Chemistry STPM Sem 3 MSAB Pre-Trial Question

UJIAN PENILAIAN PRA-PENTAKSIRAN MSAB SEMESTER 3 /2014

SULIT 2

Section A [ 15 marks ]

Answer all questions in this section. Write your answer on the spaces provided in page 5

1. Naphthalene is an active component in mothballs. Its structural

formula is shown below. How many hydrogen atoms are there in the

molecule?

A 8 B 10 C 11 D 12

2. What happens when one mole of ethane is mixed in the dark at room temperature with six moles of

chlorine?

A CCl3CCl3 and HCl are formed. B CH3CH2Cl and HCl are formed.

C CH3CCl3 and HCl are formed. D There is no reaction.

3. Which one of the following is a propagation step in the reaction between methane and chlorine when

they are irradiated with light?

A. H + Cl2 HCl + Cl B. CH4 + Cl+ CH3

+ + HCl

C. CH4 + Cl CH3 + HCl D. CH4 + Cl2 CH3 + Cl + HCl

4. Which of the following statements is not caused by the delocalisation of pi electrons in benzene?

A. The C-C bond lengths in benzene are identical.

B. Each carbon atom in benzene undergoes sp2 hybridisation.

C. Benzene tends to undergo substitution rather than addition reactions.

D. The enthalpy of hydrogenation of benzene is higher than that of cyclohexene.

5. A hydrocarbon X contains 85.7% carbon and 14.3% of hydrogen by mass. X reacts with hydrogen in

the presence of nickel catalyst. The structural formula of X could be.

A. CH3CH2CH2CH2CH2CH3 B. CH3CH=CHCH2CH2CH3

6. Which of the following statements about the two alkenes CH3CH2CH=CH2 and CH3CH=CHCH3 are

incorrect?

I. Both exhibits cis - trans isomerism.

II. Both may be polymerised.

III. Both reacts with bromine to give 1,4-dibromobutane.

IV. Both reacts with hydrogen to form butane

A. I and II only B. I and III only

C. II and III only correct D. II and IV only correct

7. Trichloroethene, CHCl=CCl2, is widely used as a dry-cleaning agent. With which of the following

does trichloroethene react to give a chiral product?

A. Br2 B. H2 C. HCl D. NaOH

C. D.


SULIT 3

8. Which of the following reactions is an example of electrophilic addition?

I. CH2=CH2 + H2SO4 CH3CH2OSO3H

II. CH2=CH2 + Br2 + H2O CH2BrCH2Br + CH2BrCH2OH

III. C6H6 + HNO3 C6H5NO2 + H2O

IV. C6H6 + 3 Cl2 C6H6Cl6

A. I only correct B. I and II only correct

C. I, II and III only correct D. I, II and IV only correct

9. Which of following statements about the reaction below could be correct?

C6H6 + HNO3 4SO2H.conc

C6H5NO2 + H2O

A. The reaction is carried out at temperature between 0C to 10C.

B. The reaction is a nucleophilic substitution reaction.

C. The nitronium ion attacks benzene ring at the initial stage of reaction.

D. The concentrated sulphuric acid acts as a strong oxidising agent in the reaction.

10. Which reagent and conditions are used to bring about the reaction shown?

A. Cl2 in the dark

B. Cl2 with AlCl3

C. Cl2 with ultraviolet light

D. concentrated HCl catalysed by ZnCl2 heated under reflux

11. An amine compound is formed according to the following reaction.

What are the reagents required in step I and step II of the above reactions?

Step I Step II

A Ammonia gas Hydrogen gas

B Ammonia gas Hydrogen cyanide

C Potassium cyanide Lithium tetrahydridoaluminate

D Aqueous Ammonia gas Sodium hydroxide in ethanol

12. An amine is prepared in the following reaction.

C2H5I + 2NH3 C2H5NH2 + NH4I

What is the type of reaction take place?

A. Electrophilic addition B. Electrophilic substitution

C. Nucleophilic addition D. Nucleophilic substitution


SULIT 4

13. It is estimated that for every chlorine atom formed from a fluorohaloalkane in the stratosphere, one

hundred thousand ozone atoms may be destroyed. Which of the following statements provides an

explanation for this?

A. They achieve high activation energy by absorbing ultraviolet light.

B. They eliminate oxygen from ozone - oxygen equilibrium.

C. They initiate ionisation of oxygen molecule.

D. They are regenerated in a chain reaction with ozone.

14. The scheme below shows the formation of compound Z from propan-2-ol.

Which of the following compounds could be X, Y, and Z?

