'EPOXY - Amazon S3 DATA … · Impregnating and insulating copper coil windings in motors and...
Transcript of 'EPOXY - Amazon S3 DATA … · Impregnating and insulating copper coil windings in motors and...
EPOXY TECHNOLOGY Number of Components Two Frozen Syringe Mix Ratio By Weight 101 Specific Gravity 118 120degC 5 Minutes
Part A 120 100C 10 Minutes Part B 102 80degC 30 Minutes
P~Li~ s3Hoorn 2 Hours Shelf Life One year at 23degC Six months at -40C Note Container(s) should be kept closed when not in use middotPlease see Applications Note available on our website -TOTAL MASS SHOULD NOT EXCEED 25 GRAMSshy-IF PARTA CRYSTALIZES IN STORAGE PLACE CONTAINER IN A WARM OVEN UNTIL CRYSTALIZATION DISAPPEARS ALLOWTO COOL TO ROOM TEMPERA TURE BEFORE MIXING WITH THE PART B HARDENER middotPlease refer to Tech Tip 7 on our website -shy
Minimum Bond Line Cure Schedule 150degC 1 Minute
Product Description EPO-TEK 353ND is a tWo component high temperature epoxy designed for semiconductor hybrid fiber optic and medical applications It is one
of the most popular EPO-TE~ brand products and is known throughout the world for its performance and reliability Also available in a single component frozen syringe
EPO-TEKreg 353ND Advantages amp Application Notes
bull Reasonable pot-life that allows for low temperature curing to be realized It has an amber color change upon cure
bull Passes NASA low outgassing standard ASTM E595 with proper cure - httpoutgassingnasagov
bull Semiconductor suggested applications wafer-wafer bonding of CSP fabrication of MEMs devices flip chip underfill
bull Hybrid suggested applications providing near hermetic seals and UHV seals in sensor devices resisting high temperature packaging o Down-Hole petrochemical fiber optic sensors resisting gt200middotC field conditions
bull Fiber optic adhesive designed to meet Telecordia 1221 - suggested applicetions o Sealing fiber into ferrules transmitting light in the optical pathway from 800- 1550 nm range o Fiber component packaging adhesive for active alignment of optics environmental seal of opto-package V-groove arrays
bull Medical suggested applications o Potting fiber optic bundles into ferrules for light guides and endoscopes capable of resisting several sterilization techniques including
ETa gamma ION beam H202 plasma and gt200 autoclave steam cycles excellent adhesion to surfaces including SST diamond titanium brass ceramics glass and most plastics
o Adhesive for catheter devices including stents and guide wires o Certified to USP Class VI and ISO 10993 biocompatibility standards for medical implants o Compatible with CIDEXreg OPA sterilization
bull Electronics Assembly suggested applications o Used as dielectric layer in the fabrication of capacitors laminating PZT ferroelectrics found in ultrasound or ink-jetting devices o Impregnating and insulating copper coil windings in motors and inductor coils Bonding ferrite cores and magnets o Structural grade epoxy found in hard-disk drive devices bonding of SST metals kapton and magnets
Typical Properties (To be used as a guide only not as a specification
Cure condition 150C11 hour iiiiiiii~iiiiiii~i~~~ij
Consistency liquid Viscosity (50 RPM23C) 3000 - 5000 cPs Thixotropic Index NA Glass Transition Temp(Tg) a 90C (Dynamic Cure
2Q-200middotC IIS0 25 Min Ramp -1Q-200middotC 20degClMin) Coefficient of Thermal Expansion (CTE)
Below Tg 54 x 10-6 ininrC Above Tg 206 x 106 ininre
Shore 0 Hardness 85 Lap Shear Strength 23C gt 2000 psi Die Shear Strength a 15 Kg 5100 psi
317
nm
200degC 022 250degC 039 300degC 087
Operating Temp Continuous 55degC to 250degC Intermittent - 55degC to 350middotC
Storage Modulus 23C 516912 psi Ions CI 329 ppm
nm
EPOXY TECHNOLOGY INC 14 Fortune Drive Billerica MA 01821-3972 Phone 9786673805 Fax 9786639782
wwwEPOTEKcom
Epoxies and Adhesives for Demanding Applicatlonstrade This information is based on data and tests believed to be accurate Epoxy Technology Inc makes no warranties
(expressed or implied) as to its accuracy and assumes no liability in connection with any use of this product n_bull VVII
Revision 1102CLP SAFETY DATA SHEET Date 30 August 2012
SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part A GHS Product Identifier EPO-TEK 353ND Part A Chemical Name Not applicable Trade name EPO-TEK 353ND Part A EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtellnc Emergency Phone No (800) 255--3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 5 Skin irritation 2 Eye Damage 3 Skin Sensitizer 1 (3115
322 332 341 ) 212 Directive 67548EEC amp Directive 199945EC - HARMFUL IRRITANT 22 Label elements 221 Label elements According to Regulation (Ee) No 127212008 (CLP)
GHS Product Identifier (EU)
Hazard lttgt~ Signal word(s) WARNINGpictogram(s)
Hazard H303 May be harmful if swallowed statement(s) H315 Causes skin irritation
H317 May cause an allergiC skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer
Precautionary P202 Do not handle until all safety precautions have been read and understood statement( s) P2S0 Wear protective glovesprotective clothingeye protectionface protection
P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P33S IF IN EYE8 Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P30S + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to 8end to a licensed recycler reclaimer or incinerator
222 Label elements Uf)4UrtlL amp Directive 19991451EC
Hazard Symbol
Risk Phrases R22 Harmful if swallowed R363S Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms
Safety Phrases 82 Keep out of the reach of children 823 Do not breathe fumeslvapour 82425 Avoid contact with skin and eyes 826 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 83639 Wear suitable protective clothing and eyeface protection 845 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
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EPOmiddotTEK 353ND Part A
Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Sensitizer (Skin) Irritant (Eyes Skin) HMIS Health-2 Flammability-1 Reactivity - 0
WHMIS Classification (Canada) Hazardous under WHMIS Class D2B - Material Causing Other Toxic Effects (Sensitizer Irritation)
24 Additional Information None
SECTION 3 COMPOSITIONINFORMATION ON INGREDIENTS
i
EC Classification No 12722008EC
Hazardous ingredient(~) I WIW REACH
CAS No ECNo Registration Hazard pictogram(s) and Hazard statement(s) No
3153212 341 3312
Ilttgt~Epoxy Phenol Novolac gt75 128064-14-4 None NA 412 H303 H315H317 H319 H411 EUH205
REACH Hazardous ingredient(s) WIW CAS No EC No Registration Hazard pictogram(s) and Risk (R) Phras(es)
No
Epoxy Phenol Novolac gt75 28064-14-4 None NA Xn Xi R22 3638 43 51
Additional Information - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 DeSCription of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and effects both acute and delayed
43 Indication of the immediate medical attention and special treatment needed
Remove patient from exposure Keep patient at rest and give oxygen if breathing difficult If symptoms develop obtain medical attention
Remove contaminated clothing immediately and drench affected skin with plenty of water If irritation (redness rash blistering) develops get medical attention
Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion may cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes serious eye irritation Causes skin irritation Allergic contact dermatitis Ingestion may cause irritation of the gastrointestinal tract
Delayed and chronic effects Allergic eczema
Treat symptomatically
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EPO-TEK 353ND Part A
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or waterspray Media Unsuitable Extinguishing None known Media
52 Special hazards arising A self contained breathing apparatus and suitable protective clothing should from the substance or be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or waterspray
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions protective equipment and emergency procedures
62 Environmental precautions 63 Methods and material for
containment and cleaning up 64 Reference to other sections 65 Additional Information
Ensure full personal protection (including respiratory protection) during removal of spillages
Ventilation recommended
Transfer to a lidded container for disposal or recovery See Also Section 7 8 13 None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapours Keep away from oxidizing agents Keep away from fire sparks and heated surfaces- no smoking Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
I CAS No LTEL I LTEL STEL STEL
i
SUBSTANCE Note8 hr TWA ppm) (8 hr TWA mgm3) (ppm) (mgm3) I
NE NE NE NE PEL (OSHA)
Epoxy Phenol Novolac 28064-14-4 I
i i NE NE NE NE TLV (ACGIH)
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812 Biological limit value
I Limit value type (country of origin)
SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
i Industry - Long Term - Local effects NA NA NA
Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term - Systemic effects NA NA NA
Professional- Long Term - Local effects NA NA NA
Professional- Long Term - Systemic effects NA NA NA
Professional - Short term - Local effects NA NA NA
i Professional - Short term - Systemic effects NA NA NA
Consumer - Long Term - Local effects NA NA NA
Consumer - Long Term - Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
ITerrestrial Compartment Not available
I Atmospheric Compartment Not available
822 Personal protection equipment
O[ Respirators IWear suitable respiratory protective equipment if exposure to levels bull above the occupational exposure limit is likely I
01 Eye Safety glasses Protection
I
Gloves Wear protective gloves
ill I
Body Wear suitable protective clothing and gloves Ie protection
Engineering Use adequate ventilation andor engineering controls in high Controls tem~erature processing to prevent ex~osure to vapors Other Remove contaminated saturated clothing immediately Contaminated
clothing should be thoroughly cleaned
