CONRAD & O'BRIEN, P.c. · conrad & o'brien, p.c. attorneys at law the drexel building 15th and...

CONRAD & O'BRIEN, P.c.ATTORNEYS AT LAW

THE DREXEL BUILDING15TH AND WALNUT STREETS . / , a _

PHILADELPHIA, PENNSYLVANIA 19102 ( ' ( ""0(215) 864-0810

July 1, 1985

HAND DELIVER

Mary M. LetzkusCompliance OfficerUnited States EnvironmentalProtection Agency - Region III841 Chestnut StreetPhiladelphia, PA 19107

RE: Heleva Landfill

Dear Mary:

Enclosed, as requested, is the data specified in ChuckSands' memorandum to Patricia Krantz of May 30, 1985. Alsoenclosed is the raw data for samples PW-02, PW-03 and PW-28.

Cordially,

.iam J. O'Brien

men

Enclosures

cc: Joseph J. C. Donovan, Esquire (w/o enclosures)

Aft

QUANT REPORT

perator ID: BOB Quant Time: 850316 19:34Injected at: 850316 18:58

Data File: >P0084::B1 Dilution Factor: 1.00Name: preJC. i~f

ID File: HSLUOATitle: HAZARDOUS SUBSTANCE LIST UOA COMPOUNDSLast Calibration: 850314 09:39

Compound R.T. Scan* Area Cone Units

1) *BROMOCHLOROMETHANE 10.80 140 188154 50.00 ug/L6) METHYLENE CHLORIDE 7.24 85 14537 2.83 ug/L7) TRICHLOROFLUOROMETHANE 9.50 120 5943 .67 ug/L10) ACETONE 8.02 97 7345 3.62 ug/L /12) 1,1-DICHLOROETHENE (a CCC) 10.28 132 55211 14.96 ug/L^15) CHLOROFORM (a CCC) 13.12 176 16872 1.68 ug/L17) l,2-DICHLOROETHANE-d4 (SURROG) 13.77 186 221205 37.30 ug/L18) «1,4-DIFLUOROBENZENE 21.39 304 875984 50.00 ug/L•22-*——WWL ACCTaTC————————————————18.74——243———63056———00.44 ug.'L-26) TRICHLOROETHENE 18.29 256 54131 8.47 ug/L«29) BENZENE 18.80 264 103382 6.78 ug/L^ ) *CHLOROBENZENE-d5 26.36 381 681386 50.00 ug/L

) TOLUENE (a CCC) 25.33 365 85845 7.88- ug/L9) TOLUENE-d8 (a SURROGATE) 25.13 362 647805 48.49 ug/L40) CHLOROBENZENE (a SPCC) 26.49 383 64595 4.53 ug/L45) 4-BROMOFLUOROBENZENE (a SURRO) 31.14 455 445330 51.54 ug/L

29

•* Compound is ISTD

It

TOTAL ION CHROHPTOQRRMFil« >P0084 38.0-260.0 **u.

TIC

.... i ... f ??... i ... 2P?... i . . . ?P?....... 4?9....480000-1 ' ' ' '

440000-

400000-

360000-

320000-

280000-

240000-t

200000-

160000-

120000-

' 80000-

40000-

0-18 16 80 ' 2*4" ' " 2*8 ' ' s'2 ' ' 3*6

Data File: >P0084::8.1Name: f.feJc, fai {?-**Misc!Id File: HSLUOATitle: HAZARDOUS SUBSTANCE LIST UOA COMPOUNDSLast Calibration: 890314 09:39

Operator ID: BOBQaunt Time: 850316 19:34

QUANT REPORT

orator ID: BOB Quant Time: 850316 20:16Injected at: 850316 19:39

Data File: >P0085::B1 _ Dilution Factor: 1.00Name : Fred C.



