Concrete Project3

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    ConcreteAdmixtures

    Team Members:

    Navid Borjian

    Dean ArthurRey Alcones

    Angelique Fabbiani-Leon

    SRJC Engr. 45

    December 7, 2009

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    Concrete is composed mainly of cement (commonly Portland cement),

    aggregate, water, and chemical admixtures.

    Portland Cement

    Fine Aggregate

    Coarse Aggregate

    Chemical Admixtures

    http://localhost/var/www/apps/conversion/tmp/scratch_15/Zoom%20into%20Concrete.avihttp://localhost/var/www/apps/conversion/tmp/scratch_15/Zoom%20into%20Concrete.avi
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    Concrete solidifies and hardens after mixing with water and placement due

    to a chemical process known as hydration.

    The water reacts with the cement, which bonds the other components

    together, eventually creating a stone-like material.

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    Concrete is used more than any other man-made material in the world.

    The word concrete comes from the Latin word "concretus" (meaning

    compact or condensed).

    The first major concrete users were the Egyptians in around 2,500 BC and

    the Romans from 300 BC.

    Opus caementicium laying bare on a tomb near Rome. In

    contrast to modern concrete structures, the concrete

    walls of Roman buildings were covered, usually with

    brick or stone.

    Outer view of the Roman Pantheon, still the largest

    unreinforced solid concrete dome to this day.

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    Concrete has many applications and is used to make pavements, pipe,

    structures, foundations, roads, bridges/overpasses, walls and footings for

    gates.

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    Properties:

    Concrete has relatively high compressive strength, but significantly lowertensile strength, and as such is usually reinforced with materials that arestrong in tension (often steel).

    The elasticity of concrete is relatively constant at low stress levels but startsdecreasing at higher stress levels as matrix cracking develops.

    Concrete has a very low coefficient of thermal expansion, and as it maturesconcrete shrinks.

    All concrete structures will crack to some extent, due to shrinkage andtension.

    Concrete can be damaged by fire, aggregate expansion, sea water effects,bacterial corrosion, leaching, physical damage and chemical damage (fromcarbonation, chlorides, sulfates and distillate water).

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    Types of Concrete: There are various types of concrete for different applications that are created by changing the proportions of the

    main ingredients.

    The mix design depends on the type of structure being built, how the concrete will be mixed and delivered, and howit will be placed to form the structure.

    Examples include:

    Regular concrete

    Pre-Mixed concrete

    High-strength concrete Stamped concrete

    High-Performance concrete

    UHPC (Ultra-High Performance Concrete)

    Self-consolidating concretes

    Vacuum concretes

    Shotcrete

    Cellular concrete

    Roller-compacted concrete

    Glass concrete Asphalt concrete

    Rapid strength concrete

    Rubberized concrete

    Polymer concrete

    Geopolymer or Green concrete

    Limecrete

    Gypsum concrete

    Light-Transmitting Concrete

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    Regular Concrete

    Cement, Aggregate, and water

    Geopolymer (Green concrete)

    Fly Ash and Regular

    Concrete

    High Strength Concrete ~

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    Our Samples:

    Sample 1:

    Portland cement + coarse aggregate + fine aggregate + water

    Sample 2:

    Portland cement + coarse aggregate + fine aggregate + water +

    fly ash + water reducer

    Sample 3:

    Portland cement + coarse aggregate + fine aggregate + water +

    fly ash + water reducer + silica fume

    Sample 4:

    Portland cement + coarse aggregate + fine aggregate + water +

    fly ash + water reducer + silica fume + polypropylene fibers

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    Admixtures and Properties

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    Background

    There are two types of fly ash used

    in concrete which is classified as

    Class-C and Class-F.

    Class-F is more widely used

    because it is made from the burning

    of older anthracite (i.e. black coal ,

    black diamond, etc.) which is in

    abundance, with an opposing

    amount of uses.

    Fly ash that is not used in concrete

    is poured in landfills with its micro

    dust particles to flutter in theatmosphere.

    As far as human health is concern,

    fly ash in itself contains traces of

    heavy metals which pertains to

    arsenic, selenium, lead, and more.

    BenefitsFor every ton of Portland cement one ton of carbon dioxide is released into the atmosphere. Decreasing the

    amount of Portland cement would lower the carbon emissions. Replacing this portion with fly ash would help with

    decreasing the amount of Portland cement needed as well as making use for the ash that would otherwise be put

    in landfills or the factories.