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EPO-TEK 353ND Part A
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Clear liquid Colour Clear liquid Odor Mild I Slight Odor Threshold (ppm) Not available Melting Point (C) I
Not available Boiling pointboiling range (0C) Not available Freezing Point (C) Flash Point (C) gt 200F 193degC Explosive limit ranges Not available Auto Ignition
Not available Decomposition Temperature (0C) Not ~vailableTemperature eC) Explosive properties Not available Oxidizing properties Not available Flammability (solid
Not available pH (Value) Not available gas) Evaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) Not available Density (gml) Not available Solubility (Water) Practically insoluble Solubility (Other) Not available Partition Coefficient (n-
Not available Viscosity (mPas) Not available Octanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity Slight
102 Chemical stability Stable under normal conditions
103 Possibility of hazardous reactions Can react violently if in contact with - Oxidizing agents
104 Conditions to avoid Avoid contact with heat and ignition sources
105 Incompatible materials Bleaching products and comparable oxidizers
106 Hazardous Decomposition Carbon monoxide Carbon dioxide Product(s)
SECTION 11 TOXICOLOGICAL INFORMATION
I SUBSTANCE CAS No LDso Oral LCso (Inhalation LD50 (Dermal
Rat Rat Rat)
Epoxy Phenol Novolac 28064-14-4 Not established Not established Not established
I 111
1112
112
~~~k
Information on toxicological effects
Mixtures Acute toxicity Irritation
Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction
Other information
Page 59
May be harmful if swallowed Causes skin and eye irritation May cause transient irritation Notto be expected May cause sensitization by skin contact No data No data No data No data
None
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SECTION 12 INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Biodegradable Not persistent
123 Bioaccumulative potential The product has low potential for bioaccumulation
124 Mobility in soil The product has high mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (ADRIRID) (b)(c)(d) UN number UN3082
Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Hazard label(s) Miscellaneous Environmental hazards Marine Pollutant Special precautions for None user
Sea transport (IMDG) (b)(c) UN number UN3082 Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Marine Pollutant Yes Special precautions for None user
Land transport (Within USA) (c)(d) UN number
Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Hazard label(s) None Environmental hazards None Special precautions for None user
Air transport (ICAOIIATA) (c) (d) UN number Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Environmental hazards None Special precautions for None user
(b)- Fullpropershipplngname Environmentally Hazardous Substance Liquid nOs (Epoxy Phenol Novolac)
(c)- Consult with transport provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex of MARPOL7378 and the IBC Code
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SECTION 15 REGULATORY INFORMATION
151
1511
1512
152
153
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions Consult the supplier on use European Union None (EINECSELINCS) WGK number Not Applicable
National regulations
USA
TSCA (Toxic Substance Control Act)
SARA 311312 - Hazard Categories
SARA 302 - Extremely Hazardous Substances SARA 313 - Toxic Chemicals
CERCLA (Comprehensive Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990)
CWA (Clean Water Act)
State Right to Know Lists
Proposition 65 (California)
Canada
WHMIS Classification
Canada (DSLINDSL)
Canada Ingredient Disclosure List (CIDL)
Chemical Safety Assessment
Label elements (EU)
All chemicals listed
Acute Health
Listed - None
Contains None
Listed - None
Listed - None
Listed - None
Listed - CAS28064-14-4 NJ PA
Listed - None
Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Sensitizer
Irritation) Listed - DSL
Listed as required
Irritant (Skin Eye) (Skin Sensitizer Irritation)
Label as Harmful Irritant under 199945EC 19072006EC and 127212008EC See Section 2 for full label requirements
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EPO-TEK 353ND Part A
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 1-16
LEGEND
ACGIH American Conference of Governmental Industrial NA not applicable not available Hygienists
AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and Health
ANSI American National Standards Institute NO not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective equipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TDG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CAS Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R3638 Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms S2 Keep out of the reach of children S23 Do not breathe fumeslvapour S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
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EPO-TEK 353ND Part A
Hazard statement(s) and Precautionary statement(s)
H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
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SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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EPO-TEK 353ND Part B
point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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EPO-TEK 353ND Part B
43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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EPO-TEK 353ND Part B
SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
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EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
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EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
Revision 1102CLP SAFETY DATA SHEET Date 30 August 2012
SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part A GHS Product Identifier EPO-TEK 353ND Part A Chemical Name Not applicable Trade name EPO-TEK 353ND Part A EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtellnc Emergency Phone No (800) 255--3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 5 Skin irritation 2 Eye Damage 3 Skin Sensitizer 1 (3115
322 332 341 ) 212 Directive 67548EEC amp Directive 199945EC - HARMFUL IRRITANT 22 Label elements 221 Label elements According to Regulation (Ee) No 127212008 (CLP)
GHS Product Identifier (EU)
Hazard lttgt~ Signal word(s) WARNINGpictogram(s)
Hazard H303 May be harmful if swallowed statement(s) H315 Causes skin irritation
H317 May cause an allergiC skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer
Precautionary P202 Do not handle until all safety precautions have been read and understood statement( s) P2S0 Wear protective glovesprotective clothingeye protectionface protection
P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P33S IF IN EYE8 Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P30S + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to 8end to a licensed recycler reclaimer or incinerator
222 Label elements Uf)4UrtlL amp Directive 19991451EC
Hazard Symbol
Risk Phrases R22 Harmful if swallowed R363S Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms
Safety Phrases 82 Keep out of the reach of children 823 Do not breathe fumeslvapour 82425 Avoid contact with skin and eyes 826 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 83639 Wear suitable protective clothing and eyeface protection 845 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
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23
33
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EPOmiddotTEK 353ND Part A
Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Sensitizer (Skin) Irritant (Eyes Skin) HMIS Health-2 Flammability-1 Reactivity - 0
WHMIS Classification (Canada) Hazardous under WHMIS Class D2B - Material Causing Other Toxic Effects (Sensitizer Irritation)
24 Additional Information None
SECTION 3 COMPOSITIONINFORMATION ON INGREDIENTS
i
EC Classification No 12722008EC
Hazardous ingredient(~) I WIW REACH
CAS No ECNo Registration Hazard pictogram(s) and Hazard statement(s) No
3153212 341 3312
Ilttgt~Epoxy Phenol Novolac gt75 128064-14-4 None NA 412 H303 H315H317 H319 H411 EUH205
REACH Hazardous ingredient(s) WIW CAS No EC No Registration Hazard pictogram(s) and Risk (R) Phras(es)
No
Epoxy Phenol Novolac gt75 28064-14-4 None NA Xn Xi R22 3638 43 51
Additional Information - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 DeSCription of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and effects both acute and delayed
43 Indication of the immediate medical attention and special treatment needed
Remove patient from exposure Keep patient at rest and give oxygen if breathing difficult If symptoms develop obtain medical attention
Remove contaminated clothing immediately and drench affected skin with plenty of water If irritation (redness rash blistering) develops get medical attention
Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion may cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes serious eye irritation Causes skin irritation Allergic contact dermatitis Ingestion may cause irritation of the gastrointestinal tract
Delayed and chronic effects Allergic eczema
Treat symptomatically
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SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or waterspray Media Unsuitable Extinguishing None known Media
52 Special hazards arising A self contained breathing apparatus and suitable protective clothing should from the substance or be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or waterspray
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions protective equipment and emergency procedures
62 Environmental precautions 63 Methods and material for
containment and cleaning up 64 Reference to other sections 65 Additional Information
Ensure full personal protection (including respiratory protection) during removal of spillages
Ventilation recommended
