2.6 Elements and the Periodic Table • Elements in a group ...
Elements of group 3
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Transcript of Elements of group 3
74 Coordination C~e~is~~~ev~ews.30(1979}74-136 0 ElsevierScientific PublishingCompany, Amsterdam -PrintedinThe Netherlands
Chapter 3
tLt%.NTS OF GROUP 3
George Davidson
3.1 bORON .._...._...______.__ 75
3.1.1 boranes. _ _ . . _ _ _ . _ . _ _ _ _ _ _ _ . 3.1-2 Eorane Anions and Metallo-derivatives, _ _ _ :; 3-l-3 Carha- and other i\ion-metal beterokoranes _ _ 3.1.4 Metallo-heterohoranes. . _ _ . _ _ . . . . _ s8: 3.1.5 Compounds containing B-C fronds . . . . . . . 92 3.1.6 Atninotoranes and other Corrpounds containing 94
B-hBonds_._.__.__ __ _ _ ____ 3-l-7 Compounds containing b-P Bonds _ _ _ _ _ _ _ 3.1.8 Compounds containing B-O Eonds _ . . . _ . . 9"; 3.1-Y boron Halides. . _ _ . . _ _ _ _ _ . . _ _ _ 99 3.1.10 Boron-containing heterocycles . . . . . . . 101 3.1.11 boron Nitride, Metal Borides _ . . . . . . . 109
3.2 ALUMINIUW _ _ _ _ . _ _ . _ _ _ _ . c . _ _ _ 109
3.2.1 Aluminium Hydrides _ _ _ _ _ _ _ _ . _ . _ . 3.09 3.2.2 CoIfrpounds containing AR-C or AP-Ge Bonds . . 110 3.2.3 Compounds containing AQ-N or A&-P Bonds. . _ 111 3.2-4 Compounds containing A!Z-0 or At-Se Eonds . . 113 3.2.5 Aluminium hydrides . . . . . . . . . . . . . 116
3.3 GALLIUM . . . . . . _ . . . _ . . = . . . _ . 118
3.3.1 Compounds containing Ga-C Bonds . _ . _ . __ 118 3.3-2 Compounds containing Ga-N or Ga-P Bonds _ __ 118 3.3.3 Compounds containing Ga-0, Ga-S or Ga-Se
bonds............._ _ . . . . 13.9 3.3.4 Gallium halides. . . . . . . . . . . . . . . 120
3.4 IhDIUM..._..._ _.._ ___._ ._ _ I.21
3.4.1 General * _ _ _...I _ * _ 3-4-2 Compounds_c&;akng Gonds between Indium and
121
Atoms of Group 6 tlements . . . . . . . . . 122 3.4.3 Indiuxn halides . . . . _ . _ . . _ . . . . . 123
3.5 TBALLIW~.... . . _ . _ . . _ . _ _ . . . - - 124
3_5_1 Thallium (III) Compounds . . _ _ . . . _ _ _ 124 3.5-Z Thallium (I) Compounds . _ . _ _ . . . . . . 125
128
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