Membrane Gas–Solvent Contactor Trials of CO2 Absorption From Syngas
Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2...
Transcript of Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2...
![Page 1: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/1.jpg)
Down Flow Gas Contactor
Presentation by Jyoti Palekar
![Page 2: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/2.jpg)
Why DGC ?
![Page 3: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/3.jpg)
DGC is a Co-current Down flow Reactor providing
the most efficient Mass Transfer System for Gas
What is DGC ?
the most efficient Mass Transfer System for Gas
Liquid Contact
![Page 4: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/4.jpg)
Downflow Gas Contact Reactor
• Consists of Column Reactor.
• Downward Co-current flow of
Gas and Liquid – through
specially designed entry section. specially designed entry section.
• Shear created at interface provides
effective gas-liquid mixing:
allows mass transfer operations to
approach equilibrium in very
short contact time.
![Page 5: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/5.jpg)
Bubble Dispersion in DGC
![Page 6: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/6.jpg)
DGC Reactor – A snapshot
Gas Utilisation Close to 100%
Gas/liquid mass transfer
area
1000 – 6000 m2/m3
Volumetric Mass Transfer
Coefficient
0.2 – 12 kLa
Internal Moving parts Absent
Scale-up (without loss in
efficiency)
Easy
Engineering and Fabrication
costs
Low as the system can be fabricated in India. Only top nozzle
of DGC will be imported
Design Simple/ Compact /FlexibilityDesign Simple/ Compact /Flexibility
Environmental Applications Gas absorption (Biogas enhancement, EO treatment, Air
Stripping of VOCs/ Solvents etc)
Waste water treatment
DGC for Wet air oxidation process- effluent / sludges
Activated sludge treatment
Fermentation
Operation Mode Batch/continuous mode
Operating volume Smaller
Tolerance to particulates high solid content
Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO2 etc.
![Page 7: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/7.jpg)
Industrial Applications
• GAS ABSORPTION
• EFFLUENT TREATMENT
• CHEMICAL REACTIONS
![Page 8: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/8.jpg)
Thank YouThank You
![Page 9: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/9.jpg)
Media Composition 60% Biogas, 38% CO2, 2% H2S
Media Used Sea salt NaOH + Water
Na2CO3+Water+MethylEthylamine
Sea water
Case Study - CO2 Capture from Biogas
Liquid Flow Rate 10-15 L/min
Gas Flow Rate 1-3 L/min
Pressure 1-4.5 bar
Inlet CO2 in Air 38%
Outlet CO2 in Air 2-8 %
![Page 10: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/10.jpg)
DGC for Waste water Treatment Application
![Page 11: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/11.jpg)
UV Lamp 2.0kw
Flow Rate 10 L/min
Gas Flow Rate (O2 flow rate) 0.05 L/min
Temperature 330C
Pressure 0-8 bar
CASE STUDY- PHARMACEUTICAL
WASTEWATER TREATMENT
Pressure 0-8 bar
Operating Mode Batch
Volume Of DGC Reactor 17 Litre
Batch Volume 15 Litre
Residence time in DGC 1.5 min
Contact time O2- 42 sec
UV- 36 sec
![Page 12: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/12.jpg)
COD reduction in DGC
![Page 13: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/13.jpg)
DGC Advantages
� Lower power consumption
� Smaller operating volumes
� No foaming
� Close 100% Gas utilisation
� No internal moving parts
� Lower capital and operating costs
� Higher gas hold ups
� Tolerance to particulates
� High and accurate control of
interfacial areas
� Simple, compact and flexibility of
design
� Ease of scale-up with no loss of
efficiency
� Ease of automation and control
� Low engineering and fabrication
costs
![Page 14: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/14.jpg)
Wide application of DGC technology in waste
treatment will include:
� Treatment of effluents from pulp and paper industry,
Pharmaceutical effluents, spent caustic from refineries,
pesticide effluents, dye industry and cyanide containing
effluents eg. steel, electroplating industries.
� Treatment of landfill leachates
� DGC can be used for biological treatment process from
achieving the effective transfer of oxygen.
![Page 15: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/15.jpg)
� For biogas enhancement – increasing the methane content of
biogas
� Reducing the carbon footprint by Carbon capture from flue
gas- power plants, iron ore industry
� Capture and degradation of gaseous pollutants such as
ethylene oxide without scrubbing and generating liquid
effluents.
� Minimisation of sludge from wastewater treatment plant
![Page 16: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/16.jpg)
GAS ABSORPTION� Gas-Liquid contacting devices are widely used in the chemical
industry for absorbing gases into liquids and solvents
� Conventional devices range from stirred vessels to packed beds
and bubble columns
� Most devices employ up flow mode of gas flow with relatively � Most devices employ up flow mode of gas flow with relatively
low gas hold ups
� Problems with conventional technologies include gas
disengagement, coalescence and back mixing problems
� Gas pockets are also formed causing safety problems
![Page 17: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/17.jpg)
DGC Pilot Plant P&ID
![Page 18: Down Flow Gas Contactor · Modifications Can be modified to incorporate UV, Ozone, O2/ UV/ TiO 2 etc. Industrial Applications • GAS ABSORPTION • EFFLUENT TREATMENT • CHEMICAL](https://reader035.fdocuments.us/reader035/viewer/2022070112/60581119a5debd6bc30a30e4/html5/thumbnails/18.jpg)
Thank YouThank You