Transfer to a lidded container for disposal or recovery See Also Section 7 8 13 None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapours Keep away from oxidizing agents Keep away from fire sparks and heated surfaces- no smoking Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
I CAS No LTEL I LTEL STEL STEL
i
SUBSTANCE Note8 hr TWA ppm) (8 hr TWA mgm3) (ppm) (mgm3) I
NE NE NE NE PEL (OSHA)
Epoxy Phenol Novolac 28064-14-4 I
i i NE NE NE NE TLV (ACGIH)
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EPO-TEK 353ND Part A
812 Biological limit value
I Limit value type (country of origin)
SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
i Industry - Long Term - Local effects NA NA NA
Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term - Systemic effects NA NA NA
Professional- Long Term - Local effects NA NA NA
Professional- Long Term - Systemic effects NA NA NA
Professional - Short term - Local effects NA NA NA
i Professional - Short term - Systemic effects NA NA NA
Consumer - Long Term - Local effects NA NA NA
Consumer - Long Term - Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
ITerrestrial Compartment Not available
I Atmospheric Compartment Not available
822 Personal protection equipment
O[ Respirators IWear suitable respiratory protective equipment if exposure to levels bull above the occupational exposure limit is likely I
01 Eye Safety glasses Protection
I
Gloves Wear protective gloves
ill I
Body Wear suitable protective clothing and gloves Ie protection
Engineering Use adequate ventilation andor engineering controls in high Controls tem~erature processing to prevent ex~osure to vapors Other Remove contaminated saturated clothing immediately Contaminated
clothing should be thoroughly cleaned
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EPO-TEK 353ND Part A
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Clear liquid Colour Clear liquid Odor Mild I Slight Odor Threshold (ppm) Not available Melting Point (C) I
Not available Boiling pointboiling range (0C) Not available Freezing Point (C) Flash Point (C) gt 200F 193degC Explosive limit ranges Not available Auto Ignition
Not available Decomposition Temperature (0C) Not ~vailableTemperature eC) Explosive properties Not available Oxidizing properties Not available Flammability (solid
Not available pH (Value) Not available gas) Evaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) Not available Density (gml) Not available Solubility (Water) Practically insoluble Solubility (Other) Not available Partition Coefficient (n-
Not available Viscosity (mPas) Not available Octanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity Slight
102 Chemical stability Stable under normal conditions
103 Possibility of hazardous reactions Can react violently if in contact with - Oxidizing agents
104 Conditions to avoid Avoid contact with heat and ignition sources
105 Incompatible materials Bleaching products and comparable oxidizers
106 Hazardous Decomposition Carbon monoxide Carbon dioxide Product(s)
SECTION 11 TOXICOLOGICAL INFORMATION
I SUBSTANCE CAS No LDso Oral LCso (Inhalation LD50 (Dermal
Rat Rat Rat)
Epoxy Phenol Novolac 28064-14-4 Not established Not established Not established
I 111
1112
112
~~~k
Information on toxicological effects
Mixtures Acute toxicity Irritation
Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction
Other information
Page 59
May be harmful if swallowed Causes skin and eye irritation May cause transient irritation Notto be expected May cause sensitization by skin contact No data No data No data No data
None
Expiration Date 30 August 2014
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EPO-TEK 353ND Part A
SECTION 12 INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Biodegradable Not persistent
123 Bioaccumulative potential The product has low potential for bioaccumulation
124 Mobility in soil The product has high mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (ADRIRID) (b)(c)(d) UN number UN3082
Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Hazard label(s) Miscellaneous Environmental hazards Marine Pollutant Special precautions for None user
Sea transport (IMDG) (b)(c) UN number UN3082 Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Marine Pollutant Yes Special precautions for None user
Land transport (Within USA) (c)(d) UN number
Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Hazard label(s) None Environmental hazards None Special precautions for None user
Air transport (ICAOIIATA) (c) (d) UN number Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Environmental hazards None Special precautions for None user
(b)- Fullpropershipplngname Environmentally Hazardous Substance Liquid nOs (Epoxy Phenol Novolac)
(c)- Consult with transport provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex of MARPOL7378 and the IBC Code
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EPO-TEK 353ND Part A
SECTION 15 REGULATORY INFORMATION
151
1511
1512
152
153
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions Consult the supplier on use European Union None (EINECSELINCS) WGK number Not Applicable
National regulations
USA
TSCA (Toxic Substance Control Act)
SARA 311312 - Hazard Categories
SARA 302 - Extremely Hazardous Substances SARA 313 - Toxic Chemicals
CERCLA (Comprehensive Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990)
CWA (Clean Water Act)
State Right to Know Lists
Proposition 65 (California)
Canada
WHMIS Classification
Canada (DSLINDSL)
Canada Ingredient Disclosure List (CIDL)
Chemical Safety Assessment
Label elements (EU)
All chemicals listed
Acute Health
Listed - None
Contains None
Listed - None
Listed - None
Listed - None
Listed - CAS28064-14-4 NJ PA
Listed - None
Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Sensitizer
Irritation) Listed - DSL
Listed as required
Irritant (Skin Eye) (Skin Sensitizer Irritation)
Label as Harmful Irritant under 199945EC 19072006EC and 127212008EC See Section 2 for full label requirements
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EPO-TEK 353ND Part A
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 1-16
LEGEND
ACGIH American Conference of Governmental Industrial NA not applicable not available Hygienists
AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and Health
ANSI American National Standards Institute NO not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective equipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TDG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CAS Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R3638 Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms S2 Keep out of the reach of children S23 Do not breathe fumeslvapour S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
Page 89 Expiration Date 30 August 2014
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EPO-TEK 353ND Part A
Hazard statement(s) and Precautionary statement(s)
H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
Page 99 Expiration Date 30 August 2014
Revision 1102CLP SAFETY DATA SHEET Date 30 August 2012
SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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EPO-TEK 353ND Part B
point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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EPO-TEK 353ND Part B
43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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EPO-TEK 353ND Part B
SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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C
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
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EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
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EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
23
33
Revision 1102GLP SAFETY DATA SHEET Date 30 August 2012
EPOmiddotTEK 353ND Part A
Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Sensitizer (Skin) Irritant (Eyes Skin) HMIS Health-2 Flammability-1 Reactivity - 0
WHMIS Classification (Canada) Hazardous under WHMIS Class D2B - Material Causing Other Toxic Effects (Sensitizer Irritation)
24 Additional Information None
SECTION 3 COMPOSITIONINFORMATION ON INGREDIENTS
i
EC Classification No 12722008EC
Hazardous ingredient(~) I WIW REACH
CAS No ECNo Registration Hazard pictogram(s) and Hazard statement(s) No
3153212 341 3312
Ilttgt~Epoxy Phenol Novolac gt75 128064-14-4 None NA 412 H303 H315H317 H319 H411 EUH205
REACH Hazardous ingredient(s) WIW CAS No EC No Registration Hazard pictogram(s) and Risk (R) Phras(es)
No
Epoxy Phenol Novolac gt75 28064-14-4 None NA Xn Xi R22 3638 43 51
Additional Information - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 DeSCription of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and effects both acute and delayed
43 Indication of the immediate medical attention and special treatment needed
Remove patient from exposure Keep patient at rest and give oxygen if breathing difficult If symptoms develop obtain medical attention
Remove contaminated clothing immediately and drench affected skin with plenty of water If irritation (redness rash blistering) develops get medical attention
Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion may cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes serious eye irritation Causes skin irritation Allergic contact dermatitis Ingestion may cause irritation of the gastrointestinal tract
Delayed and chronic effects Allergic eczema
Treat symptomatically
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EPO-TEK 353ND Part A
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or waterspray Media Unsuitable Extinguishing None known Media
52 Special hazards arising A self contained breathing apparatus and suitable protective clothing should from the substance or be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or waterspray
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions protective equipment and emergency procedures
