ENVIRODYNE ENGINEERS '314)434-6960 · First International Building 1201 Elm Street Dallas, TX 75201...
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ENVIRODYNE ENGINEERS 1215"' Lackiard Road, S: Louis, Missouri 63141 '314)434-6960 July 5, 1983 1957 Mr. Dave Peters USE PA, Region VI First International Building 1201 Elm Street Dallas, TX 75201 Dear Mr. Peters: Enclosed is the report of analysis of 9 soil samples for 2,3,7,8-TCDD according to SAS Contract No. 57 6F. The contents of this report are listed on the following page. None of the samples contained detectable levels of 2,3,7,8-TCDD. 'The blank jar sent with the samples was extracted but the extract was spilled during concentration. We will analyze another blank jar if you want to send one. No sample was designated to be spiked. If analysis of a spiked sample is required, please let us know which sample. If you have any questions regarding these data, please contact me. Sincerely, / Earl M. Senior Chemist JLS/csg Enclosures
Transcript of ENVIRODYNE ENGINEERS '314)434-6960 · First International Building 1201 Elm Street Dallas, TX 75201...
ENVIRODYNEENGINEERS
1215"' Lackiard Road,S: Louis, Missouri 63141'314)434-6960
July 5, 19831957
Mr. Dave PetersUSE PA, Region VIFirst International Building1 2 0 1 Elm StreetDallas, TX 75201
Dear Mr. Peters:
Enclosed is the report of analysis of 9 soil samples for 2,3,7,8-TCDDaccording to SAS Contract No. 57 6F. The contents of this report arelisted on the following page.
None of the samples contained detectable levels of 2,3,7,8-TCDD. 'Theblank jar sent with the samples was extracted but the extract wasspilled during concentration. We will analyze another blank jar if youwant to send one. No sample was designated to be spiked. If analysisof a spiked sample is required, please let us know which sample.
If you have any questions regarding these data, please contact me.
Sincerely, /
Earl M.Senior Chemist
JLS/csgEnclosures
LIST OF TABLES AND APPENDICES
Table No.
1 EPA Chain of Custody Record
2 TCDD Data Summary
3 Quality Control Summary
4 Calibration Summary
5 Source List for Standard
Appendix No.
1 Mass Chromatograms of Standards
2 Mass Chromatograms of Samples
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Date /Time Remarks
Distribution: Original Accompanies Shipment: Copy to Coordinator Field Files
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TABLE 2
DATA SLMMARY
Case: 576F
Sample Number tlon
576F-01
576F-02
576F-03
576F-03D
576F-04
576F-05
576F-06
576F-01A
576F-02A
576F-03A
MB
Notes: MB =
J =
S =
A,B,C =
FRN =
D =
D.L. =
N =
r,« assumes 1 0 g sample.
S ^<p C...3^ ^^ .--„ 0• S- ^ts ^ y o o
N
Ex+rac
J
J
J
J
J
J
J
J
J
J
J
Method Bl
Jar Extraction
Soxhiet Extraction
Cleanup Option from
File Refence Number
Dupl Ica+e
Detection
Native 2,
-
Cleanup
A
A
A
A
A
A
A
A
A
A
A
ank
Limit
5,7,8-TCDD
Wet
Weight
(grams)
10.7
10.4
1 0 . 7
10.8
10 .7
10 .7
10.3
10.2
10.0
1 0 . 1
—
Method
Spike
TCDD
(ppb)
-
-
-
-
-
~
(ug/kg)
D.L.
0.40
0 . 1 1
0.07
0.18
0.08
0.08
0.07
0.04
0.06
0.06
0.093
320/322
-
-
1 1 2 - - -
-
-
-
-
-
-
-
Surrogate
Percent
Recovery
102
94
1 0 1
103
99
106
98
97
100
100
520
.
-
-
-
-
-
-
-
-
—
322
-
-
-
-
-
-
-
-
-
2 8
257
.
-
-
-
-
-
-
-
-
-
2 5
332
5196
4535
6530
8964
5935
4612
3770
7179
4620
4650
3913
GC Colu
334
6443
5626
8233
10952
7336
6038
4 7 1 6
9329
5795
5819
4871
inn: SP-
328
5057
4068
6401
9568
5864
4512
3834
6933
4326
4471
3751
2340, 60 m
FRN
Number
6772
6773
6774
6791
6792
6793
6794
6795
6796
6797
6798
TABLE 3
QUALITY CONTROL SUMMARY
Item
Surrogate Recovery
Method Blank
Implicate Samples
No. ofData points Mean ± SD
11 lO^.O3
1 lOO13
2 loe.sis.s0
NOTES: SD = Standard Deviation•^Warning Limits (±2 SD) : 91.8-110%Action Limits (±3 S D ) : 87.2-115%Average recovery for eight method blanks analyzed to dateby the May Method is 89.0±6.0%.
