Chemistry Investigatory Project on Evaporation of Liquid

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    KENDRIYA VIDYALAYA

    JANAKPURI

    SESSION : 2016-17

    INVESTIGATORY PROJECT-

     EVAPORATION OF LIQUID

    Name : DIVYANSU

    R!"" N!# : 17

    C"a$$ : %II

    Se&'(!) : A

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    CERTIFICATE

    This is to certify that Divyanshu of 

    Class XII ‘A’ has satisfactorily completed the

     project on “ EVAPORATION OF LIQUID” under 

    the guidance of M!"#M $%MA& "'T(

    Chemistry during the session)*+,(+-!

    "lace. $!/!0ana1puri "#M $%MA 

    Date. "'T(Chemistry

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    ACKNO*LEDGE+ENT

    I2d li1e to e3press my greatest gratitude to the people 4ho have helped 5supported me

    throughout my project! I’ m grateful to +R#

    PRE+ KU+AR, PGT-Cem($'./  for his

    continuous support for the project& from initial

    advice 5 encouragement to this day!

    6pecial than1s of mine goes to my colleague

    4ho helped me in completing the project 7y

    giving interesting ideas& thoughts 5 made this

     project easy and accurate!I 4ish to than1s my parents for their 

    undivided support 5 interest 4ho inspired me

    5 encouraged me to go my o4n 4ay& 4ithout

    4hich I 4ould 7e una7le to complete my

     project! At last 7ut not the least I 4ant to

    than1s my friends 4ho appreciated me for my

    4or1 5 motivated me and finally to 'od 4ho

    made all the things possi7le!!!

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    CONTENTS

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    INTRODUCTION

    #vaporation is the process 4here7y atoms

    or molecules in a liuid state Eor solid state

    if the su7stance su7limesF gain sufficient

    energy to enter the gaseous state!

    The thermal motion of a molecule must 7e

    sufficient to overcome the surface tension

    of the liuid in order for it to evaporate&

    that is& its 1inetic energy must e3ceed the

    4or1 function of cohesion at the surface!

    #vaporation therefore proceeds more

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    uic1ly at higher temperature and in

    liuids 4ith lo4er surface tension! 6ince

    only a small proportion of the molecules

    are located near the surface and are

    moving in the proper direction to escape at

    any given instant& the rate of evaporation is

    limited! Also& as the faster(moving

    molecules escape& the remaining molecules

    have lo4er average 1inetic energy& and the

    temperature of the liuid thus decreases!

    If the evaporation ta1es place in a closed

    vessel& the escaping molecules accumulate

    as a vapor a7ove the liuid! Many of the

    molecules return to the liuid& 4ith

    returning molecules 7ecoming more

    freuent as the density and pressure of the

    vapor increases! Ghen the process of

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    escape and return reaches euili7rium& the

    vapor is said to 7e Hsaturated&H and no

    further change in either vapor pressure and

    density or liuid temperature 4ill occur!

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     Aim

    To compare the rate of evaporation of 

    various liuids!

     Apparatus

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    1.  China dish

    2.  "ipette E +* ml F

    # Geighing machine

     Materials Required 

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    +! ; different liuid samples

    EAcetone&Gater&Diethyl ether are ta1en

    hereF

    Theory

    Factors influencing rate of evaporation:-

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    +! Concentration of the su7stance

    evaporating in the air! If the air already has

    a high concentration of the su7stance

    evaporating& then the given su7stance 4ill

    evaporate more slo4ly!

    )! Concentration of other su7stances in the

    air! If the air is already saturated 4ith other 

    su7stances& it can have a lo4er capacity for 

    the su7stance evaporating!

    ;! Temperature of the su7stance! If the

    su7stance is hotter& then evaporation 4ill

     7e faster!

    :! lo4 rate of air! This is in part related to

    the concentration points a7ove! If fresh airis moving over the su7stance all the time&

    then the concentration of the su7stance in

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    the air is less li1ely to go up 4ith time&

    thus encouraging faster evaporation! In

    addition& molecules in motion have more

    energy than those at rest& and so the

    stronger the flo4 of air& the greater the

    evaporating po4er of the air molecules!

    forces 1eeping the molecules together in

    the liuid or solid state the more energy

    that must 7e input in order to evaporate

    them!