62 Environmental precautions 63 Methods and material for
containment and cleaning up 64 Reference to other sections 65 Additional Information
Ensure full personal protection (including respiratory protection) during removal of spillages
Ventilation recommended
Transfer to a lidded container for disposal or recovery See Also Section 7 8 13 None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapours Keep away from oxidizing agents Keep away from fire sparks and heated surfaces- no smoking Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
I CAS No LTEL I LTEL STEL STEL
i
SUBSTANCE Note8 hr TWA ppm) (8 hr TWA mgm3) (ppm) (mgm3) I
NE NE NE NE PEL (OSHA)
Epoxy Phenol Novolac 28064-14-4 I
i i NE NE NE NE TLV (ACGIH)
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EPO-TEK 353ND Part A
812 Biological limit value
I Limit value type (country of origin)
SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
i Industry - Long Term - Local effects NA NA NA
Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term - Systemic effects NA NA NA
Professional- Long Term - Local effects NA NA NA
Professional- Long Term - Systemic effects NA NA NA
Professional - Short term - Local effects NA NA NA
i Professional - Short term - Systemic effects NA NA NA
Consumer - Long Term - Local effects NA NA NA
Consumer - Long Term - Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
ITerrestrial Compartment Not available
I Atmospheric Compartment Not available
822 Personal protection equipment
O[ Respirators IWear suitable respiratory protective equipment if exposure to levels bull above the occupational exposure limit is likely I
01 Eye Safety glasses Protection
I
Gloves Wear protective gloves
ill I
Body Wear suitable protective clothing and gloves Ie protection
Engineering Use adequate ventilation andor engineering controls in high Controls tem~erature processing to prevent ex~osure to vapors Other Remove contaminated saturated clothing immediately Contaminated
clothing should be thoroughly cleaned
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EPO-TEK 353ND Part A
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Clear liquid Colour Clear liquid Odor Mild I Slight Odor Threshold (ppm) Not available Melting Point (C) I
Not available Boiling pointboiling range (0C) Not available Freezing Point (C) Flash Point (C) gt 200F 193degC Explosive limit ranges Not available Auto Ignition
Not available Decomposition Temperature (0C) Not ~vailableTemperature eC) Explosive properties Not available Oxidizing properties Not available Flammability (solid
Not available pH (Value) Not available gas) Evaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) Not available Density (gml) Not available Solubility (Water) Practically insoluble Solubility (Other) Not available Partition Coefficient (n-
Not available Viscosity (mPas) Not available Octanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity Slight
102 Chemical stability Stable under normal conditions
103 Possibility of hazardous reactions Can react violently if in contact with - Oxidizing agents
104 Conditions to avoid Avoid contact with heat and ignition sources
105 Incompatible materials Bleaching products and comparable oxidizers
106 Hazardous Decomposition Carbon monoxide Carbon dioxide Product(s)
SECTION 11 TOXICOLOGICAL INFORMATION
I SUBSTANCE CAS No LDso Oral LCso (Inhalation LD50 (Dermal
Rat Rat Rat)
Epoxy Phenol Novolac 28064-14-4 Not established Not established Not established
I 111
1112
112
~~~k
Information on toxicological effects
Mixtures Acute toxicity Irritation
Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction
Other information
Page 59
May be harmful if swallowed Causes skin and eye irritation May cause transient irritation Notto be expected May cause sensitization by skin contact No data No data No data No data
None
Expiration Date 30 August 2014
Revision 1102CLP SAnETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part A
SECTION 12 INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Biodegradable Not persistent
123 Bioaccumulative potential The product has low potential for bioaccumulation
124 Mobility in soil The product has high mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (ADRIRID) (b)(c)(d) UN number UN3082
Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Hazard label(s) Miscellaneous Environmental hazards Marine Pollutant Special precautions for None user
Sea transport (IMDG) (b)(c) UN number UN3082 Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Marine Pollutant Yes Special precautions for None user
Land transport (Within USA) (c)(d) UN number
Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Hazard label(s) None Environmental hazards None Special precautions for None user
Air transport (ICAOIIATA) (c) (d) UN number Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Environmental hazards None Special precautions for None user
(b)- Fullpropershipplngname Environmentally Hazardous Substance Liquid nOs (Epoxy Phenol Novolac)
(c)- Consult with transport provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex of MARPOL7378 and the IBC Code
Page 69 Expiration Date 30 August 2014 EPOXY TECHNOUXW
Revision 1102CLP SAFETY DATASHEET Date 30 August 2012
EPO-TEK 353ND Part A
SECTION 15 REGULATORY INFORMATION
151
1511
1512
152
153
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions Consult the supplier on use European Union None (EINECSELINCS) WGK number Not Applicable
National regulations
USA
TSCA (Toxic Substance Control Act)
SARA 311312 - Hazard Categories
SARA 302 - Extremely Hazardous Substances SARA 313 - Toxic Chemicals
CERCLA (Comprehensive Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990)
CWA (Clean Water Act)
State Right to Know Lists
Proposition 65 (California)
Canada
WHMIS Classification
Canada (DSLINDSL)
Canada Ingredient Disclosure List (CIDL)
Chemical Safety Assessment
Label elements (EU)
All chemicals listed
Acute Health
Listed - None
Contains None
Listed - None
Listed - None
Listed - None
Listed - CAS28064-14-4 NJ PA
Listed - None
Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Sensitizer
Irritation) Listed - DSL
Listed as required
Irritant (Skin Eye) (Skin Sensitizer Irritation)
Label as Harmful Irritant under 199945EC 19072006EC and 127212008EC See Section 2 for full label requirements
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EPO-TEK 353ND Part A
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 1-16
LEGEND
ACGIH American Conference of Governmental Industrial NA not applicable not available Hygienists
AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and Health
ANSI American National Standards Institute NO not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective equipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TDG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CAS Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R3638 Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms S2 Keep out of the reach of children S23 Do not breathe fumeslvapour S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
Page 89 Expiration Date 30 August 2014
Revision 1102CLP SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part A
Hazard statement(s) and Precautionary statement(s)
H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
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SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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EPO-TEK 353ND Part B
point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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EPO-TEK 353ND Part B
43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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EPO-TEK 353ND Part B
SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
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EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
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EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
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EPO-TEK 353ND Part A
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or waterspray Media Unsuitable Extinguishing None known Media
52 Special hazards arising A self contained breathing apparatus and suitable protective clothing should from the substance or be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or waterspray
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions protective equipment and emergency procedures
62 Environmental precautions 63 Methods and material for
containment and cleaning up 64 Reference to other sections 65 Additional Information
Ensure full personal protection (including respiratory protection) during removal of spillages
Ventilation recommended
Transfer to a lidded container for disposal or recovery See Also Section 7 8 13 None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapours Keep away from oxidizing agents Keep away from fire sparks and heated surfaces- no smoking Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
I CAS No LTEL I LTEL STEL STEL
i
SUBSTANCE Note8 hr TWA ppm) (8 hr TWA mgm3) (ppm) (mgm3) I
NE NE NE NE PEL (OSHA)
Epoxy Phenol Novolac 28064-14-4 I
i i NE NE NE NE TLV (ACGIH)
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EPO-TEK 353ND Part A
812 Biological limit value
I Limit value type (country of origin)
SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
i Industry - Long Term - Local effects NA NA NA
Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term - Systemic effects NA NA NA
Professional- Long Term - Local effects NA NA NA
Professional- Long Term - Systemic effects NA NA NA
Professional - Short term - Local effects NA NA NA
i Professional - Short term - Systemic effects NA NA NA
Consumer - Long Term - Local effects NA NA NA
Consumer - Long Term - Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
ITerrestrial Compartment Not available
I Atmospheric Compartment Not available
