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Jotamastic 87 Comp A
Not available.
Liquid.
1-800-424-9300(Staffed 24/7)
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification:
:
:
:
Supplier's details : Jotun Paints, Inc.9203 Highway 23Belle Chasse, LA 70037Telephone: (800) 229-3538 or+1 [email protected]
Relevant identified uses of the substance or mixture and uses advised against
Uses in Coatings - Industrial useUses in Coatings - Professional use
Identified uses
Jotamastic 87 Comp A
Product code : 515
Product description : Paint.
515;519;527;1549 1,2 515
epoxy mastic ^(ValidationDate). 1Coatings: Solvent-borne.
Approved
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1SKIN SENSITIZATION - Category 1SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
AQUATIC HAZARD (LONG-TERM) - Category 3
Classification of the
substance or mixture
:
Signal word : Danger.
Hazard statements : Flammable liquid and vapor.Causes serious eye damage.
Causes skin irritation.May cause an allergic skin reaction.May cause damage to organs through prolonged or repeated exposure.Harmful to aquatic life with long lasting effects.
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).
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Section 2. Hazards identificationPrevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep containertightly closed. Avoid release to the environment. Do not breathe vapor or spray. Washhands thoroughly after handling. Contaminated work clothing should not be allowed out
of the workplace.
Response : Get medical attention if you feel unwell. IF ON SKIN (or hair): Take off immediately allcontaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash withplenty of soap and water. Take off contaminated clothing. If skin irritation or rashoccurs: Get medical attention. IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or physician.
Storage : Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national andinternational regulations.
Hazards not otherwise
classified
: None known.
Section 3. Composition/information on ingredients
epoxy resin (MW 700) 10 -
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Section 4. First aid measures
Get medical attention immediately. Call a poison center or physician. Wash out mouthwith water. Remove dentures if any. Remove victim to fresh air and keep at rest in aposition comfortable for breathing. If material has been swallowed and the exposedperson is conscious, give small quantities of water to drink. Stop if the exposed personfeels sick as vomiting may be dangerous. Do not induce vomiting unless directed to doso by medical personnel. If vomiting occurs, the head should be kept low so that vomitdoes not enter the lungs. Chemical burns must be treated promptly by a physician.Never give anything by mouth to an unconscious person. If unconscious, place inrecovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Wash with plentyof soap and water. Remove contaminated clothing and shoes. Wash contaminatedclothing thoroughly with water before removing it, or wear gloves. Continue to rinse forat least 10 minutes. Chemical burns must be treated promptly by a physician. In theevent of any complaints or symptoms, avoid further exposure. Wash clothing beforereuse. Clean shoes thoroughly before reuse.
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case ofinhalation of decomposition products in a fire, symptoms may be delayed. The exposedperson may need to be kept under medical surveillance for 48 hours.
Skin contact
Ingestion :
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it issuspected that fumes are still present, the rescuer should wear an appropriate mask orself-contained breathing apparatus. It may be dangerous to the person providing aid togive mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with waterbefore removing it, or wear gloves.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
Adverse symptoms may include the following:stomach pains
Adverse symptoms may include the following:pain or irritationrednessblistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxideshalogenated compoundsmetal oxide/oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur andthe container may burst, with the risk of a subsequent explosion. Runoff to sewer maycreate fire or explosion hazard. This material is harmful to aquatic life with long lastingeffects. Fire water contaminated with this material must be contained and preventedfrom being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO,water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools andexplosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatmentplant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via alicensed waste disposal contractor. Contaminated absorbent material may pose thesame hazard as the spilled product. Note: see Section 1 for emergency contactinformation and Section 13 for waste disposal.
:
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools andexplosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate wastedisposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any informationin Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment beforeentering eating areas. See also Section 8 for additional information on hygienemeasures.
Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see Section 10) and food and drink. Storelocked up. Eliminate all ignition sources. Separate from oxidizing materials. Keepcontainer tightly closed and sealed until ready for use. Containers that have beenopened must be carefully resealed and kept upright to prevent leakage. Do not store inunlabeled containers. Use appropriate containment to avoid environmentalcontamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with ahistory of skin sensitization problems should not be employed in any process in whichthis product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor ormist. Do not ingest. Avoid release to the environment. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enterstorage areas and confined spaces unless adequately ventilated. Keep in the originalcontainer or an approved alternative made from a compatible material, kept tightlyclosed when not in use. Store and use away from heat, sparks, open flame or any otherignition source. Use explosion-proof electrical (ventilating, lighting and materialhandling) equipment. Use only non-sparking tools. Take precautionary measuresagainst electrostatic discharges. Empty containers retain product residue and can behazardous. Do not reuse container.
:
Precautions for safe handling
xylene ACGIH TLV (United States, 4/2014).
STEL: 651 mg/m 15 minutes. STEL: 150 ppm 15 minutes. TWA: 434 mg/m 8 hours.
TWA: 100 ppm 8 hours.OSHA PEL (United States, 2/2013).
TWA: 435 mg/m 8 hours. TWA: 100 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 655 mg/m 15 minutes. STEL: 150 ppm 15 minutes. TWA: 435 mg/m 8 hours.
TWA: 100 ppm 8 hours.benzyl alcohol AIHA WEEL (United States, 10/2011).
TWA: 10 ppm 8 hours.2-methylpropan-1-ol ACGIH TLV (United States, 4/2014).
TWA: 152 mg/m 8 hours.
TWA: 50 ppm 8 hours.NIOSH REL (United States, 10/2013).
TWA: 150 mg/m 10 hours. TWA: 50 ppm 10 hours.OSHA PEL (United States, 2/2013).
TWA: 300 mg/m 8 hours. TWA: 100 ppm 8 hours.OSHA PEL 1989 (United States, 3/1989).
TWA: 150 mg/m 8 hours. TWA: 50 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protectionethylbenzene OSHA PEL 1989 (United States, 3/1989).
TWA: 100 ppm 8 hours. TWA: 435 mg/m 8 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m 15 minutes.NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours. TWA: 435 mg/m 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m 15 minutes.OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours. TWA: 435 mg/m 8 hours.
ACGIH TLV (United States, 4/2014). Notes:
K TWA: 20 ppm 8 hours. Form:
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard (NIOSH-approved P95) if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, checkduring use that the gloves are still retaining their protective properties. It should benoted that the time to breakthrough for any glove material may be different for differentglove manufacturers. In the case of mixtures, consisting of several substances, theprotection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unlessthe assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist beforehandling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothingshould include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proofventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Washcontaminated clothing before reusing. Ensure that eyewash stations and safetyshowers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selectedbased on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative densityVapor density
Solubility
Liquid.
Not available.
1.44 to 1.555 g/cmNot available.
Not available.
Insoluble in the following materials: cold water and hot water.
Characteristic.Odor
pH
Various colors.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 35C (95F)
Not available.
Not available.
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive
(flammable) limits
: Not available.
Decomposition temperature : Not available.
12.02 to 12.98 pounds/gallon
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Information on toxicological effects
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Section 11. Toxicological information
xylene LC50 Inhalation Gas. Rat 6700 ppm 4 hoursLD50 Oral Rat 4300 mg/kg -
2-methylpropan-1-ol LC50 Inhalation Vapor Rat 19200 mg/m 4 hoursLD50 Dermal Rabbit 3400 mg/kg -
LD50 Oral Rat 2460 mg/kg -ethylbenzene LC50 Inhalation Gas. Rabbit 4000 ppm 4 hours
LD50 Dermal Rabbit >5000 mg/kg -LD50 Oral Rat 3500 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Information on the likely
routes of exposure
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
2-methylpropan-1-ol Category 3 Not applicable. Respiratory tractirritation andNarcotic effects
Name Category
Name Category
ethylbenzene Category 2 Not determined ears
Aspiration hazard
Name Result
ethylbenzene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
: Not available.
Potential acute health effects
Classification
xylene - 3 -
Product/ingredient name NTPIARCOSHA
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure. Oncesensitized, a severe allergic reaction may occur when subsequently exposed to very lowlevels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation No specific data.
