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Dangerous Goods Management
Ships in Service Training Material A-M CHAUVEL
International MaritimeDangerous Goods
2009
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The IMDG Code was designed for mariners
and first adopted by
the means of IMO resolution A.81 (IV) in 1965.
The provisions of the Code affect industries,
storage, warehousing, handling and
transport services from
manufacturers to consignees.
IMDG Code : Origin
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The IMDG Code is a guide on :
- Classification and Terminology.
- Identification and Packaging,
- Marking, Labelling and Placarding.
- Documentation
of dangerous cargoes
for transport by sea.
IMDG Code : Scope
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- Emergency Schedules for ships carrying dangerous goods ( EmS ).
- Medical First Aid Guide for use in accidents involving dangerous goods ( MFAG ).
- Code of safe practice for solid Bulk Cargoes ( BC Code ).
- Reporting procedures under SOLAS 74 and MARPOL 73/78.
- IMO / ILO guidelines for packaging cargo in freight containers or vehicles.
IMDG Code : Supplement
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- Recommendations on the safe use of pesticides in ships.
- Code for the safe carriage of irradiated nuclear fuel, plutonium and high-level radioactive wastes on board ships ( INF Code ).
- Other relevant recommendations.
IMDG Code : Supplement
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Dangerous Goodsin Packaged Forms
IMDG Code
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Class 1 - Explosives : substances and articles.
1.1- Mass explosion hazard.
1.2- Projection hazard but not a mass explosion hazard.
1.3- Fire explosion hazard or minor projection hazard and a minor blast hazard or minor projection hazard or both but not a mass explosion hazard.
1.4- No significant hazard.
1.5- Very insensitive with a mass explosion hazard.
1.6- Extremely insensitive with no mass explosion hazard.
Classification of Dangerous Goods
Ships in Service Training Material A-M CHAUVEL
in Packaged Forms
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Class 2 - Gases : Compressed, liquefied, or dissolved under pressure.
2.1- Flammable.2.2- Non-flammable, non-poisonous.2.3- Poisonous.
Class 3 - Flammable liquids.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged Forms
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Class 4.1 - Flammable solids.
Class 4.2 - Substances liable to spontaneous combustion.
Class 4.3 - Substances in contact with water emit flammable gases.
Class 5.1 - Oxidizing substances.
Class 5.2 - Organic peroxides.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged Forms
Class 4 -
Class 5 -
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Class 6.1 - Toxic substances.
Class 6.2 - Infectious substances.
Class 8 - Corrosives.
Class 9 - Miscellaneous dangerous substances and articles.
Class 7 - Radioactive materials.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged Forms
Class 6 -
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IMDG Code requires written statements
in the form of
declarations or certificates
that packages, freight containers
and/or vehicles are
properly packed.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged FormsPacking & Packaging
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Types of packages and packaging
are recommended by IMDG Code
to ensure a high degree of safety.
Specifications and performance tests
applicable are available in the annex 1.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged FormsPacking & Packaging
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Requirements for
intermediate bulk containers ( IBC's ):
- Rigid, semi-rigid or flexible portable packaging.
- Other than those specified in the annex 1.
Specifications and performance tests
applicable are available in section 26
of the General Introduction.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged FormsPacking & Packaging
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Requirements for portable tanks and road tank vehicles are given in section 13 of the General Introduction :
Type 1, 2 and 4 :
Liquids other than liquefied gases.
Type 5 and 6 :
Non-refrigerated liquefied gases.
Type 7 and 8 :
Refrigerated liquefied gases.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged FormsPacking & Packaging
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Other provisions given in the General
Introduction of the IMDG Code:
Section 12
Freight container traffic.
Section 17
Carriage on roll-on roll-of ships.
Section 19
Carriage in barges or barge-carrying
ship.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged FormsPacking & Packaging
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Dangerous goods must be identified according
to section 7 of the IMDG code for the necessary
care and precautions of those involved:
- Product name.
- UN number.
- Marine pollutant, if the case,
on documentation accompanying
a consignment of dangerous goods.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged Forms: Identification,Marking, Labeling, Placarding
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Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged Forms: Identification,Marking, Labeling, Placarding
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Each package should be durably marked :
- Product name.
- UN number.
- Marine pollutant, and If required by the
IMDG Code with the marine pollutant mark.
In case of cargo-transport units,
enlarged labels ( Placards ) should be used
and fixed to each cargo-transport.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged Forms: Identification,Marking, Labeling, Placarding
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Are harmful substances as defined in article 2 of the MARPOL 73/78
and its Annex III.
Marine pollutant : which have an extreme pollution potential are identified as severe maritime pollutants.Incidents involving the good must be reported.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged Forms: Identification,Marking, Labeling, Placarding
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The following segregation terms used are : - Away from... - Separated from... - Separated by a complete compartment or hold from... - Separated longitudinally by an intervening compartment or hold from...
Two substances or articles are considered mutually incompatible
when their storage together may result in undue hazards in cases
of leakage or spillage.
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goodsin Packaged Forms: Compatibility & Segregation
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Secure Modular, Storage Cabinets or Compartments
Ships in Service Training Material A-M CHAUVEL
Classification of Dangerous Goods
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Explosives1
INFLAMMABLE LIQUID
Flammable liquids3
SOLIDINFLAMMABLE
Flammable solids, Substances liable to spontaneous combustion,Substances which in contact with water emit flammable gases
4
Gases compressed, liquefied or dissolved under pressure2
Radioactive materials7
Toxic and infectious substances6
Miscellaneous dangerous substances9
Oxidising substances and organic peroxides5
Corrosives8
CORROSIVECORROSIVECORROSIVE
Classification of Dangerous Goodsin Packaged Forms: Marpol Annex III
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A-M CHAUVEL - BUREAU VERITAS - DNS / DCO Ships in Service Training Material A-M CHAUVEL
Good Practices Dangerous Goods
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Dangerous GoodsSolid Bulk Materials
IMDG Code
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1- Structural damage due to improper
distribution of the cargo.
2- Loss or reduction of stability due to
a shift of cargo or cargo liquefying.
3- Chemical reaction.
Hazards associated with the shipment of
solid bulk material come under the following
main categories :
Solid Bulk Materials : Hazards
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- Appendix A
Bulk materials which may liquefy.
- Appendix B
Bulk materials possessing chemical hazards.
- Appendix C
Bulk materials which are neither liable to
liquefy nor to possess chemical hazards.
The Solid Bulk Carrier Code makes the following distinctions :
Carriage of grain is regulated under the International Code for the Safe Carriage of Grain.
Solid Bulk Materials : Hazards
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High Density Cargoes
Danger of over-stressing is particularly relevant when the ship is moving at sea.
Require careful distribution within prescribed limits to prevent over-stressing.
In port, careful consideration must be given to the sequence of loading and the quantity of materials loaded at each port as well for the technique used for unloading.
Structure damage, unless discover in time,may result in the loss of the ship.
Solid Bulk Materials : Hazards
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Cargoes Liable to Liquefy
Cargoes which may liquefy must be kept in a dry or nearly dry state.
Liquefaction of cargoes results in loss of the ship stability and possible loss of the ship.
Increase of moisture content above the transportable moisture limit may result of liquefaction.
The shipper should provide the information.
Sampling procedures are specified in the BC Code.
Solid Bulk Materials : Hazards
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Cargoes Liable to Shift
Trimming instructions are specified for cargoes with an angle of response: - Less than or equal to 30°. - 30° to 35°. - Greater than 35° = Greater care.
The measure of the danger of shifting to which a non-cohesive cargo is subject is given in its angle of response.
BC Code makes a distinction between cohesive and non-cohesive cargoes.