822 Personal protection equipment
O[ Respirators IWear suitable respiratory protective equipment if exposure to levels bull above the occupational exposure limit is likely I
01 Eye Safety glasses Protection
I
Gloves Wear protective gloves
ill I
Body Wear suitable protective clothing and gloves Ie protection
Engineering Use adequate ventilation andor engineering controls in high Controls tem~erature processing to prevent ex~osure to vapors Other Remove contaminated saturated clothing immediately Contaminated
clothing should be thoroughly cleaned
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EPO-TEK 353ND Part A
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Clear liquid Colour Clear liquid Odor Mild I Slight Odor Threshold (ppm) Not available Melting Point (C) I
Not available Boiling pointboiling range (0C) Not available Freezing Point (C) Flash Point (C) gt 200F 193degC Explosive limit ranges Not available Auto Ignition
Not available Decomposition Temperature (0C) Not ~vailableTemperature eC) Explosive properties Not available Oxidizing properties Not available Flammability (solid
Not available pH (Value) Not available gas) Evaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) Not available Density (gml) Not available Solubility (Water) Practically insoluble Solubility (Other) Not available Partition Coefficient (n-
Not available Viscosity (mPas) Not available Octanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity Slight
102 Chemical stability Stable under normal conditions
103 Possibility of hazardous reactions Can react violently if in contact with - Oxidizing agents
104 Conditions to avoid Avoid contact with heat and ignition sources
105 Incompatible materials Bleaching products and comparable oxidizers
106 Hazardous Decomposition Carbon monoxide Carbon dioxide Product(s)
SECTION 11 TOXICOLOGICAL INFORMATION
I SUBSTANCE CAS No LDso Oral LCso (Inhalation LD50 (Dermal
Rat Rat Rat)
Epoxy Phenol Novolac 28064-14-4 Not established Not established Not established
I 111
1112
112
~~~k
Information on toxicological effects
Mixtures Acute toxicity Irritation
Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction
Other information
Page 59
May be harmful if swallowed Causes skin and eye irritation May cause transient irritation Notto be expected May cause sensitization by skin contact No data No data No data No data
None
Expiration Date 30 August 2014
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EPO-TEK 353ND Part A
SECTION 12 INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Biodegradable Not persistent
123 Bioaccumulative potential The product has low potential for bioaccumulation
124 Mobility in soil The product has high mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (ADRIRID) (b)(c)(d) UN number UN3082
Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Hazard label(s) Miscellaneous Environmental hazards Marine Pollutant Special precautions for None user
Sea transport (IMDG) (b)(c) UN number UN3082 Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Marine Pollutant Yes Special precautions for None user
Land transport (Within USA) (c)(d) UN number
Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Hazard label(s) None Environmental hazards None Special precautions for None user
Air transport (ICAOIIATA) (c) (d) UN number Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Environmental hazards None Special precautions for None user
(b)- Fullpropershipplngname Environmentally Hazardous Substance Liquid nOs (Epoxy Phenol Novolac)
(c)- Consult with transport provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex of MARPOL7378 and the IBC Code
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EPO-TEK 353ND Part A
SECTION 15 REGULATORY INFORMATION
151
1511
1512
152
153
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions Consult the supplier on use European Union None (EINECSELINCS) WGK number Not Applicable
National regulations
USA
TSCA (Toxic Substance Control Act)
SARA 311312 - Hazard Categories
SARA 302 - Extremely Hazardous Substances SARA 313 - Toxic Chemicals
CERCLA (Comprehensive Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990)
CWA (Clean Water Act)
State Right to Know Lists
Proposition 65 (California)
Canada
WHMIS Classification
Canada (DSLINDSL)
Canada Ingredient Disclosure List (CIDL)
Chemical Safety Assessment
Label elements (EU)
All chemicals listed
Acute Health
Listed - None
Contains None
Listed - None
Listed - None
Listed - None
Listed - CAS28064-14-4 NJ PA
Listed - None
Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Sensitizer
Irritation) Listed - DSL
Listed as required
Irritant (Skin Eye) (Skin Sensitizer Irritation)
Label as Harmful Irritant under 199945EC 19072006EC and 127212008EC See Section 2 for full label requirements
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SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 1-16
LEGEND
ACGIH American Conference of Governmental Industrial NA not applicable not available Hygienists
AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and Health
ANSI American National Standards Institute NO not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective equipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TDG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CAS Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R3638 Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms S2 Keep out of the reach of children S23 Do not breathe fumeslvapour S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
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EPO-TEK 353ND Part A
Hazard statement(s) and Precautionary statement(s)
H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
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SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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EPO-TEK 353ND Part B
point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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EPO-TEK 353ND Part B
43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
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EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
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European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
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EPO-TEK 353ND Part A
812 Biological limit value
I Limit value type (country of origin)
SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
i Industry - Long Term - Local effects NA NA NA
Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term - Systemic effects NA NA NA
Professional- Long Term - Local effects NA NA NA
Professional- Long Term - Systemic effects NA NA NA
Professional - Short term - Local effects NA NA NA
i Professional - Short term - Systemic effects NA NA NA
Consumer - Long Term - Local effects NA NA NA
Consumer - Long Term - Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
ITerrestrial Compartment Not available
I Atmospheric Compartment Not available
822 Personal protection equipment
O[ Respirators IWear suitable respiratory protective equipment if exposure to levels bull above the occupational exposure limit is likely I
01 Eye Safety glasses Protection
I
Gloves Wear protective gloves
ill I
Body Wear suitable protective clothing and gloves Ie protection
Engineering Use adequate ventilation andor engineering controls in high Controls tem~erature processing to prevent ex~osure to vapors Other Remove contaminated saturated clothing immediately Contaminated
clothing should be thoroughly cleaned
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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Clear liquid Colour Clear liquid Odor Mild I Slight Odor Threshold (ppm) Not available Melting Point (C) I
Not available Boiling pointboiling range (0C) Not available Freezing Point (C) Flash Point (C) gt 200F 193degC Explosive limit ranges Not available Auto Ignition
Not available Decomposition Temperature (0C) Not ~vailableTemperature eC) Explosive properties Not available Oxidizing properties Not available Flammability (solid
Not available pH (Value) Not available gas) Evaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) Not available Density (gml) Not available Solubility (Water) Practically insoluble Solubility (Other) Not available Partition Coefficient (n-
Not available Viscosity (mPas) Not available Octanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity Slight
102 Chemical stability Stable under normal conditions
103 Possibility of hazardous reactions Can react violently if in contact with - Oxidizing agents
104 Conditions to avoid Avoid contact with heat and ignition sources
105 Incompatible materials Bleaching products and comparable oxidizers
106 Hazardous Decomposition Carbon monoxide Carbon dioxide Product(s)
SECTION 11 TOXICOLOGICAL INFORMATION
I SUBSTANCE CAS No LDso Oral LCso (Inhalation LD50 (Dermal
Rat Rat Rat)
Epoxy Phenol Novolac 28064-14-4 Not established Not established Not established
I 111
1112
112
~~~k
Information on toxicological effects
Mixtures Acute toxicity Irritation
Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction
Other information
Page 59
May be harmful if swallowed Causes skin and eye irritation May cause transient irritation Notto be expected May cause sensitization by skin contact No data No data No data No data
None
Expiration Date 30 August 2014
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SECTION 12 INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Biodegradable Not persistent
123 Bioaccumulative potential The product has low potential for bioaccumulation
124 Mobility in soil The product has high mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (ADRIRID) (b)(c)(d) UN number UN3082
Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Hazard label(s) Miscellaneous Environmental hazards Marine Pollutant Special precautions for None user
