . . . . . . . . . . . . . . . . . . . . . 124 Moisturizing Daycream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1125 Moisturizing Day Cream (Sericin) . . . . . . . . . . . . . . . . . . . . . . . . 126 Incroquat Behenyl TMS Cream . . . . . . . . . . . . . . . . . . . . . . . . . . 126 Moisturizing Skin Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127 Moisturizing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127 Multi Purpose Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128 Neck Firming Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129 Night Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130 Cold Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130 Night Creme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131 Night Repair Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132 Cleansing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132 Night Repair Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 Facial Cleansing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 Night Time Moisturizing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . 134 Cleansing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134 Nighttime Moisturizing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . 135 Under Make-up Cream for Normal Skin . . . . . . . . . . . . . . . . . . . 135 Oil-Free Exfoliating Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136 O/W-Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137 Phytodermin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139 O W Basic Cream, Without Paraffin . . . . . . . . . . . . . . . . . . . . . . . 1139 Protective Cream with Cromoist CM Glucan . . . . . . . . . . . . . . . . . 140 Rain Forest Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141 Rejuvenating AHA Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142 Skin Care Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Skin Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 Hand Care Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 Skin Lightening Night Cream Against Age Spots . . . . . . . . . . . . . 145 Cleansing Cream with Salicylic Acid . . . . . . . . . . . . . . . . . . . . . . 145

Moisturizing Cream with MPC . Milk Peptide Complex . . . . . . . . 118

Contents and Subject Index xv

Skin Rejuvenating Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146 Skin Therapy Creme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 Cream. Type O N . with Protectan . . . . . . . . . . . . . . . . . . . . . . . . 147 Ultra Skin Treatment Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148 W/O Basic Cream for Dry Skin. with Evening

Primrose Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Peeling Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 W/O Cream with Almond Oil and Shea Butter . . . . . . . . . . . . . . . 150 Soft W/O Cream with Softisan 649 . . . . . . . . . . . . . . . . . . . . . . . 150 W/O-Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151 Chamomile Glycerin Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151

SECTION VI: HAIR CARE PRODUCTS . . . . . . . . . . . . . . . . . . . . 152 Acudyne 255 55% VOC DME Aerosol Hair Spray . . . . . . . . . . . . 153 Non-Aerosol Hair Spray. Low VOC . . . . . . . . . . . . . . . . . . . . . . 153 Acudyne 255 55% VOC Extra Hold Pump Hair Spray . . . . . . . . . 154

154

Aqueous Conditioning and Styling Mousse . . . . . . . . . . . . . . . . . . 155

Acudyne 255 0% VOC Pump Hair Spray . . . . . . . . . . . . . . . . . . . Aerosol Styling Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155

Alcohol-Free Aerosol Hairspray . . . . . . . . . . . . . . . . . . . . . . . . . 156 Hairspritz . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156 Alcohol-Free Firm Holding Mousse . . . . . . . . . . . . . . . . . . . . . . . Alcohol-Free Styling Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . 157 Alcohol-Free Non-Aerosol Spritz . . . . . . . . . . . . . . . . . . . . . . . . 158 Super Hold Pump Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 158 Alcohol-Free Ringing Gel with Hold . . . . . . . . . . . . . . . . . . . . . . 159 Cream Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 Alcohol-Free Styling Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 Brush-On Hair Color . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161 Creme-in Hair Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161 California Dream Hairspray - 55% VOC - 5% Solids . . . . . . . . . 162 Non-Alcohol Hairspray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162 Clear Hair Rinse Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 163 Pearlescent Cream Rinse Formulation . . . . . . . . . . . . . . . . . . . . . . 163 Concentrated Hair Repair with UV Protection . . ~ . ~ ~ ~ ~ . . ~ ~ ~ . I 164 Iridescent Hair Gel Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . 164 Conditioner for Dry Brittle Hair . . . . . . . . . . . . . . . . . . . . . . . . . . 165 Hair Styling Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 Conditioning Perm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166 Scalp and Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166 Conditioning Styling Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167 Thermal Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167 Cream Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168 Conditioning Rinse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168

157

xvi Contents and Subject Index

Cream Curl Activator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169 Hair Pomade . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169 Cream Rinse Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170

and Permed Hair . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 173 Jojoba Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 173 Detangling Creme Rinse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 Easy Spreading Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175 Gantrez Hair Spray with Cyclomethicone . . . . . . . . . . . . . . . . . . . 175

Acudyne 255 Spray Gel Formulation . . . . . . . . . . . . . . . . . . . . . . 176 Extra-Hold Conditioning Mousse . . . . . . . . . . . . . . . . . . . . . . . . . 177 De-Frizzing Creme-Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177 Firm Holding Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 178 Spray Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 178 Glossing Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179 Acidic Hair Rinse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179 Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180 Hair Conditioner with DLL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 181 Hot Oil Conditioner with CPO . . . . . . . . . . . . . . . . . . . . . . . . . . . 182 Hair Conditioner with DLL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182 Hair Cream Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183 Hair Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183 Hair Repair and Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184 Conditioning Hair Rinse for Oily Hair . . . . . . . . . . . . . . . . . . . . . 184 Hair Shaping Gloss . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 185 Conditioning, Setting Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 185 Hair Straightener . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186 Hair Relaxer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186 Hair Styling Cream (for dried hair) . . . . . . . . . . . . . . . . . . . . . . . 187 Resyn Hair Spray with Dimethicone Copolyol . . . . . . . . . . . . . . . . 187 High Performance Creme Rinse Conditioner . . . . . . . . . . . . . . . . . 188 Hair Shine Concentrated Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . 188 High Performance 80% VOC Non-Aerosol Hair Spray . . . . . . . . . 189 Ultra-Hold Finishing Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189 Hot Oil Conditioner with CPO 190 Hair Straightener . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190 Modern Expression Hair Mask . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 Spiking Spritz . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 Non-Aerosol Finishing Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 Finishing Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . $92 Replenishing Creme Rinse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 Pelan Hair Conditioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 193

Creme Rinse Conditioner for Color-Treated

Elegant Touch Strong Hold, 80% VOC Hair Spray . ~ . . I . ~ . . ~ 176

. . . . . . . . . . . . . . . . . . . . . . . . . . .

Pomade . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194

Contents and Subject Index xvii

Hair Straightener . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194 Premium Biodegradable Hair Conditioner . . . . . . . . . . . . . . . . . . . Ethnic Hair Shine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195 Pump Hair Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 196 Flexible Spray Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 196 Salon Type Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pump Spray Hair Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Soft Set Conditioning Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . 198 StylingIConditioning Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . . 198 Strong Advantage Mousse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 Shape W Style Volumizing Spritz . . . . . . . . . . . . . . . . . . . . . . . . 199 Vision '98 55% VOC Hairspray . . . . . . . . . . . . . . . . . . . . . . . . . . Vision '98 Pump Hairspray - 55% VOC - 6% Solids . . . . . . . . . . Forever Curls Hair Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wheat Moisturizing and Styling Gel . . . . . . . . . . . . . . . . . . . . . . . 202 Pump Hairspray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202 W/O Hair Sculpturing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203 Spray Detangler/Conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203 55% VOC Aerosol Hair Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . 204 Acudyne 255 55% HFC-152a Aerosol Hair Spray . . . . . . . . . . . . 204 80% VOC Aerosol Hair Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 80% VOC Single Phase Hydrocarbon Aerosol Hair Spray . . . . . . . 205 55% VOC Innovative Product Formulation . . . . . . . . . . . . . . . . . . 206 Aerosol Finishing Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206 80% VOC Innovative Aerosol Hair Spray . . . . . . . . . . . . . . . . . . 207 55% VOC Innovative Aerosol Hair Spray . . . . . . . . . . . . . . . . . . 207

195

197

200 201 201

SECTION VII: LOTIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 AHA Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209 Anti-Aging Day Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210 Cationic Lotion with Incroquat Behenyl TMS . . . . . . . . . . . . . . . . 210 Body Lotion for Sensitive Skin . . . . . . . . . . . . . . . . . . . . . . . . . . 211 Cleansing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 211 Botanical Facial Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . 212 Cationic Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 213 Body Lotion: Water in Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 213 Cromoist CM-Glucan Lotion with Crodafos CES . . . . . . . . . . . . . . 214 Dihydroxyacetone Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 215 Isolan DO Lotion O/W Cold Process . . . . . . . . . . . . . . . . . . . . . . 215 Emollient Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216 Ethnic Hand & Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217 Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 218 Cocoa Butter Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . 218 Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219

xviii Contents and Subject Index

Depilatory Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219 Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 220 Dry Touch Emollient Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . 220 Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221 Rehydrating Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221 Hand and Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222 Hand Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222 Hand & Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223 Light Conditioning Hand Lotion . . . . . . . . . . . . . . . . . . . . . . . . . 223 Incroquat Behenyl TMS Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . 224 High SPF-30 Lotion Cold Process . . . . . . . . . . . . . . . . . . . . . . . . 225

Acid Phytosome . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 226 Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227 Collagen Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227 Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 228 Silicone Barrier Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 228 O N Hand & Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 229 Aculyn 33 Hand Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 229 Pearlized Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 Protective Lotion with Cromoist CM Glucan . . . . . . . . . . . . . . . . . 231 Rain Forest Lotion with Cronatural Brazil Nut Oil . . . . . . . . . . . . 232 Dihydroxyacetone Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232 Skin Firming Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233 Facial Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233 Therapeutic Hand & Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . 234 Ethnic Hand & Body Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . 234 Under Make-up Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235 Water-in-Oil Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . 236 Facial Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236 W/O Lotion, EO-free with Softisan 649 . . . . . . . . . . . . . . . . . . . . 237 New "Light Lotion" with Imwitor 375 . . . . . . . . . . . . . . . . . . . . . 237 2% AHA Viscosity Lotion with Uninontan U-34 . . . . . . . . . . . . . 238

Low pH Glycolic Acid Lotion with 18-B Glycyrrhetinic

SECTION VIII: SHAMPOOS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 239 Anti-Dandruff Shampoo Suspending Sulfur

with Ritavena 5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 240 Children's Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . 240 Antidandruff Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 241 Moisturizing Antidandruff Shampoo . . . . . . . . . . . . . . . . . . . . . . . 241 Clear Shampoo with Microcapsules . . . . . . . . . . . . . . . . . . . . . . . 242 All Natural Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 242 Conditioning Color Enhancer Shampoo . . . . . . . . . . . . . . . . . . . . 243 Shampoo-Clear Gel Type . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243

Contents and Subject Index xix

Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 244 Clear. Colorless Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . 250 Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 251

Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 252 Everyday Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 252 Deodorizing Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 253 Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 253

Water White Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 254 255

Pearlescent Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . 255 Noma1 Hair Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 256 Baby Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 256 Opaque Antidandruff Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . 257 Ultra Pearlescent Conditioning Shampoo . . . . . . . . . . . . . . . . . . . 257 Pearlescent Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 258 Basic Shampoo Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 261 Pearlescent Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 262 Salon Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . 262 Pearlized Conditioning Shampoo with Amilan GST 40 . . . ~ . . 263 Shampoo-Clear Gel Type . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263 Pearl Pigment Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 264 Pearlescent Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . 264 Salon Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . 265 Conditioning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 265 Shampoo-All Purpose for Normal Hair . . . . . . . . . . . . . . . . . . . . 266 Shampoo-All Purpose for Oily Hair . . . . . . . . . . . . . . . . . . . . . . 266 Shampoo-Inexpensive . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266 Shampoo-Clear Gel Type . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267 Shampoo-Clear Liquid Conditioning . . . . . . . . . . . . . . . . . . . . . . 268 Shampoo - All Purpose . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 268 Shampoo - Clear Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 268 Shampoo - Clear Viscous . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 269 Shampoo-Conditioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 269 Shampoo-Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 270 Shampoo Clear Liquid Conditioning . . . . . . . . . . . . . . . . . . . . . . . 270 Shampoo-Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271 Shampoo -Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27P Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 272 Shampoo with Silicone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273 Gentle Everyday Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273 Temporary Color-In Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . 274 Shampoo-Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 274

Shampoo with Silicone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 251

Mild Deep Cleaning Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . 254

Moisture Therapy Shampoo with Hydrotriticum WAA . . . . . . . . . .

xx Contents and Subject Index

Transparent Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 275 Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 275 All Purpose Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 275 Water White Shampoo from a Blend . . . . . . . . . . . . . . . . . . . . . . 276 Premium Water White Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . 276 Water White Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 276 3 in 1 Antidandruff Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . 277 Hair Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 277

SECTION IX: SHAVING PRODUCTS . . . . . . . . . . . . . . . . . . . . . . 278 Brushless Shave Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 279 Non-Foaming Shaving Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 280 After Shave Balm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 280 Shave Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 281 Low Alcohol Moisturizing Lotion . . . . . . . . . . . . . . . . . . . . . . . . 281

SECTION X: SOAPS AND HAND CLEANERS . . . . . . . . . . . . . . . . 282 Anti-Bacterial Handsoap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 283 Baby Mild Cleansing Bar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 284 Hand Cleaners-Anti-Bacterial Handsoap . . . . . . . . . . . . . . . . . . 285 Waterless Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 285 Hand Cleaner, Heavy Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 286 Hand Cleaner. Liquid, Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 286 Hand Cleaners-Liquid Dispenser Type . . . . . . . . . . . . . . . . . . . . 287 Liquid Dispenser Type: Pearlescent . . . . . . . . . . . . . . . . . . . . . . . 287 Hand Cleaners-Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . 288 Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 288 Liquid. Soap. Antiseptic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 288 Hand Cleaner-Liquid Dispenser Type . . . . . . . . . . . . . . . . . . . . . 289 Hand Cleaner-Liquid Dispenser Type. Pearlescent . . . . . . . . . . . . 289 Hand Cleaner. Liquid, Soap Antiseptic . . . . . . . . . . . . . . . . . . . . . 290 Handsoap-Clear Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 290 Hand Cleaners-Powder Dispenser Type . . . . . . . . . . . . . . . . . . . 291 Powder Dispenser Type . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291 Hand Cleaner. Powder Dispenser Type . . . . . . . . . . . . . . . . . . . . . 292 Hand Cleaners-Handsoap-Clear Liquid . . . . . . . . . . . . . . . . . . . 293 Heavy Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293 Hand Cleaner, Waterless. Liquid . . . . . . . . . . . . . . . . . . . . . . . . . 294 Hand Cleaner-Waterless Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . 294 Waterless Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 295 Hand Cleaners-Waterless Paste . . . . . . . . . . . . . . . . . . . . . . . . . 296 Waterless Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 296 Hand Cleaner-Waterless Paste . . . . . . . . . . . . . . . . . . . . . . . . . . 297 Hand Cleaner-Liquid. Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 298

Contents and Subject Index xxi

Hot Pour Syndet Bar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Syndet Bar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 299 Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 300 Hand Cleaning Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 300 Lotion Hand Cleaner (With Abrasive) . . . . . . . . . . . . . . . . . . . . . 301 Mild Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 301 Mild Pearlized Hand Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . 302 Pearled Gel Facial Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 302 Facial Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 302 Opaque Liquid Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 303 Transparent Toilet Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 303 Soap Bar for Hard Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 304 Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 305 Waterless Hand Cleaner with Abrasive . . . . . . . . . . . . . . . . . . . . . 305

299

SECTION XI: SUN CARE PRODUCTS . . . . . . . . . . . . . . . . . . . . . 306 After Sun Cream with Aloe Vera and Evening Primrose . . . . . . . . 307 W/O Sun Protection Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 307 After Sun Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 308 Light After Sun Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 308 After Sun Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 309 Sunscreen Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 309 AfterSunMilk . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 310 W/O-Sun Screen Milk . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3710 Insect Repellent Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31B Light After Sun Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 312 After Sun Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 312 Oil Free Skin Bronzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 313 OW-Sun Blocker . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 314 Aculyn 33 Sun Screen Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . 314 OW-Sun Screen Milk . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 315 OW-Sun Blocker . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 315 O W Sun Screen with Organic and Inorganic Screens . . . . . . . . . . 316 O W Sun Protection Lotion (SPF 15) . . . . . . . . . . . . . . . . . . . . . . 316 Pre-Sun Moisture Accelerator . . . . . . . . . . . . . . . . . . . . . . . . . . . 317 Oil in Water Sunscreen Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . 317 Self Tanning DHA Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 318 Skin Protecting Waterproof Sunscreen . . . . . . . . . . . . . . . . . . . . . 319 Waterproof Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319 Solar Protection Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 320 Ti02 Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 320 Sprayable Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321 Waterproof Aerosol Sunscreen (SPF 10) . . ~ . a . ~ . ~ a . . ~ . . 3211 Sunblock Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 322

xxii Contents and Subject Index

Sunblock with Ti02 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 322 Sunless Tanning Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 323 Tanning Accelerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 323 Sunscreen Cream SPF 9 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 324 Sunscreen Cream SPF 12+ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 325 After Sun Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 325

326 Sunscreen Emulsion with Titanium Dioxide . . . . . . . . . . . . . . . . . 327 Sunscreen Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 328 Lip Care Balm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 328 Sunscreen Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 329 Sunscreen Milk W/O . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 330 After Sun Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 330 Sunscreen Milk W/O . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 331 Sunscreen Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 331 Sunscreen Moisturizing Cream . . . . . . . . . . . . . . . . . . . . . . . . . . 332 Sunscreen Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 333 Aloe After Sun Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 333 Sun Tan Oil-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 334 Sun Tan Oil-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 334 Sun Tan Oil-C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 334 Wash-Off Resistant Sunscreen Lotion

with Crodafos CES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 335 Water-In-Oil Sunscreen SPF 26 . . . . . . . . . . . . . . . . . . . . . . . . . 336 Waterproof SPF 30 Sunscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . 337 Waterproof Sunscreen Lotion (SPF 15) Using

Pemulen TR-1 and Carbopol Ultrez 10 . . . . . . . . . . . . . . . . . 338 Sunscreen Cream . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 338 Waterproof Suntan Lotion SPF 17 . . . . . . . . . . . . . . . . . . . . . . . . 339 SPF 12 Sunscreen Liposome Lotion . . . . . . . . . . . . . . . . . . . . . . . 339 Water-Resistant Suntan Lotion . . . . . . . . . . . . . . . . . . . . . . . . . . 340 Zinc Oxide Sunscreen (Measured SPF=9.2) . . . . . . . . . . . . . . . . . . 341 Sunscreen Lotion Using Micronized Ti02 . . . . . . . . . . . . . . . . . . . 341 Zinc Oxide Sunscreen Cream (PABNOxybenzone

Free) Estimated SPF=20 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 342

Sunscreen Cream with UVA Protection (Est . SPF=25) . . . . . . . . . .

SECTION XU: MISCELLANEOUS . . . . . . . . . . . . . . . . . . . . . . . . . 343 Fluoride Dentifrice . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 344 Mouthwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 344 Gum-Massage-Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 344 Glycerol Gel Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 345 Aculyn 33 Fluid Gel Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . 345 Oil Liposome Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 346 Ritavena 5 (l.O%)/Acritamer 934 (1.0%) Blend . . . . . . . . . . . . . . 347

Contents and Subject Index xxiii

Gel Stick . . . . . . . . . . . . . . . . . . . . . . . . . . . I . . . . . . . . . . . . . . 347

SECTION WII: TRADE-NAMED RAW MATERIALS . . I . . . ~ ~ , ~ 348

SECTION XIV: SUPPLIERS' ADDRESSES * . . , . . . . . . . . . . ~ . . 394

Section I Antiperspirants and

Deodorants

1

2 Cosmetic and Toiletry Formulations

Solid Antiperspirant

F o r m u l a t i n g Des ign and Advantages:

Hexaned io l Behenyl Beeswax i n a s i 1 i c o n e o i 1 , p r o d u c i n g an opaque s t i c k wh ich i s creamy and sp reads e v e n l y .

I l l u s t r a t e d i n t h i s f o r m u l a i s t h e g e l l i n g p r o p e r t i e s o f

Formula: Hexaned io l Behenyl Beeswax ( K o s t e r Keunen) Deodor i zed Orange Wax ( K o s t e r Keunen) K e s t e r Wax 82 ( K o s t e r Keunen) S i l i c o n e O i l 556 (Dow) C e t y l S t e a r y l A l c o h o l ( P & G ) Aluminum C h l o r o h y d r a t e (Rehe is )

Wt% 12 .0

6 . 0 8 . 0

3 6 . 0 1 8 . 0 20 .0

P rocedure :

a t 5 5 ~ .

A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t :

d e o d o r a n t / a n t i p e r s p i r a n t . F rag rances a r e e a s i l y added.

SOURCE: K o s t e r Keunen, I n c . : A Guide t o N a t u r a l F o r m u l a t i n g

M e l t and homogenize a t 75C, c o o l and pour i n t o c o n t a i n e r

I r g a s o n DP-300 can be added t o change t h i s p r o d u c t t o a

Anti Perspirant Stick

I n Q r e d i e n t : V o l a t i l e S i 1 i c o n e S t e a r y l A l c o h o l O i l s of A loha Kukui Nu t O i l A r l a c e l 165 S i l i c a Aluminum C h l o r h y d r a t e

WtO/o 44 I 50 2 3 . 0 0

5 . 0 0 2.00 0 . 5 0

2 5 . 0 0

M a n u f a c t u r i n g P rocedure : Combi ne i n g r e d i e n t s a t 75C.

S t e a r y l a l c o h o l i s t h e h a r d e n i n g agen t t h a t make t h e s t i c k . The S i l i c a s e r v e s as a s t a b i l i z e r and t h e Oils o f A l o h a

Kukui Nu t o i 1 s e r v e s two f u n c t i o n s - r e d u c e s t a c k i n e s s and reduces w h i t e n i n g on t h e s k i n .

SOURCE: O i l s o f A l o h a : Suggested F o r m u l a t i o n

Section II Baby Products

3


Baby Conditioner (Formula 86-0404M)

Rhodaquat D261C/75 C e t y l A l c o h o l NF A1 kamul s PSML-80 C e l l o s i z e QP 52,000 H C i t r i c Ac id F rag rance , D y e ( s ) , P r e s e r v a t i v e Water

% by Weight 2 . 2 0 1 . 7 0 0 . 1 5 1 . 7 0

0.10 94 .15

Q.S . t o p H 3 . 5 - 4 . 5

B l e n d i n g P rocedure :

ous a g i t a t i o n , l i g h t l y s i f t C e l l o s i z e QP 52,000H i n t o w a t e r . With smooth a g i t a t i o n , c o n t i n u e t o h e a t system t o 70-75C. W i t h smooth a g i t a t i o n , s l o w l y b l e n d Rhodaquat D261C/75, C e t y l A l c o h o l NF, and A lkamu ls PSML-80 i n t o h e a t e d w a t e r system. M i x u n t i l c o m p l e t e l y u n i f o r m . W i t h smooth a g i t a t i o n , cool system t o 40C and b l e n d i n c o m p a t i b l e F rag rance , D y e ( s ) , and P r e s e r v - a t i v e .

D i s s o l v e C i t r i c Ac id i n w a t e r and h e a t t o 30-35C. W i t h v i g o r -

T y p i c a l Formul a t i on P r o p e r t i e s : Appearance @ 25C: V i s c o u s , Opaque L i q u i d V i s c o s i t y f3 25C: 16,000+ cps (No, 4 s p i n d l e (3 10 RPM)

% Non V o l a t i l e s : 5-6 pH: 3 .5 -4 .5

Spray-On Detangler for Children(Formula 88-708M)

Rhodaquat D261 C/75 S i l i c o n e 344 F l u i d (Dow C o r n i n g ) C i t r i c Ac id F rag rance , Dye(s) , P r e s e r v a t i v e Water

% by Wei a h t 1 . o 0 . 5 Q .S . Q.S.

9 8 . 5

B l e n d i n g P rocedure : Heat w a t e r t o 70C. W i t h r a p i d b u t smooth a g i t a t i o n , s l o w l y

b l e n d i n Rhodaquat D261C/75 and mix u n t i l u n i f o r m . W i t h smooth a g i t a t i o n , cool system t o 40-45C and b l e n d i n S i l i c o n e 344 F l u i d . Once system i s u n i f o r m , a d j u s t f o r m u l a t i o n p H t o 3 . 5 - 4 . 5 w i t h C i t r i c Ac id as needed and add c o m p a t i b l e F rag rance , D y e ( s ) , and P r e s e r v a t i v e .

Use D i r e c t i o n s : Dispense v i a pump o r a e r o s o l s p r a y .

T y p i c a l Formul a t i on P r o p e r t i es : Appearance fJ 25C: T h i n L i q u i d pH: 3 . 5 - 4 . 5

SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : F o r m u l a t i o n s f o r Pe rsona l Care

Baby Products 5

Baby Cream

Formula: A : P r o p y l e n e G l y c o l S t e a r a t e S t e a r i c A c i d C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) A c e t y l a t e d Lanol i n A1 coho1 L a n o l i n O i 1 C e t y l A l c o h o l P r o p y l p a r a b e n B: Tech-0 11-070 S t e r - 0 - P r o (Beacon CMP) C : P r o p y l e n e G1 y c o l T r i e t h a n o l ami ne (85%) Me thy lpa raben I m i d a z o l i d i n y l Urea

% by Weight

9 - 0 0 2 . 0 0 8 . 0 0 1 . o o 1 - 0 0 0 . 5 0 0 .10

2 . 0 0

1 . 5 0 0 . 9 0 0 . 2 0 0 . 2 0

P rocedure : Weigh A and h e a t w i t h s t i r r i n g t o 75C. I n a s e p a r a t e c o n t a i n e r

we igh B and m i x u n t i l d i s p e r s e d . Add C and h e a t t o 75C w i t h s t i r r i n g . W i t h b o t h phases a t 75C add B t o A w i t h good a g i t a t i o n , m ix 10 m i n u t e s a t t h i s t e m p e r a t u r e , t h e n c o o l w i t h m i x i n g t o room t e m p e r a t u r e .

Conditioning Baby Lotion

Formu la : A : C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) S t e a r i c A c i d C e t y l A l c o h o l P ropy lpa raben S i l i c o n e 220 F l u i d Tech-0 11-075 C o n c e n t r a t e d Oat P r o t e i n B: D e i o n i z e d Water T r i e t h a n o l ami ne 99% Methy lpa raben DMDM H y d a n t o i n P r o p y l e n e G1 y c o l

% by Weight

1 0 . 0 0 5 . 0 0 1 . 5 0 0 . 1 5 4 . 0 0

(Beacon CMP) 2 - 0 0

71 .OO 3 . 0 0 0 . 1 5 0 . 2 0 3 . 0 0

P rocedure :

b e a k e r , weigh B and h e a t t o 75C. W i t h b o t h phases a t 75C, add A t o B and m i x w e l l f o r 10 m i n u t e s , t h e n mix and c o o l t o room t e m p e r a t u r e .

I n t o a beaker , weigh A . Heat w i t h m i x i n g t o 75C. I n a n o t h e r

SOURCE: W i t c o Corp. : Suggested F o r m u l a t i o n s


Baby Lotion

Stage M a t e r i a1 : Oil Phase: 1 AEC O c t y l P a l m i t a t e 2 D e r v a c i d 3155 3 Cocoa B u t t e r , R e f i n e d 4 Lasemul 92 AE 5 L i p o v o l PAL

Aqueous Phase: 6 Water; Pure 7 Xanthan Gum 8 G l y c e r i n e 0P 9 T r i e t h a n o l a m i n e 99%

P r e s e r v a t i v e M i x : 10 N i p a s t a t 11 P r o p y l e n e G l y c o l USP

Cool i ng C y c l e : 12 P. Cocoa b u t t e r AA 6780 13 C . S . D&C Red 33; 1% S o l n

Q u a n t i t y

2 . ooog 3 . OOOg 1 .ooog 2 .5009 3 . OOOg

81 .095g 0 .350g 1 .ooog 0.7009

0,2509 5 . OOOg

0.1009 0 .0059

M i x i n g I n s t r u c t i o n s :

h e a t t o 70/75C w i t h o c c a s i o n a l s t i r r i n g . Meter o u t t h e w a t e r i n t o t h e m i x i n g v e s s e l and s t a r t h e a t i n g .

m i x i ng .

mix b r i e f l y w i t h t h e S i l v e r s o n t o smooth t h e m i x t u r e . Remember t o p r e m i x t h e P r o p y l e n e G l y c o l & N i p a s t a t t o a i d s o l u b i l i t y .

Add t h e O i l s t o t h e w a t e r w i t h c a r e f u l S i l v e r s o n m i x i n g and mix w h i l e c o o l i n g . When c o o l a d j u s t pH, add perfume, mach c o l o u r t o Master Sample and g i v e a f i n a l b r i e f m ix w i t h t h e S i l v e r s o n .

pH : 7 .20-8 .00 V i s c o s i t y 3 / 1 2 r : 45-65 SG: 0 .985-0.995 P r o j e c t : J W 2434/Formula R e f . : 974*0

Weigh t h e i t e m s o f t h e O i l Phase i n t o a j a c k e t e d v e s s e l and

D i s p e r s e t h e Xanthan Gum and h e a t t o 70/75C w i t h c o n t i n u o u s

Add t h e o t h e r i t e m s o f t h e Aqueous Phase w h i l e h e a t i n g and

Baby Oil

Stage M a t e r i a1 : 1 L i g h t M i n e r a l O i l 2 AEC O c t y l P a l m i t a t e 3 L i p o v o l PAL 4 I s o p r o p y l M y r i s t a t e (IPM)

P r o j e c t : JW 2434/Formula: 975*0

SOURCE: A & E Connock Ltd.: Suggested F o r m u l a t i o n s

Q u a n t i t y 80 . OOOg 10, ooog

5 . OOOg 5 . OOOg

Baby Products 7

Baby Shampoo

% b y Weinht S t e o l CS-130 30 .0 Amphosol CA 2 0 . 0 P o l y s o r b a t e 20 5 . 0 Kessco PEG 6000 DS 2 . 0 Sodium H y d r o x i d e (50%) Q.S. Fragrance, Dye, P r e s e r v a t i v e Q . S . Sodi um C h l o r i d e Q.S. D . I . Water Q . S . t o 100 .0 M i x i n g P rocedure :

Heat t o 60C and m i x u n t i l t h e PEG 6000 DS i s c o m p l e t e l y d i s - p e r s e d , Add t h e P o l y s o r b a t e 20 and Amphosol C A . B l e n d w e l l and c o o l t o 30C. A d j u s t pH t o 6 . 5 - 7 . 0 w i t h sodium h y d r o x i d e . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e .

Add t h e S t e o l CS-130 and Kessco PEG 6000 DS t o D.I. Water .

Baby Shampoo

YO b y Weight Stepan-Mi 1 d SL3 1 9 . 0 S t e o l CS-330 1 7 . 5 Amphosol CG 1 6 . 5 Kessco PEG 6000 DS 2 . 0 C i t r i c A c i d (50%) Q.S. Fragrance , Dye, P r e s e r v a t i v e Q . S . Sodium C h l o r i d e Q . S . D . I. Water Q . S . t o 100 .0 M i x i n g P rocedure :

h e a t t o 50-6OC. Add PEG 6000 DS and m i x u n t i l a l l s o l i d s have m e l t e d . Cool t o 35C and a d j u s t pH t o 6 . 0 - 7 . 0 w i t h c i t r i c a c i d . Add f r a g r a n c e , dye and p r e s e r v a t i v e , i f d e s i r e d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h s o d i um c h l o r i d e .

Add t h e f i r s t t h r e e components t o D.I. Water w i t h m i x i n g and

Baby Shampoo

YO b y Weight SteDan-Mi ld BSB* 4 0 . 0 D i s t i 11 ed Water Q.S. Sodium C h l o r i d e Q . S . t o 1 0 0 . 0 C i t r i c A c i d (50%) Q . S . F rag rance , Dye, P r e s e r v a t i v e Q.S. M i x i ng Procedure :

Combine f i r s t two i n g r e d i e n t s w i t h m i x i n g . A d j u s t t o d e s i r e d pH ( 6 . 5 - 7 . 5 ) w i t h c i t r i c a c i d . A d j u s t t o d e s i r e d v i s c o s i t y w i t h sodium c h l o r i d e . Add r e m a i n i n g i n g r e d i e n t s w h i l e m i x i n g .

SOURCE: Stepan C o n : Suggested F o r m u l a t i o n s


Baby Shampoo (Formula 91-1004)

Mi racare MS-1 Fragrance and Dye(s) Benzyl A1 coho1 Dowicil 200 (Dow) Citric Acid Water

Blending Procedure: Charge water into mixing vessel and s

MS-1. Mix unti 1 completely uniform. With slowly blend in compatible Fragrance and uniform. Slowly blend in Benzyl Alcohol, Citric Acid as needed to adjust formulat

Typical Properties: Appearance @ 25C: Clear Liquid % Non-Volatiles: 19-21

Viscosity @ 25C: 800-2,000 cps pH: 6.8-7.2

CTFA Identification: Water, PEG-80 Sorbitan Laurate,

Disodium Lauroamphodiacetate, PEG- Hydroxysul tai ne, Sodi um Laureth-13 Fragrance, Benzyl Alcohol, Quatern

9b by Weight 50.00

0.15 0.15

49.70

Q.S.

Q . S . to pH 6.8-7.2

owly blend in Mi racare smooth agitation, Dye(s). Mix until Dowicil 200, and on pH to 6.8-7.2.

Sodium Trideceth Sulfate, 50 Di stearate, Cocami dopropyl Carboxylate, Citric Acid, urn-15, Dye(s).

Note: While the suggested Miracare MS-1 Baby Shampoo has been proven to be essentially non-irritating to the eyes, the addition of untested Fragrances, Dyes, and other additives can adversely affect the irritation potential of the resulting formula.

SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulation for Personal Care: Formula 91-1004

Baby Products 9

Baby Shampoo (Formula 91-1003)

M i r a c a r e BC-10 F rag rance and Dye(s) D o w i c i l 200 (Dow) C i t r i c A c i d Sodium C h l o r i d e Water

% by Weight 3 8 . 5

Q . S . Q.S.

Q.S. t o p H 6 . 5 - 7 . 5 0 . 5 - 1 . 5

6 0 . 0

B1 end i n g P rocedure :

BC-10. M i x u n t i l c o m p l e t e l y u n i f o r m . W i t h smooth a g i t a t i o n , s l o w l y b l e n d i n c o m p a t i b l e F rag rance , Dye(s ) and D o w i c i l 200 p r e s e r v a t i v e . M i x u n t i l c o m p l e t e l y u n i f o r m . A d j u s t t h e p H o f t h e system t o 6 . 5 t o 7 . 5 w i t h C i t r i c A c i d as needed. A d j u s t form- u l a t i o n v i s c o s i t y t o 1,000-2,000 c p s w i t h i n c r e m e n t a l a d d i t i o n o f Sodium C h l o r i d e as needed.

T y p i c a l P r o p e r t i e s :

Charge w a t e r i n t o m i x i n g v e s s e l and s l o w l y b l e n d i n M i r a c a r e

Appearance @ 25C: C l e a r L i q u i d % Non V o l a t i l e s : 17-18

V i s c o s i t y I3 25C: 1,200-2,000 cps pH: 6 . 5 - 7 . 5

CTFA I d e n t i f i c a t i o n : Water , PEG-80 S o r b i t a n L a u r a t e , Cocamidopropyl B e t a i n e ,

Sodium T r i d e c e t h S u l f a t e , Sodium C h l o r i d e , Lau roamphog lyc ina te , PEG-150 D i s t e a r a t e , Sodium Laure th -13 C a r b o x y l a t e , F rag rance , C i t r i c Acid, Quatern ium-15, T e t r a s o d i u m EDTA, D y e ( s ) .

No te : W h i l e t h e suggested M i r a c a r e BC-10 Baby Shampoo has been p r o v e n t o be e s s e n t i a l l y n o n - i r r i t a t i n g t o t h e eyes, t h e a d d i t i o n o f u n t e s t e d F rag rances , Dyes and o t h e r a d d i t i v e s can a d v e r s e l y a f f e c t t h e i r r i t a t i o n p o t e n t i a l o f t h e r e s u l t i n g f o r mu 1 a . SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : F o r m u l a t i o n

f o r Pe rsona l Care

Diaper Rash Lotion

C e t e a r y l a l c o h o l (and) c e t e a r e t h - 2 0 D ime th i cone PPG-2 m y r i s t y 1 e t h e r p r o p i o n a t e C a r n a t i o n S t e a r i c a c i d A l o e v e r a P r o p y l e n e g l y c o l (and ) d i a z o l i d i n y l u r e a (and )

p r o p y l p a r a b e n Sodi um c i t r a t e Nonoxynyl h y d r o x y e t h y l c e l l u l o s e Water

% b y Weight 8 . 0 0

20 .00 5 . 0 0 4 . 0 0

10 .00 1 . o o

1 . o o 3 . 0 0

q . s . 100.00

SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n


Baby Skin Wash

U r e d i e n t s : Water T e t r a s o d i urn EDTA Sodium L a u r e t h S u l f a t e (28% 2M. E.O.) Sodium T r i d e c e t h S u l f a t e PEG-18 G l y c e r y l O lea te /Cocoa te ( A n t i 1 171) C i t r i c A c i d (25% S o l u t i o n ) t o D ime th i cone Copo lyo l ( A b i l B 8852) P r e s e r v a t i v e s Col or Fragrance L a u r y l G1 u c o s i de (and) Cocami d o p r o p y l B e t a i ne (Tego

Sodium C h l o r i d e (25% s o l u t i o n ) G l u c o s i d L 5 5 )

Wei q h t % 52 .40

0 . 1 0 18 .00 1 5 . 0 0

1 . 7 5

0 . 2 5 pH 6 . 5

Q . S . Q . S . Q.S.

12 .50 Q . S .

Procedure : 1 . Heat w a t e r t o 40-5OC. 2 . Combi ne i n g r e d i e n t s i n o r d e r - m i x i ng we1 1 between add i t i ons I

3 . A d j u s t p H and v i s c o s i t y .

Diaper CreamCream (W/O Emulsion)

I n q r e d i en>; Phase A : C e t y l D ime th i cone Copo lyo l ( A b i l EM-90) P e t r o l a t u m D i me th i cone ( 5 0 0 c s ) C e t y l D ime th i cone ( A b i 1 Wax 9801 ) O c t y l S t e a r a t e ( T e g o s o f t O S ) M i n e r a l O i l P o l y g l y c e r y l - 4 I s o s t e a r a t e ( I s o l an GI -34) Hydrogenated C a s t o r O i l S y n t h e t i c Wax

Phase B: Water Sodium C h l o r i d e P r e s e r v a t i ves

Phase C: F rag rance

Weight%

2 . 0 4 . 5 3 . 0 1 . 5 5 . 0 4 . 0 0 . 5 0 . 8 1 . 2

7 6 . 9 0 . 6 Q . S .

Q . S .

Procedure : 1 . Add t h e components o f Phase A , Heat w h i l e m i x i n g t o 80C t o

2 . Heat Phase B t o 50C. Add B t o A s l o w l y w i t h a l o w energy

3 . Cool t o 35C w i t h sweep m i x e r . Add f r a g r a n c e . 4 . Homogeni z e ,

SOURCE: Go1 dschmi d t Chemical Corp . : Suggested Formul a t i ons

i n c o r p o r a t e t h e waxes. Cool t o 50C.

m i x e r . M a i n t a i n a smooth m i l k y appearance a t a l l t i m e s .

Baby Products 11

Baby Wash (Formula 91-1113)

T h i s u l t r a - m i l d s k i n c l e a n s e r f o r m u l a i s i d e a l l y s u i t e d f o r b a b i e s , c h i l d r e n and anyone w i t h s e n s i t i v e s k i n . I t g e n t l y c l e a n s t h e s k i n and i m p a r t s an e l e g a n t , s o f t a f t e r f e e l . I t can a l s o be used as a m i l d b u b b l e b a t h t h a t i s s a f e f o r c h i l d r e n .

M i r a n o l BT Geropon SBFA-30 Jaguar C-162 C i t r i c A c i d F rag rance , D y e ( s ) , P r e s e r v a t i v e Water

% BY Weight 2 5 . 0 1 0 . 0 0 . 3 Q.S. Q.S.

6 4 . 7

81 e n d i n g P rocedure :

smooth a g i t a t i o n , a d j u s t f o r m u l a t i o n p H t o 5-6 w i t h C i t r i c A c i d as needed. W i t h smooth a g i t a t i o n , b l e n d i n M i r a n o l BT and Geropon SBFA-30. M ix u n t i l c o m p l e t e l y u n i f o r m . A d j u s t f o r m u l a t i o n p H t o 6-7 w i t h C i t r i c A c i d as needed and add c o m p a t i b l e F rag rance , Dye(s ) and P r e s e r v a t i v e .

T y p i c a l Formul a t i on P r o p e r t i es :

W i t h v i g o r o u s a g i t a t i o n , d i s p e r s e Jaguar C-162 i n w a t e r . W i t h

Appearance @ 25C: C l e a r L i q u i d V i s c o s i t y @ 25C: 50-300 cps

% Non V o l a t i l e s : 13-14 pH: 6-7

Foam Bath for Children (Formula 87-0508R)

Rhodapex ES

C e l l o s i z e QP 30,000 H C i t r i c A c i d Versene 100 (Dow) F rag rance , Dye, P r e s e r v a t i v e Water

Geropon SBFA-30

% by Weight 6 . 2

1 4 . 5 1 . 2

Q S t o p H 6 . 5 - 7 . 0 0 . 1 QS

7 8 . 0

B l e n d i n g P rocedure : Warm w a t e r t o 50-55C and s l o w l y b l e n d i n Rhodapex ES. W i t h

r a p i d b u t smooth a g i t a t i o n , s l o w l y s i f t C e l l o s i z e QP 30,000 H i n t o w a t e r and m i x u n t i l c o m p l e t e l y d i s p e r s e d . Cool t o 40-45C w i t h moderate a g i t a t i o n and add Geropon SBFA-30 and Versene 100. A d j u s t pH o f system t o 6 . 5 - 7 . 0 w i t h C i t r i c A c i d as needed and t h e n add c o m p a t i b l e F rag rance , Dye, and P r e s e r v a t i v e .



Economy Baby Lotion (Formula 87-0901M)

Water Phase: % by Weight A ) Methy lpa raben 0 .15

P r o p y l e n e G1 y c o l 2 .50 B) D . I . Water 90 .97 C) Carbopol 934 ( G o o d r i c h ) 0 . 1 5 D) Sodium H y d r o x i d e (50% Aq. S o l u t i o n ) 0 . 1 3

O i l Phase: Derma lca re N I A1 kamul s MM/M A lkamu ls GMS S t e a r i c A c i d TP P r o p y l p a r a b e n

1 . 5 0 1 . 5 0 1 . o o 2 . 0 0 0 .10

B1 e n d i ng P rocedure : Water Phase: A ) D i s p e r s e Me thy lpa raben i n P r o p y l e n e G l y c o l . W i t h m i x i n g , hea t

system u n t i 1 M e t h y l paraben has c o m p l e t e l y d i s s o l v e d i n P r o p y l ene G1 y c o l .

B) S l o w l y b l e n d P r o p y l e n e G l y c o l m ix i n t o D e i o n i z e d Water . Heat w a t e r system t o 45-5OC.

C ) W i t h r a p i d b u t smooth a g i t a t i o n , s l o w l y d i s p e r s e Carbopol 934 i n t o h e a t e d w a t e r base . C o n t i n u e t o h e a t system t o 75-8OC.

D ) S l o w l y b l e n d Sodium H y d r o x i d e s o l u t i o n i n t o h e a t e d w a t e r base. The system s h o u l d i m m e d i a t e l y t h i c k e n and c l e a r .

Oil Phase:

w i t h g e n t l e h e a t , warm O i l Phase t o 70-75C ( a v o i d s c o r c h i n g ) . W i t h r a p i d b u t smooth a g i t a t i o n , s l o w l y b l e n d h e a t e d O i l Phase i n t o h e a t e d Water Phase. Once system i s u n i f o r m , c o o l t o 40-45C w i t h moderate a g i t a t i o n and b l e n d i n c o m p a t i b l e F rag rance and D y e ( s ) .

T y p i c a l P r o p e r t i e s :

I n a s e p a r a t e m i x i n g v e s s e l combine O i l Phase i n g r e d i e n t s and,

Appearance ( a f t e r s t a n d i n g 72 h r s . ) : V i scous , Smooth L o t i o n pH (10% A q . ) : 6 . 5 - 7 . 5

CTFA I d e n t i f i c a t i on :

C e t e a r y l A l c o h o l and Ce tea re th -20 , G l y c e r y l S t e a r a t e , Carbomer 934, Me thy lpa raben , P ropy lpa raben , F rag rance , Dyes.

SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : F o r m u l a t i o n

Water, P r o p y l e n e G l y c o l , Sodium S t e a r a t e , M y r i s t y l M y r i s t a t e ,

f o r Pe rsona l Care : F o r m u l a t i o n 87-0901M

Baby Products 13

Shampoo-Baby

I n g r e d i e n t s : P a r t A : Water Cocoamphohydroxy Su l t a i ne Cal foam ES-303

P a r t B: PEG-60 A1 mond G1 y c e r i de PEG-150 P e n t a e r y t h r i t y l T e t r a s t e a r a t e

Weight96

51.30 1 2 . 0 0 2 0 . 0 0

P a r t C : Germaben 11, F rag rance

Comments abou t t h i s f o r m u l a : 1 . F i r s t m ix p a r t A u n t i 1 c l e a r . 2 . M e l t PEG-60 Almond G l y c e r i d e and t h e n m i x w i t h PEG-150

P e n t a e r y t h r i t y l T e t r a s t e a r a t e a t abou t 50C. 3 . Add p a r t B i n t o p a r t A and s t i r u n t i l u n i f o r m . 4 . Add f r a g r a n c e and p r e s e r v a t i v e as needed. 5 . A d j u s t pH i f needed.

SOURCE: P i l o t Chemical Co. : F o r m u l a t i o n SHM-015-01

15 .00 0 . 5 0

9 . 5 0

Baby Shampoo with Olive Oil

I n g r e d i e n t s : Weight% Amphol y t J B 130K (Cocami d o p r o p y l B e t a i ne ) 15.00 M a r l i n a t CM 100/80 ( L a u r e t h - 1 1 C a r b o x y l i c A c i d ) 1 5 . 0 0 S o f t i g e n 767 (PEG-6 C a p r y l i c / C a p r i c G l y c e r i d e s ) 5 . 0 0 I m w i t o r 375 ( G l y c e r y l C i t r a t e / L a c t a t e / L i n o l e a t e / 01 e a t e ) 3 .00

O l i v e O i l 1 . o o A n t i 1 141 L i q u i d ( P r o p y l e n e G l y c o l (and ) PEG-55

P r o p y l e n e G1 y c o l 01 e a t e ) 4 . 0 0 P r e s e r v a t i ve 9 , s . F r a g r a n c e 9 , s . Water up t o 100.00

P r e p a r a t i on :

and s t i r r e d u n t i l homogeneous.

SOURCE: H u l s Amer ica Inc.: F o r m u l a t i o n 3 .5E

A l l i n g r e d i e n t s a r e mixed t o g e t h e r , h e a t e d t o 40 degrees C . ,

Section IIIBath and Shower Products

14

Bath and Shower Products I 5

After Bath Moisturizing Lotion

A m i l d , smooth, w h i t e l o t i o n t h a t b o o s t s c o n t r a c t i o n and r e o r g a n i z a t i o n o f c o l l a g e n f i b e r s w i t h R a f f e r m i n e t o r e i n f o r c e f i r m n e s s and e l a s t i c i t y o f t h e s k i n .

I n g r e d i e n t s : 1 . D i s t i 1 l e d / D e i o n i zed Water 2 . P r o p y l e n e G l y c o l 3 . Me thy lpa raben 4. A c r i t a m e r 941 (Carbomer) 5 . R i t a p r o 300 ( C e t e a r y l A l c o h o l and C e t e a r e t h - 2 0 ) 6 . R i t a IPM ( I s o p r o p y l M y r i s t a t e ) 7 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 8 . S t e a r i c A c i d 9 . P r o p y l p a r a b e n 1O.NaOH (50% S o l u t i o n ) 11 . R a f f e r m i n e ( H y d r o l y z e d Soy F l o u r )

%w/w 8 8 . 9 7

2 . 5 0 0 . 1 5 0 . 1 5 1 . 5 0 1 . 5 0 1 - 0 0 2 . 0 0 0 . 1 0 0 . 1 3 2 . 0 0

Compoundi ng Procedure : Combine i t e m s 1-3 and b e g i n m i x i n g . S l o w l y add i t e m 4 w h i l e

m i x i n g . Heat t o 75C. Combine i t e m s 5-9 and h e a t t o 75C. Add i t e m 10 t o w a t e r . Add o i l t o wa te r w h i l e m i x i n g . Cool t o 40C and add i t e m 11 .

R e f . No. 120-208A

3-Phase Bath Oil

An a p p e a l i n g t r i - l a y e r b a t h o i l wh ich m o i s t u r i z e s t h e s k i n and c o n t a i n s S imch in f o r a l u x u r i o u s f e e l ,

I n g r e d i e n t s : 1 . M i n e r a l O i 1 7NF 2 . S imch in N a t u r a l ( J o j o b a O i l ) 3 . D i e t h y l p h t h a l a t e 4 . Fragrance- "B lue M i n t " 5 . Me thy lpa raben 6 . G l y c e r i n e 7 . D i s t i 11 ed/Dei o n i zed Water 8 . NaCl 9 . G l y d a n t

%w/w 2 6 . 4 0

6 . 6 0 32 .00

1 . o o q . s

2 2 . 6 7 9 . 0 7 2 . 2 6

Q . S

Compounding P rocedure :

f r a g r a n c e i n d i e t h y l p h t h a l a t e . D i s s o l ve NaCl and G1 y d a n t i n w a t e r and m i x w i t h g l y c e r i n e . M i x a l l t h r e e phases t o g e t h e r .

D i s s o l v e S i mchi n i n m i n e r a l o i 1 , D i s s o l v e me thy lpa raben and

R e f . No. 121-102

SOURCE: R . I . T . A . C o r p . : Suggested F o r m u l a t i o n s


Bath and Body Wash

I n g r e d i e n t s : Cal foam ES-303 Sodium C h l o r i d e Water Cal t a i ne C-35 Calamide C Decyl Po l y g l ucose

Comments abou t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n GEL-002-01

Bath and Shower Gel

I n g r e d i e n t s : Cal foam ES-302 Cal t a i ne C-35 Calamide F S a l t Water ( F r a g r a n c e , Dye, C i t r i c A c i d )

Comments abou t t h i s f o r m u l a : V i s c o s i t y i s 90,000 CPS. T o t a l s o l i d s 16.25% F o r m u l a t i o n GEL-003-01

Bath and Shower Gel

I n n r e d i e n t s : C a l B l e n d Gel Sodium C h l o r i d e Water F rag rance , Dye, P r e s e r v a t i v e

Comments abou t t h i s f o r m u l a : Add t h e Sodium C h l o r i d e t o t h i c k e n t h e f o r m u l a t i o n . T h i c k e n s t o 90,000 C P S . F o r m u l a t i o n GEL-004-01

SOURCE: P i 1 o t Chemi c a l Co. : Suggested Formul a t i ons

Wei qht90 60 .10

1 . 1 0 5 . 3 0 5 .00 8 . 8 0

19.70

Wei q h t % 42.70

4 .05 2 .55 0 .75

49 .95

Weight% 50

1 . o - 2 . 0 Q.S. 0 . 5

Bath and Shower Products 17

Bath Oil

Phase : A A A A A A A A A

I n n r e d i e n t : Cyc lometh i cone Phenyl T r i m e t h i c o n e M i n e r a l O i l C12-15 A l c o h o l s Benzoate F rag rance O i l s o f A loha K u i k u i Nut O i l O i l s o f A loha Macadamia Nut O i l V i t a m i n E A l o e O i l

Wt% 1 5 . 0 0 5 . 0 0

48 .80 1 5 . 0 0

5 . 0 0 5 . 0 0 5 . 0 0 0 . 2 0 1 . 0 0

M a n u f a c t u r i n g P rocedure : Phase A: M i x a l l i n g r e d i e n t s a t room t e m p e r a t u r e .

A f l o a t i n g b a t h o i l t h a t f o l l o w s you o u t o f t h e t u b and keeps you f e e l i n g s i l k y . The O i l s o f A loha Macadamia and Kukui Nut O i l c o u n t e r a c t s t h e e x c e s s i v e h y d r a t i o n f r o m t h e b a t h . The h i g h l e v e l o f f r a g r a n c e g i v e s a n i c e bouque t .

SOURCE: O i 1s o f A l o h a : Suggested F o r m u l a t i o n

Bath and Shower Gel

& L a u r e t h - 7 Sodi um L a u r e t h S u l f a t e (Phoenate SLES-70) Cocami de DEA (Phoenami d CD) D i sod i um L a u r e t h Su l f o s u c c i n a t e S i l i c o n e Quatern ium-5 ( P e c o s i l SMQ-40) Dei o n i zed Water D i sod i um EDTA

- B: P r o p y l ene G1 y c o l (and ) D i azo1 i d i n y l Urea (and )

Me thy lpa raben (and ) P r o p y l p a r a b e n

C o l o r F rag rance

5 4 . 0 0

50 .00 6 . 0 0 2 . 5 0 5 . 0 0

31 - 4 8 0 . 0 2

1 . 0 0

9 , s . q . s .

Procedure : Add Phase A i t e m s i n o r d e r w i t h s l o w sweep a g i t a t i o n . Heat

i f necessa ry t o a f f e c t d e a e r a t i o n . When Phase A i s be low 45C, add Phase B w i t h s l o w sweep a g i t a t i o n .

SOURCE: Phoenix Chemica l , I n c . : Suggested F o r m u l a t i o n

18 Cosmetic and Toiletv Formulations

Body Shampoo (Formula 92-0214)

A1 kamide DC 212/S Geropon TC-42 A lkamu ls 6000 DS Water C i t r i c A c i d F rag rance , d y e ( s ) , p r e s e r v a t i v e

% b y Weinht 6 .0

1 5 . 0 0 . 5 Q . S . Q . S . Q . S .

B1 end i n g P rocedure : Charge t a n k w i t h w a t e r , A l kamide DC 212/S, Geropon TC-42

and A lkamu ls 6000 DS, and m ix w h i l e h e a t i n g t o 65C. Cool t o 35C. A d j u s t pH t o 7 . 5 b y a d d i t i o n o f c i t r i c a c i d . Add f r a g r a n c e , d y e ( s ) and p r e s e r v a t i v e . T y p i c a l F o r m u l a t i o n P r o p e r t i e s :

Appearance @ 25C: C l e a r , s l i g h t l y v i s c o u s l i q u i d V i s c o s i t y @ 25C: 1,000-1,500 cps p H : 7 . 5 S o l i d s : 11-11 - 5 %

Water , Cocami de DEA, Sodi u m M e t h y l Cocoyl T a u r a t e , PEG-1 50 CTFA I d e n t i f i c a t i on :

D i s t e a r a t e , C i t r i c A c i d .

Economy Bubble Bath (Formula 91-1008)

M i r a c a r e MPC C i t r i c Ac id ( t o pH 5 .5 -6 .5 ) F rag rance , D y e ( s ) , P r e s e r v a t i v e Sodium C h l o r i d e Water

% by Weight 2 0 . 0

Q . S . Q.S.

1 . o - 2 . 0 78 .5

B1 end i ng P rocedure :

MPC. M i x u n t i l c o m p l e t e l y u n i f o r m . A d j u s t f o r m u l a t i o n pH t o 5 . 5 - 6 . 5 w i t h C i t r i c A c i d as needed. Add c o m p a t i b l e F rag rance , Dye(s ) , and P r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o d e s i r e d c o n s i s t e n c y w i t h t h e j u d i c i o u s a d d i t i o n o f Sodium C h l o r i d e as needed. T y p i c a l F o r m u l a t i on P r o p e r t i e s :


Appearance @ 25C: C l e a r L i q u i d V i s c o s i t y @ 25C: 3,000-4,000 cps

% Non V o l a t i l e s : 8-10

Water , Sodium L a u r e t h S u l f a t e , Cocamide DEA, Sodium C h l o r i d e ,

pH: 5 . 5 - 6 . 5


Cocamidopropyl B e t a i n e , F rag rance , P r e s e r v a t i v e , C i t r i c Acid, D y e ( s > .



Bath & Shower Gel

- _ _ _ I n g r e d i en= Cal B1 end C1 e a r F rag rance , Dye, P r e s e r v a t i v e Sodium C h l o r i d e Water

%Wt. 5 0 . 0 0

Q . S 0 . 1 - 0 . 7

4 9 . 6

Comments About t h i s Fo rmu la : B1 endi n g Procedure :

W i t h smooth a g i t a t i o n , s l o w l y b l e n d C l e a r i n t o w a t e r and m i x u n t i 1 u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 1 5 , 0 0 9 - 2 0 , 0 0 0 c p s (No. 4 S p i n d l e @ 10rpm) w i t h t h e i nc remen ta ! a d d i t i o n o f sodium c h l o r i d e as needed I

T y p i c a l F o r m u l a t i o n P r o p e r t i e s : Appearance: C l e a r , V i scous L i q u i d V i s c o s i t y @ 2 5 C : 1 5 , 0 0 0 - 2 0 , 0 0 0 cps

96 Non V o l a t i l e s : 17-19 CTFA I d e n t i f i c a t i o n : Water , Sodi um L a u r e t h Sul f a t e , Cocami de

pH: 6 . 0 - 7 . 0

DEA, Cocamidopropyl B e t a i n e , Sodi urn C h l o r i d e , F rag rance , P r e s e r v a t i v e , C i t r i c A c i d , D y e ( s )

F o r m u l a t i o n #GEL-001 - 0 1

Bath & Shower Gel

__ I n g r e d i e n t s : - -~ Cal foam ES-302 Cal t a i ne C-35 Calamide F S a l t Water ( F r a g r a n c e , Dye, C i t r i c A c i d )

Comments About t h i s Formula: V i s c o s i t y i s 90,000 cPs. T o t a l s o l i d s 16.25% F o r m u l a t i o n #GEL-003-01

Bath & Shower Gel

Sodium C h l o r i d e Water F rag rance , Dye, P r e s e r v a t i v e

".UL.. 4 2 - 7 0

4 . 0 5 2 , 5 5 0 . 7 5

49 * 95

1 .0-2.@ 9 . 5 9 . 5

Comments About t h i s Formula: Add t h e Sodium C h l o r i d e t o t o t h i c k e n t h e f o r m u l a t i o n T h i c k e n s t o 9 0 , 0 0 0 cPs. F o r m u l a t i o n #GEL-004-01

SOURCE: P i l o t Chemical Co. : Fo rmu la ry


Bubble Bath-Children's

I n g r e d i e n t s : Water Cal foam ES-303 C a l s o f t T-60 Calamide C C i t r i c A c i d 0 i sod i um EDTA P r e s e r v a t i v e Perfume, C o l o r

% W t . 39.45 40.00 14 .00

5.00 0 . 1 5 1 . o o 0 . 0 5 0 . 1 0

Comments About t h i s Formula: 1 . Add t h e f i r s t t h r e e i n g r e d i e n t s and s t i r ; t h e b l e n d becomes

q u i t e v i s c o u s when t h e amide i s added. 2 . Add C i t r i c A c i d t o a d j u s t t h e pH t o 6 .

F o r m u l a t i o n #SUB-001-01

Bubble Bath-Liquid

I n n r e d i e n t s : Water NaCl Cal foam ES-303 Calamide LL PEG 7 G l y c e r y l Cocoate Cocami d o p r o p y l ami ne Ox ide Perfume, Dye(s ) , P r e s e r v a t i v e s

% W t . 48 .50

1 - 0 0 40.00

5 . 0 0 2 .50 3 .00 9 . 5 0

Comments About t h i s Formula: 1 . M i x t h e i n g r e d i e n t s i n o r d e r 1 i s t e d . 2 . A d j u s t t h e amount o f s a l t a s needed t o c o n t r o l t h e v i s c o s i t y . 3 . The b l e n d o f amide and amine o x i d e p r o v i d e s a h i g h l e v e l of

d e t e r g e n c y w i t h minimum i r r i t a t i o n p o t e n t i a l n o t p o s s i b l e i n a s t r i c t l y h i g h amide b l e n d . F o r m u l a t i o n #BUS-O02-01

Bubble Bath, Emollient

I n a r e d i e n t s : Water Cal foam ES-302 PEG 7 G l y c e r y l Cocoate Calamide LL Perfume, Dye(s ) , P r e s e r v a t i v e

Comments About t h i s Formula: 1 . M i x a l l t h e i n g r e d i e n t s i n o r d e r l i s t e d . 2 . The p r o d u c t i s c l e a r .

F o r m u l a t i o n #BUS-003-01

SOURCE: P i l o t Chemical Co. : F o r m u l a r y

31 . 7 0 60 I 00

5 .00 3 .00 0 .30


Bubble Bath - Economy Foam Bath

I n g r e d i e n t s : CalB1 end C1 e a r F rag rance , Dye, P r e s e r v a t i v e Sodium C h l o r i d e Water

Wei n h t % 15 .00

Q . S . Q . S .

85.00

Comments abou t t h i s f o r m u l a : B l e n d i n g P rocedure :

W i t h smooth a g i t a t i o n , s l o w l y b l e n d C a l B l e n d C l e a r i n t o wa te r and m i x u n t i l u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 1,000-3,000 cps w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e as needed.

CTFA I d e n t i f i c a t i o n : Water , Sodium L a u r e t h S u l f a t e , Sodium C h l o r i d e , Cocamide

DEA, Cocamido p r o p y l B e t a i n e , F rag rance , P r e s e r v a t i v e , C i t r i c A c i d , D y e s ( s ) .

F o r m u l a t i o n BUB-004-01

Bubble Bath - Moisturizing Foam Bath

I n g r e d i e n t s : Cal B1 end C1 e a r G l y c e r i n e F rag rance , Dye, P r e s e r v a t i v e Sodium C h l o r i d e Water

Wei n h t % 3 7 . 0 0

1 . 5 0 Q . S .

0 . 2 - 0 . 8 61 . O O

Comments abou t t h i s f o r m u l a : B1 end i ng P rocedure :

i n e i n t o w a t e r . M i x u n t i l c o m p l e t e l y u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 5,000-8,000 cps w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e as needed.

W i t h smooth a g i t a t i on, s l o w l y b l e n d CalB1 end C1 e a r and g l y c e r -

CTFA I d e n t i f i c a t i o n : Water , Sodium L a u r e t h S u l f a t e , Cocamide DEA, G l y c e r i n e ,

Cocamidopropyl B e t a i n e , Sodium C h l o r i d e , F ragarnce , P r e s e r v - a t i v e , C i t r i c A c i d , D y e ( s ) .


SOURCE: P i 1 o t Chemical Co, : Suggested Formul a t i ons


Bubble Bath - Premium Foam Bath

I n g r e d i e n t s : Cal B1 end C1 e a r F rag rance , Dye, P r e s e r v a t i v e Sodi um C h l o r i d e Water

Wei n h t % 2 5 - 0 0

Q . S . Q . S .

7 5 . 0 0


W i t h smooth a g i t a t i o n , s l o w l y b l e n d C a l B l e n d C l e a r i n t o w a t e r and m i x u n t i l u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 1 ,000-3 ,000 cps w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e as needed.

CTFA I d e n t i f i c a t i o n :

Cocamido p r o p y l B e t a i n e , F rag rance , P r e s e r v a t i v e , C i t r i c A c i d , D y e ( s ) .

Water , Sodium L a u r e t h S u l f a t e , Sodium C h l o r i d e , Cocamide DEA,


Bath and Shower Gel

I n g r e d i e n t s : CalB1 end C l e a r F rag rance , Dye, P r e s e r v a t i v e Sodium C h l o r i d e Water

w h t % 50 .00

Q . S

49.60 0 . 1 0 - 0 . 7 0


W i t h smooth a g i t a t i o n , s l o w l y b l e n d C l e a r i n t o w a t e r and m i x u n t i l u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 15,000-20,000 cps (No . 4 S p i n d l e @ 10 r p m ) w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e a s needed.

T y p i c a l F o r m u l a t i o n P r o p e r t i e s : Appearance: C1 e a r , V i scous L i q u i d V i s c o s i t y @ 25C: 15,000-20,000 cps

% Non V o l a t i l e s : 17-19 pH: 6 . 0 - 7 . 0


B e t a i n e , Sodium C h l o r i d e , F rag rance , P r e s e r v a t i v e , C i t r i c A c i d , D v e ( s ) .

Water , Sodium L a u r e t h S u l f a t e , Cocamide DEA, Cocamidopropyl

F o r m u l a t i o n No. GEL-001 -01

SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s

Both and Shower Products 23

Clear Body Wash

D . I. Water S t e o l CS-330 N i n o l 30-LL Amphosol CG Tween 20 Versene 100 G l y c e r i n P r e s e r v a t i v e , F rag rance , Dye

M i x i ng P rocedure : Combine a l l i n g r e d i e n t s w i t h m i x i n g . A d j u s t pH t o - 6 . 7

Clear Body Wash

D . I . Water B io -Te rge AS-40 N i n o l 55-LL S t e o l CS-330 Kessco PEG 6000DS P r e s e r v a t i v e , Dye, F rag rance C i t r i c A c i d (50%) Sodium C h l o r i d e

% b y Wei a h t Q.S. t o 100.0

57 .7 3 . 5 5 . 0 0 . 3 0 0 .20 0 . 5 Q.S.

% by Weight Q . S . t o 100 .0

37 .50 4 . 0

28.50 1 . o Q.S . Q . S . Q . S .

M i x i ng P rocedure : Combine f i r s t f i v e i n g r e d i e n t s i n a c o n t a i n e r and h e a t t o

165F w i t h m i x i n g . Keep t e m p e r a t u r e c o n s t a n t u n t i l a l l s o l i d p a r t i c l e s have m e l t e d . W i t h m i x i n g , c o o l t o 11OF, add p r e s e r v - a t i v e , f r a g r a n c e and dye .

A d j u s t pH t o 6 . 0 - 6 . 5 w i t h 50% c i t r i c a c i d . A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e .

Foaming Bath Powder

Stepano l ME-Dry Sodium B i c a r b o n a t e Sodium S e s q u i c a r b o n a t e L a t h a n o l LAL P r o p y l Paraben PPG-12-PEG-50 Lanol i n F rag rance

% by We ish t 19.00 21 . o o 44.85 11 - 0 0 0 . 1 5 3 .00 1 .oo

M i x i n g Procedure: Combine f i r s t f i v e i n g r e d i e n t s i n a c o n t a i n e r w i t h l i d and

m i x u n t i l u n i f o r m . M i x f o l l o w i n g two i n g r e d i e n t s i n s e p a r a t e c o n t a i n e r u n t i l u n i f o r m . S l o w l y combine a l l i n g r e d i e n t s w h i l e m i x i n g . S t o r e i n s e a l e d c o n t a i n e r s . SOURCE: Stepan C o . : Suggested F o r m u l a t i o n s


Creamy Shower Gel

I n n r e d i e n t s : Sodi um Cocoyl I s e t h i o n a t e Water T e t r a s o d i u m EDTA Sodium L a u r e t h S u l f a t e (28% 2M. E . O . ) Sodi um L a u r y l S u l f a t e (28%) Sodium L a c t a t e (and ) Sodium PCA (and ) G l y c i n e (and )

F r u c t o s e (and ) Urea (and ) N i a c i n a m i d e (and) I n o s i t o l (and) Sodium Benzoate (and ) L a c t i c A c i d ( L a c t i l )

DATEM ( A m i l a n GST 40) PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) Cocami d o p r o p y l B e t a i n e (Tego B e t a i n e F50) G l y c o l D i s t e a r a t e (and ) S t e a r e t h - 4 (Tego P e a r l N 1 0 0 ) P r e s e r v a t i v e s Sodium C h l o r i d e : A d j u s t t o d e s i r e d v i s c o s i t y C i t r i c A c i d (10%) : A d j u s t t o pH 5 . 5 - 6 . 0 i f needed Procedure :

Weight% 2 .37

52 .28 0 .10

25 .00 10 .00

0 . 2 5 2.00 1 . o o 5 . 0 0 2 . 0 0

Q . S .

1 . D i s s o l v e Sodium Cocoyl I s e t h i o n a t e i n warm w a t e r a t 60C. 2 . Add Sodium L a u r y l S u l f a t e , Sodium L a u r e t h S u l f a t e . 3 . Cool t o 40C. 4 . Add r e m a i n i n g i n g r e d i e n t s i n o r d e r as l i s t e d , s t i r r i n g

between each a d d i t i o n . 5 . Cool t o 30-35C. Add Tego P e a r l N 100 and p r e s e r v a t i v e s . 6 . A d j u s t p H and v i s c o s i t y .

Skin Conditioning Body Shampoo(cold process)

I n q r e d i e n t s : Wei q h t % T e t r a s o d i u m EDTA 0 . 1 0 Water 44 .25 Ammonium L a u r e t h S u l f a t e - (28% 2M. E . O . ) 25.00 Ammoni um L a u r y l S u l f a t e (28%) 2 0 . 0 0 PEG-18 G l y c e r y l O lea te /Cocoa te ( A n t i 1 171) 1 . 5 0 Cocamidopropyl B e t a i n e (Tego B e t a i n e F 5 0 ) 5 .00 PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) 2 . 5 0

D ime th i cone C o p o l y o l (Ab i 1 B 8852) 0 . 5 0 Water (and ) E t h o x y d i g l y c o l (and ) P r o p y l e n e G1 y c o l

PEG-30 G l y c e r y l L a u r a t e (Taga t L ) 1 . o o

(and ) B u t y l e n e G l y c o l (and) M a t r i c a r i a E x t r a c t (and ) Sage E x t r a c t (and ) Yarrow E x t r a c t (and ) Balm M i n t E x t r a c t (and ) Rosemary E x t r a c t (and ) Res tha r row E x t r a c t (and) C o l t s f o o t E x t r a c t (and) W i l d Thyme E x t r a c t (and ) H o r s e t a i l E x t r a c t (and) F r u c t o s e (and ) A l t h e a E x t r a c t ( E x t r a p o n e 3 Speci a1 2/789490 Dragoco) 0 .15

C i t r i c A c i d (25% s o l u t i o n ) t o p H 6 P r e s e r v a t i v e s Q . S . Fragrance Q . S . Ammonium C h l o r i d e (25% s o l u t i o n ) as needed P r o c e d u r e :

pH. A d j u s t v i s c o s i t y .

SOURCE: Goldschmi d t Chemical Corp I : Suggested F o r m u l a t i o n s

Add i n g r e d i e n t s i n o r d e r , m i x i ng between a d d i t i o n s . A d j u s t


Deodorizing Body Wash

D. I. Water Stepan-Mi 1 d LSB Stepanol WAT N i n o l 96-SL Propy lene G l y c o l I r g a s a n DP-300 Kessco PEG 400 ML H y d r o l y z e d C o l l a g e n P r e s e r v a t i v e , Dye, F rag rance Sodi um H y d r o x i de (50%) Sodium C h l o r i d e

% by Wei p h t Q.S t o 100.0

60 .00 25.00

4 . 0 0 1 . 5 0 .5 2 . 0 0 . 5 Q.S. Q.S. Q . S .

M i x i ng P rocedure :

165F w i t h m i x i n g . When u n i f o r m , c o o l t o 11OF. Meanwhi le , i n a s e p a r a t e c o n t a i n e r , combine i t e m s 5 and 6 m i x i n g u n t i l i t e m 6 i s d i s s o l v e d . Add t o main m i x t u r e . W h i l e m i x i n g , add r e m a i n i n g i terns.

Combine f i r s t f o u r i n g r e d i e n t s i n a c o n t a i n e r and h e a t t o

A d j u s t pH t o 6 .0 -6 .5 w i t h 50% sodium h y d r o x i d e . A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e .

Deodorizing Body Wash

D . I. Water Stepan-Mi 1 d LSB S t apa no 1 WAT N i n o l 96-SL P r o p y l e n e G l y c o l I rgasan DP-300 Kessco PEG 400 ML Hydro1 yzed Col 1 agen P r e s e r v a t i v e , Dye, F rag rance Sodium H y d r o x i d e (50%) Sodium C h l o r i d e

% by We igh t Q.S. t o 100.0

60 .00 25.00

4 . 0 0 1 . 5 0 . 5 2 . 0 0 . 5 Q.S. Q.S. Q.S.

M i x i ng P rocedure : Combine f i r s t f o u r i n g r e d i e n t s i n a c o n t a i n e r and hea t t o

1 6 5 F w i t h m i x i n g . When u n i f o r m , c o o l t o llOF. Meanwhi le i n a s e p a r a t e c o n t a i n e r , combine P r o p y l e n e G l y c o l and I r g a s a n DP-300, and m i x u n t i l I r g a s a n DP-300 i s d i s s o l v e d . Add t o ma in m i x t u r e . W h i l e m i x i n g , add r e m a i n i n g i t e m s .

A d j u s t pH t o 6 .0 -6 .5 w i t h 50% sodium h y d r o x i d e . A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e .

SOURCE: Stepan Co. : Suggested F o r m u l a t i o n s


Economy Foam B a t h

._ I n g r e d i e n t s : Cal B1 end C1 ea r F rag rance , Dye, P r e s e r v a t Sodium C h l o r i d e Water

Comments About t h i s Formu B1 end i ng Procedure :

W i t h smooth a g i t a t i o n ,

ve

a :

w:, Q . S . Q . S .

1 5 . 0 0

8 5 . 0 0

s l o w l y b l e n d Ca lB lend C l e a r i n t o wa te r and m ix u n t i l u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 1 ,000 -3 ,000 cps w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e as needed.

CTFA I d e n t i f i c a t i on : Water , Sodium L a u r e t h S u l f a t e , Sodium C h l o r i d e , Cocamide

DEA, Cocamido p r o p y l B e t a i n e , F rag rance , P r e s e r v a t i v e , C i t r i c A c i d , D y e ( s ) .

F o r m u l a t i o n #BUB-OO4-001

Moisturizing Foam Bath

I n g r e d i e n t s : Cal B l e n d C1 ea r G 1 y c e r i ne F rag rance , Dye, P r e s e r v a t i v e Sodium C h l o r i d e Water

% W t . 3 7 . 0 0

1 . 5 Q . S .

0 . 2 - 0 . 8 61 . O O

B l e n d i n g P rocedure :

i n e i n t o w a t e r . M i x u n t i l c o m p l e t e l y u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 5,000-8,000 cps w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e as needed.

W i t h smooth a g i t a t i o n , s l o w l y b l e n d Ca lB lend C l e a r and g l y c e r -


Cocamidopropyl B e t a i n e , Sodi urn C h l o r i d e , F rag rance , P r e s e r v a t i v e , C i t r i c A c i d , D y e ( s ) .

Water , Sodium L a u r e t h S u l f a t e , Cocamide DEA, G l y c e r i n e ,

F o r m u l a t i o n #SUB-005-01

SOURCE: P i l o t Chemical Co I : Fo rmu la ry


Hand and Bath Gel

I n q r e d i e n t s : Weight% Phase A : Water 50 .15 T e t r a s o d i um EDTA 0 . 1 0 Sodi um I s e t h i o n a t e 3 . 0 0 Sodi um L a u r y l S u l f a t e (30%) 1 5 . 0 0 D i sod i um L a u r e t h - 3 Su l f o s u c c i n a t e 1 0 . 0 0 D i me th i cone Copol yo1 ( A b i 1 B 8851 ) 0 . 7 5 PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) 1 . o o P o l y g l y c e r y l - 4 I s o s t e a r a t e ( I s o l a n G I 34) 0 . 5 0 G l y c e r i n 3 . 0 0 Sodium L a c t a t e (and ) Sodium PCA (and) G l y c i n e (and )

F r u c t o s e (and ) Urea (and ) N i a c i n a m i d e (and) I n o s i t o l (and) Sodium Benzoate (and) L a c t i c A c i d ( L a c t i l ) 0 . 2 5

P r e s e r v a t i v e s Q.S. C o l o r Q . S . Fragrance Q . S . PEG-18 G l y c e r y l O lea te /Cocoa te ( A n t i 1 1 7 1 ) 2 . 0 0 Cocoami d o p r o p y l B e t a i ne (Tego B e t a i ne F 5 0 ) 11 .75 G l y c o l D i s t e a r a t e (and ) S t e a r e t h - 4 (Tego P e a r l N 100) 2 .50 Sodium C h l o r i d e Q.S. Procedure : 1 . D i s s o l v e t h e T e t r a s o d i u m EDTA i n t h e w a t e r . 2 . Add i n g r e d i e n t s i n o r d e r , m i x i n g between a d d i t i o n s . A v o i d

3 . S l o w l y m i x i n t h e PEG-18 G l y c e r y l O lea te /Cocoa te . 4 . Add t h e Cocamidopropyl B e t a i n e . 5 . A d j u s t v i s c o s i t y w i t h t h e 25% s o l u t i o n o f Sodium C h l o r i d e .

I n g r e d i e n t s : Wei a h t % Phase A : G1 y c o l D i s t e a r a t e ( T e g i n EGS) 2.50 M y r i s t i c A c i d 4 . 0 0 J o j o b a O i 1 5 .00 Sodium L a u r e t h S u l f a t e (28% 2M. E . O . ) 45 .00 Water 1 0 . 0 0 Phase B: Water 19 .00 PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) 2 . 0 0 Phase C : P r o p y l ene G1 y c o l (and) PEG-55 P r o p y l e n e G1 y c o l 01 e a t e

( A n t i 1 141L) 2 . 5 0 F rag rance , P r e s e r v a t i v e , e t c . Q.S. Phase D: Cocamidopropyl B e t a i n e (Tego B e t a i n e F 5 0 ) 1 0 . 0 0 P rocedure : 1 . Heat Phase A t o a p p r o x i m a t e l y 70C w h i l e m i x i n g (above t h e

m e l t i n g p o i n t o f T e g i n E G S ) . 2 . Heat t h e i n g r e d i e n t s o f Phase B t o t h e same t e m p e r a t u r e a s Phase A . 3 . S t i r Phase B i n t o Phase A . Cool t o 40C. 4. Add Phase C . M i x w e l l . A v o i d a i r en t rapmen t . 5 . Add Phase D w i t h s t i r r i n g . A v o i d a i r en t rapmen t .

SOURCE: Goldschmid t Chemical C o r p . : Suggested F o r m u l a t i o n s

a i r en t rapmen t .

Creamy "2 in 1" Body Wash


Luxury Shower Gelee

A c l e a r , v i s c o u s , r i c h - l a t h e r i n g shampoo f o r h a i r and body wh ich c l e a n s e s g e n t l y , and l e a v e s a s o f t , smooth a f t e r f e e l .

P a r t : I n c l r e d i e n t (Trade Name) : A Dei on1 zed Water

TEA L a u r y l S u l f a t e (S tepano l WAT) Na4EDTA I m i d a z o l i d i n v l Urea (Germa l l 115) Me thy l Paraben Cocamidopropyl Amine Ox ide (Mazox CAPA) Ammonium Cocoyl I s e t h i o n a t e (Jordapon ACI-30) Ammonium L a u r e t h S u l f a t e ( A l f o n i c 1412-A)

B Cocamide MEA (Monamid CMA) Cocamide DEA (Mazamide JT-128) F rag rance

W B 41 . 6 1 5 . 6

0 . 2 0 . 2 0 . 2

1 0 . 4 1 3 . 0 1 3 . 0

2 . 3 2 . 6 0 . 5

C C i t r i c A c i d 0 . 4

pH: 6 . 3 - 6 . 8 V i s c o s i t y : 7500-10,000 cps ( B r o o k f i e l d #3 @ 6 rpm) Appearance: C l e a r , v i s c o u s l i s u i d

P rocedure :

I n a s i d e v e s s e l . p remix p a r t B, warming t o 40C t o d i s s o l v e t h e cocamide M E A . Add B t o A, m i x i n g u n t i l c l e a r and u n i f o r m . A d j u s t P H .

M i x p a r t A i n g r e d i e n t s i n m a i n v e s s e l u n t i l c l e a r and u n i f o r m .

Formul a t i on F-105

Combo Bar

M o d i f i c a t i o n o f an example i n US P a t e n t #5,041 , 2 3 3

I n g r e d i e n t LTrade Name) : Ta l l ow /Coco Soap ( 8 5 / 1 5 ) Sodium Cocoyl I s e t h i o n a t e ( a n d ) S t e a r i c A c i d

Water Sodium I s e t h i o n a t e ( W i t c o n a t e NIS) Sodium C h l o r i d e F rag rance T i 02 Na3H EDTA BHT

(Jordapon C I -75 )

Formul a t i on M104

Wt?h 5 5 . 6

29 .3 1 0 . 3

2 . 0 0 . 4 1 . o 1 . 0 0 . 2 0 . 2

SOURCE: PPG I n d u s t r i e s , Inc. : Suggested F o r m u l a t i o n s


Mild Body Shampoo

This pearlized formula flash-foams to a voluminous, lacylather and leaves skin feeling soft and smooth, not dry andti ght.

Ingredient (Trade N_ame_^: Wt%Deionized Water 52.6Sodium Cocoyl Isethionate (Jordapon CI-UP) 7,9Sodium C12-15 Pareth-15 Sulfonate (Avanel S-150 CG) 4.2Ammonium Lauryl Sulfate (Stepanol AM) 10.1Ammonium Laureth Sulfate (Alfonic 1412-A) 7.5Glycol Stearate (Mapeg EGMS) 0.7Tetrasodium EDTA 0.2Methyl Paraben O . 2I m i d a z o l i d i n y l Urea (Germall 115) 0.2Cocamidopropyl Hydroxysultaine (Mafo CSB-50) 15.1Soyamide DEA (Mazamide SS-1Q) 1.2Citric Aci d 0.1

pH: 6.0-6.5Viscosity: 6600 cps (Brookfield #2 (3 3rpm)Appearance: Clear, pale straw-colored l i q u i d

Procedure:Mix the first eight ingredients together, heating to 65C

u n t i l all solids are dissolved. Add the last four ingredientsin order, m i x i n g u n t i l uniform. Adjust pH with c i t r i c acid or'triethanolamine, if necessary.

SOURCE: PPG Industries, Inc.: Formulation F-2Q4

Hand Cleaning Cream with Solvent

Wt %Part A:Zusolat 1005/85 10.5Shellsol T 34.5P a r a f f i n o i l 9.0Aerosi1 200 1 . O

Part B:Oxypon 2145 2.5Extrakt 52 15.0Water, perfume, preservative 27.5

Mix part A and part B separately.F i n a l l y add part B to part A whils t s t i r r i n g .

SOURCE: Zschimmer & Schwarz GmbH & Co.: Formulation B 27/2


Mild Body Shampoo

T h i s h i g h - v i s c o s i t y shower g e l e e i s s u i t a b l e f o r p a c k a g i n g i n t u b e s . I t f l a s h e s i n t o a dense, r i c h , s o f t - f e e l i n g l a t h e r wh ich r i n s e s e a s i l y and l e a v e s a smooth a f t e r f e e l on t h e s k i n .

P a r t : I n g r e d i e n t ( T r a d e Name): Wtl A D e i o n i zed Water 5 2 . 6

Po lyquatern ium-10 (Ucare Polymer JR-125) 0 .3

B Ammonium L a u r y l S u l f a t e ( S t e p a n o l AM) 1 0 . 1

Ammonium L a u r e t h S u l f a t e ( A l f o n i c 1412-A) 7 . 5 Sodium Cocoyl I s e t h i o n a t e (Jordapon CI-UP) 7.9 N a 4 EDTA 0 . 2 M e t h y l Paraben 0 . 2 I m i d a z o l i d i n y l Urea (Germal l 11 5 ) 0 . 2

C Cocamidopropyl H y d r o x y s u l t a i n e (Mafo CSB-50) 1 5 . 1 Soyami de DEA (Mazami de SS-10) 1 . 2 Fragrance 0 . 5 C i t r i c A c i d Q . S .

Sodium C12-15 Pare th-15 S u l f o n a t e (Avanel S-150 CG) 4 . 2

pH: 6 . 3 - 6 . 8 V i s c o s i t y : 19,900 cps ( B r o o k f i e l d #3 @ 3rpm) Appearance: C l e a r , v i s c o u s y e l l o w l i q u i d

Procedure :

p r o p e l l o r a g i t a t i o n . C o n t i n u e m i x i n g f o r a t l e a s t 20 m i n u t e s w h i l e h e a t i n g t o 40C. Add t h e p a r t B i n g r e d i e n t s i n o r d e r , m a i n t a i n i n g t h e 40C t e m p e r a t u r e u n t i l a l l s o l i d s a r e d i s s o l v e d . Add t h e Mafo CSB-50, t h e Mazamide SS-10, and t h e f r a g r a n c e i n o r d e r , t h e n a d j u s t t h e pH.

SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n F-107

D i s p e r s e t h e p o l y q u a t e r n i u m - 1 0 i n t h e p a r t A w a t e r w i t h good

Hand Washing Paste

S u l f e t a l T C 50 P u r t o n SFD Carboxymethy l c e l l u l o s e S o f t soap Quar tz sand Ch ina c l a y Sodi um t r i p o l y p h o s p h a t e q.s. t o make 100%: ‘water ,

Wt% 4 . 0 1 . o 1 . 5

1 2 . 0 60 .0

6 . 0 1 . 0

per fume, p r e s e r v a t i v e

SOURCE: Zschimmer & Schwarz GmbH & Co.: F o r m u l a t i o n B22/2


Moisturizing Body Wash

S t e o l CS-230 Stepano l AM-V S t e pan o 1 WA- Ex t r a N i n o l 30-LL EDTA Stepan TAB-2 S i 1 i cone DC200 Avocado O i l Maprosy l 30 H y d r o l y z e d Corn P r o t e i n P r e s e r v a t i v e , Dye, Fragrance C i t r i c A c i d (50%) Sodi urn Chl o r i de

% by Weight 30.00 25.00 23 .00 4.5 0.2 5.0 1 . o 0.5 10.0 0.5 Q . S . Q.S. Q.S.

M i x i n g Procedure : Combine f i r s t f i v e i n g r e d i e n t s i n a c o n t a i n e r and h e a t t o

165-170F w i t h m i x i n g . I n a s e p a r a t e c o n t a i n e r , h e a t Stepan TAB-2, S i l i c o n e DC200, and Avocado O i l t o 165-170F w i t h m i x i n g . When m e l t e d , add t o f i r s t f i v e i n g r e d i e n t s . M i x t h o r o u g h l y . Cool t o llOF, t h e n add t h e r e m a i n i n g i n g r e d i e n t s (Maprosy l 30, H y d r o l y z e d c o r n p r o t e i n , p r e s e r v a t i v e , dye, and f r a g r a n c e ) w i t h m i x i n g .

A d j u s t pH t o 5.0-6.2 w i t h 50% c i t r i c a c i d . A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e .

Pearlescent Body Wash

D . I. Water B i o-Terge AS-40 Kessco EGMS N i n o l 55-LL S t e o l CS-330 Kessco PEG 6000DS P r e s e r v a t i v e , Dye, Fragrance C i t r i c A c i d (50%) Sodium C h l o r i d e

% by Wei a h t Q.S. t o 100.0

37 a 50 1 . oo 4 .00

28.50 1 . o o Q.S. Q.S. Q.S.

M i x i n g Procedure :

w i t h m i x i n g . Keep t e m p e r a t u r e c o n s t a n t f o r one h a l f h o u r . W i t h m i x i n g , c o o l t o llOF, add p r e s e r v a t i v e , f r a g r a n c e and dye.

Combine f i r s t s i x i n g r e d i e n t s i n a c o n t a i n e r and h e a t t o 165F

A d j u s t pH t o 6.0-6.5 w i t h 50% c i t r i c a c i d . A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e .

SOURCE: Stepan 60.: Suggested F o r m u l a t i o n s


Pearlescent Shower Gel

Phase : A A A A A A A B B

I n n r e d i e n t i D e i o n i z e d Water Sodium L a u r y l S u l f a t e Ammoni um L a u r e t h S u l f a t e Cocamid DEA G l y c o l S t e a r a t e P r e s e r v a t i v e O i l s o f A loha Kukui Nut O i l Sodium C h l o r i d e Perfume

% by W t 65.50 2 0 . 0 0

8 . 0 0 5 .00 1 . 5 0 QS

0 .50 1 . o o 0 .25

M a n u f a c t u r i n g P rocedure : Phase A : Combine a l l i n g r e d i e n t s excep t p r e s e r v a t i v e and per fume a t 60C Cool t o 40C. Phase B . Add p r e s e r v a t i v e and pe r fume. Package.

Here t h e f u n c t i o n o f t h e Kukui Nut O i l i s t o r e p l e n i s h t h e o i l s l o s t on t h e h a i r so t h a t i t does n o t g e t o v e r l y d r y . U s i n g t o o much O i l wou ld c u t down on foaming .

After Bath Talc

Phase: I n n r e d i e n t : A T a l c B Perfume O i l E3 PPG-20 M e t h y l Glucose E t h e r B O i I s o f A l o h a Macadami a Nut O i 1

% bv W t 92 .50

5 .00 1 . 5 0 1 . o o

M a n u f a c t u r i n g P rocedure : Combine Phase B and when u n i f o r m b l e n d i n t o t a l c .

Here t h e O i l s o f A loha Macadamia Nut O i l h e l p s t h e t a l c sp read and c u t s down on t h e d r y f e e l i n g o f t h e s k i n . Leaves a n i c e smooth f e e l .

SOURCE : O i 1 s o f A 1 oha : Suggested Formul a t i ons

Spreading Bath Oil

__-___ Formula: Ado1 66 C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) I s o p r o p y l M y r i s t a t e A r o s u r f 66-PE 12 F r a g r a n c e

Procedure :

SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n M i x c o l d i n o r d e r l i s t e d .

56 by Weight 7 . 0 0

45.00 45 .00

1 .oo 2 . 0 0


Pearlized Shower Gel

A p e a r l i z e d body shampoo w i t h P a t i o n i c I S L f o r m o i s t u r e , R i t a t a i n e f o r m i l d n e s s , and P o l y q u t a 400 f o r s k i n c o n d i t i o n i n g .

I n g r e d i e n t s : 1 . Sodium C14-16 O l e f i n S u l f o n a t e 2 . P r o p y l e n e G l y c o l 3 . R i t a EGMS ( G l y c o l S t e a r a t e ) 4 . R i t a EGDS ( G l y c o l D i s t e a r a t e ) 5 . P a t i o n i c I S L (Sodium I s o s t e a t o y l L a c t y l a t e ) 6 . R i t a t a i ne (Cocami d o p r o p y l B e t a i ne) 7 . R i t a m i d e C (Cocamide DEA) 8 , Pol y q u t a 400 ( P o l y q u a t e r n i um-1 0 ) 9 . R i t a l o e 200M ( A l o e Vera G e l ) l O . D i s t i l l e d / D e i o n i z e d Water 11 . G1 y d a n t

%w/w 37.50

5 . 0 0 2 . 0 0 2 . 0 0 3 . 0 0 5 .00 3 . 0 0 1 . o o 0 .50

40 .80 0 . 2 0


and h e a t t o 70C. Add i t e m s 3-7 and m i x u n t i l u n i f o r m . A l l o w t o c o o l . Add i tem 11.

D i s s o l v e i t e m s 8 and 9 i n i t e m 10 . Combine w i t h i t e m s 1 and 2

R e f . No. 121-145

Shower Gel

A shower g e l c o n t a i n i n g P o l y q u t a 400 f o r v i s c o s i t y and c o n d i t i o n i n g .

1 . 2 . 3 . 4 . 5 . 6 . 7 . 8 .

I n g r e d i e n t s : D i s t i l l e d / D e i o n i z e d Water Sodi um L a l r y l s u l f a t e Ammoni um L a u r y l S u l f a t e Cocamidopropyl B e t a i ne Laurami de DEA P o l y q u t a 400 ( P o l y q u a t e r n i u m - 1 0 ) C i t r i c A c i d 50% G1 y d a n t

%w/w 42 .60 2 5 . 0 0 25.00

3 . 0 0 3 . 0 0 1 . o o 0 . 2 0 0 .20


Add i t e m s 2-5 w h i l e s t i r r i n g . A l l o w t o c o o l . Add i t e m s 7 -8 . Heat w a t e r t o 70C and add P o l y q u t a 400. M i x u n t i l d i s s o l v e d .

R e f . No. 121-108A



Premium Foam Bath

I n g r e d i e n t s : Cal B1 end C1 e a r F rag rance , Dye, P r e s e r v a t i v e Sodium C h l o r i d e Water

%Wt. 25 .00

Q . S . Q . S .

75 .00

Comments About t h i s Formula: B l e n d i n g P rocedure :

Wi th smooth a g i t a t i o n , s l o w l y b l e n d C a l B l e n d C l e a r i n t o w a t e r and m i x u n t i l u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 1 ,000-3 ,000 cps w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e as needed.


Cocamido p r o p y l B e t a i n e , F rag rance , P r e s e r v a t i v e , C i t r i c Acid, Dye(s ) I

Water, Sodium L a u r e t h S u l f a t e , Sodium C h l o r i d e , Cocamide DEA,

F o r m u l a t i o n #BUB-006-01

Bath Body Wash

I n g r e d i e n t s ; Cal foam ES-303 Sodi um Chl o r i de Water Cal t a i ne C-35 Calamide C Decyl Po l y g l ucose

F o r m u l a t i o n #GEL-002-01

SOURCE: P i l o t Chemical Co,: F o r m u l a r y

O/oWt. 60.10

1 . 1 0 5 . 3 0 5 . 0 0 8 . 8 0

19 .70


Rona/Shampoo/Shower Gel

Use o f t i t a n a t e d m ica p e a r l p i g m e n t s i n shampoo f o r m u l a t i o n s c r e a t e s i r i d e s c e n t e f f e c t s w h i c h canno t be a c h i e v e d w i t h conven- t i ona l s t e a r a t e p e a r l i ng a g e n t s . Rona ' s T i m i r o n Super C o l o r s , wh ich d e r i v e t h e i r e f f e c t f r o m l i g h t i n t e r f e r e n c e , r e f l e c t s i n g l e c o l o r s a c r o s s t h e v i s i b l e spec t rum. T i m i r o n Super G o l d produces a g o l d l u s t e r , T i m i r o n Super Red a r e d r e f l e c t a n c e , and so on . Comb ina t ions o f t h e Super C o l o r s and w a t e r - s o l u b l e dyes w i 11 r e s u l t i n u n i q u e " t w o - c o l o r " e f f e c t s , whose appearance v a r i e s w i t h t h e a n g l e o f v i e w i n g .

Rona has deve loped a system f o r suspend ing m ica p igmen ts i n d e t e r g e n t f o r m u l a t i o n s . An i n c r e a s e i n v i s c o s i t y a l o n e w i 11 n o t p r e v e n t s e t t l i n g ; a t h i x o t r o p i c g e l i s needed. The c o m b i n a t i o n o f Veegum HV (Mg A1 S i l i c a t e ) and K l u c e l G ( h y d r o x y p r o p y l - c e l l u l o s e ) y i e l d s a g e l n e t w o r k t h a t i s c o m p a t i b l e w i t h many d e t e r g e n t systems: t h e Veegum p r o v i d e s t h e suspens ion p r o p e r - t i e s , w h i l e t h e K l u c e l a c t s as a p r o t e c t i v e c o l l o i d t o p r e v e n t a g g l o m e r a t i o n o f t h e Veegum.

The d e t e r g e n t systems c o n t a i n i n g t h e Veegum/Klucel c o m b i n a t i o n can be manu fac tu red v i a c o l d p r o c e s s . The p r e - h o m o g e n i z a t i o n s t e p t o s w e l l t h e Veegum can be a c c e l e r a t e d w i t h h e a t . Because Veegum i s s e n s i t i v e t o s a l t s , l a c k o f a g g l o m e r a t i o n o f t h e Veegum w i t h t h e d e s i r e d d e t e r g e n t l e v e l and s a l t c o n t e n t s h o u l d be i n s u r e d b e f o r e p r o c e e d i n g w i t h f o r m u l a t i o n .

Pearlized Bath Salts

Phase # : 1 B a t h C r y s t a l s 1 P e a r l p igmen t ( e . 9 . C o l o r o n a Magenta)

2 L u v i s k o l VA641 2 I s o p r o p a n o l 2 F rag rance

Wt% 99 .00

1 - 0 0

0 .40 3 .60

9 , s .

Procedure : Combine phase 1 w i t h g e n t l e t u m b l i n g a g i t a t i o n . Combine phase

2 . When homogenoeus, s p r a y o n t o phase 1 w i t h c o n t i n u o u s t u m b l i n g a g i t a t i o n . Evapora te s o l v e n t v i a vacuum o r t r a y d r y i ng .

SOURCE: Rona/EM I n d u s t r i e s , I n c . : F o r m u l a t i o n SD123


Shebu Shower Gelee

A b a t h g e l e e w i t h a smooth u n i q u e f e e l f r o m P a t i o n i c I S L and Shebu i s a s k i n c o n d i t i o n e r .

I n g r e d i e n t s : 1 . Sodium L a u r e t h S u l f a t e (ES-3) 2 . R i t a m i d e C (Cocamide DEA) 3 . Shebu WS (PEG-50 Shea B u t t e r ) 4 . P a t i o n i c I S L (Sodium I s o s t e a r o y l L a c t y l a t e ) 5 . G l y d a n t P l u s 6 . D i s t i l l e d / D e i o n i z e d Water 7 . F r a g r a n c e 8 . R i t a p e g 150 DS (PEG-150 D i s t e a r a t e )

%w/w 53 .00

4.00 3 .00 3 . 0 0 0.20

3 6 . 2 0 0 . 1 0 0 . 5 0

Compounding P rocedure : Heat i n g r e d i e n t s 1-6 t o 65C w i t h a g i t a t i o n . Cool t o 43C and

add p e r f u m e . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e and pH w i t h l a c t i c a c i d .

R e f . No. 121-80A

Shebu Shower Gelee

A b a t h g e l e e w i t h a smooth u n i q u e f e e l . Shebu i s a s k i n c o n d i t i o n e r . I n g r e d i e n t s : 1 I Sodium L a u r e t h S u l f a t e (ES-3) 2 . R i t a m i d e C (Cocamide DEA) 3 . Shebu WS (PEG-50 Shea B u t t e r ) 4 . G l y d a n t P l u s 5 . D i s t i 1 l e d / D e i o n i zed Water 6 . F r a g r a n c e 7 . R i t a p e g 150 O S (PEG-150 D i s t e a r a t e )

w/w 53.00

4 . 0 0 3 .00 0 . 2 0

39 .20 0 . 1 0 0 . 5 0

Compounding P rocedure : Heat i n g r e d i e n t s 1 -6 t o 65C w i t h a g i t a t i o n . Cool t o 43C and

add pe r fume. A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e and pH w i t h l a c t i c a c i d .

R e f . No. 121-808

SOURCE: R . I . T . A . Corp. : Suggested F o r m u l a t i o n s


Shower Gel with Mbaruti Oil

Stage M a t e r i a l : Stage A : 1 Water; Pure 2 EDTA, D isod ium S a l t 3 Germaben 11-E 4 Sodium L a u r e t h S u l f a t e (SLES) 5 Gafquat 734 6 M b a r u t i O i l (Mexican Poppy O i l ) 7 F rag rance

Stage B: 8 D-Panthenol 75% 9 Cocamide CDE 10 Empigen BB

Stage D: 11 Tego P e a r l S33 12 Phosphor i c A c i d 13 C . S . D&C Y e l l o w No. 6; 1?6 S o l n 14 C . S . FD&C B l u e No. 1; 1% S o l n 1 5 Sodium C h l o r i d e ( s a l t )

Q u a n t i t y

52,2459 0.2009 0.7509

37. OOOg 0 .2009 0.1009 0.3009

0.2009 2. ooog 1 .ooog

3 . OOOg 0.0459 0.1409 0.7009 2 ,7509


a f t e r each a d d i t i o n .

match b e f o r e f i n a l l y a d j u s t i n g t h e v i s c o s i t y by a d d i n g Sodium C h l o r i d e .

Me te r o u t t h e w a t e r and add each i t e m i n t u r n , m i x i n g w e l l

A d j u s t t h e pH w i t h p h o s p h o r i c ( o r C i t r i c ) a c i d and c o l o u r

P r o j e c t J W 2422/Formula R e f . 936* 1

Shower Gel

S tage M a t e r i a1 : H . E . Ginseng Pre-Mix 1 : 1 F rag rance 2 Empigen BB 3 I r g a s a n DP300 Stage A : 4 Water; Pure 5 Sodium L a u r e t h S u l f a t e (SLES) S tage B: 6 Emp i lan E 2502 7 C i t r i c A c i d BP 8 Sodium C h l o r i d e ( s a l t ) 9 H . E . Chamomile 10 C o l o u r s as r e q u i r e d

M i x i n g I n s t r u c t i o n s : Make i n o r d e r .

SOURCE: A&E Connock: Suggested F o r m u l a t i o n s P r o j e c t JW 0263/Formula R e f . : 782*0

____. Quan t i ty 0 . ooog

0.5009 5 . OOOg 0.1009

44,5509 45. ooog

1.2009 0.2509 2 .2009 1 .ooog 0.2009


Shower Gel with Softigen 767

I n g r e d i e n t s : Weight% A . S o f t i g e n 767 (PEG-6 C a p r y l i c / C a p r i c G l y c e r i d e s ) 5 . 0 0

M a r l i n a t 242/28 (Sodium L a u r e t h S u l f a t e ) 38.00 Ampholy t JB 130/K (Cocamidopropyl B e t a i n e ) 10.00 E l f a c o s GT 282 S (Hydrogenated T a l l o w e t h - 6 0

M y r i s t y 1 G l y c o l ) 6 .00 C o l o r P r e s e r v a t i v e Water , up t o

q . s . q . s .

100.00

F rag rance q . s .

P r e p a r a t i o n :

about 60 degrees C, and s t i r r e d d u r i n g c o o l i n g t o about 30 degrees C . The perfume i s t h e n added.

A l l t h e m a t e r i a l s i n ( A ) a r e mixed t o g e t h e r , hea ted up t o

Formul a t i on 5 . 4 5

Shower Shampoo

I n n r e d i e n t s : Weight%

Arnpholyt JB 130K (Cocamidopropyl B e t a i n e ) 13.00 A) M a r l i n a t 242/28 (Sod i um L a u r e t h S u l f a t e ) 41 . o o

S o f t i g e n 767 (PEG-6 C a p r y l i c / C a p r i c G l y c e r i d e s ) 2 . 0 0 Dehyquar t LT ( L a u r t r i m o n i u m C h l o r i d e ) 1 . so Pan theno l 1 . o o P r e s e r v a t i v e q . s . Sodium C h l o r i d e 1 . 0 0 Water up t o 100.00

B) F rag rance L imobai n A . 11 6.830 0 . 5 0


( 6 ) i s added a t abou t 35 degrees C . ( A ) i s m ixed t o g e t h e r and m e l t e d a t about 50 degrees C .

F o r m u l a t i o n 5 . 4 T

SOURCE: Huls Amer ica I n c . : Suggested F o r m u l a t i o n s


Skin Conditioning Bath Gelee with Ritavena 5

I n n r e d i e n t s : %w/w P a r t A : 1 . D i s t i l l e d Water (1OOC) 10 .00 2 . R i t a v e n a 5 2 . 0 0 P a r t B: 3 . Sodium L a u r e t h S u l f a t e 53 .00 4. D i s t i l l e d Water 21 .15 5 . Monamid 150 ADD 4 .00 6 . R i tawax 15 3 . 0 0 7 . P a t i o n i c I S L 3 .00 8. R i t a p e g 150 DS 0 . 5 0 9 . Me thy lpa raben 0 . 1 5 P a r t C: 10 .F rag rance 1 . o o

12.Sodium C h l o r i d e ( 2 5 % S o l u t i o n ) +-1 . o o

Compoundi ng P rocedure : Heat P a r t B t o 165F w i t h m i x i n g . Premix P a r t A i n a b l e n d e r

f o r 2 m i n u t e s . Add t o P a r t B. M i x u n t i l u n i f o r m . Cool t o 120F. Add P a r t C . A d j u s t pH t o 6 . 0 - 6 . 5 u s i n g P a t l a c LA (44% S o l u t i o n ) . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e (25% S o l u t i o n ) . SOURCE: R . 1 , T . A . C o r p . : R i t a v e n a 5 : F o r m u l a t i o n 111-203

11.Kathon CG 0 . 5 0

1 3 . P a t l a c LA (44% S o l u t i o n ) + - O n 70

Dispersible Bath Oil

Formul a : C r o v o l PK-40 P r o c e t y l 10

C a r n a t i o n M i n e r a l O i 1 F rag rance Procedure :

A1 coho1 SD-40

S t r a i g h t b l e n d a1 1 i n g r e d i e n t s u n t i 1 c l e a r .

Wt% 9 . 0 0

16 .00 10.00 64.00

q . s .

Floating Bath-Oil Bar

Formula: Wt% W i t c o n o l APM 69 .0 C a r n a t i o n M i n e r a l O i 1 1 0 . 0 P r o p y l ene G1 y c o l 1 0 . 0 Sodium S t e a r a t e ( W i t c o ) 8 . 0 Water 3 . 0 C o l o r , Perfume q . s . p r o c e d u r e :

m i n e r a l o i l , p r o p y l e n e g l y c o l and w a t e r . Heat t o 80 t o 85C. S t i r u n t i l c l e a r . Cool w i t h s t i r r i n g t o 77C and add c o l o r and pe r fume. Pour i n t o molds a t 73C.

SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n s

D i s p e r s e sodium s t e a r a t e C-1 i n W i t c o n o l APM. Add C a r n a t i o n


Washing LotionWith a bacteriostatic effect, clear, 9.9% active ingredient

Reci pe : A O c t o p i r o x B Genapol AMG C F rag rance

Glucamate DOE 120 D y e s t u f f sol u t i on P r e s e r v a t i v e

D A l l a n t o i n E Water F Genagen CAB

Procedure : 1 D i s s o l v e A i n 6 . 2 S t i r t h e components o f C one a f t e r a n o t h e r i n t o 1 . 3 D i s s o l v e D i n E w h i l e h e a t i n g s l i g h t l y . 4 A d d 3 t o 1 . 5 I f necessa ry a d j u s t t h e pH. 6 A d j u s t t h e v i s c o s i t y w i t h F.

Formula A II/4022

Washing Lotion Clear, 10.5% active ingredient

Rec ipe : A Hostapon KCG 6 F rag rance C Water

Glucamate DOE 120 Magnesium c h l o r i d e D y e s t u f f s o l u t i o n P r e s e r v a t i v e Genagen CAB

Procedure : 1 D i s s o l v e B i n A . 2 S t i r t h e components o f C one a f t e r a n o t h e r i n t o 1 . 3 I f necessa ry a d j u s t t h e p H .

Fo rmu la A II/4021

SOURCE: Hoechs t : Guide Rec ipes f o r t h e Cosmet ic I n d u s t r y

Wt% 0 .20

25.00 0 . 3 0 1 . o o

q . s . q . s . 0.20

63.30 10.00

W O

3 0 . 0 0 0 . 3 0

55.20 3 . 0 0 1 . 5 0

q . s . q . s .

10.00


2 in 1 Shower Gel and Body Lotion24.5% active ingredient

Reci pe : A Emulsogen LP

Genapol L-3 C e t i o l HE Soybean o i l I s o p r o p y l p a l m i t a t e

Wt% 2 . 0 0 3 . 0 0 2 . 0 0 3 . 0 0 3 . 0 0

B P r i f a c 2942 4.00

C Hostapon S C I Genapol LRO l i q u i d Genapol AMG F rag rance D y e s t u f f s o l u t i on P r e s e r v a t i v e Genagen CAB

D Polymer JR 400 A 1 1 a n t o i n

2 . 5 0 25 .00 1 5 . 0 0

1 . o o q . s . q . s .

6 .00

0.50 0.30

E Water 3 2 . 7 0

Procedure : 1 . D i s s o l v e B i n A w h i l e h e a t i n g g e n t l y . 2 . S t i r t h e components o f C i n s u c c e s s i o n i n t o 1, wh ich s h o u l d

s t i l l be warm. 3 . D i s s o l v e t h e components o f D i n E w h i l e h e a t i n g g e n t l y . 4 . S t i r 3 i n t o 2 . 5 . Homogenize.

Formula A I / 8 0 6 5

Creamy Bath Oil Clear, low viscosity

Rec ipe : A Hos tapha t K L 340 N

Emulsogen LP M i n e r a l o i 1, h i g h v i s c o s i t y Soybean o i l I s o p r o p y l p a l m i t a t e F rag rance D y e s t u f f s o l u t i on

2 . 0 0 2 . 0 0

5 3 . 0 0 10.00 30.00

3 . 0 0 q . s .

P rocedure :

t e m p e r a t u r e . M i x t o g e t h e r a l l t h e components i n any sequence a t room

Formula A X V / 1 0 1 0

SOURCE: Hoechs t : Guide Recipes f o r t h e Cosmet ic I n d u s t r y

Section IV Beauty Aids

42

Beauty Aids 43

Aloe Vera Cream Scrub

F-0.cELLi~a.L y c b y \ V e i q h t A : Dei o n i z e d Water 6 5 . 9 5 A l o e Vera Gel 1 .00 0 : P r o p y l e n e Gl y c o i 2 . 0 0 M e t h y l p a r a b e r i 0 . 2 0 E t h y l p a r a b e n 0. i 5 C : G l y c e r y l S t e a r a t e S E 5.00 C a r n a t i o n Mi n e r a i Oi 1 ( W i t c o ) 5.00 S a f f 1 ower O i 1 i .00 S e s a m e O i l 1 . 0 0 S q u a l a n e 1 . o n

P a l m i t a t e ( W i c k h e n ) 1 . n o S t e a r i c A c i d 2 . 5 0 C e t y l A 1 c o h o 1 0 . 5 0 M e t h o c e l 4 0 - i o 0 0 . 5 0 n : Dei o n i z e d W a t e r 1 .00 T r i e t h a n o l ami n e 1 .00 E : C o l o r q . s F : P e r f u m e O i l 0 . 1 0 G: D e i o n i z e d Water i . o o Dowici i 2 0 0 A n t i m i c r o b i a l 0 . 1 0 H : Po l y e t . h y l e n e 9 A ?0.00

D i o c t y l A d i p a t e ( a n d ) O c t y l S t e a r a t e ( a n d ) O c t y l

Procedure :

t o 8 0 C . I n s e p a r a t e v e s s e l , p r e p a r e B b y h e a t i n g p r o p y l e n e g l y c o l ; a d d p a r a b e n s a n d when d i s s o i v e d a d d t o A . Combine w i t h b a t c h a n d m j x f a r 5 r n i n s . Add D a n d b e g i n t o c o o l . Add E , t h e n F w h e n b a t c h i s b e l o w 45C. Add G a n d s p r i n k l e : n ti.

Melt. water i n t o v e s s e l , a d d a l o e v e r a , mix a n d b e g i n h e a t i n g

Moisture Stick Base

_ _ Formul i: : 61 a n a o l M i n e r a l 01 1 [ W i t c o ) Rosswax 26-1 1 5 2 Rosswax 7 5- 1 i 0 2 Rosswax 1 8 2 4 Ameriate P

Yo by Vje ign t 50 2 8

2 1 0 10

P rocedure :

m i x e d t h o r o u g h l y , p o u r i n t o m o l d s . SOURCE : W i t c o Corp I : Suggested Formul a t i ons

Melt i n g r e d i e n t s i n a k e t t l e a t 1 7 0 F u n d e r a g i t a t i o n . When


Aloe Vera Moisturizer

E x c e l l e n t f e e l , c o n t a i n i n g R i t a l o e f o r s k i n c o n d i t i o n i n g and C l a r i s k i n f o r p r e v e n t i n g and a t t e n u a t i n g age s p o t s . I n g r e d i e n t s : %w/w 1 . R i t a c h o l ( M i n e r a l O i l and L a n o l i n A l c o h o l ) 2 .00

3 . M i n e r a l O i l ( B r i t o l 9NF) 8.00 4 . R i t a C e t e a r y l A l c o h o l 5 0 / 5 0 ( C e t e a r y l A l c o h o l ) 2 . 0 0

6 . R i t a s o l ( I s o p r o p y l L a n o l a t e ) 1 . o o 7 . R i t a c e t i ( C e t y l E s t e r s ) 1 .oo 8. R i t a GMS ( G l y c e r y l S t e a r a t e ) 4 .00 9 . T r i e t h a n o l ami ne 50% 1 . o o 1 0 . G1 y c e r i ne 2 . 0 0 11 , P r o p y l ene G1 y c o l 2 .00 12 .Me thy l Pa rahydroxy Benzoate 0 . 3 0 1 3 . P r o p y l Parahydroxy Benzoate 0 . 1 0 1 4 . R i t a l o e 200M ( A l o e Vera Gel ) 1 . o o 15 . S o r b i t o 1 70% 2.00 16 , C l a r i s k i n (Yeas t E x t r a c t ) 5 . 0 0 17.Per fume q . s . 18 , D i s t i 11 ed /De ion i zed Water 64.10 Compounding P rocedure :

M ix i t e m s 1-8 and h e a t t o 8OC. Combine i t e m s 9-15 and 18, and h e a t t o 80C. S l o w l y add w a t e r phase t o o i l phase w i t h a g i t a t i o n . Cool w i t h g e n t l e a g i t a t i o n t o 45C. Add i t e m 16-17 and c o o l t o 4 0 C .

2 . L a n o l i n USP X-Tra Deo 0 .50

5 . S t e a r i c Ac id 4 . 0 0

R e f . No. 122-838

Liposome Gel

A s o o t h i n g g e l comb in ing t h e b e n e f i t s o f v i t a m i n s A, C and E i n a s y n e r g i s t i c and e f f e c t i v e l i posome system w i t h h y d r o l y z e d soy p r o t e i n , I n b r e d i e n t s : 1 . D i s t i 11 ed/Dei o n i zed Water

56wJw_ 87.40

2 . A c r i t a m e r 940 (Carbomer 940) 0 . 5 0 3 . Xanthan Gum 0 . 1 0 4 . 1 , 3 B u t y l e n e G l y c o l 5 . 0 0 5 . R i t a s i 1 190 (D ime th i cone C o p o l y o l ) 0 . 1 0 6 . Shebu WS (Shea B u t t e r ) 1 . o o

8. Promois WS ( H y d r o l y z e d Soy P r o t e i n ) 0 .20 9 . G l y d a n t 0 . 2 0 1 0 . F r a g r a n c e 0 .10 11 . Rovi some ACE ( V i t am i n B l e n d ) 5 . 0 0 Compounding P rocedure :

Add i t e m s 4,5 and 6 s e p a r a t e l y . Add TEA u n t i l b a t c h t h i c k e n s . Add i t e m s 8 ,9 ,10 and 11. The pH o f a g e l i s 5 . 5 .

7 . TEA @ 99% 0 . 4 0

D i s p e r s e i t e m 2 i n w a t e r . Add i t e m 3 and m i x u n t i l d i s s o l v e d .

R e f . No. 121-95

SOURCE: R.I.T,A. C o r p , : Suggested F o r m u l a t i o n s

Beauty Aids 45

Anti-Wrinkle Cream

I n g r e d i e n t s : 1 . D i s t i 11 ed/Dei o n i zed Water 2 . A c r i t a m e r 940 (Carbomer 940) 3 . Xanthan Gum 4. 1 ,3 B u t y l e n e G l y c o l 5 I R i t a s i 1 190 ( D i me th i cone Copol yo1 ) 6 . Shebu WS (Shebu B u t t e r ) 7 . TEA 13 99% 8 . Promois ECP ( C o l l a g e n ) 9 . G l y d a n t 1 0 , F r a g r a n c e 11 .Tens i ne (Wheat P r o t e i n)

%w/w 87 .40

0 . 5 0 0 .10 5.00 0 .10 1 . o o 0 . 4 0 0 . 2 0 0 .20 0 . 1 0 5 .00


Add i t e m s 4 , 5 and 6 s e p a r a t e l y . Add TEA u n t i l b a t c h t h i c k e n s . Add i t e m s 8,9,10 and 11. The pH o f a g e l i s 5 . 5 .


R e f . No. 122-103A

Facial Firming Gel

An o i l - f r e e f o r m u l a t i o n t h a t r e h y d r a t e s t h e s k i n and p r o t e c t s a g a i n s t s k i n r e l a x a t i o n and w r i n k l e s w i t h v i t a l p r o t e i n s .

I n g r e d i e n t s : 1 . D i s t i 11 ed/Dei o n i zed Water 2 . A c r i t a m e r 940 (Carbomer) 3 I D i s t i 11 ed/Dei o n i zed Water 4 . P r o p y l e n e G l y c o l 5 . D isod ium EDTA 6. T r i e t h a n o l a m i n e (99%) 7 . Tens ine (Wheat P r o t e i n ) 8 . R e d u c t i n e (Oat P r o t e i n ) 9 . B ioCare SA (Albumen and H y a l u r i c A c i d and

10. G1 ydan t 1 1 , B l u e Dye

D e x t r a n S u l f a t e )

aw/w 60,50

0 .80 27.90

5 .00 0 . 2 0

5 .00 1 . o o

9,5.

0 . 1 0 0 .50 9,5.

Compoundi ng P rocedure : S l o w l y d i s p e r s e A c r i t a m e r i n t o w a t e r w i t h r a p i d a g i t a t i o n . M ix

u n t i l w e l l d i s p e r s e d . Add i t e m s 3-5. W i t h s l o w m i x i n g add i t e m 6 . Add i t e m s 7-10 and m i x .