    Decreasing the amount of water is always a benefit when it comes to cement. Fly ash lowers the amount of

    water needed because its smoother and spherical shape on a micro level allows the concrete to have more

    consistency without plasticizing with more water.Fly ash lowers the amount of voids (compared to regular cement) because of the particles small size.

    Fly Ash Background Being a pozzolan, fly ash has the

    ability to act cementitious with the

    presence of cement and water. This

    process is able to happen because

    of fly having silica and alumina.

    Fly ash on a micro level takes the

    form of a sphere which allows the

    particle to fit easily within the pores

    of the concrete. This circular form of

    the fly ash also allows the concrete

    to be more fluid and workable. When

    it comes to setting the concrete, its

    a benefit for workers by it having

    this feature making it easier to place.

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    Silica FumeProperties

    When silica is in combination of alkali

    which is found in the concentration of

    concrete a destructive reaction occurs.

    When alkali is in the presence of silica

    hydroxyl ions expansion occurs causeing

    crakes, which is why a low-alkali cement

    is used in the presence of silica fume. Silica fume, like fly ash, is a pozzolan

    and has cement properties. Silica fume

    as the ability to act as if it were cement

    (with the presence of water and cement

    of course) because its extremely small

    particles (at the size of about 1/100th to a

    cement particle) , having a considerableamount of silicon dioxide, and large

    surface area makes the admixture an

    active pozzolan.

    When concrete has silica fume and low

    water the outcome of the concrete

    becomes highly resistant which causes

    penetration by chloride ions.

    Benefits

    When concrete has silica fume the strength is greatly increased,

    having an average compressive strength of 15,000psi.

    With silica fume being very resistant to corrosion, concrete with

    silica fume is now being used in bridges and for rebuilding older

    structures.

    Silica fume molecules have the ability to combine with calcium

    hydroxide (which is exhaled from the cement during the

    hydration process) which increases the cements overall

    durability.

    Since silica fumes particle is extremely small which makes it

    able to fit into the voids made from the spacing between the

    cements particle, it reduces permeability. Being a microfiller

    helps protect the reinforcing steel from the concrete.

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    Polypropylene Fibers

    BenefitsWith the addition of polypropylene fiber in the mixture of concrete it enhances the toughness and tensile strength. When

    concrete is by itself it has the tendency to be very brittle especially in the area of a tensile test which is where the fibers

    come into play to build in where regular concrete lags, which can increase the compressive strength to a dramatic level.

    In coastal areas there is a high concentration of chloride ions from the salty air, this creates corrosion with the steel

    product which produces rust as a result. This rust has the capacity to expand four to ten times larger than the iron causing

    a large expansion which makes crakes and voids. Polypropylene fibers now are underway in replacing the reinforcing

    steel in concrete, which has a much greater strength and can reach up to 20k psi.

    Background Polypropylene is a recent additive to cement as of the 1960s,

    whereas other fibers are underway of being tested strength

    wise for concrete.

    PropertiesWhen regular concrete is under a great amount of compression it will spilt and deform on the spot into separate

    pieces once it reaches its greatest tensile load. Mixing sporadically polypropylene fibers into the cement will

    balance this effect by attaching to the other piece that wants to spilt away and maintain both sides for a longer

    duration.

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    Making Our

    Samples

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    Slump Test

    The goal of the test is to measure theconsistency of concrete through out the mix.

    "Slump" is simply a term coined to describe how

    consistent a concrete sample is.

    The test also further determines the workabilityof concrete, how easy is it to handle, compact,

    and cure concrete.

    By adjusting the cement-water ratio or addingplasticizers to increase the slump of the concretewill give a desired mix.

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    Process

    Fill one-third of the cone with the concrete mixture. Thentamp the layer 25 times using the steel rod in a circularmotion, making sure not to stir.

    Add more concrete mixture to the two-thirds mark. Repeat

    tamping for 25 times again. Tamp just barely into theprevious layer(1")

    Fill up the whole cone up to the top with some excessconcrete coming out of top, then repeat tamping 25 times.(If there is not enough concrete from tamping compression,stop tamping, add more, then continue tamping at previousnumber)

    Remove excess concrete from the opening of the slumpcone by using tamping rod in a rolling motion until flat.

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    Slowly and carefully remove the cone by

    lifting it vertically (5 seconds +/- 2

    seconds), making sure that the concrete

    sample does not move.