Sea transport (IMDG) (b)(c) UN number UN3082 Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Marine Pollutant Yes Special precautions for None user
Land transport (Within USA) (c)(d) UN number
Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Hazard label(s) None Environmental hazards None Special precautions for None user
Air transport (ICAOIIATA) (c) (d) UN number Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Environmental hazards None Special precautions for None user
(b)- Fullpropershipplngname Environmentally Hazardous Substance Liquid nOs (Epoxy Phenol Novolac)
(c)- Consult with transport provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex of MARPOL7378 and the IBC Code
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EPO-TEK 353ND Part A
SECTION 15 REGULATORY INFORMATION
151
1511
1512
152
153
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions Consult the supplier on use European Union None (EINECSELINCS) WGK number Not Applicable
National regulations
USA
TSCA (Toxic Substance Control Act)
SARA 311312 - Hazard Categories
SARA 302 - Extremely Hazardous Substances SARA 313 - Toxic Chemicals
CERCLA (Comprehensive Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990)
CWA (Clean Water Act)
State Right to Know Lists
Proposition 65 (California)
Canada
WHMIS Classification
Canada (DSLINDSL)
Canada Ingredient Disclosure List (CIDL)
Chemical Safety Assessment
Label elements (EU)
All chemicals listed
Acute Health
Listed - None
Contains None
Listed - None
Listed - None
Listed - None
Listed - CAS28064-14-4 NJ PA
Listed - None
Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Sensitizer
Irritation) Listed - DSL
Listed as required
Irritant (Skin Eye) (Skin Sensitizer Irritation)
Label as Harmful Irritant under 199945EC 19072006EC and 127212008EC See Section 2 for full label requirements
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SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 1-16
LEGEND
ACGIH American Conference of Governmental Industrial NA not applicable not available Hygienists
AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and Health
ANSI American National Standards Institute NO not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective equipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TDG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CAS Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R3638 Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms S2 Keep out of the reach of children S23 Do not breathe fumeslvapour S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
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EPO-TEK 353ND Part A
Hazard statement(s) and Precautionary statement(s)
H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
Page 99 Expiration Date 30 August 2014
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SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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EPO-TEK 353ND Part B
point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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EPO-TEK 353ND Part B
43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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EPO-TEK 353ND Part B
SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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C
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EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
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EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
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EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
Revision 1102ClP SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part A
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Clear liquid Colour Clear liquid Odor Mild I Slight Odor Threshold (ppm) Not available Melting Point (C) I
Not available Boiling pointboiling range (0C) Not available Freezing Point (C) Flash Point (C) gt 200F 193degC Explosive limit ranges Not available Auto Ignition
Not available Decomposition Temperature (0C) Not ~vailableTemperature eC) Explosive properties Not available Oxidizing properties Not available Flammability (solid
Not available pH (Value) Not available gas) Evaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) Not available Density (gml) Not available Solubility (Water) Practically insoluble Solubility (Other) Not available Partition Coefficient (n-
Not available Viscosity (mPas) Not available Octanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity Slight
102 Chemical stability Stable under normal conditions
103 Possibility of hazardous reactions Can react violently if in contact with - Oxidizing agents
104 Conditions to avoid Avoid contact with heat and ignition sources
105 Incompatible materials Bleaching products and comparable oxidizers
106 Hazardous Decomposition Carbon monoxide Carbon dioxide Product(s)
SECTION 11 TOXICOLOGICAL INFORMATION
I SUBSTANCE CAS No LDso Oral LCso (Inhalation LD50 (Dermal
Rat Rat Rat)
Epoxy Phenol Novolac 28064-14-4 Not established Not established Not established
I 111
1112
112
~~~k
Information on toxicological effects
Mixtures Acute toxicity Irritation
Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction
Other information
Page 59
May be harmful if swallowed Causes skin and eye irritation May cause transient irritation Notto be expected May cause sensitization by skin contact No data No data No data No data
None
Expiration Date 30 August 2014
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EPO-TEK 353ND Part A
SECTION 12 INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Biodegradable Not persistent
123 Bioaccumulative potential The product has low potential for bioaccumulation
124 Mobility in soil The product has high mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (ADRIRID) (b)(c)(d) UN number UN3082
Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Hazard label(s) Miscellaneous Environmental hazards Marine Pollutant Special precautions for None user
Sea transport (IMDG) (b)(c) UN number UN3082 Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Marine Pollutant Yes Special precautions for None user
Land transport (Within USA) (c)(d) UN number
Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Hazard label(s) None Environmental hazards None Special precautions for None user
Air transport (ICAOIIATA) (c) (d) UN number Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Environmental hazards None Special precautions for None user
(b)- Fullpropershipplngname Environmentally Hazardous Substance Liquid nOs (Epoxy Phenol Novolac)
(c)- Consult with transport provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex of MARPOL7378 and the IBC Code
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EPO-TEK 353ND Part A
SECTION 15 REGULATORY INFORMATION
151
1511
1512
152
153
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions Consult the supplier on use European Union None (EINECSELINCS) WGK number Not Applicable
National regulations
USA
TSCA (Toxic Substance Control Act)
SARA 311312 - Hazard Categories
SARA 302 - Extremely Hazardous Substances SARA 313 - Toxic Chemicals
CERCLA (Comprehensive Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990)
CWA (Clean Water Act)
State Right to Know Lists
Proposition 65 (California)
Canada
WHMIS Classification
Canada (DSLINDSL)
Canada Ingredient Disclosure List (CIDL)
Chemical Safety Assessment
Label elements (EU)
All chemicals listed
Acute Health
Listed - None
Contains None
Listed - None
Listed - None
Listed - None
Listed - CAS28064-14-4 NJ PA
Listed - None
Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Sensitizer
Irritation) Listed - DSL
Listed as required
Irritant (Skin Eye) (Skin Sensitizer Irritation)
Label as Harmful Irritant under 199945EC 19072006EC and 127212008EC See Section 2 for full label requirements
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EPO-TEK 353ND Part A
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 1-16
LEGEND
ACGIH American Conference of Governmental Industrial NA not applicable not available Hygienists
AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and Health
ANSI American National Standards Institute NO not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective equipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TDG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CAS Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R3638 Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms S2 Keep out of the reach of children S23 Do not breathe fumeslvapour S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
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EPO-TEK 353ND Part A
Hazard statement(s) and Precautionary statement(s)
H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
Page 99 Expiration Date 30 August 2014
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SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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EPO-TEK 353ND Part B
43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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C
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EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
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EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
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European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
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EPO-TEK 353ND Part A
SECTION 12 INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Biodegradable Not persistent
123 Bioaccumulative potential The product has low potential for bioaccumulation
124 Mobility in soil The product has high mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (ADRIRID) (b)(c)(d) UN number UN3082
Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Hazard label(s) Miscellaneous Environmental hazards Marine Pollutant Special precautions for None user
