Engineering Sd
Click here to load reader
-
Upload
cristian-roa -
Category
Documents
-
view
953 -
download
19
Transcript of Engineering Sd
-
Elements of C
hemical R
eaction Engineering
file:///H:/start.htm
[05/12/2011 16:54:00]
Elem
ents ofC
hemical
Reaction
Engineering
Third E
dition
By H
. Scott Fogler U
niversity ofM
ichigan A
nn Arbor,
Michigan
Welcom
e!
Welcom
e to the CD
-RO
M that accom
panies the Third Edition ofElem
ents of Chem
ical Reaction Engineering by H. Scott Fogler.
Follow the links (below
) to learn how to get the m
ost out of this CD
-R
OM
.
Introduction
B
egin: Chapter 1
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Elements of C
hemical R
eaction Engineering
file:///H:/start.htm
[05/12/2011 16:54:00]
APPEN
DIC
ES
-
Introduction
file:///H:/htm
lmain/intro.htm
[05/12/2011 16:54:01]
Welcom
eN
avigationC
omponents
Usage
Welcom
e
This CD
-RO
M is intended to be used as a learning resource; the m
aterial on this CD
-RO
Msupports the chem
ical reaction engineering concepts covered in the text. You are encouraged
to use the CD
-RO
M to supplem
ent and expand upon your own studies. W
e are certain thatyou w
ill find the extra knowledge you gain w
ill be worthy of the tim
e you invest to obtain it.
Warnings!
Macintosh U
sersThe m
ajority of the files on the CD
-RO
M are H
TML files. G
reat carew
as taken in trying to insure that these files would w
ork on both PCs
and Macs. H
owever, m
any of the non-HTM
L files on the CD
-RO
M(i.e., Polym
ath, all of the Interactive Com
puter Modules, and m
ost ofthe plug-ins included on the C
D) are W
indows/D
OS-based program
s,for w
hich there are (unfortunately) no Macintosh equivalents. Y
oum
ay still use these files, if you have a PC em
ulator program on your
Mac, such as V
irtual PC.
ICM
sSom
e users have experienced problems, trying to run the Interactive C
omputer M
odulesdirectly from
the ICM
directory on the CD
-RO
M. If you have trouble w
ith being able to runthe Interactive C
omputer M
odules from the C
D-R
OM
, then try installing them on your hard
drive.
Hidden Files
To clear up some of the confusion about w
hich files to use in certain directories (e.g.,Polym
at4 and ICM
s), some files and folders w
ere hidden. You m
ay find it easier to navigatethe C
D-R
OM
, if you make certain that you are N
OT view
ing hidden files.
Recom
mended Softw
are
Before you begin, w
e advise you to download or install the follow
ing software program
s andplug-ins on your com
puter, if they are not already present on your system:
-
Introduction
file:///H:/htm
lmain/intro.htm
[05/12/2011 16:54:01]
Adobe A
crobat Reader and Plug-in
The Appendices (and certain other files on the C
D-R
OM
) are in PDF
format. Y
ou must have A
dobe Acrobat R
eader installed to access thesefiles. Y
ou will also need the A
dobe Acrobat R
eader Plug-in to readthese files from
your web brow
ser.
Note: The PC
version of Adobe A
crobat Reader 3.02 has been
included on the CD
-RO
M in a directory called Softw
are\Adobe. If
you run the ar302.exe program, it w
ill install the reader software
and the browser plug-in on your com
puter.
Apple Q
uickTime Plug-in
There are a few Q
uickTime m
ovies on the CD
-RO
M, w
hich will require
the QuickTim
e Plug-in to view them
.
Note: Q
uickTime 3.0 (for PC
s) has been included on the CD
-RO
Min a directory called Softw
are\Quick. If you run the quick3.exe
program, it w
ill install the movie view
er and the plug-in on yourcom
puter and in your browser, respectively.
WinZip (O
ptional)
Some of the Polym
ath files for the Living E
xample Problem
s arearchived as Zip files. Y
ou may need an unzip utility, such as W
inZip toaccess them
. See the Polymath section of the C
D-R
OM
for more
information.
MA
TLAB
(Optional)
In addition to Polymath, you m
ay use MA
TLAB
to access the Living
Exam
ple Problems. See the M
ATLA
B section of the C
D-R
OM
form
ore information.
IMPO
RT
AN
T!
Different brow
sers and font sizes may affect the alignm
ent and general appearance of theH
TML content of the C
D-R
OM
. To ensure that items are aligning properly, you m
ay need toadjust your brow
ser's font size.
The HTM
L content of this CD
-RO
M is also available at the U
niversity of Michigan's
Chem
ical Reaction Engineering W
ebsite:
-
Introduction
file:///H:/htm
lmain/intro.htm
[05/12/2011 16:54:01]
http://ww
w.engin.um
ich.edu/~cre
Next Step
Once you have dow
nloaded and/or installed this software, you should proceed to the section
on Navigation, to learn how
to get around this CD
.
The Com
ponents section will give you inform
ation on the various "modules" that are
available on this CD
.
The Usage section w
ill give you information on the best w
ay to integrate the information on
this CD
with the inform
ation in your book.
Welcom
e Navigation C
omponents U
sage
B
egin: Chapter 1
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Elements of C
hemical R
eaction Engineering, Credits
file:///H:/htm
lmain/credits.htm
[05/12/2011 16:54:02]
The following people have conspired to bring you this C
D-R
OM
:
The U
niversity of Michigan T
eam
H. Scott Fogler, A
uthorD
ieter Andrew
Schweiss, M
edia Project Manager
Ellyne B
uckingham, A
rtist, ToPS
Scott Conaw
ay, Wetlands
Susan Fugett, MA
TL
AB
Exam
plesA
nuj Hasija, H
TM
L D
esignerLisa Ingall, T
oPSB
rad Lintner, ToPS
Timothy M
ashue, Reactive D
istillationJam
es Piana, ICM
sSusan Stagg, C
obra Problem A
uthorG
avin Sy, Cobra Problem
(ToPS = Thoughts on Problem Solving)
Special thanks to:
Nicholas A
bu-Absi
John Bell
Michael C
utlip, Polymath
Sean Connors
Anurag P. M
airalProfessor Susan M
ontgomery
Mordechai Shacham
, Polymath
Probjot SinghIbrahim
"Abe" Sendajarevic
Mayur V
alanju
The T
eam at Prentice-H
all PTR
:
Bernard G
oodwin, E
xecutive Editor
Diane Spina, A
ssistant to the Executive E
ditorSophie Papanikolaou, D
irector of ProductionLisa Iarkow
ski, Manager, Production
Yvette R
aven, Media Project M
anagerTalism
an Desktop Productions, D
eveloperScholar's N
et Academ
ic Multim
edia, Design/Program
ming
-
Elements of C
hemical R
eaction Engineering, Credits
file:///H:/htm
lmain/credits.htm
[05/12/2011 16:54:02]
Additional C
redits
Mem
brane Reactors
Parts of this site was originally presented as an O
pen-Ended Problem in the W
inter 1997 Chem
icalR
eaction Engineering Class at the U
niversity of Michigan. The students w
ho developed this module w
ereK
im D
illon, Nam
rita Kum
ar, Am
y Miles, and Lynn Zw
ica.
The module w
as further expanded and improved by Ellyne B
uckingham, D
ieter Andrew
Schweiss, A
nuragM
airal, and H. Scott Fogler for use w
ith the Chem
ical Reaction Engineering Web Site and C
D-RO
M.
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Easter Egg
file:///H:/htm
lmain/easter.htm
[05/12/2011 16:54:02]
Easter E
ggThis is the only easter egg that I know
of on the CD
-RO
M (but there m
ay be more). M
y name is D
ieter Andrew
Schweiss, and after devoting a year of m
y life to this project, I had to put something hidden on this thing!
I've really enjoyed working w
ith Scott, the University of M
ichigan Team, and the people from
Prentice-Hall on this
CD
-RO
M project. It has helped m
e fulfill a long-time dream
of contributing to the accumulated know
ledge that is thefield of C
hemical Engineering. (That, and the fact that nothing quite like this C
D had ever been done before in C
hE!)
Anyw
ays, good luck with your classes. B
e sure to use the resources available to you on this CD
, especially the LectureN
otes and the worked exam
ple problems. They'll really com
e in handy. (Trust me, I know
!)
I like what this sym
bol represents:
life is a balance between order and chaos, yet
pure order still retains some elem
ent of chaos and pure chaos retains som
e element of order
(kind of like my desk...)
Special Recognition
Professor H. Scott Fogler w
ould like to extend a special thanks to Dieter A
ndrew Schw
eiss, without w
hom the
Elements of C
hemical Reaction Engineering C
D-RO
M w
ould never have been possible. Dieter w
orked countless daysand nights to bring this project to com
pletion, coordinating his efforts with both the U
niversity of Michigan Team
andthe Prentice-H
all Team. Thank you, D
ieter!
