EAS 4/8803: Experimental Methods in AQ
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Transcript of EAS 4/8803: Experimental Methods in AQ
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EAS 4/8803: Experimental Methods in AQProf. Rodney WeberWeeks 1 4 Experiments 1 & 2Prof. Michael BerginWeeks 5 8 Experiments 3 & 4Dr. Karsten BaumannWeeks 8 11 Experiments 5 & 6
Handout: AQ Management in the US, NRC, Natl Acad Press, 2004 http://books.nap.edu/catalog/10728.html
Recommended: Baumbach, AQ Control, Springer 1996Seinfeld & Pandis, Atm Chem & Phys, Wiley 1998Finlayson-Pitts & Pitts, Chem of U & L Atmos, AP 1999Warneck, Chem of Natural Atmos, 2nd Ed, AP 2000Data and Findings from SCISSAP and FAQS http://cure.eas.gatech.edu/faqs/index.html
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EAS 4/8803: Experimental Methods in AQSo far:Measurement Errors and UncertaintiesRandom (Precision), Systematic (Accuracy), Rounding (DL), Comparing (Correlations)Flow Rate Measurements (Exp 1)Volumetric (cm3/s), Mass (g/s), Fs = Fa*Ta/Ts * Ps/Pa (Ideal Gas Law)PM Size & Number Distribution (Exp 2)Dp, Modes (UF, Fine, Coarse, Primary, Secondary)Methods (SMPS, APS, OPC, SEM, TEM )Aerosol Optical Properties (Exp 3 & 4)Scattering, Absorption, Extinction (Visibility, Climate)Methods (OPC, Nephelometer)
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EAS 4/8803: Experimental Methods in AQWeeks 8 - 11:Air Quality Management (AQM)Clean Air Act (History, Objectives, NAAQS)Emissions and Atmospheric Trends (Links)Principal Measurement Techniques (O3, NOx, CO, SO2, Pb, PM)Measurement of CO (Exp 5)NDIR Method (Interferences, Stability, DL, Precision, Accuracy)Controlling O3Why controlling O3 (Agriculture, Health)Photochemical Processes (NOx vs VOC sensitivities, limitations)Ambient Measurements and Trends (World, USA, GA)Measurement of O3 (Exp 6)UV Absorption (Interferences, Stability, DL, Precision, Accuracy)
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Clean Air Act (CAA) GoalsProtecting and promoting human health & public welfare by:Mitigating potentially harmful human and ecosystem exposure to six criteria pollutants: CO, NO2, SO2, O3, PM, and lead (Pb).Limiting the sources of and risks from exposure to HAPs (air toxics).Protecting and improving visibility impairment in wilderness areas and national parks.Reducing the emissions of species that cause acid rain, specifically SO2 and NOx.Curbing the use of chemicals that have the potential to deplete the stratospheric O3 layer.
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The Air Pollutants of Concern in AQMCarbon monoxide (CO)Sulfur dioxide (SO2)Nitrogen dioxide (NO2)Particulate matter (PM)Ozone (O3)Lead (Pb)Air toxics (solvents, fuels, metals, etc.)Haze
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Federal AQM Legislation History
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History: CAAs First NAAQS
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1990 CAA AmendmentsTitle I: Non-attainment regionsNon-attainment regions for O3 are ranked in terms of pollution severity; deadlines to achieve NAAQS. New and amended NAAQS must be attained in 5 years (possible 5-yr extension).Title II: Mobile sourcesGasoline reformulation to lower toxic and VOC by 1997.Reduction in NOx (60%) and HC (40%) LDV emissions; cold T (20F) CO emissions standards > 1994.Clean car (ZEV, electric car) pilot program in California (150,000/300,000 vehicles by model year 1996/99).Title III: ToxicsEmissions of 189 HAPs controlled. EPA-approved MACT mandated.Title IV: Acid rain (Electricity Generation Facilities)NOx: cut emissions by 2.0 x 106 tons/yr; SO2: reduce to 9.2 x 106 / 8.9 x 106 tons/yr (US total) by 2000 / 10.Phase I (beginning 1995): 110 large power plants; Phase II (beginning 2000): remaining unitsPolicy: market-based cap and trade rather than command and control. If a utility reduces SO2 emissions below their emissions allowance , the utility can sell their extra allowance to another utility.Title V: PermitsNew and existing major sources must secure permits, duration 5 yr. Fees to sustain state air pollution control agencies.Title VI: Stratospheric ozonePhase out chlorofluorocarbons, halons, and carbon tetrachloride by2000; CH3CCl3 / HCFCs by 2002 / 30Title VII: EnforcementLarger penalties.
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Process of Setting/Amending NAAQS
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History: NAAQS Reviews and Revisions
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NAAQS Effective January 2003Primary Standard (Health-Based) Secondary Std (Welfare-Based)Type LevelType LevelPM10 Annual arithmetic mean50 g/m3Same as primary24-hr avg not to be exceeded150 g/m3Same as primary more than 1/yr on avg over 3yr
PM2.5Spatial and annual 15 g/m3Same as primary arithmetic mean in area 98th percentile of 24-hr avg65 g/m3Same as primaryO3Maximum daily 1-hr avg to be 0.12 ppmSame as primary exceeded no more than 1/yr averaged over 3 consec years3-yr avg of the annual fourth0.08 ppmSame as primary highest daily 8-hr average
NO2 Annual arithmetic mean0.053 ppm Same as primary
SO2 Annual arithmetic mean 0.03 ppm3-hr 0.50 ppm24-hr average 0.14 ppmCO 8-hr (not to be exceeded more9 ppmNo secondary than once per year)1-hr (not to be exceeded more35 ppm No secondary than once per year)
Lead Maximum quarterly average1.5 g/m3 Same as primary
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Role of Science in AQM
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Four Topics of Concern for AQM
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Q: Why should we care about air quality? A: Each day a typical adult may consume...2 - 10 lbs. of food (1000 - 3000 calories); 1 - 6 lbs. of fluids (12 - 96 oz.);
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Concern: Human HealthAsthma is a chronic lung disease that affects a persons fundamental ability to breathe. Its prevalence in the U.S. population is epidemic. The percentage of the population with the disease has nearly doubled since 1980. In 2000, approximately 11 million people in the U.S. experienced an asthma attack. Morbidity & Mortality: 2002 Chart Book on Cardiovascular, Lung, and Blood Diseases; National Institutes of Health, National Heart, Lung, and Blood Institute; 2002.
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Concern: EconomicsThe estimated economic cost of asthma in the U.S. in 1998 was $11.3 billion. By 2002, this estimate had increased to $14.0 billion. This latter figure includes direct costs of $3.1 billion for hospital care, $2.6 billion for physicians services, and $3.7 billion for prescription drugs. Direct medical costs of asthma account for approximately 1% of all health care expenditures in the United States. The remaining $4.6 billion in costs are estimated indirect costs that include loss of productivity due to mortality, and decreases in productivity due to absences from work or school. Asthma and the Environment: A Strategy to Protect Children; Presidents Task Force on Environmental Health Risks and Safety Risks to Children; January 28, 1999; Revised May 2000.
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Link to AQ Ozone is one of many environmental factors that can trigger asthma attacks in those that have the disease. Studies show that ERVs for treatment of asthma increase by 30 to 40% when [O3] is elevated.
Romieu I, et al.; American J. Epidemiology; 141 (6): 546-553; 1995.Stieb DM, et al.; Env. Health Perspectives; 104 (12): 1354-1360; 1996.Thurston GD, et al.; J. Exposure Analysis and Env. Epidemiology; 2 (4): 429-450; 1992.Weisel CP, et al.; Env. Health Perspecitves; 103: 97-102 Suppl. 2; 1995.White MC, et al.; Env. Research; 65 (1): 56-68; 1994.Friedman MS, et al.; J. Am. Medical Assoc.; 285 (7): 897-905; 2001.Tolbert PE, et al.; Am. J. Epidemiology; 151 (8): 798-810; 2000.EPA 454/K-02-001; US EPA Office of Air Quality Planning and Standards (OAQPS); September 2002.
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Symptom: Human HealthEvidence of health impact of ozone on human respiratory system based on an experimental study involving human subjects. Left: A healthy lung airway, and right: A lung airway inflamed from exposure to ozone.Ozone and Your Health. EPA 452/F-99-003. Office of Air and Radiation, U.S. EPA: http://www.epa.gov/airnow/brochure.html
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Symptom: Ecological HealthCotton showing chronic response to ozone on the lower leaves after exposure to rel. low concentrations (e.g. < 40 ppb), with periodic, random, intermittent episodes of rel. high ozone concentrations (e.g. > 80 ppb) throughout the plant growth season. Krupa, S.V., A.E.G. Tonneijck, and W.J. Manning. 1998. Ozone. Pp. 2-1-2-28 in Recognition of Air Pollution Injury to Vegetation: A Pictorial Atlas, 2nd Ed, R.B. Flagler, et al., eds. Pittsburgh, PA: Air & Waste Management Association.
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Symptom: Buildings, Monuments & Parks
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Symptom: Visibility
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Symptom: VisibilityStandard visual range for the period 1996-1998 in units of kilometers. Visibility Information Exchange Web System, 2003.
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Link to AQLast (O3) non-attainment designations in 1991.
More than 90% of the affected population resided in 70 metro areas.
Average Size: ~2 million(Cincinnati)Median Size: ~1 million(Louisville)Largest: ~20 million (New York)Smallest: ~87,000 (Owensboro, KY)Counties in which the 1998 2nd daily maximum 1-h [O3] exceeds the 1-h average 120 ppb NAAQS. EPA 2000.
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Consequences of New O3 NAAQSCounties in which the 1998 4th daily maximum 8-h [O3] exceeds the 8-h average 80 ppb NAAQS. EPA 2000.In addition to most of the original 70 metro areas, ca. 60 additional metro areas may be impacted.
Of these 60 new metro areas
Average Size: ~360,000 (Madison, WI)Median Size: ~290,000 (Macon, GA)Largest: ~1.3 million (San Antonio)Smallest: ~74,000 (Victoria, TX)
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PM2.5 NAAQS will also impact many smaller citiesMonitors at which the 1999 annual average [PM2.5] exceeds (yellow and red) the 15 g/m3 annual average PM2.5 NAAQS.