R e f . No. 122-95

SOURCE: R , I . T . A . C o r p . : Suggested F o r m u l a t i o n s


Biorepair Skin Gel

T h i s w h i t e g e l w i t h e m o l l i e n t s has a good p e n e t r a t i o n w i t h a n o n - o i l y a f t e r f e e l . Hyasol-BT d e l i v e r s m o i s t u r e t o t h e s k i n . Repai r f u n c t i o n i s p r o v i d e d b y F i t o b r o s i de ( 1 i p i d b a r r i e r ) and Immucel l ( a c t i v a t i o n o f c e l l r e s p i r a t i o n ) I

Item I n q r e d i e n t s : Weight% 1 A ) D e i o n i z e d Water 70.40 2 G l y c e r i n 5 . 0 0 3 Hamamelis E x t r a c t 5 . 0 0 4 D-Panthenol 50P 1 .oo 5 Phenoni p 0 . 3 0 6 Carbopol 1342 0 .60 7 N a t r o s o l 250 HR 0 . 3 0 8 L u v i s k o l K90 0 . 1 0 9 B) Sodium H y d r o x i d e 18% S o l u t i o n 2 .70

10 C ) I s o p r o p y l M y r i s t a t e 3 . 0 0 11 B i s a b o l o l 0 . 5 0 12 A n t a r o x CO 630 2 . 0 0 13 D) F i t o b r o s i de 3 .00 14 Immucel l 3 .00 15 Hyasol -BT 3 . 0 0 16 F rag rance 0 . 1 0

P rocedure : D i s s o l v e i t e m s 2-8 i n w a t e r ( 1 ) . N e u t r a l i z e w i t h phase € 3 ) . M i x phase C and i n c o r p o r a t e i n t h e r e s u l t i n g g e l I A w h i t e g e l i s o b t a i n e d . F i n a l l y add i t e m s 13-16 one a f t e r a n o t h e r . A p p l i c a t i o n No. D 009 .A /04 .93

Anti-Aging Leave On Mask

T h i s r e f r e s h i n g q u i c k mask a c c e l e r a t e s s k i n c e l l t u r n o v e r ( I m m u c e l l ) and s t r e n g t h e n s t h e weakened l i p i d b a r r i e r (Lac tomide )

I n g r e d i e n t s : Wei a h t % 1 A) D e i o n i z e d Water 76.90 2 G l y c e r i n 5 . 0 0 3 Phenoni p 0 . 3 0 4 I m i d a z o l i d i n y l Urea 0 . 2 0 5 U l t r e z 10 0 . 3 0 6 T r i e t h a n o l ami ne 0 .30 7 A b i l B 8843 2 . 0 0 8 Amerchol L 101 5 . 0 0 9 Immuce l l 5 . 0 0

10 Lactomi de 5 . 0 0 P rocedure :

D i s s o l v e i t e m s 2-5 i n w a t e r ( 1 ) . N e u t r a l i z e w i t h T r i e t h a n o l a m i n e ( 6 ) t o pH 5 . 5 - 6 . 0 . F i n a l 111 i n c o r p o r a t e i terns 7-10 under s t i r r i ng one a f t e r a n o t h e r . A p p l i c a t i o n No. D 031 . C / O 1 - 9 6

SOURCE: Pentapharm L t d . : Suggested F o r m u l a t i o n s

Beauty Aids 47

Blusher

Syncrowax ERL-C Syncrowax HR-C Ceraphyl 368 M y r i t o l 318 Emerest 2452 Methy l Paraben P r o p y l Paraben Supra T a l c B i r o n ESQ M i c a M-RP C o l o r g r i n d - 50% 19-012 ( D & C Red #6 Ba Lake)

i n M y r i t o l 318

Wt% 1 2 . 1 0

1 .90 38 I 40

3 . 0 0 0 . 5 0 0 .20 0 .10

18 .55 15.00

8 . 2 5

2 . 0 0

M a n u f a c t u r i n g P rocedure : The c o l o r g r i n d was p r e p a r e d i n advance on a t h r e e r o l l e r

m i l l . Combine t h e waxes, g r i n d and o i l s . Heat t o 80-85C u n t i l homogeneous. Add t h e t a l c , m ica and BiOC1. A g i t a t e w i t h a h i g h speed m i x e r u n t i l no agg lomera tes r e m a i n . S t i r i n t h e p e a r l p igmen t w i t h moderate a g i t a t i o n . Pour a t 7 0 C .

F o r m u l a t i o n AN2-33-2

Starlight Body Freshener

Phase # : I n g r e d i e n t s : 1 Dei o n i zed w a t e r 1 G1 y c e r i ne 1 SD 40 A l c o h o l 1 T i m i r o n S t a r l i g h t C o l o r

Wei s h t % 31 - 5 5

5 . 0 0 20.00

0 . 1 0

2 1% Carbopol 941 s o l u t i o n 40 .00

3 T r i e t h a n o l ami ne 99% 3 D e i o n i zed w a t e r

4 S o l u l a n 98 4 F rag rance

0 . 6 0 2 .00

0 . 5 0 0 .25

5 C e r t i f i e d d y e ( s ) qs

Procedure :

add t h e r e m a i n i n g phases i n o r d e r . Combine phase #1 w i t h p r o p e l l e r a g i t a t i o n . When homogeneous,

F o r m u l a t i o n EM2-27

SOURCE: Rona/EM I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Body Emulsion, Type O/W, with MPC - Milk Peptide Complexand Calendula Oil CLR

I n a r e d i e n t s : a ) Eumulg in VL 75

L a n e t t e 0 Monomuls 60-35 C C e t i o l LC C e t i o l B C e t i o l PGL C a l e n d u l a O i l CLR Phenoni p

b ) Water , d i s t i l l e d Phenon i p Carbopol 980 G1 y c e r i n

c ) KOH, 20% s o l u t i o n d ) Water , d i s t i l l e d

N a 3 - C i t r a t e x 2H20 MPC-Mi 1 k P e p t i de Compl ex

M a n u f a c t u r e : a) M e l t and b r i n g t o a p p r o x . 70C; b ) Heat t o a p p r o x . 70C and s t i r i n t o a ) .

C o n t i n u e s t i r r i n g u n t i l c o o l e d t o a p p r o x . 50C; c ) S t i r i n . C o n t i n u e s t i r r i n g u n t i l c o o l e d t o a p p r o x . d ) S t i r i n .

Perfume, homogenize

Weight% 4 . 5 0 2 . 0 0 1 .oo 4 . 0 0 5 .00 1 . o o 3 .00 0 .30

65.85 0 .30 0 . 3 0 2 . 0 0 0 . 7 5 9 .38 0 . 1 2 0 . 5 0

30C;

Ceramide-Complex CLR (P)

Ceramide Complex CLR (P ) c o n t a i n s 2% l i p i d s i n l a m e l l a r , l i q u i d c r y s t a l l i n e f o r m . The p l a n t d e r i v e d l i p i d m i x t u r e c o n s i s t s o f a t l e a s t 10% s p h i n g o l i p i d s ( ce ramides , g l y c o c e r a m i d e s = c e r e b r o s i d e s ) .

Eye Gel with Ceramide Complex CLR (P)

I n q r e d i e n t s : Weight%

K e l t r o l , 1% aqueous s o l u t i o n 30 .00 Water , d i s t i l l e d 35 .70 Phenoni p 0 . 3 0 C e t i o l 3 600 4 . 0 0

b ) Ceramide Complex CLR (P) 1 0 . 0 0 M a n u f a c t u r e :

a ) H i s p a g e l 200 20 .00

M i x a ) a t room t e m p e r a t u r e i n t h e o r d e r g i v e n ; Add b ) t o a) w i t h slow s t i r r i n g . Per fume.

SOURCE: Chemisches L a b o r a t o r i u m D r . K u r t R i c h t e r GmbH: Suggested F o r m u l a t i o n s

Beauty Aids 49

Clear Facial Cleansing Gel

A c l e a r , m i l d f oaming f a c i a l c l e a n s e r s u i t a b l e f o r a t u b e o r pump packag ing . The Jordapon ACI-30 p r o v i d e s e x c e l l e n t foaming, g e n t l e c l e a n s i n g , and a s o f t , smooth a f t e r f e e l on t h e s k i n .

___ P a r t : I n q r e d i e n t ( T r a d e Name): _- W t % A Dei o n i zed Water 51 .40

H y d r o x y p r o p y l M e t h y l c e l l u l o s e (Me thoce l 40-100) 0 .20 T r i e t h a n o l a m i n e 0 . 0 5 Na4EDTA 0 . 1 0 C i t r i c A c i d , 50% 0 . 0 5 I m i d a z o l i d i n y l Urea (Germa l l 11 5 ) 0 . 1 5

B

C

Dei o n i zed Water TEA L a u r y l S u l f a t e ( S t e p a n o l WAT) Me thy l Paraben PEG-150 D i s t e a r a t e (Mapeg 6000DS)

20 I O 0 3 . 5 0 0 . 1 5 0 .50

Ammonium Cocoyl I s e t h i o n a t e ( Jo rdapon ACI-30) 16 .80 Cocamidopropyl H y d r o x y s u l t a i n e (Mafo CSB-50) 4 . 0 0 Soyami de DEA (Mazami de SS-10) 1 . 5 0 Cocami de DEA (Mazami de JT-128) 1 . 5 0

D F rag rance C i t r i c A c i d , 50%

0 . 1 0 Q. S

pH: 6 . 3 - 6 . 8 V i s c o s i t y : 18,900 cps ( B r o o k f i e l d #3 @ 3 rpm) Appearance: C1 e a r , v i scous ye1 l o w 1 i q u i d

P rocedure : D i s p e r s e t h e h y d r o x y p r o p y l m e t h y l c e l l u l o s e i n t h e p a r t A

w a t e r , s t i r r i n g f o r about t e n m i n u t e s . Add t h e Na4EDTA and t h e t r i e t h a n o l ami ne; c o n t i nue m i x i ng f o r abou t 20 m i n u t e s t o e n s u r e comp le te h y d r a t i o n . Add t h e r e m a i n i n g p a r t A i n g r e d i e n t s and c o n t i n u e m i x i n g a t room t e m p e r a t u r e . I n a s e p a r a t e v e s s e l , p r e m i x t h e p a r t B i n g r e d i e n t s , h e a t i n g t o 65C t o d i s s o l v e t h e Mapeg 6000DS. Add p a r t B t o p a r t A w i t h good a g i t a t i o n . Add t h e p a r t C i n g r e d i e n t s i n o r d e r , m i x i n g u n t i l c l e a r and u n i f o r m . Add t h e f r a g r a n c e and a d j u s t t h e pH.

SOURCE: PPG i n d u s t r i e s , I n c . : F o r m u l a t i o n K-103


Conditioning Skin Mousse

- Formula : A: Cel q u a t L-200 D i s t i l l e d Water P ropy lene G l y c o l T r i e t h a n o l a m i n e P r e s e r v a t i v e B : C a r n a t i o n M i n e r a l Oi 1 ( W i t c o ) A c e t u l an Amerchol L-101 Emerest 2407 C e t y l A1 coho1 S t e a r i c A c i d X X X Crodano l I P M C: F rag rance

YO b y WeighJ

0 . 5 0 8 9 . 1 0

2 .00 0 . 5 0

q . s .

2 .00 0 . 5 0 1 . 5 0 0 . 7 5 0 . 2 5 1 . 0 0 2 . 0 0

a . s .

Procedure : D i s s o l v e Ce lqua t L-200 i n w a t e r , add remai n i ng i n g r e d i e n t s

o f A w h i l e m i x i n g . Heat t o 7 5 C . Prepare B and h e a t t o 75C. When each i s u n i f o r m , add B t o A . C o o l . Add C when 35C. F i 1 1 .

Silky Blush

Formula : Pigment SF1 21 4 S i 1 i cone F1 u i d Orgaso l 2002 Crodamol PMP Wh i te Fonol i ne P e t r o l a t u m (Wi t c o ) C r o s i l k Powder (Croda) Magnesium S t e a r a t e - D ( W i t c o )

% -. b y Wei q h t 30 .00 27.00 2 5 . 0 0

7 . 0 0 5 . 6 0 5 . 0 0 0 . 4 0

P rocedure :

powders e v e n l y . Add Crodamol PMP and c o n t i n u e h i g h s h e a r . Add Wh i te F o n o l i n e P e t r o l a t u m and p r e s s i n t o s u i t a b l e mo ld . T h i s i s a s i l k y p ressed b l u s h t h a t can be smoothed on w i t h a b r u s h o r b y hand.

SOURCE: W i t c o Corp , : Suggested Formul a t i ons

B l e n d p igment powders and add SF1214. Use h i g h shear t o wet

Beauty Aids 51

Cooling Facial Balm

I n g r e d i e n t s : Weight% Phase A : P o l y g l y c e r y l - 3 M e t h y l g l u c o s e D i s t e a r a t e (Tego Care 450) 2 . 0 C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) 2 . 0 O c t y l P a l m i t a t e ( T e g o s o f t OP) 2 . 5 C e t e a r y l I sononanoa te ( T e g o s o f t C I ) 1 . o

Phase E : Propy lene G1 y c o l Water

Phase C: O c t y l S t e a r a t e ( T e g o s o f t OS) Carbomer ETD 2050 E thano l Cyc l omet h i cone

Phase D : Sodium H y d r o x i d e (10% s o l u t i o n )

Phase E : Fragrance ( s u i t a b l e f o r f a c i a l p r o d u c t ) P r e s e r v a t i ves

1 .8 7 2 . 6

3 . 5 0 . 2

1 0 . 0 4 . 0

0 . 4

Q.S. Q . S .

Procedure : 1 . Heat t h e i n g r e d i e n t s o f Phase A t o 80C. 2 . Heat t h e i n g r e d i e n t s o f Phase B t o 80C. 3 . Add A t o B o r B t o A w i t h o u t s t i r r i n g . 4 . S t i r . 5 . D i s p e r s e Carbomer i n t o t h e o i l / e s t e r add t o A / B . Homogenize. 6 . Cool t o 35-40C w i t h s t i r r i n g . 7 . Add E t h a n o l and Cyc lometh i cone . 8 . Add Phase D/E . S t i r . 9 . M ix u n t i l v i s c o s i t y i s c o r r e c t .

SOURCE: Go ldschmid t Chemical Corp , : Suggested F o r m u l a t i o n


Cream Eye Shadow

I n p r e d i e n t s : A : S t e a r i c Ac id

G1 y c e r y l S t e a r a t e C e t e a r y l A l c o h o l and Ce tea re th -20 (Promulgen D) Candel i 11 a Wax M y r i s t y 1 M y r i s t a t e D ime th i cone (DC 200 F l u i d , 350 c s t k ) P r o p y l p a r a b e n

8: D e i o n i z e d Water U1 t r a m a r i nes (C43-1810 Cosmet ic B1 ue) T i t a n i u m D i o x i d e (C47-5175 Cosmet ic W h i t e )

C: M i c a (and ) T i t a n i u m D i o x i d e ( T i m i c a P e a r l W h i t e )

D : D e i o n i z e d Water PVP (PVP K-60)

E : P r o p y l e n e G l y c o l Hydroxy P r o p y l M e t h y l C e l l u l o s e (Me thoce l 40-202) Veegum, Magnesi urn A1 umi num S i 1 i c a t e

F : D e i o n i z e d Water T r i e t h a n o l ami ne, 99% Phenoxyethanol (Dowanol EPh) EDTA (Versene 100) S i m e t h i c o n e ( A n t i f o a m AF Emu ls ion )

G : D e i o n i z e d Water Quatern ium-15 (Dow ic i 1 200 )

W t .%* 3 . 0 0 2 .oo 1 . o o 1 . o o 1 .oo 0 . 5 0 0 . 1 0

34.30 6 . 0 0 1 .50

5 .00

30 . O O 4 .00

5 . 0 0 0 .20 0 . 5 0

2 .00 1 . 2 0 0 . 5 0 0 .10 0 . 0 5

1 . o o 0 .05

P rocedure : Weigh t h e P a r t B and P a r t D w a t e r i n t o a b e a k e r . Add Veegum

and m ix f o r 20 m i n . u s i n g a homogenizer a t 5000 r p m . D i s p e r s e t h e Me thoce l i n P r o p y l e n e G l y c o l , add t o t h e b a t c h and mix f o r 10 m i n . a t 5000 rpm. Weigh and m i x t o g e t h e r P a r t F, add them t o t h e b a t c h and m i x f o r 5 m in . Add t h e r e m a i n i n g P a r t B and m ix f o r 5 m i n . Add t h e PVP and m i x 2 m i n . Heat t h e b a t c h t o 80C, m i x and h e a t P a r t A t o 80C. Add P a r t A t o t h e b a t c h and m i x f o r 10 m in . a t 5000 rpm. T r a n s f e r t h e b a t c h t o a p r o p e l l e r m i x e r and b e g i n c o o l i n g . A t 60C add P a r t C and c o n t i n u e c o o l i n g and m i x i n g s l o w l y . A t 45C m i x P a r t G i n g r e d i e n t s and add them t o t h e b a t c h . C o n t i n u e m i x i n g w h i l e c o o l i n g t o room t e m p e r a t u r e .

*As r e c e i v e d b a s i s

SOURCE: R . T . V a n d e r b i l t Co. , I n c . : Veegum Formula f r o m Dow Chemical Co.

Beauty Aids 53

Creamy Lipstick (Summer Mauve)

Formu 1 a : A: O z o k e r i t e Po l y e t h y l ene Wax Wh i te P r o t o p e t 1s P e t r o l a t u m (Vi1 t c o ) Mal ea ted Soybean O i 1 D i i s o p r o p y l Adi p a t e C12-15 A1 k y l L a c t a t e T r i d e c y l Neopentanoate M y r i s t y 1 L a c t a t e I s o c e t y l S t e a r o y l S t e a r a t e Hydrogen a t ed Po 1 y b u t e ri e I s o p r o p y l p a r a b e n ( a n d ) I s o b u t y l p a r a b e n ( a n d )

B : D&C Red # 7 Ca lc ium Lake T i t a n i um D i o x i d e I r o n Ox ide (Cosmet ic Red) I r o n Ox ide (Cosmet ic Y e l l o w ) C : M ica B i srnuth O x y c h l o r i d e M ica ( a n d ) B ismuth O x y c h l o r i d e (and) Carmine

~ _ _ _ ~ ~~

B u t y l paraben

?/o b y Weigh t

7 . 4 6 . 2

1 0 . 3 2 . 0 3 . 1 7 . 2 7 . 2

1 0 . 0 11 . o 6 . 2

0 . 4

1 . 2 6 . 8 0 . 5 0 . 5

5 . 0 5.0

1 0 . 0

Procedure :

Cool t o 8 0 C . Add C . M ix 30 rn jnu tes and f i 11 . Heat A t o 95C u n t i l c l e a r . Cool t o 85C. Add B. M i x 30 m i n u t e s .

Petrolatum Stick/Lip Balm

Formula : Wh i te P r o t o p e t 1 s P e t r o l a t u m (\Vi t c o ) Syncrowax HGLC Syncrowax ERLC

%-.!a .We i s h 2 3 5 . 0 1 2 . 0

3 . 0

Procedure : Combine t h e Wh i te P r o t o p e t 1s P e t r o l a t u m and t h e waxes. M i x

w h i l e h e a t i n g t o 8OC. Cool t o 65-706: and p o u r . C h i l l t h e molds t o 40C p r i o r t o p o u r i n g .

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s


Enriched Emollient Liquid Makeup

The c o m b i n a t i o n o f Veegum and C e l l u l o s e Gum i n t h i s f o r m u l a p r o v i d e s s y n e r g i s t i c r h e o l o g i c a l e f f e c t s i n c l u d i n g t h i c k e n i n g and s t a b i l i z a t i o n o f t h e emu ls ion and suspens ion o f t h e p igmen ts . The u n u s u a l l y h i g h c o n c e n t r a t i o n o f s e v e r a l e m o l l i e n t s p r o v i d e s an e n r i c h e d l i q u i d makeup t h a t spreads smoo th l y and e a s i l y and c o v e r s we1 1 w i t h o u t t a c k y a f t e r f e e l .

I n a r e d i e n t : A : Veegum, Magnesium Aluminum S i l i c a t e

C e l l u l o s e Gum (CMC-7MF) Dei o n i zed Water T r i e t h a n o l a m i n e , 99% G l y c e r e t h - 2 6 ( L i p o n i c EG-1) Me thy lpa raben

B : T i t a n i u m D i o x i d e T a l c I r o n Ox ides

C : I s o p r o p y l I s o s t e a r a t e M i n e r a l O i 1 (and ) Lano l i n A l c o h o l (Amerchol L-1 01 ) I s o p r o p y l P a l m i t a t e I s o p r o p y l M y r i s t a t e Hydrogenated Soy G l y c e r i d e (Myvero l 18-06) S t e a r i c A c i d D i o c t y l A d i p a t e (and ) O c t y l S t e a r a t e (and ) O c t y l

P a l m i t a t e (Wickeno l 161 ( 1 . 1 % by w t ) & Wickenol 163 ( 1 . 0 % by w t )

Vanseal CS , Cocoyl S a r c o s i ne L i t h i um S t e a r a t e P ropy lpa raben B u t y l paraben

W t .%* 0 .70 0 . 2 5

42.28 0 . 7 5

10 .50 0 . 3 0

10 .00 3 . 1 5 1 .97

10.00 6 .50 4 .00 2 .50 2 . 1 0 1 .60

2 . 1 0 1 . o o 0 .10 0 .10 0 . 1 0

Procedure :

a v a i l a b l e shear u n t i l smooth. S l o w l y m i x i n r e m a i n i n g P a r t A i n g r e d i e n t s . M ix P a r t B i n g r e d i e n t s t h o r o u g h l y i n t o A u n t i l u n i f o r m . M a i n t a i n t e m p e r a t u r e a t 70 t o 75C. Heat P a r t C t o 70 t o 75C and add t o P a r t s A+B. M i x w h i l e c o o l i n g .

Heat t h e w a t e r t o 70 t o 75C. Add t h e Veegum and m ix a t maximum


SOURCE: R.T.Vanderbilt Co., I n c . : Veegum F o r m u l a t i o n No. 433

Beauty Aids 55

Exfoliant Scrub

M a t e r i a1 : Water, Pure G l y c e r i n e BP L i g h t M i n e r a l O i l P o l y e t h y l e n e Spheres AEC I s o c e t y l S t e a r a t e GMS s /e, A c i d S t a b l e ESO Vo lpo cs20 AEC C e t y l P a l m i t a t e AEC Decyl O l e a t e Carbopol 940 T r i e t h a n o l ami ne 99% Phenoni p S u p e r h a r t o l an F rag rance

Foermul a R e f . : 1051 *O

Exfoliating Foot Scrub

M a t e r i a1 : Water; Pure Sodium L a u r e t h S u l f a t e (SLES) AEC Corn Cob Granu les Veegum Regul a r Cocami d o p r o p y l B e t a i ne Cocamide CDE E . O . Peppermint B r o n i d o x L/15 EDTA, D i sodium S a l t C.S. FD&C Y e l l o w No. 5; 1% S o l n E . O . Tea T r e e C.S. FD&C B l u e No. 1; 1% S o l n Myacide SP L a c t i c Acid, N a t u r a l

Formula R e f . : 1202*0

SOURCE: A&E Connock L t d . : S u g g e s t e d F o r m u l a t i o n s

%w/w 6 8 . 5 0 0

5 . 0 0 0 5 . 0 0 0 5 . 0 0 0 5 . 0 0 0 3 .000 3.000 2.000 1 . o o o 0 . 8 0 0 0 .500 0 . 5 0 0 0 I 500 0 . 2 0 0

%w/w 44.810 40.000

5 .000 4 .000 3.000 2.000 0 . 2 0 0 0 .200 0 .200 0 .170 0 . 1 5 0 0 .135 0 . 1 0 0 0.035


Exfoliant Scrub

Staae M a t e r i a l : Quan t i t v Oil Phase: 1 L i g h t M i n e r a l O i l 5 . OOOg 2 AEC I s o c e t y l S t e a r a t e 5 . OOOg 3 GMS s / e , A c i d S t a b l e ESO 3 . OOOg 4 Vo lpo cs20 3 . OOOg 5 AEC Decyl O l e a t e 1 .ooog 6 AEC C e t y l P a l m i t a t e 2 . ooog 7 S u p e r h a r t o l an 0.5009 Aqueous Phase: 8 Water , Pure 68.5009 9 G l y c e r i n e BP 5 . OOOg 10 Carbopol 940 0,8009 11 T r i e t h a n o l a m i n e 99% 0.5009 12 Phenonip 0.5009 Cool i ng C y c l e : 13 P o l y e t h y l e n e Spheres 5 . OOOg 14 F r a g r a n c e 0 * 2oog M i x i n g I n s t r u c t i o n s :

The O i l Phase i s added t o t h e Aqueous a t 70C w i t h m i x i n g . M i x i n g i s c o n t i n u e d w h i l e c o o l i n g , and t h e g e n t l y e x f o l i a t i n g P o l y e t h y l e n e Spheres added be low 40C. Do n o t homogenise o r use h i g h shear m i x i n g a f t e r t h e a d d i t i o n o f t h e P o l y e t h y l e n e Spheres.

The h i g h e s t e r c o n t e n t base w i l l s o f t e n s k i n and a s s i s t t h e g e n t l e e x f o l i a t i n g a c t i o n o f t h e P o l y e t h y l e n e Spheres. The spheres a r e a v a i l a b l e i n a v a r i e t y o f c o l o u r s making i t p o s s i b l e t o f o r m u l a t e v e r y i n t e r e s t i n g p r o d u c t s . SOURCE: A & E Connock L t d . : P r o j e c t JW 2461/Formula R e f . : 1051*0

Foaming Facial Cleanser

A r i c h p e a r l e s c e n t l o t i o n w i t h r a p i d f l a s h foaming and g e n t l e c l e a n s i n g , wh ich l e a v e s t h e s k i n s o f t and smooth. P a r t : I n g r e d i e n t ( T r a d e Name) :

A Dei o n i zed Water 3 8 . 7 P r o p y l e n e G l y c o l 1 0 . 0 Sodium I s e t h i o n a t e , 56% ( W i t c o n a t e N I S ) 9 . 0 TEA L a u r y l S u l f a t e ( S t e p a n o l WAT) 2 . 5 Cocamidopropyl Amine Ox ide (Mazox CAPA) 1 6 . 0

( Jo rdapon C I -75 ) 1 9 . 3

( B r a d p r i d e C h i p ) 2 . 5

B Sodium Cocoyl I s e t h i o n a t e (and ) S t e a r i c Ac id

Sodium T a l l o w a t e (and ) Sodium Cocoate

S t e a r i c A c i d ( H y s t r e n e 5016) 2 . 0 p H : 6 . 3 - 6 . 8 V i s c o s i t y : 2 . 4 x 10 6 c p s F i r m w h i t e p a s t e

P rocedure : B l e n d t h e p a r t A i n g r e d i e n t s i n t h e main v e s s e l , h e a t i n g t o

80-85C. Add t h e p a r t B i n g r e d i e n t s i n o r d e r , m a i n t a i n i n g temp- e r a t u r e . M i x a t t e m p e r a t u r e u n t i l a l l s o l i d s a r e d i s s o l v e d , abou t 30 m i n u t e s . S t i r - c o o l t o 40-45C and a d j u s t p H i f necessa ry .

SOURCE: PPG I n d u s t r i e s , I n c , : Formula K-104

Beauty Aids 57

Exfoliating Foot Scrub

Staqg Mate-r l a 1 1 P r e - M i x 1 1 E . O . Tea T r e e 2 E . O . Peppermint 3 Cocami d o p r o p y l Beta1 ne

Stage A : 4 Water; Pure 5 Myacide S P 6 EDTA, D isod ium S a l t 7 Bror i idox L / l 5 8 Veegum Regu la r

Stage B : 9 Sodium L a u r e t h S u l p h a t e (SLES)

Stage C : 1 0 AEC Corn Cob Granu les 11 Cocamide CDE 12 C . S . FD&C Y e l l o w No. 5 ; 1% S o l n 1 3 C . S . FD&C B l u e No. 1 ; 1 % S o l n 1 4 L a c t i c Ac id ; N a t u r a l

Quan t i ty

0 . 1 5 0 g 0 .200g 3 . O O O g

4 4 . 8 1 0 8 0 .1oog 0 .200g 0 .2009 0 . 4 0 0 g

4 0 . OOOg

5 . OOOg 2 . ooog 0 . 1 7 O g 0 . 1 3 5 9 0 , 0 3 5 9

M i x i ng I n s t r u c t i ons :

The Tea T ree o i l i s a n a t u r a l f u n g i c i d e , t h e pepperm in t o i l has a n a t u r a l c o o l i n g ac t . i on and t h e Corn Cob Granu les e x f o l i a t e rough and dead s k i n . 1 . Me te r o u t t h e w a t e r and s t a r t h e a t i n g . Add Myacide/EDTA/

B r o n i dox I

2 . C o n t i n u e h e a t i n g & d i s p e r s e t h e Veeyum; h e a t t o 60/65C t o o b t a i n a smooth p a s t e , s w i t c h o f f h e a t .

3 . W h i l e m i x i n g v e r y c a r e f u l l y t o a v o i d foaming s l o w l y & c a r e - f u l l y add Sodium L a u r e t h S u l f a t e . T h i s b r i n g s t h e t e m p e r a t u r e down t o a p p r o x . 45C. C o n t i n u e m ix - i ng u n t i l a smooth p a s t e ( a b o u t 3 0 m i n s . ) .

4 . S e p a r a t e l y m i x t o g e t h e r Tea T ree /Pepperm in t O i l and Cocamido- p r o p y l B e t a i n e and add t o main m i x .

5 . W h i l e s t i l l l i q u i d s t i r i n t h e AEC Corn Cob Granu les f o l l o w e d by Cocamide DEA wh ich w i l l t h i c k e n t h e p r o d u c t .

6 . Match c o l o u r , a d j u s t pH t o 7 . 5 - 8 . 5 , s t i r u n t i l p r o d u c t t h i c k - ens t o a v o i d Corn Cob Granu les f l o a t i n g t o t h e s u r f a c e .

T h i s F o o t Sc rub has a c l e a n s i n y and g e n t l e e x f o l i a t i n g a c t i o n ,

SOURCE: A & E Connock L t d , : P r o j e c t JW2566/Formula R e f . 1202*0


Extra Light W/O Emulsion I n g r e d i e n t s : Weight% O i l Phase: P o l y g l y c e r y l - 4 I s o s t e a r a t e (and ) C e t y l D ime th i cone C o p o l y o l (and) Hexy l L a u r a t e (Ab i 1 WE-09) 4 . 0

C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 1 . o D i m e t h i c o n e (350 c s ) 1 . 0 Beeswax 0 . 2 Hydrogenated C a s t o r O i l 0 . 2 Cyc lometh i cone 9 . 0 O c t y l S t e a r a t e ( T e g o s o f t OS) 4 . 0 I s o p r o p y l P a l m i t a t e ( T e g o s o f t P) 3 . 0 I s o p r o p y l M y r i s t a t e ( T e g o s o f t M) 4 . 0 Water Phase: Water 7 2 . 8 NaCl 0 . 8 P r e s e r v a t i v e s , C o l o r , F rag rance Q.S. Procedure : 1 . Add t h e components o f t h e o i l phase t o g e t h e r . Heat t o m e l t

and d i s p e r s e t h e waxes. When d i s p e r s e d , m a i n t a i n t e m p e r a t u r e O f 5 0 - 6 0 C .

2 . M i x t h e w a t e r and sodium c h l o r i d e . Heat t o 50-60C. 3 . W i t h l i g h t n i n ' m i x i n g , s t r e a m t h e wa te r phase i n t o t h e o i l

phase. 4 . W i t h sweep a g i t a t i o n , c o o l t o 35C. 5 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e s . 6 . Homogenize w i t h a r o t o - s t a t o r homogenizer .

Pearlescent Eye ShadowI n g r e d i e n t s : Phase A : T a l c S i l i c a Kaol i n M i c a I r o n Ox ides U1 t r a r n a r i ne 81 ue Me thy lpa raben P r o p y l p a r a b e n Phase 9: C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) Behenoxy D i m e t h i c o n e ( A b i l Wax 2440) Phenyl T r i m e t h i c o n e ( A b i l AV 20 ) Cyc lometh i cone (and ) D i m e t h i c o n o l (and) D ime th i cone

F rag rance Procedure :

( A b i l OSW 12)

Wei a h t %

44.40 4 .00

14.00 8 . 0 0

18 .00 4 .00 0 . 2 5 0 . 1 5

4.20 1 . o o 0 .25

1 . 7 5 Q.S.

1 . Combine t h e i n g r e d i e n t s o f Phase A i n a b l e n d e r . M i x u n t i 1

2 . Combine t h e i n g r e d i e n t s o f Phase B . Warm i f necessa ry t o

3 . P r e s s i n t o g o d e t s . SOURCE: Goldschmi d t Chemical Corp . : Suggested F o r m u l a t i o n s

u n i f o r m .

d i s p e r s e t h e A b i l Wax 2440. M i x . Add t o A . Reblend.

Beauty Aids 59

Eye Mascara

F o r m u l a t i n g Des ign and Advantages : T h i s mascara p r o v i d e s a q u i c k d r y i n g i n i t i a l e f f e c t . The

p r o d u c t i s s i l k y t o t h e l a s h e s and smudge p r o o f . O i l Phase: Wt% S i l i c o n y l Beeswax ( K o s t e r Keunen) 7 . 5 0 PEG Carnauba ( K o s t e r Keunen) 7 . 5 0 G l y c e r o l Monos tea ra te (Wi t c o ) 2 . 7 5 Orange Wax ( K o s t e r Keunen) 2 . 0 0 S t e a r i c A c i d ( K o s t e r Keunen) 1 . o o P a r a f f i n 150 /155 ( K o s t e r Keunen) 1 . 5 0 M i c r o c r y s t a l 1 i ne W445 (Wi t c o ) 1 . 5 0 P r o p y l Paraben ( S u t t o n ) 0 . 3 0 Water Phase: Water (De i o n i zed) 58 .45 Sodium B o r a t e (Bo rax ) 1 . 2 0 P r o p y l ene G1 y c o l (BASF) 1 . o o Carbopo l 2% S o l u t i o n ( B . F . Goodr i ch ) 1 . o o A 1 coho1 Phase: A l c o h o l SDA 30 (Quantum) 1 0 . 0 0 P u r i f i e d B l a c k Ox ide ( C l a r k e ) 4 . 0 0 P rocedure :

t o t h e wa te r phase. Cool t o 40C and add t h e p remixed a l c o h o l phase. C o o l . A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t :

A v a r i e t y o f p igmen ts can be s u b s t i t u t e d t o s u i t t h e p r o d u c t ' s needs. V i s c o s i t y can be a l t e r e d by r e d u c i n g s o l i d s and i n c r e a s i n g w a t e r phase.

Heat t h e o i l phase and wa te r phase t o 75C. Add t h e o i l phase

Powder Formula

Formul a t i ng Desi gn and Advantages : B i nder systems u t i 1 i z i n g t h e s i 1 i cone o i 1 /Cera A1 b a l a t e 103

g e l p roduces a d r y n o n - o i l y s k i n f e e l . These t y p e of p r o d u c t s a l s o have h i g h s t r u c t u r a l i n t e g r i t y and can w i t h s a t n d f i v e d r o p s f rom one t o two f e e t . B i n d e r : W32? S i l i c o n e O i l 3.45 (Dow) 6 0 . 0 Hexaned io l Behenyl Beeswax ( K o s t e r Keunen) 4 0 . 0 Pressed Powder: Cosmetic Tan C33-130 (Sun Chemica l ) 1 3 . 0 T a l c ( W h i t t a k e r C&D) 4 7 . 0 B i n d e r ( K o s t e r Keunen) 4 0 . 0 P rocedure :

Homogenize and p r e s s i n c o n t a i n e r a t 1000 p s i f o r 15-20 seconds. A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t :

sys tem. I n t h e f i n a l p r o d u c t , p igmen ts and c o n c e n t r a t i o n o f b i n d e r can e a s i l y be a l t e r e d t o p roduce v a r y i n g degrees o f c reaminess and f i r m n e s s o f t h e powder . SOURCE: K o s t e r Keunen, I n c . : A Gu ide t o N a t u r a l F o r m u l a t i n g

O the r o i l s and /o r waxes can b e s u b s t i t u t e d i n t o t h e b i n d e r

60 Cosmetic and Toiletry Fornzulations

Eye Shadow

Phase# : 1 T a l c 141

L i t h i um s t e a r a t e K a o l i n 2457 M i c r o c e l E M e t h y l Paraben P r o p y l Paraben B i r o n ESQ (BiOC1) C o n v e n t i o n a l P igments

W B q . s .

2 .50 5 . 0 0 0 .50 0 .20 0 .10

see b e l ow see b e l ow

2 P e a r l escen t Pigment see b e l ow

3 Amerchol L-1 01 3 Super H a r t o l an 3 W h i t e P e t r o l a t u m

11 - 0 0 1 .oo 1 .oo

P rocedure : Combine phase #1. P u l v e r i z e w i t h a hammer m i l l , p a s s i n g t w i c e

t h r o u g h a 0 .027" h e r r i n g bone sc reen . A d d phase # 2 w i t h g e n t l e a g i t a t i o n . Combine phase #3. Heat t o 70C. Spray o n t o b a t c h w h i l e a g i t a t i n g b u l k . Pass e n t i r e b a t c h t h r o u g h a jump gap.

Combi n a t i ons :

1 B i r o n ESQ 3 .00 1 B i r o n ESQ 3 .00 1 B l a c k I r o n Ox ide (7133) 5 . 0 0 1 B l a c k I r o n Ox ide (7133) 1 . 0 0 1 Red I r o n Ox ide (7054) 2 .00 1 Red I r o n O x i d e (7054) 5 .40 1 Y e l l o w I r o n Ox ide (7055)3 .00 1 Y e l l o w I r o n Ox ide (7055)3 .60 2 C o l o r o n a Chameleon 60.00 2 C o l o r o n a Sienna 60.00

P3-83-1 : P3-83-2:

P3-83-3: 1 B i r o n ESQ 3 .00 1 B l a c k I r o n Ox ide (7133) 0 .75 1 Red I r o n Ox ide (7054) 3 .00 1 Y e l l o w I r o n Ox ide (7055)6 .25 2 C o l o r o n a C o m e r 60.00 . . P3-83-5: 1 B i r o n ESQ 0 .20 1 B i c r o n a Carmine 1 4 . 0 0 2 C o l o r o n a Bordeaux 60.00

1 B i r o n ESQ 3 .00 1 B l a c k I r o n Ox ide (7133) 0 .50 1 Manganese V i o l e t (71 01 ) 2 . 0 0

P3-83-7:

P3-83-4: 1 B i r o n ESQ 3.00 1 B l a c k I r o n Ox ide (7133) 0.50 1 Y e l l o w I r o n Ox ide (7055)9 .50 2 Co lo rona Bronze 60.00 P3-83-6: 1 B i r o n ESQ 0 .20 1 B i c r o n a I r o n B l u e 14 .00 2 C o l o r o n a Bordeaux 60.00 P3-83-8: 1 B i r o n ESQ 3.00 1 B l a c k I r o n Ox ide (7133) 0 . 5 0

2 D i c h r o n a BG 5 5 . 0 0 1 Chromium H y d r a t e 2 . 0 0

2 C o l o r o n a Magenta 55 .00

1 B i r o n ESQ 2.60 P3-83-9:

1 B l a c k I r o n Ox ide (7133) 0 . 5 0 1 B i c r o n a I r o n B l u e 2.00 2 C o l o r o n a Dark B l u e 55.00

SOURCE: Rona/EM I n d u s t r i e s , I n c . : F o r m u l a t i o n P3-83

Beauty Aids 61

Facial Cleanser with Pemulen TR-2 Polymer Emulsifier and Carbopol Ultrez 10 Polymer

T h i s c l e a n s i n g f o r m u l a t i on i s 1 i g h t , non-greasy and w a t e r - r i n s a b l e . I t p r o v i d e s t h o r o u g h c l e a n s i n g w i t h o u t d r y i n g t h e s k i n .

I n g r e d i e n t s : P a r t A : Dei o n i zed Water M i r a n o l U l t r a D o w i c i l 200 Me thy lpa raben Propy lpa raben

P a r t 6: F i n s o l v SB Berne l E s t e r DOM C a p r y l i c / C a p r i c T r i g l y c e r i d e Wickenol 171 Pemulen TR-2 Carbopol U l t r e z 10

P a r t C : AMP-95

We igh t

8 9 . 5 5 1 . o o 0 . 1 0 0 . 1 0 0 . 0 5

4 . 0 0 2 . 0 0 1 . o o 1 . o o 0 . 2 0 0 . 6 0

0 . 4 0

P rocedure : 1 . Combine P a r t A i n g r e d i e n t s i n a v e s s e l wh ich w i l l c o n t a i n

t h e e n t i r e f o r m u l a t i o n . M i x t o d i s s o l v e D o w i c i l 200. 2 . Combine P a r t B i n g r e d i e n t s i n a s e p a r a t e v e s s e l . M i x t o

d i s p e r s e any s o f t lumps o f Pemulen and Carbopol p o l y m e r . 3 . W i t h moderate a g i t a t i o n , add t h e P a r t B s l u r r y t o P a r t A .

M i x f o r 10-20 m i n u t e s t o a l l o w p o l y m e r s t o s w e l l . 4 . Add P a r t C and m i x v i g o r o u s l y t o p roduce a smooth, w h i t e

cream.

P r o p e r t i es : pH: 5 . 6 - 6 . 0 V i s c o s i t y * ( cPs ) a t 25C: 28,000-35,000

* B r o o k f i e l d RVT @ 20 r p m , #6 s p i n d l e

SOURCE: Angus Chemical Co . : P r o d u c t F o r m u l a r y : F o r m u l a t i o n PF-0368 sugges ted by 8. F.Goodr i ch (UOOOS)


Facial Scrub

Phase: I n g r e d i e n t : Wt% A Carbomer 940 (2%) 15 .00 A D e i o n i z e d Water 57.75 A P r o p y l ene G1 y c o l 2 .50 A A l o e Vera Gel 0 .25

B O i l s o f A loha Macadamia Nu t O i l 2 .50 B S t e a r i c A c i d XXX 3 . 5 0

B Cyc lometh i cone 5 . 0 0

B Promulgen D 1 . oo B I s o p r o p y l M y r i s t a t e 10 .00 C T r i e t h a n o l a m i n e 99% 1 . oo D P o l y e t h y l e n e AC-SA 1 . 5 0 E P r e s e r v a t i ve QS

M a n u f a c t u r i n g Procedure : Phase A : D i s p e r s e Carbopo l i n t o wa te r w h i l e h e a t i n g t o 75C.

Phase 8 : Heat o i l phase t o 75C and add t o wa te r phase. Phase C : Add T r i e t h a n o l a m i n e t o o i l / w a t e r m i x t u r e and c o o l t o

Phase D/E : Add P o l y e t h y l e n e AC-SA. Add p r e s e r v a t i v e .

f o r p e o p l e w i t h o i l y s k i n and needs t o have a d r y i n g e f f e c t . Uses two v e r y d r y emollients-cyclomethicone and i s o p r o p y l m y r i s t a t e . They l e a v e a d r y f e e l i n g s k i n . The O i l s o f A loha Macadamia Nut O i l l e a v e s t h e s k i n w i t h a f r e s h , m o i s t a f t e r f e e l . Kukui Nut O i l wou ld a l s o work v e r y w e l l i n t h i s f o r m u l a . SOURCE: O i 1 s o f A1 oha : Suggested Formul a t i on

Add P r o p y l e n e G l y c o l and A l o e Vera G e l .

40C.

Carbomer 940 i s t h e suspend ing a g e n t . T h i s s c r u b i s des igned

Facial Cleansing Gel

WtOA, D e i o n i z e d Water 60 .90 Sodium PCA 0 .10 Carbomer 940 (2% Aq . ) 25.00 TEA-Lauryl S u l f a t e 2 .oo Cocami de DEA (Phoenami d CD) 2 .50 S i l i c o n e Quatern ium-6 ( P e c o s i l SPB-1240) 2 .00 PEG-3 D i s t e a r a t e (Phoenate BDSA) 1 .50 P ropy lene G l y c o l 5 .00 - 8: P r o p y l e n e G l y c o l (and) D i azo1 i d i n y l Urea (and)

Me thy lpa raben (and ) P ropy lpa raben 1 . o o C o l o r q . s . Fragrance q . s . Procedure :

Combine Phase A i t e m s , a g i t a t e and h e a t t o 70C. When Phase A i s u n i f o r m , b e g i n c o o l i n g under s low sweep a g i t a t i o n t o 45C. Add Phase B w i t h c o n t i n u e d s low sweep a g i t a t i o n . S l o w l y sweep AB u n t i l u n i f o r m .

SOURCE: Phoen ix Chemical , I n c . : Suggested F o r m u l a t i o n

Beauty Aids 63

Gel with MPC-Liposomes

MPC-Mi 1 k P e p t i d e Complex: MPC c o n t a i n s n a t u r a l p o l y p e p t i d e s f r o m m i l k , i n a c t i v a t e d

f o r m . A p r o t e c t i v e e n v i ronment e x c l u s i v e l y compr i sed o f m i 1 k components such as l a c t a l b u m i n , l a c t o g l o b u l i n , l a c t o f e r r i n , l a c t o s e and l a c t a t e p r o v i d e s f o r p r o d u c t s t a b i l i t y and mai n tenance o f b i o a c t i v i t y . B i o a c t i v i t y i s s t a n d a r d i zed i n e v e r y b a t c h o f MPC t o a r e p r e s e n t a t i v e c o n c e n t r a t i o n range (EC50). I n v i t r o b i o a s s a y s i n c e l l c u l t u r e s and i n v i v o t e s t s on e p i t h e l i a l t i s s u e and on human s k i n g i v e p r o o f o f t h e b i o a c t i v i t y and c o s m e t i c b e n e f i t s o f MPC.

a) H i s p a g e l 200 Water , d i s t i 11 ed K e l t r o l , 1% s o l u t i o n C e t i o l J 600 Phenoni p

20.00 20.70 30 .00

4 . 0 0 0.30

b ) MPC-Liposomes (2% MPC) 2 5 . 0 0

M a n u f a c t u r e : M i x a ) a t room t e m p e r a t u r e ; S l o w l y add b ) t o a ) and combine. Perfume.

SOURCE: Chemisches L a b o r a t i u m D r . K u r t R i c h t e r GmbH: Formula

Body Moisturiser with Wild Borage Oil

M a t e r i a l : Water; Pure P r o p y l e n e G1 y c o l USP AEC Decyl O l e a t e Cocoa B u t t e r , Ref i ned Tego Care 450 AEC D i i s o s t e a r y l T r i m e t h y l o l p r o p a n e S i l o x y S i 1 i c a t e GMS NSE Sodium PCA C e t e a r y l A l c o h o l W i I d Borage O i 1 N i paguard BPX F rag rance Xanthan Gum L a c t i c A c i d ; N a t u r a l

SOURCE: A & E Connock L t d . : Formula R e f . : 1052*0

%w/w 76.560

5 . 0 0 0 4 .000 3 . 0 0 0 3 . 0 0 0 2 . 0 0 0 2 .000 1 . 5 0 0 1 . o o o 1 . o o o 0.500 0 . 3 0 0 0 . 1 2 5 0 . 0 1 5


Hand and Body Moisturizer Formu 1 a : % bv Weight A : Benol M i n e r a l O i l ( W i t c o ) 7 . 0 0 E s t o l EHP 1543 2 . oo P r i s t e r i ne 4904 3 .50 E s t o l 1462 3 . 0 0 M y r j 52 1 . o o A b i l B8852 1 . o o L a n o l i n O i 1 0 .20 B: Dei o n i zed Water 79 .60 T r i e t h a n o l a m i n e 1 . 3 0 P r i c e r i ne 9083 2 .00 Dermacryl -79 1 . o o C : Carbopol 934 0 .20 D : Germaben 1 1 - E 1 - 0 0 E: F rag rance 04696 (Ques t ) 0 . 2 0 P rocedure :

Combine A i n g r e d i e n t s and h e a t t o 80C. I n s e p a r a t e v e s s e l , m ix w a t e r , P r i c e r i n e and TEA. W h i l e m a i n t a i n i n g good a g i t a t i o n , s l o w l y add D e r m a c r y l . Heat t o 50C and add C s l o w l y . When each p o r t i o n i s u n i f o r m , add A t o B/C and m i x 15 m i n s . ; c o o l t o 40C. Add D and E and cool t o room temp.

____

Liquid Makeup-__-_ Fo rmu la : "/,by Weight A : G e l w h i t e GP 1 . 2 K e l t r o l Xanthan Gum 0 . 2 P r o p y l e n e G l y c o l 3 . 0 T r i e thano lami ne 1 . o Water 5 8 . 4 E : I r o n Ox ides 1 . 2 T a l c 3 . 0 T i t a n i um D i o x i de 6 . 0 C : C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) 10 .0 I s o p r o p y l P a l m i t a t e 5 . 0 N i m l e s t e r o l D M i n e r a l O i l 5 . 0 O l e i c A c i d 6 . 0 P r e s e r v a t i v e s 9 , s . Procedure :

S l o w l y add G e l w h i t e CP t o t h e w a t e r w h i l e a g i t a t i n g a t maximum s h e a r . Add K e l t r o l s l o w l y and m i x a t moderate speed u n t i l smooth. Add p r o p y l e n e g l y c o l and TEA w h i l e m i x i n g w i t h medium s h e a r . B l e n d B and g r i n d i n m o r t a r w i t h a p o r t i o n o f A u n t i l w e l l m ixed . Combine w i t h rema inder o f A and h e a t t o 60C. Combine C and h e a t t o 65C. Add C t o A/B; c o n t i n u e s l o w m i x i n g u n t i l temp. d r o p s t o 30C. Add p r e s e r v a t i v e s . SOURCE : W i t c o Corp, : Suggested Formul a t i ons

Beauty Aids 65

Lipcare Emollient Lipstick

Phase A : Anhydrous 1 ano l i n P95 Argonol 50 M i n e r a l o i l Beeswax C e t y l a l c o h o l O z o k e r i t e Candel i 11 a wax P r e s e r v a t i v e

Phase 0 : C o l o u r p igmen ts i n c a s t o r o i l : T i t a n i um d i o x i d e D&C r e d 6 T i m i c a p e a r l w h i t e

Phase C : F rag rance o r f 1 avour

%w/w 1 4 . 0 0

5 . 0 0 4 0 . 0 0

5 . 0 0 6 . 0 0 2 . 0 0 8 . 0 0

q s

5 . 0 0 1 .oo 4 .00

Heat t o g e t h e r A u n t i l c l e a r , add B and m i x w e l l . A d j u s t t o

*A g l o s s y l i p s t i c k w i t h good s p r e a d a b i l i t y . 60C, t h e n add C . Pour i n t o moulds.

Medicated Lip Balm

Beeswax USP P a r a f f i n wax 130/135 F i n s o l v TN AC P o l y e t h y l e n e 617 Camphor

%w/w 10.00 1 0 . 0 0 54.00

6 .00 20 * 00

Combine t h e f i r s t f o u r i n g r e d i e n t s and h e a t t o 90-95C w h i l e m i x i n g . C o n t i n u e m i x i n g and c o o l t o 80-85C. Add t h e camphor and m ix u n t i l c o m p l e t e l y d i s s o l v e d . Cool once more, t o 40-45C. P o u r i n t o moulds.

i m p a r t s a non-greasy, emo l l i e n t f e e l t o chapped 1 i p s .

SOURCE: A1 1 i ed-Si gna l , I n c . : Suggested Formul a t i ons

*A s o l i d w h i t e s t i c k t h a t r u b s e a s i l y o n t o t h e l i p s . I t


LipcareLip Pomade

Phase A : Anhydrous Lanol i n P95 Lanesta S P e t r o l e u m j e l l y M i n e r a l o i l O z o k e r i t e I r o p r o p y l m y r i s t a t e P a r a f f i n wax

xw/w 10 .00 18.00 1 2 . 0 0 38 .00

5 . 0 0 10 .00

7 - 0 0

Phase B: Fragrance o r f 1 avour

Heat phase A u n t i l c l e a r . Cool t o 45C t h e n add 0 . F i l l warm.

* T h i s g i v e s a ' b u t t e r - l i k e ' p r o d u c t , wh ich l i q u e f i e s on c o n t a c t w i t h t h e s k i n , making a p p l i c a t i o n easy and g i v i n g emol 1 i e n t p r o t e c t i o n .

Lip Gloss

Phase A : Argono l 50 Argono l ACE 5 Carnauba wax Ozoker i t e Candel i 11 a wax C a s t o r o i l

Phase 8: C o l o u r d i s p e r s e d i n c a s t o r o i l

Phase C : F ragrance o r f 1 avour

%w/w 8 .10 3.00 3.60 7 . 0 0 6 . 0 0

t o 100.00

Heat t o g e t h e r A u n t i l c l e a r , t h e n add B, s t i r r i n g w e l l u n t i l

*A s o f t , smooth g l o s s t h a t p r o t e c t s , smoothes and g i v e s a f u l l y d i s p e r s e d . Cool t o 50C and add C . F i l l warm.

1 i g h t col o u r a

SOURCE: A l l i e d - S i g n a l I n c . : Suggested F o r m u l a t i o n s

Beauty Aids 67

Lip Salve with Glycyrrhetinic Acid

PEG-45/dodecyl g l y c o l copolymer Beeswax J o j o b a o i l Hydrogenated 1 ano l i n Cocoa b u t t e r Cas to r o i l A n t i o x i d a n t s G1 ycami 1 G1 y c y r r h e t i n i c a c i d Z i n c o x i d e T i t a n i um d i o x i d e F1 avour

%w/w 2 5 . 0 0

5 .00 2 .50 5 . 0 0

1 0 . 0 0 25.00

0 . 0 5 qs

0 . 5 0 10 .00

1 - 0 0 q s

M e l t t h e f i r s t seven i n g r e d i e n t s , t h e n add G l y c a m i l and t h e g l y c y r r h e t i n i c a c i d . D i s p e r s e t h e ZnO and T i 0 2 i n t h e m e l t e d i n g r e d i e n t s . F i n a l 1 y J add t h e f 1 avour m i x i ng u n t i 1 room t e m p e r a t u r e .

Lip Salve Sunscreen

Candel i 11 a wax W h i t e beeswax E u t a n o l G L i p e x 2 0 5 c a n o l a o i 1 C e t y l a l c o h o l L i p e x 102 shea b u t t e r C i t m o l 316 TM L i p e x 106 I l l i p e ' b u t t e r P a r s o l MCX L i p e x 104 L i p e x 203 mango k e r n a l o i 1 Benzophenone-3 P r o p y l paraben

%w/w 21 . o o 15 .00 10 .65 10.25 10 .00

8 . 5 0 6 .50 6.00 5 . 0 0 4 .00 2 .50 0 . 5 0 0 . 1 0

Heat t o g e t h e r a l l t h e i n g r e d i e n t s u n t i l c l e a r . Pour i n t o c o n t a i n e r s a t 60C and c o o l .

Lip Fix

E t h a n o l Dei o n i sed w a t e r Gan t rez ES-425

S imp le m i x .

SOURCE: A l l i e d - S i g n a l , I n c . : Suggested F o r m u l a t i o n s

%w/w 7 0 . 0 0 10 .00 2 0 . 0 0


Lipstick

Phase # : 1 C a s t o r O i l 1 C19-011 D&C Red#7 Ca Lake 1 C19-022 D&C Red#6 Ba Lake

2 2 2 2 2 2 2 2 2 2 2 2

C a s t o r O i l Candel i 11 a Carnauba O z o k e r i t e #77W M i c r o c r y s t a l 1 i ne Wax #214 C a p r y l i c / C a p r i c T r i g l y c e r i d e M i n e r a l O i 1/9Ocs O c t y l Dodecyl S t e a r o y l S t e a r a t e O c t y l Dodecanol H y d r o x y l a t e d Lanol i n M e t h y l Paraben P r o p y l Paraben

wt% 7 .00 1 . 5 0 1 . 5 0

33.70 5 .70 1 . 8 0 1 .50 3 . 0 0

16 .00 2 - 0 0 5 .00 5 .00 1 . o o 0 . 2 0 0 .10

3 P e a r l escen t Pigment 15.00

P rocedure : Combine phase #l. S t i r w i t h a h i g h i n t e n s i t y m i x e r u n t i l

homogeneous. Pass a c r o s s a t h r e e r o l l m i l l u n t i l agg lomera tes a r e reduced t o l e s s t h a n 25 um. Combine phase #2. Heat t o 80-85C w i t h L i g h t n i n ' m i x e r a g i t a t i o n , s t i r r i n g u n t i l c l e a r . Add phase #1 . Add p e a r l e s c e n t p igmen t (phase # 3 ) , mai n t a i n i ng a g i t a t i o n u n t i l d i s p e r s e d . Pour i n t o ambient t e m p e r a t u r e molds a t 72-74CI

Rona P e a r l Pigment Comb ina t ions : AN2-55-1 : T i m i r o n Super Red AN2-55-2 : T i m i r o n Super 61 ue AN2-55-3: T im i r o n Super G o l d AN2-55-4 : T i m i r o n MP-1001 AN2-55-5: T i m i r o n MP-1500 AN2-55-6: Col o rona Red Go1 d AN2-55-7: C o l o r o n a Red Brown

Wax M e l t i n g P o i n t s : C a n d e l l i l a : 68.5-72.5C Carnauba: 83C m i n i mum O z o k e r i t e #77W: 73.3-79.4C M i c r o c r y s t a l 1 i ne Wax #214: 71 .1-76.7C

SOURCE: Rona/EM I n d u s t r i e s , I n c , : F o r m u l a t i o n AN2-55

Beauty Aids 69

Lip Stick

I ng r ed i e n t s : Wei n h t % A . M i g l yo1 840 ( P r o p y l e n e G1 y c o l / D i c a p r y l a t e / D i c a p r a t e ) 10 .00

S o f t i san 649* 4 . 0 0 Beeswax M i n e r a l O i l C a s t o r O i l Carnaubawax T i m i r o n S i l k Red S i c o r e t Rot F 12150 A n t i o x i d a n t i e n

9 . 0 0 2 . 0 0

60.00 5 . 0 0 9 - 0 0 1 . o o

Q . S .

B. F rag rance 9 , s .

*Bi s-Di g l y c e r y l Pol y a c y l a d i pa te -2

P r e p a r a t i o n : A i s m e l t e d and s t i r r e d u n t i l homogeneous. A t 50C B i s added and t h e mass i s pou red i n t o molds a t c a . 40C F o r m u l a t i o n HUK LST

Lip Care Stick with Sunscreen

I n g r e d i e n t s : A . S o f t i s a n 100

S o f t i san 649* D y n a c e r i n 660 ( O l e y l E r u c a t e ) Beeswax Carnaubawax Neo H e l i o p a n E 1000 C a s t o r O i l

Wei n h t % 40.00 1 4 . 0 0 12.00 1 5 . 0 0

2 .00 2 . 0 0

15 .00

B. F rag rance q . s .

* B i s -Di g l y c e r y l Pol y a c y l a d i pa te -2

P r e p a r a t i on : A i s m e l t e d and s t i r r e d u n t i l homogeneous. A t 50C B i s added and t h e mass i s p o u r e d i n t o molds a t c a . 40C. Formul a t i on HUK LCST

SOURCE: H u l s A k t i engesel l s c h a f t : Suggested F o r m u l a t i o n s


Lipstick, Glossy

Ingredients: WeIght%A) Miglyol Gel B (Caprylic/Capric Triglyceride (and)

Stearalkoniurn Hecton'te (and) Propylene Carbonate) 14.00Miglyol 829 (Caprylic/Capric/Succinic Triglyceride) 8.00Imwitor 78OK (Isostearyl Diglyceryl Succinate) 6.00Softisan 645 (Bis-Diglycery1 Polyacry1adipate-1) 22.00Polyisobutene 19.00Lanoli n Wax 10.OONa-Stearate 1 .00C a n d e l i l i a Wax 8.00Beeswax 7.00

B) Timiron Starlight Red (Mica (and) Titanium Dioxide) 5.00

Preparati on:(A) is melted and stirred until homogeneous up to 75

degrees C. At about 50 degrees C. (B) is added, and then themixture is poured into molds.

Formulation 2.20

Lip Stick

I ngredi ents: Weight%A) Miglyol 840 (Propylene Glycol Dicaprylate/

Dicaprate) 10.00Softisan 649 (Bis-Diglycery1 Polyacy1adipate-2) 4.00Beeswax 9.00Mi neral Oil 2.OOCastor O i l 60.OOCarnauba Wax 5.OOTimiron S i l k Red (Mica (and) Titanium Dioxide) 10.00Antioxidants q.s.

B) Fragrance Tendresse 75418 B q.s.

Preparati on i(A) is melted and stirred u n t i l homogeneous. At 50 degrees C,

(B) is added and the mass is poured into molds.Formulation 2.2P

SOURCE: HuIs America Inc.: Suggested Formulations

Beauty Aids 71

Lipstick "Soft and Moist" (Modified)

M a t e r i a l s : 1 . O z o k e r i t e W h i t e 170 2 . Castorwax 3 . C a n d e l i l l a Wax, L i g h t R e f i n e d 4 . Lexo l PG 855 5 . C a s t o r O i l 6 . Propy lparaben 7. Tenox 4 8 . Bentone Gel CAO R h e o l o g i c a l A d d i t i v e 9 . Pigment C o n c e n t r a t e * 10.Per fume

*Pigment C o n c e n t r a t e : C a s t o r O i l C o l o r No. 3106 D&C Red No. 6

% by Weight 4 . 0 2 . 0 8 . 0

31 - 3 24.0

0 . 1 0 . 1

1 0 . 0 20 .0

0 . 5

30 .00 70 .00

M a n u f a c t u r i n g D i r e c t i o n s : 1 . Weigh i t e m e 1 t h r o u g h 7 i n t o a s t a i n l e s s steam j a c k e t e d

k e t t l e . Heat t o 85C u n t i l m e l t e d c l e a r . 2 . B r i n g t e m p e r a t u r e down t o 80C. Add and mix i n i t e m 8 u s i n g

a homomixer a t medium speed. M i x f o r 10 m i n u t e s a t 80C. 3 . Add and mix i t e m 9 f o r 5 m i n u t e s o r u n t i l d i s p e r s e d . 4 . C o n t i n u e m i x i n g a t medium speed and l o w e r t e m p e r a t u r e t o

70C and add i t e m 10. Remove h e a t and s t i r s l o w l y u n t i l congealed, o r pour i n t o t r a y s .

5 . When c a s t i n g , m e l t and p o u r m o l t e n mass i n t o mold a t 75C, w i t h s l o w a g i t a t i o n ( a v o i d a i r e n t r a p m e n t ) .

Note : For a s h i n y p o l i s h e d s u r f a c e on t h e l i p s t i c k , t h e s t i c k s s h o u l d be s u r f a c e f l a m e d .

Pigment C o n c e n t r a t e P r e p a r a t i o n : 1 . Weigh d r y powder i n t o t h e c a s t o r o i l u s i n g a s l o w speed

2 . G i v e t h i s c o n c e n t r a t e two passes o v e r a 3 r o l l m i l l a t

SOURCE: Rheox I n c . : Suggested F o r m u l a t i o n

Hobar t t y p e m i x e r and mix u n t i l u n i f o r m .

room t e m p e r a t u r e .

Lipstick Base

W t % - 1 W t % - 2 A-C 617 8 7 A c e t y l a t e d L a n o l i n 16 16 2 - E t h y l Hexy l S t e a r a t e 6 7 O z o k e r i t e 20 20 M i n e r a l O i l (75 SS) 50 50 Procedure :

c l o u d p o i n t s w i t h m i l d a g i t a t i o n . ( B l e n d s 1 & 2 have c l o u d p o i n t s o f 80 & 79C r e s p e c t i v e l y ) . Once b l e n d i s c l e a r t h e m i x t u r e can be c o o l e d and packaged. SOURCE: A l l i e d - S i g n a l I n c . : Suggested F o r m u l a t i o n s

Weigh o u t a l l i n g r e d i e n t s . Heat m i x t u r e s l i g h t l y above t h e i r


Lipstick with A-C 400, No. 162

1 . T i 0 2 i n C a s t o r O i l (40% p i g m e n t ) 2 . Red 6 i n C a s t o r O i l (25% p i g m e n t ) 3 . Red 7 i n C a s t o r O i l (25% p i g m e n t ) 4 . C a s t o r O i l ( e x t r a ) 5 . P o l y b u t e n e H-100

7 . E u t a n o l G 8 . R e f i n e d L a n o l i n 9 . Candel i 11 a 1 0 . P o l y g l y c e r y l d i - i s o s t e a r a t e (Emerest 2452)

6 . A-C 400A

%w/w 1 . 8

1 4 . 3 1 0 . 8

3 . 3 9 . 3 4 . 7

2 3 . 3 9 . 3

1 3 . 0 10 .2

P rocedure :

i n g r e d i e n t s t o g e t h e r , h e a t and m i x t o 93C. Cool t o 85C and p o u r t h e m i x t u r e i n t o t h e mo lds .

NOTE: T h i s s t i c k was f l a m e d . W i t h o u t f l a m i n g i t wou ld n o t be as g l o s s y . To make i t more m a t t e , reduce p o l y b u t e n e t o 546, and i n c r e a s e No. 7 b y 2%, No. 8 b y 0.5%, No. 9 by 1%, and No. 1 0 by 1.5%. P r e s e r v a t i v e and a n t i - o x i d a n t as m i n o r amounts s h o u l d n o t be a p rob lem.

The p igmen t c a s t o r o i l b l e n d s a r e p r e d i s p e r s e d . Weigh a l l

Lip Gloss

1 . 2 . 3 . 4 . 5 . 6 . 7 . 8 . 9 .

2 - e t h y l h e x y l s t e a r a t e C a s t o r o i l

L a n o l i n a l c o h o l 01 e y l a1 coho1 Perfume Brown umber shade 1985 Brown r e d shade 1654 P r e s e r v a t i v e

A-C 400

%w/w 51 ,175 15 20

5 8 0 . 7 5 0.025 0 . 0 5 q.s.

Procedure : A . D i s p e r s e p igmen t i n 0.225% c a s t o r o i 1 . 6. M i x t h e r e m a i n i n g 1 ,2 ,3 ,4 ,5 and h e a t t o 85-9OC w i t h s t i r r i n g

u n t i 1 t h e p o l y e t h y l e n e has c o m p l e t e l y d i s s o l v e d . Add p igmen t m i x t u r e t o i t .

C . M i x s l o w l y , add per fume a t 50-55C and d e - a e r a t e . Pour i n t o molds o r c o n t a i n e r s and a l l o w t o c o o l t o room t e m p e r a t u r e .

SOURCE: A l l i e d - S i g n a l I n c . : Suggested F o r m u l a t i o n s

Beauty Aids 73

Liquid Make-Up

Formul a t i n g Desi gn and Advantages :

and l e a v e s a smooth and s i l k y a f t e r - f e e l . I t w i l l a l s o reduce t r a n s e p i d e r m a l w a t e r 1 oss .

T h i s make-up c o v e r s n i c e l y y e t i t i s v e r y l i g h t on t h e s k i n

O i l Phase: Hexaned io l Behenyl Beeswax ( K o s t e r Keunen) O c t y l P a l m i t a t e ( L e x o l ) S i l i c o n e O i l 556 (Dow C o r n i n g ) I s o p r o p y l P a l m i t a t e ( L e x o l ) I s o s t e a r i c A c i d (Uni chema) O y s t e r Nut O i l ( K o s t e r Keunen) P r o p y l Paraben ( S u t t o n )

Water Phase: D e i o n i z e d Water Xanthan Gum ( K e l c o ) C e l l u l o s e Gum (Aqua lon ) T r i e t h a n o l a m i n e (Dow C o r n i n g ) G1 y c e r i n (Uni chema) P r o p y l e n e G l y c o l (BASF) P o l y s o r b a t e 60 (BASF) M e t h y l Paraben ( S u t t o n )

Pigment Phase: O p t a t i n t T i t a n i u m D i o x i d e ( C o l o r c o n ) Deodor i zed Orange Wax ( K o s t e r Keunen) S i l i c o n y l Beeswax ( K o s t e r Keunen) PEG Carnauba ( K o s t e r Keunen) Brown I r o n Ox ide ( C l a r k C o l o r s ) Y e l l o w I r o n O x i d e ( C l a r k C o l o r s )

Wt% 0 . 5 0 2 .00 4 . 0 0 2 .00 1.50 1 . o o 0 . 3 0

59.60 0 . 4 0 0 . 3 0 0 . 7 0 2 .00 2 . 0 0 0 . 6 0 0 .30

13 .00 2 . 0 0 2 . 3 0 2 . 3 0 2 . 2 0 1 . o o

P rocedure : Heat p igmen t phase u n t i l m e l t e d , s t i r r i n g t o b r e a k up any

g l o b u l e s . L e t c o o l . Reheat and m e l t a g a i n s t i r r i n g g l o b u l e s . Add t o t h e p r e h e a t e d o i l phase a t 75C. Add t h e o i l phase t o t h e 75C h e a t e d w a t e r phase under v i g o r o u s a g i t a t i o n . C o o l .

A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t : Smal l amounts o f sunscreen may be added t o r e p l a c e t h e o i l s .

The o i l may be reduced t o g i v e an even l i g h t e r f e e l . Replacement o f O y s t e r Nut O i l w i t h P o l y e t h y l e n e G l y c o l D i s t e a r a t e w i l l make t h i s f o r m u l a an o i l f r e e p r o d u c t .



Liquid Makeup

I n s r e d i e n t : A : D e i o n i z e d Water

B: Veegum, Magnesi um A1 umi num S i 1 i c a t e C e l l u l o s e Gum (CMC 7H3SF)

C: P r o p y l e n e G l y c o l L e c i t h i n Me thy lpa raben

D : T i t a n i u m D i o x i d e M i c a (and) S i l i c o n D i o x i d e (Cashmir K-11) T a l c ( M i c r o Ace P-2) I r o n Oxides S i 1 i ca (Spheron P-1500)

E: C e t y l A l c o h o l G l y c e r y l S t e a r a t e ( L i p o GMS 450) I s o p r o p y l P a l m i t a t e ( L i p o IPP) S t e a r i c A c i d C a p r y l i c / C a p r i c T r i g l y c e r i d e ( L i p o n a t e GC) I s o e i c o s a n e (Permethy l 102A) I s o s t e a r i c Acid (Emerol 871)

F: T r i e t h a n o l a m i n e , 99% P r o p y l p a r a b e n I m i d a z o l i d i n y l Urea (Germa l l 115)

W t .%* 48.83

0 . 5 0 0 . 1 5

5.00 1 . o o 0.20

9 .00 2 . 0 0 2.00 1 .40 0 .50

1 . 0 0 0 .80 4 .00 0 . 8 0 6.00

12.50 2 . 4 0

1 .62 0 .10 0 . 2 0

P rocedure : Dry b l e n d P a r t B i n g r e d i e n t s . Add P a r t B t o P a r t A w h i l e

m i x i n g w i t h a homogenizer f o r 20 m i n u t e s a t 5000 r p m . B e g i n h e a t i n g t o 75C. Add t h e P a r t C and P a r t D i n g r e d i e n t s i n t h e o r d e r shown m i x i n g each f o r 3 m i n u t e s . Check t o make s u r e t h e p igmen ts a r e u n i f o r m l y d i s p e r s e d . I n a s e p a r a t e v e s s e l m ix and h e a t t h e P a r t E i n g r e d i e n t s t o 75C. When b o t h phases a r e a t 75C, add t h e P a r t E t o P a r t s A+B+C+D. M i x f o r 15-20 m i n u t e s . B e g i n c o o l i n g w i t h s l o w speed m i x i n g . A t 50C add t h e P a r t F i n g r e d i e n t s i n t h e o r d e r shown. C o n t i n u e c o o l i n g t o room t e m p e r a t u r e w h i l e m i x i n g a t s l o w speed.


SOURCE: R . T . V a n d e r b i l t Co., I n c . : Veegum F o r m u l a t i o n f r o m P r e s p e r s e , I n c .

Beauty Aids 75

Luxurious Makeup

Formula: % by WeIghtA:Veegum 1,20Water 37.90Magnesium Sulfate 0.40B:Talc 5.50Kaolin 1.50Titanium Dioxide 5.00Iron Oxides 3.00C;Carnation Mineral Oil (Witco) 15.00Polysynlane (Polyesther) 8.00Ritachol 8.00Lanapene (Lanaetex) 7.0070% Sorbitol Solution 5.00Witcamide 511 (Witco) 1.50

Preservatives q.s.

Procedure:Add Veegum to water slowly, agitating continually u n t i l

smooth. Grind B and add to A 1 m i x i n g until uniform. Add A and Bto C and mix until smooth and uniform.

Cleansing Milk

£p_rmuIa : %_by. Wejjgh.tLanolin Anhydrous 5.0Propylene Glycol Monostearate 3.0Polysynlane (Polyesther) 38.0I.P.M. 4.0Paraffin Wax 4.0Beeswax 16.0Potassium Hydroxide 0.7Carnation Mineral Oil 3,0Perfume and Preservatives q.s.Water to 100.0

SOURCE: Witco Corp.; Suggested Formulations


Makeup Foundation I n a r e d i e n t : A : 8:

C :

D:

E:

D e i o n i z e d Water Veegum U1 t r a , Magnesi um A1 umi num S i 1 i c a t e Xanthan Gum N y l o n - I 2 (Orgaso l 2002 D E x t r a N a t u r a l Cos) Sodium PCA ( A j i d e w N-50) Dei o n i zed Water P r o p y l e n e G l y c o l I r o n Ox ides (and) T a l c T i t a n i um D i o x i d e G l y c e r y l S t e a r a t e (Cerasyn t GMS) S t e a r i c A c i d DEA-Cetyl Phosphate (Amphi so l ) Me thy lpa raben (and) B u t y l p a r a b e n (and ) E t h y l p a r a b e n

I s o s t e a r y l Neopentanoate M i n e r a l O i l (and) Hydrogenated B u t y l e n e / E t h y l e n e /

S t y r e n e Copolymer (and) Hydrogenated E t h y l e n e / P r o p y l e n e / S t y r e n e Copolymer (Geahlene)

(and ) P ropy lpa raben ( N i p a s t a t )

Phenoxyethanol (Emeressence 1160) Tocophero l A c e t a t e

W t .%* 46.50

0.80 0 . 3 0 1 . 2 0 1 . o o

10.00 7 .00 2 . 5 5 5.60 2 .oo 2.00 2 . 0 0

0 .25 3 .00

15.00 0 . 7 0 0 .10

Dry b l e n d t h e P a r t B i n g r e d i e n t s and add them t o P a r t A w h i l e m i x i n g w i t h a homogenizer a t 5000 rpm f o r 20 m i n u t e s . Add t h e P a r t C i n g r e d i e n t s i n o r d e r and m ix each f o r 3 m i n u t e s . I n a s e p a r a t e c o n t a i n e r homogenize t h e P a r t D i n g r e d i e n t s u n t i l smooth. Add P a r t D t o P a r t s A+B+C and m i x 10 m i n u t e s w h i l e h e a t i n g t o 80C. Heat t h e P a r t E i n g r e d i e n t s t o 80C and m i x u n t i l t h e s o l i d s a r e d i s s o l v e d . Add P a r t E t o t h e main b a t c h and m i x f o r 30 m i n u t e s . C o n t i n u e m i x i n g a t s l o w speed w h i l e c o o l i ng t o 35C. *As r e c e i v e d b a s i s

I n g r e d i e n t : W t .%* A : Veegum, Magnesium Aluminum S i l i c a t e 1 .50 B: D e i o n i z e d Water 3 0 . 7 8 C: PVP (PVP K-30) 0 . 2 2

Hydro1 yzed K e r a t i n ( Kera-Tei n 1000 SD) 1 - 0 0 K e r a t i n A m i no A c i d s ( Kera-Tei n AA) 0.50 P r o p y l ene G1 y c o l 5 .00

D: P e t r o l a t u m 3.00 P e t r o l e u m D i s t i 11 a t e s 32 .00 Carnauba Wax 5.00 S y n t h e t i c Beeswax 5 .00 Candel i 11 a Wax 3.00 P a r a f f i n 2 .50 Oleamide DEA 5 .00

E : I r o n O x i d e (C33-134 Cosmet ic B l a c k ) 5 . 5 0 F: P r e s e r v a t i v e 4 . S .

a t 5000 rpm. Add P a r t C i n g r e d i e n t s i n t h e o r d e r shown m i x i n g each 3 m i n u t e s b e f o r e a d d i n g t h e n e x t i n g r e d i e n t . Heat P a r t s A+B+C t o 75C. M i x and h e a t P a r t D i n g r e d i e n t s t o 80C. Add P a r t D t o P a r t s A+B+C and m ix 10 m i n u t e s . Add P a r t E and m i x 10 m i n u t e s . Beg in c o o l i n g w h i l e m i x i n g s l o w l y . A t 40C add P a r t F. M ix & c o o l . SOURCE: R . T . V a n d e r b i l t C o o , Inc.: Formulas: Penreco 8, Maybrook

Lash-Conditioning Mascara

Add P a r t A t o P a r t 6 and m ix w i t h a homogenizer f o r 20 m i n u t e s

Beauty Aids 77

Make-up Remover

0 . I . Water Sodi um B o r a t e Neobee M-5 Cosmet ic M i n e r a l O i l Beeswax USP Lanol i n Drewpol 10-1 0-0 OMDM H y d a n t o i n

% b y Weiaht Q.S. t o 100 .0

0.60 40.00 2.00 10.00 1-00 2.50 0.25

M i x i ng P rocedure : P repare w a t e r phase by a d d i n g t o g e t h e r D . I . Water and Sodium

B o r a t e . S t a r t m i x i n g . When t h e r e a r e no c r y s t a l s , s t a r t h e a t i n g t o 160-165F. Prepare o i l phase by comb in ing Neobee M-5 Cosmet ic , M i n e r a l O i l , Beeswax USP, L a n o l i n , and Drewpol 10-10-0. Heat t o 165-17OF. Add w a t e r phase i n t o o i l phase w i t h good a g i t a t i o n . E m u l s i f y f o r 25-30 m i n u t e s a t 165-17OF. Cool t o 11OF. Add DMDM H y d a n t o i n . W i t h m i x i n g , c o o l t o room t e m p e r a t u r e .

AHA Facial Cleanser

D. I. Water G l y c e r i n EDTA B i o-Terge AS-40 Amphosol CG Avanel S-150 S a l i c y l i c Ac id

% by Weight Q.S. t o 100.0

2.5 0 . 2 30.0 20.0 6.5 1 . o


and m ix w e l l . I n t o a s e p a r a t e v e s s e l , p r e m i x Avanel S-150 and S a l i c y l i c A c i d , making s u r e a l l c r y s t a l s a r e d i s s o l v e d . Add p r e m i x t o t h e b a t c h . M i x w e l l . Check p H ( 4 . 0 ) and a d j u s t v i s c o s i t y , i f necessa ry .

SOURCE: Stepan Co. : Suggested F o r m u l a t i o n s

Add w a t e r , G l y c e r i n , EDTA, B io -Te rge AS-40, and Amphosol CG


Mascara Remover

A smooth l u b r i c a t i n g c l e a n s e r f o r t h e removal o f mascara.

Sequence: Raw M a t e r i a l : 1 L i p o v o l MOS-70* 1 L i p o n a t e NPGC-2 1 Uniphen P-23 2 L i p o s o r b L-20 2 L i p o n i c EG-1

P e r c e n t 82.45 15.00 0 . 3 0 1 . 2 5 1 . o o

* P a t e n t #4,659,573

Room Temperature P rocedure : 1 . Add Sequence #1 i n o r d e r of a d d i t i o n w h i l e m i x i n g a t medium

2 . Premix Sequence #2 and add t o Sequence #1 w i t h overhead m i x e r speed w i t h overhead m i x e r .

a t medium speed.

SOURCE: L i p o Chemicals Inc, : Formula No. 900

Pressed Powder Eyeshadow

Formul a : A : T a l c Z i n c S t e a r a t e I r o n Ox ide ( B l a c k ) A n t i m i c r o b i a l Mear lm ica SVA ( M e a r l ) Gemstone Moonstone GO04 B: A n t i o x i d a n t C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) C : Gemstone Moonstone GO04

% by Weight

2 5 . 0 0 3 .00 4 . 0 0

1 5 . 0 0 3 5 . 0 0

q . s .

q . s . 8 . 0 0

q . s .

P rocedure : T h o r o u g h l y b l e n d and d i s p e r s e A . Add B i n t o s u p p o r t v e s s e l .

Heat and m i x u n t i l u n i f o r m . Spray B i n t o A and c o n t i n u e b l e n d i n g . P u l v e r i z e and r e t u r n t o b l e n d e r . Add C and m i x u n t i l u n i f o r m .

SOURCE : W i t c o Corp. : Suggested Formul a t i on

Beauty Aids 79

Medicated Lip Balm

Beeswax P a r a f f i n wax AC 617 F i n s o l v TN C12-15 A1 k y l Benzoate

Combine & h e a t t o 95C. Cool t o 80C - add

Camphor

Pour i n t o room temp mo lds .

Lip Stick Base

C a s t o r O i l Po l ybu tene H100 AC 400 A R e f i n e d Lano l i n Candel i 11 a E u t a n o l G ( O c t y l Dodecanol ) Pol y g l y c e r y l D i -i s o s t e a r a t e

o/ow/w 1 0 . 0 0 10.00

6 . 0 0 54.00

2 0 . 0 0

%w/w 2 5 . 0 1 0 . 0

5 . 0 1 0 . 0 1 4 . 0 2 5 . 0 11 . o

P rocedure :

t h a t t h e p o l y e t h y l e n e i s homogeneous w i t h t h e b l e n d . B l e n d a l l i n g r e d i e n t s and h e a t t o 92-95C. Ho ld , t o be s u r e

Lipstick Base

1 I A-C P o l y e t h y l e n e 617A 2 . A c e t y l a t e d Lanol i n 3 . 2 - E t h y l h e x y l S t e a r a t e 4 . O z o k e r i t e 64W 5 . M i n e r a l O i l , 70 s s .

Procedure :

When w e l l mixed, c o o l t o 85C and pour i n t o molds. Weigh a l l i n g r e d i e n t s and h e a t t o l O O C , w i t h a g i t a t i o n .

R e f : 4676-48-8

%w/w 8 . 0

1 6 . 0 6 . 0

2 0 . 0 5 0 . 0

SOURCE: A1 1 i ed-Si gna l , I n c . : Suggested F o r m u l a t i o n s

80 Cosinetic and Toiletry Formulations

Men's Active Wrinkle Smoother

T h i s s o f t cream, wh ich c o n t a i n s U V - f i l t e r s , i s absorbed i n s t a n t l y and i s s u i t a b l e f o r men's s k i n . The c o m b i n a t i o n o f Dismut in-BT and Lac tomide e x e r t s p r o t e c t i n g , s k i n - f i r m i n g and a n t i - i n f l a m m a t o r y a c t i v i t y .

Item 1 2 3 4 5 6 7 8 9

10 1 1 12 13

I n g r e d i e n t s A ) A r l a t o n e 985

B r i j 721 A r l a m o l HD P a r s o l 1789 P a r s o l MCX 344 S i l i c o n F l u i d

B) D e i o n i z e d Water Phenon i p A t l a s G-2330 El h i b i n Lactomi de

C) D i smut i n-BT F r a g r a n c e : Vulcano 0/242294

Wei g h t % 5.00 3.00 10.00 1-00 2.00 1 . o o

67 I 90 0.50 3 IO0 3.00 3.00 0.30 0.30

Procedure : Heat t h e i n g r e d i e n t s o f f a t t y phase A ) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase 8 ) t o 75C. Under s t i r r i n g add phase B) t o phase A ) , c o o l t o 50C, homogenize and c o o l t o 30C. Then add i t e m s 12 and 13, one a f t e r a n o t h e r . A p p l i c a t i o n N o . A 035.0/02.96

Skin Tightening Gel

T h i s c l e a r , s o l i d g e l e x h i b i t s immed ia te s k i n t i g h t e n i n g p r o p e r t i e s and smoothens t h e f i n e w r i n k l e s on t h e s k i n . An i d e a l f r e s h - u p f o r an e v e n i n g a f t e r a t i r i n g d a y .

Itern I n g r e d i e n t s : 1 A) D e i o n i z e d Water 2 Phenoni p 3 I m i d a z o l i d i n y l Urea 4 Glucam E 10 5 Carbopol 940 6 B) T r i e t h a n o l ami ne 7 C) Pentacare-HP

Procedure : D i s s o l v e i t e m s 2-4 i n w a t e r (I). Under v i g o r o u s s t i r r i ng i n c o r p o r a t e i tern 5. N e u t r a l i z e w i t h i t e m 6. F i n a l l y add i t e m 7. A c l e a r , s o l i d g e l i s o b t a i n e d . A p p l i c a t i o n No. D 032.0/06.93

SOURCE: Pentapharm L t d : Suggested F o r m u l a t i o n s

Weight% 87.95 0.30 0.20 5.00 0.75 0.80 5.00

Beauty Aids 81

Moisturizing Gel

T h i s m o i s t u r i z i n g g e l l e a v e s a n o n - t a c k y m o i s t u r i z i n g f i l m on t h e s k i n . The Hypan f u n c t i o n s as a m o i s t u r i z i n g f i l m f o r m e r and he1 ps

S e q u e E c . 1 1 1 1 1 1 1 2 2 3 4 4 5 6 6

p r o v i d e an e l e g a n t f e e l I

Raw M a t e r i a l : Dei o n i zed Water Uniphen P-23 Me thy lpa raben Hampene Na2T Panthenol G l y c e r i n e Hexyl ene G1 y c o l L i p o n i c EG-1 Hypan SA l O O H Carbopol ETD 2001 (2% s o l ' n ) Dei o n i zed Water T r i e t h a n o l a m i n e , 99% Dow C o r n i n g 344 F l u i d Dei o n i zed Water U n i c i d e U-13

P e r c e n t 73.90

0 . 3 0 0 . 2 0 0 . 0 5 0 . 5 0 1 .50 1 . o o 0 . 5 0 0 . 1 5

17.50 1 . o o 0 . 6 5 1 . 5 0 1 - 0 0 0 . 2 5

P rocedure : 1 . Premix and h e a t Sequence #1 t o 80C w i t h overhead m i x e r a t

2 . Premix i n t o s l u r r y , Sequence #2 and add t o Sequence #1 a t 80C

3 . Heat Sequence #3 t o 70C and add t o b a t c h b r i n g i n g t e m p e r a t u r e

4. M i x Sequence #4 and add t o b a t c h a t 80C w i t h overhead m i x e r

5 . Cool b a t c h t o 55C and add Sequence #5 on overhead m i x e r w i t h

6 . Cool b a t c h t o 35C and add p remixed Sequence #6. 7 . Cool t o 25C.

SOURCE: Li po Chemicals I n c . : Formula No. 839

medi um speed w i t h p r o p e l 1 e r b l a d e .

w i t h overhead m i x e r a t medium speed.

back t o 80C on overhead m i x e r .

a t medium/high speed.

p r o p e l 1 e r b l ade.


Moisturizing Lip Balm

Formu 1 a : Candel i 11 a Wax Carnauba Wax M i c r o c r y s t a l l i n e Wax ( W i t c o ) S y n t h e t i c Beeswax PEG-75 Cocoa B u t t e r C 1 e a r l an Lanol i n A c e t a t e E s t e r L a n o l i n O i l M e t h y l Paraben P r o p y l Paraben BHA C a s t o r O i l

% by Weight 7 .00 2 . 0 0 1 . 0 0 1 .50 5 * 00 7 .00

10 .00 5 . 0 0 0 . 3 0 0 . 2 5 0 . 0 5

60.70

Procedure: Combine a l l i n g r e d i e n t s and h e a t w i t h s t i r r i n g t o 75-8OC.

M a i n t a i n t h e t e m p e r a t u r e a t 8OC w i t h s t i r r i n g u n t i l t h e m i x t u r e i s c l e a r and m o l t e n . Pour i n t o s t i c k s a t 75-8OC. T h i s p r o d u c t i s d e s i g n e d t o i m p a r t a s o f t , m o i s t u r i z e d f e e l t o l i p s and t o p r o v i d e a l i g h t g l o s s y e f f e c t . I t can be worn a l o n e o r o v e r l i p c o l o r f o r s h i n e .

Lipstick

____ Formula: Lexemul 515 C a s t o r O i l C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) Pigment W h i t e P r o t o p e t I S ( W i t c o ) Carnauba Wax Lexgard P

% by Weigh t 42 .00 36.80

8 . 0 0 5.00 4 . 0 0 4 . 0 0 0 . 2 0

Procedure: M e l t i n g r e d i e n t s t o g e t h e r and m ix u n t i l homogeneous. Pour

i n t o molds and c o o l . Lexemul 515 c o n t r i b u t e s t o t h i s f o r m u l a ' s s o f t n e s s and s p r e a d a b i l i t y .

SOURCE : W i tco Corp, : Suggested Formul at i ons

Beauty Aids 83

MPC - Milk Peptide Complex

MPC c o n t a i n s n a t u r a l p o l y p e p t i d e s f r o m m i l k , i n a c t i v a t e d fo rm. A p r o t e c t i v e env i ronmen t e x c l u s i v e l y compr i sed o f m i 1 k components such as l a c t a l b u m i n , l a c t o g l o b u l i n , l a c t o f e r r i n , l a c - t o s e and l a c t a t e p r o v i d e s f o r p r o d u c t s t a b i 1 i t y and mai n tenance o f b i o a c t i v i t y . B i o a c t i v i t y i s s t a n d a r d i z e d i n e v e r y b a t c h o f MPC t o a r e p r e s e n t a t i v e c o n c e n t r a t i o n range (EC50). I n v i t r o b i o a s - says i n c e l l c u l t u r e s and i n v i v o t e s t s on e p i t h e l i a l t i s s u e and on human s k i n g i v e p r o o f o f t h e b i o a c t i v i t y and c o s m e t i c b e n e f i t s o f MPC.

Anti Cellulite Emulsion, Type O/W with MPC - Milk Peptide Complex

I n g r e d i e n t s : a ) Emulgade 1000 N I

L a n e t t e 16 M y r i t o l 318 Phenoni p

b ) Water , d i s t i l l e d Carbopol 934

c ) Water , d i s t i l l e d Phenoni p T r i e t h a n o l ami ne

d ) Water , d i s t i l l e d Na3-Ci t r a t e , anhydrous MPC-Mi 1 k P e p t i de Complex

M a n u f a c t u r e : a ) M e l t and b r i n g t o app rox b ) M e l t and b r i n a t o aDDrox

Weight% 4 . 0 0 1 . o o

1 0 . 0 0 0 .30

5 0 . 0 0 0 . 4 0

23 .60 0 .30 0 .40

9 . 3 6 0 .14 0 . 5 0

70C; 70C and add t o a ) w i t h s t i r r i n g ;

. C o n t i n u e s t i r r i n g u n t i l c o o l e d t o a p p r o x . 30C; c ) D i s s o l v e and add t o a b ) ; d ) D i s s o l v e a t room t e m p e r a t u r e and add t o abc ) w i t h s t i r r i n g .

Perfume , homogenize.

SOURCE: Chemisches L a b o r a t o r i u m D r I K u r t R i c h t e r GmbH: Suggested F o r m u l a t i on


Night Cream Moisturizer

An e l e g a n t , g l o s s y , w h i t e , m o i s t u r e - r e t a i n i n g cream t h a t r e p a i r s t h e s k i n .

I n n r e d i e n t s : 1 . D i s t i 11 ed/Dei o n i zed Water 2 . A c r i t a m e r 940 (Carbomer) 3 . R i t a l o e 1X ( A l o e Vera G e l ) 4 . D i s o d i um 01 eami do PEG-2 S u l f o s u c c i n a t e 5. P r o p y l e n e G l y c o l 6 . Hydrogenated P o l y i sobutene 7 . D i m e t h i c o n e 8 . R i t a p r o - 1 6 5 ( G l y c e r y l S t e a r a t e and PEG-100 S t e a r a t e ) 9 . M i n e r a l O i l 1 0 . R i t a IPP ( I s o o p r o p y l P a l m i t a t e ) 11 .Tocophery l A c e t a t e 12. Tocophery l L i n o l e a t e 1 3 . R i t a IPM ( I s o p r o p y l M y r i s t a t e ) 1 4 . R i t a C e t e a r y l A l c o h o l 70/30 1 5 . T r i e t h a n o l a m i n e (99%) 16.Corn S t a r c h 17.Germaben I 1 1 8 . R a f f e r m i n e ( H y d r o l y z e d Soy F l o u r ) 19. R e d u c t i ne (Oat P r o t e i n )

%&& 61.65

0 .40 0 .20 2 .00 2 .00 5 . 0 0 2 .00 5.00 4.00 6 .00 0 . 2 5 0 .10 0.50 1 .50 0 . 4 0 1 . 0 0 1 . o o 3 . 0 0 4.00


i t e m s 3-5 and h e a t t o 75C. Combine i t e m s 6-14 and h e a t t o 75C. Add t o w a t e r and m i x . Add i t e m 1 5 . Cool t o 40C and add i t e m s

S l o w l y d i s p e r s e i t e m 2 i n i t e m 1 . M i x u n t i l d i s s o l v e d . Add

16-19. R e f . No. 122-1OC

Skin Nutrient Gel

I n g r e d i e n t s : 1 . D i s t i l l e d / D e i o n i z e d Water 2 . A c r i t a m e r 940 (Carbomer 940) 3 . Xanthan Gum 4. 1 , 3 B u t y l e n e G l y c o l 5 . R i t a s i l 190 ( D i m e t h i c o n e C o p o l y o l ) 6 . Shebu WS (Shea B u t t e r ) 7 . TEA @ 99% 8 . Promois ECP ( C o l l a g e n ) 9 . G l y d a n t 10 .F rag rance 11 . R i t a HA C-1 -C (Sod i um H y a l u r o n a t e )

w 87.40

0 .50 0 .10 5 .00 0 . 1 0 1 . o o 0 .40 0 . 2 0 0 .20 0 . 1 0 5.00


Add i t e m s 4, 5 and 6 s e p a r a t e l y . Add TEA u n t i l b a t c h t h i c k e n s . Add i t e m s 8,9,10 and 11. The pH o f a g e l i s 5.5

SOURCE: R . I . T . A . Corp,: Suggested F o r m u l a t i o n s


R e f . No. 122-1036

Beauty Aids 85

Nonionic L i q u i d Makeup

Veegum p r o v i d e s a l i q u i d makeup w i t h u n i f o r m , shear coverage. Veegum s t a b i l i z e s t h e e m u l s i o n w h i l e i n h i b i t i n g p igment s e t t l i n g . The 5 : l Veegum/xanthan gum r a t i o p r o v i d e s opt imum v i s c o s i t y and f l o w a b i l i t y . The b l e n d o f o i l phase i n g r e d i e n t s i s des igned t o g i v e e m o l l i e n c e w i t h o u t an o i l y o r g r e a s y f e e l . A n o n i o n i c e m u l s i f y i n g system g i v e s maximum s t a b i l i t y t o t h e f o r m u l a a t pH 5 . 5 - 6 . 0 . The f o r m u l a i s des igned s p e c i f i c a l l y f o r o i l y s k i n .

I n s r e d i e n t : A : Veegum, Magnesi um A1 umi num S i 1 i c a t e

R h o d i g e l , Xanthan Gum D e i o n i z e d Water G1 y c e r i n C i t r i c A c i d

B: T a l c T i t a n i um D i o x i d e I r o n Ox ides

W t .%* 0 . 7 5 0 . 1 5

67.10 4 . 0 0 0.30

5 . 0 0 5 . 0 0 3 . 7 0

C : M i n e r a l O i l (and) L a n o l i n A l c o h o l ( R i t a c h o l ) 5 .00 M y r i s t y 1 M y r i s t a t e (Crodamol MM) 2 .50 Hydrogenated P o l y i s o b u t e n e ( P o l y s y n l a n e ) 2 . 0 0 01 e y l A1 coho1 2 .00 S t e a r y l A l c o h o l (and) C e t e a r e t h - 2 0 (Cosmowax K ) 2 .oo P o l y s o r b a t e 8 5 (Tween 85) 0 . 5 0

D : P r e s e r v a t i v e q . s .

Procedure :

a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e m i x i n g u n t i l smooth. Add t h e g l y c e r i n and c i t r i c a c i d . M i x u n t i l smooth. M i x P a r t B ( g r i n d i f n e c e s s a r y ) u n t i l homogeneous. Add P a r t B t o P a r t A and mix u n t i l u n i f o r m . Heat P a r t s A+B t o 60-65C. Heat P a r t C t o 60-65C. Add P a r t C t o P a r t s A+B and mix w h i l e c o o l i n g . A t 40C, add P a r t D and mix u n t i l u n i f o r m .

B lend Veegum and R h o d i g e l . S l o w l y add t o t h e w a t e r , w h i l e


SOURCE: R . T . V a n d e r b i l t Co., I n c . : Veegum F o r m u l a t i o n No. 349


Seauence : 1 1 1 1 1 2 2 2 2 2 3 4 4 4 4 4 5 5

*Paten t

Oil Free Make-Up with Hypan SR150H

Raw M a t e r i a1 : Dei o n i zed Water Hypan SR150H Methy lparaben P r o p y l ene G1 y c o l T r i e t h a n o l ami ne 99% T i t a n i um D i o x i d e #3328 I r o n Oxide Y e l l o w I r o n Oxide Red I r o n Ox ide B l a c k Orgaso l 2002D Nat Cos D e i o n i z e d Water L i p o v o l MOS-70* L i ponate TDTM L i p 0 GMS-450 L i p 0 S t e a r i c A c i d Propy lparaben D e i o n i z e d Water U n i c i d e U-13

#4,659,573

P e r c e n t 48.14

0.01 0.25 4.60 0 I 9 0 8.00 0.80 0.40 0.10 1 .oo

20.00 10.00 1 .oo 1 - 0 0 2.50 0.20 1 . o o 0.10

Procedure : 1 .

2.

3.

4.

5.

6.

7 .

I n t o main k e t t l e , combine Sequence #1 i n g r e d i e n t s under L i g h t n i n ' m i x i n g and h e a t t o 60-7OC. I n aux i 1 i a r y k e t t l e , combine Sequence # 2 i n g r e d i e n t s and add t o Sequence #1 s l o w l y under L i g h t n i n ' m i x i n g . Pass combined Sequences # l and #2 t h r o u g h c o l l o i d m i l l and r e c i r c u l a t e u n t i 1 p igments a r e e v e n l y d i s p e r s e d . R inse c o l l o i d m i l l u s i n g Sequence #3 i n g r e d i e n t and add t o Sequences #1 and #2 under L i g h t n i n ' m i x i n g . Heat combined b a t c h t o 76C. I n a u x i l i a r y k e t t l e combine Sequence #4 under L i g h t n i n ' m i x i n g and h e a t t o 82C. A t p r o p e r t e m p e r a t u r e add Sequence #4 i n g r e d i e n t s t o b a t c h under sweep m i x i ng, mai n t a i n i ng t e m p e r a t u r e u n t i 1 emu1 s i f i ca- t i o n i s comple te . B e g i n c o o l i n g t o 35CJ s w i t c h i n g t o s low sweep m i x i n g as b a t c h t h i c k e n s . A t 35C add premixed Sequence #5 i n g r e d i e n t s t o b a t c h and c o o l t o 25C.

SOURCE: L ip0 Chemicals I n c . : Formula No. 875

Beauty Aids 87

Oil Moisturizer

M i n e r a l O i l L a n o l i n X - t r a Deo O c t y l D i m e t h y l PABA Beeswax R i t a v e n a 5 Borax DL Panthenol S o r b i t a n Monoo lea te C o l o r Kathon CG D i s t i 1 1 ed Water

Wt% 24.75

5 .00 0 . 5 0 3 . 0 0 1 .50 0 . 2 5 0 . 1 0 0 .80 0 . 0 6 0 . 2 0

6 3 . 8 4

pH: 7 . 1 V i s c o s i t y : 8500 c p s S t a b i 1 i t i e s :

4F: S e p a r a t i o n a f t e r 1 c y c l e 40F: No change a f t e r 6 weeks

11OF: No change a f t e r 6 weeks C e n t r i f u g e R e s u l t s : A f t e r 20 m i n u t e s a t 5000 RPM

D e s c r i p t i o n o f System: W i t h o u t p e t r o l a t u m w i t h R i t a v e n a

Formul a t i on 11 4-34

S1 i g h t s e p a r a t i o n

5 ( 1 . 5 % )

Oil Moisturizer with Ritavena 5

I n g r e d i e n t s : 96w/w P a r t A : 1 . M i n e r a l O i 1 24 .75 2 . L a n o l i n , X - t r a Deo 5 .00 3 . O c t y l D i m e t h y l PABA 0 . 5 0 4 . Beeswax 3 . 0 0 P a r t B: 5. R i t a v e n a 5 1 . 5 0

P a r t C : 7 . D i s t i l l e d Water 53.60 8 . Borax ( 9 9 . 5 % Pure) 0 . 2 5

1 0 . S o r b i t a n Monoo lea th 0 . 8 0 P a r t D : 11 . Fragrance 0.30 12.Kathon CG 0 . 2 0 Compoundi ng Procedure :

w h i l e m a i n t a i n i n g 165F f o r 10 m i n u t e s . Premix P a r t B i n a b l e n d e r f o r 2 m i n u t e s . Add P a r t 0 t o m i x t u r e . M i x u n t i l u n i f o r m . Cool t o 120F. Add P a r t 0 . M i x .

6 . D i s t i l l e d Water (1OOC) 10 .00

9 . R i t a p a n DL 0 .10

Heat P a r t s A and C t o 165F. Pour P a r t A i n t o P a r t C . M i x

F o r m u l a t i o n 11 4-34

SOURCE: R,I.T.A. C o r p , : R i t a v e n a 5 : Suggested F o r m u l a t i o n s


O/W-Skin MilkManufacturing at room temperature possible

Recipe: A Hos taphat KML

M i n e r a l o i 1, l o w v i s c o s i t y Almond o i 1 I s o p r o p y l p a l m i t a t e A n t i o x i d a n t

Wt% 3.00

12.00 5.00 5 . 0 0

q . s .

B Carbopol 980 0 . 4 0

C C a u s t i c soda s o l u t i o n (10%) A q u a m o l l i n BC p d r . h . c . C i t r i c a c i d (10%) Water P r e s e r v a t i v e

2 .70 0 .10 0 . 2 5

71.25 q . s .

D Fragrance 0 . 3 0

Procedure : 1 S t i r B i n t o A, t h e n add C and s t i r w e l l . 2 S t i r D i n t o 1 . 3 Homogenize t h e e m u l s i o n .

Formula A VI /1150

O/W-Skin MilkManufacturing at room temperature possible

Recipe : A Hostaphat KL 340 N

H o s t a c e r i n DGI M i n e r a l o i l , low v i s c o s i t y I s o p r o p y l p a l m i t a t e C e t i o l 868

B Carbopol 980

C C a u s t i c soda s o l u t i o n (10%) Water P r e s e r v a t i ve

D F r a g r a n c e

Procedure : 1 M i x A and 8, t h e n add C and s t i r w e l l 2 Add D t o 1 w h i l e s t i r r i n g . 3 F i n a l l y homogenize t h e e m u l s i o n .

Formula A VI /1118

wt% 1 . 5 0 2 .00 8 .00 6 .00 5 . 0 0

0.40

1 . 6 0 75.20

4 . s .

0.30

SOURCE: Hoechst : Gu ide Rec ipes f o r t h e Cosmet ic I n d u s t r y

Beauty Aids 89

O/W-Skin Milk"Contains no ethylene oxide", manufacturing at room temperature

possible

Recipe: A H o s t a c e r i n D G I

M i n e r a l o i l , l o w v i s c o s i t y I s o p r o p y l p a l m i t a t e Squal ane Eu tano l G Walnut o i 1 A n t i o x i d a n t

B Carbopol 980 C Hostapon KCG

A q u a m o l l i n BC p d r . h . c . C i t r i c a c i d (10%) C a u s t i c soda s o l u t i o n (10%) PEG 400 Hoechst P o t a s s i um S o r b a t e Germa l l I 1 Water

D F rag rance Procedure : 1 S t i r B i n t o A, t h e n add C and s t i r w e l l . 2 Add D t o 1 . 3 F i n a l l y homogenize t h e e m u l s i o n .

Formula A VI /1253

O/W-Skin Milk"contains no ethylene oxide"

Rec ipe : A H o s t a c e r i n DGMS

M i n e r a l o i 1, h i g h v i s c o s i t y I s o p r o p y l p a l m i t a t e C e t i o l 868

B Carbopol 980 C Hostapon KCG

C a u s t i c soda s o l u t i o n (10%) G1 y c e r i n Water P r e s e r v a t i ve

D F rag rance Procedure : 1 M e l t A a t c a . 70C, t h e n add B . 2 Heat C t o c a . 70C. 3 S t i r 2 i n t o 1 and s t i r u n t i l c o o l . 4 A t c a . 35C add D t o 3 . 5 F i n a l 1 y homogeni ze t h e emu1 s i on.

Formula A VI/1252

Wt% 2 . 0 0 3 . 0 0 4 .00 2 . 0 0 4 .00 3 . 0 0

0 . 5 0 0 . 8 0 0 . 1 0 0 . 5 0 1 . 8 0 3 . 0 0 0 . 2 5 0 . 2 5

74.40 0 .30

q . s .

Wt% 2 . 0 0 8 . 0 0 5 . 0 0 4 .00 0 . 3 0 0 .60 1 . 2 0 4 . 0 0

74.60

0 . 3 0 q . s .

SOURCE: Hoechs t : Guide Recipes t o t h e Cosmet ic I n d u s t r y


Petroleum Oil/Petroleum Wax Free Lipstick

F o r m u l a t i n g Des ign and Advantages: T h i s l i p s t i c k i s a creamy s t i c k t h a t does n o t use any

p e t r o l e u m o i l s o r waxes i n t h e f o r m u l a , n o r does i t use any s y n t h e t i c raw m a t e r i a l s t h a t have p e t r o l e u m p r o d u c t s i n i t .

O i l Phase I : wt% Hydroxy P o l y e s t e r ( K o s t e r Keunen) 3 . 7 R i c e Bran O i l ( K o s t e r Keunen) 5 . 0 O c t y l P a l m i t a t e ( I n o l e x ) 9 . 0 C a s t o r O i l ( A l n o r ) 3 8 . 0 PEG Carnauba ( K o s t e r Keunen) 1 . 3 T i t a n i u m D i o x i d e Powder ( W h i t t a k e r C&D) 2 . 0 S i l i c o n e O i l 556 (Dow C o r n i n g ) 1 0 . 0 D&C Red #30 ( C l a r k e ) 3 . 0 O i l Phase 1 1 : K80-D22 ( K o s t e r Keunen) 5 . 0 S y n t h e t i c C a n d e l i l l a ( K o s t e r Keunen) 9 . 0 Hexanedi ol Behenyl Beeswax ( K o s t e r Keunen) 7 . 0 Deodor i zed Orange Wax ( K o s t e r Keunen) 4 . 0 P rocedure :

C o o l . Repeat two more t i m e s . Reheat t o 75C and add Phase I 1 t h a t has been hea ted t o 75C. Cool t o 65C and pour i n t o mo lds . A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t :

V a r i o u s o i l s u b s t i t u t i o n s can be made t o s u i t f o r m u l a .

M i x Phase I, h e a t t o 75C b r e a k i n g up any s m a l l agg lomera tes .

Lip Gloss with Sun Protection


o f t h e PEG Carnauba and Deodor i zed Orange Wax w h i l e a d d i n g m o i s t u r e and c o l o r t o t h e l i p s .

T h i s p r o d u c t p r o t e c t s t h e l i p s f r o m t h e sun, w i t h t h e h e l p

Formul a : __ W t % 1 . PEG Carnauba ( K o s t e r Keunen) 5 . 0 2 . Deodor i zed Orange Wax ( K o s t e r Keunen) 5 . 0 3. Whi t e P e t r o l e u m (Wi t c o ) 2 6 . 1 4 . Shea B u t t e r ( K o s t e r Keunen) 5 . 0 5 . J o j o b a O i l ( J o j o b a Growers) 2 . 0 6 . Hexaned io l Behenyl Beeswax ( K o s t e r Keunen) 1 0 . 5 7 . C a p r y l i c / C a p r i c T r i g l y c e r i d e ( I n o l e x ) 4 5 . 0 8 . Gamma Orzano l ( K o s t e r Keunen) 0 . 6 9 . P igments 0 . 8 P rocedure :

Combine 9 , 1 , 2 , h e a t t i l l d i s p e r s e d . Add t h e r e s t o f t h e i n g r e d i e n t s t o t h e b a t c h , excep t t h e gamma o r z a n o l wh ich s h o u l d be added l a s t , a f t e r e v e r y t h i n g has been d i s p e r s e d . A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t :

To make t h e p r o d u c t w i t h g r e a t e r g l o s s i t wou ld n o r m a l l y r e q u i r e more p e t r o l e u m . To make t h e p r o d u c t s o f t e r l e s s wax s h o u l d be used. SOURCE: K o s t e r Keunen, I n c , : A Guide t o N a t u r a l F o r m u l a t i n g

Beauty Aids 91

Pressed Powder Blush

Formula: A : T a l c Z i n c S t e a r a t e S h i n j u lOOT ( M e a r l ) Mear l i t e GBU (Mear l ) T i m i c a S p a r k l e 11OP ( M e a r l ) C l o i s o n n e ' C e r i s e Flambe 5502 ( M e a r l ) C1 o i sonne' B1 ue F1 ambe 6502 I r o n Ox ide (Brown) I r o n Oxide ( R u s s e t ) I r o n Ox ide (Tan) A n t i m i c r o b i a1 s B: Fragrance A n t i o x i d a n t C a r n a t i o n M i n e r a l O i 1 (Wi t c o ) S o r b i t a n D i i s o s t e a r a t e C : Flamenco Superpear l 120C ( M e a r l ) C l o i s o n n e ' Monarch Gold 233X ( M e a r l )

% by Weight

50 .30 7 . 0 0

11 . o o 6 . 5 0 1 . 2 5 1 . 1 0 2 .60 1 . 7 5 2 .00 1 - 0 0

q . s .

q . s . q . s .

2.90 2 .90

4.70 5 . 0 0

Procedure :

I n s e p a r a t e v e s s e l combine 6 and h e a t and mix u n t i l u n i f o r m . Spray B i n t o p remixed A and c o n t i n u e b l e n d i n g . P u l v e r i z e and r e t u r n t o b l e n d e r . Add C and mix u n t i l u n i f o r m .

B1 end and d i s p e r s e A i n d r y b l endi n g / d i s p e r s i ng equipment I

Pressed Powder Eyeshadow

Formula: A : M e a r l t a l c TCA ( q . s . t o 100) ( M e a r l ) Z i n c S t e a r a t e Mear lmica CF ( M e a r l ) Chromi um Oxide Green I r o n Ox ide ( Y e l l o w ) A n t i m i c r o b i a1 B : A n t i o x i d a n t Squal ane C a r n a t i o n M i n e r a l O i l ( W i t c o )

% by Wei a h t

45.00 6 . 0 0

34 .00 3.00 6 . 0 0

q . s .

q . s . 2 . 5 0 3 - 5 0

Procedure : Thorough ly b l e n d and d i s p e r s e Phase A i n a p p r o p r i a t e d r y

b l endi ng /d i s p e r s i ng equipment . Add Phase B i n g r e d i e n t s i n t o a s u p p o r t v e s s e l . Heat and mix u n t i l u n i f o r m . Spray phase B i n t o p remixed A and c o n t i n u e u n t i l u n i f o r m . P u l v e r i z e and p r e s s .



Purified Bentonite Refining Mask

Veegum HS i s c l a s s i f i e d as “ P u r i f i e d B e n t o n i t e ” i n t h e USP/NF. T h i s mask f o r m u l a t i o n i s f o r a l l s k i n t y p e s and t a k e s advantage o f t h e r e c o g n i z e d a b s o r b a t i v e and c l e a n s i n g p r o p e r t i e s o f b e n t - o n i t e . A p p l y a t h i n c o a t i n g t o t h e f a c e . A l l o w i t t o d r y o r remove i t a f t e r 10 t o 15 m i n u t e s b e f o r e i t i s c o m p l e t e l y d r y . R i n s e o f f w i t h c l e a r w a t e r and a s o f t c l o t h o r c o t t o n b a l l .

I n g r e d i e n t : A : Veegum HS, Magnesium Aluminum S i l i c a t e

Rhodi g e l , Xanthan Gum D e i o n i z e d Water

W t .%* 4 . 0 0 0 . 3 0

43 I 70

B: Sucrose 15.00

DEA-Oleth-3 Phosphate ( C r o d a f o s N-3 N e u t r a l ) 5.00 G l y c e r i n 10.00

C: P r o p y l ene G l y c o l (and) Grape E x t r a c t (and) Hyper icum E x t r a c t (and) A r n i c a E x t r a c t (and) W i t c h Hazel E x t r a c t (and) Horse Chestnu t E x t r a c t (and) I v y E x t r a c t ( P h y t e l ene Compl ex EGX 243) 3 .00

P r o p y l e n e G l y c o l (and) Ca lendura E x t r a c t (and) Chamomile E x t r a c t (and) L i n d e n E x t r a c t (and) C o r n f l o w e r E x t r a c t (and) M a t r i c a r i a E x t r a c t (and) Hyper icum E x t r a c t ( P h y t e l e n e Complex EGX 244) 3 .00

A1 l a n t o i n 1 . o o Oat F l o u r ( S t e r - 0 - P r o ) 10.00 Z i n c Ox ide 5 . 0 0

D: P r e s e r v a t i v e q.s.

Procedure : Dry b l e n d t h e Veegum HS and R h o d i g e l . Add them t o t h e w a t e r ,

a g i t a t i n g a t maximum a v a i l a b l e shear u n t i l smooth. Add t h e P a r t B i n g r e d i e n t s and mix u n t i l smooth. Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r shown and m i x each u n t i l u n i f o r m . Add P a r t D and mix u n t i 1 u n i f o r m .

* As r e c e i v e d b a s i s

SOURCE: R . T . V a n d e r b i l t Co., I n c . : Veegum F o r m u l a t i o n No. 419

Beauty Aids 93

Silky Shadow

Phase#: I n g r e d i e n t s : Weight% 1 1625 T a l c 17.60 1 S i l k Mica 30.00 1 B i r o n B-50 5.00 1 S i l t e x M Super 3 .50 1 Z i n c S t e a r a t e #695 3 .50 1 Hubersorb 600 0 . 5 0 1 7055 (Ye1 low i r o n o x i d e ) 10 .00 1 7054 (Red i r o n o x i d e ) 7 .50 1 7133 ( B l a c k i r o n o x i d e ) 2 .00 1 M e t h y l Paraben 0 . 2 0 1 P r o p y l Paraben 0 . 1 0 2 T r i v e n t OC-G 9 . 0 5 2 Emerest 2452 0 . 5 0 2 Schercermol CP 0 I 50 2 BHA 0 . 0 5 3 T i m i r o n MP-24 Go ld K a r a t 1 0 . 0 0

Procedure : Combine phase # 1 . P u l v e r i z e w i t h a hammer m i 11, p a s s i n g t w i c e

t h r o u g h an 0.027" h e r r i n g bone s c r e e n . Combine phase # 2 . Heat t o 65C w i t h s t i r r i n g . Spray o n t o b a t c h w h i l e a g i t a t i n g t h e b u l k . P u l v e r i z e once t h r o u g h t h e 0 . 0 2 7 " s c r e e n . Add phase #3. B l e n d i n w i t h g e n t l e a g i t a t i o n . Do n o t p u l v e r i z e .

F o r m u l a t i o n P 2133

Powder Eyeshadow

Supra T a l c B i r o n ESQ M i c r o c e l E Orgasol 2002 UD Nat Cos 43001 (manganese v i o l e t ) 43W1810 ( u l t r a m a r i n e b l u e ) 33-5198 ( b l a c k i r o n o x i d e ) Mica M-RP Magnesi urn M y r i s t a t e M e t h y l Paraben P r o p y l Paraben

!v&6 9 . 7 0

20 * 00 1 . o o 5 .00

15.00 15 .00

2 . 0 0 15 .00

9 - 0 0 0 . 2 0 0 . 1 0

Ceraphyl 847 O c t y l d o d e c y l S t e a r o y l S t e a r a t e 6 . 9 5 Emerest 2452 0 . 5 0 C e t y l P a l m i t a t e 0 .50 Oxynex LM 0 . 0 5 M a n u f a c t u r i n g Procedure :

Combine t h e p igments and f i l l e r s w i t h t u m b l i n g a g i t a t i o n . P u l v e r i z e u s i n g a hammer m i l l t w i c e t h r o u g h an 0 . 0 2 7 " sc reen. Combine t h e o i l phase. Heat t o 70C u n t i l homogeneous. Spray o n t o b a t c h w h i l e a g i t a t i n g .