1.) "BROMOCHLOROMETHANE 10.80 140 171461 50.00 ug/L6) METHYLENE CHLORIDE 7.18 84 14345 3.06 ug/L7) TRICHLOROFLUOROMETHANE 9.50 120 5598 .70 ug/L10) ACETONE 8.02 97 7391 4.00 ug/L12) 1,1-DICHLOROETHENE (a CCC) 10.28 132 80662 23.98 ug/L15) CHLOROFORM (a CCC) 13.12 176 15120 1.65 ug/L17) l,2-DICHLOROETHANE-d4 (SURROG) 13.77 186 213266 39.46 ug/L18) » 1 , 4 - D I F L U O R O B E N Z E N E 2 1 . 3 8 304 792906 50.00 ug/L

R810QI03

26) TRICHLOROETHENE 18.29 256 73531 12.7129) BENZENE 18.80 264 143566 10.40

*CHLOROBENZENE-d5 26.36 381 608662 50.00TOLUENE (a CCC) 25.32 365 109801 11.28TOLUENE-d8 (a SURROGATE) 25^13 362 588822 49.34 ug/L

40) CHLOROBENZENE (a SPCC) 26.49 383 90238 7.09 ug/L45) 4-BROMOFLUOROBENZENE (a SURRO) 31.07 454 409809 53.09 ug/L

* Compound is ISTD

TOTflL ION CHROMPTOSRflMfilm >PQ085 35.0-860.0 *»u.

TIC

.... i ... f?9. . . i . ... ???. . . i . , . ???. . . i . . . 4?9 . . . i . . . ?P?480000-

440000-

400000-

360000-

320000-

280000-

240000-

200000-

160000-

120000-

80000-

40000-

0-4 ' ' ' k ' ' ' l'a' ' ' iV ' 2V T 24 r 2F8 r 3'2

Data File: >P0085::B1Name:Misc:

Id File: HSLUOATitle: HAZARDOUS SUBSTANCE LIST UQA COMPOUNDSLast Calibration: 850314 09:39


A R I O O I O U

L

QUANT REPORT

fcator ID: JOHN Quant Time: 850319 00:02Injected at: 850318 23:25

File; >P0118::B2 ^ Dilution Factor: 1.00ameJ f'rfia C. H^rT

D File: HSLYOAitle: HAZARDOUS SUBSTANCE LIST UOA COMPOUNDS.ast Calibration: 850314 09:39


1)6)7)9)

.6)7).8)

•'8)=9)i15)

* BROMOCHLOROMETHANE•METHYLENE CHLORIDETR I CHLOROFLUOROMETHANEACROLEIN

1,2-DICHLOROETHANEl,2-DICHLOROETHANE-d4 (SURROG)

* 1 , 4-D I FLUOROBENZENEBENZENE*CHLOROBENZENE-d5TOLUENE (a CCC)TOLUENE-d8 (a SURROGATE)

^ETHYLBENZENE (a CCC)Im ^YLENE ———^m-XYLENE————— .kin p-VVLFIOF

4-BROMOFLUOROBENZENE (a SURRO)

10.857.239.498.27^ m

13.8913.7621.3818.7926.3525.3225.1228.4828 4033.84•5-5.8431.13

14084119100

10J187185303263380364361413

496496454

1365611358043854529

149972 ——747521970775600523855464573522316741918429050?9flcn —59905990

296994

503

81 T5

10113605039503546

—— 6-1

47

.00

.64

.68

.80

.88

.13

.00

.54

.00

.17

.23

.83

.25-S5-.47

ug/Lug/Lug/Lug/L

-ugrfug/ug/ug/ug/ug/ug/ug/ug/

ug/-wgr4_

LLLLLLLLL*. t— .

ug/L

* Compound is ISTD

00105

TOTRL ION CHROMflT06RflH>P0118 35.0-260.0 *MU.

TIC

.... i ... f ?? ... i 200 300 400 BOO360QOOH

320000-

280000-

240000-

200000-

160000-

laoooo-

80000-

40000-

4 ' 8 5» ' 16 ' 20 ' 2'4 -' 2'8 ' 3'2 ' &

Data File: >P0118:: 82Name: re^C r f

Id File: HSLUOATitle: HAZARDOUS SUBSTANCE LIST UOA COMPOUNDSLast Calibration: 850314 09:39

Operator ID: JOHNQaunt Time: 850319 00:02

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QUANT REPORT

Operator ID: BOB Quant Time: 850316 10:44Injected at: 850316 10:07

Data File: >P0073::B1 Dilution Factor: 1.00Name: r e<*,SJZ<*.\'t/\}0\\$f~ j*)/<k.\Kh i sc :