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Annual Average PM2.5 in Urban Areas, 2002
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Annual Average PM2.5 in Rural Areas, 2002Source: IMPROVE Network, 2002
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Measurement SitesSouthern Center for theIntegratedStudy ofSecondary AirPollutants(US EPA)
Fall-lineAirQuality Study(GA-EPD)
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PM2.5 Seasonal Comparison: Suburban vs RuralFall-99Winter-99/00Summer-99Rural DixonSuburbanHendersonville Differences in composition are insignificant regionally but not seasonally Differences in mass related to different BL dynamics and SOA (Un-ID)
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32.5581275228
2.7460954353
12.618546291
1.6089523363
20.1202340236
8.0480936094
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SO4= NO3- NH4+ EC OC OOE LOA Others UnID
24.3 +-9.3
Atl Sum99
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6TOC.6+svocOthersUnID.4UnID.6UnID.6svMw/CwMw/Cw +svocNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6UnID.6svTOC.6+svocCheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%][%][%]
7/287/28/99 7:507/29/99 6:00132622.142.352.290.980.857.9110.053.506.470.0850.3555.411.8243.440.093.480.000.4610.490.800.400.0912.431.36XAD4.977.461.2818.6921.180.098.876.382.1-19372183324.11.18.03.128.611.43.00.214.743.048.733.2139.7
7/307/30/99 6:007/31/99 6:00121820.344.002.173.210.416.386.822.853.880.0954.2853.950.7143.360.054.220.080.7310.530.390.730.0012.932.02XAD5.177.761.1219.2221.810.136.513.921.9-23412219-324.31.79.74.729.811.92.60.315.044.350.333.4143.0
8/18/1/99 6:008/2/99 6:00144024.053.382.291.580.627.9616.137.049.070.0261.6459.001.9149.040.134.730.160.120.7612.760.910.550.2911.711.11XAD4.687.031.7518.1420.480.4111.128.782.3-262122661526.01.59.72.323.99.63.60.822.737.041.835.8137.2
8/38/3/99 6:038/4/99 6:01143721.3498327.30.1582.182.3824.1369.9125.52.812.471.100.523.1610.724.845.850.0342.4239.790.8132.240.033.980.000.000.5010.560.000.200.258.360.95XAD3.345.010.4512.1513.820.034.072.401.9-2218220732.71.612.32.925.910.41.40.112.637.742.945.0138.2
8/58/5/99 6:038/6/99 6:01143823.5698028.00.5572.182.5937.8355.1114.32.332.421.970.375.469.654.405.220.0363.3066.600.7750.780.025.670.060.010.6818.350.180.320.269.231.18XAD3.695.540.7613.6815.530.0911.139.282.6-314113827936.11.311.22.318.27.31.50.221.926.930.649.7129.1
8/78/7/99 6:038/7/99 18:0172012.0498330.1-0.3451.912.9825.9289.4152.22.934.460.711.089.309.313.725.580.0150.0674.190.9240.580.033.960.030.080.7613.240.460.430.027.970.653.86XAD3.194.780.9112.0813.6717.530.139.778.174.312.61.8-219122766832.61.99.81.619.77.92.20.324.129.833.744.910.643.2186.2
8/78/7/99 18:138/8/99 6:0170811.6798227.21.1622.290.0947.0228.62.521.125.310.262.9814.797.667.130.0058.8562.621.3147.810.025.090.000.000.6913.110.790.320.129.970.707.33XAD3.995.981.2315.2017.1924.530.0213.0011.013.672.71.6-28211273227.41.410.61.520.98.32.60.027.231.836.037.77.751.3191.7
8/98/9/99 6:038/10/99 6:00143723.8597827.3-0.0702.592.6726.0048.297.02.062.141.160.567.526.453.033.410.0238.1440.721.1731.300.003.380.030.000.499.850.160.320.126.000.753.55XAD2.403.600.608.9910.1913.740.037.816.613.062.71.7-18782052631.51.610.82.419.27.71.90.124.928.732.643.39.843.9183.2
8/108/10/99 18:018/11/99 5:5872011.8497925.80.4873.030.0820.4633.275.00.610.331.110.080.666.172.783.350.0458.2055.751.0745.110.016.390.020.7016.870.320.380.2010.841.120.70XAD4.346.500.9016.0718.2418.940.033.931.761.061.81.7-35411351837.41.514.22.524.09.62.00.18.735.640.451.42.342.0180.6
8/118/11/99 6:048/12/99 6:00143623.9598029.1-0.1632.542.9541.1147.0121.01.951.991.830.729.2511.495.456.020.0257.6648.642.0140.440.074.380.000.090.7411.520.750.600.249.170.873.93XAD3.675.501.5814.4216.2620.180.168.356.522.592.31.6-24312240928.51.810.82.122.79.13.90.420.635.740.239.26.449.9192.0
8/138/13/99 6:028/13/99 17:4370111.8098030.9-0.5602.772.5338.7760.8105.01.902.870.870.708.7912.645.437.210.0039.6144.491.5237.110.003.140.190.000.698.490.000.590.0010.121.582.37XAD4.056.070.5914.7516.7719.140.198.266.243.872.21.8-174111771422.91.98.54.327.310.91.60.522.339.745.231.510.451.6200.7
8/138/13/99 18:008/14/99 6:5677612.7697926.60.4732.670.0545.3733.41.200.911.950.251.717.063.393.670.0019.2620.910.6919.960.002.460.040.000.525.860.000.000.000.000.000.000.000.000.0411.0711.07-1368122-629.42.612.30.00.255.50.00.040.495.9
8/158/15/99 6:028/15/99 17:4570311.6698227.8-0.4552.033.3712.4974.1115.03.222.640.260.482.648.123.444.670.0219.9633.223.1223.080.003.000.000.000.445.700.990.810.006.650.26XAD2.663.991.8111.1112.440.002.561.231.8-1667119-4024.71.913.01.128.811.57.80.011.148.253.934.0147.2
8/158/15/99 17:598/16/99 6:0072111.9498428.70.7632.550.0735.7545.22.971.201.250.261.1710.624.915.710.0028.9543.682.7734.170.103.390.000.000.257.601.290.770.0014.360.68XAD5.748.612.0622.1525.030.10-0.00-2.871.4-1884158-2622.20.79.92.042.016.86.00.3-0.064.873.230.6168.7
8/178/17/99 6:018/18/99 6:00143923.7898427.7-0.6592.222.4840.6753.6138.02.373.181.500.556.0312.835.767.020.0540.3846.561.7542.130.113.870.000.000.6311.300.570.530.0910.550.943.82XAD4.226.331.1815.9518.0621.880.119.337.223.402.31.7-214102353126.81.59.22.225.010.02.80.322.137.942.936.98.151.9199.8
8/188/18/99 10:028/18/99 17:004187.1398033.4-1.6341.832.8817.57122.9136.01.994.670.130.286.0010.603.616.790.2028.8430.625.9435.670.003.640.000.002.069.752.671.410.247.810.401.13XAD3.134.694.3215.2616.8317.950.004.563.001.872.01.7-202332033527.35.810.21.121.98.812.10.012.842.847.237.65.250.3195.9
8/198/19/99 6:028/19/99 18:0071812.0898030.5-0.8441.872.6534.8894.3182.02.817.130.040.355.8610.833.707.020.1035.1234.755.4240.360.033.960.160.001.4910.252.950.880.278.751.634.98XAD3.505.254.1016.3518.1023.080.196.494.74-0.242.11.4-220242131825.43.79.84.021.78.710.20.516.140.544.834.9-0.657.2193.0
8/218/21/99 6:028/22/99 6:00143823.6598225.8-0.6521.693.2431.7650.6110.01.862.510.660.385.186.372.673.630.0627.8934.352.2630.140.084.300.000.030.7113.151.170.440.245.340.603.89XAD2.143.201.859.3210.3914.280.111.950.88-3.011.81.0-239112744743.62.314.32.017.77.16.10.46.530.934.560.0-10.047.4169.3
8/238/23/99 6:028/24/99 6:00143823.5998125.2-0.4752.482.2424.5049.999.01.630.350.650.212.077.413.264.090.0626.4435.862.2328.670.013.400.000.001.1110.840.320.590.266.250.614.20XAD2.503.751.179.9211.1715.370.012.791.54-2.661.81.1-188182265537.83.911.92.121.88.74.10.09.734.639.052.0-9.353.6179.6
8/258/25/99 6:028/26/99 6:00143823.4098022.9-0.5912.652.6823.1023.951.01.290.680.560.114.452.861.211.650.0019.841.2721.110.041.460.000.011.025.190.240.500.003.450.793.20XAD1.382.070.745.576.269.460.057.036.343.143.41.8-81161084324.64.86.93.716.36.53.50.233.326.429.633.814.944.8182.8
8/278/27/99 6:028/28/99 6:00143823.5098224.4-0.6651.983.0030.3344.0100.02.752.091.010.314.436.122.623.430.0735.6643.712.2837.930.004.930.080.040.8715.020.720.660.126.860.854.89XAD2.744.111.5011.1012.4717.360.125.043.67-1.222.11.2-274143135339.62.313.02.218.17.23.90.313.329.332.954.5-3.245.8172.4
8/298/29/99 6:028/30/99 6:00143823.7098226.5-0.3632.202.7119.2153.0105.04.161.701.120.252.848.033.504.530.0034.7347.090.3435.070.005.050.030.000.1016.180.140.150.046.460.453.26XAD2.593.880.329.3710.6613.930.033.892.59-0.672.01.3-28023375846.10.314.41.318.47.40.90.111.126.730.463.5-1.939.7169.5
8/318/31/99 6:029/1/99 6:00143823.2398522.4-0.2491.343.1527.1339.792.02.571.940.890.282.315.262.133.130.0013.6815.680.8715.550.051.090.000.040.312.220.280.280.105.470.561.22XAD2.193.280.658.319.4010.620.092.981.890.661.91.6-60546-914.32.07.03.635.114.14.20.619.253.460.419.64.368.3225.2
AVG28-Jul-9931-Aug-992318.698126.8-0.2632.232.4030.2052.3112.82.452.181.300.435.078.923.885.000.0435.720.043.860.040.030.6811.010.590.480.148.420.913.553.375.051.2013.0314.7116.420.106.614.621.032.11.50-214112292630.52.010.72.623.59.43.60.317.236.441.141.93.049.4171.999.7
StDev6.022.30.4120.400.818.1915.729.80.831.070.820.222.443.381.571.870.039.910.041.270.050.040.304.060.510.210.112.820.381.241.131.690.694.174.734.270.103.253.112.520.70.2770585288.41.12.30.95.82.31.90.27.48.59.611.68.27.832.7
AVG for XAD days w/ backup33.760.033.750.030.020.7410.950.630.490.137.260.793.552.904.361.2511.4112.8616.420.086.034.581.032.271.50-208122283230.81.910.82.623.69.43.40.318.536.541.242.441.246.0189.1101.3
23Site: Atlanta, GA, Jefferson St
Blue Numbers indicate Final Results KB data where denuder inefficiencies were taken into accountMeasurement Period: July 28 through August 31, 1999
Bold blue numbers indicate HONO/HNO3 calculated from nitrite/nitrate difference between D1 and D2# of samples: 23
Plum numbers indicate consideration of average denuder inefficiencies, average of ion conc from both teflons, and partial IC reruns
AVGSTD
35.729.91
5.072.44ppbv
2.181.07ppbv
2.450.83ppbv
Atl Sum99
2.34678894412.28683295210.97772454990.84562942557.91223506873.50156305556.47085822030.0765893682
4.00219015332.16849783323.20640800480.40749074156.38018603132.85123273573.87781345290.0883025194
3.37594874652.29172404481.58229778230.61814296867.96011580167.03584266979.07209957430.0204955413
2.81258805012.47411345771.10497193470.51882845263.1631719714.83965452515.85229151880.0300714198
2.33319872562.41799374361.96790782620.36626809025.45680780354.40392041475.21955592570.0259711338
2.92509266654.46036261030.71129399441.0775606039.29940792293.72197946275.582136350.0104519182
2.51521007341.11622587045.30965512720.25532697152.98125476447.66300891797.12644525470
2.06319448792.14291264611.15623005370.5574050577.52117530073.02696598213.40741971760.0176340078
0.61374762060.32549243021.11374815260.08205061430.66302420692.77504313613.35352970170.0383351196
1.94917295231.98915647591.83042634780.71545457679.24525653365.44685308136.02327279420.0159274761
1.89614319022.86570152460.86883093260.69753928378.78969917165.42641364267.21015300490.0027263035
1.20004835340.91277123251.94843033780.25097511441.70980449373.38600904543.6728643510
3.21806759692.64331609870.26420627030.48315888692.63797071063.43542449214.66658815450.0167294128
2.97411528661.2008438051.25089041660.25929544441.17044897994.9118922675.70679727580
2.36696766893.17683761431.50239346070.55252254416.02504814755.76331559647.01700865740.046998373