F o r m u l a t i o n P3-57-6



Silky Smooth Emollient Liquid Makeup I n g r e d i e n t : A : Veegum P l u s , Magnesium Aluminum S i l i c a t e (and)

C e l l u 1 ose Gum D e i o n i z e d Water G l y c e r e t h - 2 6 ( L i p o n i c EG-1) T r i e t h a n o l a m i n e , 99%

T a l c T i t a n i um D i o x i d e

M i n e r a l O i l (and) L a n o l i n A l c o h o l (Amerchol L-101) I s o p r o p y l P a l m i t a t e I s o p r o p y l M y r i s t a t e Hydrogenated Soy G l y c e r i d e (Myvero l 18-06) S t e a r i c A c i d XXX D i o c t y l Adi p a t e (and) O c t y l S t e a r a t e (and) O c t y l

P a l m i t a t e ( 1 . 1 % by w t Wickenol 161 + 1 . 0 % by w t W i c k e n o l 163)

B: I r o n Ox ides

C: I s o p r o p y l I s o s t e a r a t e

Vanseal CS , Cocoyl S a r c o s i n e L i t h i u m S t e a r a t e

D: P r e s e r v a t i v e

W t .%*

1 .oo 5 3 . 5 0 10.50 0 . 7 5 1 . 2 9 1 .oo 3,OO 9 .06 6 . 5 0 4 .00 2 .50 2.10 1 . 6 0

2 . 1 0 1.00 0 . 1 0

a . s ~~ ~

Heat t h e water t o 70-75C. Add t h e Veegum P l u s and mix a t ’ 1 8 0 0 r p m f o r 20 m i n u t e s . S l o w l y m i x i n t h e r e m a i n i n g P a r t A i n g r e d - i e n t s . M i x t h e P a r t B i n g r e d i e n t s t h o r o u g h l y i n t o P a r t A u n t i l u n i f o r m . M a i n t a i n t e m p e r a t u r e a t 70 t o 75C. Heat P a r t C t o 70 t o 75C and add t o P a r t s A+B. Mix u n t i l c o o l i n g . A t 40C, add P a r t D and mix u n t i l u n i f o r m .

Mascara I n g r e d i e n t s : W t .%* A : Demi n e r a l i zed Water 56.10

Veegum, Magnesium Aluminum S i l i c a t e 1 . 2 0 B u t y l ene G1 y c o l 10 .00 C e l l u l o s e Gum (CMC 7MF) 0.60 Methy lparaben 0 .20 D i a z o l i d i n y l Urea (Germal l 11) 0 .20 T r i e t h a n o l a m i n e , 99% 1 . 5 0

B: C a n d e l i l l a Wax 10 .00 S t e a r i c A c i d 7 .00 I s o s t e a r i c Acid 1 .oo M i n e r a l O i l 2 .00 P r o p y l p a r a b e n 0 . 2 0

C: I r o n Ox ide (C33-134 Cosmet ic B l a c k ) 10.00

k e t t l e , f i t t e d w i t h a homogenizer t y p e d i s p e r s e r , weigh t h e f o l l o w i n g : water ; s p r i n k l e i n t h e Veegum; i t i s t h o r o u g h l y d i s p e r s e d add t h e b u t y l e n e g l y c o l ; d u s t i n t h e CMC; when t h e CMC i s c o m p l e t e l y d i s p e r s e d add t h e r e m a i n i n g P a r t A i n g r e d i e n t s . Dust i n P a r t C i n g r e d i e n t s w i t h h i g h m i l l i n g and r a i s e t h e temp- e r a t u r e t o 76C. Heat P a r t €3 t o 79C and mix u n t i l u n i f o r m . Add P a r t B t o t h e main k e t t l e w i t h h i g h m i l l i n g f o r 15 m i n . Sweep c o o l t o room t e m p e r a t u r e t o e l i m i n a t e t h e a i r .

SOURCE: R . T . V a n d e r b i l t Co., I n c . : Formulas No. 460 & Sun Chemical

I n t o a s i d e k e t t l e add a l l P a r t B i n g r e d i e n t s . I n t o t h e main


Beauty Aids 95

Topical Spray Powder

I n g r e d i e n t s : Anhydrous E t h a n o l AMP Regu la r Dermacry l -79 D r y - F l o PC Prope l 1 a n t A-46

% b y We igh t 42.00

0 . 3 8 2 . 0 0

10.00 45.62

P rocedure : D i s s o l v e AMP i n e t h a n o l . W h i l e m a i n t a i n i n g good a g i t a t i o n ,

s l o w l y s i f t i n Dermacry l -79 . When s o l u t i o n i s comp le te , s i f t i n D r y - F l o PC. M i x w e l l u n t i l homogeneous. F i l l cans.

Va lve : S e a q u i s t NS-41 Stem O r i f i c e : 2 x 0 .025 Gasket : Buna P 0.042" THK Code 150 cup : R e g u l a r , Epoxy Top, Lamina te Bot tom Dimpled,

Code 1610, Tapersea l S p r i n g : 0 .020 ss Seat : None Body : 0.062 S t a n d a r d Vapor Tap: 0 .018" Tub ing I D : 0 .165" A-D D i m : A c t u a l 8 A c t u a t o r S t y l e : E x c e l 1 100 M i s t y O r i f i c e S i z e : 0 .018" M i s t y

F o r m u l a t i o n PF-0373 sugges ted by N a t i o n a l S t a r c h & Chemi c a l C O . (7423-858)

Hydroalcoholic Fragranced Spray Gel

I n g r e d i e n t s : S t a b i l e z e XL-80W 200 p r o o f e t h a n o l

V a n i l l a BB-36943 AMP-95

Procedure : 1 . Add E t h a n o l t o S t a b i l e z e XL-80%' and m ix w e l l . 2 . Add AMP-95 t o t h e b a t c h and m i x w e l l . 3 . Add a f r a g r a n c e and m ix w e l l . 4 . Package.

P h y s i c a l C h a r a c t e r i s t i c s : A c l e a r y e l l o w i s h s p r a y a b l e g e l . Apparent pH: 6 . 0 S t a b i l i t y : S t a b l e a t RT f o r 3 months.

Recommended S p r a y e r : Calmar Mark I V

SOURCE: Angus Chemical Co. : P r o d u c t F o r m u l a r y

F o r m u l a t i o n PF-0378 sugges ted b y ISP (10227-5)

% b y Weight 24 .60 -17 .14 70.00-77.59

0 .40 - 0 . 2 7 5 . 0 0 - 5 . 0 0


Vitamin F Skin Moisturizer

Formula : A : S t e a r i c A c i d C e t i o l MM M y r i s t y l M y r i s t a t e C a r n a t i o n M i n e r a l O i 1 (Wi t c o ) L a n e t t e 0 C e t e a r y l A l c o h o l V i t a m i n F F o r t e CLR B : Water D o w i c i l 200 Carbopol 941 C: T r i e t h a n o l ami ne D : D&C Y e l l o w No. 5 ( 0 . 1 a s . ) F r a g r a n c e

% by Weight

4.0 5 . 0

1 . 5 1 . o

1 0 . 0

76 .8 0 . 1 0 . 2

1 . o

0 . 2 0 . 2

Procedure : M i x and h e a t P a r t A t o 65-70C. D i s p e r s e Carbopol 941 i n t o

w a t e r and mix P a r t B . Add C t o B and h e a t t o 65-7OC. Add B-C t o P a r t A and mix u n t i l c o o l e d t o 40C. Add D when c o o l e d t o 35-4OC. A d j u s t pH t o 7 . 5 .

Body Smoother

Formula: O i l Phase: Super S t e r o l E s t e r Po l awax (Croda) Crodaco l C-95 (Croda) C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) Water Phase: Croquat M (Croda) G1 y c e r i ne Germaben I I Water , Dei o n i zed Hydrosoy 2000/SF (Croda)

% by Weight

10 .0 7 . 5 2 . 0

1 0 . 0

2 . 0 5 . 0 1 . o

61 . 5 1 . o

Procedure : Heat o i l phase t o 75-78C. Heat w a t e r phase t o 75-8OC. Add

w a t e r t o o i l w i t h good a g i t a t i o n . M i x . Cool t o 45C. Add Hydrosoy 2000/SF.


Beauty Aids 97

Waterproof Special Effects Mascara

Phase # : 1 S o l t r o l 100 1 P o l y e t h y l e n e 6A 1 C a n d e l l i 1 a wax 1 OH1 an

2 P e n t a l y n C 2 S o l t r o l 100

3 M e t h y l Paraben 3 P r o p y l Paraben

4 Z i n c S t e a r a t e

5 Bentone Gel SS71

6 P e a r l Pigment

Rona P e a r l Pigment Combinat ions : A D i c h r o n a BG B Co lorona Dark B l u e C T r a n s p a r e n t B l a c k D Co lorona Magenta E Col o rona Ma] e s t i c Green F Co lorona Dark B l u e G D i c h r o n a BG

Wt% 30 .95 11 . o o

4 .50 0 .25

2 . 0 0 2 . 0 0

0 . 2 0 0 . 1 0

1 . o o

35 .00

13 .00 13 .00 13 .00 10 .00 10 .00 1 0 . 0 0 10 .00

Procedure :

t o 65-70C w i t h c o n s t a n t L i g h t n i n ' m i x e r a g i t a t i o n u n t i l c l e a r .

Combine phase # l i n a c l o s e d v e s s e l . Heat t o 90-95C w i t h L i g h t n i n ' m i x e r a g i t a t i o n . When c l e a r , add t o r e m a i n i n g phases i n o r d e r , i n s u r i n g t h a t each i s f u l l y d i s p e r s e d b e f o r e proceed- i n g . Cool t o 30C w i t h s idesweep a g i t a t i o n . A t 55C, check f o r s o l v e n t 1 oss and a d j u s t i f necessary .

SOURCE: Rona/EM I n d u s t r i e s , I n c . : F o r m u l a t i o n AN251

Prepare phase #2 i n advance: combine i n a c l o s e d v e s s e l . Heat


W/O Liquid Foundation

I n g r e d i e n t s : Phase A : C e t y l D ime th i cone Copo lyo l ( A b i 1 EM-90) P o l y g l y c e r y l - 3 O l e a t e ( I s o l a n GO-33) C e t y l D ime th i cone ( A b i l Wax 9801) O c t y l P a l m i t a t e ( T e g o s o f t OF) Hydrogenated C a s t o r O i l Beeswax

Phase 6: Cyc lometh i cone

Phase C : Red, Y e l l o w , B l a c k I r o n Ox ides T i t a n i urn D i o x i d e T a l c

Phase D : B u t y l e n e G1 y c o l Water Sodi urn C h l o r i d e

Phase E : F rag rance

- Weight%

2 . 0 0 1 . o o 1 . o o 1 . 0 0 0 . 4 0 0 . 8 0

18 .00

3.00 7 . 8 0 1 . 7 0

2 . 8 0 6 0 . 0 0

0 . 5 0

Q . S

Procedure : 1 . Combine i n g r e d i e n t s o f Phase A . M ix and h e a t t o 85-9OC. M i x

2 . Cool t o 50C. Add Cyc lometh i cone . 3. Add i n g r e d i e n t s o f Phase C . M ix t h o r o u g h l y t o d i s p e r s e . 4 . Cool t o 50C w i t h m i x i n g . 5 . Combine i n g r e d i e n t s o f Phase D a t ambien t t e m p e r a t u r e . Add

Phase 0 s l o w l y t o A / B / C m i x t u r e w i t h s l o w a g i t a t i o n . 6 . I n c r e a s e a g i t a t i o n speed a f t e r a l l o f Phase D i s added.

( 1 0 - 1 5 m i n u t e s ) . 7 . Homogen i ze. 8 . F rag rance ,

SOURCE: Goldschmi d t Chemical Corp , : Suggested Formul a t i on

u n t i l u n i f o r m .

Beauty Aids 99

W/O Moisturizing Emulsion

I n g r e d i e n t s : Weight% A) M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 8 .00

Dynacer i n 660 (01 e y l E r u c a t e ) 5 .00 S o f t i s a n 645 ( B i s - d i g l y c e r y l P o l y a c r y l a d i p a t e - 2 ) 4.00 I m w i t o r 780K ( I s o s t e a r y l D i g l y c e r y l Succ i n a t e ) 3 . 0 0 A b i l WE 09 (Polyglyceryl-4-Isostearate (and ) C e t y l

D ime th i cone C o p o l y o l (and) Hexy l L a u r a t e ) 4 .00 Lunacera M (Hydrogenated M i c r o c r y s t a l l i n e Wax) 1 . 0 0

8) D-Panthenol P r e s e r v a t i ve Water

2.00

67.00 q . s .

C) Tocophery l A c e t a t e 3 .00 H y d r o v i t o n (Water (and ) Sodium L a c t a t e (and) L a c t i c

A c i d (and ) G l y c e r i n (and) S e r i n e (and) S o r b i t o l (and) TEA-Lactate (and) T r i e t h a n o l a m i n e (and ) Urea (and) Sodi um C h l o r i d e (and ) L a u r y l D i e t h y l enedi ami no- g l y c i n e (and) A1 1 a n t o i n (and ) L a u r y l ami n o p r o p y l - g l y c i n e (and) SD A l c o h o l 39-C) 3 . 0 0


i s b r o u g h t t o t h e same t e m p e r a t u r e and t h e n e m u l s i f i e d i n t o ( A ) . (C) can be mixed w i t h t h e wa te r phase o r added i n a f t e r - wards .

(A) i s hea ted t o 65 degrees C . and homogeneously mixed. (6)

Formul a t i on 1 .2K

Skin Care Oil with Citric Acid Ester

I n g r e d i e n t s : Wei g h t % A) I m w i t o r 375 ( G l y c e r y l C i t r a t e / L a c t a t e / L i n o l e a t e /

01 e a t e ) 10 .00 M i g l y o l 810 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 40.00 M i g l yo1 840 ( P r o p y l ene G1 y c o l D i c a p r y l a t e / D i c a p r a t e ) 20 .00 S o f t i g e n 701 ( G l y c e r y l R i c i n o l e a t e ) 1 . 0 0 M i n e r a l O i l 29.00 A n t i o x i d a n t s q . s . Fragrance Men A t S p o r t 61569 0 . 3 0

P r e p a r a t i on : A l l i n g r e d i e n t s a r e mixed t o g e t h e r a t about 45 degrees C . F o r m u l a t i o n 1 .5U ( 1 )

SOURCE: H u l s America I n c . : Suggested F o r m u l a t i o n s


W/O Sheer Make-up

I n q r e d i e n t s : Phase A : C e t y l D ime th i cone C o p o l y o l ( A b i l EM 90 ) P o l y g l y c e r y l - 3 O l e a t e ( I s o l a n GO 33) C e t y l D ime th i cone ( A b i l Wax 9801) O c t y l P a l m i t a t e ( T e g o s o f t OP) Hydrogenated C a s t o r O i l Beeswax Decyl O l e a t e ( T e g o s o f t DO) D ime th i cone 350 c s t O c t y l S t e a r a t e ( T e g o s o f t O S )

Phase 0 : Cyc lometh i cone

Phase C : I r o n O x i d e s : Red, Y e l l o w , B l a c k , Brown T i t a n i u m D i o x i d e

Phase D : Water Sodium C h l o r i d e P r o p y l e n e G 1 y c o l

Weight%

2 . 0 0 0 . 7 5 2 . 0 0 3 . 0 0 0 . 4 0 0 . 8 0 1 . o o 0 . 2 5 3 . 0 0

1 5 . 0 0

0 .30 2 . 1 0

6 6 . 9 0 0 . 5 0 2 . 0 0

P rocedure : 1 . Combine i n g r e d i e n t s o f Phase A . M i x and h e a t t o 85-9OC.

2 . Cool t o 7 0 C . Add Cyc lometh i cone . 3 . Add i n g r e d i e n t s o f Phase C . M i x t h o r o u g h l y t o d i s p e r s e . 4 . Cool t o 50C w i t h m i x i n g . 5 . Combine i n g r e d i e n t s o f Phase D a t ambient t e m p e r a t u r e .

6 . Homogeni z e .

SOURCE: Goldschrn idt Chemical Corp. : Suggested F o r m u l a t i o n

M i x u n t i l u n i f o r m .

Add Phase D s l o w l y t o A / B / C m i x t u r e w i t h g e n t l e a g i t a t i o n

Section V Creams

101


AEC Cocoa Butter Cream

Stage Ma te r iaJL ___ Q u a n t i t y S tage A : 1 L i g h t M i n e r a l O i l 20 . ooog 2 Pe t ro leum J e l l y ; Wh i te 25 . OOOg 3 Cocoa B u t t e r , R e f i n e d 44. OOOg 4 Castorwax Mp80 1 0 . ooog C o o l i n g C y c l e : 5 V i t a m i n E A c e t a t e 0 ,5009 6 C a r r o t O i l ; Novarom 0 .1009 7 P . Cocoabu t te r AA 6780 0 .400g M i x i n g I n s t r u c t i o n s :

Change i n m a t e r i a l p r o p o r t i o n s t o make i t l e s s draggy and n e a r e r Palmers O r i g i n a l .

Use a j a c k e t e d k e t t l e s u i t a b l e f o r h e a t i n g and c o o l i n g , p r e f e r a b l y f i t t e d w i t h a g a t e o r anchor t y p e m i x e r .

S tage 1 : Weigh i n t h e m i n e r a l o i 1 and commence h e a t i n g w i t h s l o w s t i r r i n g .

Add Pe t ro leum J e l l y and c o n t i n u e h e a t i n g and s t i r r i n g u n t i l a l l m e l t e d ,

Add Cocoa B u t t e r and C a s t o r Wax and c o n t i n u e h e a t i n g and s t i r r i n g u n t i 1 a1 1 me l ted , t h e t e m p e r a t u r e s h o u l d n o t exceed 6 0 C .

When a c l e a r , homogeneous m i x i s o b t a i n e d s t a r t c o o l i n g w i t h c o n t i n u o u s m i x i ng .

C o o l i n g S tage : Add t h e V i t a m i n E A c e t a t e and C a r r o t O i l a t about 55C and t h e Perfume a t about 40C.

The p r o d u c t w i l l t h i c k e n and t h e n s e t , i d e a l l y i t s h o u l d be h o t f i l l e d j u s t above i t s s e t t i n g t e m p e r a t u r e . Some e x p e r i m e n t a l ba tches may be necessary t o d e t e r m i n e t h e optimum f i l l i n g temp- e r a t u r e .

P r o j e c t : JW 2527/Formul a R e f . : 1186*3

Cocoa Butter Cream

Stage M a t e r I a1 . Quant i t y O i l Phase: 1 L ;ght M i n e r a l O i l 1 7 . OOOg 2 Cocoa B u t t e r , R e f i n e d 42 I OOOg 3 Pe t ro leum J e l l y ; Wh i te 3 2 . 5 0 0 9 4 Castorwax Mp80 8 I OOOg Cool i ng C y c l e : 5 P . Cocoabu t te r AA 6780 0 .5009 M i x i n g I n s t r u c t i o n s :

Weigh o u t t h e m i n e r a l o i l and s t a r t h e a t i n g . Add each i t e m i n t u r n , m i x and c o n t i n u e h e a t i n g u n t i l a l l

S w i t c h o f f h e a t and c o o l w i t h s low m i x i n g , add t h e per fume

The p r o d u c t may t h e n be f i l l e d h o t . P r o j e c t : JW 2450/Formula R e f . 1005*0

i n g r e d i e n t s have me1 t e d .

a t 40C.

SOURCE: A & E Connock L t d . : Suggested F o r m u l a t i o n s

Creams 103

AHA Renewal Cream

T h i s e l e g a n t , w h i t e AHA-cream w i t h l o w pH i s an a c t i v e a n t i - w r i n k l e f o r m u l a . P e n t a v i t i n reduces s k i n ' s s e n s i t i v i t y p r e v e n t i n g f r o m i r r i t a t i o n r e a c t i o n s . Fur thermore , P e n t a v i t i n i n c r e a s e s t h e m o i s t u r e c o n t e n t o f t h e s k i n .

Item 1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18

I n g r e d i e n t x A) Promulgen D

Soya O i l A r l a c e l 165 M y r j 59 Dow C o r n i n g 345 F l u i d F i toderm M i g l y o l 812

8 ) D e i o n i z e d Water Phenoni p G1 y c e r i n 1 ,3 -Butand i 01 Pemulen TR-1

C) D e i o n i z e d Water I m i d a z o l i d i n y l Urea G1 y c o l i c A c i d P e n t a v i t i n

D ) T r i e t h a n o l ami ne F r a g r a n c e : R i Val i a 0/221212

Weight% 3 . 5 0 1 . 0 0 3.50 1 . o o 2.50 5.00 4.00

60.00 0 . 3 0 3 . 0 0 3 . 0 0 0.20 2.50 0.20 5.00 5.00

0 , 3 0

Procedure: D i s p e r s e Pemulen (12) i n phase B) and h e a t t o 7 5 C . Heat phase A) t o 70C. Under s t i r r i n g , add phase A) t o phase B ) , c o o l t o 50C, homogenize and c o o l t o 30C. Add phase C) and a d j u s t pH w i t h i t e m 17 t o 3 . 5 . Add f r a g r a n c e (18) and s t i r c o l d .

SOURCE: Pentapharm L t d . : A p p l i c a t i o n No. A 034.1/03.96

Glycerin Cream with Citric Acid Esters

I n g r e d i e n t s : Wei s h t % A ) I m w i t o r 377 ( G l y c e r y l L a u r a t e / C i t r a t e / L a c t a t e ) 5.00

I m w i t o r 900 ( G l y c e r y l S t e a r a t e ) M i g l yo1 81 2 ( C a p r y l i c / C a p r i c T r i g l y c e r i de) P a r a f f i n , W h i t e C e t y l A1 coho1

G l y c e r i n P r e s e r v a t i v e Water

B) K e l t r o l F (Xanthan Gum)

4.00 5.00 5.00 4.00 0.50 5.00

71.50 q . s .

P r e p a r a t i on : (A) i s h e a t e d t o c a . 65 degrees C . ( B ) i s heated up t o t h e

same t e m p e r a t u r e and e m u l s i f i e d i n t o ( A ) . The cream i s c o n s t a n t l y s t i r r e d u n t i l c o o l .

SOURCE: H u l s Amer ica I n c . : F o r m u l a t i o n 1 . l o


Alpha Hydroxy Acid Liposome Cream

An e l e g a n t w h i t e creamy e m u l s i o n d e l i v e r i n g Rovisome AHA ( L a c t i c A c i d ) t o t h e s k i n .

I n g r e d i e n t s : 1 . R i t a C e t e a r y l A l c o h o l (50/50) 2 . S t e a r e t h - 2 3 . S t e a r e t h - 2 1 4 . PPG-15 S t e a r y l E t h e r 5 . D i o c t y l A d i p a t e 6 . D i o c t y l c y c l ohexane 7 . Dow C o r n i n g 200 F l u i d (200 c s t ) 8. R i t a s i 1 190 ( D i meth i cone Cop01 yo1 ) 9 . Sunf lower Seed O i 1 l O . D i s t i l l e d / D e i o n i z e d Water 1 1 . 1 , 3 B u t y l e n e G l y c o l 12. Xanthan Gum ( K e l t r o l CG-T) 13. Rovi some-AHA ( L a c t i c A c i d ) 1 4 . M e t h y l d i b r o m o G l u t a r o n i t r i l e and Phenoxyethanol

2 . 5 0 2 . 5 0 1 . 5 0 3 .00 3 . 0 0 2 . 0 0 2.00 0 . 5 0 4 . 0 0

68.40 4 .00 0 . 3 0 6 . 0 0 0.30

Compounding Procedure : D i s p e r s e i t e m 12 i n w a t e r and b u t y l e n e g l y c o l m i x t u r e . I n

s e p a r a t e beaker h e a t i t e m s 1-9 t o 70C. Heat water phase t o 70C and add t o o i l phase. Then homogenize and c o o l t o 35C. Add Rovisome and p r e s e r v a t i v e .

R e f . NO. 122-94

Washable Cleansing Cream

A g l o s s y c l e a n s i n g cream w i t h w a t e r r i n s a b i l i t y and r e s i d u a l e m o l l i e n c e . C l a r i s k i n h e l p s t o a t t e n u a t e s k i n brown s p o t s .

I n g r e d i e n t s : 1 . R i t a l a n ( L a n o l i n O i l ) 2 . M i n e r a l O i l ( D r a k e o l - 9 ) 3 . S t e a r i c A c i d 4. R i t a CA ( C e t y l A l c o h o l ) 5 . D i s t i 11 ed/Dei o n i zed Water 6. G l y c e r i n e 7. T r i e t h a n o l a m i n e (50%) 8 . R i t a b a t e - 6 0 ( P o l y s o r b a t e - 6 0 ) 9 . G l y d a n t 10.Per fume 1 1 . C l a r i s k i n (Yeas t E x t r a c t )

w 3 . 0 0

20.00 5 . 0 0 3.00

54.00 5 . 0 0 3 . 0 0 2 .00

q . s . q . s .

5 . 0 0

Compounding Procedure : Heat 1-4 i t e m s t o 70C. Heat i t e m s 5-9 t o 65C. Add o i l phase t o

w a t e r phase w i t h a g i t a t i o n . Cool t o 40C and add i t e m s 10 and 1 1 . R e f . No. 122-108


Creams 105

Anti-Wrinkle Cream

M a t e r i a1 : Water; Pure C a p r y l i c / C a p r i c T r i g l y c e r i d e P ropy lene G1 y c o l USP AEC O c t y l P a l m i t a t e AEC Hydroxyoc tacosany l H y d r o x y s t e a r a t e AEC PEG 45 D o d e c y l g l y c o l Copolymer Cocoa B u t t e r , Ref i ned GMS NSE AEC Methoxy Peg 22 D o d e c y l g l y c o l Copolymer N i paguard BPX F rag rance

Formula R e f . : 1081 *O

AEC Cocoa Butter Cream

M a t e r i a1 : Cocoa B u t t e r , Ref i ned P e t r o l e u m J e l l y; W h i t e L i g h t M i n e r a l O i l Castorwax Mp80 V i t a m i n E A c e t a t e P . C o c o a b u t t e r AA 6780 C a r r o t O i l ; Novarom


%w/w 65.250

7 .000 5 .000 5 . 0 0 0 5 .000 4.000 3 .000 3 IO00 2 .000 0 .500 0 .250

%w/w 44.000 25.000 20 .000 10 .000

0 . 5 0 0 0 .400 0 .100

Cocoa Butter Cream

M a t e r i a1 : Cocoa B u t t e r , Ref i ned P e t r o l e u m J e l l y , W h i t e L i g h t M i n e r a l O i l Castorwax Mp80 P . C o c o a b u t t e r AA 6780

Forrnul a R e f . : 1005*0

%w/w 42.000 32.500 17 .000 8 .000 0 .500

SOURCE: A&E Connock, L t d . : Suggested F o r m u l a t i o n s


Anti-Wrinkle Moisturizing Cream

A m o i s t u r i z i n g cream f o r m u l a t i o n t h a t g i v e s a smooth, creamy p r o d u c t t h a t f i g h t s w r i n k l e s . Lnn red i e- w 1 . R i t a c h o l 1000 ( R . I . T . A . B lend ) 3 . 0 0 2 . R i t a CA ( C e t y l A l c o h o l ) 3 . 0 0 3 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 1 . o o 4 . S t e a r i c A c i d 2 . 7 5 5 . R i t a c h o l ( M i n e r a l O i l and L a n o l i n A l c o h o l ) 2 * 00 6 . R i tade rm ( R . I . T . A . B lend ) 1 0 . 0 0 7 . R i t a SSO (Sun f lower Seed O i l ) 4 . 0 0 8 . BHA 0 .10 9 . P ropy lpa raben 0 . 1 0 1 0 . D i s t i 11 ed/Dei o n i zed Water 64 .50 1 1 . A c r i t a m e r 940 (Carbomer) 0 .10 1 2 . G l y c e r i ne 5 . 0 0 13 . Me thy lpa raben 0 . 1 0 1 4 . T r i e t h a n o l a m i n e (99%) 1 . 2 5 1 5 . R e d u c t i n e (Oat P r o t e i n ) 2 . 0 0 16 .Quatern ium 15 ( 2 0 % S o l u t i o n ) 0 . 1 0 1 7 , F rag rance 1 . o o Compounding Procedure :

s t i r r i n g . C o n t i n u e s t i r r i n g u n t i l a homogeneous m i x t u r e i s fo rmed. Add i t e m s 12-14 t o i t e m s 10-11 and hea t t o 70C. Add o i l t o w a t e r a t 70C w h i l e s t i r r i n g . Beg in c o o l i n g . A t 40C add i t e m s 15-17.

Heat i t e m s 1-7 t o 70C. S l o w l y add i t e m 11 t o i t e m 10 w h i l e

R e f . No. 120-188

Anti-Wrinkle Treatment Cream

..~ I a r e d i e n t s : - YowJ4-J 1 , R i t a C e t e a r y l A l c o h o l 50/50 2 . 5 0 2 . S t e a r e t h - 2 2 .50 3 . S t e a r e t h - 2 1 1 . 5 0 4 . PPG-15 S t e a r y l E t h e r 3 . 0 0 5 . D i o c t y l A d i p a t e 3 . 0 0 6 . D i o c t y l c y c l ohexane 2 . 0 0 7 . Cyc l ometh i cone 2 ,oo 8 . D ime th i cone 0 . 5 0 9 . R i t a SSO (Sun f lower Seed O i l ) 4 . 0 0 10, D i s t i 11 ed/Dei o n i zed Water 68 ,40 11 . 1 , 3 - B u t y l ene G 1 y c o l 4 . 0 0 12 .Xanthan Gum 0 . 3 0 1 3 . Reduct i ne (Oat P r o t e i n ) 6 . 0 0 14 .Methy ld ib rorno G l u t a r o n i t r i l e 0 . 3 0 Compounding Procedure :

D i s p e r s e i t e m 12 i n wa te r and b u t y l e n e g l y c o l m i x t u r e , Heat t o 7OC. Combine i t e m s 1-9 and h e a t t o 70C. Add t o wa te r phase. M ix and c o o l t o 30C. Add i t e m s 13 l n d 1 4 .

R e f . No. 120-193


Creams 107

Anti-Wrinkle Treatment Cream

Inqredi ents: 1 . Rita Cetearyl Alcohol 5O/SO 2 Steareth-2 3. St~areth-21 4. PPG-15 Stearyl Ether 5. Dioctyl Adipate 6. D i octyl Cyclohexane 7. Dow Corn?ng 200 Fluid (200 cst) 8. Ritasil 190 (Dimethicone Copolyol) 9. Sunflower Seed Oil 10.Disti illed/Deionized Water 11.1,3 Butylene Glycol 12.Xanthan Gum 13. Rovi some ACE (ROVI 31 end) 14.Reductine (Oat Protein) 15,Methyldibromo Glutaronitri le and Phenoxyethanol

SWLVj 2.50 2.50 1 .50 3.00 3.00 2.00 2.00 0.50 4.00 64,40 4.00 0.30 5.00 5.00 0.30

Compounding Procedure: Disperse item 12 in items 10 and 1 1 a n d heat to 70C. Mix

items 1-9 and heat to 70C. Add water phase to oil phase, then homogenize. Cool to 35C and add items 13-15.

Ref. No. 122-96

Night-Cream

A smooth, moisturizing cream containing Clariskin for prevent- ing and attenuating age spots.

Ingredi en-ts; 1 . Ritachol 2000 (R.I.T.A. Blend) 2. Rita SA (Stearyl Alcohol) 3. Mineral Oil (Britol-7) 4. Lanol i n X-Tra Deo 5. Ritaderm (R.I.T.A. Blend) 6 . Propylparaben 7. Butylated Hydroxyanisole 8 . D i s t i lled/Deionized Water 9. Acritamer 941 (Carbomer) 10 I Propylene G1 ycol 11.Methylparaben 1 2 I T r 1 et h a no 1 ami ne 99% 13,Bromopol 14.Clariskin (Yeast Extract) 15.Perfume

%W%W 8.00 2.50 12.00 1 .oo 10.00 0.10 0.10

55.96 0.10 5.00 0.10 0.10 0.04 5.00 q . s .

Cornpounding Procedure:

until lump free. Add items 10 and 1 1 and heat to 75C. Add oil phase to water phase with agitation. Cool to 40-45C and add items 13-15. Cool to 25-30C and package.

SOURCE: R . I . T . A . Corp.: Suggested Formulations

Combine items 1-7 and heat to 75C. Disperse item 9 into water

Ref. No. 122-818


Basic-Cream with AHA-Esters, Food Approved

I n g r e d i e n t s : Wei a h t % A . M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 16 .00

S o f t i s a n 378 (Caprylic/Capric/Stearic T r i g l y c e r i d e ) 5 . 0 0 I m w i t o r 375 ( G l y c e r y l C i t r a t e / L a c t a t e / L i n o l e a t e / 01 e a t e ) 5 . 0 0

I m w i t o r 928 ( G l y c e r y l Cocoate) 3 .00 I m w i t o r 370 ( G l y c e r y l S t e a r a t e C i t r a t e ) 7 . 0 0 A n t i o x i d a n t q . s .

B. G l y c e r o l P r e s e r v a t i v e Water , ad

5 .00

100.00 q . s .

F r a g r a n c e q . s .


t h e same t e m p e r a t u r e and e m u l s i f i e d i n t o A . The cream i s s t i r r e d c o l d and a t abou t 30C f r a g r a n c e i s added.

I n g r e d i e n t s o f A a r e h e a t e d t o abou t 70C. B i s b r o u g h t t o

F o r m u l a t i o n BAS FO

Eye Wrinkle Cream with UV Absorber With citric acid ester as active ingredient

I n q r e d i e n t : Wei q h t %

M i g l yo1 829 ( C a p r y l i c / C a p r i c /D i g l y c e r y l Succ i n a t e ) 5 . 0 0 Dynacer i n 660 ( O l e y l E r u c a t e ) 5 . 0 0 I m w i t o r 370 ( G l y c e r y l C i t r a t e ) 5 . 0 0 I m w i t o r 375 ( G l y c e r y l C i t r a t e / L a c t a t e / L i n o l e a t e / O l e a t e ) 8 .00 Eveni ng P r i m r o s e O i 1 3 . 0 0 A n t i o x i d a n t 4 , s .

A . M i g l y o l 818 ( C a p r y l i c / C a p r i c / L i n o l e i c T r i g l y c e r i d e ) 5 . 0 0

B. K e l t r o l F(Xanthan Gum) Me thoce l K 100 LV ( H y d r o x y m e t h y l c e l l u l o s e ) P r e s e r v a t i v e Water , ad

0 . 5 0 Om 50

100.00 q . s .


K e l t r o l F and Me thoce l i s d i s p e r s e d i n w a t e r and s t i r r e d t o homogenei ty . Then B i s b r o u g h t t o t h e same t e m p e r a t u r e and e m u l s i f i e d i n t o A .

I n g r e d i e n t s o f A a r e h e a t e d t o about 70C. To b u i l d phase 6

The cream i s s t i r r e d c o l d . F o r m u l a t i o n EYE OW

SOURCE: Hu ls A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n s

Creams 109

Bleaching Night Cream Against Age Spots

T h i s a g r e e a b l e , r i c h n i g h t cream c o n t a i n s Fadeout , wh ich has b l e a c h i n g a c t i v i t y . P e n t a v i t i n p r o v i d e s t h e s k i n w i t h m o i s t u r e and r e g e n e r a t e s t h e s k i n .

I t e m : 1 2 3 4 5 6 7 8 9

____ .__ I n g r e d i e n t s : A ) Cremophor A-6

Cremophor A-25 C u t i na GMS L a n e t t e - 0 S t e a r i c A c i d P a r a f f i n o i l C e t i o l SN Vase1 i ne w h i t e Abi 1 -350

10 B ) Water d e m i n e r a l i z e d 1 1 I m i d a z o l i d i n y l u r e a 12 Phenoni p 13 G1 y c e r i n 14 P e n t a v i t i n 15 Fadeou t

"/ow& 2 . 5 0 2 . 5 0 4 - 0 0 3 . 0 0 1 . o o

10 .00 5 . 0 0 3 . 0 0 0 . 4 0

54.60 0 . 2 0 0 .50 3 . 0 0 5 . 0 0 5 . 0 0

16 C ) F r a g r a n c e / C h i a r a 0/238927 0 . 3 0

P rocedure : Heat t h e i n g r e d i e n t s o f f a t t y phase A) t o 70C. Heat t h e i n g r e d i e n t s o f phase B ) t o 75C. Under s t i r r i n g add phase B ) t o phase A ) , c o o l t o 50C,

Then add phase C) and s t i r c o l d . homogenize and c o o l t o 30C.

SOURCE: Pentapharm L t d , : Appl i c a t i on No I A 032 I B/O1 I 96


Cleansing Cold Cream W/O


r e f r e s h e s w h i l e d e e p l y c l e a n s i n g t h e s k i n o f d i r t and o i l s , l e a v i n g t h e s k i n smooth and s i l k y . N a t u r a l a n t i - m i c r o b i a l a g e n t s i n h e r e n t i n t h e beeswax and o range wax p r e s e r v e t h i s

T h i s c l a s s i c p r o d u c t has a n a t u r a l m i l d orange aroma wh ich

p r o d u c t a l o n g w i t h t h e pH (pH=8) .

O i l Phase: NF W h i t e Beeswax ( K o s t e r Keunen) C e r e s i n e Wax 130/135 ( K o s t e r Keunen) Deodor i zed Orange Wax ( K o s t e r Keunen) L i o h t M i n e r a l O i l ( W i t c o ) P r o p y l e n e G l y c o l S t e a r a t e ( I n o l e x )

Water Phase: Water ( D i s t i l l e d ) Carbopol 940 2% S o l u t i o n (BF Goodr Sodium B o r a t e ( B o r a x )

P rocedure : Add Carbopol s o l u t i o n t o t h e wa

add b o r a x under a g i t a t i o n . M i x and o i l phase t o t h e w a t e r phase w h i l e c o n t a i n e r s .

c h

wt% 1 0 . 0 6 . 0 4 . 0

3 8 . 5 2 . 0

2 7 . 5 1 0 . 0

2 . 0

e r phase m ix and h e a t t o 75C, me t o i l phase t o 75C. Add m i x i n g . Cool and pour i n t o


t h e c o n c e n t r a t i o n o f t h e orange wax w i l l e l i m i n a t e t h e n a t u r a l orange aroma. P l a n t o i l s can be added i n l o w c o n c e n t r a t i o n s f o r 1 a b e l c l a ims.

Smal l changes i n t h i s f o r m u l a a r e p o s s i b l e , such as, r e d u c i n g


Hand Care Cream

P a r t A : S u l f e t a l CJOT 60 I m w i t o r 960

u 1 0 . 0 1 4 . 0

P a r t 8 : Water 75 .5

P a r t C: Perfume, p r e s e r v a t i v e 0 . 5

M i x p a r t A and C s e p a r a t e l y . Add p a r t B and C s u c c e s s i v e l y

A d j u s t pH t o app rox . pH 6 . 5 u s i n g c i t r i c a c i d . t o p a r t A w h i l s t s t i r r i n g .

SOURCE: Zschimmer & Schwarz GmbH & Co.: F o r m u l a t i o n B 27/18

Creams 111

Cream Foundation

I n g r e d i e n t : A : D e i o n i z e d Water

W t .%* 39 .80

B: Veegum U l t r a , Magnesium Aluminum S i l i c a t e Rhodi g e l , Xanthan Gum

1 . o o 0 .20

C : P r o p y l e n e G l y c o l 5 .00

D : I r o n Ox ides T i t a n i um D i o x i d e

2 . 1 7 8 . 8 3

E : C e t e a r y l A l c o h o l (and) C e t e a r e t h - 2 0 (L ipowax D) 4 . 0 0 C e t e a r e t h - 4 ( L i poco1 SC-4) 2 . 0 0 Decyl O l e a t e 4.00 M i n e r a l O i l 20 * 00 S t e a r i c A c i d 2 - 0 0 L a n o l i n O i l 3 . 0 0 PPG-15 S t e a r y l E t h e r 3 .00 Phenoxyethanol (and) Me thy lpa raben (and) E t h y l p a r a b e n

(and) P r o p y l p a r a b e n (and) B u t y l p a r a b e n (Uniphen P-23) 1 . 0 0 I s o p r o p y l M y r i s t a t e (and) L e c i t h i n (and )

Tocophero l (Un i p h e r o l U-14) 0 .70

F: T r i m e t h y l d o d e c a t r i e n o l (Uni s t a b S-69) 0 .50 F a r n e s y l A c e t a t e (and) F a r n e s o l (and ) Pan theny l

T r i a c e t a t e ( U n i t r i e n o l T-27) 2 . 0 0

G : Water I m i d a z o l i d i n y l Urea (Uni c i de 4-1 3)

0 . 5 0 0 . 3 0

P rocedure : Dry b l e n d t h e P a r t B i n g r e d i e n t s . Heat t h e P a r t A w a t e r t o

70C. Add t h e P a r t B i n g r e d i e n t s and m i x f o r 30 m i n u t e s w i t h a p r o p e l l e r m i x e r a t 1800 rpm. Add P a r t C and m i x 5 m i n u t e s . Add t h e P a r t D i n g r e d i e n t s s i m u l t a n e o u s l y and m i x u n t i l u n i f o r m l y d i s p e r s e d . M i x and h e a t t h e P a r t E i n g r e d i e n t s t o 70C. Add P a r t E t o P a r t s A+B+C+D and m i x 10 m i n u t e s . Slow t h e m i x e r and c o o l t h e b a t c h t o 45C and add P a r t s F and G i n t h e o r d e r shown. C o n t i n u e c o o l i n g t o 30C and package.


SOURCE: R . T . V a n d e r b i l t C o . , I n c . : Veegurn F o r m u l a t i o n f r o m Induchern AG


Cream, Type O/W, with MPC-Milk Peptide Complex*

a ) Emulgade 1000 N I 4 . 0 0 L a n e t t e 16 1 . o o M y r i t o l 318 10 .00 Phenoni p 0 . 3 0

b ) Water , d i s t i l l e d 50.00 Carbopo l 934 0 . 4 0

c) Water , d i s t i l l e d 23 .60 Phenoni p 0 . 3 0 T r i e t h a n o l ami ne 0 . 4 0

d ) Water , d i s t i l l e d 9 . 3 6 Na3-Ci t r a t e , anhydrous 0 . 1 4 MPC-Mi 1 k P e p t i de Compl ex 0 . 5 0

M a n u f a c t u r e : M e l t a ) and b r i n g t o app rox . 70C. M e l t b ) , b r i n g t o app rox . 70C and add t o a ) w i t h s t i r r i n g . Con t inue s t i r r i n g u n t i l c o o l e d t o app rox . 30C. D i s s o l v e c ) and add t o a b ) . D i s s o l v e d ) a t room t e m p e r a t u r e and add t o abc) w i t h s t i r r i n g . Perfume, homogen i ze

Cream, Type W/O, with MPC-Milk Peptide-Complex

A r l a c e l 1689

Lunacera M P a r a f f . i num sub1 i q u i d u m Beeswax Vase1 i ne Cocoa b u t t e r Vege tab le o i 1 Phenoni p Oxynex LM Water , d i s t i 1 l e d Phenoni p G1 y c e r i n Magnesi um s u l f a t e Water , d i s t i l l e d N a 3 - C i t r a t e x 2H20 MPC-Mi 1 k Peot i de Comol ex

G-4909 0 . 5 0 3.00

1 2 . 0 0 0 . 5 0 6 . 0 0 4 . 0 0 4 . 0 0 0 . 3 0 0 . 0 5

51 . 8 5 0 .30 4 . 0 0 0 . 5 0 9 . 3 8 0 . 1 2 0 . 5 0

Manu fac tu re : M e l t a ) and b r i n g t o app rox . 75C. B r i n g b ) t o app rox . 75C and s t i r i n t o a ) . Con t inue s t i r r i n g u n t i l c o o l e d t o app rox . 30C. D i s s o l v e c ) a t room t e m p e r a t u r e and add t o ab) w i t h s t i r r i n g . Perfume, r o l l .

*MPC-Mi 1 k P e p t i de Compl ex c o n t a i ns n a t u r a l p o l y p e p t i d e s f r o m m i l k , i n a c t i v a t e d f o r m .

SOURCE: Chemisches L a b o r a t o r i u m D r . K u r t R i c h t e r GmbH: Formulas

Creams 113

Day Cream with Evening Primrose Oil

I n g r e d i e n t s : Wei g h t % A) M i g l y o l 818 ( C a p r y l i c / C a p r i c / L i n o l e i c T r i g l y c e r i d e ) 5 . 0 0

M i g l y o l 829 (Caprylic/Capric/Diglyceryl S u c c i n a t e ) 5 . 0 0

I m w i t o r 370 ( G l y c e r y l C i t r a t e ) 5 . 0 0 I m w i t o r 375 ( G l y c e r y l C i t r a t e / L a c t a t e / L i n o l e a t e / O l e a t e ) 8 . 0 0

Eveni ng P r i m r o s e O i 1 3 . 0 0 A n t i o x i d a n t s 9 , s .

D y n a c e r i n 660 ( O l e y l E r u c a t e ) 5 . 0 0

B ) Methocel K 100 LV ( H y d r o x y p r o p y l M e t h y l c e l l u l o s e ) 0 . 5 0 K e l t r o l F (Xanthan Gum) 0 . 5 0 Hydrov i t o n (Water (and ) Sodium L a c t a t e (and ) L a c t i c A c i d (and ) G l y c e r i n (and) S e r i n e (and ) S o r b i t o l (and ) TEA-Lactate (and ) T r i e t h a n o l a m i n e (and ) Urea (and) Sodium C h l o r i d e (and) L a u r y l D i e t h y l e n e - d i a m i n o g l y c i n e (and ) A l l a n t o i n (and ) L a u r y l Amino- p r o p y l g l y c i ne (and) SD A1 coho1 39-C) 3 .00

P r e s e r v a t i v e 9 . S . Water up t o 100 .00 Perfume O i l 9 . S .

P r e p a r a t i o n : (A ) i s added t o g e t h e r , h e a t e d up t o 75-80 degrees C . , and

homogenized. ( B ) i s s t i r r e d u n t i l homogeneous, h e a t e d t o t h e same t e m p e r a t u r e , and e m u l s i f i e d i n t o ( A ) . The cream i s t h e n s t i r r e d u n t i l c o o l .

F o r m u l a t i o n 1.1Q

Basic O/W Cream, with Citric Acid Esters

I n g r e d i e n t s : Wei q h t % A) S o f t i s a n 378 ( C a p r y l i c / C a p r i c / S t e a r i c T r i g l y c e r i d e ) 5 . 0 0

M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 16 .00 I m w i t o r 375 ( G l y c e r y l C i t r a t e / L a c t a t e / L i no1 e a t e / 01 e a t e ) 5 . 0 0

I m w i t o r 928 ( G l y c e r y l Cocoate) 3 . 0 0 I m w i t o r 370 ( G l y c e r y l S t e a r a t e C i t r a t e ) 7 .00 A n t i o x i d a n t s q . s .

B) G l y c e r i n P r e s e r v a t i ves Water

5 . 0 0

up t o 100.00 q . s .

Perfume O i l 0 .30


t h e same t e m p e r a t u r e and e m u l s i f i e d i n t o ( A ) . The pe r fume i s added a t c a . deg rees C .

F o r m u l a t i o n 1 . 1 P

( A ) i s h e a t e d up t o c a . 75 degrees C . , and ( B ) i s b r o u g h t t o

SOURCE: H u l s Amer ica I n c . : Suggested F o r m u l a t i o n s


Dry Skin Cream

Formula: % by Wei ghtWater Phase;Water q.s. to 100Triethanolamine 0.3Glycerine 2,0Methylparaben 0.2Oil Phase:White Protopet 15 Petrolatum (Witco) 3,0Carnation Mineral Oil (Witco) 4.0Cetyl Alcohol 0.5Isopropyl Ricinoleate 3.0Sorbitan Oleate 2.0Steari c Acid 1.0Naturechem GMHS (CasChem) 3.0Naturechem EGHS (CasChem) 1.5Naturechem OHS (CasChem) 2.0Ceresi ne Wax 1 . 1Laureth 23 0.3Propylparaben O.1Fragrance 0.3Procedure:

Heat both phases to 8OC. Add oil phase to water phase withhigh speed mixing. Maintain 8OC temperature while m i x i n g for15 minutes. Allow to cool and continue mixing to 35C; addfragrance; mix thoroughly.

Aloe Night Cream

EonDJJJLJLL %_by_WeightA :Water 6 7 . 6 2 5Methylparaben 0,2Promulgen-D 2.0Triethanolamine 0.75B:Ceraphyl-368 10.0Kessco-653 3.0Emerson-132 6.0Carnation Mineral Oil (Witco) 6.0Glyceryl Monostearate 2.0Propylparaben 0.05Vybar-5013 (Petrolite) 2.0C:Aloe-Con WG-40 (Florida Food Products) 0.375D:Fragrance q.s,

SOURCE: Witco Corp.: Suggested Formulations

Creams 115

Emollient CreamI n g r e d i e n t : A : M e t h y l Glucose D i o l e a t e ( G l u c a t e DO)

W t .%* 1 .50

PEG 20 Methy l Glucose Sesqui s t e a r a t e (G1 ucamate SSE-20) 3 .00

P e t r o l a t u m 8 . 0 0 I s o p r o p y l P a l m i t a t e ( P r o p a l ) 3 .00 M i n e r a l O i l 6 . 0 0 D ime th i cone 0 . 5 0 S t e a r y l A l c o h o l ( S t e a r a l ) 2 . oo C e t y l A l c o h o l ( C e t a l ) 1 . o o

B: D e i o n i z e d Water 73.70 Veegum, Magnesi um A1 umi num S i 1 i c a t e 1 . o o Rhodi g e l , Xanthan Gum 0 . 3 0

C : P r e s e r v a t i v e q . s . P rocedure :

Weigh P a r t B w a t e r i n t o a s u i t a b l e v e s s e l and m i x w i t h homo- g e n i z e r a t 5000 r p m . Weigh and d r y b l e n d t h e Veegum and Rhod ige l and add them s l o w l y t o t h e w a t e r . M i x f o r 20 m i n u t e s a t 5000 r p m . Beg in h e a t i n g t o 70C. Weigh t h e P a r t A i n g r e d i e n t s i n t o a n o t h e r v e s s e l and h e a t t o 70C. Add P a r t A t o P a r t B and m ix f o r 10 m i n u t e s a t 5000 r p m . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o p roduce a s m a l l v o r t e x . Cool t o 40C and add t h e P a r t C i n g r e d i e n t . C o n t i n u e c o o l i n g and package a t 35C.

Formula f r o m Amerchol Corp.

Hand Cream I n n r e d i e n t : W t * %* A : D ime th i cone , 1000 c s . (SF-96) 2.50

I s o p r o p y l M y r i s t a t e 2 . 0 0 S t e a r i c A c i d 7.00 L a n o l i n 0 .50 Emu1 s i f y i n g Wax NF ( P o l awax) 4 .00 S o r b i t a n O l e a t e ( A r l a c e l 80) 0 .50 P o l y s o r b a t e 60 (Tween 6 0 ) 2 .50

B: P r o p y l e n e G l y c o l 7 .00 Dei o n i zed Water 66.00 Veegum, Magnesium Aluminum S i l i c a t e (5% Aqueous

D i s p e r s i o n ) 8 .00 C: P r e s e r v a t i v e q . s . P rocedure :

a t 5000 r p m . M i x t h e d i s p e r s i o n f o r 20 m i n u t e s . Weigh t h e i n d i - c a t e d amount o f t h e d i s p e r s i o n i n t o a s u i t a b l e v e s s e l . M i x w i t h a p r o p e l l e r m i x e r a t 1800 r p m and add t h e P a r t B w a t e r . Hea t t o 70C. Add t h e P r o p y l e n e G l y c o l and m ix f o r 5 m i n u t e s . Weigh t h e P a r t A i n g r e d i e n t s i n t o a s u i t a b l e v e s s e l , m ix and h e a t t o 70C. Add P a r t A t o P a r t B and m ix a t 1800 rpm f o r 10 m i n u t e s a t 70C. Slow t h e m i x e r t o p roduce a s l i g h t v o r t e x and b e g i n c o o l i n g . A t 40C, add P a r t C, c o n t i n u e c o o l i n g and package a t 35C.

P repare t h e 5% Veegum d i s p e r s i o n u s i n g a homogenizer o p e r a t i n g

Formula f r o m Genera l E l e c t r i c Co. *As r e c e i v e d b a s i s

SOURCE: R . T . V a n d e r b i l t Co., I n c . : Veegum F o r m u l a t i o n s


Emollient Eye Cream

Thi s emol 1 i e n t cream i s spec i f i c a l l y d e s i gned f o r use around t h e eyes and c o n t a i n s Crodamol ISNP f o r t h e g e n t l e , y e t v e r y e m o l l i e n t , e f f e c t s t h a t i t c o n f e r s t o such d e l i c a t e a reas as t h e eyes, f a c e and neck . Super S t e r o l E s t e r and Cromois t HYA a r e m o i s t u r i z e r s t h a t h e l p keep t h e s k i n a round t h e eyes smooth and s u p p l e . A c o m b i n a t i o n o f Polawax and e t h y l e n e g l y c o l monosteara te i s used t o e m u l s i f y t h e cream.

I n a r e d i e n t s : P a r t A : Dei o n i zed w a t e r Carbomer 934 G1 y c e r i n

P a r t B: Crodamol ISNP ( I s o s t e a r y l Neopentanoate) Polawax ( E m u l s i f y i n g Wax NF) Super S t e r o l E s t e r (C10-30 C h o l e s t e r o l / L a n o s t e r o l

E t h y l e n e G l y c o l Monosteara te

P a r t C:

E s t e r s )

TEA 99%

P a r t D: Cromois t HYA ( H y d r o l y z e d P r o t e i n (and) H y a l u r o n i c A c i d ) P r o p y l e n e G l y c o l (and) Diazo1 i d i n y l Urea (and) M e t h y l

Procedure :

Paraben (and ) P r o p y l Paraben

wt%

84.50 0 . 2 5 1 . 5 0

3 .00 3 .00

2 . 0 0 4 .00

0 . 2 5

0 . 5 0

1 .00

Add t h e Carbomer 934 o f P a r t A t o t h e water w i t h m i x i n g and h e a t t o 65-7OC. When homogeneous, add t h e g l y c e r i n o f P a r t A w i t h m i x i n g . Combine t h e i n g r e d i e n t s o f P a r t B w i t h m i x i n g and h e a t t o 65-7OC. Add P a r t A t o P a r t B w i t h m i x i n g and c o o l t o 60C. Add P a r t C w i t h m i x i n g and c o o l t o 40C. Add P a r t D w i t h m i x i n g and c o o l t o d e s i r e d f i l l t e m p e r a t u r e .

pH=6.0+-0.5 V i s c o s i t y (RVT S p i n d l e #TB, 10 rpm, 25C)=25,0OOcps+-lO% N . A . T . C . Approved

SOURCE: Croda I n c , : F o r m u l a t i o n SC-256

Creams 117

Enriched W/O Cream with Vitamin E Oil

Stage M a t e r i a1 : O i l Phase: 1 Peach K e r n e l O i l 2 Almond O i l USP; Sweet 3 AEC Macadamia Nut O i l 4 AEC Hydroxyoc tacosany l H y d r o x y s t e a r a t e 5 AEC Methoxy Peg 22 D o d e c y l g l y c o l Copolymer 6 AEC PEG 45 D o d e c y l g l y c o l Copolymer 7 V i t a m i n E O i l Aqueous Phase: 8 Water; Pure 9 P r o p y l e n e G l y c o l USP 10 Magnesium S u l p h a t e 11 N ipaguard BPX C o o l i n g C y c l e : 12 Fragrance

Q u a n t i t y

10. ooog 5 . OOOg 3 . OOOg 7 . OOOg 4 , O O O g 3. OOOg 1.5009

60.7709 5, OOOg 0.0809 0.15Og

0.500g M i x i ng I n s t r u c t i o n s :

Heat t h e O i l Phase i n a s u i t a b l e j a c k e t e d v e s s e l . Heat t h e Aqueous Phase i n a s e p a r a t e v e s s e l . S l o w l y add t h e h o t w a t e r t o t h e h o t o i l s w i t h h i g h shear

m i x i n g and mix f o r f i v e m i n u t e s . S t a r t c o o l i n g and m i x w i t h a g a t e t y p e m i x e r ; add t h e per fume a t about 35C and homogenise.

T h i s r i c h w / o e m u l s i o n i s made w i t h n a t u r a l o i l s and uses V i t a m i n E O i l as a f r e e r a d i c a l scavenger .

P r o j e c t : JW 2382/Formula: 796*1

Anti-Wrinkle Cream

Stage M a t e r i a1 : Q u a n t i t y O i l Phase: 1 AEC Hydroxyoc tacosany l H y d r o x y s t e a r a t e 5 . OOOg 2 AEC Methoxy Peg 22 D o d e c y l g l y c o l Copolymer 2 . ooog 3 AEC PEG 45 D o d e c y l g l y c o l Copolymer 4 . OOOg 4 Cocoa B u t t e r , R e f i n e d 3 . OOOg 5 GMS NSE 3. OOOg 6 AEC O c t y l P a l m i t a t e 5 . OOOg 7 C a p r y l i c / C a p r i c T r i g l y c e r i d e 7 . OOOg Aqueous Phase: 8 P r o p y l e n e G l y c o l USP 5 . OOOg 9 N ipaguard BPX 0 .5009 10 Water; Pure 65.2509 Cool i ng C y c l e : 11 Fragrance 0.2509 M i x i n g I n s t r u c t i o n s :

T h i s i s a w/o cream. The o i l phase and aqueous phase a r e heated s e p a r a t e l y t o 80C and t h e aqueous phase added s l o w l y t o t h e h o t o i l s w i t h h i g h shear m i x i n g . The p r o d u c t i s s t i r r e d s l o w l y u n t i l c o o l and t h e n g i v e n a f i n a l homogenis ing m i x .

V i t a m i n E, V i t a m i n A, Sodium H y u r o l o n a t e and c o l l a g e n wou ld be s u i t a b l e a d d i t i v e s .

P r o j e c t : AEC/Formula R e f . : 1081*0

SOURCE: A & E Connock L t d . : Suggested F o r m u l a t i o n

11 8 Cosmetic and Toiletry Formulations

Eye Contour Cream, Type W/O, with MPC-Milk Peptide Complex

I n n r e d i e n t s : a ) Dehymuls F

Vase1 i ne , w h i t e S o f t i s a n Gel P a r a f f i num sub1 . Phenoni p

b ) Water , d i s t i l l e d Phenoni p G l y c e r i n Magnesium S u l f a t e x 7H20

c ) Water , d i s t i l l e d Na3 C i t r a t e x 2 H20 MPC-Milk P e p t i d e Complex

Wei ght% 12.00

5 .00 1 0 . 0 0 10.00

0 . 3 0

46.70 0 .30 5 . 0 0 0 .70

9 .38 0 . 1 2 0 . 5 0

M a n u f a c t u r e : a) M e l t and b r i n g t o app rox . 70C; b ) B r i n g t o app rox . 70C and s t i r i n t o a ) ; C o n t i n u e s t i r r i n g

c ) Add under s t i r r i n g . Perfume, r o l l . u n t i l cream has c o o l e d t o a p p r o x . 30C.

Moisturizing Cream with MPC - Milk Peptide Complex

I nq r e d i e n t s : a ) Promulgen D

P a r a f f i n u m p e r l i q u i d u m Glucam E - 1 0 Cremerol HMG Phenoni p

b ) Carbopol 940 Water , d i s t i l l e d MPC-Mi 1 k P e p t i de Complex

c ) Water , d i s t i l l e d Phenoni p T r i e t h a n o l ami ne

Wei p h t % 3 .50

1 0 . 0 0 3 .00 1 . 5 0 0 . 3 0

0 . 1 0 70 .70

0 . 5 0

1 0 . 0 0 0 .30 0 .10

M a n u f a c t u r e : a ) M e l t and d i s s o l v e a t app rox . 75C. A l l o w t o c o o l t o app rox . 40C b) D i s p e r s e a t room t e m p e r a t u r e w i t h r a p i d s t i r r i n g . c) D i s s o l v e a t room t e m p e r a t u r e and s t i r i n t o b ) .

Add m i x t u r e bc) t o a ) w i t h s l o w s t i r r i n g . A d j u s t abc) t o app rox . pH 6 . 8 4 . Homogenize.

SOURCE: Chemi sches L a b o r a t o r i urn D r . K u r t R i c h t e r GmbH: Suggested F o r m u l a t i o n s

Creams 119

Gentle Night Repair CreamWater in Oil Emulsion

F o r m u l a t i n g Des gn and Advantages: T h i s p r o d u c t encapsul a t e s Bar1 ey B e t a an a c t i v e i n g r e d i e n t

wh ich i s a n t i - m c r o b i a l and reduces t h e e f f e c t s o f s k i n a g i n g . T h i s cream q u i c k l y p e n e t r a t e s t h e s k i n l e a v i n g a s o f t s i 1 k y f e e l .

O i 1 Phase: Emu1 s i f y i ng Wax ( K o s t e r Keunen) Hexaned io l Behenyl Beeswax ( K o s t e r Keunen) S i l i c o n y l Beeswax ( K o s t e r Keunen) O z o k e r i t e 164/170 ( K o s t e r Keunen) Sun f lower O i 1 (A1 n o r O i 1 ) R i c e Bran O i l ( K o s t e r Keunen) Foraha O i l ( K o s t e r Keunen) L i q u a p a r ( S u t t o n L a b o r a t o r i e s ) F i tode rm-Vege ta l Squalane (Centerchem) S i l i c o n e 200/100 (Dow C o r n i n g ) G l y c e r o l Monos tea ra te ( W i t c o ) I s o p r o p y l P a l m i t a t e ( I n o l e x ) V i t a m i n E (BASF) V i t a m i n A P a l m i t a t e (BASF)

Water Phase: Water (Dei o n i zed) Me thy l Paraben ( A l d r i c h ) Sodium B o r a t e (Amend) Carbopol 940 2% (B .F .Goodr i ch )

A c t i ve Phase : F i r m i ng L i posome (Co l 1 a b o r a t i ve L a b o r a t o r i es ) APT (Centerchem) B e t a Glucan ( K o s t e r Keunen)

Weight% 3 .10 3 . 0 0 3 .00 1 - 0 0 8 . 0 0 4 . 0 0 1 . o o 0 .50 2 . 0 0 2 . 0 0 2 . 1 0 0.80 0 . 1 0 0 . 1 0

48.70 0 . 3 0 0.50 9 .60

4 . 0 0 3 . 0 0 0 . 2 0

P rocedure :

t e m p e r a t u r e o f 82C. I n a s e p a r a t e v e s s e l h e a t t h e components o f t h e w a t e r phase, m i x and m a i n t a i n a t a t e m p e r a t u r e o f 80C. Add t h e o i l phase t o t h e w a t e r under moderate a g i t a t i o n , and c o o l s l o w l y w h i l e m i x i n g . Add t h e B e t a Glucan a t a t e m p e r a t u r e l e s s t h a n 8OC. Cool t o 40C and add t h e F i r m i n g Liposome and APT. Cool t o room t e m p e r a t u r e .

A d a p t a t i o n of Formula and Its I n f l u e n c e on t h e P r o d u c t :

on t h e f o r m u l a t i o n d e s i r e d .

Heat t h e components o f t h e o i l phase, m ix and m a i n t a i n a t a

S u b s t i t u t i o n can be made o f t h e v a r i o u s p l a n t o i l s depend ing

SOURCE: K o s t e r Keunen, I n c , : A Guide t o N a t u r a l F o r m u l a t i n g


Intensive Anti-Wrinkle Soft Cream with AH-Acids (O/W)

Ingredients: Wei ght%A) Imwitor 370 (Glyceryl Stearate Citrate) 5.00

Miglyol 812 (Caprylic/Capric Triglyceride) 15,00Softisan 601 (Glyceryl Cocoate (and) HydrogenatedCoconut Oil (and) Ceteareth-25) 12.00

Ewalan ODE-50 (Octy1dodecy1 Lanolate) 2.00

B) Pronalen Fruit Acid AHA-5 (Lemon & Passion FruitConcentrate) 7.00

Preservative q.s.Water up to 100.00

C) Perfume 726096 0.30

Preparation:(A) is heated to 75-80 degrees C. (B) is mixed together,

broght to the same temparature, and emulsified into (A).(C) is added at about 30 degrees C.

Formulati on 1 . 1 M

W/O Cream with 17% Pigments

Ingredi ents: Weight%A) Softisan 378 (Capry1 ic/Capric/Stearic Triglyceride) 16.00

Softisan 649 (Bis-Digl ycery 1 Polyacryladipate-1) 28.00Imwitor 78OK (Isostearyl Diglyceryl Succinate) 5.00Beeswax 6.00Vit a m i n E (Tocopherol) 0.10Zinc Oxide 16.00Talc 1.00

B) Allantoin 0.20d-Panthenol USP 2.00Preservative q.sWater 25.70

Preparati on;(A) is mixed u n t i l homogeneous and brought up to 75 degrees C.

(B) is brought to the same temperature and emulsified into (A).Formu1 at i on 2.1L

SOURCE; Huls America Inc.: Suggested Formulations

Creams 121

Light Moisturizing Cream for Dry Skin

U l t r a l i g h t w e i g h t and l o w c o s t m o i s t u r i z i n g cream f o r no rma l / d r y s k i n . Leaves t h e s k i n w i t h a s o f t s a t i n y f e e l f r o m t h e L i - pona te NPGC-2. L i po/DNS Completech MBAC-DS h e l p s c o n t r o l t h e d ryness o f t h e s k i n .

Seguence -- Raw M a t e r i a l ~- ~__._ : 1 Dei o n i zed Water 1 Me thy lpa raben 1 T r i s o d i urn EDTA

We i s h C/O 66 .35

0 . 2 5 0 . 0 5

2 Carbopol 2984 (2% s o l ' n ) 17 .50

3 L i p o n a t e NPGC-2 3 L i pomul se 165 3 L i p o c o l C 3 P ropy lpa raben 3 B u t y l paraben

4 Dei o n i zed Water 4 T r i e t h a n o l a m i n e , 99%

5 D e i o n i z e d Water 5 U n i c i d e U-13

6 Dei o n i zed Water 6 DNS Completech MBAC-OS

4 . 0 0 1 . 5 0 0 . 6 0 0 . 1 0 0 . 0 5

1 . o o 0.35

1 . o o 0 . 2 5

5 . 5 0 1 . 5 0

P rocedure : 1 . Heat Sequence #1 t o 75C. M i x w i t h overhead m i x e r a t medium

2 . Heat Sequence # 2 t o 75C and add t o Sequence #1 w i t h medium

3 . M ix Sequence #3 t o g e t h e r and hea t t o 75C, t h e n add t o b a t c h

4 . Premix Sequence #4 i n g r e d i e n t s and add t o b a t c h a t 7

speed u n t i l a l l i n g r e d i e n t s a r e c o m p l e t e l y i n t o s o l u t i o n .

a g i t a t i o n ( h o l d i n g t e m p e r a t u r e a t 75C).

w i t h medium/high a g i t a t i o n .

S w i t c h t o modera te sweep and c o o l s l o w l y t o 35C. 5 . A t 35C add p remixed Sequence #5 i n g r e d i e n t s t o b a t c h

6 . Premix Sequence #6 t o g e t h e r u n t i l c o m p l e t e l y i n t o so c o o l t o 25C.

and t h e n add t o b a t c h on sweep m i x e r .

SOURCE: L i p 0 Chemica ls I n c . : F o r m u l a t i o n No. 868

- 7 5 c .

and

u t i o n


Light Skin-Feel Cleansing CreamW/O

F o r m u l a t i n g Des ign and Advantages: T h i s a d a p t a t i o n o f a t y p i c a l c o l d cream has been updated w i t h

new i n g r e d i e n t s t o reduce o i l i n e s s w h i l e deep c l e a n s i n g o f t h e s k i n i s s t i l l p o s s i b l e , l e a v i n g t h e s k i n w i t h a l u x u r i o u s smooth and s i l k y a f t e r f e e l .

O i 1 Phase: Hexaned io l Behenyl Beeswax ( K o s t e r Keunen) S i l i c o n y l Beeswax ( K o s t e r Keunen) C e r e s i n e 130/135 ( K o s t e r Keunen) L i g h t M i n e r a l O i l ( W i t c o ) I s o s t e a r i c Ac id (Unichema) C e t y l s t e a r y l A l c o h o l ( K o s t e r Keunen) Dow 200/100 Dow 245 Emu1 s i f y i ng Wax ( K o s t e r Keunen) L i q u a p a r O i 1 ( S u t t o n )

Water Phase: Water ( D e i o n i z e d ) Carbopol 940 2% S o l u t i o n (BF G o o d r i c h ) Sodium B o r a t e ( B o r a x )

Wt% 5 . 0 0 3 .00 7 . 0 0

17 .25 2 .00 1 . o o 6 . 0 0

11 .25 2 . 0 0 0 . 3 0

33 .95 10 .00

1 . 2 5

P rocedure :

add b o r a x under a g i t a t i o n . M i x and m e l t o i l phase t o 75C. Add o i l phase t o t h e w a t e r phase w h i l e m i x i n g . Cool and pour i n t o c o n t a i n e r s .

Add Carbopol s o l u t i o n t o t h e wa te r phase m i x and h e a t t o 75C,


a d d i t i o n o f s m a l l amounts o f p l a n t o i l s f o r l a b e l c l a i m s .


Smal l changes i n t h i s f o r m u l a a r e p o s s i b l e , such as t h e

Hand Care Cream

P a r t A : M u l s i f a n CB Wt% 6 . 0

Dow C o r n i n g 593 F l u i d 2 . 0 D o w C o r n i ng 200-1000 2 . 0 Avocado o i l 3 . 0 P a r a f f i n o i l 2 . 0

P a r t B : Water 8 4 . 0 Carbopol ETD 2001 0 .15

P a r t C: C a u s t i c soda (45%) approx . 0 . 0 7 P a r t D : Perfume, p r e s e r v a t i v e , a n t i o x i d a n t 0 . 3

M i x p a r t A , B and D each s e p a r a t e l y . Add p a r t B, C and D s u c c e s s i v e l y t o p a r t A w h i l s t s t i r r i n g . A d j u s t pH t o approx . pH 6 . 5 u s i n g c a u s t i c soda (15%) o r

c i t r i c a c i d . SOURCE: Zschimmer & Schwarz GmbH & C o . : F o r m u l a t i o n B27/19

Creams 123

Moisturizer O/W Cream


t o d e l i v e r m i l d a n t i - m i c r o b i a l a c t i v i t y , wh ich a l l o w s t h e fo rm- u l a t o r t o reduce t h e c o n c e n t r a t i o n o f s y n t h e t i c p r e s e r v a t i v e s . The l i g h t y e l l o w c o l o r e d cream q u i c k l y p e n e t r a t e s t h e s k i n , l e a v i n g a non-greasy f e e l and d i m i n i s h e s t h e s i g n s o f a g i n g b y l a y i n g down a f l e x i b l e b a r r i e r .

T h i s p r o d u c t u t i l i z e s t h e m i n o r components o f n a t u r a l p r o d u c t s

O i l Phase: Orange Wax ( K o s t e r Keunen) NF Y e l l o w Beeswax ( K o s t e r Keunen) I s o s t e a r i c A c i d (Unichema) Almond O i l ( A r i s t a ) M i n e r a l O i l ( W i t c o ) G l y c e r o l Monos tea ra te (Henkel ) C e t y l S t e a r y l A l c o h o l (P&G) O c t y l P a l m i t a t e (Un i chema)

Water Phase: Water ( D i s t i 11 ed) P r o p y l e n e G l y c o l (Dow) T r i e t h a n o l a m i n e (Dow) P o l y s o r b a t e 60 (Spec i a1 t y I n d u s t r i a1 P rod , ) Germaben I 1 ( S u t t o n )

4 . 5 2 . 5 1 . 0 3.0 3 . 5 6 . 0 6 . 0 2 . 5

6 7 . 8 1 . 5 1 . o 0 . 2 0 . 5

P rocedure :

o i l phase a t 75C under a g i t a t i o n . C o n t i n u e m i x i n g t i l l c o o l .


a l t e r i n g t h e a e s t h e t i c s . Changing t h e t y p e s o f o i l s s h o u l d o n l y a l t e r t h e v i s c o s i t y , i f m a i n t a i n i n g s i m i l a r c o n c e n t r a t i o n s o f o i l s . V i s c o s i t y changes a r e a c h i e v e d by r e d u c i n g t h e c o n c e n t r a t i o n o f c e t y l s t e a r y l a l c o h o l and g l y c e r o l monos tea ra te , by a p p r o x i m a t e l y 30-40%, however t h i s may cause i n s t a b i 1 i t y .


Add a mixed and u n i f o r m wa te r phase t o a mixed and u n i f o r m

A c t i v e s a r e e a s i l y i n c o r p o r a t e d i n t o a p r o d u c t w i t h o u t


Moisturizing Cream w/Tritisol

_____ Formula : A : Po l awax Pncroquat Behenyl TMS C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) B: Dei o n i zed Water T r i t i s o l ( S o l u b l e Wheat P r o t e i n ) Germaben I 1

YO b y W e i g h t

1 0 . 0 0 3 .00 5 . 0 0

8 0 . 0 0 1 . o o 1 . o o

Procedure:

B t o A w i t h good m i x i n g . Con t inue m i x i n g and c o o l t o 45C. Add C w i t h m i x i n g and c o o l t o d e s i r e d f i l l t e m p e r a t u r e .

Combine A w i t h m i x i n g and h e a t t o 70C. Heat E3 t o 70C. Add

Makeup Remover Cleansing Creme

_-___ Formul a : A : Water S tearami d o p r o p y l PG D i moni um C h l o r i d e Phosphate Cocami d o p r o p y l PG D i moni um C h l o r i d e Phosphate B : C a r n a t i o n M i n e r a l O i 1 (Wi t c o ) C e t y l A l c o h o l M y r i s t y l A l c o h o l D ime th i cone Propy lene G l y c o l S t e a r a t e

% b L W e i f i t 8 2 . 5

3 . 0 1 . 5

4 . 5 '3 . 0 3 . 5 0.1 1.9

Procedure: Heat p a r t s A and B t o 60C. Add 13 t o A w i t h good a g i t a t i o n .

Remove h e a t . When p r o d u c t b e g i n s t o t h i c k e n , i n c r e a s e speed of m i x e r t o ensu re adequate a g i t a t i o n . Add p r e s e r v a t i v e , c o l o r and f r a g r a n c e as r e q u i r e d . S t i r and c o o l t o 34C and f i l l .

Moisturizing Hand & Body Cream

Formula : Dei o n i zed Water Carbomer 934 G l y c e r i n e P o l y g l y c e r y l - 1 0 S t e a r a t e Whi t e Fono l i ne P e t r o l a t u m (Wi t c o ) C a r n a t i o n M i n e r a l O i 1 (Wi t c o ) M y r i s t y l P r o p i o n a t e G l y c e r y l Monos tea ra te S t e a r i c A c i d T r i e t h a n o l ami ne 99% G l y d a n t P1 u s (Lonza)

SOURCE: W i tco Corp, : Suggested Formul at 1 ons

% b y We igh t 8 2 . 0 0

0 . 5 0 5 . 0 0 1.50 2.00 2.00 2 . 0 0 1.50 2 . 5 0 1 .oo

g . s .

Creams 125

Moisturizing Daycream

S e r i c i n i n t h i s p l e a s a n t daycream p r o t e c t s t h e s k i n b y i t s f i l m f o r m i n g and m o i s t u r i z i n g p r o p e r t i e s . Due t o t h i s h i g h - m o l e c u l a r p r o t e i n , t h e emu ls ion i s a l s o i d e a l as a make-up base.

___ I t e m : I n n r e d i e n t x 1 A) G l u c a t e SS 2 Glucamate SSE 20 3 S t e a r i c A c i d 4 Promulgen D 5 Modul an 6 P a r a f f i n O i l 7 E u t a n o l G

8 B ) Water demi n e r a l i zed 9 Phenoni p

10 Glucam E 20 11 Carbopol 1342

12 C) T r i e t h a n o l a m

13 D) S e r i c i n 14 Fragrance/Ch

Procedure :

ne

a r a 0/238927

%wVy 1 . 2 0 1 . 8 0 1 . 5 0 1 . o o 1 . o o 5 . 0 0 1 . o o

77 .30 0 . 5 0 4.00 0 I 40

PH 6

5 . 0 0 0 . 3 0

Heat t h e i n g r e d i e n t s o f f a t t y phase A) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase B ) t o 7 5 C . Under s t i r r i n g add phase B ) t o phase A ) , w i t h i t e m 12 a d j u s t

Then add i t e m s 1 3 and 1 4 , one a f t e r a n o t h e r . t h e pH t o 6 . 0 , homogenize and c o o l t o 30C.

SOURCE: Pentapharm L t d . : A p p l i c a t i o n No. A020,A/10.93


Moisturizing Day Cream (Sericin)S e r i c i n i n t h i s p l e a s a n t day cream p r o t e c t s t h e s k i n by i t s

f i l m f o r m i n g and m o i s t u r i z i n g p r o p e r t i e s . Due t o t h i s h i g h m o l e c u l a r w e i g h t p r o t e i n , t h e e m u l s i o n i s a l s o i d e a l as a make-uD base. Item I n g r e d i e n t s :

1 A) G l u c a t e SS 2 3 4 5 6 7 8 B) 9

10 11 12 C) 13 D) 14

Procedure :

Glucamate SSE 20 S t e a r i c A c i d Promulgen D Modul an P a r a f f i n O i 1 Eutano l G Dei o n i zed Water Phenoni p Glucam E 20 Carbopol 1342 T r i e t h a n o l a m i n e , q . s . pH 6 . 0 S e r i c i n Fragrance-Ch iara 0/238927

Wei q h t % 1 . 2 0 1 . 8 0 1 .50 1 - 0 0 1 . o o 5 .00 1 .oo

77.30 0 . 5 0 4 . 0 0 0 .40

5 .00 0 . 3 0

Heat t h e i n g r e d i e n t s o f f a t t y phase A) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase B) t o 75C. Under s t i r r i n g add phase 0 ) t o phase A) , w i t h i t e m 12 a d j u s t t h e pH t o 6.0, homogenize and c o o l t o 30C. Then add i t e m s 13 and 14 one a f t e r t h e o t h e r .

SOURCE: Pentapharm L t d . : A p p l i c a t i o n No. A 020.A/10.93

Incroquat Behenyl TMS Cream T h i s b a s i c f o r m u l a t i o n shows how I n c r o q u a t Behenyl TMS can

f o r m a s t a b l e and e l e g a n t , y e t s i m p l e , e m u l s i o n . The s o f t / powdery f e e l i t c o n f e r s on t h e s k i n i s due t o t h e c o n d i t i o n i n g e f f e c t s o f t h e behenyl q u a t . I n g r e d i e n t s : Weight% P a r t A : I n c r o q u a t Behenyl TMS (Behentr imonium M e t h o s u l f a t e (and) C e t e a r y l A l c o h o l ) 3 .00

Crodamol I S N P ( I s o s t e a r y l Neopentanoate) 5.00 D i m e t h i c o n e 200 (2OOcps) 1 .oo Vo lpo S-2 ( S t e a r e t h - 2 ) 0 .10 Vo lpo S-10 ( S t e a r e t h - 1 0 ) 0 . 5 0 P e t r o l a t u m 2 .00 P a r t B: Dei o n i zed Water 79.40 P a r t C : Dei o n i zed Water 5 .00 H y d r o t r i t i c u m WAA (Wheat Amino A c i d s ) 1 . o o P a r t D : P r o p y l e n e G l y c o l (and) D i azo1 i d i n y l Urea (and) Methy lparaben (and) P r o p y l p a r a b e n 1 .oo

Crodasome CM-Glucan (Sodium Carboxymethy l B-Glucan) 1 . o o I n c r o m e c t a n t LAMEA (Acetamide MEA ( a n d ) Lactamide MEA) 1 . 0 0

SOURCE: Croda I n c , : F o r m u l a t i o n SC-269

pH=5.0+-0.5 Viscosity=16,000cps+-lO% (RVT S p i n d l e #TC, 10 rpm, 25C)

Creams 127

Moisturizing Skin CreamAn e l e g a n t and r i c h m o i s t u r i z i n g cream based on t h e NMF

( N a t u r a l M o i s t u r i z i n g F a c t o r ) concep t of Prodew 100. I n g r e d i e n t : W t .%* A : D e i o n i z e d Water 59 .60

Veegum HV, Magnesium Aluminum S i l i c a t e 1 . o o T r i e t h a n o l ami ne , 99% 2 . 4 0 Rhodi g e l , Xanthan Gum 0 . 2 0

B: Squalane ( F i t o d e r m ) 6.00 C e t y l P a l m i t a t e 4 .00 D i o c t y l M a l e a t e 8 .00 P r o p y l e n e G l y c o l I s o s t e a r a t e 4 .00 P e n t a e r y t h r i t y l T e t r a p e l a r g o n a t e 4 .00 D i me th i cone ( 100 c s . ) 0 . 8 0 Hydrogenated Soy G l y c e r i d e 1 - 0 0 S t e a r y l A l c o h o l 1 . 0 0

Sodium PCA (and) H y d r o l y z e d C o l l a g e n (Prodew 100) 3 . 0 0 P r e s e r v a t i v e q . s .

Weigh t h e P a r t A w a t e r i n t o a s u i t a b l e v e s s e l and m ix w i t h a

S t e a r i c A c i d 5 . 0 0 C : S o r b i t o l (and) Sodium L a c t a t e (and ) P r o l i n e (and )

Procedure:

homogenizer a t 5000 rpm. Weigh and d r y b l e n d t h e Veegum HV and R h o d i g e l , add them s l o w l y t o t h e w a t e r and c o n t i n u e m i x i n g f o r 20 m i n u t e s . B e g i n h e a t i n g t o 6%. Add t h e r e m a i n i n g P a r t A i n g r e d i e n t s and c o n t i n u e m i x i n g a t 5000 rpm. Weigh t h e P a r t B i n g r e d i e n t s i n t o a n o t h e r v e s s e l . M i x and h e a t t o 70C. Add P a r t B t o P a r t A and m ix f o r 10 m i n u t e s a t 5000 r p m . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o p roduce a s m a l l v o r t e x . Cool w h i l e m i x i n g t o 35C and add t h e P a r t C i n g r e d i e n t s i n o r d e r , m i x i n g each f o r 5 m i n u t e s . C o n t i n u e c o o l i n g and package a t a t 25-3OC.

I n a r e d i e n t s : W t .%* A : S t e a r i c A c i d 2 .00

C e t y l A l c o h o l 2 .00 I s o p r o p y l M y r i s t a t e 2 .00 L a n o l i n O i l ( L a n t r o l 1673) 10.00

Moisturizing Cream

G l y c e r y l S t e a r a t e (and ) PEG-100 S t e a r a t e ( A r l a c e l 165) 3 . 0 0 B : Veegum , Magnesi um A1 umi num S i 1 i c a t e 1 .50

D e i o n i z e d Water 74.50 C : G l y c e r i n 4 .00

D: P r e s e r v a t i ve 9 . S . Procedure :

homogenizer o p e r a t i n g a t 5000 r p m and b e g i n h e a t i n g t o 70C. S l o w l y add t h e Veegum and m ix f o r 20 m i n u t e s . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g each f o r 3 m i n u t e s a t 5000 rpm. Weigh t h e P a r t A i n g r e d i e n t s i n t o a n o t h e r v e s s e l . M i x and h e a t t o 70C. Add P a r t A t o P a r t B a t 70C and m i x f o r 10 m i n u t e s a t 5000 rpm. Move t h e b a t c h t o a p r o p e l l e r m i x e r , a d j u s t t h e speed t o p roduce a s m a l l v o r t e x and b e g i n c o o l i n g . A t 40C, add P a r t D and package a t 35C. *As r e c e i v e d b a s i s SOURCE:R.T.Vanderbilt Co., I n c . : Formulas: Centerchem/ICI Amer ica

T r i e t h a n o l ami ne , 99% 1 . o o

Weigh t h e P a r t B w a t e r i n t o a s u i t a b l e v e s s e l . M i x w i t h an


Multi Purpose Cream

T h i s w h i t e , creamy e m u l s i o n ha5 a good c o s m e t i c t e x t u r e and i s s u i t a b l e f o r d i f f e r e n t a p p l i c a t i o n s . P h y t a l u r o n a t e adds a p l e a s - a n t s l i p t o t h e f o r m u l a , whereas F i t o b r o s i d e ( p e n e t r a t i o n enhancer) and R e v i t a l i n - B T e x e r t t h e i r a c t i o n s i n deeper l a y e r s o f t h e s k i n .

I t e m : 1 2 3 4 5 6 7

I n Q r e d i e n t s : A ) G l u c a t e SS

Glucamate SSE 20 S t e a r i c a c i d Promulgen D Modul an M i n e r a l o i l E u t a n o l G

8 8 ) Water demi n e r a l i zed 9 I m i d a z o l i d i n y l u r e a

10 Phenoni p 11 Glucam E 20 12 P h y t a l u r o n a t e 13 Revi t a l i n-BT 14 Carbopol 1342

%w/w 1 . 2 0 1 . 8 0 1 . 5 0 1 . o o 2 . 0 0 4 .00 2 .QO

71 - 6 0 0 . 2 0 0 . 3 0 4.00 3 . 0 0 3 .00 0 . 5 0

15 C) T r i e t h a n o l ami ne 0 . 6 0

16 D ) F i t o b r o s i d e 3 . 0 0

17 E ) Fragrance /B lack Dragon I 1 0/232511 0 . 3 0

P rocedure : Heat t h e i n g r e d i e n t s o f f a t t y phase A ) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase 8 ) t o 75C. Under s t i r r i n g add phase 8) t o phase A ) , w i t h phase C ) a d j u s t

Than add phases D) and E) one a f t e r a n o t h e r and s t i r c o l d . t h e pH t o 6 . 0 , homogenize and c o o l t o 3 0 C .

SOURCE: Pentapharm L t d . : A p p l i c a t i o n No. A 028.6/07.93

Creams 129

Neck Firming Cream

Formul a t i n g Desi gn and Advantages : The neck i s t h e most n e g l e c t e d p a r t o f t h e body and shows

t h e f i r s t v i s i b l e s i g n s o f a g i n g . T h i s p r o d u c t d e l i v e r s a c t i v e s t o t h a t a r e a i n a c o s t e f f e c t i v e p r o d u c t wh ich has e m o l l i e n t and m o i s t u r i z i n g p r o p e r t i e s t h a t f i r m s t i n y l i n e s . C o n t i n u e d use h e l p s promote t h e l o o k o f f i r m , r e s i l i e n t , s o f t , y o u t h f u l - l o o k i n g s k i n .

Phase A : Deodor i zed Orange Wax ( K o s t e r Keunen) Emu1 s i f y i ng Wax NF ( K o s t e r Keunen) Shea B u t t e r (Sederma) S t e a r i c Ac id (Unichema) M i n e r a l O i l ( W i t c o ) I s o p r o p y l P a l m i t a t e (Unichema) G l y c e r o l Monos tea ra te ( K o s t e r Keunen) Squalane ( B a r n e t ) P h y t o g l y c o l i p i d ( B a r n e t ) C e t y l S t e a r y l A l c o h o l (P&G)

Phase B: Water ( D i s t i 1 l e d ) Carbopol 940 ( B . F . G o o d r i c h ) T r i e t h a n o l a m i n e (Dow) G1 y c e r i n (Uni chema) A l o e Vera Gel ( A c t i v e O r g a n i c s ) P r o p y l e n e G l y c o l (Dow) Germaben I 1 ( S u t t o n )

Phase C: E l a s t o s o l Animal C o l l a g e n & E l a s t i n (Croda)

3.0 5 . 0 3 . 0 3 . 0 5 . 0 5 . 0 1 . 5 3 . 0 2 . 0 0 . 5

5 7 . 9 0 . 2 0 . 4 2 . 0 0 . 5 2 . 0 1 . o

5 . 0

P rocedure :

homogeneous. Heat Phase B t o 75C w h i l e m i x i n g . Add Phase A t o Phase B under r a p i d a g i t a t i o n . Cool t o 45C and add Phase C . C o n t i n e m i x i n g t i l l 35 t o 40C.

A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t : Sunscreens a r e e a s i l y i n c o r p o r a t e d i n t o a f o r m u l a o f t h i s

t y p e . By r e d u c i n g t h e c o n c e n t r a t i o n o f w a t e r and /o r t h e o i l s , E s c a l o l 507 (Van Dyk) can b e s u b s t i t u t e d a t a p p r o x i m a t e l y 5% t o p roduce an SPF o f 6-8.


Weigh o u t m a t e r i a l s f o r Phase A , h e a t t o 80C and m i x t i l l


Night Cream

Phase : A A A A A B B B B B B B B C D

I n g r e d i e n t : D e i o n i zed Water Sodi um B o r a t e G1 y c e r i n Xanthan Gum Te t rasod ium EDTA C e t e a r y l A1 coho1 S o r b i t a n Sesqui 01 e a t e G l y c e r y l Monos tea ra te O i l s o f A loha Macadamia Nut O i l V i t a m i n E A c e t a t e Beeswax M i n e r a l O i l O c t y l P a l m i t a t e Germaben I 1 F rag rance

Wt% 43.45

0 . 7 0 2.00 0 . 3 0 0 .10 2 . 0 0 2 . 0 0 5 . 0 0 8.00 0 . 2 0

1 2 . 0 0 15.00 8 .00 1 .oo 0 . 2 5

M a n u f a c t u r i n g Procedure:. Heat Phase A t o 75C. Heat Phase 6 t o 75C. Add Phase B t o Phase A . Cool t o 40C. Add remai n i ng phases . Homogeni ze .

T h i s f o r m u l a i s meant t o be l e f t on t h e s k i n and t o have a h e a v i e r f i l m so t h a t i t l a s t s a l l n i g h t . T h i s i s a w a t e r i n o i l emu ls ion and t h e p r i n c i p a l e m u l s i f i e r s a r e S o r b i t a n S e s q u i o l e a t e and a c o m b i n a t i o n o f sodium b o r a t e and beeswax. The c o m b i n a t i o n o f o i l s g i v e s p r o p e r w e i g h t and f e e l . Cou ld be a l l Macadamia Nut O i l , b u t i t m i g h t be expens ive . T h i s f o r m u l a t i o n can a l s o be used as a makeup remover f o r l i p s t i c k and eye makeup. SOURCE: O i l s o f A loha: Suggested F o r m u l a t i o n

Cold Cream

Formula: P o l y s y n l a n e ( P o l y e s t h e r ) C a r n a t i o n M i n e r a i O i 1 (Wi t c o ) P a r a f f i n Wax I . P . M . Beeswax Lano l i n Propy lene G l y c o l P o t a s s i um Hydrox i de A r l a c e l 40 P . O . E . S o r b i t o l Beeswax S t e a r i c A c i d Perfume, P r e s e r v a t i v e s Water, t o

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n

% by Weigh t 32 # 0

4 . 0 4 . 0 8 . 0 3 . 0 8 . 0 4 . 0 0 . 3 2 . 5 1 . o 1 . 5 q . s

1 0 0 . 0

Creams 131

Night Cream

M i n e r a l O i l R i t a c h o l R i t a c h o l 1000 P a t i o n i c SSL R i t a EGMS P a t i o n i c I S L R i tawax Propy lpa raben D i s t i l l e d Water P ropy lene G1 y c o l Me thy lpa raben

pH: 5 . 2 V i s c o s i t y : 135,000 cps S t a b i 1 i ti e s :

4F: No change a f t e r 3 c y c l e s 40F: V . s l . s e p a r a t i o n a f t e r 1 week

11OF: V . s l . s e p a r a t i o n a f t e r 24 h r s . F o r m u l a t i o n 111-204

Night Cream

M i n e r a l O i l R i t a c h o l R i t a c h o l 1000 P a t i o n i c SSL R i t a EGMS P a t i o n i c I S L R i tawax P r o p y l p a r a b e n D i s t i l l e d Water P r o p y l ene G1 y c o l Me thy lpa raben R i t a v e n a 5

pH: 5 . 0 V i s c o s i t y : 175,000 cps S t a b i 1 i t i e s :

4F: No change a f t e r 3 c y c l e s 40F: No change a f t e r 6 weeks

11OF: S1. s e p a r a t i o n a f t e r 24 h r s . F o r m u l a t i o n 111-205

5 8.00 4 .00 8 .00 6 . 0 0 5 . 0 0 2.00 1 . o o 0 .10

60.70 5 .00 0 . 2 0

Q 8.00 4 .00 8 . 0 0 6 . 0 0 5 . 0 0 2 .00 1 . o o 0 .10

58 .70 5 .00 0 . 2 0 2 . 0 0

SOURCE: R . 1 , T . A . Co rp , : Ritavena 5: Suggested Formulations


Night Repair Cream

- I n q r ed i e_n_t,s_ 1 . N a t u r a l Beeswax 2 , O z o k e r i t e 3 . L i g h t M i n e r a l O i l 4 . R i t a I P M ( I s o p r o p y l M y r i s t a t e ) 5 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 6 . R i t o x 59 (PEG-100 S t e a r a t e ) 7 . R i t a c h o l 2000 ( C e t e a r y l A l c o h o l and P o l y s o r b a t e - 6 0 ) 8 . R i t a c e t - 2 0 (Ce tea re th -20 ) 9 . I s o s t e a r i c A c i d 10 .Tocophero l 1 1 . R e t i n y l P a l m i t a t e 1 2 . D i s t i l l e d / D e i o n i z e d Water 1 3 , D i a z o l i d i n y l Urea 14.Sodium B o r a t e 1 5 . A c r i t a m e r 940 (Carbomer) 1 6 . R a f f e r m i n e ( H y d r o l y z e d Soy F l o u r ) 17. Tens i ne (Wheat P r o t e i n )

7 . 3 0 4 .30

19 .50 2 . 3 0 2 .10 1 . 5 0 1 .20 1 . o o 0 . 8 0 0 . 1 0 0 .10

53.25 1 * o o 0 . 4 0 0 . 1 5 2 . 0 0 3 . 0 0

Compounding Procedure : D i s p e r s e i t e m 15 i n i t e m 12 w h i l e h e a t i n g t o 70C. Combine

i t e m s 1-11 and h e a t t o 7 0 C . Add t o w a t e r phase. Add i t e m s 13 and 14 and mix w h i l e c o o l i n g . A t 40C add i t e m s 16 and 1 7 .

R e f . N o . 122-17C

Cleansing Cream

A g l o s s y w a t e r - i n - o i 1 c l e a n s i ng cream c o n t a i n i ng C1 a r i s k i n w i t h t h e p r o p e r t i e s o f a t t e n u a t i n g s k i n bro+dn s p o t s .

I ng r ed i en t s : 1 . R i t a h y d r o x ( H y d r o x y l a t e d L a n o l i n ) 2 I R i t a s o l ( I s o p r o p y l L a n o l a t e ) 3 . N a t u r a l BeeSwaX 4 . M i n e r a l O i l (D rakeo l -9 ) 5 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 6 . O z o k e r i t e 7 . D i s t i 11 ed/Dei o n i zed Water 8 . B i o c a r e Polymer HA-24 9 . Borax ( 9 9 . 5%) 1 0 . C l a r i s k i n (Yeas t E x t r a c t ) 11.Germaben I I E 12.Perfume

- %wJy 3 . 0 0 2 . 0 0

10 .00 4 4 . 0 0

2 . 0 0 5 . 0 0

23 .60 3 . 8 0 0 . 6 0 5 . 0 0 1 - 0 0

q . s .

Compoundi ng Procedure :

Heat t o 45-50C i f necessa ry . When d i s p e r s e d , add i t e m 9 and h e a t t o 80C. M i x i t e m s 1-6 and hea t t o 8 0 C . Add w a t e r phase t o o i l phase w i t h a g i t a t i o n . Add i t e m 11 a t 75C. Con t inue t o mix u n t i l m i x t u r e reaches 35C, t h e n add i t e m s 1 0 and 1 1 .


Add i t e m 8 t o i t e m 7 a t 25C. Mix u n t i l t h o r o u g h l y d i s p e r s e d .

R e f . No. 122-798

Creams 133

Night Repair Cream

Formula: O c t v l d i m e t h v l Paba F i n s o l ve C a r n a t i o n M i n e r a l O i l ( W i t c o ) Wh i te P r o t o p e t 1s ( W i t c o ) S t e a r i c Ac id A c e t y l a t e d - L a n o l i n Amerchol -L-101 Genero l -1 22 Generol-122E-10 Lexemul Benzy le , A l c o h o l Ceraphy l -65 G l y c e r i n Se l a s t i n E L - 1 0 (Seco l ) Water C o l l a g e n Secolan BA 1-1% S o l u t i o n ( S e c o l ) Na-Hya lu rona te S e l u r o n 1% S o l u t i o n ( S e c o l ) Germa l l 115 F rag rance

% by Weiqh t 3 2 2 3 2 3 3 2 3 8 3 2 5

10 q . s .

5 3 0 .25

As D e s i r e d

Facial Cleansing Cream

Formula: A : G e l w h i t e GP Water S o r b i t o 1 (70%) B : P o l e s t a r 400A (ECC Amer ica) C : C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) S o l u l a n 16 Tween 80 A r l a c e l 186 Whi t e P r o t o p e t 1 S S y n t h e t i c Beeswax P r e s e r v a t i v e s

% by Weight

2 . 0 31 . O

5 . 0

20 .0

1 7 . 0 3 . 0 1 . o 3 . 0

1 0 . 0 5 . 0 q . s .

Procedure :

shear . Add g l y c e r i n e and S o r b i t o l a t moderate speed u n t i l smooth. Add B t o A w i t h s l o w m i x i n g . Combine C and h e a t t o 65C. Heat A/B t o 70C and s l o w l y add t o C . C o n t i n u e m i x i n g u n t i l temp. c o o l s t o 30C. Add d e s i r e d p r e s e r v a t i v e s and m ix u n t i l smooth and u n i f o r m .


S l o w l y add G e l w h i t e t o t h e w a t e r w h i l e m i x i n g a t maximum


Night Time Moisturizing Cream

R i c h e m u l s i o n c o n t a i n i n g R i t a s i l 190 as a l u b r i c a n t .

I n g r e d i e n t s : 1 . M i n e r a l O i l ( B r i s t o l 9 NF) 2 . R i t a IPP ( I s o p r o p y l P a l m i t a t e ) 3 . S t e a r i c A c i d 4 . R i t o x 52 (PEG-40 S t e a r a t e ) 5 . R i t a s i l 190 ( D i m e t h i c o n e C o p o l y o l ) 6 . R i t a l a n ( L a n o l i n O i l ) 7 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 8 . D i s t i 11 ed/Dei o n i zed Water 9 . T r i e t h a n o l a m i n e @ 99Y0 10 .Dermacry l -79 (Acrylates/Octylpropenamide Copolymer) 1 1 . A c r i t a m e r 934 (Carbomer 934) 12 . Germaben 11 E 13. F r a g r a n c e

o/ow/w 10.00

2 . 0 0 4 .00 1 . o o 1 . o o 0 .50 3,OO

74.75 1 . 3 0 1 . o o 0 . 2 5 1 . o o 0 .20

Compounding P rocedure : Heat w a t e r and T r i e t h a n o l a m i n e 99% t o 80C. S l o w l y s i f t

i t e m 10 and m i x u n t i l c o m p l e t e l y d i s s o l v e d . S i f t i t e m 11 s l o w l y . Combine i t e m s 1-7 i n a s e p a r a t e v e s s e l , h e a t t o 80C and m ix u n t i l c l e a r . Add i t e m s 1-7 t o i t e m s 8-10 and m i x f o r 30 m i n u t e s a t 80C. Cool t o 40C, t h e n add i t e m s 12 and 13 .

R e f . No. 121-96

Cleansing Cream

A c l e a n s i n g cream w i t h R a f f e r m i n e t o promote s k i n f i r m n e s s and reduce s k i n e l a s t i c i t y w i t h e m o l l i e n c e f r o m R i t a c h o l and humectancy f rom g l y c e r i n e .

I n g r e d i e n t s : 1 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 2 . R i t a c h o l ( M i n e r a l O i l and L a n o l i n A l c o h o l ) 3 . M i n e r a l O i l ( L i g h t ) 4 . R i t a c h o l 2000 ( R . I . T . A . B l e n d ) 5 , D i s t i 11 ed/Dei o n i zed Water 6 . G l y c e r i n e 7 , R a f f e r m i n e ( H y d r o l y z e d Soy F l o u r ) 8 . G l y d a n t 9 . F rag rance

o/,w/w 3 .00 4 . 0 0

20 I O 0 3 .00

6 2 . 0 0 5 . 0 0 2 . 0 0 1 . o o

q . s .

Compoundi ng P rocedure :

h e a t t o 70C w i t h m i x i n g . Add o i l t o w a t e r w i t h m i x i n g . Cool t o 40C and add i t e m s 7-9.

Combine i t e m s 1 -4 and h e a t t o 70C. Combine i t e m s 5 and 6 and

Ref. No. 120-205A

SOURCE: R , I . T . A , C o r p . : Suggested F o r m u l a t i o n s

Creanis 135

Nighttime Moisturizing Cream

A g l o s s y w h i t e n i g h t cream c o n t a i n i n g a c o l l a g e n f i b e r r e s t r u c t u r i ng b o o s t e r : R a f f e r m i n e . T h i s e l e g a n t cream a1 so c o n t a i n s R i t a IPP and R i t a l a n as e m o l l i e n t s .

I n n r e d i e n t s : 1 . M i n e r a l O i 1 2 . R i t a IPP ( I s o p r o p y l P a l m i t a t e ) 3 . S t e a r i c A c i d 4 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 5 . R i t o x 52 (PEG-40 S t e a r a t e ) 6 . R i t a s i l 190 ( D i m e t h i c o n e C o p o l y o l ) 7 . R i t a l a n ( L a n o l i n O i l ) 8 . D i s t i 1 1 ed/Dei o n i zed Water 9 . T r i e t h a n o l a m i n e (99%) 10. A c r y l a t e s / t - O c t y l propenami de Copolymer 1 1 . A c r i t a m e r 934 (Carbomer) 12.Germaben I I E 13. Fragrance 1 4 . R a f f e r m i n e ( H y d r o l y z e d Soy F l o u r )

%w/w 10.00

2 .00 4 . 0 0 3 .00 1 . o o 1 . o o 0 . 5 0

71 - 9 5 1 . 3 0 1 . o o 0 . 2 5 1 . o o q . s

3.00

Compounding Procedure :

and mix u n t i l c o m p l e t e l y d i s s o l v e d . Then s l o w l y add A c r i t a m e r and mix u n t i l d i s s o l v e d . Combine i t e m s 1 - 7 and h e a t t o 80C and mix u n t i l c l e a r . Add t o w a t e r and mix f o r 30 m i n u t e s a t 80C. Cool t o 40C and add i t e m s 12-14.

Combine i t e m s 8 and 9 and h e a t t o 80C. S l o w l y add i t e m 10

R e f . No. 122-3A

Under Make-up Cream for Normal Skin

An e l e g a n t , non-greasy, p r o t e c t i v e day cream f o r under make-up use, Tens ine smoothes t h e s k i n and h e l p s make-up s t a y on.

I n g r e d i e n t s : 1 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 2 . C e t e a r e t h - 1 5 3 . R i t a I P P ( I s o p r o p y l P a l m i t a t e ) 4 . R i t a c h o l 2000 ( R . I . T . A . B l e n d ) 5 . D i s t i 11 ed/Dei o n i zed Water 6 . Propy lene G l y c o l 7 . Methy lparaben 8 . Propy lparaben 9 . Borage O i l 10. Fragrance 11 I Tensi ne (Wheat P r o t e i n )

%w/w 8 . 0 0 3 .00 5 .00 5 .00

63 .80 5 .00 0 . 1 5 0 . 0 5 3 .00 1 . o o 6 . 0 0

Compounding Procedure : Heat i t e m s 1-4 t o 70C. Heat i t e m s 5-8 t o 70C. Add o i l t o

w a t e r . Cool t o 40C. Add i t e m s 9-11. R e f . No. 122-13

SOURCE: R . I , T . A , C o r p . : Suggested F o r m u l a t i o n s


Oil-Free Exfoliating Cream

Formul a t i ng Desi gn and Advantages : The use o f n a t u r a l e x f o l i a t i n g agent ( e a s i l y d i s p e r s e d ) i n

t h i s cream f o r m u l a g i v e s a marve lous , n o n - i r r i t a t i n g , a b r a s i v e q u a l i t y f o r t h e removal of spent s u r f a c e c e l l s . T h i s w i l l renew and r e v i t a l i z e worn and damaged s k i n , l e a v i n g a b a r r i e r wh ich c o n t a i n s n a t u r a l a n t i - o x i d a n t s i n h e r e n t i n t h e beeswax and d e o d o r i z e d orange wax.

Phase A : Deodor ized Orange Wax ( K o s t e r Keunen) Hydroxy P o l y e s t e r ( K o s t e r Keunen) I s o s t e a r i c A c i d (Unichema) D i meth i cone 200/100 (Dow) G l y c e r o l Monosteara te ( K o s t e r Keunen) C e t y l S t e a r y l A l c o h o l (P & G) O c t y l P a l m i t a t e (Unichema)

Phase B: Water ( D e i o n i z e d ) Propy lene G l y c o l (Dow) T r i e t h a n o l ami ne (Dow) P o l y s o r b a t e 60 ( S p e c i a l t y I n d u s t r i a l Prod . ) Carbopol 940 (BFGoodr ich) M e t h y l Paraben ( A l d r i c h )

Wt% 3 . 0 2 . 0 3 . 0 7 . 5 1 . 5 1 . o 3 . 0

6 4 . 3 5 2 . 5 1 . o 0 . 2 0 . 2 0 . 7 5

Phase C: M i c r o g r a n u l a t e d Carnauba, 20-60 mesh ( K o s t e r Keunen) 1 0 . 0

Procedure :

B a t 75C under a g i t a t i o n . C o n t i n u e m i x i n g and c o o l t o 50C. Add Phase C and mix u n t i l homogeneous.


i n g s t e a r i c a c i d f o r i s o s t e a r i c a c i d , t o accomodate your p r e f e r r e d c o n t a i n e r . For s e n s i t i v e s k i n , reduce t h e orange wax, and r e p l a c e w i t h K e s t e r Wax 62 and C e r e s i n 130/135. A low v i s c o s - i t y w i l l a l l o w t h i s p r o d u c t t o be packaged i n an open j a r . The f o r m u l a t i n g advantages remain u n - a l t e r e d by t h e changes i n v i s c o s i t y .

SOURCE: K o s t e r Keunen, I n c : A Guide t o N a t u r a l F o r m u l a t i n g

Add a mixed and u n i f o r m Phase A t o a mixed and u n i f o r m Phase

V i s c o s i t y o f t h i s p r o d u c t can e a s i l y be a l t e r e d by s u b s t i t u t -

Creams 137

O/W-Cream

Rec ipe : A H o s t a c e r i n DGS

Wt% 5 . 0 0

H o s t a c e r i n DGL I s o p r o p y l p a l m i t a t e Almond o i 1 J o j o b a o i l Wheat germ o i l Sunf 1 ower o i 1 A n t i o x i dan t

B Carbopo l 980

C Aquamo l l i n BC p d r . h . c . C i t r i c a c i d (10%) C a u s t i c soda s o l u t i o n ( 1 0 % ) Water P r e s e r v a t i v e

D F rag rance Procedure : 1 M e l t A a t c a . 70C, t h e n add 0 . 2 Heat C t o c a . 70C. 3 S t i r 2 i n t o 1 and s t i r u n t i l c o o l . 4 A t c a . 35C add D t o 3 . 5 Homogenize t h e emu ls ion .

Formula A V I /1852

O/W-Cream"contains no ethylene oxide"

R e c i L e i A H o s t a c e r i n DGMS

M i n e r a l o i l , l o w v i s c o s i t y Eu tano l G Almond o i 1 A n t i o x i d a n t

0 . 5 0 8 . 0 0 4 . 0 0 2 .00 5 . 0 0 4 . 0 0

a . s

0.30

0 . 1 0 0 . 2 5 1 . 2 0

69 .25 q . s

0 . 4 0

W t % 5 . 0 0

1 0 . 0 0 7 . 0 0 6 . 0 0

C I . S

B Carbopo l 980 0 . 5 0

C Hostapon KCG C a u s t i c soda s o l u t i on ( 1 0%) Water P r e s e r v a t i v e

0 . 4 0 2 . 0 0

68 .70 a . s

D F rag rance 0 . 4 0 P rocedure : 1 M e l t A a t c a . 80C, t h e n add B . 2 . Heat C t o c a . 80C. 3 S t i r 2 i n t o 1 and s t i r u n t i l c o o l , 4 . A t c a . 35C add D t o 3 . 5 . Homogenize t h e emu ls ion .

Formula A V I /1751

SOURCE: Hoechs t : Gu ide Rec ipes f o r t h e Cosmet ic I n d u s t r y


O/W-Cream

Reci pe : A H o s t a c e r i n DGMS

Hos tapha t KML M i n e r a l o i l , l o w v i s c o s i t y E u t a n o l G Almond o i 1 I s o p r o p y l p a l m i t a t e A n t i o x i d a n t

B Carbopol 980

C C a u s t i c soda s o l u t i o n (10%) A q u a m o l l i n BC p d r . h . c . C i t r i c a c i d (10%) Water P r e s e r v a t i ve

D F r a g r a n c e

Procedure : 1 M e l t A a t c a . 8OC, t h e n add 0 . 2 Heat C t o c a . 8OC. 3 S t i r 2 i n t o 1 and s t i r u n t i l c o o l . 4 A t c a . 35C add D t o 3 . 5 Homogenize t h e e m u l s i o n .

Formula A V I / 1 5 5 0

O/W-Cream"Contains no ethylene oxide",

manufacturing at room temperature possible

Reci pe : A H o s t a c e r i n D G I

M i n e r a l o i l , l o w v i s c o s i t y I s o p r o p y l p a l m i t a t e E u t a n o l G

B Carbopol 980

C Hostapon KCG Caust i c soda s o l u t i on ( 10%) Water P r e s e r v a t i v e

D F rag rance

Wt% 4.00 2.00 8 . 0 0 6.00 4 . 0 0 4.00

q . s .

0 . 5 0

2 .70 0 . 1 0 0 .25

6 8 . 1 5 q . s .

0 . 3 0

Wt% 2 . 0 0 8 .00 4 . 0 0 4 . 0 0

0 .70

0.80 2 .80

77 I 30 a . s .

0 .40

P rocedure : 1 . S t i r B i n t o A, t h e n add C and s t i r w e l l . 2 . S t i r D i n t o 1 . 3 . F i n a l l y homogenize t h e e m u l s i o n .

SOURCE: Hoechst : Guide Recipes f o r t h e Cosmet ic I n d u s t r y Formula A V1/1752

Creams 139

Phytodermin

Phytodermi n c o n t a i ns s o l u b i 1 i zed h i g h m o l e c u l a r wei g h t c o n s t i t u e n t s o f t h e p l a n t m a t r i x f r o m soybeans i n n a t u r a l d i s t r i b u t i o n : h y d r o x y p r o l i n e - r i c h g l y c o p r o t e i n s as e x t e n s i n s , a r a b i noga l a c t a n s as p r o t e o g l ycan e q u i Val e n t s and p r o 1 i ne- r i c h g l y c o p r o t e i n s . The s p e c i f i c , most g e n t l e p r o d u c t i o n p rocedure a p p l i ed i n t h e case o f Phy todermi n mai n t a i n s , c o n t r a r y t o c o n v e n t i o n a l soya h y d r o l y s a t e s , t h e n a t i v e c h a r a c t e r o f t h e m a t r i x components c o n t a i n e d . I n i n v i v o t e s t s , Phy tode rm in has p roved t o be an e f f i c i e n t a l t e r n a t i v e t o t h e c l a s s i c an ima l d e r i v e d m a t r i x c o m p o s i t i o n .

Regenerative Cream, Type W/O, with PhytoderminIns red ignLs : . Wei n h t %

Dehymu 1 s PGPH Lameform T G I Be e s w a x I s o p r o p y l m y r i s t a t e M y r i t o l 318 C e t i o l 868 Phenoni p Oxynex LM Water , d i s t i 1 1 ed Phenoni p K a r i o n F l i q u i d Phytodermi n

7 . 0 0 3 . 0 0 5 . 0 0

1 0 . 0 0 5 . 0 0 5 . 0 0 0 . 3 0 0 . 1 0

4 9 . 3 0 0 . 3 0 5 . 0 0

1 0 . 0 0 Manu fac tu re : a ) M e l t and b r i n g t o app rox . 75C; b ) Heat t o app rox . 7 5 C and s t i r i n t o a ) .

c ) S t i r i n . Con t inue s t i r r i n g u n t i l c o o l e d t o app rox . 30C;

Perfume, r o l l .

SOURCE: Chemisches L a b o r a t o r i urn D r I K u r t R i c h t e r GmbH: Suggested F o r m u l a t i o n

O/W Basic Cream, Without Paraffin

I n g r e d j e_nts: We1 g h t % A) S o f t i s a n 601 ( G l y c e r y l Cocoate ( a n d ) Hydrogenated

Coconut O i l (and) Ce tea re th -25 ) 3 5 . 0 0 M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 3 . 0 0 C e t y l A l c o h o l 2 . 0 0

B) P r e s e r v a t i ve q . s . Water 6 0 . 0 0 T h i s b a s i c cream can be used t o i n c o r p o r a t e n o n i o n i c a c t i v e

i n g r e d i e n t s . P r e p a r a t i o n :

t e m p e r a t u r e and t h e n e m u l s i f i e d i n t o (A). The cream is t h e n c o n s t a n t l y s t i r r e d u n t i 1 c o o l .

SOURCE: H u l s Amer ica I n c , : F o r m u l a t i o n 1 . 1 N

( A ) i s hea ted t o c a . 65 degrees C . ( B ) is hea ted t o t h e same


Protective Cream with Cromoist CM Glucan

Due t o t h e i n c o r p o r a t i o n o f C romo is t CM Glucan, t h i s cream can p r o t e c t s k i n f r o m e n v i r o n m e n t a l i n s u l t and h e l p i t t o f u n c t i o n b e t t e r . C r o m o i s t CM Glucan i s a u n i q u e p r o t e c t i v e and t h e r a p e u t i c agen t t h a t works by s t i m u l a t i n g t h e s k i n ’ s own d e f e n s e mechanisms, r e s u l t i n g i n p r o t e c t i v e e f f e c t s t h a t enhance s k i n f u n c t i o n and i n c r e a a s e t h e s k i n ’ s r e s i s t a n c e t o UVA- i n d u c e d o x i d a t i v e s t r e s s . C roda fos CES i s a s u b s t a n t i v e phosphate-based e m u l s i f y i n g system t h a t enhances t h e d e l i v e r y o f t h e o t h e r i n g r e d i e n t s and improves t h e a p p l i c a t i o n p r o p e r t i e s o f t h e cream.

I n a r e d i e n t s : Wei q h t % P a r t A : Croda fos CES ( C e t e a r y l A l c o h o l (and) C e t e a r y l Phosphate) 4 . 0 Crodamol GTCC ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 5 . 0 Corona PNL ( L a n o l i n ) 1 . o

P a r t B : Dei o n i zed Water T r i e t h a n o l a m i n e (98%)

P a r t C : D e i o n i z e d Water H y d r o t r i t i c u m WAA (Wheat Amino A c i d s )

6 9 . 8 0 . 2

5 . 0 1 . o

P a r t D : P r o p y l e n e G l y c o l (and ) D i a z o l i d i n y l Urea (and ) M e t h y l -

paraben (and ) P ropy lpa raben 1 . o C romo is t CM-Glucan (Sodium Carboxymethy l B-Glucan) 1 . o I n c r o m e c t a n t LAMEA (Ace tamide MEA (and ) Lac tamide MEA) 5 . 0

P a r t E : Dei o n i zed Water DL Panthenol

5 . 0 2 . 0

pH=4.5+-0.5 V i s c o s i t y = 2 0 , 0 0 0 cps+-10% (RVT S p i n d l e #TC @ 10 rpm @ 25C)

P rocedure :

Combine i n g r e d i e n t s o f P a r t B w i t h m i x i n g and h e a t t o 75-8OC. Add i n g r e d i e n t s o f P a r t A t o B w i t h m i x i n g and c o o l t o 50C. Add i n g r e d i e n t s o f P a r t C, D and E w i t h m i x i n g and c o o l t o d e s i r e d f i 11 t e m p e r a t u r e .

SOURCE: Croda I n c . : F o r m u l a t i o n SC-265

Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 75-8OC.

