Classification of Minerals Descriptive Mineralogyruby.colorado.edu/~smyth/G3010/System01.pdf ·...
Transcript of Classification of Minerals Descriptive Mineralogyruby.colorado.edu/~smyth/G3010/System01.pdf ·...
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Descriptive Mineralogy
Classification of Minerals
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Classification of the Minerals• Native Elements• Halides• Sulfides• Oxides• Hydroxides• Carbonates• Sulfates• Phosphates
• Silicates– Orthosilicates– Sorosilicates– Cyclosilicates– Chain Silicates– Layer Silicates– Tektosilicates
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Native Elements
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Native Elements
• Fe, Co, Ni: Meteorites• Platinum Group: (Ru, Rh, Pd, Os, Ir, Pt): Mafic
Igneous Rocks• Coinage metals: Cu, Ag, Au
– Cu, Ag: Supergene Enrichments (Sulfide Oxidation)– Au: Low Temperature Hydrothermal, Placer
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Native Elements
• Carbon:– Graphite: Metamorphic Rocks– Diamond: Kimberlites
• Sulfur (+Se):– Salt Domes (Sulfate reduction),– Volcanos (H2S oxidation)
• Tellurium (Te) Telluride oxidation
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Halides
• Halite (NaCl) and Sylvite (KCl): Evaporites• Fluorite (CaF2) Low temperature hydrothermal• Cryolite (Na3AlF6): Pegmatite
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Sulfides
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Fe Sulfides
• Fe:– Pyrite FeS2
– Marcasite FeS2
– Pyrrhotite Fe1-xS– Troilite FeS– Arsenopyrite FeAsS
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Fe-S Diagram
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Cu Sulfides
• Cu Sulfides– Chalcocite Cu2S– Covellite CuS
• Cu-Fe Sulfides– Chalcopyrite CuFeS2
– Bornite Cu5FeS4
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Other Sulfides
• Sphalerite ZnS• Molybdenite MoS2
• Galena PbS• Realgar AsS and Orpiment As2S3
• Arsenopyrite FeAsS• Stibnite Sb2S3
• Cinnabar HgS
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Simple Oxides• Hemioxides
– Cuprite (Cu2O)– Ice (H2O)
• Monoxides– Periclase (MgO)– Wüstite (FeO)– Manganosite (MnO)– Lime (CaO)– Zincite (ZnO)– Bromellite (BeO)– Tenorite (CuO)
• Sesquioxides– Corundum (Al2O3)– Hematite (Fe2O3)– Bixbyite (Mn2O3)
• Dioxides– Rutile (TiO2)– Anatase (TiO2)– Brookite (TiO2)– Cassiterite(SnO2)– Pyrolusite(MnO2)
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Simple Oxides
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Hemi-Oxides (M2O)
• Ice (H2O) Hexagonal• Cuprite (Cu2O)• Why not Na2O?
– (Na radius too large)
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Monoxides (MO)
• Rocksalt oxides MgO, FeO, MnO, CaO, NiO– Periclase MgO - Wuestite FeO– Manganosite MnO– Lime CaO– Bunsenite NiO
• Zincite oxides: zincite ZnO, bromellite BeO• Other monoxides:
– TenoriteCuO, MontroyditeHgO
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Periclase Structure
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Sesquioxides (M2O3)
• Corundum Group– Corundum Al2O3
– Hematite Fe2O3
– Karelianite V2O3 and Eskolaite Cr2O3
• Other Sesquioxides– Bixbyite Mn2O3
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Dioxides
• Rutile Group– Rutile TiO2; Anatase; Brookite– Cassiterite SnO2
– Pyrolusite MnO2
– Stishovite SiO2
• Uraninite (UO2) and Thorianite (ThO2)• Baddeleyite ZrO2
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Complex Oxides
• Two or more different cations– Spinel Group: M2TO4
– Ilmenite Group : FeTiO3
– Pseudobrookite Group : A2BO5
– Perovskite Group : CaTiO3
• High Pressure silicate analogues
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Spinel Group
• Spinel MgAl2O4
• Hercynite FeAl2O4
• Chromite FeCr2O4
• MagnesiochromiteMgCr2O4
• Magnetite Fe2+Fe3+2O4
• Magnesioferrite MgFe2O4
• Gahnite ZnAl2O4
• Ulvospinel TiFe2O4
• Ringwoodite Mg2SiO4
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Spinel Structure
Space Group Fd3m
Edge sharing octahedra
Cell edge ~8.5Å
Two octahedra per
Tetrahedron
Mg Al 2 O 4 (Normal) or
Al (MgAl) O4 (Inverse)
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Ilmenite Group
• Ilmenite FeTiO3• Geikielite MgTiO3• MgSiO3
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Ilmenite Structure• Corundum Structure• Space Group R-3• Alternating layers of
Fe and Ti Octahedra• Face-sharing
Octahedra• Dense
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Pseudobrookite Group
• Pseudobrookite Fe2+Ti2O5
• Ferro-pseudobrookite TiFe3+2O5
• Armalcolite (Mg,Fe2+)Ti2O5
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Pseudobrookite Structure
• Space GroupBbmm
• M1 dark• M2 lighter
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Perovskite
• Perovskite CaTiO3• MgSiO3 (Lower mantle phase)
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Perovskite Structure
• Pseudo-cubic• Orthorhombic• Space Group
Pbnm
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Accessory Oxides
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Hydroxides
• Brucite Mg(OH)2
• Gibbsite Al(OH)3
• Boehmite and Diaspore AlO(OH)• Bauxite (Mixed Al hydroxides)• Goethite FeO(OH) (+Lepidochrosite)• Limonite Fe(OH)3
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Carbonates
• Calcite Group• Aragonite Group• Dolomite Group• Other carbonates
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Calcite Group
• Calcite CaCO3
• Magnesite MgCO3
• Siderite FeCO3
• Rhodochrosite MnCO3
• Smithsonite ZnCO3
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Calcite Structure
• Space GroupR-3c
• Divalent cationradius < 1.00Å
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Aragonite Group• Aragonite CaCO3
• Strontianite CaCO3
• Witherite BaCO3
• Cerussite PbCO3
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Aragonite Structure
• Space GroupPbnm
• Cation Radius >1.00Å
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Dolomite Group
• Dolomite CaMg(CO3)2
• Ankerite CaFe(CO3)2
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Other Carbonates (+Nitrates)
• Malachite (Green) Cu2(OH)2CO3
• Azurite (Blue) Cu3(OH)2(CO3)2
• Cu1+ or Cu 2+?• Niter KNO3
• Soda Niter NaNO3
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Sulfates
• Gypsum CaSO4•2H2O• Anhydrite CaSO4
• Celestine SrSO4
• Barite BaSO4
• Anglesite PbSO4
• Alunite KAl3(OH)6(SO4)2
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Gypsum Anhydrite
• CaSO4•2H2O• Hardness 2• Evaporite Mineral• Contains molecular
water
• CaSO4
• Hardness 3-3.5• Evaporite Mineral• Contains no
molecular water
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Celestine Barite Anglesite
• SrSO4 BaSO4 PbSO4• Hydrothermal Hydrothermal OxHydrothermal
•
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Phosphates, Tungstates, Vanadates
• Phosphates are based on P5+O4 tetrahedron.• By far the most important one is apatite.• Ca5(PO4)3(OH,F,Cl)• Tungstates and Vanadates are based on W6+O4
and V5+O4 tetrahedra. Some are isostructuralwith apatite and so included in the samegroup, but they are usually considered oxides.
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Apatite
• Ca5(PO4)3(OH,F,Cl)• Hydroxy- Fluor-, and Chlor- apatites• Major component of teeth and bone• Common accessory mineral in igneous and
metamorphic rock.• Some sedimentary phosphates (phosphate
sands).