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Biodiesel: orBiodiesel: orYour fries giveYour fries give
me gasme gas
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Who are we?Who are we? Jill ParleeJill Parlee
Handel CallenderHandel Callender
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Sources ofSources of
feedstockfeedstockRestaurantsRestaurantsHotelsHotels
SnackettesSnackettes
School cafeteriasSchool cafeterias
CruiseshipsCruiseships
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You can also growYou can also grow
your own fuel.your own fuel.Dominica has aDominica has arange of oil crops,range of oil crops,coconut being thecoconut being the
most popularmost popular
Coconut yields 2,260Coconut yields 2,260
kg oil/hectarekg oil/hectare
Jatropha yieldsJatropha yields
1,590 kg oil/hectare1,590 kg oil/hectare
Castor bean yieldsCastor bean yields
1188 kg oil/hectare1188 kg oil/hectare
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Raw materialsRaw materials
neededneeded Vegetable oil (feedstock)Vegetable oil (feedstock) MethanolMethanol
Potassium Hydroxide or Sodium HydroxidePotassium Hydroxide or Sodium Hydroxide
Safety precautions:Safety precautions:
Methanol is a highly toxic and flammable alcohol.Methanol is a highly toxic and flammable alcohol.
Gloves, masks, long sleeved work clothes and aGloves, masks, long sleeved work clothes and awell ventilated area should be all accessible whenwell ventilated area should be all accessible whenworking with itworking with it
Sodium Hydroxide is highly alkaline and willSodium Hydroxide is highly alkaline and willproduce severe burns when in contact with skinproduce severe burns when in contact with skin
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The chemistry ofThe chemistry of
biodieselbiodiesel Vegetable oil + Methanol + Potassium Hydroxide =Vegetable oil + Methanol + Potassium Hydroxide =Methylester (biodiesel)Methylester (biodiesel)
TRIGLYCERIDE MOLECULE (VEGE OIL)
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Whats the equipment youWhats the equipment you
need?need?
(piecing it together)(piecing it together)Requirement DescriptionFeedstock storage To hold all vegetable oil collected or
produced
Biodiesel reactor For mixing oil and chemicals
Byproduct storage To hold glycerin byproductWater storage Rain or river water
Biodiesel wash system Cleaning the crude biodiesel beforeplacing in vehicles
Waste water treatment and
storage
Cleaning up the water used to wash
biodieselBiodiesel storage
Distribution Pumps or fuel containers to deliver fuelto vehicle tank
A small room for a lab Fuel quality testing and chemical prep
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Stage 1: Feedstock storage andStage 1: Feedstock storage and
pretreatmentpretreatmentYou may need:55 gallon metal drums1000 litre containersWater tanksLarge metal storage tanks
Some basic requirements for feedstock
storage:Ideally it should have a cone shaped
bottomIt should be able to take some heat
(up to70 Celsius)
It should have fittings to easily connectplumbingIt should be easily and safely filled
Additional components for feedstock storage:A pump and plumbing fittings are needed to
transfer prepared oil to reactor
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Stage 2: The ReactorStage 2: The Reactor
You may need:You may need:
55 gallon metal drum55 gallon metal drum
HDPE prefabricated plasticHDPE prefabricated plasticcontainercontainer
Stainless steel vesselStainless steel vessel
Some basic requirements for biodieselSome basic requirements for biodieselreactorreactor
It should be sealed or have a coverIt should be sealed or have a coverto prevent fume leaksto prevent fume leaks
Ideally it should have a coneIdeally it should have a cone
shaped bottomshaped bottom
It must have a pump or a high toIt must have a pump or a high tomedium speed mixer of some kindmedium speed mixer of some kind
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The Reactor cont.The Reactor cont.
It should be able to take heat.It should be able to take heat.The reaction temp is optimal atThe reaction temp is optimal ataround 55 Celsiusaround 55 Celsius
It should have fittings to easilyIt should have fittings to easilyconnect plumbingconnect plumbing
It should be easily and safelyIt should be easily and safelyfilledfilled
Some welding may be requiredSome welding may be required
Plumbing will be needed toPlumbing will be needed totransfer crude biodiesel to thetransfer crude biodiesel to thewash stagewash stage
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The biodieselThe biodiesel
reactionreactionOil and methanol areOil and methanol aremixed in the presence of amixed in the presence of a
catalyst NaOH or KOH.catalyst NaOH or KOH.
100 Gallons of oil100 Gallons of oil
produces 80 gallons ofproduces 80 gallons of
biodiesel and 25 gallons ofbiodiesel and 25 gallons of
glycerin.glycerin.
Glycerin can be disposedGlycerin can be disposed
of as biodegradableof as biodegradable
waste, used as soap, orwaste, used as soap, or
refined into pure glycerin.refined into pure glycerin.
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The biodieselThe biodiesel
reactionreaction
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Stage 3: Washing and drying theStage 3: Washing and drying the
BiodieselBiodiesel
Washing biodiesel involves the
removal of chemical impurities and
soaps created in the production
process, that would cause harm to
a vehicle engine. Washing involves
mixing water with the crudebiodiesel
Drying biodiesel requires the
removal of water, via heat or
settling, from the biodiesel after ithas been washed.
There is new technology now, that
does allow for cleaning biodiesel
without the use of water.
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Stage 3: Washing and drying theStage 3: Washing and drying the
biodiesel cont.biodiesel cont.
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Stage 3: Washing and drying theStage 3: Washing and drying the
biodiesel cont.biodiesel cont.
You will need:You will need:
Thorough mixing ofThorough mixing ofbiodiesel and water viabiodiesel and water viapumps or mixerspumps or mixers
Application of heat forApplication of heat fordrying, to remove moisturedrying, to remove moisturefrom biodiesel afterfrom biodiesel afterwashingwashing
Good drainageGood drainage
Plumbing to transfer fromPlumbing to transfer fromwashing to storagewashing to storage
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Economics ofEconomics of
biodieselbiodieselInputsInputs
SupplySupply
DemandDemand
Niche MarketNiche Market
ExpensesExpenses
RevenuesRevenues
Pricing structurePricing structure
Business structureBusiness structure
FundingFunding
R t i lR t
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Raw materialRaw mater ainputsinputsSecuring raw materialsSecuring raw materials
Vege oil collectionVege oil collectionFree?Free?
Shared?Shared?
StrategicStrategicpartnerships withpartnerships withsuppliers? Friends?suppliers? Friends?Communities?Communities?
Chemical importationChemical importationcostscosts
Shared?Shared?
Bulk?Bulk?
Alternatives?Alternatives?
Concessions andConcessions andincentives from Gov.incentives from Gov.
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Your expensesYour expenses ElectricityElectricity
Used mainly to heat oil and biodiesel, and power pumpsUsed mainly to heat oil and biodiesel, and power pumps
Conventional?Conventional?
Alternatives?Alternatives?
WaterWater
Mainly for cleaning up biodieselMainly for cleaning up biodiesel
Cleaning your water is a huge plus, even if it was originally free.Cleaning your water is a huge plus, even if it was originally free.
Human labourHuman labour
Collecting oilCollecting oil
Processing biodieselProcessing biodiesel
Sales and marketingSales and marketing
Admin.Admin.
FuelFuel
Energy is also used in the vehicle to collect oil and drop offEnergy is also used in the vehicle to collect oil and drop offbiodieselbiodiesel
Where can you save?Where can you save?
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Your revenuesYour revenues
Developing the byproduct, glycerinDeveloping the byproduct, glycerin
Unique opportunities exist in Dominica toUnique opportunities exist in Dominica todevelop assisting technologiesdevelop assisting technologies
Coconut drying technologyCoconut drying technologyWater harvestersWater harvesters
Coconut oil businesses specifically for biodieselCoconut oil businesses specifically for biodiesel
How you generate income can influence yourHow you generate income can influence yourpricing structure, how you promote the fuelpricing structure, how you promote the fuel
and your business philosophy.and your business philosophy.
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Why supportWhy support
biodiesel?biodiesel?Biodiesel is produced primarily with local materials,Biodiesel is produced primarily with local materials,significantly reducing foreign exchange expendituresignificantly reducing foreign exchange expenditure
Reduced vulnerability to external fluctuations in fuelReduced vulnerability to external fluctuations in fuelprices.prices.
Improves Barbados image as an eco destination.Improves Barbados image as an eco destination.
Provides a solution to current waste disposal problems andProvides a solution to current waste disposal problems andreduces costs incurred through disposal.reduces costs incurred through disposal.
Health/environmental benefits due to use of the fuel.Health/environmental benefits due to use of the fuel.
Significant savings in health care costsSignificant savings in health care costs
Job creation.Job creation.
Establishes linkages to agriculture that might help solidifyEstablishes linkages to agriculture that might help solidifynew avenues for the sectornew avenues for the sector
Can take Barbados steps ahead to true sustainableCan take Barbados steps ahead to true sustainabledevelopmentdevelopment
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Benefits ofBenefits of
biodieselbiodieselHealth/EnvironmentHealth/EnvironmentReduction of carbon dioxide emissions (CO2) by 100%Reduction of carbon dioxide emissions (CO2) by 100%
Reduction of sulfur dioxide (SO2) emissions by 100%Reduction of sulfur dioxide (SO2) emissions by 100%
Reduction of soot emissions by 40-60%Reduction of soot emissions by 40-60%
Reduction of carbon monoxide (CO) emissions by 10-Reduction of carbon monoxide (CO) emissions by 10-50%50%
Reduction of hydrocarbon (HC) emissions by 10-50%Reduction of hydrocarbon (HC) emissions by 10-50%
Reduction of all polycyclic aromatic hydrocarbonsReduction of all polycyclic aromatic hydrocarbons(PAHs) and specifically the reduction of the following(PAHs) and specifically the reduction of the followingcarcinogenic PAHs:carcinogenic PAHs:Reduction of phenanthren by 97%Reduction of phenanthren by 97%Reduction of benzofloroanthen by 56%Reduction of benzofloroanthen by 56%Reduction of benzapyren by 71%Reduction of benzapyren by 71%Reduction of aldehydes and aromatic compounds byReduction of aldehydes and aromatic compounds by13%13%
Reduction or increase in nitrous oxide (NOx) emissionsReduction or increase in nitrous oxide (NOx) emissionsby 5-10% depending on the age and type of engine.by 5-10% depending on the age and type of engine.
Benefits ofBenefits of
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Benefits ofBenefits ofbiodiesel.biodiesel.
Biodiesel runs in any conventional, unmodified diesel engine.Biodiesel runs in any conventional, unmodified diesel engine.In other words, you just pour it into the fuel tank.In other words, you just pour it into the fuel tank.
Biodiesel can be stored anywhere that petroleum diesel fuelBiodiesel can be stored anywhere that petroleum diesel fuelis stored.is stored.
Biodiesel can be used alone or mixed in any amount withBiodiesel can be used alone or mixed in any amount with
petroleum diesel fuel.petroleum diesel fuel.
Biodiesel is more lubricating than diesel fuel. Its higherBiodiesel is more lubricating than diesel fuel. Its higherlubricity enhances the lifetime of the engine.lubricity enhances the lifetime of the engine.
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Benefits ofBenefits of
biodieselbiodieselBiodiesel is safe to handle because it isBiodiesel is safe to handle because it isbiodegradable and non-toxic. According to thebiodegradable and non-toxic. According to theNational Biodiesel Board, neat biodiesel is asNational Biodiesel Board, neat biodiesel is asbiodegradable as sugar and less toxic than salt.biodegradable as sugar and less toxic than salt.
Biodiesel is safe to transport. Biodiesel has a highBiodiesel is safe to transport. Biodiesel has a highflash point, or ignition temperature, of about 300flash point, or ignition temperature, of about 300
deg. F compared to petroleum diesel fuel, which hasdeg. F compared to petroleum diesel fuel, which hasa flash point of 125 deg. F.a flash point of 125 deg. F.
Engines running on biodiesel run normally and haveEngines running on biodiesel run normally and havesimilar fuel mileage to engines running on dieselsimilar fuel mileage to engines running on dieselfuel. Auto ignition, fuel consumption, power output,fuel. Auto ignition, fuel consumption, power output,and engine torque are relatively unaffected byand engine torque are relatively unaffected bybiodiesel.biodiesel.
When burned in an engine, the exhaust fumes haveWhen burned in an engine, the exhaust fumes havethe pleasant aroma of popcorn or French fries.the pleasant aroma of popcorn or French fries.
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Starting up inStarting up in
DominicaDominica Consider starting as aConsider starting as a
group. Discuss fundinggroup. Discuss fundingoptions, businessoptions, businessstructure etc.structure etc.
Seek affordable groupSeek affordable grouptrainingtraining
Consider collecting rawConsider collecting rawmaterial. It might bematerial. It might bewiser to begin collectingwiser to begin collectingearly.early.
Get the materials youGet the materials youhave to purchase, in bulkhave to purchase, in bulk
Discuss how much youDiscuss how much youwant to produce and startwant to produce and startfor yourselves first.for yourselves first.
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ReferencesReferences
http://www.journeytoforever.orghttp://www.journeytoforever.org
http://www.biofuels.coop/http://www.biofuels.coop/
http://www.journeytoforever.org/http://www.journeytoforever.org/http://www.journeytoforever.org/ -
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