Creams 141

Rain Forest Cream

T h i s f o r m u l a produces a r e l a t i v e l y v i s c o u s , s h i n y w h i t e cream and f e a t u r e s C r o n a t u r a l Cohune O i l , an e m o l l i e n t o i l h a r v e s t e d o u t o f t h e r a i n f o r e s t , and Crodafos CES. The use o f Crodafos CES enhances t h e f o r m u l a t i o n ' s a p p l i c a t i o n p r o p e r t i e s s i g n i f - i c a n t l y , a l l o w i n g t h e cream t o r u b i n e f f o r t l e s s l y w i t h o u t any i n d i c a t i o n o f d r a g . Crodafos CES c o n f e r s a p l e a s i n g e m o l l i e n c e , p r o v i d i n g t h e s k i n w i t h a c o n d i t i o n e d a f t e r f e e l .

I n g r e d i e n t s : Wt% P a r t A : C r o n a t u r a l Cohune O i l (Cohune O i l ) 10 .00 Crodafos CES ( C e t e a r y l A l c o h o l (and) C e t e a r y l Phosphate) 6 .50

P a r t B: D e i o n i z e d Water Carbomer 2984 G l y c e r i n Na2EDTA

P a r t C: TEA 99%

79.00 0 . 2 0 2.00 0 .05

1 . 2 5

P a r t D: P r o p y l e n e G l y c o l (and) D i a z o l i d i n y l Urea (and) M e t h y l

Paraben (and) P r o p y l Paraben 1 . o o

V iscos i t y=22 ,000+-10% (RVT S p i n d l e 8, 1Orpm @ 25C) pH=7.0+-0.5

Procedure :

Carbomer 2984 i n t o w a t e r o f P a r t B. When f u l l y h y d r a t e d , add g l y c e r i n w i t h m i x i n g and h e a t t o 70-75C. Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 70-75C. Add P a r t A t o P a r t B w i t h m i x i n g . Add C t o A/B w i t h m i x i n g and c o o l t o 40C. Add P a r t D w i t h m i x i n g and c o o l t o d e s i r e d f i l l t e m p e r a t u r e .


D i s s o l v e t h e Na2EDTA o f P a r t B i n d e i o n i z e d w a t e r . D i s p e r s e

N . A . T . C . Approved


Rejuvenating AHA Cream (W/O Emulsion)

I n q r e d i e n t s : O i l Phase: P o l y g l y c e r y l - 4 I s o s t e a r a t e (and ) C e t y l D ime th i cone

Hydrogenated C a s t o r O i l M i c r o c r y s t a l 1 i ne Wax C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) O c t y l S t e a r a t e ( T e g o s o f t OS) I s o p r o p y l M y r i s t a t e ( T e g o s o f t M ) I s o p r o p y l P a l m i t a t e ( T e g o s o f t P) C e t y l D ime th i cone ( A b i l Wax 9801) Cyc l ometh i cone

C o p o l y o l (and) Hexyl L a u r a t e ( A b i 1 WE-09)

Water Phase: Water NaCl P r o p y l ene G1 y c o l Sodi um C i t r a t e M a l i c Ac id G r a n u l a r Sodium L a c t a t e (and ) Sodium PCA (and) G l y c i n e (and )

F r u c t o s e (and ) Urea (and ) N i a c i n a m i d e (and) I n o s i t o l (and ) Sodium Benzoate (and) L a c t i c A c i d ( L a c t i l )

P r e s e r v a t i v e s , C o l o r , F rag rance

Procedure : 1 . Add t h e comoonents o f t h e o i l ohase t o o e t h e r . Heat

Wei q h t %

5 . 0 0 0 . 5 0 0 . 5 0 3 . 0 0 5.00 4 . 0 0 1 . o o 1 . o o 4 .00

70.75 0 .80 2 . 0 0 0 . 6 0 1 . 6 0

0 .25 Q . S .

t o 80-85C t o m e l t a n d ' d i s p e r s e t h e waxes'. When d i s p e r s e d , c o o l and m a i n t a i n a t e m p e r a t u r e o f 45-50C.

2 . M i x w a t e r , p r o p y l e n e g l y c o l and sodium c h l o r i d e t o g e t h e r d i s s o l v i n g sodium c h l o r i d e . Add and m ix t h e r e m a i n i n g i n g r e d - i e n t s o f t h e w a t e r phase.

3 . A d j u s t t h e pH o f t h e w a t e r phase t o 4 . 0 - 4 . 5 i f necessa ry . 4 . W i t h s l o w l i g h t n i n ' m i x i n g , s l o w l y s t r e a m t h e w a t e r phase i n t o

5 . W i t h sweep a g i t a t i o n , cool t o 35C. 6 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e s . 7 . Homogenize w i t h a r o t o - s t a t o r homogenizer .

SOURCE: Go1 dschmi d t Chemical Corp I : Suggested Formul a t i on

t h e o i 1 phase.

Creams 143

Skin Care Cream


appearance, t hough t h e p r o d u c t i o n i s c o s t e f f e c t i v e . There a r e a l s o b a r r i e r and m o i s t u r i z i n g p r o p e r t i e s wh ich a r e h i g h l y e f f - e c t i v e h y d r a t i o n system f o r a l l s k i n t y p e s . The f o r m u l a a l s o w i l l h e l p reduce t r a n s e p i d e r m a l w a t e r l o s s .

T h i s p r o d u c t i m p a r t s good s k i n f e e l and has a h i g h q u a l i t y

Oil Phase: C e t y l S t e a r y l A l c o h o l 1618 (P&G) NF W h i t e Beeswax ( K o s t e r Keunen) I s o p r o p y l P a l m i t a t e (Unichema) L i g h t M i n e r a l Oil ( W i t c o ) P r o p y l e n e g l y c o l D i o c t a n a t e ( I n o l e x ) S t e a r i c A c i d (Unichema) Coconut O i 1 (CocoChem) P r o p y l Paraben ( S u t t o n )

Water Phase: Water ( D i s t i 11 ed) G l y c e r i n e (UniChema) Carboxymethy l C e l l u l o s e (CMC, H e r c u l e s ) Carbopol 940 (BFGoodr ich) Sodium B o r a t e ( B o r a x ) T r i e t h a n o l ami ne (Dow) Me thy l Paraben ( S u t t o n )

wt% 4 . 5 0 2 .50 3 . 0 0 5 .00 1.50 0 . 5 0 1 . 2 5 0 . 2 0

74.25 5.50 0 . 3 0 0 . 6 0 0 - 4 0 0 . 3 0 0 . 2 0

P rocedure : Add t o t h e w a t e r phase under a g i t a t i o n , i n o r d e r ; CMC u n t i l

e v e r y t h i n g i s d i s s o l v e d t h e n p r o p y l paraben w h i l e m i x i n g . Then add Carbopo l , m ix t i l l homogeneous making s u r e t h e r e i s no a g g l o m e r a t i o n . Add t h e rema inder o f t h e w a t e r phase components, m ix and h e a t t o 75C. Add a l l t h e o i l phase components, h e a t t i l l 75C and m i x . Add s l o w l y t h e o i l phase t o t h e w a t e r phase under a g i t a t i o n m a i n t a i n i n g a t e m p e r a t u r e o f 75C. When t h e o i l phase i s added, c o o l and p o u r i n t o c o n t a i n e r .

A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t : By r e d u c i n g t h e c o n c e n t r a t i o n s o f m i n e r a l o i l b y 2.0%,

p r o p y l e n e g l y c o l d i o c t a n a t e by 0.5% and t h e a d d i t i o n o f 2.5% E s c a l o l 507 (Van Dyk) t h e cream w i l l t a k e on an SPF o f 6-8. The p r o d u c t has t h e same appearance, s k i n f e e l and s t a b i l i t y as t h e above f o r m u l a . F rag rances can a l s o be added w i t h o u t a f f e c t i n g i t s t e x t u r e .



Skin Cream

F o r m u l a t i n g Desi gn and Advantages:

cream. The e m u l s i f y i n g wax adds t o t h e s t a b i l i t y and r i c h n e s s o f t h e

O i l Phase: E m u l s i f y i n g Wax NF ( K o s t e r Keunen) Sunf 1 ower O i 1 (A1 n o r o i 1 ) 01 i ve O i 1 , Unsaponi f i ab1 e (Col l a b o r a t i v e Labs) I s o p r o p y l M y r i s t a t e (Unichema) L i q u a p a r ( S u t t o n )

Water Phase: Water ( D e i o n i z e d ) G l y c e r i n e (Unichema)

W> 1 2 . 0

6 . 0 3.0 2 . 0 1 . 0

7 4 . 0 2 .0

P rocedure :

75C. Add o i l phase t o w a t e r phase. C o o l .

A d a p t a t i o n of Formula and I t s I n f l u e n c e on t h e P r o d u c t :


M i x and h e a t o i l phase t o 75C. M ix and h e a t w a t e r phase t o

O t h e r a c t i v e s may b e s u b s t i t u t e d f o r t h e o l i v e o i l .

Hand Care Cream

P a r t A : S e t a c i n F S p e z i a l Pas te I m w i t o r 960 M i g l y o l 840

Water P a r t B : Carboxymethy l C e l l u l o s e

P a r t C : L a c t i c a c i d Perfume, p r e s e r v a t i v e

!&& 5 8 . 0 1 0 . 0

5 . 0

0 . 5 2 5 . 5

0 . 3 0 . 7

M i x p a r t A , B and C each s e p a r a t e l y . Add p a r t B and C s u c c e s s i v e l y t o p a r t A w h i l s t s t i r r i n g .

SOURCE: Zschimmer & Schwarz GmbH & Co.: F o r m u l a t i o n B 2 7 / 1 4

Creams 145

Skin Lightening Night Cream Against Age Spots

T h i s a g r e e a b l e , r i c h n i g h t cream c o n t a i n s M e l f a d e , wh ich has a b l e a c h i n g a c t i v i t y . P e n t a v i t i n p r o v i d e s t h e s k i n w i t h m o i s t u r e and r e g e n e r a t e s t h e s k i n .

Item I n q r e d i e n t s : 1 A) Cremophor A6 2 Cremophor A25 3 C u t i n a GMS 4 L a n e t t e 0 5 S t e a r i c A c i d 6 P a r a f f i n O i l 7 C e t i o l SN 8 Vase1 i ne w h i t e 9 Abi 1-350

10 8) D e i o n i z e d Water 11 I m i d a z o l i d i n y l Urea 12 Phenoni p 13 G1 y c e r i n 14 P e n t a v i t i n 15 M e l f a d e

Wei n h t % 2.50 2 .50 4 .00 3 .00 1 . o o

10 .00 5 . 0 0 3 . 0 0 4 . 0 0

51 - 0 0 0 . 2 0 0 . 5 0 3 . 0 0 5 . 0 0 5 .00

16 C ) F rag rance : Chi a r a 0/238927 0 .30

P rocedure : Heat t h e i n g r e d i e n t s o f f a t t y phase A ) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase B ) t o 75C. Under s t i r r i n g add phase B ) t o phase A ) , c o o l t o 50C, homogenize and c o o l t o 30C. Then add phase C) and s t i r c o l d .

SOURCE: Pentapharm L t d , : A p p l i c a t i o n No. A 032 .8 /01 .96

Cleansing Cream with Salicylic Acid

I n n r e d i e n t s : Weight% A . S o f t i s a n 601 ( G l y c e r y l Cocoate (and ) Hydrogenated

Coconut O i l ( and ) C e t e a r e t h - 2 5 ) 18.00 I m w i t o r 370 ( G l y c e r y l S t e a r a t e C i t r a t e ) 10 .00 M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 15 .00 C e t y l A1 coho1 2 .00 S a l i cy1 i c A c i d 0 .50

B . P r e s e r v a t i ve Water

q . s . up t o 100.00


h e a t e d t o t h e same t e m p e r a t u r e and i s e m u l s i f i e d i n t o " A t t . S t i r u n t i l c o l d .

I n g r e d i e n t s o f "A t1 a r e m e l t e d t o abou t 75 degrees C . " B t l i s

SOURCE: H u l s Amer ica I n c . : F o r m u l a t i o n 1 . 1 L


Skin Rejuvenating Cream

A s y n e r g i s t i c c o m b i n a t i o n o f Gum i s used t o t h i c k e n and s t a b Approx i mate1 y 5% G1 y c o l i c Ac i d , o r a t e d i n t o t h e f o r m u l a t o p r o v a t i n g f u n c t i o n .

Veegum P l u s and Rhod ige l Xanthan l i z e t h i s o i l - i n - w a t e r e m u l s i o n . an a lpha-hydroxy a c i d , i s i n c o r p - de i t s we l l -known s k i n r e j u v e n -

I n n r e d i e n t : A : Veegum P1 us, Magnesi um A1 umi num S i 1 i c a t e

Dei o n i zed Water Rhodi g e l , Xanthan Gum

W t .%* 0 . 9 5

63 I 67 0 . 2 9

B : G l y c e r i n 4 .75

C: T r i e t h a n o l a m i n e , 99% 0 . 7 1

D : C e t y l A l c o h o l 2 . 8 5 G l y c e r y l S t e a r a t e (and) PEG-100 S t e a r a t e ( A r l a c e l 165) 4 . 2 8 S t e a r i c A c i d 1 . 4 3 I s o p r o p y l P a l m i t a t e 4 . 2 8 M i n e r a l O i 1 ( a n d ) Lano l i n A l c o h o l (Amerchol L-101) 4 .28 D imeth icone (350 c s . ) 1 . 4 3

E : P r e s e r v a t i ve G l y c o l i c A c i d (67% S o l n . ) Sodi urn H y d r o x i de (50% Sol n . )

0 .95 7 . 1 3 3 .00

Procedure :

m i x t u r e t o room t e m p e r a t u r e w a t e r w h i l e s t i r r i n g w i t h a p r o p e l l e r m i x e r a t 1800 rpm. C o n t i n u e m i x i n g f o r 30 m i n u t e s . Add P a r t B and mix 5 m i n u t e s . Heat P a r t s A+B t o 50-55C and add P a r t C . M i x 3 m i n u t e s . Heat t h e w a t e r phase t o 75C. M i x and h e a t P a r t D t o 75-80C. Add P a r t D t o p a r t s A+B+C w h i l e s t i r r i n g a t 1800 rpm f o r 10 m i n u t e s . M a i n t a i n t e m p e r a t u r e a t 75C. Beg in c o o l i n g w h i l e s t i r r i n g . A t 40C, add P a r t E i n t h e o r d e r shown, m i x i n g each u n t i l u n i f o r m . C o n t i n u e c o o l i n g and s l o w t h e s t i r r e r t o 900 rpm. Check t h e pH and a d j u s t , i f necessary , t o 4 . 2 - 4 . 5 . Package a t

Dry b l e n d t h e Veegum P l u s and R h o d i g e l and s l o w l y add t h e

35-38C. *As r e c e i v e d b a s i s

SOURCE: R , T . V a n d e r b i l t Co., I n c , : Veegum F o r m u l a t i o n No. 462

Creams 147

Skin Therapy Cream

I n g r e d i e n t s : Phase A : Phosphol i p i d GLA Phosphol i p i d SV G l y c e r i n T i t a n i u m D i o x i d e Germaben I I E

Water

Phase 6: C e t y l A l c o h o l S t e a r e t h - 2 Monafax 160 Squal ane O c t y l S t e a r a t e I s o p r o p y l P a l m i t a t e Dow C o r n i n g F l u i d 200/350 c s .

AMP-95

% b y Weight

1 . 5 0 2 . 2 0 2 .00 0 . 5 0 0 .40 0.40

80.00

2 . 0 0 2 .00 1 - 0 0 0 .80 4 .00 2 . 4 0 0 . 8 0

P rocedure :

w i l l t h i c k e n beyond use.

SOURCE: Angus Chemical Co. : P roduc t F o r m u l a r y : F o r m u l a t i o n

Add Phase 6 t o Phase A v e r y s l o w l y ; keep v i s c o s i t y low o r i t

PF-0347 sugges ted by Mona I n d u s t r i e s

Cream, Type O/W, with Protectan*

a ) C u t i n a MD C u t i n a CP Eumulg in 61 Eumulg in 62 C e t i o l 6 Phenon i p

b ) Water , d i s t i l l e d Phenoni p Carbopol 940 T r i e t h a n o l ami ne G1 y c e r i n

% b y Weight 4 .00 4 .00 1 .oo 1 . o o 5 .00 0 .30

70.40 0 . 3 0 0 . 5 0 0 . 5 0 3 . 0 0

c ) P r o t e c t a n 10 .00

M a n u f a c t u r e :

s t i r i n t o a ) . C o n t i n u e s t i r r i n g u n t i l c o o l e d t o app rox . 30C. Add c ) w i t h s t i r r i n g . Perfume, homogenize.

M e l t a ) and b r i n g t o app rox . 70C. B r i n g b ) t o app rox . 70C and

* P r o t e c t a n i s a Lac tococcus l a c t i s l y s a t e . H i g h a n t i o x i d a t i v e p o t e n t i a l .

SOURCE: Chemi sches L a b o r a t o r i um D r . K u r t R i c h t e r GmbH: Formula


Ultra Skin Treatment Cream

Veegum U l t r a i s an i d e a l c a n d i d a t e f o r t h i c k e n i n g and s t a b i l - i z i n g t h i s a c i d i c o i l - i n - w a t e r e m u l s i o n because i t y i e l d s a l o w pH when d i s p e r s e d i n w a t e r . When used i n c o m b i n a t i o n w i t h Rhodi - g e l Xanthan Gum, s y n e r g i s t i c t h i c k e n i n g and s t a b i l i z a t i o n i s a c h i e v e d . A p p r o x i m a t e l y 5% G l y c o l i c A c i d i s added t o p r o v i d e i t s we l l - known s k i n r e j u v e n a t i n g f u n c t i o n .

I n q r e d i e n t : A : Veegum U l t r a , Magnesium Aluminum S i l i c a t e

D e i o n i z e d Water

W t .%* 1 . 4 3

63.51 R h o d i g e l , Xanthan Gum 0 . 2 9

B: G l y c e r i n 4 . 7 6

C : T r i e t h a n o l a m i n e , 99% 0 .71

D: C e t y l A l c o h o l 2 . 8 5 G l y c e r y l S t e a r a t e (and ) PEG-100 S t e a r a t e ( A r l a c e l 165) 4 .28 S t e a r i c A c i d 1 . 4 3 I s o p r o p y l P a l m i t a t e 4 .28 M i n e r a l O i 1 (and) L a n o l i n A l c o h o l (Amerchol L-101) 4 .28 D ime th i cone (350 c s . ) 1 . 4 3

E : P r e s e r v a t i ve G l y c o l i c A c i d (67% S o l n . ) Sodi um H y d r o x i de (50% So l n . )

0 . 9 5 7 . 1 4 2 . 6 6

P rocedure :

t u r e t o room t e m p e r a t u r e w a t e r w h i l e s t i r r i n g w i t h a p r o p e l l e r m i x e r a t 1800 r p m . C o n t i n u e m i x i n g f o r 30 m i n u t e s . Add P a r t B and m i x 5 m i n u t e s . Heat P a r t s A+B t o 50-55C and add P a r t C . M i x 3 m i n u t e s . Heat t h e w a t e r phase t o 75C. M i x and h e a t t h e P a r t D i n g r e d i e n t s t o 75-8OC. Add P a r t D t o P a r t s A+B+C. S t i r a t 1800 r p m f o r 10 m i n u t e s . M a i n t a i n t e m p e r a t u r e a t 75C. B e g i n c o o l i n g w h i l e s t i r r i n g . A t 40C, add t h e P a r t E i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g each u n t i l u n i f o r m . C o n t i n u e c o o l i n g and s l o w t h e m i x e r t o 900 r p m . Check t h e pH and a d j u s t , i f necessa ry , t o 3 . 5 - 4 . 0 , Package a t 35-38C.

SOURCE: R . T . V a n d e r b i l t C o . , I n c . : Veegurn F o r m u l a t i o n No. 463

Dry b l e n d t h e Veegum U l t r a and R h o d i g e l . S l o w l y add t h e m i x -

Creams 149

W/O Basic Cream for Dry Skin, with Evening Primrose Oil

I n s r e d i e n t s : Wei s h t % A) M i g l yo1 840 ( P r o p y l e n e G l y c o l D i c a p r y l a t e / D i c a p r a t e ) 4 .00

I m w i t o r 780K ( I s o s t e a r y l D i g l y c e r y l S u c c i n a t e ) 5 . 0 0

B )

D y n a c e r i n 660 ( O l e y l E r u c a t e ) S o f t i san Gel ( B i s-Di g l y c e r y l Pol y a c y l a d i pa te -2

(and) P r o p y l e n e G1 y c o l D i c a p r y l a t e / D i c a p r a t e (and) S t e a r a l k o n i um H e c t o r i t e (and ) P r o p y l e n e Carbona te )

W h i t e Beeswax Lunacera M ( M i c r o c r y s t a l l i n e Wax) M i n e r a l O i l Eveni ng P r i m r o s e O i 1

P r e s e r v a t i v e Water

Perfume O i l

6 . 0 0

3 .00 2 . 0 0 2 . 0 0 6 . 0 0 5 . 0 0

q . s . 6 5 . 0 0

Q . S .


h e a t e d t o t h e same t e m p e r a t u r e and e m u l s i f i e d i n t o ( A ) . The per fume o i l can be added below 30 degrees C . The e m u l s i o n must be s t i r r e d u n t i l c o o l .

F o r m u l a t i o n 1 . 2 L

(A) h e a t e d up t o c a . deg rees C . u n t i l homogeneous. (B) i s

Peeling Cream

I n a r e d i e n t s : A ) S o f t i s a n 601 ( G l y c e r y l Cocoate (and ) Hydrogenated

Wei a h t %

Coconut O i 1 (and ) C e t e a r e t h - 2 5 ) 1 0 . 0 0 I m w i t o r 900 ( G l y c e r y l S t e a r a t e ) 10 .00 M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 1 5 . 0 0 M i g l yo1 840 ( P r o p y l e n e G l y c o l D i c a p r y l a t e /

D i c a p r a t e ) 3 . 0 0

M a r l i p a l 1618/25 ( C e t e a r e t h - 2 5 ) 1 . 8 0 Dynacer i n 660 (01 e y l E r u c a t e ) 2 . 0 0

Cremophor A6 ( C e t e a r e t h - 6 (and ) S t e a r y l A l c o h o l ) 1 . 2 0

B) Ampholy t JB 130/K (Cocamidopropyl B e t a i n e ) 5 . 0 0 A1 1 a n t o i n 0 . 2 0 P r e s e r v a t i v e q . s . Water up t o 100.00

C) F rag rance Almond Meal ( o r 1 . 5 % Sea Sand)

9 , s . 3 .00


same t e m p e r a t u r e and e m u l s i f i e d i n t o ( A ) . Almond Meal o r Sea Sand and f r a g r a n c e i s added a t about 35 degrees C .

SOURCE: H u l s Amer ica I n c . : Suggested F o r m u l a t i o n s

(A) i s m e l t e d a t abou t 75 degrees C . (B) i s b r o u g h t t o t h e

Formul a t i on 1 . 1 S


W/O Cream with Almond Oil and Shea Butter

I n g r e d i e n t s : Wei q h t % A) S o f t i s a n Gel ( B i s - D i g l y c e r y l P o l y a c r y l a d i p a t e - 1

(and) P r o p y l e n e G l y c o l D i c a p r y l a t e / D i c a p r a t e (and) S t e a r a l k o n i u m H e c t o r i t e (and) P r o p y l e n e Carbonate) 10.00

M i g l y o l 840 ( P r o p y l e n e G l y c o l D i c a p r y l a t e / D i c a p r a t e ) 10.00 D y n a c e r i n 660 ( O l e y l E r u c a t e ) 2 .00 I m w i t o r 780K ( I s o s t e a r y l D i g l y c e r y l S u c c i n a t e ) 5 .00 Almond O i l 2 .oo Shea B u t t e r 2 .00 Oxynex 2004 (BHT (and) G l y c e r y l S t e a r a t e (and)

C i t r i c A c i d (and) P r o p y l e n e G l y c o l ) 0 . 0 2 G1 y c e r y l 01 e a t e (and) A s c o r b y l Pal m i t a t e (and )

B) Magnesium S u l f a t e N i p a g i n M ( M e t h y l Paraben) N i p a s o l M ( P r o p y l Paraben) Phenoxyethanol Dei o n i zed Water

2.00 0 . 1 5 0 . 0 5 0 I 50

66.28

P r e p a r a t i o n : (A ) i s h e a t e d t o 75-80 degrees C . (B) i s b r o u g h t t o t h e

same t e m p e r a t u r e and e m u l s i f i e d i n t o ( A ) . Cool w h i l e s t i r r i n g t o t h e d e s i r e d t e m p e r a t u r e .

F o r m u l a t i o n No. 1.2M

Soft W/O Cream with Softisan 649

I n a r e d i e n t s : Weight% A ) I m w i t o r 780K ( I s o s t e a r y l D i g l y c e r y l Succ i n a t e ) 5 .00

S o f t i s a n 649 ( B i s - D i g l y c e r y l P o l y a c y l a d i p a t e - 2 ) 3 .00 A l u g e l DF 30 (Aluminum S t e a r a t e ) 0 . 7 5 M i n e r a l O i l 10.00 P e t r o l a t u m 10 .00

6) P r e s e r v a t i v e Water

9.5.. up t o 100 .00

Fragrance Be l 1 e f r e s h 0.30


i s b r o u g h t t o t h e same t e m p e r a t u r e and e m u l s i f i e d i n t o ( A ) . Perfume i s added a t about 35 degrees C .

(A) i s mixed homogeneously and b r o u g h t t o 80 degrees C. (B)

F o r m u l a t i o n 1 . 2 N

SOURCE: H u l s Amer ica Inc.: Suggested F o r m u l a t i o n s

Creams 151

W/O-Cream

Rec ipe : A H o s t a c e r i n WOL

Lunacera M M i n e r a l o i l , low v i s c o s i t y I s o p r o p y l p a l m i t a t e I s o p r o p y l i s o s t e a r a t e Squal ane Pant heno l

6 1,2-Propy lene g l y c o l Magnesi um s u l f a t e C i t r i c a c i d (10%) Hoechst P o t a s s i urn Sorba te Hoechst S o r b i c A c i d Water

C Fragrance

Procedure : 1 M e l t A a t c a . 80C. 2 Heat B t o ca . 80C. 3 S t i r 2 i n t o 1 and s t i r u n t i l c o o l . 4 A t ca . 35C add C t o 3 .

Formula A V I /2754

Chamomile Glycerin Cream

Reci pe : A H o s t a c e r i n CG

M i n e r a l o i 1, h i g h v i s c o s i t y C e t i o l SN I s o p r o p y l i s o s t e a r a t e

WtOIo 6 . 0 0 2 . 5 0 5 . 0 0 4 . 0 0 4 .00 5 . 0 0 0 .50

4 .00 0 .70 0 . 1 0 0 .15 0 . 0 8

6 7 . 5 7

0 . 4 0

WtOIo 1 0 . 0 0

8 .00 4 .00 4 .00

B Carbopol 980 0 .30

C Aquamo l l i n BC p d r . h . c . C i t r i c a c i d (10%) Caust i c soda s o l u t i on ( 10%) E x t r a p o n chamomi 1 e spec i a1 G1 y c e r i n Water P r e s e r v a t i ve

0 . 1 0 0 . 2 5 1 . 2 0 0 .50

10 .00 61 - 2 5

q . s .

D F rag rance 0 .40

P rocedure : 1 M e l t A a t ca . 70C t h e n add B. 2 Heat C t o c a . 70C. 3 S t i r 2 i n t o 1 4 S t i r u n t i l c o o l . 5 A t 35C add D t o 4. 6 Homogenize i f necessa ry .

SOURCE: Hoechs t : Gu ide F o r m u l a t i o n s f o r t h e Cosmetic I n d u s t r y

Formula A V I /6506

Section VI Hair Care Products

152

Hair Care Products 153

Acudyne 255 55% VOC DME Aerosol Hair Spray

F a s t - d r y i n g , e x t r e m e l y l o w - t a c k and e x c e l l e n t c u r l r e t e n t i o n f o r m u l a .

I n g r e d i e n t s : A . Water

E thano l

DC-190 F l u i d AMP-95

% b y Weight 31 . 8 4 25,OO

0 . 5 6 0 . 1 0

8 . Acudyne 255 (41%) 12.50

C . Dymel A 30.00

P rocedure : P repare phase A . Then add phase €3 w i t h s t i r r i n g . M ix u n t i l

s o l u t i o n i s s l i g h t l y t u r b i d b u t a c t i v e i n g r e d i e n t s a r e d i s p e r s e d . Add phase C . The m i x t u r e w i l l i m m e d i a t e l y t u r n c l e a r .

P h y s i c a l C h a r a c t e r i t i c s : C loud p o i n t : <-22F Vapor P r e s s u r e : 33 p s i g a t 70F

F o r m u l a t i o n PF-0371 sugges ted b y Rohm & Haas (PF-050) 87 p s i g a t 130F

Non-Aerosol Hair Spray, Low VOC

I n g r e d i e n t s : A . A l c o h o l , d e n a t u r e d

Gant r e z ES-225

8. AMP-95 Permethy l 101A Permet h y l 102A V i g i l a n AWS

% b y Weight 7 4 - 0 0

9 . 2 0

0 .40 5 . 1 5

1 0 . 0 0 1 . o o

C . F rag rance 0 . 2 5

P rocedure :

M i x u n t i l c l e a r s o l u t i o n d e v e l o p s . Add C as d e s i r e d . M ix A u n t i l c l e a r and u n i f o r m . S l o w l y add B i n o r d e r shown.

F o r m u l a t i o n PF-0372 sugges ted by P r e s p e r s e

SOURCE: Angus Chemi c a l Co. : P r o d u c t F o r m u l a r y


Acudyne 255 55% VOC Extra Hold Pump Hair Spray

I n s r e d i e n t s : A . Water

E t h a n o l

DC 190 F l u i d AMP-95

% by Weight 27 .14 5 5 . 0 0

0 .76 0 . 1 0

B . Acudyne 255 (41%) 17 .00

P rocedure :

s o l u t i o n i s c l e a r . P repare phase A . Then add phase 8 w i t h s t i r r i n g . M i x u n t i l

P h y s i c a l C h a r a c t e r i s t i c s : C loud p o i n t : -18F V i s c o s i t y (#1 @ 60 r p m ) : 1 0 . 0 cps

F o r m u l a t i o n PF-0390 sugges ted by Rohm & Haas Co. (PF-056)

Acudyne 255 0% VOC Pump Hair Spray

I n q r e d i e n t s : Water AQ-55 AMP-95 C i t r o f 1 ex-2 Acudyne 255 (41%) P r e s e r v a t i v e

% b y Weinht 88.78

3 .20 0 .42 0 . 1 0 7 .50

9 , s .

Procedure : Heat 40 p a r t s w a t e r t o 9OC. Add phase 0 w i t h s t i r r i n g . Add

48 .8 p a r t s ambient t e m p e r a t u r e w a t e r and a l l o w t o c o o l t o a p p r o x i m a t e l y room t e m p e r a t u r e . Add rema inder o f i n g r e d i e n t s i n o r d e r .

P h y s i c a l C h a r a c t e r i s t i c s : C loud p o i n t : - l O C V i s c o s i t y : 4 . 0 cps


SOURCE: Angus Chemical Co. : P r o d u c t Fo rmu la ry


Aerosol Styling Spray

Formula ted t o g i v e a v e r y q u i c k d r y i n g s p r a y w h i c h g i v e s a f i r m b u t n a t u r a l h o l d . The f a s t d r y i n g f e a t u r e a l l o w s i n s t a n t s e t t i n g o f c u r l s . The spray a l s o a f f o r d s easy comb-out and washabi 1 i t y . I n g r e d i e n t s : V e r s a t y l - 4 2 Ami nomethy l Propano l P u r c e l 1 i n O i 1 2/066210 Dow C o r n i n g 190 S u r f a c t a n t Monamid 716 Fragrance Ethano l , SDA-40 P r o p e l 1 a n t A-46

P a r t s by Weight 4 .50 1 . 0 8 0 .10 0 . 1 0 0 . 1 0 0 .10

49.02 45.00

P r e p a r a t i o n : Charge m i x i n g v e s s e l w i t h SDA-40. W h i l e m i x i n g , add amino-

methy l p r o p a n o l . S i f t V e r s a t y l - 4 2 i n t o sol u t i on w i t h c o n t i n u e d m i x i n g . When s o l u t i o n i s comple te , add r e m a i n i n g i n g r e d i e n t s . F i l t e r s o l u t i o n and f i l l a e r o s o l c o n t a i n e r s . Charge p r o p e l l a n t .

Can: C o n t i n e n t a l V a l v e : P r e c i s i o n , 0 . 0 1 8 f f stem (#04-1220) , Buna g a s k e t

(#05-0310, SS s p r i n g (#06-6010) , 0 .018" body x 0 .013" V . T . (#07-0131) , #12-7100 cup, #09-2010 d i p t u b e , #01-1836 a c t u a t o r .

F o r m u l a t i o n No. 6186-101

Aqueous Conditioning and Styling Mousse

T h i s c o n d i t i o n i n g mousse p r o v i d e s improved g l o s s and manage- a b i 1 i t y a1 l o w i ng f o r e a s i e r s t y 1 i ng.

I n g r e d i e n t s : A ) C e l q u a t L-200

P a r t s by Weight 1 . o o

Dei o n i zed Water 81 - 9 0 B ) C r o t e i n SPO 0 .20

C r o t e i n Q 0 . 2 0 Ethoquad 0/12 1 .oo DC- 190 0 . 2 0 Sodium C h l o r i d e 0 .50 P r e s e r v a t i ve q . s . F ragrance q . s .

C) P r o p e l l a n t A-46 15 .00 V a l v e S p e c i f i c a t i o n s : P r e c i s i o n Foam V a l v e

Stem: 2 x 0 .020" Body: I n v e r t e d w i t h T a i l p i e c e A c t u a t o r : Mars I n v e r t e d Spout


and f i l l c o n c e n t r a t e . Charge ( C ) .

SOURCE: N a t i o n a l S t a r c h and Chemical Co. : Suggested F o r m u l a t i o n s

Prepare s o l u t i o n o f ( A ) . Add (6). When homogenous, f i l t e r

F o r m u l a t i o n No. 4497-113


Alcohol-Free Aerosol Hairspray

Ingredi ents: % by Wei ghtLovocryl 47 5.00AMP-95 1.01Burst, RSD-10 0.50Deioni zed Water 60.49Dimethyl ether 33.00Preservative q.s.

Cloud Point: -15C

Procedure:Disperse Burst in water. Dissolve AMP-95 in the solution.

When complete, slowly sift in Lovocryl 47 while maintaininggood agitation. Mix until homogeneous. Filter and f i l l . Chargewi th propel 1 ant.

Valve: Seaquist Valve NS-34Stem: 0.013"Gasket: Butyl, 0.042" Ink. Code: 501Spring: 0.020" SSBody: Capi11aryCup: Regular, Epoxy Top, Laminate Bottom,

Dimpled, Code: 1610Vapor Tap: 0.013"Dip Tube: 0.040"Actuator: Excel-200 Misty 0.016" Misty

Formulation PF-0351 suggested by National Starch & ChemicalCorp. (7502:956)

Hair Spritz

Ijigredi ents : % by Wei ghtCrovol M40~ 0.50AMP-95 0.16Ethanol DEB100 to 100.00Gantrez ES425 8.00Escalol 507 1.OODeionized water 11.36d-Panthenol 0.10Perfume q.s.Preservati ves q.s.Color q.s.

Procedure:Dissolve AMP in the alcohol. Add Gantrez ES resin with mixing.

Mix in the Escalol and then add the Crovol. Pre-mix the waterand panthenol, and then add the alcohol. Mix until clear.

Formulation PF-0359E suggested by Croda, UK

SOURCE: Angus Chemical Co.: Product Formulary


Alcohol-Free Firm Holding Mousse

T h i s a l c o h o l - f r e e , f i r m h o l d i n g mousse g i v e s v e r y good w e t / d r y c o m b a b i l i t y , e x c e l l e n t h o l d , and a l s o c o n d i t i o n s t h e h a i r .

I n a r e d i e n t s : A . Amphomer

L o v o c r y l - 4 7

T r i t o n X-100 DC-929 S i 1 i cone P r o p y l e n e G1 y c o l Panthenol Var i on CADG- LS D o w i c i l 200 D e i o n i z e d Water

AMP-95

8 . N a t r o s o l 250 HHX Dei o n i zed Water

% b v We igh t 2 . 6 3 1 .13 0 . 6 4 0 . 2 0 0 . 6 0 0 . 1 0 0 . 2 0 0 .20 0 . 1 0

46.90

0 . 3 0 37.00

C . P r o p e l l a n t A-46 10.00

P rocedure : P repare p o r t i o n s ( A ) and ( B ) . When s o l u t i o n s a r e comp le te ,

add ( A ) t o ( B ) and m ix u n t i l homogeneous. F i l t e r and f i l l conc- e n t r a t e . Emplace V a l v e . Charge p r o p e l l a n t ( C ) .

Corp. (8384-49-4) F o r m u l a t i o n PF-0354 sugges ted b y N a t i o n a l S t a r c h & Chemical

Alcohol-Free Styling Mousse

I n g r e d i e n t s : A . L o v o c r y l 47

AMP-95 DC-929 S i 1 i cone T r i t o n X-100 V a r i on CADG-LS F rag rance D o w i c i l 200 D e i o n i z e d w a t e r

6. N a t r o s o l 250 HHR D e i o n i z e d w a t e r

% b y Weight 2 .50 0 .51 0 . 4 0 0 . 3 0 0 . 1 0

0.10 48.79

0 .30 37.00

9.5.

C. P r o D e l l a n t A-46 1 0 . 0 0

P rocedure : P repare p o r t i o n s ( A ) and ( B ) s e p a r a t e l y . When s o l u t i o n s a r e

comp le te , add ( A ) t o ( B ) and m i x u n t i l homogeneous. F i l t e r and fill c o n c e n t r a t e . CHarge w i t h p r o p e l l a n t ( C ) .

Corp. (7502:105A)

SOURCE: Angus Chemical C o r p . : Produc t F o r m u l a r y

Formul a t i on PF-0355 sugges ted b y Na t i o n a l S t a r c h and Chemi c a l


Alcohol-Free Non-Aerosol Spritz

T h i s l o w VOC f o r m u l a t i o n p r o v i d e s s p r a y a b i l i t y , f i r m h o l d , and good h u m i d i t y r e s i s t a n c e .

I n g r e d i e n t s : Emu ls ion 25-3800 (50% a c t i v e )

Monawet MO-75E D e i o n i z e d w a t e r

AMP-95

% by Weight 14 .00

1 . o o 0 . 3 0

84.70

P rocedure :

w i t h s t i r r i n g u n t i l c o m p l e t e l y d i s s o l v e d . F i l t e r and f i l l c o n c e n t r a t e .

V a l v i ng and A c t u a t o r :

Combine w a t e r , MO-75E and AMP. Nex t , add po lymer emu ls ion

Pump Type: E u r o M i s t , 190 mcl L i n e r : PE/Buty l C1 o s u r e : 24-410, W h i t e S p r i n g : 302 SS, 1 l b 0 o z . Body : 190 m c l o u t p u t D i p Tube: 7 ” , 0 .060” I D I n s e r t : ,010” x , 0 1 0 ” deep Seal V a l v e : S tandard Hood : SBS, C l e a r T u r r e t : 24 mm

F o r m u l a t i o n PF-0402 sugges ted by N a t i o n a l S t a r c h & Chemical CO. (8757-120-2)

Super Hold Pump Spray

I n a r e d i e n t s : % b y Weight A . SD A l c o h o l 40, 190 p r o o f 84 .21

D e i o n i z e d w a t e r 8 . 1 2 AMP-95 1 . 4 7 Dow C o r n i n g 02-5220 P o l y e t h e r 0 . 1 0 F r a g r a n c e (Peach F l o r a l 92F/3235) 0 .10

B. Luv imer 100 P 6 . 0 0

P rocedure :

each a d d i t i o n . Combine phase A i n g r e d i e n t s i n o r d e r l i s t e d , m i x i n g a f t e r

S p r i n k l e B i n t o A w i t h m i x i n g u n t i l c l e a r .

F o r m u l a t i o n PF-0398 sugges ted b y BASF (DKL84/3)

SOURCE: Angus Chemical Go.: P r o d u c t F o r m u l a r y


Alcohol-Free Ringing Gel with Hold

Ingredients: Part A: Dei oni zed Water Propylene Glycol AMP-Regul ar Amphome r Part B: Lt. Mineral Oil Volpo 5 Crodafos N10 Neutral Crodafos N3 Neutral Part C: Germaben I 1

Parts by Weiaht

57.59 12.00 0.41 3.00

10.00 9 .oo 4.00 3.00

1 . o o

Preparat i on : Part A: Combine the water, AMP, and propylene glycol. While

maintaining good agitation, slowly sift in Amphomer. Slowly heat Part A to 70C.

Part 6: Combine ingredients o f Part B and heat to 80C. Add Part B to Part A with mixing and start to cool. Add Part C when the temperature drops to approximately 55C. Continue mi xi ng for fi ve mi nutes o r unti 1 homogeneous. Cool to room temperature.

Formul a No. 8802 : 766

Cream Hair Conditioner

This cream hair conditioner has excellent wet combability, adds body to the hair, and has good hold.

Inaredi ents: A) Cel quat L-200

Triethanolamine Propylene G1 ycol D i sti 1 1 ed Water Preservative

B) Acetulan Amerchol L-101 Stearic Acid XXX Emerest 2407 Mineral Oil Fragrance

Parts by Weight 1 . o o 0.50 2.25

76.25 9,s.

0.50 2.50 1.25 1 . oo

14.75 9,s.

Preparat i on : Heat A and 6 separately to BOC. While mixing, add 6 to A.

Continue mixing while cooling to 25-3OC. Add C. Adjust pH to 7 . 5 if necessary. M i x until uniform.

SOURCE: National Starch and Chemical Co.: Suggested Formulations

Formula No. 3474-28



T h i s a l c o h o l - f r e e s t y l i n g mousse has good w e t / d r y c o m b a b i l i t y , good s u b j e c t i v e p r o p e r t i e s and e x c e l l e n t h o l d .

- I n g r e d i e n t s : A . L o v o c r y l 47

AMP-95 DC-929 S i 1 i cone T r i t o n X - 1 0 0 d l -Pan theno l Neo H e l i o p a n Hydro C r o t e i n 0 D o w i c i l 200 Dei o n i zed w a t e r

B . N a t r o s o l 250 HHR Dei o n i zed w a t e r

C . P r o p e l l a n t A - 4 6

% b y Weigh t 3 . 0 0 0 . 6 3 0 . 3 0 0 . 3 0 0 . 1 0 0 . 1 0 0 . 2 0 0 . 1 0

40 .01 0 . 4 0

44 .86 1 0 . 0 0

P rocedure : P repare p a r t A b y d i s s o l v i n g AMP-95 i n w a t e r . W h i l e main-

t a i n i n g good a g i t a t i o n , s l o w l y s i f t i n t h e L o v o c r y l - 4 7 . When s o l u t i o n i s comp le te , add t h e r e m a i n i n g i n g r e d i e n t s . P repare p a r t B . When s o l u t i o n s a r e comp le te , add A t o B and m ix u n t i l homogeneous. F i l t e r and f i l l c o n c e n t r a t e . Charge cans w i t h p r o p e l 1 a n t C I

Corp . ( 7 8 7 9 : H l O l ) Formul a t i on PF-0356 suggested by Nat i o n a l S t a r c h & Cherni c a l


I n g r e d i e n t s : A_ Amphomer

AMP-95 DC-929 S i 1 i cone T r i t o n X - 1 0 0 V a r i o n CADG F rag rance D o w i c i l 200 D e i o n i z e d w a t e r DC- 190

B . N a t r o s o l 250 H H R D e i o n i z e d w a t e r

C . Prope l l a n t A-46

% b y Weigh t 3 .00 0 . 5 2 0 . 4 0 0 . 3 0 0 . 1 0

0 . 1 0 48 .08

0 . 4 0 0 . 3 0

36 .80 1 0 . 0 0

q . s .

Procedure :

A t o B and mix u n t i l homogeneous. F i l t e r and f i l l c o n c e n t r a t e . Charge p r o p e l l a n t C .

Formul a t i on PF-0357 suggested b y N a t i o n a l S t a r c h & Chemi c a l Corp . (7974:32-3)

SOURCE: Angus Chemical Corp , : P roduc t Fo rmu la ry

P repare p o r t i o n s A and B . When s o l u t i o n s a r e comple te , add


Brush-On Hair Color

T h i s f o r m u l a t i o n p r o v i d e s d r a m a t i c s t r e a k s and h i g h l i g h t s y e t r i nses o u t e a s i 1 y .

A : Veegum, Magnesium Aluminum S i l i c a t e (5% A q . S o l n . ) B: H y d r o x y p r o p y l c e l l u l o s e (5% A q . S o l n . ) ( K l u c e l G ) C : D e i o n i z e d Water

PVP ( L u v i s k o l K30) Me thy lpa raben

D : C e t y l A l c o h o l C e t e a r e t h - 2 5 (Cremophor A25) P r o p y l p a r a b e n

E : D e i o n i z e d Water P r o p y l e n e G1 y c o l

F : M i c a (and ) I r o n Ox ides ( C o l o r o n a Copper) G: DMDM H y d a n t o i n ( G l y d a n t )

__ W t % 10.00 15.00 24.00

2 . 0 0 0 . 2 0 3 . 6 0 2 . 4 0 0 . 1 0

17 .34 5 .00

20 I O 0 0 .36

P rocedure :

s t i r r i n g . Combine D. Heat t o 75C s t i r r i n g u n t i l c l e a r . Add D t o C w i t h c o u n t e r r o t a t i o n a g i t a t i o n . Cool t o 40C. S e p a r a t e l y , add B t o A f o l l o w e d b y E , s t i r r i n g u n t i l homogeneous. Add combined A,B,E t o C+D. Homogenize a t h i g h speed f o r 5 m i n u t e s w i t h a S i l v e r s o n - t y p e homogenizer . Add F and G, s t i r r i n g w i t h c o u n t e r r o t a t i o n a g i t a t i o n . Cool t o 30C. Package i n mascara v i a1 s w i t h b r u s h app l i c a t o r .

P repare A and B i n advance. Combine C and h e a t t o 75C w i t h

Formula f r o m Rona

Creme-in Hair Cleanser

Ammoni u m L a u r y l S u l f a t e (Carson01 ALS) Cocoamidopropyl B e t a i ne Laurami de DEA (Carsami de SAL-7) PPG-5-Ceteth 10 Phosphate ( C r o d a f o s SG) S t e a r y l A l c o h o l (and ) C e t e a r e t h 20 (Cosmowax K ) Sucrose Cocoate ( C r o d e s t a SL-40) S t e a r t r i m o n i u m H y d r o x y e t h y l H y d r o l y z e d C o l l a g e n

Veegum K , Magnesi u m A 1 umi num S i 1 i c a t e Water Dye, f r a g r a n c e

( C r o t e i n Q )

__ W t % 15 .00 10.00 2 .oo 2 . 0 0 2 . 5 0

12 .00

3 .00 0 . 4 5

53.05 q . s .

P rocedure :

a u n i f o r m s l u r r y i s a c h i e v e d . D i s s o l v e t h e C r o d e s t a i n t h e r e s t o f t h e w a t e r , t h e n d i s s o l v e t h e C r o t e i n Q . Heat o t h e r i n g r e d i e n t s t o 60C w i t h s t i r r i n g . Cool t o 40C, add f r a g r a n c e and f i l l o f f .

D i s p e r s e t h e Veegum K i n h a l f t h e w a t e r and h e a t t o 85C u n t i l

Formula f r o m Croda

SOURCE: R . T . V a n d e r b i l t Co. , Inc.: Veegum F o r m u l a t i o n s

I62 Cosmetic and Toiletry Formulations

California Dream Hairspray - 55% VOC - 5% Solids

I n n r e d i e n t s : Phase A : Dei o n i zed Water SD A l c o h o l 40, 190 p r o o f D-Panthenol Cremophor A 25 Dow C o r n i n g 193 P o l y e t h e r

Luv imer Low VOC AMP-95

Phase B: F rag rance ( V i b r a n t Spash 94F/2203)

Phase C: Dymel A

P rocedure : Combine Phase A i n g r e d i e n t s i n t h e w r i t t e n o r d e r . Add B t o A and m i x w e l l . F i 11 i n t o a p p r o p r i a t e c o n t a i n e r s w i t h p r o p e l l a n t .

% b v Weiaht

27.83 15.80

0 . 2 0 0 . 2 5 0 .50 1 . 2 2

14.00

Packag ing : W h i t e Coated Aluminum Can ( P e e r l e s s Tube C o r p . ) Aquasol V a l v e & Concave Kosmos A c t u a t o r ( P r e c i s Overcap ( B e r r y P l a s t i c s )

F o r m u l a t i o n PF-0349 sugges ted b y BASF Corp. (SG

Non-Alcohol Hairspray

I n g r e d i e n t s : Amp homer

Dei o n i zed Water Sodi um Benzoate Ammoni urn h y d r o x i de F rag rance G1 y c e r i ne DC-190 S i l i c o n e D i m e t h y l E t h e r

AMP-95

0 . 2 0

40 .00

on V a l v e Corp )

096/4)

% by Weiaht 5 .00 0 . 8 9

61 - 6 6 0 . 1 0 0 . 0 5

0 . 1 0 0 . 2 0

32 .00

q . S .

Procedure : D i s s o l v e AMP-95, Sodium Benzoate and Ammonium H y d r o x i d e i n

t h e w a t e r . S l o w l y add Amphomer t o t h e s o l u t i o n w h i l e m a i n t a i n i n g good a g i t a t i o n . When s o l u t i o n i s comp le te , add r e m a i n i n g i n g r e d - i e n t s u n t i l homogeneous. F i l t e r and f i l l c o n c e n t r a t e . Add p r o p e l 1 a n t .

F o r m u l a t i o n PF-0350 sugges ted by N a t i o n a l S t a r c h & Chemical Corp. (6472 :93 )

SOURCE: Angus Chemical Co. : P r o d u c t Fo rmu la ry


Clear Hair Rinse Formulation

N a t r o s o l v i s c o s i f i e s t h i s c r y s t a l - c l e a r h a i r r i n s e , wh ich f o r m u l a s made w i t h o u t N a t r o s o l promotes m a n a g e a b i l i t y . C o n t r o

have v i s c o s i t i e s o f l e s s t h a n

I n g r e d i e n t s : N a t r o s o l 250HHR CS Water Cocami d o p r o p y l ami ne o x i d e (30% Laurami ne o x i d e (30%) Cet r i mon i urn c h 1 o r i de ( 25%) Perfume, p r e s e r v a t i v e

P rocedure :

00 c p s .

Wei qht% 1 . 0

73 .5 5 . 1

1 0 . 2 1 0 . 2

q . s . t o 100 .0

1 . D i s p e r s e N a t r o s o l i n wa te r w i t h good a g i t a t i o n . M i x u n t i l f u l l y d i s s o l v e d .

2 . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g we1 1 between a d d i t i o n s . ( B r o o k f i e l d v i s c o s i t y a t 30 rpm, 25C=3,360 cps [mPas])

Pearlescent Cream Rinse Formulation

N a t r o s o l v i s c o s i f i e s t h i s p r o d u c t and p r e v e n t s phase s e p a r a t i o n

I n g r e d i e n t s : Phase A : N a t r o s o l 250HHR CS Water

Phase B : S t e a r a l k o n i u m c h l o r i d e (25%) P r o p y l e n e g l y c o l G l y c o l s t e a r a t e 01 e th -20 Pol y q u a t e r n i um-1 7 (62%)

Wei q h t %

1 . 3 8 2 . 3

1 0 . 1 1 . 5 1 . 5 1 . 5 1 . 8

Perfume, p r e s e r v a t i v e q . s . t o 100.0

P rocedure : 1 . D i s p e r s e N a t r o s o l i n wa te r w i t h good a g i t a t i o n . M i x u n t i l

2 . I n a s e p a r a t e v e s s e l , m ix t h e s t e a r a l k o n i u m c h l o r i d e and

3 . Add t h e o t h e r i n g r e d i e n t s l i s t e d i n Phase B, i n t h e o r d e r

f u l l y d i s s o l v e d .

p r o p y l e n e g l y c o l . Heat t o 80C.

l i s t e d , t o t h e m i x t u r e o f s t e a r a l k o n i u m c h l o r i d e and p r o p y l - ene g l y c o l . M i x w e l l between each a d d i t i o n .

we1 1 . Cool t o 35C.

( B r o o k f i e l d v i s c o s i t y a t 30 rpm, 25C = 8,600 cps [mPas

4 . Add t h e s u r f a c t a n t m i x t u r e t o t h e N a t r o s o l s o l u t i o n . M

5 . Add pe r fume and p r e s e r v a t i v e .

X

SOURCE: Aqualon D i v i s i o n : H a i r C o n d i t i o n i n g P r o d u c t s w i t h Nat r o s o l H y d r o x y e t h y l c e l l u l ose


Concentrated Hair Repairwith UV Protection

I n g r e d i e n t s : Phase A : D i meth i cone (50-60,000 c s ) Isohexadecane C y c l omet h i cone Cyc lometh icone and D i m e t h i c o n o l and D imeth icone

( A b i l OSW 12) Dimeth icone/Sodium PG-Propyl D i m e t h i c o n e T h i o s u l f a t e

Copolymer ( A b i l S 201) Phenyl T r i m e t h i c o n e ( A b i l AV 20) O c t y l Methoxyc i nnamate P r o p y l p a r a b e n

Phase 0: Quaternium-80 ( A b i l Quat 3474) E t h a n o l Denatured M e t h y l G luce th-20

Procedure :

Weight%

1 5 . 0 0 29.65 15 .00

25.00

1 . o o 5.00 1 . o o 0 .10

0 . 7 5 4 .00 3 .50

1 . Combine i n g r e d i e n t s o f Phase A t o g e t h e r i n o r d e r shown. M i x

2 . Combine i n g r e d i e n t s o f Phase 6 t o g e t h e r . M i x w e l l . 3 . Add B t o A . M i x w e l l . A v o i d a i r e n t r a p m e n t .

u n t i l f u l l y d i s p e r s e d .

Iridescent Hair Gel Concentrate

I n g r e d i e n t s : Weight%

Cyc lometh icone ( a n d ) D i m e t h i c o n o l ( a n d ) D imeth icone ( A b i 1 OSW-12)

Phenyl T r i m e t h i c o n e ( A b i l AV-20) P r o p y l e n e G1 y c o l Hexy l ene G1 y c o l Water P r e s e r v a t i ves P o l y a c r y l a m i d e ( a n d ) C13-14 I s o p a r a f f i n (and) L a u r e t h

27.27 4.55

40 .93 4.55

20.45

7 2 .25 Q . S .

Procedure :

When a l l i n g r e d i e n t s a r e combined, c o n t i n u e m i x i n g u n t i l c l e a r and i r i d e s c e n t .

SOURCE: Go1 dschmi d t Chemi c a l Co. : Suggested Formul a t i ons

Add t h e i n g r e d i e n t s i n o r d e r , m i x i n g w e l l between a d d i t i o n s .


Conditioner for Dry Brittle Hair

I n g r e d i e n t : Dei o n i zed Water Guar Hyd. P r o p y l Tr imonium C h l o r i d e Quatern ium-76 H y d r o l y z e d Animal P r o t . G1 y c o l S t e a r a t e C e t y l A l c o h o l M y r j 52s (PEG-40 S t e a r a t e ) O i l s o f A loha Kukui Nut O i l P r e s e r v a t i v e

Phase : A A A B B B B C

WtO/o 88.20

0 . 8 0 6 . 0 0 2 . 0 0 0 .50 1.50 1 . o o

QS

M a n u f a c t u r i n g Procedure : Phase A : D i s p e r s e Guar i n w a t e r w h i l e h e a t i n g t o 65C. Phase 6: Combine f a t t y components and add t o w a t e r phase. Cool t o

Phase C : Add r e m a i n i n g i n g r e d i e n t s . 40C.

pH: 5 . 0

The p r i m a r y c o n d i t i o n e r s a r e Guar hydroxy p r o p y l t r i m o n i u m c h l o r i d e and t h e Quatern ium-76 H y d r o l y z e d Animal P r o t e i n . E m u l s i f i e r i s t h e M y r j 52s. Kukui Nut O i l (Macadamia Nut c o u l d be used) p r o v i d e s a g l o s s i n g agent f o r d r y h a i r and r e p l a c e s t h e n a t u r a l o i l s l o s t i n shampooing.


Hair Styling Gel

- A : D e i o n i z e d Water Carbomer 940 - B: Dei o n i zed Water T r i e thano lami ne (99%) L : - V i n y l c a p r o l actam/PVP/Di methy l ami n o e t h y l m e t h a c r y l a t e

- D : S i l i c o n e Quatern ium-5 ( P e c o s i l SMQ-40) - E : Methylchloroisothiazolinone (and) M e t h y l i s o t h i a z o l i n o n e

Procedure :

Copolymer

Wt% 8 5 . 9 5

1 . o o

3.00 1 .oo

7 .50

1 . 5 0

0 . 0 5

D i s p e r s e Carbomer i n Phase A w a t e r . When a u n i f o r m d i s p e r s i o n i s o b t a i n e d , add Phase B t o Phase A . S l o w l y sweep i n Phase C, Phase D and Phase E u n t i l a u n i f o r m g e l i s o b t a i n e d .

SOURCE : Phoeni x Chemi c a l , I n c . : Suggested Formul a t i on


Conditioning Perm

Formula: O i l Phase: C rodaco l C-95 Croda fos N l O N Vo lpo s-2 C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) W h i t e P r o t o p e t 1s P e t r o l a t u m ( W i t c o ) S t e a r i c Ac id XXX Water Phase: Vo lpo s-10 Croquat M P r o p y l ene G1 y c o l U . S . P . Hampol OL C r y s t a l s (Lowenste i n ) Germaben I 1 Water, D e i o n i z e d Ammoni um T h i o g l y c o l a t e (60%) Ammoni um H y d r o x i de (29%)

% by Weight

2 .00 1 .50 0 .50

13.00 1 1 - 5 0 8 . 0 0

2 . 5 0 1 .oo 2 . 0 0 0 . 7 5 1 . o o

42.62 9 . 0 0 4 . 6 3

P rocedure :

t o o i l s under good a g i t a t i o n . A d j u s t ammonium t h i o g l y c o l a t e w i t h ammonium h y d r o x i d e , c o o l e m u l s i o n t o 45C t h e n add t o ammonium t h i o g l y c o l a t e s o l u t i o n . F i l l o f f .

Heat o i l phase t o 80C; h e a t w a t e r phase t o 80-85C. Add w a t e r

Scalp and Hair Conditioner

Formula: Emerest 1723 Emerest 2316 W h i t e P r o t o p e t 1s P e t r o l a t u m ( W i t c o ) Emsorb 2500 Emerwax 1266 Emerest 2486 F rag rance

% by Wei g h t 20 .5 1 4 . 5 4 7 . 0

6 . 5 1 0 . 5

1 . o q . s .

P rocedure :

Cool t o 65C w i t h moderate a g i t a t i o n . Perfume and package.


Combine a l l i n g r e d i e n t s and hea t t o 85-9OC w i t h a g i t a t i o n .


Conditioning Styling Mousse

T h i s mousse has e x c e l l e n t c o n d i t i o n i n g p r o p e r t i e s and s u p e r i o r wet combing w i t h a n a t u r a l f e e l .

I n g r ed i e n t s : Cel q u a t L-200 PEG-36 C a s t o r O i l Col 1 ami no Compl ex 40 Arquad T-50 P r e s e r v a t i ve F rag rance Anhydrous E t h a n o l , SDA D i s t i l l e d Water P r o p e l 1 a n t A-46

.40

P a r t s b y Wei Q h t 1 . o o 0 . 1 0 0 . 1 0 0 . 1 0

q . s q . s

15 .00 73 .70 10 .00

P rocedure : S l o w l y s i f t C e l q u a t L-200 i n t o d i s t i l l e d w a t e r w h i l e m i x i n g .

When s o l u t i o n i s comp le te , add r e m a i n i n g i n g r e d i e n t s i n concen- t r a t e . M i x u n t i l homogeneous. F i l t e r and f i l l .

I n s t r u c t i o n s f o r Use:

p r e s s b u t t o n t o d i s p e n s e e g g - s i z e d amount o f foam i n t o pa lm o f hand. A d j u s t amount depending on h a i r l e n g t h and amount o f c o n t r o l d e s i r e d . Massage e v e n l y t h r o u g h h a i r . Do n o t r i n s e . S t y l e h a i r as d e s i r e d .

Shampoo, r i n s e , and t o w e l d r y h a i r . Shake can w e l l , i n v e r t and

F o r m u l a t i o n No. 5231 -32

Thermal Mousse

T h i s a l c o h o l - f r e e c o n d i t i o n i n g mousse has s u p e r i o r wet combing, adds body t o h a i r , and has good f i x a t i v e p r o p e r t i e s .

I n g r e d i e n t s : A ) Cel q u a t L-200

DC 929 S i l i c o n e T r i t o n X-100 d l Panthenol C r o t e i n Q Germaben I 1 Dei o n i zed Water

E) P r o p e l l a n t A-46

P a r t s b y Weight 3 . 0 0 0 . 3 0 0 . 3 0 0 . 1 0 0 . 2 0 1 . 0 0

85 .10 10.00

P r e p a r a t i o n : D i s s o l v e t h e C e l q u a t L-200 i n d e i o n i z e d w a t e r . When s o l u t i o n

i s comp le te , add t h e r e m a i n i n g i n g r e d i e n t s and m i x u n t i l homogeneous. F i l t e r and f i l l c o n c e n t r a t e . Charge cans w i t h p r o p e l l a n t

Formul a t i on No. 7879 : H102B



Cream ConditionerI n q r e d i e n t s : Wei q h t % Phase A : Water 8 5 . 4 5 Sodium C h l o r i d e 0 . 3 0 Stearami d o p r o p y l D i me thy l ami ne (Tego Amid S 18) 1 . 5 0 C i t r i c A c i d Monohydrate 0 . 6 0 M e t h y l Paraben 0 .20 M i n e r a l O i l 1 . 2 5 Cyc lometh i cone 3 .50 G l y c e r y l S t e a r a t e S.E. ( T e g i n ) 3 .00 C e t e t h - 2 1 . 5 0 C e t y l A l c o h o l 0 . 5 0 C e t y l D i m e t h i c o n e ( A b i l Wax 9801) 0 . 3 5 Phase B : P r o p y l e n e G1 y c o l 1 . o o Q u a t e r n i um-80 ( A b i 1 Quat 3270) 0 . 2 5 D i m e t h i c o n e C o p o l y o l ( A b i l B 8852) 0 . 5 0 Phase C: P r o p y l Paraben 0 . 1 0 Perfume Q . S . C o l o r Q.S. P rocedure : 1 . Heat t h e w a t e r t o 70-80C. 2 . Add i n g r e d i e n t s o f Phase A i n descend ing o r d e r . M i x . 3 . Beg in ambient c o o l i n g o f b a t c h . Add p re -m ixed m a t e r i a l s

4 . Add m a t e r i a l o f Phase C a t 40C w i t h sweep m i x e r . Dispense o f Phase B t o r e a c t o r . Homogenize.

a t 35C.

Conditioning Rinse(Cold Process)

I n n r e d i e n t s : Weight% Phase A : G l y c o l D i s t e a r a t e (and ) S t e a r e t h - 4 (Tego P e a r l N 100) 3 . 0 Q u a t e r n i urn-80 ( A b i 1 Quat 3272) 0 . 4 Cocami d o p r o p y l B e t a i n e (Tego B e t a i ne F ) 2 . 5 F rag rance Q.S. Water 40 .9 G1 y c e r i n 1 . 5 Phase B :

H y d r o x y e t h y l C e l l u l ose 1 . 5 Guar H y d r o x y p r o p y l t r i m o n i u m C h l o r i d e 0 . 2 P r e s e r v a t i ves Q.S. Phase C : C i t r i c A c i d t o pH 4 . 0 P rocedure : 1 . M i x t h e i n g r e d i e n t s o f Phase A, 2 . Add t h e w a t e r o f Phase B

t o a t a n k . Add p r e s e r v a t i v e s . M ix u n t i l c l e a r . D i s p e r s e H y d r o x y e t h y l C e l l u l o s e and Guar H y d r o x y p r o p y l t r i r n o n i u m C h l o r i d e . M i x u n t i l f u l l y d i s p e r s e d and v i s c o s i t y i n c r e a s e s .

Water 5 0 . 0

3 . Add Phase B t o Phase A . M i x . 4 . A d j u s t p H t o 4 . 0 w i t h C i t r i c A c i d . SOURCE: Go1 dschmi d t Chemi c a l Corp , : Suggested Formul a t i ons


Cream Curl Activator

Formul a : A: D e i o n i z e d Water Hydroxyp ropy l M e t h y l c e l l u l o s e T r i e t h a n o l a m i n e Pantheno l Hydro l yzed S i 1 k P r o t e i n Qua te rn i um-1 5 B: Macol CPS S o l u l a n 16 B lando l M i n e r a l O i 1 (Wi t c o ) Masi l 656 F l u i d M a s i l SF-V F l u i d M a s i l 280 C : C i t r i c A c i d 50% F rag rance

_- % b y Weight.

8 0 . 4 3 0 . 2 0 0 . 0 2 1 . o o 1 . o o 0 . 3 0

6 . 0 0 1 . o o 2 . 0 0 3 . 0 0 3 . 0 0 2 . 0 0

0 . 0 5 q . s .

P rocedure : D i spe rse h y d r o x y p r o p y l me thy l c e l l u l ose i n t h e w a t e r , add TEA

t o i n i t i a t e h y d r a t i o n . A f t e r 20 m i n s . add r e m a i n i n g A i n g r e d i - e n t s , h e a t to 55C and s t i r . S e p a r a t e l y b l e n d B and h e a t t o 55C. Add B t o A , m a i n t a i n a g i t a t i o n w h i l e c o o l i n g t o 40C. A d j u s t pH and add f r a g r a n c e .

Hair Pomade

__.___ Formula : Wh i te P r o t o p e t 1s ( W i t c o ) 61 ando l M i n e r a l O i 1 (Wi t c o ) Oh1 an H y d r o x y l a t e d Lano l i n Kessco PEG 400 D i l a u r a t e P a r a f f i n Wax I s o p r o p y l M y r i s t a t e Perfume and C o l o r

.-bYA!!!ei&T 2 8 . 0 3 0 . 0 2 7 . 0

8 . 0 6 . 0 1 . o q * s

P rocedure :

u n i f o r m and c l e a r , Cool w i t h s t i r r i n g t o 40C.


Combine a l l i n g r e d i e n t s , h e a t t o 80C w i t h s t i r r i n g u n t i l


Cream Rinse Conditioner

T h i s cream r i n s e f o r m u l a f e a t u r e s Crodafos CES, t o g e t h e r w i t h a c a t i o n i c c o n d i t i o n e r , I n c r o q u a t BES-35s . By i t s a b i l i t y t o promote f a s t r e l e a s e o f o i l s and c o n d i t i o n i n g a g e n t s t o t h e h a i r and i t s c o m p a t i b i l i t y w i t h q u a t e r n a r y c o n d i t i o n e r s , Crodafos CES enab les t h i s cream r i n s e t o p r o v i d e enhanced c o n d i t i o n i n g e f f e c t s . The i n c r e a s e d sheen, s i l k i e r , s o f t e r f e e l , and improved t e x t u r e t h e h a i r a c q u i r e s i s t h e r e s u l t o f t h e q u i c k d e l i v e r y o f t h e Crodamol e s t e r s , Super R e f i n e d Wheat Germ O i l and I n c r o - q u a t 8ES-35S by Crodafos CES. Because Crodafos CES a l s o improves i t s a p p l i c a t i o n p r o p e r t i e s , t h e p r o d u c t r i n s e s o u t e x t r e m e l y e a s i l y w i t h o u t i n c i d e n c e o f d r a g o r a waxy d e p o s i t .

I n g r e d i e n t s : 5 P a r t A : Crodafos CES ( C e t e a r y l A l c o h o l (and) C e t e a r y l Phosphate) 6.0 I n c r o q u a t BES-35s (Behenamidopropylethyldimonium E t h o -

s u l f a t e (and) S t e a r y l A l c o h o l ) Crodaco l CS-50 ( C e t e a r y l A l c o h o l ) Super R e f i n e d Wheat Germ O i l Crodamol OS ( O c t y l S t e a r a t e ) Crodamol OPG ( O c t y l P e l a r g o n a t e )

P a r t B : Dei o n i zed Water TEA 99% P r o p y l e n e G l y c o l (and) D i a z o l i d i n y l Urea (and) M e t h y l

Paraben (and) P r o p y l Paraben

pH=5.5+-0.5 Viscosity=16,000cps+-lO%, ( S p i n d l e TD @ 10RPM @ 25C)

1 . 5 1 . 5 2 . 0 2 . 0 2 .0

83.65 0 .35

1 . o

Procedure:

Combine i n g r e d i e n t s P a r t B w i t h m i x i n g and h e a t t o 75-8OC. Add P a r t 0 t o P a r t A w i t h m i x i n g and c o o l t o d e s i r e d f i l l t e m p e r a t u r e .

Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 75-80C.


SOURCE: Croda I n c . : F o r m u l a t i o n HP-180

Hair Cure Products 171


T h i s cream r i n s e f o r m u l a f e a t u r e s Crodafos CES, t o g e t h e r w i t h a c a t i o n i c c o n d i t i o n e r , I n c r o q u a t CTC-30. By i t s a b i l i t y t o promote f a s t r e l e a s e o f o i l s and c o n d i t i o n i n g a g e n t s t o t h e h a i r and i t s c o m p a t i b i l i t y w i t h q u a t e r n a r y c o n d i t i o n e r s , Crodafos CES enab les t h i s cream r i n s e t o p r o v i d e enhanced c o n d i t i o n i n g e f f e c t s . The i n c r e a s e d sheen, s i l k i e r , s o f t e r f e e l , and improved t e x t u r e t h e h a i r a c q u i r e s i s t h e r e s u l t o f t h e q u i c k d e l i v e r y o f t h e Crodamol e s t e r s , Super R e f i n e d Wheat Germ O i l and I n c r o q u a t CTC-30 by Crodafos CES. Because Crodafos CES a l s o improves i t s a p p l i c a t i o n p r o p e r t i e s , t h e p r o d u c t r i n s e s o u t e x t r e m e l y e a s i l y w i t h o u t i n c i d e n c e o f d r a g o r a waxy d e p o s i t .

I n g r e d i e n t s : P a r t A : Crodafos CES ( C e t e a r y l A l c o h o l (and) C e t e a r y l Phosphate) Crodacol CS-50 ( C e t e a r y l A l c o h o l ) Super R e f i n e d Wheat Germ O i 1 Crodamol OS ( O c t y l S t e a r a t e ) Crodamol OPG ( O c t y l P e l a r g o n a t e )

P a r t 9: Dei o n i zed Water I n c r o q u a t CTC-30 (Cet r imon ium C h l o r i d e ) TEA 99%

P a r t C : Propy lene G1 y c o l (and) D i azo1 i d i n y l Urea (and ) M e t h y l


pH=5.5+-0.5 Viscosity=18,500cps+-lO% ( S p i n d l e TD @ 10 RPM @ 25C)

Procedure :

Wt%

6.0 1.5 2 . 0 2.0 2 . 0

83.65 1 . 5 0.35

1 . o

Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 75-8OC. Combine i n g r e d i e n t s o f P a r t 0 w i t h m i x i n g and h e a t t o 75-8OC. Add P a r t 0 t o P a r t A w i t h m i x i n g and c o o l t o 50C. Add P a r t C whi 1 e m i x i ng and c o o l t o des i r e d f i 1 1 t e m p e r a t u r e .





T h i s cream r i n s e f o r m u l a f e a t u r e s Croda fos CES, a cond t i o n i n g and e m u l s i f y i n g system f r o m Croda, t o g e t h e r w i t h a c a t i o n c c o n d i t i o n e r , I n c r o q u a t CTC-30. By i t s a b i l i t y t o promote a s t r e l e a s e o f o i l s and c o n d i t i o n i n g a g e n t s t o t h e h a i r and i t s c o m p a t i b i l i t y w i t h q u a t e r n a r y c o n d i t i o n e r s , C roda fos CES e n a b l e s t h i s cream r i n s e t o p r o v i d e enhanced c o n d i t i o n i n g e f f e c t s . I n c r e a s e d sheen, s i l k i e r , s o f t e r f e e l , and improved t e x t u r e . The p r o d u c t r i n s e s o u t e x t r e m e l y e a s i l y w i t h o u t i n c i d e n c e o f d r a g o r a waxy d e p o s i t .

I n g r e d i e n t s : Wei n h t % P a r t A : Croda fos CES ( C e t e a r y l A l c o h o l (and) C e t e a r y l Phosphate) 6 . 0 Crodaco l CS-50 ( C e t e a r y l A l c o h o l ) 1.5 Super R e f i n e d Wheat Germ O i 1 (Wheat Germ O i 1 ) 2 . 0 Crodamol OS ( O c t y l S t e a r a t e ) 2 . 0 Crodamol OPG ( O c t y l P e l a r g o n a t e ) 2 . 0

P a r t 0 : Dei o n i zed Water I n c r o q u a t CTC-30 (Ce t r imon ium C h l o r i d e ) TEA 99%

83.65 1.50 0.35

P a r t C : P r o p y l e n e G l y c o l (and) D i azo1 i d i n y l Urea (and) M e t h y l

Paraben (and) P r o p y l Paraben 1 . oo pH=5.5+-0.5 Viscosity=18,500cps+-lO% ( S p i n d l e TD @ 1 0 RPM (3 25C)

P rocedure :

Combine i n g r e d i e n t s o f P a r t 6 w i t h m i x i n g and h e a t t o 75-80C. Add P a r t 0 t o P a r t A w i t h m i x i n g and c o o l t o 50C. Add P a r t C w h i l e m i x i n g and c o o l t o d e s i r e d f i l l t e m p e r a t u r e .

Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 75-80C

N .A .T .C . Approved



Creme Rinse Conditioner for Color-Treated and Permed Hair(Formula 89-1202)

T h i s s p e c i a l l y f o r m u l a t e d c o n d i t i o n e r g e n t l y c o n d i t i o n s t h e h a i r o n l y where i t i s needed and h e l p s p r o t e c t and r e s t o r e damaged, o r c h e m i c a l l y t r e a t e d h a i r .

% by Weight Water 9 1 . 5 M i r a c a r e CT-100 3 . 5 C e t y l A l c o h o l , N.F. 1 . 5 DL-Panthenol (Roche) 0 . 5 Hydro1 yzed Ani mal P r o t e i n (Hormel P e p t e i n 2000) 3 . 0 C i t r i c A c i d Q . S . t o pH 4 - 4 . 5

B1 end i ng P rocedure : 1 . Heat w a t e r t o 75C. 2 . W i t h smooth a g i t a t i o n , s l o w l y b l e n d i n g r e d i e n t s i n t h e o r d e r

3 . A d j u s t pH o f system t o 4 . 0 - 4 . 5 w i t h c i t r i c a c i d , as needed. 4 . Cool t o 40-45C and add c o m p a t i b l e f r a g r a n c e , d y e ( s ) and

l i s t e d .

p r e s e r v a t i v e .

T y p i c a l F o r m u l a t i o n P r o p e r t i e s : Appearance (3 25C: V iscous , opaque l i q u i d

% Non V o l a t i l e s : 4 . 0 - 4 . 5 pH: 8 . 5 - 1 0 . 0

SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : F o r m u l a t i o n f o r Pe rsona l Care

I n g r e d i e n t s : ( A ) : Water D.I.

C e l q u s t H-100

(6): Polawax A-31 J o j o b a O i l PVP (K-30)

( C ) : SDA-40B (Reg) G1 y d a n t Perfume

Jojoba Mousse

% by Weight 8 0 . 0

0 . 5

7 . 5 1 . o 1 . 5

1 5 . 2 0 . 2 0 . 1

M a n u f a c t u r i n g D i r e c t i o n s : ( 1 ) S t i r A t i l l c l e a r s o l u t i o n . ( 2 ) Add B and h e a t and s t i r t i l l d i s s o l v e d . ( 3 ) Cool and add C pH-4 Aeroso l F i l l : 85% o f above c o n c e n t r a t e / l 5 % o f A-46 P r o p e l l e n t S u p p l i e r s :

Cans - L i n e d P e e r l e s s Mousse c o n t a i n e r s Va lves - P r e c i s i o n Value Mousse v a l v e s and s p o u t s

OSURCE: F rank 8 . Ross Co., I n c . : Suggested F o r m u l a t i o n


Detangling Creme Rinse

N-Hance 3000 c a t i o n i c guar p r o v i d e s wet and d r y c o m b a b i l i t y t o t h i s f l o w a b l e , opaque, a f te r - shampoo r i n s e f o r h a i r d e t a n g l i n g and c o n d i t i o n i ng . T h i s p r o d u c t w i 11 a1 so i ncrease h a i r s o f t n e s s and reduce f l y - a w a y . The c y c l o m e t h i c o n e c o n t r i b u t e s g l o s s and adds p r o t e c t i o n a g a i n s t damage f r o m h e a t s t y l i n g . W i t h N-Hance, t h e v i s c o s i t y i s 2,000 cps and t h e pH=5 .2 . W i t h o u t N-Hance, t h e f o r m u l a t i o n i s w a t e r - t h i n and e x p e r i e n c e s phase s e p a r a t i o n .

I n s r e d i e n t : Aqueous Phase:

D i s t i l l e d w a t e r N-Hance 3000 c a t i o n i c guar Ce t r imon ium c h l o r i d e (25% a c t i v e ) C i t r i c a c i d (50% s o l u t i o n )

O i l Phase: C e t y l a l c o h o l Cyc l ometh i cone Stearami d o p r o p y l d i m e t h y l ami ne G1 y c e r y l s t e a r a t e P o l y s o r b a t e 80 P r o p y l e n e g l y c o l (and) d i a z o l i d i n y l u r e a (and)

me thy lpa raben (and ) p r o p y l p a r a b e n

Wt%

9 , s . t o 100.00 1 . o o 4 . 0 0 0 . 3 5

1 .50 1 . 5 0 0 . 7 0 0 . 6 0 0 . 4 0

0 . 7 5

P rocedure : 1 . D i s p e r s e N-Hance 3000 c a t i o n i c gua r by a d d i n g i t t o t h e

v o r t e x o f w e l l - a g i t a t e d w a t e r . Add t h e c i t r i c a c i d s o l u t i o n , wh ich promotes h y d r a t i o n o f t h e N-Hance and n e u t r a l i z e s t h e s t e a r a m i d o p r o p y l d i m e t h y l a m i n e . As e l e v a t e d t e m p e r a t u r e i s needed t o f o r m t h e emu ls ion , s t a r t h e a t i n g t o 65C. M ix u n t i l t h e po lymer i s f u l l y d i s s o l v e d .

2 . Add t h e c e t r i m o n i u m c h l o r i d e and m i x w e l l . 3 . I n a s e p a r a t e v e s s e l , combine t h e o i l - p h a s e i n g r e d i e n t s . Heat

4 . Add t h e aqueous-phase i n g r e d i e n t s t o t h e o i l - p h a s e i n g r e d -

5 . When a t 40C o r be low, add p r e s e r v a t i v e s and f r a g r a n c e .

SOURCE: Aqualon D i v i s i o n : N-Hance 3000 C a t i o n i c Guar : F o r m u l a t i o n

t o 65C.

i e n t s w i t h good a g i t a t i o n . Tu rn o f f h e a t b u t c o n t i n u e m i x i n g .


Easy Spreading Mousse

T h i s mousse c o n t a i n s Dow C o r n i n g 193 s u r f a c t a n t t o p l a s t i c i z e t h e Gan t rez r e s i n and t o enhance t h e s p r e a d a b i l i t y o f t h e r e s i n on t h e h a i r . Dow C o r n i n g 193 s u r f a c t a n t a l s o a s s i s t s i n foam b u i l d i n g and foam s t a b i l i t y .

I n a r e d i e n t s : Dow C o r n i n g 193 Gan t rez ES-225

Water SD A l c o h o l 40 P rope l 1 a n t A-46

AMP-95

% b v Weight 0 .50 5 . 0 0 0 .20

74.30 1 0 . 0 0 10 .00

P rocedure :

C o r n i n g 193 s u r f a c t a n t t o t h e w a t e r . S t i r t h e w a t e r m i x t u r e i n t o t h e e t h a n o l m i x t u r e . Add f r a g r a n c e and p r e s e r v a t i v e , i f d e s i r e d . Ae roso l F i l l i n g :

hyd roca rbon p r o p e l l a n t (10% b y w e i g h t ) . S t a b i 1 i t y :

Add t h e AMP-95 t o t h e e t h a n o l . S t i r i n t h e G a n t r e z . Add Dow

Load t h e c o n c e n t r a t e (90% b y w e i g h t ) and f i l l w i t h A-46

The s t a b i l i t y o f t h i s f o r m u l a t i o n has n o t been assessed. F o r m u l a t i o n PF-0364 suggested b y Dow C o r n i n g Corp. (E2-5284)

Gantrez Hair Spray with Cyclomethicone

T h i s h a i r s p r a y c o n t a i n s s i l i c o n e c y c l i c s , wh ich p l a s t i c i z e t h e r e s i n . The c y c l i c s g i v e improved c u r l r e t e n t i o n when compared w i t h t h e same f o r m u l a t i o n w i t h o u t c y c l i c s . T h i s f o r m u l a t i o n shows how s i l i c o n e c y c l i c s can be used i n Gantrez-based h a i r s p r a y s .

I n g r e d i e n t s : Dow C o r n i n g 345 F l u i d Gan t rez ES-425 AMP-Regul a r SD A l c o h o l 40 P r o p e l 1 a n t A-46

% b y W e i g h t 1 .oo 7 . 6 0 0 . 1 6

71 .24 2 0 . 0 0

P rocedure : Weigh o u t t h e a l c o h o l and d i s s o l v e t h e AMP i n t o i t . S t i r i n

t h e G a n t r e z . Add t h e Dow C o r n i n g 345 f l u i d . Add f r a g r a n c e if d e s i r e d . Dow C o r n i n g 344 f l u i d can be s u b s t i t u t e d f o r Dow C o r n i n g 345 f l u i d . Aerosol F i 11 i ng :

hyd roca rbon p r o p e l l a n t (20% b y w e i g h t ) . S t a b i 1 i t y :


Load t h e c o n c e n t r a t e (80% by w e i g h t ) and f i l l w i t h A-46

The s t a b i l i t y o f t h i s f o r m u l a t i o n has n o t been assessed. F o r m u l a t i o n PF-0365 sugges ted by Dow C o r n i n g Corp . (E2-5273)


A .

B .

C .

D .

Elegant Touch Strong Hold, 80% VOC Hair Spray

I n g r e d i e n t s : % b y Weight SD A l c o h o l 40, 200 p r o o f 40.00 D-Panthenol USP L u v i q u a t Mono CP L u v i s k o l VA 73 W U v i n u l MC 80 Dow C o r n i n g Q2-5220 AMP Regu la r

Luv imer 36D

F r a g r a n c e

D i m e t h y l E t h e r

0 .30 0 . 1 0 1 . o o 0 .10 0 . 2 3 1 . 4 7

16.70

0 .10

40.00

P rocedure : Combine i n g r e d i e n t s i n phase A . Add B t o A and m i x w e l l . Add C t o AB. F i l l i n t o a p p r o p r i a t e c o n t a i n e r s w i t h p r o p e l l a n t .

F o r m u l a t i o n PF-0393 sugges ted b y BASF (SG1085/1A)

Acudyne 255 Spray Gel Formulation


E t h a n o l D i s o d i um EDTA

Kathon CG C i t r o f 1 ex-2 Acudyne 255 (41%)

AMP-95

% b y We igh t 79 .94

6 .00 0 .10 0.62 0 . 0 4 0 . 1 0

1 0 . 0 0

B. A c u l y n 22 3 .20

P rocedure :

add phase B . S t i r u n t i l t h i c k e n e d .

P h y s i c a l C h a r a c t e r i s t i c s :

Add i n g r e d i e n t s o f phase A i n o r d e r l i s t e d . S t i r u n t i l c l e a r ,

V i s c o s i t y ( # 4 (3 60 rpm) : 400 cps

F o r m u l a t i o n PF-0392 sugges ted by Rohm & Haas C o . (PF-022b)



Extra-Hold Conditioning Mousse

I n g r e d i e n t s : % b y Weight

AMP-95 0 . 6 0 Amodimethicone (and) nonoxynol -10 (and ) t a l l o w -

0 . 4 0 Phosphol i p i d EFA 0 . 6 0 A l c o h o l , d e n a t u r e d 10 .00 Water 3 7 . 3 5

A . Amphomer 3 . 7 5

t r i mon i um c h 1 o r i de

B. H y d r o x y e t h y l c e l l u l ose 0 . 3 0

C . Water 3 7 . 0 0

D. Prope l 1 a n t 10.00

P rocedure :

H e a t i n g may h e l p s o l u b i l i z a t i o n . B l e n d BC i n A . P r e s s u r i z e w i t h D Combine A . C a r e f u l l y s p r i n k l e B i n C w i t h good a g i t a t i o n .

F o r m u l a t i o n PF-0370 sugges ted by Angus/Mona

De-Frizzing Creme-Gel

I n g r e d i e n t s : A . D e i o n i z e d w a t e r

D-Panthenol 5 0 P

Luv imer 36 D AMP-95

B. L u v i t o l EHO S e p i g e l 305

% by Weight 89 .45

1 . 0 0 0 . 2 5 2 .80

2 . 0 0 4 . 0 0

C . N ipaguard DMDMH 0 . 5 0

D . F rag rance q . s .

Procedure : Combine phase A i n o r d e r l i s t e d w h i l e m i x i n g . Combine phase B. Add B t o A under p r o p e l l e r m i x i n g u n t i l u n i f o r m e m u l s i o n i s

Add C and D t o AB and m ix u n t i l u n i f o r m .

F o r m u l a t i o n PF-0395 sugges ted b y BASF (ND547/2)

formed.



Firm Holding Mousse (Alcohol F r e e )

I n q r e d i e n t s : Wei n h t % Phase A : Water 43.80 T e t r a s o d i um EDTA 0 .10 O c t y l a c r y l ami d e / A c r y l a t e s / B u t y l ami n o e t h y l M e t h a c r y l a t e

Copolymer 3 . 7 5 A m i nomethy l Propanol 0 .65 O c t o x y n o l - 9 0 . 2 0 Q u a t e r n i um-80 ( A b i 1 Quat 3 2 7 2 ) 0 . 2 5 Dimeth icone C o p o l y o l ( A b i l B 88183) 0 .40 Cocami d o p r o p y l B e t a i ne (Tego B e t a i n e E ) 0 . 2 5

Sodium L a c t a t e (and) Sodium PCA (and) G l y c i n e (and) P r o p y l e n e G1 y c o l 0 . 2 0

and Sodium Benzoate (and) L a c t i c A c i d ( L a c t i l ) 0 .20 Pant hano l 0 . 2 0 P r e s e r v a t i v e s Q . S . F ragrance Q.S. Phase B : H y d r o x y e t h y l C e l l u l o s e 3 . 0 0 Water 3 7 . 0 0 Phase C : P r o p e l 1 a n t A-46 1 0 . 0 0 Procedure : 1 . M i x i n g r e d i e n t s o f Phase A . 2 . D i s p e r s e t h e H y d r o x y e t h y l C e l l u l o s e i n t o t h e w a t e r o f Phase B

3 . Combine Phases A / B . F i l t e r . 4 . F i l l . 5 . Charge P r o p e l 1 a n t .

F r u c t o s e (and ) Urea (and) N i a c i n a m i d e (and) I n o s i t o l

M ix u n t i l c l e a r .

Spray Hair Conditioner

I n g r e d i e n t s : Weight% Water 9 1 - 1 0 P r e s e r v a t i ves Q.S. P r o p y l e n e G1 y c o l 3 . 0 0 G1 y c e r i n 2 . 5 0 Quaternium-80 ( A b i l Quat 3 2 7 2 ) 0 . 3 5 Sodium L a c t a t e (and) Sodium PCA (and) G l y c i n e (and)

F r u c t o s e (and) Urea (and) N i a c i n a m i d e (and) I n o s i t o l (and) Sodium Benzoate (and) L a c t i c A c i d ( L a c t i l ) 0 . 2 5

C i t r i c A c i d 0 . 2 0 D i m e t h i c o n e C o p o l y o l (Ab i 1 B 8851) 0 .60 PEG-30 G l y c e r y l O l e a t e (Tagat 0) 2 . 0 0 Fragrance Q.S. Procedure :

Combi ne i n g r e d i e n t s i n o r d e r , m i x i ng we1 1 between a d d i t i o n s .

SOURCE: Goldschmid t Chemical Corp . : Suggested F o r m u l a t i o n s


Glossing Hair Conditioner

T h i s c o n d i t i o n e r p r o v i d e s e x c e p t i o n a l h a i r c o n t r o l , wet and d r y c o m b a b i l i t y , and g i v e s a s o f t g l o s s t o t h e h a i r . I n g r e d i e n t s : Weight% Phase A : Water 91 .25 C i t r i c A c i d 0 . 5 0 Phase 8: Stearami d o p r o p y l D i m e t h y l ami ne (Tego Amid S 18) 1 . 2 5 G l y c e r y l S t e a r a t e S.E. ( T e g i n ) 3 .00 Cete th-2 1 . 5 0 Behenoxy D i meth i cone ( A b i 1 Wax 2440) 0 . 3 5 Phase C : Propy lene G1 y c o l 0 .90 Q u a t e r n i um-80 ( A b i 1 Quat 3272) 0 . 4 0 Phase D : D imeth icone C o p o l y o l ( A b i 1 B 8851) 0 .25 Sodium C h l o r i d e - 25% aqueous s o l u t i o n 0 . 6 0 Phase E : C o l o r , F ragrance, P r e s e r v a t i v e s Q . S . Procedure : 1 . Heat t h e w a t e r t o 70C. Add and d i s p e r s e t h e C i t r i c A c i d . 2 . Add t h e i n g r e d i e n t s o f Phase B t o Phase A, one a t a t i m e ,

m i x i n g between a d d i t i o n s . A f t e r a l l a d d i t i o n s a r e made, mix u n t i l homogeneous.

m i x e r . m i x e r .

3 . Cool b a t c h t o 40C. M i x Phase C and add t o A / B . Use sweep

4 . Add r e m a i n i n g i n g r e d i e n t s . M i x u n t i l u n i f o r m u s i n g sweep

Acidic Hair Rinse

Gives permed and dyed h a i r a s o f t smooth t a c t i l e f e e l and g l o s s .

I n g r e d i e n t s : Wei q h t % Phase A : P o l y g l y c e r y l - 3 M e t h y l g l u c o s e D i s t e a r a t e (Tego Care 450) 4.0 Phase 0 : Water 73 .8 G l y c e r i n 2 . 0 C i t r i c A c i d (10%) 0 . 2 Phase C : H y d r o x y e t h y l c e l l u l o s e ( 2 . 5 % aqueous s o l u t i o n ) * 2 0 . 0 Phase D: Perfume Q.S. P r e s e r v a t i ve Q.S.

Procedure : 1 . Heat Phase A and B t o 70C, s t i r B i n t o A and homogenize. 2 . Add t h e H y d r o x y e t h y l c e l l u l o s e and homogenize a g a i n . S t i r

3 . The per fume i s added a t 30C. SOURCE : Go1 dschmi d t Chemical Corp , : Suggested Formul a t i ons

* N a t r o s o l 250 HR

u n t i l t h e e m u l s i o n i s c o o l ( 3 0 C ) .


Hair Conditioner

Formul a t i ng Des ign and Advantages: T h i s f o r m u l a i n c o r p o r a t e s a m i x t u r e o f amino a c i d s f rom t h e

S i 1 k ' n S o l u b l e L i q u i d (Dacso) . These amino a c i d s have a good a f f i n i t y f o r h a i r , e s p e c i a l l y when b l e a c h e d and damaged, l e a v i n g y o u r h a i r smooth and s i l k y .

Water Phase I : Water ( D i s t i l l e d ) B u t y l e n e G1 y c o l (Hoechs t ) G1 y c e r i ne (Uni chema) S i l k ' n S o l u b l e L i q u i d (Dasco) Cel l o s i ze ( H e r c u l e s ) Me thy lpa raben ( S u t t o n )

O i l Phase: Cera B e l l i n a (Pg-3 Beeswax, K o s t e r Keunen) M i n o s i l ( P r i d e S o l v e n t s ) G l y c e r o l Monos tea ra te (Henkel ) Amerchol L 101 (Amercho l ) V i t a m i n E ( P h i b r o Chem) P r o p y l p a r a b e n ( S u t t o n )

Water Phase 1 1 : Water ( D i s t i l l e d ) T r i e t h a n o l a m i n e (Dow)

y s 6 4 . 0

4 . 0 2 . 0 0 . 3 0 . 3 0 . 3

3 . 5 3 . 5 2 . 0 1 . 5 0 . 5 0 . 1

1 7 . 0 1 . o

P rocedure :

t h e e n t i r e phase i s s o l u b i l i z e d . M e l t and m ix t h e o i l phase u n t i l homogeneous and a t e m p e r a t u r e o f 75C i s m a i n t a i n e d . S l o w l y add t h e w a t e r phase I t o t h e o i l phase under moderate a g i t a t i o n . A l l o w t o c o o l t o 55C and add wa te r phase 11. C o n t i n u e m i x i n g and c o o l u n t i l a t room t e m p e r a t u r e .


i n t r o d u c e d i n t o t h i s t y p e o f f o r m u l a . C o n s i s t e n c y i s e a s i l y i n c r e a s e d by u s i n g a g r e a t e r c o n c e n t r a t i o n o f Cera B e l l i n a . Th i s w i 11 a1 so combi ne t o i n c r e a s e t h e c o n d i t i o n i n g p r o p e r t i e s o f t h e p r o d u c t .

Heat t h e w a t e r phase I t o 75C under a g i t a t i o n e n s u r i n g t h a t

O the r a c t i v e compounds and c o n d i t i o n i n g agen ts a r e e a s i l y



Hair Conditioner with DLL Quan t i t i Staqe M a t e r i a1 :. ~~

O i l Phase: 1 P r o c o l CS-20 D 2 * ooog 2 AEC Cher ry P i t O i l 0 .5009 Aqueous Phase: 3 Water ; Pure 87 .8509 4 N a t r o s o l 250 HR 0 ,5009 5 AEC D ime th i cone ( a ) L a u r e t h - 4 ( & ) Lau re th -23 2 . ooog 6 AEC D ice ty ld i rnon ium C h l o r i d e 3 . OOOg 7 P ropy lene G l y c o l USP 3 . OOOg 8 Germaben 11-E 0 .5009 C o o l i n g C y c l e : 9 D-Panthenol 75% 0 .500g 10 Fragrance; Cher ry AG6330 0 .150g 11 C o l o u r s as r e q u i r e d 9 M i x i n g I n s t r u c t i o n s :

D i s p e r s e t h e H y d r o x y e t h y l C e l l u l o s e i n w a t e r and b r i n g t o 70C w h i l e a d d i n g t h e r e m a i n i n g i t e m s o f t h e Aqueous Phase.

S e p a r a t e l y h e a t t h e O i l Phase t o 70C and w i t h h i g h shear m i x i n g add t h e O i l Phase t o t h e Aqueous, mix b r i e f l y t h e n s t i r u n t i l c o o l .

Add Pantheno l and f r a g r a n c e and a d j u s t t h e pH t o 5 . 0 - 5 . 5 w i t h c i t r i c o r p h o s p h o r i c a c i d .

C o l o u r as r e q u i r e d . T h i s s i m p l e f o r m u l a may be r e a d i l y adapted t o t a k e h e r b a l

P r o j e c t : J W 2390/Formul a R e f . : 81 7*2 a d d i t i v e s , s o l u b l e p r o t e i ns and o t h e r a c t i v e i n g r e d i e n t s .

Hair Conditioner with DLLSt~3S_!!!a_t_e r.iia.1.: Qua.r-ti t y O i l Phase: 1 C e t e a r y l A l c o h o l 3 . OOOg 2 Emulgade 1000 N I 1 .5009 Aqueous Phase: 3 Water ; Pure 91 ,700g 4 N a t r o s o l 250 HR 1 .ooog 5 AEC D ime th i cone ( & ) L a u r e t h - 4 ( a ) Laure th -23 2 . ooog 6 Germaben 11-E 0 .5009 Cool i ng C y c l e : 7 P . A G 9960 F r u i t y F l o r a l f o r h a i r 0 .150g 8 Phosphor i c A c i d 0.15Og 9 C o l o u r s a s r e q u i r e d 9 M i x i n g I n s t r u c t i o n s :

D i s p e r s e t h e H y d r o x y e t h y l C e l l u l o s e i n w a t e r and b r i n g t o 70C. S e p a r a t e l y h e a t t h e O i l Phase t o 70C and w i t h h i g h shear

m i x i n g add t h e O i l Phase t o t h e Aqueous, mix b r i e f l y t h e n s t i r u n t i l c o o l .

t h e pH t o 5 . 0 - 5 . 5 .

add i t i ves, s o l u b l e p r o t e i ns and o t h e r a c t i v e i n g r e d i e n t s as r e q u i r e d .

SOURCE: A & E Connock L t d , : Suggested F o r m u l a t i o n s

Add Fragrance, P r e s e r v a t i v e and c o l o u r as r e q u i r e d and a d j u s t

T h i s s i m p l e f o r m u l a may be r e a d i l y adapted t o t a k e h e r b a l

P r o j e c t JW 2390/Formula R e f . : 815*2


Hair Conditioner with DLL

M a t e r i a1 : Water; Pure AEC D i c e t y l d i m o n i um C h l o r i d e P ropy lene G1 y c o l USP AEC D i m e t h i c o n e ( & ) L a u r e t h - 4 ( & ) Laure th-23 P r o c o l CS-20D D-Panthenol 75% N a t r o s o l 250 HR AEC C h e r r y P i t O i 1 Germaben 11 - E Fragrance; Cher ry AG6330 C o l o u r s as r e q u i r e d

Formula R e f . : 81782

Hot Oil Conditioner with CPO

M a t e r i a l : Water, Pure I n c r o q u a t SDQ-25 P r o p y l ene G1 y c o l USP Lexami ne S-13 C o l o u r s as r e q u i r e d Emulgade 1000 N I AEC Cher ry P i t O i l N a t r o s o l 250 HR D-Panthenol 75% Germaben 11-E C i t r i c A c i d BP Fragrance; Cher ry AG6330


Hair Conditioner with DLL

M a t e r i a l : Water; Pure C e t e a r y l A1 coho1 AEC D i m e t h i c o n e ( & ) L a u r e t h - 4 ( & ) L a u r e t h - 2 3 Emulgade 1000 N I N a t r o s o l 250 HR Germaben 11-E Phosphor i c A c i d P . AG 9960 F r u i t y F l o r a l f o r H a i r C o l o u r s as r e q u i r e d


SOURCE: A & E Connock L t d . : Suggested F o r m u l a t i o n s

o/ow/w 87.850

3 .000 3.000 2.000 2.000 0 .500 0.500 0 I 500 0 .500 0 .150

e 85.440

3.000 3 . 0 0 0 2 .220 2 .000 1 . ooo 1 .ooo 0 .750 0 .500 0 .500 0.440 0 .150

%w/w 91 .700

3 . 0 0 0 2.000 1 .500 1.000 0 .500 0.150 0 .150

Hair Cure Products 183

Hair Cream Gel

Phase: A A A A A A B B

I n g r e d i e& Ceteare th-12 C e t e a r e t h - 2 0 PEG-7 G1 y c e r y l Cocoate O i l s o f A loha Macadamia G1 y c e r i ne D e i o n i z e d Water P r e s e r v a t i v e Perfume

Nut O i l

W S 10 .00 10.00 1 0 . 0 0

5 . 0 0 10 .00 54.00

QS 1 . o o

M a n u f a c t u r i ng Procedure : Phase A : Combine i n g r e d i e n t s a t 95C. Cool t o 40C. Phase B : Add p r e s e r v a t i v e and f r a g r a n c e .

Used t o f i r m t h e h a i r and t o g i v e i t a b e a u t i f u l sheen.


Hair Gel

Phase# : 1 1 1 1 1

2

3 3

4 4

I n n r e d i e n t s : Dei o n i zed w a t e r G1 y c e r i ne SD 40 A l c o h o l D i s o d i um EDTA Co lorona Bordeaux

1% Carbopol 941 s o l u t i o n

T r i e t h a n o l a m i n e 99% Dei o n i zed w a t e r

SD 40 A l c o h o l PVP/VA E-735

Wt% 18.00

2 .00 1 0 . 0 0

0 . 0 5 5 . 0 0

50 .00

0 . 7 5 2 .20

1 0 . 0 0 2 . 0 0

Procedure :

add t h e r e m a i n i n g phases i n o r d e r .

SOURCE: Rona/EM i n d u s t r i e s , I n c . : F o r m u l a t i o n EM3-57-2

Combi ne phase #1 w i t h p r o p e l 1 e r a g i t a t i o n . When homogeneous,


Hair Repair and Conditioner

I n g r e d i e n t s : Phase A : Water G l y c e r y l S t e a r a t e S.E. ( T e g i n ) M i n e r a l O i l C e t y l A l c o h o l Phenyl T r i m e t h i c o n e ( A b i 1 AV-20) C e t e t h - 2 Phase B : G l y c e r i n P r o p y l e n e G l y c o l D i meth i cone/Sodi um P o l y PG-Propyl D i meth i cone

Quatern ium-80 ( A b i l Quat 3272) Phase C: C o l o r P r e s e r v a t i v e s Fragrance C i t r i c A c i d (25% s o l u t i o n ) Procedure : 1 . Heat t h e i n g r e d i e n t s o f A t o g e t h e r w i t h m i x i n g t o 2 . Cool t o 45-50C. S w i t c h t o sweep m i x e r . 3 . B lend B. Add t o A . Sweep m i x . Cool t o 35-40C. 4 . A d j u s t pH. Add C o l o r , F r a g r a n c e and P r e s e r v a t i v e s .

T h i o s u l f a t e Copolymer ( A b i 1 S 201 )

Weight%

88.10 4 .00 1 . o o 2 .00 0 .50 1 .oo

1 . o o 1 .oo

1 . 0 0 0 . 4 0

Q . S . Q . S . Q.S.

t o pH 7 . 2

70C.

Conditioning Hair Rinse far Oily Hair

P r o v i d e s r e f a t t i n g , m o i s t u r i z i n g and reduces s t a t i c f l y - a w a y o f h a i r . S o f t c o n d i t i o n i n g .

I n g r e d i e n t s : Phase A : Pol y g l y c e r y l - 3 M e t h y l g l ucose D i s t e a r a t e (Tego Care 450) Phase B: Water D i m e t h i c o n e C o p o l y o l ( A b i 1 B 8852) P r o p y l e n e G1 y c o l C i t r i c A c i d (10%) Quatern ium-80 ( A b i l Quat 3272) Phase C: H y d r o x y e t h y l c e l l u l o s e ( 2 . 5 % aqueous s o l u t i o n ) * Phase D : Perfume P r e s e r v a t i ve

Procedure : *Nat r o s o l 250HR

%w/w

4 . 0

71 . 5 1 . o 3 . 0 0 . 2 0 . 3

2 0 . 0

Q . S . Q . S .

1 . Heat Phase A and B t o 70C, s t i r B i n t o A and homogenize. 2 I Add t h e H y d r o x y e t h y l c e l l u l o s e and homogeni ze a g a i n . S t i r

3 . The per fume i s added a t 30C.

SOURCE: Go ldschmid t Chemical Corp. : Suggested F o r m u l a t i o n s

u n t i l t h e e m u l s i o n i s c o o l ( 3 0 C ) .


Hair Shaping Gloss

Fgrrnul!a_:_ % by WeightOil Phase:Volpo 10 (Croda) 9.00Crodafos N3N (Croda) 3.20Crodafos N10N (Croda) 2.50Crodamol PTC (Croda) 0.80Blandol Mineral Oil (Witco) 12.00Parsol MCX 0.60Propyl Paraben 0,15Aqueous Phase:Volpo S-20 (Croda) 1.50Glycerine 9.00Propylene Glycol 1,40Methyl Paraben 0.30Germall 115 0.20Deionized Water 58.85Protein Phase:Cromoist HYA (Croda) 0.25Kerasol (Croda) 0.25

Procedure:Heat oil phase to 80-85C, heat aqueous phase to 85C. Add

aqueous phase to oils under good mechanical agitation. Cool to45C, add proteins. F i l l off.

Conditioning, Setting Gel

Fp_rjmjl_aj_ % by WeightA:Isoceteth-20 20.0Blandol Mineral Oil (Witco) 11.0Oleth-2 6,0B:Water 49.6Sorbitol Solution, USP 7.0Propylene Glycol 5,0Soyaethyl Morpholinium Ethosulfate 1.4

Procedure:Heat A and B to 9OC. Add B to A with gentle stirring. Cool

to 8OC and add make-up water. Stir until uniform and pour whilestil l fluid.

SOURCE: Witco Corp,: Suggested Formulations


Hair Straightener

Formula;- O i l Phase: C a r n a t i o n M i n e r a l O i 1 (Wi t c o ) Wh i te P r o t o p e t 1 s ( W i t c o ) Lipowax N I L i p o c o l C L i p o c o l S-2 Water Phase A : Dei o n i zed Water L i p o c o l 5-20 L i p o l a n 31 P ropy lene G l y c o l ( A r c o ) S ipon 201-10 ( A l c o l a c ) Water Phase B: L i t h i u m Hydrox ide Monohydrate Dei o n i zed Water

% b y Wei q h t

11 - 0 0 1 1 . o o 1 6 . 0 0

1 . o o 0 . 5 0

50 .00 1 .50 2 .00 2 .00 0 . 2 5

3 . 5 0 1 . 2 5

P rocedure : Combine a l l i n g r e d i e n t s i n o i l phase i n main k e t t l e and h e a t

t o 75C. Combine A i n s i d e k e t t l e and h e a t t o 75C, Add A t o O i l Phase a t 75C w i t h c o n s t a n t a g i t a t i o n . Cool t o 65C w i t h m i x i n g and s p r i n k l e i n l i t h i u m h y d r o x i d e f r o m 6 . Cool t o 50C and add c o l d w a t e r f r o m B. Cool t o 42C and f i l l . Reduc ing Lipowax N I l e v e l t o 12% r e s u l t s i n s o f t e r cream.

Hair Relaxer

..-______ Formula : A: 61 ando l M i n e r a l O i 1 (Wi t c o ) Macol 124 C e t y l A l c o h o l PEG-75 Lano l i n B : Water P r o p y l ene G1 y c o l Avanel S-150 Cal c i um H y d r o x i de

Water Xanthan G u m (Ke lco-Merck)

% b y Weigh t

1 2 . 0 11 . o 2 . 0 3 . 0

2 8 . 0 5 . 0 3 . 5

1 0 . 0

25 .0 0 . 5

P rocedure : B l e n d A i n g r e d i e n t s , hea t s l o w l y t o 70C. Premix B and h e a t

t o 70C; add s l o w l y t o A w i t h h i g h shear , f o r m i n g t h e e m u l s i o n . Premix C, h e a t i n g t o 55C. When u n i f o r m add t o main b a t c h w i t h h i g h s h e a r . Cool w h i l e m a i n t a i n i n g sweep a g i t a t i o n . Package a t 35-4OC.

SOURCE: W i t c o Corp I : Suggested F o r m u l a t i o n s


Hair Styling Cream (for dried hair) I n q r e d i en& % b y Weigh t Phase 1 : Lanocer i n 1 2 . 0 0 E s t o l EHP 8 . 0 0 Crodaco l CS-50 6 . 0 0 S tandapo l WAQ-Speci a1 5 . 0 0 P e t r o l a t u m 5 . 0 0 Crodaco l C-95 2 .00 L i p o c o l C-10 1 . o o I n c r o c a s - 4 0 1 . o o O z o k e r i t e Wax 1 . o o L i p o c o l S-10 0 .75 Carnauba Wax 0 . 5 0 Phase 2 : D i s t i 11 ed Water 4 0 . 4 1 P r o p y l ene G1 y c o l 4 .00 Amp homer 2 . 0 0 AMP-95 0 . 3 4 Phase 3 : E t h a n o l , SDA-40 10 .00 Germaben I 1 1 . o o Procedure :

Combine i n g r e d i e n t s i n Phase 1 . Heat t o 80C. Combine a l l i n g r e d i e n t s o f phase 2, excep t f o r Amphomer. W i t h v i g o r o u s a g i t a t i o n , hea t i n g r e d i e n t s t o 60C. S l o w l y s i f t i n Amphomer. B r i n g hea t t o 80C. Combine i n g r e d i e n t s o f Phase 1 w i t h i n g r e d - i e n t s o f Phase 2 . Mix f o r 15 m i n u t e s . Cool t o 50C. Add i n g r e d - i e n t s o f Phase 3 . M i x f o r 10 m i n u t e s . Pour i n t o c o n t a i n e r . A l l o w t o c o o l .

Corp . (8334-66) Formul a t i on PF-0353 suggested by N a t i o n a l S t a r c h & Chemical

Resyn Hair Spray with Dimethicone CopolyolT h i s h a i r s p r a y c o n t a i n s Dow C o r n i n g 193 s u r f a c t a n t wh ich

p l a s t i c i z e s t h e r e s i n . T h i s f o r m u l a t i o n shows how s i l i c o n e g l y - c o l s can be used i n Resyn-based h a i r s p r a y s . Dow C o r n i n g Q2-5220 r e s i n m o d i f i e r can be s u b s t i t u t e d f o r Dow C o r n i n g 193 s u r f a c t a n t .

Dow C o r n i n g 193 0 . 5 0 Resyn 28-3307 3 . 0 0 AMP Regu la r 0 . 2 8 SD A l c o h o l 40 76 .22 P rope l 1 a n t A-46 2 0 . 0 0 Procedure :

D i s s o l v e t h e Resyn i n t o t h e e t h a n o l . Add t h e AMP. Add Dow C o r n i n g 193 s u r f a c t a n t . S t i r u n t i l u n i f o r m . Add f r a g r a n c e i f d e s i r e d . Ae roso l F i 11 i ng :

hyd roca rbon p r o p e l l a n t (20% b y w e i g h t ) . S t a b ? 1 i t y :

I n q r e d i en=; %.&LvgiLsiht

Load t h e c o n c e n t r a t e (80% b y w e i g h t ) and f i l l w i t h A-46

The s t a b i l i t y o f t h i s f o r m u l a t i o n has n o t been assessed. F o r m u l a t i o n PF-0363 suggested b y Dow C o r n i n g Corp . (E2-5285)

SOURCE: Angus Chemical C o r p . : P roduc t Fo rmu la ry


High Performance Creme Rinse Conditioner

The d u a l a c t i o n o f t h e Croda fos CES and t h e I n c r o q u a t Behenyl TMS i n t h i s f o r m u l a t i o n g i v e e x c e l l e n t c o n d i t i o n i n g t o h a i r .

I n g r e d i e n t s : Wt% P a r t A : Croda fos CES ( C e t e a r y l A l c o h o l (and) C e t e a r y l Phosphate) 6 . 0 0 I n c r o q u a t Behenyl TMS (Behen t r imon ium M e t h o s u l f a t e (and) C e t e a r y l A1 coho1 ) 1 - 0 0

P r o p y l paraben 0 .10 Vo lpo S-2 ( S t e a r e t h - 2 ) 0 .50 Crodaco l C-70 ( C e t y l A l c o h o l ) 2 . 0 0 Crodamol PTIS ( P e n t a e r y t h r i t y l T e t r a i s o s t e a r a t e ) 1 . o o

P a r t 0 : Dei o n i zed Water 87 .98 I n c r o m e c t a n t Lamea (Acetamide MEA (and ) Lac tamide MEA) 1 - 0 0 M e t h y l Paraben 0 .10

P a r t C : TEA 99% 0 .32

P rocedure :

Combine i n g r e d i e n t s o f P a r t B w i t h m i x i n g and h e a t t o 65-70C. Add P a r t 0 t o P a r t A w i t h m i x i n g and c o o l t o 40C. C o n t i n u e m i x i n g and add P a r t C . Cool t o d e s i r e d f i l l t e m p e r a t u r e .

Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 65-7OC.

pH=4.50+-0.5 V iscos i t y=56 ,000+-10% (RVT S p i n d l e , #T-D, 10 rpm, d 25C) N.A.T.C. Approved

SOURCE: Croda I n c . : F o r m u l a t i o n HP-178-1

Hair Shine Concentrated Gel

I n g r e d i e n t s : Water A b i l OSW-12 A b i l AV-20 P r o p y l e n e G1 y c o l Hexy l ene G1 y c o l P r e s e r v a t i v e s Po l y a c r y l ami de (and ) C1

Procedure :

%w/w 25.45 27.27

4 . 5 5 35 .00

4 . 5 5

14 I s o p a r a f f i n (and ) L a u r e t h - 7 3 . 1 8 Q . S .

B l e n d t h e i n g r e d i e n t s t o g e t h e r i n t h e o r d e r g i v e n w i t h m i x i n g . When a1 1 i n g r e d i e n t s a r e combi ned, c o n t i nue m i x i ng u n t i 1 c l e a r . V i s c o s i t y w i l l d e v e l o p a f t e r m i x i n g .

SOURCE: Go ldschmid t Chemical C o r p . : Suggested F o r m u l a t i o n


High Performance 80% VOC Non-Aerosol Hair Spray

T h i s h i g h s o l i d s 80% VOC non-aeroso l h a i r s p r a y combines low s o l u t i o n v i s c o s i t y , a f i n e , m i s t y s p r a y and o p t i m a l d r y i n g t i m e w i t h a h a r d h o l d and good h u m i d i t y r e s i s t a n c e .

I n g r e d i e n t s : L o v o c r y l - 4 7 AMP Regu lar C i t r o f 1 ex-2 C r o t e i n ADW d l -Pantheno1 P u r c e l 1 i n O i 1 Dei o n i zed Water Anhydrous E t h a n o l , SDA-40

P a r t s by Weight 8 . 0 0 1.61 0 . 2 0 0 . 1 0 0 . 0 5 0 . 0 5 9 . 9 9

8 0 . 0 0

Valve S p e c i f i c a t i o n s : Calmar Mark I 1 V a l v e Head : WS I n d u c t o r : 6 1 / 4 " SPV: 302 SS ACM: 1 BLIP GSK: 05744

P r e p a r a t i o n : D i s s o l v e AMP i n w a t e r and e t h a n o l . Whi l e m a i n t a i n i n g good

a g i t a t i o n , s l o w l y s i f t i n L o v o c r y l - 4 7 . Once d i s s o l v e d , add b a l a n c e o f i n g r e d i e n t s and mix u n t i 1 homogeneous. F i l t e r and f i l l .

F o r m u l a t i o n 7974:115

Ultra-Hold Finishing Spray

T h i s anhydrous a e r o s o l h a i r s p r a y has a s t i f f h o l d w i t h e x c e l l e n t h u m i d i t y r e s i s t a n c e , c o m p a t i b i l i t y w i t h a w ide v a r i e t y o f a d d i t i v e s and e x c e l l e n t s u b j e c t i v e p r o p e r t i e s on h a i r .

I n a r e d i e n t s : Resyn 28-2930 AMP Regu lar

Phosphol i p i d EFA TEA Sa l i c y 1 a t e Monamid 716 Fragrance Anhydrous E t h a n o l , SDA-40 Prope l 1 a n t A-46

DC Q2-5220

P a r t s by Weight 5 . 4 0 0 . 5 4 0 . 2 0 0 . 2 0 0 . 0 5 0 .10

68.51 25.00

q . s .

P r e p a r a t i on : D i s s o l v e AMP i n e t h a n o l , W h i l e m a i n t a i n i n g good a g i t a t i o n ,

s l o w l y s i f t Resyn 28-2930 i n t o t h e v o r t e x . When t h e s o l u t i o n i s comple te , add r e m a i n i n g i n g r e d i e n t s and mix u n t i 1 homogeneous. F i l t e r and f i l l c o n c e n t r a t e . Charge w i t h p r o p e l l a n t .

F o r m u l a t i o n 6472:146



Hot Oil Conditioner with CPO

Stage M a t e r i a1 : Q u a n t i t y S tage A : 1 Water ; Pure 85.4409 2 N a t r o s o l 250 HR 0 .7509 3 Germaben 11-E 0 .5009 S tage B: 4 I n c r o q u a t SDQ-25 3 . OOOg 5 Emulgade 1000 N I 1 . o o o g 6 AEC C h e r r y P i t O i l 1 .ooog 7 P r o p y l e n e G l y c o l USP 3 . OOOg 8 C i t r i c A c i d BP 0.4409 9 Lexamine S-13 2 ,2209 C o o l i n g C y c l e : 10 D-Panthenol 75% 0.5009 11 F rag rance ; C h e r r y AG6330 0 .150g 12 C o l o u r s as r e q u i r e d 2 . ooog M i x i n g I n s t r u c t i o n s :

D i s p e r s e t h e H y d r o x y e t h y l C e l l u l o s e i n w a t e r and b r i n g t o 70C. S e p a r a t e l y h e a t t h e O i l Phase t o 70C and w i t h h i g h shear

m i x i n g add t h e O i l Phase t o t h e Aqueous, mix b r i e f l y t h e n s t i r u n t i l c o o l .

Add F r a g r a n c e , P r e s e r v a t i v e and c o l o u r as r e q u i r e d and a d j u s t t h e pH t o 5 . 0 - 5 . 5 .

T h i s s i m p l e f o r m u l a may be r e a d i l y adap ted t o t a k e h e r b a l a d d i t i v e s , s o l u b l e p r o t e i n s and o t h e r a c t i v e i n g r e d i e n t s as r e q u i r e d .

SOURCE: A & E Connock L t d . : P r o j e c t : JW 2335/Formula R e f . 816*l

Hair Straightener

P a n a l a n e ' s f u n c t i o n i s t o reduce s c a l p b u r n w h i l e p r o v i d i n g e m o l l i e n c e and s p r e a d a b i l i t y . Ye t i t has a l e s s g reasy f e e l i n g on t h e s k i n t h a n o t h e r o i l s used i n t h i s t y p e o f p r o d u c t . Pana- l a n e i s s t a b l e a t t h e h i g h pH r e q u i r e d f o r t h i s a p p l i c a t i o n . Sequence: Raw M a t e r i a l : P e r c e n t

1 Dei o n i zed Water 56.00 1 P r o p y l e n e G1 y c o l 2 . 0 0 1 Uniphen P-23 1 . o o 2 Lipowax P 15.00 2 P e t r o l a t u m W h i t e 8 . 0 0 2 Panal ane L-14E 10.00 3 Sodi um H y d r o x i de (25% s o l n ) 8 . 0 0

P rocedure : 1 . Combine and h e a t Sequence #1 and Sequence #2 s e p a r a t e l y t o 75C 2 . Add Sequence # 2 t o Sequence #1 w i t h r a p i d m i x i n g . 3 . Cool t o 40C b e f o r e a d d i n g Sequence #3 . 4 . Cool t o room t e m p e r a t u r e and package.

SOURCE: L i p 0 Chemica ls I n c . : Formula No. 825


Modern Expression Hair Mask


P1 u r a c a r e F127 L u v i q u a t Mono CP D-Panthenol 50 P L u v i s k o l VA 73 W Dow C o r n i n g 193 P o l y e t h e r Hydro1 yzed Wheat P r o t e i n

N i paguard DMDMH

Tenox BHT (10% i n SD A l c o h o l )

So l u - S O ~ EN25

AMP-95

B. Cremophor RH 40 F rag rance

% b y We igh t 70.01 20.00

1 . o o 2 . o o 1 - 0 0 0 . 5 0 0 . 7 0 0 . 3 0 0 .50 0 . 4 9 1 . 0 0

0 . 3 5 0 . 1 5

C . Luv imer 100 P 2 . 0 0

Procedure :

t o t h e w a t e r and m i x u n t i l t h e s o l u t i o n i s homogeneous. U s i n g c o l d w a t e r f o r phase A (4C-1OC) s l o w l y add t h e P l u r a c a r e

Add t h e r e m a i n i n g i n g r e d i e n t s o f A t o t h e P l u r a c a r e s o l u t i o n . Combine Phases B and C s e p a r a t e l y . M a i n t a i n t h e phase A t e m p e r a t u r e be low 1OC and add phases B

T r a n s f e r t h e m i x t u r e t o a p p r o p r i a t e c o n t a i n e r s and a l l o w t o and C t o A .

warm up t o room t e m p e r a t u r e , whereupon t h e l i q u i d becomes a r i n g i n g g e l .

F o r m u l a t i o n PF-0397 sugges ted by BASF (SG1103/2)

Spiking Spritz

T h i s s p i k i n g s p r i t z c o n t a i n s Dow C o r n i n g 190 s u r f a c t a n t , wh ich reduces t a c k i n e s s and p r o v i d e s a 1 i g h t , nongreasy f e e l .

I n g r e d i e n t s : E t h a n o l (190 p r o o f ) Dow C o r n i n g 190 S u r f a c t a n t AMP-Regul a r Amp homer

Procedure : M ix i n o r d e r .

% by Weight 91 .90

1 . 0 0 1 . 1 0 6 . 0 0

S t a b i 1 i t y : 3 months a t 40C 6 months a t room t e m p e r a t u r e

F o r m u l a t i o n PF-0367 sugges ted b y Dow C o r n i n g Corp. (E8239-21)

SOURCE: Angus Chemical Co . : P roduc t Formul a r y


Non-Aerosol Finishing Spray

A l i g h t , holding spray that provides a conditioning sheenthrough the use of Phospholipid EFA,

%_By WeightSD Alcohol 40 94.10Vinyl Acetate/Crotonic Acid Copolymer 3.75Water 1.20Phospholipid EFA 0.60Aminomethyl Propanol 0.35

Add vinyl acetate/crotonic acid copolymer to alcohol slowlywith adequate agitation, mix until well dispersed. Add amino-methyl propanol to neutralize, and mix until dissolved. Addremaining ingredients, color, fragrance and package.

Finishing Spray

% By.__Weigil±SD Alcohol 40 94.10Resyn 28-1310 3.75Water 1 .20Aminomethyl Propanol 0.35Phospholipid EFA 0.60

Procedure:Add Resyn 28-1310 to alcohol slowly with adequate agitation,

mix until well dispersed. Add aminomethyl propanol to neutralize,and mix until dissolved. Add remaining ingredients color, frag-rance and package.

Replenishing Creme Rinse

% By WeightWater 87.80Hydroxyethyl Cellulose 0.70Glycol Distearate 2.00Cetearyl Alcohol 2.50Monaquat TG 6.70Phospholipid EFA 0.30

Procedure;Charge water, carefully add Natrosol 250 HHR with good agit-

ation. Heat to 50-60 and add remaining ingredients and continueheating to 7OC. Cool to 45C and adjust pH to 4.5 to 5.0. Addcolor, fragrance and preservative as required. Continue agit-ation and cooling until pearl develops.

Formula F-577

SOURCE: Mona Industries, Inc.: Suggested Formulations


Pelan Hair Conditioner

T h i s p r o d u c t employs humectants , e m o l l i e n t s and n a t u a l c o n d i - t i o n e r s such as Pe lan B l a c k and L i p o q u a t R wh ich s o f t e n and e n r i c h t h e h a i r , l e a v i n g a h e a l t h y s h i n e .

Sequence Raw M a t e r i a1 : 1 Dei o n i zed Water 1 K e l t r o l

3 L i p o n i c EG-1 3 Uniphen P-23

Wei q h t % 79.00

0 . 3 0

2 .00 0 . 5 0

4 Pe lan B l a c k 8 .00

5 5 5 5 5 5 5 5 5 5

L i p o c o l C L i p 0 GMS-450 L i p o n a t e SPS Lipowax D L ipopeg 6000 DS L i p o n a t e I P P Lipowax P L i p o c o l S L i p o n a t e DPC-6 V i t a m i n E A c e t a t e

6 Dei o n i zed Water 6 L i poqua t R

1 . 5 0 1 . 2 5 1 . o o 1 . o o 1 . o o 0 . 7 5 0 . 7 5 0 . 6 5 0 . 5 0 0 . 5 0

1 . o o 0.30

Procedure : 1 . Heat Sequence #1 t o 76C. 2 . Add Sequence #2 t o Sequence # 1 s l o w l y on overhead m i x e r a t

3 . Once Sequence #2 i s c o m p l e t e l y h y d r a t e d , add Sequence #3 i n

4 . Add Sequence # 4 t o b a t c h under homogen iza t i on a t low/medium

5 . Heat Sequence #5 t o 78C, u n t i l c l e a r , t h e n add t o b a t c h under

6 . A t room t e m p e r a t u r e , p r e m i x Sequence #6 and add t o h e a t e d

7 . S w i t c h t o overhead m i x e r a t l o w speed w h i l e c o o l i n g t o room

medi um/hi gh speed.

o r d e r o f a d d i t i o n , w h i l e h o l d i n g t e m p e r a t u r e a t 76C.

speed whi 1 e h o l d i ng t e m p e r a t u r e a t 76C.

homogen iza t i on a t low/medium speed.

b a t c h on homomixer a t l o w speed f o r 20-30 seconds.

t e m p e r a t u r e .

Speci f i c a t i ons : p H : 5 . 2 t - 0 . 2 V i s c o s i t y : 27,900i-10% LVT #3 @ 3 . 0 rpm

SOURCE: L i p 0 Chemicals I n c . : F o r m u l a t i o n No. 946


Pomade

Formul a t i ng Desi gn and Advantages :

s t i l l have good f u n c t i o n a l p r o p e r t i e s t o w a r d h a i r . T h i s anhydrous p r o d u c t has been f o r m u l a t e d f o r l o w c o s t and

Formul a : P e r f e c t a P e t r o l a t u m ( W i t c o ) M i n e r a l O i 1 USP (Kaydo l - W i t c o ) E m u l s i f y i n g Wax NF ( K o s t e r Keunen) Ceres ine Wax 130/135 ( K o s t e r Keunen) V i t a m i n E (BASF) Deodor i zed Orange Wax ( K o s t e r Keunen) D & C Red # 1 7 Dye ( W h i t t a k e r ) Coconut F rag rance O i l (Aroma Tech)

YO b y Weiqht 3 2 . 0 0 51 . 5 5

6 . 0 0 8 . 0 0 0.20 2.00 0 . 0 5 0.20

Procedure :

70C and m i x . Once homogeneous, a l l o w t o c o o l w h i l e m i x i n g . Add f r a g r a n c e a t 50C and pour i n t o c o n t a i n e r .


p r o d u c t c o n s i s t e n c y . A d d i t i o n a l a c t i v e s may b e i n c o r p o r a t e d t o f i t consumer ' s needs .

Add a l l i n g r e d i e n t s excep t f r a g r a n c e i n t o a v e s s e l , h e a t t i l l

S u b s t i t u t i o n o f t h e dye and /o r f r a g r a n c e w i l l n o t a l t e r


Hair Straightener

_ _ _ _ _ ~ ~ _ Formula : A : Dei o n i zed Water P ropy lene G1 y c o l B: Pol awax W h i t e P r o t o p e t 1s P e t r o l a t u m ( W i t c o ) Hydrogenated P o l y i s o b u t e n e C: Sodium H y d r o x i d e (25% s o l . ) D: P ropy lene G 1 y c o l ( a n d ) D i azo1 i d i n y l Urea ( a n d )

Me thy lpa raben ( a n d ) P ropy lpa raben ( S u t t o n )

1 5 . 0 0 8 . 0 0

10 .00

8 . 0 0

1 . o o

P rocedure :

75C. Add t h e o i l phase t o t h e wa te r phase w i t h r a p i d m i x i n g . Cool t o 40C b e f o r e add ing C and D . Cool t o room temp. and package.

Combine and h e a t w a t e r phase A and o i l phase B s e p a r a t e l y t o



Premium Biodegradable Hair Conditioner

D. I. Water H y d r o x y e t h y l C e l l u l o s e Sodi um H y d r o x i de (50%) Ammonyx GA-SO/GA-70PG Kessco C e t y l A l c o h o l Kessco O c t y l I sononanoa te Potass ium C h l o r i d e C i t r i c A c i d (50%) F rag rance , Dye, P r e s e r v a t i v e

% b y Weight Q . S . t o 100 .0

0 .70 Q.S.

2 .22 /2 .86 2 .00 2 . 0 0 0 . 5 0

Q . S . Q . S .

M i x i n g Procedure: I n t o a s u i t a b l e v e s s e l equ ipped w i t h h e a t i n g , c o o l i n g , and

a g i t a t i o n means, add D . I . Wa te r . B e g i n m i x i n g . I n t o a v o r t e x , s p r i n k l e i n H y d r o x y e t h y l C e l l u l o s e . Add Sodium H y d r o x i d e t o r a i s e t h e p H t o 7 . 5 - 8 . 0 and c o n t i n u e a g i t a t i o n u n t i l a l l of t h e H y d r o x y e t h y l C e l l u l o s e has d i s s o l v e d (30-40 m i n u t e s ) I Heat t o 70-75C. Add Ammonyx GA-90 o r GA-70PG, Kessco C e t y l A l c o h o l , and Kessco O c t y l I sononanoa te . E m u l s i f y f o r 30 m i n u t e s and m a i n t a i n t h e t e m p e r a t u r e between 70-75C. Cool t o 38-48C and add Potass ium C h l o r i d e d i s s o l v e d i n w a t e r . A d j u s t f i n a l pH ( 3 . 5 - 4 . 5 ) w i t h c i t r i c a c i d , i f n e c e s s a r y . Cool t o amb ien t t e m p e r a t u r e w i t h c o n t i n u o u s m i x i n g , add r e m a i n i n g i n g r e d i e n t s .

Ethnic Hair Shine

Dow C o r n i n g S i l i c o n e 245 Kessco O c t y l I sononanoa te O c t y l Me thoxyc i nnamate

M i x i ng P rocedure : Combi ne a1 1 i n g r e d i e n t s w i t h m i x i ng I

SOURCE: Stepan Co.: Suggested F o r m u l a t i o n s

56 by Weiqht 7 0 . 0 25 .0

5 . 0


Pump Hair Spray

Pump H a i r Spray based on t h e we l l -known Gant rez ES-225, c o n t a i n s Dow C o r n i n g 3225C F o r m u l a t i o n a i d wh ich f u n c t i o n s i n two ways. F i r s t , t h e c y c l o m e t h i c o n e component p r o v i d e s l u b r i c i t y f o r t h e i n i t i a l s t y l i n g and combing. Second, t h e d i m e t h i c o n e c o p o l y o l component remains b e h i n d a f t e r a l l t h e v o l a t i l e s a r e gone, t o p r o v i d e easy combing. Daw C o r n i n g 3225C a l s o a c t s as a r e s i n p l a s t i c i z e r and d e t a c k i f i e r .

I n g r e d i e n t s : Dow C o r n i n g 3225C F l u i d Gant rez ES-225 AMP-Regul a r SD A l c o h o l 40

% by Weight 1 .oo 6 .90 0 . 2 0

91.90

Procedure : Weigh o u t t h e a l c o h o l and d i s s o l v e t h e AMP i n t o i t . S t i r i n

t h e r e s i n and t h e Dow C o r n i n g 3225C f o r m u l a t i o n a i d . M i x u n t i l u n i f o r m and add f r a g r a n c e i f d e s i r e d I

S t a b i l i t y : The s t a b i l i t y o f t h i s f o r m u l a t i o n has n o t been assessed. F o r m u l a t i o n PF-0366 suggested by Dow C o r n i n g Corp. (E2-3287)

Flexible Spray Gel

H i g h l y shear t h i n n i n g due t o t h e copolymer t h i c k e n e r i n Phase B.

I n g r e d i e n t s : P a r t A : Water E t h a n o l D i sod i um EDTA

Kathon CG C i t r o f l ex-2 Acudyne 255, 41%

P a r t B: A c u l y n 22

AMP-95

46 by Weight

79.94 6 .00 0 . 1 0 0 . 6 2 0 .04 0 . 1 0

10 .00

3 . 2 0

Procedure :

t h i c k e n e d .

P r o p e r t i 8s :

Combine A i n o r d e r shown. S t i r u n t i l c l e a r . Add B . S t i r u n t i l

V i s c o s i t y ( # 4 a t 60 rpm) : 400 cps F o r m u l a t i o n PF-0369 suggested b y Rohm & Haas.

SOURCE: Angus Chemical Co.: P r o d u c t Formulary


Salon Type Hair Conditioner

S t a t e o f t h e a r t p r o t e i n /pan theno l based c o n d i t i o n e r d e s i g n e d f o r achievement o f s a l o n t y p e pe r fo rmance .

I n g r e d i e n t s : 1 . R i t a CA ( C e t y l A l c o h o l ) 2 . R i t a STAC-80- ( S t e a r t r i m o n i u m C h l o r i d e ) 3 . R i t a CTAC-605 (Ce t r imon ium C h l o r i d e ) 4 . C i t r i c A c i d @ 50% 5. D i m e t h y l Stearami ne (Adogen MA-1 08) 6 . D i s t i 11 ed/Dei o n i zed Water 7 . Amandul ine SG (Sweet Almond P r o t e i n ) 8. R i t a l o e 200M ( A l o e Vera G e l ) 9 . R i t a p a n DL ( d l - P a n t h e n o l ) 10. P r o p y l e n e G1 y c o l 11 . P o l y q u t a 400 (Po lyqua te rn ium-10) 12 .Ka thon CG 13.Dow C o r n i n g 7224 14.Dow C o r n i n g 344 F l u i d 1 5 . F r a g r a n c e

%w/w 5 .00 2 .50 0.50 0 . 1 8 0 . 1 3 85.84

2 .00 0.50 1 - 0 0 0 . 5 0 1 - 0 0 0 . 0 3 0 . 4 0 0 . 1 7 0 .25

Compounding P rocedure : D i s p e r s e i t e m 11 i n i t e m 6 w h i l e m i x i n g . Heat t o 70C. Add

i t e m s 8, 9, 10 and 1 3 . Combine i t e m s 1, 2, 3 and 5 and h e a t t o 70C. Add t o w a t e r phase. Add i t e m 4 and m ix w h i l e c o o l i n g . Add i t e m s 7, 12, 14 and 15 when c o o l .

R e f . No. 121-177

Pump Spray Hair Conditioner

A pump s p r a y c o n d i t i o n e r c o n t a i n i n g P o l y q u t a 400 , R i t a s i 1 190 and Amandul ine SG f o r c o n d i t i o n i n g .

I n g r e d i e n t s : 1 . D i s t i 11 ed/Dei o n i zed Water

Y f i 89.60

2 . P o l y q u t a 400 (Po lyqua te rn ium-10) 0 . 5 0 3 . Amandul ine SG ( H y d r o l y z e d Sweet Almond P r o t e i n ) 5.00

5. P r o p y l e n e G l y c o l 3 .50 4. R i t a s i l 190 ( D i m e t h i c o n e C o p o l y o l ) 1 - 0 0

6 . G l y d a n t 0 . 2 0 7 . F rag rance 0 .20

Compounding P rocedure : D i s p e r s e i t e m 2 i n i t e m 1 . Heat i f necessa ry . A l l o w t o c o o l

and add i t e m s 3-7. M i x u n t i l u n i f o r m . R e f . No. 121-181



Soft Set Conditioning Mousse

T h i s c o n d i t i o n i n u mousse f o r m u l a t i o n D r o v i d e s f o r b o t h a s o f t , non tacky h o l d t o a ha f i b e r s . The Sodium Po c o n t r i b u t e s g l o s s and I n gr ed 1-e n t s : P a r t A: Water S tea ramidopropy l PG-d P a r t 8 : I s o p r o p y l A l c o h o l Sod1 um P o l y PG-propyl

( A b i l 5-201) AMP-95 B u t y l E s t e r o f PVM/MA P a r t C :

r s e t and a c o n d i t i o n i n g e f f e c t on t h e h a i r y PG-propyl D ime th i cone T h i o s u l f a t e hydrophob i c i t y t o t h e h a i r .

YO b y Weigh t

82 .20 moniurn c h l o r i d e Dhosphate 3 . 0 0

D ime th i cone T h i o s u l f a t e

copo lymer

1 0 . 0 0

0 . 5 0 0 . 3 0 2 .00

D ime th i cone Copo lyo l (Ab1 1 B 8851) 2 . 0 0 P a r t D: Fragrance, P r e s e r v a t i v e s q . s . F i l l : C o n c e n t r a t e 83 .30 I s o b u t a n e 1 6 . 7 0 P rocedure :

M ix A . Heat t o 65C and c o n t i n u e t o m ix u n t i l homogeneous. Cool t o 40C. S e p a r a t e l y m ix B a t 25C u n t i l homogeneous. Add A t o B w i t h s t i r r i n g . Add C and D, m ix u n t i l homogeneous. Add f r a g r a n c e , c o l o r i n g and p r e s e r v a t i v e as r e q u i r e d . Cool t o 25C. Charge i n t o a e r o s o l c o n t a i n e r . Add p r o o o l l a n t .

Formul a t 1 on PF-0237 suggested by Go1 dschmi d t Cherni c a l Corp.

Styling/Conditioning Mousse

I n g r e d i e n t s : 9/0 b y Wg1gtll Phase A : Water , d e i o n i z e d 74 .15 Mu lgo fen ON-870 0 . 1 0 Gafquat H S - 1 0 0 10 .00 D ime th i cone p o l yo1 0 . 4 0 Phase 8 : Ethano l 1 0 . 0 0 Advantage CP 5 . 0 0 AMP Regu la r 0 . 3 5 Aeroso l F i 11 : C o n c e n t r a t e 90-95 P ropane ibu tane 5-1 0 P rocedure :

P repare Phase A b y d i s s o l v i n g Mu lgo fen i n w a t e r . Add r e m a i n i n g i n g r e d i e n t s i n o r d e r l i s t e d , s t i r t h o r o u g h l y a f t e r each a d d i t i o n . P repare Phase B b y d i s s o l v i n g AMP Regu la r i n e t h a n o l . Then add Advantage C P , m ix u n t i l u n i f o r m . Add per fume w i t h s t i r r i n g . Add Phase B t o Phase A w i t h s t i r r i n g . M i x u n t i l u n i f o r m . Charge a e r o s o l c o n t a i n e r s and p r e s s u r i ze w i t h p r o p e l 1 a n t .

SOURCE: Angus Chemical Corp . : P roduc t Fo rmu la ry Formul a t 1 on PF-0240E suggested by ISP


Strong Advantage Mousse


L u v i q u a t Mono CP D-Panthenol 50P Dow C o r n i n g 193 P o l y e t h e r Hydro1 yzed Wheat P r o t e i n N i paguard DMDMH AMP-95

% b y Weight 81 - 5 0

1 .oo 0 .32 1 . o o 0 .20 0 . 5 0 0 . 9 8

B . Luv imer 100 P 4 . 0 0

C . Cremophor RH 40 L ipopeg 6000 DS F rag rance ( H a i r Monster U800 025)

0 . 3 0 0 . 1 0 0 . 1 0

D. P r o p e l l a n t A46 1 0 . 0 0

P rocedure : Combine a l l i n g r e d i e n t s i n phase A and m i x u n t i l homogeneous. Add phase B t o A and m i x . Add C t o AB and m i x . F i 11 i n t o a p p r o p r i a t e c o n t a i n e r s w i t h p r o p e l 1 a n t ,

F o r m u l a t i o n PF-0396 suggested b y BASF (SG1099/2)

Shape N' Style Volumizing Spritz

I n g r e d i e n t s : A . SD A l c o h o l 40, 190 p r o o f

Dei o n i zed w a t e r L u v i s k o l VA 73 E D-Panthenol USP U v i n u l MC 80

F rag rance AMP-95

% b y We igh t 82 .00

7 . 4 1 4 . 0 0 0 . 5 0 0 . 1 0 0 . 4 9

q . s

8. Luv imer 36 D 5 .50

P rocedure :

each a d d i t i o n . Combine phase A i n g r e d i e n t s i n o r d e r l i s t e d , m i x i n g a f t e r

Add B t o A and m i x .

F o r m u l a t i o n PF-0394 sugges ted by BASF (ND546/1)

SOURCE: Angus Chemical C o . : P roduc t F o r m u l a r y


Vision '98 55% VOC Hairspray

I na r e d i en t s : A . SD A l c o h o l 40, 190 p r o o f

Dei o n i zed w a t e r D-Panthenol USP

Dow C o r n i n g 190 S u r f a c t a n t Luv imer Low VOC

AMP-95

% by Weight 58.00 23.87

0 . 5 0 1 .13 0 .10

16.20

B . F r a g r a n c e 0 .20

Procedure : Combine phase A i n g r e d i e n t s i n t h e w r i t e n o r d e r under m i x i n g . Add B t o A and m i x w e l l .

F o r m u l a t i o n PF-0400 suggested by BASF Corp. (ND6098/1)

Vision '98 55% VOC Hairspray


Dei on i zed w a t e r D-Panthenol USP


AMP-95

% by Weight 58.00 1 4 . 3 5

0 . 5 0 1 .70 0 . 2 0

25.00

0 . Fragrance 0 . 2 5

Procedure : Combine phase A i n g r e d i e n t s i n t h e w r i t t e n o r d e r under m i x i n g . Add B t o A and mix w e l l .




Vision '98 Pump Hairspray - 55% VOC - 6% Solids

I n q r e d i e n t s : Phase A : D e i o n i z e d Water SD A l c o h o l 40, 190 p r o o f D-Panthenol


AMP-95

Phase B: F rag rance (Balsam HF-F-95

Procedure : Combine phase A i n g r e d Add B t o A and m ix we1

Packagi ng :

YO by We iqh t

23 .50 5 8 . 0 0

0 .50 1 . 5 0 0 . 1 0

1 6 . 2 0

14276) 0 . 2 0

e n t s i n t h e w r i t t e n o r d e r .

M i l a n - O v a l B o t t l e (Ca lpac C o n t i n e r C o r p . ) A i r Fo rce I 1 Pump (Emerson C o r p . )


Forever Curls Hair Spray

P a r t i c u l a r l y e f f e c t i v e f o r c u r l r e t e n t i o n , t h i s pump s p r a y keeps c u r l s b e a u t i f u l l y i n p l a c e . By g i v i n g h a i r more body and a d d i n g l u b r i c i t y , H y d r o t r i t i c u m QL enhances t h e h o l d and keeps h a i r f e e l i n g s o f t and smooth. C rovo l A-70 i s used h e r e as a s o l u b i 1 1 z e r and p l a s t i c i z e r .

I ng red?. e n t SA P a r t A :

Amphomer 28-4910

P a r t 8: Dei o n i zed Water Crovo l A-70

SDA-40 A 1 coho1

AMP-95

P a r t C: H y d r o t r i t i c u m QL

63 .50 0 . 7 5

33 .62 1 - 0 0 0 . 1 3

1 . o o

P rocedure :

w i t h v i g o r o u s m i x i n g . Combine i n g r e d i e n t s o f P a r t B w i t h m i x i n g . Add P a r t A t o P a r t B w i t h m i x i n g . When c l e a r , add P a r t C w i t h m i x i n g and f i l l .

Combine i n g r e d i e n t s o f P a r t A by d u s t i n g Amphomer i n t o a l c o h o l

F o r m u l a t i o n PF-0169 suggested by Croda I n c .

S O U R C E : Angus Chemical C o . : P roduc t Fo rmu la ry


Wheat Moisturizing and Styling Gel

T h i c k , s p r e a d a b l e g e l h o l d s , m o i s t u r i z e s , and adds s h i n e and p r o t e c t i v e p r o t e i n s t o h a i r .

~- I n q r e d i e n t _ s l P a r t A : Pol y s o r b a t e - 2 0 PPG-12 PEG-65 l a n o l i n o i l ( I v a r l a n AWS) F rag rance

YO by We igh t

1 . 0 0 2.00 0.20

P a r t B: G l y c e r i n 10.00 Dei o n i zed w a t e r 2 2 . 2 0 H y d r o l y z e d wheat p r o t e i n (Wheat-Tei n NL) 1 . o o P r e s e r v a t i v e , c o l o r q . s .

P a r t C : Carbomer 940 , 2% a q . s o l n . (Carbopol 9 4 0 )

P a r t D: AM P - 9 5

P a r t E : I s o p r o p y l A l c o h o l , 99% PVP/PA copolymer (PVP/VA E-735)

50.00

0.60

1 0 . 0 0 2 . 0 0

P a r t F: E t h y l e s t e r o f h y d r o l y z e d k e r a t i n ( K e r a - t e i n 1000 A S ) 1 . D O

P rocedure :

C . Add D to ABC. M i x t u r e w i l l c l e a r and t h i c k e n . Premix E . Add t o b a t c h . Add F; m i x .

Premix A u n t i l c l e a r . Add B . M ix u n t i l homogeneous. Add t o

Forniul a t i o n PF-0255 sugges ted by Maybrook

Pump Hairspray

_. I n g r e d i ~ e n t s : Gan t rez ES 225 AMP Regu la r F i n s o l v TN E t h a n o l

"/. bYLW&Q!Lt 9 . 0 0 0 * 45 0 . 5 0

9 0 . 0 5

P rocedure :

ue m i x i n g u n t i l u n i f o r m . Add F i n s o l v TN and m i x . D i s s o l v e AMP i n e t h a n o l . Add t h e r e s i n w i t h m i x i n g and c o n t i n -

F o r m u l a t i o n PF-0358 sugges ted by F i n e t e x

SOURCE: Angus Chemical C o . : P roduc t F o r m u l a r y


W/O Hair Sculpturing Cream

I n g r e d i e n t s : Wei a h t % Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e (and ) C e t y l D ime th i cone Copo lyo l (and) Hexyl L a u r a t e (Ab i 1 WE-09) 5 . 0 0

Hydrogenated C a s t o r O i l 0 .50 M i c r o c r y s t a l 1 i ne Wax 0 . 2 0 P e t r o l a t u m 1 . 8 0 M i n e r a l O i l 7 . 5 0 Phenyl T r i m e t h i c o n e ( A b i l AV 20 ) 1 . o o O c t y l S t e a r a t e ( T e g o s o f t O S ) 2 . 0 0 O c t y l P a l m i t a t e ( T e g o s o f t OP) 2 . 0 0 I s o p r o p y l P a l m i t a t e ( T e g o s o f t P ) 2 .00 Phase B: G l y c e r i n 2 . 5 0 P ropy lene G1 y c o l 2 .50 P r e s e r v a t i ves Q . S . Water 70.15 Sodium C h l o r i d e 0 . 8 0 DL-Panthenol 0 . 4 0 H y d r o l y z e d Wheat P r o t e i n 0 .40 PV P 1 . o o Q u a t e r n i urn-80 ( A b i 1 Quat 3272) 0 .25 Phase C : F rag rance Q . S . P rocedure : 1 . Add t h e components o f t h e o i l phase t o g e t h e r . Heat t o m e l t

and d i s p e r s e t h e waxes. When d i s p e r s e d , c o o l t o t e m p e r a t u r e o f 45-50C.

2 . M i x t h e w a t e r and sodium c h l o r i d e . Heat t o 45-5OC. 3 . W i t h s o f t l i g h t n i n ' m i x i n g , s t r e a m t h e w a t e r phase s l o w l y

i n t o t h e o i l phase. 4 . W i t h sweep a g i t a t i o n , c o o l t o 35C. 5 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e s . 6 . Homogenize w i t h a r o t o - s t a t o r homogenizer .

Spray Detangler/Conditioner

I n g r e d i e n t s : Water Te t rasod ium EDTA P r e s e r v a t i v e s P r o p y l e n e G1 y c o l Q u a t e r n i urn-80 ( A b i 1 Quat 3272) PEG-30 G l y c e r y l O l e a t e (Taga t 0) Sodium L a c t a t e (and) Sodium PCA (and) G l y c i n e (and)

F r u c t o s e (and ) Urea (and) N i a c i n a m i d e (and) I n o s i t o l (and) Sodium Benzoate (and) L a c t i c A c i d ( L a c t i l )

D ime th i cone C o p o l y o l ( A b i l B 88183)

Wei Q h t % 96 I 50

0 . 1 0

1 . 6 0 0 .30 0 . 4 5

Q . S .

0.30 0 , 7 5

C i t r i c A c i d (25% s o l u t i o n ) t o pH 4 . 0 F rag rance Q . S . Procedure :

SOURCE: Go1 dschmi d t Chemical Corp . : Suggested F o r m u l a t i o n s Add i n g r e d i e n t s i n o r d e r . A d j u s t pH. F r a g r a n c e .


55% VOC Aerosol Hair Spray

I n g r e d i e n t s : SD 40 B A l c o h o l Water

Omni rez-2000 Ammoni um H y d r o x i de MEA B o r a t e and MIPA B o r a t e

AMP-95

% by Weight 1 4 . 9 0 38 - 9 7

0 .33 10 .00

0 .30 0.40

D i m e t h y l E t h e r 35 .00

Va l v e : Seaqui s t : ST-74 Stem: 0 .018" Body : c a p i 11 a r y V . Tap: 0 .01 5" I D T u b i n g : 0 .050" A c t u a t o r : ST-150 M i s t y O r i f i c e : 0 .023"

F o r m u l a t i o n PF-0383 sugges ted b y I S P (10263-11)

Acudyne 255 55% VOC HFC-152a Aerosol Hair Spray

I n s r e d i e n t s : A . Water

E t h a n o l

DC 190 F l u i d AMP-95

% b y Weight 1 . 8 0

55 .00 0 . 5 6 0 . 1 0

B . Acudyne 255 (41%) 12.50

C . Dymel HFC-152a 12.50

P rocedure : P repare phase A . Then add phase B w i t h s t i r r i n g , M i x u n t i l

s o l u t i o n i s s l i g h t l y t u r b i d b u t a c t i v e i n g r e d i e n t s a r e d i s p e r s e d . Add Dhase C .

P h y s i c a l C h a r a c t e r i s t i c s : C loud p o i n t : <-22F


SOURCE: Angus Chemical Co.: P r o d u c t F o r m u l a r y


80% VOC Aerosol Hair Spray

I n q r e d i e n t s : SD 40 B A l c o h o l Water

Omni rez-2000 D ime th i cone C o p o l y o l Lauramide DEA Ammonium H y d r o x i d e MEA B o r a t e and MIPA B o r a t e P ropane / I sobu tane b l e n d (A-70)

AMP-95

% bv Weigh t 57,00 11 .13

0 . 3 7 16.00

0 . 1 0 0 . 1 0 0 .10 0 .20

15 .00

V a l v e : P r e c i s i o n Aquasol Stem: 2 x 0 .20 " Body : .023" V.Tap: N/A-chamber 2 X 0 .10 " I D T u b i n g : 0 .060" A c t u a t o r : P r e c i s i on O r i f i c e : 0.016" C02

F o r m u l a t i o n PF-0379 sugges ted b y ISP (10250-18-1)

80% VOC Single Phase Hydrocarbon Aerosol Hair Spray

Ingr ed i en t s : SD 40 B A l c o h o l Water

Omni rez-2000 D ime th i cone C o p o l y o l Laurami de DEA Ammoni um H y d r o x i de MEA B o r a t e and MIPA B o r a t e D i m e t h y l E t h e r

AMP-95

Val ve : Seaqui s t ST-74 Stem: 0 .01 8" Body : c a p i l l a r y ( u n d e r development) V.Tap: 0 . 0 1 3" I D T u b i n g : 0 .030" A c t u a t o r : ST-150 M i s t y O r i f i c e : 0 .020"

F o r m u l a t i o n PF-0380 sugges ted by I S P ( 1 0250-1 8-2)

SOURCE: Angus Chemical C o . : P r o d u c t F o r m u l a r y

% by Weight 37 .00 11 - 1 3

0 . 3 7 16.00 0 .10 0 . 1 0 0 . 1 0 0 . 2 0

3 5 . 0 0


55% VOC Innovative Product Formulation

I n g r e d i e n t s : L o v o c r y l 47

Monamid 716 V a r i o n CADG LS DC 556 P u r c e l l i n O i 1 D e i o n i z e d Water E t h a n o l , SDA-40 F rag rance n-Butane D i m e t h y l e t h e r

AMP-95

I b y Weight 1 0 . 0 0

1 . 7 3 0 .15 0 .10 0 . 1 0 0 . 1 5 7 .77

5 0 . 0 0

12 .00 18 .00

q . s .

P rocedure :

a g i t a t i o n , s l o w l y s i f t i n L o v o c r y l 47. When s o l u t i o n i s comp le te , add remai n i ng i n g r e d i e n t s . M i x u n t i 1 homogeneous. F i 1 t e r and f i l l . Charge cans w i t h p r o p e l l a n t .

V a l v e :

D i s s o l v e AMP-95 i n e t h a n o l and w a t e r . Whi l e mai n t a i n i ng good

S e a q u i s t V a l v e : NS-34 Stem O r i f i c e : 0 . 0 1 3 ” D i p Tube: 0 . 0 4 0 ” Body : Capi 11 a r y Vapor Tap: 0 . 0 1 3 ” A c t u a t o r : Exce l 200 0 . 0 1 3 ” M i s t y

F o r m u l a t i o n PF-0352 sugges ted by N a t i o n a l S t a r c h & Chemical Corp. (7879-1221)

Aerosol Finishing Spray


D-Panthenol 50P AMP Regu la r F rag rance

% by We igh t 55.16

1 . o o 0 . 7 4 0 .10

B. Luv imer 1OOP 3 .00

C . HFC 152a 40.00

Yo voc: 55%

Procedure : Combine phase A . S p r i n k l e B i n t o A and m ix w e l l . F i 11 i n t o a p p r o p r i a t e c o n t a i n e r s w i t h p r o p e l l a n t .

F o r m u l a t i o n PF-0399 sugges ted by BASF Corp . (ND538/1)

SOURCE: Angus Chemical Corp. : P roduc t F o r m u l a r y


80% VOC Innovative Aerosol Hair Spray

I n n r e d i e n t s : SD 40 B A l c o h o l

Omni rez-2000 D ime th i cone C o p o l y o l Laurami de DEA 152A HFC p r o p e l l a n t D i m e t h y l E t h e r

V a l v e :

AMP-95

Seaqui s t : ST-74 Stem: 0 . 0 1 0 " Body : c a p i 11 a r y VaporTap : 0 . 0 1 0" I D Tub ing : 0 .030" A c t u a t o r : ST-150 M i s t y O r i f i c e : 0 . 0 2 0 "

% b y Weight 44.36

0 . 4 4 20.00

0 . 1 0 0 . 1 0

1 5 . 0 0 20.00

F o r m u l a t i o n PF-0381 sugges ted by ISP (10250-18-8)

55% VOC Innovative Aerosol Hair Spray

I n n r e d i e n t s : SD 40 B A l c o h o l Water

Omni rez-2000 D i me th i cone Copol yo1 Lau r ami de DEA Ammoni um H y d r o x i de MEA B o r a t e and M I P A B o r a t e 152 A HFC P r o p e l l a n t D i m e t h y l E t h e r

AMP-95

% b v We igh t 44 .36

4 . 0 6 0 * 44

20 .00 0 .10 0 . 1 0 0 .10 0 . 2 0

3 0 . 0 0 5 .00

Val ve : Seaqui s t : ST-74 Stem: 0 . 0 1 0 " Body : c a p i 11 a r y VaporTap : 0 . 0 1 0 " I D T u b i n g : 0.030" A c t u a t o r : ST-150 M i s t y O r i f i c e : 0 .020"

F o r m u l a t i o n PF-0382 suggested by ISP (10250-18-9)

SOURCE: Angus Chemical Co. : Produc t F o r m u l a r y

Section VIILotions

208

Lotions 209

AHA Moisturizing Lotion

D . I. Water % by Weight

Q .S . t o 100.0 G1 y c e r i n 5 .00 M e t h y l Paraben 0 . 1 5 Ammonyx GA-70 PG 2 .85 Neobee M-5 Cosmet ic 1 5 . 0 Kessco GMS Pure 2 . 5 Kessco IPM 2 . 0 Kessco C e t y l A l c o h o l 2 . 0 S t e a r y l A l c o h o l 1 . 5 P r o p y l Paraben 0 .01

P r e s e r v a t i ve, C o l o r , F rag rance Q . S . M i x i ng Procedure :

I n t o a s u i t a b l e v e s s e l equ ipped w i t h h e a t i n g , c o o l i n g , and a g i t a t i o n , p r e p a r e t h e wa te r phase by a d d i n g D . I . Water, G l y c e r i n , Me thy l Paraben, and Ammonyx GA-70 PG. S t a r t h e a t i n g t o 70-75C. I n t o a s e p a r a t e v e s s e l , p r e p a r e t h e o i l phase b y a d d i n g t o g e t h e r Neobee M-5 Cosmet ic , Kessco GMS Pure, Kessco IPM, Kessco C e t y l A l c o h o l , S t e a r y l A l c o h o l , and P r o p y l Paraben. Heat t o 73-77C. Add t h e o i l phase t o t h e w a t e r phase w i t h good a g i t a t i o n . E m u l s i f y f o r 20-25 m i n u t e s a t 80-82C. W i t h m i x i n g , s t a r t c o o l i n g t o room t e m p e r a t u r e . S l o w l y add G l y c o l i c A c i d (70%) a t 30C. M i x we1 1 . Add P r e s e r v a t i v e , C o l o r , and F r a g r a n c e . A d j u s t pH t o 3 . 0 - 3 . 5 i f n e c e s s a r y .

G l y c o l i c A c i d (70%) 7 . 0 - 1 0 . 0

AHA Moisturizing Lotion

D. I. Water % by Weight

Q . S . t o 100 .0 M e t h y l Paraben 0 . 1 5 G l y c e r i n 1 . 5 Kessco GMS S.E. /A.S. 2 . 0 Kessco GMS Pure 3 . 5 Kessco C e t y l A1 coho1 1 . 5 Neobee M-5 Cosmet ic 5 . 0 Kessco ICs 1 . 5 G l y c o l i c A c i d (70%) 7 . 2 P r e s e r v a t i ve, C o l o r , F rag rance Q . S . M i x i ng Procedure :

I n t o a s u i t a b l e v e s s e l equ ipped w i t h h e a t i n g , c o o l i n g , and a g i t a t i o n , p r e p a r e t h e w a t e r phase b y a d d i n g D . I . Water , M e t h y l Paraben, and G l y c e r i n . S t a r t m i x i n g and h e a t i n g t o 75-8OC. I n t o a s e p a r a t e v e s s e l p r e p a r e t h e o i l phase b y a d d i n g t o g e t h e r Kessco GMS S .E . /A .S . , Kessco GMS Pure, Kessco C e t y l A l c o h o l , Neobee M-5 Cosmet ic , and Kessco ICs. S t a r t h e a t i n g t o 77-82C. Add t h e o i l phase t o t h e w a t e r phase w i t h good a g i t a t i o n . E m u l s i f y f o r 20-25 m i n u t e s a t 80-82C. W i t h m i x i n g , s t a r t c o o l i n g t o room t e m p e r a t u r e . S l o w l y add G l y c o l i c A c i d (70%) a t 30C. M ix w e l l . Add P r e s e r v a t i v e , C o l o r , and F r a g r a n c e . A d j u s t pH t o 3 . 5 - 4 . 0 , i f necessa ry .


210 Cosinetic and Toiletry Formulations

Anti-Aging Day LotionT h i s s o f t , a n t i - a g i n g l o t i o n l e a v e s a n o n - o i l y , g e n t l e a f t e r

f e e l on t h e s k i n . P e n t a v i t i n improves t h e w a t e r r e t e n t i o n and Immucel l makes s k i n smoother and more d e l i c a t e . Item I n g r e d i e n t s : Wei g h t %

1 A ) G l u c a t e DO 2 . 0 0 2 G l u c a t e SS 1 . 5 0 3 Glucam E 20 D i s t e a r a t e 1 . 5 0 4 Promulgen D 1 .50 5 I s o p r o p y l P a l m i t a t e 3 . 0 0 6 Sesame O i l 1 . o o 7 B) D e i o n i z e d Water 77 .30 8 Phenoni p 0 .30 9 I m i d a z o l i d i n y l Urea 0 . 2 0

10 Glucam E 10 3 .00 11 Carbopol 1342 0 . 2 0 12 P e n t a v i t i n 5 .00 13 Immucel l 3 . 0 0 14 C ) T r i e t h a n o l a m i n e 0 . 2 0 15 D ) Fragrance-Courage 0/243101 0 . 3 0

P rocedure : Heat t h e i n g r e d i e n t s o f f a t t y phase A) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase 8 ) t o 75C. Under s t i r r i n g add phase B) t o phase A ) . W i t h phase C a d j u s t t h e p H t o 6 . 0 , homogenize and c o o l t o 30C. Then add phase D) and s t i r c o l d .

SOURCE: Pentapharm L t d . : A p p l i c a t i o n No. C 014.B/09.95

Cationic Lotion with Incroquat Behenyl TMS Due t o t h e s u p e r i o r e m u l s i f y i n g and c o n d i t i o n i ng p r o p e r t i e s

o f I n c r o q u a t Behenyl TMS, o n l y a few b a s i c i n g r e d i e n t s a r e needed t o f o r m t h i s s t a b l e and e l e g a n t l o t i o n . T h i s l o t i o n a c q u i r e s i t s s o f t , powdery a f t e r f e e l f r o m t h e c o n d i t i o n i n g e f f e c t s o f t h e Behenyl q u a t . I f d e s i r e d , e m o l l i e n t s , p r o t e i n s o r o t h e r such m a t e r i a l s can e a s i l y be added t o t h e f o r m u l a t o enhance t h e appeal o f t h e f i n a l p r o d u c t . I n s r e d i e n t s : Wei e h t % P a r t A: Dei o n i zed Water 83 .0 G l y c e r i n 5 . 0 P a r t B: M i n e r a l O i l (7Ossu) 5 . 0 P e t r o l a t u m 2 . 0 I n c r o q u a t Behenyl TMS (Behen t r imon i um M e t h o s u l f a t e

(and ) C e t e a r y l A l c o h o l ) 4 . 0 P a r t C : P r o p y l e n e G l y c o l (and) D i azo1 i d i n y l Urea (and) M e t h y l

P rocedure :

70-75C. Combine i n g r e d i e n t s o f P a r t B w i t h m i x i n g and h e a t t o 70-75C. Add P a r t B t o P a r t A w i t h m i x i n g and c o o l t o 40C. Add P a r t C w i t h m i x i n g and c o o l t o d e s i r e d f i l l t e m p e r a t u r e . SOURCE: Croda I n c . : F o r m u l a t i o n SC-267

Paraben (and ) P r o p y l Paraben 1 . o

Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o

Lotions 211

Body Lotion for Sensitive Skin

T h i s p u r e w h i t e and e l e g a n t l o t i o n , w i t h a p l e a s a n t end f e e l , c o n t a i ns D i smut i n-BT and P h y t a l u r o n a t e . T h i s combi n a t i o n r e g e n e r a t e s and p r o t e c t s s e n s i t i v e o r d r y s k i n .

Item I n s r e d i e n t s __ W e i a t ? ? 1 A) Cremophor A6 2 Cremophor A25 3 L u v i t o l EHO 4 P a r a f f i n O i l 5 C e t y l A l c o h o l 6 C u t i n a GMS

7 B) D e i o n i z e d Water 8 Phenoni p 9 I m i d a z o l i d i n y l Urea

10 P r o p y l ene G1 y c o l 11 P h y t a l u r o n a t e

12 C) D i smut i n-BT

Procedure : Heat t h e i n g r e d i e n t s o f f a t t y phase A ) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase B) t o 75C. Under s t i r r i n g add phase B ) t o phase A ) , c o o l t o 50C, homogenize and c o o l t o 30C. Then add phase C ) and s t i r c o l d .

SOURCE: Pentapharm L t d , : A p p l i c a t i o n N o . C 0 0 4 . D / 0 1 . 9 6

1 . o o 1 - 0 0 7 . 0 0 8 . 0 0 1 . o o 2 . 5 0

7 1 . 7 0 0 . 3 0 0 . 2 0 2 . 0 0 5 . 0 0

0 . 3 0

Cleansing Lotion

I n g r e d i e e = Wei s h t % A) M i g l y o l 829 ( C a p r y l i c / C a p r i c / S u c c i n i c T r i g l y c e r i d e ) 12 .00

I m w i t o r 370 ( G l y c e r y l S t e a r a t e C i t r a t e ) 5 .00 I m w i t o r 928 ( G l y c e r y l Cocoate) 5 . 0 0

B ) Hyg rop lex HHG (Hexy lene G l y c o l ( a n d ) G lucose ( a n d ) F r u c t o s e ( a n d ) Sucrose ( a n d ) Urea ( a n d ) D e x t r i n ( a n d ) A 1 a n i ne (and) G1 u tami c A c i d (and) A s p a r t i c A c i d ( a n d ) Hexy l N i c o t i n a t e ) 5 . 0 0

K e l t r o l F (Xanthan Gum) 0 . 8 0 P r e s e r v a t i v e q . s . Water up t o . 1 0 0 . 0 0

F rag rance F l e u r B lanches 0 . 3 0

P r e p a r a t i o n : ( A ) i s hea ted t o 75 degrees C . , (B) i s mixed homogeneously,

b r o u g h t t o t h e same t e m p e r a t u r e , and e m u l s i f i e d i n t o ( A ) . Perfume i s added a t about 35 degrees C .

SOURCE: H u l s Amer ica I n c . : F o r m u l a t i o n 1 .3U


Botanical Facial Moisturizing Lotion

% by Weight D. I , Water Q . S . t o 100.0 Carbopol 934 0.15 Cyc l ometh i cone 0 . 2 5 G l y c e r i n 3 .50 M e t h y l Paraben 0 . 1 5 Neobee M-5 Cosmet ic 2 . 0 0 Drewpol 3-1 -0 1 .50 P e t r o l a t u m 1 .50 Kessco C e t y l A l c o h o l 1 .oo S t e a r i c A c i d T . P . 2 .50 P r o p y l Paraben 0 .10 DMDM H y d a n t o i n 0 .25 T e t r a s o d i u m EDTA 0 .10 T r i e t h a n o l ami ne 1.65 Avocado E x t r a c t 0 . 0 1

M i x i ng Procedure : Combine water and Carbopol 934 w i t h good m i x i n g , a g i t a t e

u n t i l a t h i n s o l u t i o n f r e e o f lumps i s o b t a i n e d . Add n e x t 3 i n g r e d i e n t s and m i x u n t i l c o m p l e t e l y d i s s o l v e d . Heat t o 165F. Prepare t h e o i l phase by a d d i n g t o g e t h e r Neobee M-5 Cosmet ic , Drewpol 3-1-0, P e t r o l a t u m , Kessco C e t y l A l c o h o l , S t e a r i c A c i d T . P . , and P r o p y l Paraben. Heat t o 165-17OF. Add t h e o i l phase t o t h e w a t e r phase ( b o t h a t 165-17OF) w i t h good a g i t a t i o n . E m u l s i f y f o r 20 m i n u t e s and t h e n b e g i n t o c o o l w i t h s low a g i t a - t i o n . A t 11OF, add DMDM H y d a n t o i n , T e t r a s o d i u m EDTA, T r i e t h a n o l - amine, and Avocado E x t r a c t . C o n t i n u e t o cool t o 9OF. A t room t e m p e r a t u r e , a d j u s t pH t o 7 .0 -8 .0 i f n e c e s s a r y . Check v i s c o s i t y .

SOURCE: Stepan C o . : Suggested F o r m u l a t i o n

Lotions 213

Cationic Lotion

Formula: A : Dei o n i zed Water G1 y c e r i ne Pol y q u a t e r n i urn 10 V a r i s o f t TA-100 B : Adol 52 Adol 62 F i n s o l v TN W h i t e P r o t o p e t 1s ( W i t c o ) C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) S t a r f o l OS DC F l u i d 345 DC F l u i d 593 Varon i c 63-E-20 V a r o n i c L I - 6 7 C : P r e s e r v a t i v e

% by We igh t

77.25 5 . 0 0 0 . 7 5 1 .50

1 . o o 3 . 0 0 2 . 0 0 1 .50 1 . 5 0 1 .50 1 . o o 1 .50 1 . o o 1 .50

q . s .

P rocedure : M i x w a t e r , g l y c e r i n e and P o l y q u a t e r n i u m 10 u n t i l even.

S p r i n k l e i n V a r i s o f t TA-100 w i t h m i x i n g . C o n t i n u e m i x i n g and h e a t phase A t o 75-8OC. Heat phase B t o 75-8OC. Add phase A t o phase B . Cool t o 30C w i t h m i x i n g . Add p r e s e r v a t i v e .

Body Lotion: Water in Oil

Formula: O i l Phase: Abi 1-We 09 Abi l -Wax 9800 I s o p r o p y l M y r i s t a t e C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) PCL L i q u i d (Dragoco) W h i t e Fonol i ne P e t r o l a t u m ( W i t c o ) Water Phase: Water G1 y c e r o l Sodium C h l o r i d e Perfume, P r e s e r v a t i v e


% b y Weight

5 . 0 3 . 0 6 . 0 5 .0 4 . 0 3 . 0

71 . 2 2 . 0 0 . 8 q . s .


Cromoist CM-Glucan Lotion with Crodafos CES

T h i s l o t i o n f e a t u r e s Cromo is t CM Glucan and Croda fos CES - two h i g h a c t i v i t y i n g r e d i e n t s t h a t r e f l e c t t o d a y ' s demands f o r t r u l y f u n c t i o n a l p r o d u c t s . C romo is t CM G lucan works b y s t i m u - l a t i n g t h e s k i n ' s r e s i s t a n c e t o o x i d a t i v e s t r e s s and improve i t s l e v e l o f s k i n own f u n c t i o n . C roda fos CES works b y e x h i b i t i n g shear t h i n n i n g , p r o d u c i n g a system t h a t p r o v i d e s b e t t e r o i l d e p o s i t i o n , f a s t e r d e l i v e r y o f a c t i v e i n g r e d i e n t s , and enhanced a p p l i c a t i o n p r o p e r t i e s . The l o t i o n i t s e l f has a g l o s s y w h i t e t e x t u r e , a l u b r i c i o u s f e e l and q u i c k r u b - i n .

I n n r e d i e n t s : Wei q h t % P a r t A : Croda fos CES ( C e t e a r y l A l c o h o l (and) C e t e a r y l Phosphate) 4 . 0 Crodamol GTCC ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 5 . 0 C rodaco l C-70 ( C e t y l A l c o h o l ) 0 . 5 Vo lpo S-2 ( S t e a r e t h - 2 ) 0 . 1 Vo lpo S-10 ( S t e a r e t h - 1 0 ) 0 . 5

P a r t B : T r i e t h a n o l ami ne (98%) Dei o n i zed Water

0 . 2 8 7 . 7

P a r t C : C romo is t CM-Glucan (Sodium Carboxymethy l 8-Glucan) 1 . o P r o p y l e n e G l y c o l (and ) Diazo1 i d i n y l Urea (and) M e t h y l

Paraben (and ) P r o p y l Paraben 1 . o

pH=5.0+-0.5 V i s c o s i t y = 5 , 7 0 0 cps+-10% (RVT S p i n d l e TC, 10 rpm I3 25C)

P rocedure :

Combine i n g r e d i e n t s o f P a r t B w i t h m i x i n g and h e a t t o 70C. Add P a r t A t o P a r t B w i t h m i x i n g . Cool t o 45C w i t h m i x i n g . Add i n g r e d i e n t s o f P a r t C s e p a r a t e l y . C o n t i n u e m i x i n g t o d e s i r e d f i l l t e m p e r a t u r e .

SOURCE: Croda I n c . : Suggested F o r m u l a t i o n SC-264

Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 70C.

Lotions 215

Dihydroxyacetone LotionI n g r e d i e n t s : Weight% Phase A : C e t y l D ime th i cone C o p o l y o l ( A b i l EM-90) 1 . 5 P o l y g l y c e r y l - 4 I s o s t e a r a t e (and) C e t y l D ime th i cone

Copo lyo l (and ) Hexyl L a u r a t e ( A b i l WE-09) 1 . o O c t y l S t e a r a t e ( T e g o s o f t OS) 4 . 0 Isohexadecane 7 . 0 Hydrogenated C a s t o r O i l 0 . 4 Beeswax 0 . 4 Phase 6 : Cyc l ometh i cone 6 . 0 Phase C: Water 72 .9 P r o p y l e n e G1 y c o l 2 . 0 Sodium C h l o r i d e 0 . 8 D ihyd roxyace tone 4 . 0 P r e s e r v a t i v e s Q . S . C o l o r Q . S . Phase D : F rag rance Q . S . P rocedure : 1 . B l e n d t h e components o f Phase A . Heat t o 85C i n a c l o s e d

2 . Cool t o 40C. 3 . Add t h e Cyc lometh i cone . M i x . 4 . Heat Phase C components t o 40C w h i l e m i x i n g . 5 . Add C t o A/B s l o w l y w i t h s l o w a g i t a t i o n u n t i l B i s f u l l y

6 . Add f r a g r a n c e w i t h s low a g i t a t i o n . 7 . Homogenize.

k e t t l e w h i l e m i x i n g u n t i l a l l waxes a r e d i s p e r s e d .

d i spe rsed .

Isolan DO Lotion O/W Cold Process

I n g r e d i e n t s : Wei g h t % Phase A :

O c t y l S t e a r a t e ( T e g o s o f t O S ) 5 . 0 O c t y l P a l m i t a t e ( T e g o s o f t OP) 5 . 0 I s o p r o p y l P a l m i t a t e ( T e g o s o f t P) 5 . 0 Phase B : Water 7 9 . 0 G l y c e r i n 3 . 0 P r e s e r v a t i ve Q . S . Phase C : Carbomer 1382 0 . 2 I s o p r o p y l P a l m i t a t e ( T e g o s o f t P ) 0 . 8 Phase D: NaOH (10% S o l u t i o n ) a d j u s t pH t o 5 . 5 - 6 . 5 Q . S . P rocedure : 1 . M i x t h e i n g r e d i e n t s o f Phase A and B s e p a r a t e l y . Add B t o A

w i t h o u t m i x i n g . 2 . Homogenize A/B, o i l p a r t i c l e s i z e ( 0 . 1 urn. 3 . D i s p e r s e t h e Carbomer 1382 i n t o t h e o i l / e s t e r and add t o A/B.

S t i r i n t e n s i v e l y f o r 30 m i n u t e s . 4 . Add D and s t i r f o r f i v e a d d i t i o n a l m i n u t e s . Temperature o f t h e phases A, B, C , D: a r e 20-25C

M e t h y l g l ucose D i o l e a t e ( I s o l an DO) 2 . 0

SOURCE: Go ldschmid t Chemical C o r p . : Suggested F o r m u l a t i o n s


Emollient Lotion

A s y n e r g i s t i c c o m b i n a t i o n o f Veegum and Carbomer i s used t o t h i c k e n and s t a b i l i z e t h i s e l e g a n t c o s m e t i c l o t i o n . The e m o l l - i e n t s i n t h i s f o r m u l a were s e l e c t e d f o r t h e i r m o i s t u r i z i n g p r o p e r t i e s . The e m u l s i f i c a t i o n f o r t h e f o r m u l a i s p r o v i d e d by t h e g l y c e r y l monosteara te and t h e t r i e t h a n o l a m i n e s t e a r a t e ( f o r m e d i n s i t u ) .

I n n r e d i e n t : A : Veegum, Magnesium Aluminum S i l i c a t e

Dei o n i zed Water Carbomer 934 (Carbopo l 934)

8: T r i e t h a n o l a m i n e G l y c e r i n e

W t .%* 0 . 5 0

8 3 . 6 6 0 . 1 0

0 . 1 0 4.00

C: M i n e r a l O i l 4.00 P e t r o l a t u m 0.44 S t e a r i c A c i d XXX 1 . 8 0 C e t y l A l c o h o l 0.90 G l y c e r y l S t e a r a t e SE (Kessco GMS-SE) 1 . 6 0 C e t y l A c e t a t e ( a n d ) A c e t y l a t e d L a n o l i n A l c o h o l

2 . 2 0 D imeth icone, 350 c s 0 . 7 0

( Acet u 1 an )

D: P r e s e r v a t i v e q . s .

Procedure : Add t h e Veegum t o t h e w a t e r s l o w l y , a g i t a t i n g a t maximum

a v a i l a b l e shear u n t i l smooth. Add t h e r e m a i n i n g P a r t A i n g r e d i e n t and mix u n t i l t h o r o u g h l y d i s p e r s e d . Add t h e P a r t B i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g each u n t i l u n i f o r m . Heat P a r t s A+B t o 70-7%. M i x and h e a t t h e P a r t C i n g r e d i e n t s t o 75-8OC. Add P a r t C t o P a r t s A+0 w i t h h i g h speed a g i t a t i o n . B e g i n c o o l i n g w h i l e m i x i n g s l o w l y and add P a r t D a t 40C o r l o w e r .


SOURCE: R . T , V a n d e r b i l t Co., I n c , : Veegum F o r m u l a t i o n No. 378

Lotions 217

Ethnic Hand & Body Lotion % by Weight

D , I. Water Q . S . t o 1 0 0 . 0 T e t r a s o d i um EDTA 0 . 1 0 Me thy l Paraben 0 . 1 5 ProDvl Paraben 0 . 1 0 Carbopol 934 T r i e t h a n o l am G1 y c e t i n Neobee M-20 S t e a r i c A c i d Wecobee S Kessco C e t y l Kessco GMS P

ne (88%)

Tech.

A1 c o h o l r e

0 . 1 5 1 .80 5 . 0 0 6.50 3 . 0 0 0 . 5 0 0 .46 0 . 1 0

S i l i c o n e DC-200 (200 cps ) 0 . 1 0 DMDM H y d a n t o i n 0 . 2 5 M i x i n g P rocedure :

I n t o a s u i t a b l e c o n t a i n e r equ ipped w i t h m i x i n g , h e a t i n g , and c o o l i ng capabi 1 i t i es, add t h e D . I . Water , T e t r a s o d i um EDTA, Me thy l Paraben, P r o p y l Paraben, Carbopol 934, and G l y c e r i n . M i x w i t h v e r y good a g i t a t i o n u n t i l t h e r e a r e no lumps. Add T r i e t h a n - o lam ine ( 8 8 % ) . S t a r t h e a t i n g t o 165-17OF. I n a s e p a r a t e c o n t - a i n e r , combine Neobee M-20, S t e a r i c a c i d , Wecobee S, Kessco C e t y l A l c o h o l , and Kessco GMS Pure . Heat t o 170-175F. Add t o w a t e r phase and e m u l s i f y f o r 20-25 m i n u t e s . S t a r t c o o l i n g . A t lOOF, add S i l i c o n e DC-200. A t 9OF, add DMDM H y d a n t o i n . A t room t e m p e r a t u r e , a d j u s t p H t o 7 . 8 - 8 . 0 i f necessa ry . Check v i s c o s i t y .

Ethnic Hand & Body Lotion % by weight^

D . I . Water Q . S T t o 1 0 0 . 0 Me thy l Paraben 0 . 1 5 Neobee M - 5 1 0 . 0 0 Kessco GMS-Pure 3 .00 Kessco C e t y l A 1 c o h o l 2 * 00 Wecobee SS 2 . 5 0 B r i j 78 0 .40 P r o p y l Paraben 0.05 S i l i c o n e DC-200 ( 3 5 0 c p s ) 1 . o o DMDM H y d a n t o i n 0 . 2 5 M i x i ng P rocedure :

I n t o a s u i t a b l e c o n t a i n e r equ ipped w i t h m i x i n g , h e a t i n g , and c o o l i ng capab i 1 i t i es, p r e p a r e wa te r phase by a d d i n g D . I. Water and M e t h y l Paraben. S t a r t m i x i n g and h e a t t o 160-165F. I n a s e p a r a t e c o n t a i n e r , p r e p a r e o i l phase by a d d i n g Neobee M-5, Kessco GMS-Pure, Kessco C e t y l A l c o h o l , Wecobee SS, B r i j 78, and P r o p y l Paraben. Heat t o 165-17OF. I n c r e a s e a g i t a t i o n o f wa te r phase and s l o w l y add o i l phase. E m u l s i f y f o r 20-25 m i n u t e s a t 165-17OF. S t a r t c o o l i n g , A t lOOF, add S i l i c o n e DC-200 and DMDM H y d a n t o i n . A t room t e m p e r a t u r e , a d j u s t pH t o 7 . 8 - 8 . 0 i f neces- s a r y . Check v i s c o s i t y ,

SOURCE: Stepan C o . : Suggested F o r m u l a t i o n s


Hand and Body Lotion

_ ~ _ _ _ _ Formula : ? b y Weigh t A: Carbopo l 934 0 . 1 5 De ion i zed Water 83 .45 B : Me thy lpa raben 0 . 2 0 P ropy lpa raben 0 . 1 0 P r o p y l ene G1 y c o l 0 . 8 0 D i s o d i um EDTA 0 . 1 0 G 1 y c e r i n 5 . 0 0 C: C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) 4 .00 S t e a r i c A c i d 2 . 0 0 G l y c o l S t e a r a t e 1 . 5 0 C e t y l A c e t a t e / A c e t y l a t e d L a n o l i n A l c o h o l 0 . 5 0 G l y c e r y l S t e a r a t e 0 .50 D i meth icone 0 . 5 0 C e t y l A1 coho1 0 . 2 0 T r i e t h a n o l ami ne 1 . o o F rag rance c l . s Procedure :

h e a t t o 75C. Comb-ine B i n g r e d i e n t s , add t o A under modera te a g i t a t i o n . S e p a r a t e l y combine C i n g r e d i e n t s , hea t t o 75C. S l o w l y combine C t o A-B w i t h good a g i t a t i o n . Add TEA c o o l i n g w i t h slow a g i t a t i o n t o 45C. Add f r a g r a n c e , c o o l t o room temp.

P a r t A -D ispe rse Carbopol i n t o w a t e r under r a p i d a g i t a t i o n ,

Cocoa Butter Hand and Body Lotion

Formula : "/.&!L _w_e_.iMLt O i l Phase: G l y c e r y l S t e a r a t e 1 . 2 8 H y d r o f o l A c i d 1655CG 2 . 0 3 C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) 7 . 5 0 Ado1 52NF 1 . 0 7 L a n o l i n 0 . 5 3 I s o p r o p y l Pa l m i t a t e 0 . 5 7 Cocoa B u t t e r 0 . 5 0 Water Phase: Va ron i c L I -48 1 . 6 0 T r i e t h a n o l a m i n e 0 . 8 9 P ropy lene G1 y c o l 1 . 6 0 D e i o n i z e d Water 82 .43 P r e s e r v a t i v e s : Me thy l Paraberi 0 . 1 0 P r o p y l Paraben 0 . 0 5 Procedure:

Prepare Water and O i l Phases s e p a r a t e l y . Warm each phase t o 80C. B l e n d O i 1 Phase i n t o Water Phase w i t h r a p i d b u t smooth a g i t a t i o n , Cool system w i t h smooth a g i t a t i o n t o 40C. B lend i n P r e s e r v a t i v e s . C o n t i n u e a g i t a t i o n t o 35C and add dye and per fume SOURCE: Wi tco C o r p . : Suggested F o r m u l a t i o n s

Lotions 219


For mu 1 a : A : Veegum P r o Water G l y c e r i n 8: E r v o l M i n e r a l O i l ( W i t c o ) W h i t e P r o t o p e t 1s P e t r o l a t u m ( W i t c o ) A r l a c e l 165 Synchrowax A w l - C C : A1 1 a n t o i n P r e s e r v a t i ve

% by We igh t

2 .00 70.75

6 . 0 0

1 0 . 0 0 4.00 5 . 0 0 1 .25

1 . 0 0 q . s .

Procedure :

i n g a t maximum s h e a r . M i x u n t i l smooth. Add g l y c e r i n e and m i x u n t i l u n i f o r m . Heat B t o 75-8OC. Add B t o A and m i x u n t i l c o o l I Add C and m i x u n t i l u n i f o r m . Veegum P r o e f f e c t i v e l y t h i c k e n s and s t a b i l i z e s t h e e m u l s i o n even a t e l e v a t e d t e m p e r a t u r e s .

Heat t h e wa te r t o 70-75C, t h e n s l o w l y add Veegum w h i l e a g i t a t -

Depilatory Lotion

Formula: A : Water Avenel S-150 (PPG-Mazer) Cal c i um H y d r o x i de Me1 ami ne L i t h i um H y d r o x i de B: Macol 124 ( PPG-Mazer) C a r n a t i o n M i n e r a l O i l ( W i t c o ) C : Water T h i o g l y c o l i c A c i d ( W i t c o )

% by Weight

5 7 . 1 3 . 0 6 .5 3 . 0 2 . 8

6 . 0 7 . 0

1 0 . 0 4 . 6

P rocedure : B l e n d A i n g r e d i e n t s . Heat A t o 6 5 C . Premix B i n g r e d i e n t s ,

h e a t i n g t o 65C. Add B t o A w i t h h i g h shear a g i t a t i o n . W i t h sweep a g i t a t i o n c o o l b a t c h t o 30C. Premix C a t o r be low room temp. and add s l o w l y t o main b a t c h . M a i n t a i n temp. a t 35C d u r i n g t h e a d d i t i o n .

SOURCE: W i t c o Corp , : Suggested F o r m u l a t i o n s


Hand and Body Lotion A Veegum and C e l l u l o s e Gum c o m b i n a t i o n i s used e f f e c t i v e l y

i n t h i s f o r m u l a t o p r o v i d e e m u l s i o n s t a b i l i z a t i o n and v i s c o s i t y c o n t r o l , The c o m b i n a t i o n o f l i q u i d e m o l l i e n t s p r o v i d e s smooth r u b - i n and non-greasy f e e l . S t e a r i c A c i d i s used as a non-greasy o i 1 phase t h i c k e n e r . I n g r e d i e n t : W t .%* A : Veegum, Magnesium Aluminum S i l i c a t e 1 - 0 0

C e l l u l o s e Gum (CMC 7MF) 0 .15 D e i o n i z e d Water 8 0 . 7 5 S i m e t h i c o n e (Dow C o r n i n g A n t i f o a m AF) 0 . 1 0

B: M i n e r a l O i l 5 .00 M i n e r a l O i 1 (and) Lano l i n A l c o h o l (Amerchol L-101) 4 . 0 0 S t e a r i c A c i d XXX 3 .OO G l y c e r y l S t e a r a t e (and) PEG-100 S t e a r a t e ( A r l a c e l 165) 4 .00 L a n o l i n O i l 2 . 0 0

C: P r e s e r v a t i v e q . s . Procedure :

Add t h e Veegum/Cel lu lose Gum d r y b l e n d t o t h e w a t e r s l o w l y , a g i t a t i n g a t maximum a v a i l a b l e shear u n t i l smooth. Add Simeth- i c o n e a t s l o w m i x i n g speed. Heat P a r t A t o 70C and P a r t B t o 75C. Add P a r t B t o P a r t A and mix w h i l e c o o l i n g . Package a t 40C.

Formula No. 370

Dry Touch Emollient LotionVeegum s t a b i l i z e s t h e e m u l s i o n and a d j u s t s t h e v i s c o s i t y o f

t h i s l o t i o n . The e m o l l i e n t s used f o r t h e s e l o t i o n s were s e l e c t e d f o r t h e i r m o i s t u r i z i n g p r o p e r t i e s . The e m u l s i f i c a t i o n f o r t h e s e f o r m u l a s i s p r o v i d e d by t h e g l y c e r y l monosteara te and t h e t r i - e thano lamine s t e a r a t e ( fo rmed i n s i t u ) .

A :

B:

C :

D:

I n p r e d i e n t : Veegum, Magnesi um A1 umi num S i 1 i c a t e - .

Water T r i e t h a n o l a m i n e G1 y c e r i n M i n e r a l O i l P e t r o l a t u m S t e a r i c A c i d XXX C e t y l A l c o h o l G l y c e r y l S t e a r a t e SE (Kessco GMS-SE) C e t y l A c e t a t e (and) A c e t y l a t e d L a n o l i n A l c o h o l

( A c e t u l an) D imeth icone, 350 c s . C o l o r , P r e s e r v a t i v e , Perfume

W t .%* 0 .50

85.50 0 .10 3.50 3 . 6 0 0 . 4 0 1 .60 0 . 8 0 1 .40

2 . 0 0 0.60 q.s.

Procedure : Add t h e Veegum t o t h e w a t e r s l o w l y , a g i t a t i n g a t maximum

a v a i l a b l e shear u n t i l smooth. Add t h e P a r t B i n g r e d i e n t s t o P a r t A and h e a t t o 70-75C w i t h g e n t l e s t i r r i n g . Heat t h e P a r t C i n g r e d i e n t s t o 75-80C. Add P a r t C t o P a r t s A+B and m i x t h o r o u g h l y w h i l e c o o l i n g . A t 40C add P a r t 0, m i x u n t i l u n i f o r m .

Formula No. 377 *As r e c e i v e d b a s i s


Lotions 221


Formula: A : G l u c a t e SS Glucamate SSE-20 Modul an S t e a r i c A c i d B l a n d o l M i n e r a l O i l A p r i k o l ( B e l l ) Phenoni p (Fann i ng) 8 : Glucam E-20 Dei o n i zed Water D o w i c i l 200 C: P a c i f i c Sea K e l p E x t r a c t Chamomile E x t r a c t Hawai an W h i t e G inger E x t r a c t Fragrance 5-5390 ( B e l l )

% by Wei ght

1 .oo 1 . o o 2 . 0 0 2 . 0 0 3 .00 3 . 0 0 0 . 2 0

5 .00 81 . O O

0 . 2 0

0 .25 0 . 2 5 0 .25 0 . 3 0

Premix Tween 20 0 . 5 0

Procedure :

t o 45C. Add B o t a n i c a l s and F r a g r a n c e . S t i r t o 30C and package. Heat Phases A and B t o 85C. Add B t o A a t 85C. S t i r and c o o l

Rehydrating Body Lotion

Formula: A : Water T e t r a s o d i u m EDTA Methy lparaben Propy lparaben P r o p y l ene G l y c o l Carbopol 940 2% i n Water B: C a r n a t i o n M i n e r a l O i 1 (Wi t c o ) S t e a r i c A c i d XXX A l d o MS ( G l y c o ) F l u i l a n L i p o n a t e GC F i n s o l v TN B u t y l Paraben C : T r i e t h a n o l ami ne 99% D : Aloe-Moi s t ( T e r r y )

% by Weight

60.68 0 . 0 4 0 . 1 6 0 . 0 8 4 . 0 0 5 . 6 0

5 .60 2.00 2.40 0 . 4 0 2 . 4 0 0 . 0 4 0 . 0 4

0 . 8 0

15.00

Procedure :

Cool t o 55C and add 0. Cool t o 30C. SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

Add B a t 80C w h i l e s t i r r i n g . Add C and s t i r 15 m i n u t e s a t 80C.



A non - tacky , m o i s t u r i z i n g hand and body l o t i o n w i t h n a t u r a l s k i n f e e l , c o n t a i n i n g C l a r i s k i n f o r e l i m i n a t i n g brown age s p o t s . I n g r e d i e n t s : 1 . D i s t i 11 ed/Dei o n i zed Water

- 36w/w

78 .90 2 . D isod ium EDTA 0 . 1 0 3 . A c r i t a m e r 941 (Carbomer) 0 .20 4 . P r o p y l e n e G l y c o l 0 . 8 0 5 . G l y c e r i n e 5 . 0 0 6 . Me thy lpa raben 0 . 2 0 7. P r o p y l p a r a b e n 0 .10 8 , M i n e r a l O i 1 (Drake01 -21 ) 4 .00 9 . S t e a r i c A c i d 2 . 0 0 1 0 . R i t a EGMS ( G l y c o l S t e a r a t e ) 1 . 5 0 11 .R i tawax ALA ( R . I . T . A . B l e n d ) 0 . 5 0 12 . R i t a SA ( S t e a r y l A1 c o h o l ) 0 . 5 0

1 4 . R i t a s i l 190 (D ime th i cone C o p o l y o l ) 0 . 5 0 15 . T r i e t h a n o l a m i n e 0 . 5 0 1 6 . C l a r i s k i n (Yeas t E x t r a c t ) 5 .00 Compounding P rocedure :

M i x i t e m s 4-7 and add t o t h e combined i t e m s 1-3, t h a n h e a t t o 65C. M i x i t e m s 8-14 and h e a t t o 65C. Add o i l phase t o w a t e r phase. H o l d t e m p e r a t u r e a t 65C and add i t e m 15. Cool t o 40C and add i t e m 16.

1 3 . R i t a CA ( C e t y l A l c o h o l ) 0 . 2 0

D i s p e r s e i t e m 2 i n t o t h e w a t e r u n t i l u n i f o r m and add i t e m 2 .

R e f . No. 122-888

Hand Lotion

A non-greasy hand l o t i o n des igned f o r normal s k i n . I n g r e d i e n t s : %w/w 1 . M i n e r a l O i 1 ( L i g h t ) 3 .00 2 . S t e a r i c A c i d 2 .50

4 . Ri tawax ALA ( C e t y l A c e t a t e and A c e t y l a t e d L a n o l i n A1 c o h o l ) 0 . 7 5

5 . R i t a CA ( C e t y l A l c o h o l ) 0 .50 6 . P r o p y l p a r a b e n 0 . 0 5 7 . A c r i t a m e r 934 (Carbomer) 0 .10 8 . D i s t i 11 ed/Dei o n i zed Water 81 - 8 5 9 . Me thy lpa raben 0 .10 10 . T r i e t h a n o l a m i n e (50%) 0 . 6 5 11 . P r o p y l ene G1 y c o l 3 .50 1 2 . F r a g r a n c e q . s . 13. Tens i ne (Wheat P r o t e i n ) 5 . 0 0 Compounding P rocedure :

h e a t t o 70C. Combine i t e m s 1-6 and h e a t t o 70C. Add i t e m s 10 and 11 t o w a t e r . Add o i l t o w a t e r w i t h m i x i n g . B e g i n c o o l i n g w h i l e m i x i n g . Add i t e m s 12 and 1 3 .

SOURCE: R , I , T . A . C o r p . : Suggested F o r m u l a t i o n s

3 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 2 .00

S l o w l y add i t e m 7 t o i t e m 8 w i t h a g i t a t i o n . Add i t e m 9 and

R e f . No. 122-2A

Lotions 223

Hand & Body Lotion For mu 1 a : % by Weigh t A : D e i o n i z e d Water 72 .15 B : Po l yso rba te -20 2 . 0 0 Me thy lpa raben 0 . 2 0 E t h y l paraben 0 . 1 5 C : G1 y c e r i n 3 . 0 0 Xanthan Gum 0 . 1 2 D: Sesame O i l 4 .00 C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) 1 . o o G l y c e r y l S t e a r a t e & PEG-100 S t e a r a t e 3 . 0 0 S o r b i t a n S t e a r a t e 2 . 0 0 C e t y l A l c o h o l 1 . 0 0 M i n e r a l O i 1 and Lano l i n A1 coho1 (Amerchol ) 3 . 0 0 D ime th i cone 0 .50 BHA 0 . 0 5 Methocel 40-100 0 . 1 0 V i t a m i n E O i l 0 . 0 1 S t e a r i c A c i d 1 . 5 0 E : Dei o n i zed Water 1 . 5 0 D o w i c i l 200 0 . 1 0 F: Dei o n i zed Water 1 . o o Col 1 agen 0 . 0 1 E l a s t i n 0 . 0 1 G : F rag rance 0 . 1 0 P rocedure :

Heat A t o 70-8OC. Combine B i n g r e d i e n t s and warm. Add t o A a t 75-80C, combine C i n g r e d i e n t s and m i x w e l l t o p re -we t xan than . Add t o A . Weigh D i n g r e d i e n t s i n t o s t e a m - j a c k e t e d k e t t l e and h e a t t o 80C. Add t o w a t e r phase. T u r n h e a t o f f and m i x e m u l s i o n down t o 45C. P repare E, add t o b a t c h a t 45C. Add F a t 45C. Add G t o e m u l s i o n .

Light Conditioning Hand Lotion Formula: % by Weiaht A : G1 ucqua t 100 1 . 0

Dei o n i zed Water 84 .0 B : G l u c a t e SS 0 . 8

Gl ucamate SSE-20 1 . 2 A c e t u l a n 2 . o G l y c e r y l Monos tea ra te 0 . 5 C a r n a t i o n M i n e r a l O i l ( W i t c o ) 7 . 5 Perfume and P r e s e r v a t i v e q . s .

D i s s o l v e G luqua t 100 i n w a t e r and h e a t t o 70C. I n s e p a r a t e P rocedure :

v e s s e l , combine B and h e a t t o 70C w i t h p r o p e l l e r a g i t a t i o n . S l o w l y add A t o B and m i x u n t i l u n i f o r m . Cool t o room temp- e r a t u r e w i t h m i x i n g . SOURCE: W i t c o Corp. : Suggested Formul a t i ons


Incroquat Behenyl TMS Lotion

T h i s b a s i c f o r m u l a t i o n shows how I n c r o q u a t Behenyl TMS can f o r m a s t a b l e and e l e g a n t , y e t s i m p l e , e m u l s i o n . The s o f t / p o w d e r y f e e l i t c o n f e r s on t h e s k i n i s due t o t h e c o n d i t i o n i n g e f f e c t s o f t h e beheny l q u a t .

I n g r e d i e n t s : Wei n h t % P a r t A : I n c r o q u a t Behenyl TMS (Behen t r imon ium M e t h o s u l f a t e (and ) C e t e a r y l A l c o h o l ) 3 . 0 0

Crodamol GTCC ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 5 .00 D ime th i cone 200 (200 c p s ) 1 . 0 0 Vo lpo S-2 ( S t e a r e t h - 2 ) 0 .10 Vo lpo S-10 ( S t e a r e t h - 1 0 ) 0 . 5 0

P a r t B: Dei o n i zed Water 77 .40

P a r t C : Dei o n i zed Water 5 . 0 0 H y d r o t r i t i c u m 2000 ( H y d r o l y z e d Whole Wheat P r o t e i n ) 1 .oo P a r t D: P r o p y l e n e G l y c o l (and) D i azo1 i d i n y l Urea (and) M e t h y l -

paraben (and ) and P r o p y l p a r a b e n 1 .oo Crodasome CM-Glucan (Sodium Carboxymethy l B-Glucan) 1 . 0 0 I n c r o m e c t a n t LAMEA (Acetamide MEA (and) Lac tamide MEA) 5 .00

pH=4.5+-0.5 V i s c o s i t y = 9 , 0 0 0 cps+-10% (RVT S p i n d l e #TC, 10 rpm, 25C)

Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 75-80C. P rocedure :

Heat P a r t B t o 75-80C. Add P a r t A t o B w i t h m i x i n g . Cool w i t h m i x i n g t o 50C and add P a r t s C and D . C o n t i n u e m i x i n g and c o o l t o d e s i r e d f i l l t e m p e r a t u r e .

SOURCE: Croda, I n c . : F o r m u l a t i o n SC-268

Lotions 225

High SPF-30 LotionCold Process

A c t i v e I n g r e d i e n t s : O c t y l Methoxyc innamate 3% O c t y l S a l i cy1 a t e 3% T i t a n i um D i o x i d e 2%

I n q r e d i e n t s : Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e (and ) C e t y l D ime th i cone

Copo lyo l (and ) Hexyl L a u r a t e ( A b i 1 WE-09) C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) Cyc lometh i cone O c t y l P a l m i t a t e ( T e g o s o f t OP) O c t y l S t e a r a t e ( T e g o s o f t OS) Po l ydecene C e t y l D ime th i cone ( A b i l Wax 9801) O c t y l Me thoxyc i nnamate O c t y l Sa l i c y l a t e

Phase B : Water Sodium C h l o r i d e H y d r o x y e t h y l C e l l u l ose T i t a n i u m D i o x i d e (40% aq . d i s p e r s i o n ) P r e s e r v a t i v e s F rag rance C o l o r

Wei n h t %

5 . 0 0 3.00 3.00 3 . 0 0 2 . 0 0 2 . 0 0 1 . o o 3 . 0 0 3.00

68.40 0.80 0 . 8 0 5 . 0 0

Q . S . Q.S. Q . S .

Procedure : 1 . Combine t h e i n g r e d i e n t s o f Phase A t o g e t h e r . M i x w e l l . 2 . D i s s o l v e t h e H y d r o x y e t h y l C e l l u l o s e i n t o t h e v o r t e x o f t h e

a g i t a t i n g w a t e r phase. A l l o w t h e c e l l u l o s e t o f u l l y h y d r a t e p r i o r t o a d d i n g t h e sodium c h l o r i d e . Add T i 0 2 (40% aq. d i s p e r s i o n ) . M i x u n t i l u n i f o r m . Add p r e s e r v a t i v e s .

3 . Add Phase B s l o w l y i n t o Phase A w i t h s l o w a g i t a t i o n . 4 , Homogeni ze. 5 . Fragrance and c o l o r can be added upon f o r m i n g t h e e m u l s i o n .

SOURCE: Go ldschmid t Chemical C o r p , : Suggested F o r m u l a t i o n


Low pH Glycolic Acid Lotion with 18-8 Glycyrrhetinic Acid Phytosome

An AHA l o t i o n c o n t a i n i n g L i p 0 F r u i t A c i d Complex f o r s o f t e r smoother s k i n and 18-6 G l y c y r r h e t i n i c A c i d Phytosome wh ich s h o u l d make t h i s more a c c e p t a b l e t o s e n s i t i v e s k i n .

Sequence : -__ Raw M a t e r i a1 : Wt% 1 Dei o n i zed Water 52 I 65 1 Hypan QT-100 (1% g e l ) 0 . 2 0 1 Benzy l A l c o h o l 0 . 5 0 1 FG-10 A n t i foam S i meth i cone Emu1 s i on 0 .10

2 L i pona te NPGC-2 2 L i p o c o l C 2 L i pomul s e 165 2 DC S i l i c o n e 200/350 c t s . 2 Lipowax D

5 . 0 0 1 . 7 5 5 . 0 0 0 . 5 0 3 . 0 0

3 L i p o n i c E G - 1 6 . 0 0 3 18-8 G l y c y r r h e t i n i c A c i d Phytosome 0 . 5 0

4 L i p 0 F r u i t A c i d Complex 5 . 0 0

P rocedure : 1 . I n main k e t t l e , combine Sequence #1 i n g r e d i e n t s under homoge-

2 . I n a u x i l i a r y k e t t l e , combine Sequence #2 i n g r e d i e n t s and hea t

3 . A t p r o p e r tempera tu re , add combined Sequence #2 t o Sequence #1

n i z e r and h e a t t o 75C.

t o 80C.

under homogenizer and c o n t i n u e t o homogenize u n t i l e r n u l s i f i - c a t i o n i s comp le te and a l l Hypan Gel p a r t i c l e s a r e n o t v i s i b l e . Beg in t o c o o l and s w i t c h t o l i g h t n i n ' m i x i n g .

u n t i l d i s s o l v e d and b a t c h i s u n i f o r m . Cool t o 25C w i t h sweep b l a d e a t l o w speed.

4 . Cool t o 40C and add p remixed Sequence #3 i n t o b a t c h mix

5 . A t 25C, add Sequence # 4 i n t o b a t c h . 6 . A d j u s t pH t o 3 . 8 - 4 . 1 w i t h a p p r o p r i a t e b u f f e r .

SOURCE: L i p 0 Chemica ls I n c . : F o r m u l a t i o n No. 891

Lotions 227

A :

B :

Moisturizing LotionI n g r e d i e n t : W t .%*

G l y c e r y l S t e a r a t e (and) PEG-100 S t e a r a t e (Lexemul 561) 2 . 0 0 I s o p r o p y l M y r i s t a t e ( L e x o l IPM) 1 - 0 0 G l v c o l S t e a r a t e (Lexemul EGMSl 0 .50 M i n e r a l O i l A c e t y l a t e d Lanol i n A1 coho1 C e t y l A l c o h o l S t e a r i c A c i d Cyc lometh i cone P r o p y l p a r a b e n ( L e x g a r d P ) S o r b i t o 1 , 70% Veegum, Magnesium Aluminum T r i e t h a n o l a m i n e , 99% t o p H Carbomer 934 Me thy lpa raben (Lexgard M) Dei o n i zed Water

S i 1 i c a t e 7 . 0

0 . 5 0 1 . o o 1 . o o 1 - 0 0 0 . 5 0 0 . 0 5 4 . 0 0 0 .30

0 . 2 0 0 . 1 5

87.80

9.s .

P rocedure :

m i x i n g w i t h a homogenizer a t 5000 rpm. Add t h e Veegum s l o w l y and c o n t i n u e m i x i n g f o r 20 m i n u t e s . A d d t h e S o r b i t o l and M e t h y l Paraben and m i x each f o r 3 m i n u t e s a t 5000 rpm. Add t h e Carbomer 934 and m i x f o r 3 m i n u t e s . Weigh t h e P a r t A i n g r e d i e n t s i n t o a n o t h e r v e s s e l . M i x and h e a t t o 70C. Add P a r t A t o P a r t B and mix f o r 10 m i n u t e s a t 70C. Move t h e b a t c h t o a p r o p e l l e r m i x e r , a d j u s t t h e speed t o p roduce a s m a l l v o r t e x , and b e g i n c o o l i n g . A t 40C, measure t h e pH and a d j u s t t o 7 . 0 u s i n g T r i e t h a n o l a m i n e . C o n t i n u e c o o l i n g and package a t 35C.

Weigh t h e w a t e r i n t o a s u i t a b l e v e s s e l and h e a t t o 70C w h i l e

Collagen LotionThe Veegum/Rhodigel m i x t u r e s t a b i l i z e s t h e e m u l s i o n and

a d j u s t s t h e v i s c o s i t y o f t h i s c o l d p r o c e s s l o t i o n . The l o t i o n p r o v i d e s an e l e g a n t f e e l i n b o t h i n i t i a l a p p l i c a t i o n and i n t h e r e s i d u a l f i l m .

A :

B:

C:

D :

I n q r e d i e n t : Veegum, Magnesi um A1 umi num S i 1 i c a t e

W t .%* 1 - 0 0

R h o d i g e l , Xanthan Gum 0 . 5 0 D e i o n i z e d Water 76.25 G1 y c e r i n 6 . 0 0 S o l u b l e C o l l a g e n ( C o l l a s o l ) 5 . 0 0 A1 1 a n t o i n 0 .25 Hydrogenated Po l y i s o b u t y l ene (Po l y s y n l ane) 4 .00 M i n e r a l O i l ( and ) L a n o l i n A l c o h o l (Amerchol L-101) 3 . 0 0 C10-30 C h o l e s t e r o l / L a n o s t e r o l E s t e r s (Super S t e r o l

E s t e r ) 2 . 0 0 DEA-Oleth-3 Phosphate (Croda fos N-3 N e u t r a l ) 1 . o o D ime th i cone , 350 c s . (Dow C o r n i n g 200 F l u i d ) 1 . o o P r e s e r v a t i ve q . s .

Procedure : Dry b l e n d Veegum and Rhod ige l and add them t o t h e w a t e r w h i l e

a g i t a t i n g a t maximum a v a i l a b l e shear u n t i l smooth. Add P a r t B i n o r d e r , m i x i n g each u n t i l smooth and u n i f o r m . Combine P a r t C i n g r e d i e n t s , s t i r r i n g u n t i l u n i f o r m . Add P a r t C t o P a r t s A+B. M i x u n t i l homogeneous. *As r e c e i v e d b a s i s SOURCE: R . T . V a n d e r b i l t C o , , I n c . : Fo rmu las : I n o l e x Chernical /#381


Moisturizing LotionI n q r e d i e n t : W t .%* A : P e n t a e r y t h r i t y l T e t r a l a u r a t e 5 .00

G l y c e r y l S t e a r a t e (and) PEG-100 S t e a r a t e 5 .00 M i n e r a l O i l 2 . 5 0 A c e t y l a t e d L a n o l i n A l c o h o l 1 .00 D i met h i cone 1 . o o S t e a r i c A c i d 1 .oo S t e a r y l A l c o h o l 0 . 5 0 C e t y l A l c o h o l 0 .50

B: D e i o n i z e d Water 78.00 Veegum HV, Magnesi um A1 umi num S i 1 i c a t e 0 .30 Carbomer 934, 3% S o l n . (Carbopo l 934) 5 .00

C: T r i e t h a n o l ami ne, 9945 0.20 P r e s e r v a t i ve q . s .

Procedure : Prepare t h e 3% Carbomer s o l u t i o n i n accordance w i t h t h e manu-

f a c t u r ’ s recommendat ions. Weigh t h e P a r t B water i n t o a s u i t a b l e v e s s e l and heat t o 50C. W h i l e m i x i n g t h e water w i t h a homogenizer a t 5000 rpm, s l o w l y add t h e Veegum HV and c o n t i n u e m i x i n g f o r 20 m i n u t e s w h i l e h e a t i n g t o 75F. Add t h e Carbomer s o l u t i o n and c o n t i n u e m i x i n g . Weigh t h e P a r t A i n g r e d i e n t s i n t o a n o t h e r ves- s e l . M i x and h e a t t o 75C. Add P a r t A t o P a r t B and mix f o r 10 m i n u t e s a t 75C. Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o p roduce a s m a l l v o r t e x . B e g i n c o o l i n g . A t 45C, add t h e T r i e t h a n o l a m i n e . A t 40C, add t h e p r e s e r v a t i v e and package a t 35c.

Formul a f rom Rhone-Poul enc, I nc .

Silicone Barrier Lotion I n t h i s f o r m u l a , Veegum i s used a l o n g w i t h Rhod ige l Xanthan

Gum t o s t a b i l i z e t h e e m u l s i o n and a d j u s t t h e v i s c o s i t y . T h i s l o t i o n uses a s i l i c o n e f l u i d t o a c h i e v e an e m o l l i e n t p r o t e c t i v e b a r r i e r w i t h a p l e a s a n t non-greasy f e e l . S t e a r i c A c i d i s used as a non-greasy o i l phase t h i c k e n e r . The Span/Tween c o m b i n a t i o n p r o v i d e s t h e e m u l s i f i c a t i o n f o r t h i s f o r m u l a . L o t i o n v i s c o s i t y i s a d j u s t e d b y chang ing t h e Veegum/Rhodigel l e v e l . I n g r e d i e n t : W t .%* A : Veegum, Magnesium Aluminum S i l i c a t e 1 - 0 0

Rhodi g e l , Xanthan Gum 0.25 Water 80 .75

B : Phenyl T r i m e t h i c o n e (Dow C o r n i n g 556 F l u i d ) 5 .00 S t e a r i c A c i d XXX 5 . 0 0 P o l y s o r b a t e 20 (Tween 20 ) 4 .50 S o r b i t a n L a u r a t e (Span 20 ) 3 .50

C : P r e s e r v a t i ve q . s . Procedure :

Add t h e Veegum/Rhodigel d r y b l e n d t o t h e w a t e r s l o w l y , a g i t - a t i n g a t maximum a v a i l a b l e shear u n t i l smooth. Heat P a r t A t o 70C. Heat P a r t B t o 75C. Add P a r t B t o P a r t A and mix whi l e c o o l i n g t o room t e m p e r a t u r e . Add P a r t C and m i x u n t i l u n i f o r m .

Formula No. 374 * As r e c e i v e d b a s i s SOURCE: R , T . V a n d e r b i l t Co., I n c , : Veegum F o r m u l a t i o n s

Lotions 229

O/W Hand & Body Lotion

A .

B.

C.

D.

E.

I n g r e d i e n t s : G l y c e r y l Monos tea ra te C e t y l A l c o h o l C e t i o l LC S i l i c o n e 200/100 cs Edeta BD Phenon i p Amphisol A

D e i o n i z e d Water AMP Regu la r (10% s o l ' n )

D e i o n i zed Water Pemulen TR-1 1% s o l n P r o p y l ene G1 y c o l

AMP Regu la r (10% s o l ' n )

Perfume O i l

% by Wei Qht 4 . 0 0 1 . o o

10 .00 0 . 5 0 0 . 1 0 0 .60 1 . 5 1

10.00 4 . 0 0

52 .69 10.00

5 . 0 0

0 . 6 0

q . s .

Procedure : Heat p a r t A t o 85C w h i l e s t i r r i n g . When homogeneous, add

p a r t B p r e - h e a t e d t o 75C, w h i l e m i x i n g . Add p a r t s C and D p r e - h e a t e d t o 75C, w h i l e m i x i n g . Cool t o 40C, add p a r t E . Compensate f o r w a t e r l o s s and c o n t i n u e s t i r r i n g , w h i l e c o o l i n g t o amb ien t t e m p e r a t u r e .

Remark: b ) Recommended p e r c e n t a g e o f s u i t a b l e d e r m a t o l o g i c a l l y t e s t e d per fume f o r cream 0 . 5 % .

F o r m u l a t i o n PF-0374E sugges ted by Givaudan-Roure SA

Aculyn 33 Hand Lotion

_- I n g r e d i e n t s : A . Water

I m i d a z o l i d i n y l Urea EDTA Na2 C e t e a r y l g l y c o s i d e I s o p r o p y l m y r i s t a t e Acu lyn 33

B. AMP-95 (10% s o l n . )

P rocedure : M i x t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d .

96 b y Weight t o 100%

0 . 3 0 0 . 1 5

20 .00 5 . 0 0 3 . 0 0 3 . 0 0

P h y s i c a l C h a r a c t e r i s t i c s : pH: 7 . 4 V i s c o s i t y ( 6 r p m ) : 12,000 cps F o r m u l a t i o n PF-0388 suggested by Rohm and Haas C o . (PF-034)

SOURCE: Angus Chemical C o r p . : P roduc t Fo rmu la ry


Pearlized Body Lotion

Phase# : 1 Dei o n i zed Water 1 P e a r l e s c e n t P i gment (Rona)

Wt%

2 . 0 0 - 5 . 0 0 q . s .

2 Carbopol 941 0 .40

3 P r o p y l e n e G1 y c o l 3 M e t h y l Paraben

8 . 0 0 0 . 2 0

4 D i s o d i um EDTA 0 . 0 5

5 T r i e t h a n o l a m i n e 99% 5 Dei o n i zed w a t e r

0 . 6 0 2 . 0 0

6 C r o d e s t a SL40 3 .00

7 M i n e r a l O i l 9Ocs 7 Schercemol 185 7 C r i l l 6 7 P r o p y l Paraben

4 . 0 0

1 . o o 0 .10

8 DMDM H y d a n t o i n 55% 0 . 1 8

9 Fragrance 0 .10

Procedure :

Combine phase 1, h e a t t o 70C. Add phase 2 w h i l e homogeniz ing. Combine phase 3 , add t o b a t c h . Add phase 4 . Combine phase 5, add t o b a t c h . Add phase 6 . Heat t o 75C. Add combined phase 7, m a i n t a i n homogenizer a g i t a t i o n for 1 5 m i n u t e s . Cool t o 45C, add phases 8 , 9 . Cool t o 30C.

Combine phase 7, h e a t t o 80C w i t h s t i r r i n g u n t i l homogeneous

Rona P e a r l P i gment Combi n a t i ons : EM1 -55-1 T i m i r o n Super Go ld 2%

EM1 -55-2 T i m i r o n Super Red 2%

EM1 -55-3 T i m i r o n Super V i o l e t 2%

EM1 -55-4 T i m i r o n Super B l u e 2%

EM1 -55-5 T i m i r o n Super Green 2%

EM1 -55-6 T i m i r o n Super Copper 2%

SOURCE: Rona/EM I n d u s t r i e s , Inc . : F o r m u l a t i o n EM1-55

Lotions 231

Protective Lotion with Cromoist CM Glucan

T h i s l o t i o n i s i d e a l f o r e v e r y day use due t o t h e p r o t e c t i v e e f f e c t s o f C romo is t CM Glucan on t h e s k i n and i s e s p e c i a l l y b e n e f i c i a l b e f o r e and a f t e r exposure t o t h e sun . By s t i m u l a t i n g t h e s k i n ’ s own d e f e n s e mechanisms, t h e p o w e r f u l p r o t e c t a n t and t h e r a p e u t i c agen t i s a b l e t o i n c r e a s e t h e s k i n ’ s r e s i s t a n c e t o UV-A i n d u c e d o x i d a t i v e s t r e s s and o t h e r e n v i r o n m e n t a l i n s u l t s . C roda fos CES i s a u n i q u e c o n d i t i o n i n g and e m u l s i f y i n g system t h a t enhances t h e p r o t e c t i v e and e m o l l i e n t e f f e c t s o f t h e l o t i o n b y p r o m o t i n g b e t t e r d e l i v e r y o f C r o m o i s t CM Glucan and Crodamol PMP, t h e e m o l l i e n t e s t e r used t o reduce t h e g r e a s i n e s s o f t h e p e t r o l a t u m .

I n Q r e d i e n t s : Wei q h t % P a r t A : Croda fos CES ( C e t e a r y l A l c o h o l (and) C e t e a r y l Phosphate) 4 . 0 Crodamol PMP (PPG-2 M y r i s t y 1 E t h e r P r o p i o n a t e ) 5.0 P e t r o l a t u m 2 . 0

P a r t B: D e i o n i z e d Water T r i e t h a n o l a m i n e (98%)

P a r t C : Dei o n i zed Water Col 1 a s o l ( S o l u b l e Col 1 agen)

7 5 . 8 0 . 2

5 . 0 1 . o

P a r t D: P r o p y l e n e G l y c o l (and) D i azo1 i d i n y l U rea (and ) M e t h y l -

paraben (and ) P r o p y l p a r a b e n 1 . o C romo is t CM-Glucan (Sodium Carboxymethy l B-Glucan) 1 . o I n c r o m e c t a n t LAMEA (Acetamide MEA (and ) Lauramide MEA) 5 . 0

pH=4.5+-0.5 V i s c o s i t y = 6 , 0 0 0 cps+-10% (RVT S p i n d l e # TC @ 10 r p m @ 25C)

P rocedure :

Combine i n g r e d i e n t s o f P a r t B w i t h m i x i n g and h e a t t o 75-8OC. Add i n g r e d i e n t s o f P a r t A t o B w i t h m i x i n g and c o o l t o 50C. Add i n g r e d i e n t s o f P a r t C and D w i t h m i x i n g and c o o l t o d e s i r e d f i l l t e m p e r a t u r e .

Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 75-8OC



Rain Forest Lotion with Cronatural Brazil Nut Oil T h i s f o r m u l a t i o n produces a s h i n y w h i t e , pumpable l o t i o n w i t h

e x c e l l e n t r u b - i n c h a r a c t e r i s t i c s and d r i e s q u i c k l y t o a v e r y c o n d i t i o n e d s o f t n e s s . C r o n a t u r a l B r a z i l Nut O i l i m p a r t s a d r y e m o l l i e n t f e e l w i t h o u t a h i n t o f o i l i n e s s . I n g r e d i e n t s : WtSb P a r t A : I n c r o m i n e BB (Behenamidopropyl D imethy lamine) 3 . 0 C r o d a c i d B (Behen ic A c i d ) 2 . 5 M i n e r a l O i l (7Ossu) 1 5 . 0 C r o n a t u r a l B r a z i l Nut O i l 5 . 0 P a r t 8 : Dei o n i zed Water 73 .5 P a r t C : Propy lene g l y c o l (and) d i a z o l i d i n y l u r e a (and) m e t h y l

paraben (and) p r o p y l paraben* 1 . o pH: 7 . 5 t - 0 . 5 V i s c o s i t y : 3,000 cps+-10% (RVT S p i n d l e # 5 , 50 rpm (3 25C)

Procedure : Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 80-85C.

Heat P a r t B t o 80-85C. Add P a r t B t o P a r t A w i t h m i x i n g and c o o l t o 40C. Add P a r t C w i t h m i x i n g and c o o l t o d e s i r e d f i l l temp- e r a t u r e .

*Germaben I 1 ( S u t t o n Labs) N . A . T . C . Approved


Dihydroxyacetone LotionPhase A : w A b i l EM-90 1 . 5 Abi 1 WE-09 1 . o A b i l B 8839 6 . 0 T e g o s o f t OS 4 . 0 Isohexadecane 7 . 0 Hydrogenated C a s t o r O i l 0 . 4 Beeswax 0 . 4 Phase B : Water 72 .9 P r o p y l e n e G1 y c o l 2 . 0 Sodium C h l o r i d e 0 .8 D i h y d r o x y a c e t o n e 4 . 0 P r e s e r v a t i ves Q . S . C o l o r Q.S. Phase C : F r a g r a n c e Q.S. Procedure : 1 . B l e n d t h e components o f Phase A . Heat t o 85C i n a c l o s e d

2 . Cool t o 40C. 3 . Heat Phase B components t o 40C w h i l e m i x i n g . 4 . Add B t o A s l o w l y w i t h s l o w a g i t a t i o n u n t i l B i s f u l l y

5 . Add f r a g r a n c e w i t h s low a g i t a t i o n . 6 . Homogenize. SOURCE : Go1 dschmi d t Chemi c a l Corp. : Suggested Formul a t i on

k e t t l e w h i l e m i x i n g u n t i l a l l waxes a r e d i s p e r s e d .

d i spersed.

Lotions 233

Skin Firming Lotion

A l i g h t s k i n l o t i o n c o n t a i n i n g R a f f e r m i n e t o enhance t h e f i r m n e s s o f t h e s k i n .

I n g r e d i e n t s : 1 . S t e a r i c Ac id 2 . Soy G l y c e r i d e s 3 . R i t a c h o l 2000 ( C e t e a r y l A1 coho1 and Pol y s o r b a t e - 6 0 ) 4 . Capry l i c / C a p r i c T r i g l y c e r i d e s 5 . Me thy lpa raben 6 . P r o p y l paraben 7 . C12-15 A l k y l Benzoate 8 . D i s t i l l e d / D e i o n i z e d Water 9 . A c r i t a m e r 940 (Carbomer) 10 . M e t h y l G1 uce th -20 11 . P r o p y l e n e G1 y c o l 1 2 . R a f f e r m i n e ( H y d r o l y z e d Soy F l o u r ) 13.TEA (50%)

%w/w 3 . 1 0 3 . 1 0 1 . 2 0 2 . 5 0 0 . 1 5 0 .05 1 . 5 0

79 .10 0 . 1 5 3 . 0 0 3 . 2 0 2 . 0 0 0 . 5 0


11 . Heat t o 70C w h i l e d i s p e r s i n g i t e m 9 . Add o i l t o w a t e r . Add TEA and m i x w h i l e c o o l i n g . A t 40C add i t e m 12 .

Combine i t e m s 1-7 and h e a t t o 70C. Combine i t e m s 8, 10 and

R e f . No. 121-125

Facial Moisturizing Lotion

E l e g a n t m i n e r a l o i 1 and 1 a n o l i n based emu1 s i on f o r m u l a t e d w i t h P o l y q u t a t o add s u b s t a n t i v i t y t o t h e s k i n and R i t a s i l 190 f o r p l e a s a n t s k i n f e e l i n g .

I n q r e d i e n t s : 1 . R i t a p r o - 1 6 5 ( R . I . T . A . B l e n d ) 2 . 3 . 4 . 5 . 6 . 7 . 8 . 9 . 10

M i n e r a l O i l L a n o l i n USP ( R . I . T . A . X - t r a Deo) R i t a p r o 100 ( R . I . T . A . B l e n d ) R i t a s i l 190 (D ime th i cone C o p o l y o l ) D i s t i 11 ed/Dei o n i zed Water P r o p y l e n e G1 y c o l Pol y q u t a 3000 ( P o l y q u a t e r n i um-1 0 ) G1 y d a n t

. F r a g r a n c e - L i g h t Musk 169-119

4 . 0 0 5 . 0 0 0 .50 1 - 5 0 0 . 4 0

81.70 6 . 0 0 0 . 5 0 0 . 2 0 0 . 2 0

Cornpoundi ng P rocedure :

S e p a r a t e l y h e a t i t e m s 1-5 t o 70C. Add t h i s m i x t u r e t o w a t e r m i x t u r e . M i x t o u n i f o r m and c o o l t o 40C. Add p r e s e r v a t i v e and per fume.

SOURCE: R.I.T.A. C o r p . : Suggested F o r m u l a t i o n s

D i s s o l v e P o l y q u t a 3000 i n w a t e r . Add i t e m 7 and h e a t t o 70C.

R e f . No. 121-89


Therapeutic Hand & Body Lotion

Raw M a t e r i a1 : W t % (as - . i s ) 1 . D . I . Water Q . S . t o 100.00 2 . M e t h y l Paraben 0 . 1 5 3. G l y c e r i n e 3.5 4 . B r i j 78 0 . 4 5 . O c t y l I sononanoa te 10 .0 6 . Kessco GMS 3 . 0 7 . Kessco C e t y l A l c o h o l 2 . 0 8 . Wecobee S 2 . 5 9 . P r o p y l Paraben 0 .01 1 0 . S i l i c o n e 200 (350 c p s ) 1 . o 11 . G I y d a n t 0 . 2 5 1 2 , C i t r i c Ac id 50% Q . S . l B . F r a g r a n c e , C o l o r Q.S.

P r o p e r t i es : Appearance: Opaque L o t i o n pH @ 25C: 6 . 0 - 7 . 0


o i l phase b y a d d i n g 4 , 5 , 6 , 7 , 8 and 9. Heat t o 70C. Add o i l phase t o t h e w a t e r phase. I n c r e a s e a g i t a t i o n . M i x a t 70C f o r 20-25 m i n u t e s . S t a r t c o o l i n g t o room t e m p e r a t u r e w i t h c o n t i n u o u s a g i t a - t i o n . A t 45C, add 10 and 11. A d j u s t pH i f necessa ry . Cool t o ambient t e m p e r a t u r e .

P repare w a t e r phase by a d d i n g 1,2 and 3. Heat t o 70C. P repare

Ethnic Hand & Body Lotion

D . I. Water G1 y c e r i n Ammonyx 4 P e t r o l a t u m Kessco IPP S i l i c o n e DC-200 (350 c p s ) Kessco C e t y l A l c o h o l P o t a s s i um C h l o r i d e C i t r i c A c i d (50%) P r e s e r v a t i ve

% b y Weight Q . S . t o 100.0

4 . 0 0 18.40

4.00 3 . 0 0 1 . o o 2 - 0 0 0 .40

Q . S . Q . S .

M i x i n g P rocedure : I n t o a s u i t a b l e c o n t a i n e r equ ipped w i t h m i x i n g , h e a t i n g , and

c o o l i n g c a p a b i l i t i e s , add t h e D . I . Water , G l y c e r i n , and Ammonyx 4 . S t a r t m i x i n g and h e a t i n g t o 155-16OF. A t 155-160F, add P e t r o l - atum, Kessco IPP, S i l i c o n e DC-200, and Kessco C e t y l A l c o h o l . M i x w e l l f o r 20 m i n u t e s , k e e p i n g h e a t a t 160F. S t a r t c o o l i n g t o room t e m p e r a t u r e . A t lOOF, p r e m i x p o t a s s i u m c h l o r i d e w i t h s m a l l amount o f D . I . Water and add t o t h e b a t c h . A t 9OF, add p r e s e r v a t i v e . A t room t e m p e r a t u r e , a d j u s t p H t o 4 . 0 - 4 . 5 i f necessa ry w i t h c i t r i c a c i d (50%) . SOURCE: Stepan Co,: Suggested F o r m u l a t i o n s

Lotions 235

Under Make-Up Lotion

A non-greasy , p r o t e c t i v e day cream c o n t a i n i n g Tens ine and Reduc t ine t o f i r m t h e s k i n and h e l p reduce f i n e l i n e s .

-~ I n s r e d i ents:. 1 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 2 . Ce tea re th -25 3 . R i t a I P P ( I s o p r o p y l P a l m i t a t e ) 4 . R i t a c h o l 2000 (Ceteary ! A l c o h o l and P o l y s o r b a t e - 6 0 ) 5 . Me thy lpa raben 6 . P ropy lpa raben 7 . D i s t i l l e d / D e i o n i z e d Water 8 . P ropy lene G l y c o l 9 . Tens i ne (Wheat P r o t e i n ) 10 .Reduc t ine (Oat P r o t e i n ) 11.TEA (99%) 1 2 . F rag rance

%J'/ 8 . 0 0 3 . 0 0 5 . 0 0 5 . 0 0 0 * 20 0 .10

62 .50 5 . 0 0 6.00 5 . 0 0

0 . 2 0 q.s.

Compounding P rocedure : Combine i t e m s 1 - 6 and hea t t o 70C. Combine i t e m s 8 and 9 arid

h e a t t o 70C. Add o i l t o wa te r and m i x . A l l o w t o c o o l t o 40C and add i t e m s 9-12 .

R e f . No. 120-195

Under Make-Up Lotion

A non-greasy , p r o t e c t i v e day cream c o n t a i n i n g Tens ine and Reduc t ine t o f i r m t h e sk . in and h e l p reduce f i n e l i n e s .

- I m e d i e n t s : 1 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 2 . Ce tea re th -6 and S t e a r y l A l c o h o l 3 . R i t a I P P ( I s o p r o p y l P a l m i t a t e ) 4 . R i t a c h o l 2000 ( C e t e a r y l A l c o h o l 5 . Me thy lpa raben 6 . P ropy lpa raben 7 . D i s t i l l e d / D e i o n i z e d Water 8 . P ropy lene G l y c o l 9 . Tens ine (Wheat P r o t e i n ) 1 0 . Reduc t i ne (Oat P r o t e i n ) 1 1 . T E A (99%) 12 .F rag rance

.~ % W A 8 . 0 0 3 . 0 0 5 . 0 0

and P o l y s o r b a t e - 6 0 ) 5 .00 0 . 2 0 0 . 1 0

62 .50 5 . 0 0 6 . 0 0 5 . 0 0

0 .20 q . s .

Compounding P rocedure : Combine i t e m s 1-6 and hea t t o 70C. Combine i t e m s 8 and 9 and

h e a t t o 7OC. Add o i l t o wa te r and m i x . A l l o w t o c o o l t o 40C and add i t e m s 9-12.

R e f . No. 120-196



Water-in-Oil Moisturizing Lotion

Formula: % by WeIghtA:Veegum 1 .3Water 55.7Magnesium Sulfate 0.5B:Carnation Mineral Oil (Witco) 9.0Polysynlane 10.0Ni mlesterol D 7.5Amerchol L101 9.070% Sorbitol Solution 5.0Witcamide 511 2.0

Preservative q.s.

Procedure:Add Veegum to water slowly, agitating continually u n t i l

smooth. Add magnesium sulfate and mix u n t i l smooth. Blend B andadd A to B. Mix until smooth and uniform. This formula is arich, pourable or pumpable lotion and may be dispensed froma suitable glass or plastic bottle.

Facial Lotion

Formul a : %_by WeightWater Phase:Water q.s. to 100Triethanolamine 0.2Oi1 Phase:Carnation Mineral Oil (Witco) 4.0Steari c Aci d 1.0Naturechem GMHS (CasChem) 2.5Lanoli n Oi1 2.0Imidazolidinyl Urea, Methylparaben, Propylparaben 0,2Fragrance O,3

Procedure:Heat both phases to 75C. Add oil phase to water phase with

high speed m i x i n g . Allow to cool and continue m i x i n g to 35C;add preservative and fragrance; mix thoroughly.

SOURCE: Witco Corp,: Suggested Formulations

Lotions 237

W/O Lotion, EO-free with Softisan 649

I n a r e d i e n t s : Wei a h t % A . M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 8 . 0 0

M i g l y o l 840 ( P r o p y l e n e G l y c o l / D i c a p r y l a t e / D i c a p r a t e ) 8 . 0 0 S o f t i san 649* 5 .00 A r l a c e l 1689 ( P o l y g l y c e r i n (and) S o r b i t o l ) 4 . 0 0 A r l a m o l HD ( I sohexadecane) 3 . 0 0

B . Magnesium S u l p h a t e P r e s e r v a t i v e Water , ad

2 . 0 0

100 .00 q . s .

C . F rag rance q . s .

* B i s-Di g l y c e r y l P o l y a c y l a d i p a t e - 2

P r e p a r a t i on : A i s h e a t e d up a t abou t 75C. 6 i s b r o u g h t t o t h e same t e m p e r a t u r e . A i s e m u l s i f i e d w i t h an homogenizer i n t o A . C i s added a t 30C. F o r m u l a t i o n HUK WOL

New "Light Lotion" with Imwitor 375

I n q r e d i e n t s : Wei q h t % A . M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 1 6 . 2 5

01 e a t e ) 3 .00 I m w i t o r 375 ( G l y c e r y l C i t r a t e / L a c t a t e / L i n o l e a t e /

6 . N a t r o s o l P l u s 330 CS P r e s e r v a t i v e Wate r , ad

0 . 7 5

1 0 0 . 0 0 q . s .

C . F rag rance q . s .

P r e p a r a t i on : I n g r e d i e n t s of A a r e h e a t e d t o abou t 70C. To b u i l d phase B N a t r o s o l i s d i s p e r s e d i n w a t e r and s t i r r e d t o homogenei t y . Then B i s b r o u g h t t o t h e same t e m p e r a t u r e and e m u l s i f i e d i n t o A . The cream i s s t i r r e d c o l d and t h e n C i s added. F o r m u l a t i o n HUK LL

SOURCE: H u l s A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n

238 Cosmetic and 7ililrtry Fontidations

2% AHA Low Viscosity Lotion with Uninontan U-34

An AHA L i p 0 F r u i t A c i d l o t i o n w i t h Un inon tan U-34 and Gorg- o n i a n E x t r a c t t o p r o v i d e an even s k i n t o n e and h e l p m i n i m i z e s k i n i r r i t a t i o n . T h i s f o r m u l a a l s o c o n t a i n s a ba lanced emuls- i f i e r sys tem f o r e x c e l l e n t s t a b i l i t y and a v a r i e t y o f e m o l l i e n t s / m o i s t u r i z e r s f o r s k i n s o f t n e s s .