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Chapter O
ne
file:///H:/htm
l/01chap/frames.htm
[05/12/2011 16:54:04]
CH
APT
ER
1
1
Mole B
alancesA
fter completing C
hapter 1 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Define the rate of chem
icalreaction.
Apply the m
ole balanceequations to a batchreactor, C
STR, PFR
, andPB
R.
Describe tw
o industrialreaction engineeringsystem
s.
Describe photos of real
reactors.
Describe how
to surf theC
D-R
OM
attached with
this text.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
APPEN
DIC
ES
-
Legal Information
file:///H:/htm
lmain/legal.htm
[05/12/2011 16:54:04]
About Prentice H
all
PREN
TICE
HA
LL CD
-RO
M/W
EB SITE: LEG
AL D
ISCLA
IMER
Unless otherw
ise indicated, this CD
-RO
M/W
eb Site and its contents are the property of P
rentice-Hall, Inc. ("P
rentice Hall") and are
protected, without lim
itation, pursuant to U.S
. and foreign copyright and trademark law
s.
PR
EN
TICE
HA
LL MA
KE
S N
O R
EP
RE
SE
NTA
TION
S O
R W
AR
RA
NTIE
S W
ITH R
ES
PE
CT TO
THIS
CD
-RO
M/W
EB
SITE
OR
ITSC
ON
TEN
TS, W
HIC
H A
RE
PR
OV
IDE
D FO
R U
SE
"AS
IS." P
RE
NTIC
E H
ALL D
ISC
LAIM
S A
LL WA
RR
AN
TIES
, EX
PR
ES
S O
RIM
PLIE
D, IN
CLU
DIN
G W
ITHO
UT LIM
ITATIO
N TH
E IM
PLIE
D W
AR
RA
NTIE
S O
F M
ER
CH
AN
TAB
ILITY A
ND
FITNE
SS
FOR
AP
AR
TICU
LAR
PU
RP
OS
E, W
ITH R
ES
PE
CT TO
THE
CD
-RO
M/W
EB
SITE
AN
D A
NY
CD
-RO
M/W
EB
SITE
WITH
WH
ICH
IT ISLIN
KE
D. P
RE
NTIC
E H
ALL A
LSO
MA
KE
S N
O R
EP
RE
SE
NTA
TION
S O
R W
AR
RA
NTIE
S A
S TO
WH
ETH
ER
THE
INFO
RM
ATIO
NA
CC
ES
SIB
LE V
IA TH
IS C
D-R
OM
/WE
B S
ITE, O
R A
NY
CD
-RO
M/W
EB
SITE
WITH
WH
ICH
IT IS LIN
KE
D, IS
AC
CU
RA
TE,
CO
MP
LETE
, OR
CU
RR
EN
T. Price inform
ation is subject to change without notice.
In no event shall Prentice H
all or its employees, agents, suppliers, or contractors be liable for any dam
ages of any kind orcharacter, including w
ithout limitation any com
pensatory, incidental, direct, indirect, special, punitive, or consequential damages,
loss of use, loss of data, loss of income or profit, loss of or dam
age to property, claims of third parties, or other losses of any kind
or character, even if Prentice H
all has been advised of the possibility of such damages or losses, arising out of or in connection
with the use of this C
D-R
OM
/WE
B S
ite or any CD
-RO
M/W
EB
Site w
ith which it is linked.
Portions of this S
ite (such as "chat rooms" or "bulletin boards") m
ay provide users an opportunity to post and exchange information,
ideas and opinions (the "Postings"). B
E A
DV
ISE
D TH
AT P
RE
NTIC
E H
ALL D
OE
S N
OT S
CR
EE
N, E
DIT, O
R R
EV
IEW
PO
STIN
GS
PR
IOR
TO TH
EIR
AP
PE
AR
AN
CE
ON
THIS
SITE
, and Postings do not necessarily reflect the view
s of Prentice H
all. In no eventshall P
rentice Hall assum
e or have any responsibility or liability for the Postings or for any claim
s, damages or losses resulting from
their use and/or appearance on this Site. Y
ou hereby represent and warrant that you have all necessary rights in and to all
Postings you provide and all inform
ation they contain and that such Postings shall not infringe any proprietary or other rights of third
parties or contain any libelous, tortious, or otherwise unlaw
ful information. Y
ou hereby authorize Prentice H
all to use and/orauthorize others to use your P
ostings in any manner, form
at or medium
that Prentice H
all sees fit.
Additional G
uidelines for CD
-RO
M/W
ebmasters on Linking/R
epurposing/Permissioning
We at S
imon &
Schuster H
igher Education are very active participants in the internet culture, and w
e appreciate and support it'sopenness. W
e strive to produce high quality, but hassle free content--minim
izing access problems for professors and students w
house our textbook products. N
ote that we can only continue in this hassle-free environm
ent if our copyrights are respected. In short,please don't m
istake our lack of password protection for leniency--w
e take copyright violations very seriously.
Repurposing our S
ource Code
All of the source code on this site is copyrighted, w
hether html, javascript, or otherw
ise. Please read our for details about w
hatcopyright m
eans. If you would like to use our source code for any reason, please send a request to C
D-
RO
M/W
ebmaster@
prenhall.com
Linking
Establishing standard hypertext links to our C
ompanion C
D-R
OM
/Websites is a w
elcome extension of internet culture, and w
einvite adopting faculty, or students w
ho have purchased our texts, to establish links to our Com
panion CD
-RO
M/W
ebsites. We
require no formal notice that you've linked to our site, although w
e do appreciate standard notifications be sent to CD
-R
OM
/Webm
when you've done so. This w
ill allow us to notify you in the event that the U
RL for a site changes,
or if we rem
ove content from our site.
Note how
ever that the current practice known as "fram
ing" where a link is established in such a w
ay as to display our content insom
e form other than it is displayed in full view
by our server, or otherwise displaying our content only partially, or w
ithout ourcopyright notice, is definitely uninvited and unw
elcome. N
ote that we are very w
illing participants in internet culture (and we provide
most of our content to the internet com
munity free of charge), but w
e do take copyright very seriously.
Repurposing C
omponents of our C
D-R
OM
/Website
-
Legal Information
file:///H:/htm
lmain/legal.htm
[05/12/2011 16:54:04]
P
rentice-Hall, Inc.
A S
imon &
Schuster C
ompany
Upper S
addle River, N
ew Jersey 07458
Rem
oving pieces of our Com
panion CD
-RO
M/W
ebsites and incorporating them into class hom
epages always requires form
alperm
ission in writing. W
e are very cooperative in arranging permission for use of our com
ponents by faculty who have adopted our
book. Note that the creation of a class hom
epage linked to Com
panion CD
-RO
M/W
ebsites using Syllabus B
uilder does not requireperm
ission, if you are using our textbook for your course.
Please read our legal statem
ent for details.
To contact our permissions departm
ent, please fax a request to A
ttention: CD
-RO
M/W
ebsite Perm
issions Dept
fax 201-236-3290
Note that your fax m
ust include a printed copy of the CD
-RO
M/W
ebpages that contain the material you'd like to re-use, w
ith aclear indication of the pieces you desire. Y
ou must also include a short w
ritten description of your intended use for thesecom
ponents. This MU
ST include:
the intended audience, an estimate of how
many persons w
ill view the content you've requested, and the dates that you
expect the material to be available to your audience.
a description of access control methods (is a passw
ord required to access the site)a description of the cost to access your siteif possible, an exam
ple of how you w
ould display our content and copyright notice
* if possible, an example of how
you would display our content and copyright notice
Prentice-H
all, Inc. AS
imon &
Schuster C
ompany U
pper Saddle R
iver, New
Jersey 07458
-
Chapter Tw
o
file:///H:/htm
l/02chap/frames.htm
[05/12/2011 16:54:06]
CH
APT
ER
2
2
Conversion and R
eactor SizingA
fter completing C
hapter 2 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Define conversion and
space time.
Write the m
ole balances interm
s of conversion for abatch reactor, C
STR, PFR
,and PB
R.
Size reactors either alone orin series once given the rateof reaction, -rA , as afunction of conversion, X.
Write relationship betw
eenthe relative rates ofreaction.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
APPEN
DIC
ES
-
Chapter Three
file:///H:/htm
l/03chap/frames.htm
[05/12/2011 16:54:08]
CH
APT
ER
3
3
Rate L
aw and Stoichiom
etryA
fter completing C
hapter 3 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Write a rate law
and definereaction order andactivation energy.
Set up a stoichiometric
table for both batch andflow
systems and express
concentration as a functionor conversion.