1.98922852054.67455170670.13228096850.28207900225.99906504373.61134708766.78789781450.2045324704
2.80831678337.12548512190.04464248470.35167209795.86052905513.70316515967.02475478230.0998055999
1.85858734042.51008136690.66200875990.37717129395.17899793362.66815317263.63370157710.0647210519
1.6290925230.3483210820.65004045840.20590813622.07076060313.25863186734.09392890860.057285096
1.28949934590.67577460330.55691531060.11410523774.45163533721.20852284671.6475009950.0044395037
2.75359021632.09037559051.01056430060.31331347694.42774128972.62279346383.4339177920.0665727426
4.16264720871.69541099761.11907095480.24621879722.83981755153.50049842144.52850906670
2.57310339541.94002434590.89066739110.2765083352.30524533772.13150631833.1282136390
2.45433825072.17736095551.29887824020.43121503795.06657967393.87894252065.00369266680.0353501879
AM
PM
AM
AM
PM
PM
NH3
HNO3
HONO
HCl
SO2
Acetic
Formic
Oxalic
[ppbv]
Gases - Atlanta Summer '99
HV Sum99
0.09265561467/283.47861602200.456405023710.49073957510.79896698170.39580341850.08705868412.43386530114.97354612041.36347215078.8695430715
0.05295218237/304.21948685270.08000616010.729032544110.52778283570.38860553760.7320086122012.92965655035.17186262012.01976184736.5064266754
0.12811473360.16343150384.73372998930.11740151560.755958279912.76165807290.90818190210.54908707280.28825646111.71124119994.684496481.112832874211.1208313887
0.02875119690.0022945823.981519659700.503234455210.559419971900.20335700670.2494342828.35530673373.34212269350.94901418824.0690175362
0.0238181570.05878216815.67187654610.00735879320.68338914718.35021825350.17506141990.31799078150.26369269649.2336137793.69344551161.177637290311.1257625895
0.02699908850.02828780583.9596196010.07741839510.756092176213.24089655030.46395326580.42942885080.01743840537.97451598233.18980639290.64747384249.7651305945
0.017124170405.089560720400.688392092713.11164826230.78592704770.32286909210.12462377619.97369708513.98947883410.701057153113.0025114521
00.02830795283.381863374100.49392754519.85261245510.15689241780.31754431770.12378533925.99537873262.39815149310.747984417.8052485454
0.01254711538/106.39107928580.01654381040.695567962616.87239797110.31619799650.37993570710.198917571810.84070460214.33628184081.12266196533.9297211159
0.074160503704.37934886540.08896971290.743601660811.51817632870.74565324980.59682497830.23883633759.17159108093.66863643240.86603954748.3502847564
00.19486490273.142485407900.6931140598.490151911700.5864348512010.11577915644.04631166261.58023003938.2645510598
00.03572960942.461805594100.52155389885.86330011120008/1308/1311.073484433
003.000156865600.44457296795.70451310850.99403712190.811472165306.64864070422.65945628170.25751777382.5550173501
0.096897104303.389675705100.24951469117.5986475351.28598435450.769201097014.35658311425.74263324570.6808990384-0
0.114763565603.865701791700.628093833411.29856185050.5670839410.52964081210.087303379910.55050589324.22020235730.94077268089.3299415984
003.636053575102.06053718379.75073577062.67337256751.40936879080.24207040677.81283982173.12513592870.39534852114.5600515975
0.02772392510.16205491063.962771051901.486910423110.24808955342.9456065860.88199687140.27015582888.75068210413.50027284161.62881759326.492321524
0.083874453604.30303234330.02732961090.70834256813.15240585851.16777062250.44160630120.24159658385.33755211382.13502084550.59887567291.9475347894
0.009825999703.39762765101.106673283710.83691921860.32272282660.58829186770.25956807696.24931346192.49972538480.60854737832.7923589662
0.041358058701.46483402610.01083776181.02007095455.19339899680.23525393210.50324847203.44909408711.37963763490.78684307657.0297622544
00.07970569564.93396240630.03795205780.870485652415.02394327630.72052660350.66150925830.11595428766.85778664522.74311465810.8513519385.0382154193
00.02520324575.053012782800.102427753716.1833281160.13621429490.14732439370.03737053736.46307612422.58523044970.45212550463.8857570615
0.045673060501.09030149410.04054086380.30561076722.22146572180.28072033210.27509749010.09811313745.46531323432.18612529370.5646924172.9788537408
0.04269186130.03590467183.86214005160.02504335560.682300585311.00881446210.58876137650.47588278420.13608544418.42041594213.36816637680.91397285776.6145144549
AM
AM
AM
PM
PM
PM
Na+
Ca++
NH4+
Cl-
NO3-
SO4=
Acetate
Formate
Oxalate
OC
OOE.4
EC
UnID.4
[mg m-3]
Atlanta PM2.5 Summer 1999
DX Sum99
218.42056163127.3601842237-192.82793913332.952806722-192.827939133
219.191814193111.7566931797-233.8961669984-2.9476596256-233.8961669984
265.701812885312.190909206-262.401884107515.4908379839-262.4018841075
219.85050951258.1153758294-220.70508091657.2608044253-220.7050809165
382.057427722111.0206280757-314.405573507478.6724822904-314.4055735074
275.679711644312.1930684767-219.491108704268.3816714168-219.4911087042
272.988720847311.1013077366-282.12642574171.9636028422-282.1264257417
205.13455038827.9652885842-187.464710313625.6351286588-187.4647103136
351.288735604811.2170289087-354.2726876838.2330768305-354.272687683
239.812124271311.991641039-242.75769763719.0460676731-242.7576976371
176.767685023111.1774562004-174.195421723513.7497195-174.1954217235
122.0757882838.4108030774-136.4637247284-5.9771333681-136.4637247284
118.76979197397.1693753891-166.3058129491-40.3666455861-166.3058129491
158.20627805474.0237815054-187.8977663606-25.6677068005-187.8977663606
235.23968041910.1289120041-214.285021712431.0835707107-214.2850217124
203.013445151533.2291111713-201.555076225434.6874800973-201.5550762254
213.368510376923.9785586691-219.665801105217.6812679408-219.6658011052
273.837307067911.4230377039-238.527291756746.7330530151-238.5272917567
225.628132804917.8466905938-188.338561583755.1362618151-188.3385615837
108.128232287816.4501040878-81.199225395143.3791109804-81.1992253951
312.803316184714.0378270017-273.501242032453.3399011539-273.5012420324
336.94208028251.6517941256-280.100486852458.4933875558-280.1004868524
46.25162860394.928411017-60.4379985667-9.2579589458-60.4379985667
229.207046888411.0030734607-214.08758600726.1225343422-214.087586007
AM
AM
AM
PM
PM
PM
SO4=
NO3-
NH4+
Net Acidity
[ne m-3]
Net Acidity/Components of Acidity - Atlanta Summer '99
HV Fall99
30.469458752
2.0245884923
10.7032098963
2.5589559363
23.4886330542
9.3954532217
3.5583380689
0.2717656869
17.2284733195
Atlanta Supersite Mass Composition Summer 1999
DX Fall99
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwOOEsv/OCNet AcidityECOCOOELOAOthersUnIDTOC.4TOC.6CheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%]
7/27/2/99 10:407/3/99 6:00115519.13100426.626.182801.03.515116131.00.330.450.250.251.795.182.182.930.0721.6419.613.9919.980.241.930.000.763.301.521.660.183.630.16XX1.452.183.368.439.160.245.174.442.8-1071269-2616.53.89.60.818.17.316.81.225.942.245.822.7136.6
7/47/4/99 6:007/5/99 6:00144023.92100928.427.973720.71.116211180.02.230.580.540.502.635.982.503.480.0045.9642.711.5236.390.164.190.231.1210.230.260.510.006.490.26XX2.603.890.779.8611.150.3910.349.053.0-23218213-128.13.111.50.717.87.12.11.128.427.130.738.7124.8
7/67/6/99 6:007/7/99 6:00144024.03100928.627.869691.12.029830093.01.801.540.270.312.046.422.913.410.1123.7924.080.6519.280.051.220.070.000.474.110.000.230.005.770.47XX2.313.460.238.319.460.124.583.432.2-688862521.32.46.32.429.912.01.20.623.843.149.129.3145.2
7/87/8/99 9:007/9/99 6:0084014.01100527.526.673731.02.318918980.00.692.130.250.425.196.892.654.060.1835.1437.741.2929.800.001.770.120.000.109.050.450.720.005.590.52XX2.243.361.179.0010.120.129.248.123.1-9821889230.40.36.01.818.87.53.90.431.030.233.941.8136.9
7/107/10/99 6:007/11/99 6:00144025.1352.01.890.620.320.072.136.163.003.090.0731.4626.620.5423.340.002.340.000.070.606.390.000.020.004.280.32XX1.712.570.026.016.870.077.606.743.2-130101331327.42.610.01.418.37.30.10.332.625.829.437.7125.4
7/127/12/99 6:007/13/99 6:00144025.1369.01.091.120.530.132.314.031.582.400.0535.2441.391.1231.380.003.580.090.070.5110.040.290.430.045.040.50XX2.023.030.777.828.830.168.777.773.1-19882091932.01.611.41.616.16.42.40.528.024.928.144.0125.1
7/147/14/99 6:007/15/99 6:00144025.1391.00.670.830.830.202.883.411.411.900.1045.1547.650.7637.160.004.630.020.020.5615.670.120.770.174.200.59XX1.682.521.066.947.780.058.727.883.5-25693267942.21.512.51.611.34.52.80.123.518.720.958.0121.1
7/167/16/99 6:007/17/99 6:00144025.1386.00.570.260.430.370.351.860.631.220.0017.5218.490.4514.390.013.200.000.000.245.220.000.000.002.270.22XX0.911.360.003.173.630.012.321.872.4-1784109-6536.31.722.31.515.76.30.00.116.222.025.249.9113.3
7/197/19/99 6:457/20/99 6:005509.19100928.727.872720.61.719723478.01.611.601.010.313.499.293.236.060.0030.7067.360.1925.530.001.510.000.000.198.561.950.000.008.781.02XX3.515.271.9514.2416.000.00-0.00-1.761.4-8431789733.50.75.94.034.413.87.60.0-0.055.862.746.1164.6
7/227/22/99 6:007/22/99 18:30550.84100929.027.873740.51.422424373.02.322.450.740.315.8621.416.8814.530.0040.5536.1118.6059.380.000.000.000.007.102.0212.2317.500.0013.371.82XX5.358.0229.7348.4551.120.000.00-2.671.40114421573.412.00.03.122.59.050.10.00.081.686.14.7172.4
7/257/25/99 7:307/26/99 1:204307.17101331.429.264681.22.1182167103.04.593.210.471.1618.718.874.164.710.0047.0249.422.2739.860.004.740.040.001.5010.360.000.001.097.010.30XX2.804.211.0910.9012.300.0412.0010.603.1-26324216-2326.03.811.90.817.67.02.70.130.127.330.935.8124.1
7/277/27/99 12:107/28/99 6:003956.52101027.928.471640.71.5299209109.03.031.311.540.370.607.984.393.590.0037.8142.021.1431.310.002.830.590.142.547.190.000.000.009.690.61XX3.885.820.0013.5715.510.733.851.911.8-157411503422.98.19.01.931.012.40.02.312.343.349.531.6136.7
7/317/31/99 7:008/1/99 2:003055.08101832.931.459610.82.422124689.02.671.690.850.412.0117.026.4010.620.0040.5343.423.9436.100.002.260.070.000.677.172.552.292.9411.500.91XX4.606.907.7823.8826.180.071.14-1.161.5-125111493519.91.86.32.531.912.721.50.23.266.172.527.3169.1
8/68/6/99 7:508/6/99 17:155659.38101231.128.837401.32.018417398.01.282.840.100.395.146.642.713.920.0026.4631.190.8523.290.022.200.100.000.677.590.000.270.004.260.42XX1.702.550.276.237.080.126.065.212.8-122111584732.62.99.41.818.37.31.10.526.026.730.444.8128.0