Seque n ge R_ay Mater1 a1 : 1 Dei on1 zed Water 1 Uniphen P-23 1 L i p o n i c EG-1

2 K e l t r o l 2 Veegum

U l t r a p u r e L L i p 0 GMS 450 L ipopeg 6000 DS Lipowax G Lipowax P L i p o c o l C L i pona te NPGC-2 L i p o v o l SAF L iDovo l SES

w.ei PI-! % 7 6 . 6 4

0 . 5 0 1 . 5 0

0 . 2 5 0 . 1 5

1 . 5 0 1 .50 1 . 7 5 0 . 2 5 0 . 4 5 1 . o o 4 . 0 0 0.50 0 . 5 0

4 Uni non tan U-34 5 . 0 0

5 Gorgon ian E x t r a c t 6 T r i e t h a n o l a m i n e , 99%

0.50 QS *

k To a d j u s t pH

Procedure : 1 . M ix Sequence # 1 t o g e t h e r w i t h overhead m i x e r w h i l e h e a t i n g

t o 78C. 2 . Dry m i x Sequence #2 t o g e t h e r and add s l o w l y t o Sequence # 1

w i t h medium/high a g i t a t i o n . (Mix w e l l u n t i l b o t h gums a r e c o m p l e t e l y hydrated/homogeneous.)

3 . M i x Sequence #3 t o g e t h e r and h e a t t o 78C u n t i l c o m p l e t e l y m e l t e d and add t o b a t c h . (Coo l t o 55C, p l a c e on sweep b l a d e and c o n t i n u e t o c o o l t o 45C) .

and add t o b a t c h u s i n g sweep b l a d e a t l o w speed. Lower t e m p e r a t u r e t o 4 0 C .

4 . A t 45C, p remix Sequence # 4 t o g e t h e r a t room t e m p e r a t u r e

5 . A t 40C, add Sequence #5 t o t h e b a t c h . 6 . Cool down t o 25C and remove f r o m m i x e r . 7 . A d j u s t pH t o 3 . 8 - 4 . 2 w i t h Sequence #6 .

S p e c i f i c a t i o n s : pH: 4 . 0 + - 0 . 2 V i s c o s i t y : 6 , 7 0 0 cps+-10% LVT #4 @ 30rpm

SOURCE: L i p 0 Chemica ls I n c . : F o r m u l a t i o n No, 936

Section Vlll Shampoos

239

240 Cosmetic and Toiletry Formillations

Anti-Dandruff Shampoo Suspending Sulfur with Ritavena 5

Sodi um L a u r y l S u l f a t e D i s t i 11 ed Water P a t i o n i c ISL /85 E t h y l e n e G l y c o l D i s t e a r a t e Cocamide DEA P r o p y l e n e G l y c o l NaCl (25% S o l u t i o n ) L a c t i c A c i d (44%) F l o w e r s o f S u l f u r R i t a v e n a 5

Wt% 51 - 7 0 28 .30 3.00 3.00 4 .50 2.00 1 . o o QS

2.00 4.50

p H : 7 . 5 5 V i s c o s i t y : 15,800 cps S t a b i 1 i t y :

Freeze/Thaw: v . sl . p r e c i p . a f t e r 2 c y c l e s 40F: no change a f t e r 6 weeks

11OF: s l i g h t s e p a r a t i o n b u t s u l f u r s t a y s Foam T e s t i ng : Foam H20

0 . 0 m i n u t e 31 0 80 1 . O m i n u t e 31 0 1 0 0 3 . 0 m i n u t e 295 100

SOURCE: R . I . T . A . C o r p . : R i t a v e n a 5 : F o r m u l a t i o n 1 1 2 - 1 2 0 - 8

Children's Conditioning Shampoo

Mackadet BSC Mackalene 426 Sodium C h l o r i d e M a c k s t a t DM Water , Dye, F rag rance qs t o

W S 2 5 . 0

3 . 0 1 . 5 qs

1 0 0 . 0

P rocedure : 1 . Add f i r s t two components t o wa te r and h e a t t o 40 degrees C . 2 . B l e n d u n t i l c l e a r . 3 . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e . 4 . Add r e m a i n i n g components and c o o l .

SOURCE: M c I n t y r e Group L t d . : Pe rsona l Care F o r m u l a r y : Formula

Shampoos 241

Antidandruff Shampoo

A : Water Veegum, Magnesi um Alumi num S i 1 i c a t e

B: Cocobeta i ne Ammoni um L a u r y l S u l f a t e D i s o d i um Oleamido PEG-2 Su l f o s u c c i n a t e

Wt%

47 .0 0 . 5

6 . 0 2 5 . 0 1 5 . 0

C : D i azo1 i d i n y l Urea (and ) Me thy lpa raben (and)

P ropy lpa raben (and ) P r o p y l e n e G l y c o l (Germaben 11) 1 . o Hyd r o x y p r o p y l Guar 0 . 5 Cocamide DEA 3 . 0 Z i n c P y r i t h i o n e 2 . 0

D : Dye, f r a g r a n c e q . s .

Procedure: S l o w l y add Veegum t o t h e w a t e r u s i n g maximum a v a i l a b l e s h e a r .

A l l o w t o f u l l y d i s p e r s e and h y d r a t e under c o n t i n u o u s m i x i n g f o r a minimum o f 15 m i n u t e s . B l e n d B i n g r e d i e n t s i n t o A w i t h c o n t i n - uous s t i r r i n g f o r 5 m i n u t e s . I n s e p a r a t e k e t t l e d i s p e r s e guar and cocamide DEA i n Germaben 1 1 . B l e n d i n z i n c p y r i t h i o n e . When u n i f o r m add A + B t o C . Add dye and f r a g r a n c e . No h e a t i s r e q u i r e d .

Formula f r o m ISP S u t t o n L a b o r a t o r i e s

Moisturizing Antidandruff Shampoo

Sodium L a u r e t h S u l f a t e , 30% Po tass ium Cocoyl H y d r o l y z e d C o l l a g e n (Maypon Cocamide DEA P r o p y l e n e G1 y c o l Z i n c P y r i t h i o n e , 48% Veegum, Magnesi um A1 umi num S i 1 i c a t e H y d r o x y p r o p y l M e t h y l c e l l u l o s e M e t h y l Paraben ( L e x g a r d M) P r o p y l Paraben (Lexgard P ) Water

Wt% 25.00

4c 1 10.00 1 .oo 3 .00 4 .50 1 . o o 1 . 2 0 0 . 1 5 0 . 0 5

q . s . t o 100

Procedure :

r e m a i n i n i n g i n g r e d i e n t s and m ix t h o r o u g h l y . Cool t o 40C. T y p i c a l p r o p e r t i e s : pH 6 . 7 . V i s c o s i t y a t 24C: 2925 c p s . T h i c k l a t h e r , s m a l l b u b b l e s .

Heat w a t e r t o 70C. D i s p e r s e me thy l c e l l u l o s e and Veegum. Add

Formul a f ron I no1 ex Chemical Corp.

SOURCE: R . T . V a n d e r b i l t Co., I n c . : Veegum Formulas


Sequence: 1 1 1 1 2 2 3 4 4 5 5 6

Clear Shampoo with Microcapsules

Raw M a t e r i a1 : Dei o n i zed Water Sodium C h l o r i d e Me thy lpa raben Hampene Na2T L i p o n i c E G - I Hypan SR15OH Carbopol ETD 2020 (2% s o l I n ) D e i o n i z e d Water T r i e t h a n o l a m i n e , 99% Standapo l ES-2 Standapo l T L i p o P e a r l Green V i t a m i n E A c e t a t e

P e r c e n t 39.60

0 . 2 0 0 . 2 5 0 . 0 5 1 . o o 0 . 1 0

3 0 . 0 0 1 . o o 0 . 8 0

20.00 6 . 0 0 1 . o o

P rocedure : 1 . M i x and h e a t Sequence # I t o 80C w i t h overhead m i x e r a t medium

speed. 2 . Premix i n t o s l u r r y Sequence #2 and add t o Sequence #1 a t 80C

w i t h overhead m i x e r . 3 . Premix Sequence #3 and add t o b a t c h w i t h overhead m i x e r

a t medium speed. 4 . Premix Sequence #4 and add t o b a t c h w i t h overhead m i x e r a t

medi um speed. 5 . A t l ow speed on overhead m i x e r add Sequence # 5 i n o r d e r o f

a d d i t i o n ( k e e p i n g a e r a t i o n t o a minimum). Cool t o 25C w i t h sweep b l ade.

6 . A t 25C s l o w l y add Sequence #6 m i c r o c a p s u l e s u s i n g sweep b l a d e a t low speed.

SOURCE: L i p 0 Chemicals I n c . : Formula No. 869

All Natural Shampoo

Mackadet WGS Mackami de LLM Sodium C h l o r i d e M a c k s t a t DM EDTA (40%) F rag rance Dei o n i zed Water Q. S .

WtO/o 45.0 1 0 . 0

2.5 Q . S . Q . S . Q . S .

1 0 0 . 0

P rocedure : 1 . Add components t o w a t e r and b l e n d u n t i l c l e a r . 2 . I f a h i g h e r v i s c o s i t y i s needed, a d j u s t w i t h sodium c h l o r i d e .

SOURCE: M c I n t y r e Group L t d . : Pe rsona l Care F o r m u l a r y

Shampoos 243

Conditioning Color Enhancer Shampoo

I n g r e d i e n t s : Phase A : Water Sodium L a u r e t h S u l f a t e (28% 2M. E . O . ) D i sod i um Cocoamphodi p r o p i o n a t e PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) Quaternium-80 ( A b i l Quat 3272)

Phase 6 : B a s i c B l u e 99 B a s i c Brown 16 A c i d V i o l e t 43 B a s i c Red 36 B a s i c Ye1 l o w 57

Phase C : Water T e t r a s o d i um EDTA Cocamidopropyl B e t a i n e (Tego B e t a i n e E ) D ime th i cone C o p o l y o l ( A b i 1 B 8852) F rag rance P r e s e r v a t i ves C i t r i c A c i d PEG-18 G l y c e r y l O lea te /Cocoa te ( A n t i l 171) P rocedure : 1 . Combine i n g r e d i e n t s o f Phase A . 2 . B l e n d c o l o r s , add t o Phase A . M i x w e l l .

Weight%

20 n 00 20.00 10 .00

1 . 5 0 0 . 5 0

Q . S . Q . S . Q . S . Q . S . Q . S .

38 .40 0 . 1 0 7 . 0 0 0 . 5 0

Q . S . Q . S .

t o pH 6 . 0 2 . 0 0

3 . Add i n g r e d i e n t s o f Phase C t o A/B i n o r d e r , m i x i n g w e l l .

4 . A d j u s t v i s c o s i t y w i t h t h e PEG-18 G l y c e r y l O lea te /Cocoa te

SOURCE: Go1 dschmi d t Chemical Co. : Suggested Formul a t i ons

A v o i d foaming . A d j u s t p H t o 6 .0 w i t h C i t r i c A c i d .

( A n t i l 1 7 1 ) .

Shampoo-Clear Gel Type

I n g r e d i e n t s : Wei q h t % Carbopol ETD 2020, 1 .5% 77.70 D i s o d i um EDTA 0 .10 Cal foam SLS-30 15.00 Cal foam ES-303 5 .00 Calamide C 2 .00 Comments abou t t h i s f o r m u l a : 1 . A 1.5% s o l u t i o n i s made b y d i s p e r s i n g t h e Carbopol i n 40C

2 . The d i s p e r s i o n i s s l i g h t l y hazy w i t h g e l - l i k e c o n s i s t e n c y . 3 . P r o b a b l y even a 1% s o l u t i o n wou ld be s u i t a b l e f o r t h i s

4 . The i n g r e d i e n t s a r e g r a d u a l l y added i n t o t h e Carbopol s o l u t i o n

warm w a t e r and s t i r r i n g .

a p p l i c a t i o n .

and s t i r r e d u n t i l a homogeneous p r o d u c t i s p r e p a r e d .



Conditioning Shampoo

T h i s f o r m u l a uses I n c r o q u a t HO-aOPG, a q u a t e r n a r y c o n d i t i o n i n g agen t s u i t a b l e f o r 2 - i n - 1 shampoos, i n c o m b i n a t i o n w i t h I n c r o m i n e O x i d e C and C r o d a f o s SG t o g i v e h a i r improved wet combing and a s o f t , d r y f e e l . I n c r o q u a t HO-80 PG has been f o u n d t o work e s p e c i a l l y w e l l w i t h p o l y m e r i c q u a t e r n a r i e s , l i k e t h e Jaguar C14S used h e r e , as i t appears t o enhance t h e e f f e c t s o f t h e s e p o l y q u a t s , r e s u l t i n g i n g r e a t e r c o n d i t i o n i n g .

I n n r e d i e n t s : P a r t A : Dei o n i zed Water Guar H y d r o x y p r o p y l t r imon iu rn C h l o r i d e C i t r i c A c i d

P a r t B: SLES ( 3 mo le ) SLS Inc ronam 30 (Cocoamidopropyl B e t a i n e ) I n c r o m i de L R (Laurami de DEA) Croda fos SG (PPG-5-Ceteth-10 Phosphate) G1 y c e r o x HE (PEG-7 G1 y c e r y l Cocoate) I n c r o q u a t HO-80PG ( D i o l e o y l ami d o e t h y l H y d r o x y e t h y l -

G1 y c o l S t e a r a t e I n c r o m i n e Ox ide C (Cocamidopropylamine Ox ide )

P a r t C : P r o p y l ene G1 y c o l (and ) D i azo1 i d i n y l Urea (and ) M e t h y l

Hexy l ene G1 y c o l D i m e t h i cone Copol yo1

P rocedure :

moni um M e t h o s u l f a t e )


Weight%

57 .05 0 . 3 5 0 . 1 0

15 .00 5.00 6 . 0 0 3 . 0 0 2 . 0 0 1 .oo

2 . 5 0 0.50 2 . 0 0

1 .oo 3 .00 1 . 5 0

Combine P a r t A i n g r e d i e n t s w i t h good m i x i n g . Heat P a r t A i n g r e d i e n t s t o 45C. Add P a r t B i n g r e d i e n t s t o P a r t A as l i s t e d . Heat b a t c h up t o 70-75C w i t h good m i x i n g . Make sure a l l i n g r e d - i e n t s a r e d i s s o l v e d . S t a r t c o o l i n g b a t c h . A t 50C, add P a r t C .

pH=5.5+-0.5 V i s c o s i t y = 3 , 0 0 0 cps + - l o % , S p i n d l e #4 @ 10 rpm N.A.T.C. Approved

SOURCE: Croda Inc . : F o r m u l a t i o n SH-96

Shampoos 245


T h i s f o r m u l a uses I n c r o q u a t Behenyl HE, a q u a t e r n a r y cond- i t i o n i n g agent s u i t a b l e f o r 2 - i n - 1 shampoos, i n c o m b i n a t i o n w i t h I n c r o m i n e Ox ide C and Crodafos SG t o g i v e h a i r improved wet combing and a s o f t , d r y f e e l . I n c r o q u a t Behenyl HE a l s o works e s p e c i a l l y w e l l w i t h p o l y m e r i c q u a t e r n a r i e s , l i k e t h e Jaguar C14S used h e r e , and has been found t o enhance t h e e f f e c t s o f t h e s e p o l y q u a t s , r e s u l t i n g i n g r e a t e r c o n d i t i o n i n g .

I n n r e d i e n t s : P a r t A : Dei o n i zed Water Guar H y d r o x y p r o p y l t r i m o n i u m C h l o r i d e C i t r i c A c i d

P a r t 8 : SLES ( 3 m o l ) SLS Incronam 30 (Cocamidopropyl B e t a i n e ) I n c r o m i n e Oxide C (Cocamidopropylamine O x i d e ) I n c r o m i de LR (Laurami de DEA) Crodafos SG (PPG-5-Ceteth-10 Phosphate) G l y c e r o x HE (PEG-7 G l y c e r y l Cocoate) I n c r o q u a t Behenyl HE (Behenamidopropyl H y d r o x y e t h y l

D i moni um C h l o r i d e )

Weight%

59.55 0 . 3 5 0 . 1 0

15.00 5 .00 6 .00 2 .00 3 . 0 0 2 . 0 0 1 . o o

2.50

P a r t C : Propy lene G1 y c o l (and) D i azo1 i d i n y l Urea (and) M e t h y l

Hexy l ene G1 y c o l 2 . 5 0

Procedure: Combine P a r t A i n g r e d i e n t s w i t h good m i x i n g . Heat P a r t A

i n g r e d i e n t s t o 45C. Add P a r t B i n g r e d i e n t s t o P a r t A as l i s t e d Heat b a t c h up t o 70-75C w i t h good m i x i n g . Make s u r e a l l i n g r e d i e n t s a r e d i s s o l v e d . S t a r t c o o l i n g b a t c h . A t 50C, add P a r t C .

Paraben (and) P r o p y l Paraben 1 . o o

pH=5.0+-0.5 V i s c o s i t y = 1 0 , 0 0 0 + - l o % , S p i n d l e #4 @ 10 rpm. N . A . T . C . Approved

SOURCE: Croda I n c , : F o r m u l a t i o n SH-97



T h i s f o r m u l a uses I n c r o q u a t HO-80 PG, a q u a t e r n a r y c o n d i t i o n - i n g agen t s u i t a b l e f o r 2 - i n - 1 shampoos, i n c o m b i n a t i o n w i t h I n c r o m i n e Ox ide C and Croda fos SG t o g i v e h a i r improved wet combing and s o f t , d r y f e e l . I n c r o q u a t HO-80 PG has been f o u n d t o work e s p e c i a l l y w e l l w i t h p o l y m e r i c q u a t e r n a r i e s , l i k e t h e Jaguar C 14s used he re , as i t appears t o enhance t h e e f f e c t s o f t h e s e p o l y q u a t s , r e s u l t i n g i n g r e a t e r c o n d i t i o n i n g .

I n g r e d i e n t s : P a r t A : D e i o n i z e d Water Guar H y d r o x y p r o p y l t r i m o n i u m C h l o r i d e * C i t r i c A c i d

P a r t B : SLES ( 3 mole) s LS Incronam 30 (Cocoamidopropyl B e t a i n e ) I n c r o m i de LR (Laurami de DEA) Croda fos SG (PPG-5-Ceteth-10 Phosphate) G1 y c e r o x HE (PEG-7 G1 y c e r y l Cocoate) I n c r o q u a t HO-80PG ( D i o l e o y l a m i d o e t h y l H y d r o x y e t h y l -

G l y c o l S t e a r a t e I n c r o m i n e Ox ide C (Cocamidopropylamine Ox ide )

moni um Methosu l f a t e )

Wt%

57.05 0 . 3 5 0 .10

1 5 . 0 0 5 . 0 0 6 .00 3 . 0 0 2 . 0 0 1 . o o

2 .50 0 . 5 0 2 . 0 0

P a r t C: P r o p y l e n e G1 y c o l (and) D i azo1 i d i n y l Urea (and) M e t h y l

Paraben (and ) P r o p y l Paraben** 1 . o o Hexy l ene G1 y c o l 3 . 0 0 D i m e t h i c o n e C o p o l y o l * * * 1 . 5 0

P rocedure : Combine P a r t A i n g r e d i e n t s w i t h good m i x i n g . Heat P a r t A

i n g r e d i e n t s t o 45C. Add P a r t B i n g r e d i e n t s t o P a r t A as l i s t e d . Heat b a t c h up t o 70-75C w i t h good m i x i n g . Make s u r e a l l i n g r e d - i e n t s a r e d i s s o l v e d . S t a r t c o o l i n g b a t c h . A t 50C, add P a r t C.

pH=5.56+-0.5 V i s c o s i ty=4200cps+-1090, Spi n d l e #4 @ 10 rpm

*Jaguar C14S ( Rhone-Poul enc) **Germaben I 1 ( S u t t o n Labs)

***Dow C o r n i n g 190 P o l y e t h e r (Dow C o r n i n g ) N .A .T .C . approved

SOURCE: Croda I n c . : F o r m u l a t i o n SH-96

Shampoos 247


T h i s f o r m u l a uses i t i o n i n g agen t s u i t a b I n c r o m i n e Ox ide C and combing and a s o f t , d r y e s p e c i a l l y w e l l w i t h PO C14S used h e r e , and has t h e s e p o l y q u a t s , r e s u l t

I n c r o q u a t Behenyl HE, a q u a t e r n a r y cond- ' l e f o r 2 - i n - 1 shampoos, i n c o m b i n a t i o n w i t h

Croda fos SG t o g i v e h a i r improved wet f e e l . I n c r o q u a t Behenyl HE a l s o works y m e r i c q u a t e r n a r i e s , l i k e t h e Jaguar been f o u n d t o enhance t h e e f f e c t s o f ng i n g r e a t e r c o n d i t i o n i n g .

I n g r e d i e n t s : P a r t A : Dei o n i zed Water Guar H y d r o x y p r o p y l t r i m o n i u m C h l o r i d e * C i t r i c A c i d

P a r t 0 : SLES ( 3 mo le ) s LS Incronam 30 (Cocoami d o p r o p y l B e t a i n e ) I n c r o m i n e Ox ide C (Cocamidopropylarnine Ox ide ) I n c r o m i d e LR (Lauramide DEA) C roda fos SG (PPG-5-Ceteth-10 Phosphate) G1 y c e r o x HE (PEG-7 G1 y c e r y l Cocoate) I n c r o a u a t Behenvl HE (Behenamidopropyl H y d r o x y e t h y l

D i moni um Chl or; de) .

P a r t C: P r o p y l ene G1 y c o l (and ) D i azo1 i d

Paraben (and ) P r o p y l Paraben** Hexyl ene G1 y c o l

P rocedure :

i n g r e d i e n t s t o 45C. Add P a r t B Combine P a r t A i n g r e d i e n t s w

Wt%

5 9 . 5 5 0.35 0 . 1 0

15.00 5 . 0 0 6 .00 2 .00 3 . 0 0 2 . 0 0 1 . 0 0

2 . 5 0

n y l Urea (and ) M e t h y l 1 . o o 2 .50

t h good m i x i n g . Heat P a r t A n n r e d i e n t s t o P a r t A as l i s t e d .

Heat b a t c h up t o 70-75C w i t h good-m ix ing . Make s u r e a l l i n g r e d - i e n t s a r e d i s s o l v e d . S t a r t c o o l i n g b a t c h . A t 50C, add P a r t C .

pH=5.26+-0.5 V i s c o s i ty=4800cpst -10%, Sp i n d l e #4 @ 1Orpm

*Jaguar C145S (Rhone-Poulenc)

N .A .T .C . Approved **Germaben I 1 ( S u t t o n Labs)




Staue M a t e r i a l : S tage A : 1 Water ; Pure 2 Sodium L a u r e t h S u l f a t e (SLES) 3 Tegobe ta ine L7 4 PEG 150-d i s t e a r a t e

Quan t i t v

49.6009 40. OOOg

5 . OOOg 2 . ooog

Stage 0 : 5 AEC D ime th i cone ( a ) Laure th -4 ( a ) Laure th -23 2 ,5009 6 Germaben 11-E 0 I 4009 7 P . AG 9960 F r u i t y F l o r a l f o r h a i r 0 .3009 6 Phosphor i c A c i d 0 , 2 0 0 9

C o l o u r s as r e q u i r e d g


4 has d i s s o l v e d , about 65C.

35C add 7 and a d j u s t t h e pH t o 5 . 5 - 6 . 5 .

Measure o u t t h e w a t e r and add i t e m s 2, 3 and 4 and hea t u n t i l

M i x b r i e f l y t h e n s t a r t c o o l i n g , add i t e m s 5 & G and when a t

C o l o u r as r e q u i r e d . T h i s s i m p l e fo rmu l a may be r e a d i 1 y adapted t o i n c o r p o r a t e

h e r b a l e x t r a c t s , h y d r o l yzed p r o t e i n , pan theno l and o t h e r s p e c i a1 i n g r e d i e n t s as r e q u i r e d .

P r o j e c t JW 2390/Formula R e f . 639*0


Stme- Mkitsx-d I Stage A : 1 Water ; Pure 2 Texapon L20/M 3 Tegobe ta ine L7 4 PEG 150-d7 s t e a r a t e

Quant i t y

46.6009 40 I OOOg 5. OOOg 2 . ooog

Stage 0 : 5 AEC D ime th i cone ( a ) L a u r e t h - 4 ( & ) Lau re th -23 3 .5009 6 Germaben 11-E 0 ,4009 7 F rag rance 0 ,3009 8 Phosphor i c A c i d 0 , 2 0 0 9 9 C o l o u r s a s r e q u i r e d 9


4 has d i s s o l v e d , about 65C.

35C add 7 and a d j u s t t h e pH t o 5.5-6.5.

Measure o u t t h e wa te r and add i t e m s 2,3 and 4 and hea t u n t i l

M i x b r i e f l y t h e n s t a r t c o o l i n g , add i t e m s 5 & 6 and when a t

C o l o u r a s r e q u i r e d . T h i s s i m p l e f o r m u l a may be r e a d i l y adapted t o i n c o r p o r a t e

h e r b a l e x t r a c t s , h y d r o l yzed p r o t e i n , p a n t h e n o l and o t h e r s p e c i a1 i n g r e d i e n t s as r e q u i r e d .

SOURCE: A & E Connock L t d , : Suggested F o r m u l a t i o n s P r o j e c t : J W 2390/Formula R e f . : 837*1

Shampoos 249


I n g r e d i e n t : D e i o n i z e d Water S tandapo l ES1 (30%) V e l v e t e x BK35 (35%) Laurami de DEA O i 1 s o f A loha Macadamia Nut O i 1 Perfume P r e s e r v a t i v e

Phase : A A A A A B B

% b y W t 61.25 25.00 1 0 . 0 0 3.00 0 . 5 0 0 . 2 5

QS

M a n u f a c t u r i n g P r o c e d u r e :

p r e s e r v a t i v e and per fume. Cool t o 40C. Add p r e s e r v a t i v e and per fume. Package.

Phase A : Heat w a t e r t o 70C and add a l l i n g r e d i e n t s e x c e p t

O i l s o f A loha Macademia Nut O i l s e r v e s as a r e f a t t i n g agen t t o r e p l a c e t h e n a t u r a l o i l s l o s t d u r i n g shampooing.

SOURCE: O i l s o f A l o h a : Suggested F o r m u l a t i o n


- A : Dei o n i zed Water Sodium L a u r e t h S u l f a t e (Phoenate SLES-70) Cocamidopropyl B e t a i ne Pecosi 1 C A P - I 240 Decyl Po l y g l ucose Laurami de DEA (Phoenami d LD) PEG-3 D i s t e a r a t e (Phoenate 3DSA) Sodium C h l o r i d e PEG-1 20 M e t h y l G1 ucose D i o l e a t e D i me th i cone Copol yo1 Phosphate (Pecos i 1 PS

Wt% 57 .80 20.00

1 . 6 0 2 . 0 0 8 . 0 0 2 . 0 0 2 . 4 0 0 . 8 0 2 .40

100) 2 . 0 0

B: P r o p y l e n e G1 y c o l (and) D i azo1 i d i n y l Urea (and) Me thy lpa raben (and) P r o p y l p a r a b e n

C o l o r F rag rance

1 - 0 0

9 , s . q . s .

10% Aqueous C i t r i c A c i d S o l u t i o n a d j u s t t o p H 5.0-6.0

Procedure :

A i s u n i f o r m , b e g i n c o o l i n g under s l o w sweep a g i t a t i o n t o 45C. Add Phase B w i t h c o n t i n u e d s l o w sweep a g i t a t i o n . When AB i s u n i f o r m , a d j u s t pH t o 5 . 0 - 6 . 0 .

SOURCE: Phoenix Chemical , I n c . : Suggested F o r m u l a t i o n

Combine Phase A i t e m s , a g i t a t e and h e a t t o 70C. When Phase



T h i s mu1 t i f u n c t i o n a l shampoo p r o v i des c l eans i ng and cond i t i on- ing i n one p r o d u c t . I t g i v e s improved g l o s s , wet and d r y comb- i b i l i t y , and m a n a g e a b i l i t y t o t h e h a i r . F requent use w i l l n o t lead t o a "g reasy" b u i l d u p on t h e h a i r .

[ n g r e d i e n t s : :el q u a t SC-240C ) i s t i l l e d Water r t o n a t e r i c 805 j t e p a n o l WAT donamid 716 ' ropy1 ene G1 y c o l ;errnaben I 1 > i t r i c A c i d

P r e p a r a t i on W h i l e ma

i n t o w a t e r . and m i x u n t

Formul a t

P a r t s by Weight 0 . 7 0

55.00 18 .80 1 8 . 5 0 4.00 2 .00 0 .50 0 .50

n t a i n i n g good a g i t a t i o n , s l o w l y s i f t C e l q u a t SC-240C When s o l u t i o n i s comple te , add r e m a i n i n g i n g r e d i e n t s 1 homogeneous. F i l t e r and f i l l c o n t a i n e r . on No. 8802:92

Clear, Colorless Conditioning Shampoo

T h i s c l e a r , c o l o r l e s s shampoo p r o v i d e s e x c e l l e n t c o n d i t i o n i n g and body t o t h e h a i r .

I n g r e d i e n t s Cel q u a t SC-230M D i s t i 11 ed Water S tandapo l A R e w o t e r i c AM 814 Monamid 716 Versene 100 Sodium C h l o r i d e P r e s e r v a t i v e

P a r t s by Weight 0 .25

56.40 35.00

7 .00 1 . o o 0 . 2 5 0 .10

4 , s .


When s o l u t i o n i s comple te , add r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r 1 i s t e d .

Add Cel q u a t SC-230M t o w a t e r whi 1 e mai n t a i n i ng good a g i t a t i on I

F o r m u l a t i o n No. 6919-117


Shampoos 251


M a t e r i a1 : Water; Pure Texapon L20/M Tegobe ta i ne L7 AEC D i m e t h i c o n e ( & ) L a u r e t h - 4 ( & ) L a u r e t h - 2 3 PEG 150-d i s t e a r a t e Germaben 11-E F rag rance Phosphor i c A c i d C o l o u r s a s r e q u i r e d



M a t e r i a1 : Water; Pure Sodium L a u r e t h S u l p h a t e (SLES) Tegobe ta i ne L7 AEC Dimethicone(&)Laureth-4(&)Laureth-23 PEG 150-d i s t e a r a t e Germaben 11 -E P.AG 9960 F r u i t y F l o r a l f o r h a i r Phosphor i c A c i d C o l o u r s as r e q u i r e d

Formula Re f . : 839*0

Shampoo with Silicone

M a t e r i a1 : Water; Pure Sodium L a u r e t h S u l p h a t e (SLES) Empico l TL 4 0 t Texapon SBN AEC D i m e t h i c o n e ( & ) L a u r e t h - 4 ( & ) L a u r e t h - 2 3 Emp i lan LDE Emp i lan EGMS Polymer JR 400 Kathon CG 100 Sodium H y d r o x i d e 33%


SOURCE: A & E C o n n o c k L t d . : Suggested F o r m u l a t i o n s

%w/w 48,600 40.000

5.000 3 .500 2 .000 0 .400 0 .300 0 a 200

%w/w 49.600 40.000

5.000 2 , 5 0 0 2 .ooo 0 .400 0 .300 0 I 2 0 0

%w/w 47 .390 18.000 17 .500 9 .500 4 I 000 2 .000 1 .ooo 0 . 5 0 0 0.100 0 .010



% By Weiqht Water 45.35 Sodium L a u r e t h S u l f a t e (2 Mole 26%) ( S i p o n ES2) 20.00 Sodium L a u r y l S u l f a t e and Disodium L a u r y l

Su l f o s u c c i n a t e (Monaterge 1164) 20.00 T r i s o d i um Lauroampho PG A c e t a t e Phosphate C h l o r i d e

( P h o s p h o t e r i c QL-38) 10 .00 D i m e t h i c o n e (Dow C o r n i n g 200 F l u i d 200 CS) 2 . 5 0 G l y c o l D i s t e a r a t e (Kessco E t h y l e n e G l y c o l D i s t e a r a t e ) 1 . o o Cocamide MEA (Monamid CMA) 1 . 0 0 Sodium C h l o r i d e 0 .15

Procedure :

70C. Cool t o 40C. A d j u s t pH t o 5 . 5 t o 6.0 w i t h 50% c i t r i c a c i d . Add f r a g r a n c e , c o l o r and p r e s e r v a t i v e as r e q u i r e d .

F o r m u l a t i o n P r o p e r t i e s :

Add i n g r e d i e n t s i n o r d e r l i s t e d w i t h a g i t a t i o n . Heat t o

P h y s i c a l P r o p e r t i e s : W h i t e p e a r l e d l o t i o n V i s c o s i t y @ 25C: 7,100 cps

Forrnul a F-578

Everyday Shampoo

% By Weight Water 48 I 00 Sodium L a u r e t h S u l f a t e ( 2 Mo le 26%) 20.00 Monaterge 11 64 20.00 P h o s p h o t e r i c QL-38 10 .00 Monamid CMA 1 .oo Sodium C h l o r i d e 1 . 0 0

Procedure :

Cool t o 40C. A d j u s t pH t o 5 . 5 t o 6 .0 w i t h 50% c i t r i c a c i d . Add f r a g r a n c e , c o l o r and p r e s e r v a t i v e as r e q u i r e d .

F o r m u l a t i o n P r o p e r t i e s :

Add i n g r e d i e n t s i n o r d e r l i s t e d w i t h a g i t a t i o n . Heat t o 60C.

P h y s i c a l Appearance: V i scous 1 i q u i d S o l i d s : 17.00%

Formula F-609

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

Shampoos 253

Deodorizing Shampoo

I n g r e d i e n t s : Phase A : Water T e t r a s o d i um EDTA Sodium L a u r y l S u l f a t e (28%) Sodium L a u r e t h S u l f a t e (28% 2M E . O . ) PEG-20 G l y c e r y l L a u r a t e (Tagat L ) PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) PEG-18 G l y c e r y l O lea te /Cocoate ( A n t i 1 171) G1 y c o l D i s t e a r a t e (Teg i n EGS) Z i nc R i n c i no1 e a t e (and) T r i e t h a n o l ami ne (and)

D i p r o p y l ene G1 y c o l (and) L a c t i c Ac i d (Tego Deo HY77)

Phase 0 : Water P r e s e r v a t i ves Fragrance Cocamidopropyl B e t a i n e (Tego B e t a i n e L7 ) C i t r i c A c i d (20% s o l u t i o n ) Sodium C h l o r i d e (25% s o l u t i o n )

Wei n h t %

32 60 0 . 1 0

17 .50 20.00

2 . 5 0 2 I 50 2 . 5 0 3 .00

1 .80

1 0 . 0 0 Q . S . Q . S .

7.50 t o pH 7 . 0

Q . S .

Procedure : 1 . Heat Phase A t o 70C. Add components i n o r d e r , m i x i n g w e l l

2 . Beg in c o o l i n g . S l o w l y c o o l t o 35-40C. Some o f t h e w a t e r o f

3 . Add t h e i n g r e d i e n t s o f Phase B . 4 . A d j u s t pH and v i s c o s i t y .

SOURCE: Go1 dschmi d t Chemi c a l Corp. : Suggested Formul a t i on

between a d d i t i o n s . A v o i d foam.

Phase B can be used t o s t a r t t h e c o o l i n g .

Shampoo

I n g r e d i e n t s : Water Cal foam SLS-30 Cal foam ES-303 Calamide C C i t r i c A c i d Sodium C h l o r i d e Perfume and Dye

Weight% 74.45

5 . 0 0 16 .00 2 . 0 0 0 . 1 0 2 . 5 0 0 . 1 0

Comments about t h i s f o r m u l a : 1 . M i x t h e f i r s t f o u r i n g r e d i e n t s ( p H = l O ) . 2 . Add t h e C i t r i c A c i d ( a p p r o x i m a t e l y 0 .1%) t o a d j u s t pH t o

3 . Add s a l t t o t h e d e s i r e d v i s c o s i t y . 4 . Perfume and dye as d e s i r e d .

SOURCE: P i l o t Chemical C o , : F o r m u l a t i o n SHM-003-01

about 6 .


MiId Deep Cleaning Shampoo

T h i s u n i q u e shampoo f o r m u l a t i o n p r o v i d e s e x c e l l e n t c l e a n s i n g o f t h e "g reasy" b u i l d u p on h a i r , w i t h o u t d r y i n g t h e h a i r o r s c a l p . T h i s shampoo a l s o a i d s i n p r e v e n t i n g / c o n t r o l l i n g s t a t i c f 1 yaway . I n g r e d i e n t s : F l e x a n 130 D i s t i l l e d Water S tepano l WAT R e w o t e r i c AM B-14LS P r o p y l ene G1 y c o l Monamid 716 Sodium C h l o r i d e G l y d a n t

P a r t s by Weight 2 .00

62 .55 20.00 10.00

2.00 2.25 0 . 8 0 0 . 4 0

P r e p a r a t i on : W h i l e m a i n t a i n i n g good a g i t a t i o n , add F l e x a n 130 t o w a t e r .

When s o l u t i o n i s comple te , add r e m a i n i n g i n g r e d i e n t s one a t a t i m e and m i x u n t i l homogeneous. F i l t e r and fill.

SOURCE: N a t i o n a l S t a r c h and Chemical Co. : F o r m u l a t i o n 8802:3813

Water White Shampoo

D . I. Water S t epano 1 WA- Ex t r a Amphosol CA N i n o l 40-CO Sodium C h l o r i d e P r o p y l e n e G1 y c o l G l y c e r i n C i t r i c A c i d (50%) Kathon CG Sodium C h l o r i d e

% by Weisht Q . S . t o 100 .0

46.50 5 .00 2 .50 1 .oo 1 . o o 0 .50 0 . 1 0 0 . 0 6 Q.S

M i x i ng Procedure :

Kathon CG. A d j u s t pH w i t h C i t r i c A c i d (50%) t o 6 . 5 - 7 . 0 . A d j u s t v i s c o s i t y w i t h Sodi um C h l o r i d e .

SOURCE : Stepan Co. : Suggested Formul a t i on

Heat f i r s t seven i n g r e d i e n t s t o 165F. M i x . Cool t o 11OF. Add

Shampoos 255

Moisture Therapy Shampoo with Hydrotriticum WAA

The use o f H y d r o t r i t i c u m WAA i n t h i s shampoo g i v e s h a i r deep- down m o i s t u r i z a t i o n f o r s h i n e t h a t shows c l e a r t h r o u g h t o t h e o u t s i d e . H y d r o t r i t i c u m WAA i s a p o w e r f u l wheat p r o t e i n - d e r i v e d amino a c i d complex t h a t has been shown t o p e n e t r a t e i n s i d e t h e h a i r , e n a b l i n g i t t o m o i s t u r i z e f r o m w i t h i n . As a c o l d f o r m u l a , t h i s shampoo i s economical and easy t o make. I n g r e d i e n t s : Weight% P a r t A : I n c r o m i de LR (Laurami de DEA) 5.00 Incronam 30 (Cocami d o p r o p y l B e t a i n e ) 5 . 0 0 Sodi um Pare th -25 S u l f a t e 1 5 . 0 0 H y d r o t r i t i c u m WAA (Wheat Amino A c i d s ) 1 . o o Dei o n i zed Water 73.00 P a r t B : P r o p y l e n e G l y c o l (and) D i a z o l i d i n y l Urea (and) M e t h y l

P rocedure :

Then add P a r t B w i t h m i x i n g . A d j u s t pH t o 5.0 w i t h a 10% c i t r i c a c i d s o l u t i o n .

Paraben (and ) P r o p y l Paraben 1 . o o

Combine i n g r e d i e n t s o f P a r t A, w i t h m i x i n g u n t i l c l e a r .

pH=5.0+-0.5 V i s c o s i t y = 8 , 0 0 0 + - 1 0 % (RVT S p i n d l e #4, lOrpm, 25C) N.A.T.C. Approved


I n q r e d i e n t : D i s t i 1 l e d w a t e r

Pearlescent Conditioning Shampoo

W t % q . s . t o 1 o o x

T E A - l a u r y l s u l f a t e (40% a c t i v e ) 1 5 . 0 0 Sodium lau roamphoace ta te (and) sodium t r i d e c e t h s u l f a t e 10 .00 Cocamide DEA 2 .50 G1 y c o l s t e a r a t e 1 . 2 0 P r o p y l e n e g l y c o l (and) d i a z o l i d i n y l u r e a (and ) m e t h y l -

paraben (and) p r o p y l p a r a b e n 0 . 7 5 Benecel MP 943 R h y d r o x y p r o p y l m e t h y l c e l l u l o s e 0 . 6 0 N-Hance 3000 c a t i o n i c gua r 0 .50 C i t r i c a c i d (50% s o l u t i o n ) pH a d j u s t P rocedure : 1 . D i s p e r s e t h e N-Hance b y a d d i n g t o t h e v o r t e x o f w e l l - a g i t a t e d

w a t e r . Reduce t o pH 7 .0 w i t h c i t r i c a c i d s o l u t i o n t o promote d i s s o l u t i o n o f t h e s u r f a c e - t r e a t e d N-Hance. Heat t o 50C.

2. S i f t t h e Benecel i n t o t h e N-Hance s o l u t i o n . M i x u n t i l b o t h po l ymers a r e f u l l y d i s s o l v e d .

3 . I n c r e a s e t h e t e m p e r a t u r e t o 70C. Add t h e TEALS and g l y c o l s t e a r a t e , one a t a t i m e . M i x w e l l between each a d d i t i o n . Tu rn o f f h e a t when homogeneous. Mai n t a i n m i x i ng.

p r e s e r v a t i v e . 5 . A d j u s t t o pH 5 . 0 w i t h c i t r i c a c i d s o l u t i o n . 4 . When t e m p e r a t u r e i s a t 55C, add r e m a i n i n g s u r f a c t a n t s and

6 . When be low 40C, add f r a g r a n c e .

SOURCE: Aqualon Div, :N-Hance 3000 C a t i o n i c Guar : F o r m u l a t i o n


B

Normal Hair Shampoo A good, b a s i c shampoo w i t h e x c e l l e n t f l a s h foam and l a t h e r

wh ich i s dense and s o f t . P a r t : I n g r e d i e n t (Trade Name): - W t %

A De ion i zed Water 58 .64 Hydroxyp ropy l M e t h y l c e l l u l o s e (Methocel 40-100) 0.10 Na4EDTA 0 . 2 0 T r i e t h a n o l ami ne 0 .01 TEA L a u r y l S u l f a t e (S tepano l WAT) 22.50 Me thy l Paraben 0 .20 I m i dazo l i d i n y l Urea (Germal 1 1 15) 0 . 2 0 Ammonium L a u r e t h S u l f a t e ( A l f o n i c 1412-A) 5 .50 Ammonium Cocoyl I s e t h i o n a t e (Jordapon ACI-30) 6 .70

C Cocamide DEA (Mazamide 80) 3 . 0 0 Soya Ethy ld imon ium E t h o s u l f a t e (M-Quat 1033) 0 .70 C i t r i c A c i d 0 .25 Ammon i um Ch 1 o r i de 2 .00

pH: 6 .3 -6 .7 V i s c o s i t y : 5500-6000 cps Appearance: C1 ea r , s t raw-col o r e d 1 i q u i d

Procedure: I n t h e main v e s s e l , d i s p e r s e t h e hyd roxyp ropy l m e t h y l c e l l -

u l o s e i n t h e w a t e r , m i x i n g f o r t e n m i n u t e s . Add t h e Na4EDTA and t r i e t h a n o l a m i n e , wh ich i n i t i a t e s h y d r a t i o n o f t h e gum. Mix f o r about 20 m inu tes t o ensure comple te h y d r a t i o n , t h e n add t h e p a r t B i n g r e d i e n t s i n o r d e r g i v e n . When b a t c h i s c l e a r and u n i f o r m , add t h e Mazamide 80 and t h e M-Quat 1033, and a d j u s t t h e pH and v i s c o s i t y .

Formula A-208 Baby Shampoo

C l e a r , m i l d , g e n t l e - c l e a n s i n g shampoo. Note: w h i l e PPG t e s t d a t a on t h e i n d i v i d u a l i n g r e d i e n t s i n d i c a t e t h a t t h i s f o r m u l a shou ld be e x t r e m e l y m i l d t o s k i n and eyes, PPG has n o t pe r fo rmed m i ldness t e s t i n g on t h i s system. P a r t : I n g r e d i e n t (Trade Name): Wt%

A D e i o n i z e d Water 68.1 PEG-80 S o r b i t a n L a u r a t e (T-Maz 28) 3 .0 Sodium C12-15 Pare th-15 S u l f o n a t e (Avanel

S-150 CG) 7 .1 PEG-150 D i s t e a r a t e (Mapeg 6000DS) 1 . 0

B Ammonium Cocoyl I s e t h i o n a t e (Jordapon ACI-30) 10 .0 Cocamidopropyl H y d r o x y s u l t a i n e (Mafo CSB-50) 9 . 0 Cocamide DEA (Mazamide JT-128) 1 . 5

C Qua te rn i um 15 (Dow ic i 1 200) 0 . 2 Fragrance 0 . 1

pH: 6 . 8 - 7 . 2 V i s c o s i t y : 3,400 cps ( B r o o k f i e l d #2 @ 6 rpm) Appearance: C l e a r , p a l e s t r a w - c o l o r e d l i q u i d

Procedure : B lend t h e P a r t A i n g r e d i e n t s , h e a t i n g t o 60-65C t o d i s s o l v e

t h e Mapeg 6000DS. When u n i f o r m , add t h e P a r t B i n g r e d i e n t s i n o r d e r and b e g i n c o o l i n g . Add t h e P a r t C i n g r e d i e n t s a t approx- i m a t e l y 40C.

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s Formula A-1 12

Shampoos 257

Opaque Antidandruff Shampoo

Water Wt%

6 5 . 3 Veegum, Magnesi um A1 umi num S i 1 i c a t e 1 . o Hydroxyp ropy l M e t h y l c e l l u l o s e 1 . 1 Z i n c P y r i t h i o n e , 48% ( Z i n c Omadine) 4 .2 C i t r i c Acid, 50% 0 . 4 Sodi um L a u r y l E t h e r S u l f a t e 1 8 . 0 Cocamide DEA 5 . 0 Sodi um L a u r y l Sa rcos i n a t e 1 . o Hydro1 yzed Col 1 agen 2 . 0 FD&C B l u e No. 1 , 0 . 2 % 1 . 5 FD&C Ye1 l o w No. 5, 01 . % 0 . 5 Fragrance 9 , s . Procedure :

Heat t h e water t o 70C. Beg in and m a i n t a i n r a p i d s t i r r i n g (1 ,500 rpm) d u r i n g t h e add ing o f i n g r e d i e n t s . Add t h e Veegum and s t i r 15 m inu tes . Add t h e h y d r o x y p r o p y l m e t h y l c e l l u l o s e and s t i r an a d d i t i o n a l 15 m inu tes . Add t h e Z i n c Omadine and s t i r 5 m i n u t e s . Reduce speed t o 300 rpm. Add t h e c i t r i c a c i d and s t i r u n t i l mixed. Tu rn o f f h e a t . W h i l e c o o l i n g , add t h e o t h e r i n g r e d i - e n t s ( e x c e p t f r a g r a n c e ) i n t h e o r d e r l i s t e d . S t i r u n t i l m ixed a f t e r each a d d i t i o n . Weigh back and add wa te r t o make up f o r e v a p o r a t i o n l o s s e s . Cool t o room tempera tu re , s t i r r i n g s l o w l y . Add f r a g r a n c e . A d j u s t pH t o 8 .

Formula f rom O l i n Corp.

Ultra Pearlescent Conditioning Shampoo

T h i s 1 u x u r i ous shampoo f o r m u l a i s t h i c k e n e d u s i ng Veegum U l t r a wh ich a l s o suspends t h e mica p igment t h a t p r o v i d e s pear lescence . Vanseal CS ( c o c o y l s a r c o s i n e ) p r o v i d e s m i l d n e s s and h a i r c o n d i t i o n i n g p r o p e r t i e s w h i l e comb in ing w i t h l a u r a m i d e DEA t o marked ly enhance t h e q u a l i t y and s t a b i l i t y o f t h e l a t h e r p roduced d u r i n g shampooing.

A : Veegum U1 t r a , Magnesi um A1 umi num S i 1 i c a t e 2 . 0 0 D e i o n i z e d Water 61 - 2 5

B: M ica (and) T i t a n i u m D i o x i d e (T imeron MP-1001) 0 .50 C : Sodium L a u r e t h S u l f a t e 2 5 . 0 0

Laurami de DEA (Monami d 71 6 ) 7 .50 Vanseal CS, Cocoyl Sa rcos ine 3 .75 P r e s e r v a t i v e , dye, f r a g r a n c e 9 , s .

S i f t Veegum U l t r a i n t o t h e wa te r w h i l e m i x i n g a t 700 rpm Procedure :

w i t h a p r o p e l l e r s t i r r e r . A d j u s t t h e p r o p e l l e r speed t o 1500- 1700 r p m and m ix f o r 30 m i n u t e s . Add t h e B i n g r e d f o r 5 m inu tes . A d j u s t t h e speed t o 200 t o 500 rpm i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g a f t e r each smooth and u n i f o r m .

Formula No. 452

SOURCE: R . T . V a n d e r b i l t Co., I n c , : Veegum Formu la t

e n t s and m i x and add t h e C a d d i t i o n u n t i

ons


Pearlescent Shampoo

Three c o l o r v a r i a n t s u s i n g t i t a n a t e d mica p e a r l p igments a r e suggested w i t h t h i s shampoo f o r m u l a .

__ W t %

H y d r o x y p r o p y l c e l l u l o s e (5% aq. S o l n . ) ( K l u c e l G) 20 .oo

A : Veegum HV, Magnesium Aluminum S i l i c a t e (5% aq. Susp.) 14.00

D i s t i l l e d Water 6 . 0 0

B: D i s t i l l e d Water TEA L a u r y l S u l f a t e (S tandapo l T)

C : C i t r i c A c i d D i s t i l l e d Water

q . s . t o 100.00 2 5 . 0 0

0 . 1 0 2 - 0 0

D :

D i azo1 i d i n y l Urea (Germal l I I ) 0.30 T i t a n i u m D i o x i d e (and) M ica ( T i m i r o n Super Go ld o r

Cocamidopropyl B e t a i n e ( V e l v e t e x BA-35) 5 . 0 0 Cocamide DEA (Standamid KD) 3 . 0 0

Me thy l Paraben 0 . 2 0

Super Red) 0 . 2 0

E : Water S o l u b l e Dyes:

(w/ red p e a r l ) 0 .2% aq D&C Red 33 ( w / g o l d p e a r l ) 0 .02% FD&C B l u e 1

Ye1 low 5 ( o r ) 0 .02% FD&C B l u e 1 ( o r ) D&C Red 33

0 . 2 5 0 . 3 0 0.40 1 . oo 2 . 0 0

Procedure :

A . Homogenize u n t i l no und ispe rsed p a r t i c l e s remain . Con t inue b a t c h w i t h s idesweep a g i t a t i o n . Add B i n o r d e r . Combine C, add t o b a t c h . Combine D; add t o b a t c h . Add E, i n s u r i n g t h a t each i s w e l l d i s p e r s e d b e f o r e p roceed ing .

SOURCE: R . T . V a n d e r b i l t Co., I n c , : Veegum Formula f r o m Rona

Prepare t h e p a r t A d i s p e r s i o n and s o l u t i o n i n advance; combine

Shampoos 259

Pearlescent Shampoo

T i t a n a t e d mica p e a r l p igments can g i v e un ique " two c o l o r " i r i d e s c e n t e f f e c t s , w i t h appearance chang ing w i t h a n g l e o f v i ewi rig,

A : Veegum HV, Magnesi um A1 umi num S i 1 i c a t e , (5% aqueous

susp. ) 14.00 Hydroxyp ropy l c e l l u l ose (5% aq. So l n . ) (K1 u c e l G) 20.00 D i s t i l l e d Water 6 . 0 0

B : D i s t i l l e d Water TEA L a u r y l S u l f a t e (S tandapo l T)

q . s . t o 100.00 35.00

C : Coco-Betaine (Dehyton AB30) 10.00 Cocami de DEA (Standami d KD) 1 . oo H y d r o x y c e t y l Hyd roxye thy l Dimonium C h l o r i d e (Dehyquar t E ) 2 . 0 0

D: D i azo1 i d i n y l Urea (Germal l I I ) D i s t i 11 ed Water

E : T i t a n i u m D i o x i d e (and) M ica ( T i m i r o n MP-1001) 0.02% D&C Red No. 33 0.02% FD&C B l u e No . 1

0.25 0 . 5 0

0 . 2 0 2 . 0 0 1 . o o

Procedure :

u n t i 1 no und i spersed p a r t i c l es remai n. Cont inue b a t c h w i t h sidesweep a g i t a t i o n . Add B i n o r d e r . Add C t o b a t c h i n o r d e r , m i x i n g each w e l l . Combine D; add t o b a t c h . Add E i n o r d e r , i n s u r i n g t h a t each i s we1 1 d i spersed b e f o r e p roceed i ng .

SOURCE: R.T. V a n d e r b i l t Co., I n c . : Veegum Formula f r o m Rona

Prepare t h e d i s p e r s i o n s i n advance; combi ne A . Homogenize


Pearlescent Shampoo

Phase .&l 1 5% Veegum HV suspens ion (as ) 1 5% K l u c e l G s o l u t i o n (aq) 1 D i s t i 11 ed wa te r

2 D i s t i 1 l e d wa te r 2 S tandapo l T (TEA l a u r y l s u l f a t e )

3 C i t r i c A c i d 3 D i s t i 11 ed wa te r

4 Sodium C h l o r i d e 4 D i s t i l l e d wa te r

5 Me thy l paraben 5 Germal l I 1

Wt% 14.00 2 0 . 0 0 6.00

1 2 . 3 0 25.00

0 .10 2 .00

2 . 0 0 10.00

0.20 0 . 3 0

6 T i 02/mi ca ( e . g . T i m i r o n Super Go1 d) 0 .10 -0 .30

7 Vel v e t e x BA-35 5 .00

8 Standamid KD 3 . 0 0

9 Water s o l u b l e dyes 9 , s .

Procedure : Prepare t h e Veegum and K l u c e l d i s p e r s i o n s i n advance, combine

phase # l a Homogenize u n t i l no und ispe rsed p a r t i c l e s remain . Combine b a t c h w i t h sidesweep a g i t a t i o n . Add phase #2 i n g r e d i e n t s i n o r d e r . Combine phase #3; add t o b a t c h . Combine phase #4; add to b a t c h . Add rema in ing i n g r e d i e n t s i n o r d e r , i n s u r i n g t h a t each i s d i s p e r s e d b e f o r e p r o c e e d i n g .

SDl-67-1A: C o l o r Combi n a t i ons : 0 . 2 0 % T i m i r o n Super Red 0.25% D&C Red #33 ( 0 . 0 2 % aq)

SD1-67-1 B: C o l o r Combi n a t i o n s : 0 . 2 0 % T i m i r o n Super G o l d 0.30% FD&C B l u e #1 (0 .02% as) 0.40% FD&C Y e l l o w #5 ( 0 . 0 2 % aq)

SD1-67-1 C: C o l o r Combi n a t i ons : 0 . 2 % T i m i r o n Super Go ld 1.0% FD&C B l u e #I ( 0 . 0 2 % aq) 2 . 0 % D&C Red #33 (0 .02% aq)

SD1-67-1 E : C o l o r Combi n a t i o n s : 0 . 2 % T i m i r o n Super V i o l e t 1 .0% FD&C B l u e #1 ( 0 . 0 2 % aq) 2 .0% D&C Red #33 ( 0 . 0 2 % aq)

SD1-67-11; C o l o r Combinat ions : 0 . 2 0 % T i m i r o n MP-1001 1.00% FD&C B l u e #1 ( 0 . 0 2 % aq) 2 .00% D&C Red #33 (0.02% aq)

C o l o r Combinat ions : 0.20% T im i r o n Super S i 1 v e r 0.10% FD&C B l u e #1 (2% aq)

SD1-67-1 J:

SOURCE: Rona/EM I n d u s t r i e s , I n c . : F o r m u l a t i o n SD1-67-1

Shampoos 261

Pearlescent Shampoo

I n g r e d i e n t s : CalB1 end P e a r l F ragrance, Dye, P r e s e r v a t i v e Sodium C h l o r i d e Water

Weight% 30.00

Q.S, 1 .oo-2.00

68 .50

Comments about t h i s f o r m u l a : B1 end i ng Procedure :

M i x u n t i l u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s - e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 4,000-7,000 cPs (No. 4 S p i n d l e @ 10rpm) w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e as needed.

Charge wa te r i n t o m i x i n g vesse l and s l o w l y b l e n d i n P e a r l .

T y p i c a l F o r m u l a t i o n P r o p e r t i e s : Appearance: Whi te , P e a r l e s c e n t L i q u i d V i s c o s i t y @ 25C: 4,000-7,000 cPs

% Non V o l a t i l e s : 12 .5-13 .5 pH: 6.0-7.0


B e t a i n e , G l y c o l S t e a r a t e , Fragrance, P r e s e r v a t i v e , PEG-45MJ C i t r i c A c i d , D y e ( s ) .

Water, Sodium L a u r e t h S u l f a t e , Cocamide DEA, Cocamidopropyl

F o r m u l a t i o n SHM-020-01

Basic Shampoo Gel

I n a r e d i e n t s : Ca l foam ES-303 Calamide F Sodium C h l o r i d e Water

Wei ah t% 42.86

3 .00 3 . 0 0

51 . 1 4

Comments about t h i s f o r m u l a : 1 . The v i s c o s i t y o f t h i s f o r m u l a i s 125,000 CPS. A t 2 .5% s a l t ,

t h e v i s c o s i t y i s 96,000 cPs. 2 . I n c r e a s i n g t h e amide p r o v i d e s f o r h i g h e r v i s c o s i t i e s a t l o w e r

s a l t l e v e l s . Fo r example, a t 4% amide, a v i s c o s i t y o f 112,000 cPs i s reached a t 1.5% s a l t , and 230,000 cPs i s reached a t 2% s a l t . F o r m u l a t i o n SHM-018-01



Pearlescent Shampoo

A p e a r l i z e d shampoo u t i l i z i n g P a t i o n i c I S L f o r m i l d n e s s and R i t a p a n DL f o r c o n d i t i o n a l f e e l .

I n g r e d i e n t s : 1 . P a t i o n i c I S L (Sodium I s o s t e a r o y l L a c t y l a t e ) 2 . R i t a p e g 150 DS (PEG-150 D i s t e a r a t e ) 3 . R i t a EGDS ( G l y c o l D i s t e a r a t e ) 4 . Sodium L a u r e t h S u l f a t e (S tandapo l ES-2) 5 . D i s t i 11 ed/Dei o n i zed Water 6 . Me thy lpa raben 7 . R i t a p a n DL ( P a n t h e n o l ) 8 . Laneto-50 (PEG-75 L a n o l i n ) 9 . P r o p y l e n e G l y c o l 10.Per fume 11 .Ka thon CG 12.NaC1 (25% S o l n . )

zw/w 2 .25 0 . 7 5 2 . 0 0

53 .60 37.45

0 . 1 5 0 . 2 5 0 I 7 5 2.50 0 . 2 0 0 .10

Q . S .

Compoundi ng P rocedure : Heat i t e m s 1-7 t o 70-75C. Add i t e m s 8 and 9 . Cool t o 40-45C.

Add i t e m s 10-12. R e f . No. 122-104

Salon Conditioning Shampoo

O p t i m i z e d c o n d i t i o n i n g l e v e l i s a c h i e v e d t h r o u g h use o f a P o l y q u t a C a t i o n i c Polymer and R i t a p a n DL ( P r o - V i t a m i n 6-5).

I n q r e d i e n t s : 1 . Sodi um L a u r e t h - 2 S u l f a t e (S tandapo l ES-2) 2 , P a t i o n i c I S L (Sodium I s o s t e a r o y l L a c t y l a t e ) 3 . R i t a p e g 150 DS (PEG-I50 D i s t e a r a t e ) 4 . R i t a p a n DL ( d l - P a n t h e n o l ) 5 . Laneto-50 (PEG-75 Lano l i n ) 6 . P o l y q u t a 400 ( P o l y q u a t e r n i u m - 1 0 ) 7 . Kathon CG 8 . F rag rance-Na tu re H a r v e s t 165-050 9 . D i s t i 11 ed/Dei o n i zed Water 10.Amandul ine S . G . ( H y d r o l y z e d Sweet Almond P r o t e i n )

40.00 3 .00 0 . 5 0 0 . 5 0 0 .75 0 . 5 0 0 . 0 3 0 . 3 0

49.42 5 . 0 0


u n i f o r m . Then add i t e m 4 , 2, 1, and 5 i n o r d e r and m i x u n t i l u n i f o r m . Cool t o 120F. Add i t e m s 7, 8 and 10.

D i s p e r s e i t e m 6 i n w a t e r a t 165F. Add i t e m 3 and m i x u n t i l

R e f . No. 121-178

SOURCE: R . I . T , A . C o r p . : Suggested F o r m u l a t i o n s

Shampoos 263

Pearlized Conditioning Shampoo

(cold process) with Amilan GST 40

I n q r e d i e n t s : Water T e t r a s o d i um EDTA Sodi urn L a u r y l S u l f a t e (28%) Sodium L a u r e t h S u l f a t e ( 2 8 % 2M. E . O . ) PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) D ime th i cone C o p o l y o l ( A b i l B 88183) Quatern ium-80 ( A b i l Quat 3272) Cocamidopropyl B e t a i n e (Tego B e t a i n e F) DATEM ( A m i l a n GST 40) G l y c o l D i s t e a r a t e and S t e a r e t h - 4 (Tego P e a r l N 1 0 0 ) P r e s e r v a t i v e s C o l o r F rag rance Sodium C h l o r i d e (25% S o l u t i o n ) C i t r i c A c i d (10%) A d j u s t t o pH 5 . 5 - 6 .

Weight_% 46 .00

0 . 1 0 20 .00 2 0 . 0 0

1 . o o 1 . o o 0 . 4 0 7 . 5 0 1 . 5 0 2 . 5 0

Q . S Q. S Q . S

V i s c . A d j 0 i f needed

Procedure : 1 . Add i n g r e d i e n t s i n o r d e r - m i x i n g between a d d i t i o n s . 2 . A d j u s t v i s c o s i t y w i t h t h e Sodium C h l o r i d e .

SOURCE: Go ldschmid t Chemical C o . : Suggested F o r m u l a t i o n


I j g r _ e d i e n t s : Carbopol ETD 2020, 1 . 5 % D i sod1 utn EDTA Cal foam T i s - 4 0 Calamide C

Wei y h t% 77 .70 0.10

20.00 2.00

Comments about t h i s f o r m u l a : 1 . A 1 . 5 % s o l u t i o n i n w a t e r i s p r e p a r e d by d i s s o l v i n g t h e

2 . The d i s p e r s i on i s s l i g h t l y hazy i'ii t h g e l - 1 1 ke c o n s i s t e n c y . 3 . P r o b a b l y even a 1% s o l u t i o n wou ld be s u i t a b l e f o r t h i s

4 . The i n g r e d i e n t s a r e g r a d u a l l y added i n t o t h e Carbopol

5 . The b l e n d t u r n s c l e a r upon Calfoani TLS-40 a d d i t i o n . 6 . S t i r u n t i l t h e b l e n d i s homogeneous. 7 . W i t h o u t a d j u s t m e n t t h e pH i s 5-6.


Carbopol a t 4 0 C .

app l i c a t i on .

so! u t i on .


Pearl Pigment Shampoo

Veegum HV, Magnesium Aluminum S i l i c a t e & ( K 1 u c e l G) H y d r o x y p r o p y l C e l l u l ose S o l u t i on TEA L a u r y l S u l f a t e (Texapon 1 4 2 ) C i t r i c Ac id Sodium C h l o r i d e P r e s e r v a t i ve S i comet Amaranth 85 E123 o r S icomet B l u e S 42045

T i t a n i u m D i o x i d e (and) M ica (T imeron MP 1001 o r

Cocamidopropyl B e t a i n e (Dehyton K ) Cocami de DEA ( Comper 1 an KD) Water demi n e r a l i zed Procedure:

C o m p o s i t i o n o f Veegum/Kl u c e l Suspension : A ) Veegum HV ( 5 % ) 35%; 8) K l u c e l G (5%) 50%; Water 15%.

F o r t h e Veegum HV Suspension (A ) h y d r a t e 5% Veegum HV i n w a t e r , f o l l o w e d b y homogen iza t i on w i t h ( e . g . ) an U l t r a T u r r a x . Fo r t h e K l u c e l G s o l u t i o n (B) add 5% K l u c e l G t o t h e approp- r i a t e amount o f w a t e r s t i r r i n g c o n t i n u o u s l y . T h i s i s f o l l o w e d by t h e a d d i t i o n o f a p r e s e r v a t i v e , e . g . Germa l l 115. Then t h e s o l u t i o n i s a l l o w e d t o s w e l l f o r abou t 1 2 h o u r s . The s t o c k suspens ion (A ) and s o l u t i o n (B ) a r e m ixed as a s s i g n e d (A:35%, B:50%, C:15% w a t e r ) and homogenized. To t h e r e s u l t i n g Veegum/ K l u c e l suspens ion a l l o t h e r components a r e added i n t h e o r d e r a s i n d i c a t e d , w h i l e s t i r r i n g . Developed b y D r . A . T h u r n - M u l l e r .

( D y e s t u f f Suspension 1%)

T imeron S.I. Pigmen ts )

Formula f r o m E . Merck

4 0 . 0 2 5 . 0

0 . 1 2 . 0 0 . 2

0 .5 -0 .2

0.1-0.2

0 . 1 - 0 . 2 5 . 0 3 . 0 q . s .

Pearlescent Conditioning ShampooM

A : Veegum HV, MAS (5% D i s p . ) 14.00 H y d r o x y p r o p y l C e l l u l o s e ( 5 % S o l n . ) (K1 u c e l G) 2 0 . 0 0 D i s t i 1 l e d Water 11 .50

8 : Sodium L a u r y l S u l f a t e (S tandapo l WAQ Spec.) 30.00 H y d r o l y z e d C o l l a g e n ( N u t r i l a n L) 10 .oo

C : Sodium C h l o r i d e 1 . o o D i s t i l l e d Water 1 . 5 5

0: D i a z o l i d i n y l Urea (Germa l l 11) 0 . 2 0 D i s t i 11 ed Water 1 . 5 5

E : T i t a n i u m D i o x i d e (and ) M i c a (T imeron Super Go ld ) 0 . 2 0 Coco-Beta ine (Dehyton AB30) 10 .00 Water s o l u b l e dyes, o p t i o n a l q . s .

Procedure: P repare d i s p e r s i o n s i n advance; combine A . Homogenize u n t i l

no u n d i s p e r s e d p a r t i c l es remai n . C o n t i nue b a t c h w i t h s i desweep a g i t a t i o n . Add 8, i n o r d e r . Combine C, add t o b a t c h . Combine D, add t o b a t c h . Add E i n o r d e r , i n s u r i n g t h a t each i s d i s p e r s e d b e f o r e p r o c e e d i n g .

Formula f r o m Rona

SOURCE: R . T . V a n d e r b i l t Go., I n c . : Veegum F o r m u l a t i o n s

Shampoos 265

Salon Conditioning Shampoo

O p t i m i z e d c o n d i t i o n i n g l e v e l i s a c h i e v e d t h r o u g h use o f a P o l y q u t a C a t i o n i c Polymer and R i t a p a n DL ( P r o - V i t a m i n 6-51) I

I n a r e d i e n t s : 1 . Sodi urn L a u r e t h - 2 S u l f a t e (S tandapo l ES-2) 2 . P a t i o n i c I S L (Sodium I s o s t e a r o y l ' L a c t y l a t e ) 3 . R i t a p e g 150 DS (PEG-150 D i s t e a r a t e ) 4 . R i t a p a n DL ( d l -Pantheno1 ) 5 . Laneto-50 (PEG-75 Lanol i n) 6 . P o l y q u t a 400 (Po lyquatern ium-10) 7 . Sodium C h l o r i d e (25% S o l n . ) 8 . Kathon CG 9 . Fragrance-Nature H a r v e s t 165-050 1 0 . D i s t i l l e d Water 1 l . A m a n d u l i n e S . G . ( H y d r o l y z e d Sweet Almond P r o t e i n )

%w/w 54.35

3 . 0 0 1 .oo 0 . 2 5 0 . 7 5 0.50 0.25 0 . 0 3 0 .30

37.87 5 .00

Compounding Procedure :

u n i f o r m . Then add i t e m 4, 2, 1, 5 and 7 i n o r d e r and mix u n t i l u n i f o r m . Cool t o 120F. Add p r e s e r v a t i v e and per fume. A d j u s t v i s c o s i t y w i t h NaCl .

D i s p e r s e i t e m 6 i n w a t e r a t 165F. Add i t e m 3 and m i x u n t i l

R e f . No. 121-171


A r i c h shampoo c o n t a i n i n g Amandul ine SG and P a t i o n i c ISL f o r c o n d i t i o n i n g and h a i r r e p a i r .

I n a r e d i e n t s : 1 . Sodium L a u r e t h S u l f a t e 29% 2 . Sodium L a u r y l S u l f a t e 29% 3 . R i t a m i d e C (Cocamide DEA) 4 . P a t i o n i c I S L (Sodium I s o s t e a r o y l L a c t y l a t e ) 5 a D i s t i 11 ed/Dei o n i zed Water 6 . R i t a PEO-3 (PEG-23M) 7 . Amandul ine SG ( H y d r o l y z e d Sweet Almond P r o t e i n ) 8 . G l y d a n t

%w/w 2 5 . 0 0 20.00

5 .00 3 .50

40.80 0 .50 5 . 0 0 0 . 2 0

Compoundi ng Procedure:

m i x i n g u n t i l u n i f o r m . A l l o w t o c o o l t o 40C. Add i t e m s 7 and 8 . D i s p e r s e i t e m 6 i n t o i t e m 5 . Add i t e m s 1-4 and h e a t w h i l e

R e f . No. 121-161C

SOURCE: R . I . T . A . Corp . : Suggested F o r m u l a t i o n s


Shampoo All Purpose for Normal Hair

I n g r e d i e n t s : Water Cal foam ES-303 Cal t a i ne C-35

Weight% 5 0 . 0 0 40 .00

5 . 0 0 Calamide LL 1 . 5 0 C i t r i c A c i d 0 . 0 7

NaCl 2 .50 Comments abou t t h i s f o r m u l a :

F rag rance , Dye(s ) 0 . 0 0

1 . M i x t h e f i r s t f o u r i n g r e d i e n t s . 2 , Add C i t r i c A c i d t o a d j u s t t h e pH t o 5 . 5 - 6 . 5 . 3 . Add t h e r e p o r t e d amount o f s a l t . S a l t c o n t e n t can be

4 . F r a g r a n c e o r dye c o m p a t i b i l i t y were n o t e v a l u a t e d . F o r m u l a t i o n SHM-006-01

a d j u s t e d t o a c h i eve d e s i r e d v i s c o s i t y .

Shampoo All Purpose for Oily Hair

I n g r e d i e n t s : Wei g h t % Water 46 .00 Cal foam SLS-30 25 .00 Cal foam ES-303 2 5 . 0 0 Calamide LL 2.50 C i t r i c A c i d 0 . 1 0 F rag rance , Dye(s ) 0 . 0 0 NaCl 1 . o o Comments abou t t h i s f o r m u l a :

1 . M i x t h e f i r s t f o u r i n g r e d i e n t s . 2 . Add enough C i t r i c A c i d t o a d j u s t t h e p H t o 5 . 5 - 6 . 5 . 3 . F rag rance o r dye c o m p a t i b i l i t y was n o t e v a l u a t e d . F o r m u l a t i o n SHM-007-01

Shampoo-Inexpensive

I n g r e d i e n t s : Water NH4C1

Weight% 45 .70

1 . o o PEG-75 Lanol i n 0 . 3 0 Cal foam ALS-30 50 .00 Calamide C 3 . 0 0 P r e s e r v a t i ve 0 . 0 0 F rag rance , Dye 0 . 0 0 Comments abou t t h i s f o r m u l a :

1 . The i n g r e d i e n t s s h o u l d be mixed i n o r d e r r e p o r t e d . 2 . I f needed, a d j u s t pH t o 5 . 5 - 6 . 5 w i t h C i t r i c A c i d . F o r m u l a t i o n SHM-009-01

SOURCE: P i 1 o t Chemical Co, : Suggested Formul a t i ons

Shampoos 267


I n g r e d i e n t s : Carbopol ETD 2020 ( 1 - 5 % ) D i sod i um EDTA Cal foam TLS-40 Calamide C

O/oWt. 7 7 . 7 0

0 . 1 0 20 I O 0

2 . 0 0

Comments About t h i s Formula:

(Easy t o D i s p e r s e ) - 6 . F . G o o d r i c h

1 . A 1 .5% s o l u t i o n i n w a t e r i s p r e p a r e d by d i s s o l v i n g t h e Carbo-

2 . The d i s p e r s i o n i s s l i g h t l y hazy w i t h g e l - l i k e c o n s i s t e n c y . 3 . P r o b a b l y even a 1% s o l u t i o n would be s u i t a b l e f o r t h i s app-

4. The i n g r e d i e n t s a r e g r a d u a l l y added i n t o t h e Carbopol s o l -

5 . The b l e n d t u r n s c l e a r upon Cal foam TLS-40 a d d i t i o n . 6 . S t i r u n t i l t h e b l e n d i s homogeneous. 7 . W i t h o u t a d j u s t m e n t t h e p H i s 5 -6 .

Carbopol ETD 2020-Hydrophobi c a l l y Modi f i ed Po l y a c r y l i c Ac i d

p o l a t 40C.

1 i c a t i o n ,

u t i o n .

F o r m u l a t i o n #SHM-004-01


I n s r e d i e n t s : Carbopol ETD 2020 ( 1 . 5 % ) D i s o d i um EDTA Cal foam SLS-30 Cal foam ES-303 Calamide C

%Wt. 77 I 7 0

0 . 1 0 1 5 . 0 0

5 . 0 0 2 .00

Comments About t h i s Formula:

P o l y a c r y l i c Acid, 6 . F . G o o d r i c h

1 . A 1 .5% s o l u t i o n i s made by d i s p e r s i n g t h e Carbopol i n 40C

2 . The d i s p e r s i o n i s s l i g h t l y hazy w i t h g e l - l i k e c o n s i s t e n c y . 3 . P r o b a b l y even a 1% s o l u t i o n would be s u i t a b l e f o r t h i s app-

1 i c a t i on. 4 . The i n g r e d i e n t s a r e g r a d u a l l y added i n t o t h e Carbopol s o l -

u t i o n and s t i r r e d u n t i l a homogeneous p r o d u c t i s p r e p a r e d . F o r m u l a t i o n #SHM-005-01

Carbopol ETD 2020 (Easy t o D i spe rse ) -Hydrophob i c a l l y Modi f i ed

warm w a t e r and s t i r r i n g .

SOURCE: P i l o t Chemical Con : Formul a r y


Shampoo-Clear Liquid Conditioning

I n g r e d i e n t s : Water Cal foam ES-301 Cal t a i ne C-35 Cocami d o p r o p y l ami ne Ox ide Calamide C PEG-7 G1 y c e r y l Cocoate PEG-1 5 Cocopol yami ne F rag rance , Dye(s ) P r e s e r v a t i ve Comments abou t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s , one a t a t i m e , i n t h e o r d e r

2 . Adjust pH t o 6 . 5 + - 0 . 5 W i t h C i t r i c A c i d . 3 . Smal l a d d i t i o n o f s a l t can be used t o a d j u s t

a g i t a t i o n .


Shampoo-All Purpose

I n g r e d i e n t s : Water Cal foam ES-302 Cal t a i ne C-35 Calamide C NaCl Kathon CG Comments abou t t h i s f o r m u l a : 1 . M i x i n g r e d i e n t s as 1 i s t e d . 2 . A d j u s t pH t o 6 . 3 w i t h C i t r i c A c i d . 3 . Formula i s s i m i l a r t o SHM-006-0.


Shampoo-Clear Liquid

I n g r e d i e n t s : Water

Wei g h t % 55 .00 30 .00

6 .50 3 . 0 0 1 . 5 0 2 . 0 0 2 . 0 0 0 . 0 0 0 . 0 0

g i v e n , under

v i s c o s i t y .

Wei n h t % 51 . 2 0 40 I 00

5 . 0 0 3 .00 0 . 7 5 0 . 0 5

Wei g h t % 60.70

n-coco B e t a Amino P r o p i o n i c A c i d 7 . 0 0 Cal foam TLS-40 28.00 Calamide LL 4 .00 F r a g r a n c e 0 . 0 0 Sodium C h l o r i d e 0 . 2 5 Kathon CG 0 . 0 5 Comments abou t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s i n t h e o r d e r g i v e n under adequate a g i t a t i o n .

2 . A d j u s t t o pH 6 . 5 w i t h C i t r i c A c i d . 3 . Adequate a g i t a t i o n i s i m p o r t a n t - o t h e r w i s e g e l - l i k e p a r t i c l e s

( i f f r a g r a n c e i s added, p r e - m i x i t w i t h Calamide L L ) .

w i l l f o r m upon s t a n d i n g f o r a few d a y s . F o r m u l a t i o n SHM-013-01

SOURCE: P i 1 o t Chemical Co I : Suggested F o r m u l a t i o n s

Shampoos 269

Shampoo-Clear Viscous

I n g r e d i e n t s : Cal B1 end C1 e a r F rag rance , Dye, P r e s e r v a t i v e Sodium C h l o r i d e Water

W_ei g h t % 30 .00 Q.S

1 . 0 0 - 2 . 0 0 68.50

Comments abou t t h i s f o r m u l a : 81 e n d i n g P rocedure :

Charge w a t e r i n t o m i x i n g v e s s e l and s l o w l y b l e n d i n C l e a r . M i x u n t i l c o m p l e t e l y u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 3,000-5,000 CPS (No. 4 S p i n d l e @ 10 rpm) w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e as needed.

T y p i c a l F o r m u l a t i o n P r o p e r t i e s : Appearance: C l e a r , V i scous L i q u i d V i s c o s i t y @ 25C: 3,000-5,000 cPs

% Non V o l a t i l e s : 11 .5 -12 .5 pH: 6 . 0 - 7 . 0


B e t a i n e , Sodium C h l o r i d e , F rag rance , P r e s e r v a t i v e , C i t r i c A c i d , Water , Sodium L a u r e t h S u l f a t e , Cocamide DEA, Cocamidopropyl

D y e ( s ) . F o r m u l a t i o n SHM-019-01

Shampoo-Conditioning

I n g r e d i e n t s : Water Ca l foam SLS-30 Calamide LL Calamide C S i 1 i cone D i merami doquat EG Monos tea ra te NaCl P r e s e r v a t i v e , Dye, F rag rance*

Wei q h t % 57.85 35 .00

3 .00 0 . 5 0 2 . 0 0 0 .50 1 .oo 9 . 5 0

Comments abou t t h i s f o r m u l a : 1 . M i x i n g r e d i e n t s i n o r d e r r e p o r t e d w h i l e h e a t i n g t o abou t 60C. 2 . Cool b e f o r e add i ng f r a g r a n c e . 3 . Add p r e s e r v a t i v e and dye as needed. 4 . A d j u s t pH t o 6 w i t h C i t r i c A c i d .

*F rag rance , F rag rance #S-5704 - F i n e F l a v o r s & F rag rances , I n c Formu 1 a t i on SHM-0 1 7-0 1



Shampoo-Concentrate

I n g r e d i e n t s : Water P r o p y l ene G1 y c o l Cal foam TLS-40 Calamide C Calamide LL Cal foam ALS-30 C i t r i c A c i d NaCl

1 . 2 . 3 .

4 . 5 . 6 . 7 .

%Wt. 1 2 . 7 5 8 . 0 0

20 * 00 1 2 . 5 0 1 2 . 5 0 26.00

0 .75 7 . 5 0

Comments About t h i s Formula: M i x w a t e r and P r o p y l e n e G l y c o l . Add t h e n e x t t h r e e i n g r e d i e n t s i n t o t h e water/PG s o l u t i o n The l a s t s u r f a c t a n t added i s ALS-30; t h e b l e n d becomes v i scous I A d j u s t t h e pH w i t h C i t r i c A c i d (pH 6 - 7 ) . Add NaCl l a s t . The c o n c e n t r a t e i s v e r y v i s c o u s . Add Perfume, Dye(s) and P r e s e r v a t i v e as d e s i r e d . F i n i s h e d shampoo can be made by d i l u t i n g 1 p a r t c o n c e n t r a t e w i t h 7-15 p a r t s w a t e r . F o r m u l a t i o n #SHM-008-01

Shampoo Clear Liquid Conditioning

I n g r e d i e n t s : Water Cal foam ES-301 Cal t a i ne C-35 Cocami d o p r o p y l ami ne Ox ide Calamide C PEG-7 G l y c e r y l Cocoate PEG-1 5 Cocopol yami ne F rag rance , Dye(s ) P r e s e r v a t i ve

O/oWt. 5 5 . 0 0 30.00

6 . 5 0 3.00 1 .50 2 . 0 0 2 . 0 0 0 . 0 0 0 . 0 0

Comments About t h i s Formula: 1 . Add i n g r e d i e n t s , one a t a t i m e , i n t h e o r d e r g i v e n , under

2. A d j u s t pH t o 6 . 5 + - 0 . 5 w i t h C i t r i c A c i d . 3 . Smal l a d d i t i o n o f s a l t can be used t o a d j u s t v i s c o s i t y .

SOURCE: P i l o t Chemical Co . : Fo rmu la ry

a g i t a t i o n .


Shampoos 271

Shampoo-Concentrate

I n g r e d i e n t s : Water P ropy lene G1 y c o l Cal foam TLS-40 Calamide C Calamide LL Cal foam ALS-30 C i t r i c A c i d NaCl

Wei q h t % 12 .75 8 . 0 0

20 .00 12 .50 12 .50 26 .00

0 . 7 5 7 . 5 0

Comments abou t t h i s f o r m u l a : 1 . M i x w a t e r and P r o p y l e n e G l y c o l . 2 . Add t h e n e x t t h r e e i n g r e d i e n t s i n t o t h e water/PG s o l u t i o n . 3 . The l a s t s u r f a c t a n t added i s ALS-30; t h e b l e n d becomes v i s c o u s 4 . A d j u s t t h e pH w i t h C i t r i c A c i d (pH 6 - 7 ) . 5 . Add NaCl l a s t . The c o n c e n t r a t e i s v e r y v i s c o u s . 6 . Add Perfume, Dye(s) and P r e s e r v a t i v e as d e s i r e d . 7 . F i n i s h e d shampoo can be made by d i l u t i n g 1 p a r t c o n c e n t r a t e

w i t h 7-15 p a r t s w a t e r . F o r m u l a t i o n SHM-008-01

Shampoo-Cream

I n g r e d i e n t s : P a r t A : Cal foam SLS-30 S t e a r i c A c i d PEG-5 Soya S t e r o l

P a r t 0 : Water NaOH, 50% NaCl

Weight%

45 .00 7 . 5 0 1 . o o

43 .50 1 . 0 0 2 . 0 0

Comments abou t t h i s f o r m u l a : 1 . Heat P a r t A and P a r t B ( s e p a r a t e l y ) t o 70C w i t h a g i t a t i o n . 2 . Add P a r t A t o P a r t B . 3 . Cool w h i l e s t i r r i n g . 4 . Add Perfume, Dye(s) and P r e s e r v a t i v e as needed a t 45C. 5 . The E t h o x y l a t e d Soya S t e r o l p r o v i d e s a d e s i r a b l e a f t e r

shampoo sheen t o t h e h a i r . F o r m u l a t i o n SHM-012-01



Shampoo-Cream

I n g r e d i e n t s : Cal s o f t T-60 Calamide 0 Cal foam EA-603 S t e a r i c A c i d NaOH, 50% S o l u t i o n C i t r i c A c i d Water

%A 2 2 . 0 0

4 .75 1 6 . 0 0

7 . 0 0 0 . 5 0 0 .10

49 .65

Comments About T h i s Formula: 1 . M i x t h e f i r s t f o u r i n g r e d i e n t s t o g e t h e r . 2 . A p p l y h e a t t o m e l t t h e S t e a r i c A c i d (75C). 3 . Add C a u s t i c and C i t r i c A c i d i n t o w a t e r and h e a t t o about

60-7OC. 4. Add t h e s o l u t i o n i n t o t h e s u r f a c t a n t b l e n d w i t h s t i r r i n g . 5 . Cool t h e p r o d u c t w h i l e s t i r r i n g . 6 . The p r o d u c t i s a s o f t cream


Shampoo

I n g r e d i e n t s : Water Cal foam SLS-30 Cal foam ES-303 Calamide C C i t r i c Ac id Sodium C h l o r i d e Perfume & Dye

S/oWt. 74 .45

5 . 0 0 16.00 2 .00 0 . 1 0 2 . 5 0 0 . 1 0

Comments About t h i s Formula: 1 . M i x t h e f i r s t f o u r i n g r e d i e n t s (pH=lO). 2 . Add C i t r i c A c i d ( a p p r o x i m a t e l y 0.1%) t o a d j u s t pH t o about 6 . 3 . Add s a l t t o t h e d e s i r e d v i s c o s i t y . 4 . Perfume and dye as d e s i r e d .


SOURCE : P i 1 o t Chemi c a l Co. : Formul a r y

Shampoos 273

Shampoo with Silicone

Stane M a t e r i a1 : Q u a n t i t y S tage A : 1 Water; Pure 47,3909 2 Polymer JR 400 0.5009 3 Kathon CG 100 0.1009 Stage B: 4 Sodium L a u r e t h S u l p h a t e (SLES) 18 , ooog 5 Empico l TL 4 0 t 17 ,5009 6 Texapon SBN 9.5009 Stage C : 7 Empi lan EGMS 1.ooog 8 Emp i lan LDE 2 . ooog Stage D: 9 AEC D ime th i cone ( & ) L a u r e t h - 4 ( a ) Laure th -23 4. OOOg Stage E: 10 Sodium H y d r o x i d e 33% 0.01og M i x i n g I n s t r u c t i o n s :

add Kathon. Weigh o u t w a t e r and s t a r t h e a t i n g . D i s p e r s e Polymer JR and

Add i t e m s o f P a r t B and b r i n g t o 65/70C. S t i r i n i t e m s o f P a r t C and s t i r u n t i l d i s s o l v e d , more h e a t i n g

may be r e q u i r e d . Add S i l i c o n e CM2139-D1 and S i l v e r s o n m ix - do n o t i n t r o d u c e

a i r - A d j u s t pH. Cool w i t h s l o w s t i r r i n g . SOURCE: A & E Connock L t d . : P r o j e c t JW 2465/Formula R e f . : 1067*0

Gentle Everyday Shampoo

T h i s m i l d shampoo i s s u i t a b l e f o r eve ryday use. A c l e a r , wa te r -wh i t e , v i s c o u s shampoo w i t h e x c e l 1 e n t h e a t s t a b i 1 i t y .

I n g r e d i e n t s : Wei a h t % D i s t i 11 ed w a t e r 9 , s . t o 100.00 Sodi um 1 a u r e t h s u l f a t e , 28% 1 9 . 6 0 Cocami d o p r o p y l b e t a i n e , 35% 11 .oo Sodi um l a u r o y l s a r c o s i n a t e , 30% 9 .60 PEG-1 50 d i s t e a r a t e 2 -90 Benecel MP 943 R 1 . 1 0 Methylchloroisothiazolinone and m e t h y l i s o t h i a z a o l i n e ,

1 .5% 0 . 0 8 P rocedure : 1 . D i s p e r s e t h e Benecel by a d d i n g t o t h e v o r t e x o f w e l l - a g i t a t e d

w a t e r . H e a t i n g t o 40-45C w i l l a c c e l e r a t e h y d r a t i o n . M ix u n t i l f u l l y d i s s o l v e d .

add i t i on.

o l v e d . Tu rn h e a t o f f .

p r e s e r v a t i v e .

2 . Add t h e s u r f a c t a n t s , one a t a t i m e , m i x i n g w e l l between each

3 . Heat t o 70-75C. Add t h e PEG-150 d i s t e a r a t e . M i x u n t i l d i s s -

4 . When t e m p e r a t u r e reaches 40C o r be low, add f r a g r a n c e and

SOURCE: Aqua1 on : B u l l e t i n VC-526D: Per formance o f Benecel


Temporary Color-In Shampoo

I n g r e d i e n t s : Wei g h t % Phase A : Water 36 .40 T e t r a s o d i u m EDTA 0 . 0 5 Cocamidopropyl B e t a i n e (Tego B e t a i n e E ) 7 . 0 0 L a u r y l G1 u c o s i d e (Tego G1 u c o s i d 121 6) 6 . 5 0 P r o p y l e n e G1 y c o l 1 . 2 5 PEG-18 G l y c e r y l O l e a t e Cocoate ( A n t i 1 171) 2 . 0 0 Cocami d o p r o p y l ami ne Ox ide ( A m i n o x i d WS 35) 5 .00 Quatern ium-80 ( A b i l Quat 3272) 0 . 3 0 D i s o d i um Cocoamphodi p r o p i o n a t e 1 8 . 0 0 Phase B: PEG-7 G l y c e r y l Cocoate ( T e g o s o f t GC) 2 . 5 0 B a s i c B l u e 99 1 B a s i c Brown 16 ) B l e n d as needed A c i d V i o l e t 43 ) f o r c o l o r 1 . o o B a s i c Red 76 1 B a s i c Y e l l o w 57 ) Water 20 .00 Phase C: F rag rance Q . S . P r e s e r v a t i v e s Q . S . Phase D: C i t r i c A c i d 25% S o l u t i o n t o pH 6 . 5 P rocedure : 1 . Heat t h e w a t e r o f Phase A t o 50C. Add t h e r e m a i n i n g i n g r e d i -

e n t s o f Phase A i n o r d e r , m i x i n g between a d d i t i o n s . 2 . Combine t h e i n g r e d i e n t s o f Phase 0 . M i x u n t i l u n i f o r m . 3 . Combine t h e i n g r e d i e n t s o f Phase C . M i x . Heat t o 50C. 4 . Add Phase B t o Phase C . M i x w e l l . 5 . Add Phase B/C t o Phase A . M i x . 6 . Cool t o 40C. A d j u s t pH and f r a g r a n c e . SOURCE: Go ldschmid t Chemical Corp. : Suggested F o r m u l a t i o n s

Shampoo-Cream

I n g r e d i e n t s : Cal s o f t T-60 Calamide 0 Cal foam EA-603 S t e a r i c A c i d NaOH, 50% S o l u t i o n C i t r i c A c i d Water Comments abou t t h i s f o r m u l a : 1 . M i x t h e f i r s t f o u r i n g r e d i e n t s t o g e t h e r . 2 . A p p l y h e a t t o m e l t t h e S t e a r i c A c i d (75C) . 3 . Add C a u s t i c and C i t r i c Ac id i n t o w a t e r and h e a t

4 . Add t h e s o l u t i o n i n t o t h e s u r f a c t a n t b l e n d w i t h 5 . Cool t h e p r o d u c t w h i l e s t i r r i n g . 6 . The p r o d u c t i s a s o f t cream. SOURCE: P i 1 o t Chemical Co I : Formula SHM-001-01

60-7OC.

Weight% 22.00

4 . 7 5 1 6 . 0 0

7 . 0 0 0 . 5 0 0 . 1 0

49 .65

t o about

s t i r r i ng .

Shampoos 275

Transparent Shampoo

M i r a c a r e MPC C i t r i c A c i d ( t o pH 5 . 5 - 6 . 5 ) F rag rance , Dye(s) , P r e s e r v a t i v e Sodium C h l o r i d e Water

Wei q h t % 2 5 . 0 Q.S. Q.S.

0 . 6 - 1 . 6 7 4 . 0

81 e n d i n g P rocedure :

MPC. M ix u n t i l c o m p l e t e l y u n i f o r m . A d j u s t f o r m u l a t i o n pH t o 5 . 5 - 6 . 5 w i t h C i t r i c Ac id as needed. Add c o m p a t i b l e F rag rance , Dye(s ) , and P r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o d e s i r e d c o n s i s t e n c y w i t h t h e j u d i c i o u s a d d i t i o n o f Sodium Ch lo - r i d e as needed.


T y p i c a l F o r m u l a t i o n P r o p e r t i e s : Appearance (3 25C: C l e a r L i q u i d V i s c o s i t y (3 25C: 4,000-6,000 cps

% Non V o l a t i l e s : 10-12 pH: 5 .5 -6 .5


Cocami d o p r o p y l B e t a i ne, F rag rance , P r e s e r v a t i v e , C i t r i c A c i d, D y e ( s ) .

SOURCE: Rhone Poulenc S u r f a c t a n t s & S p e c i a l t i e s : Formula 91-1008

Water, Sodium L a u r e t h S u l f a t e , Cocamide DEA, Sodium C h l o r i d e ,

Shampoo

Water Cal foam SLS-30 Cal foam ES-303 Calamide C C i t r i c Ac id NaCl F rag rance , Dye

P i l o t Formula #SHM-003-01

Weight% 74.40

5 . 0 0 16 .00

2 . 0 0 0 . 1 0 2 .50

Q.S.

All Purpose Shampoo

Water Cal foam ES-302 Cal t a i ne C-35 Calamide C NaCl Kathon CG

P i l o t Formula #SHM-010-01

Weight% 51 . 2 0 40 .00

5 . 0 0 3 .00 0 . 7 5 0.05

SOURCE: P i l o t Chemical Cor : Persona l Care F o r m u l a t i o n s


Water White Shampoo from a Blend

Agent 1829-50* Sodium C h l o r i d e D. I. Water DMDM H y d a n t o i n C i t r i c A c i d (50%) Sodium C h l o r i d e

% by Wei a h t 25.00

0 . 5 0 Q . S . t o 100 .00

0 . 2 0 0 . 1 1

Q. S


w i t h 50% c i t r i c a c i d . M i x f i r s t f o u r i n g r e d i e n t s t o g e t h e r . A d j u s t p H t o 6 . 5 - 7 . 0

A d d i t i o n a l sodium c h l o r i d e may be added t o i n c r e a s e v i s c o s i t y .

* C o n t a i n s Ammonium L a u r y l S u l f a t e , Sodium L a u r e t h S u l f a t e , Lauramide DEA, C i t r i c A c i d

Premium Water White Shampoo

Stepan-Mi 1 d LSB S t e o l CS-330 Amphosol CA N i n o l 4 0 4 0 D . I . Water C i t r i c Acid (50%) Kathon CG Sodium C h l o r i d e

% by Wei p h t 2 5 . 0 1 0 . 0 1 0 . 0

3 . 0 Q.S. t o 100.0

Q . S . 0 . 0 6 Q.S.

M i x i n g P rocedure :

w i t h c i t r i c a c i d . Add p r e s e r v a t i v e . M i x f i r s t f i v e i n g r e d i e n t s t o g e t h e r . A d j u s t p H t o 6 . 5 - 7 . 0

Sodium c h l o r i d e may be added t o i n c r e a s e v i s c o s i t y .

Water White Shampoo

D . I . Water Stepan-Mi 1 d LSB S t e o l CA-130 N i n o l 96-SL DMDM Hydan to i n C i t r i c A c i d (50%) Sodium C h l o r i d e

% by Weiaht Q.S. t o 100.0

2 4 . 0 15 .4

2 . 0 0 . 2 5 Q.S . 1 . o

M i x i ng P rocedure : M i x f i r s t f o u r i n g r e d i e n t s t o g e t h e r w i t h h e a t . ( H e a t i n g t o

150F) . M i x f o r 30 m i n u t e s . Cool t o room t e m p e r a t u r e w i t h m i x i n g . Add DMDM H y d a n t o i n and a d j u s t pH t o 5 .5 -6 .5 w i t h c i t r i c a c i d . V i s c o s i t y can be a d j u s t e d w i t h a d d i t i o n a l sodium c h l o t i d e .


Shampoos 277

3 in 1 Antidandruff Shampoo 17.2% active ingredient

Reci pe : A O c t o p i r o x

B Water

C Genapol LRO l i q u i d Hostapon KCG Genamin KSL C e t i o l HE B e l s i 1 DMC 6032 Merquat 550 Fragrance

D Water

E Glucamate DOE 120

F Genagen CAB Genapol L-3 Genapol TSM

Procedure : 1 M i x A w i t h 8 . 2 Add t h e components o f C t o 1 and s t i r w e l l . 3 D i s s o l v e E i n D, add t o 1 and s t i r w e l l . 4 S t i r t h e components o f F one a f t e r a n o t h e r i n t o 1 5 A d j u s t t h e pH t o 6 . 0

Formula BI /6142

Wei a h t % 0 . 4 0

10 .00

30.00 5 .00 2 . 0 0 1 . o o 2 . 0 0 5 . 0 0 0 .30

30.30

1 . o o

8 . 0 0 2 - 0 0 3.00

H a i r Shampoo For daily use, clear, 15.8% active ingredient

Rec ipe : Wt% A Genapol LRO l i q u i d 30.00

B Genapol AMG Hostapon KCG Fragrance Water D y e s t u f f sol u t i on P r e s e r v a t i v e Genagen CAB Genapol L-3

8 .00 5 .00 0 . 3 0

46.70 q . s . 9 , s .

6 .00 2 . 0 0

C Sodium c h l o r i d e 2 . 0 0 Procedure : 1 S t i r t h e components o f B one a f t e r a n o t h e r i n t o A . 2 I f necessary a d j u s t t h e pH. 3 F i n a l l y a d j u s t t h e v i s c o s i t y w i t h C .

Formula BI /1130

SOURCE: Hoechs t : Guide Recipes f o r t h e Cosmet ic I n d u s t r y

Section IX Shaving Products

2 78

Shaving Products 279

Brushless Shave CreamFormul a : A : Dei o n i zed Water G1 y c e r i ne T r i e t h a n o l ami ne B : Methocel 40-1 00 (Dow)

% by Weight

78 .193 5 .000 0.857

0 .100 C: S t e a r i c A c i d 10.000 S t e a r y l A l c o h o l 0 .500 A c e t y l a t e d Lanol i n A l c o h o l 1 . 5 0 0 W h i t e P r o t o p e t 1 s ( W i t c o ) 1 . 5 0 0 G l y c e r y l S t e a r a t e SE 1 .500 D: D e i o n i z e d Water 0 .500 Dowi c i 1 200 A n t i m i c r o b i a1 0 . 2 0 0 E : Perfume O i 1 -A1 mond 0 .150 Procedure :

M i x A a t room temp. 10 m i n . , t h a n add B and m i x u n t i l com- p l e t e l y d i s s o l v e d . Beg in h e a t i n g A&B and, i n s e p a r a t e v e s s e l , combine and h e a t C i n g r e d i e n t s . When b o t h m i x t u r e s a r e between 75 and 8OC, combine w i t h r a p i d a g i t a t i o n . When b a t c h c o o l s be low 45C add D . Add E when b a t c h is below 40C.

Brushless Shave Cream Formula: % by Weiqht A : Dei o n i zed Water 78.193 G l y c e r i n e 5 I 000 B: Methocel 40-100 0.100 C : T r i e t h a n o l a m i n e 0 .857 D : S t e a r i c A c i d 10.000 S t e a r y l A1 coho l 0 .500 A c e t y l a t e d Lanol i n A1 c o h o l 1 .500 W h i t e F o n o l i n e P e t r o l a t u m ( W i t c o ) 1 .500 G1 y c e r y l S t e a r a t e SE 1 . 5 0 0 E: Dei o n i zed Water 0 . 5 0 0 Dowi c i 1 200 P r e s e r v a t i v e 0 . 2 0 0 F : Perfume O i 1 (Almond) 0 .150 Procedure:

a g i t a t i o n , t h e n C . The d i s p e r s e d Methoce l w i 11 h y d r a t e i n about 15 mins . Beg in h e a t i n g t h e s o l u t i o n and i n a s e p a r a t e v e s s e l combine and h e a t D . When b o t h m i x t u r e s a r e 75-8OC combine w i t h r a p i d a g i t a t i o n . When b a t c h c o o l s t o 45C add E . Add F when b a t c h i s be low 40C. SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n s

Mix A i n g r e d i e n t s a t room temp. f o r 10 m i n s . , t h e n add B w i t h


Non-Foaming Shaving GelT h i s non- foaming shave g e l i s u n i q u e l y d e s i g n e d t o g i v e

e x c e l l e n t r a z o r g l i d e w i t h o u t u s i n g w a t e r . Areas o f sugges ted use a r e as a t r a v e l s h a v i n g g e l , an e t h n i c p r o d u c t o r f o r p r o b l e m s k i n where b l e m i s h e s o r o t h e r s e n s i t i v e a reas a r e v i s i b l e . Sequence Raw M a t e r i a1 :

1 Standamid LD 1 S t e o l CS-460 1 L i p o c o l 0 /95 1 L i p o c o l S-20 1 L i p o n a t e IPM 1 L i p o n i c EG-1

Weight% 5 . 5 0 4.50 3 . 0 0 6 .50 5 . 0 0

10 .00 1 U l t r a o l 70 N F 15.00 1 Panal ene L-14E 5 .00 2 Dei o n i zed Water 45.25 2 Me thy lpa raben 0 .25

P rocedure : 1 . Premix Sequence #1 i n g r e d i e n t s and h e a t t o 80C w i t h medium

2 . Heat Premixed Sequence #2 t o 80C and m ix u n t i l t h e m e t h y l -

3 . Add Sequence #2 t o Sequence #1 w i t h medium speed and s l o w l y

SOURCE: L i p 0 Chemicals I n c , : F o r m u l a t i o n No, 898

I n n r e d i e n t s : Weight% Phase A : SD A l c o h o l 40A 30 .00 Water 30 .00 Carbomer 940 0 . 4 0 Phase B : Water 5 . 7 4 T r i e t h a n o l a m i n e 0 . 5 6 A1 1 a n t o i n 0 . 2 0 Phase C : G l y c e r y l S t e a r a t e (and ) Ce te th -20 ( T e g i n a c i d H ) 0 .75 S t e a r e t h - 7 (and) S t e a r y l A l c o h o l (and) S t e a r e t h - 1 0

(Emu lga to r 2155) 0 .75 Decyl O l e a t e ( T e g o s o f t DO) 3 . 0 0 I s o p r o p y l S t e a r a t e ( T e g o s o f t S ) 3 . 0 0 Menthol 0 . 0 5 Phase D : Water 25.55 Phase E: F rag rance Q . S . Procedure : 1 . D i s p e r s e t h e Carbomer i n t h e w a t e r and a l c o h o l . 2 . M i x Phase B and add t o Phase A . M i x w e l l . 3 . Heat Phase C t o

speed on overhead m i x e r .

paraben i s c o m p l e t e l y s o l u b i l i z e d .

a l l o w t o c o o l .

After Shave Balm

80C. 4 . Heat t h e w a t e r (Phase D ) t o 80C and add t o Phase C . B e g i n h o m o g e n i z a t i o n and c o o l t o 50C. 5 . U s i n g sweep m i x e r , add Phase A/B t o Phase C / D . Homogenize. Sweep m ix c o o l t o 30C. D i spense.

SOURCE: Go ldschmid t Chemical Corp . : Suggested F o r m u l a t i o n

Shaving Products 281

Shave Gel

The r i c h l a t h e r o f t h i s s h a v i n g g e l has good foam and l u b r i c i - t y w i t h l o w i r r i t a n c y c h a r a c t e r i s t i c s .

I n q r e d i e n t s : 1 . D i s t i 11 ed/Dei o n i zed Water 2 . Sodium L a u r e t h S u l f a t e 3 . P a t i o n i c 138C ( S o d i u L a u r o y l L a c t y l a t e ) 4 . R i t a m i d e C (Cocamide DEA) 5 . R i t a p e g 150 DS (PEG-150 D i s t e a r a t e ) 6 . T i t a n i u m D i o x i d e 7 . R i t a PEO-1 (PEG-5M) 8 . Me thy lpa raben 9 . Perfume 1 0 . G l y d a n t 11 . T r i e t h a n o l ami ne 50% 12.Sodium C h l o r i d e (25% s o l u t i o n )

%w/w 53 .73 26 I 67 10 .00

4 .00 2 .00 0 . 5 0 0.10 0 . 1 0 0 .20 0 . 2 0

t - 2 . 0 0 + - O n 50


w i t h T r i e t h a n o l a m i n e . Cool t o 120F and add i t e m s 9 and 10 . A d j u s t v i s c o s i t y w i t h Sodium C h l o r i d e s o l u t i o n .

Heat i t e m s 1-8 t o 165F w h i l e m i x i n g . N e u t r a l i z e t o p H 7 . 5

R e f . No. 122-91

Low Alcohol Moisturizing Lotion

A m o i s t u r i z i n g , l o w a l c o h o l , opaque a f t e r s h a v e , wh ich has a c o o l i n g , s o o t h i n g s k i n - t i g h t e n i n g f e e l w i t h a s u b s t a n t i v e a f t e r - f e e l f r o m t h e P a t l a c I L and P a t i o n i c I S L .

I n q r e d i e n t s : 1 . A c r i tamer 941 (Carbomer) 2 . D i s t i 11 ed/Dei o n i zed Water 3 . P a t l a c I L ( I s o s t e a r y l L a c t a t e ) 4 . R i t a p r o 165 ( G l y c e r y l S t e a r a t e and PEG-100 S t e a r a t e ) 5. P a t i o n i c I S L (Sod i um I s o s t e a r o y l L a c t y l a t e ) 6 . R i t a CA ( C e t y l A l c o h o l ) 7 . M y r i s t y l L a c t a t e 8 . T r i e t h a n o l ami ne ( 5 0 % ) 9 . A l c o h o l SD 40 lO.Per fume, A . S . Type

0 . 7 5 81.61

1 . o o 0 . 5 0 1 . 0 0 0 . 5 0 1 . 0 0 0 . 6 4

12.00 1 . o o


i t e m s 3-7 t o i t e m s 1-2, t a k i n g c a r e n o t t o e n t r a p a i r . Cool t o 140F. Add i t e m s 8 -9 . Cool t o 11OF and add i t e m 10 . A d j u s t p H t o 5 . 3 . Pour i n t o c o n t a i n e r s .

NOTE: A sweep a g i t a t o r i s recommended f o r t h i s p r o d u c t . Weigh i t e m s 1-2 and i t e m s 3-7 and h e a t t o 165F. S l o w l y add

V i s c o s i t y : B r o o k f i e l d RVF H e l i o p a t h TA @ 10 rpm @ 27C: 6 4 6 0 ~ ~ ~ R e f . No. 122-90

SOURCE: R . I , T . A , Corp. : Suggested F o r m u l a t i o n s

Section X Soaps and Hand Cleaners

282

Soaps and Hand Cleaners 283

Anti-Bacterial Handsoap

I n q r e d i e n t s : CalB1 end C1 e a r N i p a c i d e PX P r o p y l ene G1 y c o l Versene 100 F rag rance , Dye, P r e s e r v a t i v e Sodium C h l o r i d e Water

%Wt 3 5 . 0

0 . 7 5 1 .50 0 . 2 0

Q . S . Q . S .

6 2 . 5 5

Comments About t h i s Fo rmu la : 51 e n d i n g P rocedure :

100 i n t o wa te r and m ix u n t i 1 u n i f o r m . I n a s e p a r a t e m i x i n g v e s s e l , d i s p e r s e N i p a c i d e PX i n p r o p y l e n e g l y c o l and, w i t h smooth a g i t a t i o n , warm s l i g h t l y u n t i l c l e a r and u n i f o r m . W i t h smooth a g i t a t i o n , s l o w l y b l e n d t h e p r o p y l e n e g l y c o l / P X m i x t u r e i n t o t h e main C a l B l e n d C l e a r system and s t i r u n t i l u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye and p r e s e r v a t i v e . I f d e s i r e d , t h e v i s c o s i t y o f t h e system may be i n c r e a s e d w i t h t h e t r a c e a d d i t i o n ( 0 . 0 5 - 0 . 2 5 % ) o f sodium c h l o r i d e o r decreased w i t h t h e a d d i t i o n ( 0 . 2 - 0 . 5 % ) o f p r o p y l e n e g l y c o l a s needed.

T y p i c a l F o r m u l a t i o n P r o p e r t i e s : A c t i v e I n g r e d i e n t : C h l o r o x y l e n o l Appearance: C1 e a r L i q u i d V i s c o s i t y @ 25C: 6 , 0 0 0 - 1 0 , 0 0 0 cps

CTFA I d e n t i f i c a t i o n : Wate r , Sodium L a u r e t h S u l f a t e , Cocamide

W i t h smooth a g i t a t i o n , s l o w l y b l e n d C a l B l e n d C l e a r and Versene

pH: 6 . 5 - 7 . 5

DEA, Cocamidopropyl B e t a i n e , Sodi urn C h l o r i d e , F r a g r a n c e , P r e s e r v a t i v e , T e t r a - sodium EDTA, C i t r i c A c i d , D y e ( s ) .

SOURCE: P i l o t Chemical C o . : F o r m u l a t i o n #HAN-019-01


Baby Mild Cleansing Bar(Formula 91-1103)

T h i s h i g h foaming c l e a n s i n g b a r i s m i l d enough f o r baby use . T h e r e f o r e , i t i s p e r f e c t f o r anyone who wants a good c l e a n s i n g p r o d u c t f o r s e n s i t i v e s k i n . I t s n o n - a l k a l i n e f o r m u l a g e n t l y c l e a n s e s t h e s k i n w i t h o u t t h e d r y i n g e f f e c t s o f soap. I t s e m o l l i e n t s and m o i s t u r i z e r s l e a v e t h e s k i n f e e l i n g c l e a n , s o f t and smooth.

S tep A : Geropon AS-200 (Rhone-Poulenc) S t e a r i c A c i d , T r i p l e Pressed Wickenol 550 (CasChem) T i t a n i u m D i o x i d e

S t e p 8 : DV-3284* (Rhone-Poulenc)

S tep C: Water Sodium C h l o r i d e

Step D: Fragrance, D y e ( s ) , P r e s e r v a t i v e

% by Weight

64.0 Q . S . 6 . 0 0 . 2

6 . 0

4 . 0 0 . 4

Q.S.

*DV-3284 i s a 55% aqueous s o l u t i o n o f Sodium I s e t h i o n a t e

81 e n d i n g Procedure : S tep A :

Wickenol 550, T i t a n i u m D i o x i d e ) i n a powder m i x e r .

S tep B:

S P O t S .

B lend t h e d r y components (Geropon AS-200, S t e a r i c A c i d ,

S l o w l y and e v e n l y , add t h e DV-3284 t o S tep A t o a v o i d wet

S tep C: D i s s o l v e t h e Sodium C h l o r i d e and any o t h e r w a t e r s o l u b l e

components i n t h e water and u n i f o r m l y add t o S teps A and B t o a v o i d wet s p o t s ,

S tep D :

mixed, m i l l and/or r e f i n e t h e b a t c h u n t i l i t i s homogeneous. E x t r u d e and stamp i n t o b a r s .

Typ i c a l Formul a t i on P r o p e r t i es :

F i n a l l y , add t h e f r a g r a n c e e v e n l y t o t h e b a t c h . When u n i f o r m l y

Appearance: Opaque Bar pH (5% d i s p e r s i o n ) : 5-6

SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : F o r m u l a t i o n f o r Persona l Care


Hand Cleaners

Anti-Bacterial Handsoap

I n n r e d i e n t s : Wei n h t % CalB1 end C1 e a r 3 5 . 0 0 N i p a c i d e PX 0 . 7 5 P r o p y l e n e G l y c o l 1 . 5 0 Versene 100 0 . 2 0 F rag rance , Dye, P r e s e r v a t i v e Q . S . Sodium C h l o r i d e Q . S Water 62 .55 Comments abou t t h i s f o r m u l a : B l e n d i n g P rocedure :

100 i n t o w a t e r and m i x u n t i l u n i f o r m . I n a s e p a r a t e m i x i n g ves- s e l , d i s p e r s e N i p a c i d e PX i n p r o p y l e n e g l y c o l and, w i t h smooth a g i t a t i o n , warm s l i g h t l y u n t i l c l e a r and u n i f o r m . W i t h smooth a g i t a t i o n , s l o w l y b l e n d t h e p r o p y l e n e g l y c o l / P X m i x t u r e i n t o t h e main C a l B l e n d C l e a r system and s t i r u n t i l u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye and p r e s e r v a t i v e . I f d e s i r e d , t h e v i s c o s i t y o f t h e system may be i n c r e a s e d w i t h t h e t r a c e a d d i t i o n (0 .05 -0 .25%) o f sodium c h l o r i d e o r dec reased w i t h t h e a d d i t i o n ( 0 . 2 - 0 . 5 % ) o f p r o p y l e n e g l y c o l as needed. T y p i c a l F o r m u l a t i o n P r o p e r t i e s :

A c t i v e I n g r e d i e n t : C h l o r o x y l e n o l Appearance: C l e a r L i q u i d V i s c o s i t y @ 25C: 6,000-10,000 cps

W i t h smooth a g i t a t i o n , s l o w l y b l e n d C a l B l e n d C l e a r and Versene

pH: 6 . 5 - 7 . 5 CTFA I d e n t i f i c a t i o n :

Water, Sodium L a u r e t h S u l f a t e , Cocamide DEA, Cocamidopropyl B e t a i n e , Sodium C h l o r i d e , F rag rance , P r e s e r v a t i v e , T e t r a s o d i u m EDTA, C i t r i c A c i d , D y e ( s ) .

F o r m u l a t i o n HAN-019-01

Waterless Liquid

I n n r e d i e n t s : Wei nht% W h i t e M i n e r a l O i l 3 0 . 0 0 Deodor i zed Kerosene 10 .00 EGMS ( E t h y l e n e G l y c o l Monos tea ra te ) 5 . 0 0 Cal i mu1 se PRS 5 . 0 0 P r o p y l e n e G1 y c o l 5 . 0 0 E thoxy L a n o l i n ( 7 5 Mole ) 6 . 0 0 Water 39.00 Comments abou t t h i s f o r m u l a : P a r t A : W h i t e M i n e r a l O i l , Kerosene, EGMS, and C a l i m u l s e PRS.

P a r t B: P r o p y l e n e G l y c o l , E thoxy L a n o l i n and w a t e r . Combine and

P a r t C : Dye and Perfume i f d e s i r e d . Cool A and B, b l e n d be low

Combine and h e a t t o 160F t o m e l t EGMS.

h e a t t o 160F. Combine p a r t s A and B.

11 OF b e f o r e add i ng. F o r m u l a t i o n HAN-009-01

SOURCE: P i l o t Chemical Co.: Suggested F o r m u l a t i o n s


Hand Cleaner, Heavy Duty

Phase A: I n g r e d i e n t s : d - L i monene Cal oxy1 a t e N-9 P i 1 o t SXS-40

Phase B : I n g r e d i e n t s : Water Cal s o f t AOS-40 Cal f a x 1 OL-45 Calamide C

4bWt 35.00 13.00

4 . 0 0

%Wt 30 .00

4.00 10 .00

4.00

Comments About T h i s Formula: P r o p y l e n e G l y c o l can be used i n s t e a d o f SXS-40.

Phase A-Organic Phase: M i x t h e i n g r e d i e n t s i n o r d e r l i s t e d . Upon SXS-40 a d d i t i o n , t h e b l e n d i s s l i g h t l y hazy ( t h e b l e n d i s c l e a r when Propy lene G l y c o l i s u s e d ) .

Phase 0-Aqueous Phase: M i x t h e i n g r e d i e n t s i n o r d e r l i s t e d .

Add Phase A i n t o Phase B w i t h v i g o r o u s m i x i n g . A w h i t e creamy p a s t e i s fo rmed. T h i s i s a good grease c u t t i n g hand c l e a n e r .

F o r m u l a t i o n #HAN-004-01

Hand Cleaner, Liquid, Soap

I n g r e d i e n t s : Cal foam SLS-30 Cal t a i ne C-35 Calamide C EGMS C i t r i c A c i d Kathon CG N i p a c i d e PX Water Ammonium C h l o r i d e

Forrnul a t i on #HAN-005-01

%Wt 27 .64

5 .00 3 . 0 4 1 . 7 7 0.09 0 .09 0 . 0 9

62.01 0 . 2 5

SOURCE: Pilot Chemical Co.: Formulary


Hand Cleaners

Liquid Dispenser Type

I n g r e d i e n t s L Deodor i zed Kerosene W h i t e M i n e r a l O i l Ca lsuds CD-6 Water Perfume

Wei q h t % 5 3 . 0 0

5 . 0 0 9 .50

32 .40 0 .10

Comments abou t t h i s f o r m u l a : P a r t A : Kerosene, W h i t e O i l , and Ca lsuds CD-6. B l e n d and h e a t t o

P a r t 8: Water . Heat s e p a r a t e l y t o 70C. Then combine and m i x w i t h

P a r t C : Per fume. Cool P a r t A and B m i x t u r e t o 25C b e f o r e a d d i n g

70C.

P a r t A .

P a r t C . Formul a t i on HAN-001-01

Liquid Dispenser Type: Pearlescent

- I n g r e d i e n t s l Cal foam SLS-30 EGMS ( E t h y l e n e G l y c o l Monos tea ra te ) Calamide LL Kathon CG Perfume, C o l o r Water C i t r i c A c i d

Comments abou t t h i s f o r m u l a : 1 . Warm t o 140F t o d i s p e r s e t h e EGMS. 2 . V i s c o s i t y 1,200 cPs.