1) *BROMOCHLOROMETHANE 10.88 141 187617 50.00 ug/L6J METHYLENE CHLORIDE 7.26 85 18623 3.63 ug/L7) TRICHLOROFLUOROMETHANE 9.52 120 12281 1.39 ug/L15) CHLOROFORM (a CCC) 13.14 176 16837 1.68 ug/L17) l,2-DICHLOROETHANE-d4 (SURROG) 13.79 186 212182 35.88 ug/L18) »1,4-DIFLUOROBENZENE 21.40 304 807341 50.00 ug/L22) UINYL ACETATE 18.69 262 71021 98.30 ug/L33) *CHLOROBENZENE-d5 26.38 381 699260 50.00 ug/L38) TOLUENE (a CCC) 25.28 364 28586 2.56 ug/L39) TOLUENE-d8 (a SURROGATE) 25.09 361 621265 45.31 ug/L~45) 4-BROMOFLUOROBENZENE (a SURRO) 31.09 454 477324 53.83" ug/L

* Compound is ISTD

TOTAL ION CHROMAT08RAM^File >P0073 35.0-260.0 AMU.TIC

Mtmjl...............,, *p° ,.,.ff?, , <?°480000-

4400001

4000001j360000-

I

320000-

280000-

240000-

200000-

160000-

120000-

80000-

40000-

0-

Data File: >P0073::Q1Name: l ««;e -f uJ^tTerjMisc: ^



ftltOOl 1-8

QUANT REPORT

Operator ID: BOB Quant Time: 850316 11:26Injected at: 850316 10:49

Data File: >P0074::B1 Dilution Factor: 1.00Name: Ooeh CUtcmsc:ID Fi le: HSLUOATitle: HAZARDOUS SUBSTANCE LIST UQA COMPOUNDSLast Calibration: 850314 09:39


1). *BROMOCHLOROMETHANE 10.77 139 213961 50.00 ug/L2) CHLOROMETHANE (a SPCC) 2.12 5 121163 82.00 ug/L3) BROMOMETHANE 3.02 19 61640 63. 27 ug/L4) UINYL CHLORIDE (a CCC) 3.80 31 64918 41.48 ug/L5) CHLOROETHANE 4.77 46 46175 56.13 ug/L6). METHYLENE CHLORIDE 7.09 82 109764 18.76 ug/L7) TRICHLOROFLUOROMETHANE 9.42 118 308769 30.74 ug/L8) ACRYLONITRILE 8.64 106 65164 32.72 ug/L9) ACROLEIN 7.87 94 6291 7.80 ug/L10) ACETONE 7.80 93 45697 19.79 ug/L11) CARBON DISULFIDE 8.&4 109 1112977 68.84 ug/L12) 1,1-DICHLOROETHENE (a CCC) 10.19 130 160390 38. 21, .ug/L13) 1,1-D I CHLOROETHANE (a SPCC) 11.61 152 393637 37.59 ug/L14) trans-l,2-DICHLOROETHENE 12 .39 164 219814 47.51 ug/L15) CHLOROFORM (a CCC) 13.03 174 447055 39.20 ug/L16) 1,2-D I CHLOROETHANE 13.81 186 304436 36.08 ug/L17) l,2-DICHLOROETHANE-d4 (SURROG) 13.68 184 252309 37.41 ug/L18) *1,4-DIFLUOROBENZENE 21.36 303 1045026 50.00 ug/L19) 2-BUTANONE 15.55 213 1650 19.53 ug/L21) CARBON TETRACHLORIDE 15.55 213 165528 22.66 ug/L22) UINYL ACETATE 18.72 262 66369 70.97 ug/L23) BROMOD I CHLOROMETHANE 16.13 222 352337 32.90 ug/L24) 1,2-DICHLOROPROPANE (a CCC) 17.49 243 289873 37.39 ug/L25) trans-l,3-DICHLQROPROPENE 17.75 247 177867 35.96__ug/L26) TRICHLOROETHENE 18.26 255 347734 45.61 ug/L27) DIBROMOCHLOROMETHANE 18.97 266 304223 33.22 ug/L28) 1, 1, 2 -TR I CHLOROETHANE 19.10 268 242365 43. 44_ug/L29) BENZENE 18.78 263 700592 38.51 ug/L30) cia-l,3-DICHLOROPROPENE 17.75 247 177868 13.20 ug/L.31) 2-CHLQROETHYLUINYLETHER 20.14 284 187243 41., 8.0. _yg/L ..32) BROMOFORM (a SPCC) 21.75 309 234449 24.69 ug/L33) *CHLOROBENZENE-d5 26.34 380 767921 50.00 ug/L34) 2.-HEXANONE 23., 69 33.9 2.36496 33..Jl7_ug/L_35) 4-METHYL-2-PENTANONE 22.14 315 347391 33.91 ug/L36) i;i,2,2-TETRACHLOROETHANE(SPCC 24.08 345 355737 37.87 ug/L37) TETRACHLOROETHENE 24.01 344 328903 46. p7^ug/L__.38) TOLUENE <a CCC) • 25.24 363 513074 41.77 ug/L39) TOLUENE-d8 Ca SURROGATE) 25.05 360 747251 49.63 ug/L4J>) CHLQROBENZENE (a SPCC) 26.47 382 660724 41.12. ug/L41) ETHYLBENZENE <a CCC) 28.47 413 302207 42.30 ug/L42) STYRENE 32.54 476 635292 44.66 ug/L43) m-XYLENE 32.80 480 367232 45.62 ug/L44) o AND p-XYLENE 32.80 480 367232 § R t4g{j&f Li/L45) 4-BROMOFLUOROBENZENE (aSURRO), 31.05 453 529883 59.41 'u|/L