    6# S.a&e a.ea a)3 'em4e.a'.e:

    -Because molecules or atoms evaporate

    from a liuid’6 surface& a larger surface

    area allo4s more molecules or atoms to

    leave the liuid& and evaporation occurs

    more uic1ly! or e3ample& the same

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    amount of 4ater 4ill evaporate faster if

    spilled on a ta7le than if it is left in a cup!

    ?igher temperatures also increase the rate

    of evaporation! At higher temperatures&

    molecules or atoms have a higher average

    speed& and more particles are a7le to 7rea1

    free of the liuid’6 surface! or e3ample& a

    4et street 4ill dry faster in the hot sun

    than in the shade!

     ntermolecular forces: -

    Most liuids are made up of molecules&

    and the levels of mutual attraction among

    different molecules help e3plain 4hy some

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    liuids evaporate faster than others!

    Attractions 7et4een molecules arise

     7ecause molecules typically have regions

    that carry a slight negative charge& and

    other regions that carry a slight positive

    charge! These regions of electric charge are

    created 7ecause some atoms in the

    molecule are often more electronegative

    Eelectron(attractingF than others! The

    o3ygen atom in a 4ater E?)9F molecule is

    more electronegative than the hydrogenatoms& for e3ample& ena7ling the o3ygen

    atom to pull electrons a4ay from 7oth

    hydrogen atoms! As a result& the o3ygen

    atom in the 4ater molecule carries a partialnegative charge& 4hile the hydrogen atoms

    carry a partial positive charge! Gater

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    molecules share a mutual attractionJ

     positively charged hydrogen atoms in one

    4ater molecule attract negatively charged

    o3ygen atoms in near7y 4ater molecules!

    Intermolecular attractions affect the rate of 

    evaporation of a liuid 7ecause strong

    intermolecular attractions hold the

    molecules in a liuid together more tightly!

    As a result& liuids 4ith strong

    intermolecular attractions evaporate more

    slo4ly than liuids 4ith 4ea1intermolecular attractions! or e3ample&

     7ecause 4ater molecules have stronger

    mutual attractions than gasoline molecules

    Ethe electric charges are more evenlydistri7uted in gasoline moleculesF&

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    gasoline evaporates more uic1ly than

    4ater!

     !rocedure

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    +! Ta1e three china dishes!

    )! "ipette out +* ml of each sample!

    ;! Dish A( Acetone

      Dish B( Gater 

      Dish C( Diethyl ether 

    :! ecord the 4eights 7efore 7eginning the

    e3periment!

    an hr and 4ait patiently!

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    ,! ecord the 4eights of the samples

    after the given time!

    -! Compare the prior and present

    o7servations!

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     !hotograph

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    "#servation

    Amount of each liuid sample ta1enL+*ml

    Gater 

    EgmF

    Acetone

    EgmF

    Dieth

    ethe

     Egm

    Geight of dish

    Geight of

    Edishsu7stanceF

     7efore evaporation

    Geight of

    Edishsu7stanceF

    after evaporation

    Geight of su7stanceevaporated

    $onclusions

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    The rate of evaporation of the given threeliuids is in order .(

    Diethyl #therNAcetoneNGater 

     7ecause Gater has e3tensive hydrogen 7onding in 7et4een o3ygen atom of one

    molecule and hydrogen atom of another

    molecule! But this is a7sent in the case of

    Acetone!

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     %%&"'RA!() 

    https.OOen!4i1ipedia!orgO4i1iO#vaporation

    http.OO444!encyclopedia!comOtopicOevapor 

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    gory.MeasuringPinstrumentsPEevaporation

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    https://en.wikipedia.org/wiki/Evaporationhttp://www.encyclopedia.com/topic/evaporation.aspxhttp://www.encyclopedia.com/topic/evaporation.aspxhttps://commons.wikimedia.org/wiki/Category:Measuring_instruments_(evaporation)https://commons.wikimedia.org/wiki/Category:Measuring_instruments_(evaporation)https://commons.wikimedia.org/wiki/Category:Measuring_instruments_(evaporation)http://www.encyclopedia.com/topic/evaporation.aspxhttp://www.encyclopedia.com/topic/evaporation.aspxhttps://commons.wikimedia.org/wiki/Category:Measuring_instruments_(evaporation)https://commons.wikimedia.org/wiki/Category:Measuring_instruments_(evaporation)https://commons.wikimedia.org/wiki/Category:Measuring_instruments_(evaporation)https://en.wikipedia.org/wiki/Evaporation