Liquid Dispenser Type: Pearlescent

m e d i e n t s : Calsuds CD-6 Cal s o f t LAS-99 P i 1 o t SXS-40 O p a c i f i e r Kathon CG Water

Comments abou t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d Forrnul a t i o n HAN-003-01

Wei q h t % 2 5 . 0 0

2 .00 5 . 0 0 0 . 2 0 0 . 1 0

67.60 0 .10

Wei n h t % 1 5 . 0 0

3 . 7 0 1 . 2 5 1 . o o 0 .50

78.55

SOURCE: P i 1 o t Chemical Co I : Suggested Formul a t i ons


Hand Cleaners

Liquid Soap

I n q r e d i e n t s : Cal foam SLS-30 Cal t a i ne C-35 Calamide C EGMS ( E t h y l e n e G l y c o l Monos tea ra te ) C i t r i c A c i d Kathon CG N i p a c i d e PX Water Ammoni urn C h l o r i d e Comments abou t t h i s f o r m u l a :

M i x a l l t h e i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HAN-005-01

Liquid Soap

I n g r e d i e n t s ; Cal foam SLS-30

Weight% 27 .64

5 . 0 0 3 . 0 4 1 . 7 7 0.09 0 . 0 9 0 . 0 9

6 2 . 0 1 0 . 2 5

Weighty? 28 .00

Cal t a i ne C-35 5 . 0 0 Calamide C 3 .00 EGMS ( E t h y l e n e G l y c o l Monos tea ra te ) 1 . o o P r o p y l e n e G1 y c o l 1 . o o PEG 46M 0 . 5 0 Kathon CG 0 .05 C i t r i c A c i d 0 . 2 0 Comments abou t t h i s f o r m u l a : 1 . I n g r e d i e n t s 1-6 combined and hea ted t o 70C t o m e l t EGMS. 2 . Kathon CG added a f t e r c o o l i n g b e f o r e a d j u s t i n g pH. 3 . Sodium C h l o r i d e (1%) can be added t o a d j u s t t h e v i s c o s i t y

(i n c r e a s e ) . F o r m u l a t i o n HAN-016-01

Liquid, Soap, Antiseptic

I n q r e d i e n t s : Cal foam SLS-30

Weight% 27 .42

Cal s o f t T-60 Calamide C EGMS ( E t h y l e n e G1 y c o l Monos tea ra te ) C i t r i c A c i d Kathon CG N i p a c i d e PX Water Ammoni urn C h l o r i de Comments abou t t h i s f o r m u l a : 1 . Combine i n g r e d i e n t s 1-5 and h e a t t o 55C t o m e l t EGMS. 2 . Cool be low 50C b e f o r e a d d i n g Kathon and N i p a c i d e . 3 . Add C i t r i c A c i d t o a d j u s t pH. 4 . Add Ammonium C h l o r i d e t o a d j u s t t h e v i s c o s i t y .

SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s F o r m u l a t i o n HAN-017-01

5 . 0 0 3 . 0 2 1 . 7 6 0 . 0 8 0 . 0 9 0 . 0 9

61 - 5 4 1 . o o


Hand Cleaner-LiquidDispenser Type

I n g r e d i e n t s : Deodor i zed Kerosene Whi te M i n e r a l O i 1 Calsuds CD-6 Water Perfume

&WA 53.00

5 .00 9 . 5 0

32.40 0 . 1 0

Comments About t h i s Formula: P a r t A : Kerosene, W h i t e O i 1 , and Ca lsuds CD-6.

P a r t B : Water . Heat s e p a r a t e l y t o 70C t h e n combine and m i x w i t h

P a r t C: Perfume. Cool P a r t A & B m i x t u r e t o 25C b e f o r e a d d i n g

B l e n d and h e a t t o 70C.

P a r t A .

P a r t C . F o r m u l a t i o n #HAN-001-01

Hand Cleaner-LiquidDispenser Type, Pearlescent

I n c l r e d i ents: Cal foam SLS-30 EGMS Calamide LL Kathon CG Perfume, C o l o r Water C i t r i c A c i d

Comments About t h i s Formula: 1 . EGMS-Ethylene G l y c o l Monosteara te 2 . Warm t o 140F t o d i s p e r s e t h e EGMS 3 . V i s c o s i t y - 1 ,200 cPs.

#HAN-002-01

Hand Cleaner-Liquid Dispenser Type, Pearlescent

I n n r e d i e n t s : Ca lsuds CD-6 Cal s o f t LA.S-99 P i l o t SXS-40 Opaci f i e r Kathon CG Water


SOURCE: P i l o t Chemical Co. : Formulary

SbWt 25.00

2.00 5 . 0 0 0 .20 0 .10

67.60 0 . 1 0

15 .00 3 .70 1 . 2 5 1 .oo 0 .50

78.55


Hand Cleaner, Liquid, SoapAntiseptic

I n g r e d i e n t s : Cal foam SLS-30 Cal s o f t T - 6 0 Calamide C EGMS C i t r i c A c i d Kathon CG N i p a c i d e PX Water Ammonium C h l o r i d e

Q& 27 .42

5 .00 3 .02 1 . 7 6 0 . 0 8 0 . 0 9 0 . 0 9

61 .54 1 . o o

Comments About t h i s Formula: EGMS-Ethylene G l y c o l M o n o s t e a r a t e . 1 . Combine i n g r e d i e n t s 1-5 and h e a t t o 55C t o m e l t EGMS. 2 . Cool be low 50C b e f o r e a d d i n g Kathon and N i p a c i d e . 3 . Add C i t r i c A c i d t o a d j u s t pH. 4 . Add Ammonium C h l o r i d e t o a d j u s t t h e v i s c o s i t y .


Handsoap-Clear Liquid

I n g r e d i e n t s : Cal B1 end C1 e a r F rag rance , Dye P r e s e r v a t i ve Sodium C h l o r i d e Water

O/oWt 3 0 . 0

Q . S . Q . S .

1-2 6 8 . 5

Comments About t h i s Formula: 81 end i ng P rocedure :

Charge w a t e r i n t o m i x i n g v e s s e l and s l o w l y b l e n d i n C l e a r . M i x u n t i l c o m p l e t e l y u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 3,000-5,000 cps (No. 4 S p i n d l e f j 10 rpm) w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e a s needed.

Typ i c a l Formul a t i on P r o p e r t i es : Appearance: C1 e a r , V i scous L i q u i d

V i s c o s i t y f j 25C: 3 ,000 -5 ,000 % Non V o l a t i l e s : 11 .5 -12 .5 CTFA I d e n t i f i c a t i o n : Water , Sodium L a u r e t h S u l f a t e , Cocamide

pH: 6 . 0 - 7 . 0

DEA, Cocamidopropyl B e t a i n e , Sodi um C h l o r i d e , F rag rance , P r e s e r v a t i v e , C i t r i c Acid, D y e ( s ) .

Formul a t i on #HAN-018-01

SOURCE: P i 1 o t Chemical Co. : F o r m u l a r y


Hand Cleaners

Powder Dispenser Type

I n g r e d i e n t s : Cal s o f t F-90 P i 1 o t SXS-96 Sodium S e s q u i c a r b o n a t e Borax C r y s t a l s C o l o r & Perfume

Comments abou t t h i s f o r m u l a : 1 . B l e n d C a l s o f t F-90, SXS-96, and S e s q u i c a r b o n a t e 2 . Add Borax . 3 . Add per fume and dye b y o v e r s p r a y i n g .



I n g r e d i e n t s : Sodium S u l f a t e Sodi um S e s q u i c a r b o n a t e Cal s o f t F-90 T r i t o n X-100

Comments abou t t h i s f o r m u l a : 1 . T r i t o n X-100 used as a n t i - d u s t i n g a g e n t . 2 . Formula has h i g h e r b u l k d e n s i t y t h a n HAN-007 .



I n g r e d i e n t s : Sodium Sesqu ica rbona te C a l s o f t F-90 T r i t o n X-100

Comments abou t t h i s f o r m u l a : T r i t o n X-100 used as a n t i - d u s t i n g a g e n t . F o r m u l a t i o n HAN-007-01

Weight% 2 . 0 0 1 .oo

86 .80 10 .00 0.20

Wei qht% 71.70 15 .90 12 .00

0 . 4 0

Weight% 85.30 14 .20

0 . 5 0



Hand Cleaner, PowderDispenser Type

I n g r e d i e n t s : C a l s o f t F-90 P i 1 o t SXS-96 Sodi um Sesqu icarbonate Borax C r y s t a l s C o l o r & Perfume

Comments About t h i s Formula: 1 . B l e n d C a l s o f t F-90, SXS-96, and S e s q u i c a r b o n a t e . 2 . Add Borax . 3 . Add per fume and dye by o v e r s p r a y i n g .

F o r m u l a t i o n WAN-006-01

Hand Cleaner-PowderDispenser Type

I n g r e d i e n t s : Sodium S e s q u i c a r b o n a t e Cal s o f t F-90 T r i t o n X-100

Comments About t h i s Formula: T r i t o n X-100 used as a n t i - d u s t i n g a g e n t . F o r m u l a t i o n #HAN-007-01

Hand Cleaner-PowderDispenser Type

I n g r e d i e n t s : Sodium S u l f a t e Sodium Sesqu icarbonate Cal s o f t F-90 T r i t o n X-100

Comments About t h i s Formula: 1 . T r i t o n X-100 used a a n t i - d u s t i n g a g e n t . 2. Formula has h i g h e r b u l k d e n s i t y t h a n HAN-007.


SOURCE: Pi 1 o t Chemical CO. : F o r m u l a r y

__ % W t 2 .00 1 - 0 0

86 .80 10.00

0 .20

S6Wt 8 5 . 3 0 14 .20

0 . 5 0

7 1 . 7 0 15.90 1 2 . 0 0

0 . 4 0


I n g r e d i e n t s : C a l B l e n d C l e a r F rag rance , Dye P r e s e r v a t i v e Sodium C h l o r i d e Water

Hand Cleaners

Handsoap-Clear Liquid

Wei wht% 3 0 . 0 0

Q.S. Q.S.

1 * 00 -2 .00 68 .50

Comments abou t t h i s f o r m u l a : 81 endi ng Procedure :

Charge w a t e r i n t o m i x i n g v e s s e l and s l o w l y b l e n d i n C l e a r . M i x u n t i l c o m p l e t e l y u n i f o r m . Add c o m p a t i b l e f r a g r a n c e , dye, and p r e s e r v a t i v e . A d j u s t f o r m u l a t i o n v i s c o s i t y t o 3,000-5,000 c p s (No. 4 S p i n d l e @ 10 rpm) w i t h t h e i n c r e m e n t a l a d d i t i o n o f sodium c h l o r i d e as needed.

T y p i c a l F o r m u l a t i o n P r o p e r t i e s : Appearance: C1 e a r , V i scous L i q u i d V i s c o s i t y @ 25C: 3,000-5,000 cps

% Non V o l a t i l e s : 1 1 . 5 - 1 2 . 5 pH: 6 . 0 - 7 . 0


Sodium C h l o r i d e , F rag rance , P r e s e r v a t i v e , C i t r i c Acid, D y e ( s ) . Sodium L a u r e t h S u l f a t e , Cocamide DEA, Cocamidopropyl B e t a i n e ,


Heavy Duty

Phase A I n g r e d i e n t s : d - L i monene C a l o x y l a t e N-9 P i 1 o t SXS-40

~ _ _ _ Phase B I n g r e d i e n t s : Water Cal s o f t AOS-40 Cal f a x 1 OL-45 Calamide C

Wei a h t % 35 .00 13 .00

4 . 0 0

3 0 . 0 0 4 .00

1 0 . 0 0 4 .00

Comments about t h i s f o r m u l a : P r o p y l e n e G l y c o l can be used i n s t e a d o f SXS-40. Phase A-Organic Phase: M i x t h e i n g r e d i e n t s i n o r d e r l i s t e d . Upon SXS-40 a d d i t i o n , t h e b l e n d i s s l i g h t l y hazy ( t h e b l e n d i s c l e a r when P r o p y l e n e G l y c o l i s u s e d ) . Phase B-Aqueous Phase: M i x t h e i n g r e d i e n t s i n o r d e r l i s t e d . Add Phase A i n t o Phase 8 w i t h v i g o r o u s m i x i n g . A w h i t e creamy p a s t e i s formed. T h i s i s a good g rease c u t t i n g hand c l e a n e r .


SOURCE: P i 1 o t Chemical Co. : Suggested Formul a t i o n s


Hand Cleaner, Waterless, Liquid

- I n g r e d i e n t s : ~~

Wh i te M i n e r a l O i l Deodor i zed Kerosene EGMS Cal i mu1 se PRS Propy lene G l y c o l E thoxy L a n o l i n ( 7 5 Mole ) Water

Comments About t h i s Formula : EGMS-Ethylene G l y c o l Monos tea ra te .

om 3 0 . 0 0 1 0 . 0 0

5 . 0 0 5 . 0 0 5 . 0 0 6 . 0 0

3 9 . 0 0

P a r t A: W h i t e M i n e r a l O i l , Kerosene, EGMS,and C a l i m u l s e PRS.

P a r t 8 : P ropy lene G l y c o l , E thoxy L a n o l i n and w a t e r . Combine

P a r t C: Dye and Perfume i f d e s i r e d . Cool A 8 B, b l e n d be low

Combine and h e a t t o 160F t o m e l t EGMS.

and hea t t o 1 6 0 F . Combine p a r t s A & B .

1 1 OF b e f o r e add i ng . F o r m u l a t i o n #HAN-009-01

Hand Cleaner-Waterless Paste

I ng r ed Len t-s : Wh i te M i n e r a l O i l Deodor i zed Kerosene EGMS C a l i m u l s e PRS P ropy lene G 1 y c o l E thoxy L a n o l i n ( 7 5 Mole) Water

Comments About t h i s Fo rmu la : P a r t A: I n g r e d i e n t s 1 - 4 . Heat P a r t B : I n g r e d i e n t s 5 - 7 . Heat

P a r t C : Per fume. Cool " A " and " B ' ! .

%Yt 3 0 . 0 0 1 0 . 0 0 1 0 . 0 0

5 . 0 0 5 . 0 0 6 . 0 0

3 4 . 0 0

and mix t o 1 6 0 F . and m ix t o 1 6 0 F . Combine " A " and

!tB!! , b l e n d be low lOOF b e f o r e a d d i n g . Package i m m e d i a t e l y , f o rms a p a s t e on c o o l i n g .


SOURCE: P i l o t Chemical Co. : Fo rmu la ry


Hand Cleaners

Waterless Paste

I n s r e d i en t s : O l e i c A c i d T r i e t h a n o l ami ne 85% C a l o x y l a t e N-9 Calamide CWT d-Limonene Water , D . I .

Wei q h t % 1 . 6 0 0 .40

11 - 0 0 4 . 0 0

34 .00 49.00

Comments abou t t h i s f o r m u l a : 7 . Combine i n g r e d i e n t s 1-5 and h e a t t o 80C w i t h m i x i n g . 2 . S l o w l y add w a t e r w h i l e m a i n t a i n i n g t e m p e r a t u r e . 3 . Forms a g e l on c o o l i n g .


Waterless Paste

I n q r e d i e n t s : Calamide CWT Cal oxy1 a t e N-9 Laurami ne Ox ide d-Limonene G1 y c e r o l Water , D . I .

Weight% 10 .50

6 .00 0 . 5 0

40 .00 1 . 5 0

41 .50

Comments abou t t h i s f o r m u l a : P a r t A : I n g r e d i e n t s 1-4, combine and h e a t t o 70C. P a r t B : Combine and h e a t i n g r e d i e n t s 5 and 6 t o 70C. Combine

w i t h P a r t " A l l . Package b e f o r e c o o l i n g . Formul a t i on HAN-014-01

Waterless Paste

.- I n g r e d i e n t s : Calamide CWT O l e i c A c i d T r i e t h a n o l ami ne 85% C a l o x y l a t e N-9 d - L i monene G1 y c e r i ne Water

Weight% 5 . 0 0 5 100 1 . 5 0 2 . 5 0

45 IO0 1 . 5 0

39 .50

Comments about t h i s f o r m u l a : P a r t A : I n g r e d i e n t s 1-5, m ix and h e a t t o 70C. P a r t B : I n g r e d i e n t s 6 and 7, warm t o 80C and add t o P a r t " A " .

Cool and package, b e f o r e c o o l i n g . F o r m u l a t i o n HAN-015-01

SOURCE: P i 1 o t Chemical Cos : Suggested Formul a t i ons


Hand Cleaners

Waterless Paste

I n g r e d i e n t s : W h i t e M i n e r a l O i l

Weight% 30 .00

Deodor i zed Kerosene 10.00 EGMS ( E t h y l e n e G l y c o l Monos tea ra te ) 10 .00 Cal i mu1 se PRS 5 . 0 0 P r o p y l e n e G1 y c o l 5 . 0 0 E thoxy L a n o l i n ( 7 5 Mo le ) 6 .00 Water 34 .00 Comments abou t t h i s f o r m u l a : P a r t A : I n g r e d i e n t s 1 - 4 . Heat and m i x t o 160F. P a r t B: I n g r e d i e n t s 5 -7 . Heat and m ix t o 160F. Combine " A "

P a r t C : Perfume. Cool "A" and "B", b l e n d be low 1OOF b e f o r e ad- d i n g .

Package i m m e d i a t e l y , f o rms a p a s t e on c o o l i n g .

and "B" .


Waterless Paste

I n g r e d i e n t s : Weight% Deodor i zed Kerosene 42.10 Ca lsuds CD-6 13.60 W h i t e M i n e r a l O i l 3 .30 Water 40.40 Kathon CG 0 . 5 0 Perfume 0 . 1 0 Comments abou t t h i s f o r m u l a : P a r t A : I n g r e d i e n t s 1-3, combine and h e a t t o 7 0 C . P a r t B : I n g r e d i e n t 4, h e a t t o 60C and add w i t h m i x i n g t o P a r t " A " P a r t C : I n g r e d i e n t s 5 and 6 . Cool A/B, b l e n d be low 40C b e f o r e

a d d i n g . Forms a g e l on s t a n d i n g . F o r m u l a t i o n HAN-011-01

Waterless Paste

I n n r e d i e n t s : Calamide CWT O l e i c A c i d T r i e t h a n o l a m i n e 85% Deodor i zed M i n e r a l Sp i r i t s G1 y c e r o l Water

Wei g h t % 5 . 0 0 5 . 0 0 1 .50

45 .00 1 . 5 0

42.00

Comments abou t t h i s f o r m u l a : P a r t A : M i x and h e a t i n g r e d i e n t s 1-4 t o 8OC. P a r t 8 : M i x and h e a t i n g r e d i e n t s 5 and 6 t o 8 O C . Combine w i t h

P a r t " A " . Forms a g e l on c o o l i n g .

SOURCE: P i 1 o t Chemical Co. : Suggested Formul a t i ons F o r m u l a t i o n HAN-012-01


Hand Cleaner-Waterless Paste

I n g r e d i e n t s : Deodor i zed Kerosene Ca lsuds CD-6 Wh i te M i n e r a l O i l Water Kathon CG Perfume

-_ % W t 42 .10 13 .60

3 . 3 0 40 .40

0 . 5 0 0 . 1 0

Comments About t h i s Formula : P a r t A: I n g r e d i e n t s 1-3, combine and h e a t t o 70C. P a r t B: I n g r e d i e n t 4, h e a t t o 60C and add w i t h m i x i n g t o P a r t " A " P a r t C : I n g r e d i e n t s 5 and 6 . Cool A/B, b l e n d be low 4 0 C b e f o r e

a d d i n g . Forms a g e l on s t a n d i n g . F o r m u l a t i o n #HAN-011-01

Hand Cleaner-Waterless, Paste

Ing red ien ts ; Calamide CWT O l e i c A c i d T r i e t h a n o l ami ne 85% Deodor ized M i n e r a l Spi r i t s G1 y c e r o l Water

"/t 5 . 0 0 5 . 0 0 1 . 5 0

45 .00 1 .50

4 2 . 0 0

Comments About t h i s Formula : P a r t A: M ix and h e a t i n g r e d i e n t s 1-4 t o 80C. P a r t B : M i x and h e a t i n g r e d i e n t s 5 and 6 t o 80C. Combine w i t h

P a r t " A " . Forms a g e l on c o o l i n g . Formul a t i on #HAN-012-01


Jngr_edi e n t s : O l e i c A c i d T r i e t h a n o l ami ne 85% Cal oxy1 a t e N-9 Calamide CWT d - L i monene Water , D . I .

Comments About t h i s Formula : 1 . Combine i n g r e d i e n t s 1-5 and h e a t t o 80C w i t h m i x i n g . 2 . Slow1 y add wa te r w h i 1 e mai n t a i n i ng t e m p e r a t u r e . 3 . Forms a g e l on c o o l i n g .


SOURCE: P i l o t Chemical Co I : Formul a r y

%K!. 1 . 6 0 0 . 4 0

1 1 . o o 4 . 0 0

34 .00 49 .00



Ingredi ents; %WtCalamide CWT 10.50Caloxylate N-9 6.00Lauramine Oxide 0.50d-Limonene 40.00Glycerol 1.50Water, D.I, 41.50

Comments About this Formula:Part A: Combine and heat ingredients 1-4 to 7OC.Part B: Combine and heat ingredients 5&6 to 7OC. Combine with

Part "A". Package before cooling.Formulation #HAIM-01 4-01


Ingredi ents: %WtCaI amide CWT 5.00Olei c Aci d 5.00Triethanolamine 85% 1.50Caloxylate N-9 2.50d-Limonene 45.00Glyceri ne 1.50Water 39.50

Comments About this Formula:Part A: Ingredients 1-5, mix and heat to 7OC.Part B: Ingredients 6&7, warm to 8OC and add to Part "A".

Cool and package.Formulation #HAN-015-01

Hand Cleaner-Liquid, Soap

Ingredients: Wt%Calfoam SLS-30 28.00Caltaine C-35 5.00Calamide C 3.00EGMS 1.00Propylene Glycol 1.00PEG 46M 0.50Kathon CG 0.05Ci trie Aci d 0.20

Comments About this Formula:EGMS-Ethy1ene Glycol Monostearate1. Ingredients 1-6 combined and heated to 7OC to melt EGMS.2. Kathon CG added after cooling before adjusting pH.3. Sodium Chloride (1%) can be added to adjust the viscosity

(i ncrease).Formulation #HAIM-01 6-01

SOURCE: Pilot Chemical Co.: Formulary


Hot Pour Syndet Bar

T h i s m i l d c l e a n s i n g b a r p r o v i d e s r i c h l a t h e r and s o f t s k i n as a r e s u l t o f Jordapon CI -60 . The f o r m u l a i s d e s i g n e d t o be manufac tured u s i n g h o t - f i l l equipment ; no soapmaking l i n e s a r e needed.

I n g r e d i e n t : Wt% Sodi um Cocoyl I s e t h i o n a t e (and) S t e a r i c A c i d

(Jordapon GI-60) 80 .0 S t e a r y l A l c o h o l (GO-1895) 1 0 . 0 PEG-150 (Carbowax E-8000) 3 . 0 T r i e t h a n o l a m i n e , 99% 5 . 0 Demi n e r a l i zed Water 2 . 0

pH ( 5 % s o l u t i o n ) : 6 . 3

Procedure : W i t h a l l i n g r e d i e n t s i n t h e v e s s e l , h e a t t o 70C. Beg in

p r o p e l l o r a g i t a t i o n when t h e b a t c h becomes f l u i d . M a i n t a i n s low m i x i n g u n t i l a l l s o l i d s a r e d i s s o l v e d and t h e b a t c h becomes a un i fo rm, nonv iscous , opaque f l u i d . F i l l molds, a l l o w t o s o l i d i f y .

Formula M102

Syndet Bar

Modi f i cation of an example i n US Patent #4,707,288

- I n g r e d i e n t : Sodi um Cocoyl I s e t h i o n a t e (and) S t e a r i c A c i d

(Jordapon CI -75) Tal low/Coco Soap Water NaCl T i 02 Fragrance BHT N a 3 H EDTA

Formula M103

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

7 6 . 5 1 6 . 7

4 . 1 0 . 3 1 . o 1 . o 0 . 2 0 . 2


Liquid Soap

A m i l d , h i g h - f o a m i n g f o r m u l a t i o n w h i c h i s s i m p l e , y e t o f f e r s l u b r i c i o u s l a t h e r and s o f t s k i n a f t e r f e e l t h a n k s t o t h e Jordapon C I - U P . The Mapeg EGMS p r o v i d e s a b r i g h t p e a r l e s c e n c e t o t h e system. I t can be o m i t t e d i f a c l e a r p r o d u c t i s d e s i r e d .

P a r t : - I n g r e d i e n t ( T r a d e Name): A Dei o n i zed Water 74 .4

Sodi um C o c o y l I s e t h i o n a t e (Jordapon CI-UP) 3 . 0 Ammoni um L a u r y l S u l f a t e ( S t e p a n o l AM) 13.0 G l y c o l S t e a r a t e (Mapeg EGMS) 0 . 5 Na4 EDTA 0 . 1 M e t h y l Paraben 0 . 2

B Cocami d o p r o p y l B e t a i ne (Mafo CAB) Cocamide DEA (Mazamide JT-128)

C Fragrance C i t r i c A c i d

6 . 0 2 . 5

0 . 2 0 . 1

pH: 6 . 0 - 6 . 5 V i s c o s i t y : 2500-3500 cps ( w i t h 0 .6 -0 .9% NaC1) Appearance: Creamy , P e a r l e s c e n t L i q u i d

Procedure : M i x and h e a t p a r t A i n g r e d i e n t s t o 65C (150F) . When u n i f o r m ,

add t h e Mafo CAB and t h e Mazamide JT-128. Cool t h e b a t c h t o 40C (150F) , add f r a g r a n c e and a d j u s t pH. A d j u s t v i s c o s i t y w i t h sodium c h l o r i d e .

SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n N-201

Hand Cleaning Gel

Wt% Z u s o l a t 1004 25 .0 O l e i c a c i d 4 . 0 C a u s t i c soda (15%) a p p r o x . 3 .0 S h e l l s o l D 40 1 8 . 0 9 , s . t o make 100%: w a t e r , per fume, p r e s e r v a t i v e

SOURCE: Zschimmer & Schwarz GmbH & C o . : F o r m u l a t i o n B 25/216


Lotion Hand Cleaner (With Abrasive)

D i s t i 1 1 ed Water B i o t e r g e AS-40 Me thy lpa raben R i t a s y n t I P P a t i o n i c I S L R i t a p e g 150 DS Walnut She1 1 s (Coarse) Kathon CG TEA (50% S o l u t i o n ) Perfume

61 - 5 5 2 5 . 0 0

0 . 1 5 4.00 3 . 0 0 1 . o o 5 .00 0 . 1 0 0 . 1 5 0 . 0 5

pH: 6 . 0 V i s c o s i t y : 3400 cps Foami ng R e s u l t s : Foam n20

0 . 0 M i n u t e 260 85 1 . O M i n u t e 260 95 3 . 0 M i n u t e 260 100

4F: Wa lnu ts d r o p t o b o t t o m a f t e r 1 c y c l e 40F: Walnuts d r o p t o b o t t o m a f t e r 4 weeks 70F: Wa lnu ts d r o p t o b o t t o m o v e r n i g h t

S t a b i 1 i t i e s :

110F: S e p a r a t i o n o v e r n i g h t - a 1 1 w a l n u t s a t b o t t o m C e n t i f u g e R e s u l t s : Separa tes a f t e r 10 seconds @ 1600 rpm D e s c r i p t i o n : 1% R i t a p e g 150 DS W i t h o u t R i t a v e n a 5

SOURCE: R . 1 , T . A . C o r p . : R i t a v e n a 5 : F o r m u l a t i o n 114-24

Mild Hand Cleanser

Mackanate LO-Speci a1 Mackami de PKM Mackern i um 007 M a c k s t a t DM Water , F rag rance g s t o

___ W t % 8 3 . 0

4 . 0 0 . 8

qs 1 0 0 . 0

P rocedure : 1 . Add Mackamide PKM t o Mackanate LO-Special and h e a t t o 70

degrees C . 2 . B l e n d u n t i l homogeneous. 3 . D i s s o l v e Mackernium 007 i n wa te r and add t o p r o d u c t . 4 . B1 end u n t i 1 c o m p l e t e l y homogeneous. 5 . Cool t o 50 degrees C . w i t h m i l d a g i t a t i o n . 6 . Add M a c k s t a t DM and f r a g r a n c e and c o o l w i t h c o n t i n u o u s

a g i t a t i o n .

SOURCE: M c I n t y r e Group L t d . : Persona l Care F o r m u l a r y : Formula


Mild Pearlized Hand Cleanser

Water Sodi urn C h l o r i d e M o n a t e r i c 951A Monamate LNT-40 Monamid 1089 Cerasyn t I P Phosphol i p i d PTC

% Bv Weiqht 6 1 . 4

0 . 3 2 0 . 8 12 .5

1 . o 1 . 5 2 . 5

Procedure :

a t i o n t o 60C. M a i n t a i n 60C u n t i l t h e Cerasyn t I P has d i s s o l v e d . Cool - a d j u s t pH w i t h p h o s p h o r i c a c i d . A t pH 6 . 5 , v i s c o s i t y i s about 2000 c p s .

Formula F-128

Add i n g r e d i e n t s i n o r d e r l i s t e d and warm w i t h g e n t l e a g i t -

Pearled Gel Facial Cleanser

% B y Weiah t Water 52 .5 Sodium L a u r e t h ( 1 ) S u l f a t e (25% A c t i v e ) 2 8 . 0 Monamate CPA-40 1 2 . 5 Monamid 1089 3 . 0 Cerasyn t I P 1 . 5 Phosphol i p i d PTC 2 . 5

P rocedure : Add i n g r e d i e n t s i n o r d e r l i s t e d and h e a t w i t h g e n t l e a g i t -

a t i o n t o 70C w h i l e t h e Cerasyn t I P d i s s o l v e s . Cool and a d j u s t pH l e v e l d e s i r e d . A t pH 5 t o 6 t h e p r o d u c t i s a p e a r l e d , b a r e l y f l o w a b l e g e l w h i c h i s s u i t a b l e f o r p a c k i n g i n t u b e s . Hand l a t h e r i s c o p i o u s , w i t h a so f t - c reamy f e e l . When d r y , t h e s k i n has a s i 1 ky f e e l .

Formula F-156

Facial Cleanser

T h i s h i g h foaming f o r m u l a t i o n u t i l i z e s t h e m i l d c l e a n s i n g and a n t i - i r r i t a t i o n p r o p e r t i e s o f P h o s p h o l i p i d PTC. I t s sub- s t a n t i v i t y t o t h e s k i n and e f f e c t i v e c o n d i t i o n i n g a c t i v i t y w i l l h e l p t o m i n i m i z e o r a l l e v i a t e d r y s k i n c o n d i t i o n s w h i l e l e a v i n g a s i 1 ky t a l c - 1 i ke a f t e r f e e l .

Phosphol i p i d PTC M o n a t e r i c CLV Sodium L a u r e t h ( 1 ) S u l f a t e (26%) Water

% BY Weight 2 . 5

1 2 . 5 28 .0 5 7 . 0

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Opaque Liquid Soap

N a t r o s o l 250HHR h y d r o x y e t h y l c e l l u l o s e e f f e c t i v e l y b o o s t s t h e v i s c o s i t y o f t h i s l o w e r a c t i v e s opaque shampoo base. A t a s u r f a c t a n t s o l i d s l e v e l o f o n l y 7.3%, t h e a d d i t i o n o f N a t r o s o l y i e l d s a r i c h l i q u i d soap w i t h a v i s c o s i t y o f 4,000 cps (MPas) ( B r o o k f i e l d LVT a t 30 rpm, 25C) .

LwreL iLen t_ s-:.. Water Sodium C14-Cl6 o l e f i n s u l f o n a t e , 40% a c t i v e Sodi um 1 a u r o y l s a r c o s i n a t e , 30% a c t i v e Cocami dop ropy l b e t a i ne, 35% a c t i v e G l y c o l s t e a r a t e N a t r o s o l 250HHR CS h y d r o x y e t h y l c e l l u l o s e P ropy lene g l y c o l G1 y c e r i n Te t rasod ium EDTA S t e a r a l k o n i u m c h l o r i d e Me thy l paraben

W-e i gh t YC 7 5 I 88

7 . 5 0 6 . 6 6 6 . 6 6 1 . o o 0 . 8 0 0 . 5 0 0 . 5 0 0 . 3 0 0 . 1 0 0 . 1 0

P rocedure : 1 . D i s p e r s e t h e N a t r o s o l i n w a t e r w i t h good a g i t a t i o n . Mix u n t i l

f u l l y d i s s o l v e d . Modera te h e a t i n g o r an i n c r e a s e i n s o l u t i o n pH t o s l i g h t l y a l k a l i n e w i l l a c c e l e r a t e h y d r a t i o n .

2 . D i s p e r s e t h e me thy l paraben i n t h e p r o p y l e n e g l y c o l . Add t o t h e N a t r o s o l s o l u t i o n . M ix u n t i l d i s s o l v e d .

3 . W h i l e s l o w l y s t i r r i n g t h e w a t e r - s o l u b l e po lymer s o l u t i o n , add t h e s t e a r a l k o n i u m c h l o r i d e , o l e f i n s u l f o n a t e , and g l y c o l s t e a r a t e . Heat t h e m i x t u r e t o 80C u n t i l a l l o f t h e g l y c o l s t e a r a t e has m e l t e d and t h e s o l u t i o n has t u r n e d opaque.

s l o w l y t o room t e m p e r a t u r e .

Formula N09-01W

4 . Add t h e r e m a i n i n g i n g r e d i e n t s w h i l e c o o l i n g t h e s o l u t i o n

5 . Add c o l o r and f r a g r a n c e .

Transparent Toilet Soap

N a t r o s o l 250HR g i v e s v i s c o s i t y and p s e u d o p l a s t i c f l o w t o t h i s t r a n s o a r e n t hand soap.

Lngred i ents; Water Sod1 um C14-Cl6 Sodi um 1 a u r o y l Cocamide MEA N a t r o s o l 250HR D i s o d l urn EDTA Me thy l paraben

o l e f i n s u l f o n a t e , 40% a c t i v e s a r c o s i n a t e , 30% a c t i v e

cs

Wei g h t % 65 .70 2 0 . 0 0 1 0 . 0 0

3 . 0 0 1 . o o 0 . 2 0 0 . 1 0

Formul a N09-02W

SOURCE: Aqua1 on Di v i s i o n : N a t r o s o l 2 5 0 H y d r o x y e t h y l c e l l u l o s e


Soap Bar for Hard Water(Formula 91-1106)

T h i s soap b a r i n c o r p o r a t e s a m i l d a m p h o t e r i c s u r f a c t a n t t o improve foaming i n h a r d w a t e r s i t u a t i o n s . A d d i t i o n a l l y , t h e a m p h o t e r i c reduces t h e ha rshness o f t h e soap system i n any washing e n v i r o n m e n t . T h i s b a r i s l e s s d r y i n g t h a n a p u r e soap based p r o d u c t .

% by-Weight S tep A : 80/20 B r a d p r i d e Soap Base ( O r i g i n a l B r a d f o r d Soap Works) Q . S . Bentone EW (Rheox) 1 0 . 0

S tep 8 : Water M i r a n o l C2M-SF 70%

S tep C: F rag rance , D y e ( s ) , P r e s e r v a t i v e

7.5 5 . 0

Q . S

B l e n d i n g P rocedure : S tep A :

a powder m i x e r .

S tep B :

components i n t h e wa te r w i t h h e a t i n g . S l o w l y and e v e n l y add t h e aqueous s o l u t i o n t o S tep A t o a v o i d wet s p o t s .

S tep C :

mixed, m i l l and /o r r e f i n e u n t i l t h e b a t c h i s homogeneous. E x t r u d e and stamp i n t o b a r s .

T y p i c a l F o r m u l a t i o n P r o p e r t i e s :

B lend t h e d r y components ( B r a d p r i d e Soap Base, Bentone EW) i n

D i s s o l v e t h e M i r a n o l C2M-SF 70% and any o t h e r wa te r s o l u b l e

F i n a l l y , add t h e f r a g r a n c e t o S teps A and B . When u n i f o r m l y

Appearance: Opaque Bar pH (5% d i s p e r s i o n ) : 1 0 . 0 - 1 0 . 5


H e c t o r i t e , Water, D isod ium Cocamphod ip rop iona te .

SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : F o r m u l a t i o n

Sodi um T a l l o w a t e , Sodi um Cocoate and /o r Sodi um Palm Kerna l a t e ,

f o r Pe rsona l Care


Waterless Hand Cleaner

__ Formu 1 a : A: M i n e r a l C o l l o i d BP (ECC Amer ica) Water B: P o t a s s i um Hydrox i de Water C: M i c r o w h i t e 100 (ECC Amer ica) D : O l e i c A c i d Deodor ized Kerosene S o l u l a n 98 Ye1 low P r o t o p e t 2A P e t r o l a t u m (Wi t c o )

% b y Weigh t

2 . 0 3 6 . 0

1 . o 5 . 0

2 0 . 0

6 . 0 2 5 . 0

3 . 0 2 . 0

P r e s e r v a t i ves q . s .

Procedure :

a t max. s h e a r . D i s s o l v e po tass ium h y d r o x i d e i n w a t e r . Add 8 t o A w i t h medium s h e a r . Add M i c r o w h i t e 100 t o A/B and m ix u n t i l smooth and u n i f o r m . Heat A/B/C t o 60C. Combine D and h e a t t o 65C. Add D t o A / B / C w i t h s low m i x i n g u n t i l c o o l e d t o 30C. Add p r e s e r v a t i v e s and mix u n t i l smooth and u n i f o r m . M i n e r a l C o l l o i d , a r e f i n e d s m e c t i t e c l a y , e f f e c t i v e l y t h i c k e n s and s t a b i l i z e s t h e emu1 s i on and suspends t h e a b r a s i v e .

S l o w l y add t h e M i n e r a l C o l l o i d BP t o t h e wa te r w h i l e a g i t a t i n g