Solid Bulk Materials : Hazards
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Class 4.1 - Flammable solids.
Class 4.2 - Substances liable to spontaneous combustion.
Class 4.3 - Substances in contact with water emit flammable gases.
Class 5.1 - Oxidizing substances.
Are classified in the similar way to packaged dangerous goods:
Ships in Service Training Material A-M CHAUVEL
Solid Bulk MaterialsSolid Bulk Materials : Hazards
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Class 6.1 - Toxic ( poisonous ) substances.
Class 6.2 - Infectious substances.
Class 8 - Corrosives.
Class 9 - Miscellaneous dangerous substances and articles.
Class 7 - Radioactive materials.
MHB - Materials Hazardous only in Bulk.
Ships in Service Training Material A-M CHAUVEL
Solid Bulk MaterialsSolid Bulk Materials : Hazards
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Stowage and segregation requirements apply
similarly to packaged dangerous goods
between:
- Bulk materials and bulk materials.
- Bulk materials and packaged form.
Ships in Service Training Material A-M CHAUVEL
Solid Bulk Materials posing Chemical Hazards
Solid Bulk Materials : Hazards
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Dust is inherent to cargo operations with many bulk materials.
Dust should be reduced to the minimum.
Precautions are necessary to minimize the risks due to exposure to the residual dust of certain materials carrier in bulk.
High standard of personal is required with use of protective clothing and barrier creams particularly in case of toxic materials.
Ships in Service Training Material A-M CHAUVEL
Solid Bulk Materials posing Dust Hazards
Solid Bulk Materials : Hazards
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Dust created by certain cargoes may constitute
an explosion hazard especially during :
- Cargo operations.
- Cleaning holds.
The risk can be minimized by :
- Ventilating spaces with dust-laden atmospheres.
- Hosing down rather than seeping.
Sampling and laboratory test procedures are
specified in the BC Code.
Ships in Service Training Material A-M CHAUVEL
Solid Bulk Materials posing Dust Hazards
Solid Bulk Materials : Hazards
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To assess the dangers for those on board, a shipmaster must be provide with the information essential to load and unload the ship safely.
The shipper should provide the shipmaster with appropriate certificates of test with details as : - chemical hazards. - flow moisture point. - stowage factor. - moisture content. - angle of response, etc…
Ships in Service Training Material A-M CHAUVEL
Solid Bulk Materials : HazardsInformation for Ships
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Dangerous GoodsBulk Liquids
IMDG Code
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SOLAS 74 - Chapter VII part B
- Construction and equipment.
International Bulk Chemical Code ( IBC )
- Detailed requirements.
MARPOL 73/78 - Annex II
- Standards for Procedures and
Arrangements for the discharge of
Noxious Liquid Substances.
Ships in Service Training Material A-M CHAUVEL
Bulk LiquidsLiquid Chemical Standards
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SOLAS 74 - Chapter VII part C
- Construction and equipment.
International Gas Carrier Code ( IGC )
- Further regulations.
Ships in Service Training Material A-M CHAUVEL
Bulk LiquidsLiquefied Gases Requirements
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MARPOL 73/74 - Chapter VII part B
- Construction, equipment and operation.
- Annex 1 defines Oil as any mineral oil.
Ships in Service Training Material A-M CHAUVEL
Bulk LiquidsOil tanker Requirements
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Ships in Service Training Material A-M CHAUVEL
Personal Protective Equipment
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Safety Protection : Head
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Safety Protection : Eyes
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Safety Protection : Ears
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Ships in Service Training Material A-M CHAUVEL
Safety Protection : Facial and Respiratory
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Safety Protection : Hands
Ships in Service Training Material A-M CHAUVEL
Gloves for Vibration
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Safety Protection : Body
Ships in Service Training Material A-M CHAUVEL
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Ships in Service Training Material A-M CHAUVEL
Safety Protection : Body
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Safety Protection : Feet
Ships in Service Training Material A-M CHAUVEL