Sample 576F-03 was analyzed in duplicate.
TABLE 4
CALIBRATION SUMMARyB
2,3,7,8-TCDDb Native(ug/kg) RF
Initial Calibrations:
FRN DateSurrogate
RF
6/2 5/8 36/25/83
6/25/83
1 . 05.0
25.2
0.830.77
0.75
664266436644
Daily Verifications:
7/2/837/3/83
1 . 01 . 0
0.800.77
67716790
1 . 0 7
1 .07
1 . 0 8
0.991 . 1 0
r--C\l
CO
(M
00
NOTES: aThe standard concentrations are corrected using7.9±0.4 ug/ml for the Radian Standard (Lot 20603,12.5±1.2 ug/ml).
-Assunes 10 g sample.
TABLE 5
SOURCE LIST FOR STANDARDS
Material Source
2,3,7,8-TCDD Radian
"^C^S^e-TCDD CambridgeIsotopeLaboratories
3'7C'L^-2 ,3 ,7 ,Q-'TCDD CambridgeIsotopeLaboratories
Description Received
Repository No. E-000206 1/83Standard Code 2060312 .5±1 .2 ug/ml in isooctane
Lot AWN-1203-65 4/83Standard Code R0020150±5 ug/ml in isooctane
Lot SSY-6-123 5/8350±5 ug/ml in anisole
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APPENDIX 1
MASS CHROMATOGRAMS OF STANDARDS
BLO TCDD STD 3 ULC.-25-83 HRM 6<45
6642
1 1 2
145
1 6 1
329
375
493
1627
0
1^
00(M00
18 19 20 21
?ER TRBLE ENTRIES: FRN 6642
Ti me
1 9 . 41 9 . 419.519.519 .419 .4
ILCULflTE %
MASS
257.0320.0322.032B.0332.0334.0
ON ENTRY «:^Efl TABLE ENTRIESi FRN
ntry Time
1 9 . 41 9 . 419 .519 .51 9 . 419 .4
UCULRTE %
Mftftft
257.0320.0322.0328.0332.0334.0
ON ENTRY •l
Rrea
563.1332.1572.3786.39 1 6 .4059.
6642
flre«
563.1332.1572.3706.3916.4659.
35.664.7
100.0241.0249.3309. 1
1 1 . 627.432.376.080.6
100.0
.0 TCDD STD 3 ULt-25-83 HRM 6:45
6642
m
00c^00
ie 19 2(3 21
0»~" ^ f* r~" r * t ' tf^JLO<-J^*7
I'lED TCDD STD 3 UL1-.-25-83 HRM
66.43
239 -t= 2087.T
606
646
CM
^
CO
OsJ
0
0
18T1 9
T20
:! TRBLE ENTRIES; FRN 6643
•y T 1 me Mas E
1 9 . 4 257.01 9 . 4 320.01 9 . 4 322.01 9 . 4 328.01 9 . 4 332.01 9 . 4 334.0
:ULRTE '/. ON ENTRY «:^ TRBLE ENTRIES: FRN
Mass'y T ime
1 9 . 41 9 . 41 9 . 41 9 . 41 9 . 41 9 . 4
:ULRTE \
257.0320.0322.0326.0332.0334.0
ON ENTRY • ;
flrea
20&7.5428.7196.3532.3656.4412.
6643
flr»*
2007.542S.7 1 9 0 .3532.3658.4 4 1 2 .
2 7 . 975.5
100.049. 15 0 . 96 1 . 4
45.5123.01 6 3 . 0B0.06 2 . 9
190.0
|HI TCDD STD 3 UL|r;-25-83 HRM 8:00
£.6.44
1727
4565
5746
657
724
934
4194
26
ft T f l B L E E N T R I E S : F R N 6644
ry T i nri € MASS
1 9 . 3 257.e1 9 . 3 320.01 9 . 3 322.01 9 . 2 326.01 9 . 2 332.01 9 . 2 334.0
:ULflTE '/. ON ENTRY • :"-< TRBLE ENTRIES: FRN
MASS'y T i tii e
1 9 . 31 9 . 319 .319.219 .21 9 . 2
;ULRTE '/.