Waterless Hand Cleaner with Abrasive

~~~ Formui a : A: Veegum Pro Water 8 : P o t a s s i um Hydrox i de Water C: O l e i c A c i d C a r n a t i o n M i n e r a l 0 ; 1 ( W i t c o ) C l l - 1 2 I s o p a r a f f i n D: P o l y e t h y l e n e P r e s e r v a t i v e

2 . o 3 9 . 4

0 . 9 2 . 7

9 . 0 9 . 0

2 7 . 0

q . s .

Procedure :

a v a i l a b l e s h e a r . M i x until smooth. Add B w i t h c a r e f u l m i x i n g and mix u n t i l u n i f o r m , Add C t o A/B and m ix u n t i l emu ls ion i s smooth and u n i f o r m . Add D and m i x u n t i l u n i f o r m . T h i s i s a medium v i s c o s i t y cream.


S l o w l y add Veegum P r o t o t h e w a t e r , a g i t a t i n g a t maximum

Section XI Sun Care Products

306

Sun Care Products 307

After Sun Cream with Aloe Vera and Evening Primrose

I n g r e d i e n t s : Wei qht% A) I m w i t o r 370 ( G l y c e r y l S t e a r a t e C i t r a t e ) 7 .00

I m w i t o r 375 ( G l y c e r y l C i t r a t e / L a c t a t e / L i no1 e a t e / 01 e a t e ) 5 .00

I m w i t o r 928 (G1 y c e r y l Cocoate) 3 .00

S o f t i s a n 378 ( C a p r y l i c / C a p r i c / S t e a r i c T r i g l y c e r i d e ) 5 .00 A l o e Vera L i p 0 Quinone E x t r a c t ( A l o e Barbadens is

M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) 1 2 . 0 0

E x t r a c t ) 2 . 0 0 Eveni ng P r imrose 2 . 0 0

8) Carbopo l Gel 1% 15.00 A1 l a n t o i n 0 .20 P r e s e r v a t i v e q . s . d-Pantheno l 3 .00 Water up t o 100.00

C) F rag rance 9 . S . V i t a m i n E 0 . 2 0

P r e p a r a t i on : Carbopo l Gel :

Carbopo l 980 (Carbomer) 1 .O% KOH 10% 4.0% Water up t o 100.0%

A f t e r Sun Cream:

b r o u g h t t o t h e same t e m p e r a t u r e and e m u l s i f i e d i n t o ( A ) . (C) i s added a t about 35 degrees C .

(A) i s hea ted up t o c a . 75 degrees C . (6) i s s t i r r e d and

F o r m u l a t i o n 4.1D

W/O Sun Protection Lotion

I n g r e d i e n t s : Weight% A) S o f t i s a n Gel ( B i s - D i g l y c e r y l P o l y a c r y l a d i p a t e - 1

(and) P r o p y l ene G1 y c o l D i c a p r y l a t e / D i c a p r a t e (and ) S t e a r a l k o n i u m H e c t o r i t e (and ) P ropy lene Carbonate) 5 . 0 0

Dynacer i n 660 (01 e y l E r u c a t e ) 1 8 . 0 0 S o f t i san 378 ( C a p r y l i c / C a p r i c / S t e a r i c T r i g l y c e r i d e ) 5 . O O A b i l WE 09 ( P o l y g l y c e r y l - 4 I s o s t e a r a t e (and ) C e t y l

D ime th i cone C o p o l y o l (and) Hexy l L a u r a t e ) 5 .00

6) Hombitec L5 ( T i t a n i u m D i o x i d e ) 3 .00 Euso lex 6300 ( 4 - M e t h y l b e n z y l i d e n e Camphor) 3 . 0 0

Magnesium S u l f a t e 2 . 0 0 P r e s e r v a t i ve q . s . Water up t o 100 .00

P r e p a r a t i o n : (A) i s warmed up t o c a . 75 degrees C . and s t i r r e d . ( B ) i s

b r o u g h t t o t h e same t e m p e r a t u r e and e m u l s i f i e d i n t o (A ) w i t h an homogen izer . (C) i s added a t about 35 degrees C .

F o r m u l a t i o n 4 .28

SOURCE: Huls America I n c . : Suggested F o r m u l a t i o n s


After Sun Lotion

The c o m b i n a t i o n o f E l h i b i n and Lac tomide i n t h i s deep a c t i n g l o t i o n r e g e n e r a t e s t h e s k i n t h r o u g h t h e a n t i e l a s t a s e e f f e c t and l i p i d b a r r i e r r e c o n s t r u c t i o n . The f o r m u l a i s i d e a l f o r a f t e r sun a p p l i c a t i o n s .

Item I n g r e d i e n t s 1 A) Tween 60 2 A r l a c e l 60 3 A r l a c e l 165 4 C e t y l A1 coho1 5 I s o p r o p y l M y r i s t a t e 6 6 ) D e i o n i z e d Water 7 Phenoni p 8 I m i d a z o l i d i n y l Urea 9 P r o p y l ene G1 y c o l

10 E l h i b i n 11 Lactomi de 12 C) F r a g r a n c e : T imbuk tu 0/186901

Procedure : Heat t h e i n g r e d i e n t s o f f a t t y phase A ) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase B) t o 75C. Under s t i r r i n g add phase 8 ) t o phase A ) , c o o l homogenize and c o o l t o 30C. Then add phase C ) and s t i r c o l d . A p p l i c a t i o n No. C 008.1/01.96

Wei n h t % 5.00 3 . 0 0 2 . 0 0 2 . 5 0 8 . 0 0

66 .40 0 . 5 0 0.30 2 . 0 0 5 .00 5 . 0 0 0 .30

t o 50C,

Light After Sun Fluid

D i s b u t i n - B T , i n t h i s q u i c k b r e a k emu ls ion , p o s i t i v e l y i n f l u e n c e s t h e r e g e n e r a t i v e c a p a c i t y o f t h e s k i n by i n s t a n t d i s m u t a t i o n o f t h e oxygen f r e e r a d i c a l s p r e v e n t i n g t i s s u e damage.

Itern I nc r red i e n t s : 1 A ) Pemulen TR-1

Wei q h t % 0 . 2 5

2 C e t i o l 868 8 . 0 0 3 P a r a f f i n O i l 1 0 . 0 0 4 V i t a m i n E A c e t a t e 0 . 5 0 5 B) D e i o n i z e d Water 78.15 6 G l y c e r i n 2 . 0 0 7 Phenoni p 0 . 3 0 8 I m i d a z o l i d i n y l Urea 0 . 2 0 9 C) Sodium H y d r o x i d e 18% S o l u t i o n qs. pH 6 . 0

10 D) D i smut i n-BT 0 . 3 0 11 F r a g r a n c e : C h i a r a 0/238927 0 .30

P rocedure : M i x phase A) and homogenize f o r 2 m i n u t e s . Under s t i r r i n g add phase 6 ) t o phase A) and homogenize. N e u t r a l i z e w i t h phase C and t h e n add i t e m s 10 + 11, s t i r . Appl i c a t i on No. A 033. A/01 - 9 6

SOURCE: Pentapharm L t d . : Suggested F o r m u l a t i o n s


After Sun Lotion

A smooth l o t i o n t h a t adds m o i s t u r e t o t h e s k i n a f t e r s u n n i n g . I n n r e d i e n t s : %w/w 1 . S t e a r i c A c i d 2 . 0 0 2 . C12-15 A l k y l Benzoate 6.50 3 . Cocoa B u t t e r 1 . o o 4. Wheat Germ O i 1 1 . o o 5 . Tocophery l A c e t a t e 0 , 5 0 6 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 2.00 7 . R i t o x 52 (PEG-40 S t e a r a t e ) 1 . o o 8 . D i s t i 11 ed/Dei o n i zed Water 68.30 9 . R i t a l o e 1X ( A l o e Vera G e l ) 10 .00 10. G1 y c e r i ne 3 .00 11 I T r i e t h a n o l ami ne (99%) 1 . 0 0 12. A1 1 a n t o i n 0 . 5 0 1 3 . A c r i t a m e r 941 (Carbomer) 0 . 2 0 14. A c r y l a t e s / O c t y l a c r y l ami de Copolymer 1 . o o 15.Germaben I I E 1 - 0 0 16 . Fragrance q . s . 1 7 , D e f e n s i n e (Wheat Germ E x t r a c t ) 1 .oo Compoundi ng Procedure :

add i t e m 13 w i t h r a p i d a g i t a t i o n . Heat t o 80C. S l o w l y s i f t i n i t e m 14 and mix u n t i l d i s s o l v e d . Add o i l t o w a t e r . Cool t o 40C w h i l e m i x i n g . Add i t e m s 15-17.

Combine i t e m s 1-7 and h e a t t o 80C. Combine i t e m s 8-12. S l o w l y

Ref . No. 122-6A

Sunscreen Cream

An e l e g a n t , smooth cream. The sunscreen has an e s t i m a t e d SPF o f about 15 w i t h a l i g h t f e e l and g r e a s e l e s s r u b i n . The f o r m u l a i s s t a b i 1 i zed w i t h A c r i tamer . I n g r e d i e n t s : %w/w 1 . A c r i t a m e r 934 (Carbomer) 0 . 4 0 2 . D i s t i 11 ed /De ion i zed Water 64.95 3 . P r o p y l e n e G l y c o l 3,OO 4 . Benzophenone-3 5 .00 5 . O c t y l Methoxyc innamate 7 . 5 0 6 . C12-15 A1 k y l Benzonate 7 . 5 0 7 . R i t a c h o l ( M i n e r a l O i l and L a n o l i n A l c o h o l ) 4 .00 8 . S t e a r i c A c i d ( T . P . ) 2 .00 9 . R i t a b a t e - 8 0 ( P o l y s o r b a t e - 8 0 ) 0 .50 1 0 . R i t a CA ( C e t y l A l c o h o l ) 0 .50 1 1 . T E A (99%) 0 .65 12.Rovisome C (ROVI B l e n d ) 4 .00 13 . G1 y d a n t q . s . 14.Per fume 9 , s . Compounding Procedure :

D i s p e r s e i t e m 1 i n t o i t e m 2 and h e a t t o 75-80C. Add i t e m 3 . M i x i t e m s 4-10 and h e a t t o 75-80C. Combine phases w i t h m i x i n g . A d j u s t pH w i t h i t e m 11. Cool t o 35-40C and add i t e m s 11-14.

SOURCE: R . I . T . A , C o r p . : Suggested F o r m u l a t i o n s

R e f . N o . 122-124

3 I O Cosmetic and Toiletry Formulations

After Sun Milk Reci pe : A Hos tapha t KL 340 N

H o s t a c e r i n DGS M i n e r a l o i 1, h i g h v i s c o s i t y I s o p r o p y l p a l m i t a t e C e t i o l SN J o j o b a o i l Walnut o i 1 0-Pant heno l B-Caro t i n A n t i o x i d a n t

B Carbopo l 980 C A l l a n t o i n

A q u a m o l l i n BC p d r . h . c . C i t r i c a c i d (10%) G1 y c e r i n C a u s t i c soda s o l u t i o n (10%) Water P r e s e r v a t i v e

D C o l l a g e n KD E thano l F rag rance

Procedure : 1 M e l t A a t c a . 70C, t h e n add B. 2 Heat C t o ca . 70C. 3 S t i r 2 i n t o 1 and s t i r u n t i l c o o l . 4 Add c a . 35C add t h e components o f D t o 3 . 5 Homogenize t h e e m u l s i o n .

Formula A V I /3016

W/O-Sun Screen Milk Rec ipe :

W B 1 . 5 0 4 .00 3 . 0 0 3 . 0 0 3 .00 3 .00 3 . 0 0 1 . o o q . s . 9 , s .

0 . 4 0 0.20 0 . 1 0 0 . 2 5 3 .00 1 .60

6 8 . 1 5

3 .00 1 .50 0 . 3 0

q . s .

A H o s t a c e r i n WO 2 . 0 0 A r l a c e l 989 2 .00 M i n e r a l o i l , l o w v i s c o s i t y 10 .00 I s o p r o p y l p a l m i t a t e 5 .00 Eu tano l G 5 .00 Neo-He l iopan E 1000 4 .00 Neo-He1 i opan 66 1 . o o

B A l l a n t o i n 0 . 2 0 Aquamoll i n BC p d r . h . c . 0 .10 C i t r i c a c i d (10%) 0 . 2 5 Sodium c h l o r i d e 2 . 0 0 Water 68 .15 P r e s e r v a t i v e q . s

C F rag rance 0 I 30 Procedure : 1 M e l t A a t c a . BOC. 2 S t i r s o l u t i o n B i n t o 1 a t room t e m p e r a t u r e and s t i r u n t i l

3 A t c a . 35C add C t o 2 .

SOURCE: Hoechs t : Gu ide Rec ipes f o r t h e Cosmetic I n d u s t r y

c o o l .

Formula A VI/7300


Insect Repellent Sunscreen

T h i s l o t i o n c o n t a i n s b o t h U n i r e p U-18 w h i c h i s a h i g h l y e f f e c t i v e r e p e l l e n t a g a i n s t a v a r i e t y o f i n s e c t s , and m u l t i p l e sunscreen i n g r e d i e n t s wh ich p r o v i d e an SPF o f 20+.

Sequence: Raw M a t e r i a1 : 1 Dei o n i zed Water 1 Me thy lpa raben 1 Hampene Na3T 2 Carbopol 934 (2% aq. d i s p . ) 3 U n i r e p U-18 3 Uvatone 2-6 3 E s c a l o l 557 3 Neohel i opan BE3 3 L i p o v o l MOS-70* 3 L i pomul se 165 3 Lipowax P 3 P r o p y l p a r a b e n 4 Dei o n i zed Water 4 T r i e t h a n o l a m i n e , 99% 5 Dei o n i zed Water 5 U n i c i d e U-13

* P a t e n t #4,659,573

P e r c e n t 51 .OO

0 . 2 5 0.05

12 .25 12 .75

7 . 7 5 7 .25 2 .50 1 . 4 5 1 . 4 5 1 . 4 5 0 . 1 0 0 . 5 0 0 . 2 5 0 .75 0 .25

P rocedure : 1 . Heat Sequence #1 t o 80C w h i l e m i x i n g w i t h overhead m i x e r a t

medi um speed. 2 . Heat Sequence #2 t o 65C and add t o Sequence #1 w i t h overhead

m i x e r a t medium speed ( h o l d i n g t e m p e r a t u r e a t 80C). 3 . I n a n o t h e r v e s s e l m i x and h e a t Sequence #3 t o 8OC o r u n t i l

c o m p l e t e l y m e l t e d and add t o b a t c h on overhead m i x e r a t medi um speed.

4 . Premix Sequence #4 and add t o b a t c h s w i t c h i n g t o sweep b l a d e a t l o w speed. Lower t e m p e r a t u r e t o 35C.

5 . A t 35C p r e m i x Sequence #5 and t o b a t c h . Cool t o 25C.

SOURCE: L i p 0 Chemica ls I n c . : Formula No, 884


Light After Sun Fluid

D i s b u t i n - B T , i n t h i s q u i c k b r e a k e m u l s i o n , p o s i t i v e l y i n - f l u e n c e s t h e c a p a c i t y o f r e g e n e r a t i o n o f t h e s k i n by i n s t a n t d i s m u t a t i o n o f t h e oxygen f r e e r a d i c a l s and t h e r e f o r e p r e v e n t i n g t i s s u e damage.

I t e m : I n n r e d i e n t s : 1 A) Pemulen TR1

%w/w 0 . 2 5

2 C e t i o l 868 8 . 0 0 3 P a r a f f i n O i l 10 .oo 4 V i t am i n-E-Acetate 0 .50 5 B) Water demi n e r a l i zed 78.15

7 Phenoni p 0 . 3 0

9 C ) Sodium H y d r o x i d e (18% s o l u t i o n i n demin.

6 G l y c e r i n 2 . 0 0

8 Imi d a z o l i d i n y l u r e a 0 .20

w a t e r ) q s . pH=6 10 D ) D i s b u t i n-BT 0 . 3 0 11 F r a g r a n c e / C h i a r a 0/238927 0 . 3 0

P rocedure : M ix phase A ) and homogenize f o r 2 m i n u t e s . Under s t i r r i n g add phase B ) t o phase A) and homogenize. N e u t r a l i z e w i t h phase C) and t h e n add i t e m s 10 + 11, s t i r . A p p l i c a t i o n No. A 033.A/01.96

After Sun Lotion

The c o m b i n a t i o n o f E l h i b i n and Lac tomide i n t h i s deep a c t i n g l o t i o n p r o v i d e s s k i n r e g e n e r a t i o n t h r o u g h t h e a n t i e l a s t a s e e f f e c t and l i p i d b a r r i e r r e c o n s t r u c t i o n . T h i s makes t h i s f o r m u l a i d e a l f o r a f t e r sun a p p l i c a t i o n .

I t e m : I n g r e d i e n t s : 1 A ) Tween 60 2 A r l a c e l 60 3 A r l a c e l 165 4 C e t y l a1 coho1 5 I s o p r o p y l m y r i s t a t e 6 B ) Water demi n e r a l i zed 7 I m i d a z o l i d i n y l u r e a 8 Phenoni p 9 P r o p y l e n e g l y c o l

10 E l h i b i n 11 Lactomi de 12 C ) F rag rance /T imbuk tu 0/186901

Procedure : Heat t h e i n g r e d i e n t s o f f a t t y phase A ) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase B ) t o 75C. Under s t i r r i n g add phase 8 ) t o phase A ) , c o o l t o

Then add phase C) and s t i r c o l d . A p p l i c a t i o n No. C 008 .1 /01 .96

homogenize and c o o l t o 30C.

SOURCE: Pentapharm L t d . : Cosmet ic A p p l i c a t i o n s

50C,

rn 5 . 0 0 3 .00 2 .00 2 .50 8 . 0 0

66.40 0 .30 0 . 5 0 2 .00 5 .00 5 .00 0 . 3 0


Oil Free Skin Bronzer

Ingredients; Weight% Phase A : P o l y g l y c e r y l - 3 M e t h y l g l u c o s e D i s t e a r a t e (Tego Care 450) 3 . 0 0 G l y c e r y l S t e a r a t e ( T e g i n M) 2 . 0 0 C e t y l A l c o h o l (Tego A l k a n o l 16 ) 1 . 5 0 Polydecene 4 .00 C e t e a r y l Oc tanoa te ( T e g o s o f t L i q u i d ) 4 . 0 0 Capry l i c / C a p r i c T r i g l y c e r i d e ( T e g o s o f t CT) 3 . 5 0

Phase B: G1 y c e r i n B u t y l ene G 1 y c o l Water P r e s e r v a t i v e s

Phase C: T i t a n i um D i o x i d e I r o n Oxides

Phase D : F rag rance

1 .50 2 . 0 0

76 .50 Q . S .

0 . 7 0 1 . 3 0

Q . S .

Procedure : 1 . Combine t h e i n g r e d i e n t s o f Phase A t o g e t h e r . Heat t o 65C and

m i x . 2 . Combine t h e i n g r e d i e n t s o f Phase B t o g e t h e r . Heat t o 65C. 3 . Add Phase A t o 8 . Homogenize. 4 . Add p i g m e n t s . C o n t i n u e t o homogenize. When t h e p igmen ts a r e

5 . Cool t o 35-45C w i t h sweep a g i t a t i o n . 6 . Add F r a g r a n c e . Sweep m i x . 7 . D ispense .

SOURCE: Goldschmi d t Chemi c a l Corp I : Suggested Formul a t i on

f u l l y d i s p e r s e d , b e g i n c o o l i n g .


O/W-Sun Blocker

- I n w e d i _______ e n t s : A . H o s t a c e r i n DGL

H o s t a c e r i n DGS M i n e r a l o i l , l o w v i s c o s i t y I s o p r o p y l p a l m i t a t e Euso lex 6300 D-Panthenol

B . PNC 400

C . Euso lex 232

D . T r i s Amino Water P r e s e r v a t i v e

E . F rag rance

by Weigh t 1 . 0 0 4 . 0 0

1 0 . 0 0 5 . 0 0 5 . 0 0 0 . 5 0

1 . 3 0

5.00

2.21 65 .69

q . s

0 . 3 0

Procedure : 1 . M e l t A a t c a . 70C, t h e n add B. 2 . D i s s o l v e C i n D a t c a . 70C. 3 . S t i r 2 i n t o 1 and s t i r u n t i 1 c o o l . 4 . A t c a . 35C add E t o 3 . 5 . Homogeni ze t h e emu1 s i on.

F o r m u l a t i o n PF-0377E suggested by Hoechst AG ( A V I /7204)

Aculyn 33 Sun Screen Lotion

- I n p r e d i e n t s : A . Montan OV 68

Lano l 37T Dow C o r n i n g 200/350 Euso lex 6300 Solagum L

6 . Water Euso lex 232TS Acu lyn 33 T r i s Amino C r y s t a l s

C . P r e s e r v a t i ve Perfume

___ % by Weight 5 . 0 0

15 .00 5 . 0 0 3 . 0 0 0 . 5 0

63 .00 3 .00 3 . 0 0 2 .00

q . s . q . s .

P h y s i c a l C h a r a c t e r i s t i c s : Appearance: B r i l l i a n t cream pH: 7 V i s c o s i t y (RVT, #3 /20 ) : 1 5 , 0 0 0

F o r m u l a t i o n PF-0386 suggested by Rohm & Haas Co. (PF-037)

SOURCE: Angus Chemical Co. ; P roduc t Fo rmu la ry


O/W-Sun Screen Milk

Rec ipe : A H o s t a c e r i n DGL

Host acer i n DGS M i n e r a l o i 1, h i g h v i s c o s i t y Avocado o i l Neo-Hel iopan E 1000 Neo-He1 i opan BB A n t i o x i d a n t

B PNC 400 C A q u a m o l l i n BC p d r . h . c .

C i t r i c a c i d (10%) Water P r e s e r v a t i ve

D Fragrance

Procedure : 1 M e l t A a t c a . 70C, t h e n add B. 2 Heat C t o c a . 70C. 3 S t i r 2 i n t o 1 and s t i r u n t i l c o o l . 4 A t c a . 35C add D t o 3 . 5 Homogenize t h e e m u l s i o n .

Formula A VI /7200

O/W-Sun Blocker

Reci pe : A H o s t a c e r i n DGL

H o s t a c e r i n DGS M i n e r a l o i 1 , l o w v i s c o s i t y I s o p r o p y l p a l m i t a t e Euso lex 6300 D-Panthenol

6 PNC 400 C Euso lex 232 D T r i s ( h y d r o x y m e t h y 1 )-ami nomethane

Water P r e s e r v a t i ve

E Fragrance

Procedure : 1 M e l t A a t c a . 70C, t h e n add B . 2 D i s s o l v e C i n D a t c a . 70C. 3 S t i r 2 i n t o 1 and s t i r u n t i l c o o l . 4 A t c a . 35C add E t o 3. 5 Homogenize t h e e m u l s i o n

SOURCE: Henkel : Guide Recipes f o r t h e Cosmet ic I n d u s t r y

Formula A V I /7204

Wt% 1.00 4.00 6 .00 1 . o o 9 . 0 0 1 . o o

0 . 3 0 0 . 1 0 0 . 2 5

77 I 05

0 .30

q . s .

q . s .

Wt% 1 . o o 4 .00

10 .00 5 . 0 0 5 . 0 0 0 I 50 1 . 3 0 5 . 0 0 2.21

65 .69

0 . 3 0 q . s .


O/W Sun Screen with Organic and Inorganic Screens

I n g r e d i e n t s : A . I m w i t o r 370 ( G l y c e r y l S t e a r a t e C i t r a t e )

I m w i t o r 375 ( G l y c e r y l Citrate/Lactate/Linoleate/

M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) S o f t i s a n 649 ( B i s - D i g l y c e r y l P o l y a c y l a d i p a t e - 2 )

O l e a t e )

B . L u v i s k o l K 30 (PVP) K e l t r o l F (Xanthan) P r e s e r v a t i ve Water , ad

C . Perfume

SPF c a . 10, w a t e r r e s i s t a n t

P r e p a r a t i on : A i s hea ted t o 75-8OC. B i s m ixed and h e a t e d up t B i s e m u l s i f i e d i n t o A . A t 30C C i s added.

C e t y l a1 coho1 Euso lex 6300 ( 4 - M e t h y l b e n z y l i d e n e Camphor) Hombi t e c L 5 ( T i t a n d i o x i de )

t h e same tempera tu

O/W Sun Protection Lotion (SPF 15)

I n g r e d i e n t s : A ) I m w i t o r 370 ( G l y c e r y l S t e a r a t e C i t r a t e )

I m w i t o r 377 ( G l y c e r y l L a u r a t e / C i t r a t e / L a c t a t e ) M i g l y o l 812 ( C a p r y l i c / C a p r i c T r i g l y c e r i d e ) S o f t i san 649 ( B i s-Di g l y c e r y l Pol y a c y l a d i p a t e - 2 ) Euso lex 6300 ( 4 - M e t h y l b e n z y l i d e n e Camphor) Hombi tec L5 ( T i t a n i u m D i o x i d e )

B) K e l t r o l F (Xanthan Gum) P r e s e r v a t i v e

Weight% 5 . 0 0

3 . 0 0 16 .00

5 . 0 0 3 .00 3 .00 3 .00

0 . 5 0 0 . 5 0

100.00

0 . 3 0

9 , s .

Weight% 3 . 0 0 5 .00

16 .00 5 . 0 0 3 .00 3 . 0 0

0 . 5 0 q . s .

Water Up To 100.00

C) F rag rance q . s .


b r o u g h t t o t h e same t e m p e r a t u r e and e m u l s i f i e d i n t o ( A ) . ( C ) i s added a t abou t 35 degrees C .

( A ) i s h e a t e d up t o c a . 75 degrees C . (B) i s s t i r r e d and

F o r m u l a t i o n 4.2C

SOURCE: Huls Amer ica I n c . : Suggested F o r m u l a t i o n s

Sun Care Products 31 7

Pre-Sun Moisture Accelerator

A g l o s s y o i 1 -i n-wa te r emu1 s i o n c o n t a i n i ng V i t am i n E , v i t am i n A, R i t a p a n D and D e f e n s i n e t o p r o t e c t a g a i n s t t h e d r y i n g and damaging e f f e c t s o f t h e sun. I n g r e d i e n t s : o/,w/w 1 . R i t a b a t e - 8 0 ( P o l y s o r b a t e 80) 3 . 0 0 2 . R i t a IPP ( I s o p r o p y l P a l m i t a t e ) 2 .50 3 . R i t a GMS ( G l y c e r y l S t e a r a t e ) 2 . 5 0

5 . Tocophery l L i no1 e a t e 1 . 5 0 6 . S o r b i t a n S t e a r a t e 1 . 5 0 7. R i t a c e t y l ( A c e t y l a t e d L a n o l i n ) 1 . 5 0 8 . Tocophery l A c e t a t e 1 . o o 9 . D i s t i l l e d / D e i o n i z e d Water 79 .65 1 0 . R i t a p a n D ( P a n t h e n o l ) 1 . o o 1 1 . A c r i t a m e r 934 (Carbomer) 0 . 3 0 1 2 . T r i e t h a n o l a m i n e (99%) 0 .60 1 3 . V i t a m i n A P a l m i t a t e 1 . 2 0 14 . Germaben I I E 0 . 7 5 15 . F rag rance 4 , s . 16 .De fens ine (Wheat Germ E x t r a c t ) 1 . 0 0 Compounding P rocedure :

a g i t a t i o n . Heat t o 75C. Heat i t e m s 1-8 t o 75C. Add t o w a t e r w i t h a g i t a t i o n . Add i t e m 12. Cool t o 40C. Add i t e m s 13-16. Cool t o room t e m p e r a t u r e whi 1 e m i x i ng .

4 . R i t a SA ( S t e a r y l A l c o h o l ) 2 * 00

D i s s o l v e i t e m 10 i n i t e m 9 and s l o w l y add i t e m 11 w i t h r a p i d

R e f . NO. 121-174

Oil in Water Sunscreen Cream

An o i l i n w a t e r emu ls ion t h a t p r o t e c t s a g a i n s t UV-B r a y s . I n a r e d i e n t s : w 1 . P o l y e t h y l e n e 2 .oo 2 . S t e a r i c A c i d 0 .50 3 . R i t a l a n ( L a n o l i n O i l ) 6 . 0 0 4. R i t a IPP ( I s o p r o p y l P a l m i t a t e ) 12 .50 5 . S o r b i t a n S t e a r a t e 1 . 3 0 6 . R i t a b a t e - 6 0 ( P o l y s o r b a t e 60) 1 .80 7 . O c t y l Me thy loxyc innamate 6 . 5 0 8 . D i s t i l l e d / D e i o n i z e d Water 6 2 . 0 0 9 . A c r i t a m e r 940 (Carbomer) 0 . 2 0 1 0 . S o r b i t a n (70%) 5 . 0 0 11.Germaben I 1 0 .80 12. T r i e t h a n o l a m i n e (99%) 0 .40 13 .De fens ine (Wheat Germ E x t r a c t ) 1 . o o Compounding P rocedure :

10 and 11 and h e a t t o 85C. Combine i t e m s 1-7 and h e a t t o 95C. S l o w l y add t o w a t e r w h i l e m i x i n g . Add i t e m 12 w i t h a g i t a t i o n u n t i l smooth and u n i f o r m . Cool t o 40C and add i t e m 13.

S l o w l y s i f t i t e m 9 i n t o i t e m 8 w i t h r a p i d a g i t a t i o n . Add i t e m s

R e f . No. 121-172

SOURCE: R . I . T . A , C o r p . : Suggested F o r m u l a t i o n s


Self Tanning DHA Cream(W/O Emulsion)

I n a r e d i e n t s : O i l Phase A : P o l y g l y c e r y l - 4 I s o s t e a r a t e (and ) C e t y l D i m e t h i c o n e

Hydrogenated C a s t o r O i l M i c r o c r y s t a l 1 i ne Wax C a p r y l i c / C a p r i c T r i g l y c e r i d e s ( T e g o s o f t CT) O c t y l S t e a r a t e ( T e g o s o f t OS) I s o p r o p y l M y r i s t a t e ( T e g o s o f t M ) I s o p r o p y l P a l m i t a t e ( T e g o s o f t P) C e t y l D ime th i cone ( A b i l Wax 9801)

O i l Phase 6: Cyc l ometh i cone

Water Phase: Water P r o p y l e n e G l y c o l D i h y d r o x y a c e t o n e NaCl P r e s e r v a t i v e s , C o l o r , F rag rance

C o p o l y o l (and) Hexyl L a u r a t e ( A b i 1 WE-09)

Weight%

5 . 0 0 . 5 0 . 5 3 . 0 5 . 0 4 . 0 1 . o 1 . o

4 . 0

69 .2 2 . 0 4 . 0 0 . 8 Q . S

P rocedure : 1 . Add t h e components o f t h e O i l Phase t o g e t h e r . Heat t o m e l t

and d i s p e r s e t h e waxes. When d i s p e r s e d , c o o l t o 40C w h i l e m i x i ng .

2 . Add t h e Cyc lometh i cone . M i x . 3 . Add t h e components o f t h e Water Phase t o g e t h e r . Heat t o

4 . A d j u s t pH o f t h e Water Phase t o 4 . 0 - 4 . 5 , i f necessa ry . 5 . W i t h l i g h t n i n ' m i x i n g , s t r e a m t h e Water Phase i n t o t h e

6 . W i t h sweep a g i t a t i o n , c o o l t o 35C. 7 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e s . 8 . Homogenize w i t h a r o t o - s t a t o r homogenizer .

SOURCE: Go ldschmid t Chemical C o r p . : Suggested F o r m u l a t i o n s

40C.

O i l Phase.

Sun Care Products 31 9

Skin Protecting Waterproof Sunscreen

A w a t e r p r o o f sunscreen t h a t p r o t e c t s t h e s k i n by a v o i d i n g f r e e r a d i c a l f o r m a t i o n w i t h D e f e n s i n e .

I n q r e d i e n t s : 1 . Oc ty lme thoxyc innamate 2 . Benzophenone-3 3 . R i t a IPP ( I s o p r o p y l P a l m i t a t e ) 4 . R i t a CA ( C e t y l A l c o h o l ) 5 . S t e a r i c A c i d 6 . R i t o x 52 (PEG-40 S t e a r a t e ) 7 . R i t a s i l 190 (D ime th i cone Copolyo 8 . D i m e t h y l Stearami ne 9 . A c r y l a t e s / O c t y l a c r y l a1 amide Cop0 l O . D i s t i l l e d / D e i o n i z e d Water 1 1 . A c r i t a m e r 941 (Carbomer) 1 2 . T r i e t h a n o l a m i n e (99%) 13.Germaben 11-E 1 4 . D e f e n s i n e (Wheat Germ E x t r a c t )

1

ymer

%w/w 7 .50 3 . 0 0 3 .00 1 . o o 2 . 0 0 1 . 5 0 1 .oo 2 . 0 0 2 .00

72.60 0 .20 0 . 7 0 1 .oo 2 . 5 0

Compounding P rocedure : Combine i t e m s 1-8 and h e a t t o 70C. S l o w l y s i f t i n i t e m 9 .

D i s p e r s e i t e m 11 i n i t e m 10 and h e a t t o 70C. When c o m p l e t e l y d i s p e r s e d add i t e m 12 . A d d o i l t o w a t e r and m i x . A l l o w t o c o o l and add i t e m s 13 and 14 .

R e f . No. 120-1948

Waterproof Sunscreen

A h i g h SPF sunsc reen l o t i o n wh ich i s w a t e r p r o o f and c o n t a i n s R i t a s i l 190 f o r l u b r i c i t y .

I n n r e d i e n t s : 1 . D i s t i 11 ed/Dei o n i zed Water 2 . A c r i t a m e r 941 (Carbomer 941) 3 . Oc ty lme thoxy Cinnamate 4 . Benzophenone-3 5 . R i t a IPP ( I s o p r o p y l P a l m i t a t e ) 6 . R i t a CA ( C e t y l A l c o h o l ) 7 . S t e a r i c A c i d XXX 8 . R i t o x 52 (PEG-40 S t e a r a t e ) 9 . R i t a s i l 190 (D ime th i cone C o p o l y o l ) 10 .D ime thy l S tea ramine 11 . A c r y l a t e s / O c t y l a c r y l ami de Copolymer 12.TEA 13.Germaben I I E

%w/w 74.90

0 . 2 0 7 . 5 0 3 .00 3 . 0 0 1 . o o 2 . 0 0 1 . 5 0 1 . o o 2 .00 2 . 0 0 0.70 1 . o o

Compounding P rocedure : D i s p e r s e i t e m 2 i n i t e m 1 and h e a t t o 70C. When c o m p l e t e l y

d i s p e r s e d add i t e m 12 . Combine i t e m s 3-10 and h e a t t o 70C. S l o w l y s i f t i n i t e m 11 and m i x u n t i l u n i f o r m . Add to w a t e r phase and m i x . Cool t o 45C and add i t e m 13.

SOURCE: R . I . T . A . C o r p . : Suggested F o r m u l a t i o n s R e f . No. 121-99


Solar Protection Lotion I n s r e d i e n t : Wt%* K: Dimeth i cone 2 . 0 0

Hydroxyoc tocosany l H y d r o x y s t e a r a t e 3 .50 P o t a s s i um C e t y l Phosphate (Amphi s o l K) 0 . 5 0 T i t a n i u m D i o x i d e (and) C12-15 A l k y l Benzoate

( T i o v e i 1 FIN) 1 2 . 5 0 S o r b i t a n P a l m i t a t e 3 .50 D i l a u r y l T r i m e t h y l o l p r o p a n e S i l o x y S i l i c a t e 5 .00

8 : D e i o n i z e d Water 63.10 Veegum U1 t r a , Magnesi um A1 umi num S i 1 i c a t e 0 .80

P r o p y l e n e G1 y c o l 5 . 0 0 P o l y s o r b a t e 20 3 .50 Sodi um L a c t a t e 0 .30 L a c t i c Ac id t o pH 5 . 5 q . s .

o l i n o n e (Ka thon CG) 0 . 1 0

Rhodi g e l , Xanthan Gum 0 . 2 0

C: Methylchloroisothiazolinone (and) M e t h y l i s o t h i a z -

P rocedure :

M i x w i t h a homogenizer o p e r a t i n g a t 5000 r p m . Weigh and dry b l e n d t h e Veegum U l t r a and R h o d i g e l , add them t o t h e w a t e r and m i x f o r 20 m i n u t e s . Add t h e r e m a i n i n g P a r t B i n g r e d i e n t s and m ix each f o r 3 m i n u t e s . M a i n t a i n t e m p e r a t u r e a t 75C. Weigh t h e P a r t A i n g r e d i e n t s i n t o a s e p a r a t e v e s s e l , m ix and h e a t t o 75C. Add P a r t A t o P a r t B. M i x f o r 10 m i n u t e s a t 5000 rpm. T r a n s f e r t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o c r e a t e a s m a l l v o r t e x . Beg in c o o l i n g w h i l e m i x i n g , a t 40C, add P a r t C . Package a t ambient t e m p e r a t u r e . Note: A v o i d pH o f 6 . 5 - 7 . 5 a s t h i s may a f f e c t SPF v a l u e .

Weigh t h e w a t e r i n t o a s u i t a b l e v e s s e l and h e a t t o 75C.

Formula f r o m A&E Connock, L t d .

I n n r e d i e n t : A : P r o p y l e n e

TiO2 Lotion

G l y c o l I s o c e t e t h - 3 A c e t a t e ( H e t e s t e r PHA) 10.00 O c t y i d o d e c y l - Neopentanoate ( E l e f a c 1-250) 10 .oo T i t a n i u m D i o x i d e (and ) B i smuth O x y c h l o r i d e

( T i t a n i u m D i o x i d e 110) 1 0 . 0 0 B : D e i o n i z e d Water 68.90

Veegum, Magnesium Aluminum S i l i c a t e 0 . 7 0 Rhodi g e l , Xanthan Gum 0 .30

C : M e t h y l c h l o r o i s o t h i a z o l i n o n e (and) M e t h y l i s o t h i a z o l - i none 0 .10

P rocedure : Weigh t h e w a t e r i n t o a s u i t a b l e v e s s e l and m ix w i t h a p r o p -

e l l e r m i x e r a t 1800 rpm. Dry b l e n d t h e Veegum and R h o d i g e l and add them t o t h e w a t e r . M i x f o r 60 m i n u t e s . I n a s e p a r a t e v e s s e l , m i x t h e P a r t A i n g r e d i e n t s u n t i l t h e T i t a n i u m D i o x i d e i s u n i - f o r m l y d i s p e r s e d . Add P a r t A t o P a r t B and m i x u n t i l u n i f o r m . Add P a r t C, m i x u n t i l u n i f o r m and package.

Formula f r o m B e r n e l Chemical Co., I n c . *As r e c e i v e d b a s i s



Sprayable Sunscreen

I n n r e d i e n t s : P a r t A : Dei o n i zed Water G1 y c e r i n AMP-95

P a r t B : O c t y l Methoxy C i nnamate O c t y l Sa l i cy1 a t e Oxybenzone C12-15 A1 coho1 s Benzoate 01 e th -10 S o r b i t a n 01 e a t e D i me th i cone, 100 c s . Pemulen TR-2

% b y Weight

79.20 3 . 0 0 0 .12

7 .00 3 . 0 0 2 . 0 0 4 .00 0 . 0 8 0 . 0 5 0 . 5 0 0 . 1 5

P a r t C : P ropy lene G1 y c o l (and) D i azo1 i d i n y l Urea (and ) M e t h y l - paraben (and) P r o p y l p a r a b e n 0 . 8 0

D i s o d i um EDTA 0 .10 P rocedure :

Combine A i n g r e d i e n t s i n a v e s s e l wh ich w i l l c o n t a i n t h e e n t i r e f o r m u l a t i o n . I n a s e p a r a t e v e s s e l , combine a l l B i n g r e d - i e n t s e x c e p t d i m e t h i c o n e and Pemulen. Heat t o 45-50C t o h a s t e n d i s s o l u t i o n o f oxybenzone. D i s c o n t i n u e h e a t i n g and add Pemulen. M i x t o o b t a i n a smooth d i s p e r s i o n . Add d i m e t h i c o n e . Add B t o A w i t h r a p i d a g i t a t i o n . C o n t i n u e m i x i n g t o o b t a i n a smooth emul- s i o n . Add C . D i sod ium EDTA s h o u l d be added i n c r e m e n t a l l y such t h a t a B r o o k f i e l d v i s c o s i t y o f 500-1000 cps i s a c h i e v e d (model RVT @ 20 RPM, #2 s p i n d l e ) .

F o r m u l a t i o n PF-0320 sugges ted by B . F . G o o d r i c h

Waterproof Aerosol Sunscreen (SPF 10)

I n q r e d i e n t s : % b v Weinht SD A l c o h o l 40 43.65 AMP-95 0 . 3 5 Dermacry l 2 . 0 0 D e i o n i zed w a t e r 9 - 0 0 O c t y l Methoxyc innamate 7 . 5 0 Men thy l An than i l a t e 4 . 0 0 Cyc l ometh i cone 3 . 0 0 Tocophery l A c e t a t e 0 . 5 0 D i m e t h y l E t h e r 30 .00 P rocedure :

s i f t i n Dermacry l -79. M ix u n t i l c o m p l e t e . Add r e s t e x c e p t D i m e t h y l E t h e r . C o n t i n u e m i x i n g u n t i l c o m p l e t e . F i l t e r , f i l l and c h a r g e w i t h d i m e t h y l e t h e r .


Combine SD A l c o h o l 40 w i t h AMP-95. W i t h good a g i t a t i o n , s l o w l y

F o r m u l a t i o n PF-0318 sugges ted by N a t i o n a l S t a r c h & Chemical (7172-100)


Sunblock LotionI n t h i s f o r m u l a , Veegum i s used w i t h Rhod ige l Xanthan Gum and

a Xanthan Gum-based d i s p e r s i b l e emu1 s i f i e r t o s t a b i 1 i ze t h e e m u l s i o n and a d j u s t emu ls ion v i s c o s i t y . T h i s c o l d p r o c e s s l o t i o n has a l i g h t f e e l w i t h q u i c k , g r e a s e l e s s r u b - n . The sunsc reen s h o u l d o f f e r c o n s i d e r a b l e p r o t e c t i o n a g a i n s t sun1 i g h t - i n d u c e d s k i n p rob lems . The R i t a c h o l and F i n s o l v a r e n c l u d e d f o r emol- l i e n c e and r a p i d s k i n a b s o r p t i o n on r u b - i n . I n g r e d i e n t : A : Veegum, Magnesi um Alumi num S i 1 i c a t e

R h o d i g e l , Xanthan Gum Dei o n i zed Water

W t .%* 0 .60 0 . 1 5

65.45 N o n f a t D ry M i l k (and) Xanthan Gum (and) G l y c e r y l

S t e a r a t e (and) Hydrogenated V e g e t a b l e G l y c e r i d e s Phosphate 0 .80

P r o p y l e n e G l y c o l 3 . 0 0 B: C12-15 A l k y l Benzoate ( F i n s o l v TN) 8 . 0 0

Benzophenone-3 ( E s c a l o l 567) 5 . 0 0 O c t y l Methoxyc innamate ( P a r s o l MCX) 7 .50 M i n e r a l O i 1 (and) Lanol i n A l c o h o l ( R i t a c h o l ) 4 .00 P o l y s o r b a t e 80 0 . 5 0

C : Z inc Ox ide 5 .00 D : P r e s e r v a t i ve q . s .

Add t h e Veegum/Rhodigel d r y b l e n d t o t h e w a t e r s l o w l y , a g i t - a t i n g a t maximum a v a i l a b l e shear u n t i l smooth. Add t h e r e m a i n i n g P a r t A i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g a f t e r each u n t i l smooth and u n i f o r m . M i x t h e P a r t B i n g r e d i e n t s u n t i l t h e Benzo- phenone-3 d i s s o l v e s . Add P a r t 8 t o P a r t A and m i x u n t i l smooth. Add P a r t C and t h e n P a r t D and m ix each u n t i l smooth and u n i f o r m .

Sunblock with TiO2I n g r e d i e n t : W t .%* A : D i i s o p r o p y l Dimer D i l i n o l e a t e (Schercemol D I D ) 10.00

C e t y l Oc tanoa te (Schercemol CO) 1 . 5 0 S o r b i t a n S t e a r a t e 3 . 0 0 G l y c e r y l I s o s t e a r a t e 1 - 0 0 D i m e t h i c o n e C o p o l y o l 1 . o o T i t a n i um D i o x i d e (and ) C a p r y l i c / C a p r i c T r i g l y c e r i d e 1 2 . 5 0 C e t e a r y l A l c o h o l (and ) Ce tea re th -20 1 . o o Phenyl T r i met h i cone 1 .50

B: D e i o n i z e d Water 62.20 Veegum, Magnesi um A1 umi num S i 1 i c a t e 1 . o o Rhod ige l , Xanthan Gum 0 .30 P r o p y l e n e G1 y c o l 2 . 0 0 P o l y s o r b a t e 60 3 . 0 0

Weigh t h e w a t e r i n t o a s u i t a b l e v e s s e l and h e a t t o 70C. M i x C : P r e s e r v a t i v e q . s .

t h e w a t e r w i t h a homogenizer a t 5000 rpm. Weigh and d r y b l e n d t h e Veegum and R h o d i g e l , add them t o t h e w a t e r and c o n t i n u e m i x i n g f o r 20 m i n u t e s . Add t h e r e m a i n i n g P a r t B i n g r e d i e n t s , m i x i n g each f o r 3 m i n u t e s . Weigh t h e P a r t A i n g r e d i e n t s i n t o a n o t h e r v e s s e l , m i x and h e a t t o 70C. Add P a r t A t o P a r t B and m i x f o r 10 m i n u t e s a t 5000 rpm. Move t h e b a t c h t o a p r o p e l l e r m i x e r , a d j u s t t h e speed t o c r e a t e a s m a l l v o r t e x and b e g i n c o o l i n g . A t 40C add P a r t C and c o n t i n u e c o o l i n g . Package a t 35C. SOURCE: R . T . V a n d e r b i l t Co., I n c . : Formula #367 & Scher Chemicals


Sunless Tanning Lotion

D. I. Water M e t h y l Paraben P r o p y l Paraben G l y c e r i n B r i j 7 8 Neobee M-5 Cosmet ic Kessco GMS Kessco C e t y l A1 coho1 Wecobee S S i l i c o n e 200 (350 cps ) G1 ydan t D i h y d r o x y a c e t o n e C i t r i c A c i d (50%)

% by Wei a h t Q.S. t o 100.0

0.15 0.01 3.5 0.4 10.0 3.0 2.0 2.5 1 . o 0.25 3.5 Q . S .

M i x i ng P rocedure : P repare w a t e r phase b y a d d i n g w a t e r , M e t h y l Paraben, and

G l y c e r i n . M ix w e l l . Heat t o 160F. P r e p a r e o i l phase b y a d d i n g B r i j 7 8 , Neobee M-5 Cosmet ic , Kessco GMS, Kessco C e t y l A l c o h o l , P r o p y l Paraben, and Wecobee S. Heat t o 165F. Add o i l phase t o t h e wa te r phase. I n c r e a s e a g i t a t i o n . M i x a t 165F f o r 20-25 m i n u t e s . S t a r t c o o l i n g t o room t e m p e r a t u r e . A t llOF, add G l y d a n t . Premix D i h y d r o x y a c e t o n e w i t h w a t e r . Add a t 95F. Mix w e l l . A d j u s t p H ( t o 5.5-6.0) w i t h C i t r i c A c i d .

Tanning Accelerator

D . 1, Water M e t h y l Paraben P r o p y l Paraben G1 y c e r i n B r i j 7 8 Neobee M-5 Cosmet ic Kessco GMS Kessco C e t y l A l c o h o l Wecobee S S i l i c o n e DC 200 (350 c p s ) G1 y d a n t D i hyd roxyace tone C i t r i c A c i d (50%)

% by Weight Q . S . t o 100.0

0.15 0.01 3.5 0.4 10.0 3.0 2 . o 2.5 1 . o 0.25 3.5 Q . S .

M i x i ng Procedure : P repare w a t e r phase by a d d i n g w a t e r , M e t h y l Paraben, and

G l y c e r i n . M i x w e l l . Heat t o 160F. P r e p a r e o i l phase b y a d d i n g B r i j 7 8 , Neobee M-5 Cosmet ic , P r o p y l Paraben, Kessco GMS, Kessco C e t y l A l c o h o l , and Wecobee S . Heat t o 165F. Add o i l phase t o t h e w a t e r phase. I n c r e a s e a g i t a t i o n . M ix a t 165F f o r 20-25 m i n u t e s . S t a r t c o o l i n g t o room t e m p e r a t u r e . A t llOF, add G l y d a n t . Premix D ihyd roxyace tone w i t h w a t e r . Add a t 9 5 F . Mix w e l l . A d j u s t pH ( t o 5 . 5 - 6 . 0 ) w i t h C i t r i c A c i d . SOURCE: Stepan Co.: Suggested F o r m u l a t i o n s


Sunscreen Cream SPF 9

Phase # : 1 Dei o n i zed w a t e r 1 2% Carbopol 980 aqueous s o l u t i o n 1 P r o p y l e n e g l y c o l 1 Me thy lpa raben 1 P r o p y l p a r a b e n 1 T r i e t h a n o l ami ne 99%

2 Dei o n i zed w a t e r 2 T e t r a s o d i um EDTA 2 Euso lex 232 (2 -pheny l b e n z i m i d a z o l e - 5 - s u l f o n i c

2 T r i e t h a n o l ami ne 99% a c i d )

3 A r l a c e l 165 ( g l y c e r y l s t e a r a t e (and) PEG-100

3 Dow C o r n i n g 344 F l u i d ( c y c l o m e t h i c o n e ) 3 Emersol 132 L i l y S t e a r i c A c i d , NF 3 P r i s o r i ne 2039 (i s o s t e a r y l i s o s t e a r a t e ) 3 F i n s o l v TN (C12-15 a l k y l benzoa te )

s t e a r a t e )

Wt% 29.53 15 .00

5 . 0 0 0 .20 0 . 1 0 0.45

10 .00 0 .02

4.00 4 .20

1 - 0 0 5 . 0 0 5 . 0 0

10 .00 10.50

Procedure :

a t i o n . Heat Phase 1 t o 75-8OC. Combine Phase 2 i n g r e d i e n t s ; m i x t o c l a r i t y w h i l e h e a t i n g t o 70C. S l o w l y add Phase 2 t o Phase 1 . M i x combined phases a t 75-8OC. Combine Phase 3 i n g r e d i e n t s ; h e a t and m i x t o 85C. S l o w l y add Phase 3 t o b a t c h ; m i x f o r 15 m i n u t e s a t 85C. Remove f r o m h e a t ; s w i t c h t o p a d d l e m i x i n g and c o o l t o room t e m p e r a t u r e .

SOURCE: Rona/EM I n d u s t r i e s , I n c . : F o r m u l a t i o n EUS2-47-5

Add Phase 1 i n g r e d i e n t s t o main v e s s e l under i m p e l l e r a g i t -


Sunscreen Cream SPF 12+

Phase # : 1 Dei o n i zed w a t e r 1 2% Carbopol 980 aqueous s o l u t i o n 1 P r o p y l e n e g l y c o l 1 Me thy lpa raben 1 P r o p y l p a r a b e n 1 T r i e t h a n o l ami ne 99% 1 T e t r a s o d i um EDTA 2 O c t y l me thoxyc i nnamate 2 Euso lex 4360 2 A r l a c e l 165 ( g l y c e r y l s t e a r a t e (and) PEG-100

s t e a r a t e ) 2 Dow C o r n i n g 344 F l u i d ( c y c l o m e t h i c o n e ) 2 G1 y c e r y l s t e a r a t e 2 Emersol 132 L i l y S t e a r i c A c i d , NF 2 P r i sori ne 2039 (i s o s t e a r y l i s o s t e a r a t e ) 2 Castorwax (hyd rogena ted c a s t o r o i l ) 2 F i n s o l v TN (C12-15 a1 k y l benzoa te )

P rocedure :

E% 44.23 15 .00

5 . 0 0 0 .20 0 . 1 0 0 * 45 0 . 0 2 5 .00 3 . 0 0

1 - 0 0 5 IO0 4 .00 2 .50

10.00 2.00 2 . 5 0

Add Phase 1 i n g r e d i e n t s t o main v e s s e l under i m p e l l e r a g i t - a t i o n . Heat Phase 1 t o 75-80C. Combine Phase 2 i n g r e d i e n t s ; h e a t and m i x t o 85C. S l o w l y add Phase 2 t o b a t c h ; m i x f o r 15 m i n u t e s a t 85C. Remove f r o m h e a t ; s w i t c h t o p a d d l e m i x i n g and c o o l t o room t e m p e r a t u r e .

F o r m u l a t i o n EUS2-93-2

After Sun Lotion

Phase # : Wt% 1 D e i o n i z e d w a t e r ad 100.00 1 T i m i r o n S t a r 1 i g h t Go1 d 4 .00 1 D-Panthenol USP 1 . o o 1 P r o p y l e n e g l y c o l 3 .00 1 P r e s e r v a t i v e s qs 2 Cremophor A6 ( C e t e a r e t h - 6 (and) S t e a r y l

A1 c o h o l ) 2 .00 2 Cremophor A25 ( C e t e a r e t h - 2 5 ) 2 . 0 0 2 L u v i t o l EHO ( C e t e a r y l O c t a n o a t e ) 7 .00 2 P a r a f f i n O i l 8 . 0 0 2 C e t y l A1 c o h o l 1 . o o 2 G l y c e r y l Monos tea ra te 6 . 0 0 2 Dow C o r n i n g 200 F l u i d ; 100 c s 0 .20 2 (+-)-'? - 6 i s a b o l o l 0 . 2 0 3 F rag rance CIS

Procedure :

eous. Combine phase 1 , h e a t t o 7O-75CJ add t o phase 2 w i t h s t i r r i n g . S t o p h e a t i n g a t 60C, b e g i n homogenizer m i x i n g . Add phase 3 f r a g r a n c e a t 40C w i t h s t i r r i n g . Cool t o room t e m p e r a t u r e w i t h s t i r r i n g .


Combine phase 2, h e a t t o 70-75C w i t h s t i r r i n g u n t i l homogen-


Sunscreen Cream with UVA Protection (Est. SPF=25)

T h i s f o r m u l a c o n t a i n s t h e UVA a b s o r b e r s Men thy l A n t h r a n i l a t e and Z i n c Ox ide f o r a s t a b l e , e l e g a n t , high-SPF c o m p o s i t i o n w i t h enhanced U V A u r o t e c t i o n .

A:

B :

C:

jngredJe_n_t: O c t y l Methoxyc i nn i mate (Ne0 He1 i opan A V ) O c t y l S a l i c y l a t e (Neo He1 Men thy l A n t h r a n i l a t e (Ne0 I s o c e t y l A l c o h o l C e t e a r y l A l c o h o l (and) Ce G l y c e r y l S t e a r a t e PEG-40 S t e a r a t e C e t y l A1 coho1 Tocophery l A c e t a t e

opan O S ) He1 iopan MA)

e a r e t h - 2 0

Z i nc ' Ox ide ( Z i nc Ox ide N e u t r a l ) D i meth i cone

Dei o n i zed Water Veegum U l t r a , Magnesium Aluminum S i l i c a t e Rhodi g e l , Xanthan Gum Propy lene G1 y c o l D i sod i um EDTA

Methylchloroisothiazolinone (and) M e t h y l i s o t h i a z o l - i n o n e (Kathon CG)

__ W t . % * 7 . 5 0 5 . 0 0 5 . 0 0 2 . 0 0 2 . 0 0 1 . 5 0 1 - 0 0 0 . 7 5 0 . 2 5 6 .00 1 - 0 0

64 .70 0 I 50 0.50 2 . 0 0 0.20

0 .10

P rocedure :

M i x t h e w a t e r w i t h a homogenizer a t 5 0 0 0 rpm. Weigh and d r y b l e n d t h e Veegum U l t r a and Rhod ige l , add them t o t h e wa te r and c o n t i n u e m i x i n g f o r 15 m i n u t e s . Add t h e r e m a i n i n g P a r t B i n g r e d i e n t s i n o r d e r , m i x i n g each f o r 3 m i n u t e s . Weigh t h e P a r t A i n g r e d i e n t s i n t o ano the r v e s s e l . M ix and h e a t t o 75-8OC. Add P a r t A t o P a r t B and m ix f o r 1 0 m i n u t e s a t 75-8OC. Move t h e b a t c h t o a p r o p e l l e r m i x e r , a d j u s t t h e speed t o p roduce a s m a l l v o r t e x and s t a r t c o o l i n g . A t 40C add P a r t C and c o n t i n u e c o o l - i n g . Package a t 35C.

Weigh t h e wa te r i n t o a s u i t a b l e v e s s e l and h e a t t o 75-8OC.


SOURCE: R . T , V a n d e r b i l t C o . , I n c . : Veegum F o r m u l a t i o n from Haarman & Reimer Corp .


Sunscreen Emulsion with Titanium Dioxide

T h i s base i s an i d e a l s t a r t i n g p o i n t f o r sunscreen l o t i o n s . I t i s a v e r y s t a b l e f o r m u l a t i o n f o r any t y p e o f p igmented p r o d u c t .

I n q r e d i e n t : A : D e i o n i z e d Water

Veegum, Magnesi um A 1 umi num S i 1 i c a t e C e l l u l ose Gum A 1 1 a n t o i n Me thy lpa raben T i t a n i u m D i o x i d e (and) A lumina (and ) G l y c e r i n (and )

S i l i c a (UV-T i tan M212)

B : L e c i t h i n Lanol i n A1 coho1 G1 y c e r y l S t e a r a t e I s o p r o p y l P a l m i t a t e S t e a r i c A c i d C a p r y l i c / C a p r i c T r i g l y c e r i d e s I s o e i c o s a n e (Permethy l 1 0 2 A ) Pol y i sobutene (Permethy l 104A) I s o s t e a r i c A c i d P ropy lpa raben

C : I m i d a z o l i d i n y l Urea

D: T r i e t h a n o l ami ne, 99% Pol y g l y c e r y l m e t h a c r y l a t e

P rocedure :

wt . -55 61 . 9 8

0 . 5 0 0 . 1 5 0 . 0 5 0 . 2 0

8 . 0 0

1 . o o 1 . 5 0 0 .80 4 . 0 0 0 . 5 0 4 . 0 0 7 . 5 0 2 . 5 0 2 . 4 0 0 . 1 0

0 . 2 0

1 . 6 2 3 . 0 0

Weigh t h e P a r t A w a t e r i n t o a s u i t a b l e v e s s e l and mix w i t h a homogenizer o p e r a t i n g a t 5000 rpm. Dry b l e n d t h e Veegum and c e l l u l o s e gum, add t h e m i x t u r e t o t h e w a t e r and c o n t i n u e m i x i n g f o r 30 m i n u t e s a t 5000 rpm, w h i l e h e a t i n g t h e b a t c h t o 70-72C. Add t h e r e m a i n i n g P a r t A i n g r e d i e n t s i n o r d e r , m i x i n g each u n t i l u n i f o r m l y d i s p e r s e d . M i x t h e P a r t B i n g r e d i e n t s i n a n o t h e r v e s s e l and h e a t t o 75C. Add P a r t B t o P a r t A and m i x f o r 10 m i n u t e s a t 5000 rpm. Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o c r e a t e a s m a l l v o r t e x . Beg in c o o l i n g w h i l e m i x i n g . A t 60C, add P a r t C . A t 40C, add t h e P a r t D i n g r e d i e n t s i n o r d e r . Package a t ambient t e m p e r a t u r e .


SOURCE: R . T . V a n d e r b i l t C o . , I n c . : Veegum F o r m u l a t i o n f r o m Presperse , I n c ,


Sunscreen Gel Cera B e l l i n a (Pg-3 Beeswax) p roduces a n o n - g r a n u l a r , l ow

p e n e t r a t i o n and h i g h s t a b i l i t y g e l . T h i s f o r m u l a u t i l i z e s an a r r a y o f o i l s and a c t i v e s p r o d u c i n g a p r o d u c t w i t h a non-greasy s k i n f e e l , p e n e t r a t e s t h e s k i n q u i c k l y and has an SPF o f 4 t o 6 , O i l Phase: wt./, Sweet Almond O i l (Croda) 2 9 . 0 Cera B e l l i n a (Pg-3 Beeswax, K o s t e r Keunen) 1 5 . 3 I s o p r o p y l P a l m i t a t e (Unichema) 1 5 . 0 J o j o b a O i 1 ( J o j o b a Growers) 1 3 . 0 Sesame O i l ( P o l y e s t h e r ) 9 . 0 Avocado O i 1 ( A r i s t a ) 9 . 0 C e t y l S t e a r y l A l c o h o l ( P r o c t o r & Gamble) 4 . 0 E s c a l o l 507 (Van Dyk) 4 . 0 O z o k e r i t e 160/164 ( K o s t e r Keunen) 1 . o Carnauba #1 Y e l l o w ( K o s t e r Keunen) 0 . 5 V i t a m i n A P a l m i t a t e (BASF) 0 . 1 V i t a m i n E C o n c e n t r a t e (BASF) 0 . 1 P rocedure :

Hea t , n o t exceed ing 75C, and m i x u n t i l homogeneous. Reduce t e m p e r a t u r e t o 60C and pour i n t o c o n t a i n e r . A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t :

By r e p l a c i n g t h e j o j o b a , sesame and avocado o i l s w i t h l i g h t m i n e r a l o i 1 (28 .8%) and i n c r e a s i ng t h e Cera B e l 1 i na c o n c e n t r a - t i o n ( 1 7 . 5 % ) , one can p roduce t h e same p r o d u c t as d e s c r i b e d above. The f o r m u l a t o r has t h e a b i l i t y t o s u b s t i t u t e t h e i r p r e f e r r e d o i l s w i t h o n l y s l i g h t c o n c e n t r a t i o n changes o f Cera B e l l i n a t o p roduce p r o d u c t s o f t h e same c o n s i s t e n c y . Orange Wax ( K o s t e r Keunen) can be added t o n a t u r a l l y enhance t h e SPF.

T h i s v e r y economical p r o d u c t o f f e r s good b a r r i e r p r o p e r t i e s

Weigh and add each component o f t h e o i l phase t o a v e s s e l .

Lip Care Balm

and has an SPF o f 4 -6 . Neo H e l i o p a n ( H & R ) i s a s o l u t i o n o f 2 - E t h y l h e x y l - p - m e t h o x y c i n n a m a t e , a U V - B abso rbe r wh ich o f f e r s p r o t e c t i o n ove r a w ide s p e c t r a range and i s c o n s i d e r e d s a f e .

WJ % P e t r o l a t u m W h i t e USP ( W i t c o ) 4 4 . 0 S t e a r y l A1 coho1 ( P r o c t o r & Gambl e ) 1 7 . 5 NF Wh i te Beeswax ( K o s t e r Keunen) 9 . 5 O z o k e r i t e 160/164 ( K o s t e r Keunen) 1 9 . 5 Deodor i zed Orange Wax ( K o s t e r Keunen) 2 . 5 I s o p r o p y l P a l m i t a t e (Unichema) 1 . o P a r a f f i n 160/165 ( K o s t e r Keunen) 3 . 0 Neo He1 i opan AV (H&R) 2 . 0 T i t a n i u m D i o x i d e (Whi t t a k e r C&D) 1 . o P rocedure :

Add a l l components, h e a t t i l l 75C and use l o w shear t o d i s - p e r s e t h e T i 0 2 . Once t h e m i x t u r e i s homogeneous, c o o l and p o u r i n t o mo lds . A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t :

o i l s and a d d i t i o n a l sunscreens t o i n c r e a s e t h e SPF. F rag rance and c o l o r s a r e a l s o e a s i l y added. T h i s f o r m u l a i s v e r y s t a b l e and s l i g h t s u b s t i t u t i o n s i n i n g r e d i e n t s can be t o 1 e r a t e d . SOURCE: K o s t e r Keunen, I n c , : A Guide t o N a t u r a l F o r m u l a t i n g

I t i s easy t o i n c o r p o r a t e a c t i v e s such as v i t a m i n s , o t h e r


Sunscreen Lotion

Formul a t i ng Desi gn and Advantages : T h i s f o r m u l a demons t ra tes t h e r h e o l o g i c a l and s t a b i 1 i z i ng

p r o p e r t i e s o f Cera B e l l i n a . I n c o r p o r a t e d i n t o t h i s f o r m u l a i s t h e sunscreen E s c a l o l ( O c t y l D i m e t h y l PABA; Van Dyk) g i v i n g t h i s f o r m u l a an a p p r o x i m a t e SPF v a l u e o f 4 t o 6 . The p r o d u c t has h i g h g l o s s and e x c e l l e n t s k i n f e e l . The r h e o l o g i c a l p r o p e r t i e s o f Cera B e l l i n a a l l o w f o r t h i s p r o d u c t t o be packaged i n c o n v e n i e n t t u b e s o r squeeze b o t t l e s .

O i l Phase: E s c a l o l 507 (Van Dyk) Amerchol L 101 (Amercho l ) Cera Be l 1 i na (Pg-3 Beeswax; K o s t e r Keunen) G l y c e r o l Monos tea ra te (Henkel ) L i g h t M i n e r a l O i l ( W i t c o ) I s o s t e a r i c A c i d (Unichema)

Water Phase: Water ( D i s t i l l e d ) 1 ,3 -Bu ty lene G l y c o l (Hoechs t ) G l y c e r i n e (Unichema) T r i e t h a n o l a m i n e (Dow) Germaben I 1 ( S u t t o n ) Carboxymethy l C e l l u l o s e ( H e r c u l e s )

Wt% 5 . 6 3 4 . 7 0 3 . 8 0 2 . 7 7 2 . 8 3 1 . 0 0

71 - 6 6 2.90 2 . 8 3 0 . 8 0 0 .80 0 . 2 8

P rocedure :

e n t i r e phase i s s o l u b i l i z e d . M e l t and m i x t h e o i l phase a t 75F. S l o w l y add t h e o i l phase t o t h e wa te r phase under v i g o r o u s a g i t a - t i o n . A l l o w t o c o o l t o 35C and p o u r i n t o j a r s .

A d a p t a t i o n o f Formula and I t s I n f l u e n c e on t h e P r o d u c t : I t i s easy t o a l t e r t h e sunscreen t o s u i t you r p r e f e r e n c e ,

w i t h o u t chang ing t h e c o n s i s t e n c y . The e m u l s i o n v i s c o s i t y can e a s i l y be a l t e r e d by chang ing t h e o i l and /o r wax c o n c e n t r a t i o n . Orange Wax ( K o s t e r Keunen) can b e a l t e r e d b y c h a n g i n g t h e o i l and/or wax c o n c e n t r a t i o n . Orange Wax ( K o s t e r Keunen) can be added t o n a t u r a l l y enhance t h e SPF.


Heat t h e w a t e r phase t o 75C under a g i t a t i o n e n s u r i n g t h a t t h e


Sunscreen Milk W/O

I n t h i s w/o sunscreen m i l k , L i p o g a r d a c t s as a f r e e r a d i c a l scavenger and p r o t e c t s s k i n l i p i d s f rom p e r o x i d a t i o n . P e n t a v i t i n D r o v i d e s t h e s k i n w i t h m o i s t u r e .

Itern I n g r e d i e n t s : 1 A) A r l a c e l 989 2 A r l a c e l 481 3 P a r a f f i n O i 1 4 I s o p r o p y l P a l m i t a t e 5 P a r s o l MCX 6 P a r s o l 1789 7 L i pogard

8 B ) D e i o n i z e d Water 9 Phenoni p

10 P e n t a v i t i n

Wei q h t % 6 . 0 0 1.50

14.00 6 . 0 0 3 . 0 0 3 . 0 0 3.00

57.70 0.50 5.00

1 1 C ) F r a g r a n c e : S o l a r a 0/227632 0 I 30

Procedure : Heat t h e i n g r e d i e n t s o f f a t t y phase A) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase B ) t o 75C. Under s t i r r i n g add phase 6) t o phase A ) , c o o l t o 50C, homogenize and c o o l t o 30C. Then add phase C) and s t i r c o l d .

SOURCE: Pentapharm L t d . : A p p l i c a t i o n No. G 006 .A /03 ,96

After Sun Lotion

I n g r e d i e n t s : Weight% A ) I m w i t o r 960K, F l a k e s ( G l y c e r y l S t e a r a t e SE) 4 . 0 0

M i g l yo1 840 ( P r o p y l e n e G1 y c o l D i c a p r y l a t e / D i c a p r a t e ) 7.00 C e t y l A1 coho1 1-00 Hos tapha t KL 340 N ( D i l a u r e t h - 4 - P h o s p h a t e ) 5.00

8 ) P r e s e r v a t i ve K e l t r o l F Gel 2% (Xanthan Gum) C i t r i c A c i d Water

C) F rag rance V i t a m i n E

4 , s . 30.00 0.30

up t o 100.00

q . s . 0 . 2 0


b r o u g h t t o t h e same t e m p e r a t u r e and e m u l s i f i e d i n t o ( A ) . ( C ) i s added a t about 35 degrees C.

SOURCE: H u l s Amer ica I n c . : F o r m u l a t i o n 4 . 2 D

( A ) i s h e a t e d up t o c a . 75 degrees C . ( B ) i s s t i r r e d and


Sunscreen Milk W/O

I n t h i s w/o sunsc reen m i l k , L i p o g a r d a c t s a s f r e e r a d i c a l scavenger and p r o t e c t s t h e s k i n l i p i d s f r o m p e r o x i d a t i o n . P e n t a v i t i n p r o v i d e s t h e s k i n w i t h m o i s t u r e .

I t e m : I n g r e d i e n t s : 1 A ) A r l a c e l 989 2 A r l a c e l 481 3 P a r a f f i n O i l 4 I s o p r o p y l p a l m i t a t e 5 P a r s o l MCX 6 P a r s o l 1789 7 L i pogard 8 8 ) Water d e m i n e r a l i z e d 9 Phenoni p

10 P e n t a v i t i n 11 C ) Fragrance/0/227632 S o l a r a

P rocedure : Heat t h e i n g r e d i e n t s o f f a t t y phase A ) t o 70C. Heat t h e i n g r e d i e n t s o f w a t e r phase B) t o 75C. Under s t i r r i n g add phase B) t o phase A ) , c o o l t o 50C,

Then add phase C ) and s t i r c o l d . n i z e and c o o l t o 30C.

SOURCE: Pentapharm L t d . : A p p l i c a t i o n No. G 006.A/03.96

%w/w 6 . 0 0 1 . 5 0

14 .00 6 . 0 0 3 . 0 0 3 . 0 0 3 . 0 0

57 .70 0 . 5 0 5 .00 0 . 3 0

homoge-

Sunscreen Spray

Phase / Ing red i e n t : % by Wei g h t 1 A ) Cyc lometh i cone DC 345 5 5 . 6 0 2 A ) *Pol y s y n l ane 10.00 3 A ) *Grapeseed O i l 2 . 0 0 4 A ) *Sun f lower Seed O i 1 2 . 5 0 5 A) V i t a m i n E A c e t a t e 0 . 2 5 6 A ) Tenox 6 0.15 7 A) Fragrance Novarome NC-48 0 .50 8 B ) Ceraphy l 230 5 .00 9 B) O c t y l Me thoxyc i nnamate 7 . 5 0

10 B) Oxybenzone 4 .00 11 B) O c t y l S a l i c y l a t e 5 .00 12 B ) T r a n s c u t o l 7 .50

*Po l y e s t h e r Corp. P roduc t M a n u f a c t u r i n g I n s t r u c t i ons:

Combine phase A . Combine phase 8. Add phase B t o phase A . Package.

An easy t o a p p l y s p r a y t h a t l e a v e s t h e s k i n p r o t e c t e d f r o m b o t h UVA and UVB r a d i a t i o n . I t sp reads q u i c k l y and i s c o m p l e t e l y non-greasy. The a n t i c i p a t e d SPF i s 15. The f o r m u l a t i o n e x h i b i t s e x c e l l e n t s o l u b i l i z a t i o n o f t h e oxybenzone, wh ich i s o f t e n seen t o c r y s t a l l i z e o u t .

SOURCE: P o l y e s t h e r C o r p . : Suggested F o r m u l a t i o n


Sunscreen Moisturizing Cream

F o r m u l a t i n g Des ign and Advantages: T h i s f o r m u l a demonst ra tes t h e r h e o l o g i c a l and s t a b i 1 i z i ng

p r o p e r t i e s o f Cera B e l l i n a . I n c o r p o r a t e d i n t o t h i s f o r m u l a i s t h e sunscreen E s c a l o l ( O c t y l D imethy l PABA; Van Dyk) g i v i n g t h i s f o r m u l a an a p p r o x i m a t e SPF v a l u e o f 4 t o 6 . The cream has h i g h g l o s s and e x c e l 1 e n t s k i n f e e l . O i l Phase: Cera B e l l i n a (PG-3 Beeswax, K o s t e r Keunen) M i n o s i l ( P r i d e S o l v e n t s ) E s c a l o l 507 (Van Dyk) Amerchol L l O l (Amerchol ) C a s t o r O i l (Caschem) G l y c e r o l Monosteara te ( H e n k e l ) I s o p r o p y l P a l m i t a t e (Unichema) O z o k e r i t e 160/164 ( K o s t e r Keunen) S i l i c o n e F l u i d 245 (Dow C o r n i n g ) P r o p y l Paraben ( S u t t o n )

Water Phase: Water ( D i s t i l l e d ) B u t y l e n e G l y c o l (Hoechs t ) Sodium B o r a t e ( B o r a x ) M e t h y l Paraben ( S u t t o n )

Wt% 6 . 0 6 . 0 5 . 1 5 . 0 3 . 0 2 . 0 2 . 0 1 . o 1 . o 0 . 2

65.3 2 . 9 0 . 2 0 . 3

Procedure :

e n t i r e phase i s s o l u b i l i z e d . M e l t and mix t h e o i l phase u n t i l homogeneous and a t e m p e r a t u r e o f 75C i s m a i n t a i n e d . S l o w l y add t h e o i l phase t o t h e w a t e r phase under v i g o r o u s s t i r r i n g . A l l o w t o c o o l t o 35C and pour i n t o j a r s .

A d a p t a t i o n o f Formula and i t s I n f l u e n c e on t h e P r o d u c t : I t i s easy t o a l t e r t h e sunscreen t o s u i t your p r e f e r e n c e ,

w i t h o u t c h a n g i n g t h e c o n s i s t e n c y . The e m u l s i o n v i s c o s i t y can e a s i l y be a l t e r e d by chang ing t h e o i l and /or wax c o n c e n t r a t i o n . Orange Wax ( K o s t e r Keunen) can b e added t o n a t u r a l l y enhance t h e SPF.


Heat t h e w a t e r phase t o 75C under a g i t a t i o n e n s u r i n g t h a t t h e

Sun. Care Products 333

Sunscreen Stick

I n p r e d i e n t : Beeswax M y r i t o l 318 O i l s o f A loha Macadamia Nut O i l C e t e a r y l A l c o h o l Carnauba Wax P e t r o l a t u m O c t y l p-Methoxyc i nnamate V i t a m i n E

Phase : A A A A A A A A

% by We igh t 15 .00 15 .00 1 0 . 0 0 8 .00 1 . 5 0

50.50 5 . 0 0 0 .25

M a n u f a c t u r i n g Procedure: Combine i n g r e d i e n t s a t 75C. Pour i n t o mo lds .

SPF wou ld be 4 t o 6 . Sunscreen i s t h e O c t y l p -Me thoxyc inn -

Beeswax, carnauba and c e t e a r y l a l c o h o l f o r m t h e s t i c k . The Macadamia Nu t O i l h e l p s reduce P e t r o l a t u m ' s t a c k y f e e l . V i t a m i n E s e r v e s as an a n t i - o x i d a n t .

amate.

SOURCE: O i l s o f A loha : Suggested F o r m u l a t i o n

Aloe After Sun Lotion

Formula: A : Water G1 y c e r i n T r i e t h a n o l a m i n e Germaben I 1 8: S t e a r i c Ac id C a r n a t i o n M i n e r a l O i 1 (Wi t c o ) F i n e s o l v TN C e t y l A1 coho1 S i l i c o n e F l u i d 225 Cocoa B u t t e r I s o p r o p y l L a n o l a t e C : Aloe-Con WG-40 ( F l o r i d a Food P r o d u c t s ) D: F rag rance

% by Weiaht

74 .00 3 . 0 1 . o 0 . 5

8 . 0 5 . 0 2 . 0 1 . o 0 . 5 2 . 0 2 . 0

1 . o

q . s .

Procedure:

M i x and c o o l t o 55C. Add a l o e c o n c e n t r a t e t o b a t c h a t 55C. Add f r a g r a n c e a t 45C.


Heat phases t o 80C. A t 80C add o i l phase t o w a t e r phase.


Sun Tan Oil-A

Formula: SF1 204 SS4267 51 ando l M i n e r a l O i 1 ( W i t c o ) E s c a l o l 507 P r e s e r v a t i ve Perfume

Sun Tan Oil-B

Formula: SF1 204 SS4267 B l a n d o l M i n e r a l O i 1 ( W i t c o ) F1 u i 1 an Sunf 1 ower O i 1 ( L i po) E s c a l o l 507 P r e s e r v a t i v e Perfume

Sun Tan Oil-C

Formula: SF1 204 554267 B l a n d o l M i n e r a l O i 1 ( W i t c o ) F l u i l a n Almond O i 1 S u n f 1 ower O i 1 E s c a l o l 507 P r e s e r v a t i v e Perfume

% by Weiaht 45

5 45

5 9 , s . q . s .

% by Weight 40

5 40

5 5 5

q . s . q . s .

% by Weight 40

5 35

5 5 5 5

q . s . 9 . s .

P rocedure :

c l e a r s o l u t i on .


B l e n d a l l i n g r e d i e n t s e x c e p t SS4267. Add SS4267 and s t i r t o a


Wash-Off Resistant Sunscreen Lotion with Crodafos CES

The i n c o r p o r a t i o n o f Crodafos CES i n t h e f o r m u l a e n a b l e s t h i s sunscreen l o t i o n t o a t t a i n h i g h e r s t a t i c SPF and s u s t a i n a more improved w a t e r p r o o f SPF. These improved SPF's a r e due t o t h e a b i l i t y o f Crodafos CES t o enhance o i l d e p o s i t i o n , wh ich g i v e s t h e h i g h e r i n i t i a l SPF, and t o i t s s u b s t a n t i v i t y as a phosphate- based e m u l s i f y i n g system, wh ich r e s u l t s i n b e t t e r r e s i s t a n c e t o wash-o f f t o g i v e t h e h i g h e r s u s t a i n e d w a t e r p r o o f SPF.

I n g r e d i e n t s : P a r t A : Crodafos CES ( C e t e a r y l A l c o h o l (and) C e t e a r y l Phosphate) Crodaco l C-70 ( C e t y l A l c o h o l ) Vo lpo S-2 ( S t e a r e t h - 2 ) Vo lpo S-10 ( S t e a r e t h - 1 0 ) P e t r o l a t u m M i n e r a l O i l (7Ossu)

P a r t 8 : D e i o n i z e d w a t e r TEA 99%

P a r t C : Propy lene G l y c o l (and) D i a z o l i d i n y l Urea (and) M e t h y l

O c t y l Methoxyc innamate Paraben (and) P r o p y l Paraben

pH=5.0+-0.5 V i s c o s i t y = ( R V T S p i n d l e #5, lOrpm, 25C)=13,00Ocps+-10%

Procedure :

Wt%

6 . 0 0 .5 0 . 5 1 . o 4 . 5 8 . 0

70.7 0 . 3

1 . o 7 . 5

Combine i n g r e d i e n t s o f P a r t A w i t h m i x i n g and h e a t t o 75-8OC. Combine i n g r e d i e n t s o f P a r t B w i t h m i x i n g and heat t o 75-80C. Add P a r t B t o P a r t A w i t h m i x i n g and c o o l t o 40C. Add i n g r e d - i e n t s o f P a r t C w i t h m i x i n g and c o o l t o d e s i r e d f i l l temp- e r a t u r e .


SOURCE; Croda I n c . : F o r m u l a t i o n SC-258


Water-In-Oil Sunscreen SPF 26

I n q r e d i e n t s : Phase A : C e t y l D i m e t h i cone Copol yo1 (and ) Pol y g l y c e r y l - 4

I s o s t e a r a t e (and ) Hexy l L a u r a t e ( A b i l WE-09) C e t y l D i m e t h i c o n e ( A b i 1 Wax 9840) O c t y l P a l m i t a t e ( T e g o s o f t OP) O c t y l S t e a r a t e ( T e g o s o f t OS) M i n e r a l O i l Beeswax Hydrogenated C a s t o r O i l

Phase B : O c t y l Methoxyc innamate T i t a n i um D i o x i d e Cyc l ometh i cone

Phase C : Water Sodium C h l o r i d e P r e s e r v a t i ves

Weight%

5 .00 0 . 2 5 1 .25 5 . 3 5 1 . 7 5 1 . 2 0 0 . 8 0

5 .00 5 . 0 0 4 . 4 0

69.20 0 . 8 0 Q.S

Procedure : 1 . Heat Phase A t o 85C t o m e l t and d i s p e r s e waxes. 2 . Cool Phase A t o 50C. Add B t o A s l o w l y w i t h a l o w energy

3 . R o l l e r m i l l t o reduce p a r t i c l e s i z e o f T i t a n i u m D i o x i d e . 4 . Cool t o 50C. 5 . Heat Phase C t o 50C. Add Phase C t o A/B s l o w l y w i t h l o w

m i x e r .

ene rgy m i x i n g . M a i n t a i n a smooth m i l k y appearance a t a l l t i m e s w h i l e m i x i n g .

6 . Cool t o 35C and homogenize.

SOURCE: Go ldschmid t Chemical C o r p . : Suggested F o r m u l a t i o n


Waterproof SPF 30 Sunscreen

T h i s sunsc reen f o r m u l a c o n t a i n i ng Croda s new c o n d i t i o n i ng and e m u l s i f y i n g system Croda fos CES was c l i n i c a l l y t e s t e d by AMA L a b o r a t o r i e s f o r i t s Sun P r o t e c t i o n F a c t o r (SPF) and shown t o have a s t a t i c SPF o f 31.66 and a W a t e r p r o o f SPF o f 3 0 . 3 1 . The a b i l i t y o f C roda fos CES t o i n c r e a s e o i l d e p o s i t i o n and improve wash-o f f r e s i s t a n c e appears t o enhance t h e f o r m u l a ' s sunscreen pe r fo rmance and c o n t r i b u t e t o t h e h i g h SPF.

I n q r e d i e n t s : D e i o n i zed Water Carbopol 981

Wei n h t % 6 3 . 2 3

0.13

Croda fos CES ( C e t e a r y l A l c o h o l (and ) C e t e a r y l Phosphate) 6 .50 Benzophenone-3 5 . 0 0 O c t y l Methoxyc innamate 7 . 5 0 O c t y l Sa l i cy1 a t e 5 . 0 0 Men thy l A n t h r a n i l a t e 5 . 0 0 Crodamol OS ( O c t y l S t e a r a t e ) 5 . 0 0

NaOH-10% S o l n . 1 . 5 4 BHT 0 . 1 0 P r o p y l e n e G l y c o l (and) Diazo1 i d i n y l Urea (and) Me thy l

Paraben (and ) P r o p y l Paraben 1 . o o

pH=5.8+-0.5 V i s c o s i t y = 1 7 , 0 0 0 cps+-10% (RVT S p i n d l e TB, 10 rpm @ 25C). S t a t i c SPF=31.66 W a t e r p r o o f SPF=30.31

P rocedure :

M i x w e l l f o r good h y d r a t i o n . B e g i n h e a t i n g t o 75-80C. Add Croda fos CES and m ix w e l l u n t i l a l l i s m e l t e d and homogeneous. Add Benzophenone-3, O c t y l Methoxyc innamate, O c t y l S a l i c y l a t e , Men thy l A n t h r a n i l a t e and Crodamol OS i n d i v i d u a l l y and w i t h good m i x i n g . C o n t i nue m i x i n g a t 75-80C, u n t i 1 homogeneous. Begi n s l o w c o o l i n g and a t 60C add NaOH s o l u t i o n . Cool t o 45C and add BHT and p r e s e r v a t i v e .

Dust Carbopol i n t o t h e d e i o n i z e d w a t e r w h i l e s t i r r i n g r a p i d l y .

N . A . T . C Approved



Waterproof Sunscreen Lotion (SPF 15)Using Pemulen TR-1 and Carbopol Ultrez 10

I n s r e d i e n t s : A . D e i o n i z e d Water

Methocel E4M Nuosept C D i s o d i um EDTA AMP-95

B . Neo H e l i o p a n , Type AV Neo He1 i o p a n , Type OS U v i n u l M-40 F i n s o l v TN Pemulen TR-1 Carbopol U l t r e z 1 0

F rag rance #99189 "Twi stet-" C . C r o v o l A-40

?&by Weight 82.60

0 . 1 0 0 . 2 0 0 .05 0 . 2 5 7 .00 3 .00 2 . 0 0 4 . 0 0 0 . 2 5 0 . 2 0 0 . 2 0 0 . 1 5

P rocedure : 1 . Combine P a r t A i n g r e d i e n t s . M i x u n t i 1 homogeneous. 2 . Combine f i r s t f o u r P a r t B i n g r e d i e n t s i n a s e p a r a t e v e s s e l .

3 . Cool P a r t B t o 45C. D i s p e r s e l a s t two P a r t B i n g r e d i e n t s i n

4 . W i t h moderate a g i t a t i o n , add P a r t B t o P a r t A . M i x f o r 20

Heat m i x t u r e u n t i l oxybenzone has d i s s o l v e d .

P a r t B v e s s e l M ix u n t i l po l ymers a r e d i s p e r s e d w e l l .

m i n u t e s o r u n t i l a smooth, n o n - g r a i n y d i s p e r s i o n i s appar- e n t . Add P a r t C and m i x v i g o r o u s l y u n t i l a smooth, l u s t r o u s p r o d u c t i s o b t a i ned. F o r m u l a t i o n PF-0375 sugges ted by 8 . F .Goodr i ch (P0052)

Sunscreen Cream


Rheol a t e 5000 P r o p y l ene c a r b o n a t e

S i 1 i cone 7207 Promulgen D Ceraphyl 494

B. Panalene

C . AMP-95 D . Euxy l K-400

F i n s o l v TN E s c a l o l 507

% by Weight 78.16

0 . 3 0 2 . 5 0 8 .00 1 . o o 0 . 5 0 2 . 0 0 0 .24 0 . 3 0 2.00 5 . 0 0

P rocedure :

p r o p y l e n e c a r b o n a t e . Heat t o 80C. Combine B and h e a t t o 78C. Add B t o A w i t h s t i r r i n g . M ix f o r 10 m i n u t e s and add C . Cool t o 40C and add D. Package a t room t e m p e r a t u r e .


S i f t t h e po lymer i n t h e w a t e r , m ix f o r 20 m i n u t e s and add t h e

F o r m u l a t i o n PF-0313 sugges ted by Rheox, I n c .


Waterproof Suntan Lotion SPF 17 I n q r e d i e n t : Wt%x:

C e t y l A l c o h o l 1 . o o DEA C e t y l Phosphate 2 . 0 0

A : I s o s t e a r i c A c i d 4 .00

D ime th i cone 0 . 5 0 O c t y l Methoxyc innamate ( P a r s o l MCX) 7 . 5 0 O c t y l S a l i c y 1 a t e 4 . 0 0 Benzophenone-3 ( U v i n u l M-40) 2 . 0 0 O c t y l d o d e c y l Neopenanoate (E e f a c 1-205) 10 .00

B: D e i o n i z e d Water 63 .00 Veegum, Magnesi um A1 umi num S 1 i c a t e 0 . 7 5 Rhodi g e l , Xanthan Gum 0 . 2 5 G1 y c e r i n 4 . 0 0

C: P r o p y l ene G1 y c o l (and) D i azo1 i d i n y l Urea ( a n d ) Me thy lpa raben (and) P ropy lpa raben 1 . 0 0

Weigh t h e wa te r i n t o a s u i t a b l e v e s s e l and h e a t t o 85C. Dry b l e n d t h e Veegum and Rhod ige l and add them t o t h e w a t e r w h i l e m i x i n g w i t h a homogenizer a t 5 0 0 0 rpm. Con t inue m i x i n g f o r 20 m i n u t e s , Add t h e r e m a i n i n g P a r t B i n g r e d i e n t and m i x 3 m i n u t e s . Weigh and m ix t h e P a r t A i n g r e d i e n t s i n ano the r v e s s e l and h e a t them t o 85C. Add P a r t A t o P a r t B and m i x f o r 1 0 m i n u t e s a t 5000 rpm. Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o c r e a t e a s m a l l v o r t e x . Beg in c o o l i n g w h i l e m i x i n g s l o w l y . A t 40C, add P a r t C . Con t inue c o o l i n g and package a t 35C.

Formula f r o m B e r n e l Chemical C o . , I n c .

T h i s i s an e l e g a n t f e e l i n g sunscreen i n a c o l d - p r o c e s s l o t i o n SPF 12 Sunscreen Liposome Lotion

c o n t a i n i ng 1 i posomes f o r l o n g e r 1 a s t i ng p r o t e c t i o n I I n g r e d i e n t : _____ W t .%* A: D e i o n i z e d Water 5 8 . 5 3

Veegum, Magnesi um A1 umi num S i 1 i c a t e 1 . 4 0 Rhodi g e l Xanthan Gum 0 . 1 8 C e l l u l o s e Gum (CMC 7MF) 0 . 5 6

B : G l y c e r i n , 99% 3 . 0 0 B u t y l e n e G l y c o l ( a n d ) G l y c e r i n ( a n d ) Ch lo rophenes in

(and) Me thy l paraben ( K i 11 i t o 1 ) 3 . 0 0 Water (and) O c t y l Methoxyc innamate ( a n d ) Phenyl

T r i m e t h i c o n e (and) Cyc lometh icone ( a n d ) D i m e t h i c o n a l (and) Phosphog lyce r ides ( a n d ) Phenoxyethano l ( a n d ) Me thy lpa raben (and) E t h y l p a r a b e n ( a n d ) P ropy lpa raben (and) B u t y l p a r a b e n (Sansur f OMC) 2 3 . 3 3

Water ( a n d ) O c t y l Methoxyc innamate ( a n d ) Soy Phospho- g l y c e r i d e s (and) Phenoxyethanol (and) Tocophery l A c e t a t e (and) Me thy lpa raben (and) P ropy lpa raben (and) E t h y l p a r a b e n ( a n d ) B u t y l p a r a b e n (Sunscreen Liposomes) 1 0 . 0 0

Weigh t h e w a t e r i n t o a s u i t a b l e v e s s e l and m ix w i t h a p r o p - e l l e r s t i r r e r a t 1800 rpm. Weigh and d r y b l e n d t h e Veegum, Rhod ige l and CMC and add them t o t h e w a t e r . C o n t i n u e m i x i n g f o r 60 m i n u t e s a t 1800 rpm. Reduce t h e m i x e r speed t o p roduce a s l i g h t v o r t e x and add t h e P a r t B i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g each f o r 5 m i n u t e s . Package. *As r e c e i v e d b a s i s

SOURCE: R . T . V a n d e r b i l t Co . , Inc. : Veegum F o r m u l a t i o n s Formula from C o l l a b o r a t i v e L a b o r a t o r i e s

340 Costlietic and Toiletry Formulations

Water-Resistant Suntan Lotion

Formula: A :

% by Weigh t

Dei o n i zed Water Versene Powder Carbomer 934 B : G l y c e r i n P r o p y l e n e G l y c o l Me thy lpa raben E t h y l pa raben C : P r o p y l e n e G1 y c o l Xanthan Gum D: S o l u t i o n o f 10% E t h o c e l (Dow) and D i i s o p r o p y l A d i p a t e C a r n a t i o n M i n e r a l O i 1 ( W i t c o ) G l y c e r y l S t e a r a t e S o r b i t a n S t e a r a t e S t e a r i c Ac id D i m e t h i cone O c t y l D i m e t h y l PABA W h i t e F o n o l i n e P e t r o l a t u m ( W i t c o ) C e t y l A l c o h o l E : Dei o n i zed Water T r i e t h a n o l ami ne F : Dei o n i zed Water D o w i c i l 200 G: Perfume

60.90 0 . 0 5 0 . 1 5

3 .00 1 . o o 0 . 2 0 0 . 1 5

2 . 0 0 0 . 1 0

10 .00 10.00

3 .00 1 .oo 2 . 0 0 0 . 5 0 1 . 5 0 1 . o o 1 . o o

1 . 0 0 0 . 2 0

1 . o o 0 . 1 0

0 . 1 5

P rocedure :

S p r i n k l e i n Carbomer and m ix r a p i d l y . S t a r t h e a t i n g t o 80C. M i x B phase, h e a t t o 80C; add t o A when A i s above 60C. M i x C, add t o A a t 60C. M i x D, h e a t t o 80C, add t o w a t e r phase when b o t h a t 80C. M i x E, add t o b a t c h , m ix 10 m i n . , s t a r t t o c o o l . A t 45C, add F, t h e n per fume o i l .

SOURCE: Wi tco C a r p . : Suggested F o r m u l a t i o n

B e g i n m i x i n g w a t e r w i t h o u t h e a t ; add Versene and d i s s o l v e .


Zinc Oxide Sunscreen (Measured SPF=9.2)I n g r e d i e n t : W t .%* A : G l y c e r y l S t e a r a t e 2 . 5 0

PEG-40 S t e a r a t e 0 . 7 5 C e t e a r y l A l c o h o l (and) C e t e a r e t h - 2 0 0 . 7 5 T r i c o n t a n y l PVP 2 . 0 0 C a p r y l i c / C a p r i c T r i g l y c e r i d e s 5 . 0 0 M i n e r a l O i l 5 . 0 0 D ime th i cone 2 . 0 0

B : Z i n c Ox ide ( Z i n c Ox ide N e u t r a l ) 10 .00 C : D e i o n i z e d Water 6 5 . 3 5

Veegum U1 t r a , Magnesi um A1 umi num S i 1 i c a t e 0 . 7 5 Rhodi g e l , Xanthan Gum 0 . 5 0 P r o p y l e n e G l y c o l 5 . 0 0 T e t r a s o d i um EDTA 0 . 1 0

D: DMDM H y d a n t o i n ( a n d ) I o d o p r o p y n y l B u t y l c a r b a m a t e 0 . 2 0 L a c t i c A c i d , 88% 0 . 1 0 Weigh t h e P a r t C w a t e r i n t o a s u i t a b l e v e s s e l and m ix w i t h

a p r o p e l l e r s t i r r e r o p e r a t i n g a t 1800 rpm. Weigh and d r y b l e n d t h e Veegum U l t r a and Rhod ige l and add them t o t h e w a t e r . M i x f o r 30 m i n u t e s a t 1800 rpm. Add t h e r e m a i n i n g P a r t C i n g r e d i e n t s i n o r d e r and m i x u n t i l u n i f o r m . Beg in h e a t i n g t h e w a t e r phase t o 80C. Weigh t h e P a r t A i n g r e d i e n t s i n t o a n o t h e r v e s s e l and h e a t t o 80C. Add P a r t B t o P a r t A and m i x u n t i l u n i f o r m . S l o w l y add P a r t s A+B t o P a r t C and homogenize a t 5000 rpm u n t i l u n i f o r m . T r a n s f e r t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o produce a s m a l l v o r t e x , B e g i n c o o l i n g . A t 40C, add P a r t D . C o n t i n u e m i x i n g and c o o l i n g . Package a t 25-3OC.

- I m r e d i e n t : Sunscreen Lotion Using Micronized TiO2

A : P r o p y l e n e G l y c o l I s o c e t e t h - 3 A c e t a t e C12-15 A l k y l Benzoate Casein ( a n d l Xanthan Gum (Tensami 306) P ropy lpa raben ( T r i s e p t P) .

Aluminum S i B: D e i o n i z e d Water

Veegum, Magnesi urn C: M e t h y l G luce th -20

G1 y c e r i n Me thy lpa raben ( T r T i t a n i um D i o x i de

D: D e i o n i z e d Water

s e p t M) M i c r o T i t a n

I r n i d a z o l i d i n y l Urea ( T r i s t a t I U ) E : Sodium L a c t a t e

i c a t e

um D i o x i d e MT-5OOB)

W t . % * 8 . 0 0 5 . 0 0 1 . 5 0 0 . 2 5

67.40 0 . 7 0 5 . 0 0 3 .00 0 . 2 5 5 . 0 0 3 . 0 0 0 . 3 0 0 . 6 0

Weigh t h e w a t e r i n t o a s u i t a b l e v e s s e l and h e a t t o 7 5 C . M i x t h e wa te r w i t h a homogenizer a t 5000 rpm. Add t h e Veegum t o t h e wa te r and c o n t i n u e m i x i n g f o r 20 m i n u t e s . Add t h e P a r t C i n g r e d - i e n t s i n o r d e r , m i x i n g each f o r 5 m i n u t e s . Weigh t h e P a r t A i n g r e d i e n t s i n t o a n o t h e r v e s s e l . M i x and h e a t them t o 75C. Add P a r t A t o P a r t s B+C and m ix f o r 1 0 m i n u t e s a t 75C. Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o c r e a t e a s m a l l v o r t e x . Beg in c o o l i n g w i t h c o n t i n u o u s , s l o w m i x i n g . M i x t h e P a r t D i n g r e d i e n t s and add them a t 40C, t h e n add P a r t E. C o n t i n u e m i x i n g and c o o l i n g . Package a t 35C.

SOURCE: R . T . V a n d e r b i l t C o . : Formulas Haarman & Re imer /T r i -K *As r e c e i v e d b a s i s .


Zinc Oxide Sunscreen Cream (PABA/Oxybenzone Free)Estimated SPF=20

I n n r e d i e n t : A : O c t o c r y l e n e (Neo H e l i o p a n 303)

O c t y l Methoxyc innamate (Neo He I s o c e t y l A l c o h o l C e t e a r y l A l c o h o l (and ) Ce tea re G l y c e r y l S t e a r a t e PEG-40 S t e a r a t e D i m e t h i cone C e t y l A l c o h o l Tocophery l A c e t a t e

B: Z i n c Ox ide C : D e i o n i z e d Water

i opan A V )

h-20

Veegum U1 t r a , Magnesi um A1 umi num S i 1 i c a t e Rhodi g e l , Xanthan Gum P r o p y l ene G l y c o l D i s o d i um EDTA

D: P r o p y l e n e G1 y c o l (and ) D i azo1 i d i n y l Urea (and ) Me thy lpa raben (and ) P ropy lpa raben

W t I %* 7 . 0 0 7 . 5 0 2 . 0 0 2 .00 3 .00 1 .oo 1 . 0 0 0 .75 0 . 2 5 6 . 0 0

65.30 0 .50 0 . 5 0 2 .00 0 .20

1 .oo

P rocedure :

p r o p e l l e r s t i r r e r o p e r a t i n g a t 1800 rpm. Weigh and d r y b l e n d t h e Veegum U l t r a and Rhod ige l and add them t o t h e w a t e r . M i x f o r 30 m i n u t e s a t 1800 rpm. Add t h e r e m a i n i n g P a r t C i n g r e d i e n t s i n o r d e r and m ix u n t i l u n i f o r m . Beg in h e a t i n g t h e w a t e r phase t o 75C. Weigh t h e P a r t A i n g r e d i e n t s i n t o a n o t h e r v e s s e l and h e a t t o 75C. Add P a r t B t o P a r t A and m ix u n t i l u n i f o r m . S l o w l y add P a r t s A+B t o P a r t C and homogenize a t 5000 r p m u n t i l u n i - f o r m . T r a n s f e r t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o p roduce a s m a l l v o r t e x . B e g i n c o o l i n g . A t 40C, add P a r t D. C o n t i n u e m i x i n g and c o o l i n g . Package a t 25-28C.

SOURCE: R . T . V a n d e r b i l t C o . , I n c . : Veegum Formula f r o m Haarman &

Weigh t h e P a r t C w a t e r i n t o a s u i t a b l e v e s s e l and m ix w i t h a

Reimer Corp.

Section XIIMiscellaneous

343

344 Costnetic and Toiletry Formulations

Fluoride Dentifrice*

I n g r e d i e n t s : Cal c i um py rophospha te S o r b i t o 1 , 70% aq. s o l n . Sodi um l a u r y l s u l f a t e Sodium c a r b o x y m e t h y l c e l l u l o s e Sodi urn s a c c h a r i ne Stannous f l u o r i d e H e x e t i d i n e F1 a v o r i ng Water

% b y Weight 45.00 20.00 1.20 0.60 0.10 0.40 0.20 0.75

31.75

*UK P a t e n t 2,001,526A h e l d b y W i l l i a m R . Warner Co. L t d . (1979)

Mouthwash*

I n g r e d i e n t s : E t h a n o l

% b y Weight 10.00

G l y c e r o l 5 .00 E t h o x y l a t e d h i g h - p u r i t y c a s t o r o i l (Cremophor EL) 0.25 Z i n c C i t r a t e 0.15 Hexet i d i ne F l a v o r i n g , s a c c h a r i n e Water

0.20 0.10

t o 100.00

*European P a t e n t 0,049,830 A2 h e l d by P r o f e s s o r Hans Muehlmann (1982)

Gum-Massage-Gel*

I n q r e d i e n t s : Water A1 1 a n t o i n Pan theno l C e t y l p y r i d i n i u m c h l o r i d e Hexet i d i ne M e t h y l c e l l u l ose Peppermi n t o i 1

% by We iqh t 87.69

1 . o o 5.00 0.01 0.10 6.00 0.20

* S w i s s P a t e n t 622,945 h e l d by Hans Lukaschek and P r o f e s s o r Man f red Mai e r ( 1 981 )

SOURCE: Angus Chemical Co.: P r o d u c t F o r m u l a r y

Miscellaneous 345

Glycerol Gel Base

Other ingredients may be incorporated as desired.

I n g r e d i e n t s : Water, d e i o n i z e d S t a b i l e z e 06

G l y c e r i n e A d d i t i v e s Germa l l I 1

AMP-95

% b y Weight 9 . 0 0 0 .50 0 . 5 0

8 9 . 7 0

0 . 3 0 q . s .

Procedure: D i s p e r s e S t a b i l e z e i n wa te r w i t h s t i r r i n g f o r 1 0 m i n u t e s .

Heat t h e d i s p e r s i o n t o 70-80C f o r 15 t o 20 m i n u t e s , u n t i l t h i c k e n i n g o c c u r s . S t a r t c o o l i n g . Add AMP w i t h s t i r r i n g . M i x u n t i l u n i f o r m . Add g l y c e r i n e s l o w l y o v e r 10 m i n u t e s w i t h s t i r r i n g . S t i r u n t i l u n i f o r m g e l i s o b t a i n e d . Add r e m a i n i n g i n g r e d i e n t s , m i x i n g t h o r o u g h l y a f t e r each a d d i t i o n .

F o r m u l a t i o n PF-0244E sugges ted by I S P

Aculyn 33 Fluid Gel Emulsion


A c u l y n 33 I s o p r o p y l m y r i s t a t e I m i d a z o l i d i n y l Urea EDTA Na2

% by Weight t o 100%

2 .50 10.00

0 .30 0 . 1 5

8. AMP-95 2 .50

P rocedure : M ix t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d .

P h y s i c a l C h a r a c t e r i s t i c s : Appearance: F1 u i d g e l pH: 7 . 3 4 V i s c o s i t y : 700 cps

F o r m u l a t i o n PF-0387 sugges ted by Rohm & Haas C o . (PF-039)

SOURCE: Angus Cherni c a l CO. : P r o d u c t Formul a r y


Oil Liposome Gel

I n n r e d i e n t s : Phase 1 : Water , dem.

Pan theno l

Phase 2 : A l c o h o l

Phase 3 : U l t r e z 1 0

Phase 4 : J o j o b a O i l T i t a n i um D i o x i d e

Phase 5 : T r i s Amino Water , dem.

Phase 6 : N a t i p i d e I 1

Phase 7 : P r e s e r v a t i ves, Perfume

46 by Weight ad 100.00

10.00

13 .30

0 . 8 0

5 . 0 0 0 . 5 0

q . s . 5 . 0 0

5 . 0 0

q . s .

M a n u f a c t u r e : 1 . M a n u f a c t u r i n g a t room t e m p e r a t u r e . 2 . S l o w l y add phase 2 t o phase 1 w h i l e s t i r r i n g t h o r o u g h l y . 3 . S l o w l y add phase 3 w h i l e s t i r r i n g t h o r o u g h l y . 4 . Homogenize t h e m i x t u r e i n t e n s i v e l y . 5 . Add phase 4 w h i l e s t i r r i n g t h o r o u g h l y . 6 . Homogenize t h e m i x t u r e i n t e n s i v e l y . 7 . Add phase 5 w h i l e s t i r r i n g t h o r o u g h l y . 8 . Homogenize t h e m i x t u r e i n t e n s i v e l y . 9 . Add phase 6 w h i l e s t i r r i n g t h o r o u g h l y . 1 0. Homogeni ze t h e m i x t u r e i n t ens i ve 1 y . 11.Add phase 7 and homogenize t h e m i x t u r e i n t e n s i v e l y f o r a

s h o r t t i m e .

F o r m u l a t i o n PF-0376E sugges ted by Rhone-Poulenc R o r e r .


Miscellaneous 347

Ritavena 5 (1.0%)/Acritamer 934 (1.0%) Blend

I n g r e d i e n t s : P a r t A : 1 . D i s t i l l e d Water 2 . Me thy lpa raben

P a r t B : 3 . R i t a v e n a 5 4 . D i s t i l l e d Water , ( 1 O O C )

P a r t C : 5 . A c r i t a m e r 934 6 . D i s t i l l e d Water

P a r t D: 7 . G l y d a n t 40/700 8 . NaOH (20% S o l u t i o n )

%w/w

0 . 0 0 0 . 1 5

1 . o o 10 .00

1 . o o 75.80

0 . 2 5 1 . 8 0

Compoundi ng P rocedure :

m i n u t e s . M i x A and B. Add C . A d j u s t p H t o 7 . 0 w i t h NaOH s o l u t i o n . Combine. M i x u n t i l u n i f o r m .

F o r m u l a t i o n 11 1-1 17

Premix A i n h o t w a t e r b a t h . Premix C . M i x B i n B l e n d e r f o r 2

Gel Stick

A s o l i d g e l s t i c k o b t a i n e d by u s i n g Behenoyl L a c t y l a t e and Propy lene G l y c o l . The a d d i t i o n o f R i t a v e n a 5 adds s l i p and g l i d e f o r a p p l i c a t i o n , and reduces c r u m b l i n g o f edges. The R i t a v e n a 5 a l s o reduces s y n e r i s i s o f t h e g l y c o l .

I n g r e d i e n t s : P a r t A: 1 . Behenoyl L a c t y l a t e 2 . P r o p y l e n e G l y c o l 3 . R i t a CA

P a r t 8: 4 . D i s t i l l e d Water (1OOC) 5 . R i t a v e n a 5

P a r t C: 6 . Sodium H y d r o x i d e (20% S o l u t i o n )

w 15.00 70.00

3 . 0 0

6 .48 1 . o o

4 .52

Compounding P rocedure : Weigh and h e a t P a r t A t o 170F. A l l i t e m s s h o u l d b e l i q u i d .

M i x u n t i l u n i f o r m . Premix P a r t B i n a B l e n d e r f o r 2 m i n u t e s . Add P a r t B t o P a r t A . M i x . A d j u s t pH t o 8 . 5 w i t h P a r t C . Package w h i l e f l u i d .

M e l t p o i n t ca . 5 5 C . F o r m u l a t i o n 11 4-1 11

SOURCE: R . I . T . A . C o r p , : R i t a v e n a 5 : Suggested F o r m u l a t i o n s

Section XIII Trade-Named Raw Materials

348

Trade-Named Raw Materials 349

RAW MAT E R I ALS

A b i l AV-20, B 8851 , B 8852, B 88183

A b i l EM-90

A b i l OSW 12

A b i l Quat 3270, 3272, 3474

A b i l S-201

A b i l Wax 2440

A b i l Wax 9800

A b i 1 Wax 9801, 9840

A b i 1 WE-09

A b i l 100, 350

A - C Copolymer 400, 400A

A c e t u l a n

A c i d Phytosome

CHEMICAL D E S C R I P T I O N SOURCE

Phenyl t r i m e t h i cone Go1 dschmi d t

C e t y l d i m e t h i cone c o p o l yo1 Go1 dschmi d t

Cyc l ometh i c o n e / d i me th i - Go1 dschmi d t c o n o l / d i m e t h i cone

Q u a t e r n i um-80 Go1 dschmi d t

D i m e t h i cone /sod i um PG Go1 dschmi d t p r o p y l d i m e t h i c o n e / t h i o - s u l f a t e copolymer

Behenoxy d i m e t h i c o n e Go1 dschmi d t

S t e a r y l d i m e t h i c o n e Go1 dschmi d t

C e t y l d i m e t h i cone Go1 dschmi d t

Pol y g l y c e r y l - 4 - i s o s t e a r a t e / Go1 dschmi d t c e t y l d i m e t h i c o n e c o p o l y o l / h e x y l 1 a u r a t e

D i m e t h i c o n e Go1 dschmi d t

E t h y l e n e - v i n y l a c e t a t e A1 1 i ed-Si g- copolymer

A c e t y l a t e d 1 a n o l i n a1 coho1 Amerchol

Phosphol i p i d s L i PO

A-C P o l y e t h y l e n e 9A, 617, P o l y e t h y l e n e 61 7A

A c r i tamer 934 Carbomer 934



Acudyne 255, 41%

A c u l y n 22, 33

A1 1 i ed-Si g -

RITA

RITA

RITA

Rohm & Haas

Rohm & Haas

350 Cosrnetic and Toiletry Formulations

RAW M A T E R I A L S

Adogen MA-1 08

Adol 52NF

Adol 62, 66

Advantage CP

A e r o s i l 200

Agent 1829-50

A l d o MS

A l d o MSA

A1 f o n i c 141 2-A

A1 kamide DC 212/S

A lkamu ls GMS

A1 kamul s MM/M

A1 kamul s PSML-80

A1 oe-Con WG-40

A1 oe-Moi s t

CHEMICAL D E S C R I P T I O N

D i m e t h y l s t e a r a m i ne

C e t y l a1 c o h o l

F a t t y a1 c o h o l

Fumed s i l i c a

Compl ex o f c h e m i c a l s

G l y c e r y l f a t t y a c i d e s t e r

G1 y c e r y l s t e a r a t e & PEG-1 00 s t e a r a t e

Ammonium l a u r e t h s u l f a t e

A1 kano l ami de

A1 oe

A1 oe

A l o e Vera L i p o Quinone E x t r a c t

A l u g e l OF30 A 1 umi num h y d r o x i de

SOURCE

W i t c o

W i t c o

I S P

Degussa

Stepan

Lonza

Lonza

V i s t a

Rhone-

Rhone-

Rhone-

Rhone-

F l o r i d a

T e r r y

T e r r y

G i u l i n i

Amandul i ne SG Hydro1 yzed sweet almond p r o t e i n RITA

Amaranth 85E123 D y e s t u f f suspens ion 1% BAS F

Amerchol L-101 M i n e r a l o i l & l a n o l i n a l c o h o l Amerchol

Ammonyx GA-70 PG Amine o x i d e Stepan

Ammonyx GA-SO/GA-70PG Amine o x i d e Stepan

Ammonyx 4 Amine o x i d e Stepan

Ammonyx 4B S t e a r a l k o n i u m c h l o r i d e Stepan


RAW MATERIALS

A m e r l a t e P

A m i l a n GST 40

Amphisol A

Amphisol K

Amp homer

Arnphomer 28-4910

AMP R e g u l a r , AMP-95

Ampholyt J B 130/K

Amphosol CA, CG

A n t a r o x CO 530

A n t i l 141 L i q u i d

A n t i l 171

A q u a m o l l i n BC p d r . h c

A rgono l

A r i s t o f 1 ex A60%

A r l a c e l 60

A r l a c e l 165

A r l a c e l 186

A r l a c e l 481

A r l a c e l 989

CHEMICAL DESCRIPTION SOURCE

L a n o l i n f a t t y a c i d / e s t e r Arnerchol

DATEM Go1 dschmi d t

G i vaudan

P o t a s s i um c e t y l phospha te G i vaudan

Octylacrylamide/acrylates/ Nat S t a r c h b u t y l a m i n o e t h y l m e t h a c r y l - a t e copolymer

Nat S t a r c h

2-ami no-2-methy l -1 -p ropano l Angus

Cocami d o p r o p y l b e t a i ne Hul s

Stepan

Nonoxynol 6 I S P

P r o p y l e n e G l y c o l & PEG-55 Go ldschmid t P r o p y l e n e G l y c o l O l e a t e P r e s e r v a t i v e

PEG-18 G l y c e r o l o l e a t e c o c o a t e Go ldschmid t

E t h y l enedi ami ne t e t r a a c e t i c Hoechst a c i d sodium s a l t

V A / c r o t o n a t e s copo lymer , Hoechst i s o p r o p y l a l c o h o l

S o r b i t a n monos tea ra te I C 1

G l y c e r y l s t e a r a t e & PEG-100 I C 1 s t e a r a t e

G1 y c e r o l monool e a t e I C 1

G l y c e r y l s o r b i t a n o l e o s t e a r a t e I C 1

PEG-7 hyd rogena ted c a s t o r o i l I C 1

A r l a c e l 1689 P o l y g l y c e r i n & s o r b i t o l I C 1


RAW MAT E R I A LS CHEMICAL DESCRIPTION SOURCE

A r l a m o l HD Isohexadecane I C 1

A r o s u r f 66-PE12 S u r f a c t a n t Sherex

Arquad T-50 T a l l o w t r i m o n i u m c h l o r i d e & Akzo i s o p r o p y l a l c o h o l

Avanel S-150 A n i o n i c s u r f a c t a n t PPG

Avanel 5-150 CG Sodium C12-15 p a r e t h - 1 5 PPG

B i o t e r g e AS-40 Sodium C14-16 o l e f i n s u l f o n a t e

Balsam HF-F-95-14276 F r a g r a n c e

B e l s i l DMC 6032 D ime th i cone c o p o l y o l

Benol W h i t e m i n e r a l o i 1

Bentone EW Hec to r ; t e c l a y

Bentone Gel CAO, SS71 R h e o l o g i c a l a d d i t i v e

B i o c a r e Polymer HA-24

B i o c a r e SA A1 bumen/Hyalur i c a c i d / D e x t r a n s u l f a t e

B i r o n B-50

B i r o n ESQ B i OC1

B1 ando l M i n e r a l o i l

B r i j 78 S t e a r e t h - 2 0

B r i t o l 9NF W h i t e m i n e r a l o i 1

B r o n i dox L/15

Brooksome SOD

Stepan

Hogan

Wac ke r

W i t c o

Rheox

Rheox

Stepan

Stepan

Rona

Rona

W i t c o

I C 1

W i t c o

Brooks

Brookswax P Brooks


RAW M A T E R I A L S CHEMICAL D E S C R I P T I O N

Brown Red Shade 1654

Brown Umber Shade 1985

B u r s t , RSD-10 Defoamer

B u t y l Carb i t o 1 S o l v e n t

B u t y l C e l l o s o l v e Sol v e n t

C19-011 D&C Red #7 Ca Lake C19-022 D&C Red #6 Ba Lake

SOURCE

Hydro1 abs

Un ion Carb

Un ion Carb

Rona

Calamide C Coconut d e r i v e d ami de P i l o t

Calamide CWT Super amide P i 1 o t

Calamide F Modi f i ed ol eami de DEA P i l o t

Calamide LL L i q u i d 1 aurami de DEA P i l o t

Calamide 0 Modi f i ed coco-01 e i c d i e t h a n o l - P i 1 o t amide 100%

Cal b l e n d C 1 e a r E t h e r s u l f a t e based c o n c e n t r a t e P i l o t

Cal b l end P e a r l P e a r l e s c e n t c o n c e n t r a t e P i l o t

C a l e n d u l a O i l CLR R i c h t e r

C a l f a x IOL-45 D i s u l f o n a t e d a1 k y l d i p h e n y l P i l o t e t h e r

Cal foam ALS-30 Ammonium l a u r y l s u l f a t e 30% P i l o t

Cal foam EA-603 Ammoni um l a u r y l e t h e r s u l f a t e P i l o t

Cal foam ES-301, ES-302 Sodi um l a u r y l e t h e r s u l f a t e 30% P i l o t ES-303

Cal foam SLS-30 Sodium l a u r y l s u l f a t e 30% P i 1 o t

Cal foam TLS-40 TEA l a u r y l s u l f a t e 40% P i l o t

Cal i mu1 se PRS I s o p r o p y l 1 i near a1 k y l benzene P i l o t s u l f o n a t e 90%

C a l o x y l a t e N-9 Nonyl pheno l e t h o x y l a t e P i l o t


RAW MAT E R I ALS CHEMICAL DESCRIPTION

C a l s o f t AOS-40, F-90 L i n e a r a1 k y l a t e s u l f o n a t e

Cal s o f t L-40 L i n e a r a1 k y l benzene s u l f o n a t e

Cal s o f t LAS-99, T-60 L i n e a r a1 k y l a t e s u l f o n a t e

Cal t a i ne C-35 Cocami d o p r o p y l b e t a i ne

Captex 300 F a t t y a c i d e s t e r (med. c h a i n )

Carbopol ETD 2001, Car bome r ETD 2020

Carbopol U l t r a 10 Carbomer

Carbopol 934 Carbomer 934







Carbowax E-8000 PEG-1 50

C a r d r e T i 02 /Z -Coa t /Oc ty l me thoxyc i nnamate D i s p e r s i on

C a r n a t i o n M i n e r a l O i l

Carnauba Wax

Carnauba #1 Y e l l o w

C a r r o t t O i l CLR

C a r s i m i de SAL-7 Laurami de DEA

Carsmol ALS Ammoni um 1 a u r y l s u l f a t e

Castorwax MP80 Hydrogenated c a s t o r o i l

C e l l o s i ze H y d r o x y e t h y l c e l l u l o s e

SOURCE

P i 1 o t

P i l o t

P i l o t

P i l o t

C a p i t a l

Goodr i c h

Goodr i c h

Goodr i c h

Good r i ch

G o o d r i c h

Good r i ch

G o o d r i c h

G o o d r i c h

Goodr i c h

Card re

W i t c o

Keumen

Keunen

R i c h t e r

Lonza

Lonza

CasChem

Union Carb


RAW MATER1 ALS

C e l l o s i z e QP 30,00OH, QP 52,000H

Cel q u a t H-100, L-200

C e l q u a t SC-230M, sc-24oc

Cerarni de Cornpl ex CLR

Ceraphyl -368

Ceraphyl 494

Ceraphyl 868

Cerasyn t I P

Ceres i ne Wax 130/135

C e t i o l B

C e t i o l HE

C e t i o l 3600

C e t i o l LC

C e t i o l MM

C e t i o l PGL

C e t i o l SN

C e t i o l V

C e t i o l 868

C e t y l s t e a r y l A1 c o h o l

C e t y l s t e a r y l A1 c o h o l

Charnorni 1 e O i 1

Ci t rno l 316 TM

C i t r o f 1 ex-2

CHEMICAL DESCRIPTION

H y d r o x y e t h y l c e l l u l o s e

Pol y q u a t e r n i um-4

P o l y q u a t e r n i urn-10

O c t y l p a l m i t a t e

Emu1 s i f i e r

Ernoll i e n t

Emu1 s i f i e r

Emol l i e n t e s t e r s

PEG-7 g l y c e r y l c o c o a t e

Emol l i e n t e s t e r s

Emol 1 i e n t e s t e r s

M y r i s t y 1 m y r i s t a t e

E m o l l i e n t e s t e r s

C e t e a r y l i sononanoa te

Decyl o l e a t e

O c t y l s t e a r a t e

1618

T r i e t h y l c i t r a t e

SOURCE

Un ion Carb

N a t i o n a l

N a t i o n a l

R i c h t e r

ISP/Van Dyk

ISP/Van Dyk

ISP/Van Dyk

ISP/Van Dyk

Keunen

Henkel

Henkel

Henkel

Henkel

Henkel

Henkel

Henkel

Henkel

Henkel

Keunen

P r o c t o r &

Dragoco

M o r f 1 ex


RAW MATER1 ALS CHEMICAL DESCRIPTION

C1 a r i s k i n Yeast e x t r a c t

C l e a r l a n Lanol i n

C l o i s o n n e ' B l u e Flambe 6502: Cosmet ic p e a r l powders C l o i sonne' C e r i s e Flambe 5502 C l o i s o n n e ' Monarch G o l d 233X

CMC, CMC 7MF Carboxymethy l c e l l u l o s e

CO-1895 S t e a r y l a1 c o h o l

Coconut F rag rance O i l

C o l l a g e n KD

C o l l a g e n Seco lan BA

C o l l ami no Complex 40 C o l l agen ami no a c i d s

Col 1 a s o l S o l u b l e c o l 1 agen

Col o r o n a Copper P e a r l e s c e n t p igmen ts C o l o r o n a Red Go ld Co lo rona Red Brown

Comperlan KD Cocamide DEA

Corona PNL Lanol i n

Cosmet ic Tan C33-130 I r o n o x i d e

Cosmowax K S t e a r y l a l c o h o l / c e t e a r e t h 20

Cremerol HMG S u r f a c t a n t

Cremophor A6 C e t e a r e t h - 6 / s t e a r y l a l c o h o l

Cremophor A25 C e t e a r e t h 25

Cremophor EL E t h o x y l a t e d c a s t o r o i l

Cremophor RH40 S u r f a c t a n t

C r i l l 6 S o r b i t a n e s t e r

C rodaco l C-70 C e t y l a1 c o h o l

SOURCE

RITA

Henkel

Mear l

Aqua1 on

Aroma Tech

GFN

Secol

B rooks

Croda

Rona

Henkel

Croda

Sun

Croda

H u l s

Hul s

BASF

BASF

BASF

Croda

Croda


RAW MATER I A LS

Crodacol C-95

Crodacol CS-50

Croda fos CES

Croda fos N3 N e u t r a l

C roda fos N10 N e u t r a l

C roda fos SG

Crodamol GTCC

Crodamol IPM

Crodamol OPG

Crodamol OS

Crodamol PMP

Crodamol PTC

Crodasome CM-Glucan

Crodes ta SL-40

Cromoi s t CM-G1 ucan, Cromoi s t GM-G1 ucan

Cromo is t HYA

Croquat M

C r o s i 1 k Powder

C r o t e i n ADW

C r o t e i n Q

C r o t e i n SPO

C r o v o l A-40


C e t y l a1 c o h o l

C e t e a r y l a1 c o h o l

C e t e a r y l a l c o h o l / c e t e a r y l phosphate

DEA o l e t h - 3 - p h o s p h a t e

DEA o le th -10 -phospha te

PPG-5-ceteth-10-phosphate

C a p r y l i c / c a p r i c t r i g l y c e r i de

F a t t y a c i d e s t e r

O c t y l p e l a r g o n a t e


SOURCE

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Croda

PPG-2 m y r i s t y 1 e t h e r p r o p i o n a t e Croda

P e n t a e r y t h r i t y l t e t r a c a p r y l a t e l c a p r a t e

Sodi um ca rboxymethy l B -g l ucan

Sucrose c o c o a t e

Carboxymethy l B-g1 ucan

C a t i o n i c p r o t e i n d e r i v a t i v e

I s o s t e a r o y l h y d r o l y z e d wheat p r o t e i n

S t e a r t r i moni um h y d r o x y e t h y l hyd ro1 yzed c o l 1 agen

Hydro1 yzed c o l 1 agen

Modi f i ed e t h o x y l a t e d o i 1

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Croda


RAW MATERIALS CHEMICAL D E S C R I P T I O N

C r o v o l A - 7 0 PEG-60 almond g l y c e r i d e s

Croda M40

C r o v o l PK-40 M o d i f i e d e t h o x y l a t e d o i 1s

C u t i na GMS G l y c e r y l s t e a r a t e

DC Q2-5220 D i me th i cone c o p o l yo1

DC S i 1 i cone 200/350 c t s D i me th i cone

DC-190 D i me th i cone c o p o l yo1

DC 200/200 c s D ime th i cone

DC 345 F l u i d Cyc l omethi cone

DC 556 Phenyl t r i me th i cone

DC 929 S i 1 i c o n e Amodimethicone & nonoxynol -10 & t a l 1 o w t r i moni um c h l o r i d e

D e f e n s i ne Wheat germ e x t r a c t

Dehymuls F

Dehymul s PGPH

Dehyquar t E H y d r o x y c e t y l h y d r o x y e t h y l d imonium c h l o r i d e

Dehyquar t LT L a u r t r i moni um c h l o r i de

Dehyton AB 30 Coco-be ta i ne

Dehyton K Cocami d o p r o p y l b e t a i ne

Dentphos K D i c a l c i um phosphate

Deodor i zed Orange Wax

Dermacry l , Dermacry l LT

S k i n c a r e po lymer

SOURCE

Croda

Croda

Croda

Henkel

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

R I T A

Henkel

Henkel

Henkel

Henkel

Henkel

Henkel

Hoechst

Keunen

N a t i o n a l


RAW MATER1 ALS CHEMICAL DESCRIPTION

Dermal c a r e N I S k i n c a r e po lymer

Dermacry l -79 S k i n c a r e polymer

Dervac i d 31 55

D i m e t h y l E t h e r

D i o c t y l A d i p a t e & O c t y l S t e a r a t e & O c t y l P a l m i t a t e

D i smut i n-BT Superox ide d i smutase

DL-Pant heno l

DNS Compl e t e c h MBAC-DS Chemicals complex

Dowanol TPM T r i p r o p y l e n e g l y c o l m e t h y l e t h e r

Dow C o r n i n g F l u i d D i meth i cone 200/350 c s .

Dow C o r n i ng Q2-5220 D i meth i cone cop01 yo1

Dow C o r n i n g S i l i c o n e D imeth icone 245

Dow C o r n i n g 190, 193 D imeth icone c o p o l y o l

Dow C o r n i n g 200 F l u i d D imeth icone

Dow C o r n i n g 344 F l u i d , Cyc lometh icone 345 F l u i d

Dow C o r n i n g 3225C F l u i d

Dow C o r n i n g 7224

Dowic ide A A n t i m i c rob i a1 agent

D o w i c i l 200 P r e s e r v a t i ve

D-Panthenol

D-Panthenol USP

D-Panthenol 50P Pant henol & p r o p y l ene g l y c o l

Drakeo l -9 M i n e r a l o i l

SOURCE

Rhone-Poul

N a t i o n a l

DuPont

W i ckhen

Pentapharm

Roche

L i PO

Dow

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

Dow C o r n i n g

Dow

Dow

Hoffman-La

BAS F

BAS F

Penreco


RAW MATERIALS CHEMICAL DESCRIPTION SOURCE

Drakeol-21 Mineral o i l Penreco

Drewpol 3-1-0, Emulsifier Stepan 10-10-0

Dry-Flo PC Aluminum starch octenylsuccinate National

DV-3284 Sodium isethionate ( 5 5 2 )

Dymel A, HFC-152a

Dynaceri n 660 Oleyl erucate

Edeta BD

Elastosol Animal Collagen & Elastin

Elefac 1-205 Octyldodecyl neopentaoate

Elfacos GT282S Hydrogenated talloweth-60 myristyl glycol

Flhibi n Soy protejn

Emerest 1723 Ester

Emeres t 23 16 Ester

Emerest 2407 Glyceryl stearate SE

Emerest 2452 Ester

Emerest 2486 Ester

Emerson-132

Emerwax 1266

Empicol TI 40t Anionic surfactant

Einpigen BE Lauryl betaine

Empilan EGMS Surfactant

Empilan E2502 Cocamide DEA surfactant

Rhone-Poul

DuPont

Huls

BAS F

Croda

Bernel

Akzo

Pentapharm

Henkel

Henkel

Henkel

Henkel

Henkel

Henkel

Henkel

Albright

Albright

A 1 br i gh t

Albright


RAW MATER I ALS CHEMICAL DESCRIPTION

Empi I a n LDE S u r f a c t a n t

Emsorb 2500 S o r b i t a n e s t e r

Emul gade 1 O O N I

Emul gade 1 O O O N I

Emul g a t o r 21 55 S t e a r e t h - 7 & s t e a r y l a l c o h o l & s t e a r e t h - 1 0

Emul s i f y i ng Wax

Emul s i on 25-3800 (50%)

Emulsogen EL

Emulsogen LP

E r v o l

E s c a l o l 507

E s c a l o l 557

E s c a l o l 567

E s t o l EHP/EHP 1543/ 1462

E t h o c e l

Ethoquad 0 / 1 2

Eumulg in VL 75

Eusolex 232/232TS/

Eu tano l G

6300

Euxy l K-400

Ewal an ODE-50

PEG-36 c a s t o r o i l

01 e t h - 5

W h i t e m i n e r a l o i l

O c t y l d i m e t h y l PABA

Sunscreen

Benzophenone-3

Cosmet ic e s t e r

E t h y l c e l l u l o s e

PEG-2 01 eammoni um/i s o p r o p y l a l c o h o l

Cosmet i c emu1 s i f i e r o/w

Sunscreen

O c t y l dodecanol

Cosmet ic p r e s e r v a t i v e

O c t y l d o d e c y l l a n o l a t e

SOURCE

A1 b r i g h t

Henkel

Go1 dschmi d t

Keunen

Nat i o n a l

Hoechst

Hoechst

W i t c o

ISP Van Dyk

I S P Van Dyk

I S P Van Dyk

Uni chema

Dow

Armak

Henkel

EM

Henkel

Cal gon

Wagner

Dragoco Ex t rapon Chamomi l e Speci a1


RAW MATERIALS CHEMICAL DESCRIPTION

E x t r a p o n W i t c h Hazel

Ex t rapone 3 Speci a1 Chemical complex

E x t r a k t 52

FG-10

F i nso

F i nso

F i r m i

A n t i foam S i me th i cone Emu1 s i on

v SI3

v TN C12-15 a1 k y l benzoa te

g Liposome

F i t o b r o s i de W a t e r / g l y c o l i p i ds/phospho- l i p i d s / c a r b o h y d r a t e s

F i t ode rm Squal ane

F1 amenco S u p e r p e a r l 1 2 0 C cosmet i c s p i gment

F l e x a n 130 Sodium p o l y s t y r e n e s u l f o n a t e

F l u i l a n L i q u i d l a n o l i n

Foraha O i l

F rag rance

F rag rance

F rag rance

F rag rance

F rag rance

F rag rance

F rag rance Bel 1 e f r e s h

F rag rance 5-5390

F r a g r a n c e

F rag rance

B l a c k Dragon I 1 0/23511

Chi a r a 0/238927

So l a r a 0/227632

PCV 1677

R i v a l i a 0/221212

T imbuk tu 0/186901

L imoba in A . 116 .830

Men a t S p o r t 61569

SOURCE

Dragoco

Dragoco

Zsch i mmer

Dow C o r n i n g

F i n e t e x

F i n e t e x

Col l a b o r a t

Pentapharm

Centerchem

Mear l

N a t i o n a l

Croda

Keunen

Dragoco

Dragoco

Dragoco

G i vaudan

Dragoco

Dragoco

Haarman

Bel 1

Haarman

Haarman


RAW MATERIALS

Fragrance Q4696

F rag rance #S-5704

F rag rance Tendresse 754188

F rag rance #99189 "Twi s t e r "


Quest

F i n e F l a v

Haarman &

Croon

G-4909

Ga fqua t HS-100 C a t i o n i c copolymer

Gamma Orzano l

Gan t rez ES225, V i n y l e t h e r po l ymer E5425

G e l i t a So l C Hydro1 yzed c o l 1 agen

G e l w h i t e GP Wh i te m o n t m o r r i l o n i t e

Gemstone Moonstone GO04 Cosmet ic p e a r l powder

Genagen CAB

Genamin CTAC

Genamin DSAC

Genamin KSL

Genapol AMG

Genapol L-3

Genapol LRO L i q u i d , Pas te

Genapol TSM

Genapol ZRO L i q u i d

Genero l 122, 122E-10

Germaben I 1

I S P

Keunen

ISP

D t . G e l a t i n

ECC

Mear l

Cocami d o p r o p y l b e t a i ne Hoechst

Cet r i moni um c h l o r i de Hoechst

D i s t e a r y l d i m o n i u m c h l o r i d e Hoechst

PEG-5 s t e a r y l ammonium l a c t a t e Hoechst

Magnesium PEG-3 cocamide s u l f a t e Hoechst

L a u r e t h - 3 Hoechst

Sodi um 1 a u r e t h s u l f a t e Hoechst

PEG-3 d i s t e a r a t e , sod i um Hoechst 1 au re

Sodi urn

Cosmet

h s u l f a t e

l a u r e t h s u l f a t e Hoechst

c p r e s e r v a t i ve S u t t o n


RAW MATERIALS CHEMICAL D E S C R I P T I O N SOURCE

Germaben 1 1 - E Cosmet ic p r e s e r v a t i v e ISP S u t t o n

Germa l l I 1 D i azo1 i d i n y l u r e a ISP S u t t o n

Germa l l 115 I m i d a z o l i d i n y l u r e a ISP S u t t o n

Geropon AS-200 Rhone- Pou 1

Geropon SBFA-30 Rhone-Poul

Geropon TC-42 Rhone-Poul

Gorgon ian E x t r a c t B u t y l e n e g l y c o l / s e a wh ip e x t r a c t L i p 0

Glucam E-10 M e t h y l g l uce th -10 Amerc ho 1

Glucam E-20 M e t h y l g l u c e t h - 2 0 Amercho 1

G1 ucam E-20 D i s t e a r a t e M e t h y l g l u c o s e sesqu i s t e a r a t e Amerchol

G1 ucamate DOE-1 20 PEG-120 m e t h y l g l u c o s e d i o l e a t e Amerchol

Glucamate SSE-20 PEG-20 m e t h y l g l u c o s e sesqu i - s t e a r a t e

G l u c a t e DO M e t h y l g l u c o s e d i o l e a t e

G l u c a t e SS M e t h y l g l u c o s e sesqu i s t e a r a t e

G1 ycami 1

G l y c e r o l Monos tea ra te

G l y c e r o x HE PEG-7 g l y c e r y l c o c o a t e

G1 ydan t DMDM h y d a n t o i n

G 1 y d a n t P1 u s DMDM h y d a n t o i n

G1 y d a n t 40/700 DMDM h y d a n t o i n

Ame r c ho 1

Ame r c ho 1

Ame r c h o 1

A1 1 i ed-Si g

Keunen

Croda

Lonza

Lonza

Lonza

Trade -Named Raw Materials 365

RAW MATER I ALS CHEMICAL DESCRIPTION SOURCE

H a i r Mons te r U800 025 F rag rance dram Frag -

Hampene Na2T

Hampene Na3T

Hamamel i s Water

Hamp-ene 100

Hampol OL

HDK N20

H . E . Chamomi 1 e

H . E . Ginseng

H e t e s t e r PHA

Chel a t i ng agen t Hampshi re

Chel a t i n g agen t Hampshire

W i t c h h a z e l Dragoco

T e t r a s o d i u m EDTA c h e l a t i n g agen t Hampshi re

Chel a t i ng agent

H i g h l y d i s p e r s e d si 1 i c i c a c i d

Anthemi s n o b i 1 i s (Chamomi 1 e e x t r a c t )

Ginseng e x t r a c t

P r o p y l e n e g l y c o l i s o c e t e t h - 3 a c e t a t e

Hexanedi ol Behennyl Beeswax

Hexet i d i ne

H ispage l 200

Hoechst Po tass

Hoechst S o r b i c

Hombi tec L5

H o s t a c e r i n CG

H o s t a c e r i n D G I

H o s t a c e r i n DGL

H o s t a c e r i n DGMS

Hos tace r i n DGS

H o s t a c e r i n T-3

H o s t a c e r i n WO

um

Ac

S o r b a t e

d

T i t a n i um d i o x i d e

Hampshi r e

Wacker-

PJ Cosmet-

PJ Cosmet-

B e r n e l

Keunen

Angus

Hoechst

Hoechst

Sachet 1 eben

Hoech st

P o l y g l y c e r y l - 2 s e s q u i i s o s t e a r a t e Hoechst

P o l y g l y c e r y l - 2 PEG-10 l a u r a t e Hoechst

P o l y g l y c e r y l - 2 s t e a r a t e Hoechst

Po lyg l yce ry l -2 -PEG-4 S t e a r a t e Hoechst

C e t e a r e t h - 3 Hoechst

Hoechst



H o s t a c e r i n WOL Chemical complex

Hos tapha t KL340N T r i l a u r e t h - 4 phospha te

Hos tapha t KML Laure th -4 phosphate, p o l y g l y - c e r y l - 2 , sesqui s o s t e a r a t e

Hostapon CT-Paste Sodi urn m e t h y l c o c o y l t a u r a t e

Hostapon KCG Sodi urn c o c o y l g l u t a m a t e

Hostapon SCI, S C I D Sod

Huberso rb 600

Hyasol -BT Sod

um c o c o y l i s e t h i o n a t e

um h y a l u r o n a t e

H y d r o f o l A c i d 1655CG F a t t y a c i d and g l y c e r i d e s

Hydro1 yzed Wheat P r o t e i n

Hydrosoy 2000/SF

H y d r o v i t o n Chemicals complex

H y d r o t r i t i c u m QL

H y d r o t r i t i cum WAA Wheat ami no a c i d s

H y d r o t r i t i c u m 2000 Wheat p r o t e i n h y d r o l y z a t e s

Hydroxy P o l y e s t e r

Hypan QT-100 P o l y q u a t e r n i urn-31

Hypan SA 100H

Hypan SR 150H

Hypure N

SOURCE

Hoechst

Hoechst

Hoechst

Hoechst

Hoechst

Hoechst

Huber

Pentapharm

Sherex

VegeTech

Croda

Dragoco

Croda

Croda

Croda

Keunen

L i po

Sodium h y p o c h l o r i t e , 10% s o l n O l i n


RAW MATERIALS

I g e p a l CO-630

Immucel l

I m w i t o r 370

I m w i t o r 375

I m w i t o r 377

I m w i t o r 780K

I m w i t o r 900

I m w i t o r 928

I n c r o c a s - 4 0

I n c r o m e c t a n t LAMEA

I n c r o m i d e LR

I n c r o m i n e Ox ide C

Incronam 30

I n c r o q u a t Behenyl HE


Nonoxynol I SP

G1 y c o p r o t e i ns Pentapharm

I n c r o q u a t Behenyl

I n c r o q u a t CTC-30

I n c r o q u a t HO-80PG

I n c r o q u a t SDQ-25

I s o - A d i p a t e

I s o l a n DO

I s o l a n G I -34

I s o l a n GO-33

G l y c e r y l s t e a r a t e c i t r a t e

G l y c e r y l c i t r a t e / l a c t a t e / 1 i no1 e a t e / o l e a t e

G l y c e r y l l a u r a t e / c i t r a t e / l a c t a t e

I s o s t e a r y l d i g l y c e r y l s u c c i n a t e

G1 y c e r y l s t e a r a t e

G1 y c e r y l c o c o a t e

PEG-40 c a s t o r o i l

Acetamide MEA/Lactami de MEA

Laurami de DEA

Cocami d o p r o p y l ami ne o x i de

Cocamidopropyl b e t a i n e

Behenamidopropyl h y d r o x y e t h y l d imoni urn c h l o r i d e

TMS Behentr imonium m e t h o s u l f a t e / c e t e a r y l a1 coho1

Cet r i mon i um c h l o r i de

D i o e l e o y l ami d o e t h y l h y d r o x y - e t h y l m o n i um methosul f a t e

Q u a t e r n a r y c o s m e t i c c o n d i t i o n e r

D i i s o p r o p y l a d i p a t e

Me thy l g l ucose d i o l e a t e

P o l y g l y c e r y l - 4 i s o s t e a r a t e

P o l y g l y c e r y l - 3 o l e a t e

Hul s

Hu l s

Hul s

Hul s

Hul s

Hul s

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Croda

Dragoco

Go1 dschm

Go1 dschm

Go1 dschm

d l

d i

dl



I s o p r o p y l I s o s t e a r a t e

I s o s t e a r i c A c i d

I v a r l a n AWS

I r g a s a n DP300

Jaguar C14S

Jaguar C-162

Jaguar HP-60

Jordapon ACI-30

Jordapon CI-UP

Jordapon C I -60 / CI-75

K80-D22

K a o l i n 2457

K a r i o n F L i q u i d

Kathon CG/ CG100

K e l t r o l CG-T/F

K e r a s o l

Ke ra -Te in 1000 AS

PPG-12 PEG-65 l a n o l i n o i l

T r i c l o s a n b a c t e r i o s t a t

Guar h y d r o x y p r o p y l t r i m o n i u m c h l o r i de

Guar gum

H y d r o x y p r o p y l gua r

Ammoni urn c o c o y l i s e t h i o n a t e

Sodi um c o c o y l i s e t h i o n a t e

Sodi um c o c o y l i s e t h i o n a t e / s t e a r i c a c i d

M e t h y l c h l o r o i s o t h i a z o l i none/ me thy l i s o t h i a z o l i none

Xanthan gum

E t h y l e s t e r o f h y d r o l y z e d k e r a t i n

Kessco C e t y l A l c o h o l

Kessco EGMS

Kessco E t h y l ene G1 y c o l D i s t e a r a t e

Kessco GMS-Pure

SOURCE

Uni chema

Uni chema

Brooks

C i ba-Gei gy

Rhone-Poul

Rhone-Poul

Rhone-Poul

P PG

P PG

PPG

Keunen

E . Merck

Rohm & Haas

K e l c o

Croda

Maybroo k

Stepan

Stepan

Stepan

Stepan



Kessco GMS S.E. /A.S. Stepan

Kessco ICs Stepan

Kessco IPM Stepan

Kessco IPP Stepan

Kessco O c t y l I sononanoa te Stepan

Kessco PEG 400 D i l a u r a t e Stepan

Kessco PEG 400 DL

Kessco PEG 6000 DS

Kessco-653

K e s t e r Wax 82

K i 11 i t o 1

K1 e a r o l

K l u c e l G

K u i k u i Nut O i l

L a c t i 1

Lactomi de

Lameforrn T G I

Lanapene

Lanes ta S

Laneto-50

L a n e t t e - 0

L a n e t t e 16

L a n o c e r i n

Stepan

Stepan

F a t t y e s t e r Stepan

Keunen

B u t y l e n e g l y c o l / g l y c e r i n / c h l o r - Col l a b o r a ophenesin/ rnethy lparaben

Wh i te m i n e r a l o i l

H y d r o x y p r o p y l c e l l u l o s e

Cherni c a l s complex

Water /phosphol i p i ds/cerarni des

I s o p r o p y l m y r i s t a t e

PEG-75 1 a n o l i n

C e t e a r y l a l c o h o l

C e t y l a l c o h o l

L a n o l i n wax

W i t c o

Aqua1 on

O i l s A l o h a

Go1 dschrni d t

Lanaet ex

Lanaetex

RITA

Henkel

Hen ke 1

Arnerchol



Lanol 37T

L a n o l i n USP

L a n o l i n USP X-TRA Deo

Lasemul 92AE

L a t h a n o l LAL

Lexami ne S-13

Lexemu 1

Lexemul 515

Lexgard M

Lexgard P

L i p e x 102

pex 106

pex 203

pex 205

L i p o c o l C

L i p o c o l C-10

L i p o c o l 0 /95

L i p o c o l S - 2

L i poco1 S - 1 O/S-20

L i po F r u i t Ac i d Complex

L i pogard

L i p 0 GMS 450

L i p o l a n 31

L i p o l PG 855

Foami ng agent

C a t i o n i c e m u l s i f i e r

Cosmet i c emu1 s i f i e r

Cosmet ic e m u l s i f i e r

M e t h y l paraben

P r o p y l paraben

Shea b u t t e r

I 1 1 i pe b u t t e r

Mango k e r n a l o i l

Canola o i l

C e t y l a l c o h o l

SOURCE

Seppi c

R I T A

RITA

Stepan

I no1 ex

I n o l ex

I n o l e x

I n o l e x

I n o l e x

L i po

L i po

L i PO

L i PO

P o l o x y e t h y l e n e f a t t y e t h e r L i PO

G l y c o l i c a c i d (and ) t a m a r i n d L i p 0 e x t r a c t

Squal ane (and ) Ubi q u i none Pentapharm

G l y c e r y l s t e a r a t e L i PO

L a n o l i n d e r i v a t i v e L i po

L i PO


RAW MATER I ALS

L i pomul se 165

L i pona te DPC-6/GC

L i p o n a t e IPM

L i p o n a t e IPP

L i p o n a t e NPGC-2

L i p o n a t e SPS

L i pona te TDTM

L i p o n i c EG-1

L i p o p e a r l Green

L ipopeg 6000 DS

L i poquat R

L i p o s o r b L-20

L i p 0 S t e a r i c A c i d

L i p o v o l MOS-70

L i p o v o l PAL

L i p o v o l SAF

L i p o v o l SES

Lipowax D

Lipowax G

Lipowax N I

L ipowax P

L i q u a p a r O i 1

L o v o c r y l - 4 7


G 1 y c e r y l s tearate/PEG-100 s t ea r a t e

F a t t y e s t e r

F a t t y e s t e r

F a t t y e s t e r

Neopen ty l g l y c o l d i c a p r y l a t e / d i c a p r a t e

F a t t y e s t e r

F a t t y e s t e r

G1 y c e r e t h-26

PEG-150 d i s t e a r a t e

F a t t y a c i d amide e t h o s u l f a t e

S o r b i t a n e s t e r

N a t u r a l v e g e t a b l e o i 1

N a t u r a l v e g e t a b l e o i 1

Sa f f 1 ower o i 1

Sesame o i l

C e t e a r y l a1 coho1 / c e t e a r e t h - 2 0

S t e a r y l a l c o h o l / c e t e a r e t h - 2 0

S e l f - e m u l s i f y i n g wax

E m u l s i f y i n g wax, NF

P r e s e r v a t i ve

Octylacrylamide/acrylates b u t y l a m i n o e t h y l m e t h a c r y l a t e copolymer

SOURCE

L i po

L i PO

L i PO

L i po

L i po

L i po

L i p o

L i PO

L i PO

L i po

L i po

L i PO

L i po

L i po

L i PO

L i PO

L i PO

L i PO

L i PO

L i PO

L i PO

S u t t o n

N a t i o n a l


RAW MATER I ALS

Lunacera M

Luvimer Low VOC

Luv imer 360

Luv imer 1OOP

L u v i q u a t Mono CP

L u v i s k o l K30/K90/ VA73E/VA73W/VA641

L u v i t o l EHO


Hydrogenated m i c r o c r y s t a l l i n e wax H B F u l l e r

BAS F

BAS F

BASF

P o l y q u a t e r n i um BAS F

PV P BASF

C e t e a r y l o c t a n o a t e BASF

Macademi a Nut O i 1 O i 1 s A l o h a

Macol CPS j l24 P o l y o x y e t h y l e n e f a t t y e t h e r P PG

Mafo CAB Cocami d o p r o p y l b e t a i ne PPG

Mafo CSB-50 Cocamidopropyl h y d r o x y s u l t a i ne PPG

Magnabri t e S t a b i 1 i z i ng, suspend ing agen t AmCol l o i d

Magnesi um S t e a r a t e - D W i t c o

Mapeg EGMS

Mapeg 6000 DS

Maprosy l 30

M a r l i n a t CM 100/80

M a r l i n a t 242/28

Mar 1 i p a l 161 8/25

Masi 1 SF-V F l u i d

M a s i l 280

M a s i l 656 F l u i d

Maypon 4C

G1 y c o l s t e a r a t e


Lau re th -11 c a r b o x y l i c a c i d

Sodium + l a u r e t h s u l f a t e

C e t e a r e t h - 2 5

Cyc l omet h i cone

D ime th i cone c o p o l y o l

S i 1 i cone

Po tass ium c o c o y l - h y d r o l y z e d c o l 1 agen

PPG

P PG

Stepan

Hul s

Hul s

Hul s

PPG

P PG

PPG

I no1 ex



Mazami de CMEA Cocami de CMEA

Mazami de JT-128 Cocamide DEA

Mazami de SS-10 Soyamide DEA

Mazox CAPA Cocami d o p r o p y l ami ne o x i de

MEA B o r a t e and MIPA B o r a t e

M e a r l i t e GBU S y n t h e t i c p e a r l p igmen t

Mear lm ica CF/SVA Cosmet ic m ica powder

M e a r l t a l c TCA T a l c

M e d i a l a n LD Sodi um 1 a u r o y l s a r c o s i n a t e

Merquat 550 Po l y q u a t e r n i urn-7

Methocel E/E4M/ H y d r o x y p r o p y l m e t h y l c e l l ul ose K1 OOLV/40-100

M i c a M-RP

M i c r o c e l E

M i c r o c r y s t a l l i n e W445 Wax

M i c r o T i t a n i um D i o x i d e MT-500B Ti t a n i urn d i o x i d e

M i c r o w h i t e 100

M i g l y o l Gel B C a p r y l i c / c a p r i c t r i g l y c e r i d e / s t e a r a l k o n i urn h e c t o r i t e / p r o p - y l ene c a r b o n a t e

M i g l yo1 81 0/812 C a p r y l i c / c a p r i c t r i g l y c e r i d e

M i g l y o l 818 Caprylic/capric/linoleic t r i g l y c e r i de

M i g l y o l 829 C a p r y l i c / c a p r i c / d i g l y c e r y l s u c c i n a t e

M i g l y o l 840 P r o p y l e n e g l y c o l d i c a p r y l a t e

M i 1 f o i 1 E x t r a c t

SOURCE

P PG

P PG

PPG

PPG

Mona

Mear 1

Mear 1

Mear 1

Hoechst

Cal gon

Dow

Rona

Rona

W i t c o

T r i - K

ECC

H u l s

Hul s

H u l s

Hul s

Hul s

Ke l i sema


RAW M A T E R I A L S CHEMICAL D E S C R I P T I O N SOURCE

M i n e r a l Col 1 o i d BP Montmori 11 o n i t e ECC America

M i n e r a l O i l and L a n o l i n A l c o h o l Amer cho 1

M i n o s i 1

M i r a c a r e BC-IO

M i r a c a r e CT-100

M i r a c a r e MPC

M i r a c a r e MS-1

M i r a n o l BT

M i r a n o l C2M-SF70%

M i r a n o l C2M-SF Conc.

M i r a n o l U1 t r a

Modul an

Monafax 160

Monafax 1214

Monamate CPA-40

Monamate LNT-40

Monamid CMA

Monami d 150-ADD

Monamid 716

Monamid 1089

Monamul s 60-35C

Monaquat TG

Monaterge 11 64

S u r f a c t a n t

Cocoamphocarboxyglycinate

D i sod i um cocoamphodi p r o p i o n a t e

S u r f a c t a n t

A c e t y l a t e d 1 ano l i n

Phosphate e s t e r

Deceth-4-phosphate

M i I d a n i o n i c d e t e r g e n t

M i l d a n i o n i c d e t e r g e n t

Cocamide MEA

Cocamide DEA

Laurami de DEA

Super f a t t y a l k a n o l a m i d e

Q u a t e r n a r y p h o s p h o l i p i d cpd .

Sodi um 1 a u r y l s u l f a t e / d i s o d i urn 1 a u r y l s u l f o s u c c i n a t e

P r i d e S o l v

Rhone-Poul

Rhone-Poul

Rhone-Poul

Rhone-Poul

Rhone-Poul

Rhone-Poul

Rhone-Poul

Rhone-Poul

Amerchol

Mona

Mona

Mona

Mona

Mona

Mona

Mona

Mona

Mona

Mona

Mona



M o n a t e r i c CM-36s M i l d a m p h o t e r i c e m u l s i f i e r

M o n a t e r i c 805 D i s o d i um cocoamphodi a c e t a t e / d i s o d i u m cocami do MIPA-su1 f o - s u c c i n a t e

M o n a t e r i c 951A M i I d a m p h o t e r i c e m u l s i f i e r

Monawet MO-75E W e t t i ng agent

Monazol i ne CY I - h y d r o x y e t h y l - 2 - c a p r y l i m i d - azo1 i ne

Montan OV 68

MPC-Mi 1 k Pept i de Compl ex

M-Pyrol n-Methy l P y r r o l i done

Mu lgo fen ON-870

Myacide SP 2 , 4 - d i c l o r o b e n z y l a l c o h o l

M y r i t o l 318

M y r j 52 P o l y o x y e t h y l e n e s t e a r a t e

M y r j 525 PEG-40 s t e a r a t e

M y r j 59 PEG-100 s t e a r a t e

Na-Hyal u r o n a t e S e l u r o n Sol u t i on

N a t i p i d e I 1

N a t r o s o l P1 us 330 CS/ H y d r o x y e t h y l c e l l u l o s e 250HHR/250HHR CS/ 250HHX/250HR/250HR CS

N a t u r a l Beeswax

SOURCE

Mona

Mona

Mona

Mona

Mona

Seppi c

R i c h t e r

ISP

Rhone- Pou 1

I n o l e x

I C 1

IC1

I C 1

Secol

Natterrnan

Aqua1 on

Naturechem EGHS C a s t o r o i 1 d e r i v a t i v e

R i t a

CasChem


RAW MATERIALS

Naturechem GMHS

Naturechem OHS

Neobee M-5

Neobee M-20

Neodol 2 3 - 6 . 5

Neo-He1 i opan AV

Neo-He1 i opan BB

Neo-He1 i opan, Hydro

Neo-He1 i opan MA

Neo-He1 i opan OS

Neo-He1 i opan E1000

Neo-Hel iopan 303

N-Hance 3000

N i m l e s t e r o l D

N i n o l 30-LL

N i n o l 40-CO

N i n o l 55-LL

N i n o l 96-SL

N i p a c i d e PX

N i p a g i n M

N i paguard BPX

N i paguard DMDMH

N i p a s o l


C a s t o r o i l d e r i v a t i v e CasChem

Cosmet ic i n g r e d i e n t CasChem

C a p r y l i c / c a p r i c t r i g l y c e r i d e Stepan

Cosmet ic o i l Stepan

C12-Cl3 1 i near p r i m a r y a l c o h o l She1 1 e t h o x y l a t e

O c t y l me thoxyc i nnamate

Benzophenone-3

Phenyl b e n z i m i d a z o l e sul f o n i c a c i d

Men thy l a n t h t h r a n i l a t e

O c t y l s a l i cy1 a t e

I soamyl -p -me thoxyc innamate

O c t o c r y l i ne

C a t i o n i c gua r

M i n e r a l o i l

A1 k y l o l ami des

Cocamide DEA

A 1 k y l o l ami de

A1 k y l o l ami de

M e t h y l paraben

DMDM h y d a n t o i n

P r o p y l pa raben

Haarman

Haarman

Haarman

Haarman

Haarman

Haarman

Haarman

Aqualon

Ma 1 mst rom

Stepan

Stepan

Stepan

Stepan

N i pa

N i pa

N i pa

N i pa

N i pa


RAW MATER1 ALS CHEMICAL D E S C R I P T I O N

N i p a s t a t

Nuosept C

N u t r i l a n L H y d r o l y z e d c o l l a g e n

M i c r o b i o c i de

Oc top i r o x P i r o c t o n e a1 ami ne

Oh1 an H y d r o x y l a t e d 1 ano

Omnirez 2000

i n

O p a t i n t FD&C a1 umi num 1 ake c o n c e n t r a t e

Orange Wax

Orgaso l 2002D Nat Cos Nylon-12

Orgasol 2002UD Nat Cos Ny lon -12

O x e t a l VD 20

Oxynex LM A n t i o x i d a n t

Oxynex 2004 A n t i o x i d a n t

Oxypon 2145

O y s t e r Nut O i l

O z o k e r i t e Wax



O z o k e r i t e W h i t e 170

O z o k e r i t e 64W

O z o k e r i t e #77W

O z o k e r i t e 160/

O z o k e r i t e 164/

64

70

SOURCE

N i pa

N i p a

Henkel

Hoech s t

Ame r c ho

I S P

Col o r c o n

Keunen

Atochem

Atochem

Zschimmer

Zsch i mmer

Zsch i mmer

Zsch i mmer

Keunen

I n t Wax

Keunen

Ross

Keunen

Keunen

37% Cosmetic and Toiletry Formulations

RAW MATERIALS

Panal ane

Panal ane L-14E

P a r a f f i n O i l

P a r a f f i n 150/155

P a r a f f i n 160/165

P a r s o l MCX

P a r s o l 1789

P a t i o n i c I S L

P a t i o n i c ISL /85


Hydrogenated i s o b u t y l e n e Amoco

Hydrogenated i s o b u t y l e n e Amoco

M i n e r a l o i l Merck

Keunen

Keunen

O c t y l me thoxyc i nnamate G i vaudan

UV-A sunscreen G i vaudan

Sodi um i s o s t e a r o y l 1 a c t y l a t e RITA

Sodi um i s o s t e a r y l l a c t y l a t e 85% RITA

P a t i o n i c SSL Sodium s t e a r o y l l a c t y l a t e

P a t l a c I L I s o s t e a r y l l a c t a t e

P a t l a c LA L a c t i c a c i d

PCL L i q u i d

Peach F l o r a l 92F/3235 F rag rance

P e a r l e s c e n t P igments

Pecosi 1 CAP-1240

Pecosi 1 PS-100

Pecosi 1 SMQ-40

Pecosi 1 SPB-1240

PEG Carnauba

Pe lan B l a c k

Pemulen TR-1

Pemulen TR-2

P e n t a l y n C

D i me th i cone c o p o l yo1 phospha te

S i 1 i cone q u a t e r n i um-5

S i 1 i cone a u a t e r n i um-6

RITA

RITA

RITA

Dragoco

F rag rance

Rona

Phoen i x

Phoenix

Phoenix

Phoenix

Keunen

A c r y l a t e s / C l O - 3 0 a1 k y l a c r y l a t e Goodr i c h

Pol ymer i c emu 1 s i f i e r G o o d r i c h

S y n t h e t i c r e s i n H e r c u l e s


RAW MATERIALS

P e n t a v i t i n

P e p t e i n 2000

P e r f e c t a

Perfume

Perfume 726096

Permethy l 101A/102A/ 104A

Permu lg in D

Pg-3 Beeswax

Phoenamid CD

Phoenamid L D

Phoenate SLES-70

Phoenate 3SDA

Phoenoni p

Phoskadent Na211


S a c c h a r i d e i somerate

H y d r o l y z e d animal p r o t e i n

P e t r o l a t u m

Courage 0/243101

F rag rance

A l i p h a t i c hyd roca rbon

Custom b l e n d e d wax

Cera B e l l i n a

Cocamide DEA

Laurami de DEA

Sodi urn 1 a u r e t h s u l f a t e


L i q u i d p r e s e r v a t i ve system

D e n t a l g rade phospha te

SOURCE

Pentapharm

Hormel

W i t c o

Dragoco

Haarman

Permethy l

Keunen

Keunen

Phoen i x

Phoenix

Phoen i x

Phoenix

N i pa

BK-Laden-

Phosphol i p i d EFA/GFA/ B i omi m e t i c phosphol i p i d Mona PTC/SV

P h o s p h o t e r i c QL-38 T r i sod i urn 1 auroampho PG a c e t a t e Mona phosphate c h l o r i de

P h y t a l u r o n a t e Locus t bean gum Pentapharm

P i l o t SXS-4O/SXS-96 H y d r o t r o p e P i l o t

P1 u r a c a r e F127 BASF

P l u r a f a c C-17 O x y e t h y l a t e d a l c o h o l BAS F

PNC 400 Sodi um carbomer 3 V GmbH

Pol awax E m u l s i f y i n g wax NF Croda

Polawax A-31 E m u l s i f y i n g wax NF Ross


RAW MATER1 ALS

P o l e s t a r 400A

P o l y b u t e n e H-100

Po l y e t h y l ene 6A/9A

Polymer JR400

Po l y p e p t i de LSN

P o l y q u t a 400/3000

P o l y s y n l ane

PPG-36 C a s t o r O i l

P r i c e r i n e 9083

P r i f a c 2942

P r i s t e r i ne 4904

P r o c e t y l 10

P r o c o l CS-POD

Prodew 100

Promois ECP

Promoi s WS

Promulgen D


Cal c i ned c l ay

Po lyqua te rn ium-10

Hydro1 yzed c o l 1 agen

P o l y q u a t e r n i um-1 0

Hydrogenated p o l y i s o b u t e n e

G1 y c e r i ne

M y r i s t i c a c i d

S t e a r i c a c i d

A1 k o x y l a t e d c e t y l e t h e r

S o r b i t o 1 / s o d i u m 1 a c t a t e / p r o - l i n e / s o d i u m PCA/hydro lyzed c o l 1 agen

Col 1 agen

H y d r o l y z e d soy p r o t e i n

SOURCE

ECC Amer ica

Amerc ho 1

I n o l e x

RITA

Po l y e s t h e r

P PG

Uni chema

Uni chema

Uni chema

Croda

A j i nomoto

RITA

RITA

C e t e a r y l a l c o h o l / c e t e a r e t h - 2 0 Amerchol

P r o n a l e n F r u i t A c i d AHA-5 Lemon & Pass ion F r u i t Conc. Centerchem

P r o p e l l a n t A-46 Hydrocarbon p r o p e l l a n t Phi 1 1 i psPe t

P r o p y l e n e G l y c o l / d i a z o l i d i n y l u rea /me thy lpa raben / S u t t o n p r o p y l p a r a b e n

P r o t e c t a n Lac tococcus 1 a c t i s 1 y s a t e R i c h t e r

P u r c e l 1 i n O i 1 C e t e a r y l o c t a n o a t e / i s o p r o p y l Dragoco m y r i s t a t e



P u r c e l l i n O i l 2/066210 C e t e a r y l o c t a n o a t e Dragoco

P u r t o n SFD F a t t y a c i d a l k a n o l a m i d e Zsch i mmer

PVP K-30 PV P ISP

PVP/VA E-735 PVP/VA copolymer ISP

R a f f e r m i ne

Reduct i ne

Resyn 28-1 31 O / 28-2930/28-3307

Revi t a l i n-BT

R e w o t e r i c AM 514

R e w o t e r i c AM B14LS

Rheol a t e 5000

Rhodafac RA-600

Rhodapex ES

Rhodaquat D261 C/75

Rhodi g e l

Rhodopol 23/50MD

R i c e B ran O i 1

R i t a b a t e - 2 0

R i t a b a t e - 6 0

R i t a b a t e - 8 0

R i t a CA

R i t a c e t - 2 0

Hydro1 yzed soy f 1 o u r

Oat p r o t e i n

H a i r s p r a y po lymer

GI y c o p r o t e i ns

Cocami d o p r o p y l b e t a i ne

Cocami d o p r o p y l b e t a i ne

A c r y l a te /Va copolymer

Deceth-4 phospha te

E t h e r s u l f a t e

Xanthan gum

Xanthan gum

Po l y s o r b a t e - 2 0

P o l y s o r b a t e - 6 0

Pol y s o r b a t e - 8 0

C e t e a r y l a l c o h o l

Ce tea re th -20

RITA

RITA

N a t i o n a l

Pentapharm

W i t c o

W i t c o

Rheox

Rhone-Poul

Rhone-Poul

Rhone- Pou 1

V a n d e r b i l t

V a n d e r b i l t

Keunen

R I T A

RITA

RITA

RITA

R I T A



R i t a C e t e a r y l A l c o h o l ( 5 0 / 5 0 ) RITA

R i t a C e t e a r y l A l c o h o l (70 /30 ) RITA

R i t a c e t i

R i t a c e t y l

R i t a c h o l

R i t a c h o l 1000

R i t a c h o l 2000

R i t a CTAC-605

R i t ade rm

R i t a EGDS

R i t a EGMS

R i t a GMS

R i t a HA C - I - C

R i t a h y d r o x

R i t a I P M

R i t a IPP

R i t a l an

R i t a l o e 1X

R i t a l o e 200M

R i t a m i d e C

R i t a p a n D

R i t a p a n DL

R i t a p e g 150 DS

R i t a PEO-1

C e t y l e s t e r s RITA

A c e t y l a t e d 1 ano l i n R I T A

M i n e r a l o i 1 /l a n o l i n a l c o h o l RITA

RITA B l e n d RITA

C e t e a r y l a1 coho1 / p o l y s o r b a t e - 6 0 RITA

Cet r i moni um c h l o r i de RITA

P e t r o l a tum/ l a n o l i n / s o d i um PCA/ RITA p o l y s o r b a t e 85

G1 y c o l d i s t e a r a t e RITA

G1 y c o l s t e a r a t e RITA

G1 y c e r y l s t e a r a t e RITA

Sodi um h y a l u r o n a t e R I T A

H y d r o x y l a t e d 1 a n o l i n R I T A

I s o p r o p y l m y r i s t a t e R I T A

I s o p r o p y l p a l m i t a t e RITA

L a n o l i n o i l RITA

A l o e v e r a g e l R I T A

A l o e v e r a g e l R I T A

Cocamide DEA RITA

d-Panthenol R I T A

d l -Pantheno1 RITA

PEG-150 d i s t e a r a t e RITA

PEG-SM R I T A

Trade -Named Raw Materials 383

RAW MATERIALS

R i t a PEO-3

R i t a p r o 100

R i t a p r o - 1 6 5

R i t a p r o 300

R i t a SA

R i t a s i l 190

R i t a s o l

R i t a SSO

R i t a Stac-80

R i t a s y n t I P

R i t a t a i ne

R i t avena-5

R i tawax

R i tawax ALA

R i tawax 15

R i t o x 52

R i t o x 59


PEG-23M

RITA b l e n d

G l y c e r y l s tearate/PEG-100 s t e a r a t e

C e t e a r y l a l c o h o l / c e t e a r e t h - 2 0

S t e a r y l a1 c o h o l

D i me th i cone c o p o l yo1

I s o p r o p y l l a n o l a t e

S u n f l o w e r seed oi 1

S t e a r t r i m o n i u m c h l o r i d e

G l y c o l s t e a r a t e and o t h e r s

Cocoami d o p r o p y l b e t a i ne

Hydro1 yzed o a t f 1 o u r

Lanol i n a1 coho l

C e t y l a c e t a t e / a c e t y l a t e d 1 ano l i n a1 c o h o l

Lanol i n a1 c o h o l

PEG-40 s t e a r a t e

PEG-100 s t e a r a t e

Rona P e a r l P i gment Combi n a t i o n s

Rosswax 15-1 182 Wax

Rosswax 26-1 152 Wax

Rosswax 1824 Wax

Rovisome Ace V i t a m i n b l e n d

Rovi some-AHA L a c t i c a c i d

SOURCE

RITA

R I T A

RITA

R I T A

RITA

RITA

R I T A

RITA

RITA

RITA

RITA

R I T A

R I T A

RITA

RITA

R I T A

R I T A

Rona

Ross

Ross

Ross

R I T A

RITA



Rovisome C R O V I b l e n d RITA

Rovisome HA L e c i t h i n / a l c o h o l / s o d i um hya- RITA 1 u r o n a t e

S a n s u r f OMC Chemical compl ex C o l l abo ra -

Schercemol CO C e t y l o c t a n o a t e e s t e r Scher

Schercemol CP E s t e r Scher

Schercemol D I D D i i s o p r o p y l d imer d i 1 i no1 e a t e Scher

Schercemol 185 E s t e r Scher

S e l a s t i n E L - 1 0 Secol

S e r i c i n

SF-1 204/SF1214 D i me th i cone

Shea B u t t e r

Shebu WS PEG-50 shea b u t t e r

S h e l l s o l D40 P e t r o l e u m d i s t i l l a t e s

S h e l l s o l T P e t r o l e u m d i s t i l l a t e s

S h i n j u 1 0 0 T S y n t h e t i c p e a r l p i gment

S i comet D y e s t u f f

S icomet B l u e 542045 D y e s t u f f suspens ion 1%

S i comet Red F12150

S i 1 i cone 7207

S i 1 i cony1 Beeswax

S i l k M i c a

S i 1 k ' n So l u b l e L i q u i d

S i l t e x M Super

Pentapharm

DowCorni ng

Keunen

RITA

Shel 1

Shel 1

Mear l

BASF

BAS F

BASF

OS1 S p e c i a l

Keunen

Rona

Dasco

Rona


RAW MATERIALS

Simchi n N a t u r a l

S ipon ES2

S ipon LT-6

S ipon 201-10

S o f t i g e n 701

S o f t i g e n 767

S o f t i s a n 100

S o f t i s a n 378

S o f t i s a n Gel

S o f t i s a n 601

S o f t i s a n 645/649

Solagum L

S o l t r o l 100

S o l u l a n 16

S o l u l a n 98

Solu-Soy EN25

SS4267

S t a r f o l OS

S t a b i 1 eze XL-80W

S t a b i l e z e 06

Standarnid KD


J o j o b a o i l RITA

Sodi urn l a u r e t h s u l f a t e ( 2 mole) Rhone-Poul

TEA l a u r y l s u l f a t e

G1 y c e r y l r i c i no1 e a t e

PEG-6 c a p r y l i c / c a p r i c g l y c e r i d e s

Hydrogenated c o c o - g l y c e r i d e s

C a p r y l i c / c a p r i c / s t e a r i c t r i g l y c e r i de

Complex o f chemica l s

G l y c e r y l cocoa te /hyd rogena ted coconu t o i l / c e t e a r e t h - 2 5

B i s - d i g l y c e r y l p o l y a c y l a d i p a t e - 2

C9-11 i s o p a r a f f i n

Laneth-lG/ceteth-16/0leth-l6/ s t e a r e t h - 1 6

P o l y s o r b a t e 8 0 / c e t y l a c e t a t e / a c e t y l a t e d l a n o l i n a l c o h o l

D i r n e t h i c o n e / t r i r n e t h y l - s i l o x y - s i 1 i c a t e

D i f a t t y e s t e r

Cocamide DEA

Rhone-Poul

Rhone- Pou 1

Hul s

Hul s

Hul s

Hul s

Hul s

Hul s

Hul s

Seppi c

Phi 11 i p s

Amerc ho 1

Arne r c h o 1

Brooks

GESi 1 i cone

Sherex

I S P

ISP

Henkel


RAW MATERIALS CHEMICAL D E S C R I P T I O N

Standamid LD

S tandapo l A Ammonium l a u r y l s u l f a t e

S tandapo l ES1 (30%) Sodi um 1 a u r e t h s u l f a t e

S tandapo l ES-2 Sodium l a u r e t h s u l f a t e

S tandapo l T TEA l a u r y l s u l f a t e

S t andapol WAQ- LC Sodi urn 1 a u r y l s u l f a t e

S tandapo l WAQ Spec. Sodium l a u r y l s u l f a t e

S t e o l CA-130/CS-130/ A l c o h o l e t h e r s u l f a t e CS-230/CS-33O/CS-460

Stepan-Mi 1 d BSB

Stepan-Mi I d L S B

Stepan-Mi 1 d SL3

S tepano l AM

S tepano l AM-V/ ME-Dry/WA-Extra

S tepano l WAT

Stepan TAB-2

S u n e t t

Sunf 1 ower O i 1

Sunscreen L i posomes

Super F l o s s

Super H a r t o l an

Ammoni urn 1 a u r y l s u l f a t e

A1 k y l s u l f a t e


Acesul fame K

Complex o f chemi c a l s

D i atomaceous e a r t h

Lanol i n a1 coho1

Super R e f i ned Wheat Germ O i 1

Supersa t AWS-4 PEG-20 hyd rogena ted l a n o l i n

Supra T a l c Premi um t a l c

SOURCE

Henkel

Henkel

Henkel

Henkel

Henkel

Henkel

Hen ke 1

Stepan

Stepan

Stepan

Stepan

Stepan

Stepan

Stepan

Stepan

Hoech s t

L i PO

Col 1 a b o r a t -

Manvi 11 e

Croda

Croda

RITA

R I T A


RAW MATER1 ALS CHEMICAL DESCRIPTION SOURCE

Syncrowax A w l - C S y n t h e t i c wax Croda

Syncrowax ERL-C S y n t h e t i c wax Croda

Syncrowax HGL-C C18-36 a c i d t r i g l y c e r i d e Croda

Syncrowax HR-C S y n t h e t i c wax

S y n t h e t i c Candel i 11 a

Tagat L PEG-20 g l y c e r y l 1 a u r a t e

Tagat 0 PEG-30 g l y c e r y l o l e a t e

T a l c 141

T a l c 1625

TEA Sal i cy1 a t e TEA s a l i cy1 a t e i n p r o p y l ene g l y c o l

T e c h n o c e l l 9 0 D V

Tech-0 11-070 S t e r - 0 - P r o

Tech-0 11-075 C o n c e n t r a t e d Oat P r o t e i n

Tegi n G l y c e r y l s t e a r a t e S . E .

Teg in M G l y c e r y l s t e a r a t e

T e g i n a c i d C

Croda

Keunen

Go ldschmid t

Go1 dschmi d t

Whi t t a k e r

Haarman

Beacon CMP

Beacon CMP

Go ldschmid t

Go1 dschmi d t

Go1 dschmi d t

T e g i n a c i d H G1 y c e r y l s t e a r a t e / c e t e t h - 2 0 Go1 dschmi d t

T e g i n EGS G1 y c o l d i s t e a r a t e Go1 dschmi d t

T e g i n M G l y c e r y l s t e a r a t e Go ldschmid t

Tego A l k a n o l 16 C e t y l a l c o h o l Go 1 dsc hmi d t

Tego Amid S18 Stearami d o p r o p y l d i me thy l ami ne Go1 dschmid t

Tego B e t a i n e E/F/FSO/ Cocamidopropyl b e t a i n e Go1 dschmi d t L7


RAW MATERIALS

Tego Care 450

Tego Deo HY77

Tego G l u c o s i d L55

Tego G l u c o s i d 1216

Tego P e a r l N l O O

Tegoso f t C I

T e g o s o f t CT

Tegosof t DO

T e g o s o f t GC

T e g o s o f t L i q u i d

T e g o s o f t M

T e g o s o f t OP

T e g o s o f t OS

Tegosof t P

T e g o s o f t S

Tenox BHT

Tenox 4

Tensami 306

Tens i ne

Texapon L20M

Texapon SBN

Texapon T42


Po l y g l y c e r y l - 3 m e t h y l g l ucose d i s t e a r a t e

Z i nc r i n c i no1 e a t e / t r i e t h a n o l - ami n e / d i p r o p y l ene g l y c o l / l a c t i c a c i d

L a u r y l g l u c o s i de/cocamido- p r o p y l b e t a i n e

L a u r y l g l u c o s i d e

G l y c o l d i s t e a r a t e / s t e a r e t h - 4

C e t e a r y l i sononanoa te

Capry l i c / c a p r i c t r i g l y c e r i d e s

Decyl o l e a t e

PEG-7 g l y c e r y l c o c o a t e

C e t e a r y l o c t a n o a t e

I s o p r o p y l m y r i s t a t e

O c t y l p a l m i t a t e


I s o p r o p y l p a l m i t a t e

I s o p r o p y l s t e a r a t e

A n t i o x i d a n t

A n t i o x i d a n t

Casei n / xan than gum

Wheat p r o t e i n


SOURCE

Go ldschmid t

Go1 dschrni d t

Go1 dschmi d t

Go1 dschmi d t

Go1 dschmi d t

Go1 dschmi d t

Go1 dschmid t

Go1 dschmi d t

Go1 dschrni d t

Go1 dschmi d t

Go1 dschmi d t

Go1 dschmi d t

Go1 dschmi d t

Go1 dschmi d t

Go1 dschrni d t

Eastman

Eastrnan

A1 banMul1 e r

RITA

Henkel

Henkel

Henkel



T h i o g l y c o l a t e T r i h y d r a t e

T h i o g l y c o l i c A c i d

T i m i c a S p a r k l e 11OP Cosmet ic p e a r l powder

T i m i r o n MP-24 G o l d K a r e t I n t e r f e r e n c e Pigment

T i m i r o n MP1001 /MP1500 T i t a n i um d i o x i d e / m i ca

T i m i r o n S . I + P i gments T i t a n i um d i o x i de/mi ca

T i m i r o n S i 1 k Red/ M i c a / t i t a n i u m d i o x i d e S t a r 1 i g h t C o l o r s

T i m i r o n Super Pigments P e a r l escen t p igmen ts

T i o v e i l F IN T i t a n i u m d iox ide /C12-15 A l k y l Benzoate

T i t a n i u m D i o i x d e 110 T i t a n i u m d i o x i d e / b i s m u t h oxy - c h l o r i d e

T i t a n i u m D i o x i d e #3328

T r i s Amino T r i s ( h y d r o x y m e t h y l ) amino- methane

T r i s e p t M Me thy lpa raben

T r i s e p t P P r o p y l paraben

T r i s t a t I U I m i d a z o l i d i n y l u r e a

T r i t i s o l S o l u b l e wheat p r o t e i n

T r i t o n X-100 O c t o x y n o l - 9

T r i v e n t OC-G T r i d e c y l neopen tanoa te

Tween 20 P o l y s o r b a t e 20



SOURCE

Merck

W i t c o

Rona

Rona

Rona

Rona

Rona

Rona

T i o x i de

P resperse

Angus

T r i - K

T r i - K

T r i - K

Croda

Rohm&Haas

T r i v e n t

I C 1

I C 1

IC1


RAW M A T E R I A L S

Tween 80

T y l o s e CB 200

T y l o s e H1000

Ucare Polymer JR-125

U l t r a o l 70 NF

U l t r a p u r e L

U l t r e z 10

U n i c i d e U-13

Uni n o n t a n U-34

Uniphen P-23

U n i r e p U-18

Uvatone 2-6

U v i n u l M-40

U v i n u l MC80

UV-Ti t a n M212

Van Gel B/C/ES/O

Vani 11 a BB-36943

Vanseal CS

Vanseal NACS-30

Vanseal NALS-30

CHEMICAL D E S C R I P T I O N

P o l y s o r b a t e 80

C e l l u l ose gum

H y d r o x y e t h y l c e l l u l o s e

P o l y q u a t e r n i um-1 0

SOURCE

IC1

Hoechst

Hoechst

UnionCarb

P e t r o l a t u m U l t r a

G o o d r i c h

I m i dazo l i d i n y l u r e a L i po

W a t e r / p r o p y l ene g l y c o l / s o d i um L i po c i t r a t e / l e m o n e x t r a c t / c u c u m b e r e x t r a c t

Phenoxyethanol /me thy l paraben/ L i po e t h y l p a r a b e n / p r o p y l paraben/ b u t y l p a r a b e n

Benzophenone-3 BASF

BASF

T i t a n i um d i o x i d e / a l umi na/ Kemi r a g l y c e r i n / s i 1 i c a

Magnesium aluminum s i l i c a t e V a n d e r b i l t

Ungerer

Cocoyl s a r c o s i n e s u r f a c t a n t V a n d e r b i l t

Sodi um 1 a u r o y l s a r c o s i n a t e V a n d e r b i l t

S a r c o s i n a t e s u r f a c t a n t V a n d e r b i l t


RAW MATER I A L S

V a r i on CADG/CADG LS/

V a r i s o f t TA-100

Varon i c L I - 4 8 / L I -67/ 63-E-20

Vase1 i ne W h i t e

Veegum/ HV/ K/ P r o / R e g u l a r / T/ U l t r a

Vel v e t e x BA-35

V e l v e t e x BK-35

V e r s a t y l - 4 2

Versene Powder/100


S u r f a c t a n t Sherex

Hai r r i n s e c o n c e n t r a t e Sherex

N o n i o n i c w e t t i n g agen t Sherex

P e t r o l a t u m w h i t e W i t c o

Magnesi um a1 umi num s i 1 i c a t e Vanderb i 1 t

Cocami d o p r o p y l b e t a i ne Henkel

Henkel

H a i r s p r a y po lymer N a t i o n a l

T e t r a s o d i u m EDTA c h e l e t i n g agen t Dow

V i b r a n t S p l a s h 94F/2203 F rag rance F rag rance

V i g i l a n AWS

V i t a m n -E-Ace ta te

V i tam n F F o r t e C L R

Volpo C S 2 0

Volpo s-2

Volpo s-10

Volpo s-20

Vo lpo 5

Vybar-5013

Fann ing

Tocophery l a c e t a t e BASF

R i c h t e r

E t h o x y l a t e d o l e o y l e t h e r Croda

S t e a r e t h - 2 Croda

S t e a r e t h - I O Croda

S t e a r e t h-20 Croda

01 e t h - 5 Croda

Polymer P e t r o l i t e


RAW MAT E R I A LS CHEMICAL DESCRIPTION SOURCE

Walnu t S h e l l s (AD-7B Type) A g r a s h e l l

Waxenol 810

Wecobee S

Wecobee SS

Wheat Germ O i l

Wheat-Tei n NL

W h i t e Fonol i ne

W h i t e P r o t o p e t 1s

Wickenol 152

Wickenol 171

Wickenol 550

W i t cami de 51 1

W i t c o n a t e NIS

W i t c o n o l APM

Xanthan Gum

Y e l l o w P r o t o p e t 2A

Z e t e s o l N L

Z e t e s o l 856T

Z i n c Omadine

Z i n c Ox ide N e u t r a l

Z i n c S t e a r a t e #695

Zuso l a t 1004

Zusol a t 1 005/85

W i ckhen

S y n t h e t i c b u t t e r Stepan

S y n t h e t i c cocoa b u t t e r Stepan

R i t a

H y d r o l y z e d wheat p r o t e i n Maybrook

P e t r o l a t u m W i t c o


CasChem

Ca sCh em

CasChem

A1 kano lamide s u r f a c t a n t W i t c o

Sodi um i s e t h i o n a t e W i t c o

N o n i o n i c s u r f a c t a n t W i t c o

Ke l co


Sodium l a u r y l e t h e r s u l f a t e Zsch i mmer

F a t t y a l c o h o l e t h e r s u l f a t e Zschi mmer

Z i n c p y r i t h i o n e , 48% O l i n

Haarman

A1 k y l p o l y e t h y l ene g l y c o l e t h e r Zsch i mmer

A 1 k y l p o l y e t h y l ene g l y c o l e t h e r Zsch i mmer



18-B G l y c y r r h e t i n i c A c i d Phytosome

33-5198 B l a c k I r o n Ox ide

4311810 U l t r a m a r i n e B l u e

8 0 / 2 0 B r a d p r i d e Soap Base

7054 Red I r o n Ox ide

7055 Y e l l o w I r o n Ox ide

7133 B l a c k I r o n Ox ide

43001 Manganese V i ol e t

SOURCE

Rona

Rona

B r a d f o r d

Rona

Rona

Rona

Rona

Section XIV Suppliers' Addresses

394

Suppliers’ Addresses 395

Agrashe l 1 I n c , 5934 Keys tone D r . Ba th , PA 18014 (215)-837-6705

A j i n o m o t o USA, I n c . G l e n p o i n t C t r . W . 500 F rank W . B u r r 8 l v d . Teaneck, N J 07645 (201)-907-3244

Akzo Chemical s , I n c . 300 South R i v e r s i d e P l a z a Chicago, I L 60606 (312)-906-7500

A l b r i g h t & W i l s o n Amer icas P . O . Box 26229 Richmond, VA 23260 (804) -550-4300 / (800 ) -446-3700

A l l i e d S i g n a l , I n c . P.O. Box 2332R M o r r i stown, NJ 07962 (201 ) -455-2000

Amerchol Corp. P . O . Box 4051 136 Talmadge Rd. Ed ison , NJ 08818 (908)-248-6000

American C o l l o i d Co. Hwy 212W B e l l e Fourche, SD 57717 (605)-892-2591

Amoco Chemical Co. 200 E . Randolph D r . Chicago, I L 60601 (312) -856-3200 / (800 ) -621-4567

Angus Chemical Co. 1500 E. Lake Cook Rd. B u f f a l o Grove, I L 60089 (708)-215-8600/(800)-323-6209

Aqua1 on 1313 N. Marke t S t . W i 1 m i n g t o n , DE 19899 (302) -594-5000 / (800 ) -345-8104

Atochem N o r t h Amer ica 900 M i l k S t . C a r t a r e t , NJ 07008 (908)-541-4414

BASF Corp . 100 C h e r r y H i 1 R d . P a r s i p p a n y , NJ 07054 (201)-316-3000/(800)-526-1072

B e l l F l a v o r s & F rag rances , I n c 500 Academy D r . N o r t h b r o o k , I L 60062 (312) -291-8300 / (800 ) -323-4387

Berne l Chemical Co. , I n c . 174 Grand Ave. Englewood, N J 07631 (201)-569-8934

BK-Ladenburg Corp. 50 S p r i n g S t . C r e s s k i l l , NJ 07626 (201)-567-9100/(800)-526-2688

Brooks I n d u s t r i e s , I n c . 70 T y l e r P l a c e South P l a i n f i e l d , NJ 07080 (908)-561-5200

Calgon Corp. P . O . Box 1346 P i t t s b u r g h , PA 15230 (41 2 ) -777-8000

C a p i t a l C i t y P r o d u c t s Co. 525 W . F i r s t Ave. Columbus, OH 43216 (61 4)-299-3131/( 800)-848-1340


CasChem, I n c . 40 Avenue A Bayonne, N J 07002 (201) -858-7900/ (800) -CAS-CHEM

Centerchem, I n c . 225 High Ridge R d . S tamford , CT 06905 (203)-975-9800

C i ba-Gei gy Corp. 410 Swing Rd. Greensboro, NC 27419

Colorcon, I n c . Moyer B l v d . West P o i n t , PA 19486

(919)-632-7327/(800)-221-0453

(21 5) -699-7733

A & E Connock, L t d . F o r d i n g s b r i dge, Hunts, UK

Croda, I n c . 7 Century D r . P a r s i ppany, N J 07054 (201)-644-4900

Dow Chemical USA 2020 Dow Center M id land , M I 48674 (800)-258-CHEM

Dow Corn ing Corp. Box 0994 Mid land , M I 48686 (51 7)-496-4000

Dragoco, I n c . 10 Gordon D r i v e Totowa, NJ 07512 (201)-256-3850

DuPont Co. 1007 Market S t . W i l m i n g t o n , DE 19898 (800)-441-7515

Eastman Chemical Co. P .O. Box 431 K i n g s p o r t , TN 37662 (615)-229-4006/(800)-EASTMAN

ECC Ameri ca 5775 Peachtree-Dunwoody Rd. A t l a n t a , GA 30342 (800)-843-3222

E . Merck Darmstadt , Germany

Fanni ng Corp. 2450 W . Hubbard S t . Chicago, I L 60612 (312)-563-1234

F i n e t e x , I n c . 418 Falmouth Ave. Elmwood Park, NJ 07407 (201)-797-4686

F1 o r i da Food Produc ts , I nc . 2231 W . Hwy 44 E u s t i s , FL 32726 (904)-357-4141

H . B . F u l l e r Co. 3530 N . L e x i n g t o n Ave. S t . Paul , MN 55126 (612)-481-1588/(800)-468-6358

GE S i 1 i c o n e s 260 Hudson R i v e r Rd. W a t e r f o r d , NY 12188 (518)-237-3330/(800)-255-8886

Givaudan-Roure Corp. 100 Delawanna Ave. C l i f t o n , N J 07015 (201)-365-8000

Go1 dschmi d t Chemi c a l Corp. 914 E . Randolph Rd. Hopewel l , VA 23860 (804)-541-8658/(800)-445-1809

Suppliers' Addresses 397

B.F. Goodr i ch Co. 991 1 B recksv i 11 e R d . C1 eve1 and , OH 441 41 (216)-447-5000/(800)-331-1144

Haarman & Reimer Corp. 60 Diamond R d . S p r i n g f i e l d , NJ 07091 (201)-912-5707/(800)-432-1559

Hampshi r e Chemical Co. 55 Hayden Ave. Lex i ng ton , MA 021 73 (61 7 ) -861 -6600

Henkel Corp . 11501 N o r t h l a k e D r . C i n c i n n a t i , OH 45299 (513)-530-7300/(800)-543-7370

Hercu l es, I n c . Hercu les P1 aza W i 1 m i ng ton , DE 19894 (800)-247-4372

Hoechst Celanese Corp. 3340 W . N o r f o l k Rd. Portsmouth, VA 23703 (800)-483-7530/(800)-526-4960

Hoffman-LaRoche, I n c . 340 K i n g s l a n d S t . N u t l e y , NJ 07110 (201)-235-8080/(800)-526-0189

Hormel P.O. Box 800 Aust i n , MN 5591 2 (507)-437-5676

J.M. Huber Corp. T h o r n a l l S t . Ed ison, NJ 08837 (201)-549-8600

H u l s America, I n c . 80 C e n t e n n i a l D r . P i scataway, N J 08854 (908)-980-6946/(800)-526-0339

Hydro1 abs , I n c . 27 E . 33 S t . Pa terson, NJ 07514 (201 ) -345-51 00

I C 1 Americas I n c . Concord Pi ke & New Murphy R d . W i 1 m i n g t o n , DE 19897 (302)-575-3034/(800)-822-8215

I n o l e x Chemical Co. Jackson & Swanson S t s . P h i l a d e l p h i a , PA 19148 (215)-271-0800/(800)-521-9691

ISP: I n t e r n a t i o n a l S p e c i a l t y Prod 1361 A l p s Rd. Wayne, NJ 07470 (201)-628-3000/(800)-848-7659

Ke lco D i v . Merck & Co., I n c . 8355 Aero D r i v e San D iego, CA 92123 (619)-292-4900/(800)-535-2656

Kemira, I n c . 1170 R t e 22E P . O . Box 6784 B r i dgewater , NJ 08807 (201) -526-4644/ (800) -4-KEMIRA

Koster-Keunen, I n c , P . O . Box 447 90 Bourne B l v d . S a y v i l l e , NY 11782 (51 6) -589-0456

Lanaetex P roduc ts , I n c . 151 3 Ave. E l i zabeth , NJ 07206 (908)-351-9700

L i p 0 Chemicals, I n c . 207 19 th Ave. Pa te rson , NJ 07504 (201 ) -345-8600


Lonza, I n c . 17-17 R t e . 208 F a i r Lawn, NJ 07410 (201)-794-2400/(800)-777-1875

Mear l Corp . 41 E . 42 S t . New York , NY 10017 (212)-573-8500

Mona I n d u s t r i e s I n c . 76 E. 24 S t . P.O. Box 425 P a t e r s o n , NJ 07544 (201 ) -345-8220

M o r f l e x , I n c . 2110 H i g h P o i n t R d . Greensboro, NC 27403 (919)-292-1781

N a t i o n a l S t a r c h & Chemical Co. 10 F i n d e r n e Ave. B r i dgewater , NJ 08807 (908)-685-5000/(800)-532-1115

N i p a L a b o r a t o r i e s I n c . 104 Hag ley B l d g . Concord P1 aza 3411 S i l v e r s i d e Rd. W i l m i n g t o n , DE 19810 (302)-478-1522

O i Is o f A loha P . O . Box 685 66-935 Kaukonahua Rd. Wai a1 ua, Hawai i 96791 (800)-367-6010

01 i n Corp. 120 Long R idge Rd. P . O . Box 1355 Stamfo rd , CT 06904 (203)-356-2000/(800)-243-9171

O r i g i n a l B r a d f o r d Soap Works 200 P r o v i d e n c e S t . West Warwick, R I 02893 (401 ) -821 -21 41

Pentapharm L t d . Engelgasse 109, P.0.Box B a s e l , S w i t z e r l a n d

Penreco 138 P e t r o l i a S t . Karns C i t y , PA 16041 (412)-283-5600/(800)-245-3952

P e t r o l i t e Corp. 6910 E 14 S t . T u l s a , OK 74112 (91 8) -836-1601

Phoenix Chemical Co., I n c . 322 C o u r t y a r d D r i v e S o m e r v i l l e , NJ 08876 (908)-707-0232

P h i l l i p s 66 Co. 376 P h i l l i p s B l d g . Annex B a r t l e s v i l l e , OK 74004 (806)-274-5236/(800)-858-4327

P i l o t Chemical Co. 11756 Burke S t . Santa Fe S p r i n g s , CA 90670 (21 3) -723-0036

P o l y e s t h e r Corp . 61 H i l l S t . P . O . Drawer 5076 Southampton, NY 1 1 969 (51 6) -283-4400

PPG I n d u s t r i e s 3938 P o r e t t D r i ve Gurnee, I L 60031 (708)-244-3410/(800)-CHEM-PPG

P r o c t o r & Gamble Chemicals D i v . P . O . Box 599 C i n c i n n a t i , OH 45201 (513)-983-5607/(800)-543-1580

Quest I n t e r n a t i o n a l F rag rances 400 I n t e r n a t i o n a l D r . Mount O l i v e , NJ 07828 (201 ) -691 -71 00

Suppliers' Addresses 399

Rheox Inc. Wyckoff Mills Rd. Hightstown, NJ 08520 (609)-443-2320

Rhone-Poulenc Inc. Prospect Plai ns Rd. Cranbury, NJ 08512

Dr. K. Richter GmbH Chemi sches Laboratori um Benni gonstrabe 25, D-1000 Berlin

(609)-860-4000

R. I .T.A. Corp. 1725 Ki 1 kenny Woodstock, IL 60098

Roche Chemical Di vi si on Hoffman-LaRoche, Inc. Nutley, NJ 07110

Rohm & Haas Co. Independence Mall West Philadelphia, PA 19105

(815)-337-2500/(800)-426-7759

(201 ) -235-8077 / (800 ) -526-0189

(215)-592-3000

Rona/EM Industries 5 Skyline Drive Hawthorne, NY 10532 (91 4)-592-4660

Frank 6. Ross Co., Inc. P.O. Box 4085 Jersey City, N J 07304

Scher Chemicals Inc. Industrial W cor Styertowne Rd Clifton, N J 07012

(201 ) -433-451 2

(201 )-471-1300

Shell Chemical Co. P.O. Box 2463 Houston, TX 77002 (71 3)-241-6161

Stepan Co. 22 W . Frontage Rd. Northfield, IL 60093 (708)-446-7500

Sun Chemical Corp. 411 Summit Ave. Cincinnati , OH 45232 (513)-681-5950/(800)-343-2583

Sutton Laboratories, Inc. 116 Summit Ave. Cincinnati , OH 45232 (513)-681-5950/(800>-343-2583

Terry Laboratories, Inc. 390 N . Wickham Rd. P . O . Box 566 Melbourne, FL 32935 (407) -259-1630 / (800 ) -367-2563

Tioxide Speciaties Ltd. Billingham, Cleveland TS23 1PS United Kingdom 0642-370300

Tri-K Industries, Inc. P.O. Box 312 27 Bland St. Emerson, NJ 07630 (201) -261-2800 / (800 ) -526-0372

Trivent Chemical Co. 45 Ridge Rd. P.O. Box 597 South River, NJ 08882 (908)-251-1116

Unichema North America 4650 S. Racine Ave. Chicago, IL 60609 (312) -376-9000 / (800 ) -833-2864

Union Carbide Chemicals and

39 Old Ridgebury Rd. Danbury, CT 06817

P1 ast i cs

(203)-794-5300


R . T . V a n d e r b i l t Co., I n c . 30 W i n f i e l d S t . P . O . Box 5150 Norwal k , CT 06856 (203 ) -853-1 400

Van Dyk Ma in & W i l l i a m S t s . B e l l e v i l l e , NJ 07109 (201)-450-3264

Wacker S i l i c o n e s Corp. 3301 S u t t o n Rd. A d r i a n , M I 49221 (517)-264-8500/(800)-248-0063

W h i t t a k e r , C l a r k & D a n i e l s 1000 C o o l i d g e S t . South P l a i n f i e l d , NJ 07080 (908) -561 -61 00

W i t c o Corp. ( A l l Groups) 1 ) O l e o s u r f a c t a n t s Group 2 ) P e t r o l eum Speci a1 t i es Group 3)Polymer A d d i t i v e s Group 520 Madison Ave. New Y o r k , NY 10022 (212)-605-3600

W i t c o Corp . 5777 F r a n t z R d . P . O . Box 646 D u b l i n , OH 43017 (614)-765-6500/(800)-366-6500

Zschimmer & Schwarz P.O. Box 2179 D-5420 L a h n s t e i n, West Germany

3V I n c . 1500 Harbo r B l v d . Weehawken, NJ 07087 (201 )-865-3600

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