8/118/11/99 12:208/12/99 9:00124020.61100426.625.982830.71.419316279.02.620.481.640.234.296.263.262.990.0028.5122.101.2420.990.002.641.710.041.185.460.170.100.013.870.44XX1.552.320.285.696.471.753.833.062.4-14619114-1326.05.612.62.118.47.41.38.318.327.130.835.8112.0
8/158/15/99 6:008/16/99 6:00144023.7499421.922.570631.32.4184255.00.860.660.650.130.881.840.850.980.0019.7318.390.4915.490.002.220.000.000.246.210.060.140.002.750.39XX1.101.650.204.054.600.002.381.832.3-12341291040.11.514.42.517.87.11.30.015.426.229.755.1126.4
8/218/21/99 6:008/22/99 6:00144023.70100023.424.257491.11.9164769.01.321.060.670.391.723.151.531.580.0416.8414.560.6913.000.001.560.010.000.294.050.370.210.003.590.22XX1.432.150.585.606.320.011.260.541.8-87584331.22.312.01.727.611.04.50.19.743.148.642.9144.3
8/278/27/99 6:008/28/99 18:00160526.44100825.726.064591.01.7296891.00.762.240.480.356.503.931.632.300.0043.1346.771.1536.540.005.870.020.000.4318.600.340.160.214.970.47XX1.992.980.717.678.660.023.482.492.1-32573876950.91.216.11.313.65.41.90.09.521.023.770.0124.3
9/29/2/99 18:009/3/99 18:00144023.63100525.826.452450.91.434273104.01.271.870.350.252.847.643.274.370.0022.9524.990.6820.120.003.370.100.050.497.700.640.000.005.230.44XX2.093.140.647.979.010.15-0.00-1.051.4-1878160-1838.32.416.72.226.010.43.20.7-0.039.644.852.7137.1
9/89/8/99 18:009/9/99 18:00144023.91100426.626.045431.93.533834770.02.211.150.630.235.834.802.202.600.0012.9912.550.8211.990.002.210.260.000.834.320.640.000.002.660.004.94XX1.061.600.644.364.900.26-0.00-0.531.4-1221390-1936.16.918.40.022.28.95.32.2-0.036.440.949.6126.9
AVG2-Jul-998-Sep-992018.1100526.626.465621.02.180.01.451.180.580.293.265.262.282.940.0429.3330.431.1324.340.032.940.160.030.638.040.410.370.104.680.390.331.872.810.897.448.380.224.683.742.4-163101671432.62.712.61.620.18.03.51.017.831.735.744.8130.0100.0
StDev8.552.41.812140.30.819.20.740.670.330.142.272.080.941.190.0511.2013.160.829.270.061.360.390.060.354.700.440.460.211.490.181.320.600.900.912.512.790.403.503.390.775698418.91.74.30.75.72.33.81.910.79.310.412.210.8
2033.02.612.11.619.27.73.60.919.230.634.445.4130.0100.0
Site: Hendersonville, TN
Measurement Period: July 2 through September 8, 1999
# of samples: 20
AVGSTD
24.349.27
3.262.27ppbv
1.180.67ppbv
1.450.74ppbv
Karsten Baumann:only til 9/1 00:00
DX Fall99
SO4= NO3- NH4+ EC OC OOE LOA Others UnID
24.3 +-9.3
HV Win99
0.33052790050.45117594620.25215962350.24602027051.79418215462.17695927352.92833705560.0725174182
2.22531133440.58055380560.53649167940.49633443392.6269864792.49950690773.4774767260
1.80407464741.54044713190.26793483670.30600435432.03690137132.90737400183.40972591960.1060385782
0.69038514022.13122010780.24827878080.41756254565.18869199512.65487011894.05901237910.180195821
1.88648761220.62062100250.32232385420.07242945092.12933590993.00057295423.09160225620.0706711707
1.0863304791.11716588160.530141940.12752479742.31058992211.58132836152.40215330940.0506313336
0.67234444430.83289426910.83311809860.20244420512.88304770311.4149370081.89924200750.0987313922
0.56810058260.26320370820.42726354240.36641766470.34955443080.63299037181.22356863990
1.60803637641.60280701561.00734314830.30869873813.48857468833.22864147426.06451987040
2.31731538122.45463864880.74439467990.30841014625.85912393286.880458637314.52832915720
4.59074270053.21451039230.46584083711.159904163818.7123196864.16216558364.70925650260
3.03468066141.30991313161.53830807650.37266871440.60384617174.39209308323.59019327770
2.66699869221.68527096450.84682056290.41318203762.01026438146.395850678110.62400892480
1.27924900032.84068952310.10497220230.38935858635.13657009262.71159887593.92433403760
2.62145697360.48075473381.64082264890.23158023054.29478139473.2616389382.98984265760.0036920566
0.8614909630.6648382550.64695572330.12566845080.88374143520.85263802490.98353781360
1.32171349591.06498309460.67294357880.38866817081.72191137371.52849487561.5804982020.0437769001
0.75728776362.2350749680.48342852570.34561358956.49999929351.62618000042.29983015240
1.26802741261.87293782110.3493882440.24701188032.84414991483.26941141324.36608430020
2.21110192521.14563358530.63407259190.2300585215.83187120742.19764167372.60359809340
1.44715473461.18396874590.58256953360.29459528063.26090696532.28387899372.93777324880.0358534521
SO2 = 18.6 ppbv
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[ppbv]
Hendersonville Gases Summer 1999
DX Win99
7/20.23821929961.925640143700.75917759843.29706094031.51580253611.661411710.18050371293.62511315551.45004526220.15918660565.1673253716
7/40.15798617154.18569442450.23352703571.123053571710.22928616560.26310169810.509880686706.48757049542.59502819810.259502819810.3429813904
0.07421369070.0466826051.221930580100.47214903194.112320696400.233374304405.76552096862.30620838750.4651466124.5795337695
0.121392506101.773952171800.09585353289.05025855910.44759262210.718575880805.59414722392.23765888960.52290970529.241347606
002.33671580260.07173945130.6043873716.393234697500.021640053904.2795683591.71182734360.323710947.6009105754
0.091740708803.57684489880.06820445380.505493408110.04126616080.28839573520.43371886550.04376423875.04220938712.01688375480.49928297528.7734725938
0.0247785604.62649244610.02171537740.563282831915.67199879940.1184601540.76950685990.16895358084.20275559361.68110223740.58706899288.7205882019
00.00845947523.204313377700.24208220965.22147759770002.26597657980.90639063190.21946504412.3249072973
001.513255021700.1868226338.55796657151.951105476008.78101580593.51240632241.0224470459-0
00007.09770334262.02230608712.232919078317.5005515373013.3677622475.34710489881.815375120
0.044158250304.744353452601.503157233710.3635084525001.08696716087.00857977492.80343190990.304720859811.997413346
0.591020483502.83079836050.13999366992.53622908697.18521908140009.69437845413.87775138170.60984159473.8468872439
0.069991879402.262321612500.66692518317.17177605212.55174585232.28931923332.937452254311.50072609754.6002904390.91360908251.1373058629
0.10287263910.01632812132.200058324800.67378034117.588236961500.265654050704.25805842731.70322337090.41779055016.0621601593
1.70932106302.63609596540.04022491941.17875732515.46338502460.16661164740.0996464480.01196434693.86801799751.5472071990.43649508653.8336384007
002.223640619300.2386355826.21074578260.05694683170.139198106602.75379659361.10151863740.38506477792.3825295439
0.01414588701.561312738300.29338009924.05064149140.36647849390.214707227903.58737395521.43494958210.21547538371.2566156912
0.015534177105.868614366600.434784718518.60448941820.34084340070.15584826520.21251063544.97113617911.98845447160.46603620413.4819680517
0.103911179603.36752173720.04525595750.4913291117.70265004660.6416347901005.23143064652.09257225860.4407857307-0
0.261085823202.209019233200.82648458174.32469995110.6410913509002.65951541711.06380616680-0
0.15779912270.02745001682.94266980150.03432745020.62957511538.03771738730.40975765630.37376124220.10371539584.68242423591.87296969440.3876825794.6767449565
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[mg m-3]
Hendersonville PM2.5 Summer 1999
Mac Jun00
68.645865924312.2428253246-106.7428017561-25.8541105073-106.7428017561
212.977017814918.1108461809-232.0229725306-0.9351085348-232.0229725306
85.6198354447.614078889-67.734511093825.4994032393-67.7345110938
188.42928501051.5457754041-98.334377594291.6406828203-98.3343775942
133.10919628419.7466113692-129.529700808113.3261068453-129.5297008081
209.06238102828.1518046776-198.272998825518.9411868802-198.2729988255
326.29603996159.0837418463-256.457452668978.9223291389-256.4574526689
108.71283776273.9039221027-177.6226927784-65.005932913-177.6226927784
178.17960798393.012782341-83.883316060397.3090742646-83.8833160603
42.1050611483114.46062477960156.56568592790
215.771568862524.2405617434-262.9907678825-22.9786372766-262.9907678825
149.59856509240.9003239296-156.917869209133.5810198124-156.9178692091
149.318676912310.755123094-125.405854353134.6679456531-125.4058543531
157.989526577210.8656723293-121.954452592646.9007463138-121.9544525926
113.749427952519.0091489298-146.1250535153-13.366476633-146.1250535153
129.30971856423.8483402998-123.26167512989.8963837342-123.2616751298
84.33565461954.7311739911-86.54726930512.5195593055-86.5472693051
387.3514348997.0115258595-325.311217661969.0517430965-325.3112176619
160.37164369467.9233851156-186.6697193547-18.3746905445-186.6697193547
90.041639623313.3282467615-122.4511770055-19.0812906207-122.4511770055
167.347853160810.152799796-163.119168600114.3814843566-163.1191686001
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[ne m-3]
Hendersonville Net Acidity/Components of Acidity Summer 1999
Aug Junl00
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID6svMw/CwOOEsv/OCNet AcidityECOCOOELOAOthersUnIDTOC.4TOC.6CheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%]
6/156/15/99 6:006/16/99 6:00144024.001.2823.3823.330.3318.780.001.880.000.000.905.690.190.112.340.17XAD0.941.400.303.584.050.006.556.084.2-104151192930.34.810.00.912.55.01.60.034.919.121.641.7117.2
6/186/18/99 6:006/19/99 6:00144024.0099019.0571.3561.440.920.170.202.655.431.073.750.6125.0022.710.3619.260.001.700.000.000.866.700.000.000.002.700.29XAD1.081.620.003.784.320.005.935.393.6-94141405934.84.58.81.514.05.60.00.030.819.622.447.9120.7
7/27/2/99 16:197/3/99 6:0082213.82100424.6901.016424.01.450.340.111.672.931.261.680.0023.5821.821.2718.980.000.430.000.001.352.340.000.760.002.500.00XX1.001.500.764.264.760.0010.6010.105.6-2422494712.37.12.30.013.25.34.00.055.822.525.117.0120.4
7/47/4/99 6:007/5/99 6:00143823.85100926.1830.619051.01.300.500.170.271.217.002.804.200.0026.1726.042.5323.060.092.050.000.000.535.691.861.740.005.330.00XX2.133.203.6011.0712.130.093.642.572.1-11491181324.72.38.90.023.19.315.60.415.848.052.633.9150.3
7/67/6/99 6:007/7/99 6:00142923.57100926.8820.828653.01.350.920.220.330.818.223.504.580.1425.1111.601.7321.440.081.350.000.000.421.970.420.810.096.660.00XX2.664.001.3110.6411.970.086.995.662.4-75741-279.21.96.30.031.112.46.10.432.649.655.812.7150.7
7/107/10/99 6:007/11/99 6:00132622.4199422.8921.430139.01.110.490.150.071.995.102.252.740.1223.8624.170.7919.690.001.800.050.000.515.550.000.430.003.650.14XX1.462.190.435.546.270.056.105.373.1-10081152428.22.69.10.718.67.42.20.231.028.231.938.8129.8