* Compound is ISTD

TOTAL ION CHROMflTOQRflMFilm >P0074 35.0-260.0 AMU.

TIC

360000-

320000-

280000-

840000-

200000-

160000-

120000-

aoooo-

40000;

0-

100 200 300• • • • i i i i i I i i i i .1 • . . . T .... i .... r.

6 ' l'g ' l'fi ' 20 ' 24 ' 2r8 ' '3'2' '

Data Fi le: >P0074: : BlName: »« b

Id Fila: HSLUOATitle: HAZARDOUS SUBSTANCE LIST UOA COMPOUNDSLast Calibration: 850314 09:39


JC?*,,-/''1'-*v

IQUANT REPORT

Operator ID: JOHN Quant Times 850318 17:06Injected at: 850318 16:26

Data File: >P0109::B2 Dilution Factor: 1.00Name: REAGENT WATERMisc: U/SURR AND INT STDS@50ug/l

ID File: HSIJJOATitle: HAZARDOUS SUBSTANCE LIST «JQA COMPOUNDSLast Calibration: 850314 09:39


1) *BROMOCHLOROMETHANE 10.85 140 129243 50.00 ug/L6) METHYLENE CHLORIDE 7.23 84 11875 3.36 ug/L7) TRICHLOROFLUOROMETHANE 9.56 120 6198 1.02 ug/L

15) CHLOROFORM (a CCC) 13.17 176 11553 1.68 ug/L17) l,2-DICHLOROETHANE-d4 (SURROG) 13.82 186 178133 57.43 ug/L18) *1,4-DIFLUQROBENZENE 21.44 304 580788 50.00 ug/L53) *CHLOROBENZENE-d5 26.41 381 553937 50.00 ug/L58) TOLUENE (a CCC) 25.38 365 16515 1.86 ug/L59) TOLUENE-d8 (a SURROGATE) 25.18 362 452954 48.38 ug/L43) m-XYLENE 28.54 414 1945 .33 ug/L45) 4-BROMOFLUOROBENZENE (a SURRO) 31.19 455 411839 54.35 ug/L

* Compound is ISTD

13

TOTAL ION CHROMflTOQRflM>P0109 35.0-360.0 *»u. RER6ENT U f t T E R H / S U R R RND INT STDSI

TIC

100 | 200 3pQ 400 , , . , t . 800

320000-

80000-

40000-

' la ' ' 1*6 ' ' 20 24 „ 28 32 36

Data File: >P0109::82Name: REAGENT WATERMisc: U/SURR AND INT STDS@50ug/l



flR1001 Ik

QUANT REPORT

Operator ID: JOHN Quant Time: 850318 17:50Injected at: 850318 17:08

Data File: >P0110::B2 Dilution Factor: 1.00Name: 50ug/l HSL STDMisc: U/SURR AND I NT STDS|150ug/l