257.0320.0322.0328.0332.0334.0
ON ENTRY
fir-ca
16519.44146 .55912.
6285.6005.733&.
6644
RFC*
1 6 5 1 9 .4 4 1 4 6 .55912 .
6285.6003.7336.
2 9 . 579.0
100.01 1 . 21 0 . 71 3 . 1
225.26 0 1 . 8762. 185.78 1 . 8
100.0
TCDD LOU STD 3UL7-2-83 HRM 7-10-83
6771
144
179
370
470334.0334.
1571
"00
(M
..Q
"0
18 19 26
RRER TRBLE ENTRIES; FRN
Entry T i m e Mass
1 9 . 3 257.01 9 . 3 320.01 9 . 3 322.01 9 . 3 328.01 9 . 4 332.01 9 . 3 334.0
CRLCULRTE >. ON ENTRY #:RRER TRBLE ENTRIES: FRN
^ntry T i m e Mass
257.0320.0322.0328.0332.0334,0
ON ENTRY » ;
1 9 . 31 9 . 31 9 . 319.319.419.3
C R L C U L R T E •/.
6771
Rrca
6 6 7 .1387.1722.3849.4338.5355.
6771
Rr-ea
6 6 7 .1387.1722.3849.4338.5355.
38.780.5
100.0223.4251.9310. 9
1 2 . 525.932.27 1 . 98 1 . 0
100.0
I T C D D L01») STD 3UL••-2-83 H R M 7-10-83
6.771
18 19 20
EEBITCDD LOU LEVEL STD 3UL17-3-83 8:27 PLC
6790
198
262
288
61 1528.0328.0
657
803
2774
flRER TRBLE ENTRIES: FRN 6798
[nt ry T i m e Mass
;RLCULRTE
1 9 . 11 9 ,1 9 ,1 9 ,1 9 ,1 9 ,TE •/.
,2,2,2,2,2
257.320.322.328.332.334.0
ON ENTRY »
Q0
0
0
0
Rr-ea
610.1968.2657.6996.6608.8502.
23.074. 1
100.0
263.3248.7320.0
^RER TRELE ENTRIES: FRH 6790
-;ntr^ T i m e Mass Rrea
191919191919
257 0320 0322 0328 0332 0334 0
610196826576 9 9 666088502
7 223 231 382 377 7
100 0
/./o
081 09 T 0t'T 03 T IT 0/3 89 Qt' 03
0
0r\3CO
^-J
861
Old Z3S8 £8-£-zBHI!I^n£ ais "i3A3n non aii3iKEEI21
APPENDIX 2
MASS CHROMATOGRAMS OF SAMPLES
6772•8MSMl957-576F;01 3UL17-2-83 H R M 8:00
425
467332.0332.0
596334.0334.0
1636
0^
=^\
CO
CM
'00
IS 19 20
RRER TRBLE ENTRIES: FRH
Entry T i me- Mass
1 9 . 2 257.81 9 . 3 320.01 9 . 3 322.01 9 . 4 328.01 9 . 3 332.01 9 . 3 334.0
•^RER TRBLE ENTRIES; FRH
6772
Rr-e-a
1 4 5 .200.
417.5057.5196.6443,
6772
34.74 7 . 9
100.01212.51245.71544.7
[nt r-y Ti me
19.219.319.319.419.319.3
Mass
257.0320,0322.0328.0332.0334.0
Rrea
145.200.
417.5057.5 1 9 6 .6443.
2 . 23. 16 . 5
78.58 0 . 6
100.0
1957-576F;02 3UL7-2-83 HRM 8:30
6773
146
375328.9328.0
411
509334.0334.0
1421
18 19 20
RRER TRBLE ENTRIES; FRN 6773
Entry T i m e Mass
1 9 . 3 320.01 9 . 3 322.01 9 . 4 328.01 9 . 4 332.01 9 . 3 334.0
CRLCULRTE '/. ON ENTRY #:RRER TRBLE ENTRIES: FRN
Rrea
75,75,
4068,4535,5626,
6773
9 9 . 5100.0
5390.06008.87454.1
Ent ry T i me
19.319.319.419.419.3
C R L C U L R T E •/.