7/127/12/99 7:207/13/99 7:19129921.68100421.9741.232570.00.931.430.000.275.254.561.642.810.1140.2845.590.8134.540.023.690.120.000.4713.320.160.330.250.150.00XX0.060.090.740.950.970.1415.9715.94111.0-20582778038.61.410.70.00.40.22.10.446.22.72.853.1104.9
7/147/14/99 6:007/15/99 6:00137022.84100222.7860.720474.00.470.290.390.151.706.452.843.530.0968.1475.002.1058.610.005.630.040.000.3722.970.740.980.496.040.49XX2.413.622.2110.6611.870.0418.4417.244.5-312647817239.20.69.60.810.34.13.80.131.518.220.353.9123.8
7/167/16/99 6:007/17/99 6:00143623.78101424.6830.816573.00.241.470.250.252.076.802.893.910.0055.3659.150.7645.860.085.260.000.010.3218.650.190.170.007.340.43XX2.934.400.3610.6312.100.0910.489.012.8-291538810240.70.711.50.916.06.40.80.222.923.226.455.9128.3
7/197/19/99 6:007/20/99 6:00139623.21101226.8781.024065.00.780.710.190.121.2410.264.086.180.0031.1030.821.3725.660.001.530.030.000.186.151.790.360.495.730.00XX2.293.442.6410.6711.820.037.115.962.6-8531284624.00.76.00.022.38.910.30.127.741.646.033.0148.3
7/227/22/99 6:007/23/99 6:00143023.8399727.8761.126863.01.090.990.280.180.6311.834.557.070.2133.1433.712.2428.650.001.830.000.000.516.140.650.681.276.320.07XX2.533.792.6011.4412.700.008.657.392.8-10281283521.41.86.40.222.08.89.10.030.239.944.329.5143.9
7/257/25/99 6:007/26/99 6:00139522.81101126.6830.726979.01.581.590.190.222.5510.494.386.110.0050.9253.330.9642.040.003.980.000.000.4216.740.660.320.432.220.19XX0.891.331.414.534.970.0016.1815.738.7-221734913539.81.09.50.55.32.13.40.038.510.811.854.8115.9
7/277/27/99 11:307/28/99 6:00101616.79101527.4690.823066.01.900.740.430.140.2912.245.067.160.0328.7929.891.9124.670.001.740.120.000.404.590.870.730.047.520.33XX3.014.511.6412.1713.680.125.323.822.1-96696618.61.67.11.330.512.26.70.521.649.355.425.6152.0
7/317/31/99 6:008/1/99 6:00128421.03101828.8711.324494.01.501.370.420.293.4414.115.718.360.0441.1840.300.4232.470.002.030.000.000.358.380.000.000.068.640.30XX3.465.180.0612.1513.880.009.247.512.5-11361756725.81.16.30.926.610.60.20.028.537.442.835.5144.2
8/68/6/99 6:008/7/99 6:00141023.27100524.1580.834293.01.181.470.400.254.217.933.674.250.0031.8229.370.7224.740.002.410.230.000.499.310.140.230.175.800.33XX2.323.480.558.679.830.233.312.142.0-13481946837.62.09.81.323.59.42.20.913.435.139.751.7139.9
8/158/15/99 6:008/16/99 6:00143023.8499520.5741.22957.01.360.750.280.230.943.821.991.830.0020.5918.000.5615.720.001.900.230.000.466.520.130.000.003.270.26XX1.311.960.134.705.350.231.661.011.9-10571363841.52.912.11.720.88.30.81.410.629.934.157.1131.6
8/218/21/99 18:008/22/99 18:00137822.78100022.7530.86388.01.401.480.130.192.555.142.172.860.1114.6614.560.9914.270.001.880.020.000.154.240.990.850.004.240.19XX1.702.551.847.788.630.020.00-0.851.4-104288-1429.71.113.21.329.711.912.90.10.054.560.540.9155.9
8/278/27/99 18:008/28/99 18:00143023.69100424.9600.92178.01.272.210.300.303.8311.667.464.200.0042.3245.000.5437.680.006.890.030.000.3121.060.000.710.785.510.19XX2.203.301.499.2010.300.030.00-1.101.4-38254386155.90.818.30.514.65.83.90.10.024.427.376.9128.6
9/29/2/99 18:009/3/99 18:00142922.99100725.1450.96997.00.632.300.181.063.2813.887.236.570.0725.6927.391.2925.980.003.810.250.060.579.240.600.440.117.540.33XX3.024.531.1511.7113.220.31-0.00-1.511.4-2119192-935.62.214.71.329.011.64.41.2-0.045.150.948.9144.9
9/89/8/99 18:009/9/99 18:00128721.33100423.8541.934285.02.350.840.580.203.546.142.993.120.0313.1714.681.5816.780.001.860.080.001.114.490.000.420.036.020.353.94XX2.413.610.448.8810.080.080.00-1.201.4-1031894826.86.611.12.135.914.42.70.50.052.960.136.8149.9
AVG15-Jun-998-Sep-992022.3100524.5721.069.41.211.120.260.252.207.733.404.250.0832.4432.531.1527.640.012.750.060.000.529.200.480.500.225.240.220.192.103.151.208.199.190.086.235.182.9-15281914731.32.39.80.920.98.44.70.321.734.138.343.1136.7100.2
StDev2.672.6140.319.60.470.580.130.221.403.761.982.050.1514.0216.620.6811.590.031.660.090.010.266.230.580.440.351.920.150.840.771.151.033.413.830.095.285.321.89241305010.81.73.30.68.13.24.50.414.313.515.014.813.1
2033.31.99.90.819.07.64.30.322.529.633.245.8137.299.6
Site: Dickson, TN
Measurement Period: July 2 through September 8, 1999
# of samples: 20
AVGSTD
27.6411.59
2.201.40ppbv
1.120.58ppbv
1.210.47ppbv
Aug Junl00
27.6 +-11.6
Col Jul00
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwOOEsv/OCNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6CheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%]
9/149/14/99 18:009/15/99 18:00144023.7699221.821.632311.84.4153164.02.171.250.090.1712.622.401.051.360.007.308.240.187.790.001.380.050.000.182.660.000.000.002.520.00XX1.011.510.003.524.020.05-0.00-0.501.4-77355-1834.12.317.70.032.312.90.00.6-0.045.251.647.0143.8
9/269/26/99 18:009/27/99 18:00144023.6699722.723.172680.92.711712761.01.630.770.780.112.074.151.902.250.0019.9324.020.6920.620.002.710.170.000.485.451.010.360.004.250.39XX1.702.551.377.328.170.174.093.242.4-1508114-2926.42.413.11.920.68.26.60.819.835.539.636.4131.3
10/210/2/99 18:0010/3/99 18:00144023.5898618.219.470650.81.532510061.01.360.861.060.1619.335.542.542.960.0420.8322.521.2121.420.003.170.140.000.665.791.000.540.726.540.23XX2.623.922.2711.4212.730.140.00-1.311.4-17511120-4427.03.114.81.130.512.210.60.70.053.359.437.2149.9
11/111/1/99 19:0011/2/99 18:59144022.7699411.911.970704.06.832233329.00.750.200.150.071.330.860.480.380.005.164.780.896.520.000.860.080.000.551.140.000.140.002.680.003.95XX1.071.610.143.904.430.080.00-0.541.4-48924-1517.48.413.20.041.116.42.21.30.059.868.024.0151.7
11/1911/19/99 19:0011/20/99 18:59144025.53100115.014.985841.53.018818942.02.160.180.700.176.781.420.780.650.0016.0220.351.8823.660.062.590.050.112.403.850.790.630.015.520.185.28XX2.213.311.429.1510.250.225.284.172.4-1433980-2516.310.110.90.823.39.36.00.922.338.743.322.4126.7
11/2511/25/99 19:0011/26/99 18:59144025.029978.38.076771.83.429229527.00.500.270.440.083.570.850.240.570.037.0813.963.7512.460.111.720.070.162.631.982.210.520.022.130.06XX0.851.282.745.726.150.34-0.00-0.431.4-954241-1215.921.113.80.517.16.822.02.7-0.045.949.421.9117.2
12/112/1/99 19:0012/2/99 18:59144024.4510095.48.259451.63.019816441.01.020.271.170.264.851.481.010.480.0013.1414.905.0518.500.000.540.000.200.780.883.341.360.057.790.44XX3.124.684.7515.6617.220.20-0.00-1.561.4-30131814.84.22.92.442.116.925.71.1-0.084.693.16.6184.3
AVG14-Sep-991-Dec-99724.199714.815.366631.83.546.41.370.540.630.157.222.391.141.230.0112.7815.541.9515.850.021.850.080.071.103.111.190.510.114.490.194.611.801.818.109.000.171.341.7-1031865-2020.37.412.40.929.611.810.51.26.051.957.827.9143.6100.0
StDev0.976.66.217181.11.715.60.660.420.420.076.531.800.811.010.026.427.251.796.890.041.000.060.090.991.981.210.440.272.200.180.940.881.644.364.790.102.310.5551641149.76.84.60.99.83.99.80.710.316.618.313.322.0
719.66.911.71.228.311.311.41.18.451.156.827.0143.6100.0
numbers with a yellow background are taken from Percy Priest, east of downtown NashvilleSite: Hendersonville, TN
Measurement Period: September 14 through December 1, 1999
# of samples: 7
AVGSTD
15.856.89
7.226.53ppbv
0.540.42ppbv
1.370.66ppbv
Col Jul00
15.9 +-6.9
LP Sum00
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwOOEsv/OCNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6CheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%]
9/149/14/99 18:009/15/99 18:00122520.2499319.0401.71163.02.421.130.110.144.714.922.911.950.0513.2211.150.7113.930.001.880.170.001.033.010.000.210.004.770.00XX1.912.860.216.897.840.170.95-0.001.6-1041763-2521.67.413.50.034.313.71.51.26.849.456.329.7142.3
9/269/26/99 18:009/27/99 18:00143023.8799721.9730.813549.01.300.790.440.121.336.072.913.160.0019.7327.271.0120.740.002.900.000.000.715.911.160.410.002.830.00XX1.131.701.575.536.100.005.685.113.4-16112123-2628.53.414.00.013.65.57.60.027.426.729.439.2122.7
10/210/2/99 18:0110/3/99 18:00142923.8998718.1690.817574.01.990.850.630.278.269.064.044.680.3449.5950.243.9753.880.003.070.000.001.186.731.161.200.2519.100.21XX7.6411.462.6029.3533.170.0013.349.522.1-17019140-1112.52.25.70.435.514.24.80.024.854.561.617.2158.0
11/111/1/99 19:0011/2/99 18:59142823.00100110.8723.733027.00.270.270.060.040.990.540.240.300.006.256.520.787.020.000.710.000.000.611.200.000.000.001.250.001.45XX0.500.750.001.752.000.002.752.503.6-391025-517.28.710.10.017.87.10.00.039.124.928.523.6116.1
11/711/7/99 19:0011/8/99 18:59131821.72100619.4691.725258.01.660.740.190.283.902.771.071.700.0012.9917.000.8713.870.191.930.000.020.504.210.000.000.024.200.00XX1.682.520.025.896.730.211.110.271.7-107888-1130.43.614.00.030.312.10.11.58.042.548.641.8140.9
11/1311/13/99 19:0011/14/99 18:59137123.65100018.1533.025665.01.240.780.210.131.312.541.151.390.0021.0821.450.5021.580.182.210.130.070.485.820.000.000.056.830.004.05XX2.734.100.059.6110.980.383.071.711.8-1238121627.02.210.30.031.712.70.21.814.244.550.937.1146.7
11/2511/25/99 19:0011/26/99 18:59129921.539976.6832.127135.00.370.220.350.053.521.360.680.670.0112.9216.641.1615.120.011.920.000.054.671.920.270.000.004.470.03XX1.792.680.276.537.420.06-0.00-0.891.4-1067540912.730.912.70.229.511.81.80.4-0.043.249.117.5109.7
12/112/1/99 19:0012/2/99 18:59135422.3910099.2381.817024.00.761.100.109.061.490.710.750.039.599.421.0112.080.170.801.520.010.981.430.000.000.025.050.09XX2.023.030.027.098.101.700.00-1.011.4-441630211.88.16.60.741.816.70.214.10.058.767.116.3142.0
AVG14-Sep-991-Dec-99822.599915.4632.049.41.240.730.290.144.123.621.721.850.0618.4220.261.2720.050.071.930.230.021.253.820.340.240.046.130.042.722.453.680.629.2010.420.313.502.272.2-1072079-820.28.110.80.229.111.62.12.315.642.848.627.8134.8100.0
StDev1.375.6161.118.80.740.330.200.093.192.981.411.520.1214.1514.461.1615.160.090.880.530.031.352.250.540.440.095.780.081.802.313.471.008.8710.030.584.593.690.9492247137.79.23.30.39.63.82.94.814.312.414.310.616.9
819.06.29.60.230.612.23.11.617.445.952.026.2134.8100.0
Site: Dickson, TN
Measurement Period: September 14 through December 1, 1999
# of samples: 8
AVGSTD
20.0515.16
4.123.19ppbv
0.730.33ppbv
1.240.74ppbv
LP Sum00
20.1 +-15.2
WT Sum00
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwOOEsv/OCNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6CheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%]