1) *BROMOCHLOROMETHANE 10.85 140 117372 50.00 ug/L2) , CHLOROMETHANE (a SPCC) 2.26 7 72613 89.58 ug/L3) BROMOMETHANE 3.16 21 37824 70.77 ug/L4) UINYL CHLORIDE (a CCC) 3.94 33 38808 45.20 ug/L5) CHLOROETHANE 4.97 49 23241 51.50 ug/L6) hETHYLENE CHLORIDE 7.30 85 198750 61.93 ug/L7) TRICHLOROFLUOROMETHANE 9.56 120 270732 49.14 ug/L8) ACRYLONITRILE 8.85 109 72347 66.22 ug/L9) ACROLEIN 8.07 97 28798 65.13 ug/L1-W——ACETONE ______- — -————-—————Q-r&P———9?———183348———3:44.72 uy/'faHr>- CRRBOFrDTISULFTDE"-"—-——————————8-v*8——iii——996791——107.00 uy;'L12) 1,1-DICHLOROETHENE (a CCC) 10.33 132 136645 59.34 ug/L13) 1,1-DICHLOROETHANE (a SPCC) 11.75 154 339277 59.06 ug/L14) trans-l,2-DICHLOROETHENE 12.53 166 182332 71.84 ug/L15) CHLOROFORM (a CCC) 13.17 176 392365 62.72 ug/L16) 1,2-DICHLOROETHANE 13.95 188 288272 62.28 ug/L17) l,2-DICHLOROETHANE-d4 (SURRQG) 13.82 186 175762 62.39 ug/L18) *1,4-DIFLUOROBENZENE 21.38 303 542546 50.00 ug/L19) 2-BUTANONE 15.69 215 1356 30.91 ug/L21) CARBON TETRACHLORIDE 15.63 214 198303 52.28 ug/L23) BROMODICHLOROMETHANE 16.21 223 328788 59.13 ug/L24) 1,2-DICHLOROPRQPANE (a CCC) 17.57 244 239354 59.46 ug/L25) trans-l,3-DICHLOROPROPENE 17.82 248 157887 61.49 ug/L26) TRICHLOROETHENE 18.34 256 259955 65.68 ug/L27) DIBROMOCHLOROMETHANE 19.05 267 291832 61.39 ug/L28) 1,1,2-TRICHLOROETHANE 19.12 268 196249 67.76 ug/L29) BENZENE 18.79 263 589586 62.42 ug/L30) cis-l,3-DICHLOROPROPENE 17.82 248 157887 22.57 ug/L31) 2-CHLOROETHYLUINYLETHER 20.15 284 167419 71.99 ug/L32) BROMOFORM (a SPCC) 21.76 309 259935 52.73 ug/L33) *CHLOROBENZENE-d5 26.41 381 535667 50.00 ug/L34) 2-HEXANONE 23.77 340 246279 49.37 ug/L35) 4-METHYL-2-PENTANONE 22.15 315 349857 48.95 ug/L36) 1,1,2,2-TETRACHLOROETHANE<SPCC 24.09 345 328937 50.2037) TETRACHLOROETHENE , 24.02 344 259395 52.0938) TOLUENE (a CCC) 25.32 364 428239 49.39) TOLUENE-d8 (a SURROGATE) 25.12 361 439788 48.5840) CHLOROBENZENE (a SPCC) • 26.54 383 556019 49.61 ug/L41) ETHYLBENZENE (a CCC) 28.54 414 256255 51.41 ug/L42) STYRENE 32.61 477 508441 51.24 ug/L43) m-XYLENE 32/87 481 287167 51.14 ug/L44) o AND p-XYLENE 32.87 481 287167 51.14 ug/L45) 4-BROMOFLUOROBENZENE (a SURRO) ?l'JPRi8^j j |§?7116 54.19 ug/L

* Compound is ISTD

TOTflL ION CHROMfiTOSRflM

fA

til* >P0110 35.0-260.0 *au. oOug^l HSU STD tfxSURR HND INT SToSlTIC

100 200 < _ | < [ 300 400 500

400000-

360000;

320000-

280000;

240000

200000-»

160000-

120000;

80000;

40000

8 12 16 20 24 ,28 32 36

Data File: >P011Q:s82Name: 50ug/l HSL STDMisc: U/SURR AND INT STDS@50ug/i



v

AH 1001 16

an MO a

Bromofluofobenzene^BFB)£.v-t

Contract No.

Instrument ID _£?±L___ Date 3/*6/s£ff __

Lab ID \ -\-MH —— Data Release Authorized By:

m/e ION ABUNDANCE CRITERIA XRELATIVE ABUNDANCE

50

75

95

96

173

174

175

176

177

15.0 - 40.0% of the base peak

30.0 • 60.0% of the base peak

Base peak, 100% relative abundance


Less than 1 .0% of the base peak

Greater than 50.0% of the base peak

5.0- 9.0% of mass 174

Greater than 95.0%, but less than 101.0% of mass 174 . ;

5.0 - 9.0% of mass 176 .

M&49 ?-!|uO,o*7

&M0,1ofa##5" C?? 3 '

———— —————————— > ————— —— 1 ———— -__~ * . • vf **•-'. * j L

^ (Of " tffatyv \' •* 1 / •' fi* * pI

,> '•./-•;? 'value in parenthesis is X mass 174.Value in parenthesis is X mass 176.

THIS PERFORMANCE TUNE APPLIES TO THE "FOLLOWINGSAMPLES. BLANKS AND STANDARDS.

SAMPLE ID LAB ID DATE OF ANALYSIS TIME OF ANALYSIS

Ar*R|obM

«ata file header from : >80005' ' '• '' , - ~

le: BFB CRITERIA 12HR CK Operator: BOB MS 3/16/85 8:41: 50 ng BFB TUNING CHECK

Sys. #: 2 MS model: 96 SU/HU rev.: CA ALS # : 0^-Method file: BFBCRI Tuning file: MT2002 No. of extra records: 1^Source temp.: 150 Analyzer temp.: 180 Transfer line temp. : 170

Chromatographic temperatures : 220. 220. 0. 0. 0.Chromatographic times, min. : 4.0 8.0 0.0 0.0 0.0Chromatographic rate, deg/min: 26.0 0.0 0.0 0.0 0.0

AL

Fil* >B000536.0-260.0 AftU. BFB CRITERIH 12HR CKOO ng BFB TUNIN6 CHECK.'••- , TIC

•100/\saooo-•90

•70

-60

Z4000-

20000-

w :•60

16000-* • •

•40

•30r' l

8000-r80

4000-J r10

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Fil« >B0008- BFB CRITERIA 12HR CK60 ng BFB TUNIN8 CHECK • -v Scan-84Bpk fib 3186 "-; ' 9.84 min.m

£400-

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2000-

1600-

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44

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BFB CRITERIfl 12HR 6kfeo 113 BFB TUNIN8 CHECK Scan 649.84 Min.

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15 ±.

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88V 127

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177

SO" ' ' ' ' 80" " ' " l6'd " ' 120 " ' " 140 " ' " 160 " ' " 180 " ' " 260 '

•110

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r60'-so

:40•30

•10

. -towork ing.. .draw complete...

;NRM,100:TAB

>BO005 BFB CRITERIA 12HR CK50 ng BFB TUNING CHECK54 NRM

File: >B0005 Scan #: 54 Retn. time: 9.84

m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.

37.10 7.50 49.10 4.49 68.10 12.12 87.10 7.47 126.90 7.7838.10 6.15 50.10 22.13 69.10 14.72 88.1"0 11.02 173.90 99.0639.10 6.28 51.10 8.47 73.10 11.58 93.00 3.83 174.90 7.00«.00 15.98 55.10 4.21 74.00 17.83 94.10 11.46 175?90. 98.24

.10 5.30 57.10 7.69 75.10 47.71 95.00 100.00 177.00 7.9743.10 12.65 58.10 8.00 76.00 4.61 96.00 8.79 207.00 12.5944.00 50.78 61.10 4.65 77.00 3.70 105.00 4.87 208.00 3.0145.00 9.64 62.00 4.43 80.90 4.24

: AL

ti&Tune File: MT2002

CR List: B1,B2,B3CR Cut-off: 275 blocks.