Calculate the equilibrium
conversion for both gas andliquid phase reactions.
Write the com
bined mole
balance and rate law in
measures other than
conversion.Set up a stoichiom
etrictable for reactions w
ithphase change.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
APPEN
DIC
ES
-
Chapter Four
file:///H:/htm
l/04chap/frames.htm
[05/12/2011 16:54:10]
CH
APT
ER
4
4
Isothermal R
eactor Design
After com
pleting Chapter 4 of
the text and associated CD
RO
Mm
aterial the reader will be able to:
Describe the algorithm
thatallow
s the reader to solvechem
ical reactionengineering problem
sthrough logic rather thanm
emorization.
Size batch reactors,sem
ibatch reactors, CSTR
s,PFR
s, and PBR
s forisotherm
al operation giventhe rate law
and feedconditions.
Discuss solutions to
problems taken from
theC
alifornia ProfessionalEngineers R
egistrationExam
ination.
Account for the effects of
pressure drop onconversion in packed bedtubular reactors and inpacked bed sphericalreactors.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
-
Chapter Four
file:///H:/htm
l/04chap/frames.htm
[05/12/2011 16:54:10]
APPEN
DIC
ES
-
Chapter Five
file:///H:/htm
l/05chap/frames.htm
[05/12/2011 16:54:12]
CH
APT
ER
5
5
Collection and A
nalysis of Rate D
ataA
fter completing C
hapter 5 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Determ
ine the reactionorder and specific reactionrate from
experimental data
obtained from either batch
or flow reactors.
Describe how
to use equal-area differentiation,polynom
ial fitting,num
erical differenceform
ulas and regression toanalyze experim
ental datato determ
ine the rate law.
Describe how
the methods
of half lives, and of initialrate, are used to analyzerate data.
Describe tw
o or more types
of laboratory reactors usedto obtain rate law
dataalong w
ith their advantagesand disadvantages.
Describe how
to plan anexperim
ent.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
-
Chapter Five
file:///H:/htm
l/05chap/frames.htm
[05/12/2011 16:54:12]
APPEN
DIC
ES
-
Chapter Six
file:///H:/htm
l/06chap/frames.htm
[05/12/2011 16:54:14]
CH
APT
ER
6
6
Multiple R
eactionsA
fter completing C
hapter 6 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Define different types of
selectively and yield.
Choose a reaction system
that would m
aximize the
selectivity of the desiredproduct given the rate law
sfor all the reactionsoccurring in the system
.
Describe the algorithm
usedto design reactors w
ithm
ultiple reactions.
Size reactors to maxim
izethe selectivity and todeterm
ine the speciesconcentrations in a batchreactor, sem
ibatch reactor,C
STR, PFR
, and PBR
,system
s.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
APPEN
DIC
ES
-
Chapter Seven
file:///H:/htm
l/07chap/frames.htm
[05/12/2011 16:54:15]
CH
APT
ER
7
7
Nonelem
entary Reaction K
ineticsA
fter completing C
hapter 7 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Discuss the pseudo-steady-
state-hypothesis andexplain how
it can be usedto solve reactionengineering problem
s.
Discuss different types of
polymerization reactions
and rate laws.
Describe M
ichealis-Menton
enzyme kinetics and
enzyme inhibition.
Write m
aterial balances oncells, substrates, andproducts in bioreactors.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
APPEN
DIC
ES
-
Chapter Eight
file:///H:/htm
l/08chap/frames.htm
[05/12/2011 16:54:17]
CH
APT
ER
8
8
Steady-State Nonisotherm
al Reactor D
esignA
fter completing C
hapter 8 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Describe the algorithm
forC
STRs, PFR
s, and PBR
sthat are not operatedisotherm
ally.
Size adiabatic andnonadiabatic C
STRs, PFR
s,and PB
Rs.
Use reactor staging to
obtain high conversions forhighly exotherm
icreversible reactions.
Carry out an analysis to
determine the M
ultipleSteady States (M
SS) in aC
STR along w
ith theignition and extinctiontem
peratures.
Analyze m
ultiple reactionscarried out in C
STRs,
PFRs, and PB
Rs w
hich arenot operated isotherm
ally inorder to determ
ine theconcentrations andtem
perature as a functionof position (PFR
/PBR
) andoperating variables.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
-
Chapter Eight
file:///H:/htm
l/08chap/frames.htm
[05/12/2011 16:54:17]
Legal Statem
ent
APPEN
DIC
ES
-
Chapter N
ine
file:///H:/htm
l/09chap/frames.htm
[05/12/2011 16:54:19]
CH
APT
ER
9
9
Unsteady-State N
onisothermal R
eactor Design
After com
pleting Chapter 9 of
the text and associated CD
-RO
Mm
aterial the reader will be able to:
Analyze batch reactors and
semibatch not operated
isothermally.
Analyze the start up of
nonisothermal C
STRs.
Analyze perturbations in
temperature and presence
for CSTR
s being operatedat steady state and describeunder w
hat conditions thereactors can be unsafe(safety).
Describe the effects of
adding a controller to aC
STR.
Analyze m
ultiple reactionsin batch and sem
ibatchreactors not operatedisotherm
ally.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
-
Chapter N
ine
file:///H:/htm
l/09chap/frames.htm
[05/12/2011 16:54:19]
APPEN
DIC
ES
-
Chapter Ten
file:///H:/htm
l/10chap/frames.htm
[05/12/2011 16:54:22]
CH
APT
ER
10
10
Catalysis and C
atalytic Reactors
After com
pleting Chapter 10 of
the text and associated CD
-RO
Mm
aterial the reader will be able to:
Define a catalyst, a
catalytic mechanism
and arate lim
it step.
Describe the steps in a
catalytic mechanism
andhow
one goes aboutderiving a rate law
and am
echanism and rate
limiting step consistent w
iththe experim
ental data.
Size isothermal reactors for
reactions with Langm
uir-H
inschelwood kinetics.
Discuss the different types
of catalyst deactivation andthe reactor types anddescribe schem
es that canhelp offset the deactivation.
Analyze catalyst decay and
conversion for CSTR
s andPFR
s with tem
perature-tim
e trajectories, moving
bed reactors, and straightthrough transport reactors.
Describe the steps in
Chem
ical Vapor
Deposition(C
VD
).
Analyze m
oving bedreactors that are notoperated isotherm
ally.
B
EG
IN
-
Chapter Ten
file:///H:/htm
l/10chap/frames.htm
[05/12/2011 16:54:22]
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
APPEN
DIC
ES
-
Chapter Eleven
file:///H:/htm
l/11chap/frames.htm
[05/12/2011 16:54:24]
CH
APT
ER
11
11
External D
iffusion Effects on H
eterogeneousR
eactionsA
fter completing C
hapter 11 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Define the m
ass transfercoefficient, explain w
hat itis function of and how
it ism
easured or calculated.
Analyze PB
Rs in w
hichm
ass transfer limits the rate
of reaction.
Discuss how
one goes forma region m
ass transferlim
itation to reactionlim
itation.
Describe how
catalystm
onoliths and wire gauze
reactors are analyzed.
Apply the shrinking core
model to analyze catalyst
regeneration.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
-
Chapter Eleven
file:///H:/htm
l/11chap/frames.htm
[05/12/2011 16:54:24]
APPEN
DIC
ES
-
Chapter Tw
elve
file:///H:/htm
l/12chap/frames.htm
[05/12/2011 16:54:26]
CH
APT
ER
12
12
Diffusion and R
eaction in Porous Catalysts
After com
pleting Chapter 12 of
the text and associated CD
-RO
Mm
aterial the reader will be able to:
Define the Thiele m
odulesand the effectiveness factor.
Describe the regions of
reaction limitations and
internal diffusionlim
itations and theconditions that affect them
.
Determ
ine which resistance
is controlling in a slurryreactor.
Analyze trickle bed
reactors.
Analyze fluidized bed
reactors.
Describe the operation of a
CV
D B
oat Reactor.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
-
Chapter Tw
elve
file:///H:/htm
l/12chap/frames.htm
[05/12/2011 16:54:26]
APPEN
DIC
ES
-
Chapter Thirteen
file:///H:/htm
l/13chap/frames.htm
[05/12/2011 16:54:28]
CH
APT
ER
13
13
Distributions of R
esidence Tim
es for Chem
icalR
eactorsA
fter completing C
hapter 13 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Define a residence tim
edistribution R
TD [E(t),
F(t)] and the mean
residence time.
Determ
ine E(t) form tracer
data.
Write the R
TD functions
(E(t), F(t), I(t)) for idealC
STRs, PFR
s, and laminar
flow reactors.
Predict conversions fromR
TD data using the
segregation and maxim
umm
ixedness models.