X Y Z

A PCl5 CH3CH2CH

O

B PCl5

C SOCl2

D Cl2

15. When aqueous bromine is added to an organic compound Y, the colour of bromine is discharged. To

which classes of compound could Y belong?

I. Alkene II. Phenol

III. Haloalkane IV. Aliphatic alcohol

A. I and II only correct B. I and III only correct

C. II and III only correct D. II and IV only correct


SULIT 5

MAKTAB SULTAN ABU BAKAR

UJIAN PENILAIAN PRA-PENTAKSIRAN SEM 3 2014

SUBJECT : CHEMISTRY

Name : ____________________________________ Tingkatan : UPPER 6 ____________

Section A

[15 marks]

1 6 11

2 7 12

3 8 13

4 9 14

5 10 15

Section B [ 15 marks ]

Answer all questions in this section

16. Crotyl alcohol, , is a colourless liquid which is used as a solvent.

(a) In the boxes below, write the structural formula of the organic compound(s) formed when crotyl

alcohol is reacted separately with each reagent under suitable conditions. [4 x 1 mark]

i. Hydrogen gas catalysed by

platinum

ii. Phosphorous pentachloride

iii. Bromine water

iv. hot concentrated acidified

potassium manganate (VII)

(b) Explain the stereoisomer present in crotyl alcohol and draw the isomers stated. [3 marks]

...

..

Isomers present :


SULIT 6

17. Organic chemistry is the chemistry of carbon compounds. The types of organic reactions that you

have studied are listed below.

Addition Elimination Hydrolysis Oxidation Reduction Substitution

Addition and substitution reactions are further described as follows.

Electrophilic Nucleophilic Free radical

Complete the table below. Fill in the central column by using only the types of reaction given in the

lists above. Use both lists when appropriate. In the right hand column give the name(s) or formula(e)

of the reagent(s) you would use to carry out the reaction given. [4 x 2 marks]

Organic reaction type of reaction Reagent and Condition

CH3CH2CH2CH3 CH3CH2CHBrCH3

CH3CH(OH)CH3 CH3CH=CH2

CH3CH=CH2 CH3CH(OH)CH2OH

CH3CH2Cl CH3CH2NH2

Section C [30 marks]

Answer any two questions in this Section

18. (a) A liquid hydrocarbon, M, has the following composition by mass: C, 92.3%; H, 7.7%.

i. Calculate the empirical formula of the hydrocarbon. [2 marks]

ii. Given the molecular mass of M is 104, deduce the molecular formula and molecular structure of

M [2 marks]

iii. When M react with hydrogen chloride gas, it gives two products which follow Markovnikoff's

rules. Draw the structures of the two products and label according to major and minor products

formed [2 marks]

iv. State one use of M in industries [1 mark]

(b) The following reaction scheme shows the formation of different

State the reagents or compound formed from A to H in the above reaction scheme. [8 marks]


SULIT 7

19. The reaction - energy profile for the reaction between haloalkane, P, with molecular formula C4H9Cl

and a solution of ethanolic potassium potassium cyanide below.

Energy / kJ

Reactants

Products

Reaction coordination

(a) From the reaction - energy profile, name and describe the mechanism of the reaction take place ,

and suggest the possible molecular structure that undergoes the mechanism stated [8 marks]

(b) Explain the effects toward the rate of reaction for the following changes

i. the concentration of potassium cyanide increased [2 marks]

ii. haloalkane P is replaced with another haloalkane with the formula C3H7Br [2 marks]

(c) Another isomer of is not favourable to the mechanism proposed in (a). Draw and name the

structure of the isomer described to explain why it does not favour such mechanism

[3 marks]

20. (a) The table below list the pKa value for three hydroxyl compound in aqueous solution at 298 K

Name of compound Formula pKa

Cyclohexanol

18

Phenol

10

4-nitrophenol

9.2

i. Arrange the three compound above in the order of decreasing acidity and explain your answer

[6 marks]

ii. State a chemical test used to distinguish between cyclohexanol and phenol [3 marks]

(b) 2,3-dimethylpentan-3-ol dehydrated according to Saytzeff's rule using suitable reagent and

condition. By drawing the structure of the products formed, explain how the yield of the products

varies according to the rules [6 marks]

Chemistry STPM Sem 3 MSAB Pre-Trial Question

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