Report Data ArchiveQuant I I ID Archive

Number of samples: 2 Stroke I I I I Output ArchiveBottle I I I I I I

Samp Data File Sample Name 1 I I I t I I Quant IDNo. Method File Misc Dat/$R|OOi (9 I I I I I I I Quant Output

001) >Pnn7T Rl ANK IJTTM TQTn/^IIRP flfl 1 V F N N M W«?l UDA

GC/MS TUNING AND MASS CALIBRATIONBromofluorobenzone (BFB)

'••' ' * •'- "*''fc. ' ''- " :;*.*:' 4 . , '." ~ "; ViJ

JOB*. ZPfrSd-'Z-fT CLIENT FrelC tt*r4__ ""T

Instrument in s Patu 3//&/&• r"________ Tim*

Lab ID —"> fl 00 / 0 Oata Refease Authorized By:

m/e ION ABUNDANCE CRITERIA KRELATIVE ABUNDANCE

50

75

95

96

173

-176

"

1 5.0 • 40.0% of the base peak

30.0 - 60.0% of the base peak

Base peak. 100% relative abundance


Less than 1.0% of the base peak

Greater than 50.0% of the base peak

5.0 - 9.0% of mass 174

Greater than 95.0%. but less than 101.0% of mass 174 -

5.0 - 9.0% of mass 176

*/.*y*,//o<?, o?, -*e.t 'n i . • ;, 'g, ,.$$£&•'

W.I - K '-?,i i >2"

Value in parenthesis is % man 174., Value in parenthesis is % mast 17ft.'THIS PERFORMANCE TUNE APPLIES TO THE FOLLOWINGSAMPLES. BLANKS AND STANDARDS.

-: SAMPLE ID DATE OF ANALYSIS

5S?#.

Aquarius Calibration File Management. AQUARIUS <840819.

Sample: 50ng 4-BFB Operator: JOHN MS 3/18/85 15:49Misc : EPA CRITERIA CHECKSys. #: 2 MS models 96 SW/HW rev.: CA ALS # : 0Method file: BFBCRI Tuning file: MT2002 No. of extra recordss 1Source temp.: 150 Analyzer temp.: 180 Transfer line temp. : 170


AL

File >B0010Bpk Bb 100

100-

90

80-

70-

60-

50-

40-

30-

ao-ifr

50

L ,Jo '

50ng 4-BFB EPR CRITERIA CHECK Scan 44SUB NRM ENH 9<18 min.

t

75\

.kji 111!

>8 174

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Aquarius Calibration File Management. AQUARIUS <840819.1120>

MS data file header from « >B0010

Sample: 50ng 4-BFB Operator: JOHN MS 3/18/85 15:49Misc : EPA CRITERIA CHECKSys. #: 2 MS model: 96 SW/HW rev.: CA ALS # : 0

Method file: BFBCRI Tuning file: MT2002 No. of extra records: 1Source temp.: 150 Analyzer temp.: 180 Transfer line temp. : 170


AL

Aquarius Calibration File Management. AQUARIUS <840819.1120>

SOng 4-BFB EPA CRITERIA CHECKSUB NRM ENH

File: >B0010 Scan #: 44 Retn. time: 9.18

m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.

37.10 7.48 51.10 6.90 69.10 9.75 88.00 4.37 127.00 .1438.10 6.80 55.10 .32 71.10 3.61 89.00 1.64 147.10 .2139.10 2.27 56.10 3.81 73.10 4.54 91.10 1.98 149.10 -.5640.00 -.11 57.10 3.13 74.10 15.94 93.10 2.64 151.00 4.26

• 41.10 .17 58.10 .10 75.10 47.37 94.10 10.19 163.00 1.08!&8 42.10 .32 59.10 -1.09 76.10 5.48 95.10 100.00 173.90 99.14* V43.10 .48 60.10 .38 77.10 2.31 96.10 7.45 174.90 7.66

44.10 .61 61.10 4.75 79.00 2.41 105.10 3.15 175.90 97.7045.10 .77 62.00 3.49 81.00 3.68 106.10 .63 176.90 7.0849.10 3.95 63.10 1.56 87.00 6.17 121.10 1.03 207.10 -3.5850.10 21.20 68.00 10.09

AL

AR10012-3

CONRAD & O'BRIEN, P.c. · conrad & o'brien, p.c. attorneys at law the drexel building 15th and...

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Transcript of CONRAD & O'BRIEN, P.c. · conrad & o'brien, p.c. attorneys at law the drexel building 15th and...