Predict effluentconcentrations for m
ultiplereactions using thesegregation and m
aximum
mixedness m
odels.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
-
Chapter Thirteen
file:///H:/htm
l/13chap/frames.htm
[05/12/2011 16:54:28]
APPEN
DIC
ES
-
Chapter Fourteen
file:///H:/htm
l/14chap/frames.htm
[05/12/2011 16:54:30]
CH
APT
ER
14
14
Models for N
onideal Reactors
After com
pleting Chapter 14 of
the text and associated CD
-RO
Mm
aterial the reader will be able to:
Describe the tanks-in-series
and dispersion oneparam
eter models.
Describe how
to obtain them
ean residence time and
variance to calculate thenum
ber of tanks-in-seriesand the Peclet num
ber.
Calculate the conversion
for a first order reactiontaking place in a tubularreactor w
ith dispersion
Describe how
to usecom
binations of idealrectors to m
odel a realreactor and how
to usetracer data to determ
ine them
odel parameters.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
APPEN
DIC
ES
-
Appendices
file:///H:/htm
l/appendix/frames.htm
[05/12/2011 16:54:32]
APPE
ND
ICE
S
The Appendices are in PD
F format. Y
ou must have
Adobe A
crobat Reader installed to access these files.
You w
ill also need the Adobe A
crobat Reader Plug-in
to read these files from your brow
ser. (See the CD
-R
OM
Introduction for more inform
ation.)
Appendix D
: Measurem
ent of Slopes on Semilog
Paper
Appendix E: Softw
are Packages
Appendix H
: Open-Ended Problem
s
Appendix J: U
se of Com
putational Chem
istrySoftw
are Packages
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
APPEN
DIC
ES
-
Navigation
file:///H:/htm
lmain/intro2.htm
[05/12/2011 16:54:33]
Welcom
eN
avigationC
omponents
Usage
Navigation
The O
bjectives
At the opening of every chapter is the O
bjectives. Clicking on B
EG
IN takes you to the C
hapter Outline
-- the contents for that chapter.
Chapter O
utline - The M
ain Interface
-
Navigation
file:///H:/htm
lmain/intro2.htm
[05/12/2011 16:54:33]
The Main Interface lists the contents for that chapter. There are links to the entire chapter's contents
from this page. R
eturn to this page by using the left-hand navigation bar and click on Chapter O
utline.
In the Professional Reference Shelf and L
earning Resources sections, there are E
xamples that link from
within these sections. W
hen you click on an Exam
ple, a new brow
ser window
will open. Som
e Exam
plescan also be accessed from
the Chapter O
utline, where a new
browser w
indow w
ill not open.
An E
xample in a N
ew B
rowser W
indow
This new brow
ser window
is not the main interface. To return to the previous page, close this w
indow by
clicking on the top-left button of the new brow
ser window
(for Macs), or on the top-right button of the
new brow
ser window
(for PCs).
-
Navigation
file:///H:/htm
lmain/intro2.htm
[05/12/2011 16:54:33]
Throughout this material there w
ill be Footnotes. By clicking on a footnote, you are going to open a new
browser w
indow.
Footnotes in a New
Brow
ser Window
Again, this new
browser w
indow is not the m
ain interface. To return to the previous page, close thisw
indow by clicking on the top-left button of the new
browser w
indow (for M
acs), or on the top-rightbutton of the new
browser w
indow (for PC
s).
Left N
avigation Bar
Chapter N
umber takes you to the O
bjectivespage for that chapter, w
hile Chapter O
utlinetakes you to C
ontents page for that chapter.
Software T
oolbox takes you to the Software
Toolbox, e.g. Polymath.
Interactive Com
puter Modules takes you to
the ICM
s main m
enu.
Thoughts on Problem
Solving takes you to them
ain problem solving m
enu.
-
Navigation
file:///H:/htm
lmain/intro2.htm
[05/12/2011 16:54:33]
Updates &
FAQ
s takes you to updates andcorrections for the book.
Representative Syllabi takes you to the
sample 3- and 4-credit course syllabi.
Help takes you to the help m
enu.
Except for Chapter N
umber and C
hapter Outline, inform
ation you access from this navigation bar is not
specific to any chapter. You can go directly to the T
houghts on Problem Solving section to see exam
plesof the 10 types of hom
e problems or visit the Interactive C
omputer M
odules, without leaving the
chapter that you are in.
All the m
aterial is ordered by chapter. The lower navigation bar w
ill take you to a specific Chapter or the
Appendices. The H
OM
E button w
ill take you to the welcom
e screen for this CD
.
Low
er Navigation B
ar
To find out more, go to the C
omponents section of this C
D.
Welcom
e Navigation C
omponents U
sage
-
Navigation
file:///H:/htm
lmain/intro2.htm
[05/12/2011 16:54:33]
Begin: C
hapter 1
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Com
ponents
file:///H:/htm
lmain/intro3.htm
[05/12/2011 16:54:34]
Welcom
eN
avigationC
omponents
Usage
Com
ponentsC
omponents of the C
D-R
OM
Each chapter is broken into the following bulleted com
ponents:
Learning Resources
Summ
ary Notes
Web M
odulesInteractive C
omputer M
odulesSolved Problem
s
Living Example Problem
s
Professional Reference Shelf
Additional H
omew
ork Problems
Learning R
esourcesThese resources give an overview
of the material in each chapter and provide extra explanations, exam
ples, andapplications to reinforce the basic concepts of chem
ical reaction engineering. The learning resources on the CD
-R
OM
include:
1. Summ
ary Notes
The Summ
ary Notes of the lectures given at the U
niversity of Michigan w
ill serve as an overview of
each chapter. They contain a logical flow of the equations being derived, along w
ith additionalexam
ples and material that can be view
ed either before or after reading the text. The first 26 lecturesare covered in a four-credit hour undergraduate course. The last 11 (27-37) are taken from
thegraduate course at the U
niversity of Michigan.
2. Web M
odulesThese m
odules show how
key concepts of chemical reaction engineering can be applied to non-
standard problems (e.g. the use of W
etlands to degrade toxic chemicals). C
urrent modules focus on
Chapters 4 and 6 and include W
etlands, Cobra B
ites, Mem
brane Reactors and R
eactive Distillation
modules. A
dditional web m
odules (http://ww
w.engin.um
ich. edu/~cre) are expected to be addedover the next several years.
3. Interactive Com
puter Modules
Most chapters have one or m
ore interactive computer m
odules (ICM
s) to accompany them
as alearning resource. For these chapters, students can use the corresponding IC
M(s) to review
theim
portant material and then apply it to real problem
s in a unique and entertaining fashion. Eachm
odule contains:
Menu
Review
of conceptsInteractive problem
-
Com
ponents
file:///H:/htm
lmain/intro3.htm
[05/12/2011 16:54:34]
Solution to the problem
For example, in the M
urder Mystery m
odule students take on the role of assistant sleuth as they usebasic chem
ical engineering principles to solve the strange disappearance of several of the Nutm
egaSpice C
ompany's em
ployees. This particular module has long been a favorite w
ith students acrossthe nation.
4. Solved Problems
A num
ber of solved problems are presented along w
ith problem solving heuristics. Problem
solvingstrategies and additional w
orked example problem
s and are available in the Thoughts on ProblemSolving section of the C
D-R
OM
. The Ten Types of Hom
ework Problem
s section contains two
worked exam
ples for each of the ten homew
ork problem types. These exam
ples are based on them
aterial from C
hapter 4, and they provide useful information on how
one can attack homew
orkproblem
s. The section on Getting U
nstuck is especially helpful.
Living E
xample Problem
sThe exam
ple problems that use an O
DE solver (e.g., PO
LYM
ATH
) are referred to as "living example
problems," because the students can load the program
directly on their own com
puters in order to study it.Students are then encouraged to "play" w
ith the example's key variables and assum
ptions. Students canchange param
eter values, such as the reaction rate constants to learn to deduce trends or predict thebehavior of a given reaction system
, and gain a better understanding of the concepts being studied. Using
the living example problem
s provides students with the opportunity to practice critical and creative
thinking skills as they explore the problem and ask "w
hat if...?" questions.
Professional Reference Shelf
This section of the CD
-RO
M contains:
(1) material that is im
portant to the practicing engineer, although it is typically not included in the majority
of chemical reaction engineering courses. A
short synopsis of each of the following topics is given at the
appropriate point in the text. These sections are:
i. Photographs of real reactorsii. R
ecycle reactorsiii. W
eighted least squaresiv. Experim
ental planningv. Laboratory reactors
vi. Inhibition and cofactors in enzymatic reactors
vii. Bifurcation analysis
viii. Wet and dry etching of sem
iconductorsix. C
atalytic monoliths
x. Wire gauze reactors
xi. Trickle bed reactorsxii. Fluidized bed reactors
xiii. CV
D boat reactors
(2) material that gives a m
ore detailed explanation of derivations that were abbreviated in the text.
The intermediate steps to these derivations are given on the C
D-R
OM
:
a) First order reaction in a semibatch reactor
b) Temperature-conversion relationship for an adiabatic reactor
c) Aris-Taylor dispersion
Additional H
omew
ork Problems
New
problems w
ere developed for this edition that provide a greater opportunity to use today's
-
Com
ponents
file:///H:/htm
lmain/intro3.htm
[05/12/2011 16:54:34]
computing pow
er to solve realistic problems. In addition, parts of problem
s were designed to
promote and develop critical thinking skills. M
any instructors alternate the homew
ork problems they
assign from year to year, ususally taken from
a limited num
ber of problems at the end of each
chapter. Consequently, som
e of the more traditional, yet excellent problem
s of previous editionsw
ere placed on the CD
-RO
M and they can serve as practice problem
s along with those unassigned
problems in the text.
Table CD
I-1 gives the resources available in each chapter.
TA
BL
E C
DI-1
Chapter:
12
34
56
78
910
1112
1314
Learning R
esources Sum
mary N
otes W
eb Modules
Interactive C
omputer
Modules
Solved Problems
Living E
xample Problem
s
Professional Reference
Shelf
Additional H
omew
orkProblem
s
In addition to the components listed at the end of each chapter the follow
ing components are also
included on the CD
-RO
M
Software T
oolboxInstructions on how
to use the different software packages to solve exam
ples are described for:
POLY
MA
THM
atLabA
SPEN PLU
S
All living exam
ple problems on the C
D are in both PO
LYM
ATH
and MatLab Form
at. ThePO
LYM
ATH
program can either be loaded to a com
puter and executed directly from the C
D-R
OM
.The PO
LYM
ATH
examples m
ay also be loaded on a computer or run directly from
the CD
-RO
M.
In order to execute MatLab exam
ples, MatLab m
ust be available on a server with a site license or
the student version of MatLab m
ust be purchased. Similarly, in regard to A
SPEN, the C
D show
s anexam
ple of how to use A
SPEN to solve chem
ical reaction engineering problems, how
ever, a sitelicense m
ust be available to actually use ASPEN
to solve the homew
ork problems.
Representative Syllabi for both 3 and 4 C
redit Courses
The syllabi give a sample pace at w
hich the courses could be taught as well as suggested hom
ework
problems.
Virtual R
eality Module
This module provides an opportunity to m
ove inside a catalyst pellet to observe surface reactionsand coking. This m
odule also allows students to navigate through a catalyst pore and see the
catalytic steps of diffusion, adsorption, surface reaction, and coking occurring on a catalyst pellet.
-
Com
ponents
file:///H:/htm
lmain/intro3.htm
[05/12/2011 16:54:34]
Credits
Special recognition to the students who contributed so m
uch to the CD
-RO
M. In particular, D
ieterSchw
eiss, Anuj H
asija, and Susan Fugett. In addition, Gavin Sy, Scott C
onaway, Tim
Mashue, and
Ellyne Buckingham
also worked on the C
D-R
OM
.
Clicking on the topic you w
ish to view w
ill bring up the following inform
ation:
Learning R
esources
A. Sum
mary N
otes
1. Click on this hot button and a listing of all the lectures in pairs of tw
o (e.g. Lectures 1and 2, Lectures 3 and 4, etc.) w
ill appear on the screen. Under each lecture pair w
ill be ashort listing of the topics covered in those tw
o lectures at the University of M
ichiganalong w
ith the chapters that the lectures are based upon.
2. Click on particular lecture pairs of interest to view
the Summ
ary Notes.
B. A
dditional Hom
ework Problem
s1. C
lick on the topic you choose under Web M
odules (e.g. Ch 6 - Pharm
acokinetics of Cobra B
ites) and them
odule will appear on your screen.
2. Click on the Interactive C
omputer M
odules title (e.g. Ch 4 - M
ystery Theater) and a description of thatm
odules specific will appear. N
ext click on (2) the instructions that describe how to install the m
odule onto your com
puter. Finally, load and run the interactive computer m
odule.
C. L
iving Exam
ple Problems
If you wish to run the PO
LYM
ATH
examples you can run them
directly. If you wish to run the exam
pleson M
atLab you will have to purchase the student edition of M
atLab or have MatLab available on the
server and use an interface to load and run them on your ow
n computer. A
ll the examples are in the
POLY
MA
TH directory "PO
LYM
ATH
/EXA
MPLES." To access them
, you can run POLY
MA
TH dorectly
or install POLY
MA
TH on your com
puter. If you want to study the exam
ples which use the O
DE solver
for example enter 1 w
hen the blue POLY
MA
TH screen appears. Type F9, and F9 again and the list of
examples should appear.
D. W
eb Modules
Click on the w
eb module of interest (e.g. W
etlands (Ch 4)) to pull up the m
odule. These modules provide
supplementary Exam
ples on how the principles of chem
ical reaction engineering can be applied to non-traditional situations.
E. Softw
are Toolbox
1. Click on this hot button and the follow
ing menu w
ill appear
POLY
MA
THM
atLabA
SPEN
2. Click on the hot button of your choice (e.g. PO
LYM
ATH
) and instructions will appear on the screen
describing how to use the softw
are to solve the homew
ork problems.
F. Syllabi1. C
lick on Syllabi and the menu
-
Com
ponents
file:///H:/htm
lmain/intro3.htm
[05/12/2011 16:54:34]
a. 3 credit hour courseb. 4 credit hour course w
ill appear on your screen.
2. Click on the Syllabus of your choice and a w
eek by week (lecture by lecture) listing of the topics and
chapter pages covered along with assigned hom
ework problem
s will appear.
G. T
houghts on Problem Solving (1) C
lick on this hot button and the following m
enu appears
Closed-Ended Problem
s (CEP)
Open-Ended Problem
s (OEP)
Ten Types of Hom
e Problems (10 types)
Strategies for Problem Solving
H. C
reditsC
lick on this hot button (on the HO
ME
Screen) to learn about the people who helped develop the w
ebpage and the C
D for this text.
To find out about the ways to use this C
D, go to the U
sage section of this CD
.
Welcom
e Navigation C
omponents U
sage
Begin: C
hapter 1
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Navigation
file:///H:/htm
lmain/intro4.htm
[05/12/2011 16:54:35]
Welcom
eN
avigationC
omponents
Usage
Usage
How
to Use the C
D-R
OM
The primary purpose of the C
D-R
OM
is to serve as an enrichment resource. The objectives are fourfold:
(1) To provide the option/opportunity for further study or clarification on a particular concept or topicthrough Lecture N
otes, additional examples, interactive com
puting modules and w
eb modules,
(2) To provide the opportunity to practice critical thinking skills, creative thinking skills, and problemsolving skills through the use of "W
hat if" questions and "living example problem
s,"
(3) To provide additional technical material for the professional bookshelf,
(4) To provide other tutorial information, such as additional hom
ework problem
s, thoughts on problemsolving, how
to use computational softw
are in chemical reaction engineering, and a representative course
structure.
There are a number of w
ays one can use the CD
in conjunction with the text. The general guideline is that
the CD
provides enrichment resources for the reader. Pathw
ays on how to use the m
aterials to learnchem
ical reaction engineering are shown in Figure I-1 and I-2.
The keys to the CR
E learning flow
sheet are:
Squares = Primary R
esourcesC
ircles/Ovals = Enrichm
ent Resources
I. University Student
Figure CD
I-1 "A" Student Pathw
ay to Integral Class, T
ext, CD
.
-
Navigation
file:///H:/htm
lmain/intro4.htm
[05/12/2011 16:54:35]
II. Practicing Engineer
Figure CD
I-2 "A" Problem
Solving Pathway to Integrate text, C
D.
III. Instructor
Figure CD
I-3 Resources for Instructors
The author recomm
ends that instructors use the living example problem
s before assigning home problem
s,but they m
ay be by-passed if time is not available. This is, of course, true for all of the enrichm
entresources. Please note how
ever, that class testing had shown that the enrichm
ent resources not only aidstudents in learning the m
aterial, but they also motivate students by the novel use of C
RE
principles.
Possible Implem
entation Strategies
I. Learning R
esources
A. Lecture N
otes: This material could be review
ed before reading the chapter get an overview of the
material.
B. Interactive C
omputer M
odules - (ICM
): Each module requires approxim
ately 30 minutes to
complete. If a m
odule is not assigned or required, the student could quickly go on through theR
eview of Fundam
entals Section to get an overview or to review
(ca. 10 min.). The com
pletem
odules could be used by the student as a self test to check their level of understanding. A num
berof schools assign one either every w
eek or every other week.
C. W
eb Modules: This m
aterial can be used to motivate students by show
ing them the w
ide range ofC
RE
applications of or as a basis for special projects or open-ended problems. The general problem
solving algorithm could be one of the first m
odules to be reviewed.
-
Navigation
file:///H:/htm
lmain/intro4.htm
[05/12/2011 16:54:35]
D. Solved Exam
ples: After reading the m
aterial in the chapters and studying the example problem
s,students have the opportunity to see one or tw
o more solved problem
s before embarking on
solutions of the homew
ork problems.
II. Living E
xample Problem
sThese exam
ples are meant to be used in conjunction w
ith the second problem of every chapter, beginning
with C
hapter 4 (i.e. P4-2). Typically one might assign a living exam
ple problem (e.g. P6-2) as one of the
first problems assigned in a chapter to get students fam
iliar and comfortable w
ith the material.
III. Professional Reference Shelf
This material is im
portant to the practicing engineer, but is not included in the majority of undergraduate
or graduate courses in chemical reaction engineering. C
onsequently, instructors my pick and choose from
this material along the lines of special topics. M
aterial from C
hapters 5, 8, 9 and 12 are used in thegraduate course at the U
niversity of Michigan (i.e. Experim
ental Planning, Bifurcation A
nalysis, Control
of Chem
ical Reactors, and the K
. L. Model of Fluidized B
eds, respectively).
IV. T
he Web (http://w
ww
.engin.umich.edu/~cre)
The web w
ill be used to update the CD
-RO
M and text m
aterial, provide new exam
ples and more solved
problems, and correct of typographical errors from
the first printing of the 3rd Edition.
Welcom
e Navigation C
omponents U
sage
Begin: C
hapter 1
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Elements of C
hemical R
eaction Engineering
file:///H:/htm
lmain/interac.htm
[05/12/2011 16:54:35]
The following Interactive C
omputer M
odules (ICM
s) are contained on the Elements of
Chem
ical Reaction Engineering CD
-ROM
:
Kinetics C
hallenge 1 -- Quiz Show
Introduction to K
ineticsL
earning Resource for C
hapter One
Staging -- Reactor Sequencing O
ptimization G
ame
Learning R
esource for Chapter Tw
o
Kinetics C
hallenge 2 -- Quiz Show
Stoichiom
etry and Rate Law
sL
earning Resource for C
hapter Three
Murder M
ystery C
STR V
olume A
lgorithmL
earning Resource for C
hapter Four
Tic Tac Isotherm
al Reactor D
esign: Ergun, Arrhenius, and V
an't Hoff Equations
Learning R
esource for Chapter Four
Ecology A W
etlands ProblemC
ollection and Analysis of R
ate Date: Ecological Engineering
Learning R
esource for Chapter Five
Heat Effects 1 B
asketball Challenge
Mole and Energy B
alances in a CSTR
Learning R
esource for Chapter Eight
Heat Effects 2 Effect of Param
eter Variation on a PFR
M
ole and Energy Balances in a PFR
Learning R
esource for Chapter Eight
Heterogeneous C
atalysis L
earning Resource for C
hapter Ten
Some users have experienced problem
s, trying to run the Interactive Com
puter Modules
directly from the IC
M directory on the C
D-R
OM
. If you have trouble with being able to
run the Interactive Com
puter Modules from
the CD
-RO
M, then try installing them
on
-
Elements of C
hemical R
eaction Engineering
file:///H:/htm
lmain/interac.htm
[05/12/2011 16:54:35]
your hard drive.
Instructions for installing the ICM
s and for using the ICM
s are available.
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
CR
E -- Appendices
file:///H:/htm
l/appendix/html/index.htm
[05/12/2011 16:54:36]
The Appendices are in PD
F format. Y
ou must have
Adobe A
crobat Reader installed to access these files.
You w
ill also need the Adobe A
crobat Reader Plug-in
to read these files from your brow
ser. (See the CD
-R
OM
Introduction for more inform
ation.)
Appendix D
: Measurem
ent of Slopes on Semilog
Paper
Appendix E: Softw
are Packages
Appendix H
: Open-Ended Problem
s
Appendix J: U
se of Com
putational Chem
istrySoftw
are Packages
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Polymath
file:///H:/htm
l/toolbox/polymath/index.htm
[05/12/2011 16:54:36]
Polymath
Polymath is a D
OS-based program
that can help you solve differential equations, analyze rate data (with non-linear
regression, etc.), and more. The program
is fairly straight-forward, but you w
ill want to read through the Polym
athM
anual before you start. Then we recom
mend that you take the Polym
ath Short Course to start you on your w
ay.
Polymath-R
elated Files
Polymath Program
Files
Polymath has been included on your C
D-R
OM
in a directory called Polymat4. Y
ou can run Polymath directly from
your CD
-RO
M, or you can install Polym
ath on your hard drive.
Polymath E
xamples (aka, L
iving Exam
ple Problems)
You m
ay have noticed that certain chapters have links to Living E
xample Problem
s. The example problem
s areactually in the text for the 3rd edition of Elem
ents of Chem
ical Reaction Engineering, not on the CD
-RO
M. The
chapter links for these examples direct you to the Polym
ath code for these problems. The Polym
ath code for the LivingExam
ple Problems from
Chapters 2-10 and C
hapters 13-14 is in the Htm
l\Toolbox\Polym
ath\Exam
ples directory onyour C
D-R
OM
. Each chapter is represented by a folder named C
h#, which is short for chapter num
ber, of course.
The Polymath code for these exam
ples has been included on the CD
-RO
M for your convenience, so you w
on't have tow
aste time duplicating the exam
ples from the text. (See the section on accessing the exam
ple problems or the
Polymath Short C
ourse for more inform
ation.) Once you load up an exam
ple, you are encouraged to "play around with
it" by modifying the values of constants, varying key param
eters, etc. In this way, you can get a feel for how
modifying different variables w
ill affect your results.
Using Polym
ath
Polymath is easy to use -- once you know
how! See the section on U
sing Polymath for m
ore information, and don't
forget to take a look at the Polymath M
anual for instructions on how to run and generally use Polym
ath:
On-L
ine Information
Polymath 4.0.2 M
anual in PDF form
at.
Polymath 4.1 M
anual in PDF form
at.
-
Polymath
file:///H:/htm
l/toolbox/polymath/index.htm
[05/12/2011 16:54:36]
NO
TE
: You w
ill need the Adobe A
crobat Reader Plug-in to read this file.
(See the CD
-RO
M Introduction for m
ore information.)
Why T
wo V
ersions of Polymath?
This is the second printing of the text and the CD
. Polymath 4.1 has better printing features than Polym
ath 4.0.2, but itw
as not available for the first printing of the CD
. We could have replaced Polym
ath 4.0.2 with Polym
ath 4.1, but we
decided to make both versions available instead.
Polymath Short C
ourse
You can also take a look at the Polym
ath Short Course for a quick-and-dirty introduction to Polym
ath. You w
on'tlearn everything about Polym
ath, but you will learn enough to get you started, so you can "play around" w
ith theLiving Exam
ple Problems.
Polymath M
ain | Using Polym
ath | Installing Polymath | Short C
ourse
References
Polymath w
as created by Mordechai Shacham
and Michael B
. Cutlip. They m
ake use of Polymath in their ow
n text,Problem
Solving in Chem
ical Engineering with N
umerical M
ethods, also from Prentice-H
all.
These pages on Polymath w
ere created by Dieter A
ndrew Schw
eiss. Many thanks to Tim
Hubbard and Jessica H
amm
an for proof-reading and error-testing them.
-
index.htm
file:///H:/htm
l/toolbox/matlab/index.htm
[05/12/2011 16:54:37]
MA
TL
AB
Information
by Susan Fugett, D.A
. Schweiss, and M
ayur Valanju
Ordering M
AT
LA
B
In order to use the MA
TLAB
programs included on this C
D-R
OM
, you must have your
own copy of M
ATLA
B. The latest version, M
ATLA
B 5, is available from
:
The MathW
orks, Inc.U
niversity Sales Departm
ent 24 Prim
e Park Way
Natick, M
A 01760-1500.
Phone: (508) 653-1415Fax: (508) 653-2997Em
ail: info@m
athworks.com
Web: http://w
ww
.mathw
orks.com
A Student Edition is also available.
On the C
D-R
OM
Appendix E
Appendix E contains detailed instructions for using M
ATLA
B to solve the problem
sfrom
the text. It is included in the Appendices section of the C
D-R
OM
as an Adobe
Acrobat R
eader file (PDF form
at, see the CD
-RO
M Introduction for m
ore information).
It is also available in Word 6 form
at (for the PC) in the H
tml\Toolbox\M
atlab\Word
directory. Even if you are an experienced MA
TLAB
user, we encourage you to read
Appendix E to learn how
to use the m-files in M
ATLA
B. O
therwise, you m
ay havedifficulty using them
.
M-Files
-
index.htm
file:///H:/htm
l/toolbox/matlab/index.htm
[05/12/2011 16:54:37]
Included on this CD
-RO
M are the m
-files for all the example problem
s that were solved
in the text using POLY
MA
TH. For PC
users, these files can be found in the directoryH
tml\Toolbox\M
atlab\m-files . These files m
ay be copied onto the hard drive of yourcom
puter or used directly from the C
D-R
OM
. Mac users w
ill be able to open these files,but they m
ay need to edit the contents slightly.
MA
TL
AB
Notebook, M
-book
The Microsoft W
ord 6.0 Notebook files for each exam
ple problem have also been
included on the CD
-RO
M for users w
ho wish to use this utility. These files m
ay befound in directory H
tml\Toolbox\M
atlab\Word on the C
D-R
OM
. The Notebook option
provides an interface with the M
icrosoft Word 6.0 program
, the M-book. Please note,
however, that the M
-book files are not included on the CD
-RO
M, but are included w
iththe M
ATLA
B softw
are. The Notebook interface allow
s you to run MA
TLAB
within
Word, enabling you to fully explain and docum
ent your MA
TLAB
operations. By typing
Control + E
nter at the end of a line of text, the user instructs MA
TLAB
to perform the
comm
ands written on that line. Input into M
ATLA
B is then changed to a different font
from the text and appears green on the screen. The output from
MA
TLAB
is in anotherfont w
hich is blue. Plots generated in MA
TLAB
are also added to the Word file using
this interface. The M-book function is a convenient tool to prepare a detailed
presentation of your MA
TLAB
work.
Using the M
-Files
See the page on Using and M
odifying the M-Files for m
ore information.
Rem
ember!
We included A
ppendix E on the CD
-RO
M, because it contains detailed instructions for
using MA
TLAB
with our m
-files to solve the problems from
the text. It is in theA
ppendices section of the CD
-RO
M. If you plan to use M
ATLA
B to solve these
problems, then read A
ppendix E first!
-
CR
E -- Chapter O
ne-Objectives
file:///H:/htm
l/01chap/html/obj.htm
[05/12/2011 16:54:37]
1
Mole B
alancesA
fter completing C
hapter 1 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Define the rate of chem
icalreaction.
Apply the m
ole balanceequations to a batchreactor, C
STR, PFR
, andPB
R.
Describe tw
o industrialreaction engineeringsystem
s.
Describe photos of real
reactors.
Describe how
to surf theC
D-R
OM
attached with
this text.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
-
CR
E -- Chapter O
ne
file:///H:/htm
l/01chap/html/one.htm
[05/12/2011 16:54:38]
1Learning Resources
1. Sum
mary N
otes for Lectures 1 and 2
2. Web M
odulesA
. Problem Solving A
lgorithm for C
losed-Ended Problems
B. H
ints for Getting U
nstuck on a Problem
3. Interactive C
omputer M
odulesA
. Quiz Show
I
4. Solved Problems
A. C
DP1-A
B Batch R
eactor Calculations: A
Hint of Things to C
ome
Professional Reference Shelf
1. Photographs of Real Reactors
Additional H
omew
ork Problems
CD
P1-ACalculate the time to consum
e 99% and 80%
of species A in a constant-volum
e batch reactor for a firstorder and for a second order reaction, respectively.
Solution Included
CD
P1-BDerive the differential mole balance equation for a foam
reactor.
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Elements of C
hemical R
eaction Engineering
file:///H:/htm
lmain/softw
are.htm[05/12/2011 16:54:38]
How
to Create and Sim
ulate Chem
ical Reaction M
odels with:
Polymath
Two versions of Polym
ath have been included on your CD
-RO
M, 4.0.2 and
4.1.
You can run version 4.0.2 directly from
the CD
, so that you examine
and modify the L
iving Exam
ple Problems specific to each C
hapter.Y
ou can also install it on your computer .
To use version 4.1, you will have to install it on your com
puter .Polym
ath 4.1 has better printing capabilities than Polymath 4.0.2.
MA
TLAB
MA
TLAB
m-files have been included on your C
D-R
OM
, but you will have
to purchase your own copy of M
ATLA
B, or M
ATLA
B m
ust be available onyour school's com
puters, to be able to use them.
Aspen Plus
Read these pages to learn how
to use Aspen Plus to design chem
icalengineering reaction system
s. You w
ill have to purchase (or acquire a sitelicense for) your ow
n copy of the Aspen Plus softw
are, since it is notincluded on this C
D.
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Elements of C
hemical R
eaction Engineering
file:///H:/htm
lmain/probsolv.htm
[05/12/2011 16:54:39]
The Thoughts on Problem Solving area of this C
D-R
OM
offers students step-by-step instruction for thepurpose of further developing problem
solving skills.
Closed-E
nded Problems
- these single answer hom
ework problem
s include two exam
ple problems along w
ith techniques forgetting unstuck w
hen stopped along the solution path.
Open-E
nded Problems
- solution heuristic to problems that m
ay be ill-posed, have no solution as posed, or allow for the
possibility of multiple solutions.
Ten T
ypes of Hom
e Problems
- describes how different types of hom
e problems can be used to im
prove critical and creativethinking skills.
Strategies for Creative Problem
Solving
- the award w
inning book on developing creative problem solving skills
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Elements of C
hemical R
eaction Engineering, Updates
file:///H:/htm
lmain/updates.htm
[05/12/2011 16:54:39]
3rd Edition U
pdates & FA
Qs
This area contains updates to the 3rd Edition of Elements of Chem
ical Reaction Engineering as thingslike typographical errors, etc. are found. This inform
ation is current, as of just prior to the 2nd printing ofthe text and C
D-R
OM
. You are encouraged to visit the C
hemical R
eaction Engineering Web Site every
few m
onths for new updates as m
ore typos are found, or as new problem
s, activities, etc. are added to thew
eb site.
This is also the location our reaction engineering Frequently Asked Q
uestions (FAQ
s) page.
Links
Typos in the First Printing
Which Printing D
o I Have?
Frequently Asked Q
uestions (FAQ
s)
On the C
D
Updates to the 3rd Edition can be view
ed in PDF form
at.
NO
TE:You m
ust have Adobe A
crobat Reader installed to access PD
F files. You w
ill alsoneed the A
dobe Acrobat R
eader Plug-in to read these files from your brow
ser. (See the CD
-R
OM
Introduction for more inform
ation.)
On the C
RE
Web Site
CD
-RO
M users are encouraged to check the U
pdates Section of the Chem
ical Reaction Engineering W
ebSite every few
months for new
material.
1999 Prentice-H
all PTRPrentice H
all, Inc.
-
Elements of C
hemical R
eaction Engineering, Updates
file:///H:/htm
lmain/updates.htm
[05/12/2011 16:54:39]
ISBN
0-13-531708-8
Legal Statement
-
Elements of C
hemical R
eaction Engineering
file:///H:/htm
lmain/syllabi.htm
[05/12/2011 16:54:40]
Representative Syllabus for a 3 C
redit Hour C
ourse from
the University of Illinois, C
hE 381, Fall 1998 Professor R
ichard Braatz
Representative Syllabus for a 4 C
redit Hour C
ourse from
the University of M
ichigan, ChE 344, W
inter 1998 Professor H
. Scott Fogler
Representative Syllabus for a 4 C
redit Hour C
ourse from
the University of M
ichigan, ChE 344, W
inter 1999 Professor H
. Scott Fogler
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
Elements of C
hemical R
eaction Engineering
file:///H:/htm
lmain/help.htm
[05/12/2011 16:54:40]
1. Welcom
e
2. Navigation
3. Com
ponents
4. Usage
5. Dow
nloading Software
Interactive Com
puter Modules
Polymath, M
ATLA
B, A
spen
6. About this C
D
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
CR
E -- Chapter Tw
o-Objectives
file:///H:/htm
l/02chap/html/obj.htm
[05/12/2011 16:54:41]
2
Conversion and R
eactor SizingA
fter completing C
hapter 2 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Define conversion and
space time.
Write the m
ole balances interm
s of conversion for abatch reactor, C
STR, PFR
,and PB
R.
Size reactors either alone orin series once given the rateof reaction, -rA , as afunction of conversion, X.