Sea transport (IMDG) (b)(c) UN number UN3082 Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Marine Pollutant Yes Special precautions for None user
Land transport (Within USA) (c)(d) UN number
Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Hazard label(s) None Environmental hazards None Special precautions for None user
Air transport (ICAOIIATA) (c) (d) UN number Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Environmental hazards None Special precautions for None user
(b)- Fullpropershipplngname Environmentally Hazardous Substance Liquid nOs (Epoxy Phenol Novolac)
(c)- Consult with transport provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex of MARPOL7378 and the IBC Code
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EPO-TEK 353ND Part A
SECTION 15 REGULATORY INFORMATION
151
1511
1512
152
153
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions Consult the supplier on use European Union None (EINECSELINCS) WGK number Not Applicable
National regulations
USA
TSCA (Toxic Substance Control Act)
SARA 311312 - Hazard Categories
SARA 302 - Extremely Hazardous Substances SARA 313 - Toxic Chemicals
CERCLA (Comprehensive Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990)
CWA (Clean Water Act)
State Right to Know Lists
Proposition 65 (California)
Canada
WHMIS Classification
Canada (DSLINDSL)
Canada Ingredient Disclosure List (CIDL)
Chemical Safety Assessment
Label elements (EU)
All chemicals listed
Acute Health
Listed - None
Contains None
Listed - None
Listed - None
Listed - None
Listed - CAS28064-14-4 NJ PA
Listed - None
Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Sensitizer
Irritation) Listed - DSL
Listed as required
Irritant (Skin Eye) (Skin Sensitizer Irritation)
Label as Harmful Irritant under 199945EC 19072006EC and 127212008EC See Section 2 for full label requirements
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SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 1-16
LEGEND
ACGIH American Conference of Governmental Industrial NA not applicable not available Hygienists
AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and Health
ANSI American National Standards Institute NO not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective equipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TDG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CAS Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R3638 Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms S2 Keep out of the reach of children S23 Do not breathe fumeslvapour S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
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EPO-TEK 353ND Part A
Hazard statement(s) and Precautionary statement(s)
H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
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SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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EPO-TEK 353ND Part B
SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
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Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
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European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
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SECTION 15 REGULATORY INFORMATION
151
1511
1512
152
153
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions Consult the supplier on use European Union None (EINECSELINCS) WGK number Not Applicable
National regulations
USA
TSCA (Toxic Substance Control Act)
SARA 311312 - Hazard Categories
SARA 302 - Extremely Hazardous Substances SARA 313 - Toxic Chemicals
CERCLA (Comprehensive Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990)
CWA (Clean Water Act)
State Right to Know Lists
Proposition 65 (California)
Canada
WHMIS Classification
Canada (DSLINDSL)
Canada Ingredient Disclosure List (CIDL)
Chemical Safety Assessment
Label elements (EU)
All chemicals listed
Acute Health
Listed - None
Contains None
Listed - None
Listed - None
Listed - None
Listed - CAS28064-14-4 NJ PA
Listed - None
Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Sensitizer
Irritation) Listed - DSL
Listed as required
Irritant (Skin Eye) (Skin Sensitizer Irritation)
Label as Harmful Irritant under 199945EC 19072006EC and 127212008EC See Section 2 for full label requirements
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SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 1-16
LEGEND
ACGIH American Conference of Governmental Industrial NA not applicable not available Hygienists
AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and Health
ANSI American National Standards Institute NO not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective equipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TDG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CAS Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R3638 Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms S2 Keep out of the reach of children S23 Do not breathe fumeslvapour S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
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Hazard statement(s) and Precautionary statement(s)
H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
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SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
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Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
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EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
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EPO-TEK 353ND Part A
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 1-16
LEGEND
ACGIH American Conference of Governmental Industrial NA not applicable not available Hygienists
AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and Health
ANSI American National Standards Institute NO not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective equipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TDG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CAS Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R3638 Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms S2 Keep out of the reach of children S23 Do not breathe fumeslvapour S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
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EPO-TEK 353ND Part A
Hazard statement(s) and Precautionary statement(s)
H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
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SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
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Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
Page 69 Expiration Date 30 August 2014
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EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
Revision 1102CLP SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part A
Hazard statement(s) and Precautionary statement(s)
H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
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Revision 1102CLP SAFETY DATA SHEET Date 30 August 2012
SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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EPO-TEK 353ND Part B
SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
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EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
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European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
Revision 1102CLP SAFETY DATA SHEET Date 30 August 2012
SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING
11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available
12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice
13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom
14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585
SECTION 2 HAZARDS IDENTIFICATION
21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322
331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)
GHS Product Identifier (EU)
~i~~~~am(s) Hazard statement(s)
Precautionary statement(s)
222 Label elements
Hazard Symbol
Risk Phrases
Safety Phrases
ltgt~~ Signal word(s) DANGER
H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
According to OirtivA 67A54l1fEEC amp Directive 19991451EC
R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection
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point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
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EPO-TEK 353ND Part B
SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
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Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
Page 69 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
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SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
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EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
~--------~----~--- -~ - ---shy
Revision 1102CLP MATERIAL SAF5TY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
point
23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1
WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material
24 Additional Information None
SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS
EC Classification No 1272200BEC I iHazardous ingredient(s)
I
WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Hazard statement(s)
Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315
H318 H335
Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B
3313711 B H302 H314 H361D
EC Classification No 6754BEEC
ingredient(s) WIW CAS No ECNo REACH
Registration No
Hazard pictogram(s) and Risk (R) Phras(es)
Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41
Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63
33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product
SECTION 4 FIRST AID MEASURES