1/101/10/00 10:351/11/00 9:30137523.5910035.97.940281.43.13282836.00.520.100.040.820.790.480.310.004.985.580.215.800.030.220.110.040.110.090.000.000.073.560.1510.62XX1.422.130.075.045.760.190.00-0.711.4-1222-81.62.03.82.661.324.51.13.20.086.999.22.2188.3
1/161/16/00 18:001/17/00 18:00144024.4310115.75.766661.53.2465515.00.620.190.206.240.840.510.330.0010.8616.221.7114.340.102.150.010.033.062.170.190.390.084.310.128.67XX1.722.590.666.707.560.14-0.00-0.861.4-1194945-2415.121.315.00.930.112.04.61.0-0.046.752.720.8120.2
1/221/22/00 18:001/23/00 18:00144024.379991.51.690921.12.3113926.00.000.180.003.520.710.250.450.0011.9512.961.5813.520.031.340.000.011.493.010.000.000.124.690.007.23XX1.882.810.126.697.630.030.960.021.6-7524631222.311.09.90.034.713.90.90.37.149.556.430.6143.5
1/281/28/00 18:001/29/00 18:00144024.3924.00.170.240.305.701.520.980.540.008.906.540.969.860.000.640.000.010.660.740.200.190.063.840.196.03XX1.542.300.465.836.600.011.791.031.9-351115-97.56.76.51.938.915.64.60.118.259.166.910.4154.6
2/32/3/00 18:002/4/00 18:00144024.4010012.53.166642.34.931031225.00.280.170.111.260.730.530.0010.4713.150.9111.380.031.730.010.062.572.090.290.050.052.650.0010.07XX1.061.590.394.104.630.100.780.251.7-964144-1118.422.615.20.023.39.33.40.96.936.040.725.3108.9
2/152/15/00 18:002/16/00 18:00144025.29100312.513.652481.94.131826435.00.770.430.214.081.871.180.690.0012.4315.931.3513.790.051.840.000.051.662.790.220.110.085.040.007.54XX2.023.020.417.468.470.10-0.07-1.081.4-1022758-1720.212.113.40.036.514.63.00.7-0.554.161.427.8142.9
2/212/21/00 18:002/22/00 18:00144025.09101012.212.947381.84.714315548.00.570.600.242.991.320.730.590.008.629.630.829.440.020.150.000.000.292.140.160.190.124.280.009.52XX1.712.570.476.467.310.020.39-0.471.5-85444122.63.11.60.045.318.14.90.24.168.477.431.1181.0
3/43/4/00 18:003/5/00 18:00144024.9210017.99.865541.01.731131043.00.750.360.164.581.721.090.630.0012.6516.452.3515.000.012.140.000.021.382.360.090.120.025.230.6616.89XX2.093.140.247.558.600.030.88-0.171.6-1192249-4715.79.214.34.434.813.91.60.25.950.457.321.6135.1
3/173/17/00 18:003/18/00 18:00144024.8410068.68.353531.63.7909847.00.350.320.133.111.120.540.570.015.666.461.597.510.041.200.000.031.011.880.230.100.061.940.247.89XX0.781.170.393.113.500.07-0.00-0.391.4-671639-1125.013.416.03.225.910.45.30.9-0.041.546.734.4122.5
3/243/24/00 18:003/25/00 18:00144026.00100019.120.065601.43.229425461.01.100.700.255.733.421.731.660.0321.7221.312.4924.210.082.640.010.050.676.120.690.850.285.360.496.01XX2.143.211.829.3110.390.144.833.762.3-14611127-825.32.810.92.022.18.87.50.620.038.542.934.8136.1
3/303/30/00 18:003/31/00 18:00144025.29100112.213.052441.32.73582653.00.460.390.182.511.510.630.870.019.069.603.1612.570.081.820.150.061.492.800.910.130.123.180.555.23XX1.271.911.175.626.260.280.00-0.641.4-1012458-1922.311.814.54.425.310.19.32.30.044.849.830.7125.2
4/54/5/00 18:004/6/00 18:00144026.1199518.618.349473.45.51962171.460.650.152.954.643.211.400.027.999.650.579.090.000.810.000.140.221.910.280.000.114.020.003.04XX1.612.410.396.026.830.140.00-0.801.4-45440-121.02.48.90.044.217.74.31.50.066.275.128.9170.2
AVG10-Jan-005-Apr-001224.910039.710.459541.73.637.50.590.360.163.851.731.010.720.0110.4611.981.4812.230.041.390.020.041.222.350.270.180.104.010.208.221.602.410.556.166.970.100.80-0.001.6-772049-918.19.910.81.635.114.04.21.05.153.460.425.0143.9100.0
StDev0.755.95.914170.71.214.20.400.200.091.611.170.800.410.014.304.850.864.720.030.800.050.040.921.450.270.240.071.050.243.490.420.630.491.641.840.081.401.320.3441530217.07.04.81.711.14.42.50.97.214.416.69.724.8
1219.210.011.41.632.813.14.50.96.550.456.926.4143.9100.0
numbers with a yellow background are taken from Percy Priest, east of downtown NashvilleSite: Hendersonville, TN
Measurement Period: January 10 through April 5, 2000
# of samples: 12
AVGSTD
12.234.72
3.851.61ppbv
0.360.20ppbv
0.590.40ppbv
WT Sum00
12.2 +-4.7
GF Jul01
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwOOEsv/OCNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6CheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%]
1/101/10/00 19:001/11/00 18:59143024.0999811.2292.925138.00.730.340.002.690.690.280.410.015.406.400.165.560.050.290.040.060.140.900.130.000.041.610.00XX0.640.960.172.422.740.151.671.352.4-16219516.12.55.10.028.911.53.12.630.143.549.322.1145.1
1/161/16/00 19:001/17/00 18:59124420.1610114.5752.36215.00.320.140.013.280.910.370.510.0216.710.330.4217.130.071.340.000.062.011.150.090.000.040.00XX0.000.130.130.130.1312.3712.37-743224-186.711.77.80.00.80.872.20.80.89.283.0
1/221/22/00 19:001/23/00 18:59108217.479990.7961.21334.00.250.240.004.251.330.840.470.029.8510.291.8911.740.031.030.000.001.192.740.440.600.004.130.00XX1.652.481.056.827.650.03-0.06-0.891.4-5719571923.310.28.80.035.114.18.90.2-0.558.165.132.1154.8
2/32/3/00 19:002/4/00 18:59142923.181000.52.3622.830338.00.380.220.261.710.850.490.360.005.657.141.498.730.001.540.000.042.001.730.230.170.042.140.00XX0.861.280.443.433.860.04-0.00-0.431.4-853236-1719.822.917.60.024.59.85.00.4-0.039.344.227.3110.7
2/92/9/00 19:002/10/00 18:59143024.32996.513.8453.219555.01.120.890.082.332.431.141.280.0110.3210.750.8511.640.041.210.000.000.752.840.150.000.234.590.00XX1.842.750.376.807.710.040.00-0.921.4-671259424.46.510.40.039.415.83.20.30.058.466.333.6158.2
2/152/15/00 19:002/16/00 18:59142924.02100312.4552.830918.00.800.580.203.241.810.880.920.0017.021.4115.120.012.340.080.042.683.550.180.230.094.230.00XX1.692.540.516.437.280.130.00-0.851.4-1304374-1323.517.715.50.028.011.23.40.80.042.548.132.3123.0
2/212/21/00 19:002/22/00 18:59142923.98101013.8342.116259.00.570.810.233.501.470.780.690.007.187.410.9710.820.041.080.000.010.501.950.400.130.104.620.14XX1.852.770.637.108.030.050.00-0.921.4-60841-1118.04.69.91.342.717.15.90.50.065.774.224.8164.7
2/272/27/00 19:002/28/00 18:59137922.7310099.2550.93361.00.390.410.132.010.920.400.530.003.343.490.965.380.090.670.040.010.261.490.390.320.051.470.00XX0.590.880.752.813.100.150.00-0.291.4-37431-227.74.812.40.127.310.914.02.80.052.257.638.1147.9
3/43/4/00 19:003/5/00 18:59142923.7610019.5570.828168.07.230.430.094.231.330.530.800.007.467.623.6712.410.021.940.000.012.852.540.430.140.083.150.00XX1.261.890.655.065.690.020.00-0.631.4-1074653-920.522.915.60.025.410.25.20.20.040.845.928.2114.8
3/303/30/00 19:003/31/00 18:59143124.2699211.5492.161.450.460.162.942.091.061.030.006.8410.612.6410.350.021.370.000.020.992.840.330.370.112.690.55XX1.071.610.814.575.110.030.00-0.541.4-761659-127.49.613.25.425.910.47.80.30.044.149.337.7131.1
4/54/5/00 19:004/6/00 18:59143924.8998318.0513.32121.530.620.121.612.530.991.510.027.037.511.128.150.000.930.000.040.311.860.430.480.122.040.00XX0.811.221.043.894.290.041.110.711.9-52539-822.93.811.40.025.010.012.70.513.747.752.731.5145.5
AVG10-Jan-005-Apr-001123.0100010.0542.242.91.380.480.122.861.500.710.790.017.838.111.4210.550.031.250.010.031.242.140.290.220.083.040.071.221.830.594.905.510.071.390.781.6-692045-521.010.711.70.630.112.06.40.94.549.055.028.9139.297.9
StDev2.285.0170.919.02.050.240.090.900.660.310.380.013.464.211.033.560.030.580.030.021.010.820.130.190.061.250.170.500.750.291.762.000.051.311.390.4321617105.67.73.71.76.62.64.10.910.28.910.17.718.8
1120.311.711.90.628.811.55.60.713.246.552.328.0137.4104.4
Site: Dickson, TN
Measurement Period: January 10 through April 5, 1999
# of samples: 11
AVGSTD
10.553.56
2.860.90ppbv
0.480.24ppbv
1.382.05ppbv
GF Jul01
10.6 +-3.6
GF Jan02
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6TOC.6+svocOthersUnID.4UnID.6UnID.6svMw/CwMw/Cw +svocNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6TOC.6+svocCheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%][%]
11-Jun-008:16:007:00:001364Macon ML61.73.010.670.290.402.617.343.264.010.0711.6816.47CH1, deh; SC13.780.210.660.030.040.723.700.000.680.554.890.34XX1.962.931.238.089.069.060.280.00-0.98-0.981.41.4-3712775226.95.24.82.535.514.28.92.00.058.665.765.737.0227.0
12-Jun-008:06:007:05:001379Macon Sat55.41.810.580.470.225.322.442.850.0412.25CH1; deh12.250.250.380.110.010.611.240.150.110.133.430.19XX1.372.060.395.195.885.880.374.283.593.592.62.6-2110261510.14.93.11.628.011.23.23.034.942.448.048.013.9187.1
13-Jun-007:24:007:19:001435Macon Sat47.51.120.410.220.153.091.141.930.0211.939.06CH2; deh9.060.110.690.000.000.871.660.910.120.301.770.51Qdiff0.711.061.333.814.164.160.111.411.051.052.22.2-3814351018.39.67.65.619.57.814.71.315.542.146.046.025.2174.8
14-Jun-007:43:0018:39:00656Macon Sat42.40.990.620.280.464.621.642.950.039.388.33CH2; deh8.330.210.630.040.000.142.000.470.090.151.440.180.00XAD0.580.860.712.723.013.010.252.402.112.113.13.1-35242924.11.67.62.217.36.98.53.028.832.736.136.133.1166.9
14-Jun-0019:17:007:05:00708Macon ML1.160.190.120.054.382.122.250.0215.1114.51CH2; deh14.510.071.170.000.001.112.720.340.080.172.120.080.00XAD0.851.270.593.563.983.980.075.815.395.394.14.1-6518571018.77.78.00.614.65.84.10.540.024.527.427.425.8145.1
15-Jun-007:37:006:42:001385Macon Sat50.91.050.360.160.333.051.261.750.0310.986.75CH2; deh6.750.170.630.050.030.262.160.420.280.111.030.21Qdiff0.410.620.812.252.462.460.251.010.800.802.42.4-354451431.93.89.33.115.26.112.13.614.933.436.436.443.9165.1
16-Jun-007:39:0019:04:00685Macon ML42.51.600.160.260.052.500.851.620.0312.49CH1; deh12.490.310.680.010.000.852.570.480.170.422.390.181.53XAD0.961.431.074.424.896.420.323.493.011.482.91.7-3714533020.56.85.41.419.17.68.62.627.935.439.251.428.3182.1
17-Jun-007:13:007:08:001435Macon Sat55.51.400.500.140.133.821.712.070.0429.1610.11CH2; deh10.110.120.860.000.000.442.110.230.220.201.790.17Qdiff0.721.080.663.173.523.520.123.242.882.883.23.2-48744320.94.38.51.717.77.16.51.232.131.334.934.928.7161.9
18-Jun-007:50:006:50:001380Macon ML38.00.310.160.190.393.551.641.880.0310.8913.25CH1; deh10.890.110.000.000.000.211.210.240.270.093.070.04XX1.231.840.604.905.525.520.114.423.813.812.82.803252811.11.90.00.428.211.35.51.040.645.050.750.715.2202.2
19-Jun-007:30:007:03:001413Macon ML41.30.710.190.040.141.790.701.050.0410.48CH1; deh10.480.110.850.000.001.111.780.300.080.103.050.140.60XAD1.221.830.484.755.365.950.111.731.120.522.01.6-471837817.010.68.21.329.111.64.61.116.545.351.156.823.3193.2
20-Jun-008:11:006:40:001349Macon Sat45.30.740.400.060.673.681.452.220.0216.8412.39CH2; deh12.390.151.090.000.000.363.600.180.020.092.830.24Qdiff1.131.700.294.254.824.820.152.702.142.142.42.4-606752029.02.98.82.022.99.12.31.221.834.338.938.940.0173.9
21-Jun-007:37:007:25:001428Macon Sat55.40.990.440.020.413.691.482.180.0215.3216.38CH2; deh16.380.141.660.000.001.553.860.430.130.173.510.29Qdiff1.412.110.745.656.366.360.143.242.542.542.32.3-9225801323.59.510.11.721.48.64.50.819.834.538.838.832.4164.2
AVG11-Jun-0021-Jun-001248.71.330.410.230.190.503.901.652.220.0314.9511.9811.410.160.770.020.010.692.370.340.200.202.700.220.131.081.620.744.515.056.110.182.662.120.842.51.68-4311491821.05.86.82.123.19.27.01.723.339.343.955.0728.8180.4100.0
StDev7.60.700.150.090.150.741.500.730.780.015.553.092.750.050.440.040.010.441.010.250.180.141.110.130.310.440.670.341.591.810.260.091.531.560.530.60.0525721147.13.13.21.46.42.64.01.012.18.69.83.029.821.2
1220.86.06.82.023.69.46.51.623.339.544.353.528.6190.4100.0
Site: Macon, GA
Measurement Period: 6/11/00 - 6/21/00
# of samples: 12
AVGSTD
11.412.75
0.500.74ppbv
0.410.15ppbv
1.330.70ppbv
12.06
GF Jan02
20.9525849929
5.8439419028
6.7721223009
2.0959558156
23.1118512911
9.2447405165
6.9607896926
1.7231957446
23.294817743
Macon-ML Avg Mass Composition
Summary
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwMw/Cw +svocNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6CheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%]
27-Jun-007:01:009:10:00156941.81.310.280.090.147.053.321.281.990.058.3913.80CH1; deh8.390.130.650.000.000.411.750.040.090.072.520.00XX1.011.510.203.734.240.131.721.221.222.12.1-36736720.94.87.70.030.112.02.41.620.544.550.528.7144.2
29-Jun-009:05:0018:50:0058546.81.210.350.291.783.311.092.180.0420.18CH1; deh20.180.051.100.000.080.067.070.000.000.152.530.340.00XAD1.011.520.153.684.190.137.817.307.304.54.5-6111478735.00.35.41.712.55.00.70.638.718.320.848.2125.9
29-Jun-0019:01:007:00:007190.570.140.070.001.760.790.960.0210.54CH1; deh10.540.001.070.360.000.352.290.000.000.083.100.061.29XAD1.241.860.084.435.050.361.981.360.082.01.4-59648-621.73.310.20.529.511.80.83.418.842.047.929.9138.6
2-Jul-009:05:0019:05:0060074.10.671.081.160.296.752.604.120.0336.51CH1; deh36.510.452.660.000.120.1910.510.020.000.302.720.050.00XAD1.091.630.324.134.670.5718.4017.8617.868.28.2-14832197428.80.57.30.17.43.00.91.650.411.312.839.6114.1
2-Jul-0019:15:007:06:007110.490.400.170.076.342.683.620.0330.05CH1; deh30.050.133.330.210.000.1110.790.130.870.295.780.221.71XAD2.313.471.299.3810.530.345.884.733.022.41.9-18422254235.90.411.10.719.27.74.31.119.631.235.149.4135.2
5-Jul-009:01:0018:59:0059872.60.651.541.150.4711.754.587.070.1029.54CH1; deh29.541.482.560.283.230.2310.031.881.480.315.110.640.00XAD2.043.063.6710.8211.844.980.28-0.74-0.741.51.5-14242097034.00.88.72.217.36.912.416.90.936.640.146.7124.4
5-Jul-0019:10:007:17:007270.880.590.280.007.793.204.560.0424.59CH1; deh24.590.131.820.000.200.725.581.391.190.353.100.790.00XAD1.241.862.937.277.890.348.087.467.464.04.0-101121162722.72.97.43.212.65.011.91.432.829.632.131.2125.7
8-Jul-009:01:0018:38:0057769.64.371.621.041.245.831.953.830.0627.70CH1; deh27.700.342.120.000.590.419.270.860.180.303.190.260.00XAD1.281.911.335.806.440.928.928.288.284.24.2-11771938233.51.57.60.911.54.64.83.332.220.923.246.0122.4
28-Jun-0010:35:008:18:00130241.01.620.310.140.083.441.262.160.0314.9210.80CH2; deh10.800.190.890.000.020.852.540.460.280.141.150.26Qdiff0.460.690.882.492.720.213.553.313.314.54.5-4914531723.57.98.22.410.74.38.22.032.823.125.232.4113.6
29-Jun-009:00:007:00:00132044.01.000.340.061.542.591.101.460.0215.76CH1; deh15.760.091.450.000.020.575.400.400.390.182.960.360.00XAD1.181.780.975.125.710.112.752.152.152.32.3-8091124134.33.69.22.318.87.56.10.717.432.536.247.1133.3
30-Jun-009:00:007:00:00132067.00.900.480.570.653.631.562.050.0261.6724.86CH2; deh24.860.002.860.000.030.228.480.530.290.174.750.48Qdiff1.902.850.997.648.590.045.154.204.202.52.5-15841772234.10.911.51.919.17.64.00.220.730.734.546.9132.9
1-Jul-009:00:007:00:00132074.00.960.480.200.483.801.502.280.0230.9425.86CH2; deh25.860.013.040.060.000.419.640.590.540.264.060.37Qdiff1.622.431.397.077.890.075.254.444.442.72.7-16972013937.31.611.81.415.76.35.40.320.327.430.551.3129.4
2-Jul-009:00:007:00:00132071.00.770.610.340.655.642.333.290.0339.12CH1; deh39.120.103.380.000.060.0711.240.620.450.245.240.350.00XAD2.103.151.308.649.690.1615.2714.2214.224.34.3-18712344828.70.28.60.913.45.43.30.439.022.124.839.5125.4
3-Jul-009:00:007:00:00132065.50.700.620.910.285.712.223.460.0333.2125.60CH2; deh25.600.062.380.000.000.298.181.971.010.364.320.33Qdiff1.732.593.349.3910.250.064.974.114.112.62.6-13251704331.91.19.31.316.96.813.00.219.436.740.043.9140.1
4-Jul-009:00:007:00:00132069.40.610.650.270.977.412.794.590.0341.6032.40CH2; deh32.400.173.180.000.110.5110.781.800.840.315.660.40Qdiff2.273.402.9510.8812.010.286.375.245.242.52.5-17682255633.31.69.81.217.57.09.10.919.733.637.145.8136.1
5-Jul-009:00:007:00:00132072.61.210.940.420.557.802.854.910.0429.12CH1; deh29.120.292.020.170.420.457.203.281.080.244.170.400.00XAD1.672.504.6010.4411.270.887.726.896.893.33.3-11271504524.71.56.91.414.35.715.83.026.535.838.734.0135.1
6-Jul-009:00:007:00:00132066.01.550.690.250.185.862.323.500.0427.3023.96CH2; deh23.960.101.900.060.030.446.530.890.770.192.870.50Qdiff1.151.721.865.876.440.208.527.957.954.44.4-10571363827.21.87.92.112.04.87.70.835.624.526.937.5124.4
7-Jul-009:00:007:00:00132081.91.610.700.351.764.391.792.570.0327.5322.51CH2; deh22.510.352.950.020.510.248.491.350.640.182.550.30Qdiff1.021.532.185.756.260.873.923.413.412.92.9-16441771737.71.013.11.311.34.59.73.917.425.527.851.8122.6
8-Jul-009:41:007:00:00127870.02.990.660.391.564.541.792.710.0338.81CH1; deh38.810.303.870.000.211.578.570.620.330.172.900.220.00XAD1.161.741.125.185.760.5118.9018.3218.327.97.9-21425178-1122.14.010.00.67.53.02.91.348.713.314.830.4107.3
9-Jul-009:00:007:00:00132053.00.940.710.460.335.702.143.540.0330.1118.33CH2; deh18.330.192.160.000.350.438.171.070.370.303.260.53Qdiff1.311.961.746.316.960.540.18-0.47-0.471.51.5-11971705844.62.411.82.917.87.19.53.01.034.438.061.3134.7
AVG27-Jun-009-Jul-002063.51.230.610.090.391.155.152.013.110.0330.2021.8624.280.192.290.040.220.457.460.950.540.223.580.340.221.432.151.716.737.440.466.555.831.543.41.65-12771553630.52.39.41.516.06.47.01.925.029.432.642.0129.0100.0
StDev12.90.690.260.000.271.981.850.691.160.0115.656.739.400.190.970.080.410.352.960.860.350.081.230.170.490.490.741.222.512.730.635.155.102.081.70.3054662236.92.01.90.96.12.44.22.212.08.49.59.510.1
2030.71.99.41.414.85.97.01.927.027.730.742.3129.0100.0
Site: Augusta, GA
Measurement Period: 6/27/00 - 7/9/00
# of samples: 20
AVGSTD
24.289.40
1.151.98ppbv
0.610.26ppbv
1.230.69ppbv
Summary
30.5185434427
2.3069375102
9.3866289564
1.4723449722
16.0220957092
6.4088382837
6.9514242268
1.9150944913
25.0180924076
Augusta Avg Mass Composition
PMhisto
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwMw/Cw +svocNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6CheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%]
18-Jul-007:21:006:59:0013312.311.090.513.398.093.134.900.0628.15CH1; deh28.150.002.070.000.000.366.640.941.010.287.990.693.08XAD3.194.792.2413.4215.010.004.973.370.292.01.5-11561382923.61.37.42.428.411.37.90.017.647.753.332.5151.1
19-Jul-007:16:006:59:00142386.61.661.370.520.491.8117.756.9110.750.0925.67CH1; deh25.670.132.030.030.000.275.170.490.680.459.100.54XX3.645.461.6314.3716.190.173.111.291.291.71.7-1134108-120.11.17.92.135.514.26.30.612.156.063.127.7158.9
20-Jul-007:23:006:59:00141680.01.091.280.120.351.538.083.394.630.0717.3524.34CH1; deh17.350.001.720.000.000.245.090.570.470.175.570.25XX2.233.341.209.0110.120.001.04-0.07-0.071.61.6-9541061529.41.49.91.432.112.86.90.06.051.958.340.4156.6
21-Jul-007:36:0018:59:0068376.81.301.090.281.335.121.783.290.0616.98CH1; deh; SC27.130.890.960.081.270.303.221.131.040.2512.740.168.78XAD5.107.652.4220.2722.812.240.00-2.55-11.331.40.8-535671911.91.13.50.647.018.88.98.30.074.784.116.3175.1
22-Jul-007:27:006:59:00141276.21.290.940.320.291.218.083.654.370.0517.4529.42CH1; deh17.450.121.830.000.000.325.290.120.420.176.160.37XX2.473.700.719.3410.570.120.18-1.05-1.051.41.4-10151101430.31.810.52.135.314.14.10.71.153.560.641.7156.9
23-Jul-007:31:006:59:00140879.00.040.770.080.271.255.902.713.130.0613.8523.23CH1; deh13.850.721.500.290.000.314.300.250.330.133.760.26XX1.512.260.715.986.731.000.50-0.26-0.261.51.5-835901231.12.310.81.827.210.95.27.23.643.248.642.7138.1
24-Jul-007:38:0018:59:0068157.21.570.710.180.204.891.523.310.0615.37CH1; deh; SC15.870.061.440.000.080.325.330.470.330.205.190.392.20XAD2.083.121.008.279.310.14-0.00-1.04-3.231.41.0-8051113633.62.09.02.432.713.16.30.9-0.052.158.646.2156.9
24-Jul-0021:22:006:59:005771.200.310.010.873.441.362.050.0317.99CH1; deh; SC23.830.002.270.000.000.366.310.420.330.209.820.196.54XAD3.935.890.9514.7016.660.000.00-1.96-8.511.40.8-12661311226.51.59.50.841.216.54.00.00.061.769.936.4168.0
25-Jul-007:30:006:59:00140967.20.750.160.310.775.912.553.310.0619.5135.02CH1; deh19.510.002.150.000.120.187.890.000.110.144.760.20XX1.902.860.246.917.860.122.061.111.111.81.8-11931644840.40.911.01.024.49.81.20.610.635.440.355.6141.9
16-Jul-009:00:0019:00:0060073.33.421.890.912.198.452.815.570.0624.8820.83CH2; deh20.830.761.730.141.080.365.672.990.820.284.430.00Qdiff1.772.664.0910.2911.181.980.79-0.09-0.091.61.6-9661182827.21.78.30.021.38.519.69.53.849.453.737.5144.4
17-Jul-009:00:007:00:00131487.31.210.970.472.315.892.273.580.0522.9018.39CH2; deh18.390.001.440.000.000.464.282.150.630.185.201.05Qdiff2.083.122.9610.2411.280.000.92-0.12-0.121.61.6-807891623.32.57.95.728.311.316.10.05.055.761.332.0154.0
18-Jul-008:23:007:00:00135699.81.651.100.503.718.904.284.560.0736.63CH1; deh; TEOM30.640.002.550.000.000.487.521.790.670.227.270.541.21XAD2.914.362.6912.8614.310.006.705.244.032.32.0-14181562324.51.68.31.823.79.58.80.021.942.046.733.7144.3
19-Jul-008:20:007:00:00135686.62.281.140.481.1615.738.077.590.0834.6126.58CH2; deh26.580.041.970.000.000.476.061.390.420.365.320.53Qdiff2.133.192.179.6210.690.047.896.836.832.92.9-10981262422.81.87.42.020.08.08.20.129.736.240.231.4137.5
20-Jul-008:19:007:00:00135680.03.081.990.523.059.473.336.060.0918.46CH2; deh18.460.262.040.300.320.075.660.140.140.013.460.34Qdiff1.382.070.295.135.820.894.333.633.632.72.7-1131118630.70.411.01.918.77.51.64.823.427.831.542.2124.9
21-Jul-009:20:007:00:00129674.00.000.500.520.067.365.521.630.2157.23CH1; deh; TEOM33.780.002.650.000.030.108.850.310.030.117.270.251.81XAD2.914.360.4510.6212.080.0311.289.828.023.02.4-14721843926.20.37.90.721.58.61.30.133.431.535.836.0136.6
22-Jul-008:45:007:00:00133276.21.240.950.222.285.232.133.050.0524.5219.59CH2; deh19.590.151.760.000.050.385.481.180.590.244.140.35Qdiff1.652.482.017.808.630.203.612.782.782.32.3-9861142328.01.99.01.821.18.410.31.018.439.844.038.5140.8
23-Jul-008:26:007:00:00135079.00.540.370.100.884.882.282.540.0621.2714.10CH2; deh14.100.221.450.050.150.244.690.370.580.162.470.28Qdiff0.991.481.124.585.070.422.441.951.952.42.4-804982133.31.710.32.017.57.07.93.017.332.536.045.8131.6
24-Jul-008:43:007:00:00133269.00.840.540.091.293.091.201.860.0420.39CH1; deh20.390.131.870.000.160.306.040.750.310.164.710.251.14XAD1.882.821.237.828.760.293.822.871.732.21.8-10451262729.61.59.21.223.19.26.01.418.738.343.040.8140.8
25-Jul-008:31:007:00:00134463.00.910.510.240.395.332.552.740.0424.7916.90CH2; deh16.900.002.020.000.000.236.880.410.410.213.210.14Qdiff1.281.931.045.536.170.002.091.451.452.12.1-11241433540.71.411.90.819.07.66.10.012.432.736.556.0137.7
AVG18-Jul-0025-Jul-001977.11.360.960.240.351.617.743.414.260.0719.7822.6421.390.151.890.050.120.305.880.770.470.205.670.380.912.273.401.459.3810.520.323.232.100.502.01.61-10551222228.51.59.21.826.310.56.81.713.743.749.039.2145.5100.0
StDev10.00.860.420.180.161.053.951.872.350.048.746.365.880.220.370.100.210.121.330.670.260.102.120.231.550.851.270.903.363.780.453.002.955.500.50.5220228136.30.61.71.16.72.73.92.49.710.311.68.611.0
1927.51.48.91.826.510.66.81.515.143.949.237.8145.5100.0
Site: Columbus, GA
Measurement Period: 7/18/00 - 7/25/00
# of samples: 19
AVGSTD
21.395.88
1.611.05ppbv
0.960.42ppbv
1.360.86ppbv
PMhisto
28.4872865594
1.4678672787
9.1699564421
1.8131057469
26.3262172619
10.5304869048
6.8448773271
1.6960182678
13.6641842112
Columbus Avg Mass Composition
GAShisto
Date StartTime StartTime StopSample TimeAvg amb spl Vamb pamb TdT[10m-2m]amb RHH2OUVB h-ly maxNO2O3O3 h-ly maxHONOHClLOAAceticFormicOxalicgravim M ch1gravim M ch2total SVFinal MAcetateFormateOxalateOCECSVOCFlagsOOE.4OOE.6LOATOC.4TOC.6OthersUnID.4UnID.6UnID.6svMw/CwMw/Cw +svocNet AcidityECOCOOE.4LOAOthersUnID.4TOC.4TOC.6CheckSum
ESTEST(min)(m3)(mbar)(K)(%)(%v)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ppb)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)(ug/m3)for closurefor closure[%][%][%][%][%][%][%][%][%][%][%][%][%]
8/168/16/00 0:008/17/00 0:001424.0011.62102229.266.52.240.470.290.131.744.043.180.740.1221.7927.870.5722.081.490.160.810.670.011.201.762.290.220.070.050.660.690.43XAD0.260.400.341.271.403.5311.7211.5911.1619.111.6-4528483110.48.03.73.13.01.21.616.053.15.76.314.379.4
8/178/17/00 0:008/18/00 0:001438.0023.22101929.499.43.130.570.100.382.932.540.771.680.0927.7830.201.1628.940.640.081.420.460.010.191.383.780.190.310.151.510.320.38XAD0.600.900.652.763.061.3817.8917.5917.2113.310.6-7922792213.14.84.91.15.22.12.24.861.89.510.618.099.9
8/188/18/00 0:008/20/00 0:032876.0024.01101928.597.61.560.550.250.411.034.201.412.730.0622.4531.241.2623.710.270.102.640.150.040.110.858.740.430.340.212.030.401.10XAD0.811.220.983.834.230.676.576.175.074.63.0-147141824936.93.611.21.78.63.44.12.827.716.117.950.7112.5
8/208/20/00 0:008/21/00 0:001436.0011.83101928.373.92.830.000.260.280.803.010.732.210.0715.8819.910.8516.730.130.022.280.010.010.020.437.320.030.060.173.270.181.14XAD1.311.960.254.835.480.191.490.84-0.301.91.4-12671523343.72.613.61.119.57.81.51.18.928.932.860.2130.7
8/218/21/00 0:008/22/00 0:001438.0023.82101928.8116.62.470.340.110.521.744.091.352.670.0715.8919.981.0916.980.140.022.900.090.010.020.477.690.020.230.151.650.360.11XAD0.660.990.402.723.050.282.552.222.112.92.8-1618160745.32.817.12.19.73.92.41.715.016.018.062.3111.3
8/228/22/00 0:008/23/00 0:001383.0011.48102128.269.83.750.000.350.231.535.201.673.470.0617.9123.755.2223.130.120.073.060.030.010.070.737.853.181.350.153.750.681.06XAD1.502.254.689.9310.690.300.58-0.17-1.231.61.2-17012163533.93.213.22.916.26.520.21.32.542.946.246.7138.3
8/238/23/00 0:008/24/00 0:001440.0023.83102027.481.83.010.660.500.342.632.611.211.370.0413.2117.312.2215.430.160.062.170.030.020.000.945.050.490.310.161.960.630.32XAD0.791.180.963.714.110.272.662.271.952.82.4-12015105032.76.114.04.112.75.16.21.717.324.126.645.0112.9
8/248/24/00 7:038/25/00 0:001019.005.65102026.8132.73.090.430.490.472.305.071.973.040.0611.5013.820.8912.390.080.001.640.050.100.230.644.020.090.090.272.810.571.97XAD1.121.680.454.384.940.470.670.11-1.861.61.0-911084332.45.213.24.622.69.13.63.85.435.339.944.6125.2
8/258/25/00 0:008/26/00 0:001438.0020.57101927.6122.81.020.150.401.273.451.491.920.046.176.524.4110.930.070.000.980.760.010.000.791.652.390.960.142.091.061.13XAD0.841.263.496.426.840.84-0.81-1.23-2.361.00.7-541334-715.17.28.99.719.17.731.97.7-7.458.762.620.8134.7
8/268/26/00 0:008/27/00 0:001434.007.95101628.279.33.660.700.470.521.144.591.812.700.086.638.771.5510.320.070.000.960.000.020.000.552.290.520.490.461.740.580.67XAD0.701.041.473.904.250.091.941.600.922.51.8-53948322.25.39.35.616.96.714.20.918.837.841.230.5128.4
8/278/27/00 0:008/28/00 0:001438.0020.70101528.463.12.120.500.230.381.293.441.322.090.039.0510.533.0312.070.130.001.540.000.000.000.613.721.610.520.160.630.292.59XAD0.250.382.293.173.290.132.602.48-0.125.51.1-861078230.85.112.82.45.22.118.91.121.626.227.342.4117.5
8/288/28/00 0:008/29/00 0:001377.0011.41101628.659.26.140.390.170.371.182.881.021.840.0212.2612.480.0012.260.260.021.070.060.010.000.423.680.030.060.151.290.551.56XAD0.520.780.242.052.310.364.133.872.314.62.1-597772430.03.48.74.510.54.22.02.933.716.718.841.3110.5
8/298/29/00 0:008/30/00 0:001438.0020.88101728.994.44.130.730.110.580.864.042.111.890.0511.5511.645.2016.750.250.021.360.090.000.290.643.503.081.300.231.110.190.35XAD0.450.674.616.176.400.654.234.013.665.24.0-751073820.93.88.11.26.72.727.53.925.336.938.228.7129.1
8/308/30/00 0:008/31/00 0:021434.008.03101430.4219.73.551.200.290.725.505.772.802.900.069.6810.7210.720.140.050.840.160.010.000.302.630.070.050.183.721.462.22XAD1.492.230.315.526.260.37-0.40-1.14-3.361.30.8-475551324.52.87.913.634.713.92.93.4-3.751.458.433.8139.9
8/318/31/00 0:049/1/00 0:021438.0021.26101032.5198.03.3611.3211.5011.320.200.001.120.110.010.000.133.390.010.020.042.700.743.03XAD1.081.620.073.854.390.321.771.23-1.802.11.0-622711029.91.19.96.623.99.60.62.815.634.038.841.2129.7
9/19/1/00 0:049/2/00 0:021436.0012.15101131.3100.31.360.330.360.130.473.471.901.560.0216.2718.0516.270.170.001.450.040.000.000.125.200.020.030.174.441.253.90XAD1.782.660.216.427.310.211.620.73-3.171.80.9-8021083032.00.78.97.727.310.91.31.310.039.544.944.0138.4
9/29/2/00 0:049/3/00 0:021438.0020.90101131.4134.32.561.000.150.471.434.281.672.580.0315.0516.7415.050.270.051.950.000.000.000.236.260.010.010.122.550.422.99XAD1.021.530.143.714.220.322.161.65-1.352.21.0-10841302641.61.513.02.817.06.80.92.114.324.728.057.2124.3
9/39/3/00 0:049/4/00 0:021438.0018.01101032.4127.72.6514.2314.4114.410.290.001.000.070.000.020.373.320.010.000.106.080.654.16XAD2.433.650.118.629.830.390.07-1.15-5.311.40.8-566691923.02.67.04.542.216.90.82.70.559.868.231.7160.2
9/49/4/00 13:249/5/00 0:02638.009.39100935.711323.5023.1123.502.180.051.880.060.060.000.165.860.020.030.365.620.990.76XAD2.253.370.418.279.402.344.002.872.112.11.9-10431222024.90.78.04.223.99.61.710.017.035.240.034.3126.5
9/59/5/00 0:049/6/00 0:021432.006.11101032.6127.15.8126.1035.0826.101.340.352.550.260.420.030.356.390.721.780.267.811.023.90XAD3.124.692.7613.6915.262.40-0.30-1.86-5.761.40.9-1416133-324.51.39.83.929.912.010.69.2-1.252.558.433.7143.4
9/69/6/00 0:049/7/00 0:021438.0020.88101128.2107.537.1143.3740.240.240.163.790.080.340.410.1812.200.010.010.0014.191.113.68XAD5.678.510.0219.8822.721.221.86-0.98-4.651.51.2-21032544730.30.49.42.835.314.10.13.04.649.456.541.7152.2
9/79/7/00 0:049/8/00 0:011435.0011.97101027.565.814.3215.2514.780.460.001.160.070.040.000.033.190.020.030.116.240.651.12XAD2.503.750.168.9010.140.570.28-0.97-2.091.41.2-64166321.60.27.84.442.216.91.03.91.960.268.629.7160.4
9/89/8/00 0:039/9/00 0:011438.0020.67101025.448.711.0514.1112.580.060.001.320.020.000.000.063.890.010.010.045.030.000.00XAD2.013.020.067.098.100.080.13-0.87-0.871.41.4-73181931.00.510.50.040.016.00.50.71.056.464.442.6164.4
9/99/9/00 0:039/10/00 0:011436.0011.97101026.758.15.169.127.820.100.000.830.000.000.000.112.730.010.010.041.580.630.21XAD0.630.950.062.272.580.111.160.840.632.11.9-462571334.81.410.68.020.28.10.71.414.829.033.047.9124.7
9/109/10/00 0:039/11/00 0:021439.0020.90101128.661.410.3215.1810.320.230.001.300.040.000.030.174.650.030.020.061.530.421.31XAD0.610.920.102.242.550.301.240.93-0.372.21.2-723972745.01.612.64.014.85.91.02.912.021.724.762.0120.4
9/119/11/00 0:039/12/00 0:021436.008.03101128.238.97.048.587.040.120.000.950.110.000.050.262.770.010.000.031.120.260.21XAD0.450.670.051.611.830.290.890.670.462.21.9-53458939.43.713.53.815.96.30.74.112.722.926.154.2115.8
9/139/13/00 0:039/14/00 0:011436.0013.94101325.129.84.635.155.150.090.000.480.090.000.080.201.330.000.000.181.290.570.55XAD0.520.780.181.992.250.250.320.07-0.481.71.2-26328525.74.09.211.125.110.13.54.96.338.743.735.4124.1
AVG16-Aug-0013-Sep-002715.6101528.995.83.100.560.260.401.693.911.632.230.0614.8718.002.0716.350.320.051.640.130.040.100.504.780.500.310.153.190.601.511.281.910.965.426.060.652.772.130.623.52.3-918991629.83.110.34.419.87.96.13.614.933.837.741.0127.5100.0
StDev6.242.044.11.310.310.120.141.150.860.620.670.037.709.991.647.710.370.080.850.190.100.230.412.740.890.460.092.800.341.281.121.681.324.004.530.754.044.254.873.82.647757189.22.02.93.211.74.78.53.115.816.318.412.718.9
2729.23.010.03.719.57.85.84.016.933.137.040.2127.5100.0
For light org. acids experimental denuder efficiencies are taken into account; for all other species, efficiencies of 1 are assumed.Site: LaPorte, Houston, TX
Measurement Period: 8/16/00 - 9/13/00
# of samples: 48
AVGSTD
16.357.71
1.691.15ppbv
0.560.31ppbv
3.101.31ppbv
GAShisto
29.8122667835
3.1400621334
10.3074417845
4.4049777578
19.7980173963
7.9192069585
6.0586860142
3.6156278288
4.871436349