Write relationship betw
eenthe relative rates ofreaction.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
-
CR
E -- Chapter Tw
o
file:///H:/htm
l/02chap/html/tw
o.htm[05/12/2011 16:54:41]
2Learning Resources
1. Sum
mary N
otes for Lectures 1 and 2
3. Interactive Com
puter Modules
A. R
eactor Staging
4. Solved Problems
A. C
D P2-A
B More C
STR and PFR
Calculations -- N
o Mem
orization
Additional H
omew
ork Problems
CD
P2-AB
Use Levenspiel plots to calculate PFR
and CSTR
reactor volumes given -rA = f(X
).
Solution Included
CD
P2-BA
An ethical dilem
ma as to how
to determine the reactor size in a com
petitor's chemical plant.
CD
P2-CA
Use Levenspiel plots to calculate PFR
and CSTR
volumes.
CD
P2-DA
Use Levenspiel plots to calculate C
STR and PFR
volumes for the reaction
A + B
C
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
CR
E -- Chapter Three-O
bjectives
file:///H:/htm
l/03chap/html/obj.htm
[05/12/2011 16:54:42]
3
Rate L
aw and Stoichiom
etryA
fter completing C
hapter 3 ofthe text and associated C
D-R
OM
material the reader w
ill be able to:
Write a rate law
and definereaction order andactivation energy.
Set up a stoichiometric
table for both batch andflow
systems and express
concentration as a functionor conversion.
Calculate the equilibrium
conversion for both gas andliquid phase reactions.
Write the com
bined mole
balance and rate law in
measures other than
conversion.Set up a stoichiom
etrictable for reactions w
ithphase change.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
-
CR
E -- Chapter Three
file:///H:/htm
l/03chap/html/three.htm
[05/12/2011 16:54:42]
3Learning Resources
1. Sum
mary N
otes for Lectures 3 and 4 Sum
mary N
otes for Lectures 5 and 6
3. Interactive Com
puter Module
A. Q
uiz Show II
4. Solved Problem
sA
. CD
P3-AB A
ctivation Energy for a Beetle Pushing a B
all of Dung
B. C
D P3-B
B Microelectronics Industry and the Stoichiom
etric Table
Additional H
omew
ork Problems
CD
P3-AB
Data on the tenebrionid beetle w
hose body mass is 3.3g show
s it can push a 35g ball of dung at 6.5 cm/s at
27 C, 13 cm
/s at 37 C and 18 cm
/s at 40 C. H
ow fast can it push at 41.5 C
(Heinrich, B
., The Hot-Blooded
Insects. Harvard Press, C
ambridge, 1993).
Solution Included
CD
P3-BB
Silicon is used in the manufacture of m
icroelectronic devices. Set up a stoichiometric table for the
reaction:
SiHC
l3 (g) + H2 (g)
Si(s) + HC
l(g) + Six Hg C
lz (g)
Solution Included
CD
P3-CB
The elementary reaction A
(g) + B(g)
C(g) takes place in a square duct containing liquid B
, which
evaporates into the gas phase to react with A
.
CD
P3-DB
Condensation occurs in the gas phase reaction:
C2 H
4 (g) + 2Cl2 (g)
CH
2 Cl2 (g,l) + 2H
Cl(g)
CD
P3-EB
Set up a stoichiometric table for the reaction:
-
CR
E -- Chapter Three
file:///H:/htm
l/03chap/html/three.htm
[05/12/2011 16:54:42] C6 H
5 CO
CH
+ 2NH
5 C
6 H5 O
NH
2 + NH
2 Cl
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statement
-
CR
E -- Chapter Four-O
bjectives
file:///H:/htm
l/04chap/html/obj.htm
[05/12/2011 16:54:43]
4
Isothermal R
eactor Design
After com
pleting Chapter 4 of
the text and associated CD
RO
Mm
aterial the reader will be able to:
Describe the algorithm
thatallow
s the reader to solvechem
ical reactionengineering problem
sthrough logic rather thanm
emorization.
Size batch reactors,sem
ibatch reactors, CSTR
s,PFR
s, and PBR
s forisotherm
al operation giventhe rate law
and feedconditions.
Discuss solutions to
problems taken from
theC
alifornia ProfessionalEngineers R
egistrationExam
ination.
Account for the effects of
pressure drop onconversion in packed bedtubular reactors and inpacked bed sphericalreactors.
B
EG
IN
1999 Prentice-H
all PTRPrentice H
all, Inc.ISB
N 0-13-531708-8
Legal Statem
ent
-
CR
E -- Chapter Four
file:///H:/htm
l/04chap/html/four.htm
[05/12/2011 16:54:43]
4Learning Resources
1. Sum
mary N
otes for Lectures 3 and 4 Sum
mary N
otes for Lectures 5 and 6 Sum
mary N
otes for Lectures 7 and 8 Sum
mary N
otes for Lectures 9 and 10
2. Web M
odulesA
. Wetlands
B. M
embrane R
eactorsC
. Reactive D
istillation
3. Interactive Com
puter Modules
A. M
urder Mystery
B. Tic Tac -- A
Gam
e of Reaction Engineering Tic-Tac-Toe
4. Solved Problem
sA
. CD
P4-AB A
Sinister Gentlem
an Messing w
ith a Batch R
eactorB
. Solution to a California R
egistration Exam Problem
C. Ten Types of H
ome Problem
s: 20 Solved Problems
5. Analogy of C
RE Algorithms to a M
enu in a Fine French Restaurant
6. Algorithm for G
as Phase Reaction
Living E
xample Problem
s
The following exam
ples can be accessed through the Software Toolbox.
1. Example 4-7 Pressure D
rop with Reaction -- N
umerical Solution
2. Exam
ple 4-8 Dehydrogenation in a Spherical Reactor
3. Exam
ple 4-9 Working in Term
s of Molar Flow
Rate in a PFR
4. Example 4-10 M
embrane Reactor
5. Exam
ple 4-11 Isothermal Sem
ibatch Reactor with a Second-O
rder Reaction
Professional Reference Shelf
-
CR
E -- Chapter Four
file:///H:/htm
l/04chap/html/four.htm
[05/12/2011 16:54:43]
1. Tim
e to Reach Steady State for a First Order Reaction in a C
STR
2. Recycle Reactors
3. Critiquing Journal Articles
Additional H
omew
ork Problems
CD
P4-AB
A sinister looking gentlem
an is interested in producing methyl perchlorate in a batch reactor. The reactor
has a strange and unsettling rate law. [2nd Ed. P4-28]
Solution Included
CD
P4-BC
Ecological Engineering. A m
uch more com
plicated version of problem 4-17 uses actual pond (C
STR)sizes and flow
rates in modeling the site w
ith CSTR
s for the Des Plaines river experim
ental wetlands site
(EW3) in order to degrade atrazine.
CD
P4-CB
The rate of binding ligands to receptors is studied in this application of reaction kinetics to bioengineering.The tim
e to bind 50% of the ligands to the receptros is required. [2nd Ed. P4-34]
CD
P4-DB
A batch reactor is used for the brom
ination of p-chlorophenyl isopropyl ether. Calculate the batch reaction
time. [2nd Ed. P4-29]
CD
P4-EB
California Professional Engineers Exam
Problem, in w
hich the reaction
B + H
2 A
is carried out in a batch reactor. [2nd Ed. P4-15]
CD
P4-FA
The gas-phase reaction
A + 2B
2D
has the rate law -rA = 2.5 C
A0.5C
B . Reactor volum
es of PFRs and C
STRs are required in this m
ulitpartproblem
. [2nd Ed. P4-21]
CD
P4-GB
What type and arrangem
ent of flow reactors should you use for a decom
position reaction with the rate law
-rA = k1 CA
0.5 / (1 + k2 CA )? [2nd Ed. P4-14]
CD
P4-HA
Verify that the liquid-phase reaction of 5, 6-benzoquinoline w
ith hydrogen is psuedo-first-order. [2nd Ed.P4-7]
-
CR
E -- Chapter Four
file:///H:/htm
l/04chap/html/four.htm
[05/12/2011 16:54:43]
CD
P4-IBThe liquid-phase reaction
2A + B
C
+ D
is carried out in a semibatch reactor. Plot the conversion, volum
e, and species concentrations as a functionof tim
e. Reactive distillation is also considered in part (e). [2nd Ed. P4-27]
CD
P4-JBThe reaction A
B
is catalyzed by H2 SO
4 . The reaction is carried out in a semibatch reactor, in w
hichA
is fed continuously to H2 SO
4 . Here plots of concentrations as a function of tim
e are required. [2nd Ed.P4-27]
CD
P4-KB
Calculate the overall conversion for a PFR w
ith recycle. [2nd Ed. P4-28]
CD
P4-LB
The overall conversion is required in a packed-bed reactor with recycle. [2nd Ed. P4-22]
CD
P4-MB
A recycle reactor is used for the reaction
A + B
C
in which species C
is partially condensed. The PFR reactor volum
e is required for a 50% conversion. [2nd
Ed. P4-32]