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    After the concrete stabilizes, measure the

    slump-height by turning the slump cone

    upside down next to the sample, placing

    the tamping rod on the slump cone andmeasuring the distance from the rod to the

    original displaced center.

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    A change in slump height would

    demonstrate an undesired change in the

    ratio of the concrete ingredients; the

    proportions of the ingredients are thenadjusted to keep a concrete batch

    consistent. This homogeneity improves the

    quality and structural integrity of the curedconcrete.

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    Data & Results

    What We Learned

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    Our Procedures

    Test first sample at 11 days, second sample at 18 days.

    Test third sample (comprised of two cylinders) at 25 days.

    First two samples and one of the third samples loaded wet

    side down.

    Last sample loaded dry side down.

    Photograph and record ultimate failure loads.

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    Common Failure Modes

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    Our Failure ModesTest 1

    Load:28000#Psi:990

    Load:32000#Psi:1132

    Load:38500#

    Psi:1362Load:33000#

    Psi:1167

    Sample 2Sample 1

    Sample 3 Sample 4

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    Our Failure ModesTest 2

    Load:46000#Psi:1626

    Load:25500#Psi:902

    Load:20000#

    Psi:707

    Load:62500#

    Psi:2210

    Sample 1Sample 2

    Sample 3 Sample 4

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    Our Failure ModesTest 3 (Two Cylinders)

    (Averaged)

    Load: 33750#

    Psi:1194

    (Averaged)

    Load:28250#

    Psi:999

    (Averaged)

    Load:39500#

    Psi:1397

    (Averaged)

    Load:41500#

    Psi:1468

    Sample 1 Sample 2

    Sample 3 Sample 4

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    Results from Data

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    65

    9 11 13 15 17 19 21 23 25 27

    P

    ressure(Kilo-Pounds)

    Cure Time (Days)

    Concrete Age/Admixture Strengthening

    Sample 1 Sample 2 Sample 3 Sample 4

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    Interpretation of Data

    General trend of all samples (except sample 2) were

    upward.

    Silica Fume and Silica Fume/Fiber mix did appear to

    increase overall compressive strength.

    Fly Ash data may be inconclusive when considering other

    samples upward trends.

    Appears that all samples may have been affected more by

    the constant water ratio (.45) than admixtures.

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    Potential Sources of Error

    (Based on Standardized Testing Methods)

    A test result is the average of at least two standard-cured strength specimens made from the sameconcrete sample and tested at the same age. In mostcases strength requirements for concrete are at an

    age of 28 days

    To provide for a uniform load distribution whentesting, cylinders are capped generally with sulfurmortar

    The loading rate on a hydraulic machine should bemaintained in a range of 20 to 50 psi/s

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    Conclusion

    Failure mode observed was non standard, but appearspotentially related to machined grooves in testingapparatus.

    Lack of over-all data points makes first two testsrelatively inconclusive.

    Concrete never reached potential compressivestrength (even with anomalous samples).

    Water Ratios appear to affect compressive strengthmore than admixtures.

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    References

    Images:

    http://img.ecplaza.com/my/metfabExportHouse/7.jpg

    http://www.fhwa.dot.gov/pavement/pccp/pubs/04150/images/fig138.gif

    https://reader009.{domain}/reader009/html5/0423/5ade014690145/5ade015d5eb0a.jpg

    https://reader009.{domain}/reader009/html5/0423/5ade014690145/5ade015e4a40d.jpg

    http://www.engineeringfiber.com/images/products/polypropylene_fiber.jpg

    Text:

    http://en.wikipedia.org/wiki/Anthracite

    http://www.toolbase.org/Technology-Inventory/Foundations/fly-ash-concrete

    http://www.nytimes.com/2008/12/25/us/25sludge.html

    http://www.silicafume.org/general-silicafume.html

    http://www.concretenetwork.com/concrete/concrete_admixtures/silica_fume.htm

    http://www.uritc.uri.edu/media/finalreportspdf/536101.pdf

    www.nrmca.com/aboutconcrete/cips/35p.pdf

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    Superior Supplies Inc.40 Ridgway Ave

    Santa Rosa, CA 95401(707) 546-7864

    Very special thanks to Burt Lockwood and everyone

    at Superior Supplies Inc.! As a group we cannot

    express enough how much we appreciate the help,

    materials, time and knowledge given to us for this

    concrete compression project!