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    Coal Combustion Theory

    Combustion is a rapid chemical reaction

    between fuel  and oxygen. When combustible

    elements of f uel combine with O2, heat energy

    comes out. During combustion combustible

    elements like Carbon, Sulfur, Hydrogen etc

    combine with oxygen and produce respective

    oxides. The  source of oxygen in fuelcombustion is air. By volume there is 21 % of

    Oxygen presents in air and by weight it is

    23.2 %. Although there is 79 % (by volume)

    nitrogen in air but it plays no role in

    combustion.

     

    Actually Nitrogen carries heat produced during combustion to steam boiler  stack. As per

    combustion theory  the quantity of air required for combustion is that which provides

    sufficient O2  to completely oxidize combustible elements of fuel. This quantity of air is

    normally known as STOICHIOMETRIC AIR requirement. This amount of air depends upon

    the nature of fuel. STOICHIOMETRIC AIR requirements for different fuels are obtained by

    analysis of fuel and they are given in tabular form below,

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    Fuel STOICHIOMETRIC AIR mass / unit mass of fuel

    Bituminous Coal 11.18

    Anttiasite Coal 10.7

    Coke 9.8

    Liquite 7.5

    Peat 5.7

    Residual Fuel Oil 13.85

    Distillate Fuel Oil(Gas Oil) 14.48

    Natural Gas(Methane Base) 17.3

     

    Combustion of Coal

    For sufficient air,

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    We have already said that mass wise there is 23.2 % O2  presents in air. Hence the

    amount of air required to provide 2.67 gm of O 2  is

    As per ideal combustion theory, after combustion of one gm carbon(C), product ofcombustion contains only 3.67 gm of CO2  and (11.5 - 2.67 =) 8.83 gm of N2 

    Coal Combustion for Insufficient Air

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    By weight, the requirement of air for providing this much O2  is

    After combustion of one gm carbon(C), product of combustion contains only 2.33 gm of 

    CO and (5.75 - 1.33 =) 4.42 gm of N2.

    From equation (1) and (2) it is clear that due to insufficient air combustion, the heat

    lose during 1 gm of coal combustion  is (33.94 - 10.12) = 23.82 kj

    Combustion of Sulfur

     

    So, air required for 1 gm sulfur combustion, is

    So, combustion product, after completing 1 gm of sulfur combustion, contains 2 gm of

    SO2  and (4.31 - 1 = ) 3.31 gm of N2 

    Combustion of Hydrogen

     

    From combustion theory of C, S and H2  it is found that 2.67 gm oxygen is required for 1

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    gm carbon combustion, which implies 2.67C gm oxygen is required for C gm carbon, 1

    gm oxygen is required for 1 gm sulfur combustion, which implies S gm oxygen is

    required for S gm sulfur and 8 gm oxygen is required for 1 gm hydrogen combustion,

    which implies 8H gm oxygen is required for H gm hydrogen.

    Hence 1 gm of coal (fuel) which contains C gm carbon, S gm sulfur and H gm hydrogen,

    requires (2.67C + S + 8H) gm of oxygen for efficient combustion.

    Some amount of oxygen may be contained in the fuel itself in form of differentcompounds and it takes part in combustion also. If O is the original weight of the oxygen

    presents in 1 gm of fuel, net requirement of oxygen for sufficient coal combustion  is

    (2.67C + S + 8H - O) gm.For that the amount of air required is

    This above mentioned analysis is called coal analysis for combustion.Before efficient combustion can take place, several basic requirements must be fulfilled,

    most important of them are,

    a) The combustion must be done with sufficient oxygen

    b) There must be sufficient turbulence to promote throughout mixing of combustible and

    oxygen.

    Coal Content in Proximate Analysis

    Moisture = 8 %, volatile material = 20 to 25 %, fixed carbon = 40%, ash = 30%. Fixed

    carbon's combustion temperature = 900°C. Basic component of ash is Si, Al and others.

    Now fusion temperature of Si is 1200°C.

    If the furnace temperature raises above 1100°C then Si will be fused and deposited on

    the tubes, as slag, causing improper heat transfer.

    Now to dilute the temperature excess air and complete combustion are required.

    Now, the volatile material plays important role in combustion. Less the volatile material

    flame will be high which may be chance for flame impingement of S/H coil.

    For fulfilling the point some practical steps to taken. In practice it is always necessary to

    supply more air to the combustion system than it is theoretically required. Reason for

    that air and fuel mixing process in any combustion system, as it is not possible to

    ensure complete and intimate mixing of the fuel with the necessary oxygen at the point

    of injection. So some excess air is required for proper combustion to a reasonable

    minimum power, stack loss and unburnt carbon in ash.

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    Generally 20% excess air is allowed.

    % of Excess

    Air

    Unburnt Carbon in

    Ash

    C.V. Liberated in

    FurnaceUnburnt Gas Loss

    0 % 10 % 75 %CO2, O2, N2, H2O, CO,

    CH4(15 %)

    15 % 2 % 97 %   CO2, O2, N2, H2, CO(1 %)

    100 % 0.5 % 99.5 %   CO2, O2, N2

    Third process is unsatisfactory for extra fan power and convey huge amount of heat.

    The coal particles should be at least 74 microns in 200 mesh. So pulveriser is required

    for

    i) better utility of coal

    ii) saving of time.

    There are mainly three losses occurred during coal combustion,

    1) Unburnt gas loss

    2) Dry flue gas loss

    3) Combustible in ash loss.

    Unburnt Gas Loss

     

    Remember the unburnt gas loss is mainly the result of burning carbon to carbon

    monoxide instead of carbon dioxide. It is seen that heat release in CO reaction is onethird of that in CO2  reaction. So adequate supply of oxygen or excess air will quickly

    reduce this loss to zero.

    Dry Flue Gas Loss

     

    A further loss of heat is that due to dry flue gas. It is often referred to as the stack loss.

    If more excess air is admitted, this loss increases.

    Combustible in Ash Loss

    This loss is very high when there is little or no excess air because mixing of combustible

    material and oxygen is so poor. As the air quantity is increased, the loss falls rapidly.

    However it does not reach to "zero" because the loss depends upon two factors firstly on

    air - coal mixture and secondly on fineness of pulverized coal grain. More fine grain of

    pulverized coal helps to complete combustion more perfectly and resulting less

    combustible in ash loss. In practice, though, a stage is reached where it is not worth

    grinding the coal any finer because it will cost more to grind than the extra heat release.

    Practically the loss does not reach to zero. generally a high volatile coal is crushed until

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    Objective Questions on Electrical Power Generation (MCQs)

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    75% of its bulk passes through a 200 mesh whereas a low volatile coal is crushed until

    80% passes through similar mesh.

    The loss gets less as excess air is added, reaches a minimum and then increases as still

    more excess air is added. Thus there is only one quantity of excess air which will give

    lower loss for the combustion of a particular fuel. For bituminous coal 15.5% excess air

    is optimum requirement for Coal Combustion.

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