Mass
320.0322.0328.0332.0334.0
ON ENTRY » !
Rrea
75.75.
4068.4535,5626.
1.31.3
72.380.6
100.0
|1957-576F:03 3UL17-2-83 HRM 9 : 0 5
R R E R T f l B L E E N T R I E S : F R N 6774
Entr~!y1 T i m e Mass R r c a
19.219.219. 319.319.3
320.0322.0328.0332.0334.0
44,88.
6481.6530.8233.
.51. 1
77.779.3
1 0 0 . 0
C R L C U L R T E •/; ON E N T R Y #!
11957-576F; 03 DUP 3UL-3-83 8:57 PLC
6791
296
124
742
773
949334.03 3 4 "
2736
IS 19 28 21
RRER TRBLE ENTRIES: FRN 6791
Entr^ Time Mass Rre-a
19.219.219.219. 119. 1
328.0332.0334.0322.0320.0
9568.8964.
10952.286.178.
87.481.9
100.02.61.6
1957-576F: 04 3UL7-3-83 9 : 2 6 PLC
6792
500
549;32.8t32.0
684
1898
18 19 20
RREfl TflBLE ENTRIES: FRN 6792
Entry T i r r ie Mass Rrea.
19.219.219.219. 119. 1
328.0332.0334.0322.0320.0
5864.5935.7336.
95.42.
7 9 . 98 0 . 9
100.01 . 3. 6
;RLCULRTE '/. ON ENTRY #!
1957-576F: 05 3UL7-3-83 9 : 5 2 PLC
6793
406
434
548334.0334.0
(M
0
1545 ~0
18 19 20
R R E R T f l B L E E N T R I E S : F R N 6793
E n t r i y i T i m e Mass Rrea
19.219.219.219. 119. 1
C R L C U L R T E •/.
328.0332.0334.0322.0320.0
4512.4612.603S.
55,54,
74.77 6 . 4
100.0. 9. 9
i?ER Tf lBLE E N T R I E S : F R N 6794
-it r - iy i T - i m e Mass Rre-a
19.219.219.219. 119. 1
328.0332.0334.0322.0320.0
3834.3770,4 7 1 6 .
37.38.
81.379.9
100. 0.8.8
•Ef t T R B L E E N T R I E S ; FRN 6795
t r y T i m e Mass Rrea
1 9 . 21 9 . 21 9 . 21 9 . 01 9 . 0
328.0332.0334.0322.0320.0
6933.7179.9329.
40.50.
74.377.0
100.0
. 4
. 5
gnaj[ai957-576F: 02fl 3UL B33 6796BHBB7-3-83 1 1 : 1 3 PLC
HV^
BEt S- . BEK™BB3&1 ————^—^—^^-^—^_^-^—^-^-^^-^——^~—-^—^_____i ' . ^ '~~
r^^ EBi D__384 / ^ S ~
K^i / JfflKEaan435 /N ________
^ hK / Y Bf r an '
__ 533 ' ' ' " " . . . . ^ . . . . • • • • • • • • • • • • • • - ——————————————————^
EjSB^ / - -.. ^Bfcfafc^-i C\J
B^H5! / " - ^ 0
1464 / ^ ^ 0
"" \—— _____________1 ^~-_________18 19 2£i
RRER TRBLE ENTRIES; FRN 6796
Entr-^ T i m e Mass flrea >.
1 19.2 328.0 4326. 74.72 19.2 332.0 4620. 79.73 19.2 334.0 5795. 100.04 19.1 322.0 33. .65 19.1 320.0 41. .7
0^€<^T93
0^10^^93
1957-576F: 03fl 3UL7-3-83 1 1 : 3 9 PLC
397328.0328.0 fl= 4471 .T
439
538334.0334.0
fl= 5819.T
150S
1 8 1 9
^RER TflBLE ENTRIES: FRN 6797
'Lntr-y T i m e Mass Rrca
19.219.219.219. 119. 1
328.0332.0334.0322.0320.0
4471.4656.5819.
50.27.
76.879.9
100.0
.9
.5
1957-576F; METHOD BLflNK 3UL7-3-83 12 :05 PLC
343
379
470
1310
18-T19
RREfl TflBLE ENTRIES: FRN 6796
Entr^" T i m e Mass firea
19.219.219.219. 119.0
328.0332.0334.0322.0320.0
3751.3913.4871.
54.50.
77.080.3
100.0
1. 11.0