41 Description of first aid measures
Inhalation
Skin Contact
Eye Contact
Ingestion
42 Most important symptoms and
May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention
Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention
May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention
Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention
Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract
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EPO-TEK 353ND Part B
43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
Page 39 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFIiTY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
Page 49 Expiration Date 30 August 2014
C
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EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
Page 69 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
Page 79 E)(piration Date 30 August 2014
------------------ ~~~~ --------------- --- _--shy~ ---~-
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
Page 89 Expiration Date 30 August 2014
Revision 1102CLP MATERIALSAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
43
effects both acute and delayed
Indication of the immediate medical attention and special treatment needed
Delayed and chronic effects May cause comeal damage
Treat symptomatically
SECTION 5 FIRE-FIGHTING MEASURES
Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF
51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media
52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture
53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices
SECTION 6 ACCIDENTAL RELEASE MEASURES
61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures
62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for
containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice
64 Reference to other sections See Also Section 7 8 13 65 Additional Information None
SECTION 7 HANDLING AND STORAGE
Precautions for safe 71 handling
72 Conditions for safe storage including any incompatibilities
Storage Temperature Storage Life Incompatible materials
73 Specific end use(s)
Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking
Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc
Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals
Consult the supplier
SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION
81 Control parameters
811 Occupational Exposure Limits
Page 39 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFIiTY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
Page 49 Expiration Date 30 August 2014
C
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
Page 69 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
Page 79 E)(piration Date 30 August 2014
------------------ ~~~~ --------------- --- _--shy~ ---~-
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
Page 89 Expiration Date 30 August 2014
Revision 1102CLP MATERIALSAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
Revision 1102CLP MATERIAL SAFIiTY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
SUBSTANCE I
CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)
STEL (mgm3) Note
No occupational exposure limits for this product or listed components have been established
OEls are not available for non-listed components
812 Biological limit value
Limit value type (country of origin) SUBSTANCE CAS No Biological limit
value Note
USA None None None None
813 PNECs and DNELs
I DNEL Oral Inhalation Dermal
Industry - Long Term - Local effects NA NA NA
i Industry - Long Term - Systemic effects NA NA NA
Industry - Short term - Local effects NA NA NA
Industry - Short term Systemic effects NA NA NA
i Professional - Long Term - Local effects NA NA NA
I Professional- Long Term - Systemic effects NA NA NA
I Professional Short term - Local effects NA NA NA
Professional- Short term - Systemic effects NA NA NA
I Consumer - Long Term - Local effects NA NA NA
Consumer Long Term Systemic effects NA NA NA
Consumer - Short term - Local effects NA NA NA
Consumer - Short term - Systemic effects NA NA NA
PNEC
Aquatic Compartment Not available
Terrestrial Compartment Not available
Atmospheric Compartment Not available
822 Personal protection equipment
0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely
Eye Safety glasses
Gloves Wear protective gloves
Body Wear suitable protective clothing and gloves protection
Engineering Controls
Protection
Page 49 Expiration Date 30 August 2014
C
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
Page 69 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
Page 79 E)(piration Date 30 August 2014
------------------ ~~~~ --------------- --- _--shy~ ---~-
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
Page 89 Expiration Date 30 August 2014
Revision 1102CLP MATERIALSAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
C
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPamiddotTEK 353ND Part B
Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)
92 Other information Volatile Organic Chemical (VOC) Content - Not available
SECTION 10 STABILITY AND REACTIVITY
101 Reactivity
102 Chemical stability
103 Possibility of hazardous reactions
104 Conditions to avoid
105 Incompatible materials
106 Hazardous Decomposition Product(s)
Slight
Stable under normal conditions
Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents
Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents
Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors
c-middot SECTION 11 TOXICOLOGICAL INFORMATION
I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1
111 Information on toxicological effects
1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the
gastrOintestinal tract
Irritation May cause bums to skin and eyes
Corrosivity May cause burns to skin and eyes
Repeated dose toxicity Expected to be similar to single exposures
Carcinogenicity No data
EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
Page 69 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
Page 79 E)(piration Date 30 August 2014
------------------ ~~~~ --------------- --- _--shy~ ---~-
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
Page 89 Expiration Date 30 August 2014
Revision 1102CLP MATERIALSAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353NO Part B
Mutagenicity No data
Toxicity for reproduction Suspected of damaging fertility or the unborn child
112 Other information None
SECTION 12 ECOLOGICAL INFORMATION
121 Toxicity Harmful to aquatic life Harmful to algae
122 Persistence and degradability Moderatelypartially biodegradable
123 Bioaccumulative potential Moderatelypartially biodegradable
124 Mobility in soil The product has moderate mobility in soil
125 Results of PBT and vPvB No data assessment
126 Other adverse effects No data
SECTION 13 DISPOSAL CONSIDERATIONS
131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty
132 Additional Information None
SECTION 14 TRANSPORT INFORMATION
Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None
Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267
Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name
organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None
(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions
Transport in bulk according to Annex II of MARPOL7378 and the IBC Code
SECTION 15 REGULATORY INFORMATION
151
1511
Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations
Authorisations andor restrictions on use
Consult the supplier
Page 69 Expiration Date 30 August 2014
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
Page 79 E)(piration Date 30 August 2014
------------------ ~~~~ --------------- --- _--shy~ ---~-
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
Page 89 Expiration Date 30 August 2014
Revision 1102CLP MATERIALSAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
European Union (EINECSELINCS) All chemicals listed
German WGK number 2
1512 National regulations
USA
TSCA (Toxic Substance Control Act) All chemicals listed
SARA 3111312 - Hazard Categories Acute Health
SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None
CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None
CWA (Clean Water Act) Listed - None
State Right to Know Lists Listed as required
Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005
Canada
WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material
Canada (DSUNDSL) Listed - DSL
Canada Ingredient Disclosure List (CIDL) Listed as required
Japan
Deleterious Substance Law Regulated
152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity
153 Label elements (EU)
Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements
Page 79 E)(piration Date 30 August 2014
------------------ ~~~~ --------------- --- _--shy~ ---~-
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
Page 89 Expiration Date 30 August 2014
Revision 1102CLP MATERIALSAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
------------------ ~~~~ --------------- --- _--shy~ ---~-
Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353N D Part B
SECTION 16 OTHER INFORMATION
The following sections contain revisions or new statements 116
LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available
Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and
Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and
Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)
mL milliliter WHMIS Workplace Hazardous Material Information System
References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information
Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point
Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child
Page 89 Expiration Date 30 August 2014
Revision 1102CLP MATERIALSAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY
Revision 1102CLP MATERIALSAFETY DATA SHEET Date 30 August 2012
EPO-TEK 353ND Part B
P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator
Training advice None
Additional Information None
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed
EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY