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Transcript of Disinfection
6/10/2015
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Disinfection
MK Satuan Proses
Environmental Engineering
Materi
1. Purpose of disinfection2. Disinfection methods 3. Mechanisms of Disinfectant4. Disinfection kinetics
Environmental Engineering
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Purpose of disinfection
• The killing of pathogenic organisms with the objective of preventing the spread of water-borne diseases.
• This process is function– Type and concentration microorganism– Type and concentration disinfectant– Presence of oxidant-consuming compounds– Temperature– Dose of chemical– Contact time– pH
Environmental Engineering
Disinfection Method
Physical methods• Heat treatment• Exposure to UV-rays• Exposure to metal ions
(silver, copper)
Chemical Methods• Chlorine gas• Chlorinated compounds
(chlorine dioxide)• Phenol• Phenolic compounds• Various alkalies and
acids• Ozone
Environmental Engineering
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Disinfection with Chlorine
Golongan Senyawa Klorine
1. Chlorine, Cl22. Sodium hypochlorite, NaOCl3. Calcium Hypochlorite, Ca(Ocl)24. Chlorine dioxide, ClO2
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Mechanisms of Disinfectant
1. Damage to the cell wall– Inhibit the synthesis of the bacterial cell wall– Agent : penicillin
2. Alteration of cell permeability– Allow vital nutrients, such as nitrogen and
phosphorus, to escape– Agent: phenolic compounds and detergents
Environmental Engineering
Mechanisms of Disinfectant
3. Alteration of the colloidal nature of the protoplasm.– Heat will coagulate the cell protein and acids or bases
will denature proteins, producing a lethal effect.– Agent : Heat, radiation, and highly acidic or alkaline
agent4. Inhibition of enzyme activity
– Alter the chemical arrangement of enzymes and deactivate the enzymes.
– Agents: Oxidizing agents, such as chlorine
Environmental Engineering
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Chlorine Chemistry
• When chlorine is added to wastewater (NH3 & Organic compounds) , part of it reacts to produce
• First Parts– Hypochlorous acid (HOCl) (free chlorine residual)
• Cl2 + H2O ⇌ HOCl + HCl
• Second Parts– Hypochlorite ion (OCl-) (free chlorine residual)
• HOCl⇌ OCl- + H+
– Disinfection power of HOCl is about 40-80 times greater than that of OCl-
Environmental Engineering
Chlorine Chemistry
• Third Part– reaction with ammonia to form chloroamines (mono-, di-
, and trichloroamines) (combined chlorine residual)• NH3 + HOCl NH2Cl (monochloroamines) + H2O• NH2Cl + HOCl NHCl2 (dichloroamine) + H2O• NHCl2 + HOCl NCl3 (trichloroamine) + H2O
– Comparing with free chlorine residual, combined chlorine residual, due to chloroamines, has a lower disinfecting property
Environmental Engineering
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Chlorine Chemistry
• Fourth part– oxidizing inorganic matter (e.g hydrogen
sulfide, iron, manganase)
• Fifth part– Reaction with organic compounds to form trihalomethanes
(THMs) and other chlorinated organics
Environmental Engineering
Breakpoint Chlorination
• When chlorine is added to water– It is consumed in oxidizing wide variety
compounds present in water.• No chlorine residual can be measured until the chlorine
demand is satisfied.
– Then chlorine reacts with ammonia producing combined chlorine residual.
• Combined chlorine residual increases with additional dosage until a maximum combined chlorine residual is reached
Environmental Engineering
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Breakpoint Chlorination
– Further addition of chlorine causes a decrease in combined chlorine residual.
• At this point the chloroamines are oxidized to oxides of nitrogen or other gases.
– After breakpoint chlorination is reached, free chlorine residual develops at the same rate as applied dosage
Environmental Engineering
Environmental Engineering
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KINETIKA DESINFEKSI
Environmental Engineering
Chick’s Law
• In 1908 Ms. Harriet Chick found that her disinfection experiments could best be described by a first-order reaction:
Environmental Engineering
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Chick’s LawEnvironmental Engineering
• Relationship between disinfectant concentration and contact time
The Van‘t Hoff-Arhenius Eq.
• The Van’t Hoff-Arrhenius equation can be used to relate the effects of temperature on the disinfection process
Ln (t1/t2)=[E(T2-T1)]/R.T2.T1
• Where– t1,t2 = time required for the given kills, s– E = activation energy, cal– T1,T2 = temperature corresponding to t1 and t2, K– R = gas constant
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• ExampleDetermine the contact time needed for a disinfectant to achieve a 99.99% kill for a pathogenic microorganism that has a rate constant of 0.1 s-1
• SolutionGiven rate of kill = 99.99%, k = 0.1 s-1
Find the contact time from Chick’s Law t = -(1/k)*ln(N/No)t = -(1/0.1 s-1)*ln(100-99.99/100)t = 92.103 s
Environmental Engineering
Environmental Engineering
Menentukan konstanta Chick-Watson Model
• Data berikut adalah hasil tes pada reaktor batch untuk kemampuan hidup E.coli (dalam persen) setelah dikontakkan dengan klor. Tentukan konstantapersamaan Chick-Watson model jika kematianbakteri 99%!
klor tersediabebas mg/l
waktu kontak, menit
1 3 5 10 200.05 96 81 62 20 0.3
0.1 91 58 27 0.5 -0.18 64 10 0.7 - -
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Chick-Watson model
• Bentuk Integral
• Where k’ = die-off constant C =konsentrasi disinfektann = coeeficient of dillution
• Bentuk Liniear
Environmental Engineering
Chick-Watson model
• Bentuk Liniear (Concentration vs time)
n = 1 konsentrasi dan waktu adalah pentingn > 1 konsentrasi lebih pentingn < 1 waktu lebih penting
Environmental Engineering
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• Plotting grafik -Ln(Nt/N0) vs waktu
klortersediabebasmg/l
- Ln (Nt/N0)
waktu kontak, menit
1 3 5 10 20
0.05 0.041 0.211 0.478 1.609 5.809
0.1 0.094 0.545 1.309 5.298 -
0.18 0.446 2.303 4.962 - -
Environmental Engineering
0.000
1.000
2.000
3.000
4.000
5.000
6.000
7.000
0 2 4 6 8 10 12 14 16 18 20
-ln(N
t/N
o)
time, min
0.05
0.1
0.18
99% mati
Environmental Engineering
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• Waktu kematian bakteri 99% untuk tiapkonsentrasi (dari grafik) - ln(Nt/N0)=4.61
• Mengubah C vs t dalam bentuk ln C vs ln t persamaan garis y=bx+a
C t ln C ln t
0.05 16.6 -2.99573 2.809403
0.1 8.6 -2.30259 2.151762
0.18 4.4 -1.7148 1.481605
Environmental Engineering
y = -0.964x - 0.266
-3.5
-3
-2.5
-2
-1.5
-1
-0.5
00 1 2 3
ln C
ln t
Series1 Linear (Series1)
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• Persamaan garis y = -0.964x - 0.266
• Menetukan nilai n
- 1/n = -0.964n = 1.03
• Menentukan nilai k’
= -0.266
0.964 ln[1/k’(-ln 1/100)] = -0.266ln[1/k’(-ln 1/100)] = -0.276
ln[1/k’ (4.61)] = -0.2761/k’(4.61) = exp (-0.276)
1/k’ = exp(-0.276)/4.611/k’ = 0.164
k’= 6.097
Environmental Engineering
t
0
Nln
N
Jadi persamaan Chick-Watson Model
= -6.097 C1.03t
Environmental Engineering
• Mencari nilai a dan b untuk persamaan garisY = bX + a