Adverse symptoms may include the following:stomach pains
Adverse symptoms may include the following:pain or irritationrednessblistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 6520,8 mg/kgDermal 10620,7 mg/kg
Inhalation (vapors) 77,6 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate
effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Section 12. Ecological information
Toxicity
epoxy resin (MW 700) Acute EC50 1,4 mg/l Daphnia 48 hoursAcute LC50 3,1 mg/l Fish - fathead minnow 96 hours
2-methylpropan-1-ol Chronic NOEC 4000 g/l Fresh water Daphnia - Daphnia magna 21 days
ethylbenzene Acute EC50 7,2 mg/l Algae 48 hours
Acute EC50 2,93 mg/l Daphnia 48 hoursAcute LC50 4,2 mg/l Fish 96 hours
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Acute EC50 17,4 to 21,5 mg/l Freshwater
Daphnia - Daphnia magna 48 hours
Acute IC50 37 mg/l Algae 72 hours
Product/ingredient name SpeciesResult Exposure
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
epoxy resin (MW 700) 2.64 to 3.78 31 lowxylene 3,12 8.1 to 25.9 lowhydrocarbons, c9-unsatd.,polymd.
3,627 - low
benzyl alcohol 0,87
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Section 14. Transport information
Paint.
3
III
Paint.
3
III
Paint.
1263
3
III
1263 1263
DOT
Classification
IMDG IATA
UN number
UN propershipping name
Transport
hazard class(es)
Packing group
Environmental
hazards
Special precautions for user
Transport in bulk accordingto Annex II of MARPOL
73/78 and the IBC Code
No. No. No.
Transport within users premises:always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in theevent of an accident or spillage.
: Not available.
:
TDG
Classification
1263
Paint.
3
III
No.
ADR/RID
1263
Paint.
3
III
No.
Mexico
Classification
1263
Paint.
3
III
No.
Additional information
Reportable quantity
1245 lbs / 565,22 kg [99,71 gal / 377,44 L]Package sizes shipped in quantities less than the product reportable quantity are notsubject to the RQ (reportable quantity) transportation requirements.
Emergency schedules (EmS): F-E, S-EMarine pollutant: No.
-
-
Tunnel restriction code: (D/E)Hazard identification number: 30Special provisions: 640E
-
DOT Classification
TDG Classification
Mexico Classification
ADR/RID
IMDG
IATA
:
:
:
:
:
:
IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5(applicable to receptacles < 30 litre capacity).
ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to
receptacles < 450 litre capacity).
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307: ethylbenzene
Clean Water Act (CWA) 311: xylene; ethylbenzene
:
Clean Air Act Section 112
(b) Hazardous AirPollutants (HAPs)
: Listed
Clean Air Act Section 602
Class I Substances
: Not listed
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Not determined.
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Section 15. Regulatory information
The following components are listed: BENZYL ALCOHOL; ISOBUTYL ALCOHOL;IRON OXIDE DUST; XYLENE
WARNING:This product contains a chemical known to the State of California to cause cancer.
Massachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
xylene 1330-20-7 5 -
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Section 15. Regulatory information
ethylbenzene Yes. No. 41 g/day (ingestion) No.54 g/day
(inhalation)
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventory
Australia : Not determined.
Canada : Not determined.
China : Not determined.
Europe : Not determined.
Japan : Not determined.
Republic of Korea : Not determined.
Malaysia : Not determined.
New Zealand : Not determined.
Philippines : Not determined.
Taiwan : Not determined.
Section 16. Other information
22.10.2015.
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
22.10.2015.
27.05.2015.
2
Procedure used to derive the classification
Classification Justification
Flam. Liq. 3, H226 On basis of test dataSkin Irrit. 2, H315 Calculation methodEye Dam. 1, H318 Calculation methodSkin Sens. 1, H317 Calculation methodSTOT RE 2, H373 Calculation method
Aquatic Chronic 3, H412 Calculation method
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Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Indicates information that has changed from previously issued version.
References : Not available.
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficientMARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations